ALBERT

Description: Igneous rocks were recovered from three sites on Hess Rise during Deep Sea Drilling Project Leg 62: altered basalt at Site 464, at the northern end of Hess Rise; and altered trachyte from Site 465, and rounded basalt pebbles in upper Albian to middle Miocene sediments from Site 466, both at the southern end of Hess Rise. Major-, minor-, and trace-element data for basalt from Hole 464 are consistent with these rocks being transitional tholeiites that have undergone low-temperature alteration by reaction with sea water. Trachyte from Hole 465A exhibits as many as three generations of plagioclase along with potash feldspar that are flow aligned in groundmasses alterted to smectites and random mixed-layer clays. Textural evidence indicates that these rocks were eruped subaerially. Chemical data show a range of values when plotted on two- and three-component variation diagrams. The observed variations may result in part from differentiation, but they also reflect the high degree of alteration. Several oxides and elements show strong correlation with H2O+: K2O, SiO2, Rb and Lu decrease and MgO increases with increasing H2O+. These trends, except for that of Lu, are consistent with experimentally determined changes in chemistry that accompany alteration. The trend for Lu has not been previously reported; it may result from a more-intense alteration of the HREE-rich mafic minerals than of the LREE-rich feldspars. Despite their alteration, the trachytes compare favorably with alkalic differentiates from oceanic islands. We interpret Hess Rise as a volcanic platform formed by eruption of off-ridge volcanic rocks onto MORB oceanic crust during the Aptian and Albian stages, after the basement had migrated away from the spreading center. By analogy with present oceanic islands, we propose that early tholeiitic basalts were followed by alkalic basalts and their differentiation products (trachytes), producing a volcanic archipelago of islands and seamounts. Subsequent tectonism and subsidence led to the present state of Hess Rise.

Description: From 12 radiolarian-rich claystone samples of the DSDP-Leg 25, Site 249, situated in the western Indian Ocean southwest of Madagascar 4 species of agglutinated and 38 species of calcareous benthonic foraminifera are described, 13 of them in open nomenclature. As a lot of Valanginian species and Gavelinella barremiana occur in the foraminiferal faunas described here a Valanginian-Hauterivian age is assigned to them. These microfaunas investigated here yield some index species characteristic in the Lower Cretaceous deposits of Northern Germany and also from the near-by Madagascar. Nodosariids dominate in a striking way with 36 species, especially of Astacolus, Citharina, Lenticulina, Lingulina, Marginulinopsis, Nodosaria, Saracenaria, and Vaginulina. Important Neocomian species well-known from other DSDP sites, namely Praedorothia ouachensis (SIGAL) and planktonic foraminifers, are missing. The microfaunas of Site 249 have to be derived from shelf areas.

Description: Atomic-absorption spectrophotometry and instrumental neutron activation analysis were used to determine concentrations of SiO2, Al2O3, FeOt, MgO, CaO, Na2O, K2O, MnO, La, Ce, Sm, Eu, Tb, Yb, Lu, Sc, Co, Cr, Th, Hf, and Ta for 14 basalt samples from the lower portion of Hole 462A in the Nauru Basin. The basalts are similar to normal midocean ridge basalt (MORB) for the elements analyzed, and light rare-earth elements (LREE) are depleted relative to heavy rare-earth elements (HREE). Two samples are extensively altered to smectites and show significant reductions in Al2O3, CaO, MnO, Na2O, REE, Sc, Co, and Hf and gains in MgO and FeOt relative to unaltered samples. The increase in MgO and decrease in CaO indicate that alteration was caused by hydrothermal solutions.

Description: The genus Hinia is divided in 4 subgenera; other subgenera are not represented in the area studied. It was possible to find criteria for a better discrimination of the highly variable species H. (Hinia) schlotheimi and H. (Hinia) turbinella. The species "fuchsi" has been placed in the synonymy of H. (Hinia) turbinella. The species H. (Hinia) schlotheimi (BEYRICH) and H. (Telasco) schroederi (KAUTSKY) have been united under the name H. (Hinia) schlotheimi. The easily distinguishable species H. (Tritonella) tenuistriata and H. (Hinia) sulcata belong to two different genera. H. (Tritonella) cimbrica andersoni of the Viol- and Katzheide-Beds (Reinbek-stage) is separable from the population found in the Hemmoor-stage, it turned out to be a valuable guide subspecies for the Reinbek-stage. The species H. (Tritonella) serraticosta, H. (Tritonella) catulli, H. (Hinia) holsatica, and H. (Telasco) syltensis are all similar in respect to shape and ornamentation. Criteria have been found for a better discrimination of these species. The species contabulata, effusa and seminodifera described by SPEYER (1864), turned out to be contogenetic stages of H. (Tritonella) pygmaea. H. (Tritonella) cavata, previously described from the Tertiary of the North sea area, was proven to be absent from the area investigated. The forms described under that name, belong to H. (Tritonella) woodwardi.

Description: At Deep Sea Drilling Project (DSDP) Site 462, from mudline to 447 meters below the sea floor, Cenozoic nannofossil oozes and chalks have acoustic anisotropies such that horizontal sonic velocities are 0 to 2.5% faster than those in the vertical direction. In laminated chalk, anisotropy of 5% is typical, and in limestones, radiolarian oozes, porcellanites, and cherts, the anisotropies range from 4 to 13%. Middle Maestrichtian volcaniclastics from 447 meters to 560 meters below the sea floor have an acoustic anisotropy of 2 to 32%; 4 to 13% is typical. Basalt flows and sills occur between 560 meters and 1068 meters, and have no apparent anisotropy, but minor interbedded volcaniclastics have anisotropies from 0 to 20% (5% is typical). These volcaniclastics frequently have very small anisotropies, however, compared with the volcaniclastic sequence above the basalt section. Data in cross-plots of the laboratory-measured compressional sound velocity versus wet-bulk density, wet-water content, and porosity of sediments and sedimentary rock typically lie between the equations derived by Wyllie et al. (1956) and Wood (1941); the Wyllie et al. (1956) equation has a fair fit with similar basalt velocity cross-plots. Crossplots of thermal conductivity and sound velocity indicate only a fair correlation. Cross-plots of thermal conductivity versus porosity, wet-water content, and wet-bulk density correlate well with equations derived by Maxwell (1904), Ratcliff (1960), Parasnis (1960), and Bullard and Day (1961). Electrical formation factor versus porosity for sediments and sedimentary rock agrees with the Archie (1942) equation, with m values of 2.6; for basalt, an m of about 2.1 is typical. Basalt pore-water resistivities do not appear to be greatly different from sea water. Formation factors are greater than those derived from equations in Maxwell (1904), Winsauer et al. (1952), Boyce (1968), and Kermabon et al. (1969). An "apparent interstitial water resistivity" (Rwa) curve was derived from the density and induction logs. This Rwa curve indicated an anomaly, at 393.5 to 396.5 meters, which could be interpreted as (1) 76% hydrocarbons, (2) relatively fresh pore water (1.8 per mil salinity), or (3) low-grain-density (2.2 g/cm**3) semi-lithified porcellanite-chert. Porcellanite-chert is the most plausible interpretation. In situ temperatures measured by the Uyeda temperature probe were about 2 to 5°C (50%) higher than the equilibrium temperature (Lachenbruch and Brewer, 1959) extrapolated from two Gearhart-Owen continuous temperature logs; this discrepancy probably arises because the hole was washed out in this depth interval, so these extrapolated temperatures are probably not reliable. If one ignores all precautions as to temperature artifacts, then the equilibrium temperatures of the Gearhart-Owen temperature logs suggest that hydrothermal circulation is occurring in at least the upper 40 meters of the basalt section and heat is transferred by convection and not conduction. Hydrothermal circulation is probably not indicated, however, and the temperature anomalies probably result from excessive artificial cooling of the fractured basalt zones by circulation of water during drilling.

Description: The stratigraphic position of the glacially transported 'Scholle' (large-size erratic block) at Schobüll near Husum (Schleswig-Holstein) is now considered to be Devonian rather than 'Rotliegendes'. The 'Scholle', consisting of red clay and dolomite, is overlain by red-colored till without any flint but with up to 90% carbonate clasts (containing 15% dolomite), which indicates an eastern Baltic origin. The relationship of the 'Scholle' with the glacial till also points to an eastern Baltic origin for it, with up to 1 000 km transport distance.

Description: Ferromanganese nodules in the deep-sea and in freshwater lakes usually accrete layers rich in manganese oxides alternating with layers rich in iron oxides. The mechanism producing these alternating layers is unknown; indeed, the mechanism producing the nodules themselves is unknown. In Oneida Lake, New York, precipitants from the lake water and the surfaces of nodules at the sediment-water interface are enriched in Mn, whereas nodules buried in lake sediments have surface layers enriched in Fe. It is hypothesized here, using field and laboratory evidence, that reduction and mobilization of Mn from the nodule surface during periods of anoxic sediment cover produce the high Fe layers observed in the nodules.

Description: Deep sea manganese nodules from the Central Pacific Basin are mainly composed of 10Å manganite and d-MnO2 Two zones equivalent to the minerals are evidently distinguishable according to their optical properties. Microscopic and microprobe analyses revealed quite different chemical compositions and textnral characteristics of the two zones. These different feature of the two zones of nodules suggest the different conditions under which they were formed. Concentrations of 11 metal elements in the zones and inter-element relationships show that the 10Å manganite zone is a monomineralic oxide phase containing a large amount of manganese and minor amounts of useful metals, and that the d-MnO2 zone which is apparently homogeneous under the microscope is a mixture of three or more different minerals. The chemical characteristics of the two zones can explain the variation of bulk composition of deep sea manganese nodules and inter-element relationships previously reported, suggesting that the bulk compositions are attributable to the mixing of the 10Å manganite and d-MnO2 zones in various ratios. Characteristic morphology and surface structure of some types of nodules and their relationships to chemistry are also attribut able to the textural and chemical features of the above mentioned two phases. Synthesis of hydrated manganese oxides was carried out in terms of the formation of manganese minerals in the ocean. The primary product which is an equivalent to d-MnO2 was precipitated from Mn 2+ -bearing alkaline solution under oxigenated condition by air bubbling at one atmospheric pressure and room temperature. The primary product was converted to a l0Å manganite equivalent by contact with Ni 2+, Cu 2++ or CO2+ chloride solutions. This reaction caused the decrease of Ni2+, Cu2+ or CO2+ concentrations and the increase of Na+ concentration in the solution. The reaction also proceeded even in diluted solutions of nickel chloride and resulted in a complete removal of Ni2+ from the solution. Reaction products were exclusively 10Å manganite equivalents and their chemical compositions were very similar to those of 10Å manganite in manganese nodules. The maximum value of(Cu+Ni+Co)/Mn ratio of 10Å manganite zones in manganese nodules is 0.16, and the Ni/Mn ratio of synthetic 10Å manganite ranges from 0.15 to 0.18 with the average of 0.167.

Description: Twenty-four manganese nodules from the surface of the sea floor and fifteen buried nodules were studied. With three exceptions, the nodules were collected from the area covered by Valdivia Cruise VA 04 some 1200 nautical miles southeast of Hawaii. Age determinations were made using the ionium method. In order to get a true reproduction of the activity distribution in the nodules, they were cut in half and placed for one month on nuclear emulsion plates to determine the alpha-activity of the ionium and its daughter products. Special methods of counting the alpha-tracks resolution to depth intervals of 0.125 mm. For the first time it was possible to resolve zones of rapid growth (impulse growth) with growth rates, s 〉 50 mm/106 yr and interruptions in growth. With few exceptions the average rate of growth of all nodules was surprisingly uniform at 4-9 mm/10 yr. No growth could be recognized radioactively in the buried nodules. One exceptional nodule has had recent impulse growth and, in the material formed, the ionium is not yet in equilibrium with its daughter products. Individual layers in one nodule from the Indian Ocean could be dated and an average time interval of t = 2600±400 yr was necessary to form one layer. The alternation between iron and manganese-rich parts of the nodules was made visible by colour differences resulting from special treatment of cut surfaces with HCl vapour. The zones of slow growth of one nodule are relatively enriched in iron. Earlier attempts to find paleomagnetic reversals in manganese nodules have been continued. Despite considerable improvement in areal resolution, reversals were not detected in the nodules studied. Comparisons of the surface structure, microstructure in section and the radiometric dating show that there are erosion surfaces and growth surfaces on the outer surfaces of the manganese nodules. The formation of cracks in the nodules was studied in particular. The model of age-dependent nodule shrinkage and cracking surprisingly indicates that the nodules break after exceeding a certain age and/or size. Consequently, the breaking apart of manganese nodules is a continuous process not of catastrophic or discontinuous origin. The microstructure of the nodules exhibits differences in the mechanism of accretion and accretion rate of material, shortly referred to as accretion form. Thus non-directional growth inside the nodules as well as a directional growth may be observed. Those nodules with large accretion forms have grown faster than smaller ones. Consequently, parallel layers indicate slow growth. The upper surfaces of the nodules, protruding into the bottom water appear to be more prone to growth disturbances than the lower surfaces, immersed in the sediment. Features of some nodules show, that as they develop, they neither turned nor rolled. Yet unknown is the mechanism that keeps the nodules at the surface during continuous sedimentation. All in all, the nodules remain the objects of their own distinctive problems. The hope of using them as a kind of history book still seems to be very remote.

Description: This report is Volume 3 of Descriptions of WHOI rock dredge samples. This series represents a major effort to catalog the rock dredge samples in the WHOI Sea Floor samples collection, and to disseminate this information throughout the scientific community. Volume 3 contains sample descriptions and station data for the dredge stations from five cruises during the period September 1978 through December 1980. The material in this and subsequent volumes of rock descriptions was largely prepared onboard ship by the participating scientists. Volume 3 was printed prior to volumes 1 and 2 because of the excellent documentation of the samples represented in this volume.

Description: The minor-element composition of concentric layers within a single ferromanganese nodule from the eastern North Pacific exhibits strong correlations with Fe and Mn contents but appears to be independent of pronounced mineralogic variations. On the basis of these correlations, the elemental composition of individual layers apparently is controlled by the relative contribution of two sources: seawater, and interstitial water of associated sediment. In contrast, the mineralogy of the nodule, consisting of birnessite in the outer few layers and todorokite in the inner layers, is considered to be a function of nodule diagenesis.

Description: Compositional data for coexisting manganese nodules, micronodules, sediments and pore waters from five areas in the equatorial and S.W. Pacific have been obtained. This represents the largest study of its type ever undertaken to establish the distribution of elements between the various phases within the sediment column. The composition of manganese nodules, micronodules and sediments (on a carbonate-free basis) shows marked differences between the equatorial high productivity zone and the low productivity region of the S.W. Pacific. In the case of the nodules, th is reflects an increased supply of transition elements (notably Ni, Cu and Zn) to the nodules as a result of the in situ dissolution of siliceous tests within the sediment column in the equatorial Pacific high productivity zone. Micronodules display similar, but somewhat different, compositions to those of the associated nodules in each area. Micronodule composition is therefore influenced by the same basic factors that control nodule composition, but is modified by dissolution of the micronodules in situ within the sediment column. Locally, as in the area immediately south of the Marquesas Fracture Zone, the micronodule population is contaminated by small, angular volcanic rock fragments; this leads to apparently anomalous micronodule compositions. Micronodules appear to be a transient feature in the sediment column, especially in the equatorial Pacific. Dissolution of micronodules in the sediment column therefore represents an important source of elements for the growth of manganese nodules in the equatorial Pacific. Sediment composition is markedly influenced by the carbonate content. On a carbonate-free basis, the sediments from the equatorial high productivity zone are quite distinct in composition from those in the S.W. Pacific. This reflects differences in the lithology of the sediments. In the Aitutaki Passage, the local influence of volcanoclastic material in sediment composition has been established. The major cations and anions in pore waters measured here show no major differences between equatorial and S.W. Pacific sediments. Silica is, however, higher in equatorial Pacific pore waters reflecting the dissolution of siliceous tests in these sediments.

Description: From a structural and morphological point of view, the continental margin of southwestern Africa is a middle-aged "pull-apart" or "passive-type" margin which was initially created during the breakup of the supercontinent of Gondwanaland in the Mesozoic. The most important objective of the Leg 40 expedition was the attainment of strata laid down when the newly formed ocean was very young and only a few hundred kilometers wide. Site 361 was drilled at the fall of continental platform into the Cape Basin, to a sub-sea floor depth of 1314 meters and yielded sediments that range in age from upper Eocene to lower Aptian and possibly slightly older.

Description: he forty-first cruise of Glomar Challenger was devoted to the study of the evolution of the eastern basins of the North Atlantic, off the continental margin of West Africa. As the available data a the time was showing that most litho-stratigraphic units in the deep basins of the Atlantic had enough lateral extension, the drilling of a limited number of sites in key areas would allow for large-scale regional interpretation. One of the sites was loacted in the Cape Verde deep Basin (Site 367) while others were located in shallower waters such as, the Sierra Leone Rise (Site 366), the Cape Verde Rise (Site 368) or the Continental Slope off Spanish Sahara (Site 369).

Description: On cruises 10 and 15 of Academic Kurchatov (1971, 1973) at the Jan-Mayen Ridge, a large number of samples was obtained. Most of them contained sedimentary rocks. From their study, it is safe to assume that the rocks of the Jan-Mayen Ridge were, at first, subjected to subsidence to a considerable depth, and then uplifted to their contemporary position, by the ascending tectonic movements. Thus, the Jan-Mayen Ridge is in contrast to other Atlantic submarine ridges, not only in the sedimentary rock composition, but in the character of the tectonic movements.

Description: Leg 42, Part 1 of the Deep Sea Drilling Project was scheduled to continue the geological exploration of the Mediterranean. The strategy was to search for areas where the Mediterranean Evaporite formation had been largely or completely removed by erosion, such is the case for Site 372. For Leg 42, Part 2, the project entered the Black Sea. In particular, Site 379 was located the central portion of the Black Sea.

Description: The western part of the North Atlantic Ocean holds clues to some of the most intriguing questions in marine geology. But because the geologic problems are many and varied, the sites of Leg 44 were multipurpose in nature. In particular, some of the targets were : 1) the Blake Nose, a spur of the Blake Plateau, to determine the nature, age, and origin of reef-like structures recognized on seismic profiles and 2) the Blake Outer Ridge, a long low ridge of sediments that forms the eastern boundary of the Blake-Bahama Basin, where we hoped to study the stratigraphy and sample supposed clathrates.

Description: Initial data on the hydrogen-isotopic compositions in hydrous Mn minerals from various occurrences fall in a wide range from -298 to -84 per mil, relative to SMOW. DeltaD-values of todorokite and cryptomelane from Tertiary deposits show -89 and -150 per mil. 10 Angström-manganite and Delta-MnO2 from deep-sea nodules have relatively restricted DeltaD-values ranging from -96 to -84 per mil. The DeltaD-values for manganese bog ores from recent hot springs show almost -105 per mil. It is recognized that the isotopic values obtained for the deep-sea nodules and recent bog ores are slightly different ranged. Manganite and groutite are unique in their hydrogen-isotopic compositions, having the most depleted DeltaD-values ranging from -298 to -236 per mil. MnO(OH) minerals are more deuterium-depleted hydrous minerals than any other hydrothermal minerals from various ore deposits. Hydrogen-isotope fractionation factors between manganite and water were experimentally determined to be 0.7894, 0.7958 and 0.8078 at 150°, 200° and 250°C, respectively. the present experimental results indicate that if manganites were formed at temperatures below 250°C, under isotopic equilibrium conditions, most of the manganite mineralization in the Tertiary manganese deposits must have precipitated from meteoric hydrothermal solutions.

Description: This report is Volume 1 in the series of reports entitled "Descriptions of W.H.O.I. rock dredge samples". This series represents a major effort to catalog and prepare initial descriptions for all rock dredge samples in the W.H.O.I. Sea Floor Samples Collection, and to distribute this information throughout the scientific community. Volume 1 contains sample descriptions from approximately 382 dredging stations executed during the period 1960 through 1977. It also represents a digitized listing of all dredge station data for the entire W.H.O.I. Dredge Collection through 1980. This data is sorted by Marsden Square and can serve as a regional index for all rock descriptions included in Volumes 1-3.

Description: A submersible study has been conducted in February - March 1978 at the axis of the East Pacific Rise near 21°N. The expedition CYAMEX, the first submersible program to be conducted on the East Pacific Rise, is part of the French-American-Mexican project RITA (Rivera - Tamayo), a 3-year study devoted to detailed geological and geophysical investigations of the East Pacific Rise Crest. On the basis of the 15 dives made by CYANA in the axial area of the Rise, a morphological and tectonic zonation can be established for this moderately-fast spreading center. A narrow, 0.6 to 1.2 km wide zone of extrusion (zone 1), dominated by young lava flows, is flanked by a highly fissured and faulted zone of extension (zone 2) with a width of 1 to 2 km. Further out, zone 3 is dominated by outward tilted blocks bounded by inward-facing fault scarps. Active or recent faults extend up to 12 km from the axis of extrusion of the East Pacific Rise. This represents the first determination from direct field evidence of the width of active tectonism associated with an accreting plate boundary. Massive sulfide deposits, made principally of zinc, copper and iron, were found close to the axis of the Rise. Other signs of the intense hydrothermal activity included the discovery of benthic fauna of giant size similar to that found at the axis of the Galapagos Rift. We emphasize the cyclic character of the volcanicity. The main characteristics of the geology of this segment of the East Pacific Rise can be explained by the thermal structure at depth below this moderately-fast spreading center. The geological observations are compatible with the existence of a shallow magma reservoir centered at the axis of the Rise with a half-width of the order of 10 km.

Description: Of numerous island-arc systems in the western Pacific, the Mariana arc-trench system and the basins and submerged ridges lying west of them in the Philippine Sea seemed to be best suited to answer questions regarding arc-trench and back-arc basin formation. Three years of planning by the JOIDES Active Margin Panel, Ocean Crust Panel, and Planning Committee resulted in a proposed transect of drill sites aligned more or less along the 18th parallel. This South Philippine Sea transect was designed to investigate each major basin and ridge between the central part of the West Philippine Sea and the Mariana Trench and the Pacific Ocean plate immediately to the east.

Description: The goal of Site 462 was to study the paleontologic, sedimentary, petrologic, tectonic, and magnetic histories of that area through Recent to Late Jurassic time by drilling a deep re-entry site into the Nauru Basin west of the Ralik Chain of the Marshall Islands. This area formed at a fast-spreading Pacific Plate boundary 145 to 155 m.y. ago, in the Late Jurassic. Cores from this area allow to better understand the biostratigraphic evolution and sedimentary processes in a Mesozoic open-ocean environment, the petrologic nature of fast-spreading oceanic crust, the tectonic history of the Late Jurassic Pacific Plate, and the nature of the Jurassic magnetic quiet zone.

Description: The four sites drilled during Leg 62 were needed to establish better regional coverage of the North Pacific Ocean. Although paleoenvironments were to be stressed on Leg 62, studies of igneous rocks from acoustic basement were planned, to determine ages, petrogenesis, alteration effects, rock magnetism, and Paleomagnetism of old parts of the Pacific crust. These studies were emphasized in order to establish the early history of oceanic plateaus and whether they are the result of midocean-ridge or intraplate volcanism.

Description: A primary objective of Leg 63 was to investigate the fluctuations of this eastern boundary current along a north-south transect off the Gulf of California. This information would aid in biostratigraphically correlating open-ocean planktonic zones with local California zonations. Spanning the last 30 m.y., the complicated tectonic history of the continental margin off California and Baja California comprises changes from a subduction zone to a transform boundary and then to an inactive margin. A second objective of Leg 63 was to define and clarify this history using information on sedimentation, unconformities, basement ages, and paleomagnetic reconstructions gained from drilling, in conjunction with geophysical data and pre-existing bottom samples.

Description: Undamaged deep-sea manganese nodules were retrieved from a box core from the central North Pacific and quickly preserved in formaldehyde solution. Light and scanning electron microscope studies of the nodule surface reveal the presence of a variety of fragile filamentous and coccoid bacterial morphotypes, associated with an organic film that covers the botryoid surface.

Description: Three ferromanganese nodules handpicked from the tops of 2500 cm**2 area box cores taken from the north equatorial Pacific have been analysed for their U-Th series nuclides. 230Thexc concentrations in the surface 1-2 mm of the top side of the nodules indicate growth rates of 1.8-4.6 mm/10**6 yr. In two of the nodules a significant discontinuity in the 230Th exc depth profile has been observed at ~0.3 m.y. ago, suggesting that the nodule growth has been episodic. The concentration profiles of 231Pa exc (measured via 227Th) yield growth rates similar to the 230Th exc data. The bottom sides of the nodules display exponential decrease of 230Th exc/232Th activity ratio with depth, yielding growth rates of 1.5-3.3 mm/10**6 yr. The 230Th exc and 231Pa exc concentrations in the outermost layer of the bottom face are significantly lower than in the outermost layer of the top face. Comparison of the extrapolated 230Thexc/232Th and 230Th exc/231Pa exc activity ratios for the top and bottom surfaces yields an "age" of (5-15) x 10**4 yr for the bottom relative to the top. This "age" most probably represents the time elapsed since the nodules have attained the present orientation. The 210Pb concentration in the surface ~0.1 mm of the top side is in large excess over its parent 226Ra. Elsewhere in the nodule, up to ~1 mm depth in both top and bottom sides, 210Pb is deficient relative to 226Ra, probably due to 222Rn loss. The absence of 210Pbexc below the outermost layer of the top face rules out the possibility of a sampling artifact as the cause of the observed exponentially decreasing 230Thexc and 231Paexc concentration profiles. The flux of 210Pbexc to the nodules ranges between 0.31 and 0.58 dpm/cm**2/yr. The exhalation rate of 222Rn, estimated from the 226Ra-210Pb disequilibrium is ~570 dpm/cm**2/yr from the top side and 〉2000 dpm/cm**2/yr from the bottom side. 226Ra is deficient in the top side relative to 230Th up to ~0.5-1 mm and is in large excess throughout the bottom. The data indicate a net gain of 226Ra into the nodule, corresponding to a flux of (24-46) x 10**-3 dpm/cm**2/yr. On a total area basis the gain of 226Ra into the nodules is 〈20% of the 226Ra escaping from the sediments. A similar gain of 228Ra into the bottom side of the nodules is reflected by the high 228Th/232Th activity ratios observed in the outermost layer in contact with sediments.

Description: The bulk chemical compositions of ferromanganese nodules recovered from 14 of 38 sediment cores collected from a 230 km2 area of abyssal hill topography in the northern equatorial Pacific (8° 20'N, 153° 0'W; regional depth 5000 m) vary nonrandomly between fairly wide limits. The nodules have Mn/Fe ratios ranging from 2.60 to 5.38 and all samples contain todorokite and delta-MnO2 . The variation in the Mn/Fe ratio is governed by the total Fe contents of the nodules; Mn varies to a much smaller extent. Cu and Ni contents average about 1% and vary independently of the Mn contents. The compositional variation in the nodules is related to two features of the associated sediments, which are siliceous pelagic clays. The total Fe contents correlate positively with the oxalate-soluble Fe contents of the surface (0-2 cm) sediments; and their Mn/Fe ratios correlate negatively with the accumulation rates of the sediments. It is suspected that the composition of the nodules is influenced to a considerable extent by diagenetic reactions in the sediments, the clearest manifestation of this being the transformation of oxyhydroxide Fe into an insoluble form, possibly by the formation of smectite. This in turn leads to the formation of relatively Fe-poor ferromanganese nodules. Such nodules occur on slowly accumulating sediments where relatively more diagenetic reaction in the sediments has taken place.

Description: Excess 230Th dominates the alpha activity of the surface regions of manganese nodules and deep sea sediments. If uranium series eguilibrium is maintained, total alpha activity depth profiles should be as useful in determining sedimentation rates as are 230Th measurements. We have used cellulose nitrate alpha track recorders pressed against manganese nodule slabs to record high resolution alpha activity "maps' of a large number of nodules. Total alpha activity profiles have also been obtained for several sediment cores. From the approximately 90 nodule profiles measured to date, 73 show simple, approximately exponential depth dependence; about 2/3 of these have inferred deposition rates of 4-10 mm/10power6 yr. Ten profiles show statistically significant breaks in slope, suggesting growth rate changes. Within single dredge hauls there is little variation in growth rates, although different portions of the same nodule sometimes exhibit different growth rates. There is no correlation between depth and measured growth rate, except for a general tendency for the few Atlantic Ocean nodules we have measured to have slightly lower rates than Pacific or Indian Ocean samples. For a number of nodules and sediments the alpha track results have been compared with 230Th-based deposition rates measured by other workers. Two nodules have 230Th rates (W. S. Broecker et al., pers. comm.) identical within errors to the alpha track determinations. A third nodule (S. Krishnaswami, pers. comm. ) and two sediment cores previously measured by Goldberg and Koide (E. Sci. and Meteoritics, 1963, p. 90} all have much slower rates based on 230Th measurements compared with the alpha track results.

Description: This report presents megascopic descriptions of deep-sea sediment cores obtained by personnel of the Hawaii Institute of Geophysics on cruises of the R/V Kana Keoki in the eastern Pacific Ocean during the year 1978.

Description: The unusual petrological diversity of abyssal lavas erupted along some segments of the Galapagos spreading center is a direct consequence of the propagation (elongation) of these segments into older oceanic crust. With increasing distance behind propagating rift tips, relatively unfractionated MORB erupted close to the tips are joined first by FeTi basalts (bimodal assemblage) and then by a wide range of basaltic and siliceous lavas. Further behind propagating rift tips, this broad range diminishes again, approaching the narrow compositional range of adjacent normal ridge segments. These compositional variations reflect the evolution of the subaxial magmatic system beneath the newly forming spreading center as it propagates through a pre-existing plate. We envisage this evolution as proceeding from small, isolated, ephemeral magma chambers through increasing numbers of larger, increasingly interconnected chambers to the steady-state buffered system of a normal ridge. Throughout this evolution, magma supply rates gradually increase and cooling rates of crustal magma bodies decrease. High degrees of crystal fractionation are favored only when a delicate balance between cooling rate and resupply rate of primitive magma is achieved. At other propagating and non-propagating ridge-transform intersections the degree to which the balance is achieved and the length of ridge over which it evolves control the distribution of fractionated lavas. These effects may be evaluated provided a number of tectonic variables including transform length, spreading and propagation rates are taken into account.

Description: The southernmost part of the Sohm Abyssal Plain in the Northwest Atlantic Basin is geographically distal with respect to the major source of Quaternary terrigenous material transported from the Canadian Maritime Provinces. An assessment of the proportion of more locally introduced sediment relative to that derived from distal sources is based largely on size and compositional analyses of Quaternary piston core samples. These data are supplemented by radiocarbon dating of selected core samples, bottom photographs, conductivity-temperature-depth profiles, and seismic records. The premises of the study are that (a) locally derived sediment should be most abundant near high-relief bathymetric features such as seamounts and abyssal hills, and (b) such material should contain enhanced proportions of reworked volcanic debris and alteration products. Core analyses reveal that the amounts of these are directly related to proximity of volcanic ocean-bottom features, and that a significant, although not total, amount of such volcanic materials recovered from cores are derived from submarine weathering of basalt. Associated with this assemblage are nannofossils, dating from the Quaternary to the Upper Cretaceous, reworked from older strata. This increased proportion of volcanic and related products and reworked faunas near seamounts and basement rises strongly implies that such topographic features continue to serve as major source terrains. Locally derived volcanic materials, however, are usually disseminated and masked on the Sohm Abyssal Plain, particularly in sectors receiving large amounts of terrigenous turbidites and biogenic suspensates, and/or undergoing reworking by bottom currents. We propose that the volcanic fraction can serve as a useful index, or "yardstick," to interpret the role of locally derived material in abyssal plain sedimentation. A sedimentation model is developed to illustrate the premise that as access to land-derived sources diminishes, the proportion of terrigenous components is reduced while pelagic and volcanic fractions are enhanced. Thus, sediment accumulating in abyssal plains almost totally isolated from terrigenous sources would comprise significant amounts of pelagic (including wind-blown) and volcanic components.

Description: Fossil Mn nodules of Cretaceous age from western Timor exhibit chemical, structural and radioisotope compositions consistent with their being of deep-sea origin. These nodules show characteristics similar to nodules now found at depths of 3,500-5,000 m in the Pacific and Indian Oceans. Slight differences in the fine structure and chemistry of these nodules and modern deep-sea nodules are attributed to diagenetic alteration after uplift of enclosing sediments.

Description: Nine nodules collected from throughout the deep North Pacific were analyzed for their mineralogy and major-element composition before and after leaching with Chester-Hughes solution. Data indicate that the mineral phillipsite accounts for the major part (〉 75%) of the aluminosilicate fraction of all nodules. It is suggested that formation of phillipsite takes place on growing nodule surfaces coupled with the oxidation of absorbed manganous ion. All the nodules could be described as ternary mixtures of amorphous iron fraction (Fe-Ti-P), manganese oxide fraction (Mn-Mg Cu-Ni), and phillipsite fraction (Al-Si-K-Na), these fractions accounting for 96% of the variability of the chemical composition.

Description: Manganese nodules are considered to have accumulated in general very slowly: surface layers of nodules contain a large excess of 230Th, more than would be produced by uranium decay. The decrease of excess 230Th with depth within a nodule is generally interpreted to be due to the radioactive decay, and nodule accumulation rates were then estimated from this to be a few mm/Myr. How then do these nodules escape from burial by associated marine sediments which accumulate 3 orders of magnitude faster than the nodules? One possible explanation is that the radionuclides of interest were not incorporated in the nodule matrix during its growth but were adsorbed later. Subsequent inward diffusion of the radionuclides might result in an apparent radioactive decay. We have tested this hypothesis by measuring simultaneously two radionuclides of different half lives. If the gradients of the radionuclides are really due to the radioactive decay, then, assuming a constant growth rate for a nodule, we expect the profile of the shortlived nuclide to be steeper (because of its faster decay) than that of the longlived nuclide.

Description: Crusts composed of nontronite and ferromanganese oxides were recovered from Explorer Ridge, a spreading ridge segment in the northeastern Pacific Ocean located off the west coast of Canada. The chemical and mineralogical composition of the crusts closely resembles that of the mound-like hydrothermal deposits recently discovered at the FAMOUS site on the Mid-Atlantic Ridge and on the Galapagos spreading centre. Compositional anomalies suggest that the crusts are precipitates of hydrothermal vent solutions which were ejected discontinuously and subsequently mixed with seawater.

Description: Submersible exploration on the eastern Pacific Ridge near 21 ° N has revealed an active hydrothermal system. It is manifested by the emission in the marine environment of hot and Highly mineralized fluids (370 ° C maximum). These fluids precipitate on contact with seawater and deposits of massive sulphides are built at the outlet of their sources. The mineralogical and geochemical study of the products associated with the emissions of hot fluids provides an initial evaluation of this type of deposit and leads to a comparison between the hydrothermalism responsible for the formation of sulphides and the hydrothermalism responsible for the formation of metal rich crusts formed of iron smectites and manganese oxides. This study is carried out with conventional mineralogical and geochemical investigations (optical and electronic microscopy, X-ray diffraction, X-ray fluorescence spectrometry, electron microprobe, neutron activation and mass spectrometry).

Description: In 1972, the Sea Scope Expedition was commissioned by Hughes Tool Company and carried out by Global Marine Development, Inc. The object was to gather detailed information on manganese nodules, including distribution, metallic content, methods of recovery, and sea floor bathymetry in noduliferous areas. Five of six planned cruise legs were successful. The resulting report is divided into three sections.

Description: The purpose of this volume, the eighth in a series of similar publications (Goodell, 1964, 1965, 1968; Frakes 1971, 1973 ; Cassidy et al., 1977a, 1977b), is to continue a presentation to the research community of sediment core descriptions and attendant data of cored and otherwise obtained sediments retrieved in waters of the Southern Ocean aboard the research vessel, ARA Islas Orcadas (formerly, USNS Eltanin), as a part of the circumpolar survey begun by Eltanin in 1962 (see issue of Antarctic Journal of the United States, Vol. 8, No. 3, 1973). The data presented herein are concerned with the results of coring activities aboard cruise 1176 of Islas Orcadas, the second marine geology coring cruise of this vessel under the terms of the present United States-Argentine agreement. The core descriptions are organised as follows: 1) a brief summary of the coring objectives of the cruise, together with a discussion of core recovery; 2) a table and map of station location data for materials retrieved; 3) a table of tentative age-dates for each piston core; 4) an explanation of the laboratory procedures and descriptive criteria used in the description of the sediments, and 5) lithologic descriptions of the piston and trigger cores, and the piston and trigger core bag samples.

Description: The purpose of this volume, the seventh in a series of similar publications (Goodell, 1964, 1965, 1968; Frakes 1971, 1973 ; Cassidy et al., 1977), is to continue a presentation to the research community of sediment core descriptions and attendant data of cored and otherwise obtained sediments retrieved in waters of the Southern Ocean aboard the research vessel, ARA Islas Orcadas (formerly, USNS Eltanin), as a part of the circumpolar survey begun by Eltanin in 1962 (see issue of Antarctic Journal of the United States, Vol. 8, No. 3, 1973). The data presented herein are concerned with the results of coring activities aboard cruise 0775 of Islas Orcadas, the second marine geology coring cruise of this vessel under the terms of the present United States-Argentine agreement. The core descriptions are organised as follows: 1) a brief summary of the coring objectives of the cruise, together with a discussion of core recovery; 2) a table and map of station location data for materials retrieved; 3) a table of tentative age-dates for each piston core; 4) an explanation of the laboratory procedures and descriptive criteria used in the description of the sediments, and 5) lithologic descriptions of the piston and trigger cores, and the piston and trigger core bag samples.

Description: Chemical analyses of manganese nodules from the Central Pacific Basin show that their chemical composition varies regionally, although that of the associated sediments is markedly uniform throughout the basin. Mn content varies from 16 to 32% in average. Its higher value is generally found in nodules from siliceous clay and a few from deep-sea clay. Fe content tends to enrich in nodules from deep-sea clay area. Most manganese nodules, except those from deep-sea clay, are remarkably depleted in Fe compared with ones from the other Pacific regions. Mostly, Cu and Ni contents exceed 1% in nodules from siliceous clay, and decrease towards the northwest of the basin where deep-sea clay is distributed. The inter-element relationship between manganese nodules and associated sediments suggests that the mechanism of incorporation of major and minor elements in nodules is apparently different from that of the associated sediments. This finding seems to provide a new interpretation on the problem why manganese nodules having low accumulation rate are not buried by the associated sediments with greater sedimentation rate and then occur on sediment-seawater interface.

Description: The sulfide deposit at Site 471 occurs between overlying pelagic sediment and underlying basalt. The deposit is vertically zoned and consists, from top to bottom, of the following mineral assemblages: (1) pyrite, chalcopyrite, and Zn-sulfide in chert and calcite gangue (~ 35 cm thick); (2) a 5-cm-thick metalliferous sediment layer and (3) a 4-cm-thick chert layer. The calcite gangue appears at a later stage than chert gangue in the sequence of deposition, also filling in voids and fractures. The manganese content of calcite is particularly high and varies systematically, reaching a maximum at the top of the massive sulfide portion of the deposit.

Description: Elevated regions in the central parts of ocean basins are excellent for study of accumulation of eolian material. The mass-accumulation rates of this sediment component appear to reflect changes in the influx of volcanic materials through the Early Cretaceous to Recent history of Deep Sea Drilling Project Site 463, on the Mid-Pacific Mountains. Four distinct episodes of eolian accumulation occurred during the Cretaceous: two periods of moderate accumulation, averaging about 0.2 to 0.3 g/cm**2/10**3 yr, 67 to 70.5 m.y. ago and 91 to 108 m.y. ago; a period of low accumulation, approximately 0.03 g/cm**2/10**3 yr, 70.5 to 90 m.y. ago; and a period of high accumulation, about 0.9 g/cm**2/10**3 yr, 109 to 117 m.y. ago (bottom of the hole). Much of the Cenozoic section is missing from Site 463. Upper Miocene to Recent sediments record an upward increase in accumulation rates, from less than 0.01 to about 0.044 g/cm**2/10**3 yr. The late Pliocene-Pleistocene peak may reflect the change to glacial-wind regimes, as well as an increase in volcanic source materials.

Description: Ash layers from Deep Sea Drilling Project site 178 in the northeast Pacific Ocean have been dated by the 40Ar-39Ar stepwise heating technique to resolve published discrepancies concerning the length of time explosive volcanism has affected the eastern Aleutian arc and Alaskan Peninsula. The results of the investigation indicate that the record of ash-fall deposition at site 178 extends back at least 6.5 m.y. Assuming that 6.5 m.y. ago marks the onset of renewed calc-alkalic volcanism of the volcanic arc, proposed models of continuous and discontinuous motion between the Pacific and North American lithospheric plates can be evaluated. If appreciable time elapsed between the onset of subduction and the onset of arc volcanism, the 6.5-m.y. record of ash-fall deposition in the north-east Pacific is most compatible with models of continuous plate motion throughout late Cenozoic time.

Description: Neogene palynofloras of southern California have been all too infrequently studied. Previous investigations of Pacific Coast sediments have been largely restricted to Pacific Northwest locales. Some important studies include those by Gray (1964), Wolfe, Hopkins, and Leopold (1966), Wolfe and Leopold (1967), Hopkins (1968), Piel (1969, 1977), Ballog, Sparks, and Waloweek (1972), and Musich (1973). The only published study of southern California materials is that of Heusser (1978) on Holocene sediments of the Santa Barbara basin. Most of these studies are concerned with the microflora from a particular formation; thus they have limited stratigraphic value and in most cases involve nonmarine to marginal marine rocks where no planktonic zonation was available. Musich's (1973) study was the first attempt at tying pollen assemblages to a planktonic zonation over an extended stratigraphic interval (Miocene to Pleistocene).Its location in the southern California Borderland and the sedimentary sections sampled make Leg 63 extremely valuable in deciphering the palynologic history of the Pacific Coast Neogene. Site 467 was chosen for our initial detailed study, because the relatively slow sedimentation rate provides an almost complete Neogene sequence of mainly terrigenous sediments and reliable planktonic age control is available.The goals of this study were to: (1) establish a reference section of Neogene palynomorph assemblages; (2) develop biostratigraphic criteria for use in correlation with other localities; (3) correlate the palynologic assemblages with the planktonic zonations; and (4) study the paleoenvironmental history in the southern California Neogene.

Description: The cores and dredges described at this site were taken on the SAFARI II cruise from 21 July until 1 September 1981 by the MusÈum National d'Histoire Naturelle from the R/V Marion Dufresne. A total of 65 cores, dredges and camera stations were recovered and are available at MNHN for sampling and study.

Description: Various manganese nodules donated to the Scripps Institution of Oceanography from the Hakurei Maru Cruise GH77-1, January-March, 1977, in the Central Pacific Basin have been analysed for their lithium content by J. Korkish from the Institute of Analytical Chemistry, Analysis of Nuclear Raw Materials Division, University of Vienna, Austria. The author has used a Perkin-Elmer atomic-absorption spectrometer 303 after speration by dissolution in hydrochloric acid.

Description: New information on possible resource value of sea floor manganese nodule deposits in the eastern north Pacific has been obtained by a study of records and collections of the 1972 Sea Scope Expedition. Nodule abundance (percent of sea floor covered) varies greatly, according to photographs from eight stations and data from other sources. All estimates considered reliable are plotted on a map of the region. Similar maps show the average content of Ni, Cu, Mn and Co at 89 stations from which three or more nodules were analyzed. Variations in nodule metal content at each station are shown graphically in an appendix, where data on nodule sizes are also given. Results of new analyses of 420 nodules from 93 stations for mn, fe, ni, cu, CO, and zn are listed in another appendix. Relatively high Ni + Cu content is restricted chiefly to four groups of stations in the equatorial region, where group averages are 1.86, 1.99, 2.47, and 2.55 weight-percent. Prepared for United States Department of the Interior, Bureau of Mines. Grant no. GO284008-02-MAS. - NTIS PB82-142571.

Description: Deep-sea sediment cores from Scripps Institution of Oceanography's ANTIPODE Expedition were described to identify visually distinct units based on color, texture, or other feature, sedimentary structures, lithology and abundance of component grains, and paleontology. Sixty-eight cores were examined, of which 34 are large diameter piston cores. Photographs and graphic lithology legs are included as PLATES 1-48. ANTIPODE Expedition recovered cores from: the Monterey-Ascension Fan, the Northeast Pacific, the Aleutians, the Northwest Pacific, the Philippine Sea, Indonesia, the Tonga Ridge, the Seychelles, Chagos Archipelago, the Mid-Indian Ridge, the Bay of Bengal, near Sumatra, and near the Cocos Island in the Indian Ocean. The purpose of this report is to present sufficient basic data on ANTIPODE cores for invesiigators to choose samples for their own research.

Description: Basal metalliferous sediments from sites 77B, 80 and 81 of the Deep Sea Drilling Project represent mixtures of pelagic clay, biogenic ooze, and a metalliferous component of hydrothermal origin. The metalliferous end-member of the sediments displays a strong inverse relationship (r = -0.88) between Mg and Mn. Mg is most likely tied up in an X-ray amorphous Mg-silicate ("sepiolite"), whereas Mn occurs almost exclusively in an oxide phase. Precipitation of the Mg-rich phase is favored by high flow rates and limited mixing of the hydrothermal end-member (source of silica) with seawater (source of Mg). Under those conditions much of the hydrothermal Mn(2+), with its slow oxidation kinetics, may escape to the free water column. In contrast, in highly-diluted hydrothermal fluids, which provide a source solution for Mn-rich sediments, dissolved silica is diluted below saturation with respect to "sepiolite". The separation of the Mn and Mg phases may be further compounded by hydraulic fractionation.

Description: We report here chemical analyses of sulfide and other minerals occurring in the massive sulfide deposit cored at Site 471. Details of the mineralogy and inferred paragenesis of the deposit will be reported elsewhere. The sulfide deposit at Site 471 occurs between overlying pelagic sediment and underlying basalt. The deposit is vertically zoned and consists, from top to bottom, of the following mineral assemblages: (1) pyrite, chalcopyrite, and Zn-sulfide in chert and calcite gangue (about 35 cm thick); (2) a 5-cm-thick metalliferous sediment layer described in detail by Leinen (this volume); and (3) a 4-cm-thick chert layer. The overlying sediment is a calcareous silty claystone that contains middle Miocene coccoliths (Bukry, this volume). The underlying basalt has been extensively chloritized and veined with calcite. In places feldspars are albitized, and calcite occurs as pseudomorphs after olivine. Relict textures suggest that the basalt grades into diabase and gabbro with increasing depth. Neither stock work nor disseminated sulfides was observed in the altered rocks.

Description: The investigation of the sediments at the bottom of a lake provides a record of past geologic and climatic events that have influenced the lake and its associated drainage basin. The most recent sediments of a lake are indicators of man's impact on the surrounding watershed and emphasize the complex nature of interaction between chemical, biological, and physical processes that affect the distribution of sediments and their associated minerals and chemical species. The conclusions of this report are based on samples and measurements obtained during an extensive research cruise conducted in Lake Michigan by the Canada Survey Ship Limnos in August, 1975. Grab samples were collected at the intersections of a 12-by-12-km Universal Transverse Mercator (UTM) grid over most of the lake bottom; a more detailed 7-by-7-km UTM grid was used in Green Bay and in the northeastern corner of the lake. Systematic chemical analysis was performed on the sediment samples over 23 elements. In Green Bay, elevated levels of a number of chemical elements in the sediments - notably arsenic, barium, manganese, and iron - suggest that a local geochemical process or source is important. One possible explanation is that ferromanganese nodules or concretions were observed in surface sediments from a number of locations in Green Bay and extreme northwestern Lake Michigan.

Description: Legacy product - no abstract available

Description: Chemical analyses of manganese nodules from the Central Pacific Basin show that their chemical composition varies regionally, although that of the associated sediments is markedly uniform throughout the basin. Mn content varies from 16 to 32% in average. Its higher value is generally found in nodules from siliceous clay and a few from deep-sea clay. Fe content tends to enrich in nodules from deep-sea clay area. Most manganese nodules, except those from deep-sea clay, are remarkably depleted in Fe compared with ones from the other Pacific regions. Mostly, Cu and Ni contents exceed 1% in nodules from siliceous clay, and decrease towards the northwest of the basin where deep-sea clay is distributed. The inter-element relationship between manganese nodules and associated sediments suggests that the mechanism of incorporation of major and minor elements in nodules is apparently different from that of the associated sediments. This finding seems to provide a new interpretation on the problem why manganese nodules having low accumulation rate are not buried by the associated sediments with greater sedimentation rate and then occur on sediment-seawater interface.

Description: Data from the Appendix to the PhD Thesis of the author.