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  • 1
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 32 (2017): 512–530, doi:10.1002/2016PA003072.
    Beschreibung: The carbon isotope composition (δ13C) of seawater provides valuable insight on ocean circulation, air-sea exchange, the biological pump, and the global carbon cycle and is reflected by the δ13C of foraminifera tests. Here more than 1700 δ13C observations of the benthic foraminifera genus Cibicides from late Holocene sediments (δ13CCibnat) are compiled and compared with newly updated estimates of the natural (preindustrial) water column δ13C of dissolved inorganic carbon (δ13CDICnat) as part of the international Ocean Circulation and Carbon Cycling (OC3) project. Using selection criteria based on the spatial distance between samples, we find high correlation between δ13CCibnat and δ13CDICnat, confirming earlier work. Regression analyses indicate significant carbonate ion (−2.6 ± 0.4) × 10−3‰/(μmol kg−1) [CO32−] and pressure (−4.9 ± 1.7) × 10−5‰ m−1 (depth) effects, which we use to propose a new global calibration for predicting δ13CDICnat from δ13CCibnat. This calibration is shown to remove some systematic regional biases and decrease errors compared with the one-to-one relationship (δ13CDICnat = δ13CCibnat). However, these effects and the error reductions are relatively small, which suggests that most conclusions from previous studies using a one-to-one relationship remain robust. The remaining standard error of the regression is generally σ ≅ 0.25‰, with larger values found in the southeast Atlantic and Antarctic (σ ≅ 0.4‰) and for species other than Cibicides wuellerstorfi. Discussion of species effects and possible sources of the remaining errors may aid future attempts to improve the use of the benthic δ13C record.
    Beschreibung: U.S. National Science Foundation Grant Numbers: 1634719, 0926735, 1125181; Swiss National Science Foundation Grant Numbers: PP00P2_144811, 200021_163003; Canadian Institute for Advanced Research (CIFAR); Canadian Foundation for Innovation (CFI); Natural Sciences and Engineering Research Council (NSERC)
    Beschreibung: 2017-12-03
    Schlagwort(e): Carbon ; Isotopes ; Benthic ; Foraminifera ; Calibration
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 45 (2018): 4171-4179, doi:10.1029/2017GL076498.
    Beschreibung: Estimated rates and efficiency of ocean carbon export flux are sensitive to differences in the depth horizons used to define export, which often vary across methodological approaches. We evaluate sinking particulate organic carbon (POC) flux rates and efficiency (e‐ratios) in a global earth system model, using a range of commonly used depth horizons: the seasonal mixed layer depth, the particle compensation depth, the base of the euphotic zone, a fixed depth horizon of 100 m, and the maximum annual mixed layer depth. Within this single dynamically consistent model framework, global POC flux rates vary by 30% and global e‐ratios by 21% across different depth horizon choices. Zonal variability in POC flux and e‐ratio also depends on the export depth horizon due to pronounced influence of deep winter mixing in subpolar regions. Efforts to reconcile conflicting estimates of export need to account for these systematic discrepancies created by differing depth horizon choices.
    Beschreibung: Woods Hole Oceanographic Institution (WHOI); National Science Foundation Grant Number: OCE‐1434000
    Beschreibung: 2018-10-23
    Schlagwort(e): Carbon ; Export ; Ocean
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Solid Earth 123 (2018): 7824-7849, doi:10.1029/2017JB015346.
    Beschreibung: We construct a new seismic model for central and West Antarctica by jointly inverting Rayleigh wave phase and group velocities along with P wave receiver functions. Ambient noise tomography exploiting data from more than 200 seismic stations deployed over the past 18 years is used to construct Rayleigh wave phase and group velocity dispersion maps. Comparison between the ambient noise phase velocity maps with those constructed using teleseismic earthquakes confirms the accuracy of both results. These maps, together with P receiver function waveforms, are used to construct a new 3‐D shear velocity (Vs) model for the crust and uppermost mantle using a Bayesian Monte Carlo algorithm. The new 3‐D seismic model shows the dichotomy of the tectonically active West Antarctica (WANT) and the stable and ancient East Antarctica (EANT). In WANT, the model exhibits a slow uppermost mantle along the Transantarctic Mountains (TAMs) front, interpreted as the thermal effect from Cenozoic rifting. Beneath the southern TAMs, the slow uppermost mantle extends horizontally beneath the traditionally recognized EANT, hypothesized to be associated with lithospheric delamination. Thin crust and lithosphere observed along the Amundsen Sea coast and extending into the interior suggest involvement of these areas in Cenozoic rifting. EANT, with its relatively thick and cold crust and lithosphere marked by high Vs, displays a slower Vs anomaly beneath the Gamburtsev Subglacial Mountains in the uppermost mantle, which we hypothesize may be the signature of a compositionally anomalous body, perhaps remnant from a continental collision.
    Beschreibung: National Science Foundation Grant Numbers: PLR‐1142518, PLR‐1246712, PLR 1246151, PLR‐1246416, PLR‐1744883, PLR‐ 1744883
    Beschreibung: 2019-03-22
    Schlagwort(e): Seismology ; Crust and uppermost mantle ; Ambient noise tomography ; Antarctica ; Transantarctic Mountains ; Gamburtsev Mountains
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
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    John Wiley & Sons
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Biogeosciences 120 (2015): 1825–1838, doi:10.1002/2015JG003044.
    Beschreibung: We studied marsh-atmosphere exchange of carbon dioxide in a high marsh dominated salt marsh during the months of May to October in 2012–2014. Tidal inundation at the site occurred only during biweekly spring tides, during which we observed a reduction in fluxes during day and night. We estimated net ecosystem exchange (NEE), gross primary production (GPP), and ecosystem respiration (Reco) using a modified PLIRTLE model, which requires photosynthetically active radiation, temperature, and normalized difference vegetation index (NDVI) as control variables. NDVI decreased during inundation, when the marsh canopy was submerged. Two-time series of NDVI, including and excluding effects of tidal inundation, allowed us to quantify the flux reduction during inundation. The effect of the flux reduction was small (2–4%) at our site, but is likely higher for marshes at a lower elevation. From May to October, GPP averaged −863 g C m−2, Reco averaged 591 g C m−2, and NEE averaged −291 g C m−2. In 2012, which was an exceptionally warm year, we observed an early start of net carbon uptake but higher respiration than in 2013 and 2014 due to higher-air temperature in August. This resulted in the lowest NEE during the study period (−255.9±6.9 g C m−2). The highest seasonal net uptake (−336.5±6.3 g C m−2) was observed in 2013, which was linked to higher rainfall and temperature in July. Mean sea level was very similar during all 3 years which allowed us to isolate the importance of climatic factors.
    Beschreibung: NSF grants OCE-1058747 and OCE-1238212
    Beschreibung: 2019-03-29
    Schlagwort(e): Salt marsh ; Eddy covariance ; Inundation ; NDVI ; Tide ; Carbon
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Format: application/pdf
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 122 (2017): 3696–3714, doi:10.1002/2016JC012460.
    Beschreibung: We present 34 profiles of radon-deficit from the ice-ocean boundary layer of the Beaufort Sea. Including these 34, there are presently 58 published radon-deficit estimates of air-sea gas transfer velocity (k) in the Arctic Ocean; 52 of these estimates were derived from water covered by 10% sea ice or more. The average value of k collected since 2011 is 4.0 ± 1.2 m d−1. This exceeds the quadratic wind speed prediction of weighted kws = 2.85 m d−1 with mean-weighted wind speed of 6.4 m s−1. We show how ice cover changes the mixed-layer radon budget, and yields an “effective gas transfer velocity.” We use these 58 estimates to statistically evaluate the suitability of a wind speed parameterization for k, when the ocean surface is ice covered. Whereas the six profiles taken from the open ocean indicate a statistically good fit to wind speed parameterizations, the same parameterizations could not reproduce k from the sea ice zone. We conclude that techniques for estimating k in the open ocean cannot be similarly applied to determine k in the presence of sea ice. The magnitude of k through gaps in the ice may reach high values as ice cover increases, possibly as a result of focused turbulence dissipation at openings in the free surface. These 58 profiles are presently the most complete set of estimates of k across seasons and variable ice cover; as dissolved tracer budgets they reflect air-sea gas exchange with no impact from air-ice gas exchange.
    Beschreibung: NSF Arctic Natural Sciences program Grant Number: 1203558
    Beschreibung: 2017-11-05
    Schlagwort(e): Radon-deficit ; Air-sea gas exchange ; Sea ice ; Gas transfer velocity ; Air-sea flux ; Carbon
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Publikationsdatum: 2022-05-26
    Beschreibung: © The Author(s), 2016. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Ecosphere 7 (2016): e01251, doi:10.1002/ecs2.1251.
    Beschreibung: Nitrogen (N) supply often limits the productivity of temperate forests and is regulated by a complex mix of biological and climatic drivers. In excess, N is linked to a variety of soil, water, and air pollution issues. Here, we use results from an elevation gradient study and historical data from the long-term Hubbard Brook Ecosystem Study (New Hampshire, USA) to examine relationships between changes in climate, especially during winter, and N supply to northern hardwood forest ecosystems. Low elevation plots with less snow, more soil freezing, and more freeze/thaw cycles supported lower rates of N mineralization than high elevation plots, despite having higher soil temperatures and no consistent differences in soil moisture during the growing season. These results are consistent with historical analyses showing decreases in rates of soil N mineralization and inorganic N concentrations since 1973 that are correlated with long-term increases in mean annual temperature, decreases in annual snow accumulation, and a increases in the number of winter thawing degree days. This evidence suggests that changing climate may be driving decreases in the availability of a key nutrient in northern hardwood forests, which could decrease ecosystem production but have positive effects on environmental consequences of excess N.
    Beschreibung: U.S. National Science Foundation; Andrew W. Mellon Foundation; Spanish Ministry of Education; Portuguese Ministry of Education and Science Grant Number: SFRH/BDP/87966/2012
    Schlagwort(e): Carbon ; Global change ; Microbial activity mineralization ; Nitrification ; Nitrogen ; Soil frost
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Publikationsdatum: 2022-05-26
    Beschreibung: Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 30 (2016): 629–643, doi:10.1002/2015GB005351.
    Beschreibung: Northern rivers connect a land area of approximately 20.5 million km2 to the Arctic Ocean and surrounding seas. These rivers account for ~10% of global river discharge and transport massive quantities of dissolved and particulate materials that reflect watershed sources and impact biogeochemical cycling in the ocean. In this paper, multiyear data sets from a coordinated sampling program are used to characterize particulate organic carbon (POC) and particulate nitrogen (PN) export from the six largest rivers within the pan-Arctic watershed (Yenisey, Lena, Ob', Mackenzie, Yukon, Kolyma). Together, these rivers export an average of 3055 × 109 g of POC and 368 × 109 g of PN each year. Scaled up to the pan-Arctic watershed as a whole, fluvial export estimates increase to 5767 × 109 g and 695 × 109 g of POC and PN per year, respectively. POC export is substantially lower than dissolved organic carbon export by these rivers, whereas PN export is roughly equal to dissolved nitrogen export. Seasonal patterns in concentrations and source/composition indicators (C:N, δ13C, Δ14C, δ15N) are broadly similar among rivers, but distinct regional differences are also evident. For example, average radiocarbon ages of POC range from ~2000 (Ob') to ~5500 (Mackenzie) years before present. Rapid changes within the Arctic system as a consequence of global warming make it challenging to establish a contemporary baseline of fluvial export, but the results presented in this paper capture variability and quantify average conditions for nearly a decade at the beginning of the 21st century.
    Beschreibung: National Science Foundation Grant Numbers: 0229302, 0732985; U.S. Geological Survey; Department of Indian and Northern Affairs
    Beschreibung: 2016-11-11
    Schlagwort(e): Arctic ; River ; Carbon ; Nitrogen ; Watershed ; Export
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Standort Signatur Erwartet Verfügbarkeit
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