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  • PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
  • 1
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    Publication Date: 2011-08-16
    Description: A simple but accurate form for the proton-deuteron elastic double scattering amplitude, which includes both projectile and target recoil motion and is applicable at all momentum transfer, is derived by taking advantage of the restricted range of Fermi momentum allowed by the deuteron wave function. This amplitude can be directly compared to approximations which have neglected target recoil or are limited to small momentum transfer; the target recoil and large momentum transfer effects are evaluated explicitly within the context of a Gaussian model.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review C - Nuclear Physics; vol. 10
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  • 2
    Publication Date: 2011-08-16
    Description: The strong projectile-charge-state dependence of K X-ray production in gases establishes a charge-state scale for ions penetrating solids. Si K X-ray cross sections in gaseous SiH4 were compared to those in solid Si for 40-MeV O (6+ to 8+) and 86-MeV Ar (6+ to 16+) projectiles. For Ar an effective charge of 11 plus or minus one is found compared to an emergent charge of 14.8 plus or minus 0.5. The result is discussed in terms of alternate models for steady-state excitation in solids.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review Letters; 33; Sept. 23
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  • 3
    Publication Date: 2011-08-16
    Description: The components of the one- and two-particle density matrices resulting from spin projection of a single-determinant wave function are rederived by the method of expansion in terms of the natural orbitals of charge density, and the results are found to diverge from those given by Harriman and Sando for the two-particle case. The theory is generalized to include molecules with unequal numbers of electrons and basis orbitals and is applied to a number of organic molecules and ions. The correctness and internal consistency of the results argue in favor of the modification described.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Chemical Physics; 61; Aug. 1
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  • 4
    Publication Date: 2011-08-16
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Optical Society of America; vol. 64
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  • 5
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    Publication Date: 2011-08-16
    Description: A standard photon counting technique and an argon-ion laser with 4545, 4579, 4727, 4765, 4880, 4965, 5017 and 5145-A lasing lines, providing a measurable Raman spectrum from NOCl, were used in the measurement of the Raman scattering cross section of NOCl at a Raman shift of 334.4 plus or minus 1.6/cm in relation to the N2 Raman cross section. A polarization analyzer and a quartz wedge were placed in front of the entrance slit of the double monochromator for depolarization measurements. Diagrams are plotted to show the scattering cross section and depolarization measurement results.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Applied Physics Letters; 25; Aug. 15
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  • 6
    Publication Date: 2011-08-16
    Description: The positions of the resonances calculated by the stabilization method can be improved by inclusion of the shift as given by Hazi and Fels. It is also indicated that the phase shifts calculated by the Harris method at incident energies corresponding to the stabilized roots give the positions and the widths of the resonances reasonably well.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 10
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  • 7
    Publication Date: 2011-08-16
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 10
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  • 8
    Publication Date: 2011-08-16
    Description: Measurements in liquid Xe are reported of the characteristic function that describes the avalanche, the first Townsend coefficient. An electron avalanche occurs when the drifting electrons attain sufficient kinetic energy from the electric field to cause additional ionization. Data on the avalanche were obtained by studying the pulses in a liquid-filled proportional chamber as a function of applied voltage and anode diameter. The results of the investigation show that the avalanche of free electrons in purified liquid Xe is adequately described by the same formalism used for the avalanche of electrons in gases.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 9
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  • 9
    Publication Date: 2011-08-16
    Description: The Coulomb approximation tables of Oertel and Shomo, together with binding-energy values obtained by a screening approximation, have been used to produce values of the dipole and quadrupole radial integrals needed in obtaining transition probabilities for ions of six, seven, and eight electrons. Some comparisons with more rigorously calculated values show that the present values are quite accurate, especially for ions of higher atomic number.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: vol. 27; Mar. 197
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  • 10
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    Publication Date: 2011-08-16
    Description: Evaluation of quadrupole moments obtained for CO, N2, and NO(+) with multiconfiguration self-consistent-field wave functions chosen by the optimized valence configuration (OVC) approach of Wahl and Das (1972). The quadrupole moments thus obtained are compared with both experimental and Hartree-Fock values. The Hartree-Fock results are found to be not very accurate for N2, especially if vibrational averages over vibrational levels greater than 1 or 2 are to be taken. The agreement between the OVC quadrupole moment and the experimental values is found to be best for CO.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Chemical Physics; 60; Apr. 1
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  • 11
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    Publication Date: 2011-08-16
    Description: The equation of state for cold neutron matter at high density is studied in the t-matrix formulation, and it is shown that energetically it is convenient to have neutrons in a crystalline configuration rather than in a liquid state for values of the density exceeding 1600 Tg/cu cm. The study of the mechanical properties indicates that the system is stable against shearing stresses. A solid core in the deep interior of heavy neutron stars appears to offer the most plausible explanation of speed-ups observed in the Vela pulsar.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review D - Particles and Fields; vol. 9
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  • 12
    Publication Date: 2011-08-16
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physics Letters; 49B; Apr. 1
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  • 13
    Publication Date: 2011-08-16
    Description: The theory of the intensity factors of rotational lines in diatomic molecular spectra is reviewed with an emphasis on removing obscurities and resolving ambiguities that exist. For example, a unified intensity-factor sum rule is derived that is valid for all spin-allowed and spin-forbidden dipole transitions. Further, it is shown that the electronic transition moments can always be chosen to be real and that a few simple rules ensure the application of consistent phase factors.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: vol. 27; Jan. 197
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  • 14
    Publication Date: 2011-08-16
    Description: Rigorous lower-bound p-wave positron-hydrogen phase shifts are calculated below the positronium pickup threshold. The wave function is expanded in terms of the two linearly independent D functions each multiplied by an associated Hilleraas-type radial function with two parameters. Adiabatic and nonadiabatic corrections have been included. The results are found to be larger than Armstead's (1968) in all cases near the upper edge of his estimated uncertainty.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 9
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  • 15
    Publication Date: 2011-08-16
    Description: Angular intensity distributions of helium resonance photons, experimentally determined for the first time with respect to the exciting electron beam, are presented. The angular intensity distributions were measured at selected electron-impact energies from 25 to 150 eV. The results obtained are slightly higher than theoretical data for electron impact energies from 80 to 150 eV.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 9
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  • 16
    Publication Date: 2011-08-16
    Description: Using the precision s- and p-wave elastic-scattering wave functions obtained previously, we have calculated the annihilation rate for positrons colliding with hydrogen atoms below the positronium-formation threshold. The s-wave results agree well with those of Humberston, while the p-wave results, which are new, contribute about 20% of the total at the higher energies.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 9
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  • 17
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    Publication Date: 2011-08-16
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 9
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  • 18
    Publication Date: 2011-08-16
    Description: The kinematics of the reaction O(+)(4 S) + N2 yields NO(+) + N were studied using crossed molecular beams. Product angular and energy distributions were measured for the initial relative translational energy range from 1.5 to 15.8 eV. The products are formed in their ground electronic states. The product distributions are described, with some deviations, by the spectator stripping model. No evidence was found for a persistent complex or for a second mechanism. A scattering chamber study of 0 deg lab was made of the related reactions 15N(+) + 14NO yields 15N14N(+), 15NO(+), 14NO(+). The results obtained are discussed in terms of possible surface hopping effects.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Chemical Physics; 60; Mar. 1
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  • 19
    Publication Date: 2011-08-16
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Chemical Physics; 60; Feb. 15
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  • 20
    Publication Date: 2011-08-16
    Description: Measured and calculated profiles are compared for two neutral helium lines, He I (4471 and 6678 A), and their forbidden components at high electron densities. Calculations were done at the measured plasma conditions and are compared directly with the experimental profiles. Good agreement is found between theory and experiment.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 9
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  • 21
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    Publication Date: 2011-08-16
    Description: The stabilization method for positions and widths of resonances has been applied up to now only to model problems or to problems for which definitive calculations are not possible. The method is now applied to autoionization states in He and H(-), where accurate calculations are available. It is concluded that reasonably accurate results can be obtained by this method.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 9
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  • 22
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    Publication Date: 2011-08-16
    Description: Two classes of molecular species must be considered in a calculation of photochemical rates in the stratosphere. The first class consists of molecular oxygen and ozone, while the second class contains the remainder of the minor constituents. If accurate values of the transmitted fluxes are required at large optical depths, the cross sections for molecular oxygen and ozone must be known to within a few per cent at least. On the other hand, the photochemical rates for the minor species are given simply by the relevant cross sections. A review of published cross sections is presented, giving attention to molecular oxygen, ozone, nitric oxide, nitrogen dioxide, nitrous oxide, nitric acid, ammonia, water vapor, hydrogen peroxide, carbon monoxide, carbon dioxide, and sulfur dioxide.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Canadian Journal of Chemistry; 52; 8, 19; 1974
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  • 23
    Publication Date: 2011-08-16
    Description: The foil-excitation method has been used to study the extreme ultraviolet spectra of highly ionized oxygen and fluorine. Several previously unreported lines in heliumlike fluorine are reported and other newly reported lines in heliumlike oxygen have been measured to higher accuracy. Included in the measurements are certain heliumlike oxygen transitions of significance in interpretation of solar-flare spectral observations. The wavelength determinations are usually in good agreement with calculated results which includes relativistic corrections, but discrepancies arise when nonrelativistic calculations are used. A comparison of the present results and those recently obtained by theta-pinch and laser-induced plasma sources is made for both heliumlike and lithiumlike ions; a few discrepancies occur, with results in most cases in better agreement with relativistically corrected calculations. Certain unidentified lines in the spectra may be attributable to radiative transitions between quartet states of lithiumlike ions.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 10
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  • 24
    Publication Date: 2011-08-16
    Description: The results of experiments performed to check the possibility of stimulated emission in the extreme vacuum ultraviolet (VUV) by an Al(+3) laser-generated plasma are reported. It is concluded that the spectral line intensity anomalies previously observed are not due to population inversion.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Applied Physics Letters; 25; July 1
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  • 25
    Publication Date: 2011-08-16
    Description: Absolute excitation functions for excited fragments resulting from electron bombardment of H2O, NH3, and CH4 by low-energy electrons (0 to 300 eV) have been measured in the vacuum ultraviolet (1100 to 1950 A). The predominant emission for each molecule was the H Lyman-alpha line, while the O I, N I, C I, and C II emissions were at least an order of magnitude weaker. Absolute cross sections at 100 eV are given along with the appearance potential of the various processes and the possible dissociative-excitation channels through which such processes proceed.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Chemical Physics; 60; June 15
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  • 26
    Publication Date: 2011-08-16
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Optical Society of America; vol. 64
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  • 27
    Publication Date: 2011-08-16
    Description: The relaxation theory of plasma line broadening developed by Smith and Hooper (1967) and extended by Smith (1968) is extended further to cover a case of a positively charged radiator. Differences in the theory, arising from its application to a charged radiator, are discussed in detail.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Quantitative Spectroscopy and Radiative Transfer; 14; June 197
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  • 28
    Publication Date: 2011-08-16
    Description: Using a time-of-flight method, the excitation of argon and helium metastables by electron impact is investigated in the energy range from threshold to about 50 eV. The secondary-electron yields of the metastable detector used are reviewed in detail. The effect of metastable recoil is also discussed. Comparisons with data from other investigators are presented.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 9
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  • 29
    Publication Date: 2011-08-16
    Description: Results are presented on the relaxation and frequency shifts measured for the 0-0 transition of the ground state of Rb-85 at 3.03 GHz in various physical environments. These results include data on spin-exchange, buffer-gas, and wall interactions.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 9
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  • 30
    Publication Date: 2011-08-16
    Description: The geometry of the bending of a linear triatomic molecule is analyzed, and an expression for the average rotational constant is derived. A harmonic oscillator model of C3 is fitted to the observed rotational constant within 0.6%. The bond distance between atoms at zero bending is 1.287 A according to this model; this is noticeably larger than the average internuclear distance of 1.277 A for the vibrational ground state. The first order perturbation solutions for the vibrational energy levels, taking into account the effect of a quartic perturbation potential, closely match observed levels. For a square well potential model of C3, the effect of curvilinear motion in bending is similar to that found for the harmonic oscillator model, though the decreases in energy are about twice as large. In both models, the average energy decrease is relatively constant at approximately 10% over a wide range of vibrational quantum number.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Chemical Physics; 60; Feb. 1
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  • 31
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    Publication Date: 2011-08-16
    Description: Charge states of argon produced by bombardment with 100-keV to 1-MeV H+ and He+ projectiles were studied by examining high-resolution L-shell X-ray satellite spectra. Large differences appear in charge-state populations determined from X-ray data and Auger-electron data.-
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review Letters; 32; Mar. 18
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  • 32
    Publication Date: 2011-08-16
    Description: An expansion of the three-body Coulomb potential in generalized angular-momentum eigenfunctions developed earlier by one of the authors is used to compute energy eigenvalues and eigenfunctions of bound S states of three-body Coulomb systems. The results for He, H(-), e(-)e(+)e(-), and pmu(-)p are compared with the results of other computational approaches.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 9
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  • 33
    Publication Date: 2011-08-16
    Description: A relationship between the inverse bremsstrahlung absorption cross section and the electron neutral momentum transfer cross section has been utilized to determine the infrared free-free continuum absorption coefficient for the negative ions of helium, neon, argon, krypton, and xenon. The values of the momentum transfer cross section for this calculation have been obtained from experimental measurements. Analytical expressions for the absorption coefficient have also been developed. From the results of this calculation, it is possible to determine the absorption coefficient per unit electron density per neutral atom for temperatures in the range from 2500 to 25,000 K. The results are compared with those from tabulations of previous calculations and those computed from theoretical values of the phase shifts for the elastic scattering of electrons by neutral atoms.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Astronomy and Astrophysics; 30; 2, Ja; Jan. 197
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  • 34
    Publication Date: 2011-08-16
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Quantitative Spectroscopy and Radiative Transfer; 14; Feb. 197
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  • 35
    Publication Date: 2011-08-16
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Quantitative Spectroscopy and Radiative Transfer; 14; Jan. 197
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  • 36
    Publication Date: 2011-08-16
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 9
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  • 37
    Publication Date: 2011-08-16
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 9
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  • 38
    Publication Date: 2019-06-27
    Description: The absorption coefficient for the free-bound transition H (ls) + e(-)+ h omega yields H(-)(2 sq p,(3)P(e)) is calculated (together with the differential emission rate for the inverse process) using ls - 2s - 2p close coupling continuum wave functions and a Hylleraas bound state wave function. A maximum in the absorption and emission spectra is found to occur at a photon wavelength of 1219.5 A, which is 2 A closer to the Lyman alpha line than predicted by the calculations of Drake, and is in closer agreement with the stellar absorption feature identified by Heap and Stecher. The free-bound absorption process appears to be a significant source of continuous ultraviolet opacity.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: NASA-TM-X-70570 , X-602-74-13
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  • 39
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    Publication Date: 2019-06-27
    Description: A laminate is obtained by providing a lightweight core material, such as a honeycombed plastic or metal, within the cavity defined by an annular mold cavity frame. Face sheets, which are to be bonded to the core material, are provided on opposite sides of the frame and extend over the frame, thus sealing the core material in the cavity. An adhesive is provided between the core material and the face sheets and the combined thickness of the core material and adhesive is a close fit within the opposed face sheets. A gas tight seal, such as an O-ring gasket, is provided between the frame and the face sheet members to form a gas tight cavity between the face sheet members and the frame. External heat and pressure are used to bond the face sheets to the core material. Gas pressure is introduced into the sealed cavity to minimize out-gasing of the adhesive.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
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  • 40
    Publication Date: 2019-06-27
    Description: Expressions are given for atomic photoelectron angular distributions in LS coupling in which the role of anisotropic final state electron-ion interactions emerges explicitly. Calculations of photoelectron angular distributions for atomic sulfur are presented in which these anisotropic interactions produce pronounced deviations from the predictions of the Cooper-Zare model. Such effects are expected to be a general feature of photoelectron angular distributions for most open shell atoms.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: NASA-CR-137076
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  • 41
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    Publication Date: 2019-06-27
    Description: The theory of homogeneous condensation is reviewed and equations describing this process are presented. Numerical computer solutions to transient problems in nucleation (relaxation to steady state) are presented and compared to a prior computation.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: NASA-CR-136830 , JPL-TM-33-666
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  • 42
    Publication Date: 2019-06-27
    Description: Integrated intensities of acetylene bands at 3.04, 7.53, and 13.7 microns measured at 300 K at a spectral resolution of 0.6 slit widths per cm, using the technique described by Penner (1959), are presented. Comparisons with other published measurements suggest that the presented intensity values are reasonably well determined.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Quantitative Spectroscopy and Radiative Transfer; 14; Sept
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  • 43
    Publication Date: 2019-06-27
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Quantitative Spectroscopy and Radiative Transfer; 14; Oct. 197
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  • 44
    Publication Date: 2019-06-27
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Quantitative Spectroscopy and Radiative Transfer; 14; Oct. 197
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  • 45
    Publication Date: 2019-06-27
    Description: Normalized differential and integral electron-impact cross sections are presented for elastic scattering and for specified excitation levels of atomic copper at 20 and 60 eV. For some excitation levels, an unexpectedly large cross section was found, which at certain angular and energy ranges surpasses the cross section for elastic scattering.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review Letters; 33; July 22
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  • 46
    Publication Date: 2019-06-27
    Description: The applicability of the complex-potential theory to H(-)-He collisions is investigated. Measurements are conducted of the elastic differential cross section for H(-)-He collisions, taking into account energies in the range from 5 to 120 eV. A preliminary determination is made of the energy spectrum of detached electrons. The results are interpreted in terms of the complex-potential theory. The crossing point is determined together with the general shape of the HeH(-) potential curve.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 9
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  • 47
    Publication Date: 2019-06-27
    Description: Analysis of cross sections that have been obtained for the production of the N2O(+) (A 2Sigma+ to X 2Pi) fluorescence, using vacuum ultraviolet radiation between 462 and 755 A. The fluorescence spectra produced using incident photons of 715.6- and 754.9-A wavelengths are presented, as well as the relative fluorescence cross sections for the individual observed bands of the above-mentioned N2O(+) system. Finally, absolute cross sections for the production of the N2O(+) (A 2Sigma+ to X 2Pi) system are presented, as well as band strengths for the A 2Sigma+(0,0,0) to X 2Pi(n1,n2,0) fluorescence.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Physics; vol. 7
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  • 48
    Publication Date: 2019-06-27
    Description: The photoionization efficiency curves of H2(+), O2(+), and HO2(+) have been studied in a mixture of hydrogen and oxygen over the wavelength range from 650 to 810 A. The HO2(+) ion appears at 804 A, the threshold for ionization of H2, by the reaction H2(+) + O2 yields HO2(+) + H. The relative photoionization efficiency curves of H2(+) and HO2(+) are the same from 804 to 764 A. Below 764 A production of the 4 Pi u metastable electronic state of O2(+) leads to the formation of HO2(+) by the reaction O2(+)(a 4 Pi u) + H2 yields HO2(+) + H.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Chemical Physics; 60; Feb. 15
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  • 49
    Publication Date: 2019-06-27
    Description: Existing theoretical H2 pair potentials are investigated. We develop a spherically symmetric potential applicable to solid H2. It yields a ground-state energy of -98.7 K (experimental values range from -93.5 to -101 K). Pressure-volume data are also in excellent agreement with experiment between 0 and 25 kbar. Second virial coefficients using this potential are consistently too low. When an anisotropic pair potential is used, agreement becomes very good.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review Letters; 32; Apr. 8
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  • 50
    Publication Date: 2019-06-27
    Description: Charged particles ranging in energy from 0.8 to 4.0 MeV are used to induce resonant nuclear reactions, Coulomb excitation (gamma X-rays), and X-ray emission in both thick and thin targets. Quantitative analysis is possible for elements from Li to Pb in complex environmental samples, although the matrix can severely reduce the sensitivity. It is necessary to use a comparator technique for the gamma-rays, while for X-rays an internal standard can be used. A USGS standard rock is analyzed for a total of 28 elements. Water samples can be analyzed either by nebulizing the sample doped with Cs or Y onto a thin formvar film or by extracting the sample (with or without an internal standard) onto ion exchange resin which is pressed into a pellet.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: NASA-CR-139619
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  • 51
    Publication Date: 2019-06-27
    Description: Damaged fiberglass structures are repaired by substantially filling the irregular surfaced damaged area with a liquid, self-curing resin, preferably an epoxy resin mixed with chopped fiberglass, and then applying to the resin surface the first of several woven fiberglass swatches which has stitching in a zig-zag pattern parallel to each of its edges and a fringe of warp and fill glass fibers about the edges outward of the stitching. The method is especially applicable to repair of fiberglass rocket engine casings and is particularly advantageous since it restores the repaired fiberglass structure to substantially its original strength without any significant changes in the geometry or mass of the structure.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
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  • 52
    Publication Date: 2019-06-27
    Description: The mathematical developments carried out for this investigation are reported. In addition to describing and discussing the solutions which were acquired, there are compendia of data presented herein which summarize the equations and describe them as representative trace geometries. In this analysis the relative motion problems have been referred to two particular frames of reference; one which is inertially aligned, and one which is (local) horizon oriented. In addition to obtaining the classical initial values solutions, there are results which describe cases having applied specific forces serving as forcing functions. Also, in order to provide a complete state representation the speed components, as well as the displacements, have been described. These coordinates are traced on representative planes analogous to the displacement geometries. By this procedure a complete description of a relative motion is developed; and, as a consequence range rate as well as range information is obtained.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: NASA-CR-132410-2 , REPT-74-3
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  • 53
    Publication Date: 2019-06-27
    Description: Recent calculations of the ground state energy of a system of four hydrogen atoms are reviewed with the aim of discerning the short-range repulsive part of the interaction potential between two hydrogen molecules. Extended-basis CI calculations which include a diffuse 2p orbital appear to be capable of determining the total interaction energy between to hydrogen molecules for any separation. Consistent results of such calculations suggest that the potential for intermolecular separations in the region from 1 to 2.5 A can now be specified to better than 10% with considerable confidence. Analytic fits to spherical averages of these results are presented.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 9
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  • 54
    Publication Date: 2019-06-27
    Description: The refractive index change in a collisionless gas is evaluated from the Stark shifts of the rotational energy levels that arise from the polarizability anisotropy. For the limit of an extremely short-duration excitation, a multilevel coherent effect resulted in delayed refractive index bursts. Both stationary and transient responses of this birefringence to an optical field were considered for symmetric top molecules, with particular emphasis on the special case of linear molecules.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: NASA-TM-X-70344
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  • 55
    Publication Date: 2019-06-27
    Description: Metastable fragments produced by electron impact excitation of CH4 have been investigated for incident electron energies from threshold to 300 eV. Only metastable hydrogen and carbon atoms were observed. Onset energies for the production of metastable hydrogen atoms were observed at electron impact energies of 22.0 + or - .5 eV, 25.5 + or - .6 eV, 36.7 + or - .6 eV and 66 + or - 3 eV, and at 26.6 + or - .6 eV for the production of metastable carbon atoms. Most of the fragments appear to have been formed in high-lying Rydberg states. The total metastable hydrogen cross section reaches a maximum value of approximately 1 X 10 to the minus 18th power sq cm at 100 eV. At the same energy, the metastable carbon cross section is 2 x 10 to the minus 19th power sq cm.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: NASA-CR-140179 , SRCC-209
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  • 56
    Publication Date: 2019-06-27
    Description: The application of cross-beam Laser Doppler Velocimeter (LDV) for sizing small particles was investigated from September 1973 to August 1974. Theoretical results were obtained by analyzing the scattering characteristics of small particles in a cross-beam LDV system. Theoretical calculations based on scalar diffraction theory and Mie scattering theory were performed. Experimental results were also obtained to compare with theoretical predictions. It is concluded that the forward scattering characteristics of small particles in a cross-beam LDV system can be used for particle sizing.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: NASA-CR-140446
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  • 57
    Publication Date: 2019-06-27
    Description: The photoelectron asymmetry parameter beta in LS-coupling is obtained as an expansion into contributions from alternative angular momentum transfers j sub t. The physical significance of this expansion of beta is shown to be that: (1) the electric dipole interaction transfers to the atom a charcteristic single angular momentum j sub t = sub o, where sub o is the photoelectron's initial orbital momentum; and (2) angular momentum transfers indicate the presence of anisotropic interaction of the outgoing photoelectron with the residual ion. For open shell atoms the photoelectron-ion interaction is generally anisotropic; photoelectron phase shifts and electric dipole matrix elements depend on both the multiplet term of the residual ion and the total orbital momentum of the ion-photoelectron final state channel. Consequently beta depends on the term levels of the residual ion and contains contributions from all allowed values of j sub t. Numerical calculations of the asymmetry parameters and partial cross sections for photoionization of atomic sulfur are presented.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: NASA-CR-140041
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  • 58
    facet.materialart.
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    Publication Date: 2019-06-27
    Description: Development of a theory describing the selective excitation of a three-level atom with a tunable laser. The effects of number density, line widths, and laser parameters on the final populations of the levels are discussed. An experiment is described in which a tunable dye laser is used to pump large numbers of barium atoms into a definite excited state.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Physics; vol. 7
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  • 59
    Publication Date: 2019-06-27
    Description: Measurement of the total fragmentation cross sections of C-12 and O-16 ions incident in CsI target and tungsten scintillator modules. The analysis described is based on a one-module criterion for determining the location of an interaction. The results are independent of the windows used, provided that corrections are made for interactions simulated by energy loss fluctuations in the individual modules and for Delta Z ? 1 interactions missed because of the use of wide windows. The cross sections obtained are in general agreement with the values obtained in other experiments for various target nuclei.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review D - Particles and Fields; vol. 10
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  • 60
    Publication Date: 2019-06-27
    Description: Collision-broadened line widths in CO-CO2 and CO-O2 collisions have been calculated by incorporating interactions due to octopoles and hexadecapoles and short-range repulsive interactions into Anderson's (1949) theory. It is shown how these higher-order interactions can be manipulated to yield good agreement with experimental data. A critical evaluation of this totally empirical manipulation suggests that a thorough revision of the theory is required for all but simple dipole-dipole interactions. In the process of the evaluation, the values of the multipole moments are discussed.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Quantitative Spectroscopy and Radiative Transfer; 14; Sept
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  • 61
    Publication Date: 2019-06-27
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Physics; vol. 7
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  • 62
    Publication Date: 2019-06-27
    Description: Use of ion cyclotron resonance methods to measure the thermal energy rate constants for a number of ion-molecule reactions involving hydrogen and hydrogen-helium mixtures. Assuming that the distribution of initial vibrational states in the H2(+) ion is a near-Franck-Condon distribution, the occurrence of collisional deactivation of vibrationally excited H2(+) ions by He atoms is identified, and an approximate rate constant for the deactivation process and its dependence on vibrational energy are given.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Chemical Physics; 60; Apr. 1
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  • 63
    facet.materialart.
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    In:  Other Sources
    Publication Date: 2019-06-27
    Description: Using a previously developed semiclassical theory of electronic excitations, the cross sections that result from potential-curve crossings are calculated for a model system. The phenomena appearing in the differential cross sections are displayed and discussed.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 9
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  • 64
    Publication Date: 2019-06-27
    Description: Two broad spectral features which may be easily overlooked or misinterpreted in the discussion of X-ray spectra induced by fast atomic collisions are reported. Calculations based on relatively simple models are in good agreement with the data.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physics Letters; 47A; Feb. 25
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  • 65
    Publication Date: 2019-06-27
    Description: The absorption of the principal series of calcium is observed with about 4% of the atoms placed in the 4s4p 3P level by selective laser excitation, and is compared with the absorption with all atoms in the ground state. We observe a broadening of the absorption lines accompanied by a shift to longer wavelengths and the occurrence of satellite lines at shorter wavelengths.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Physics; vol. 7
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  • 66
    Publication Date: 2019-06-27
    Description: The flatness of the energy differential cross section in impact ionization is derived analytically in the Wannier theory. However it is shown that the Wannier zone is confined to a region of the order E/5 is less than or equal to epsilon is less than or equal to 4E/5, where E is the available energy and epsilon is the energy of the electrons. By contrasting the known results of photoionization and photodetachment, one can cogently argue that in the complementary region where electrons share their energy very unequally the cross section rises to a value independent of E, and that this region determines the form of the threshold law.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: NASA-TM-X-70745 , X-602-74-239
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  • 67
    Publication Date: 2019-06-27
    Description: Preliminary charged particle dose rates are presented for the LST orbit. The trapped proton component appears to dominate the total dose for the expected shielding available. Typical dose rates should range from 400 to 800 millirads/day.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: NASA-TM-X-64858
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  • 68
    Publication Date: 2019-06-27
    Description: Aerosol particles are allowed to settle in a vertical glass walled vessel, and their settling velocity is determined by photographing them while the light entering the camera is being chopped at a known rate. The settling velocity of each particle can be determined from the photographs, and by applying the Stokes' law, one can calculate the radius of each particle. The Stokes' law for a sphere settling freely in a quiet medium is given. If the volume of the photographed region of the illumination is known, the aerosol number density and size distribution can be obtained. Experiments with alumina particles of given size distributions indicate that the method works accurately. One set of a typical experiment with 3.0-micrometer Al2O3 particles is presented, which shows that the measured size distribution peaks at approximately 3.0 micrometer.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: NASA-TM-X-64838
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  • 69
    Publication Date: 2019-06-27
    Description: The transport of charged particles diffusing in a random magnetic field parallel to a relatively large guiding field is presented. The same coefficient of diffusion is obtained by three methods. Two corrections must be added to the expression in which the diffusive flux is proportional to the gradient of the density. Explicit expressions are given for a characteristic time and a characteristic length which describe the corrections. The well known divergence of the coefficient of diffusion, which is implied by the quasilinear analysis of pitch angle scattering, does not occur if the scattering rate is finite at 90 deg pitch angle. This effect is illustrated by formulas which give the coefficient of diffusion when the quasilinear expression is perturbed by a variable amount of isotropic scattering.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: NASA-CR-138510 , TR-74-078
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  • 70
    Publication Date: 2019-06-27
    Description: The numerical representation of the average motion of a charged particle trapped in a geomagnetic field is developed. An assumption is made of the conservation of the first two adiabatic invariants where integration is along a field line between mirror points. The averaged motion also involved the parameters defining the magnetic field line to which the particle is attached. Methods involved in obtaining the motion in the equatorial plane of model magnetospheres are based on Hamiltonian functions. The restrictions imposed by the special nature of the dipole field are defined.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: NASA-TM-X-70668 , X-602-74-166
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  • 71
    Publication Date: 2019-06-27
    Description: It is shown that the accuracy of calculations can be improved if appropriate (different) values of alpha are used for each configuration. Alternatively, the Slater Transition state can be used, wherein a total energy difference is related to a difference in single electron eigenvalues. By a series expansion, the value of alpha for an excited configuration can be related to its value for the ground state configuration. The terms Delta alpha (delta Epsilon/delta alpha) exhibit a similar dependence on atomic number as the ground state values of alpha. Results of sample calculations are reported and compared with experiment.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: NASA-CR-138460
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  • 72
    Publication Date: 2019-06-27
    Description: Using a wave function including the 1s-2s-2p eigenstates of hydrogen and the 1s ground state of positronium, we have calculated the position and width of the lowest Feshbach resonance in the e(+)-H system, which lies between the positronium rearrangement threshold and the n=2 hydrogen threshold. The method differs from the usual close-coupling method, resembling in its formulation the projection operator technique, although orthogonality of closed-channel and open-channel functions is not demanded. The resonance lies 9.8281 eV above the ground state of hydrogen and has width of 0.029 eV in this approximation.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: NASA-TM-X-70617 , X-602-74-77
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  • 73
    Publication Date: 2019-06-27
    Description: The technology and methods developed at the Plum Brook Reactor to analyze 1000 samples per year and report data on as many as 56 elements are described. The manpower for the complete analysis of 20 to 24 samples per week required only 3 to 3.5 hours per sample. The solutions to problems encountered in sample preparation, irradiation, and counting are discussed. The automation of data reduction is described. Typical data on various sample matrices are presented.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: NASA-TM-X-71519 , E-7724
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  • 74
    Publication Date: 2019-06-27
    Description: The rotational spectra of a number of small molecular ions should be detectable in the microwave or millimeter wave regions in laboratory experiments using currently available techniques. The dipole moments and absorption coefficients of polar diatomics CO(+) and NO(+) as well as asymmetric isotopically enriched species, like O-18O-16(+), NE-20NE-22(+), and OC-18 O-16(+) are calculated to be sufficiently large to allow observation of their spectra. In addition to the detailed molecular structure information which such spectral data would provide, precise knowledge of the transition frequencies would render likely the detection of certain of these ions in the interstellar sources or in planetary atmospheres. All of these ions also possess vibrational spectra which should be detectable in the infrared region in laboratory or astrophysical sources.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: NASA-CR-137454 , WIS-TCI-503
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  • 75
    Publication Date: 2019-06-27
    Description: A method and apparatus for thermally growing stable silicon dioxide layers on silicon is disclosed. A previously etched and baked silicon nitride tube placed in a furnace is used to grow the silicon dioxide. First, pure oxygen is allowed to flow through the tube to initially coat the inside surface of the tube with a thin layer of silicon dioxide. After the tube is coated with the thin layer of silicon dioxide, the silicon is oxidized thermally in a normal fashion. If the tube becomes contaminated, the silicon dioxide is etched off thereby exposing clean silicon nitride and then the inside of the tube is recoated with silicon dioxide. As is disclosed, the silicon nitride tube can also be used as the ambient for the pyrolytic decomposition of silane and ammonia to form thin layers of clean silicon nitride.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
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  • 76
    Publication Date: 2019-07-13
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: International Symposium on Rarefied Gas Dynamics; Jul 10, 1972 - Jul 14, 1972; Stanford, CA
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  • 77
    Publication Date: 2019-07-13
    Description: Stay-time distributions have been obtained for Xe physisorbing on polycrystalline nickel as a function of the target temperature using a pulsed molecular-beam technique. Some interesting effects due to ion bombardment of the surface using He, Ar, and Xe ions are presented. Measured detector signal shapes are found to deviate from those predicted for first-order desorption with velocities corresponding to Maxwellian effusion at the surface temperature. Evidence is found for interaction between beam pulse adsorption and steady-state adsorption of beam species background atoms.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: International Symposium on Rarefied gas dynamics; Jul 15, 1974 - Jul 20, 1974; Goettingen; Germany
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  • 78
    Publication Date: 2019-07-13
    Description: Ground-state intermolecular interaction potentials determined from shock structure experiments with four monatomic gases are reported. These potentials are assessed for self-consistency, using the law of corresponding states, and their suitability for engineering applications in rarefied gas dynamics is discussed.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: International Symposium on Rarefied Gas Dynamics; Jul 10, 1972 - Jul 14, 1972; Stanford, CA
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  • 79
    Publication Date: 2019-07-13
    Description: The 2p fluorescence yield of argon in the presence of 0 to 6 3p holes was calculated by statistically averaging the fluorescence yields of initial state that consist of individual multiplet configurations. These configurations were formed by coupling the 2p vacancy to the partially filled 3p shell. Results agree reasonably well with experimental fluorescence yields deduced from ion-atom collision measurements.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: NASA-CR-138836 , Intern. Conf. on X-ray Processes in Matter; Jan 01, 1974; Otaniemi; Finland
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  • 80
    Publication Date: 2019-06-27
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Chemical Physics; 60; Feb. 15
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  • 81
    Publication Date: 2019-06-27
    Description: Expressions are given for atomic photoelectron angular distributions in LS coupling in which the role of anisotropic final state electron-ion interactions emerges explicitly. Calculations of photoelectron angular distributions for atomic sulfur are presented in which these anisotropic interactions produce clear deviations from the predictions of the Cooper-Zare model. Such effects are expected to be a general feature of photoelectron angular distributions for most open-shell atoms.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review Letters; 32; May 6
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  • 82
    Publication Date: 2019-06-27
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Chemical Physics Letters; 28; Sept. 1
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  • 83
    Publication Date: 2019-06-27
    Description: Presented integrated intensity data at 300 K for J multiplets between P(11) and R(11) in the nu-3 fundamental of C-12 methane are shown to be in good agreement with most previously published pertinent values. Also, line widths measured at 100 K, 130 K, 190 K, 250 K, and 300 K for R(0), R(1), and R(2) broadened by He, Ne, and Ar are presented, and the line-width temperature dependence is discussed for the three cases of broadening.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Quantitative Spectroscopy and Radiative Transfer; 14; Sept
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  • 84
    Publication Date: 2019-06-27
    Description: Drift tube-mass spectrometer measurements of several ion-molecule reactions believed to be prominent in the hydrogen-helium upper atmosphere of Jupiter are described. The total rate constant at 300 K of the reaction of He(+) with H2 is about 1.1 x 10 to the neg 13 cu cm/sec. The reaction proceeds mainly by dissociative charge transfer to produce H(+), with a small portion going by charge transfer to H2(+) and by atom rearrangement to HeH(+). The rate coefficient increases slowly with ion mean energy to a value of 2.8 x 10 to the neg 13 at 0.18 eV. The rate of the corresponding reaction with deuterium, He(+) + D2, has the rate coefficient of about 5 x 10 to the neg 14 at 300 K. Measurements of the three-body reaction of H' and the two-body reaction of HeH' with H2 to form H3(+) ions are described.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Chemical Physics; 61; Sept. 1
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  • 85
    Publication Date: 2019-06-27
    Description: An improved apparatus for obtaining short-range molecular potentials is described. The setup is a refined version of that used by Jordan-Amdur and by Leonas. The ion source is provided with a mass analyzing magnet, the capacitance manometer in the scattering cell is calibrated with a McCleod gauge, and the detection unit substitutes a Channeltron multiplier for the thermopile. The measured ground-state He-He potential for radii between 0.49 and 1.56 A is approximately V(r) = 215 x exp(-3.95r) eV, which is 25% higher than the earlier experiments. The result is supported by molecular orbital and statistical model calculations.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Chemical Physics; 61; Sept. 1
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  • 86
    Publication Date: 2019-06-27
    Description: A model of helium adsorption on an argon crystal is built up from the premise that local adsorption predominates in the first layer and nonlocal adsorption in the second. Application of the virial expansion theorem to the second layer gives a series in which the first term represents the motion of a single molecule in the external potential field and the second a two-body interaction under this field. The thermodynamic functions of the adsorbed phase are calculated ab initio, the gas-solid interaction potential being derived from lattice summation and the partition function from an appropriate choice of a site-spacing polynomial to describe the periodic potential. The mutual interaction of adsorbed molecules is calculated with a two-dimensional Lennard-Jones potential. The second virial coefficient is calculated and its dependence on temperature and choice of potential is studied. It is found that the second virial coefficient is very well approximated by a two-dimensional gas in free space. The adsorption isotherm, isosteric heat, and specific heat are obtained and compared with the results of Ross and Steele, giving excellent agreement.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Chemical Physics; 61; Sept. 1
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  • 87
    Publication Date: 2019-06-27
    Description: The Monte Carlo (MC) and continuous slowdown approximation (CSDA) approaches to the spatial deposition of energy by electrons are compared using the same detailed atomic cross section (DACS). It is found that the CSDA method overestimates the amount of energy that is deposited near the end of the path for electrons above a few hundred electron volts. The MC results are in approximate agreement with experimental data in such a way as to be relatively independent of the actual gas used. Our MC results are extended to obtain the three-dimensional deposition of energy by sub-keV electrons in molecular hydrogen.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Applied Physics; 45; July 197
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  • 88
    Publication Date: 2019-06-27
    Description: Measurements of the absolute photoionization cross section from the 6s5d 3D metastable level of barium are presented. The 3D levels were selectively populated with a high-power tuneable dye laser. The number density was determined by observing the resulting depopulation of the ground state when pumping occurred.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Physics; vol. 7
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  • 89
    Publication Date: 2019-06-27
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Quantitative Spectroscopy and Radiative Transfer; 14; Aug. 197
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  • 90
    Publication Date: 2019-06-27
    Description: The conditions of electron-impact excitation in flowing oxygen downstream from a discharge are reinterpreted. It is shown that total oxygen mass flow is not conserved as the discharge is turned on and off, even though the inlet flow rate remains constant. The total amount of gas is diminished when the discharge is turned on, apparently due to collection of atomic oxygen by the system walls. A revised total cross section is reported for the excitation of 1304-A radiation.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Chemical Physics; 60; June 1
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  • 91
    Publication Date: 2019-06-27
    Description: Using the optimized valence configurations (OVC) multiconfiguration self-consistent-field (MCSCF) method, the dipole moment function for the ground state of CO in the vicinity of the equilibrium internuclear distance has been calculated. The OVC MCSCF calculation results are compared with existing Hartree-Fock and configuration interaction treatments of this molecule at single points and also the dipole moment function deduced from experimental infrared intensities. A general prescription for constructing OVC wavefunctions for diatomic molecules is also presented.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: AD-782744 , AFCRL-TR-74-0328 , Journal of Chemical Physics; 60; June 1
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  • 92
    Publication Date: 2019-06-27
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 9
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  • 93
    Publication Date: 2019-06-27
    Description: The technique of photoelectron spectroscopy was employed in the investigation. Atomic oxygen was produced in a microwave discharge operating at a power of 40 W and at a pressure of approximately 20 mtorr. The photoelectron spectrum of the oxygen with and without the discharge is shown. The atomic states can be clearly seen. In connection with the measurement of the probability for transitions into the various ionic states, the analyzer collection efficiency was determined as a function of electron energy.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 9
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  • 94
    Publication Date: 2019-06-27
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 9
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  • 95
    Publication Date: 2019-06-27
    Description: Work has been conducted to reduce substantially uncertainties concerning the line strengths for carbon and sulfur. Two or more independent methods were used to measure thermodynamic variables and to calibrate detectors for absolute sensitivity and spectral response. The absolute transition probabilities of 124 visible and infrared lines of C I, S I, and S II were measured in a consistent way.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 9
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  • 96
    Publication Date: 2019-06-27
    Description: An investigation is conducted of the combined effects of radiator-perturber collisions and radiator translational motion in the context of foreign gas broadening of optical transitions in neutral radiators. Questions concerning the speed-dependent collision frequency are considered and aspects of general theory are explored, taking into account the correlation function, the ensemble average, and the kinetic equation formalism. An elementary solution is discussed along with a one-perturber approximation, inverse power law model calculations, and a comparison with the Voigt profile.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Quantitative Spectroscopy and Radiative Transfer; 14; July 197
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  • 97
    Publication Date: 2019-06-27
    Description: Photodissociation processes in molecular oxygen occurring in the wavelength range from 500 to 900 A, investigated through observations of the resulting atomic fluorescence radiation, are reported. The dispersed radiation from a continuous light source was used to excite the gas, and the resulting fluorescence radiation was observed in the ultraviolet and infrared. The results obtained are compared with the dissociation cross sections derived by Matsunaga and Watanabe (1967).
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Chemical Physics; 60; Mar. 15
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  • 98
    Publication Date: 2019-06-27
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Physical Review A - General Physics; vol. 9
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  • 99
    Publication Date: 2019-06-27
    Description: With the aid of a molecular resonance fluorescence technique, which utilizes optical pumping from the v = 1 level of the ground state of CO by A 1 Pi-X 1 Sigma radiation, a study is made of the efficiency of E-V transfer from O(1 D) to CO. O(1 D) is generated at a known rate by O2 photodissociation at 1470 A in an intermittent mode, and the small modulation of the fluorescent signal associated with CO (v = 1) above the normal thermal background is interpreted in terms of E-V transfer efficiency. The CO (v = 1) lifetime in this system is determined mainly by resonance trapping of the IR fundamental band, and is found to be up to ten times longer than the natural radiative lifetime. For CO, (40 plus or minus 8)% of the O(1 D) energy is converted into vibrational energy. By observing the effect of N2 on the CO (v = 1) fluorescent intensity and lifetime, it is possible to obtain the E-V transfer efficiency for the system O(1 D)-N2 relative to that for O(1 D)-CO. The results indicate that the efficiency for N2 is (83 plus or minus 10)% of that for CO.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Chemical Physics; 60; Jan. 15
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  • 100
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    In:  Other Sources
    Publication Date: 2019-06-27
    Description: Exact solutions have been obtained for the equations of an electron subjected to a transverse rotating magnetic field superimposed on a homogeneous axial magnetic field. The solutions show that complete transfer of the axial energy into transverse energy is possible for a range of values of the injection velocity and the transverse magnetic field.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: IEEE Transactions on Electron Devices; ED-21; Jan. 197
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