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Synthesis of soluble polyarylates with a propeller-like structure via Diels-Alder reaction (1998)

Zuev, Vjacheslav V. ; Kever, Jeno J. ; Sazanov, Yuri N.

Weinheim : Wiley-Blackwell

Macromolecular Rapid Communications 19 (1998), S. 631-634

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ISSN: 1022-1336

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Soluble propeller-like polyarylates with M¯n ≈ 1 × 104 and melting in the range 200-220°C were synthesized via one-pot simultaneous Diels-Alder (using anthracene or (E,E)-1,4-diphenylbutadiene as enophile and the fumaroyl moiety as dienophile) and polycondensation reaction. Thermal properties of all polyarylates were evaluated. Decomposition occurs in two steps between approximately 300-400°C. The first step is due to retro-Diels-Alder reaction and the second one to main-chain decomposition.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

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