ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Organometallic Lewis Bases, XV. Photochemical Synthesis of Hetero-Metal-Metal Bonds in Carbonyl Iron ComplexesPhotolysis of the complexe (CO)4Fe-As(CH3)2-M′ [M′ = Mo(CO)3C5H5, W(CO)3C5H5, Mn(CO)5, Co(CO)4,] in solution yielded the hetero-dinuclear complexes with metal-metal bonds (CO)4Fe[μ.-As(CH3)2]M″ [M″ - Mo(CO)2C5H5, W(CO)2C5H5, Mn(CO)4, Co(CO)3] (2a-d). They are orange to red-brown, stable towards air, and very volatile.
Notes:
Photolyse der Komplexe (CO)4Fe-As(CH3)2-M′ [M′ = Mo(CO)3C5H5, W(CO)3C5H5, Mn(CO)5, Co(CO)4] in Lösung ergab die Hetero-Zweikernkomplexe mit Metall-Metall-Bindung (CO)4Fe[μ-As(CH3)2]M″ [M″ = Mo(CO)2C5H5, W(CO)2C5H, Mn(CO)4, Co(CO)3] (2a-d). Sie sind orange bis rotbraun, luftstabil und sehr flüchtig.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19731060819
