ISSN:
0323-7648
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Permittivity ∊′ and dielectric loss ∊″ of novolac have been determined in the temperature interval from - 150 to 150°C and in the frequency interval from 102.5 to 106 Hz. Novolac exhibits a main and a secondary relaxation process. For the main relaxation a master curve of ∊″ was calculated, the shape of which was described by the Havriliak - Negami function (HN). The parameters of the HN fit were interpreted by a model that relates the values to the polymer structure. Furthermore, the temperature dependence of the dielectric relaxation times was analyzed by a WLF approach for the main relaxation and an Arrhenius approach for the secondary relaxation. The dielectric relaxation times of the main relaxation were correlated with the electrical conductivity and the melt viscosity.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/actp.1995.010460109
