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  • 1
    Electronic Resource
    Electronic Resource
    Tricarbonyl(diphenylborylbenzol)chrom(0) (1973)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 106 (1973), S. 2783-2785 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Tricarhonyl(diphenylboryl benzene)chromium(0)Diphenylboron bromide reacts with bis[tricarbonyl(phenyl)chromio]mercury (1) to yield tricarbonyl(diphenylborylbenzene)chromium(0) (2), whose spectroscopic data indicate weaker π-bonding between the boron atom and the phenyl groups as compared to the free ligand.
    Notes: Diphenylborbromid reagiert mit Bis[tricarbonyl(phenyl)chromio]quecksilber (1) zu Tricarbonyl(diphenylborylbenzol)chrom(0) (2), dessen spektroskopische Daten auf eine geringere π-Wechselwirkung zwischen dem Boratom und den Phenylgruppen, verglichen mit dem freien Liganden, hinweisen.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19731060905
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  • 2
    Electronic Resource
    Electronic Resource
    Triphenylphosphorin-chrom(0)-tricarbonyl (1970)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 103 (1970), S. 2541-2547 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: (Triphenylphosphorine)chromium(0)tricarbonylReaction of 2,4,6-triphenylphosphorine with chromium hexacarbonyl in boiling dibutyl ether affords the red-brown crystalline (2,4,6-triphenylphosphorine) chromium (0) tricarbonyl. The i. r., n.m.r., and mass spectra of this complex suggest a π-bonded phosphorin ring system.
    Notes: Die Umsetzung von 2.4.6-Triphenyl-phosphorin mit Chromhexacarbonyl liefert in siedendem Dibutyläther rotbraunes 2.4.6-Triphenyl-phosphorin-chrom(0)-tricarbonyl. Die IR-, NMR-und Massenspektren der Verbindung sprechen für ein π-gebundenes Phosphorinsystem.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19701030825
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  • 3
    Electronic Resource
    Electronic Resource
    Tricarbonyl(triphenylphosphorin)molybdän(0) (1973)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 106 (1973), S. 2222-2226 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Tricarbonyl(triphenylphosphorine)molybdenum(0)Reaction of 2,4,6-triphenylphosphorine with tricarbonyl(mesitylen)molybdenum(0) yields tricarbonyl(2,4,6-triphenyl-h6-phosphorine)molybdenum(0) at room temperature. The π-complex is also formed intramolecularly from pentacarbonyl(2,4,6-triphenylphosphorine)molybdenum(0) in boiling dibutylether.
    Notes: Die Umsetzung von 2,4,6-Triphenylphosphorin mit Tricarbonyl(mesitylen)molybdän(0) liefert bereits bei Raumtemperatur Tricarbonyl(2,4,6-triphenyl-h6-phosphorin)molybdän(0). Der π-Komplex bildet sich auch intramolekular aus Pentacarbonyl(2,4,6-triphenylphosphorin)molybdän(0) in siedendem Dibutyläther.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19731060716
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