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  • Polymer and Materials Science  (3,492)
  • 1980-1984  (3,049)
  • 1950-1954  (443)
  • 1981  (3,049)
  • 1953  (443)
Collection
Publisher
Years
  • 1980-1984  (3,049)
  • 1950-1954  (443)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 2-4 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The Prevention of Corrosion by Dehydration of the AtmosphereThe rusting of machine elements and parts and the formation of mildew on walls and ceilings is due to an excess of moisture in the surrounding air. Hence, in locations where, as a results of the process being carried out, large quantities of stream or vapour escape into the air surrounding the equipment, the consequent disadvantages can only be mitigated by the use of a suitably designed air dehydration plant. Enamelling of machinery, ceilings or walls is only a partial solution to the problem. The basic theoretical principles of air dehydration are then discussed, and some practical applications of these principles given. The introduction of warm air and the extraction of moist air are always necessary. The quantities and temperature of the incoming air, as well as the amount of heat required, are regulated by local conditions. Some numerical problems in the calculation of the individual values are solved by the use of an i-x diagram for moist air.
    Notes: Rosten von Maschinenenteilen und Schimmelbildung an Wäden und Decken ist eine Folge zu hoher Luftfeuchtigkeit. Deshalb können dort, wo durch den Arbeitsprozesse größere Dampf-bzw. Schwadenmengen in den Raum gelangen, die Übelstände nur durch eine zweckentsprechende Entnebelungsanlage behoben werden. Lackierungen von Maschinen, Decken oder Wänden bringen nur Teilerfolge. Nachfolgend werden die theoretischen Grundlagen der Entnebelung behandelt und im Anschluß daran an praktischen Beispielen deren zweckmäßige Durchführung. Stets ist die Zuführung von Warmluft und die Abführung von Feuchtluft erforderlich, wobei sich die notwendigen Lufttemperaturen und Mengen sowie die aufzuwendende Wärme nach den betrieblichen Gegebenheiten richten. An Zahlenbeispielen wird unter Benutzung eines i-x-Diagrammes für feuchte Luft die Berechnung der einzelnen Größen gezeigt.
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  • 2
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 48-48 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 3
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 119-119 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 4
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 20-21 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 5
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 1-1 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 6
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 4-14 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The Influence of Impurities on the Resistance to Corrosion of Aluminium and its AlloysIt may be deduced generally from the present experiments that the resistance to corrosion of the metal. The influence of impurities is determined by the type of corrosive medium to which the metal is subjected, and, frequently, the failure of aluminium may be due more often to the influence of operating or other exterior conditions than to impurities in the metal itself.As a result of the examination of the tendencies to corrosion due to the individual impurities and small additions of foreign elements, it has been found that iron and copper exercise a harmful effect, although the effect of the iron can be greatly reduced by the addition of manganese. Silicon in solid solution is absolutely harmless, but when it is eliminated in elementary form, the powers of resistance of aluminium are reduced. Suitable heat treatment enables up to 0,5% Si. to be retained in solid solution. According to the latest investigations, the proportion of Fe. to Si. does not appear to be of particular importance to the resistance of aluminium to corrosion. Magnesium, lead, zinc and titanium in the amounts usually present in aluminum are harmless, but nickel is always injurious. Calcium and sodium, which often appear as impurities in aluminium obtained from certain ores, also influence the resistance to corrosion.The final conclusions obtained from the date on the influence of the addition of small quantities of other elements are, in most cases, not given, as the observations and results have mostly been obtained form single experiments, and, hence, do not offer sufficient material for the formation of conclusions that might be of practical value.
    Notes: Auf Grund der vorliegenden Versuchsergebnisse kann ganz allgemein gefolgert werden, daß der Korrosionswiderstand von Reinaluminium mit steigendem Reinheitsgrad zunimmt. Der Einfluß der Verunreinigungen wird bestimmt von der Art des Korrosionsmediums und oft wird das Versagen von Aluminium mehr auf die Einflüsse der vorliegenden Betriebsbedingungen bzw. seiner Umgebung als auf den der Verunreinigungen selbst zurückzuführen sein.Bei der Betrachtung der einzelnen Verunreinigungen und geringen Zusätze an fremden Elementen hinsichtlich ihrer Korrosionsbeeinflussung ergibt sich, daß Eisen und Kupfer einen schädlichen Einfluß ausüben, wobei jedoch die Wirkung des Eisens durch Zugabe von Mangan stark verringert werden kann. Silizium ist in fester Lösung völlig unschädlich, in elementarer Form ausgeschieden verringert es die Beständigkeit des Aluminium. Durch geeignete Wärmebehandlung gelingt es jedoch, bis zu 0,5% Si in fester Lösung zu halten. Das Verhältnis Fe:Si scheint nach den neueren Auffassungen für das Korrosionsverhalten von Aluminium nicht von besonderer Wichtigkeit zu sein. Magnesium, Zink, Blei und Titan sind in Gehalten, wie sie üblicherweise im Aluminium vorkommen, unschädlich, dagegen ist Nickel in jedem Falle schädlich. Auch Calcium und Natrium, die oftmals in aus bestimmten Erzen hergestelltem Aluminium als Verunreinigungen auftreten, beeinträchtigen dessen Korrosionsbeständigkeit.Bei den Angaben über den Einfluß von geringen Zusätzen weniger üblicher Elemente werden die daraus gezogenen Schlußfolgerungen in den meisten Fällen nicht wiedergeben, da die Beobachtungen überwiegend bei Einzelversuchen gemacht worden sind und demzufolge zu wenig Beweismaterial bieten für endgültige Rückschlüsse, die für die Praxis von Bedeutung sein könnten.
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  • 7
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 33-37 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 8
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 47-47 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 9
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 113-117 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 10
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 47-47 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 11
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 48-48 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 12
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 48-48 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 13
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 48-48 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 14
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 247-248 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The Protective Action of cement against RustOf the various types od cements and concretes to be found on the market, Portland cement mixed with trass, pumice concrete and gypseous slag cement are particularly favourable to the formation of rust. The protective value of these building materials depends more on their pH value than on the thickness of the setting. Concrete for use in steel constructional work must normally contain a minimum of 30 Kgs of cement per cubic metre. The “Provisional” protection of the metal against rust by the application of a thin coating of cement slurry has not always proved successful, particularly in cases where a high degree of exposure was encountered. It would appear that a priming coat of red lead is to be recommended. Experience has proved that a coat of the cheaper variety of red lead known as “V 40” without the application of any additional coats of anti-corrosive paint, will protect the metal for periods of four and a half removed by the use of an autogenous burner.
    Notes: Unter den Handelssorten des Zements und Betons sind mit Traß versetzter Portlandzement, Bimsbeton und Gipsschlackenzement besonders zur chemischen Rostumwandlung befähigt. Der Schutzwert dieser Baustroffe wird mehr von ihrem pH-Wert als von der Dicke der Einbettung beeinflußt. Im Stahlbau verwendeter Beton muß in der Regel mindestens 300kg/m3 Zement enthateln. Der „ vorläufige“ Rostschutz durch Aufbringen dünner Zementschlämme hat sich in Fällen höherer Beanspruchung nicht durchweg bewährt. Es erscheint sodann eine einmalige Grundierung mit Bleimennige empfehlenswert, deren billigere Beisorte “V 40” das Eissen erwiesenermaßen auch ohne schützenden Deckanstrich 4½ Jahre und länger gegen Rostbildung zu schützen vermag. Alte Anstriche werden vor dem Einbetonieren am besten mit autogenen Flammstrahlern entfernt.
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  • 15
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    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 81-86 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: On the “Sweating” of paper and its effect on Iron Goods packed in such PapersWhen paper is stored in the usual storage cellars, it can contain considerable quantities of water (e.g. 10%) this water content can lead to the formation of “sweat” at corresponding temperature changes. This, in turn can lead to iron goods packed in such paper rusting. A series of test investigated the formation of “sweat” under varying conditions. In order to reduce the formation of rust from this cause it is recommended that only paper that has been stored “dry” (i.e. at less than 65% relative humidity ) should be used for packing iron goods.
    Notes: Papier kann bei Lagerung in normalen Lagerkellern erhebliche Mengen lose gebundenen Wassers (Z.b. 10%) enthalten Dieser Wassergehalt kann bei entsprechenden Temperaturschwankungen zur Bildung von Schwitzwasser führen, wodurch die Gefahr der Verrostung verpackter eiserner Gegenstände stark erhöht wird. In einer Reihe von Versuchen wird die Abhängigkeit dieser Schwitzwasserbildung von den einzelnen Umständen näher verfolgt. Zur Herabsetzung der Verrostungsgefahr wird empfohlen für die Verpackung eiserner Gegenstände Papier zu verwenden, dass möglichst trocken (z. B. bei weniger als 65% relativer Luftfeuchtigkeit) gelagert hat.
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  • 16
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 107-109 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 17
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 112-113 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953) 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 19
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 374-376 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 386-386 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 21
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 394-394 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 193-193 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 199-199 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. I 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 387-387 
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    Keywords: Chemistry ; Polymer and Materials Science
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    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 426-426 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 234-234 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 235-236 
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 240-240 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 426-426 
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 426-426 
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 474-474 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 475-475 
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 475-475 
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 475-475 
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 394-394 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 396-396 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 397-399 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Description / Table of Contents: Heat-resisting Materials and CermetsCommencing with one or two historical facts, the article continues with a brief survey of the methods, such as silifications, are patterned on the Sherardisation process. The special alloys often contain Ni, Cr, Co, Mo and W. The latest materials, the cermets, occupy a place midway between ceramic materials and metals, and combine the advantageous qualities of both groups in such a way that they stil afford protection at temperatures in excess of 1,000°C.
    Notes: Ausgehend von einigen historischen Angaben wird ein Überblick über die Fabrikation hochhitzebeständiger Werkstoffe gegeben. Die einschlägigen Diffusionsmethoden, die Inkromierung und Silicierung knüpfen dabei an das Vorbild des Sherardisierens an. Die Sonderlegierungen enthalten vielfach Ni, Cr, Co, Mo, W usw. Die neuesten Werkstoffe, die Cermets, stehen zwischen den keramischen Massen und Metallen und verknüpfen die vorteilhaften Eigenschaften beider so wirksam, daß sie noch bei ü 1000°C Schutz gewähren.
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 413-421 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 423-424 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 426-426 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 428-428 
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 334-334 
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953) 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 442-446 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Description / Table of Contents: Artifical Resins and Body TissuesThe article opens with a brief description of the irritational effects (corrosion, electrolysis, etc.), of metals entering and remaining in the human body, either, as a result of surgical treatment or accidently. The cause and effect of the irritation set up by foreign bodies is then discussed.It has been found that, in actual practice, there are artifical resins which have no effect upon human tissue. They must be chemically stable, cause no irritation of a mechanical nature and must have the physical properties of an insulator.When artifical resins are required to function statically in the human body, certain peculiar difficulties arise, which are due to the physical and chemical properties of the resin. These difficulties are described in detail.It is fact that artifical resin manufactures have not yet been able to produce a resin of a “universal” nature, which can be used as a statically functioning substitute for bones and bony structures.At the moment it would appear possible for manufacturers to produces an artifical resin which has no irritational effects and yet has no irritational mechanical strength.
    Notes: Nachdem die Metalle, welche operativ oder aus Zufall in den Körper gelangen und dort verbleiben, in der Möglichkeit ihrer Gewebereizwirkung (Korrosion, Elektrolyse) kurz behandelt wurden, wird auf die Ursache und die Wirkung der Fremdkörperreize eingegangen.Es hat sich in der Praxis bestätigt, daß es Kunstharze gibt, die keine Gewebereize ausüben. Sie müssen physikalisch einen Isolator darstellen, chemisch stabil und mechanisch reizlos sein.Bei der Übernahme statischer Funktionen innerhalb des Körpers treten bei Kunstharzen durch die ihnen eigentümlichen Eigenschaften Schwierigkeiten auf, auf welche näher eingegangen wird.Es zeigt sich, daß die relative junge Kunstharzindustrie noch kein Universalmaterial schaffen konnte, welches in allen Fällen geeignet ist, statisch funktionstüchtig als Knochenersatz verwendet zu werden.Für die Zukunft erscheint es glaubhaft, daß Kunstharze durch die Industrie erstellt werden können, die sowohl reizlos sind, wie auch in ihrer Festigkeit ausreichend sein dürften.
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 458-461 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 468-473 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 273-280 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Description / Table of Contents: The Corrosion Effects of Varying Concentrations of Nitric and Sulphuric Acids upon Welds on Aluminium and its AlloysThe action of sulphuric and nitric acids upon welded joints on aluminium and various aluminium alloys was examined. Low concentrations of sulphuric acid act first of all on the welded seam of all aluminium materials in use in industry. With higher concentrations, the effect is evenly distributed over the whole surface. Welded aluminium was shown to be highly resistant against concentrations of nitric acid varying between 1 and 65%. In the case of welded aluminium aloys, the welded seam was also the first to be acted on by medium concentrations of sulphuric acid. Welded joints made by the autogenous or the metal-arc processes do not show any great variation in their resistance to corrosion. Annealing or hammering the welds, as well as hammering followed by annealing, has, when made under the conditions obtaining during this examination, no effect upon the resistance to corrosion.
    Notes: Es wurde der Angriff von Schwefel und Salpetersäure auf Schweißverbindungen aus Reinaluminium und Aluminium-Legierungen untersucht. Schwefelsäure greift in den unteren Konzentrationsbereichen bei sämtlichen Aluminium-Werkstoffen bevorzugt die Schweißnähte an, während bei den oberen Konzentrationsgraden eine gleichmäßige Oberflächenabtragung auftritt. - Demgegenüber erwies sich geschweißtes Reinaluminium als praktisch beständig gegen 1 bis 65%ige Salpetersäure. Die geschweißten Aluminium-Legierungen erfuhren besonders bei den mittleren Konzentrationsgraden, durch Salpetersäure ebenfalls einen selektiven Angriff der Schweißnähte.-Die nach dem Autogen- bzw. Metalllichtbogen-Verfahren geschweißten Nähte zeigten keine wesentlichen Unterschiede in ihrer Korrosionsbeständigkeit, obwohl in der Angriffsform gewisse Differenzen bestehen. - Ein Nachglühen oder Hämmern der Schweißraupen sowie ein Hämmern mit anschließender Glühung ist bei den vorliegenden Angriffsbedingungen ohne jeden Einfluß auf das Korrosionsverhalten.
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 310-315 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 321-327 
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 347-347 
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 327-332 
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 332-334 
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    Materials and Corrosion/Werkstoffe und Korrosion 4 (1953), S. 336-338 
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981) 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 1-7 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Description / Table of Contents: Die Oxidation von 18/8 Stählen in Kohlendioxid + 2% Kohlenmonoxid bei hohem DruckDie Oxidation verschiedener 18/8 Stähle in Gemischen aus Kohlendioxid und 2% Kohlenmonoxid wurde im Temperaturbereich 550 bis 650°C durch intermittierende Messung der Gewichtszunahme, metallographische Untersuchung, Fraktographie und Rasterelektronenmikroskopie verfolgt. Schon in einem frühen Oxidationsstadium entsteht eine Duplex-Zunderschicht. Die Gewichtszunahme/Zeit-Kurven zeigen zwei Prozeßstufen, und zwar ein Anfangsstadium, das sich exponentiell dem zweiten langsameren Stadium annähert. Die Geschwindigkeit der Duplex-Zunderbildung zeigte nicht die übliche Temperaturabhängigkeit; indessen wurde bei etwa 600°C ein Maximum der Geschwindigkeit festgestellt. Die sekundären Verzunderungsgeschwindigkeiten waren bei 650 und 550°C deutlich zu erkennen und lagen bei der niedrigeren Temperatur höher. Im Zunder traten verschiedene Spinelle auf. Die erhaltenen Ergebnisse werden mit der Annahme gedeutet, daß Kationendiffusion durch verschiedene innere Spinelle der geschwindigkeitsbestimmende Schritt ist.
    Notes: The oxidation of a variety of 18/8 stainless steels in high pressure CO2/2% CO has been followed in the temperature range 550-650°C using intermittent weight gain measurement metallography, fractography and scanning electron microscopy. Duplex scales formed at an early stage of oxidation. The weight gain curves were analysed in terms of a two stage process, the initial stage exponentially approaching a slower secondary stage. The primary rate of duplex scale formation did not show the usual temperature dependence. Rather a maximum in the rate was observed at ∼600°C. Secondary rates were well established at 650°C and 550°C the secondary rate at 550°C, however, being higher than that at 650°C. Various spinels occurred and the results are explained in terms of the rate controlling process being cation diffusion through different inner spinels.
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 13-18 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Description / Table of Contents: Inhibitoren der passiven Korrosion - Anwendung einer neuen Untersuchungsmethode mit dünnen OxidschichtenEine neue Methode, Inhibitoren der passiven Korrosion zu untersuchen, wird vorgestellt. Potentiodynamische Stromspannungs- und Kapazitätskurven wurden im System Au/Fe2+ in Gegenwart von Inhibitoren aufgenommen. Veränderungen bei der Bildung und Reduktion des γ-FeOOH, des Goldoxids and bei der Sauerstoffentwicklung ermöglichen Aussagen über die Intensität und den Mechanismus der Inhibition.Vorzugsweise warden organische Stickstoffverbindungen untersucht. Pentylamin war ohne Einfluß auf oxidbedeckte Elektroden, während Benzimidazol und seine Derivate starke Inhibitionswirkung zeigten. Die Kapazitätsdaten lassen sich als Reihenschaltung der Kapazitäten von Oxid und Inhibitorschicht deuten. Die Inhibitionswirkung beruht wahrscheinlich auf einer Adsorption des Inhibitors an der Oxidoberfläche. Diese Adsorptionsschicht behindert den Durchtritt hydratisierter Ionen, ist aber ohne Einfluß auf Reaktionen adsorbierter Wassermoleküle, wie z. B. die Sauerstoffentwicklung.Die Anwendbarkeit der Untersuchungsmethode auf andere Systeme wird diskutiert.
    Notes: A new method to test the inhibitors of passive corrosion is presented. Potentiodynamic i(ε)- and C(ε)-curves are recorded in the system Au/Fe2+, inhibitor. The investigations of formation and reduction of the FeOOH-layer, of gold oxide and the oxygen evolution allow estimations of the inhibition efficiency and mechanism.Some organic nitrogencompounds are tested. Pentylamine is ineffective for oxide surfaces, but benzimidazole and its derivates show inhibition effects. The capacity data can be evaluated using a condensor model of a connection in series of the oxide and the inhibitor layer. The detailed discussion shows that adsorption at the film surface is most probable. Such layers inhibite the transfer of hydrated ions, but reactions of water molecules are not influenced, e.g. oxygen evolution.The applicability of this method to other systems is discussed.
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 7-12 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Einfluß von Werkstoffeigenschaften auf die Beständigkeit gegen Kavitation in FlüssigkeitenDie Wirkung der Kavitation in Flüssigkeiten auf die Bauteile von Strömungsmaschinen kann entweder durch aktive oder durch passive Maßnahmen ausgeschaltet werden. In der vorliegenden Arbeit werden Möglichkeiten zur Verringerung der Kavitationswirkung auf Werkstoffe mit Hilfe von passiven Methoden beschrieben. Dabei werden verschiedene Methoden zur Beschreibung des Erosionsverschleißes in Abhängigkeit von den Werkstoffeigenschaften erörtert. Anschließend wird ein mathematisches Modell entwickelt, bei welchem der Einfluß wichtiger mechanischer Eigenschaften auf das Erosionsverhalten gezeigt wird. Aus dem mathematischen Modell läßt sich die Beziehung zwischen der Kavitationsbeständigkeit eines Werkstoffs und seinen mechanischen Eigenschaften ableiten. Der Einfluß wichtiger Materialeigenschaften auf die Beständigkeit gegen Kavitation in Flüssigkeiten wird anhand dieses Modells erörtert.
    Notes: The influence of the liquid cavitation on the elements of fluid-flow machines can be removed in either an active or passive way. In this paper possibilities of reduction of the cavitation effect on the constructional materials in a passive way are described. Different methods of the material erosion wear description, depending on its properties, are discussed. A mathematical model, regarding the principal mechanical features of the material, is proposed. The mathematical model shows the relation between cavitation resistance of the material and its properties. The effect of principal properties of the material on its resistance on the liquid cavitation influence based on this model is discussed.
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 31-32 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 19-30 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Description / Table of Contents: Influence of phosphates and/or silicates on copper ion induced pitting of galvanized hot water tubingIn connection with studies on the copper-induced pitting of galvanized steel tubes the inhibition by phosphates and/or silicates should be investigated. The investigations were carried out in Berlin tap water, at temperatures of 65°C. Inhibitors used were o-phosphate, p-phosphate, combinations of o/p-phosphate and phosphate/silicate as well as two silicates.All these inhibitors reduced the general corrosion of galvanized steel and copper. Best results were obtained with p-phosphate. Protective layers on both metals were produced not before a time of 150-200 days.Number and depth of pits were positively influenced by nearly all the inhibitors used. But only the combination phosphate/silicate lead to a complete prevention from copper-induced pitting. O-phosphate showed the lowest efficiency.These investigations once again pointed to the importance of the phase boundaries air/water/tube or deposits/water/tube as nuclei for pitting in tubes.A second layer containing calcium and inhibitors was formed on the primary layer of zinc corrosion products. These secondary layers are responsible for corrosion protection by the inhibitors.
    Notes: Anschließend an Untersuchungen zum kupferinduzierten Lochfraß in verzinkten Rohren sollte geprüft werden, ob mittels der gesetzlich für die Nachaufbereitung von Trinkwässern zugelassenen Inhibitoren Phosphat und/oder Silikat eine positive Beeinflussung dieser in Mischinstallationen auftretenden Korrosionserscheinungen möglich ist. Die Versuche sind in Berliner Leitungswasser bei 65°C in einer Umlaufapparatur über eine Laufzeit von zwei Jahren durchgeführt worden. Dosiert wurden o-Phosphat, p-Phosphat, Mischungen aus o/p-Phosphat, zwei Silikate als Natronwasserglas sowie eine Mischung aus Silikat/Phosphat.Unter den gewählten Versuchsbedingungen wurde mit allen Inhibitoren eine Inhibition der Flächenkorrosion bei verzinktem Stahlrohr und Kupfer erzielt. Die besten Ergebnisse wurden mit Polyphosphat erreicht. Bei verzinktem Stahl und z. T. auch bei Kupfer bilden sich Schutzschichten erst nach 150-200 Tagen.Die kupferinduzierte Lochkorrosion wird zwar von den meisten Inhibitoren bezüglich Lochzahl und -tiefe günstig beeinflußt, eine vollständige Unterdrückung gelingt jedoch nur mit dem Gemisch Silikat/Phosphat. Orthophosphat hat die geringste Wirkung. Auch diese Arbeit zeigt die Bedeutung von Phasengrenzen wie Luft/Wasser/Rohr oder Ablagerungen/Wasser/Rohr als Keimbildner der Lochkorrosion.Inhibitoren und Calcium bilden auf der primären Deckschicht aus Zinkkorrosionsprodukten eine zweite, darüberliegende Schicht, deren Ausbildung für die Schutzwirkung des Inhibitors verantwortlich ist.Die Untersuchungen haben außerdem gezeigt, wie bedeutsam eine sachkundige und regelmäßige Wartung für die Funktionsfähigkeit einer Dosieranlage ist.
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 38-55 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 33-36 
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 56-56 
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 37-37 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 56-56 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. R23 
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. R24 
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981) 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. R26 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 57-65 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Corrosion behaviour of tantalum in hot hydrochloric acidOn account of its excellent resistance to corrosion and the high thermal conductivity tantalum is used in the chemical engineering industry. Used in hydrochloric acid at higher pressure and temperatures up to 200 °C localized embrittlements appeared, caused by a local increase of the hydrogen content. Loading tests in streaming hydrogen, by cathodic loading in different hydrochloric acid concentrations and different current densities as well as in the autoclave at 180 °C and hydrochloric acid concentrations up to 36% did not result in significant differences at electron beam melted or sintered material with different heat-treatments. Welding scams behaved analogous to the sheat-material, too. The electric conductivity shows a distinct dependance on the amount of hydrogen dissolved in the tantalum. To control a plant such measurements can be done on different tantalum parts to determine the amount of dissolved hydrogen.
    Notes: Tantal wird wegen seiner ausgezeichneten Korrosionsbeständigkeit und der hohen Wärmeleitfähigkeit im Chemieanlagenbau eingesetzt. Beim Einsatz in hochkonzentrierter Salzsäure bei höherem Druck und Temperaturen bis zu 200 °C zeigten sich örtlich begrenzte Versprödungserscheinungen, deren Ursache eine lokale Wasserstoffaufnahme war. Beladungsversuche im Wasserstoffstrom, durch kathodische Beladung in unterschiedlichen Salzsäurekonzentrationen und unterschiedlichen Stromdichten sowie im Autoklaven bei 180 °C und Salzsäurekonzentrationen bis 36% ergaben keine signifikanten Unterschiede bei elektronenstrahlgeschrnolzenem oder gesintertern Material unterschiedlicher Wärmebehandlung. Auch Schweißnähte verhielten sich analog zum Grundmaterial. Die elektrische Leitfähigkeit zeigt eine deutliche Abhängigkeit von der aufgenommenen Wasserstoffmenge. Zur Überwachung von Anlagen sind solche Messungen auch an Anlageteilen bei Stillstand der Anlage durchführbar.
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 66-72 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Investigations on the influence of microstructure of steels on steady state hydrogen permeationThe effect of microstructure of iron and of a low alloyed steel on steady state hydrogen permeation is studied by means of the electrochemical permeation method adapted to hydrogen gas phase charching at pH2 = 1 bar in the temperature range of 15 to 80 °C. In case of pure annealed iron the permeation coefficient is given by \documentclass{article}\pagestyle{empty}\begin{document}$$ \phi ^0 _{\rm H} ({\rm T}) = (2.57 \pm 0.48)10^{- 7} \exp \{- (34.32 \pm 0.42){\rm kJ/mol} \cdot {\rm RT}\} \,({\rm mol}\,{\rm H/cm} \cdot {\rm s} \cdot {\rm bar}^{{{\rm 1} \mathord{\left/ {\vphantom {{\rm 1} 2}} \right. \kern-\nulldelimiterspace} 2}}) $$\end{document} Impurities, oxide inclusions and a high density of lattice defects do not affect steady state hydrogen permeation remarkably. In steel specimens of different microstructure (pearlitic, martensitic, bainitic) hydrogen permeability is decreased by a factor 4 to 8. Carbide precipitates in tempered martensite do not change the permeation coefficient. Also cold deformation by rolling to about 15% shows no effect on steady state permeation. Cold rolling to about 40% or higher degrees decreases the steady state hydrogen flux considerably. In all cases, no essential change in temperature dependence is observed.
    Notes: Der Einfluß des Gefügezustandes des Eisens und eines niedriglegierten Stahls auf den stationären Wasserstoffdurchtritt wird mit Hilfe der elektrochemischen Permeationsmethode unter Wasserstoffaufnahme aus der Gasphase hci pH2 = 1 bar im Temperaturbereich von 15 bis 80 °C untersucht. Der Permeationskoeffizient des Wasserstoffs für reines rekristallisiertes Eisen läßt sich durch \documentclass{article}\pagestyle{empty}\begin{document}$$ \phi ^0 _{\rm H} ({\rm T}) = (2,57 \pm 0,48)10^{- 7} \exp \{- (34,32 \pm 0,42){\rm kJ/mol} \cdot {\rm RT}\} \,({\rm mol}\,{\rm H/cm} \cdot {\rm s} \cdot {\rm bar}^{{{\rm 1} \mathord{\left/ {\vphantom {{\rm 1} 2}} \right. \kern-\nulldelimiterspace} 2}}) $$\end{document} beschreiben. Verunreinigungen durch Fremdatome und oxidische Einschlüsse sowie eine hohe Gitterfehlerdichte haben im Eisen keinen merklichen Einfluß auf die stationäre Wasserstoffpermeation. Beim niedriglegierten Stahl liegt der Permeationskoeffizient je nach Gefügezustand (Perlit, Martensit, Bainit) urn den Faktor 4 bis 8 niedriger als beim Eisen. Karbidausscheidungen im angelassenen Martensit verändern die stationäre Permeationsstromdichte nicht. Eine geringe Kaltverformung urn 15% verursacht ebenfalls keine Änderung des stationären Permeationsstromes. Bei Verformungsgraden größer 40% wird der Wasserstoffdurchtritt stärker behindert. Eine deutliche Änderung der Temperaturabhängigkeit ist in allen Fällen nicht zu erkennen.
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 73-78 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Investigations on the influence of microstructure of steels on unsteady state hydrogen permeationThe effect of microstructure of iron and a low alloyed steel on hydrogen permeation at room temperature is studied by means of the electrochemical permeation method. Hydrogen transport through these materials during charging or effusion processes is affected by microstructural heterogeneities and hydrogen content. The diffusivity as a function of the state of the materials ranges over about five orders of magnitude. In course of non-steady state diffusion dislocations and interfaces decrease the effective diffusivity to values between 10-7 and 10-9 cm2/s. At steady state permeation the diffusivity reaches the values of 10-5 to 10-4 cm2/s.
    Notes: Der Einfluß des Gefügezustandes des Eisens und eines niedriglegierten Stahles auf die Wasserstoffpermeation bei Raumtemperatur wird mit Hilfe der elektrochemischen Permeationsmethode untersucht. Die Transportvorgänge im Werkstoff während der Wasserstoffbeladung oder -effusion werden durch die Gefügeelemente und den Wasserstoffgehalt beeinflußt. Die in Abhängigkeit vom Werkstoffzustand ermittelten Diffusionskoeffizienten überstreichen bis zu fünf Zehnerpotenzen. Bei instationärer Diffusion bewirken Versetzungen und Phasengrenzen einen Abfall des effektiven Diffusionskoeffizienten auf Werte zwischen 10-7 und 10-9 cm2/s. Bei stationärer Permeation werden Diffusionskoeffizienten zwischen 10-5 and 10-4 cm2/s erreicht.
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 104-112 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 92-104 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 85-91 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Longterm corrosion field tests with austenitic steels in the high pressure parts of a urea plantIn view of the conditions encountered in urea manufacture, in particular in the high pressure section the corrosion resistance is investigated using various austenitic steels immersed in reaction mixtures typical of urea manufacture. The specimens were placed in an operating plant; different test durations (total 13 000 hours) enable the time dependence of the attack to be assessed. The steels tested were CrNi steels with nitrogen and 17.45-19.8% Cr and 10.3-12% Ni, CrNiMo steels, some of them with Ti and Cu addition and 17% Cr and 20 and 13.8% Ni, respectively. According to the results the corrosion resistance increases with the chromium level while ferrite in particular with longer test durations has a pronounced negative effect. A suitable screening test for corrosion resistance under the conditions of urea manufacture is testing in boiling nitric acid.
    Notes: Im Hinblick auf die Verhältnisse in Harnstoffanlagen, vor allem für den Hochdruckteil, wird die Beständigkeit verschiedener austenitischer Stäble in den bei der Harnstoffsynthese auftretenden Reaktionsgemischen untersucht. Die Proben wurden dazu in Betriebsanlagen eingelegt, wobei durch unterschiedliche Beanspruchungsdauer (Gesamtdauer 13 000 Stunden) Aussagen über den zeitlichen Verlauf des Angriffs möglich waren. Bei den Stählen handelte es sich um CrNi-Stähle mit Stickstoffzusatz und 17,45 bis 19,8% Chrom sowie 10,3 bis 12% Nickel und um CrNiMo-Stähle, teilweise mit Stickstoffzusatz und 15 bis 19,7% Chrom and 11,2 bis 6,5% Nickel und schließlich um CrNiMo-Stähle mit Ti- und Cu-Zusatz sowie 17% Cr und 20 bzw. 13,8% Nickel. Aufgrund der Ergebnisse nimmt die Korrosionsbeständigkeit mit dem Chromgehalt zu, während Ferrit, besonders bei längerer Versuchsdauer, deutlich negative Wirkungen hat. Als Vorprüfung auf Beständigkeit unter den Bedingungen der Harnstoffherstellung eignet sich die Prüfung in siedender Salpetersäure.
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. R27 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 79-85 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Technical and economical evaluation of corrosion losses for steel structures in aggressive atmospheresThe paper contains a comparative survey of specific costs for procurement and maintenance of light to medium heavy steel structures protected by various coating systems (e.g. hot galvanizing with top coat renewed at regular intervals, sprayed aluminium coating with sealing coat). As an alternative the use of weathering steel is considered. In addition optimum protection variants are considered for atmospheres of defined aggressivities.
    Notes: Die Arbeit enthält einen Vergleich der spezifischen Kosten für die Anschaffung und die Instandhaltung von Stahlkonstruktionen (leicht bis mittelschwer), die mit verschiedenen Korrosionsschutzsystemen geschützt sind (z. B. Anstrichsysteme, Feuerverzinkung mit Deckanstrich, der in regelmäßigen Abständen erneuert wird, Aluminiumspritzüberzug mit Verdichtungsanstrich). Dazu wird als Alternative die Verwendung von langsamrostendem Stahl berücksichtigt. Ebenso wird auf optimale Schutzvarianten für Atmosphären definierter Aggressivität eingegangen.
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. R42 
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. R45 
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981) 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 113-118 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Description / Table of Contents: Solid corrosion products - II. Aluminium and ironThis review is concerned with the solid corrosion products of aluminium and iron which are formed in the atmosphere, in natural waters or in soils. It contains informations about the lattice type, forming conditions, solubility and morphology.
    Notes: Es wird eine Übersicht über die festen Korrosionsprodukte von Aluminium und Eisen gegeben. Es werden nur solche Verbindungen berücksichtigt, die sich an der Atmosphäre, in natürlichen Wässern oder im Erdboden bilden. Die Arbeit enthält Angaben über den Gittertyp, die Bildungsbedingungen, die Löslichkeit und über die Morphologie der Korrosionsprodukte.
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 119-128 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Einfluß des Oberflächenzustands auf die Auslösung von Spaltkorrosion an nichtrostenden StählenVorgelegt werden Ergebnisse von Lagerversuchen in natürlichem Meerwasser und im Laboratorium; dabei wurden Probenanordnungen mit Mehrfachspalten benutzt. Die Ergebnisse mit austenitischen und ferritisch-austenitischen Stählen verschiedener Oberflächenzustände zeigen, daß eine Behandlung mit Säure die Spaltkorrosionsbeständigkeit von geschliffenen Oberflächen beträchtlich verbessert. Beizen in verdünnter Schwefelsäure und Passivieren in Salpetersäure haben dabei praktisch den gleichen günstigen Effekt wie das übliche Beizen in Salpetersäure + Flußsäure. Die günstige Wirkung des passivierenden Beizens beruht auf der Entfernung der an der Oberfläche befindlichen Sulfideinschlüsse, die Keimstellen für Lochkorrosion bilden, die der Spaltkorrosion vorangeht. Die potentiodynamisch ermittelten Lochkorrosionspotentiale sowie die Ergebnisse von Versuchen in 10% FeCl3 · 6 H2O (ASTM G 48-76) zeigen schlechte Übereinstimmung mit den in Meerwasser erhaltenen Ergebnissen.
    Notes: Results from sea-water and laboratory exposure tests with multiple crevice assemblies are presented. The results from tests on austenitic and ferritic-austenitic stainless steel samples subjected to various surface treatments demonstrate that an acid treatment greatly improves the crevice corrosion resistance of previously ground surfaces. Pickling in dilute sulphuric acid and passivation in nitric acid has thereby virtually the same beneficial effect as the common nitric + hydrofluoric pickling acid. The beneficial effect of pickling and passivation is related to the removal from the surface of sulphide inclusions, being potential nucleation sites for the initiation of discrete pitting attacks preceding the onset of crevice corrosion. Potentiodynamically determined pitting potentials and results from testing in 10% FeCl3 · 6 H2O according to ASTM G 48-76 show poor correlation with results from sea-water exposures.
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    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 129-135 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: New method for the determination of pit growth kinetics - Results on aluminiumA new method to study the pit growth kinetics is proposed. On metal foils with an appropriate detecting system on the backside of the specimen the perforation time of a growing pit is easily measured. Using metal foils of different thicknesses the pit growth kinetics can be investigated for various metal/potential/environment-conditions.The results obtained on aluminium show that the pit growth rate is time dependent. It is also markedly influenced by the applied potential and the chloride concentration of the electrolyte. Furthermore pit growth limiting potentials have been determined by electrolyte exchange experiments for various chloride concentrations. Below them pit growth is not possible. Comparing these values with the potentiostatically determined pitting potentials it can be concluded that the pitting potentials of aluminium depend primarily on pit growth rather than on pit formation.
    Notes: Die in dieser Arbeit vorgeschlagene Untersuchungsmethode erlaubt es, die Lochwachstumskinetik bei allen Metallen, welche in Blechform erhältlich sind, unabhängig vom Elektrolyt und unter kontrollierten elektrochemischen Bedingungen zu studieren. Mit dem für diesen Zweck entwickelten Detektorsystem 1äßt sich jene Zeit genau erfassen, welche die Löcher benötigen, um eine bestimmte Blechdicke zu perforieren. Durch die Verwendung mehrerer Blechdicken sind Aussagen über die Wachstumskinetik möglich.Die Untersuchungen mit dieser Methodik an Aluminium haben gezeigt, daß die Lochwachstumsgeschwindigkeit bzw. die Lochstromdichte vom Potential, vgn., der Chloridkonzentration und vom Alter des Loches abhängig ist. Es konnte weiter mit Elektrolytaustauschexperimenten nachgewiesen werden, daß jeder Chloridkonzentration ein Lochwachstumspotential zugeordnet werden kann, unterhalb dem die Löcher nicht wachsen können. Der Vergleich des Lochwachstumspotentials mit dem potentiostatisch bestimmten Lochfraßpotential 1äßt den Schluß zu, daß bei Aluminium das Lochfraßpotential eher ein Lochwachstums- als ein Lochbildungspotential ist.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 99
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 138-140 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 100
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 32 (1981), S. 135-137 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Untersuchung von Acrylharz-Deckschichten mit Zusatz von Dibenzoylmethan zur Verbesserung des Korrosionsschutzes von C-haltigen Stählen unter der Bedingung des Kondensation-Feuchtigkeit-TestsDie physikalische Bindung zwischen einer organischen Schutzschicht und einer metallischen Oberfläche kann verstärkt werden, wenn chemische Wechselwirkungen auftreten. Dieser Effekt wird in dieser Arbeit durch Dibenzoylmethan erzielt, welches einer auf C-Stahl aufgetragenen Acryl-Harz-Schutzschicht zugesetzt wird. Die Wirkung beruht auf der Bildung eines Eisenkomplexes auf der Metalloberfläche und läßt sich durch den eindeutigen Anstieg der Korrosionsschutzwirkung im Kondensations-Feuchtigkeit-Test zeigen.
    Notes: The physical adhesion between organic coating film and metallic surface can be enhanced by chemical interactions. This effect is achieved in this work by dibenzoylmethane which is added to an acrylic resin solution for the coating of carbon steel surface, as demonstrated by the formation of the iron complex on the metallic surface and the significant increase in corrosion resistance of the coating film in a condensing humidity test.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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