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Deuterium isotope effects in the ninhydrin reaction of primary amines (1982)

Yu, P. H. ; Davis, B. A.

Springer

Cellular and molecular life sciences 38 (1982), S. 299-300

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ISSN: 1420-9071

Source: Springer Online Journal Archives 1860-2000

Topics: Biology , Medicine

Notes: Summary The rate of development of Ruhemann's purple in the ninhydrin reaction of two deuterated primary amines, αα-d2-p-tyramine and αα-d2-β-phenylethylamine, is significantly reduced It appears to be a primary isotope effect and indicates that the cleavage of the carbon-hydrogen bond at the α-position is involved in the rate-determining step of the color reaction.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01949352

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