ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Preparation and Vibrational Spectra of Dimeric (Isopropylidenamino)dimethylborane, -alane, and -gallaneN-Chloro-2-propanimine (1) reacts with trimethylboron, -aluminium, and -gallium to form the dimeric imino compounds [Me2C=N—MMe2]2 (M=B, Al, Ga) (2-4), which, according to the vibrational spectra, occur as M2N2 four-rings of the point group D2h. Also, the vibrational spectrum of 1 is reported.
Notes:
N-Chlor-2-propanimin (1) reagiert mit den Trimethylverbindungen von Bor, Aluminium und Gallium unter Bildung der dimeren (Isopropylidenamino)dimethyl-Derivate [Me2C=N—MMe2]2 (M=B, Al, Ga) (2-4), die nach den Schwingungsspektren zentrosymmetrische M2N2- Vierringe (Symmetrie D2h) bilden. Das Schwingungsspektrum von 1 wird ebenfalls mitgeteilt.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19771101225
