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  • 1
    Electronic Resource
    Electronic Resource
    Metallorganische Lewis-Basen, XIII. Einfach verbrückte Zweikernkomplexe des Typs (CO)5 Cr-As(CH3)2-M′ (1973)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 106 (1973), S. 2550-2555 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Organometallic Lewis Bases, XIII. Single-bridged Dinuclear Complexes of the Type (CO)5Cr-As(CH3)2-M′Metathetical reaction between (CO)5Cr. As(CH3)2Cl and NaM′ [M′ = Mo(CO)3C5H5, W(CO)3C5H5, Mn(CO)5, Re(CO)5, Fe(CO)2C5H5 and Co(CO)4] leads to the dinuclear complexes (CO)5Cr-As(CH3)2-M′ (2-7) with a single arsenic bridge. They are stable towards air and moisture. Attempts to convert them into clusters thermally or photochemically result in their disproportionation with formation of homonuclear complexes.
    Notes: Durch doppelte Umsetzung zwischen (CO)5Cr AS(CH3)2Cl und NaM′ [M′ - Mo(CO)3C5H5, W(CO)3C5H5, Mn(CO)5, Re(CO)5, Fe(CO)2C5H5 und Co(CO)4] entstehen die Zweikernkomplexe (CO)5Cr-As(CH3)2- M′ (2-7) mit einfacher Arsin-Brücke. Sie sind luft- und feuchtigkeitsstabil. Beim Versuch, sie thermisch oder photochemisch in Cluster umzuwandeln, disproportionieren sie unter Bildung homonuclearer Komplexe.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19731060817
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  • 2
    Electronic Resource
    Electronic Resource
    Metallorganische Lewis-Basen, XIV. Einfach arsenverbrückte zweikernige Eisencarbonyl-Komplexe (1973)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 106 (1973), S. 2556-2562 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Organometallic Lewis Bases, XIV. Singly Arsenic Bridged Dinuclear Iron Carbonyl ComplexesTreatment of Fe2(CO)9 with (CH3)2As=N(CH3)2 afforded (CO)4Fe·As(CH3)2 =N(CH3)2 (1), which reacted with HCI to yield (CO)4Fe·As(CH3)2Cl (2) Reaction of 2 with carbonyl metalates NaM′ resulted in the formation of the arsenic-bridged dinuclear complexes (CO)4Fe -As(CH3)2-M′ (4-8) with M′ -Mo(CO)3C5H5, W(CO)3C5H5, Mn(CO)5, Fe(CO)2C5H5, and Co(CO)4 as intensely coloured crystalline compounds.
    Notes: Aus Fe2(CO)9 und (CH3)2As=N(CH3)2 wurde (CO)4Fe. As(CH3)2=N(CH3)2 (1) gewonnen, dessen Umsetzung mit HCl zu (CO)4Fe As(CH3)2Cl (2) führte. Reaktion von 2 mit Carbonylmetallaten NaM′ ergab die arsenverbrückten Zweikernkomplexe (CO)4Fe-As(CH3)2 -M′ (4-8) mit M′ = Mo(CO)3C5H5, W(CO)3C5H5, Mn(CO)5, Fe(CO)2,C5H5 und Co(CO)4 als kräftig farbige kristalline Verbindungen.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19731060818
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  • 3
    Electronic Resource
    Electronic Resource
    Metallorganische Lewis-Basen, XV. Photochemische Synthese von Hetero-Metall-Metall-Bindungen in Carbonyl-Eisen-Komplexen (1973)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 106 (1973), S. 2563-2569 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Organometallic Lewis Bases, XV. Photochemical Synthesis of Hetero-Metal-Metal Bonds in Carbonyl Iron ComplexesPhotolysis of the complexe (CO)4Fe-As(CH3)2-M′ [M′ = Mo(CO)3C5H5, W(CO)3C5H5, Mn(CO)5, Co(CO)4,] in solution yielded the hetero-dinuclear complexes with metal-metal bonds (CO)4Fe[μ.-As(CH3)2]M″ [M″ - Mo(CO)2C5H5, W(CO)2C5H5, Mn(CO)4, Co(CO)3] (2a-d). They are orange to red-brown, stable towards air, and very volatile.
    Notes: Photolyse der Komplexe (CO)4Fe-As(CH3)2-M′ [M′ = Mo(CO)3C5H5, W(CO)3C5H5, Mn(CO)5, Co(CO)4] in Lösung ergab die Hetero-Zweikernkomplexe mit Metall-Metall-Bindung (CO)4Fe[μ-As(CH3)2]M″ [M″ = Mo(CO)2C5H5, W(CO)2C5H, Mn(CO)4, Co(CO)3] (2a-d). Sie sind orange bis rotbraun, luftstabil und sehr flüchtig.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19731060819
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  • 4
    Electronic Resource
    Electronic Resource
    Metallorganische Lewis-Basen, I. Elementorganische Mercaptide als Liganden in Pentacarbonylchrom(0)-Komplexen (1970)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 103 (1970), S. 3563-3579 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Organometallic Lewis Bases, I. Organoelement Mercaptides as Ligands in Pentacarbonylchromium(0) ComplexesThe compounds (CO)5Cr·S(R)—Sn(CH3)3 were prepared by photochemical reaction between Cr(CO)6 and the ligands. Their reaction with organo-element substrates RnE—Y (Y = alkyl or halogen) yields the complexes (CO)5Cr·S(R)—ERn with E = Li, Mg, B, C, P, As, S. New transition metal sulfur complexes arc obtained by interaction of (CO)5Cr·S(R) -Sn(CH3)3 with organometallic halides of gold, iron, manganese, and rhenium. Chemical and spectroscopic investigations show that for E = P or As the Cr(CO)5 moiety binds to these elements and not to sulfur.
    Notes: Die Verbindungen (CO)5Cr·S(R)—Sn(CH3)3 (1, 2) lassen sich photochemisch aus Cr(CO)6 und dem Liganden bereiten. Ihre Umsetzung mit elementorganischen Substraten RnE—Y (Y = Alkyl oder Halogen) überführt sie in Komplexe (CO)5Cr·S(R)—ERn (3-9) mit E = Li, Mg, B, C, P, As, S; mit organometallischen Halogeniden des Goldes, Eisens, Mangans und Rheniums erhält man neue Übergangsmetall-Schwefel-Komplexe (10-15). Chemische und spektroskopische Studien zeigen, daß für E = P oder As die Cr(CO)5-Gruppe an diese Elemente und nicht an den Schwefel gebunden ist.
    Additional Material: 6 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19701031120
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  • 5
    Electronic Resource
    Electronic Resource
    Metallorganische Lewis-Basen, VI Zweikernige Carbonyl-Komplexe von Metallen der sechsten und siebenten Nebengruppe mit einfacher Phosphin- bzw. Arsin-Brücke (1971)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 104 (1971), S. 3261-3271 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Organometallic Lewis Bases, VI Dinuclear Carbonyl Complexes of VIb and VIIb Group Metals with Single Phosphine or Arsine BridgesThe compounds (CO)5M - E(CH3)2 - M′(CO)5 (3 - 6) (M = Cr, Mo, W; E = P, As; M′ = Mn. Re) were obtained by reaction between the photochemically prepared complexes (CO)5M·E(CH3)2Cl (1, 2) and the carbonylmetalates NaM′(CO)5. They are yellow to red, crystalline, and air stable. Their thermal and photochemical decomposition leads to disproportionation into M(CO)6 and [M′(CO)4E(CH3)2]2.
    Notes: Die Verbindungen (CO)5M - E(CH3)2 - M′(CO)5 (3-6) (M = Cr, Mo, W; E = P, As; M′ = Mn, Re) entstehen durch Umsetzung der photochemisch bereiteten Komplexe (CO)5M· E(CH3)2Cl (1, 2) mit den Carbonylmetallaten NaM′(CO)5. Sie sind gelb bis rot, kristallin und luftstabil. Ihre thermische und photochemische Zersetzung führt zur Disproportionierung in M(CO)6 und [M′(CO)4E(CH3)2]2.
    Additional Material: 6 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19711041032
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  • 6
    Electronic Resource
    Electronic Resource
    Metallorganische Lewis-Basen, VII. Schwefelverbrückte Zweikernkomplexe (1972)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 105 (1972), S. 1471-1485 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Organometallic Lewis Bases, VII. Sulfur Bridged Dinuclear ComplexesThe dinuclear metal carbonyl complexes with a single methylthio bridge M-SCH3-M′ [M = C5H5(CO)2Fe, C5H5(CO)3Mo, C5H5(CO)3W, (C6H5)3P ⋅ Au; M′ = Cr(CO)5, W(CO)5, Mn(CO)2C5H5] can be prepared a) from the free organometallic Lewis bases M-SCH3 and the metal carbonyl M′, b) from the methylthiostannane derivatives (CH3)3Sn-SCH3-M′ and the halides M-Cl. They are deeply coloured, crystalline, and mostly air stable. The use of other groups M and M′ does not yield complexes of this type, but leads to disproportionation and formation of homodinuclear sulfur bridged complexes. Attempted pyrolysis of the complexes M-SCH3-M′ in order to obtain higher aggregated species so far gave no identifiable products except for simpler complexes.
    Notes: Die Metall-Carbonyl-Zweikernkomplexe mit einfacher Mercapto-Brücke M-SCH3-M′ [M = C5H5(CO)2Fe, C5H5(CO)3Mo, C5H5(CO)3W, (C6H5)3P ⋅ Au; M′ = Cr(CO)5, W(CO)5, Mn(CO)2C5H5] können a) aus der freien metallorganischen Lewis-Basen M-SCH3 und dem Metallcarbonyl M′, b) aus den Mercaptostannan-Derivaten (CH3)3Sn-SCH3-M′ und den Halogeniden M-Cl gewonnen werden. Sie sind tief farbig, kristallin und weitgehend luftstabil. Einsatz anderer Gruppen M und M′ führt nicht zu Komplexen dieses Typs, sondern unter Disproportionierung zu homonuclearen schwefelverbrückten Zweikernkomplexen. Versuche, durch Pyrolyse der Komplexe M-SCH3-M′ zu höher aggregierten Spezies zu gelangen, ergaben außer einfachen Komplexen bis jetzt keine identifizierbaren Produkte.
    Additional Material: 5 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19721050503
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  • 7
    Electronic Resource
    Electronic Resource
    Metallorganische Lewis-Basen, XIX. Nucleophile Spaltung von Metall-Metall-Bindungen mit Phosphinen (1974)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 107 (1974), S. 3860-3866 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Organometallic Lewis Bases, XIX. Nucleophilic Cleavage of Metal-Metal Bonds by PhosphinesIn arsine bridged dinuclear complexes the hetero-metal-metal bond can be cleaved by phosphines. From molecules with the framework thus compounds with the structure Fe-As-Mn-P and Fe-As-Co-P are obtained.
    Notes: IN arsinverbrückten Zweikernkomplexen läßt sich die Hetero-Metall-Metall-Bindung mit Phosphinen spalten. Aus Molekülen mit dem Baugerüst entstehen so die Verbindungen mit der Struktur Fe-As-Mn-P und Fe-As-Co-P.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19741071215
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  • 8
    Electronic Resource
    Electronic Resource
    Stufenweiser Aufbau verbrückter zweikerniger Carbonyl-Metall-Komplexe (1971)
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 83 (1971), S. 501-502 
    Details
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ange.19710831314
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  • 9
    Electronic Resource
    Electronic Resource
    Basenverbrückte, zweikernige Carbonyl-Metall-Komplexe (1971)
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 83 (1971), S. 937-937 
    Details
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ange.1971083221184
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  • 10
    Electronic Resource
    Electronic Resource
    Stepwise Formation of Bridged Dinuclear Carbonylmetal ComplexesOrganometallic Lewis bases, Part 5. This work was supported by the Deutsche Forschungsgemeinschaft.  -  Part 4: H. Vahrenkamp, J. Organometal. Chem. 28, 181 (1971). (1971)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 10 (1971), S. 513-514 
    Details
    ISSN: 0570-0833
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.197105131
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