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  • 551
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  • 1
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    Univ. Stuttgart
    Publication Date: 2021-03-29
    Description: In this work the dune model introduced by Sauermann et al. (2001) is extended and applied to investigate the formation of different dune shapes on Mars and on Earth as function of wind directionality and sand availability. The formation of sand dunes on Mars under the present atmospheric conditions of the red planet is studied and conclusions about wind speed, migration velocity of dunes and changing wind regimes on Mars are presented. Field measurements of the shape of coastal transverse dunes are presented and the formation of coastal dune fields is explained. Finally, the formation of linear dunes by bimodal wind regimes is calculated. The simulations explain the appearance of exotic bimodal dune shapes in areas of low sand availability on Mars and on Earth.
    Description: thesis
    Keywords: 523 ; 551 ; 550 ; TGG 545 ; VAN 100 ; Marsoberfläche {Astronomie} ; Abspülung {Geologie}
    Language: English
    Type: monograph , publishedVersion
    Format: 171 S.
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  • 2
    Publication Date: 2021-03-29
    Description: Marine snow, underwater cameras, particle flux, aggregation, suspended particulate matter, particle transport. - This study focusses on the vertical distribution and transportation pathways of marine particles off NW-Africa with aid of optical methodologies. A profiling camera system and a remotely operated vehicle (ROV) was used for in-situ observations on the distribution, transport processes and sinking behaviour of marine particulate matter. Between the regional areas of investigation Cape Blanc, Dakhla and Cape Bojador significant differences could be observed with respect to distribution and transportation patterns. These differences are primarily related to the different primary production conditions between the investigation areas. Primary production is the most important factor for the abundance of particulate matter, where highest particle concentrations in the entire water column were seen off Cape Blanc. Next to primary production, water depth, currents and density gradients are factors influencing the particle distribution patterns. With respect to the prevailing transport processes, the Cape Blanc region is characterised by vertically orientated transport patterns. In addition to the continuous supply of large, relatively fast sinking particle aggregates a sinking event could be documented for the first time in-situ in the water column. These events deliver huge amounts of particulate matter from the ocean surface ...
    Description: thesis
    Keywords: 551
    Language: English
    Type: monograph , publishedVersion
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  • 3
    Publication Date: 2021-03-29
    Description: Madagascar; Jurassic; Karoo; Gondwana; Breakup; Rift; Microfauna; Macrofauna; Ammonites; Indian Ocean. - The breakup of Gondwana along the former East African Orogen is widely interpreted to have lasted from the Late Palaeozoic to the Callovian. The present study indicates that the Permian-Triassic or Karoo phase of rifting was not responsible for the separation of East- and West-Gondwana, since that rift system failed in the Late Triassic. Instead the breakup of Gondwana occurred in the Late Liassic. The pre-rift phase in the Morondava Basin is represented by the Karoo deposits, and the syn-rift phase is recorded by Toarcian marine shales, locally overlain by Aalenian sandstones. A major Early Bajocian unconformity is interpreted as the breakup unconformity. The initial post-rift or drift phase is represented by the Bajocian-Bathonian carbonates, marls and sandstones of coastal plain environment and a coastal barrier/lagoon complex. During the Bathonian the siliciclastic shoreface system moved basinward. Callovian-Early Kimmeridgian shales with interbedded iron-oolites represent ...
    Description: thesis
    Keywords: 551 ; VAE 500 ; VDB 100 ; VEQ 300 ; Geotektonische Entwicklung der Erdkruste {Geologie} ; Gondwana ; Madagaskar {Geologie}
    Language: English
    Type: monograph , publishedVersion
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  • 4
    Publication Date: 2021-03-29
    Description: thesis
    Keywords: 551 ; VBQ 900 ; VBQ 800 ; VEO 170 ; Hydrogeologie einzelner Regionen ; Aquifere {Hydrogeologie} ; Sudan {Geologie}
    Language: English
    Type: monograph , publishedVersion
    Format: 133 S.
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  • 5
    Publication Date: 2021-03-29
    Description: In the unglaciated areas of Antarctica, lake sediments act as archives of the regional environmental and climatic history. In most cases, the records are restricted to the Holocene. Amongst the few exceptions are lakes in the McMurdo Dry Valleys, southern Victoria Land, which are known to have remained mostly ice-free during the Last Glacial Maximum. Within the scope of an U.S.-American-German expedition in austral summer 2002/2003, several sediment cores were recovered from the three major lakes in the Taylor Valley: lakes Fryxell, Hoare, and Bonney. In order to reconstruct the late Quaternary regional environmental and climate history, sedimentological, biogeochemical, mineralogical, and chronological investigations were conducted on the sediment sequences recovered from Lake Hoare (core Lz1020) and East Lake Bonney (core Lz1023) within the scope of this thesis. Sediment cores from Lake Hoare with a maximum length of 2.3 m mainly consist of coarse-grained material and penetrate back into the late Weichselian, when Taylor Valley was occupied by the large proglacial Lake Washburn. This lake was dammed by the advanced Ross Sea ice sheet at the valley outlet and was mainly fed by meltwater of the ice sheet. During the Pleistocene-Holocene transition, enhanced evaporation led to a significant lake level drop of Lake Washburn ...
    Description: thesis
    Keywords: 551 ; 550 ; TWC 500 ; VDI 200 ; VAU 000 ; VEY 200 ; VBN 500 ; VBL 500 ; Klimaschwankungen und Klimaänderungen im Quartär ; Quartär ; Paläolimnologie {Geologie} ; Antarktis {Geologie} ; Geochronologie einzelner Regionen im allgemeinen ; Geologische Bohrungen in einzelnen Regionen
    Language: English
    Type: monograph , publishedVersion
    Format: 121 S.
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  • 6
    Publication Date: 2021-03-29
    Description: Eleven lakes and ponds and three lacustrine sediment sequences from coastal East and North-East Greenland were studied for recent hydrological and phytoplankton characteristics and for palaeolimnology, respectively. The limnological survey of lakes and ponds from Store Koldewey in summer 2003 revealed cold, monomictic, thermally unstratified, alkaline and likely oligotrophic water bodies. The diatom phytoplankton, present in six lakes and dominated by four species, varied distinctly between the lakes. The results give information about the recent status of the ecology of these High Arctic freshwater bodies. The sediment sequences were investigated for their chronology, changes in physical and biogeochemical properties, macro- and microfossils, grain-size distribution and in the case of one sequence for its elemental profiles using XRF. The palaeolimnological studies address different time intervals at various temporal resolutions with particular attention to the latitudinal differences of late Quaternary climatic and environmental changes along the coast of East and North-East Greenland. The results include information about the Late Weichselian ice-front environments on southern Store Koldewey with information about the temporal and spatial evolution of the Greenland Ice Sheet margin west of the island ...
    Description: thesis
    Keywords: 551 ; 550 ; TWC 500 ; VDI 200 ; VAU 000 ; VEY 110 ; VBN 500 ; VBL 500 ; Klimaschwankungen und Klimaänderungen im Quartär ; Quartär ; Paläolimnologie {Geologie} ; Grönland {Geologie} ; Geochronologie einzelner Regionen im allgemeinen ; Geologische Bohrungen in einzelnen Regionen
    Language: English
    Type: monograph , publishedVersion
    Format: 148 S.
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  • 7
    Publication Date: 2021-03-29
    Description: The polar ice sheets are unique paleoclimatic archives and play an important role in recent and future climate. The melting of the big freshwater reservoirs will not only increase the global sea level, but will also influence the ocean currents. Therefore, it will be of particular interest to improve the currently available numeric climate models to achieve more accurate statements about climatic change and its consequences. In this work, the evaluation and the different applications of GPS and altimetry data will be described in respect to enhance models. The antarctic area of investigation, Dronning Maud Land (DML), is of particular interest for German polar research, because both the overwintering station Neumayer and the summer station Kohnen are located within it. In the surroundings of these two stations, highly accurate kinematic GPS measurement were made, which will be the basis for the digital elevation model presented here. Because these data are spatially limited, they are supplemened with remotely sensed data. For this purpose, two airborne altimetry data sets and spaceborne laser altimetry data of the Ice, Cloud, and land Elevation Satellite (ICESat) are used...
    Description: thesis
    Keywords: 551.312 ; 551 ; 550 ; TWC 600 ; VAR 980 ; TQI 000 ; TSY 200 ; Geophysikalische Satellitenfernerkundung ; Antarktis {Geophysik}
    Language: English
    Type: monograph , publishedVersion
    Format: 140 S.
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  • 8
    Publication Date: 2021-03-29
    Description: Diese Arbeit beschäftigt sich mit der Verknüpfung von manuellen und automatischen Inversionmethoden für die Interpretation gravimetrischer Anomalien. Eine neue Software mit dem Namen 3GRAINS wird vorgestellt. Sie wurde für das manuelle Modellieren entwickelt und benutzt rechteckförmige Prismen zur Berechnung des gravimetrischen Effekts eines Modells. Die Software bietet eine graphische Benutzeroberfläche, um eine komfortable Arbeit mit einer modellierten Struktur zu ermöglichen. Ein automatischer Inversionsalgorithmus basiert auf der Idee der evolutionären Berechnung. Die dargestellten Methoden werden auf die Interpretation der gravimetrischen Anomalien der Hellenischen Subduktionszone angewendet. Die tektonische Situation dieser Region und seismische Beobachtungen werden vorgestellt. Der Prozess der Datengewinnung und der Datenbearbeitung wird beschrieben. Schließlich werden die Ergebnisse der Interpretation der gravimetrischen Anomalien präsentiert.
    Description: thesis
    Keywords: 551 ; 622.15 ; 550 ; TOF 000 ; TQA 000 ; TSF 300 ; VAE 880 ; VEF 300 ; Schwerkraft {Geophysik} ; Gravimetrische Verfahren {Geophysik} ; Griechenland und griechische Inseln {Geophysik} ; Passive und aktive Kontinentalränder {Geologie} ; Griechenland und griechische Inseln {Geologie}
    Language: English
    Type: monograph , publishedVersion
    Format: 139 S.
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  • 9
    Publication Date: 2021-03-29
    Description: Central Asia is characterized by a number of spectacular tectonic units such as the Tibetan Plateau, the Tien Shan intra-continental mountain belt and the Altyn Tagh strike-slip fault. Deformation of the lithosphere of these units is not well understood. In this dissertation, an attempt is made to answer the following tectonic questions: To what extent do the tectonic units formed in the upper crust in the course of the convergence between India and Eurasia weaken the underlying lithosphere? How is the Tibetan Plateau gravita-tionally compensated along its northern boundary? Do the Altyn Tagh and/or West Kunlun faults persist as vertical strike-slips throughout the crust and mantle lithosphere, thus representing a fundamental plate boundary? Which dynamic processes in the crust and mantle of the Tien Shan are responsible for intra-continental mountain building? What characterizes the local stress field in the Tien Shan and what causes the deformation of these mountains? To answer these questions, the elastic plate theory is used to interpret gravity and topography data, and in turn to derive specific characteristics of the lithospheric structure in Central Asia. Theoretical deflection of the elastic plate or plates were calculated using the 3D and 2D finite-difference methods. Variable-rigidity elastic plates are subjected to vertical and horizontal loads, shear forces, and terminal bending moments. Surface topo-graphic data from the Topo30 dataset is used as vertical surface loading to calculate the flexure of the elastic lithosphere...
    Description: thesis
    Keywords: 551.8 ; 622.15 ; 551 ; 550 ; VAE 400 ; VEK 000 ; TQA 000 ; TSK 000 ; VAE 400 ; VEK 000 ; TQA 000 ; TSK 000 ; Tektogenese {Geologie} ; Zentralasien {Geologie} ; Gravimetrische Verfahren {Geophysik} ; Zentralasien {Geophysik}
    Language: English
    Type: monograph , publishedVersion
    Format: 136 Bl.
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  • 10
    Publication Date: 2021-03-29
    Description: thesis
    Keywords: 551 ; UNC 300 ; Höhe {Praktische Geodäsie}
    Language: English
    Type: monograph , publishedVersion
    Format: 163 S.
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  • 11
    Publication Date: 2021-03-29
    Description: thesis
    Keywords: 551 ; VAE 890 ; VAE 130 ; VBE 000 ; TOE 000 ; TSX 500 ; VEX 500 ; Ozeanische Kruste {Tektonik} ; Geomechanik ; Modellierung von Prozessen in der Geosphäre ; Physikalisches Verhalten der Erde {Geophysik} ; Chile {Geophysik} ; Chile {Geologie}
    Language: English
    Type: monograph , publishedVersion
    Format: 118 S.
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  • 12
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    GFZ, Helmholtz-Zentrum
    Publication Date: 2021-03-29
    Description: thesis
    Keywords: 551 ; TSX 500 ; VEX 100 ; VEX 500 ; VAE 500 ; TOH 800 ; Chile {Geophysik} ; Anden {Geologie} ; Chile {Geologie} ; Geotektonische Entwicklung der Erdkruste {Geologie} ; Paläoerdbeben {Geophysik}
    Language: English
    Type: monograph , publishedVersion
    Format: 108 S.
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  • 13
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    GFZ, Helmholtz-Zentrum
    Publication Date: 2021-03-29
    Description: Ein transversales Störungssystem im Nahen Osten, die Dead Sea Transform (DST), trennt die Arabische Platte von der Sinai-Mikroplatte und erstreckt sich von Süden nach Norden vom Extensionsgebiet im Roten Meer über das Tote Meer bis zur Taurus-Zagros Kollisionszone. Die sinistrale DST bildete sich im Miozän vor etwa 17 Ma und steht mit dem Aufbrechen des Afro-Arabischen Kontinents in Verbindung. Das Untersuchungsgebiet liegt im Arava Tal zwischen Totem und Rotem Meer, mittig über der Arava Störung (Arava Fault, AF), die hier den Hauptast der DST bildet. Eine Reihe seismischer Experimente, aufgebaut aus künstlichen Quellen, linearen Profilen über die Störung und entsprechend entworfenen Empfänger-Arrays, zeigt die Untergrundstruktur in der Umgebung der AF und der Verwerfungszone selbst bis in eine Tiefe von 3-4 km. Ein tomographisch bestimmtes Modell der seismischen Geschwindigkeiten von P-Wellen zeigt einen starken Kontrast nahe der AF mit niedrigeren Geschwindigkeiten auf der westlichen Seite als im Osten. Scherwellen lokaler Erdbeben liefern ein mittleres P-zu-S Geschwindigkeitsverhältnis und es gibt Anzeichen für Änderungen über die Störung hinweg ...
    Description: thesis
    Keywords: 551 ; VAE 850 ; TQC 220 ; TSI 000 ; VEI 400 ; Festländische Lineamente {Geologie} ; Reflexionsseismik {Geophysik} ; Vorderasien {Geophysik} ; Israel, Palästina {Geologie}
    Language: English
    Type: monograph , publishedVersion
    Format: 142 S.
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  • 14
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    GFZ, Helmholtz-Zentrum
    Publication Date: 2021-03-29
    Description: report
    Keywords: 551 ; TQH 000 ; TQA 000 ; TOF 000 ; Aerogeophysik ; Gravimetrische Verfahren {Geophysik} ; Schwerkraft {Geophysik}
    Language: English
    Type: article , publishedVersion
    Format: 48 S.
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  • 15
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    GFZ, Helmholtz-Zentrum
    Publication Date: 2021-03-29
    Description: report
    Keywords: 551
    Language: English
    Type: article , publishedVersion
    Format: 106 S.
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  • 16
    Publication Date: 2021-03-29
    Description: report
    Keywords: 551 ; TOB 300 ; TOD 500 ; TOF 000 ; TOT 400 ; Polbewegungen {Geophysik: Erde} ; Erdkern {Geophysik} ; Schwerkraft {Geophysik} ; Magnetfeld der Erde im allgemeinen {Geophysik}
    Language: English
    Type: article , publishedVersion
    Format: 15 S.
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  • 17
    Publication Date: 2021-03-29
    Description: thesis
    Keywords: 518.64 ; 551 ; TOD 400 ; TOE 000 ; TM 300 ; Erdmantel {Geophysik} ; Physikalisches Verhalten der Erde {Geophysik} ; Methodik. Arbeitsmittel. Abkürzungsverzeichnisse {Geophysik}
    Language: English
    Type: monograph , publishedVersion
    Format: 186 S.
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  • 18
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    GFZ, Helmholtz-Zentrum, Potsdam
    Publication Date: 2021-03-29
    Description: report
    Keywords: 551 ; TOF 000 ; TOB 100 ; Schwerkraft {Geophysik} ; Drehbewegungen {Geophysik: Erde}
    Language: English
    Type: article , publishedVersion
    Format: 35S.
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  • 19
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    GFZ, Helmholtz-Zentrum
    Publication Date: 2021-03-29
    Description: lecture
    Keywords: 551
    Language: English
    Type: anthology , publishedVersion
    Format: 675 S.
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  • 20
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    GFZ, Helmholtz-Zentrum
    Publication Date: 2021-03-29
    Description: report
    Keywords: 551 ; TOB 100 ; Drehbewegungen {Geophysik: Erde}
    Language: English
    Type: article , publishedVersion
    Format: 8 S.
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  • 21
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    GFZ, Helmholtz-Zentrum
    Publication Date: 2021-03-29
    Description: report
    Keywords: 551 ; TOB 300 ; Polbewegungen {Geophysik: Erde}
    Language: English
    Type: article , publishedVersion
    Format: 9 S.
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  • 22
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    GFZ, Helmholtz-Zentrum
    Publication Date: 2021-03-29
    Description: report
    Keywords: 551
    Language: English
    Type: article , publishedVersion
    Format: 39 S.
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  • 23
    Publication Date: 2021-03-29
    Description: report
    Keywords: 551
    Language: English
    Type: article , publishedVersion
    Format: 28 S.
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  • 24
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    GFZ, Potsdam | [Bibliothek des Wiss.-Parks Albert Einstein] [Vertrieb], [Potsdam]
    Publication Date: 2021-03-29
    Description: thesis
    Keywords: 551 ; VAE 140 ; VAE 820 ; VAE 160 ; VEB 110 ; TSB 000 ; VBM 000 ; Gesteinsdeformation {Strukturgeologie} ; Sedimentationsbecken als Erdkrustentypen {Geologie} ; Salztektonik {Strukturgeologie} ; Norddeutsche Senke {Geologie} ; Mitteleuropa {Geophysik} ; Geologische Interpretation geophysikalischer Beobachtungen
    Language: English
    Type: monograph , publishedVersion
    Format: 105 S.
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  • 25
    Publication Date: 2021-03-29
    Description: report
    Keywords: 551 ; TVA 000 ; TVM 800 ; TUB 000 ; Ionosphäre {Meteorologie} ; Struktur der Atmosphäre {Meteorologie} ; Atmosphärische Schwerewellen {Meteorologie} ; Beobachtungsergebnisse {Meteorologie}
    Language: English
    Type: article , publishedVersion
    Format: 96 S.
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  • 26
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    GFZ, Helmholtz-Zentrum | [Bibliothek des Wiss.-Parks Albert Einstein] [Vertrieb], [Potsdam]
    Publication Date: 2021-03-29
    Description: The glacial-isostatic adjustment in Iceland resulting from the recent melting of the Vatnajökull ice cap is controlled by the viscosity distribution in the earth's interior and by the details of the melting history. Interpretations of the results of GPS and gravity measuring campaigns in the time interval 1991-2000 and 1992-1999, respectively, by means of laterally homogeneous earth models for the determination of the lithosphere thickness, the asthenosphere thickness and the asthenosphere viscosity have so far been not fully satisfactory. In particular near the ice margin, the fitting of the computed land uplift and gravity change to the observational data was inadequate, which may be related to the neglegt of the Iceland plume in the laterally homogeneous earth models. In the present study, a program package is used for the modelling of the land uplift and gravity change that allows the computation of load-induced perturbations of a Maxwell-viscoelastic, incompressible, self-gravitating, spherical earth model. To simulate the presence of the plume below the Vatnajökull, an axisymmetric viscosity distribution is used, where the plume radius and the plume viscosity are free parameters. Based on seismic results, a 6-km-thick lithosphere is assumed above the plume, which thickens to 35 km in the peripheral region of the plume. The melting history of the Vatnajökull is founded on interpretations of geomorphological and climatological investigations and is simulated by a load co-axial with the plume with parabolic profile and time-dependent radius. The results of the modelling favour a plume radius of ~80 km and a plume viscosity of (0.3-1.0) x 10^{18} Pa s.
    Description: report
    Keywords: 551
    Language: English
    Type: article , publishedVersion
    Format: 20 S.
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  • 27
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    GFZ, Helmholtz-Zentrum | [Bibliothek des Wiss.-Parks Albert Einstein] [Vertrieb], [Potsdam]
    Publication Date: 2021-03-29
    Description: report
    Keywords: 551 ; VAE 300 ; TQI 000 ; UNH 100 ; Epirogenese {{Geologie}} ; Geophysikalische Satellitenfernerkundung ; GPS {Praktische Geodäsie}
    Language: English
    Type: article , publishedVersion
    Format: 28 S.
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  • 28
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    GFZ, Helmholtz-Zentrum | [Bibliothek des Wiss.-Parks Albert Einstein] [Vertrieb], [Potsdam]
    Publication Date: 2021-03-29
    Description: report
    Keywords: 551
    Language: English
    Type: article , publishedVersion
    Format: 228 S.
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  • 29
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    GFZ, Helmholtz-Zentrum | [Bibliothek des Wissenschaftsparks Albert Einstein] [Vertrieb], [Potsdam]
    Publication Date: 2021-03-29
    Description: thesis
    Keywords: 551 ; TOH 530 ; VAE 200 ; VAE 130 ; Häufigkeit und Verbreitung von Erdbeben {Geophysik} ; Geodynamik der Lithosphäre {Geologie} ; Geomechanik
    Language: English
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  • 30
    Publication Date: 2021-03-29
    Description: The route of the field trip described in this excursion guide follows a section through Germany from North to South, from the area of the Northern glaciation, to the Alpine glacial advances. It includes several places of historical importance, where milestones in Quaternary research have been achieved in the past, as well as new interesting sites where results of recent research is presented.
    Description: excursionguide
    Keywords: 551 ; V 000 ; VCA 520 ; Geologische Wissenschaften ; Quartärgeologie ; coastal evolution; Rügen ; Geopark Mecklenburg Ice Age Landscape ; tourism ; quaternary ; Halle ; Main ; sedimentology ; landslide ; natural hazards ; danube ; rhine ; pleistocene ; holocene ; geology
    Language: English
    Type: anthology , publishedVersion
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  • 31
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    Geozon Science Media
    Publication Date: 2021-03-29
    Description: Die Umgebung von Bayreuth sticht durch ungewöhnliche Vielfalt geologischer und tektonischer Besonderheiten hervor. Gesteine vom Altpaläozoikum bis zum Quartär treten auf. Das „Fränkische Lineament“ nebst der ihm vorgelagerten „Bruchschollenzone“ in mesozoischen Sedimentgesteinen, der Eklogit vom Weißenstein (einziger europäischer Eklogit nördlich der Alpen) und quartäre Vulkanite, mit denen sich schon Johann Wolfgang von Goethe beschäftigt hat, sind einzigartige Zeugnisse vielseitiger endogener Prozesse in der Umgebung von Bayreuth. Der vorliegende Band „DEUQUA EXCURSIONS“ wurde für die 36. Tagung der DEUQUA in Bayreuth vom 16. bis 20. September 2012 erstellt und umfasst sechs Exkursionen in der Region.
    Description: excursionguide
    Keywords: 551 ; VEB 212 ; VEB 148 ; Bayern {Geologie} ; Oberfränkisch-oberpfälzisches Schollenland {Geologie} ; field trip ; Exkursion ; Bayreuth ; landscape development ; quaternary ; paleozoic ; Archäologie ; Archaeology ; Landschaftsentwicklung
    Language: English
    Type: anthology , publishedVersion , anthology
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  • 32
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    GEOMAR, Helmholtz-Zentrum für Ozeanforschung Kiel und Institut für Geowissenschaften der Universität Kiel
    Publication Date: 2021-03-29
    Description: The 14th Symposium on Tectonics, Structural Geology and Geology of Crystalline Rocks (TSK14) is the first TSK meeting to be held on the coast. Northern Germany is void of metamorphic and structural geology outcrops and study of their processes requires going underground into salt mines or driving as far as the Harz Mountains. This is precisely what we will do for the field trip. Nevertheless, marine research is much closer to the TSK topics than might be expected. The plate tectonics revolution in the end of the 60s of last century would not have been possible without research on the oceans. Many structural concepts for deformed rock associations found on the continents have their modern counterparts below the oceans. Today, marine research cruises contribute significantly to tectonic research using a multitude of geophysical methods, sampling of the ocean floor, and deep sea drilling. The collaborative research center (SFB) 574 "Volatiles and Fluids in Subduction Zones", a joint research venture between Christian- Albrechts-University Kiel and the GEOMAR Helmholtz Centre for Ocean Research Kiel, combines marine and onshore research on subduction zone processes in Central and South America. Among other topics the DFG-funded Excellence Cluster “The Future Ocean” is concerned with marine geohazards and georesources and, thus, tectonic studies. Related results in marine geophysics, tectonics, metamorphic and magmatic petrology will be presented during TSK14, as well as several results from other marine and onshore research projects. We also invite you to gather some deeper insights into our work and our research facilities. The program of the symposium covers a wide range of current research in tectonics, geodynamics, structural geology and metamorphic petrology. We were overwhelmed by the large variety and the high quality of the submitted contributions. As the contributions did not go through a peer-review, the authors remain responsible for the content of their abstracts. There will be talks and posters on all of the six initially announced topics 1) Subduction zones and collisional orogens, 2) Rifting, spreading and transform faults, 3) Metamorphism, deformation and geochronology, 4) Fabrics, rheology and deformation mechanisms, 5) Brittle deformation, neotectonics and earthquake processes, 6) Pluton emplacement, volcano-tectonics und impact geology, with many contributions covering two and more of them.
    Description: Das 14. Symposium 'Tektonik-Strukturgeologie-Kristallingeologie' (TSK 14) ist das erste TSKTreffen, das an der Küste stattfindet. Norddeutschland ist frei an metamorphen und strukturgeologischen Aufschlüssen, und diese Forschung erfordert Untertagearbeit in Salzbergwerken oder Fahrten zumindest bis zum Harz. Genau dies ist für die Exkursion vorgesehen. Ungeachtet dessen liegt die Meeresforschung näher an den TSK-Themen, als es vielleicht erwartet wird. Die plattentektonische Revolution am Ende der 60er Jahre des letzten Jahrhunderts wäre ohne Meeresforschung nicht möglich gewesen. Viele strukturelle Konzepte deformierter Gesteinsvergesellschaftungen auf den Kontinenten finden ihre modernen Gegenstücke unter den Ozeanen. Heute tragen marine Forschungsfahrten durch die Anwendung geophysikalischer Methoden, Probennahmen vom Meeresboden oder Tiefseebohrprojekte bedeutend zur tektonischen Forschung bei. Der Sonderforschungsbereich SFB 574 "Volatile und Fluide in Subduktionszonen", ein Forschungsprogramm der Christian-Albrechts-Universität Kiel und des GEOMAR Helmholtz Zentrums für Ozeanforschung Kiel, verbindet Forschung im Meer und an Land zur Untersuchung von Subduktionszonen- Prozessen in Zentral- und Mittelamerika. Der von der DFG geförderte Exzellenzcluster "Ozean der Zukunft" befasst sich neben anderen Themen mit marinen Geogefahren und Georessourcen und somit mit tektonischen Studien. Damit verbundene Ergebnisse der marinen Geophysik, Tektonik, metamorphen und magmatischen Petrologie als auch Ergebnisse weiterer Meeres- und Küstenforschungsprojekte werden auf der TSK14 vorgestellt. Wir laden Sie auch ein, einen tieferen Einblick in unsere Forschungstätigkeit und Forschungseinrichtungen zu gewinnen. Das Programm des Symposiums umfasst eine weite Bandbreite aktueller Forschung in Tektonik, Geodynamik, Strukturgeologie und metamorpher Petrologie. Wir waren überwältigt von der großen Vielfalt und der hohen Qualität der eingereichten Beiträge. Da die Beiträge nicht begutachtet wurden, sind die Autoren allein für die Inhalte ihrer Kurzfassungen verantwortlich. Es wird Vorträge und Poster zu allen ursprünglich angekündigten Themenbereichen geben: 1) Subduktionszonen und Kollisionsorogene, 2) Rifting, Spreading und Transformstörungen, 3) Metamorphose, Deformation und Geochronologie, 4) Gefüge, Rheologie und Deformationsmechanismen, 5) Bruchhafte Deformation, Neotektonik und Erdbebenprozesse, 6) Platznahme von Plutonen, Vulkanotektonik und Impaktgeologie, wobei viele Beiträge zwei und mehr von diesen abdecken.
    Description: conference
    Keywords: 551 ; VAE 000 ; VAC 100 ; VAEA 000 ; VAE 100 ; VAE 200 ; Tektonik ; Strukturgeologie ; Tektonik {Geologie} ; Magmatismus im allgemeinen {Geologie} ; Metamorphose {Geologie} ; Strukturgeologie ; Geodynamik ; Kristallin
    Language: English
    Type: anthology , publishedVersion
    Format: 118 S.
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  • 33
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    Dteutsche Gesellschaft für Geowissenschaften, Hannover
    Publication Date: 2021-03-29
    Description: The Nördlinger Ries is a circular, flat depression of 22-24 km diameter separating the Jurassic limestone plateaus of the Franconian and Swabian Alb in Southwest-Germany. Its centre is located 110 km NW of Munich, 70 km SSW of Nuremberg and 110 km E of Stuttgart. The Ries basin was formed approximately 15 Million years ago (Gentner & Wagner, 1969; Staudacher et al., 1982) by an impact of a stony meteorite less than 1 km in size (Shoemaker & Chao, 1961; Stöffler, 1977). The Ries crater represents one of the best preserved and best investigated impact structures on Earth (Bayerisches Geologisches Landesamt 1969, 1974, 1977; Hüttner & Schmidt-Kaler 1999; Stöffler & Ostertag 1983). It gained wide public attention (e.g., Metz 1974, Steinert 1974, Lemcke 1981, Kavasch 1985, Pösges & Schieber 1994; Schieber 2004) and served as training site for Apollo 17 astronauts in August 1970 (e.g., Margolin 2000). However, apart from its impact nature, the Ries basin offers a great opportunity to study fossil lacustrine microbialites. Such lacustrine deposits within impact structures are of increasing interest for understanding the origin and evolution of early life on Earth, and possibly other planets (Cockell & Lee 2002, Osinski et al. 2005, Cabrol et al. 2001). Therefore, the focus on this field trip is on microbial and algal build-ups, their facies context, and the discussion of microbial effects and lake water chemistry.
    Description: excursionguide
    Keywords: 551 ; VKB 380 ; VEB 147 ; VDI 121 ; VKB 376 ; VAE 150 ; Sedimente bestimmter Regionen ; Schwäbische Alb und Fränkische Alb {Geologie} ; Miozän ; Organogene Sedimentgesteine ; Strukturelle Erscheinungen {Strukturgeologie} ; Ries ; Geologie ; Geologie ; Seesediment ; Biogenes Sediment ; 38.44 ; 38.28
    Language: English
    Type: article
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  • 34
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    Geologisches Institut der Georg-August-Universität Göttingen, Göttingen
    Publication Date: 2021-03-29
    Description: research
    Keywords: 551 ; VU 000 ; Geobiologie
    Language: English
    Type: anthologyArticle , publishedVersion
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  • 35
    Publication Date: 2021-03-29
    Description: In Schleswig-Holstein wurden in den zurückliegenden vier Jahrzehnten detaillierte Untersuchungen an Probenmaterial aus Aufschlüssen und Kernbohrungen durchgeführt. Analysen der Kiesfraktion und von ‚Leitgeschieben‘ aus glazialen Ablagerungen wurden für die Interpretation und Korrelation genutzt. Glazifluviatile Sedimente wurden TL- und OSL-datiert. Zusammen mit der stratigraphischen Information aus organischen Ablagerungen konnte eine neue klimatostratigraphische Tabelle des Pleistozäns für Schleswig-Holstein mit revidierter Gliederung des Mittel- und Oberpleistozäns erstellt werden. Die Pollensequenz der ältesten pleistozänen Warmzeit (Warmhörn-Thermomer) wird erstmals veröffentlicht. Das Unterpleistozän (Altpleistozän) und das untere Mittelpleistozän sind bei Lieth und bei Gorleben (Niedersachsen) in zwei kontinuierlichen Schichtfolgen vollständig dokumentiert, abgelagert in einem Wechsel von warmen und kalten Klimaphasen. Der oberste Abschnitt der Abfolge von Lieth und der unterste der Abfolge von Gorleben überlappen. Die kombinierte Abfolge bietet ein einzigartiges Referenzprofil für Korrelationen innerhalb Europas. Bisher wurden in Schleswig-Holstein nur drei Kaltzeiten mit Vergletscherungen nachgewiesen, Elster- und Saale-Kaltzeit im oberen Mittelpleistozän und die Weichsel-Kaltzeit im Oberpleistozän. Eine mögliche prä-elsterzeitliche Vergletscherung wird diskutiert. Die Holstein-Warmzeit wird mit MIS 9e korreliert. Das Saale umfasst einen unteren Abschnitt mit nicht-glaziären Kaltzeiten und mit Warmzeiten, der ‚Wacken-Warmzeit‘ (=Dömnitz) und der ‚Leck-Warmzeit‘, korreliert mit MIS 7e und MIS 7c, und einen glaziären oberen Abschnitt. Während des Weichsel gab es wahrscheinlich zwei Phasen mit Vergletscherung, die erste im frühen Mittelweichsel (‚Ellund-Phase‘, spätes MIS 4 oder/und frühes MIS 3), die zweite im oberen Weichsel (MIS 2). Die weichselzeitliche Vergletscherung Schleswig-Holsteins endet um 15 ka BP, als großflächige stagnierende Eisflächen und Toteismassen des Jungbaltischen Gletschervorstoßes (‘Mecklenburg-Phase’) schmolzen.
    Description: research
    Keywords: 551 ; pleistocene ; schleswig-holstein ; pléistocène ; correlations ; climato-stratigraphic table
    Language: English
    Type: article , Verlagsversion
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  • 36
    Publication Date: 2021-03-29
    Description: The paleosols of the Last Interglacial are presented in many loess sequences of the European temperate zone by soils with Argic horizon, that are considered to be the pedological response to the bioclimatic conditions of that period. We studied micromorphological, physical/chemical (bulk chemical composition, texture and dithionite-extractable iron) and mineralogical characteristics of two profiles – an Eemian Luvisol in Upper Austria (Oberlaab) and a Mikulino Albeluvisol in Central Russia (Alexandrov Quarry near Kursk) to compare them with recent analogous soils and to make further paleoecological and chronological inferences. Both profiles showed a set of characteristics indicative for weathering of primary minerals, clay transformation illuviation and surface redoximorphic (stagnic) processes. Paleosols demonstrate more advanced development than the Holocene analogues manifested however in different pedogenetic characteristics. The Eemian Luvisol in Upper Austria is characterized by stronger clay illuviation manifested in higher clay content and abundance of illuvial clay pedofeatures in the Bt horizon. Mikulino Albeluvisol in Central Russia is more strongly affected by eluvial and stagnic processes evidenced by deeper and more intensive accumulation of bleached silty material and clay depletion. We suppose that the properties of parent material are responsible for these differences. Russian Albeluvisol is formed on the Dnepr loess poor in weatherable minerals and having limited capacity for buffering acidity and clay formation. The higher development status of the Last Interglacial paleosols compared to the Holocene soils having however same type pedogenesis implies longer soil formation period, that agree with some of the paleobotanical proxies and could include besides MIS 5e part of MIS 5d; the warmer and moister paleoclimate during MIS 5e could also account for more advanced paleosol development Several phases of clay illuviation interrupted by frost structuring and deformation are detected in the Eemian Bt horizon in Upper Austria. It suppose even longer development that could extend to the Early Würmian interstadials (late substages of MIS5).
    Description: research
    Keywords: 551 ; paleosol ; paleoclimate ; last interglacial ; Argic horizon
    Language: English
    Type: article , Verlagsversion
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  • 37
    Publication Date: 2021-03-29
    Keywords: gas hydrate-bearing sediments; in situ synchrotron-tomography data ; 551
    Language: English
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  • 38
    Publication Date: 2021-03-29
    Description: A series of various readily water-soluble carbamates were synthesized with good yields. These compounds are useful chemical tracers for assessing the cooling progress in a georeservoir during geothermal power plant operation. Acylation of primary amines was carried out as well as using a solution of sodium bicarbonate and without the presence of salt. Products were characterized by 1H-NMR and 13C-NMR. Purity was confirmed through elemental analysis.
    Description: Open Access Publikationsfonds 2015
    Keywords: chloroformates; primary amines; carbamates; thermo-sensitive tracers; urethanes ; 551
    Language: English , English
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  • 39
    Publication Date: 2021-03-29
    Description: The combination of scanning electron microscope–cathodoluminescence (CL), fluid inclusion analysis and high-resolution electron probe microanalysis of Al, Ti, K and Fe in vein quartz has yielded results permitting a greater understanding of the complex mineralisation of the Central Oyu Tolgoi and Zesen Uul porphyry-style deposits, southern Mongolia. These data demonstrate the relationship between quartz precipitation, dissolution and ore deposition as the mineralising fluid chemistry changed through time. Four major quartz generations are identified in the A-type veins from the stockworks of both the Central Oyu Tolgoi (OTi to OTiv) and Zesen Uul deposits (ZUi to ZUiv). Despite differences in the associated alteration and mineralisation style, the observed CL textures and trace element signatures of the quartz generations are comparable between deposits. The OTi and ZUi stage formed both the primary network of A-type veins and pervasive silicification of the host rock. Using the Ti-in-quartz geothermometer, crystallisation temperatures for OTi and ZUi of between 598°C and 880°C are indicated. The main stage of sulphide mineralisation was accompanied by the dissolution of pre-existing quartz (OTi and ZUi) and precipitation of a weakly luminescent generation of quartz (OTii and ZUii) with a low Ti content, reflected in a calculated temperature drop from approximately 700°C to 340°C in Central Oyu Tolgoi and 445°C in Zesen Uul. OTii and ZUii stage quartzes show high and variable Al concentrations. The next stage of quartz in both deposits (OTiii and ZUiii) forms a fine network of veins in cracks formed in pre-existing quartz. OTiii and ZUiii quartz contain measurable fluid inclusions of moderate salinity (3–17.1 wt.% NaCl eq.), entrapped in the temperature range 256°C to 385°C. OTiii and ZUiii are not related to any sulphide mineralisation. The final OTiv and ZUiv stages are characterised by quartz–calcite micro-breccias that penetrate the A-type veins. Based on the calculated entrapment temperatures, the OTiv/ZUiv stage crystallised between 212°C and 335°C, and the quartz is characterised by elevated but variable Al and Fe contents. The CL and trace element signatures of the OTi to OTiii and ZUi to ZUiii stages of the two Mongolian porphyries show similar features to those observed in porphyry-style deposits from other regions. This suggests that a common sequence of quartz crystallisation occurs during the formation of early veins in many porphyry copper systems.
    Keywords: Copper porphyry; Quartz; Cathodoluminescence; Fluid inclusion; Trace elements; Mongolia ; 551
    Language: English
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  • 40
    Publication Date: 2021-03-29
    Description: Chemical reduction has long dominated the thinking about the mechanism of aqueous contaminant removal in the presence of metallic iron (e.g. Fe0/H2O systems). However, a large body of experimental evidence indicates that chemical reduction is not adequate to explain satisfactorily the efficiency of Fe0/H2O systems for several substances or classes of substances. By contrast, the alternative approach, that contaminants are fundamentally adsorbed and co-precipitated by iron corrosion products seems to provide a better explanation of observed efficiency. The new approach is obviously not really understood. The present communication aims at clarifying this key issue. It seems that a paradigm shift is necessary for the further development of the iron technology.
    Keywords: Contaminant removal; Paradigm shift; Removal mechanism; Water treatment; Zerovalent iron ; 551
    Language: English
    Type: article , submittedVersion
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  • 41
    Publication Date: 2021-03-29
    Keywords: Adsorption; Contaminant removal; Mechanisms; Reduction; Zerovalent metals ; 551
    Language: English
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  • 42
    Publication Date: 2021-03-29
    Keywords: Interdisciplinary approach; Peer-review system; Permeable reactive barrier; Water treatment; Zero-valent iron ; 551
    Language: English
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  • 43
    Publication Date: 2021-03-29
    Description: A detailed electrochemical, photophysical and theoretical study is presented for various new thienyl and furyl derivatives of pyrene. Their optical properties are described based on UV-VIS absorption and both steady-state and time-resolved fluorescence spectroscopy. DFT and TDDFT calculations are also presented to support experimental data. The calculations results show that HOMO-LUMO orbitals are delocalized uniformly between aromatic core and aryl substituents. Good electrochemical stability of thienyl and furyl hybrids of pyrene confirm their potential application for light emitting electrochemical cells or spintronics mainly due to their beneficial optical and charge transport properties in electrochromic devices. In order to demonstrate this potential, an OLED device is presented. Synthesized compounds included in this OLED device both facilitate electron transport and act as a light emitting layer.
    Keywords: thienyl; furyl derivatives; pyrene ; 551
    Language: English , English
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  • 44
    Publication Date: 2021-04-25
    Description: An external skeleton is an essential part of the body plan of many animals and is thought to be one of the key factors that enabled the great expansion in animal diversity and disparity during the Cambrian explosion. Molluscs are considered ideal to study the evolution of biomineralization because of their diversity of highly complex, robust and patterned shells. The molluscan shell forms externally at the interface of animal and environment, and involves controlled deposition of calcium carbonate within a framework of macromolecules that are secreted from the dorsal mantle epithelium. Despite its deep conservation within Mollusca, the mantle is capable of producing an incredible diversity of shell patterns, and macro- and micro-architectures. Here we review recent developments within the field of molluscan biomineralization, focusing on the genes expressed in the mantle that encode secreted proteins. The so-called mantle secretome appears to regulate shell deposition and patterning and in some cases becomes part of the shell matrix. Recent transcriptomic and proteomic studies have revealed marked differences in the mantle secretomes of even closely-related molluscs; these typically exceed expected differences based on characteristics of the external shell. All mantle secretomes surveyed to date include novel genes encoding lineage-restricted proteins and unique combinations of co-opted ancient genes. A surprisingly large proportion of both ancient and novel secreted proteins containing simple repetitive motifs or domains that are often modular in construction. These repetitive low complexity domains (RLCDs) appear to further promote the evolvability of the mantle secretome, resulting in domain shuffling, expansion and loss. RLCD families further evolve via slippage and other mechanisms associated with repetitive sequences. As analogous types of secreted proteins are expressed in biomineralizing tissues in other animals, insights into the evolution of the genes underlying molluscan shell formation may be applied more broadly to understanding the evolution of metazoan biomineralization.
    Keywords: Biomineralization; Mollusc; Mantle; Shell; Shell matrix proteins; Co-option; Lineage-specific novelties; Repetitive low complexity domain ; 551
    Language: English , English
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  • 45
    Publication Date: 2021-03-29
    Description: This study aims to evaluate quantitatively the land surface temperature (LST) derived from MODIS (Moderate Resolution Imaging Spectroradiometer) MOD11A1 and MYD11A1 Collection 5 products for daily land air surface temperature (Ta) estimation over a mountainous region in northern Vietnam. The main objective is to estimate maximum and minimum Ta (Ta-max and Ta-min) using both TERRA and AQUA MODIS LST products (daytime and nighttime) and auxiliary data, solving the discontinuity problem of ground measurements. There exist no studies about Vietnam that have integrated both TERRA and AQUA LST of daytime and nighttime for Ta estimation (using four MODIS LST datasets). In addition, to find out which variables are the most effective to describe the differences between LST and Ta, we have tested several popular methods, such as: the Pearson correlation coefficient, stepwise, Bayesian information criterion (BIC), adjusted R-squared and the principal component analysis (PCA) of 14 variables (including: LST products (four variables), NDVI, elevation, latitude, longitude, day length in hours, Julian day and four variables of the view zenith angle), and then, we applied nine models for Ta-max estimation and nine models for Ta-min estimation. The results showed that the differences between MODIS LST and ground truth temperature derived from 15 climate stations are time and regional topography dependent. The best results for Ta-max and Ta-min estimation were achieved when we combined both LST daytime and nighttime of TERRA and AQUA and data from the topography analysis.
    Description: Open-Access-Publikationsfonds 2016
    Keywords: land surface temperature (LST); MODIS LST products; northern Vietnam ; 551
    Language: English
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  • 46
    Publication Date: 2021-03-29
    Description: Groundwater from the La Paz arid coastal aquifer in Baja California, Mexico, is essentially the only source of drinking water for the local population and tourists, as well as irrigation water for agricultural needs. The intensive exploitation of the aquifer and water cycling has resulted in groundwater abatement (up to 10 m) and high salinity (up to *5800 mg l-1). A study using hydrochemistry, isotopic (deuterium, oxygen-18 and carbon- 14) and gaseous tracers (chlorofluorocarbons CFC-11, CFC-12, CFC-113), as well as multivariate statistics, was developed to elucidate groundwater composition, flow and occurrence. Groundwater is of meteoric origin, and a large proportion is subject to evaporation. The primary natural recharge is generated in the El Novillo and Las Cruces ranges, and groundwater subsequently flows in a SE–NW direction toward the coast. The initial water type is the result of discordant dissolution of silicate minerals and ion exchange on soils. In the lower plain portion, the aquifer system is recharged from irrigation return flow and seawater intrusion, which significantly affects groundwater chemistry. Nitrate and chloride concentrations indicate that groundwater is highly affected by an overuse of fertilizers in agricultural activities, but there is little effect from urban activities. Seawater intrusion has progressed rapidly during the past decade, and the impact currently extends 13 km inland. Radiocarbon residence time calculations suggest that groundwater is modern, with the exception of Chametla and El Centerario sites in the central and western lowlands with ages of up to *5000 years. These waters indicate an additional recharge source for the upconing of fossil groundwater or regional flow.
    Keywords: Coastal aquifers; Hydrogeochemistry; Arid regions; Isotope hydrology; Contamination ; 551
    Language: English
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  • 47
    Publication Date: 2021-03-29
    Description: A new method to correlate intrinsic reactivity and treatability efficiency of metallic iron (Fe0) was evaluated. A 2.0 mg L-1 methylene blue (MB) solution was used in gravity fed column experiments. The intrinsic reactivity of nine Fe0 materials (ten samples) was characterized using the EDTA test. Three commercial Fe0 materials ZVI1 (0.40 - 0.80 mm), ZVI9 (0.50 mm) and ZVI10 (0.45 - 0.55 mm) were tested in column experiments. A layer containing 100 g of Fe0 was sandwiched between 19.0 to 20.0 cm upper coarse sand (1.6 - 2.0 mm) and 8.0 cm lower fine sand (0.25 - 0.30 mm). 500 mL of the MB solution was daily filtered through each column for one month. Effluent solutions were characterized for MB and Fe concentrations. The columns were also characterized by the evolution of the hydraulic conductivity (k values). Results showed (i) quantitative MB removal (〉 88 %) and (ii) limited Fe release for all three columns. After about 25 days, the Fe levels were constantly less than 1.0 mg L-1. The most significant difference was observed in the evolution of the k value and was attributed to the different material sorting. Less sorted ZVI1 exhibited the lowest initial k value (8.0 vs 43.0 mm min-1 for ZVI9 and ZVI10) and most significant permeability loss. Results confirmed the usefulness of the tested protocol as a reliable method to assess the efficiency of Fe0 materials in short term column experiments. Well-sorted Fe0 materials are recommended for long term efficient Fe0 filtration systems.
    Keywords: Intrinsic reactivity; Methylene blue; Reactive filtration; Treatability efficiency; Zerovalent iron ; 551
    Language: English
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  • 48
    Publication Date: 2021-04-25
    Keywords: 551 ; VKB 350 ; 38.20
    Language: English
    Type: anthologyArticle , publishedVersion
    Format: 186-209
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  • 49
    Publication Date: 2021-03-29
    Description: In order to better understand the role of fluids during subduction and subsequent exhumation, we have investigated whole-rock and mineral chemistry (major and trace elements) and Li, B as well as O, Sr, Nd, Pb isotopes on selected continuous drill-core profiles through contrasting lithological boundaries from the Chinese Continental Scientific Drilling Program (CCSD) in Sulu, China. Four carefully selected sample sets have been chosen to investigate geochemical changes as a result of fluid mobilization during dehydration, peak metamorphism, and exhumation of deeply subducted continental crust. Our data reveal that while O and Sr-Nd-Pb isotopic compositions remain more or less unchanged, significant Li and/or B isotope fractionations occur between different lithologies that are in close contact during various metamorphic stages. Samples that are supposed to represent prograde dehydration as indicated by veins formed at high pressures (HP) are characterized by element patterns of highly fluid-mobile elements in the veins that are complementary to those of the host eclogite. A second sample set represents a UHP metamorphic crustal eclogite that is separated from a garnet peridotite by a thin transitional interface. Garnet peridotite and eclogite are characterized by a 〉10% difference in MgO, which, together with the presence of abundant hydroxyl-bearing minerals and compositionally different clinopyroxene grains demonstrate that both rocks have been derived from different sources that have been tectonically juxtaposed during subduction, and that hydrous silicate-rich fluids have been added from the subducting slab to the mantle. Two additional sample sets, comprising retrograde amphibolite and relatively fresh eclogite, demonstrate that besides external fluids, internal fluids can be responsible for the formation of amphibolite. Li and B concentrations and isotopic compositions point to losses and isotopic fractionation during progressive dehydration. On the other hand, fluids with isotopically heavier Li and B are added during retrogression. On a small scale, mantle-derived rocks may be significantly metasomatized by fluids derived from the subducted slab. Our study indicates that during high-grade metamorphism, Li and B may show different patterns of enrichment and of isotopic fractionation.
    Keywords: Fluid/rock interaction; Elemental transfer; Isotopic fractionation; Subduction and exhumation; Sulu ; 551 ; Earth Sciences; Mineralogy; Mineral Resources; Geology
    Language: English
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  • 50
    Publication Date: 2021-03-29
    Description: The Itajaí Basin located in the southern border of the Luís Alves Microplate is considered as a peripheral foreland basin related to the Dom Feliciano Belt. It presents an excellent record of the Ediacaran period, and its upper parts display the best Brazilian example of Precambrian turbiditic deposits. The basal succession of Itajaí Group is represented by sandstones and conglomerates (Baú Formation) deposited in alluvial and deltaic-fan systems. The marine upper sequences correspond to the Ribeirão Carvalho (channelized and non-channelized proximal silty-argillaceous rhythmic turbidites), Ribeirão Neisse (arkosic sandstones and siltites), and Ribeirão do Bode (distal silty turbidites) formations. The Apiúna Formation felsic volcanic rocks crosscut the sedimentary succession. The Cambrian Subida leucosyenogranite represents the last felsic magmatic activity to affect the Itajaí Basin. The Brusque Group and the Florianópolis Batholith are proposed as source areas for the sediments of the upper sequence. For the lower continental units the source areas are the Santa Catarina, São Miguel and Camboriú complexes. The lack of any oceanic crust in the Itajaí Basin suggests that the marine units were deposited in a restricted, internal sea. The sedimentation started around 600 Ma and ended before 560 Ma as indicated by the emplacement of rhyolitic domes. The Itajaí Basin is temporally and tectonically correlated with the Camaquã Basin in Rio Grande do Sul and the Arroyo del Soldado/Piriápolis Basin in Uruguay. It also has several tectono-sedimentary characteristics in common with the African-equivalent Nama Basin.
    Keywords: Dom Feliciano Belt; Ediacaran; Foreland basin; U–Pb SHRIMP ages; Provenance ; 551 ; Earth Sciences; Geophysics/Geodesy; Geology
    Language: English
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  • 51
    Publication Date: 2021-03-29
    Description: In the crystal structure of the title compound [systematic name: 5H-dibenzo[a,d]cycloheptatriene-5-carboxamide–1,4- dioxane (2/1)], 2C16H13NO C4H8O2, the cytenamide molecules form a hydrogen-bonded R2 2(8) dimer. The solvent molecule is located between two adjacent cytenamide dimers and forms N—H O hydrogen bonds with one cytenamide molecule from each dimer.
    Keywords: single-crystal X-ray study; T = 160 K; mean (C–C) = 0.004 A° ; R factor = 0.069; wR factor = 0.122; data-to-parameter ratio = 13.5. ; 551
    Language: English
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  • 52
    Publication Date: 2021-03-29
    Keywords: Adsorption; Decontamination; Reduction; Remediation; Zerovalent iron ; 551
    Language: English
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  • 53
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    Publication Date: 2021-03-29
    Keywords: letter; apology letter ; 551 ; Chlorine ; Iron ; Lindane ; Palladium ; Water Pollutants, Chemical ; Water Purification
    Language: English , English
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  • 54
    Publication Date: 2021-03-29
    Keywords: Environmental remediation; Material reactivity; Nanoscale iron; Roll-front; Zerovalent iron ; 551 ; Environment; Atmospheric Protection/Air Quality Control/Air Pollution; Climate Change; Environment, general; Soil Science & Conservation; Hydrogeology; Waste Water Technology / Water Pollution Control / Water Management / Aquatic Pollution
    Language: English
    Type: article , publishedVersion
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  • 55
    Publication Date: 2021-03-29
    Description: Basaltic dyke swarms in the southern continental part of the Cameroon Volcanic Line (Bangangte, Dschang, Manjo areas) are tholeiitic in composition with 46 to 50 wt.% SiO 2 and have moderate Mg-numbers (53–59), medium TiO 2 contents (1.48–2,05 wt.%), and flat to mildly enriched incompatible trace element patterns. Comparison with trace element patterns of representative Cenozoic basaltic rocks of the Cameroon Volcanic Line (Bana anorogenic complex, Mt. Bambouto, Adamawa Plateau basalts) indicates that these dykes are less enriched in light REE and show different incompatible trace element ratios (La/Yb: 5.7 to 8.6; Zr/Nb: 7.6 to 12.0; Ba/Th: 87.7 to 93.3). The trace element patterns of the dykes and their Sr- and Nd- isotope compositions, however, are similar to those of the pre-Cenozoic volcanic rocks of the Benue Trough in Nigeria. Our data therefore suggest that these dykes represent the magmatic history related to the break-up of Africa and South America and are unrelated to the Tertiary volcanism of the Cameroon Line.
    Keywords: Basalt dykes; Tholeiites; Phanerozoic; Cameroon volcanic line; West Gondwana ; 551
    Language: English
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  • 56
    Publication Date: 2021-03-29
    Description: The arborescent lycophyte group known as the sigillarians bore pedunculate fructifications, including Sigillariostrobus Schimper, which has a known propensity to disaggregate, making comparisons of cones and in situ spores often difficult if not impossible. Sigillariostrobus is monosporangiate, containing either megaspores or microspores. Two new species of Sigillariostrobus with megaspores are described from the British Coal Measures. Two cones of Sigillariostrobus saltwellensis sp. nov. are described from Langsettian–Duckmantian strata of Great Britain, containing in situ Laevigatisporites glabratus (Zerndt) Potonié and Kremp spores, making this the first British Sigillariostrobus species described containing such spores. Sigillariostrobus barkeri sp. nov. is given here to the previously described cone with in situ Tuberculatisporites brevispiculus (Schopf) Potonié and Kremp spores. This is the first Sigillariostrobus cone with this megaspore species in situ, and thus shows that T. brevispiculus and T. mamillarius (Bartlett) Potonié and Kremp are not conspecific as others have previously suggested.
    Description: Open-Access Publikationsfonds 2015
    Keywords: Sigillariostrobus Schimper; megasporangiate; British Coal Measures ; 551
    Language: English
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  • 57
    Publication Date: 2021-04-27
    Description: he fossil record of lichens is scarce and many putative fossil lichens do not show an actual physiological relationship between mycobionts and photobionts or a typical habit, and are therefore disputed. Amber has preserved a huge variety of organisms in microscopic fidelity, and so the study of amber fossils is promising for elucidating the fossil history of lichens. However, so far it has not been tested as to how amber inclusions of lichens are preserved regarding their internal characters, ultrastructure, and chemofossils. Here, we apply light microscopy, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), and Raman spectroscopy to an amber-preserved Eocene lichen in order to gain information about the preservation of the fossil. The lichen thallus displays lifelike tissue preservation including the upper and lower cortex, medulla, photobiont layer, apothecia, and soredia. SEM analysis revealed globular photobiont cells in contact with the fungal hyphae, as well as impressions of possible former crystals of lichen compounds. EDX analysis permitted the differentiation between halite and pyrite crystals inside the lichen which were likely formed during the later diagenesis of the amber piece. Raman spectroscopy revealed the preservation of organic compounds and a difference between the composition of the cortex and the medulla of the fossil.
    Description: Open Access Publikationsfonds 2015
    Keywords: Lichen; amber; morphology; ultrastructure; chemofossils; taphonomic alteration ; 551
    Language: English
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  • 58
    Publication Date: 2021-03-29
    Description: Fungi have been recognized as a frequent colonizer of subseafloor basalt but a substantial understanding of their abundance, diversity and ecological role in this environment is still lacking. Here we report fossilized cryptoendolithic fungal communities represented by mainly Zygomycetes and minor Ascomycetes in vesicles of dredged volcanic rocks (basanites) from the Vesteris Seamount in the Greenland Basin. Zygomycetes had not been reported from subseafloor basalt previously. Different stages in zygospore formation are documented in the studied samples, representing a reproduction cycle. Spore structures of both Zygomycetes and Ascomycetes are mineralized by romanechite-like Mn oxide phases, indicating an involvement in Mn(II) oxidation to form Mn(III,VI) oxides. Zygospores still exhibit a core of carbonaceous matter due to their resistance to degradation. The fungi are closely associated with fossiliferous marine sediments that have been introduced into the vesicles. At the contact to sediment infillings, fungi produced haustoria that penetrated and scavenged on the remains of fragmented marine organisms. It is most likely that such marine debris is the main carbon source for fungi in shallow volcanic rocks, which favored the establishment of vital colonies.
    Keywords: Fungal structure; Fungi; Vesicles; Sediment; Fossils; Zygomycetes; Seamounts; Marine geology ; 551
    Language: English , English
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  • 59
    Publication Date: 2021-03-29
    Description: Despite two decades of intensive research on using metallic iron (Fe0) for environmental remediation and water treatment, basic concerns about their efficiency still prevail. This communication presents the basic idea of the view that challenges the prevailing paradigm on the operating mode of Fe0/H2O systems. The alternative paradigm is in tune with the mainstream science on aqueous iron corrosion. Its large scale adoption will enable a scientifically based system design and increase the acceptance of this already proven efficient technology.
    Keywords: Adsorption; Co-precipitation; Filtration; Water treatment; Zero-valent iron ; 551
    Language: English
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  • 60
    Publication Date: 2021-04-27
    Description: Open-Access-Publikationsfonds 2016
    Keywords: Fossils; Leaves; Paleobiology; Mosses, Plant fossils; Eocene epoch, Bryology; Nonvascular plants ; 551
    Language: English , English
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  • 61
    Publication Date: 2021-03-29
    Keywords: methane hydrate; NGH; gas transport; self-preservation; LNG; CNG; pipeline; methane hydrate carrier; risk analysis ; 551
    Language: English
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  • 62
    Publication Date: 2021-03-29
    Description: The temperature dependence of H-Uiso in N-acetyl-l-4-hydroxyproline monohydrate is investigated. Imposing a constant temperature-independent multiplier of 1.2 or 1.5 for the riding hydrogen model is found to be inaccurate, and severely underestimates H-Uiso below 100 K. Neutron diffraction data at temperatures of 9, 150, 200 and 250 K provide benchmark results for this study. X-ray diffraction data to high resolution, collected at temperatures of 9, 30, 50, 75, 100, 150, 200 and 250 K (synchrotron and home source), reproduce neutron results only when evaluated by aspherical-atom refinement models, since these take into account bonding and lone-pair electron density; both invariom and Hirshfeld-atom refinement models enable a more precise determination of the magnitude of H-atom displacements than independent-atom model refinements. Experimental efforts are complemented by computing displacement parameters following the TLS+ONIOM approach. A satisfactory agreement between all approaches is found.
    Keywords: riding hydrogen model; QM/MM computations; neutron diffraction; invariom refinement; Hirshfeld-atom refinement; synchrotron radiation ; 551
    Language: English
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  • 63
    Publication Date: 2021-03-29
    Keywords: soil respiration ; 551
    Language: English
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  • 64
    Publication Date: 2021-03-29
    Description: This letter presents an improved discussion of the data provided in a recent article on EDTA removal from aqueous solutions using elemental iron (Fe(0)) by O. Gyliene and his co-workers. It is shown that the authors have furnished a brilliant validation of the concept that dissolved contaminants are primary removed in Fe(0)/H(2)O systems by adsorption onto iron corrosion products and co-precipitation with iron corrosion products. It is reiterated that "contaminant removal" and "contaminant reduction" should not be interchanged randomly.
    Keywords: Adsorption; Co-precipitation; EDTA; Iron corrosion; Zerovalent iron; ; 551
    Language: English
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  • 65
    Publication Date: 2021-03-29
    Description: The intrinsic reactivity of four metallic iron materials (Fe0) was investigated in batch and column experiments. The Fe0 reactivity was characterized by the extent of aqueous fixation of in-situ leached arsenic (As). Air-homogenized batch experiments were conducted for 1 month with 10.0 g/ℓ of an As-bearing rock (ore material) and 0.0 or 5.0 g/ℓ of Fe0. Column experiments were performed for 2 and 3 months. Each dynamic experiment was made up of 2 glass columns in series. The first column contained 2.5 or 5.0 g of the ore material and the second column 0.0 or 5.0 g of a Fe0 material. Results showed no significant reactivity difference in batch studies for all 4 materials, ZVI2 was by far the most reactive material in column experiments. This observation was attributed to the relative kinetics of production of aqueous As and Fe species under the experimental conditions and their impact on the formation of a protective film on Fe0. Accordingly, no protective film could be built at the surface of the least reactive materials. The results corroborated the urgent need for unified experimental procedures to characterize Fe0 materials.
    Keywords: Column study; Intrinsic reactivity; Ore mineral; Water treatment; Zerovalent iron ; 551
    Language: English
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  • 66
    Publication Date: 2021-04-25
    Description: During the last few years, the analysis of microbial diversity in various habitats greatly increased our knowledge on the kingdom Archaea. At the same time, we became aware of the multiple ways in which Archaea may interact with each other and with organisms of other kingdoms. The large group of euryarchaeal methanogens and their methane oxidizing relatives, in particular, take part in essential steps of the global methane cycle. Both of these processes, which are in reverse to each other, are partially conducted in a symbiotic interaction with different partners, either ciliates and xylophagous animals or sulfate reducing bacteria. Other symbiotic interactions are mostly of unknown ecological significance but depend on highly specific mechanisms. This paper will give an overview on interactions between Archaea and other organisms and will point out the ecological relevance of these symbiotic processes, as long as these have been already recognized.
    Keywords: Archaea; Symbioses; ; 551
    Language: English
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  • 67
    Publication Date: 2021-03-29
    Description: Most studies dealing with material properties of sandstones are based on a small data set. The present study utilizes petrographical and petrophysical data from 22 selected sandstones and ~300 sandstones from the literature to estimate/predict the material and weathering behaviour of characteristic sandstones. Composition and fabric properties were determined from detailed thin section analyses. Statistical methods applied consist of data distributions with whisker plots and linear regression with confidence regions for the petrophysical and weathering properties. To identify similarities between individual sandstones and to define groups of specific sandstone types, principal component and cluster analyses were applied. The results confirm an interaction between the composition, depositional environment, stratigraphic association and diagenesis, which leads to a particular material behaviour of sandstones. Three different types of pore radii distributions are observed, whereby each is derived from different pore space modifications during diagenesis and is associated with specific sandstone types: (1) bimodal with a maximum in capillary and micropores, (2) unimodal unequal with a maximum in smaller capillary pores and (3) unimodal equable with a maximum in larger capillary pores. Each distribution shows specific dependencies to water absorption, salt loading and hygric dilatation. The strength–porosity relationship shows dependence on the content of unstable lithic fragments, grain contact and type of pore radii distribution, cementation and degree of alteration. Sandstones showing a maximum of capillary pores and micropores (bimodal) exhibit a distinct hygric dilatation and low salt resistance. These sandstones are highly immature sublitharenites–litharenites, characterized by altered unstable rock fragments, which show pointed-elongated grain contacts, and some pseudomatrix. Quartz arenites and sublitharenites–litharenites which are strongly compacted and cemented, show unimodal unequal pore radii distributions, low porosity, high strength and a high salt resistance. The presence of swellable clay minerals in sublitharenites–litharenites leads to a medium to high hygric dilatation, whereas quartz arenites show little hygric dilatation. Sandstones with unimodal equal pore radii distribution mostly belong to weakly compacted and cemented mature quartz arenites. These are characterized by high water absorption and high porosity, low to medium strength and a low salt resistance. The data compiled in this study are used to create a sandstone quality catalogue. Since material properties are dependent on many different parameters of influence, the transition between different lithotypes is fluent.
    Keywords: Sandstones; Pore space; Prediction; Weathering behavior; Compressive strength ; 551 ; Earth Sciences; Geology
    Language: English
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  • 68
    Publication Date: 2021-03-29
    Description: Attenuation of micro-contaminants is a very complex field in environmental science and evidence suggests that biodegradation rates of micro-contaminants in the aqueous environment depend on the water matrix. The focus of the study presented here is the systematic comparison of biotransformation rates of caffeine, carbamazepine, metoprolol, paracetamol and valsartan in river water microcosms spiked with different proportions of treated effluent (0%, 0.1%, 1%, and 10%). Biotransformation was identified as the dominating attenuation process by the evolution of biotransformation products such as atenolol acid and valsartan acid. Significantly decreasing biotransformation rates of metoprolol were observed at treated effluent proportions ≥0.1% whereas significantly increasing biotransformation rates of caffeine and valsartan were observed in the presence of 10% treated effluent. Potential reasons for the observations are discussed and the addition of adapted microorganisms via the treated effluent was suggested as the most probable reason. The impact of additional phosphorus on the biodegradation rates was tested and the experiments revealed that phosphorus-limitation was not responsible.
    Description: Open-Access-Publikationsfonds 2014
    Keywords: biodegradation; pharmaceuticals; caffeine; river water; treated effluent; valsartan acid ; 551
    Language: English , English
    Type: article , publishedVersion
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  • 69
    Publication Date: 2021-03-29
    Description: A high-resolution multiproxy geochemical approach was applied to the sediments of Laguna Potrok Aike in an attempt to reconstruct moist and dry periods during the past 16 000 years in southeastern Patagonia. The age–depth model is inferred from AMS 14C dates and tephrochronology, and suggests moist conditions during the Lateglacial and early Holocene (16 000–8700 cal. BP) interrupted by drier conditions before the beginning of the Holocene (13 200–11 400 cal. BP). Data also imply that this period was a major warm phase in southeastern Patagonia and was approximately contemporaneous with the Younger Dryas chronozone in the Northern Hemisphere (12 700–11 500 cal. BP). After 8650 cal. BP a major drought may have caused the lowest lake level of the record. Since 7300 cal. BP, the lake level rose and was variable until the ‘Little Ice Age’, which was the dominant humid period after 8650 cal. BP.
    Keywords: Holocene ; Younger Dryas ; Lateglacial ; `Little Ice Age' ; lacustrine sediments ; geochemistry ; tephrochronology ; multiproxy approach ; Patagonia ; Argentina. ; 551
    Language: English
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  • 70
    Publication Date: 2021-03-29
    Description: The spatio-temporal variability of trends in vegetation greenness in dryland areas is a well-documented phenomenon in remote sensing studies at global to regional scales. The underlying causes differ, however, and are often not well understood. Here, we analyzed the trends in vegetation greenness for a semi-arid area in northeastern Brazil (NEB) and examined the relationships between those dynamics and climate anomalies, namely the El Nino Southern Oscillation (ENSO) for the period 1982 to 2010, based on annual Normalized Difference Vegetation Index (NDVI) values from the latest version of the Global Inventory Modeling and Mapping Studies (GIMMS) NDVI dataset (NDVI3g) dataset. Against the ample assumption of ecological and socio-economic research, the results of our inter-annual trend analysis of NDVI and precipitation indicate large areas of significant greening in the observation period. The spatial extent and strength of greening is a function of the prevalent land-cover type or biome in the study area. The regression analysis of ENSO indicators and NDVI anomalies reveals a close relation of ENSO warm events and periods of reduced vegetation greenness, with a temporal lag of 12 months. The spatial patterns of this relation vary in space and time. Thus, not every ENSO warm event is reflected in negative NDVI anomalies. Xeric shrublands (Caatinga) are more sensitive to ENSO teleconnections than other biomes in the study area.
    Description: Open-Access-Publikationsfonds 2014
    Keywords: NDVI3g; GIMMS; AVHRR; El Nino; inter-annual trends; teleconnections ; 551
    Language: English
    Type: article , publishedVersion
    Format: 18
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  • 71
    Publication Date: 2021-03-29
    Description: The relation of two well-known ancient carbonate deposits to hydrocarbon seepage was confirmed by this study. Archaea are found to be associated with the formation of Oxfordian seep carbonates from Beauvoisin and with a Miocene limestone from Marmorito ("tube-worm limestone"). Carbonates formed due to a mediation by archaea exhibit extremely positive or extremely negative 813Ccarbonate values, respectively. Highly positive values (+ 15%0) reflect the use of 13C-enriched CO2 produced by methanogenesis. Low 813C values of the Marmorito carbonates (-30%0) indicate the oxidation of seepagederived hydrocarbons. Likewise, the 813C content of specific tail-to-tail linked isoprenoids, biomarkers for archaea, was found to be strikingly depleted in these sampies (as low as -115%0). The isotopic signatures corroborate that archaea were involved in the cycling of seepage-derived organic carbon at the ancient localities. Another Miocene limestone ("Marmorito li mestone") shows a strong imprint of methanotrophic bacteria as indicated by 813C va lues of carbonate as low J. Peckmann (IEI) . J. Reitner Institut und Museum für Geologie und Paläontologie, Georg-August-Universität. Goldschmidtstrasse 3, D-37077 Göttingen, Germany e-mail: jpeckma@gwdg.de. Fax: + 49-551-397918 V. Thiel, W. Michaelis Institut für Biogeochemie und Meereschemie, Universität Hamburg, Bundesstrasse 55, D-20146 Hamburg, Germany P. Clari, L. Martire Dipartimento di Scienze della Terra, via Accademia delle Scienze 5, 1-10123 Torino, Italy C. Gaillard UFR des Sciences de la Terre, UMR 5565 Centre de Paleontologie stratigraphique et Paleoecologie, Universite Claude Bemard, Lyon 1, 27-43 Boulevard du 11 Novembre, F-69622 Villeurbanne Cedex, France as -40%0 and biomarker evidence. Epifluorescence microscopy and field-emission scanning electron microscopy revealed that bacterial biofilms were involved in carbonate aggregation. In addition to lucinid bivalves previously reported from both localities, we infer that sponges from Beauvoisin and tube worms from Marmorito depended on chemosynthesis as weil. Low 813C values of nodules related to sponge taphonomy (-27%0) indicate that sponges might have been Iinked to an enhanced hydrocarbon oxidation. Tube worm fossils from Marmorito closely resemble chemosynthetic pogonophoran tube worms from Recent cold seeps and are embedded in isotopically light carbonate (813C -300/00).
    Keywords: Paläontologie: Allgemeines ; 551 ; VU 000 ; 38.20 ; 38.2
    Language: English
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  • 72
    Publication Date: 2021-03-29
    Description: Widefield deconvolution epifluorescence microscopy (WDEM) combined with fluorescence in situ hybridization (FISH) was performed to identify and characterize single bacterial cells within sections of the mediterranean sponge Chondrosia reniformis. Sponges were embedded in paraffin wax or plastic prior to the preparation of thin sections, in situ hybridization and microscopy. Serial digital images generated by widefield epifluorescence microscopy were visualized using an exhaustive photon reassignment deconvolution algorithm and three-dimensional rendering software. Computer processing of series of images taken at different focal planes with the deconvolution technique provided deblurred three-dimensional images with high optical resolution on a submicron scale. Results from the deconvolution enhanced widefield microscopy were compared with conventional epifluorescent microscopical images. By the application of the deconvolution algorithm on digital image data obtained with widefield epifluorescence microscopy after FISH, the occurrence and spatial arrangement of Desulfovibrionaceae closely associated with micropores of Chondrosia reniformis could be visualized.
    Keywords: Widefield deconvolution epifluorescence microscopy; FISH; 16S rRNA oligonucleotide probes; Sponge associated bacteria; Chondrosia reniformis ; 551
    Language: English
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  • 73
    Publication Date: 2021-03-29
    Description: A series of various readily water soluble esters were synthesized by a very efficient procedure. These compounds can be useful as thermosensitive tracers for studying the cooling progress in a low enthalpy georeservoir exploitable by double flash geothermal power plant systems. The kinetics of their hydrolysis was investigated. Acylation of primary alcohols or phenols was carried out by a method based on a single-phase solvent system consisting of ethyl acetate acting as an organic solvent and triethylamine acting as a catalyst. Products were characterized by 1H-NMR, and 13C-NMR.
    Description: Open-Access-Publikationsfonds 2015
    Keywords: sulfonic acid esters; primary alcohols; phenols; acylation; reaction kinetics ; 551
    Language: English , English
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  • 74
    Publication Date: 2021-03-29
    Description: Lower Saxony, with a total land area of about 46 500 km2, constitutes one of the most important agricultural areas in Germany and thus within Europe. Roughly one third of its agricultural area is used for maize cultivation and as of today only few information exist on how a future changing climate will affect its local growing conditions. Thus the newly developed carbon-based crop model BioSTAR and a high-resolution regional climate data-set (Wettreg) were used to evaluate the change in biomass yields of an early, medium and late maize variety. The climate input data is based on the SRES A1B scenario, with a potential fertilization effect or better still, an increased water use efficiency due to rising CO2 levels, taken into account. The biomass yield for all varieties was calculated for each year from 2001 until 2099 on a total of 91 014 sites. The results suggest clearly differentiated development paths of all varieties. All three show a significant positive trend until the end of the century. However the medium variety shows a statistical significant decline of 5% during the first 30 years and only a slight recovery towards +5% around the century's end. The late variety has the clearest and strongest positive trend, with partially more than 30% increase of biomass yields around the end of the century or +25% mean increase in the last three decades. The early variety can be seen as in-between, with no negative but also not an as strong positive development path. All varieties have their strongest increase in yields after the mid of the 21st century. Statistical evaluation of these results suggests that the shift from a summer rain to a winter rain climate in Germany will be the main limiting factor for all varieties. In addition summer temperatures will become less optimal for all maize crops. Only if the plants can supply themselves sufficiently with water outside of the increasingly dry summer months, when also temperatures are much more favorable, an increase in biomass yields is feasible. As the data suggests the increasing atmospheric CO2 concentrations will play a critical role in reducing the crops water uptake, thus enabling yield increases in the first place.
    Description: Open-Access-Publikationsfonds 2014
    Keywords: Lower Saxony; Maize varieties; climate; Biomass yield development ; 551
    Language: English
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  • 75
    Publication Date: 2021-03-29
    Description: As has been demonstrated in recent years, the heterogeneities of coeval magmas can be more successfully revealed by zoned megacrysts rather than by analysis of the whole rocks hosting them. Here, the geochemical heterogeneities of feldspar megacrysts from the Karkonosze granite, Poland, are investigated by LA-ICP-MS. The crystals are the product of migration and growth in regions of poorly mixed magmas. 3D-modeling of the Ba, Sr, and Rb distributions emphasizes the importance of micro-domain growth morphologies. Two models of element behavior—a relative concentration model and a composition gradient model—provide a potentially effective tool for tracking the mixing process on a microscale. Measured concentrations of elements of different mobilities do not agree with what might be expected from the mixing of two end-member magmas. If mixing was the only process occurring, linear correlations between the concentrations of any two elements should be observed; this, however, is not the case. For combinations of any two of the three elements, modeling reveals differing non-linear correlations between concentrations. The megacryst heterogeneities provide an insight into how mixing magmas are chaotically advected to growing crystals and the degree of inter-magma element exchange between the magmas.
    Keywords: Mixing; Element mobility; Diffusion; Alkali feldspar; 3D-depiction; Cut-off value models; Gradient models; Probabilistic models; Geochemical heterogeneity; Karkonosze granite ; 551
    Language: English
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  • 76
    Publication Date: 2021-03-29
    Description: The lattice-preferred orientation (LPOs) of two late-Variscan granitoids, the Meissen monzonite and the Podlesí dyke granite, were determined from high-resolution time-of-flight neutron diffraction patterns gained at the diffractometer SKAT in Dubna, Russia. The results demonstrate that the method is suitable for the LPO analysis of polyphase, relatively coarse-grained (0.1–6 mm) rocks. The Meissen monzonite has a prominent shape-preferred orientation (SPO) of the non-equidimensional minerals feldspar, mica and amphibole, whereas SPO of the Podlesí granite is unapparent at the hand-specimen scale. The neutron diffraction data revealed distinct LPOs in both granitoids. The LPO of the non-equidimensional minerals feldspar, mica and amphibole developed mainly during magmatic flow. In the case of the Meissen monzonite, the magmatic flow was superimposed by regional shear tectonics, which, however, had no significant effect on the LPOs. In both samples, quartz shows a weak but distinct LPO, which is atypical for plastic deformation and different in the syn-kinematic Meissen monzonite and the post-kinematic Podlesí granite. We suggest that, first of all, the quartz LPO of the Meissen monzonite is the result of oriented growth in an anisotropic stress field. The quartz LPO of the Podlesí granite, which more or less resembles a deformational LPO in the flattening field of the local strain field, developed during magmatic flow, whereby the rhombohedral faces of the quartz crystals adhered to the (010) faces of aligned albite and to the (001) faces of zinnwaldite. Due to shape anisotropy of their attachments, the quartz crystals were passively aligned by magmatic flow. Thus, magmatic flow and oriented crystal growth are the major LPO-forming processes in both granitoids. For the Meissen monzonite, the solid-state flow was too weak to cause significant crystallographic re-orientation of the minerals aligned by magmatic flow. Finally, the significance of our results for the evaluation of the regional tectonic environment during magma emplacement is discussed. The discussion on the regional implications of the more methodologically oriented results provides the basis for future, more regionally aimed studies in view of the fabric characteristics of such plutons and their developing mechanisms.
    Keywords: Neutron diffraction; Lattice-preferred orientation; Shape-preferred orientation; Magmatic flow; Podlesí granite; Meissen Massif ; 551 ; Earth Sciences; Geology; Geophysics/Geodesy
    Language: English
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  • 77
    Publication Date: 2021-03-29
    Keywords: loess; loess-like deposits; Pleistocene; Weichselian; spatial analysis; NW Germany ; 551
    Language: English
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  • 78
    Publication Date: 2021-03-29
    Description: The Eastern Sierras Pampeanas were structured by three main events: the Ediacaran to early Cambrian (580–510 Ma) Pampean, the late Cambrian–Ordovician (500–440 Ma) Famatinian and the Devonian-Carboniferous (400–350 Ma) Achalian orogenies. Geochronological and Sm–Nd isotopic evidence combined with petrological and structural features allow to speculate for a major rift event (Ediacaran) dividing into two Mesoproterozoic major crustal blocks (source of the Grenvillian age peaks in the metaclastic rocks).This event would be coeval with the development of arc magmatism along the eastern margin of the eastern block. Closure of this eastern margin led to a Cambrian active margin (Sierra Norte arc) along the western margin of the eastern block in which magmatism reworked the same crustal block. Consumption of a ridge segment (input of OIB signature mafic magmas) which controlled granulite-facies metamorphism led to a final collision (Pampean orogeny) with the western Mesoprotrozoic block. Sm–Nd results for the metamorphic basement suggest that the TDM age interval of 1.8–1.7 Ga, which is associated with the less radiogenic values of εNd(540) (−6 to −8), can be considered as the mean average crustal composition for the Eastern Sierras Pampeanas. Increasing metamorphic grade in rocks with similar detrital sources and metamorphic ages like in the Sierras de Córdoba is associated with a younger TDM age and a more positive εNd(540) value. Pampean pre-540 Ma granitoids form two clusters, one with TDM ages between 2.0 and 1.75 Ga and another between 1.6 and 1.5 Ga. Pampean post-540 Ma granitoids exhibit more homogenous TDM ages ranging from 2.0 to 1.75 Ga. Ordovician re-activation of active margin along the western part of the block that collided in the Cambrian led to arc magmatism (Famatinian orogeny) and related ensialic back-arc basin in which high-grade metamorphism is related to mid-crustal felsic plutonism and mafic magmatism with significant contamination of continental crust. TDM values for the Ordovician Famatinian granitoids define a main interval of 1.8–1.6, except for the Ordovician TTG suites of the Sierras de Córdoba, which show younger TDM ages ranging from 1.3 to 1.0 Ga. In Devonian times (Achalian orogeny), a new subduction regime installed west of the Eastern Sierras Pampeanas. Devonian magmatism in the Sierras exhibit process of mixing/assimilation of depleted mantle signature melts and continental crust. Achalian magmatism exhibits more radiogenic εNd(540) values that range between 0.5 and −4 and TDM ages younger than 1.3 Ga. In pre-Devonian times, crustal reworking is dominant, whereas processes during Devonian times involved different geochemical and isotopic signatures that reflect a major input of juvenile magmatism.
    Keywords: Magmatism-metamorphism; Sm–Nd systematics; Tectonic evolution; Neoproterozoic-early Paleozoic orogenies; Eastern Sierras Pampeanas ; 551 ; Earth Sciences; Geophysics/Geodesy; Geology
    Language: English
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  • 79
    Publication Date: 2021-03-29
    Description: The expansion processes that develop in building stones upon changes of moisture content may be an important contributing factor for their deteriorations. Until recently, few data could be found in the literature concerning this parameter and weathering processes. Moreover, the processes that may be responsible for the moisture related expansion of natural building stones are not yet completely understood. To further elucidate this process, extensive mineralogical, petrophysical and fabric investigations were performed on eight German sandstones in order to obtain more information regarding the weathering process and its dependence on the rock fabric. The analysed sandstones show a wide range of pore size distributions and porosities. A positive correlation with the fabric and the pore space can be found for all studied petrophysical parameters. The intensity of the expansion and related swelling pressure cannot be attributed only to the swelling of clay minerals. The investigations suggest that the micropores and the resulting disjoining pressure during wet/dry cycles also play an important role. The results obtained suggest that the mechanism is related to the presence of liquid water within the porous material.
    Keywords: Sandstone weathering; Moisture expansion; Hygric and hydric wetting; Swelling clay minerals ; 551 ; Earth Sciences; Geology
    Language: English
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  • 80
    facet.materialart.
    Unknown
    Springer-Verlag | Berlin/Heidelberg
    Publication Date: 2021-03-29
    Description: The profitable production of dimension stone mainly depends on the extractable block size. The regularity and volume of the blocks are of critical importance, and are controlled by the three-dimensional pattern of the discontinuity system. Therefore, optimization of block size has to be the aim when quarrying for natural stone. This is mainly connected to the quantification of joints and fractures, i.e., their spacing and orientation. The problem of finding unfractured blocks within arbitrarily oriented and distributed planes can be solved effectively by a numerical algorithm. The main effects of joint orientations on block sizes and shapes will be presented in this article. Quantification of unfractured blocks with the aim of optimization is illustrated by detailed studies on several quarries. The algorithm used in this study can be applied as a powerful tool in the planning of a quarry and the future exploitation of dimension stone. Application of the described approach is demonstrated on practical examples of quarrying natural stones, namely, sandstone, granite, rhyolite, etc. Block quarrying can be optimized by using the new 3D-BlockExpert approach. The quantification of unfractured rock masses is also shown to contribute to a more ecological protection and the sustainable use of natural resources.
    Keywords: Production of dimension stones; Joints and fractures; Block sizes; Optimization ; 551 ; Earth Sciences; Geology
    Language: English
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  • 81
    Publication Date: 2021-03-29
    Description: Damages to natural building stones induced by the action of frost are considered to be of great importance. Commonly, the frost resistance of building stones is checked by standardised freeze–thaw tests before using. Corresponding tests normally involve 30–50 freeze–thaw action cycles. In order to verify the significance of such measurements, we performed long-term tests on four selected rocks over 1,400 freeze–thaw action cycles. Additionally, numerous petrophysical parameters were analysed to compare the behaviour of rocks in the weathering tests according to the current explanatory models of stress formation by growing ice crystals in the pore space. The long-term tests yield more information about the real frost sensibility of the rocks. A clear deterioration cannot be determined in most cases until 50 weathering cycles have been completed. In the freeze–thaw tests, the samples are also stressed by changing temperature and moisture, indicating that different decay mechanisms can interfere with each other. Thus, thermohygric and moisture expansion are important damage processes.
    Keywords: Freeze–thaw action; Natural building stones; Microfabric; Pore space properties ; 551 ; Earth Sciences; Geology
    Language: English
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  • 82
    Publication Date: 2021-03-29
    Description: Owing to its long building history, different types of building stones comprised the construction of the Cologne Cathedral. Severe damage is observed on the different stones, e.g., sandstones, carbonate, and volcanic rocks, especially when the different stone materials neighbor the medieval “Drachenfels trachyte” from the “Siebengebirge”. The question arises, “Is the insufficient compatibility of the implemented building materials causatively related to the strong decay of the Drachenfels trachyte?” The present investigations focus on the petrography and mineralogical composition of eight different stones from the Cologne Cathedral. Petrophysical data, i.e., phase content, moisture and thermal characteristics as well as strength properties are determined and discussed in correlation to each other, showing that not only in terms of lithology great differences exist, but also the petrophysical properties strongly diverge. The ascertained parameters are discussed in view of the deterioration behavior and decay mechanisms of the different stones. To evaluate the compatibility of original, replacement and modern building materials, the properties of the investigated stones are compared to those of Drachenfels trachyte by means of constraints given in the literature. Besides optical properties, petrophysical criteria are also defined as well as strength values. It could be shown that primarily moisture properties, i.e., capillary and sorptive water uptake, water saturation, drying processes and moisture dilatation can be addressed to the deterioration processes.
    Keywords: Stone decay; Cologne Cathedral; Compatibility of building materials; Requirements for replacement stones ; 551 ; Earth Sciences; Geology
    Language: English
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  • 83
    Publication Date: 2021-03-29
    Keywords: Groundwater; Bangladesh ; 551
    Language: English
    Type: article , submittedVersion
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  • 84
    Publication Date: 2021-04-27
    Description: The range of substrates that the bone-eating marine worm Osedax is able to consume has important implications for its evolutionary history, especially its potential link to the rise of whales. Once considered a whale specialist, recent work indicates that Osedax consumes a wide range of vertebrate remains, including whale soft tissue and the bones of mammals, birds and fishes. Traces resembling those produced by living Osedax have now been recognized for the first time in Oligocene whale teeth and fish bones from deep-water strata of the Makah, Pysht and Lincoln Creek formations in western Washington State, USA. The specimens were acid etched from concretions, and details of the borehole morphology were investigated using micro-computed tomography. Together with previously published Osedax traces from this area, our results show that by Oligocene time Osedax was able to colonize the same range of vertebrate remains that it consumes today and had a similar diversity of root morphologies. This supports the view that a generalist ability to exploit vertebrate bones may be an ancestral trait of Osedax.
    Keywords: Deep-sea; Trace fossil; Osedax; Whale; Fish; Micro-CT; Tiefsee; Spurenfossil; Osedax; Wal; Fisch; Micro-CT ; 551 ; Earth Sciences; Paleontology
    Language: English
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  • 85
    Publication Date: 2021-03-29
    Description: Despite two decades of intensive laboratory investigations, several aspects of contaminant removal from aqueous solutions by elemental iron materials (e.g., in Fe(0)/H2O systems) are not really understood. One of the main reasons for this is the lack of a unified procedure for conducting batch removal experiments. This study gives a qualitative and semi-quantitative characterization of the effect of the mixing intensity on the oxidative dissolution of iron from two Fe(0)-materials (materials A and B) in a diluted aqueous ethylenediaminetetraacetic solution (2 mM EDTA). Material A (fillings) was a scrap iron and material B (spherical) a commercial material. The Fe(0)/H2O/EDTA systems were shaken on a rotational shaker at shaking intensities between 0 and 250 min(-1) and the time dependence evolution of the iron concentration was recorded. The systems were characterized by the initial iron dissolution rate (k(EDTA)). The results showed an increased rate of iron dissolution with increasing shaking intensity for both materials. The increased corrosion through shaking was also evidenced through the characterization of the effects of pre-shaking time on k(EDTA) from material A. Altogether, the results disprove the popular assumption that mixing batch experiments is a tool to limit or eliminate diffusion as dominant transport process of contaminant to the Fe(0) surface.
    Keywords: Co-precipitation; EDTA; corrosion products; Reactivity; Zerovalent iron ; 551 ; Chelating Agents ; Corrosion ; Edetic Acid ; Iron ; Kinetics ; Metals ; Oxidation-Reduction ; Rotation ; Solubility ; Solutions
    Language: English , English
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  • 86
    Publication Date: 2021-03-29
    Keywords: Thiobencarb; Herbicides; Zero valent iron (ZVI); Removal; Wastewater treatment ; 551 ; Iron ; Magnesium ; Thiocarbamates ; Water Pollutants, Chemical ; Water Purification ; Zinc
    Language: English , English
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  • 87
    Publication Date: 2021-03-29
    Description: Geological mapping and detailed structural investigations combined with geochronological and stratigraphic data, as well as fissiontrack age dating carried out on the northern part of the Pelagonian basement and the adjacent Vardar/Axios sedimentary and metamorphic sequences in the Hellenic Alps (northwestern Greece and Former Yugoslavian Republic of Macedonia) allow us to reconstruct the geometry, kinematics and deformation history of the Pelagonian nappe pile during the Alpine orogeny. We distinguish seven deformational events (D and D to D ). Deformation started in Middle to Late Jurassic time and was associated with inneroceanic HP 1 6 thrusting, ophiolite obduction, and NW- to WNW-directed nappe stacking of the Lower and Upper Pelagonian unit (D ). The lower unit 1 was metamorphosed under greenschist to amphibolite facies conditions with relatively high pressures (T=450-620°C, P=8-12,5 kb). Blueschist-facies metamorphic assemblages (D , T=450-500°C, P〉12,5 kb) are restricted to the boundary zone between both Pela- HP gonian units. Transgressive Late Jurassic to Early Cretaceous shallow-water limestones and clastic sediments on top of the obducted ophiolites are probably related to extension and basin formation simultaneously with nappe stacking and metamorphism in the Pelagonian nappes beneath. Contractional tectonics with the same kinematics as during D continued in Aptian-Albian time and was asso- 1 ciated with intense retrogression (D , T=280-380°C, P=4-5 kb). Low-angle mylonitic extensional shear zones of low-grade metamor- 2 phism with top-to-NE sense of movement (D ) developed simultaneously with basin formation and sedimentation of shallow-water 3 limestones and flysch-like sediments in Late Cretaceous to Paleocene times. Intense imbrication under semi-ductile to brittle conditions of all tectonic units occurred during Paleocene to Eocene time with SW-directed movement towards the foreland (D ). A large 4 Pelagonian antiformal structure formed during D shortening. In Oligocene to recent time, D and D created brittle low- and high- 4 5 6 angle normal faults, respectively.
    Description: Im nördlichen Teil des Pelagonischen Kristallins und in den metamorphen und sedimentären Gesteinsfolgen der angrenzenden Vardar/Axios-Zone der Helleniden (NW-Griechenland und Frühere Jugoslawische Republik Mazedonien) wurde eine geologische Kartierung und ausführliche strukturgeologische Untersuchungen durchgeführt. Verbunden mit geochronologischen und stratigraphischen Daten erlauben unsere Ergebnisse, die Geometrie, Kinematik und Deformationsgeschichte des pelagonischen Deckenlandes während der alpidischen Gebirgsbildung zu rekonstruieren. Wir haben sieben Deformationsereignisse (D und D bis D ) HP 1 6 unterschieden. Die Deformationsgeschichte begann im Mittleren bis Späten Jura mit intra-ozeanischer Überschiebung, Ophiolith- Obduktion und NW- bis WNW-gerichteter Deckenstapelung der Unteren und Oberen Pelagonischen Einheit (D ). Die untere Einheit 1 wurde unter den Bedingungen der Grünschiefer- bis Amphibolitfazies bei relativ hohem Druck metamorph überprägt (T 450-620°C, P 8-12,5 kb). Blauschieferfazielle Paragenesen sind in der tektonischen Kontaktzone zwischen den beiden pelagonischen Einheiten erhalten (D : T 450-500°C, P 〉12,5 kb). Transgressiv auf obduzierten Ophiolithen abgelagerte oberjurassische bis unterkretazische HP Flachwasserkalke und klastische Sedimente sind wahrscheinlich mit Extension und Beckenbildung im obersten Krustenstockwerk und gleichzeitiger Deckenstapelung und Metamorphose in den unteren pelagonischen Decken verbunden. Im Aptium-Albium setzte sich die Einengungstektonik mit derselben Kinematik wie während D fort und ging mit intensiver retrograder Metamorphose einher 1 (D : T 280-380°C, P 4-5 kb). Flach einfallende mylonitische Abscherungszonen, die unter schwachen grünschieferfaziellen Metamor- 2 phosebedingungen NE-gerichteten Schersinn anzeigen (D ), entwickelten sich während der Oberen Kreide und des Paleozäns, 3 gleichzeitig mit Beckenbildung und Sedimentation von Flachwasserkalken und Flysch. Intensive Verkürzung und Imbrikation aller tektonischen Einheiten (D ) fand unter semiduktilen bis spröden Bedingungen und nach SW (gegen das Vorland) gerichteter Haupt- 4 bewegung während des Paleozäns bis Eozäns statt. Eine große Antiform bildete sich im Pelagonikum während dieser Einengungsphase. Vom Oligozän bis heute bildeten sich spröde, flach oder steil geneigte Abschiebungen (D und D ) 5 6 _______________________________________________________________________________ .
    Keywords: Vardar/Axios Zone; Pelagonian nappe; compression; Hellenides; extension ; 551
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  • 88
    Publication Date: 2021-03-29
    Description: Ice in polar ice sheets undergoes deformation during its flow towards the coast. Deformation and recrystallization microstructures such as subgrain boundaries can be observed and recorded using high-resolution light microscopy of sublimation-edged sample surfaces (microstructure mapping). Subgrain boundaries observed by microstructure mapping reveal characteristic shapes and arrangements. As these arrangements are related to the basal plane orientation, full crystallographic orientation measurements are needed for further characterization and interpretation of the subgrain boundary types. X-ray Laue diffraction measurements validate the sensitivity of different boundary types with sublimation used by microstructure mapping for the classification. X-ray Laue diffraction provides misorientation values of all four crystal axes. Line scans across a subgrain boundary pre-located by microstructure mapping can determine the rotation axis and angle. Together with the orientation of the subgrain boundary this yields information on the dislocation types. Tilt and twist boundaries composed of dislocations lying in the basal plane, and tilt boundaries composed of nonbasal dislocations were found. A statistical analysis shows that nonbasal dislocations play a significant role in the formation of all subgrain boundaries.
    Keywords: Subgrain boundaries; Antarctic, Ice; X-ray; diffraction ; 551
    Language: English
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  • 89
    Publication Date: 2021-03-29
    Keywords: Uranyl(VI) hydrolysis; Time-resolved laser-induced fluorescence spectroscopy; Speciation; Relative fluorescence yield ; 551
    Language: English
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  • 90
    Publication Date: 2021-03-29
    Keywords: Contaminant removal; Point of use; Safe water; Water filtration; Zerovalent iron ; 551
    Language: English
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  • 91
    Publication Date: 2021-03-29
    Description: A central aspect of the contaminant removal by elemental iron materials (Fe0 or Fe0 materials) is that reduction reactions are mediated by the iron surface (direct reduction). This premise was introduced by the pioneers of the reactive wall technology and is widely accepted by the scientific community. In the meantime enough evidence has been provided to suggest that contaminant reduction through primary corrosion products (secondary reductants) does indeed occur (indirect reduction). It was shown for decades that iron corrosion in the pH range of natural waters (4-9) inevitably yields an obstructive oxide film of corrosion products at the metal surface (oxide film). Therefore, contaminant adsorption on to corrosion products and contaminant co-precipitation with corrosion products inevitably occurs. For adsorbed and coprecipitated contaminants to be directly reduced the oxide film should be electronic conductive. This study argues through a literature review a series of points which ultimately lead to the conclusion that, if any quantitative contaminant reduction occurs in the presence of Fe0 materials, it takes place within the matrix of corrosion products and is not necessarily a direct reduction. It is concluded that Fe0 materials act both as source of corrosion products for contaminant adsorption/coprecipitation and as a generator of FeII and H2 (H) for possible catalytic contaminant reduction.
    Keywords: Adsorption; Co-precipitation; Elemental Iron; Groundwater; Remediation ; 551 ; Adsorption ; Corrosion ; Iron ; Oxidation-Reduction ; Water ; Water Pollutants
    Language: English , English
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  • 92
    Publication Date: 2021-03-29
    Description: Indentation of rigid blocks into rheologically weak orogens is generally associated with spatiotemporally variable vertical and lateral block extrusion. The European Eastern and Southern Alps are a prime example of microplate indentation, where most of the deformation was accommodated north of the crustal indenter within the Tauern Window. However, outside of this window only the broad late-stage exhumation pattern of the indented units as well as of the indenter itself is known. In this study we refine the exhumational pattern with new (U–Th–Sm)/He and fission-track thermochronology data on apatite from the Karawanken Mountains adjacent to the eastern Periadriatic fault and from the central-eastern Southern Alps. Apatite (U–Th–Sm)/He ages from the Karawanken Mountains range between 12 and 5 Ma and indicate an episode of fault-related exhumation leading to the formation of a positive flower structure and an associated peripheral foreland basin. In the Southern Alps, apatite (U–Th–Sm)/He and fission-track data combined with previous data also indicate a pulse of mainly Late Miocene exhumation, which was maximized along thrust systems, with highly differential amounts of displacement along individual structures. Our data contribute to mounting evidence for widespread Late Miocene tectonic activity, which followed a phase of major exhumation during strain localization in the Tauern Window. We attribute this exhumational phase and more distributed deformation during Adriatic indentation to a major change in boundary conditions operating on the orogen, likely due to a shift from a decoupled to a coupled system, possibly enhanced by a shift in convergence direction.
    Keywords: Southern and Eastern Alps; Low-temperature thermochronology; Adria indentation; Exhumation ; 551
    Language: English
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  • 93
    Publication Date: 2021-03-29
    Description: The Toba eruption that occurred some 74 ka ago in Sumatra, Indonesia, is among the largest volcanic events on Earth over the last 2 million years. Tephra from this eruption has been spread over vast areas in Asia, where it constitutes a major time marker close to the Marine Isotope Stage 4/5 boundary. As yet, no tephra associated with Toba has been identified in Greenland or Antarctic ice cores. Based on new accurate dating of Toba tephra and on accurately dated European stalagmites, the Toba event is known to occur between the onsets of Greenland interstadials (GI) 19 and 20. Furthermore, the existing linking of Greenland and Antarctic ice cores by gas records and by the bipolar seesaw hypothesis suggests that the Antarctic counterpart is situated between Antarctic Isotope Maxima (AIM) 19 and 20. In this work we suggest a direct synchronization of Greenland (NGRIP) and Antarctic (EDML) ice cores at the Toba eruption based on matching of a pattern of bipolar volcanic spikes. Annual layer counting between volcanic spikes in both cores allows for a unique match. We first demonstrate this bipolar matching technique at the already synchronized Laschamp geomagnetic excursion (41 ka BP) before we apply it to the suggested Toba interval. The Toba synchronization pattern covers some 2000 yr in GI-20 and AIM- 19/20 and includes nine acidity peaks that are recognized in both ice cores. The suggested bipolar Toba synchronization has decadal precision. It thus allows a determination of the exact phasing of inter-hemispheric climate in a time interval of poorly constrained ice core records, and it allows for a discussion of the climatic impact of the Toba eruption in a global perspective. The bipolar linking gives no support for a long-term global cooling caused by the Toba eruption as Antarctica experiences a major warming shortly after the event. Furthermore, our bipolar match provides a way to place palaeoenvironmental records other than ice cores into a precise climatic context.
    Keywords: Greenland; Antarctic ice cores; Toba eruption ; 551
    Language: English
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  • 94
    Publication Date: 2021-03-29
    Description: This letter challenges the concept that the metallic iron (Fe0) surface contributes directly to the process of micro-organism inactivation in aqueous solutions. It is shown that any antimicrobial properties of Fe0 is related to the cycle of expansion/contraction accompanying aqueous iron corrosion. This demonstration corroborates the concept that aqueous contaminant removal in the presence of Fe0 mostly occurs at the Fe-oxide/water interface or within the oxide-film on Fe0.
    Keywords: Adsorption; Antimicrobial agent; Co-precipitation; Zerovalent iron ; 551
    Language: English
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  • 95
    Publication Date: 2021-03-29
    Description: Zerovalent iron (ZVI) has been proposed as reactive material in permeable in-situ walls for contaminated groundwater. An economically feasible ZVI reactive wall requires cheap but efficient iron materials. From an uranium treatability study and results of iron dissolution in 0.002 M EDTA by five selected ZVI materials, it is shown that current research and field implementation is not based on a rational selection of application-specific iron metal sources. An experimental procedure is proposed which could enable a better material characterization. This procedure consists in mixing ZVI materials and reactive additives including contaminant releasing materials (CRM) in long term batch experiments and characterise the contaminant concentration over the time.
    Keywords: contaminant; groundwater; in-situ remediation; zerovalent iron; uranium ; 551
    Language: English
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  • 96
    Publication Date: 2021-03-29
    Description: Forests in lowland Bolivia suffer from severe deforestation caused by different types of agents and land use activities. We identify three major proximate causes of deforestation. The largest share of deforestation is attributable to the expansion of mechanized agriculture, followed by cattle ranching and small-scale agriculture. We utilize a spatially explicit multinomial logit model to analyze the determinants of each of these proximate causes of deforestation between 1992 and 2004. We substantiate the quantitative insights with a qualitative analysis of historical processes that have shaped land use patterns in the Bolivian lowlands to date. Our results suggest that the expansion of mechanized agriculture occurs mainly in response to good access to export markets, fertile soil, and intermediate rainfall conditions. Increases in small-scale agriculture are mainly associated with a humid climate, fertile soil, and proximity to local markets. Forest conversion into pastures for cattle ranching occurs mostly irrespective of environmental determinants and can mainly be explained by access to local markets. Land use restrictions, such as protected areas, seem to prevent the expansion of mechanized agriculture but have little impact on the expansion of small-scale agriculture and cattle ranching. The analysis of future deforestation trends reveals possible hotspots of future expansion for each proximate cause and specifically highlights the possible opening of new frontiers for deforestation due to mechanized agriculture. Whereas the quantitative analysis effectively elucidates the spatial patterns of recent agricultural expansion, the interpretation of long-term historic drivers reveals that the timing and quantity of forest conversion are often triggered by political interventions and historical legacies.
    Keywords: Bolivia; Amazon; Deforestation; Proximate causes; Spatial analysis; Multinomial logistic regression ; 551 ; Environment; Geology; Geography (general); Regional/Spatial Science; Climate Change; Nature Conservation; Oceanography
    Language: English
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  • 97
    Publication Date: 2021-03-29
    Description: A qualitative and quantitative monitoring of groundwater discharge was conducted based on an airborne thermal campaign undertaken along the north-western coast of the Dead Sea in January 2011 to contribute to the relatively scarce information on groundwater discharge to date in the region. The application of airborne thermal data exploits thermal contrasts that exist between discharging groundwater and background sea surface temperatures of the Dead Sea. Using these contrasts, 72 discharge sites were identified from which only 42 were known from previous in situ measurements undertaken at terrestrial springs by the Israel Hydrological Service. Six of these sites represent submarine springs and at a further 24 locations groundwater appears to seep through the sediment. Although the abundance of groundwater seepage sites suggests a significant, but so far unknown groundwater source, the main contribution appears to originate from terrestrial springs. In an attempt to provide a quantitative approach for terrestrial springs, a linear bootstrap regression model between in situ spring discharge and respective thermal discharge plumes (r2 = 0.87 p 〈 0.001) is developed and presented here. While the results appear promising and could potentially be applied to derive discharge values at unmonitored sites, several influence factors need to be clarified before a robust and reliable model to efficiently derive a complete quantitative picture of groundwater discharge can be proposed.
    Keywords: thermal discharge plume; groundwater discharge; ; 551
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  • 98
    Publication Date: 2021-03-29
    Description: The impact of wood combustion on ambient aerosols was investigated in Augsburg, Germany during a winter measurement campaign of a six-week period. Special attention was paid to the high time resolution observations of wood combustion with different mass spectrometric methods. Here we present and compare the results from an Aerodyne aerosol mass spectrometer (AMS) and gas chromatographic – mass spectrometric (GC-MS) analysed PM1 filters on an hourly basis. This includes source apportionment of the AMS derived organic matter (OM) using positive matrix factorisation (PMF) and analysis of levoglucosan as wood combustion marker, respectively. During the measurement period nitrate and OM mass are the main contributors to the defined submicron particle mass of AMS and Aethalometer with 28% and 35 %, respectively. Wood combustion organic aerosol (WCOA) contributes to OM with 23% on average and 27% in the evening and night time. Conclusively, wood combustion has a strong influence on the organic matter and overall aerosol composition. Levoglucosan accounts for 14% of WCOA mass with a higher percentage in comparison to other studies. The ratio between the mass of levoglucosan and organic carbon amounts to 0.06. This study is unique in that it provides a one-hour time resolution comparison between the wood combustion results of the AMS and the GC-MS analysed filter method at a PM1 particle size range. The comparison of the concentration variation with time of the PMF WCOA factor, levoglucosan estimated by the AMS data and the levoglucosan measured by GC-MS is highly correlated (R2 = 0.84), and a detailed discussion on the contributors to the wood combustion marker ion at mass-to-charge ratio 60 is given. At the end, both estimations, the WCOA factor and the levoglucosan concentration estimated by AMS data, allow to observe the variation with time of wood combustion emissions (gradient correlation with GC-MS levoglucosan of R2 = 0.84). In the case of WCOA, it provides the estimated magnitude of wood combustion emission. Quantitative estimation of the
    Keywords: aerosol; mass spectrometer; AMS;: ; 551
    Language: English
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  • 99
    Publication Date: 2021-03-29
    Description: This letter suggests possible improvements on the discussion of the adsorptive removal of triazoles by iron minerals which are possible corrosion products of elemental iron materials (Fe0) in a recent article by Y. Jia and his co-workers. Also recalled is the importance of the adsorption of organics by iron corrosion products which is not properly addressed in the iron technology literature when the contaminants are redox-sensitive.
    Keywords: Adsorption; Elemental Iron; Iron Corrosion; Iron Oxhydroxides; Triazoles. ; 551
    Language: English
    Type: article , submittedVersion
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  • 100
    Publication Date: 2021-03-29
    Description: The origin and possible antiquity of the spectacularly diverse modern deep-sea fauna has been debated since the beginning of deep-sea research in the mid-nineteenth century. Recent hypotheses, based on biogeographic patterns and molecular clock estimates, support a latest Mesozoic or early Cenozoic date for the origin of key groups of the present deep-sea fauna (echinoids, octopods). This relatively young age is consistent with hypotheses that argue for extensive extinction during Jurassic and Cretaceous Oceanic Anoxic Events (OAEs) and the mid-Cenozoic cooling of deep-water masses, implying repeated re-colonization by immigration of taxa from shallow-water habitats. Here we report on a well-preserved echinoderm assemblage from deep-sea (1000–1500 m paleodepth) sediments of the NE-Atlantic of Early Cretaceous age (114 Ma). The assemblage is strikingly similar to that of extant bathyal echinoderm communities in composition, including families and genera found exclusively in modern deep-sea habitats. A number of taxa found in the assemblage have no fossil record at shelf depths postdating the assemblage, which precludes the possibility of deep-sea recolonization from shallow habitats following episodic extinction at least for those groups. Our discovery provides the first key fossil evidence that a significant part of the modern deep-sea fauna is considerably older than previously assumed. As a consequence, most major paleoceanographic events had far less impact on the diversity of deep-sea faunas than has been implied. It also suggests that deep-sea biota are more resilient to extinction events than shallow-water forms, and that the unusual deep-sea environment, indeed, provides evolutionary stability which is very rarely punctuated on macroevolutionary time scales.
    Description: Open-Access-Publikationsfonds 2012
    Keywords: deep-sea fauna ; 551
    Language: English
    Type: article , publishedVersion
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