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  • Chemistry  (3,899)
  • ddc:330
  • Limnology
  • General Chemistry
  • Cell & Developmental Biology
  • 2015-2019  (377)
  • 1945-1949  (4,111)
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  • 1
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2021-08-06
    Description: Mit fortschreitender Energiewende steigt der Anteil erneuerbarer Energien im Strommix. Deren Angebot variiert im Tagesverlauf, nach Wetterlage und saisonal. Um Angebot und Nachfrage zur Deckung zu bringen, benötigt es daher Speicher mit großen Kapazitäten. Von allen technologischen Optionen mit großer Speicherkapazität sind Wasser-Pumpspeicherwerke die einzige, die langjährig erprobt und wirtschaftlich ist. Diese könnten in Braunkohletagebauen, welche im Zuge der Energiewende aufgegeben werden, errichtet werden. Unsere Überschlagsrechnung am Beispiel eines Pumpspeicherwerks in den heutigen Tagebauen Hambach, Garzweiler und Inden zeigt, dass diese mit bis zu 400 GWh ein signifikantes technisches Speicherpotenzial haben. Dies entspricht etwa der kontinuierlichen Maximalleistung eines Kernkraftwerks über zwei Wochen. Im Kontext der Diskussion um den Braunkohleausstieg skizziert das Papier ein netzdienliches Nachnutzungskonzept für Braunkohletagebaue, das zumindest für einen Teil der heute in der Kohleförderung und -Verstromung Beschäftigten mögliche Zukunftsperspektiven bietet.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: workingpaper , doc-type:workingPaper
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  • 2
    Publication Date: 2019-08-07
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 3
    Publication Date: 2019-08-07
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: contributiontoperiodical , doc-type:contributionToPeriodical
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  • 4
    Publication Date: 2021-05-04
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: contributiontoperiodical , doc-type:contributionToPeriodical
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  • 5
    Publication Date: 2019-12-16
    Description: Die Dekarbonisierung des deutschen Wohngebäudebestandes stellt einen wichtigen Baustein zum Gelingen der Energiewende dar. Politisches Ziel ist ein "nahezu klima-neutraler" Gebäudebestand bis 2050. Trotz Erfolgen in der Vergangenheit und eines umfangreichen Policy-Mix verbleibt die energetische Sanierungstätigkeit sowohl hinichtlich der Sanierungstiefe als auch der Sanierungsbreite unterhalb des politisch geforderten und ökologisch notwendigen Maßes. Die Arbeit widmet sich daher der Frage, unter welchen individuellen und quartiersbezogenen Rahmenbedingungen Immobilieneigentümer energetische Sanierungsmaßnahmen durchführen und wie die energetische Sanierungstätigkeit durch Multi-Level-Governance gesteigert werden kann. Die Analyse erfolgt fallstudienbasiert für die Eigentümergruppe der privaten Kleinvermieter, die rund 37 Prozent des deutschen Wohnungsbestandes bewirtschaften. Anhand eines mixed method-Ansatzes wird zunächst durch problemzentrierte Interviews ein Modell zur Beschreibung des Investitionsentscheidungsprozesses entwickelt, was anschließend durch eine schriftlich-postalische Befragung und ihre regressions-analytische Auswertung bewertet wird. Durch die Triangulation können förderliche und hemmende Einflussfaktoren identifiziert werden. Aufbauend auf den theoretischen Vorüberlegungen sowie den empirischen Ergebnissen werden anschließend politische Handlungsempfehlungen abgeleitet.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: doctoralthesis , doc-type:doctoralThesis
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  • 6
    Publication Date: 2021-05-04
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: contributiontoperiodical , doc-type:contributionToPeriodical
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  • 7
    Publication Date: 2021-05-04
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: contributiontoperiodical , doc-type:contributionToPeriodical
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  • 8
    Publication Date: 2021-05-04
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 9
    Publication Date: 2019-08-07
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 10
    Publication Date: 2022-02-18
    Description: Zwischen 2005 und 2016 gab es in Deutschland über 150 Stadtwerke-Neugründungen im Energiebereich. Die insgesamt rund 900 Stadtwerke, die heute im Energiesektor tätig sind, spielen für die Energiewende eine zentrale Rolle. Denn sie stellen weit über die Hälfte der Versorgung an Strom, Gas und Wärme sicher. Zudem haben Stadtwerke aufgrund ihrer kommunalen Verankerung eine besondere Position im Spannungsgefüge von Politik, Wirtschaft und Zivilgesellschaft. Dieser Beitrag zeigt auf, welche Gründe und Motive zu dieser Gründungswelle führten und welche Erfolgsfaktoren für Stadtwerke-Neugründungen ausschlaggebend waren.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 11
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    Jakarta : Economic Research Institute for ASEAN and East Asia (ERIA)
    Publication Date: 2022-02-18
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: bookpart , doc-type:bookPart
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  • 12
    Publication Date: 2022-02-18
    Description: Ein CO2-Preis ist ein zentrales Instrument, um eine umfassende Dekarbonisierung der Wirtschaft zu ermöglichen und zu erleichtern. Sie kann durch verschiedene Instrumente umgesetzt werden, insbesondere in Form einer CO2-Steuer. Es ist jedoch wichtig, dass ein CO2-Preis allein - aufgrund der vielfältigen Hindernisse (einschließlich nicht ökonomischer Hemmnisse) - die sektoralen Ziele und Instrumente nicht ersetzen kann. Vielmehr muss er komplementär zu sektorspezifischen Klimaschutzinstrumenten eingeführt werden. Der Artikel gibt Auskunft darüber, wie ein CO2-Preis konkret und angemessen ausgestaltet werden kann.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: contributiontoperiodical , doc-type:contributionToPeriodical
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  • 13
    Publication Date: 2022-02-18
    Description: Elektro- und Elektronikaltgeräte enthalten eine Vielzahl von umwelt- und ressourcenrelevanten Metallen wie Gold und Neodym, welche derzeit noch nicht optimal recycelt werden. Im vorliegenden Projekt wurden die Mengenpotenziale von 10 dieser Metalle in 30 ressourcenrelevanten Elektrogerätearten quantifiziert und die bestehenden Verluste bei der Elektroaltgeräte-Entsorgung von der Sammlung über die Behandlung bis zur Metallrückgewinnung über Mengenstrombilanzen ermittelt, teilweise unterstützt durch Sortieranalysen und Behandlungsversuche. Die Studie leitet daraus Maßnahmenempfehlungen zur Optimierung der Erfassungsstrukturen sowie der Behandlungs- und Verwertungssysteme für Elektroaltgeräte aus privaten Haushalten zur Rückgewinnung der betrachteten Metalle ab.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: report , doc-type:report
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  • 14
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    Jakarta : Economic Research Institute for ASEAN and East Asia (ERIA)
    Publication Date: 2022-02-18
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: bookpart , doc-type:bookPart
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  • 15
    Publication Date: 2022-02-18
    Description: Ex-ante policy evaluation requires a detailed understanding of how the subjects addressed by the policy react to its implementation. In the context of energy efficiency, policy measures typically aim at influencing investment decisions towards more efficient options. As has been discussed widely in the context of the "energy efficiency gap", investments in energy efficiency improvements are frequently not conducted even though they seem cost-effective from a simple cost-benefit perspective, where transaction costs have been identified as one important barrier. While transaction costs have been discussed widely from a conceptional perspective, empirical studies quantifying transaction costs and measures to reduce them are rare. This paper presents approaches, results and insights from a recently completed research project funded by the German Federal Energy Efficiency Center (BfEE), addressing transaction costs in various energy efficiency measures and the role of energy efficiency services to overcome the barrier. We analyse a set of 11 energy efficiency investments covering private households, public institutions and the industry sector. We gather data on direct investment costs and energy cost savings and provide a detailed analysis of the various barriers and transaction costs associated with the implementation. We then analyse the costs of existing energy efficiency services using data provided by the BfEE. We compare the different cost elements and analyze the potential of energy efficiency services to reduce transaction costs. We find that the role of transaction costs differs substantially between households, public institutions and companies and that the impact of energy efficiency services on transaction costs needs to be evaluated using different methodological approaches. We conclude that while data availability on disaggregated transaction costs is a major challenge, energy services can reduce transaction costs considerably.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 16
    Publication Date: 2022-02-18
    Description: Because prevention is closely linked to complex consumption patterns, even cultural changes, such as increasing environmental awareness, changes in the average size of households or changes in the industrial structure of an economy, are relevant factors for the interpretation of changes in the generation of waste - it is more or less impossible to isolate the effect of specific waste prevention measures in this complex system. This must be considered, in particular, in international comparisons of policies and their potential transferability. The guidelines of the European Commission on waste prevention also point to the particular problem of data availability in the area of prevention: as waste statistics focus mainly on the treatment and fate of wastes, they are often of limited value for prevention of waste because they don't give sufficient information about their origins or reasons for their generation. Against this background, this report has the following objectives: Chapter 2 discusses strengths and weaknesses of typical waste-based prevention indicators; Chapter 3 analyses possible indicators that consider an upstream perspective and take into account the ecological rucksacks of products and components that have become waste; Chapter 4 focuses on specific product groups that could be targeted by waste prevention indicators. In general, the report describes the complexity of measuring waste prevention and outlines pros and cons of possible approaches. The final chapter aims to draw rather pragmatic conclusions on possibly most preferable options for future policy-making.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: report , doc-type:report
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  • 17
    Publication Date: 2022-01-20
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: contributiontoperiodical , doc-type:contributionToPeriodical
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  • 18
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2022-11-10
    Description: Mit fortschreitender Energiewende steigt der Anteil erneuerbarer Energien im Strommix. Deren Angebot variiert im Tagesverlauf, nach Wetterlage und saisonal. Um Angebot und Nachfrage zur Deckung zu bringen, benötigt es daher Speicher mit großen Kapazitäten. Von allen technologischen Optionen mit großer Speicherkapazität sind Wasser-Pumpspeicherwerke die einzige, die langjährig erprobt und wirtschaftlich ist. Diese könnten in Braunkohletagebauen, welche im Zuge der Energiewende aufgegeben werden, errichtet werden. Unsere Überschlagsrechnung am Beispiel eines Pumpspeicherwerks in den heutigen Tagebauen Hambach, Garzweiler und Inden zeigt, dass diese mit bis zu 400 GWh ein signifikantes technisches Speicherpotenzial haben. Dies entspricht etwa der kontinuierlichen Maximalleistung eines Kernkraftwerks über zwei Wochen. Im Kontext der Diskussion um den Braunkohleausstieg skizziert das Papier ein netzdienliches Nachnutzungskonzept für Braunkohletagebaue, das zumindest für einen Teil der heute in der Kohleförderung und -Verstromung Beschäftigten mögliche Zukunftsperspektiven bietet.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: workingpaper , doc-type:workingPaper
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  • 19
    Publication Date: 2022-11-10
    Description: Die vorliegende Arbeit verfolgt die Zielsetzung, den Beitrag verschiedener politischer Handlungsoptionen zur Steigerung der betrieblichen Energieeffizienz zu ermitteln. Eingangs wird aufgezeigt, inwieweit die Steigerung der Energieeffizienz aufgrund ihrer vielfältigen Vorteile eine Einstufung als eigenständige Zielgröße rechtfertigt im Gegensatz zu einer bloßen Betrachtung als Mittel zum Zweck des Klimaschutzes. Für die anschließende quantitative Analyse wurden Daten aus dem Projekt Energieeffizienz Impulsgespräche des Rationalisierungs- und Innovationszentrums der Deutschen Wirtschaft (RKW) e.V. aus den Jahren 2011 bis 2013 mit eigens für diese Arbeit erhobenen Daten von 2017 für dieselben Unternehmen verglichen. Zu diesem Zweck wird ein difference-in-differences-Ansatz genutzt. Im Ergebnis erweisen sich Preise im Gegensatz zu anderen Maßnahmen wie Energieberatungen, Fördermitteln und Energiemanagementsystemen als zumindest teilweise wirksame Einflussgröße für die Energieeffizienz. Der Autor empfiehlt auf dieser Basis eine stärker marktwirtschaftlich ausgerichtete Effizienzpolitik.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: masterthesis , doc-type:masterThesis
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  • 20
    Publication Date: 2022-11-10
    Description: Im Rahmen des Forschungsprojekts "Wirtschaftsförderung 4.0" leistet die vorliegende Arbeit einen Beitrag zum besseren Verständnis der systematischen Stärkung zivilgesellschaftlicher Nachhaltigkeitsinitiativen. Das Ziel der Analyse besteht darin, Ansatzpunkte möglicher Unterstützungsmaßnahmen aufzuzeigen, die im Zuge kommunaler Wirtschaftsförderung aufgegriffen werden können. Zur Erarbeitung wurden zunächst mithilfe theoretischer Grundlagen aus der Transition- und Diffusionsforschung zentrale Einflussfaktoren zusammengetragen, die förderlich oder hemmend auf transformative Nachhaltigkeitsinitiativen wirken können. Mit dem Ziel, kontextangepasste Maßnahmen zu entwickeln, wurden die literaturbasierten Faktoren anschließend in einer qualitativen Befragung mit einer Praxisperspektive verglichen und ergänzt: Mittels leitfadengestützter Experteninterviews mit nachhaltigkeitsorientierten Initiativen in der Region Osnabrück wurden kommunale Gegebenheiten sowie die jeweiligen Erfolgsfaktoren, Herausforderungen und Bedarfe der Graswurzelinitiativen erfasst. Im Ergebnis zeigen sich sieben übergreifende Bedarfsfelder, die vor allem aus der empirischen Erhebung abgeleitet wurden. Aus ihnen wurden Handlungsempfehlungen und Ansatzpunkte kommunaler Unterstützung erarbeitet und diskutiert.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: masterthesis , doc-type:masterThesis
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  • 21
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2022-11-09
    Description: Die Autoren verdeutlichen in diesem Papier, dass der Megatrend Digitalisierung nicht zwingend unkontrollierbar über die Wirtschaft und die Gesellschaft hereinbricht. Seine Wirkung hängt vom menschlichen Verhalten, von der Gestaltung neuer Prozessen in Organisationen, aber auch Anpassungen der gesetzlichen Rahmenbedingungen ab. Dieses sozio-kulturelle, organisatorische und institutionelle Umfeld der digitalen Innovationen könne und müsse im Sinne ökologischer Nachhaltigkeit beeinflusst werden. Politik sei hier aufgefordert auf der Basis fundierter Analysen flankierend tätig zu werden. Die Autoren fordern daher, für die Digitalwirtschaft eine eigene sektorspezifische Politik zu entwickeln, wie sie für andere umweltrelevante Sektoren - etwa die Energiewirtschaft, Chemieindustrie oder Autoindustrie - bereits etabliert ist.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: workingpaper , doc-type:workingPaper
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  • 22
    Publication Date: 2021-05-19
    Description: Aquaculture activity is restricted mainly to rainbow trout in cold waters and carps in warm waters in inland waters of Iran as well as Fars Province. Probably for this reason saline waters of south and southeast Fars have not been used for aquaculture. These rivers are ecosystems with a diverse biota, it is predictable that can be found some there endemic aquatic organisms with a potential for aquaculture. Finding a suitable organism can help increase wise use of this natural resource, and local production and recruitment. However, it is highly needed to investigate various environmental elements prior to any use to obtain an estimation of the environmental consequences, parallel to finding usage potentials. In This study, we investigated Dehram saline river in south of Fars Province. Hydrological and physiographical properties, chemical composition of the river, and aquatic populations were sampled and measured monthly in 3 stations in one year. Salinity, electrical conductivity, and total dissolved solids increased from station 1 to 3, reaching from 6.6 g/L, 14.3 g/L, and 12800 µs/cm to 13.5 g/L, 17.7 g/L, and 16500 µs/cm, respectively. Dissolved oxygen and oxygen saturation were higher in station 3, and in autumn and winter. Nitrite showed lowest values in winter (0.006 mg/L) and highest values in spring (0.013 mg/L). Nitrate showed the lowest concentration in station 3 (0.43 mg/L), but no differences were seen among seasons. Ammonium showed no differences among stations or seasons. Phosphate levels in station 1 and 3 were 0.13 mg/L‌to 0.17 mg/L, with the highest level (0.29 mg/L) seen in the spring. Five species of fishes were identified in the river, which all were widely favored by local people. Some of these have been categorized as edible in previous studies, others as ornamental. On the other hand, intensive growth of an algal species throughout the river demonstrates a potential for algal cultivation. Significant role of algae in production of food for both man and livestock is now well recognized in aquaculture industry.
    Description: Iranian Fisheries Science Research Institute
    Description: Published
    Keywords: Ecology ; Dehram River ; Limnology ; Saline water ; Physico-chemical parameters ; Aquaculture
    Repository Name: AquaDocs
    Type: Report , Refereed
    Format: 62pp.
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  • 23
    Publication Date: 2021-05-19
    Description: 0Genetic polymorphism by means of biochemical genetic markers using polyacrylamide gel electrophoresis system in four barbus fish species has been investigated. Species scientific name were Barbus sharpeyi ; Gunther, 1847 , Barbus grypus ; Heckel, 1843, Barbus xanthopterus ; Heckel, 1843 and Barbus esocinus ; Heckel, 1843.Sampling site and location were mainly in the rivers located in Khoozestan province such as Karoon and Karkheh rivers and the Dez dam. Different organs such as blood, muscle, kidney, eye and heart were sampled and analysed for the presence of tf, es, sod and pgm alleles. High polymorphism and presence of different alleles scored, but populations were not in the H-W equilibrium. Considring results, using current and avaiable genetic markers such as microsattelits is recommended for future works.
    Description: Iranian Fisheries Science Research Institute
    Description: Published
    Keywords: Chemistry ; Genetics ; Genetics Markers ; Distinguish ; Barbus ; Species ; Barbus sharpeyi ; Barbus xanthopterus ; Barbus esocinus
    Repository Name: AquaDocs
    Type: Report , Refereed
    Format: 62pp.
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  • 24
    Publication Date: 2021-05-19
    Description: Cheshmehkileh River and adjacent mountainous streams, play a strategic role as a historical axis for anthropogenic civilization, human welfare also habitat and migration pathway of commercial – biologic valuable fishes e.g. Caspian trout, Caspian kuttum, members of Cyprinidae family in south Caspian Sea drainage. Treats such as overfishing of Caspian trout and Red spotted trout stocks in mountainous headwaters, barriers construction and manipulations those are out of river carrying capacity developed by human activities, affected normal function of river as well. Sand mining big factories establishment next to the river, legal and illegal trade of river sediments, direct entry of Tonekabon landfill leakage into the river, development of Rainbow trout farms since 3 decades and huge effluents into the river containing dead fish and types of solids, escapement of cultured Rainbow trouts into the river, … are major minimum factors which needs basic information for integrating inclusively drainage management system. Cheshmehkileh River contains Headwaters of Dohezar (Daryasar & Nusha), Sehezar and Valamroud rivers during 13 monthly sampling phases between September 2009 and October 2010 based on macrozoobenthoses investigations by EPT, EPT/C EPA protocols, measurements of nominated physic-chemical and microbiologic parameters. Probability of Rainbow trouts escapement and invasion, existence, nutrition in Cheshmehkileh environment indeed investigated. Data analysis explained significant differences (P〈0.05) between groups of measured parameters in different sampling stations. Dendogram of clustered analysis based on consolidation of major biologic/ physic-chemical and microbiologic parameters, separated stations No. 1, 3, 2, 4 in one group and remained classified in different groups. Station 8 and 9 similarly separated which expressed general similarities according to Sehezar river environment which were differs in comparison with other stations. Station 11 separated according to its natural quality of water and environment. Similarities between station 10 to Sehezar river stations 8 and 9 expressed general influence of Sehezar River more than Dohezar River in Cheshmehkileh condition especially in station No. 10. High scores of EPT and EPT/C indices in upstream stations 1, 3 and 8 also low score of indices in stations 7, 13 and 6 expressed levels of environment quality between these groups of stations. Maximum average biomass of macroinvertebrates belongs to Trichoptera order in Cheshmehkileh River. Significant decrease of biomass in stations 11, 12 and 13 in comparison with other stations stated environment degradation in mentioned stations relevant to excessive sand mining as well. Pollution resistant groups of invertebrates significantly increased in downstreams against upstream stations. Also disappearing of Plecoptera order in station No. 7, 9, 10 and 13 stated low quality of environment in comparison with upstream stations. Confirmation of effects quality and quantity for point and non-point sources of imported pollutants require specific management considerations in order to present exploitations, pollutants control and emergencies for river monitoring in forthcoming years.
    Description: Iranian Fisheries Science Research Institute
    Description: Published
    Keywords: River ; Pollution ; Aquaculture ; EPTC ; Assessment ; Macroinvertebrates ; Chemistry ; Microbiology
    Repository Name: AquaDocs
    Type: Report , Refereed
    Format: 138pp.
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  • 25
    Publication Date: 2021-05-19
    Description: Limnological factors of brackish water pounds of the rainbow trout, Onchorhynchus mykiss were studied at Bafgh region in Yazd province. Physicochemical factors, phytoplankton, zooplankton and benthic populations of pools, supply and drainage channels from different farms were studied in aquaculture cycle in 2002 and 2003. Means were compared using Tukey HSD and t tests. Meanings of factors in 2002 and 2003 were respectively: and 9.3 0.2ppt; dissolved oxygen 7.9 0.2mg/l water temperature 13.8 0.3°c and 14.9 0.6°c; salinity 12.3 0.2ppt and 7.2 0.1mg/l; pH between 7.8 to 9.2 and 8.1 to 9.5; depth of hyalinity 0.85 0.1m and 1.1 0.1m; ammonium 0.1-0.5mg/l; and nitrate 1.8-21mg/l. Main phytoplankton were diatoms specially Chaetoceros, and Cyanophyta. Rotifera were the dominant zooplankton. Benthic fauna mainly included immature Chironomids. Final mean lengths were between 24.7cm to 31.5cm, mean weights between 11179.9gr to 434.6gr. FCR between 1.16 to 1.6; DGR between 1.04gr/day to 3.03gr/day; production 0.03kg/m2 to 0.84 kg/m2. Supply channels had the optimum limnological condition for trout aquaculture. Limnological factors were often not significantly different between pools and drainage channels. Saeeid and Rangin-Kaman farms were the most successful farms.
    Description: Iranian Fisheries Science Research Institute
    Description: Published
    Keywords: Limnology ; Brackish water ; Onchorhynchus mykiss ; Rainbow trout ; Phytoplankton ; Zooplankton ; Chaetoceros ; Survey ; Pond culture
    Repository Name: AquaDocs
    Type: Report , Refereed
    Format: 175pp.
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  • 26
    Publication Date: 2021-05-19
    Description: Gahar-roud is in 18 kilometer far from Doroud city from East of lorestan province . This river orginated from internal part of Oshteran-kouh mountain altitude and Gahar-Lake . Survey on Gahar roud Limnology began from the end of 2001 year and during the 18 month achived, at first on the length of 20 kilometer five station of sampling was selected and biological, physical and chemical character of this river was surveyed this river in all path of it feeding with large and small spring, little rivers and water of icehouse. The amount water of this river is different and maximum water is about 21 m/s in April month. Specifity of this river is be enough the temperature of water for fish. Minimum in the Jan is about 3 centigrad deegree and maximum is July and Aug about 24 centigrade deegree phis between 6.5-8.2 and is few basic . solauble oxigen is enough and is between 8.5-13 mg/lit.during the year.This river is very bright and haven t the source of polution and during the path of river and be enaugh the dosage of mineral in water are the important physical and chemical character of this river. Gahar-roud is not biological hardness quality. About 31 genus and species from 5 family of phytoplangton and 42 genus from 26 family from the order of insects, molusca, worms and crustacea and 9 species from 12 family from the side aquatic. Plants was collected and recognized. Based on ecological potential of this region, because Gahar- roud river is poor for food material and classified in oligotroph river and hasn t high biological value. And also have a few population and in fact haven t any population and based on the safer system belong to the quatiy elass of oligotroph and amount of water, regular circulation of water with microclima condition rate of natural resource land around river, having program for culture of cold water fish is important but it is better that use from culture of fish, be regulated key word limnology, Gahar-roud, river plangton, bentoz, fish.
    Description: Iranian Fisheries Science Research Institute
    Description: Published
    Keywords: Limnology ; Fish ; Bentos ; Plankton
    Repository Name: AquaDocs
    Type: Report , Refereed
    Format: 84pp.
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  • 27
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    Massachusetts Institute of Technology and Woods Hole Oceanographic Institution
    Publication Date: 2022-05-25
    Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 2018
    Description: Many chemical constituents are removed from the ocean by attachment to settling particles, a process referred to as “scavenging.” Radioisotopes of thorium, a highly particle-reactive element, have been used extensively to study scavenging in the ocean. However, this process is complicated by the highly variable chemical composition and concentration of particles in oceanic waters. This thesis focuses on understanding the cycling of thorium as affected by particle concentration and particle composition in the North Atlantic. This objective is addressed using (i) the distributions 228,230,234Th, their radioactive parents, particle composition, and bulk particle concentration, as measured or estimated along the GEOTRACES North Atlantic Transect (GA03) and (ii) a model for the reversible exchange of thorium with particles. Model parameters are either estimated by inversion (chapter 2-4), or prescribed in order to simulate 230Th in a circulation model (chapter 5). The major findings of this thesis follow. In chapters 2 and 3, I find that the rate parameters of the reversible exchange model show systematic variations along GA03. In particular, 𝑘1, the apparent first-order rate "constant" of Th adsorption onto particles, generally presents maxima in the mesopelagic zone and minima below. A positive correlation between 𝑘1 and bulk particle concentration is found, consistent with the notion that the specific rate at which a metal in solution attaches to particles increases with the number of surface sites available for adsorption. In chapter 4, I show that Mn (oxyhydr)oxides and biogenic particles most strongly influence 𝑘1 west of the Mauritanian upwelling, but that biogenic particles dominate 𝑘1 in this region. In chapter 5, I find that dissolved 230Th data are best represented by a model that assumes enhanced values of 𝑘1 near the seafloor. Collectively, my findings suggest that spatial variations in Th radioisotope activities observed in the North Atlantic reflect at least partly variations in the rate at which Th is removed from the water column.
    Description: This work was supported by the US National Science Foundation. Two US NSF grants have supported the research in this thesis (OCE-1232578 and OCE-155644).
    Keywords: Thorium ; Chemistry
    Repository Name: Woods Hole Open Access Server
    Type: Thesis
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  • 28
    Publication Date: 2021-05-19
    Description: Dorudzan reservoir is the main provider of drinking water for the capital Shiraz, as well as the most significant storage of water in the Kor river course. In addition of eroded material, a load of agricultural outputs from upstream are moved to the lake every year. Main physiographic, physical and chemical, and biological components of the lake were monthly sampled and analysed from Novembr 2010 to October 2011. Mean annual measures were water temperature 16.7 ˚C (SD=5.8), pH 8.2 (SD=0.3), dissolved oxygen 7.6 mg/l (SD=1.7), ammonium 0.05 mg/l (SD=0.08), nitrite 0.004 mg/l (SD=0.003), nitrate 0.44 mg/l (SD=0.44), phosphate 0.20 mg/l (SD=0.23), silicate 7.00 mg/l (SD=2.49), BOD 2.29 mg/l (SD=1.00), COD 24.49 mg/l (SD=15.47), electrical conductivity 720 µs/cm (SD=219), total dissolved solids 457.67 mg/l (SD=138.72), calcium hardness 61.30 mg/l (SD=13.45), and magnesium hardness 20.23 mg/l (SD=9.18). Living parts of the ecosystem including species of fish, orders and families of benthic invertebrates, zooplanktons, and phytoplanktons were investigated. Benthic macroinvertebrates included various nematodes, oligochates, gastropods, bivalves, and insect larvae (dipteral and coleptera), most abundant of which were dipteran larvae, mollusks, and nematodes. Dominant zooplankton was Bosmina, with Daphnia and Cyclops in next ranks. Among rotifer, Trichocera was more abundant than Lecanae. Bosmina showed the most abundance in summer and Daphnia in spring. Trichocera had its most abundance in summer as well, while Lecanae was more abundant in Automn and winter. A total of 41 algal genera from 8 divisions were found. Dominant phytoplankton division was Chlorophyta, with genus Pediastrum. Dominant microalga was Dynobrion (Chrysophyta) in Spring, Cylindrospermum and (both Cyanophyta) in Summer, Microsystis in Automn, and Ceratium (Dynophyta) in Winter. Ceratium were found in all seasons in most of the sampling sites, and showed highest abundance compared to other genera of its division. Dominant genus of diatoms was Fragilaria. Fish populations include Alburnus mossulensis, Capoeta aculeate, Capoeta damascina, Carasobarbus luteus, Carassius gibelio, Cyprinus carpio, and Hypophthalmichthys molitrix. Main different parts of the lake showed quite different composition of fish species. An epidemic occurance of the crustacean ectoparasite Lernea cyprinacea among most fishes was another important finding. These findings will serve as a base for future studies as a set point of drought situations.
    Description: Iranian Fisheries Science Research Institute
    Description: Published
    Keywords: Limnology ; Reservoir ; Plankton ; Fish ; Alburnus mossulensis ; Capoeta aculeate ; Capoeta damascina ; Carasobarbus luteus ; Carassius gibelio ; Cyprinus carpio ; Hypophthalmichthys molitrix
    Repository Name: AquaDocs
    Type: Report , Refereed
    Format: 72pp.
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  • 29
    Publication Date: 2021-05-19
    Description: Abbarik River is an important river in Kerman. Study of limnology of Abbarik River for aquatics & culture was started from Mehr 1381 to Day 1382. Base of this study was physical- chemical and Biological factors. In this research 3 stations was appointed. PH- oxygen- salinity- Ca- Mg- Na- K- Cl and was majored and bentetic- fish was recognized. This study was achievement in 4 season and twice in month. Bentosis recognize was Ephemeroptera- Diptera- Anisoptera- Cleoptera Trichoptera Fishes recognize was Capoeta damascina- Nemachilus sargadensis- Cyprinion watsoni.
    Description: Iranian Fisheries Science Research Institute
    Description: Published
    Keywords: Physical ; Chemical ; Biological ; Limnology ; Bentosis fish ; Aquatic ; Culture ; PH ; Salinity ; Oxygen ; Ephemeroptera ; Diptera ; Anisoptera ; Cleoptera Trichoptera ; Capoeta damascina ; Nemachilus sargadensis ; Cyprinion watsoni
    Repository Name: AquaDocs
    Type: Report , Refereed
    Format: 44pp.
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  • 30
    Publication Date: 2021-05-19
    Description: The shiroud river is one of the important riveres in point of view of fisheries matter which located in western part of Mazndran provience. The project of Limnological study have done in this river during June/ 2002 - Jun / 2003 for more and better underestanding situations, of biological and nonbiological parameters like as phytoplankton, zooplonkton, benthoses, Ichthyology, physico - chemical and pesticides of water. - Physico- chemical paramaters by ASTM methods and spectrophotometer and pestisides by US-EPA- method and GC- ECD determined. The procedures of detemination of zooplanklon and phytoplankton by manuals of Newell, 1970 and Sorina, 1974 idantify and determined respectinely. In Ichthyology, by manual procedure Berg, 1949 identifind. The sampeling have been in four stations during four seasons and result as follow: - The maximum and minimum amount of pH were in station 5 (spring) and Station no. 4 (summer) 8.19 and 7.75 respectively. - The maximum and minimum temperature of water were in station no. 8 (summer) and stations no. 2 (winter) 27.7 c and 7.7c respectively. The fluctuatcions of nutroients datas of this study and other studies done during last 5 years showed, there were not big diffrence between them but also these datas were very close to each other. - The maximum residues of pesticides for heptachlor Epoxide (Winter ) and Lindane (spring) betweenresidues of sixteen pesticdes were 79.4 and 3.7 ppb respectively. - The maximum and minimum amount of phytoplankton biomass belong to chrysophyta during four seasons were 2572 through 1081 mg/m3. - The percentage of zooplankton belong to Rotatoria , Protozoa , Copepoda , Cladocera and Zoobenthos were in 41 , 31 , 12 , 4 and 12 percent recpectively. - The maximum aboundant percentage of bentheic animals belong to Diptera with 42 percent and were dominate whole sampeling stations . - The abundence of fishes in this river belong to two species of C. capoeta gracilis and Al. bipunctatus were catched in four seasons at eight stations . The percentages of C. capoeta gracilis species were catched in four seasons at eight stations during winter, summer , spring and fall with 96 ,81 , 73 and 67 percent respectively. The percentages of Al. bipunctatus species were catched in four seasons at eight stations during winter, summer , spring and fall with 47 , 44 , 43 and 40 percent respectively.
    Description: Iranian Fisheries Science Research Institute
    Description: Published
    Keywords: Pesticdes residues ; Phytoplankton ; Zooplankton ; Riverine fishes ; Nutrients ; Limnology ; ASTM ; Rotatoria ; Protozoa ; Copepoda ; Cladocera ; Zoobenthos
    Repository Name: AquaDocs
    Type: Report , Refereed
    Format: 127pp.
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  • 31
    Publication Date: 2021-05-04
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 32
    Publication Date: 2021-05-04
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 33
    Publication Date: 2020-10-13
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 34
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    Publication Date: 2021-05-04
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 35
    Publication Date: 2021-05-04
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 36
    Publication Date: 2020-10-13
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 37
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    Publication Date: 2020-10-13
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 38
    Publication Date: 2021-05-04
    Description: Seit einigen Jahren erfährt die Abfallwirtschaft unter dem Schlagwort "Kreislaufwirt­schaft" einen massiven Perspektivwech­sel: Nach den Vorstellungen der Europäischen Kommission, die 2015 ihren Aktionsplan Kreislaufwirtschaft vorgestellt hat, sollen Abfälle in Zukunft in erster Linie als potenzieller Rohstoff gesehen werden; sowohl die in einzelnen Produkten enthaltenen natürlichen Ressourcen als auch deren ökonomischer Wert sollen am Ende der Nutzungsphase möglichst optimal erhalten bleiben. Angesichts der Rohstoffarmut in Eu­ropa sollen die Abfälle recycelt und wieder in den Produktionsprozess zurückfließen, um so auch langfristig die europäische Wettbewerbsfä­higkeit sicherzustellen. Damit geraten jedoch auch neue Fragen in den Fokus: Was genau passiert eigentlich mit un­serem Müll? Wo bleibt er, und in welchen Teilen der Welt wird er recycelt? Und wer hat dann Zu­griff auf die Rohstoffe, die aus ihm zurückgewonnen werden?
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 39
    Publication Date: 2021-05-04
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 40
    Publication Date: 2021-05-04
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 41
    Publication Date: 2021-05-04
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 42
    Publication Date: 2019-01-07
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: report , doc-type:report
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  • 43
    Publication Date: 2021-05-04
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 44
    Publication Date: 2021-05-04
    Description: Germany's waste management system is one of the world's most advanced - its primary objective is to dispose of waste in a way that is safe for both people and the environ- ment. However, only about 14 per cent of the raw materials used in industry are derived from recycling processes; the remainder are still sourced from primary materials. The circular economy is not yet being implemented on a large enough scale. Recyclates or recycled materials, i.e. secondary raw materials recovered from waste, are being fed back into production and usage processes at volumes that are far below what is possible. If this system were to be improved, loss of value, dependence on volatile commodity markets, lower resource productivity, and externalities in the form of environmental pollution could be avoided. A drive towards digitalisation in industry and the waste management sector could make this happen. A study by the German Federal Ministry for the Environment, Nature Conservation, Building and Nuclear Safety (BMUB) indicates that no other lead market in the environmental sector stands to benefit from digitalisation more than the circular economy - and that, at the same time, no sector has ever been so poorly positioned.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 45
    Publication Date: 2022-02-18
    Description: Eine Kosten-Nutzen-Analyse ist ein bewährtes Mittel, um die Rentabilität einer Energieeffizienzmaßnahme zu bewerten: Die Investitionskosten werden mit den eingesparten Energiekosten verglichen. Investitionsentscheidungen für Energieeffizienzmaßnahmen erfolgen allerdings häufig nicht nach einer reinen Erwägung der direkten Kosten und Nutzen. Gründe hierfür sind unter anderem "versteckte" Kosten und Risiken (z. B. Kosten für die Beschaffung von Informationen, Unsicherheiten über zukünftige Energiepreise und Einsparungen), aber auch nicht-monetäre Hemmnisse, die bei Entscheidungen eine Rolle spielen (z. B. beschränkte Rationalität, Präferenzen, Zeitverfügbarkeit). Vor diesem Hintergrund verfolgt der Bericht das Ziel, ein besseres Verständnis der Kosten-Nutzen-Erwägungen von Investoren und deren Entscheidungswirklichkeit zu erlangen. Die Untersuchung zeigt, dass Energieeffizienzdienstleistungen (EEDL) generell die versteckten Kosten - Transaktionskosten - reduzieren können. Das setzt aber voraus, dass EEDL sachgerecht durchgeführt werden. Transaktionskosten werden allerdings im Zusammenhang mit Energieeffizienzmaßnahmen von den Akteuren kaum wahrgenommen und entsprechend nicht quantifiziert. Des Weiteren zeigt sich, dass insbesondere bei Unternehmen die EEDL-Kosten für bestimmte Maßnahmen hoch sein können. Doch werden gerade in diesen Fällen die Transaktionskosten reduziert. Grundsätzlich erscheinen kostenaufwendigere EEDL, wie umfassendere Vor-Ort-Beratungen, im Gegensatz zu den preiswerteren Vor-Ort-Checks besser geeignet, um Transaktionskosten zu reduzieren.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 46
    Publication Date: 2022-02-18
    Description: Mit dem Auslaufen vieler Konzessionsverträge im Strom- und Gasbereich auf der örtlichen Verteilnetzebene sind in Deutschland zahlreiche neue Stadtwerke entstanden. Die Bestandsaufnahmen der Autoren zeigen einen eindrucksvollen Sachstand: Durch Gründung von insgesamt 152 neuen Stadt-, Gemeinde- und Regionalwerken haben zahlreiche Kommunen zwischen 2005 und 2016 die Chance ergriffen, ihre Energieversorgung künftig mit eigenen Unternehmen stärker selbst gestalten zu wollen. Doch zum Ende dieser Periode lässt dieser Trend in Deutschland merklich nach. International hingegen mehren sich die Fälle kommunalwirtschaftlichen Engagements. Selbst im Mutterland des Kapitalismus, den USA, gibt es eine starke Bewegung zur Gründung von Stadtwerken. Insbesondere in den Kommunen werden die Auswirkungen verfehlter Privatisierungspolitik deutlich. Hier zeigten sich die negativen Auswirkungen einer am Shareholder Value ausgerichteten Versorgung am deutlichsten. Deshalb wird dort zunehmend nach Lösungen gesucht, die den Public Value steigern, dabei die Gemeinwohlinteressen der Kommunen in den Vordergrund stellen und die Qualität von Serviceleistungen der Daseinsvorsorge nachhaltig verbessern.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 47
    Publication Date: 2022-02-18
    Description: In addition to the expansion of renewable energies, the efficient use of energy is crucial in order to ensure energy transition successful. The Federal Government of Germany has therefore set itself clear objectives with the National Energy Efficiency Action Plan (NAPE), which aims to reduce the primary energy consumption in Germany - compared to 2008 levels - by 20 per cent until 2020, and by 50 per cent until 2050. In addition, greenhouse gas emissions should fall by 40 per cent compared to 1990. To reach this goal, the German Federal Ministry of Economic Affairs and Energy (BMWi) inter alia launched the "National Top Runner Initiative (NTRI)" in January 2016. It is an important component and concerns private homes, as well as industry, retail and services. The NTRI is intended to bring energy efficient and high-quality appliances (so called Top Runners) onto the market more quickly, thus accelerate market replacement. For this purpose, motivation, knowledge and competence in product-related energy efficiency is to be strengthened and expanded along the whole value chain - from the appliance manufacturer to the retailer and the consumer. Manufacturers are pushed to develop more efficient products and consumers get valuable information about Top-Runner products and how they can benefit. In this context, retailers are especially relevant as they act as "gatekeeper" between manufacturers and consumers. They play a key role in advancing an energy efficient production and consumption. They do not only select the products but they also have a direct contact to consumers and influence the purchase decision. In this paper, special emphasis will be put on the role of retailers and the efforts of the National Top Runner Initiative will be illustrated. Barriers and incentives to motivate this target group will be elaborated.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 48
    Publication Date: 2022-02-18
    Description: Dieses Inputpapier soll für japanische Entscheidungsträgerinnen und -träger aufzeigen, was die Hintergründe der in Deutschland zu beobachtenden Welle an Stadtwerke-Neugründungen und Rekommunalisierungen sind. Dabei wird auf aktuelle energiewirtschaftliche Entwicklungen und Rahmenbedingungen in Deutschland eingegangen, die ein besseres Verständnis vermitteln werden. Das Inputpapier soll vor allem japanische Kommunalpolitikerinnen und -politiker in die Lage versetzen, in ihren eigenen Gemeinden fundierte Diskussionen über eine mögliche Stadtwerkegründung zu führen und Entscheidungen vorzubereiten. Dies können sie auf Basis wichtiger Grundkenntnisse und Erfahrungen deutscher Städte und Gemeinden initiieren. Im Laufe des Gesamtprojektes wird im Herbst 2018 ein Werkzeugkasten entwickelt, der zur Unternehmens-Neugründung in Japan wichtige Hilfestellungen wird leisten können. Ergänzend dazu bleiben juristische und energiewirtschaftliche Fachberatungen unerlässlich, um einen erfolgreichen Start der neuen kommunalwirtschaftlichen Unternehmen zu gewährleisten. Dieses Inputpapier versteht sich daher als erste Handreichung und Hilfestellung für kommunale Entscheidungsträgerinnen und -träger in Japan, damit dort ein Grundverständnis des "Stadtwerkeprinzips" entstehen kann.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 49
    Publication Date: 2022-02-18
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 50
    Publication Date: 2022-02-18
    Description: Die sog. Klimapfadestudie und ihre Szenarien haben in der Öffentlichkeit ein breites Echo gefunden, nicht zuletzt weil der BDI damit erstmals eine eigene detaillierte Untersuchung der Machbarkeit der deutschen Klimaschutzziele vorlegt und offensiv in die Diskussionen um die langfristige Transformation des Energiesystems einsteigt. Während der BDI in der Mai-Ausgabe der "et" bereits wesentliche Ergebnisse vorgestellt hat, werden die Szenarien der Studie in diesem Artikel mit anderen vorliegenden Klimaschutzszenarien verglichen.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 51
    Publication Date: 2022-02-18
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: Japanese
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  • 52
    Publication Date: 2022-02-18
    Description: Digital platforms may yield a host of advantages in putting circular economy into effect. This paper analyses the related chances and discusses requirements of digital platforms for the realization of a circular economy. It specifically points to potential solutions offered by digital platforms for existing barriers. From there it identifies issues that need specific attendance to create economically and ecologically functional platforms. Three economically relevant perspectives are discussed for this: a management perspective, a legislative perspective and a social/systems perspective.
    Keywords: ddc:330
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  • 53
    Publication Date: 2022-11-10
    Description: Stadtwerke spielen für die Energiewende eine zentrale Rolle. Zum einen stellen sie in Deutschland weit über die Hälfte der Versorgung an Strom, Gas und Wärme sicher, zum anderen haben Stadtwerke aufgrund ihrer kommunalen Verankerung eine besondere Position im Spannungsgefüge von Politik, Wirtschaft und Privathaushalten. Wenn es aber um die Frage geht, was den Erfolg von neugegründeten Stadtwerken ausmacht, besteht in der Literatur in gewissem Maße eine Forschungslücke. Die vorliegende Studie, die vom Wuppertal Institut und der BLUBERRIES GmbH gemeinsam erstellt wurde, behandelt ausgewählte Handlungsfelder, bei denen ein Einfluss auf den Unternehmenserfolg von neugegründeten Stadtwerken zu vermuten ist. Dabei werden als Rahmen die Ziele der Rekommunalisierung herangezogen und konkret vier Handlungsfelder in den Vordergrund gerückt. Der Fokus der Studie liegt auf Fragestellungen nach dem wirtschaftlichen Erfolg neugegründeter Stadtwerke sowie deren Zielerreichung. Dabei wird auf den klassischen Ansatz der Erfolgsfaktorenforschung zurückgegriffen. Ziel dieser Studie ist die Formulierung erster Aussagen darüber, wie einerseits die unterstellten Handlungsfelder in ihrer Ausgestaltung, andererseits die Erfolgsmaße durch neugegründete Stadtwerke beurteilt werden. Aufgrund der im Rahmen dieser Untersuchung vorgenommenen Online-Befragung lassen sich für die in den Focus genommenen vier Handlungsfelder (Kooperationen, Digitalisierung, Resilienz und Soziale Verantwortung) die wichtigsten Ergebnisse wie folgt zusammenfassen: Kooperationen und verschiedene Formen der Zusammenarbeit in der Gründungsphase spielen für den Erfolg neu gegründeter Stadtwerke eine sehr große Rolle. Neu gegründete Stadtwerke legen meist großen Wert auf nachhaltige Geschäftsbeziehungen zu örtlichen Unternehmen, was einen wesentlichen Beitrag zum Public Value darstellt. Insbesondere gut ausgearbeitete Geschäftsstrategien in den Bereichen Erneuerbare Energien, Verteilnetzbetrieb, Vertrieb und Diversifikation unterstützen die Umsetzung der Unternehmensziele in Bezug auf Resilienz und Nachhaltigkeit. Die eher durchschnittliche Bewertung der Resilienz-Relevanz für den Ausbau eines Smart Grids im Verteilnetzbereich ist ein Indiz dafür, dass der Ordnungsrahmen so geändert werden müsste, dass Investitionen in diesem Bereich attraktiver werden. Aufgrund des explorativen Charakters der vorgelegten Studie, der keine repräsentativen Aussagen über die Erfolgsfaktoren von neugegründeten Stadtwerken zulässt, werden folgende vier Hypothesen abgeleitet: 1. Der Einsatz von horizontal-kooperativen Ansätzen in der Gründungsphase als ein spezifisches Wesensmerkmal der deutschen Stadtwerkelandschaft hat positive Auswirkungen auf die Verbesserung des wirtschaftlichen Erfolgs und der Rentabilität. 2. Der Fokus auf Resilienz, Nachhaltigkeit und Klimaschutz als zentrale Werte des Stadtwerks und als integrale Bestandteile des Unternehmensleitbildes unterstützt die Erreichung der strategischen Ziele des neugegründeten Stadtwerks. 3. Das Anbieten von Smart Metern zur Erhöhung der Kundentransparenz, zur Verbesserung des Kundennutzens und zur Optimierung des Verteilnetzmanagements kann als Erfolgsfaktor eingestuft werden und unterstützt seitens der Stadtwerke eine positive Unternehmensentwicklung nicht nur in der Startphase. 4. Die explizite Wahrnehmung von sozialer Verantwortung wirkt sich positiv auf den Unternehmenserfolg aus. Es müsste nun anschließend auf der Basis einer größeren Grundgesamtheit geprüft werden, ob und inwieweit die beschriebenen Tendenzen (die sich aus der Online-Befragung ergeben) und die explorativen Hypothesen im Rahmen eines konfirmatorischen Untersuchungsansatzes wissenschaftlich verifiziert werden können.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: report , doc-type:report
    Format: application/pdf
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  • 54
    Publication Date: 2022-11-10
    Description: Seit Mitte der 2000er Jahre ist in Deutschland ein Großteil der Konzessionsverträge für örtliche Strom-Verteilnetze ausgelaufen. Dies eröffnete den Kommunen vielerorts die Möglichkeit ihre bis dahin in privatem Besitz befindlichen Strom-Verteilnetze zu rekommunalisieren. Vor dem Hintergrund der Energiewende und dem damit einhergehenden Umbau der deutschen Energielandschaft hin zu dezentralen Versorgungsstrukturen eröffnete sich kommunalen Verantwortlichen so die Möglichkeit die Umsetzung energiepolitischer Ziele der Bundesregierung auf kommunaler Ebene aktiv mitzugestalten. Eine im Jahr 2013 durch das Wuppertal Institut durchgeführte Sondierungsstudie erfasste für den Zeitraum 2005 bis 2016 zahlreiche Stadtwerke-Neugründungen, welche einen Trend zur Rekommunalisierung im Bereich der Energieversorgung andeutete. Darüber hinaus versuchen sich Institutionen wie das Deutsche Institut für Urbanistik (Difu) und der Verband kommunaler Unternehmen e.V. (VKU) bereits seit Jahren einen Überblick über die Entwicklung von Rekommunalisierungen zu verschaffen. Trotzdem existiert bis heute keine flächendeckende Erhebung über Rekommunalisierungen in Deutschland. Ziel dieser Arbeit war es daher eine Bestandsaufnahme über die Rekommunalisierung von Strom-Verteilnetzkonzessionen im Untersuchungsraum Nordrhein-Westfalen zwischen 2005 und 2016 vorzunehmen. In diesem Zeitraum konnten für den Untersuchungsraum insgesamt 119 Rekommunalisierungen festgestellt werden. Damit lagen bis Ende 2016 bereits zwei Drittel aller nordrhein-westfälischen Strom-Verteilnetzkonzessionen in kommunaler Hand, womit der Trend zur Rekommunalisierung eindeutig belegt werden konnte.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: masterthesis , doc-type:masterThesis
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  • 55
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    Woods Hole Oceanographic Institution
    Publication Date: 2022-05-26
    Description: This is a report describing activities associated with the Matamek program in 1977. Research was conducted on biological, chemical and physical factors related to salmonid production in Matamek River and Matamek Lake. Canadian universities, the Quebec government and Woods Hole Oceanographic Institution cooperated in the program.
    Description: Supported by Woods Hole Oceanographic Institution and the Department of Tourism, Fish and Game of the Province of Quebec.
    Keywords: Ecology ; Limnology
    Repository Name: Woods Hole Open Access Server
    Type: Technical Report
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  • 56
    Publication Date: 2022-11-09
    Description: Deutschland verfügt über eines der weltweit führenden Systeme im Bereich der Abfallwirtschaft - vorrangiges Ziel ist es, Abfall sicher und umweltschonend zu entsorgen. Allerdings kommen nur ca. 14 Prozent der in der Industrie eingesetzten Rohstoffe aus dem Recycling, der Rest sind noch immer Primärmaterialien. Kreislaufwirtschaft findet noch nicht ausreichend statt: Rezyklate, aus Abfällen gewonnene Sekundärrohstoffe, werden noch weit unterhalb der möglichen Mengen in Produktions- und Nutzungsprozesse zurückführt. Werteverlust, Abhängigkeit von volatilen Rohstoffmärkten, geringere Ressourcenproduktivität und Externalitäten in Form von Umweltverschmutzung ließen sich damit vermeiden. Eine Digitalisierungsoffensive in Industrie und Abfallwirtschaft könnte dies bewirken. Eine Studie des Bundesministeriums für Umwelt, Naturschutz, Bau und Reaktorsicherheit (BMUB) verweist darauf, dass kein Umweltleitmarkt so stark von der Digitalisierung profitieren könnte wie die Kreislaufwirtschaft - und dass gleichzeitig kein Sektor bisher so schlecht aufgestellt ist.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: workingpaper , doc-type:workingPaper
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  • 57
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-02-16
    Keywords: Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 58
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-02-16
    Description: The comment and response concerning the report of oxidation of methane to methanol by water (Reports, 5 May 2017, p. 523) do not fully capture the implications of thermodynamic limitations. A nonisothermal process in which each cycle requires a large temperature swing and permits only substoichiometric methane conversion surely could not be carried out on any practical scale.
    Keywords: Chemistry
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  • 59
    Publication Date: 2018-02-16
    Description: Labinger argues that stepwise reaction of methane with water to produce methanol and hydrogen will never be commercially feasible because of its substoichiometric basis with respect to the active site and the requirement of a large temperature swing. This comment is not touching any new ground, beyond describing the thermodynamic feasibility, thermal cycling, and the role of water as discussed previously. Most important, it does not have a solid numerical basis.
    Keywords: Chemistry
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  • 60
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-07-27
    Keywords: Chemistry
    Print ISSN: 0036-8075
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 61
    Publication Date: 2018-07-27
    Description: Vinyl carbocations have been the subject of extensive experimental and theoretical studies over the past five decades. Despite this long history in chemistry, the utility of vinyl cations in chemical synthesis has been limited, with most reactivity studies focusing on solvolysis reactions or intramolecular processes. Here we report synthetic and mechanistic studies of vinyl cations generated through silylium–weakly coordinating anion catalysis. We find that these reactive intermediates undergo mild intermolecular carbon-carbon bond–forming reactions, including carbon-hydrogen (C–H) insertion into unactivated sp 3 C–H bonds and reductive Friedel-Crafts reactions with arenes. Moreover, we conducted computational studies of these alkane C–H functionalization reactions and discovered that they proceed through nonclassical, ambimodal transition structures. This reaction manifold provides a framework for the catalytic functionalization of hydrocarbons using simple ketone derivatives.
    Keywords: Chemistry
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  • 62
    Publication Date: 2018-06-22
    Description: It is commonly assumed that recognition and discrimination of chirality, both in nature and in artificial systems, depend solely on spatial effects. However, recent studies have suggested that charge redistribution in chiral molecules manifests an enantiospecific preference in electron spin orientation. We therefore reasoned that the induced spin polarization may affect enantiorecognition through exchange interactions. Here we show experimentally that the interaction of chiral molecules with a perpendicularly magnetized substrate is enantiospecific. Thus, one enantiomer adsorbs preferentially when the magnetic dipole is pointing up, whereas the other adsorbs faster for the opposite alignment of the magnetization. The interaction is not controlled by the magnetic field per se, but rather by the electron spin orientations, and opens prospects for a distinct approach to enantiomeric separations.
    Keywords: Chemistry
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  • 63
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-06-29
    Keywords: Chemistry
    Print ISSN: 0036-8075
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 64
    Publication Date: 2018-12-14
    Description: Theory has established the importance of geometric phase (GP) effects in the adiabatic dynamics of molecular systems with a conical intersection connecting the ground- and excited-state potential energy surfaces, but direct observation of their manifestation in chemical reactions remains a major challenge. Here, we report a high-resolution crossed molecular beams study of the H + HD -〉 H 2 + D reaction at a collision energy slightly above the conical intersection. Velocity map ion imaging revealed fast angular oscillations in product quantum state–resolved differential cross sections in the forward scattering direction for H 2 products at specific rovibrational levels. The experimental results agree with adiabatic quantum dynamical calculations only when the GP effect is included.
    Keywords: Chemistry
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  • 65
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-08-17
    Keywords: Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 66
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-08-17
    Keywords: Chemistry
    Print ISSN: 0036-8075
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 67
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-08-17
    Description: The chemistry of the carbonyl group is essential to modern organic synthesis. The preparation of substituted, enantioenriched 1,3- or 1,5-dicarbonyls is well developed, as their disconnection naturally follows from the intrinsic polarity of the carbonyl group. By contrast, a general enantioselective access to quaternary stereocenters in acyclic 1,4-dicarbonyl systems remains an unresolved problem, despite the tremendous importance of 2,3-substituted 1,4-dicarbonyl motifs in natural products and drug scaffolds. Here we present a broad enantioselective and stereodivergent strategy to access acyclic, polysubstituted 1,4-dicarbonyls via acid-catalyzed [3,3]-sulfonium rearrangement starting from vinyl sulfoxides and ynamides. The stereochemistry at sulfur governs the absolute sense of chiral induction, whereas the double bond geometry dictates the relative configuration of the final products.
    Keywords: Chemistry
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  • 68
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-08-17
    Keywords: Chemistry
    Print ISSN: 0036-8075
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 69
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-08-17
    Description: With the recent soaring production of natural gas, the use of methane and other light hydrocarbon feedstocks as starting materials in synthetic transformations is becoming increasingly economically attractive, although it remains chemically challenging. We report the development of photocatalytic C–H amination, alkylation, and arylation of methane, ethane, and higher alkanes under visible light irradiation at ambient temperature. High catalytic efficiency (turnover numbers up to 2900 for methane and 9700 for ethane) and selectivity were achieved using abundant, inexpensive cerium salts as photocatalysts. Ligand-to-metal charge transfer excitation generated alkoxy radicals from simple alcohols that in turn acted as hydrogen atom transfer catalysts. The mixed-phase gas/liquid reaction was adapted to continuous flow, enabling the efficient use of gaseous feedstocks in scalable photocatalytic transformations.
    Keywords: Chemistry
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  • 70
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-08-24
    Keywords: Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 71
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-08-24
    Keywords: Chemistry
    Print ISSN: 0036-8075
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 72
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-08-31
    Keywords: Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 73
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-08-31
    Description: Intrigued by the potential of nanoscale machines, scientists have long attempted to control molecular motion. We monitored the individual 0.7-nanometer steps of a single molecular hopper as it moved in an electric field along a track in a nanopore controlled by a chemical ratchet. The hopper demonstrated characteristics desired in a moving molecule: defined start and end points, processivity, no chemical fuel requirement, directional motion, and external control. The hopper was readily functionalized to carry cargos. For example, a DNA molecule could be ratcheted along the track in either direction, a prerequisite for nanopore sequencing.
    Keywords: Chemistry
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  • 74
    Publication Date: 2018-09-21
    Description: Phosphorothioate nucleotides have emerged as powerful pharmacological substitutes of their native phosphodiester analogs with important translational applications in antisense oligonucleotide (ASO) therapeutics and cyclic dinucleotide (CDN) synthesis. Stereocontrolled installation of this chiral motif has long been hampered by the systemic use of phosphorus(III) [P(III)]–based reagent systems as the sole practical means of oligonucleotide assembly. A fundamentally different approach is described herein: the invention of a P(V)-based reagent platform for programmable, traceless, diastereoselective phosphorus-sulfur incorporation. The power of this reagent system is demonstrated through the robust and stereocontrolled synthesis of various nucleotidic architectures, including ASOs and CDNs, via an efficient, inexpensive, and operationally simple protocol.
    Keywords: Chemistry
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  • 75
    Publication Date: 2018-09-21
    Description: Here we report an anomalous porous molecular crystal built of C–H···N-bonded double-layered roof-floor components and wall components of a segregatively interdigitated architecture. This complicated porous structure consists of only one type of fully aromatic multijoint molecule carrying three identical dipyridylphenyl wedges. Despite its high symmetry, this molecule accomplishes difficult tasks by using two of its three wedges for roof-floor formation and using its other wedge for wall formation. Although a C–H···N bond is extremely labile, the porous crystal maintains its porosity until thermal breakdown of the C–H···N bonds at 202°C occurs, affording a nonporous polymorph. Though this nonporous crystal survives even at 325°C, it can retrieve the parent porosity under acetonitrile vapor. These findings show how one can translate simplicity into ultrahigh complexity.
    Keywords: Chemistry
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  • 76
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-09-28
    Keywords: Chemistry
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  • 77
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-09-28
    Keywords: Chemistry
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  • 78
    Publication Date: 2018-09-28
    Description: Some of the simplest and most powerful carbon-carbon bond forming strategies take advantage of readily accessible ubiquitous motifs: carbonyls and olefins. Here we report a fundamentally distinct mode of reactivity between carbonyls and olefins that differs from established acid-catalyzed carbonyl-ene, Prins, and carbonyl-olefin metathesis reaction paths. A range of epsilon, zeta-unsaturated ketones undergo Brønsted acid–catalyzed intramolecular cyclization to provide tetrahydrofluorene products via the formation of two new carbon-carbon bonds. Theoretical calculations and accompanying mechanistic studies suggest that this carbocyclization reaction proceeds through the intermediacy of a transient oxetane formed by oxygen atom transfer. The complex polycyclic frameworks in this product class appear as common substructures in organic materials, bioactive natural products, and recently developed pharmaceuticals.
    Keywords: Chemistry
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  • 79
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-09-28
    Description: Alkene aminoarylation with a single, bifunctional reagent is a concise synthetic strategy. We report a catalytic protocol for the addition of arylsulfonylacetamides across electron-rich alkenes with complete anti-Markovnikov regioselectivity and excellent diastereoselectivity to provide 2,2-diarylethylamines. In this process, single-electron alkene oxidation enables carbon-nitrogen bond formation to provide a key benzylic radical poised for a Smiles-Truce 1,5-aryl shift. This reaction is redox-neutral, exhibits broad functional group compatibility, and occurs at room temperature with loss of sulfur dioxide. As this process is driven by visible light, uses readily available starting materials, and demonstrates convergent synthesis, it is well suited for use in a variety of synthetic endeavors.
    Keywords: Chemistry
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  • 80
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-10-05
    Keywords: Chemistry
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  • 81
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-10-05
    Keywords: Chemistry
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  • 82
    Publication Date: 2018-10-05
    Description: Photocatalysis based on optically active, "plasmonic" metal nanoparticles has emerged as a promising approach to facilitate light-driven chemical conversions under far milder conditions than thermal catalysis. However, an understanding of the relation between thermal and electronic excitations has been lacking. We report the substantial light-induced reduction of the thermal activation barrier for ammonia decomposition on a plasmonic photocatalyst. We introduce the concept of a light-dependent activation barrier to account for the effect of light illumination on electronic and thermal excitations in a single unified picture. This framework provides insight into the specific role of hot carriers in plasmon-mediated photochemistry, which is critically important for designing energy-efficient plasmonic photocatalysts.
    Keywords: Chemistry
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  • 83
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-10-12
    Keywords: Chemistry
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  • 84
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-10-12
    Keywords: Chemistry
    Print ISSN: 0036-8075
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 85
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-10-12
    Description: Single-electron reduction of a carbonyl to a ketyl enables access to a polarity-reversed platform of reactivity for this cornerstone functional group. However, the synthetic utility of the ketyl radical is hindered by the strong reductants necessary for its generation, which also limit its reactivity to net reductive mechanisms. We report a strategy for net redox-neutral generation and reaction of ketyl radicals. The in situ conversion of aldehydes to α-acetoxy iodides lowers their reduction potential by more than 1 volt, allowing for milder access to the corresponding ketyl radicals and an oxidative termination event. Upon subjecting these iodides to a dimanganese decacarbonyl precatalyst and visible light irradiation, an atom transfer radical addition (ATRA) mechanism affords a broad scope of vinyl iodide products with high Z -selectivity.
    Keywords: Chemistry
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    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 86
    Publication Date: 2018-10-12
    Description: Reactions that form a product with the same reactive functionality as that of one of the starting compounds frequently end in oligomerization. As a salient example, selective aldol coupling of the smallest, though arguably most useful, enolizable aldehyde, acetaldehyde, with just one partner substrate has proven to be extremely challenging. Here, we report a highly enantioselective Mukaiyama aldol reaction with the simple triethylsilyl (TES) and tert -butyldimethylsilyl (TBS) enolates of acetaldehyde and various aliphatic and aromatic acceptor aldehydes. The reaction is catalyzed by recently developed, strongly acidic imidodiphosphorimidates (IDPi), which, like enzymes, display a confined active site but, like small-molecule catalysts, have a broad substrate scope. The process is scalable, fast, efficient (0.5 to 1.5 mole % catalyst loading), and greatly simplifies access to highly valuable silylated acetaldehyde aldols.
    Keywords: Chemistry
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  • 87
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-12-21
    Keywords: Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 88
    Publication Date: 2018-12-21
    Description: Single-molecule magnets (SMMs) containing only one metal center may represent the lower size limit for molecule-based magnetic information storage materials. Their current drawback is that all SMMs require liquid-helium cooling to show magnetic memory effects. We now report a chemical strategy to access the dysprosium metallocene cation [(Cp i Pr5 )Dy(Cp*)] + (Cp i Pr5 , penta-iso-propylcyclopentadienyl; Cp *, pentamethylcyclopentadienyl), which displays magnetic hysteresis above liquid-nitrogen temperatures. An effective energy barrier to reversal of the magnetization of U eff = 1541 wave number is also measured. The magnetic blocking temperature of T B = 80 kelvin for this cation overcomes an essential barrier toward the development of nanomagnet devices that function at practical temperatures.
    Keywords: Chemistry
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  • 89
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-10-19
    Keywords: Chemistry
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    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 90
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-10-19
    Description: The development of highly reactive and stereoselective catalytic systems is required not only to improve existing synthetic methods but also to invent distinct chemical reactions. Herein, a homogenized combination of nickel-based Lewis acid–surfactant-combined catalysts and single-walled carbon nanotubes is shown to exhibit substantial activity in water. In addition to the enhanced reactivity, stereoselective performance and long-term stability were demonstrated in asymmetric conjugate addition reactions of aldoximes to furnish chiral nitrones in high yields with excellent selectivities. The practical and straightforward application of the designed catalysts in water provides an expedient, environmentally benign, and highly efficient pathway to access optically active compounds.
    Keywords: Chemistry
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  • 91
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-11-02
    Keywords: Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 92
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-12-14
    Keywords: Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 93
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-10-26
    Keywords: Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 94
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-11-02
    Description: Exploration of intermediates that enable chemoselective cycloaddition reactions and expeditious construction of fused- or bridged-ring systems is a continuous challenge for organic synthesis. As an intermediate of interest, the oxyallyl cation has been harnessed to synthesize architectures containing seven-membered rings via (4+3) cycloaddition. However, its potential to access five-membered skeletons is underdeveloped, largely due to the thermally forbidden (3+2) pathway. Here, the combination of a tailored precursor and a Pd(0) catalyst generates a Pd-oxyallyl intermediate that cyclizes with conjugated dienes to produce a diverse array of tetrahydrofuran skeletons. The cycloaddition overrides conventional (4+3) selectivity by proceeding through a stepwise pathway involving a Pd-allyl transfer and ring closure sequence. Subsequent treatment of the (3+2) adducts with a palladium catalyst converts the heterocycles to the carbocyclic cyclopentanones.
    Keywords: Chemistry
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  • 95
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-11-16
    Keywords: Chemistry
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  • 96
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-08-10
    Keywords: Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 97
    Publication Date: 2018-08-10
    Description: Understanding the practical limitations of chemical reactions is critically important for efficiently planning the synthesis of compounds in pharmaceutical, agrochemical, and specialty chemical research and development. However, literature reports of the scope of new reactions are often cursory and biased toward successful results, severely limiting the ability to predict reaction outcomes for untested substrates. We herein illustrate strategies for carrying out large-scale surveys of chemical reactivity by using a material-sparing nanomole-scale automated synthesis platform with greatly expanded synthetic scope combined with ultrahigh-throughput matrix-assisted laser desorption/ionization–time-of-flight mass spectrometry (MALDI-TOF MS).
    Keywords: Chemistry
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  • 98
    Publication Date: 2018-08-24
    Description: Researchers around the world have observed the formation of molecularly ordered structures of unknown origin on the surface of titanium dioxide (TiO 2 ) photocatalysts exposed to air and solution. Using a combination of atomic-scale microscopy and spectroscopy, we show that TiO 2 selectively adsorbs atmospheric carboxylic acids that are typically present in parts-per-billion concentrations while effectively repelling other adsorbates, such as alcohols, that are present in much higher concentrations. The high affinity of the surface for carboxylic acids is attributed to their bidentate binding. These self-assembled monolayers have the unusual property of being both hydrophobic and highly water-soluble, which may contribute to the self-cleaning properties of TiO 2 . This finding is relevant to TiO 2 photocatalysis, because the self-assembled carboxylate monolayers block the undercoordinated surface cation sites typically implicated in photocatalysis.
    Keywords: Chemistry
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  • 99
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-08-31
    Keywords: Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 100
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-08-31
    Keywords: Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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