Publication Date:
2014-05-16
Description:
Tremendous advances have been made in nickel catalysis over the past decade. Several key properties of nickel, such as facile oxidative addition and ready access to multiple oxidation states, have allowed the development of a broad range of innovative reactions. In recent years, these properties have been increasingly understood and used to perform transformations long considered exceptionally challenging. Here we discuss some of the most recent and significant developments in homogeneous nickel catalysis, with an emphasis on both synthetic outcome and mechanism.〈br /〉〈br /〉〈a href="https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4344729/" target="_blank"〉〈img src="https://static.pubmed.gov/portal/portal3rc.fcgi/4089621/img/3977009" border="0"〉〈/a〉 〈a href="https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4344729/" target="_blank"〉This paper as free author manuscript - peer-reviewed and accepted for publication〈/a〉〈br /〉〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Tasker, Sarah Z -- Standley, Eric A -- Jamison, Timothy F -- GM62755/GM/NIGMS NIH HHS/ -- R01 GM063755/GM/NIGMS NIH HHS/ -- England -- Nature. 2014 May 15;509(7500):299-309. doi: 10.1038/nature13274.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉1] Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA [2]. ; Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/24828188" target="_blank"〉PubMed〈/a〉
Keywords:
Catalysis
;
*Chemistry Techniques, Synthetic
;
Chemistry, Organic
;
Nickel/*chemistry
;
Oxidation-Reduction
Print ISSN:
0028-0836
Electronic ISSN:
1476-4687
Topics:
Biology
,
Chemistry and Pharmacology
,
Medicine
,
Natural Sciences in General
,
Physics
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