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Tricarbonyl(diphenylborylbenzol)chrom(0) (1973)

Deberitz, Jürgen ; Dirscherl, Karl ; Nöth, Heinrich

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 106 (1973), S. 2783-2785

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ISSN: 0009-2940

Keywords: Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Description / Table of Contents: Tricarhonyl(diphenylboryl benzene)chromium(0)Diphenylboron bromide reacts with bis[tricarbonyl(phenyl)chromio]mercury (1) to yield tricarbonyl(diphenylborylbenzene)chromium(0) (2), whose spectroscopic data indicate weaker π-bonding between the boron atom and the phenyl groups as compared to the free ligand.

Notes: Diphenylborbromid reagiert mit Bis[tricarbonyl(phenyl)chromio]quecksilber (1) zu Tricarbonyl(diphenylborylbenzol)chrom(0) (2), dessen spektroskopische Daten auf eine geringere π-Wechselwirkung zwischen dem Boratom und den Phenylgruppen, verglichen mit dem freien Liganden, hinweisen.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19731060905

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