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  • 04. Solid Earth::04.08. Volcanology::04.08.01. Gases  (39)
  • American Geophysical Union  (39)
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  • 1
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    Eruptive activity at Turrialba volcano (Costa Rica): Inferences from 3He/4He in fumarole gases and chemistry of the products ejected during 2014 and 2015 (2017)
    American Geophysical Union
    Details
    Publication Date: 2021-03-01
    Description: A new period of eruptive activity started at Turrialba volcano, Costa Rica, in 2010 after almost 150 years of quiescence. This activity has been characterized by sporadic explosions whose frequency clearly increased since October 2014. This study aimed to identify the mechanisms that triggered the resumption of this eruptive activity and characterize the evolution of the phenomena over the past 2 years. We integrate 3He/4He data available on fumarole gases collected in the summit area of Turrialba between 1999 and 2011 with new measurements made on samples collected between September 2014 and February 2016. The results of a petrological investigation of the products that erupted between October 2014 and May 2015 are also presented. We infer that the resumption of eruptive activity in 2010 was triggered by a replenishment of the plumbing system of Turrialba by a new batch of magma. This is supported by the increase in 3He/4He values observed since 2005 at the crater fumaroles and by comparable high values in September 2014, just before the onset of the new eruptive phase. The presence of a number of fresh and juvenile glassy shards in the erupted products increased between October 2014 and May 2015, suggesting the involvement of new magma with a composition similar to that erupted in 1864–1866. We conclude that the increase in 3He/4He at the summit fumaroles since October 2015 represents strong evidence of a new phase of magma replenishment, which implies that the level of activity remains high at the volcano.
    Description: Published
    Description: 3V. Proprietà dei magmi e dei prodotti vulcanici
    Description: 4V. Dinamica dei processi pre-eruttivi
    Description: 5V. Dinamica dei processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Turrialba volcano ; eruptive activity ; 3He/4He ; fumarole gases ; glassy shards ; juvenile component ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.08. Volcanic arcs ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
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    Spatially resolved SO2 flux emissions from Mt Etna (2017)
    American Geophysical Union
    Details
    Publication Date: 2020-12-15
    Description: We report on a systematic record of SO2 flux emissions from individual vents of Etna volcano (Sicily), which we obtained using a permanent UV camera network. Observations were carried out in summer 2014, a period encompassing two eruptive episodes of the New South East Crater (NSEC) and a fissure-fed eruption in the upper Valle del Bove. We demonstrate that our vent-resolved SO2 flux time series allow capturing shifts in activity from one vent to another and contribute to our understanding of Etna’s shallowplumbingsystemstructure.We findthatthe fissureeruptioncontributed~50,000tofSO2 or~30%of the SO2 emitted by the volcano during the 5 July to 10 August eruptive interval. Activity from this eruptive ventgraduallyvanishedon10August,markingaswitchofdegassingtowardtheNSEC.Onsetofdegassingat the NSEC was a precursory to explosive paroxysmal activity on 11–15 August.
    Description: Published
    Description: 7511-7519
    Description: 3V. Dinamiche e scenari eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Records of SO2 flux emissions from Etna’sindividualventsallowcapturing shifts in volcanic activity ; Vent-resolved SO2 flux time series provide constraints on geometry of the shallow plumbing system ; Vent-resolved SO2 flux time series demonstrate SO2 flux increase precursory to paroxysmal (lava fountaining) activity ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
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    Investigation into magma degassing at Nyiragongo volcano, Democratic Republic of the Congo (2008)
    American Geophysical Union
    Details
    Publication Date: 2021-01-27
    Description: We report the first combined measurements of the composition and flux of gas emitted from Nyiragongo volcano by ground-based remote-sensing techniques. Ultraviolet spectroscopic measurements made in May/June 2005 and January 2006 indicate average SO2 emission rates of 38 kg s−1 and 23 kg s−1, respectively. Open-path Fourier transform infrared spectroscopic measurements obtained in May/June 2005, January 2006, and June 2007 indicate average molar proportions of 70, 24, 4.6, 0.87, 0.26, 0.11, and 0.0016% for H2O, CO2, SO2, CO, HCl, HF, and OCS, respectively. The composition of the plume was remarkably similar in 2005, 2006, and 2007, with little temporal variation in proportions of CO2, SO2, and CO, in particular, on the scale of seconds or days or even between the three field campaigns that span a period of 24 months. This stability persisted despite a wide range of degassing behaviors on the surface of the summit crater's lava lake (including discrete strombolian bursts and lava fountains) and variations in the SO2 emission rate. We explain these observations by a regime of steady state degassing in which bubbles nucleate and ascend in chemical equilibrium with the convecting magma. Short-term (seconds to minutes) temporal fluctuations in the SO2–HCl–HF composition were observed, and these are attributed to shallow degassing processes.
    Description: Published
    Description: Q02017
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Nyiragongo ; volcanic gas emissions ; FTIR ; DOAS ; remote sensing ; spectroscopy ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
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    Gas emission strength and evolution of the molar ratio of BrO/SO2 in the plume of Nyiragongo in comparison to Etna (2016)
    American Geophysical Union
    Details
    Publication Date: 2021-06-25
    Description: Airborne and ground-based differential optical absorption spectroscopy observations have been carried out at the volcano Nyiragongo (Democratic Republic of Congo) tomeasure SO2 and bromine monoxide (BrO) in the plume inMarch 2004 and June 2007, respectively. Additionally filter pack andmulticomponent gas analyzer system (Multi-GAS)measurements were carried out in June 2007. Ourmeasurements provide valuable information on the chemical composition of the volcanic plume emitted fromthe lava lake of Nyiragongo. The main interest of this study has been to investigate for the first time the bromine emission flux of Nyiragongo (a rift volcano) and the BrO formation in its volcanic plume. Measurement data and results from a numerical model of the evolution of BrO in Nyiragongo volcanic plume are compared with earlier studies of the volcanic plume of Etna (Italy). Even though the bromine flux from Nyiragongo (2.6 t/d) is slightly greater than that from Etna (1.9 t/d), the BrO/SO2 ratio (maximum 7 × 10 5) is smaller than in the plume of Etna (maximum 2.1 × 10 4). A one-dimensional photochemical model to investigate halogen chemistry in the volcanic plumes of Etna and Nyiragongo was initialized using data from Multi-GAS and filter pack measurements. Model runs showed that the differences in the composition of volcanic volatiles led to a smaller fraction of total bromine being present as BrO in the Nyiragongo plume and to a smaller BrO/SO2 ratio.
    Description: Published
    Description: 277-291
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: Intraplate volcano Nyiragongo is bromine rich although chlorine poor ; BrO/Br in volcanic plumes depends on initial plume composition ; Determination of Nyiragongo chlorine, bromine, sulfur emission strength ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
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    Periodic volcanic degassing behavior: The Mount Etna example (2013)
    American Geophysical Union
    Details
    Publication Date: 2021-06-25
    Description: In contrast to the seismic and infrasonic energy released from quiescent and erupting volcanoes, which have long been known to manifest episodes of highly periodic behavior, the spectral properties of volcanic gas flux time series remain poorly constrained, due to a previous lack of hightemporal resolution gas-sensing techniques. Here we report on SO2 flux measurements, performed on Mount Etna with a novel UV imaging technique of unprecedented sampling frequency (0.5 Hz), which reveal, for the first time, a rapid periodic structure in degassing from this target. These gas flux modulations have considerable temporal variability in their characteristics and involve two period bands: 40–250 and 500–1200 s. A notable correlation between gas flux fluctuations in the latter band and contemporaneous seismic root-mean-square values suggests that this degassing behavior may be generated by periodic bursting of rising gas bubble trains at the magma-air interface.
    Description: Published
    Description: 4818–4822
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: SO2 flux ; UV camera ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
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    Gas emissions from five volcanoes in northern Chile and implications for the volatiles budget of the Central Volcanic Zone (2015)
    American Geophysical Union
    Details
    Publication Date: 2021-06-16
    Description: This study performed the first assessment of the volcanic gas output from the Central Volcanic Zone (CVZ) of northern Chile. We present the fluxes and compositions of volcanic gases (H2O, CO2, H2, HCl, HF, and HBr) from five of the most actively degassing volcanoes in this region—Láscar, Lastarria, Putana, Ollagüe, and San Pedro—obtained during field campaigns in 2012 and 2013. The inferred gas plume compositions for Láscar and Lastarria (CO2/Stot = 0.9–2.2; Stot/HCl = 1.4–3.4) are similar to those obtained in the Southern Volcanic Zone of Chile, suggesting uniform magmatic gas fingerprint throughout the Chilean arc. Combining these compositions with our own UV spectroscopy measurements of the SO2 output (summing to ~1800 t d 1 for the CVZ), we calculate a cumulative CO2 output of 1743–1988 t d 1 and a total volatiles output of 〉20,200 t d 1. 1.
    Description: Published
    Description: 4961-4969
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: Gas output from the Central Volcanic Zone ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
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    S, Cl and F degassing as an indicator of volcanic dynamics: The 2001 eruption of Mount Etna (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: The recent eruption of Mount Etna (July 2001) offered the opportunity to analyze magma-derived volatiles emitted during preand syn-eruptive phases, and to verify whether their composition is affected by changes in volcanic dynamics. This paper presents the results of analyses of F, Cl and S in the volcanic plume collected by filter-packs, and interprets variations in the composition based on contrasting solubility in magmas. A Rayleigh-type degassing mechanism was used to fit the acquired data and to estimate Henryâ s solubility constant ratios in Etnean basalt. This model provided insights into the dynamics of the volcano. Abundances of sulfur and halogens in eruptive plumes may help predict the temporal evolution of an ongoing effusive eruption.
    Description: -Gruppo Nazionale per la Vulcanologia.
    Description: Published
    Description: 1559
    Description: partially_open
    Keywords: magmatic degassing ; acidic gases ; plume chemistry ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 503 bytes
    Format: 275912 bytes
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  • 8
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    Real-time measurement of volcanic H2S and SO2 concentrations by UV spectroscopy (2006)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Sulphur speciation in volcanic gases acts as a major redox buffer, and H2S/SO2 ratios represent a valuable indicator of magmatic conditions and interactions between magmatic and hydrothermal fluids. However, measurement of H2S/SO2 even by direct sampling techniques, is not straightforward. We report here on application of a small ultraviolet spectrometer for real-time field measurement of H2S and SO2 concentrations, using open-path and extractive configurations. The device was tested at fumaroles on Solfatara and Vulcano, Italy, in November 2002. H2S concentrations of up to 220ppmm(400 ppmv) were measured directly above the Bocca Grande fumarole at Solfatara, and H2S/SO2 molar ratios of 2 and 2.4, respectively, were determined for the ‘F11’ and ‘F0’ fumaroles at Vulcano. In comparison with other optical techniques capable of multiple volcanic gas measurements, such as laser and FTIR spectroscopy, this approach is considerably simpler and cheaper, with the potential for autonomous, sustained hightime resolution operation.
    Description: Published
    Description: 1652
    Description: partially_open
    Keywords: Remote monitoring ; Plume chemistry ; sulphur species ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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    Format: 124998 bytes
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  • 9
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    Continuous monitoring of soil CO2 flux on Mt. Etna:The 2004–2005 eruption and the role of regional tectonics and volcano tectonics. (2008)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: The soil CO2 flux on Mt. Etna as recorded by the ETNAGAS network (an automatic system for measuring soil CO2 flux and meteorological parameters) started to increase strongly about 5 months prior to the onset of the 2004–2005 eruption and decreased a few months before the end of the eruption. Time delays in the occurrences of anomalies in soil CO2 flux at different sites in the geochemical network constrain the relationship between soil CO2 flux distributions and the tectonic framework of Etna volcano. The anomalies observed before the 2004–2005 eruption support the intrusion of new undegassed magma into the upper feeding system of the volcano (〈20 km below sea level). Magma subsequently rose slowly in the volcano conduits, thereby triggering the onset of the 2004–2005 eruption. The time delays in the occurrences of anomalies in combination with spectral analysis indicate the importance of tectonic and volcanotectonic structures in driving the ascent of deep gases within the crust. Moreover, greatest amplitude pulsations of the low-frequency components of the CO2 flux signals were correlated with the paroxystic activities of the 2004–2005 eruption. This study confirms that CO2 flux variation is a useful indicator for volcanic activity in the surveillance of the Mt. Etna and similar basaltic volcanoes.
    Description: Dipartimento Protezione Civile Ministero degli Interni
    Description: Published
    Description: B09206
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: CO2 flux ; Continuous monitoring of soil CO2 flux ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
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    Intercomparison of volcanic gas monitoring methodologies performed on Vulcano Island, Italy (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Volcanic gas emissions from fumaroles on the rim of La Fossa crater, Vulcano Island, Italy, were measured simultaneously using direct sampling (for H2O, CO2, total sulfur, HCl and HF), filter packs (for SO2, HCl, HF) and short-path active-mode FTIR measurements (for H2O, CO2,SO2, HCl and HF) in an intercomparison study in May 2002. The results show that Cl/F ratios were in good agreement between all three methods, and that FTIR and direct sampling determined comparable proportions of CO2 and H2O. Amounts of total S observed in direct sampling data were approximately double the amounts of SO2 measured with filter packs and FTIR. This difference could be attributed either to the fact FTIR and filter packs do not measure reduced sulfur species (e.g., H2S) or to sublimation of elemental S upon exit from the fumarole, after collection by direct sampling but before detection with FTIR and filter packs.
    Description: Published
    Description: L02610
    Description: partially_open
    Keywords: volcanic gas techniques ; gas geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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    Type: article
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