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  • Elsevier  (5,804,721)
  • Nature Publishing Group  (363,432)
  • American Institute of Physics (AIP)  (241,959)
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  • 101
    Publication Date: 2023-11-29
    Description: Seaweed farming contributes substantial amounts of organic carbon to the ocean, part of which can be locked for a long term in the ocean and perform the function of ocean carbon sequestration, and the other part can be converted into inorganic carbon through microbial mineralization and aerobic respiration, affecting the pCO2, pHT and dissolved oxygen of seawater. It is generally believed that seaweed farming will cause the seawater to become a sink of CO2 due to carbon fixation by macroalgal photosynthesis. However, little attention has been paid to the fact that seaweed farming environment may sometimes become a source rather than a sink of CO2. Here, through in-situ mesocosm cultivation experiments and eight field investigations covering different kelp growth stages in an intensive farming area in China, we found that compared with the surrounding seawater without kelps, the seawater at the fast-growth stage of kelp was a sink of CO2 (pCO2 decreased by 17−73 μatm), but became a source of CO2 at the aging stage of kelp (pCO2 increased by 20−37 μatm). Concurrently, seawater pHT experienced a transition from increase (by 0.02−0.08) to decline (by 0.03−0.04). In-situ mesocosm cultivation experiments showed that the positive environmental effects (i.e., pCO2 decrease and pHT increase) induced by kelps at the early growth stage could be offset within only 3 days at the late-growth and aging stages. The release of dissolved organic carbon by kelps at the late growth stage increased significantly, supporting the enhancement in microbial abundance and respiration, which was manifested by the remarkable decrease in seawater dissolved oxygen, ultimately leading to CO2 release exceeding photosynthetic CO2 absorption. This study suggests that mature farmed kelps should be harvested in time to best utilize their carbon sink function and environmental benefits, which has guiding significance for the rational management of seaweed farming.
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  • 102
    Publication Date: 2023-12-18
    Description: Total alkalinity (TA) is an important variable of the ocean carbonate system. In coastal oceans, carbonate system dynamics are controlled by a range of processes including photosynthesis and respiration, calcification, mixing of water masses, continental inputs, temperature changes, and seasonal upwelling. Assessments of diel, seasonal and interannual variations in TA are required to understand the carbon cycle in coastal oceans. However, our understanding of these variations remains underdeveloped due to limitations in observational techniques. Autonomous TA measurements are therefore required. In this study, an in situ TA analyzer (ISA-TA) based on a single-point titration with spectrophotometric pH detection was deployed in Tong'an Bay, Xiamen, China, over a five-month period in 2021 to determine diel and seasonal TA variations. The TA observations were combined with an artificial neural network (ANN) model to construct TA prediction models for this area. This provided a simple method to investigate TA variations in this region and was applied to predict surface water TA between March and April 2021. The in situ TA observations showed that TA values in Tong'an Bay varied within a range from 1931 to 2294 μmol kg−1 over the study period, with low TA in late winter, early summer and late summer, and high TA in early winter. The TA variations in late summer and early winter were mainly controlled by mixing of water bodies. The diel variations of TA were greatly determined by tides, with a diel amplitude of 9 to 247 μmol kg−1. The ANN model used temperature, salinity, chlorophyll, and dissolved oxygen to estimate TA, with a root-mean-square error (RMSE) of ∼14 μmol kg−1, with salinity as the input variable with the greatest weight. The approach of combining ISA-TA observations with an ANN model can be extended to study the carbonate system in other coastal regions.
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  • 103
    Publication Date: 2024-01-17
    Description: Highlights • SPM concentration and organic fractions are analyzed in coastal-offshore gradients • Diagnostic model of SPM allows separating fresh, labile from less reactive PON • Analysis of PON fractions reveals a characteristic area, the transition zone • There, particle settling is enhanced, fostering their transport back to the coast, which controls the fate of organic matter • The transition zone is generally confined to water depths below 20 m Abstract Identifying the mechanisms that contribute to the variability of suspended particulate matter concentrations in coastal areas is important but difficult, especially due to the complexity of physical and biogeochemical interactions involved. Our study addresses this complexity and investigates changes in the horizontal spread and composition of particles, focusing on cross-coastal gradients in the southern North Sea and the English Channel. A semi-empirical model is applied on in situ data of SPM and its organic fraction to resolve the relationship between organic and inorganic suspended particles. The derived equations are applied onto remote sensing products of SPM concentration, which provide monthly synoptic maps of particulate organic matter concentrations (here, particulate organic nitrogen) at the surface together with their labile and less reactive fractions. Comparing these fractions of particulate organic matter reveals their characteristic features along the coastal-offshore gradient, with an area of increased settling rate for particles generally observed between 5 and 30 km from the coast. We identify this area as the transition zone between coastal and offshore waters with respect to particle dynamics. Presumably, in that area, the turbulence range and particle composition favor particle settling, while hydrodynamic processes tend to transport particles of the seabed back towards the coast. Bathymetry plays an important role in controlling the range of turbulent dissipation energy values in the water column, and we observe that the transition zone in the southern North Sea is generally confined to water depths below 20 m. Seasonal variations in suspended particle dynamics are linked to biological processes enhancing particle flocculation, which do not affect the location of the transition zone. We identify the criteria that allow a transition zone and discuss the cases where it is not observed in the domain. The impact of these particle dynamics on coastal carbon storage and export is discussed.
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  • 104
    Publication Date: 2024-01-30
    Description: Coastal German waters contain about 1.6 million tons of dumped munition, mostly left after World Wars. This study investigated the benthic macrofauna around the 'Kolberger Heide' munition dumpsite (Baltic Sea). A total of 93 macrofauna grab samples were obtained in the proximity of the munition dumpsite and in reference areas. Environmental variables analysed included the latitude/longitude, depth, terrain ruggedness, sediment grainsize distribution, TNT concentration in the bottom water and distance to the centre of munition dumpsite. The overall abundance, biomass and diversity varied among these groups, though demonstrated no clear differences regarding the proximity to munition and modelled near-bottom dissolved TNT. Among individual taxa, however, a total of 16 species demonstrated significant correlation with TNT concentration. Moreover, TNT may serve as a predictor for the distribution of three species: molluscs Retusa truncatula, Varicorbula gibba and polychaete Spio goniocephala. Possible reasons for the species distribution including their biological traits are discussed.
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  • 105
    Publication Date: 2024-01-30
    Description: Highlights • Global primitive arc lavas (Mg# ≥60) display notable δ49/47Ti heterogeneity. • Residual rutile imposes high δ49/47Ti of 0.24 ± 0.06 ‰ on hydrous, silicic slab melts. • Primitive Aleutian rhyodacites have the same δ49/47Ti as predicted for slab melts. • A variably diluted signature of slab melts is found in all eight subduction zones. • A slab melt component is required to generate silicic primitive arc lavas. Abstract It is still a matter of intense debate to what extent partial melting of the subducting slab contributes to arc magmatism in modern subduction zones. In particular, it is difficult to differentiate between silicate melts formed by partial melting of the slab, and aqueous fluids released during subsolidus dehydration as the main medium for slab-to-mantle wedge mass transfer. Here we use δ49/47Ti (the deviation in 49Ti/47Ti of a sample to the OL-Ti reference material) as a robust geochemical tracer of slab melting. Hydrous partial melting of subducted oceanic crust and the superjacent sedimentary layer produces silicic melts in equilibrium with residual rutile. Modelling shows that such silicic slab melts have notably higher δ49/47Ti (+0.24 ± 0.06 ‰) than their protolith due to the strong preference of rutile for the lighter isotopes of Ti. In contrast, even highly saline fluids cannot carry Ti from the slab and hence hydrous peridotite partial melts have δ49/47Ti similar to mid-ocean ridge basalts (MORB; ca. 0 ‰). Primitive (Mg# ≥60) arc lavas from eight subduction zones that are unaffected by fractional crystallisation of Fe-Ti oxides show a more than tenfold larger variation in δ49/47Ti than found in MORB. In particular, primitive arc lavas display a striking correlation between SiO2 content and δ49/47Ti that ranges from island arc basalts overlapping with MORB, to primitive rhyodacites with δ49/47Ti up to 0.26 ‰ erupted in the western Aleutian arc. The elevated δ49/47Ti of these primitive arc lavas provides conclusive evidence for partial melts of the slab as a key medium for mass transfer in subduction zones. The Aleutian rhyodacites represent a rare example of slab melts that have traversed the mantle wedge with minimal modification. More commonly, slab melts interact with the mantle wedge to form an array of primary arc magmas that are a blend of slab- and peridotite-derived melt. We identify primitive arc lavas with a clearly resolvable slab melt signature in all eight subduction zone localities, confirming that slab melting is prevalent in modern subduction zones.
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  • 106
    Publication Date: 2024-01-30
    Description: Highlights • An event-scale, complete lithostratigraphic column for the Miocene BFVA was created through extensive field volcanology. • Field volcanology was supplemented by volcanic glass geochemistry to separate the eruptions. • An example is presented how to undertake lithostratigraphy-based classification in poorly preserved, deeply eroded volcanic terrains. • In the ancient BFVA landscape, sea cover during eruptions and terrestrial deposition is evident. Abstract This study documents the volcanic evolution of the Miocene silicic Bükk Foreland Volcanic Area (BFVA), Northern Hungary (Central Europe) at an event-scale. The BFVA is a deeply eroded and dissected volcanic field dominated by multiple, several 10-m thick, valley-filling silicic ignimbrite units, which are chemically and texturally very similar to each other. Hence, establishing lateral correlation is a real challenge due to the sporadic and small-scale outcrops and lack of stratotypes. Detailed field observations allowed us to identify eleven lithological members including fourteen eruption events and establish a nearly complete lithostratigraphic correlation between fifteen outcrops across the BFVA. Primary pyroclastic material of each member was sampled, and volcanic glass was geochemically analyzed for major and trace element composition. The geochemical results confirm the field-based classification of the members and enable the correlation of distinct outcrops. The major and trace element composition of the glassy pyroclasts of each member of the BFVA served as basis to create a field-wide chemical reference database for regional correlational studies. Here, a new lithostratigraphic classification scheme (consisting of one lithostratigraphic formation and eleven members) is presented, which reflects the challenges unraveling the stratigraphy of ancient volcanic terrains. The field-based event-scale lithostratigraphy of the BFVA suggests a wet, partly sea-covered depositional environment in the close vicinity of the eruption centers providing favorable conditions to ‘fuel’ silicic explosive phreatomagmatism. On the contrary, paleosol horizons formed after almost each major eruption event or sequence suggests an overall near-coast terrestrial environment for the BFVA, where the emplacement of the pyroclastic material occurred.
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  • 107
    Publication Date: 2024-02-01
    Description: Regime shifts in the diatom–dinoflagellate composition have occurred in the Baltic Sea (BS) and Bohai Sea (BHS) under eutrophication and have affected the entire coastal ecosystem, damaging the regulatory, provisioning, cultural, and supporting service functions of marine ecosystems. Therefore, finding a solution to restore the balance of phytoplankton community composition and mitigate eutrophication is of utmost importance. In this study, the Driver (per capita gross domestic product)-Pressure (terrestrial inputs)-State (seawater environmental parameters)-Impact (proportions of diatoms and dinoflagellates)-Response (eutrophication governance projects) framework served as a guide for our analysis of the causal relationship among various environmental components in the coastal system. The relevant data in BS and BHS spanning from the 1950s to the 2010s were collected and used to construct a diatom–dinoflagellate composition single index, which allowed us to identify the shifts in regimes (mutation points and phases) of the diatom–dinoflagellate composition and environmental factors using sequential t-test analysis. We also identified key environmental factors that moderated the diatom–dinoflagellate composition using redundancy analysis and analyzed the partial effects of the main environmental factors on the diatom–dinoflagellate composition using a generalized additive model. Finally, the regulation of the eutrophication governance investment on diatom–dinoflagellate composition was investigated. We found that (1) BS is a “time machine,” with coastal eutrophication governance and regime shift of diatom–dinoflagellate composition and environmental factors two decades earlier than that in BHS; (2) in BS, the key moderation factor of diatom proportion is SiO3-Si and those of dinoflagellates are sea surface salinity and N:P ratio; in BHS, the key moderation factors of diatom proportion are PO4-P and Si:N ratio and those of dinoflagellate are dissolved inorganic nitrogen and N:P and Si:P ratios; (3) it is projected that BHS will enter its recovery phase from eutrophication after mid-2020s. In summary, the N/P/Si stoichiometric relationships should be given greater consideration, with the exception of the “dose-response” relationship in both sea areas. Our results indicate an urgent need for an improved mechanistic understanding of how phytoplankton biodiversity changes in response to changes in nutrient load and how we should ultimately deal with the challenges that arise.
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  • 108
    Publication Date: 2024-02-05
    Description: A La Niña condition in the equatorial Pacific began in the early summer of 2020 and has lasted more than two and a half years (referred to as the 2020 La Niña hereafter). Predicting its temporal evolution had attracted a lot of attention. Considering the possible phase-locked impact of the 11-year solar cycle on the tropical Pacific variability, in this study the authors present the possible modulations by the solar cycle 25 (SC25) started from December 2019, on the future temporal evolution of the 2020 La Niña. Based on statistical features of historical solar cycles, the authors propose three possible scenarios of the timing of the SC25 maximum year and discuss its possible impacts on the temporal evolution of the 2020 La Niña in the next two years. The ongoing ascending phase of SC25 dampens the development of a super El Niño condition to some extent in 2023.
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  • 109
    Publication Date: 2024-02-12
    Description: Highlights: • Change in sea urchin species composition from RBC and NRBC habitats. • Sand coverage is an important factor that influences the sea urchin species composition. • The relationship between sea urchins and their habitat is species-specific. Sea urchins are important components of marine ecosystems and can act as bioindicators, reflecting the health of reefs. The spatial patterns of sea urchins are largely shaped by the type of habitat. In Hong Kong, coral communities are divided into two distinct types: reef -building coral habitats and non -reef -building coral habitats. In summer 2020, a qualitative survey was conducted using SCUBA at 56 sites across eastern and western waters, recording a total of 11 species from 6 families of sea urchins. Out of these 56 sites, 14 were selected for a quantitative survey to investigate the relationship between sea urchin assemblages and the two types of coral habitat. We found that the species composition of sea urchins differed significantly between the two habitats, and the presence of sand was a critical factor influencing the species composition of sea urchins. Sand coverage had a positive effect on Salmasic sphaeroides abundance but a negative effect on the abundance of Diadema setosum and Heliocidaris crassispina. The distribution of sea urchins across different degrees of sand coverage may be associated with food availability or species -specific adaptive behaviour, likely due to niche preferences.
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  • 110
    Publication Date: 2024-02-12
    Description: Highlights • East Asian climate evolution was dependent on the latitude of the proto-Tibetan Plateau in the deep past; • Global warming induced wetting at mid-latitude East Asian in the mid-Cretaceous; • The proto-Tibetan Plateau uplift led to drying in the subtropical East Asian in the mid-Cretaceous. Abstract Sedimentary records indicate that subtropical and mid-latitude East Asia exhibited considerable drying and wetting, respectively, during the mid-Cretaceous, which is considered to be relevant to much higher atmospheric carbon dioxide (pCO2) concentrations and/or proto-Tibetan Plateau (proto-TP) uplift. In order to explore and compare their roles on the East Asian climate evolution, we conducted simulations of the mid-Cretaceous climate system with different atmospheric pCO2 levels and varying topographies. The results show that both factors had significant influences on the East Asian climate. As the increase in atmospheric pCO2 levels from ∼560–1120 ppmv to ∼1120–2240 ppmv, the precipitation increases considerably over mid-latitude East Asia, but only small changes in the subtropical portion of East Asia occur. Simultaneously, the effects of the proto-TP uplift are opposite to those of global warming trend during that period. Generally, it leads to a precipitation decrease over subtropical East Asia, but rather minor changes over mid-latitude East Asia. These changes are qualitatively consistent with the deduction based on the geological records, but the magnitudes of the modeled precipitation changes are relatively smaller. Therefore, we can conclude that the subtropical East Asian drying during the mid-Cretaceous can be partly explained by the proto-TP uplift, while the mid-latitude East Asian wetting was partly due to global warming. However, additional factor(s) also played a significant role in the East Asian climate evolution during the mid-Cretaceous.
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  • 111
    Publication Date: 2024-02-12
    Description: Carbon dioxide removal (CDR) – the creation, enhancement, and upscaling of carbon sinks – has become a pillar of national and corporate commitments towards Net Zero emissions, as well as pathways towards realizing the Paris Agreement's ambitious temperature targets. In this perspective, we explore CDR as an emerging issue of Earth System Governance (ESG). We draw on the results of a workshop at the 2022 Earth System Governance conference that mapped a range of actors, activities, and issues relevant to carbon removal, and refined them into research questions spanning four intersecting areas: modeling and systems assessment, societal appraisal, policy, and innovation and industry. We filter these questions through the five lenses of the ESG framework and highlight several key ‘cross-cutting’ issues that could form the basis of an integrated ESG research agenda on CDR.
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  • 112
    Publication Date: 2024-02-12
    Description: Highlights • Cu complexation was measured for the first time in the Fram Strait region. • Cu-binding ligand concentrations and binding strength varied longitudinally in the Fram Strait. • More than 99 % of dCu was organically complexed by strong ligands. • On the Greenland shelf the Transpolar Drift and the coastal processes were the main sources of Cu ligands. Abstract The Fram Strait represents the major gateway of Arctic Ocean waters towards the Nordic Seas and North Atlantic Ocean and is a key region to study the impact of climate change on biogeochemical cycles. In the region, information about trace metal speciation, such as copper, is scarce. This manuscript presents the concentrations and conditional stability constants of copper-binding ligands (LCu and log KcondCu2+L) in the water column of Fram Strait and the Greenland shelf (GEOTRACES cruise GN05). Cu-binding ligands were analysed by Competitive Ligand Exchange-Adsorptive Cathodic Stripping Voltammetry (CLE-ACSV) using salicylaldoxime (SA) as competitive ligand. Based on water masses and the hydrodynamic influences, three provinces were considered (coast, shelf, and Fram Strait) and differences were observed between regions and water masses. The strongest variability was observed in surface waters, with increasing LCu concentrations (mean values: Fram Strait = 2.6 ± 1.0 nM; shelf = 5.2 ± 1.3 nM; coast = 6.4 ± 0.8 nM) and decreasing log KcondCu2+L values (mean values: Fram Strait = 15.7 ± 0.3; shelf = 15.2 ± 0.3; coast = 14.8 ± 0.3) towards the west. The surface LCu concentrations obtained above the Greenland shelf indicate a supply from the coastal environment to the Polar Surface Water (PSW) which is an addition to the ligand exported from the central Arctic to Fram Strait. The significant differences (in terms of LCu and log KcondCu2+L) between shelf and coastal samples were explained considering the processes which modify ligand concentrations and binding strengths, such as biological activity in sea-ice, phytoplankton bloom in surface waters, bacterial degradation, and meltwater discharge from 79NG glacier terminus. Overall, the ligand concentration exceeded those of dissolved Cu (dCu) and kept the free copper (Cu2+) concentrations at femtomolar levels (0.13–21.13 fM). This indicates that Cu2+ toxicity limits were not reached and dCu levels were stabilized in surface waters by organic complexes, which favoured its transport to the Nordic Seas and North Atlantic Ocean and the development of microorganism.
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  • 113
    Publication Date: 2024-02-14
    Description: The increasing global demand for seafood, coupled with the limitations of current fish stocks and aquaculture practices, requires the development of sustainable aquaculture solutions. In this context, this study explores the potential of a novel cage technology - Flow2Vortex - for the cultivation of jellyfish, a low-trophic-level organism with increasing market demand. The unique cage design creates a laminar and circular water flow, providing optimal conditions for cultivating fragile planktonic species. Indoor experiments demonstrated the successful growth of jellyfish in the cage, with growth rates of up to 11.6% per day. In addition, field tests in open waters confirmed the cage's ability to maintain a diffuse and controlled flow inside, even under strong external currents. The cage also maintained significantly higher zooplankton concentrations than the surrounding environment, offering a consistent food source for the cultivated jellyfish. These findings highlight the potential of the Flow2Vortex cage for scalable indoor and outdoor cultivation of low-trophic-level organisms, such as jellyfish, contributing to the diversification and sustainability of aquaculture practices.
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  • 114
  • 115
    Publication Date: 2024-02-22
    Description: Highlights • More diverse non-native taxa generally include more economically costly species. • Chordates, nematodes and pathogens are among significantly over-represented taxa. • Monetary cost magnitude links positively to numbers of costly invasive species. • Costs are biased towards a few ‘hyper-costly’ invasive species groups. • Future invasion rates will continue to harbour new economically costly species. Abstract A dominant syndrome of the Anthropocene is the rapid worldwide spread of invasive species with devastating environmental and socio-economic impacts. However, the dynamics underlying the impacts of biological invasions remain contested. A hypothesis posits that the richness of impactful invasive species increases proportionally with the richness of non-native species more generally. A competing hypothesis suggests that certain species features disproportionately enhance the chances of non-native species becoming impactful, causing invasive species to arise disproportionately relative to the numbers of non-native species. We test whether invasive species with reported monetary costs reflect global numbers of established non-native species among phyla, classes, and families. Our results reveal that numbers of invasive species with economic costs largely reflect non-native species richness among taxa (i.e., in 96 % of families). However, a few costly taxa were over- and under-represented, and their composition differed among environments and regions. Chordates, nematodes, and pathogenic groups tended to be the most over-represented phyla with reported monetary costs, with mammals, insects, fungi, roundworms, and medically-important microorganisms being over-represented classes. Numbers of costly invasive species increased significantly with non-native richness per taxon, while monetary cost magnitudes at the family level were also significantly related to costly invasive species richness. Costs were biased towards a few ‘hyper-costly’ taxa (such as termites, mosquitoes, cats, weevils, rodents, ants, and asters). Ordination analysis revealed significant dissimilarity between non-native and costly invasive taxon assemblages. These results highlight taxonomic groups which harbour disproportionately high numbers of costly invasive species and monetary cost magnitudes. Collectively, our findings support prevention of arrival and containment of spread of non-native species as a whole through effective strategies for mitigation of the rapidly amplifying impacts of invasive species. Yet, the hyper- costly taxa identified here should receive greater focus from managers to reduce impacts of current invasive species.
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  • 116
  • 117
    Publication Date: 2024-02-23
    Description: Highlights: • Ca. 418 ka Pauzhetka tephra from South Kamchatka was found in 11 marine sediment cores. • New major and trace element analyses allow identification of tephra glasses. • K/Ti and K/Fe maxima mark the Pauzhetka tephra presence in marine sediments. • The tephra occurs at Marine Isotope Stages 12 to 11c and below the Bermuda excursion. • The revised ash dispersal covers vast areas in the NW Pacific and Okhotsk Sea. Abstract: The distal Pauzhetka tephra, formed by a large caldera-forming volcanic eruption in South Kamchatka, has been identified in eleven recently recovered marine sediment cores based on major and trace element compositions of tephra glass. Ten SO264 cores form a transect along the Emperor Seamount Chain (ESC) in the Northwest (NW) Pacific between ∼50.3° and ∼45°N, 800–1200 km southeast of the Pauzhetka caldera. One additional core LV28-41-4 was retrieved in the Okhotsk Sea, ∼600 km west of the caldera. The Pauzhetka tephra glass shards have a characteristic medium-K rhyolite composition and trace element content compatible with the rear-arc position of the source volcano that ensures their identification. In the NW Pacific SO264 cores, the tephra is preserved as layers in cores 33, 47, 49, 53, 55, 56 and 62, as a lens in core 45, and as cryptotephra in cores 57 and 66. It forms a cryptotephra in the Okhotsk Sea core LV28-41-4. Distinctively high XRF-retrieved K/Ti and K/Fe ratios compared to those for the host sediments help identify the Pauzhetka tephra. According to our refined stable oxygen isotope (δ18O)- and magneto-stratigraphy of two studied and two reference cores, the Pauzhetka tephra occurs within a local δ18O maximum during a transition from marine isotope stage 12 to 11c (Termination V) and below a paleointensity minimum referred to as the Bermuda excursion, at ca. 418 ka. Using the tephra age as an isochron, we show that average linear sedimentation rates decrease southward along a transect of the SO264 cores, except in core 55. It partially reflects an intensification of mid-depth currents causing winnowing, erosion or non-deposition along the ESC over the past 418 kyr. An increased linear sedimentation rate in core 55, recovered from the southern leeward side of the Minnetonka Seamount, appears to record the pelagic accumulation protected from the mid-depth current influence. Our findings expand the former ash dispersal area farther southeast in the NW Pacific and southwest in the Okhotsk Sea. The new data on the tephra thickness supports the axis direction of the fallout zone southeast of the Pauzhetka caldera. Our results suggest the Pauzhetka tephra as a key middle Pleistocene isochron for the stratigraphy and correlation of the NW Pacific and Okhotsk Sea sediments.
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  • 118
    Publication Date: 2024-02-29
    Description: Highlights • Negligible Ba removal observed in the Rainbow hydrothermal system. • Insignificant modification of Ba isotope composition of the vent fluid endmember. • Rainbow vent introduces isotopically light Ba (−0.17) to the deep Atlantic Ocean. • Hydrothermal inputs contribute 4.6 ± 2.2 Gmol/yr Ba to the ocean. Abstract The marine barium (Ba) cycle is closely connected to the short-timescale carbon cycle, and Ba serves as a valuable paleo proxy for export production, ocean alkalinity, and terrestrial inputs. However, the marine Ba budget is poorly constrained, particularly regarding the fluxes of hydrothermally sourced Ba, which hinders our understanding of the Ba cycle and use of Ba-based proxies. Recent studies have suggested a modern source-sink imbalance of Ba isotopes in the global ocean, with sources being overall isotopically heavier than the sinks, and the hydrothermal Ba inputs were considered isotopically heavy sources. In this study, we present the first investigation of Ba and its isotopes in a non-buoyant hydrothermal plume based on dissolved and particulate samples collected from the Rainbow hydrothermal vent field on the Mid-Atlantic Ridge. Our data reveal strong hydrothermal signals at near-field stations, as evidenced by helium isotopes, accompanied by elevated concentrations of dissolved and particulate Ba. Dissolved Ba isotope compositions (δ138Ba) in hydrothermally influenced deep waters (∼0.3 ) are lighter than at similar depths of far-field stations (∼0.45 ) in the Atlantic Ocean. The concentrations and isotopic compositions of dissolved and labile particulate Ba in the non-buoyant hydrothermal plume can be explained by conservative mixing between a Ba-enriched hydrothermal component and North Atlantic Deep Water. By extrapolating the correlations to the vent fluid endmember, our results suggest that there is negligible removal of Ba, and insignificant modification of Ba isotopic signatures, from the vent fluid endmember to the non-buoyant hydrothermal plume. This indicates that the Rainbow hydrothermal system introduces isotopically light Ba (−0.17 ± 0.05 ) to the deep Atlantic Ocean. We estimate that global hydrothermal inputs of Ba are 4.6 ± 2.2 Gmol/yr. These observations highlight the potential of hydrothermal Ba to be an isotopically light source component of the marine Ba isotope budget.
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  • 119
    Publication Date: 2024-03-01
    Description: Highlights: • Transcriptomic immune response assessments in seahorse (Hippocampus erectus). • Seahorses exposed in two phases to heat-killed Vibrio and Tenacibaculum strains. • Adaptive immune memory evidence (double-exposed) and increased naivety to Tenacibaculum. • Upregulated gene expression pertaining to potential innate ‘trained immunity’. • Trained immunity potential compensator for deduced MHC II loss of function. Evolutionary adaptations in the Syngnathidae teleost family (seahorses, pipefish and seadragons) culminated in an array of spectacular morphologies, key immune gene losses, and the enigmatic male pregnancy. In seahorses, genome modifications associated with immunoglobulins, complement, and major histocompatibility complex (MHC II) pathway components raise questions concerning their immunological efficiency and the evolution of compensatory measures that may act in their place. In this investigation heat-killed bacteria (Vibrio aestuarianus and Tenacibaculum maritimum) were used in a two-phased experiment to assess the immune response dynamics of Hippocampus erectus. Gill transcriptomes from double and single-exposed individuals were analysed in order to determine the differentially expressed genes contributing to immune system responses towards immune priming. Double-exposed individuals exhibited a greater adaptive immune response when compared with single-exposed individuals, while single-exposed individuals, particularly with V. aestuarianus replicates, associated more with the innate branch of the immune system. T. maritimum double-exposed replicates exhibited the strongest immune reaction, likely due to their immunological naivety towards the bacterium, while there are also potential signs of innate trained immunity. MHC II upregulated expression was identified in selected V. aestuarianus-exposed seahorses, in the absence of other pathway constituents suggesting a possible alternative or non-classical MHC II immune function in seahorses. Gene Ontology (GO) enrichment analysis highlighted prominent angiogenesis activity following secondary exposure, which could be linked to an adaptive immune process in seahorses. This investigation highlights the prominent role of T-cell mediated adaptive immune responses in seahorses when exposed to sequential foreign bacteria exposures. If classical MHC II pathway function has been lost, innate trained immunity in syngnathids could be a potential compensatory mechanism.
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  • 120
    Publication Date: 2024-03-04
    Description: Climate change is driving compositional shifts in ecological communities directly by affecting species and indirectly through changes in species interactions. For example, competitive hierarchies can be inversed when competitive dominants are more susceptible to climate change. The brown seaweed Fucus vesiculosus is a foundation species in the Baltic Sea, experiencing novel interactions with the invasive red seaweed Gracilaria vermiculophylla, which is known for its high tolerance to environmental stress. We investigated the direct and interactive effects of warming and co-occurrence of the two algal species on their performance, by applying four climate change-relevant temperature scenarios: 1) cooling ) 2 °C below ambient – representing past conditions), 2) ambient summer temperature (18 °C), 3) IPCC RCP2.6 warming scenario (1 °C above ambient), and 4) RCP8.5 warming (3 °C above ambient) for 30 days and two compositional levels (mono and co-cultured algae) in a fully-crossed design. The RCP8.5 warming scenario increased photosynthesis, respiration, and nutrients' uptake rates of mono- and co-cultured G. vermiculophylla while growth was reduced. An increase in photosynthesis and essential nutrients' uptake and, at the same time, a growth reduction might result from increasing stress and energy demand of G. vermiculophylla under warming. In contrast, the growth of mono-cultured F. vesiculosus significantly increased in the highest warming treatment (+3 °C). The cooling treatment (−2 °C) exerted a slight negative effect only on co-cultured F. vesiculosus photosynthesis, compared to the ambient treatment. Interestingly, at ambient and warming (RCP2.6 and RCP8.5 scenarios) treatments, both F. vesiculosus and G. vermiculophylla appear to benefit from the presence of each other. Our results suggest that short exposure of F. vesiculosus to moderate or severe global warming scenarios may not directly affect or even slightly enhance its performance, while G. vermiculophylla net performance (growth) could be directly hampered by warming.
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  • 121
    Publication Date: 2024-03-05
    Description: Highlights • Mercury methylation in sediment rapidly transported into water and diatoms. • CH3Hg flux was highest for sediments with higher sulfide and organic content. • Mineral and compressed sediment released minor Hg and CH3Hg. • Higher sediment Hg species flux does not correlate with high sediment content. • Stable isotope incubations provide substantial insight to environmental Hg cycling. Abstract Mercury (Hg) is a conspicuous and persistent global pollutant. Ionic Hg can be methylated into noxious methylmercury (CH3Hg), which biomagnifies in marine tropic webs and poses a health risk to humans and organisms. Sediment Hg methylation rates are variable, and the output flux of created CH3Hg are dependent on sediment characteristics and environmental factors. Thus, uncertainties remain about the formation and flux of CH3Hg from sediment, and how this could contribute to the bioaccumulative burden for coastal organisms in shallow ecosystems. Cores were collected from 3 estuarine locations along the Eastern USA to examine how sediments characteristics influence the introduction of Hg and CH3Hg into the base of the food chain. Stable isotopes of inorganic 200Hg and CH3199Hg were injected into sediments of individual cores, with cultured diatoms constrained to overlying waters. Five different treatments were done on duplicate cores, spiked with: (1) no Hg isotopes (control); (2) inorganic 200Hg; (3) CH3199Hg; (4) both 200Hg and CH3199Hg isotopes, (5) both 200Hg and CH3199Hg into overlying waters (not sediment). Experimental cores were incubated for 3 days under temperature and light controlled conditions. These results demonstrate that upper sediments characteristics lead to high variability in Hg cycling. Notably, sediments which contained abundant and peaty organic material (∼28 %LOI), had the highest pore water DOC (3206 μM) and displayed bands of sulfur reducing bacteria yielded the greatest methylation rate (1.97 % day−1) and subsequent diatom uptake of CH3200Hg (cell quota 0.18 amol/cell) in the overlying water.
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  • 122
    Publication Date: 2024-03-05
    Description: Highlights • Solutions to the climate crisis are not ahistorical. • Both social and technical processes explain their rise (or fall) on the agenda. • Thinking about ocean CDR closely co-evolved with scientific understandings of global climate change. • Ocean CDR methods have followed cycles of hype, controversy and disappointment. • Key sociotechnical configurations and narrative changes explain the new hype around ocean CDR. Abstract While the ocean has long been portrayed as a victim of climate change, threatened by ocean warming and acidification, it is now increasingly framed as a key solution to the climate crisis. In particular, the promising carbon sequestration potential of the ocean is being emphasised. In this paper, we seek to historicise the practices, discourses and actors that have constructed the ocean as a climate change solution space. We conceptualise the debate about the mitigation potential of the ocean as a contested site of governance, where varying actors form alliances and different sociotechnical narratives about climate action play out. Using an innovative quali-quantitative methodology which combines scientometrics with document analysis, observational fieldwork, and interviews, we outline three historical phases in the history of ocean carbon sequestration that follow recurring cycles of hype, controversy and disappointment. We argue that the most recent hype around ocean carbon sequestration was not triggered by a technological breakthrough or a reduction in scientific uncertainty, but by new socio-technical configurations and coalitions. We conclude by showing that how climate change solutions are put on the agenda and become legitimised is both a scientific and political process, linked to how science frames the climate crisis, and ultimately, its governance.
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  • 123
    Publication Date: 2024-03-08
    Description: Marine heatwaves (MHWs) are widely recognized as prolonged periods of significantly elevated sea surface temperatures, leading to substantial adverse impacts on marine ecosystems. However, a comprehensive understanding of their characteristics and potential changes under climate change in the South China Sea (SCS, 0 ∼ 25°N, 105 ∼ 125°E) remains insufficient. Here, utilizing the OISST V2.0 reanalysis dataset, our study first examines MHW characteristics and their trends in the SCS during the historical period (1982 ∼ 2014). Then, in accordance with the criteria established in this study, GFDL-ESM4, EC-Earth3-Veg, NESM3, EC-Earth3, and GFDL-CM4 are identified from the CMIP6 ensemble of 19 models for their enhanced simulations of historical MHW characteristics. Moreover, considering that the fixed and sliding threshold methods offer distinct perspectives on the future evolution of MHWs, we employ both approaches to evaluate MHW characteristics under projected scenarios for the future period (2015 ∼ 2100) and subsequently compare the disparities between the two methodologies. The outcomes obtained using these methods consistently indicate that MHWs in the SCS are anticipated to intensify and persist for longer durations in the future. Besides, addressing seasonal variability, the peak intensity of MHWs falls in May during both the historical period and the four projected future scenarios. This study provides valuable insights into the behavior of MHWs in the SCS within the context of climate change, underscoring the urgency of adopting effective mitigation strategies. Especially, the use of two definition methods provides a more comprehensive set of information for understanding the future changes of MHWs in the SCS.
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  • 124
    Publication Date: 2024-03-18
    Description: Highlights: • Huidobria chilensis is an endemic shrub distributed in the south of the Atacama Desert with a disjunct population at the northern coast. • Population and genetic structure correlate with geographic distance and geological factors. • Rain fall and fog, as well as ground water, must be regarded as important factors for populations at the coast and the Andean valleys, respectively. • A combination of different software tool to analyze GBS data allowed a good understanding of the population structure and genetic diversity. Abstract: Survival in hyperarid deserts is a major challenge for life in general and for plants in particular. The Atacama Desert presents harsh conditions such as limited rainfall, crusted soils, high soil salinity, high altitude, and intense solar radiation. These conditions, together with paleoclimatic variations over the last 10 million years, have influenced the genetic structure and connectivity of plant populations, resulting in a diverse flora with high endemism. However, the diversification of most lineages appears to be relatively recent, in contrast to the reported age of the Atacama Desert and the onset and expansion of hyperarid conditions since the late Oligocene and early Miocene. A prominent exception is Huidobria chilensis (Loasaceae), which is thought to be endemic to the Atacama since the Eocene. However, it is still not understood why this plant has been successful in adapting to the harshening environmental conditions. To investigate its genetic structure in relation to the history of the Atacama Desert, we studied 186 individuals from 11 populations using genotyping-by-sequencing (GBS). A total of nearly 56 k genome-wide single nucleotide polymorphisms (SNPs) were analyzed for population structure and genetic diversity. We identified four genetic clusters corresponding to geographic regions: the coastal region south of Tocopilla, the Cordillera de la Costa around Chañaral, and the Copiapó catchment 1 and 2. Genetic diversity within and between these clusters was analyzed along with rainfall, altitude, and landscape data. Although the genetic data support `isolation by distance’ as a major factor for genetic divergence between populations, the study also reveals the influence of topography on the distribution of H. chilensis and highlights the role of hydrologically connected watersheds and rivers in plant migration and colonization. This shapes the species' evolutionary trajectory and genetic diversity. Understanding these patterns in H chilensis lets one draw general conclusions about adaptation and survival strategies of plants in extreme desert environments such as the Atacama.
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  • 125
    Publication Date: 2024-03-15
    Description: Highlights: • Microphytobenthos contributed to the particulate organic matter in both beaches. • Allochthonous materials provide relevant contributions to the POM in surf zones. • Estuarine subsidies' availability determines changes in consumers' isotopic niches. • Higher estuarine trophic subsidies resulted in narrower niches of dominant species. Abstract: Benthic invertebrates in the surf zone of exposed sandy beaches represent important links for energy circulation between benthic and pelagic food webs. This work assesses the trophic ecology of co-occurring epi- and hyper-benthic invertebrates inhabiting the surf zone of sandy beaches located close to an estuarine mouth. It illustrates that different sources of organic matter induce changes in resource utilization. The trophic positions, and the niche width and overlap of species were described using δ13C and δ15N stable isotope analysis. The contribution of different sources to the particulate organic matter was quantified through stable isotopes analysis and fatty acids profiles. Shifts in the trophic niches of dominant species reflected a decrease in the contribution of estuarine carbon to the diets along the coast. This change in contribution of estuarine carbon also influenced trophic niche properties: more diverse resources availability resulted in narrower niches without overlap while less diverse resources resulted in broad isotopic niches and a highest overlap. Results show that spatial variations in the availability of resources can modify carbon pathways and trophic interactions in coastal food webs. Whenever resources are abundant, species display a more specialized diet while food scarcity leads to broader diets, a pattern consistent with the optimal foraging theory. This resource maximization behavior commonly observed in nature is also occurring in surf zone ecosystems.
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  • 126
    Publication Date: 2024-03-22
    Description: High dissolved iron (dFe) concentrations of the order of 10-100 nmol L-1 are a feature of waters influenced by sedimentary inputs in oxygen minimum zones (OMZ). However, the temporal development of dFe concentrations is poorly defined due to a general reliance on snapshot cross-shelf sections to study marine trace metal dynamics. Multiple cruise campaigns since the 1980s have investigated Fe dynamics over the Peruvian shelf, particularly between 9-17°S where the shelf is broad, extremely productive and known to feature benthic dFe effluxes which are amongst the highest measured globally. This extensive long-term dataset uniquely allows us to study the interannual variability in dFe concentrations and their response to El Niño–Southern Oscillation (ENSO) events. By combining data from 11 cruises during the period 1984-2017 we are able to evaluate dFe dynamics on interannual timescales in a major OMZ. The region where average dFe concentrations are sensitive to variations in ENSO is confined to a subsurface layer at depths between 50-150 m, particularly in the narrow coastal region within 50 km of the coastline. Subsurface dFe concentrations were generally low during El Niño events (0.7-15.4 nmol L-1) and relatively high with a wider range of variability during the cold ENSO phase (1.1-52.1 nmol L-1). Inverse relationships between wind speed and surface/subsurface dFe were evident. In the subsurface layer, this may be attributable to enhanced dFe offshore transport along isopycnals when upwelling-favorable winds relax in accordance with previously outlined theories. Surface layer (〈40 m) dFe variability was likely associated with a dilution and/or oxidation effect depending on the strength of wind driven water column mixing. Upwelling brings macronutrient-rich water into the euphotic zone, but its intensity had a limited impact on upper layer dFe concentrations possibly due to the influence of an onshore geostrophic flow. Interannual variability in surface chlorophyll-a (Chl-a) was found to correlate with dFe concentration in the offshore zone of northern Peru. This is consistent with bioassay experiments and climatological residual nitrate concentrations which both indicate proximal Fe limitation of phytoplankton growth over and beyond the northern Peruvian shelf. Overall, our work highlights the importance of physical factors driving short-term variations in Fe availability in one of the world’s most economically important fishery regions and suggests that, despite pronounced spatial and temporal variability in dFe concentrations, the ENSO phase has an impact on dFe availability.
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  • 127
    Publication Date: 2024-03-22
    Description: Underwater image restoration has been a challenging problem for decades since the advent of underwater photography. Most solutions focus on shallow water scenarios, where the scene is uniformly illuminated by the sunlight. However, the vast majority of uncharted underwater terrain is located beyond 200 meters depth where natural light is scarce and artificial illumination is needed. In such cases, light sources co-moving with the camera, dynamically change the scene appearance, which make shallow water restoration methods inadequate. In particular for multi-light source systems (composed of dozens of LEDs nowadays), calibrating each light is time-consuming, error-prone and tedious, and we observe that only the integrated illumination within the viewing volume of the camera is critical, rather than the individual light sources. The key idea of this paper is therefore to exploit the appearance changes of objects or the seafloor, when traversing the viewing frustum of the camera. Through new constraints assuming Lambertian surfaces, corresponding image pixels constrain the light field in front of the camera, and for each voxel a signal factor and a backscatter value are stored in a volumetric grid that can be used for very efficient image restoration of camera-light platforms, which facilitates consistently texturing large 3D models and maps that would otherwise be dominated by lighting and medium artifacts. To validate the effectiveness of our approach, we conducted extensive experiments on simulated and real-world datasets. The results of these experiments demonstrate the robustness of our approach in restoring the true albedo of objects, while mitigating the influence of lighting and medium effects. Furthermore, we demonstrate our approach can be readily extended to other scenarios, including in-air imaging with artificial illumination or other similar cases.
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  • 128
    Publication Date: 2024-03-26
    Description: This review has been undertaken to understand the effectiveness of ocean acidification on oceanic micronutrient metal cycles (iron, copper and zinc) and its potential impacts on marine biota. Ocean acidification will slow down the oxidation of Fe(II) thereby retarding Fe(III) formation and subsequent hydrolysis/precipitation leading to an increase in iron bioavailability. Further, the increased primary production sustains enzymatic bacteria assisted Fe(III) reduction and subsequently the binding of weaker ligands favours the dissociation of free Fe(II) ions, thus increasing the bioavailability. The increasing pCO2 condition increases the bioavailability of copper ions by decreasing the availability of free CO32− ligand concentration. The strong complexation by dissolved organic matter may decrease the bioavailable iron and zinc ion concentration. Since ocean acidification affects the bioavailability of essential metals, studies on the uptake rates of these elements by phytoplankton should be carried out to reveal the future scenario and its effect on natural environment.
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  • 129
    Publication Date: 2024-03-25
    Description: The impact of oxygen on the preservation of organic matter in marine surface sediments is still controversial. We revisited this long-standing debate by determining the burial efficiency of sedimentary organic matter in the Black Sea, the largest anoxic and euxinic basin in the modern ocean. Surface sediments were sampled in the Danube paleodelta on the northwestern margin of the Black Sea at 420–1550 m water depth. Steady-state modeling of solid species (particulate organic carbon and nitrogen) and solutes (ammonium, sulfate, and total alkalinity) in sediments was performed to quantify rates of mass accumulation, particulate organic matter (POM) degradation, and POM burial. We develop a novel analytical model to quantify these rates applying an inverse modelling approach to down core data accounting for molecular diffusion, sediment burial and compaction. Our model results indicate that 56.7 ± 6.6 % of the particulate organic matter deposited in the study area is not degraded in surface sediments but accumulates below 10 cm sediment depth. This burial efficiency is substantially higher than those previously derived for seafloor areas underlying oxygenated bottom waters. Hence, our study confirms previous studies showing that euxinic bottom water conditions promote the preservation of particulate organic matter in marine sediments.
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  • 130
    Publication Date: 2024-03-25
    Description: The TetraEther indeX of 86 carbon atoms (TEX86) is widely used as a proxy to reconstruct past sea surface temperatures. Most current applications of TEX86 are primarily based on analyzing the composition of isoprenoid glycerol dialkyl glycerol tetraethers (isoGDGTs) that comprise TEX86 in sediments, with the assumption that the sedimentary isoGDGTs are mainly derived from the surface mixed layer. Here we report on the variations in the isoGDGT distribution, archaeal abundance and community through the water column of the Western Pacific Ocean, directly testing the export depth of isoGDGTs and constraining the temperature records of TEX86. Our data show that maximum isoGDGT concentrations occurred in subsurface waters (150–200 m) with maximum archaeal abundances. The ratio between isoGDGTs bearing 2 vs. 3 cyclopentane moieties, i.e. [2/3] ratio, increased with depth, which is likely related to the shift of the archaeal community from Ca. Nitrosopelagicus-dominance to norank_f__Nitrosopumilaceae-dominance. Models based on the [2/3] ratios in the water column predicted an average export depth of isoGDGTs to sediments of around 150–200 m, consistent with the robust relationship between the compiled sedimentary TEX86 and the annual mean subsurface temperature. Taken together, our findings support that TEX86 records subsurface rather than surface temperatures in the open ocean.
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  • 131
  • 132
    Publication Date: 2024-03-25
    Description: The ocean region along the latitude of 40oS in the South Atlantic, characterized by enhanced primary productivity, forms a transition zone between the nutrient replete but iron depleted Southern Ocean, and the nitrate and iron depleted Subtropical Gyre. Here, we present distributions of nutrient-type dissolved and particulate trace metals (dTMs and pTMs) including cadmium (Cd), nickel (Ni), copper (Cu), and zinc (Zn) in the South Atlantic from the GEOTRACES GA10 cruises. Phytoplankton uptake, riverine and atmospheric inputs shaped dTM and pTM concentrations in surface waters (dCd 27.8±36.0 pmol kg-1, n=222; dCu 0.732±0.429 nmol kg-1, n=222; dNi 3.38±0.52 nmol kg-1, n=219; dZn 0.332±0.398 nmol kg-1, n=214). Subsurface nutrients and dTMs (dCd 563±184 pmol kg-1, n=335; dCu 1.819±0.773 nmol kg-1, n=334; dNi 6.19±1.06 nmol kg-1, n=330; dZn 3.71±2.10 nmol kg-1, n=333) were controlled by the mixing of Antarctic origin waters and North Atlantic Deep Waters (NADW) with negligible contributions from local remineralization. Dissolved and particulate TMs in the Argentine Basin showed elevated concentrations towards the seafloor because of benthic inputs. Direct hydrothermal inputs of dTMs and pTMs to deep waters were not observed along the transect. The Cd-Cu-Zn-phosphate stoichiometries of Antarctic origin waters were set by a combination of dynamic physical circulation and preferential uptake of Cd, Cu, and Zn relative to phosphate in surface waters because of a dominance by diatoms in the Southern Ocean. Water mass mixing subsequently produced convoluted dCu-P and dZn-P relationships and apparent linear dCd-P and dNi-P relationships in the South Atlantic. More importantly, endmember characteristics of Antarctic waters and NADW are largely fixed in their formation regions in high latitude oceans. Therefore, the highly dynamic high latitude oceans are key regions that supply nutrients and TMs at specific ratios to low latitude oceans via the thermohaline circulation. Changes to processes in the high latitude oceans may have consequences for marine primary productivity downstream, and hence the global carbon cycle.
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  • 133
    Publication Date: 2024-03-25
    Description: Highlights • Investigation into the potential of Porites microatolls for SST reconstruction. • Comparison between recent and more conventional coral paleoclimatology methods. • Application of Srsingle bondU and Li/Mg paleothermometer. • Accuracy and reproducibility of Sr/Ca proved to be the most suitable proxy for SST reconstruction. Abstract Massive dome-shaped coral Porites are the predominant choice for paleoclimate studies due to their consistent and reliable growth. When growing close to sea level, they become limited in their vertical growth and form so-called ‘microatolls’. Microatolls have not yet been extensively explored for paleoclimate reconstruction. Here, we investigate how reliable modern Porites microatolls are against empirical sea-surface temperature using Sr/Ca, δ18O, Li/Mg and Srsingle bondU paleothermometry methods on samples from the Society Islands, French Polynesia. Our results show Sr/Ca ratios have the lowest Standard Error of the Inverse Prediction (SEIP) at 0.415 °C (N = 41) with a calibration of Sr/Ca (mmol mol−1) = −0.082 ± 0.006 SST (°C) + 11.256 ± 0.170 and with high reproducibility across multiple corals. The reproducibility of δ18O was less good, with SEIP increasing to 0.829 °C (N = 41). Considering methods directly from the literature, Li/Mg ratio empirically corrected for Sr/Ca had the best balance between bias and precision where no local calibration could be available. This study independently evaluates and confirms the suitability of Porites microatolls from well-flushed environments for paleoclimate studies. Fossil dome-shaped Porites grow anywhere between near-surface and roughly 20 m depths which inherently incorporates uncertainty into any sea surface temperature reconstruction. This uncertainty is significantly reduced for microatolls due to their well-constrained bathymetry. The study represents a fundamental step in paleoclimate research targeting consistently near the water-air interface bringing reliability and, especially when combined with their ability to reconstruct past sea-level changes, microatolls have the potential to be central for future paleoenvironmental studies.
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  • 134
    Publication Date: 2024-04-03
    Description: Highlights • Present day infiltration conditions in an monsoonal environment are studied. • Noble gas concentrations in groundwater are fixed near the soil surface. • Noble gas temperatures represent seasonal infiltration conditions in the monsoon. • Holocene and modern infiltration conditions are quite similar in southern Oman. Abstract Comparing directly measured soil temperatures with noble gas recharge temperatures (NGTs) inferred from noble gas concentrations indicates that the infiltrating soil water equilibrates with soil air near the soil surface during the rainy season. Therefore, NGTs of groundwater recently recharged by the Indian Summer Monsoon (ISM) in the Dhofar Mountains in southern Oman reflect the soil temperatures of the 3-month period and do not represent an annual mean. This finding highlights the need to account for seasonality when interpreting NGT data in regions with pronounced dry and wet seasons. We extend the observations from the southern flank of the Dhofar Mountains to three wells situated on the northern flank of the Dhofar Mountains. Two of these wells yield water of Holocene age that was recharged by the monsoon, their NGT signals are therefore classified as seasonal. The NGT calculated from a third well for recharge conditions during the Last Glacial Maximum (LGM), when the ISM was absent, is approximately 3 °C lower than that of the two Holocene wells. The lower LGM noble gas temperature corresponds well with the lower annual Sea Surface Temperature (SST) in the nearby Arabian Sea. NGTs from published studies from northern Oman are 1–3 °C higher when compared with our data of the same period in the southern Oman. We explain this regional difference of reconstructed temperatures for the LGM and Holocene groundwater with a more continental climatic influence on the infiltration conditions further to the north. The published NGTs from northern Oman show a large temperature difference between the late Holocene and the LGM. In view of our finding of seasonal NGT signals under monsoonal climate, part of this difference may reflect a change in the precipitation regime rather than in air temperature.
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  • 135
    Publication Date: 2024-04-03
    Description: Highlights • This study simulates the sedimentation-driven development of multiple stacked BSRs in the Danube paleo-delta, Black Sea. • Formation of multiple BSRs in the Black Sea is controlled by the sequence of sedimentation events of the levees induced by sea-level changes. • Kinetics of phase transitions plays a key role in the coexistence, location, and timing of the multiple BSRs. • Development of multiple stacked BSRs is possible only under a narrow range of parameters, unique for the Danube delta setting. Abstract The gas hydrate stability zone (GHSZ) is defined by pressure-temperature-salinity (pTS) constraints of natural gas hydrate (GH) system. It refers to a depth interval which usually extends several hundred meters into the sediment column at sufficient water depths. The lower boundary of the GHSZ often coincides in seismic reflection data with a bottom simulating reflector (BSR), which indicates the transition between the underlying free gas and the overlying no-free gas zone at the thermodynamic stability boundary. The GHSZ in geological systems is dynamic and can shift in response to sedimentation processes and/or changes in environmental conditions such as bottom water temperatures, hydrostatic pressure, and water salinity. The appearance of multiple BSRs has been interpreted as remnants of former GHSZ shifts which have persisted over geological timescales. In this study, we numerically simulate the sedimentation-driven development of multiple stacked BSRs in the Danube deep-sea fan in the Black Sea. We show that in this dynamic sediment depositional regime sufficient amounts of residual gas remain trapped in the former GHSZ, given sufficiently high initial gas hydrate saturations, so that paleo-BSRs could persist over long time scales (similar to 300 kyr). In particular, the formation and persistence of multiple BSRs in the Danube Delta is controlled by the sequence of sedimentation events of the levees induced by sea-level change. The kinetics of methane phase transitions between gas hydrate, dissolved methane, and free gas plays a key role in the coexistence, location and timing of the multiple BSRs. Thus, For a given permeability, distinct multiple BSRs appear only for a narrow range of GH formation (10(-14) 〈 k(f) [mol/m(2) Pa s] 〈= 10(-12)) and dissociation rates (10(-16) 〈 k(d) [mol/m(2) Pa s] 〈 10(-14)).
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  • 136
    Publication Date: 2024-04-03
    Description: Multiple stressors often act concomitantly on ecosystems but detection of species responses follows the “single species-single driver” strategy, and cumulative impacts are seldom considered. During 1990–2010, multiple perturbations in the Caspian Sea, led to the decline of kilka, sturgeon and Caspian seal populations. Specific causes for their collapse were identified but a cumulative assessment has never been carried out. Using loop analysis, a qualitative modelling technique suitable in poor-data contexts, we show how multiple drivers can be combined to assess their cumulative impact. We confirm that the decline of kilka, sturgeon and Caspian seal populations is compatible with a net effect of the concomitant perturbations. Kilkas collapse was certainly due to the outburst of M. leidyi and overfishing. In addition, the excess nutrient might have conspired to reduce these populations. The interplay between concurrent drivers produces trade-offs between opposite effects and ecosystem management must face this challenge
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  • 137
    Publication Date: 2024-04-03
    Description: Highlights • Four rhyolitic explosive eruption events were distinguished from 13.1 Ma to 11.6 Ma. • Silicic volcanism occurred at termination of subduction in a thinning lithosphere. • Rhyolites show extreme magma differentiation and reduced-dry character. • Zircon trace element and Hf isotope fingerprint is an effective correlation tool. Abstract The Tokaj Mts. volcanism occurred in a thinning continental lithosphere regime at the final stage of the subduction process. Using high-precision zircon U-Pb dating, four major explosive eruption events were distinguished. Among them the 13.1 Ma Sátoraljaújhely and the 12.0 Ma Szerencs eruptions could have yielded large amount of volcanic material (possibly 〉 100 km3) and they were associated with caldera collapse as shown by the several hundred-metre-thick pyroclastic deposits and the long (〉100 km) runout pyroclastic flow in case of the 13.1 Ma eruption. The 12.3 Ma Hegyköz and the 11.6 Ma Vizsoly eruptions were relatively smaller. The volcanic products can be readily distinguished by zircon and glass trace elements and trace element ratios, which can be used for fingerprinting and to correlate with distal deposits. The Rb, Ba, Sr content and strong negative Eu-anomaly of the glasses reflect extreme crystal fractionation, particularly for the Szerencs rhyolitic magma. The silicic volcanic products of the Tokaj Mts. show compositional similarities with the so-called ‘dry–reduced–hot’ rhyolite type consistent with an origin in an extensional environment, where the primary magmas were formed by near-adiabatic decompression melting in the mantle with subordinate fluid flux. In contrast, some of the older Bükkalja rhyolitic magmas evolved via more hydrous evolutionary paths, where amphibole played a role in the control of the trace element budget. The significant increase of zircon ε Hf values from −8.8 to + 0.2 in the rhyolitic pyroclastic rocks of Tokaj Mts. with time implies that mantle-derived magmas became more dominant. This can be explained by the specific tectonic setting, i.e. the final stage of subduction when the descending subducted slab became almost vertical, which exerted a pull in the upper lithosphere leading to thinning and accelerated subsidence as well as asthenospheric mantle flow just before the slab detachment.
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  • 138
    Publication Date: 2024-04-09
    Description: The overriding physicochemical controls in seawater discussed here are the chemical composition and the state of master variables including temperature, pressure, salinity, pH and redox status. Dissolved Organic Matter also plays a major role, but since its properties are not sufficiently well quantified it is described as an emergent master variable at this stage. The theoretical basis for the treatment of equilibrium chemistry and kinetics is presented, together with projections of the future development of seawater chemistry resulting from climate change. Key points • Composition of seawater • Master variables (temperature, pressure, pH, oxygen/redox state) • The role of Dissolved Organic Matter • Equilibrium chemistry • Kinetics • The consequences of ongoing global changes
    Type: Book chapter , NonPeerReviewed
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  • 139
  • 140
    Publication Date: 2024-04-09
    Description: Highlights • Developed an innovative weighted outlier detection function that adaptively selects the best outlier detection technique, markedly improving precision and robustness in multibeam echosounder data analysis. • Demonstrated superior performance of the weighted function over traditional methods, achieving higher precision, recall, and F1 scores, pivotal for accurate seafloor mapping. • Enhanced data quality for geoscientific applications by effectively identifying and removing outliers without introducing data voids, preserving the integrity of multibeam sonar data. • The function’s significance extends to supporting sustainable environmental and resource management practices through improved accuracy in seabed mapping. • Discussed the adaptability of the method to various outlier patterns and its limitations, highlighting the need for further research and validation across different marine environments and data types. Abstract Multibeam sonar data are a valuable tool for seafloor mapping and geological studies. However, the presence of outliers in multibeam data can distort the results of analyses and reduce the accuracy of seafloor maps. In this paper, we define a weighting function based on the performance of various outlier detection techniques (OTDs) for detecting outliers in multibeam data, which calculates an outlier probability score for each sounding. Our results show that each OTD has its own strengths and weaknesses, and that a combination of outlier detection techniques is promising to improve reproducibility, explainability and the accuracy of the detection process. To address the challenge of detecting outliers in multibeam data, we propose a weighted outlier detection function that outperforms individual outlier detection techniques in terms of precision, recall and F1 scores by considering their strengths and combining them in a way that accounts for variations in the data. The function detects various types of outliers with high precision and recall values, resulting in valuable improvements in outlier detection performance for multibeam data. Overall, our proposed workflow has the potential to significantly improve the way multibeam data cleaning is performed, with the weighted outlier detection function being applied first, detecting most of the outlier automatically, followed by a domain-expert review of a small group of soundings whose automatic outlier labelling is not unequivocal.
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  • 141
    Publication Date: 2024-04-10
    Description: Trace metals (TMs) manganese (Mn), cobalt (Co), and aluminium (Al) have important geochemical and biological roles in the ocean. Here, we present full depth profiles of dissolved (d) and particulate Al, Mn, and Co along the latitude of 40 °S in the South Atlantic Ocean from the GEOTRACES GA10 cruises that operated in austral spring 2010 and summer 2011. The region is characterized by enhanced primary productivity and forms a key transition zone between the Southern Ocean and South Atlantic Subtropical Gyre. The mean concentrations of dAl, dCo, and dMn (±standard deviation) were 3.36 ± 2.65 nmol kg−1, 35.3 ± 17.6 pmol kg−1, and 0.624 ± 1.08 nmol kg−1, respectively. Their distributions in surface waters were determined by external sources and complex internal biogeochemical processes. Specifically, surface ocean dCo was controlled by the interplay between phytoplankton uptake, remineralization and external inputs; dMn was likely determined by the formation and photoreduction of Mn-oxides; and dAl was supplied by atmospheric deposition and removed by scavenging onto particles. Fluvial and sedimentary inputs near the Rio de La Plata estuary and benthic sources from the Agulhas Bank resulted in elevated dTM concentrations in near-shore surface waters. These externally sourced dTMs were effectively delivered to the open ocean by offshore diffusion and/or advection, and potentially facilitated enhanced primary productivity along the transect. The distributions of dTMs at depth were predominantly controlled by the mixing of North Atlantic Deep Water (NADW) and waters of Antarctic origin (e.g., Upper Circumpolar Water (UCDW) and Antarctic Bottom Water (AABW)). The calculated endmember concentrations of dAl and dCo in NADW showed minor decreases in the SASTG following north–south transport, suggesting removal rates of 0.064 nM/year and 0.035–0.075 pM/year, respectively. The endmember concentration of dCo in AABW was maintained at ∼30 pmol kg−1 without evidence for scavenging removal in the Southern Ocean and SASTG (time frame 〉400 years). The concentrations of dMn in NADW and AABW were between 0.1 and 0.16 nmol kg−1, and any elevated dMn concentrations were ascribed to local external inputs (e.g., from sediments in the Argentine Basin and hydrothermal activity near the Mid-Atlantic Ridge). Hence, four controlling factors (sources, internal cycling, water mass mixing and time) need to be considered when assessing TM distributions in the global ocean, even for TMs that are vulnerable to scavenging removal processes. Because the deep waters formed in high latitude oceans are crucial components of the global thermohaline overturning system, any processes (e.g., glacier melting, upwelling and sinking, and biological activity) that impact the preformed dTM concentrations in high latitude oceans will determine the downstream dTM distributions. Therefore, the sources and sinks of TMs and associated biological activity in high latitude oceans could engender basin to global scale impacts on seawater distributions of Al, Co, and Mn and their stoichiometric relationships with macronutrients, and the global biogeochemical cycles of these scavenged-type TMs.
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  • 142
    Publication Date: 2024-04-15
    Description: Fishes occur in a wider range of habitats than any other vertebrate or invertebrate group, from the upper reaches of streams in high mountain ranges to the mouths of temperate and tropical rivers, and from the intertidal zone to the ocean's abyss. Fish grow in size, spawn and die, either from natural causes (predation, diseases, ageing) or from being caught in fishing nets if the population is exploited. These dynamical processes are expressed with mathematical equations and are used in population models to estimate fisheries reference points (stock assessment), which in turn provide the basis for fisheries management. Fish populations subjected to fisheries exploitation are called fish “stocks”. Fishing has been increasingly affecting fish stocks and ecosystems both directly and indirectly, and along with the human-induced climate change they pose major threats to fish biodiversity worldwide. Using the available data stored in local or global databases to assess the status of all stocks, even the data-poor fish stocks, and following an ecosystem approach to fisheries management that incorporates effort reduction through marine protected areas, may contribute to the sustainable exploitation of fisheries resources.
    Type: Book chapter , NonPeerReviewed
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  • 143
    Publication Date: 2024-04-15
    Description: Cadmium (Cd) has a nutrient-like distribution in the ocean, similar to the macronutrient phosphate. Significant isotope fractionation induced by the biological cycling of Cd makes it a potential tracer for nutrients and productivity. However, the Cd flux and Cd isotope composition of marine sediments can also be influenced by local redox conditions and partial remineralization of organically hosted Cd. These confounding factors are under-constrained and render it challenging to use Cd as a reliable paleoproxy. To understand the relative importance of each of these processes, we examined the Cd isotope systematics of 69 modern sediments deposited across a wide range of environments. We complement these data with four profiles of particulate Cd isotope compositions from the Southern Ocean. We report three main results. First, we show that the sedimentary flux of Cd is tightly coupled to that of organic matter. Second, most Cd burial occurs in regions with some bottom-water oxygen, and the flux of CdS to anoxic regions is, globally, minor. Finally, we find that remineralization can substantially modify sedimentary Cd isotope compositions, though it is challenging to relate pelagic and sedimentary processes. For example, we find that the relationship between sedimentary Cd isotope compositions and surface seawater [Cd] is the reverse of that predicted by isotope reactor models. Likewise, sedimentary Cd isotope compositions are anti-correlated with bottom-water oxygen. While this pattern is consistent with preferential remineralization of isotopically heavy Cd, profiles of marine particulate matter reveal the reverse, whereby the Cd isotope composition of large particles, which are most likely to reach the seafloor, becomes increasingly ‘heavy’ with depth. These results highlight how productivity, redox, and remineralization all influence the flux and isotope composition of Cd to marine sediments. While our study suggests that there is no simple way to relate sedimentary Cd isotopes to surface nutrient utilization, our data point toward several potential controls that could form the basis of novel proxies for local redox conditions and remineralization.
    Type: Article , PeerReviewed
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  • 144
    Publication Date: 2024-04-19
    Type: Book chapter , PeerReviewed
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  • 145
    Publication Date: 2024-04-22
    Description: Highlights: • The interactions between vortices in a four-vortex flow field using a rotating water tank. • Driven by the strain field, non-ideal vortices stretch along the centerline, and manifest an asymmetric stretching pattern. • Non-ideal vortices disperse vorticity, accumulate filaments, and exhibit distinctive variations in anti-symmetric vorticity distribution, impacting respective merging efficiency. Abstract: Oceanic vortex merging is an important physical process for the vortex evolution and its impact on marine environment. However, limitation of the in-situ oceanic observational data of vortex merging inhabits its better understanding. This study investigates the interactions between non-ideal vortices in a four-vortex flow field in a rotating tank. We examine the merging stages of anticyclonic vortices, influenced by two other cyclonic vortices and their respective dynamical behaviors and quantify the effects of merging on vortex characteristics. The results indicate a strong shear flow between two counter-rotating vortices, which accelerates the motion of the anticyclonic vortex, while cyclonic ones exhibit greater stability. Subsequently, different stages of non-ideal vortex merging in a co-rotating framework are defined, primarily the encircling stage, rapid approaching stage, and merging vortex stage. In addition, we quantify and compare variations in morphological parameters and anti-symmetric vorticity distribution of non-ideal vortices across these stages. The stretching of vortices primarily occurs along the line connecting their centers due to the strain field exerted by neighboring vortices, resulting in an asymmetric stretching pattern in the interactions among non-ideal vortices. Furthermore, during the merging process, non-ideal vortices disperse vorticity outward and accumulate vortex filaments in the surrounding environment, leading to distinctive variations in anti-symmetric vorticity distribution, affecting their respective merging efficiency.
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  • 146
    Publication Date: 2024-04-22
    Description: In the past three decades, altimeter-based remote sensing has been a widely used system to estimate ocean surface currents. However, it remains a great challenge to effectively resolve scales below ∼100 km at high latitudes and ∼ 300 km at mid-latitudes. In this study, we propose a scheme that utilizes geostrophic equilibrium and surface quasigeostrophy theory (SQG) to improve surface current resolution by incorporating remote sensing sea surface temperature (SST), sea surface height (SSH), and sea surface salinity (SSS) observations. The scheme separately characterizes the larger-scale flows and smaller-scale motions of surface currents. A case study encompassing the Agulhas surface current demonstrates that the smaller-scale motions associated with temperature fronts are well captured by introducing high spatial-temporal resolution SST data. Furthermore, the reconstructed surface current is systemically evaluated by using surface drogued drifters and a Lagrangian synthetic particle tracking tool throughout the South Indian Ocean (SIO) for 2011–2015. Notably, the reconstructed zonal velocity component is closer to the drifter observations than the meridional counterpart and corresponding velocity phase. Regionally, the Antarctic Circumpolar Current (ACC) showcases superior reconstruction performance, with higher skill scores and lower Lagrangian separation distances. However, a relatively large uncertainty is observed around the Agulhas Retroflection (AR) and Greater Agulhas System (GAS), which are linked to complicated regional dynamic regimes. We finally conduct four simulation experiments to explore the effect of different SST products on surface current reconstruction within the subdomain AR. The results indicate the varying potentials of the four evaluated SST products for informing surface current applications. Specifically, the MWIRSST enhances the likelihood of particles reaching the target field, while DMI OI shortens the average deviation distance of the arrived particles.
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  • 147
    Publication Date: 2024-04-22
    Description: Marine imaging studies have unique constraints on the data collected requiring a tool for defining the biological scope to facilitate data discovery, quality evaluation, sharing and reuse. Defining the ‘target population’ is way of scoping biological sampling or observations by setting the pool of organisms to be observed or sampled. It is used in survey design and planning, to determine statistical inference, and is critical for data interpretation and reuse (both images and derived data). We designed a set of attributes for defining and recording the target population in biological studies using marine photography, incorporating ecological and environmental delineation and marine imaging method constraints. We describe how this definition may be altered and recorded at different phases of a project. The set of attributes records the definition of the target population in a structured metadata format to enhance data FAIRness. It is designed as an extension to the image FAIR Digital Objects metadata standard, and we map terms to other biological data standards where possible. This set of attributes serves a need to update ecological metadata to align with new remotely-sensed data, and can be applied to other remotely-sensed ecological image data.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
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  • 148
    Publication Date: 2024-05-02
    Description: Highlights • Development of an autonomous DIC analyzer based on Conductometric technique using a cell with 4 hollow brass electrodes. • CO2 extraction from seawater using a gas diffusion cell with a “Tube In A Tube” configuration and a gas permeable membrane. • Formulation of mathematical temperature and salinity correction to determine accurate DIC concentration. • Demonstration of the analyzer performance in the southwest Baltic Sea. Abstract Background The increase in anthropogenic CO2 concentrations in the Earth's atmosphere since the industrial revolution has resulted in an increased uptake of CO2 by the oceans, leading to ocean acidification. Dissolved Inorganic Carbon (DIC) is one of the key variables to characterize the seawater carbonate system. High quality DIC observations at a high spatial-temporal resolution is required to improve our understanding of the marine carbonate system. To meet the requirements, autonomous DIC analyzers are needed which offer a high sampling frequency, are cost-effective and have a low reagent and power consumption. Results We present the development and validation of a novel analyzer for autonomous measurements of DIC in seawater using conductometric detection. The analyzer employs a gas diffusion sequential injection approach in a “Tube In A Tube” configuration that facilitates diffusion of gaseous CO2 from an acidified sample through a gas permeable membrane into a stream of an alkaline solution. The change in conductivity in the alkaline medium is proportional to the DIC concentration of the sample and is measured using a detection cell constructed of 4 hollow brass electrodes. Physical and chemical optimizations of the analyzer yielded a sampling frequency of 4 samples h−1 using sub mL reagent volumes for each measurement. Temperature and salinity effects on DIC measurements were mathematically corrected to increase accuracy. Analytical precision of ±4.9 μmol kg−1 and ±9.7 μmol kg−1 were achieved from measurements of a DIC reference material in the laboratory and during a field deployment in the southwest Baltic Sea, respectively. Significance This study describes a simple, cost-effective, autonomous, on-site benchtop DIC analyzer capable of measuring DIC in seawater at a high temporal resolution as a step towards an underwater DIC sensor. The analyzer is able to measure a wide range of DIC concentrations in both fresh and marine waters. The achieved accuracy and precision offer an excellent opportunity to employ the analyzer for ocean acidification studies and CO2 leakage detection in the context of Carbon Capture and Storage operations.
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  • 149
    Publication Date: 2024-05-03
    Description: Highlights: • Mnemiopsis leidyi is capable of catching and digesting herring yolk-sac larvae. • Predation on herring larvae is decreasing with prey age and increasing with predator size. • Predation of M. leidyi on herring larvae is not affected by the presence of alternative natural prey represented by the copepod Acartia tonsa. • Substantial predation of M. leidyi on yolk-sac herring larvae may occur in the field, when both overlap spatially and temporarily. Western Baltic spring spawning herring (Clupea harengus, L.) is a commercially important fish stock currently suffering a strong decline. Larval survival is essential for stock recruitment and can be substantially decreased by predation. The comb jelly Mnemiopsis leidyi A. Agassiz, 1865, is a lobate ctenophore which is invasive to the Baltic Sea and a known ichthyoplankton predator. However, predation on herring larvae in the Baltic Sea by M. leidyi has not been studied since its initial establishment in 2006. To address this knowledge gap, we conducted feeding experiments to investigate (1) the predation capability of M. leidyi on herring yolk-sac larvae, and (2) the influence of larval age, (3) predator size and (4) the presence of alternative prey on the clearance rate of M. leidyi on herring yolk-sac larvae. Our results showed that M. leidyi exhibited the ability to capture and digest herring larvae. The clearance rates of M. leidyi on herring larvae decreased with larval age and increased with predator size, while the presence of alternative prey had no effect on clearance rates. This finding suggests that M. leidyi can efficiently consume herring yolk-sac larvae under laboratory conditions. However, further investigations using mesocosm or field studies are necessary to evaluate the potential impact of M. leidyi on the mortality and recruitment of herring yolk-sac larvae under Baltic Sea field conditions.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
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  • 150
    Publication Date: 2023-10-03
    Description: Developing appropriate monitoring strategies in long-quiescent volcanic provinces is challenging due to the rarity of recordable geochemical and geophysical signals and the lack of experienced eruptive phenomenology in living memory. This is the case in the Massif Central (France) where the last eruptive sequence formed the Pavin’s Group of Volcanoes, about 7 ka ago. There, current evidence of a mantle activity reminiscence is suggested by the presence of mineral springwaters, mofettes, and soil degassing. It appears fundamental as a prerequisite to decipher the evolution of the gas phase in the magmatic system at the time of the eruptive activity to understand the meaning of current local gas emissions. In this study, we develop an innovative approach coupling CO2 densimetry and geochemistry of fluid inclusions from products erupted by the Pavin’s Group of Volcanoes. 3D imagery by Raman spectroscopy revealed that carbonate forming in fluid inclusions may lead to underestimation of CO2 density in fluid inclusions by up to 50 % and thus to unreliable barometric estimates. Fortunately, we found that this effect may be limited by focusing on fluid inclusions with a small diameter (〈4 m) and where no solid phase is detected on Raman spectra. The time evolution of the eruptions of the Pavin’s Group of Volcanoes shows a progressive decrease of the pressure of magma storage (from more than 9 kbar down to 1.5-2 kbar) in parallel to magma differentiation (from basanites at Montcineyre to benmoreites at Pavin). The analysis of the noble gases entrapped in fluid inclusions yielded two main conclusions: (1) the helium isotope signature (Rc/Ra = 6.5-6.8) is in the range of values obtained in fluid inclusions from mantle xenoliths in the Massif Central (Rc/Ra = 5.6±1.1, on average) suggesting partial melting of the subcontinental lithospheric mantle, and (2) magma degassing (4He/40Ar* from 4.0 to 16.2) mirrors magma differentiation and the progressive rise of the magma ponding zones of the Pavin’s Group of Volcanoes. According to our modelling, about 80 % of the initial gas phase would be already exsolved from these magmas, even if stored at mantle depth. Based on the results obtained from fluid inclusions, we propose a model of the evolution of the signature of noble gases and carbon isotopes from mantle depth to crustal levels. In this frame, gas emissions currently emitted in the area (Rc/Ra = 6.1-6.7 and 4He/40Ar* = 1.7) point to an origin in the lithospheric mantle. This study strongly encourages the establishment of a regular sampling of local gas emissions to detect potential geochemical variations that may reflect a change from current steady-state conditions
    Description: Published
    Description: 121603
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Fluid inclusions ; Barometry ; Noble gases ; Magma degassing ; Monitoring ; 04.08. Volcanology ; 04.01. Earth Interior
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 151
    Publication Date: 2023-08-29
    Description: In this work, we exploited the ubiquitous seismic noise generated by energy transfer from the sea to the solid Earth (called microseism) to infer the significant wave height data, with the aim of developing a microseismbased monitoring system of the Sicily Channel. We used a combined approach based on statistical analysis and machine learning by using seismic and sea state data (provided by the hindcast maps), recorded between 2018 and 2021.Through spectral and amplitude analysis, we observed that microseism was influenced by the conditions of the seas surrounding Sicily. Correlation analysis demonstrates that microseism mostly originates from sources located up to 400 km from the coastlines. Moreover, employing machine learning algorithms, we successfully reconstruct spatial and temporal sea wave distributions using microseism data. Among the tested methods, the Random Forest algorithm yields the best results, with an R2 value of 0.89 and a mean prediction error of about 0.21 m.
    Description: Published
    Description: 105781
    Description: 4A. Oceanografia e clima
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 152
    Publication Date: 2023-09-19
    Description: The understanding of the relationship between the variation of precipitation stable oxygen isotope ratio (δ18Op) and monsoon activity in the Asian monsoon region is crucial for an in-depth comprehension of the regional hydrological cycle processes and for reconstructing the history of Asian paleomonsoon changes. Based on the 1979–2017 summer δ18Op output by two isotope-enabled atmospheric general circulation models nudged to climate reanalysis data, this study explores the associations of the Indian summer monsoon (IM) and western North Pacific summer monsoon (WNPM) intensities with the interannual variations of the regional δ18Op and their possible physical mechanisms. Statistical analyses demonstrate that the East Asian δ18Op is negatively correlated with the IM intensity while the Indian δ18Op is positively correlated with the WNPM intensity. Moreover, the underlying mechanisms linking the monsoon and δ18Op vary in different regions. In strong IM years, with the intensified convection and increased precipitation near the Indian peninsula, the water vapor isotope ratio (δ18Ov) transported to East Asia has lower values, resulting in the depletion of δ18Op there. The opposite is true for weak IM years. In years of strong WNPM, the intensified convection over the tropical western Pacific and the suppressed convection over the western Indian Ocean may be linked to a Walker-type circulation anomaly, accompanied by the enlarging of the vertical wind shear between the western Pacific and the western Indian Ocean. Accordingly, the decreasing of convection and precipitation over the Arabian Sea results in higher δ18Ov values in the upstream area of India, which ultimately increases δ18Op values in the Indian peninsula through the monsoonal moisture transport; and vice versa.
    Repository Name: EPIC Alfred Wegener Institut
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  • 153
    Publication Date: 2023-09-19
    Description: Biogeochemical markers in combination with bacterial community composition were studied at two contrasting stations at the Río Negro (RN) estuary to assess the outwelling hypothesis in the Argentinian Patagonia. Inorganic nutrients and dissolved organic matter were exported clearly during the last hours of the ebb at the station Wetland. Moreover, a considerable outwelling of polyunsaturated fatty acids (PUFA), particulates and microalgae was inferred by this combined approach. The exported 22:6(n-3) and 20:5(n-3) contributed very likely to sustain higher trophic levels in the coasts of the Southwest Atlantic. The stable isotopes did not evidence clearly the outwelling; nevertheless, the combination of δ13C with fatty acid bacterial markers indicated organic matter degradation in the sediments. The dominance of Desulfobacterales and Desulfuromonadales suggested sulphate reduction in the sediments, a key mechanism for nutrient outwelling in salt marshes. Marivivens and other Rhodobacterales (Alphaproteobacteria) in the suspended particulate matter were clear indicators of the nutrient outwelling. The colonization of particles according to the island biogeography theory was a good hypothesis to explain the lower bacterial biodiversity at the wetland. The copiotrophic conditions of the RN estuary and particularly at the wetland were deduced also by the dynamic of some Actinobacteria, Bacteroidia and Gammaproteobacteria. This high-resolution snapshot combining isotopic, lipid and bacterial markers offers key pioneer insights into biogeochemical and ecological processes of the RN estuary.
    Repository Name: EPIC Alfred Wegener Institut
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  • 154
    Publication Date: 2023-12-05
    Description: Water and sediment supply are essential to the health of deltaic ecosystems. Diverse datasets were integrated to better understand how climate change is shifting the supply of water and sediment to the largest polar distributary channel pattern – the Lena River Delta. Here the increase in warming rate from an average air temperature is from 4.1 °C for the period 1950–99 to 6.1 °C during 2000–21, which is higher than in the adjacent polar regions. Streamflow and sediment yield entering the Lena Delta have increased since 1988 by 56.3 km3 and 6.1×106 t, respectively; meanwhile, the Lena River’s increases in water temperature in June, July–August and September were found to be as much as 1.1, 0.6 and 0.05 °C. These changes have a pronounced effect on sediment regimes in particular parts of the delta. Based on analyses of correlations between various hydroclimatic drivers and sediment concentration changes across particular distributaries of the Lena Delta extracted from Landsat datasets, bank degradation driven by thermal erosional processes (which are in turn related to air and soil temperature increases) is proved to be the primary factor of the sediment regime in the delta. The study also highlights that sediment load changes are sensitive to wind speed due to remobilization of bottom sediment. Sums of daily air temperature and wind speed over 3 days are correlated with sediment concentration changes in the delta. The results also indicate that carbon transport across the delta (both POC and DOC) depends on sediment transport conditions and water discharge and might increase by up to 10 %. We conclude that the Lena Delta can be recognized as the global hot spot in terms of the hydrological consequences of climate change, which is altering sediment regimes, stream hydromorphology and carbon transport.
    Repository Name: EPIC Alfred Wegener Institut
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  • 155
    facet.materialart.
    Unknown
    Elsevier
    In:  EPIC3Physics Reports, Elsevier, 1031, pp. 1-59, ISSN: 0370-1573
    Publication Date: 2023-12-05
    Description: It is a fundamental challenge to understand how the function of a network is related to its structural organization. Adaptive dynamical networks represent a broad class of systems that can change their connectivity over time depending on their dynamical state. The most important feature of such systems is that their function depends on their structure and vice versa. While the properties of static networks have been extensively investigated in the past, the study of adaptive networks is much more challenging. Moreover, adaptive dynamical networks are of tremendous importance for various application fields, in particular, for the models for neuronal synaptic plasticity, adaptive networks in chemical, epidemic, biological, transport, and social systems, to name a few. In this review, we provide a detailed description of adaptive dynamical networks, show their applications in various areas of research, highlight their dynamical features and describe the arising dynamical phenomena, and give an overview of the available mathematical methods developed for understanding adaptive dynamical networks.
    Repository Name: EPIC Alfred Wegener Institut
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  • 156
    Publication Date: 2023-10-30
    Description: Article + Kit and fortran 77 routines
    Description: Earthquakes fault plane solutions (FPSs) are routinely computed on the basis of various techniques and are reported in the literature with a wide range of formats and conventions. Although the equations relating the various parameters are well known and relatively simple, their practical application often arise to numerical singularities and indeterminations that sometimes are not well known by the authors and thus may result in wrongor inaccurate reportingof parameters. Such inaccuracies and mistakes affect about 40% of the published data we have examined to test our programs. Moreover the current use, in the seismological community, of at least two different coordinate systems to represent the Cartesian components of vectorial and tensorial quantities is a further cause of confusion. In order to simplify the management of such data, we have prepared a structured package of FORTRAN 77 subroutines performingalmost all of the possible computations and conversions amongdifferent parameters and coordinate systems. The package has been extensively tested with the data of a revised database of FPS of Italy and surrounding regions (presented in a companion paper) as well as of CMT solutions included in the Harvard catalog.
    Description: Published
    Description: 893–901
    Description: OST1 Alla ricerca dei Motori Geodinamici
    Description: JCR Journal
    Keywords: Focal Mechanisms ; FORTRAN 77 Routines ; Centroid moment tensor ; Nodal planes ; Deformation axes
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 157
    Publication Date: 2023-11-14
    Description: Continuous and multi-decadal records of faunal abundance and diversity helping to identify the impacts of ongoing global warming on aquatic ecosystems are rare in the coastal Arctic. Here, we used a 50-year-long microfaunal record from a sediment core collected in the Herschel Basin (YC18-HB-GC01; 18 m water depth) to document some aspects of the environmental responses of the southern Canadian coastal Beaufort Sea to climate change. The microfaunal indicators include benthic foraminiferal assemblages, ostracods and tintinnids. The carbonate shells of two foraminiferal species were also analyzed for their stable isotope signatures (δ13C and δ18O). We compiled environmental parameters from 1970 to 2019 for the coastal region, including sea ice data (break-up date, freeze-up date, open season length and mean summer concentration), the wind regime (mean speed, direction of strong winds and the number of storms), hydrological data (freshet date, freshet discharge and mean summer discharge of the Firth and the Mackenzie rivers), and air temperature. Large-scale atmospheric patterns were also taken into consideration. Time-constrained hierarchal clustering analysis of foraminiferal assemblages and environmental parameters revealed a near-synchronous shift around the late 1990s. The microfaunal shift corresponds to an increased abundance of taxa tolerant to variable salinity, turbulent bottom water conditions, and turbid waters towards the present. The same time interval is marked by stronger easterly winds, more frequent storms, reduced sea-ice cover, and a pervasive anticyclonic circulation in the Arctic Ocean (positive Arctic Ocean Oscillation; AOO+). Deeper vertical mixing in the water column in response to intensified winds was fostered by increased open surface waters in summer leading to turbulence, increased particle loading and less saline bottom waters at the study site. Stronger easterly winds probably also resulted in enhanced resuspension events and coastal erosion in addition to a westward spreading of the Mackenzie River plume, altogether contributing to high particulate-matter transport. Increase food availability since ∼2000 was probably linked to enhanced degradation of terrestrial organic carbon, which also implies higher oxygen consumption. The sensitivity of microfaunal communities to environmental variations allowed capturing consequences of climate change on a marine Arctic shelf ecosystem over the last 50 years.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 158
    Publication Date: 2023-10-25
    Description: Boron (B) and Lithium (Li) concentrations were studied in the Platani river, one of the most important catchments of South-Central Sicily which is under semiarid climatic conditions for roughly eight months to a year. In this area, evaporites result in potential B and Li sources for surface waters. Results from river waters have measured ionic strength values between 0.1 and 4.54 M. B and Li distributions in these waters were studied in colloidal (CF, extracted by ultrafiltration from the 0.45 μm filtrate) and total dissolved (TDF) fractions and in fractions extracted from corresponding riverbed sediments, according to changes of the B/Li ratio. In river waters, CF and TDF showed very similar B/Li values, suggesting that only negligible fractionation occurs between Li and B in the aqueous phase. Similar evidence was observed between B/Li values in TDF and the labile sediment fraction, whereas an inverse relationship arose between B/Li values in TDF and in the easily reducible sediment fraction. This relationship indicates that Mn oxy-hydroxides preferentially react with aqueous B species relative to Li at the riverbed sediment interface. The extent of the B-Mn oxy-hydroxide reactions is influenced by the ionic strength, so that only B/Li values below 4 are measured in river waters with ionic strength values above 0.5 M. Comparing B/Li and ionic strength values measured in the Platani river with those from oxic brines worldwide, the same preferential B removal relative to Li is observed. This evidence suggests that B is removed as positively-charged borate ion-pairs, formed in the aqueous phase under higher ionic strength conditions, reacting with negatively charged surfaces of Mn oxy-hydroxides. The observed B reactivity relative to Li could be exploited to bring down the B excess from natural or waste waters, allowing the natural reactions with Mn oxy-hydroxides to take place under natural conditions.
    Description: Published
    Description: 135509
    Description: 1T. Struttura della Terra
    Description: JCR Journal
    Keywords: B/Li ratio; Ionic strength; Mine drainage; Mn-oxyhydroxides; Salt minerals
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 159
    Publication Date: 2023-12-21
    Description: Cultural heritage (CH) is heavily threatened by air pollution, especially by airborne particulate matter (PM), that acts on the surfaces of fine arts, causing artistic loss. Therefore, the monitoring of air quality assumes a central role for the preventive conservation of CH. In this study, magnetic and chemical biomonitoring of PM was applied at the Peggy Guggenheim Collection, a contemporary and modern art museum in Venice, Italy. It is located in an aquatic context, where the PM sources are considerably different, with respect to the usual vehicular-dominated urban emissions. Lichen biomonitoring is a well-established technique for the assessment of air quality, especially where PM collecting devices cannot be operated for aesthetic and practical reasons. Samples of the lichen species Evernia prunastri were collected from a pristine area and exposed for three months (November 2022–February 2023) at increasing distances from the Grand Canal, planning an outdoor vs. indoor sampling design, for outlining the diffusion of airborne PM inside the museum. In combination with lichen exposure, the leaves of Pittosporum tobira hedges were sampled for determining their efficiency as bioaccumulators. The magnetic properties of lichens showed a moderate bioaccumulation of magnetite-like particles outdoors. Conversely, the magnetic properties of the indoor samples were like those of the unexposed ones, indicating a negligible accumulation of metallic particles indoors. Pittosporum tobira leaves mostly showed diamagnetic properties, resulting an ineffective species for preventing conservation purposes. Chemical analysis did not show any significant difference between unexposed, indoor and outdoor samples. A directional gradient of bioaccumulation was not evident, thus implying that the sources of metallic PM are distant or diffused, with respect to the site. The joint use of magnetic and chemical analyses was useful for evaluating the negligible impact of airborne particulate pollution arising from the Grand Canal towards the Halls of the Collection.
    Description: This research was funded by INGV Project “Pianeta Dinamico” (Ministry of University and Research), research line 2023-2025 “CHIOMA”, Cultural Heritage Investigations and Observations: a Multidisciplinary Approach. The Lakeshore 8604 VSM was funded by the Ministry of University and Research, project PON GRINT, code PIR01_00013.
    Description: Published
    Description: 100455
    Description: OSA1: Variazioni del campo magnetico terrestre, imaging crostale e sicurezza del territorio
    Description: N/A or not JCR
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 160
    Publication Date: 2023-11-24
    Description: Paleocene-Eocene sedimentary archives record a series of global warming events called hyperthermals. These events occurred across a long-term increasing temperature trend and were associated with light carbon injections that produced carbon isotope excursions (CIEs). Early Eocene hyperthermals occurred close to both long (∼405 kyr) and short (∼100 kyr) eccentricity maxima. It has been proposed that under long-term global warming, orbital forcing of climate crossed a thermodynamic threshold that destabilized carbon reservoirs and produced Early Eocene hyperthermals. However, orbital control on triggering of the largest hyperthermal, the Paleocene-Eocene Thermal Maximum (PETM), remains unclear. Identification of the precise orbital phasing of the PETM has been hindered by extensive calcium carbonate (CaCO3) dissolution, which introduces uncertainty into PETM age models. Here, we report orbital signatures in marine sediments from Contessa Road (Italy), a western Tethyan section with reduced PETM CaCO3dissolution compared to other deep ocean sites. Orbitally controlled lysocline depth adjustments and orbital phasing of the PETM CIE onset close to both long and short eccentricity maxima are documented here. Precession-based age models from the well-resolved PETM section of Ocean Drilling Program (ODP) Site 1262 (South Atlantic) confirm these results and reveal that the PETM CIE onset was partially triggered by an orbitally controlled mechanism. Climate processes associated with orbital forcing of both long and short eccentricity maxima played an important role in triggering the carbon cycle perturbations of all Paleocene-Eocene CIE events.
    Description: Published
    Description: 117839
    Description: OSA2: Evoluzione climatica: effetti e loro mitigazione
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 161
    Publication Date: 2023-12-21
    Description: Deformation across structural complexities such as along-strike fault bends may be accommodated by distributed faulting, with multiple fault splays working to transfer the deformation between two principal fault segments. In these contexts, an unsolved question is whether fault activity is equally distributed through time, with multiple fault splays recording the same earthquakes, or it is instead localized in time and space across the distributed faults, with earthquakes being clustered on specific fault splays. To answer this question, we studied the distributed deformation across a structural complexity of the Mt. Marine fault (Central Apennines, Italy), where multiple fault splays accommodate the deformation throughout the change in strike of the fault. Our multidisciplinary (remote sensing analysis, geomorphological-geological mapping, geophysical and paleoseismological surveys) study identified five principal synthetic and antithetic fault splays arranged over an across-strike distance of 500 m, all of which showing evidence of multiple surface-rupturing events during the Late Pleistocene-Holocene. The fault splays exhibit different and variable activity rates, suggesting that fault activity is localized on specific fault splays through space and time. Nonetheless, our results suggest that multiple fault splays can rupture simultaneously during large earthquakes. Our findings have strong implications on fault-based seismic hazard assessments, as they imply that data collected on one splay may not be representative of the behaviour of the entire fault. This can potentially bias seismic hazard calculations.
    Description: This work was realized under the agreement between the University of Chieti-Pescara (Dep. INGEO) and the National Institute of Geophysics and Vulcanology (INGV): “Ridefinizione delle Zone di Attenzione delle Faglie Attive e Capaci emerse dagli studi di microzonazione sismica effettuati nel territorio dei Centri abitati di Barete e Pizzoli in provincia de L'Aquila, interessati dagli eventi sismici verificatisi a far data dal 24 agosto 2016”, funded by the Commissioner structure for post-earthquake reconstruction of the Italian Government.
    Description: Published
    Description: 230075
    Description: OST2 Deformazione e Hazard sismico e da maremoto
    Description: JCR Journal
    Keywords: Structural geology ; Seismic Hazard ; Active faults ; Paleoseismology ; Distributed faulting ; 04.07. Tectonophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 162
    Publication Date: 2023-12-28
    Description: The Swarm satellite mission has been used for numerous studies of the ionosphere. Here we use a global product, based on electron density measurements from Swarm that characterises ionospheric variability. The IPIR (Ionospheric Plasma IRregularities product) provides characteristics of plasma irregularities in terms of their amplitudes, gradients and spatial scales and assigns them to geomagnetic regions. Ionospheric irregularities and fluctuations are often the cause of errors in position, navigation, and timing (PNT) based on the Global Navigation Satellite Systems (GNSS), in which signals pass through the ionosphere. The IPIR dataset also provides an indication, in the form of a numerical value index (IPIR index), of the severity of irregularities affecting the integrity of trans-ionospheric radio signals and hence, the accuracy of GNSS positioning. We analysed datasets from Swarm A and ground-based scintillation receivers. Time intervals (when Swarm A passes over the field of view of the ground-based GPS receiver) are compared to ground-based scintillation data, collecting an azimuthal selection of the GNSS data relevant to the Swarm satellite overpass. We provide validations of the IPIR product against the ground-based measurements from 23 ground-based receivers, focusing on GPS TEC and scintillation data in low-latitude, auroral and polar regions, and in different longitudinal sectors. We have determined the median, mean, maximum and standard deviation of the parameter values for both datasets and each conjunction point. We found a weak correlation of the intensity of both phase and amplitude scintillation with the IPIR index.
    Description: Published
    Description: 5399-5415
    Description: OSA3: Climatologia e meteorologia spaziale
    Description: JCR Journal
    Keywords: 01.02. Ionosphere
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 163
    Publication Date: 2023-12-04
    Description: A mineralogical, major, LA-ICP-MS trace element mineral chemistry and bulk-rock geochemical study of juvenile samples of the Mercato, Avellino, Pompeii and Pollena eruptions, collected in stratigraphically and volcano logically well-characterized sections of the Somma-Vesuvius stratovolcano (Roman Magmatic Province), along with reference data on the 1944 CE and the Pomici di Base eruptions, highlights the compositional variability of bulk-rock and glass from leucite phonotephrite to garnet-bearing phonolite. The latter products have extreme fractionation of trace elements (e.g., La/Ybn = 126, Zr/Y = 89, Zr/Hf =78, Nb/Ta = 40; Th/U = 2.3), very low Sc, V, Y, HREE and very high As, Tl, Cs, Pb, Th and U. The Pomici di Base products, older than the eruptions described above, range from leucite-bearing shoshonites to trachytes, are devoid of garnet and belong to an independent liquid-line-of-descent, having also different fractionation between trace elements (e.g., La/Ybn =15; Zr/Y = 12.4, Zr/Hf = 50, Nb/Ta = 15.6; Th/U = 3 in the Pomici di Base trachytes). A marked chemical variability of the observed phases is found. The geochemistry of garnet, amphibole, clinopyroxene and other phases shows wide variations of concentrations and elemental ratios (e.g., La/Ybn up to 520 in the sadanagaite coexisting with garnet). The magmatic evolution is dominated by low-pressure, oxidized, nearly closed-system fractional crystallization of clinopyroxene, plagioclase, leucite, ±magnetite, ±biotite, ±olivine and apatite in the transition tephrite-phonotephrite, and of potassic sanidine (±hyalophane), Fe-clinopyroxene, melanite garnet ±Fe-amphibole in the transition tephriphonolite-phonolite. Mineralogic and geochemical evidence and model ling points out the existence of independent, zoned magma batches throughout the activity of the stratovolcano, which possibly started to crystallize at similar depths. The Somma-Vesuvius magmas thus evolved in shallow independent reservoirs with respect to those of the neighbouring volcanic complexes (Campi Flegrei, Ischia) as shown, for instance, by the contrasting compositional trends of clinopyroxene and amphibole, and have very limited evidence of crustal contamination (and/or carbonate assimilation).
    Description: Published
    Description: 106854
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Somma-Vesuvius ; Phonolites ; Trachytes ; Phase geochemistry ; LA-ICP-MS analyses
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 164
    Publication Date: 2023-11-14
    Description: The AMUSED (A MUltidisciplinary Study of past global climatE changes from continental and marine archives in the MeDiterranean region) project aims at improving knowledge of late Quaternary climate variability and its expressions in different geological settings of the Mediterranean region. In this framework, the Castiglione maar, in the Colli Albani Volcanic District, central Italy, was selected for acquiring a high-resolution and geochronologically well-constrained multi-proxy record by drilling the entire lacustrine succession. Electrical Resistivity Tomography (ERT) profiles were acquired across the central portion and the SW crater edge to depict the geometry of the sedimentary infilling and select the best drilling site. Two parallel cores (C1 and C2), 116 m- and 126.5 m-depth respectively, were recovered from the central sector of the Castiglione basin, where, according to ERT profiles, the sedimentary succession reaches the maximum thickness. The sedimentary infilling consists of fine-grained sediments: mainly fine sand, silt and clay, with minor gravel intervals and numerous tephra layers and volcaniclastic lenses. Specifically, more than 60 tephras were identified and used, alongside other lithostratigraphic features, to correlate the C1 and C2 cores and to assemble a composite section. The variability in magnetic susceptibility, led by glacial-interglacial cycles, and the geochemical fingerprinting of key tephra layers allowed to establish a preliminary chronological framework for the Castiglione succession which certainly spans the last 365 ka, with a mean sedimentation rate of 0.33 mm/yr. The relatively long time span of the Castiglione maar succession arises as a new potentially meaningful node of the network of Mediterranean records for better reconstructing the late Quaternary climate dynamics on a regional and extra-regional scale.
    Description: Published
    Description: 1-14
    Description: OSA1: Variazioni del campo magnetico terrestre, imaging crostale e sicurezza del territorio
    Description: OSA2: Evoluzione climatica: effetti e loro mitigazione
    Description: JCR Journal
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  • 165
    Publication Date: 2023-12-21
    Description: We carried out a geophysical research project in the Middle Bronze Age village of Ustica (Palermo, Sicily, Italy), named “Faraglioni Village” after the stack formations which detach from the coast north of the archaeological site. The investigation, which comprised Electrical Resistivity Tomography (ERT) and Ground Penetrating Radar (GPR) techniques, allowed us to discover the buried foundations of an outwork fortification system never evi denced by previous archaeological studies, only hypothesised from the observation of aerial photography and partially outcropping boulders, which align roughly parallel to the main defensive wall of the Village. Our geophysical prospection involved the entire 250 m-long arc of the outward village defensive wall, with the acquisition of eleven ERT profiles and 27 GPR scans. The techniques were selected based on both favourable logistics and methods applicability: ERT sections allowed us to trace a series of high-resistivity anomalies ar ranged to form an arc-shaped structure along the perimeter of the defensive wall. GPR investigation was localised in the most accommodating patch of terrain of the site, with the effort of intercepting clear enough sections of the target, to determine more accurately its shape, depth, and overall dimensions. Our discovery paves the way for new investigations, mainly aimed at defining the timing of construction of the fortification system, as well as the function of the remains of other architectural structures identified close to the wall, which could represent the target of further geophysical investigations.
    Description: Published
    Description: 105272
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Keywords: Georadar ; Electrical resistivity tomography ; Middle Bronze Age ; Villaggio Dei Faraglioni ; Fortification system ; Ustica Island
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 166
    Publication Date: 2023-12-22
    Description: The Piacenzian – Gelasian transition is a time of profound changes in the Earth's climatic regime, epitomized by the definitive establishment of large ice caps in the Northern Hemisphere and the beginning of the “ice ages” at ca. 2.6 Ma. This event is sharply documented in δ18O records globally by a prominent triplet of severe glacial events (MIS 100, 98 and 96) that approximate the base of the Gelasian Stage. We have reconstructed a multi-species planktic and benthic foraminiferal δ18O and δ13C record from the Monte San Nicola section (Sicily) across the Piacenzian/Gelasian boundary, with the purpose of better constraining in time the main marker criteria for recognition of the Gelasian GSSP (Global Boundary Stratotype Section and Point) and investigating in detail the paleoclimatic and paleoceanographic response of the central Mediterranean to the definitive onset of the Northern Hemisphere Glaciation. Our results confirm the reliability and usability of the criteria originally proposed for defining the Gelasian GSSP, and significantly improve their chronology and chronostratigraphic positioning. Beyond an obvious alternation of obliquity-driven glacial-interglacial cycles, our isotopic record unraveled a pervasive climate variability in the suborbital time domain, the origin of which is still ambiguous. Altogether data presented in this paper provide the first high resolution isotopic records shedding new light both on the stratigraphic and paleoclimatic evolution of the Central Mediterranean area at the beginning of the Northern Hemisphere Glaciation.
    Description: Published
    Description: 108469
    Description: OSA1: Variazioni del campo magnetico terrestre, imaging crostale e sicurezza del territorio
    Description: OSA2: Evoluzione climatica: effetti e loro mitigazione
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 167
    Publication Date: 2023-12-27
    Description: While long-term interactions of magma with carbonate wall-rock (a.k.a. carbonate assimilation) are well-studied, only recently some experimental studies focused on short-term interactions (seconds to minutes) at magma chamber conditions (0.5 GPa and 1200 ◦C). They have shown that carbonate assimilation can effectively release CO2 and dissolve the ingested clast in syn-eruptive timescales. Carbonate wall-rock xenoliths in eruptive products can hence be seen as proof of even shallower ingestion (i.e., within the feeding dyke). To study these shallower interactions, we performed 66 experiments at atmospheric pressure (i.e., at the second endmember of the vol- canic feeding system) and at 950–1230 ◦C with varying melt compositions and limestone compositions. Decarbonation was found to be mainly dependent on temperature and limestone composition while clast dissolution is largely dependent on magma composition, temperature, pressure and interaction time. In natural systems during magma ascent and with increasing quantities of assimilated wall-rock, the magma temperature would steadily decrease, limiting its own decarbonation and assimilation ability. But even in the 950 ◦C-ex- periments decarbonation (i.e., CO2 release) remained a syn-eruptive process. We subsequently discussed the limits of carbonate assimilation as well as the potential effect of syn-eruptive addition of CO2 to the magmatic mixture on magma ascent and eruption dynamics.
    Description: Published
    Description: 121724
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Keywords: Carbonate assimilation ; Volcanic eruption ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 168
    Publication Date: 2023-12-27
    Description: Amplitude and phase scintillation indexes (S4 and SigmaPhi) provided by Ionospheric Scintillation Monitoring (ISM) receivers are the most used GNSS-based indicators of the signal fluctuations induced by the presence of ionospheric irregularities. These indexes are available only from ISM receivers which are not as abundant as other types of professional GNSS receivers, resulting in limited geographic distribution. This makes the scintillation indexes measurements rare and sparse compared to other types of ionospheric measurements available from GNSS receivers. Total Electron Content (TEC), on the other hand, is an ionospheric parameter available from a wide range of multi-frequency GNSS receivers. Many efforts have worked on establishing scintillation indicators based on TEC, and geodetic receivers in general, introducing various metrics, including the Rate of TEC change (ROT) and ROT Index (ROTI). However, a possible relationship between TEC and its variation, and the corresponding scintillation index that an Ionospheric Scintillation Monitor (ISM) receiver would estimate is not trivial. In principle, TEC can be retrieved from carrier phase measurements of the GNSS receiver, as . We investigate how to estimate SigmaPhi from time series of TEC and ROT measurements from an ISM in Ny-Ålesund (Svalbard) using Machine Learning (ML). To evaluate its usability to estimate SigmaPhi from geodetic receivers, the model is tested using TEC data provided by a quasi-co-located geodetic receiver belonging to the International GNSS Service (IGS) network. It is shown that the model performance when TEC from the IGS receiver is used gives comparable results to the model performance when TEC from the ISM receiver is utilised. The model's ability to infer the exact value of the scintillation index is bound to Mean Square Error (MSE) = 0.1 radians^2 when SigmaPhi 〈 0. 8 radians. For SigmaPhi 〉 0. 8 radians the MSE reaches 0.18 and 0.45 radians^2 in operative testing using ISM and IGS measurements, respectively. However, the model’s ability to detect phase scintillation from IGS TEC measurements is comparable to expert visual inspection. Such a model has potential in alerting against phase fluctuations resulting in enhanced SigmaPhi, especially in locations where ISM receivers are not available, but other types of dual-frequency GNSS receivers are present.
    Description: In press
    Description: OSA3: Climatologia e meteorologia spaziale
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 169
    Publication Date: 2023-12-27
    Description: The EU Center of Excellence for Exascale in Solid Earth (ChEESE) develops exascale transition capabilities in the domain of Solid Earth, an area of geophysics rich in computational challenges embracing different approaches to exascale (capability, capacity, and urgent computing). The first implementation phase of the project (ChEESE-1P; 2018–2022) addressed scientific and technical computational challenges in seismology, tsunami science, volcanology, and magnetohydrodynamics, in order to understand the phenomena, anticipate the impact of natural disasters, and contribute to risk management. The project initiated the optimisation of 10 community flagship codes for the upcoming exascale systems and implemented 12 Pilot Demonstrators that combine the flagship codes with dedicated workflows in order to address the underlying capability and capacity computational challenges. Pilot Demonstrators reaching more mature Technology Readiness Levels (TRLs) were further enabled in operational service environments on critical aspects of geohazards such as long-term and short-term probabilistic hazard assessment, urgent computing, and early warning and probabilistic forecasting. Partnership and service co-design with members of the project Industry and User Board (IUB) leveraged the uptake of results across multiple research institutions, academia, industry, and public governance bodies (e.g. civil protection agencies). This article summarises the implementation strategy and the results from ChEESE-1P, outlining also the underpinning concepts and the roadmap for the on-going second project implementation phase (ChEESE-2P; 2023–2026).
    Description: EU
    Description: Published
    Description: 47-61
    Description: OSV1: Verso la previsione dei fenomeni vulcanici pericolosi
    Description: JCR Journal
    Keywords: HPC ; Physical models ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 170
    Publication Date: 2024-01-02
    Description: The provision of probiotics benefits the health of a wide range of organisms, from humans to animals and plants. Probiotics can enhance stress resilience of endangered organisms, many of which are critically threatened by anthropogenic impacts. The use of so-called ‘probiotics for wildlife’ is a nascent application, and the field needs to reflect on standards for its development, testing, validation, risk assessment, and deployment. Here, we identify the main challenges of this emerging intervention and provide a roadmap to validate the effectiveness of wildlife probiotics. We cover the essential use of inert negative controls in trials and the investigation of the probiotic mechanisms of action. We also suggest alternative microbial therapies that could be tested in parallel with the probiotic application. Our recommendations align approaches used for humans, aquaculture, and plants to the emerging concept and use of probiotics for wildlife.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , peerRev
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  • 171
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    Elsevier
    In:  Spiess, R., Langone, A., Caggianelli, A., Stuart, F.M., Zucchi, M., Bianco, C., et al., 2021. Unveiling ductile deformation during fast exhumation of a granitic pluton in a transfer zone. J. Struct. Geol. 147, 104326.
    Publication Date: 2023-02-27
    Description: In their paper, Spiess et al. (2021) published structural, geochronological, and EBSD data on one of the monzogranite apophyses (Capo Bianco) of the buried Porto Azzurro Pluton (island of Elba, Northern Apennines, Italy), a pluton emplaced in the upper crust (P 〈 0.2 GPa; e.g. Papeschi et al., 2019). The authors published a new U/Pb age of 6.4 ± 0.4 Ma, associated with the thermal peak, and a U-Th/He apatite age of 5.0 ± 0.6 Ma, indicating cooling below 60 ◦C. Spiess et al. (2021) use these ages to model the exhumation of the pluton controlled, in their model, by the Zuccale Fault, a subhorizontal fault with 6 km of eastward displacement (ZF; Keller & Coward, 1996). Their structural dataset from the macro to the microscale and EBSD analyses relies on a small section (about 100 m wide) in the NE part of the Calamita Peninsula. Based on their documentation of (1) vertical dykes in the monzogranite, (2) vertical to low-angle top-to-the-E extensional faults, and (3) later NWstriking oblique faults, they interpret the Porto Azzurro Pluton as emplaced in an extensional to transcurrent tectonic setting, extrapolating their findings to the entire Eastern Elba.
    Description: Published
    Description: 104499
    Description: 1T. Struttura della Terra
    Description: JCR Journal
    Keywords: Upper crustal deformation ; Magmatic intrusion ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 172
    Publication Date: 2023-02-27
    Description: Crystal zoning plays a fundamental role in modern volcanology as a key to unravel the geometry and the dynamics of plumbing systems. In this study, a detailed textural and compositional study of clinopyroxene crystals entrained in intrusive, hypabyssal and effusive products from Cima Pape (Dolomites) is coupled with thermobarometric-hygrometricmodels to reconstruct the geometry and evolution of the feeding systembeneath Middle Triassic volcanic edifices. Whole-rock major, trace element distribution and Sr-Nd isotopic signature (87Sr/86Sri = 0.7045–0.7050; 143Nd/144Ndi = 0.51223–0.51228) show that the rocks from Cima Pape are SiO2- saturated and have shoshonitic affinity, and likely belong to the acme of the Mid-Triassic magmatismthat shaped the Southern Alps between 239 and 237.6Ma. Highly porphyritic trachybasaltic to basaltic trachyandesitic volcanic rocks contain a large number of concentric-zoned clinopyroxene crystals. Here, high-Mg# and -Cr2O3, REEdepleted bands (Mg# 80–91; Cr2O3 up to 1.2 wt%) with variable thickness grew between relatively low-Mg# and -Cr2O3 (Mg# 70–77; Cr2O3 〈 0.1 wt%) augitic cores and rims. In contrast, the gabbroic to monzodioritic 50- to 300-m-thick sill cropping out belowthe volcanic sequences, though to represent a relic of the shallowest portion of the plumbing system, is mostly made up of unzoned clinopyroxene crystals. Thermobarometric and hygrometric models allowed us to define that a small “mush-type” batchwas located beneath the Cima Pape volcano at depths between 7 and 14 km. Here, augitic clinopyroxene formed in equilibrium with a slightly evolved (basaltic trachyandesitic), H2O-rich melt (Mg# = 43–45; T = 1035–1075 °C; H2O = 2.6–3.8 wt%). Periodic replenishments of the magma batch by primitive (Mg# = 65–70), hotter and relatively H2O-poor (T = 1130–1150 °C; H2O = 2.1–2.8 wt%) basaltic magmas led to the formation of diopsidic bands mantling the already formed augitic cores. Later on, re-equilibration of clinopyroxene with the mixed melt resulted in the formation of low-Mg#, LILE- and LREE-enriched rims. The most Mg-poor micro-phenocrystic clinopyroxene in the volcanic rocks and in the sill records the ultimate and shallowest conditions of crystallization, occurring at T of 975–1010 °C and P comprised between 50 and 150 MPa. Based on the presence of similar zoning in clinopyroxene phenocrysts, a comparison between the Mid-Triassic Cima Pape and active volcanoes was put forward to highlight the potential of studying ancient, entirely exposed volcanic systems for interpreting the feeding systemprocesses acting beneath active volcanoes. At a regional scale, this approach represents a new, powerful tool for investigating the evolution of the Mid-Triassic magmatism in the Southern Alps and shedding light on the interactions between mantle-derived melts and differentiated batches ponding in the crust.
    Description: Published
    Description: 107459
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 173
    Publication Date: 2023-02-28
    Description: A new decomposition method for nonstationary signals, named Adaptive Local Iterative Filtering (ALIF), has been recently proposed in the literature. Given its similarity with the Empirical Mode Decomposition (EMD) and its more rigorous mathematical structure, which makes feasible to study its convergence compared to EMD, ALIF has really good potentiality to become a reference method in the analysis of signals containing strong nonstationary components, like chirps, multipaths and whistles, in many applications, like Physics, Engineering, Medicine and Finance, to name a few. In [11], the authors analyzed the spectral properties of the matrices produced by the ALIF method, in order to study its stability. Various results are achieved in that work through the use of Generalized Locally Toeplitz (GLT) sequences theory, a powerful tool originally designed to extract information on the asymptotic behavior of the spectra for PDE discretization matrices. In this manuscript we focus on answering some of the open questions contained in [11], and in doing so, we also develop new theory and results for the GLT sequences.
    Description: Published
    Description: 127-152
    Description: 2A. Fisica dell'alta atmosfera
    Description: JCR Journal
    Keywords: Mathematics - Numerical Analysis; Mathematics - Numerical Analysis; Computer Science - Numerical Analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 174
    Publication Date: 2023-02-28
    Description: This study aims to explore the reliability of flood warning forecasts based on deep learning models, in particular Long-Short Term Memory (LSTM) architecture. We also wish to verify the applicability of flood event predictions for a river with flood events lasting only a few hours, with the aid of hydrometric control stations. This methodology allows for the creation of a system able to identify flood events with acceptable errors within several hours' notice. In terms of errors, the results obtained in this study can be compared to those obtained by using physics-based models for the same study area. These kinds of models use few types of data, unlike physical models that require the estimation of several parameters. However, the deep learning models are data-driven and for this reason they can influence the results obtained. Therefore, we tested the stability of the models by simulating the missing or wrong input data of the model, and this allowed us to achieve excellent results. Indeed, the models were stable even if several data were missing. This method makes it possible to lay the foundations for the future application of these techniques when there is an absence of geological-hydrogeological information preventing physical modeling of the run-off process or in cases of relatively small basins, where the complex system and the unsatisfactory modeling of the phenomenon do not allow a correct application of physical-based models. The forecast of flood events is fundamental for correct and adequate territory management, in particular when significant climatic changes occur. The study area is that of the Arno River (in Tuscany, Italy), which crosses some of the most important cities of central Italy, in terms of population, cultural heritage, and socio-economic activities.
    Description: Published
    Description: 151885
    Description: 3IT. Calcolo scientifico
    Description: JCR Journal
    Keywords: Arno River; Deep learning; Fast catchment basin; Flood forecasting; Hydraulic models; LSTM
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 175
    Publication Date: 2023-02-28
    Description: Current global warming causes a change in atmospheric dynamics, with consequent variations in the rainfall regimes. Understanding the relationship between global climate patterns, global warming, and rainfall regimes is crucial for the creation of future scenarios and for the relative modification of water management. The aim of this study is to improve knowledge of the relationship between North Atlantic Oscillation (NAO), East Atlantic (EA), and Western Mediterranean Oscillation (WeMO) with the seasonal rainfalls in Tuscany, Italy. The study area occupies a strategic position since it lies in a transition zone between the wet area of northern Europe and the dry area of the northern coast of Africa. This research, based on a statistical correlation method and on linear models, is designed to understand the relationship between seasonal rainfalls and climate patterns. The results of this study demonstrate that the use of linear models can yield more information than traditional statistical corre- lations. The results show a decrease in rainfall in the warm period of the year, namely in the summer, when its expression is most visible. This phenomenon is ascribable to current global warming, which causes an increase in sea-surface temperatures. An increase in the Northern Atlantic Sea Surface Temperature and in the Mediterra- nean Sea Surface Temperature causes a reduction of the Iceland Low, with an extension of the Azores High. Moreover, an increase in the Genoa Gulf SST
    Description: Published
    Description: 128233
    Description: 4A. Oceanografia e clima
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 176
    Publication Date: 2023-02-28
    Description: New composite materials are always subjected to non-destructive evaluation (NDE) prior to being placed on the market. This is to fully understand the reactions (i.e., development of defects) at the interface between two subsequent layers. Active infrared thermography (aIRT) can help in this regard, especially if anticipated by a simulation of the heat transfer from the exterior (lamp) to the interior (multilayer). Comsol Multiphysics® was used in this work as a tool by developing an innovative approach, which is designed – on the one hand – to minimize the computational cost and – on the other hand – to optimize the radiation to be delivered. The innovation produced by our work also concerns the pre-processing step of the thermal images; in fact, the 2D Fast Iterative Filtering (FIF2) is here introduced, discussing its benefits in comparison to previously developed techniques. Pre-processed data were further analyzed during the post-processing step demonstrating the reliability of FIF2 in enhancing thermal imprints, which leads to an improved detection of subsurface features. In particular, enhanced thermal imprints highlight the shape of the grid of glass fibres present beneath an external coating of hemp fibres (and, in general, added to the whole specimen along the x-y vectors). This grid of glass fibres was recently introduced as an insulation material for buildings. A brief review of the use of the pre-processing step in aIRT allows the reader to better understand the decisive step forward provided by FIF2 combined with a clever numerical simulation in the applied thermal engineering field. Qualitative and quantitative IRT results are shown and discussed thoroughly. Finally, a validation among numerical and experimental (thermographic) data is provided thanks to the Parker (laser flash) method.
    Description: Published
    Description: 107553
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 177
    Publication Date: 2023-02-28
    Description: Retrieving object phase from the optical fringe pattern is a critical task in quantitative phase imaging and often requires appropriate image preprocessing (background and noise minimization), especially when retrieving phase from the single-shot fringe pattern image. In this article, for the first time, we propose to adapt the 2D Fast Iterative Filtering (FIF) method for fringe pattern decomposition and develop a novel version of FIF called the 2D fringe pattern Fast Iterative Filtering (fpFIF2), that is tailored for fringe pattern preprocessing. We show the positive influence of fpFIF2 onto fringe pattern filtering comparing to the previous 2D FIF implementation regarding processing speed, quality, and usage comfortability. We also compare the fpFIF2 with other state-of-the-art fringe pattern filtering methods in terms of aiding the Hilbert spiral transform method in phase retrieval. Employing numerical simulations and experimental fringe analysis, we prove that fpFIF2 outperforms reference methods, especially in terms of low-fringe-contrast phase reconstruction quality and decomposition time.
    Description: Published
    Description: 107069
    Description: 2A. Fisica dell'alta atmosfera
    Description: JCR Journal
    Keywords: Physics - Optics; Physics - Optics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 178
    Publication Date: 2023-02-21
    Description: Intra-oceanic arcs are typically associated with intermediate (andesitic) cone volcanoes. However, caldera volcanoes may also form in these settings from very large eruptions, resulting in sudden changes to the magma reservoir. These reservoirs can then produce either semi-continuous or intermittent low-intensity volcanism between major caldera-producing or caldera-deepening eruptions, providing insights into the post-caldera evolution of the system. Hunga volcano (Kingdom of Tonga, Southwest Pacific) is a large mainly submarine edifice that produced a series of caldera-forming eruptions ~900 years ago. Since then, numerous smaller-scale subaerial and submarine eruptions occurred, the most recent forming new islands in 2009 and 2014/15. Pyroclastic deposits associated with these latest eruptions have identical (range ~ 0.1 wt% of all major oxides) andesitic composition that overlap with the primitive end of the slightly wider compositional range of the caldera-forming episodes. Texturally simple plagioclase, clinopyroxene and orthopyroxene phenocrysts in pre-, syn- and post-caldera pyroclasts point to a single shallow storage reservoir at 5–8 km depth. Lack of complex zonation indicates that this reservoir is constantly resupplied by low-flux inputs of basaltic andesite magma and is large enough that convective mixing rapidly homogenises new inputs. The reservoir feeds intermittent, low-intensity, post-caldera volcanism with constant andesite composition, driven possibly by magmatic overpressure and “leakage” of gas-rich magma pockets around the edges of the caldera. More primitive and compositionally variable basaltic andesites formed a lava-dominated edifice prior to the caldera-forming event. This suggests a causal link between magma supply dynamics and caldera priming relating to the maturing of the plumbing system and formation of a sustained subvolcanic andesite magma reservoir.
    Description: This research was funded by the Faculty Research Development Fund, The University of Auckland to MB and SJC. We are grateful for financial and logistic support from ICON Films, Bristol, UK. We are especially grateful for the help and company of Lucy Meadows and Alex Holden, ICON Films, UK, during the field studies.
    Description: Published
    Description: 106614
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Andesite caldera, mafic ignimbrite ; Lava Explosive volcanism ; Hunga Tonga Arc volcanism ; South Pacific volcanism ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 179
    Publication Date: 2023-02-21
    Description: Many vertical seismic velocity anomalies observed below different parts of the Eurasian plate are rooted in the transition zone between the upper and lower mantle (410–660 km), forming so-called secondary plumes. These anomalies are interpreted as the result of thermal effects of large-scale thermal upwelling (primary plume) in the lower mantle or deep dehydration of fluid-rich subducting oceanic plates. We present the results of thermo-mechanical numerical modelling to investigate the dynamics of such small-scale thermal and chemical (hydrous) anomalies rising from the lower part of the Earth’s upper mantle. Our objective is to determine the conditions that allow thermo-chemical secondary plumes of moderate size (initial radius of 50 km) to penetrate the continental lithosphere, as often detected in seismo-tomographic studies. To this end, we examine the effect of the following parameters: (1) the compositional deficit of the plume density due to the presence of water and hydrous silicate melts, (2) the width of the weak zone in the overlying lithosphere formed because of plume-induced magmatic weakening and/or previous tectonic events, and (3) a tectonic regime varied from neutral to extensional. In our models, secondary plumes of purely thermal origin do not penetrate the overlying plate, but flatten at its base, forming “mushroom”-shaped structures at the level of the lithosphere-asthenosphere boundary. On the contrary, plumes with enhanced density contrast due to a chemical (hydrous) component are shown to be able to pass upwards through the lithospheric mantle to shallow depths near the Moho when (1) the compositional density contrast is ≥ 100 kg m−3 and (2) the width of the lithospheric weakness zone above the plume is ≥ 100 km. An extensional tectonic regime facilitates plume penetration into the lithosphere but is not mandatory. Our findings can explain observations that have long remained enigmatic, such as the “arrow”-shaped zone of low seismic velocities below the Tengchong volcano in south-western China and the columnar (“finger”-shaped) anomaly within the lithospheric mantle discovered more than two decades ago beneath the Eifel volcanic fields in north-western Germany. It appears that a chemical component is a characteristic feature not only of conventional hydrous plumes located over presently downgoing oceanic slabs, but also of upper mantle plumes in other tectonic settings.
    Description: Published
    Description: 117819
    Description: 1T. Struttura della Terra
    Description: JCR Journal
    Keywords: plume-lithosphere interaction ; secondary plumes ; hydrous plumes ; lithosphere rheology ; mantle transition zone ; numerical modelling
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 180
    Publication Date: 2023-02-21
    Description: Continental ultramafic rock systems, through the process of serpentinization, provide chemical and biochemical pathways that lead to the production of methane. The extent to which rock-water-gas reactions and organisms supply methane in these systems is a matter of considerable discussion and debate. Deciphering the interplay of abiotic and microbial methane observed at the surface requires several lines of reasoning as well as a variety of analyses. Despite using multiple models and interpretative tools, conclusions for the origin of methane at a particular site may vary or diverge from regional or global observations. Here, we critically address how possible conclusions of microbial versus abiotic methane in continental serpentinization systems may be interpreted and reinterpreted. We review fundamental concepts, advantages and limits, for three major methane origin models: (a) abiotic CO2 hydrogenation supplying gas reservoirs, (b) derivation from fluid inclusions in olivine-rich rocks, and (c) microbialgenesis in aquifers. We use the case of methane in the Samail ophiolite of Oman as an emblematic example of multiple interpretations; we identify ambiguous information offered by methane clumped isotopes and molecular gas compositions (e.g., the meaning of gaseous hydrocarbons heavier than methane), and suggest key tools, such as radiocarbon (14C) in methane, which may solve interpretative issues. The major constraint in any model of methane origin is the capability to sustain continuous gas flows, in terms of methane emission intensity, longevity and spatial extension, such as in natural gas sedimentary systems. Overall, this review suggests that any site interpretation can benefit from a holistic approach, integrating geochemical, geological and biological data with gas flow dynamics, as well as including regional and global contextualization.
    Description: Published
    Description: 105373
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 181
    Publication Date: 2023-02-21
    Description: Sector-zoned clinopyroxene records kinetic effects imposed by variable degrees of magma undercooling, ΔT, and can be utilised to track the dynamics of magmatic systems. The partitioning of trace elements into sectors grown in different crystallographic orientations can be used as a proxy for ΔT. However, an experimental assessment of the relationship between trace element zoning and ΔT has been lacking to date. Here we present trace element data from a series of undercooling crystallisation experiments on a primitive trachybasalt from Mt. Etna (Italy), at conditions of crustal storage (400 MPa, NNO + 2), and ΔT ranging from 23 to 173 °C. Changes in ΔT were modulated by varying both resting and liquidus temperatures, the latter via the melt-H2O content of the experiments. The resting temperature was retained for 24 h to ensure the attainment of near-equilibrium conditions. High-resolution elemental mapping reveals the distribution of trace elements in individual clinopyroxene zones. Increasing ΔT drives a shift from polyhedral morphologies with Al-rich prism and Al-poor hourglass sectors (ΔT = 23–25 °C), to skeletal (ΔT = 75–123 °C) and dendritic (ΔT = 132–173 °C) crystals with Al-rich skeletons and Al-poor overgrowths. Aluminium-rich zones have higher concentrations of rare earth elements (REE) and high field strength elements (HFSE) than Al-poor zones across all investigated ΔT conditions, and overall, Al, REE and HFSE contents increase with ΔT. This indicates that tetrahedral aluminium (TAl) and associated charge-balancing mechanisms govern the incorporation of REE and HFSE within clinopyroxene. Lattice strain parameters for REE in the M2 site indicate the incorporation of light relative to heavy REE in clinopyroxene is controlled by competing effects between the strain-free partition coefficient, D0, and the optimum cation radius, r0. Critically, the middle and heavy REE switch from incompatible to compatible with increasing ΔT. Used to model fractional crystallisation, our data demonstrate that fractionation of clinopyroxene at low ΔT controls pre-eruptive melt evolution. Importantly, this indicates crystallisation of clinopyroxene in the deep portions of Mt. Etna’s plumbing system is not rapid and is unlikely to result in the early formation of dendrites. We develop a parameterisation of ΔT based on REE partitioning between experimental clinopyroxene and coexisting melt, which can be applied to sector-zoned augite crystallising from mafic alkaline magmas, to reconstruct dynamic processes and thermal pathways during magma transport and storage. Applied to sector-zoned clinopyroxene microphenocrysts and groundmass microcrysts from the 1974 eccentric eruption at Mt. Etna, our parameterisation tracks an increase in ΔT with magma ascent and eruption, following recharge of Cr-rich mafic magma at depth. Sector-zoned clinopyroxene can track ΔT variations leading to volcanism at Mt. Etna and could be applied to quantify magma dynamics in other active volcanoes.
    Description: This work was supported by a Foundation Research Excellence Award from The University of Queensland (UQ-FREA RM2019001828, T.U.), the Advance Queensland Women’s Research Assistance Program from the Queensland Government (WRAP109-2019RD1 RM2020002371, T.U.) and the HP-HT laboratory of Experimental Geophysics and Volcanology (INGV, Rome). A.M. was supported by the Australian Government Research Training Program (RTP). S.M, M.M. and A.P. were supported by the MIUR project “Time scales of solidification in magmas: Applications to Volcanic Eruptions, Silicate Melts, Glasses, Glass- Ceramics” (PRIN 2017J277S9).
    Description: Published
    Description: 249-268
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Clinopyroxene ; Sector Zoning ; Trace element partitioning ; Undercooling ; Dendritic crystals ; Rare earth elements ; LA ICP-MS Mapping ; Mt. Etna ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 182
    Publication Date: 2023-02-21
    Description: We compute a high-resolution topographic model of the Moho beneath the fault system activated during the 2016–2017 Central Italy seismic sequence, using Receiver Function (RF) analyses. We document that Ps conversions recorded in RF data-set varies abruptly at very short distance across the crustal lineament called Ancona-Anzio Line (AAL). Moho depth varies from about 25-30 km in the Tyrrhenian domain on the West to 35- 40 km in the Adriatic domain in the East. Where the two domains are juxtaposed along the AAL, Moho depth values cluster around 50 km depth, in a stripe-like area 20 km wide. Such unique feature marks the deformation zone in the lithosphere and testifies the abrupt change in delamination style in the two sectors of the Apennines. Intermittent large normal faulting earthquakes driven by across-belt extension break through such inherited strong structural changes, conditioned by localized barriers to fluids migration and overpressuring.
    Description: Published
    Description: 229237
    Description: 1T. Struttura della Terra
    Description: 4T. Sismicità dell'Italia
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 183
    Publication Date: 2023-02-23
    Description: Trace metals and Rare Earth Element (REE) are amply discharged by submarine hydrothermal vents, sometimes leading to the formation of ore deposits of economic interest. We report on first data on the geochemical processes involving REE and trace metals, at the solid-liquid interface, in the hydrothermal area of Levante Bay at Vulcano Island (Aeolian Archipelago, Italy). Samples were collected from several submarine springs and seeps, a mud pool and one thermal well, and analyzed for Al, Si, Ti, V, Cr, Mn, Fe, Co, As, Rb, Sr, Cs, Ba, U and REE, besides major ions. Within the bay, hydrothermal fluids contaminate seawater and promote the leaching of metals from sediments through the dissolution of CO2 and H2S, while the particulate matter removes several elements from the water. The leaching of the bottom sediments and the contribution of steam-heated water produce an enrichment of some metals and REE in the Levante Bay with respect to the concentrations expected in the ambient seawater. An enrichment up to one order of magnitude is measured for Fe, Al, Ba, Cs and Rb, and up to two orders of magnitude for Mn in the submarine samples. Other transition metals (Ti, V, Co, Cr), U, As and Sr have concentrations similar or slightly lower than the ambient seawater. REE are in concentrations higher than in ambient seawater up to two orders of magnitude. Despite being significantly higher than uncontaminated seawater, the concentrations of some metals (namely Fe, Al, Ti, Cr, V, Co, U) and REE in most samples are lower than expected by the mixing between seawater and the steam-heated water, discharging from submarine springs. Indeed, equilibrium and reaction path modeling indicate the likely precipitation of Fe-oxyhydroxides, able to remove minor elements, such as Ti, Cr, Co, V and As, and REE. The last ones are significantly removed by newly-forming solid phases, due to the presence of a large amount of Fe released by the acidic fluids through the leaching of sediments. The low pH limits the formation of solution complexes of REE with carbonate ions (the main complexing agent for REE in seawater), whereas the sorption onto particles is still effective, even at close distance from the submarine springs and seeps. This study brings new insights on the geochemical processes occurring in submarine hydrothermal systems, in particular, those in subduction-related context.
    Description: Fondo Sociale Europeo (PO FSE 2014-2020)
    Description: Published
    Description: 120756
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: REE ; Trace metals ; Hydrothermal system ; Seawater ; 03.02. Hydrology ; 03.04. Chemical and biological ; 04.08. Volcanology
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  • 184
    Publication Date: 2023-02-23
    Description: Hydrogeological resources in the semiarid regions of Mexico support the economy and essential domestic activities of around 17 million people. However, adverse climatic conditions and overexploitation of aquifers affect the quantity and quality of the resource, added to problems of anthropogenic pollution and the salinity of water bodies. The Region Carbonífera aquifer represents the primary hydrogeological system in the most important coal-mining region in Mexico, located in the state of Coahuila. In this work, we present a complete dataset of 157 samples from surface and groundwaters sites have been used to characterizethe physicochemical and isotopic processes responsible for the composition of circulating waters, clarifying their origin, and to evaluate the water quality in terms of human consumption and irrigation use. The aquifer is mostly represented by Ca2+-Mg2+-SO42- and Ca2+-Mg2+-Cl- type waters, that supports salinization problems in 76% of the samples as well as sulfate excess. The origin of this chemical behavior seems to be the result of three main processes: 1) dissolution of soluble salts (gypsum, anhydrite and halite), 2) high surface evaporation under semiarid climate conditions, and 3) ionic and reverse ionic exchange. Processes 1 and 2 are also supported by the enrichment trends in the δ18O and δD signatures. For human consumption, 21% of the samples show high concentrations above the maximum permissible limits of the Official Mexican Standard (NOM-127-SSA1-1994) in total dissolved solids, Cl−, Na+, and SO42−. Additionally, 80% of the waters have some irrigation limitations due to excess sodicity or salinity. The worst quality waters for human or irrigation uses are located south of the aquifer in the municipalities of Juárez and Progreso. This study exhibits the complex hydric situation of the aquifer, raising awareness of the need to seek alternative sources, rational exploitation of resources, the use of crops that better adapt to these semiarid conditions, and intensifying hydrochemical monitoring in the region.
    Description: Published
    Description: 105307
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 185
    Publication Date: 2023-03-15
    Description: The Environmental Seismic Intensity scale (ESI-07), published 15 years ago under the umbrella of INQUA (In- ternational Union for Quaternary Research), is solely based on earthquake effects on the natural environment. ESI-07 provides complementary information with respect to other macroseismic scales, in particular those stemming from the original Mercalli scale, which are mainly based on effects on manmade structures. We collect information on 157 earthquakes, occurred between 300 AD and 2020, that have been studied using the ESI-07 scale. The ESI-07 epicentral intensity can be assigned based on linear or areal features (e.g., length of surface rupture, area affected by environmental effects); this value is generally in good agreement, or slightly larger, than estimates provided using other macroseismic scales. Higher discrepancies are found for earthquakes with ESI-07 epicentral intensity above X, where other scales tend to saturate, as expected based on the original definition of the Mercalli-family intensity scales. We develop scaling relations among ESI-07 epicentral intensity and moment magnitude, surface rupture length and affected area. After critically evaluating the scientific literature, we argue that the ESI-07 reached its original goals and proved to be particularly useful for the documentation of earthquake damage i) in remote regions, ii) in the case of strong events, where other scales saturate, and iii) in the region closer to the epicenter. Finally, we identify gaps where to focus future efforts, such as the integration of remote sensed datasets in ESI-07 assignment and the refinement of empirical regressions.
    Description: Published
    Description: 107-119
    Description: 6T. Studi di pericolosità sismica e da maremoto
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 186
    Publication Date: 2023-03-15
    Description: Volcanoes are currently to be regarded as natural sources of air pollutants. Climatic and environmental forcing of large volcanic eruptions are well known, although gases emitted through passive degassing during periods of quiescence or hydrothermal activity can also be highly dangerous for the environment and public health. Based on compositional and isotopic data, a survey on the spatial distribution in air of the main volatile compounds of carbon (CO2 and CH4) and sulfur (H2S and SO2) emitted from the fumarolic field of Pisciarelli (Campi Flegrei, Pozzuoli, Naples), a hydrothermal area where degassing activity has visibly increased since 2009, was carried out. The main goals of this study were (i) to evaluate the impact on air quality of these natural manifestations and (ii) inquire into the behavior of the selected chemical species once released in air, and their possible use as tracers to distinguish natural and anthropogenic sources. Keeling plot analysis of CO2 and CH4 isotopes revealed that the hydrothermal area acts as a net source of CO2 in air, whilst CH4 originated mainly from anthropogenic sources. Approaching the urban area, anthropogenic sources of CO2 increased and, at distances greater than 800 m from the Pisciarelli field, they prevailed over the hydrothermal signal. While hydrothermal CO2 simply mixed with that in the atmospheric background, H2S was possibly affected by oxidation processes. Therefore, SO2 measured in the air near the hydrothermal emissions had a secondary origin, i.e. generated by oxidation of hydrothermal H2S. Anthropogenic SO2 was recognized only in the furthest measurement site from Pisciarelli. Finally, in the proximity of a geothermal well, whose drilling was in progress during our field campaign, the H2S concentrations have reached values up to 3 orders of magnitude higher than the urban background, claiming the attention of the local authorities.
    Description: Published
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Air quality; Carbon and sulfur volatile compounds; Carbon isotopes; Hydrothermal systems; Natural sources of pollutants. ; 04.08. Volcanology ; 01.01. Atmosphere
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 187
    Publication Date: 2023-03-15
    Description: The exploitation of a geothermal field can be accompanied by both natural and induced seismicity. Hence the installation of a seismic network suitable for locating also low magnitude earthquakes is of great interest for geothermal development, especially for monitoring the activity related to the injection or production. Here we propose an improvement of the D-OPTIMAL algorithm (Tramelli et al., 2013) that tries and find optimal station positions minimizing the volume of the error ellipsoid of the event location using the D-criterion. In this version, we introduced the possibility to account for several prior information that is generally available when instrumenting a monitoring site permanently or temporarily. The a priori parameters introduced are: i) three-dimensional seismic velocity models, ii) seismic noise levels, iii) topographic gradient, and iv) H/V ratio values. The last three parameters are introduced in the station position 24 selection using aweighting system. We applied the methodology to the Acoculco geothermal field (Mexico) where an injection test was planned and executed in 2021. The comparison between the network defined usingthe standard approach and this updated version shows the importance of introducing a prioriinformation during the selection of the network. Installation sites resulted better distributed on the region, resulting in an overall increase of the sensitivity, and in a decreasing of the error location estimation in the target region. The methodology presented here is easy to apply to other study cases such as active volcanoes, anthropogenic activities, or whatever other study at local scale.
    Description: Published
    Description: 103995
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: Network optimization ; Geothermal areas ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 188
    Publication Date: 2023-03-15
    Description: This study analyses the geological reasons that supported the relocation of the Cavallerizzo village (Calabria, southern Italy) to a new area after the landslide event in 2005 to examine whether the institutional ordinance of displacing the entire village was the right choice. This study is based on new geological and geomorphological field investigations, on a new reading of the existing borehole data and new data collected by multi-temporal synthetic aperture radar interferometry. The results obtained reveal that only the areas bordering the Cavallerizzo village are affected by active landslides, whereas, in the historical centre, geomorphological evidence for an active landslide capable of involving the entire settlement is not found. Nowadays, 17 years after the 2005 landslide event, more than 85% of the Cavallerizzo village is completely intact, lacking evidence of instability or important damage to ancient buildings. Furthermore, in the historical urban area, very low ground displacements by InSAR investigation are observed, highlighting that the instability conditions of Cavallerizzo are less severe than those recognised in nearby villages. This evidence along with the strong negative economic and socio-cultural impacts that the village settlement had on the community involved led to the reconsideration of the adequacy of the relocation ordinance issued by the National Civil Protection. These findings can contribute to useful advice and best practices to state-run organisations and stakeholders for disaster management planning in urban sites, such as Cavallerizzo, subject to hydrogeological hazards.
    Description: This work was supported by the MIUR. Italy-ex 60% Project (Responsibility of Fabio Ietto). Copernicus Sentinel-1 IW SAR data were provided via and processed in ESA’s Geohazards Exploitation Platform (GEP), in the framework of the GEP Early Adopters Programme 2015–2020 and the Geohazards Lab initiative, the latter developed under the CEOS Working Group on Disasters. Data processing was carried out with the Snapping (Surface motioN mAPPING) service developed and integrated by Aristotle University of Thessaloniky in the GEP.
    Description: Published
    Description: 103267
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Geognostic survey ; Landslides ; MT-InSAR ; Village resettlement ; Calabria
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 189
    Publication Date: 2023-03-17
    Description: Spectral analyses of high-resolution records from the upper Eocene-lower Oligocene from the Massignano section, GSSP for the Eocene/Oligocene (E/O) boundary, and the nearby Massicore reveal orbitally controlled fluctuations in the percent concentration of calcium carbonate (wt% CaCO3) and magnetic susceptibility. Extraction of orbital components provides a consistent cyclochronology for the two sites that straddles the E/O boundary. Detection of longer-term modulation in the short eccentricity enabled tuning to the astronomical solution and development of a robust astrochronology for the E/O boundary transition in the GSSP section. Correlation with astrochronologically dated records allowed us to identify the local sedimentary response to the global paleoclimatic and palaeoceanographic events that characterize the greenhouse-icehouse transition during the late Eocene-early Oligocene.
    Description: Published
    Description: 110958
    Description: 4A. Oceanografia e clima
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 190
    Publication Date: 2023-03-22
    Description: Volcanic plume aerosol following the paroxysmal event of Mount Etna (Italy) in February 21st - 26th, 2021 was detected in Naples area (Italy), together with transport of Saharan dust aerosol, combining lidar, sunphotometer and satellite observations with back-trajectories and dispersion models simulations. Lidar data allowed to clearly distinguish the two main aerosol components, to investigate the spectral dependence of the aerosol optical properties and to retrieve their microphysical properties, essential for a detailed aerosol characterization. A new Monte Carlo algorithm, capable of retrieving the particle size distribution from lidar measurements, was applied. Lidar results are in good agreement with columnar integrated sunphotometer data. This combination of novel lidar observations of the vertically-resolved aerosol microphysics, column observations and modelling allows for a more complete description of multi-layered aerosol conditions.
    Description: Published
    Description: 106099
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 191
    Publication Date: 2023-03-22
    Description: Quantification of the subsurface geothermal potential primarily relies on the assessment of the thermal and mechanical configuration of the lithosphere. Such investigations require a detailed knowledge of the geological and tectonic forcing on the regional thermal, stress and hydraulic regimes and their counter feedback mechanisms. This approach becomes even more relevant in complex and active tectonic settings. In this regard, the Sicily region, which is located in the Central-Western Mediterranean, is an exceptional case study due to its almost unexplored geothermal potential hosted in a complex geodynamic setting. The present-day geological configuration resulted from the collision between the African and European plates, which led to the coexistence of compressional phases, beginning with the Oligocene-Miocene clockwise rotation of Corsica-Sardinia and alternated extensional phases in the Tyrrhenian basin due to the southward progression of the Sicilian- Maghrebian chain towards areas of the internal foreland (Hyblean domain). In this study, we attempt a reconstruction of the present-day lithospheric state of Sicily to quantify its thermal regime at shallow and intermediate depths. We have carried out a 3D lithospheric-scale gravity modelling in order to define the main geological units and their lithology-dependent rock properties, then integrated into a 3D geological model consistent with available borehole and seismic datasets. We have used the constructed geological model with its lithologydependent density, thermal conductivity, and radiogenic heat production to derive the present-day conductive thermal field as a whole and for individual tectonic or geological units, thereby considering different boundary conditions. We have finally validated results of the modelling against a shallow temperature dataset derived from hydrocarbon explorations. Our results indicate that the thermal field at depths shallower than 10 km is largely controlled by variability in sedimentary thickness in the foreland and the orogen, while deeper temperatures are primarily controlled by the distribution of the heat transferred from the mantle together with the radiogenic contribution of the shallow crystalline basement rocks and deeper crustal layers. The thermal modelling portrays a rather heterogenous Moho heat flow, locally higher than 80 mW/m2, revealing a particular geodynamic setting with specific areas characterized by high-to-medium enthalpy geothermal potential. As such, our modelling provides new perspectives for the exploration of geothermal resources in Sicily and helps to better constrain the thermal structure of the complex Sicilian collisional setting.
    Description: Published
    Description: 103976
    Description: 1TR. Georisorse
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 192
    Publication Date: 2023-03-20
    Description: Published in https://www.sciencedirect.com/science/article/pii/S0012821X22004617
    Description: Earthquake forecasting and prediction have long and in some cases sordid histories but recent work has rekindled interest based on advances in early warning, hazard assessment for induced seismicity and successful prediction of laboratory earthquakes. In the lab, frictional stick-slip events provide an analog for earthquakes and the seismic cycle. Labquakes are ideal targets for machine learning (ML) because they can be produced in long sequences under controlled conditions. Recent works show that ML can predict several aspects of labquakes using fault zone acoustic emissions. Here, we generalize these results and explore deep learning (DL) methods for labquake prediction and autoregressive (AR) forecasting. DL improves existing ML methods of labquake prediction. AR methods allow forecasting at future horizons via iterative predictions. We demonstrate that DL models based on Long-Short Term Memory (LSTM) and Convolution Neural Networks predict labquakes under several conditions, and that fault zone stress can be predicted with fidelity, confirming that acoustic energy is a fingerprint of fault zone stress. We predict also time to start of failure (TTsF) and time to the end of Failure (TTeF) for labquakes. Interestingly, TTeF is successfully predicted in all seismic cycles, while the TTsF prediction varies with the amount of preseismic fault creep. We report AR methods to forecast the evolution of fault stress using three sequence modeling frameworks: LSTM, Temporal Convolution Network and Transformer Network. AR forecasting is distinct from existing predictive models, which predict only a target variable at a specific time. The results for forecasting beyond a single seismic cycle are limited but encouraging. Our ML/DL models outperform the state-of-the-art and our autoregressive model represents a novel framework that could enhance current methods of earthquake forecasting.
    Description: Published
    Description: 117825
    Description: 3T. Fisica dei terremoti e Sorgente Sismica
    Description: JCR Journal
    Keywords: Physics - Geophysics; Physics - Geophysics; Computer Science - Computer Vision and Pattern Recognition
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 193
    Publication Date: 2023-03-20
    Description: The footwall of the surface rupturing Paganica normal fault, the source of the 2009 L’Aquila earthquake (Mw 6.1) in the Central Apennines (Italy), was investigated using integrated geological and geomorphological approaches. The aim was to constrain the active tectonics by studying the Raiale River that orthogonally crosscuts the fault trace, where it provides a useful geomorphological marker of long-term fluvial incision and footwall uplift. Using morphostratigraphy and paleomagnetic analysis, the Plio–Pleistocene morphotectonic evolution of the area was reconstructed, comprising an ancient continental basin and paleolandforms that predate the footwall incision. Starting from the Late Early Pleistocene–Middle Pleistocene, fluvial dissection was mainly due to marked river downcutting triggered by significant activity of the Paganica Fault, which caused progressive base-level lowering. The Raiale River downcutting formed five Middle–Late Pleistocene fluvial terraces, that, along with absolute Optically Stimulated Luminescence (OSL) dating, allowed the identification of paleolongitudinal profiles with a diverging downstream configuration. Terrace dating yielded a minimum incision rate of 0.25 ± 0.02 mm/a, which only partially compensates the footwall uplift and can thus be considered as a minimum value for the Paganica Fault throw rate, which could reach up to ~0.45 mm/a. In parallel, using terrestrial cosmogenic nuclides, a denudation rate of 0.02–0.04 mm/a was measured on the summit of the footwall block. This denudation is in keeping with the drainage incision, suggesting a non-steady state for the fault footwall topography and a dominance of relief growth. Last, the analysis of the modern Raiale River longitudinal profile denoted an ungraded status, with two main knickzones that we interpret as transient forms due to tectonic perturbations, likely triggered by activity of the Paganica Fault during the end Early Pleistocene and the Late Pleistocene. Considering the 2009 L’Aquila earthquake coseismic rupture, we observe that the younger transience on the Raiale River longitudinal profile, if it is of tectonic origin, could have only been produced by much larger seismic events (i.e., Mw 〉 6.5) than those documented in the area by paleoseismological investigations. The collective results confirmed that in the Central Apennines, conditions of dynamic equilibrium are often not met, and that the persistence of transient perturbations induced by tectonics should be accounted for.
    Description: The work was financially supported by the MIUR (Italian Ministry of Education, University and Research) project “FIRB Abruzzo - High-resolution analyses for assessing the seismic hazard and risk of the areas affected by the 6 April 2009 earthquake”, ref. RBAP10ZC8K_005 and RBAP10ZC8K_007, and by Agreement INGV-DPC 2012-2021. The airborne LiDAR survey performedby the Civil Protection of Friuli Venezia Giulia (Italy) was kindly released by Italian Civil Protection Department Special thanks to Simone Atzori, who provided the InSAR data.
    Description: Published
    Description: 108411
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Earthquake geology ; Active faults ; L'Aquila earthquake ; Morphotectonics ; active faulting
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 194
    Publication Date: 2023-03-20
    Description: In seismically active regions with variable dominant focal mechanisms, there is considerable tsunami inundation height uncertainty. Basic earthquake source parameters such as dip, strike, and rake affect significantly the tsunamigenic potential and the tsunami directivity. Tsunami inundation is also sensitive to other properties such as bottom friction. Despite their importance, sensitivity to these basic parameters is surprisingly sparsely studied in literature. We perform suites of systematic parameter searches to investigate the sensitivity of inundation at the towns of Catania and Siracusa on Sicily to changes both in the earthquake source parameters and the Manning friction. The inundation is modelled using the Tsunami-HySEA shallow water code on a system of nested topo-bathymetric grids with a finest spatial resolution of 10 m. This GPU-based model, with significant HPC resources, allows us to perform large numbers of high- resolution tsunami simulations. We analyze the variability of different hydrodynamic parameters due to large earthquakes with uniform slip at different locations, focal depth, and different source parameters. We consider sources both near the coastline, in which significant near-shore co-seismic deformation occurs, and offshore, where near- shore co-seismic deformation is negligible. For distant offshore earthquake sources, we see systematic and intuitive changes in the inundation with changes in strike, dip, rake, and depth. For near-shore sources, the dependency is far more complicated and co- determined by both the source mechanisms and the coastal morphology. The sensitivity studies provide directions on how to resolve the source discretization to optimize the number of sources in Probabilistic Tsunami Hazard Analysis, and they demonstrate a need for a far finer discretization of local sources than for more distant sources. For a small number of earthquake sources, we study systematically the inundation as a function of the Manning coefficient. The sensitivity of the inundation to this parameter varies greatly for different earthquake sources and topo-bathymetry at the coastline of interest. The friction greatly affects the velocities and momentum flux and to a lesser but still significant extent the inundation distance from the coastline. An understanding of all these dependencies is needed to better quantify the hazard when source complexity increases.
    Description: Published
    Description: 757618
    Description: 6T. Studi di pericolosità sismica e da maremoto
    Description: 8T. Sismologia in tempo reale e Early Warning Sismico e da Tsunami
    Description: 1SR TERREMOTI - Sorveglianza Sismica e Allerta Tsunami
    Description: 3IT. Calcolo scientifico
    Description: JCR Journal
    Keywords: tsunami ; inundation ; HPC ; earthquakes ; numerical simulations
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 195
    Publication Date: 2023-03-20
    Description: The present investigation provides measurements of radon (222Rn) concentration levels in 20 thermal waters at the Campi Flegrei volcanic caldera, an important geothermal system with hydrothermal manifestations in the Neapolitan area (Southern Italy). We used a RAD7® Radon-in-air detector equipped with Big Bottle RAD H2O and DRYSTIK accessories (Durridge Co. Inc.). Water samples with different chemical and/or physical conditions, not used as drink waters, are taken from continental thermal groundwaters, springs, lakes, pools and one sub merged thermal spring. The waters are mostly chlorine to bicarbonate, except of a few sulphate types sampled at the hydrothermal discharge areas of Solfatara and Pisciarelli, central in the caldera. Water temperature and pH values range from 18.1 to 91.3 ◦C and from 2 to 8, respectively. Sampling and measurement of radon in groundwater are complicated by the high volatility of the gas; a method is here proposed. In some of the 20 sites double or triple samples were collected by using different volume polyethylene terephthalate (PET) bottles, diluting sample with blank water, and modifying flow of pumped wells. We suggest that dilution can be considered when water is i) not enough to fill in the PET, resulting in large head space in the sampler, ii) too hot determining damage of the PET or iii) too saline to clog the Big Bottle System. Dissolved radon concentrations vary from 0.1 ± 0.1 to 1146 ± 57 Bq/L with an average value of 152 Bq/L, using the CAPTURE program, the default RAD7 data acquisition program. Similar values in radon concentration are obtained using the method proposed in De Simone et al. (2015) ranging between 0.1 ± 5.8 and 1286 ± 98 Bq/L with an average value of 167 Bq/L. The hottest and most acidic sulphate waters refer to a small boiling pool at Pisciarelli hydrothermal discharge area and have nearly zero 222Rn content. 222Rn concentrations from this study are mostly below the reference level of 1000 Bq/L recommended for human health protection by the European Commission and the most adopted in the scientific community (Catao ˜et al., 2022). No correlation has been observed between temperature, pH, major anions and radon content values, nor between rock composition since it is almost homogeneous trachyte at the study sites. 222Rn levels therefore appear to reflect the local sedimentological, structural or hydrogeological conditions. The levels of 222Rn here presented are an important background for the scientific community that will intend to define the natural fluctuations of dissolved 222Rn in relation with seasons, environment, hydrogeology or volcanic dynamics at the geohazardous Campi Flegrei area.
    Description: Published
    Description: 107641
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: 6SR VULCANI – Servizi e ricerca per la società
    Description: JCR Journal
    Keywords: 222Rn ; Campi Flegrei ; RAD7 ; Big Bottle RAD H2O ; DRYSTIK ; Dissolved radon
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 196
    Publication Date: 2023-03-20
    Description: The δ18O and δ2H of rivers and springs were investigated in order to characterize the groundwater recharge sources around Nyiragongo and Nyamulagira volcanoes, in the Democratic Republic of the Congo and Rwanda. Water samples were collected monthly between November 2013 and October 2014 from 5 major rivers, 3 major cold springs, 3 tepid springs and 1 hot spring. The temperatures of each spring were nearly constant over the sampling period attesting for their groundwater character, while the temperatures of the rivers were much more variable. The rivers monthly δ2H and δ18O range from 􀀀 6.8‰ to 1.9‰ and 􀀀 3.1‰ to 1.6‰, respectively, while springs showed depleted values that span from 􀀀 10.2 to 􀀀 1.1‰ for δ2H and 􀀀 3.6 to 􀀀 1.9‰ for δ18O. Catchment morphology (formed of depression, upper footslope and medium to high gradient-mountains) and the local tectonic discontinuity (fissures and faults) regulate the surface runoff and subsurface flow, control the precipitation infiltration zones and hence the aquifers recharge areas. Chemical and isotopic (δ18O and δ2H) compositions of springs and rivers reveal the presence of shallow and deep aquifers, with some waters having intermediate isotope composition. Three different recharge zones characterized by different altitudes were identified: the first is found at low altitude ranging from ~1800 m to ~2150 m, the second and intermediate recharge zone in the altitude range from ~2180 m to ~2500 m at the upper footslope area, while the third and highest recharge area is located in the altitudes range from ~2620 to ~3220 m. The two upper recharge areas are the most fractured and fissured zones allowing rapid infiltration of depleted precipitations which recharge deep aquifers found in the tepid and hot springs. Based on their chemical and isotopic composition, waters from the shallow and deep aquifers have been considered representative of mixing end members. During their ascent to the surface, water from the deep aquifer mixes with that of shallow aquifer yielding the tepid springs of intermediate chemical and isotopic composition, while the other keep their original fingerprint corresponding to the isotopically depleted hot spring.
    Description: Published
    Description: 120778
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
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  • 197
    Publication Date: 2023-03-20
    Description: Implicit integration of the viscous term can significantly improve performance in computational fluid dynamics for highly viscous fluids such as lava. We show improvements over our previous proposal for semi-implicit viscous integration in Smoothed Particle Hydrodynamics, extending it to support a wider range of boundary models. Due to the resulting loss of matrix symmetry, a key advancement is a more robust version of the biconjugate gradient stabilized method to solve the linear systems, that is also better suited for parallelization in both shared-memory and distributed-memory systems. The advantages of the new solver are demostrated in applications with both Newtonian and non-Newtonian fluids, covering both the numerical aspect (improved convergence thanks to the possibility to use more accurate boundary model) and the computing aspect (with excellent strong scaling and satisfactory weak scaling).
    Description: Published
    Description: 111413
    Description: 3IT. Calcolo scientifico
    Description: JCR Journal
    Keywords: SPH ; Low Reynods number ; Implicit integration ; BiCGSTAB ; GPU ; 05.01. Computational geophysics
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  • 198
    Publication Date: 2023-03-20
    Description: The evolution of High-Performance Computing (HPC) platforms enables the design and execution of progressively larger and more complex workflow applications in these systems. The complexity comes not only from the number of elements that compose the workflows but also from the type of computations they perform. While traditional HPC workflows target simulations and modelling of physical phenomena, current needs require in addition data analytics (DA) and artificial intelligence (AI) tasks. However, the development of these workflows is hampered by the lack of proper programming models and environments that support the integration of HPC, DA, and AI, as well as the lack of tools to easily deploy and execute the workflows in HPC systems. To progress in this direction, this paper presents use cases where complex workflows are required and investigates the main issues to be addressed for the HPC/DA/AI convergence. Based on this study, the paper identifies the challenges of a new workflow platform to manage complex workflows. Finally, it proposes a development approach for such a workflow platform addressing these challenges in two directions: first, by defining a software stack that provides the functionalities to manage these complex workflows; and second, by proposing the HPC Workflow as a Service (HPCWaaS) paradigm, which leverages the software stack to facilitate the reusability of complex workflows in federated HPC infrastructures. Proposals presented in this work are subject to study and development as part of the EuroHPC eFlows4HPC project.
    Description: Published
    Description: 414-429
    Description: 6T. Studi di pericolosità sismica e da maremoto
    Description: 8T. Sismologia in tempo reale e Early Warning Sismico e da Tsunami
    Description: 4V. Processi pre-eruttivi
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: 3IT. Calcolo scientifico
    Description: JCR Journal
    Keywords: High performance computing ; Distributed computing ; Parallel programming ; HPC-DA-AI convergence ; Workflow development ; Workflow orchestration
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 199
    Publication Date: 2023-03-23
    Description: Aquaculture represents an important source of food and it plays an important role in terms of contribution to economic development. Offshore farming offers considerable advantages, especially in terms of production costs (lower than those of onshore facilities) and of farmed product quality. Suitable areas for aquaculture activities are still available in Italy but are increasingly limited and the demand for new farms is high. The lack of coastal areas allocated to aquaculture and the complex regulatory and legal framework constitutes the major constraints for further development of the sector. Zoning is the process that can allow to sustainably identify and allocate suitable areas for aquaculture. Several aspects, such as effective legal framework and procedures, collection of bio-geochemical, physical and socio-economical information, are crucial for a correct aquaculture zoning process in order to identify the Allocated Zones for Aquaculture (AZAs). In the present work, a spatial multi-criteria decision analysis (SMCDA) was applied for the individuation of potentially suitable marine areas for fish farming across the southern Tyrrhenian coast of Tuscany (Italy). The spatial model was developed by collecting and processing Earth Observation (EO) data, oceanography in situ measurements, and infrastructural and environmental constraints. Excluding areas of constrains, obtained results highlight that 96% of the total investigated area is characterised by medium (62%) and high (34%) suitability. In particular, the highest suitability areas occur in the Talamone gulf and offhore the Argentario promontory at water depth between 15-30 m and 30 50m, respectively. Other high suitability areas occur northern of Piombino town between 30-100 m depth. Environmental data at higher spatial resolution are needed to improve aquaculture zoning and further process of site selection in order to ensure the sustainability of fish farming in the study area.
    Description: Published
    Description: 106261
    Description: 3A. Geofisica marina e osservazioni multiparametriche a fondo mare
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 200
    Publication Date: 2023-01-16
    Description: Open-vent volcanic activity is typically sustained by ascent and degassing of shallow magma, in which the rate of magma supply to the upper feeding system largely exceeds the rate of magma eruption. Such unbalance between supplied (input) and erupted (output) magma rates is thought to result from steady, degassing-driven, convective magma overturning in a shallow conduit/feeding dyke. Here, we characterize shallow magma circulation at Stromboli volcano by combining independent observations of heat (Volcanic Radiative Power; via satellite images) and gas (SO2 , via UV camera) output in a temporal interval (from August 1, 2018 to April 30, 2020) encompassing the summer 2019 effusive eruption and two paroxysmal explosions (on July 3 and August 28, 2019). We show that, during the phase of ordinary strombolian explosive activity that preceded the 2019 effusive eruption, the average magma input rate (0.1-0.2 m3 /s) exceeds the magma eruption rate (0.001-0.01 m3 /s) by ∼2 orders of magnitude. Conversely, magma input and output rates converge to an average of ∼0.4 m3 /s during the summer 2019 summit effusion, implying an overall suppression of magma recycling back into the feeding system, and hence of excess degassing. We find that, during the effusive eruption, the peak in SO2 emissions lags behind the thermal emission peak by ∼27 days, suggesting that magma output, feeding the lava flow field, initially dominates over magma input in the conduit. We propose that this conduit mass unloading, produced by this initial phase of the effusive eruption, leads to an overall decompression (of up to 30 Pa/s) of the shallow plumbing system, ultimately causing ascent of less-dense, volatile-rich magma batch(es) from depth, enhanced explosive activity, and elevated SO2 fluxes culminating into a paroxysmal explosion on August 28. Our results demonstrate that combined analysis of thermal and SO2 flux time-series paves the way to improved understanding of shallow magmatic system dynamics at open-vent volcanoes, and of the transition from explosive to effusive activity regimes.
    Description: Published
    Description: 117726
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
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