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  • Chemical Engineering  (1.749)
  • 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis  (6)
  • Wiley-Blackwell  (1.755)
  • 2010-2014  (6)
  • 1960-1964  (1.166)
  • 1955-1959  (583)
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  • 1
    Publikationsdatum: 2020-12-15
    Beschreibung: Seismogram envelopes recorded at Campi Flegrei caldera show diffusive characteristics as well as steep amplitude increases in the intermediate and late coda, which can be related to the presence of a non-uniformly scattering medium. In this paper, we first show the results of a simulation with a statistical model considering anisotropic scattering interactions, in order to match coda-envelope duration and shape.We consider as realistic parameters for a volcanic caldera the presence of large square root velocity fluctuations (10 per cent) and two typical correlation lengths for such an heterogeneous crust, a = 0.1 and 1 km. Then, we propose the inclusion of a diffusive boundary condition in the stochastic description of multiple scattering, in order to model intermediate and late coda intensities, and particularly the sharp intensity peaks at some stations in the caldera. Finally, we show that a reliable 2-D synthetic model of the envelopes produced by earthquakes vertically sampling a small region can be obtained including a single drastic change of the scattering properties of the volcano, that is, a caldera rim of radius 3 km, and sections varying between 2 and 3 km. These boundary conditions are diffusive, which signifies that the rim must have more scattering potential than the rest of the medium, with its diffusivity 2–3 orders of magnitude lower than the one of the background medium, so that the secondary sources on its interface(s) could enhance coda intensities. We achieve a good first-order model of high-frequency (18 Hz) envelope broadening adding to the Monte Carlo solution for the incident flux the secondary source effects produced by a closed annular boundary, designed on the caldera rim signature at 1.5 km depth. At lower frequencies (3 Hz) the annular boundary controls the intermediate and late coda envelope behaviour, in a way similar to an extended diffusive source. In our interpretation, the anomalous intensities observed at several stations and predicted by the final Monte Carlo solutions are mainly due to the diffusive transmission reflection from a scattering object of increased scattering power, and are controlled by its varying thickness.
    Beschreibung: This work was carried out under the HPC-Europa2 project (project number: 228398) with the support of the European Commission Capacities Area-Research Infrastructures Initiative. We thank the whole staff at EPCC (Edinburgh Parallel Computing Centre) in Edinburgh and particularly Dr. Adam Carter for their help in both developing and parallelizing the code. The challenging comments and suggestions of the editor and two anonymous reviewers helped both in focusing the aim and in overcoming the strong limits of a previous version of the paper.
    Beschreibung: Published
    Beschreibung: 1102–1119
    Beschreibung: 3.1. Fisica dei terremoti
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): Numerical solutions; ; Seismic anisotropy; ; Seismic attenuation ; Seismic tomography ; Wave scattering and diffraction ; Calderas ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 2
    Publikationsdatum: 2017-04-04
    Beschreibung: Local and regional seismicity jointly recorded by two dense small aperture arrays, one installed at surface and one at 1.3 km depth, constitutes an interesting data set useful for coda observations. Applying array techniques to earthquakes recorded at the two arrays we measure slowness, backazimuth and correlation coefficient of the coherent coda wave signals in five frequency bands in the range 1–10 Hz. Slowness distributions show marked differences between surface and underground, with slow signals at surface (slowness greater than 1.0 s km−1) that are not observed underground. We interpret these coherent signals as surface waves produced by the interaction of body waves with the free surface characterized by rough topography. The backazimuth values measured in the frequency bands centred at 1.5 and 3 Hz are almost uniformly distributed between 0 and 360◦, while those measured at higher frequencies show different distributions between surface and underground. On the contrary, the earthquake envelopes show very similar coda shapes between surface and underground recordings, with an almost constant coda-amplitude ratio (between 4 and 8) in a wide frequency range.
    Beschreibung: Published
    Beschreibung: 367-371
    Beschreibung: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): Coda waves ; Wave scattering and diffraction ; Wave propagation ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 3
    Publikationsdatum: 2017-04-04
    Beschreibung: In this work, we present regional maps of the inverse intrinsic quality factor (Qi −1), the inverse scattering quality factor (Qs −1) and total inverse quality factor (Qt −1) for the volcanic environment of Deception Island (Antarctica). Our attenuation study is based on diffusion approximation, which permits us to obtain the attenuation coefficients for every single couple source-receiver separately. The data set used in this research is derived from an active seismic experiment using more than 5200 offshore shots (air guns) recorded at 32 onshore seismic stations and four ocean bottom seismometers. To arrive at a regional distribution of these values, we used a new mapping technique based on a Gaussian space probability function. This approach led us to create ‘2-D probabilistic maps’ of values of intrinsic and scattering seismic attenuation. The 2-D tomographic images confirm the existence of a high attenuation body below an inner bay of Deception Island. This structure, previously observed in 2-D and 3-D velocity tomography of the region, is associated with a massive magma reservoir. Magnetotelluric studies reach a similar interpretation of this strong anomaly. Additionally, we observed areas with lower attenuation effects that bear correlation with consolidated structures described in other studies and associated with the crystalline basement of the area. Our calculations of the transport mean-free path and absorption length for intrinsic attenuation gave respective values of ≈950 m and 5 km, which are lower than the values obtained in tectonic regions or volcanic areas such as Tenerife Island. However, as observed in other volcanic regions, our results indicate that scattering effects dominate strongly over the intrinsic attenuation.
    Beschreibung: This work has been partially supported by the Spanish project Ephestos, CGL2011–29499-C02–01, by the EU project EC-FP7 MEDiterranean SUpersite Volcanoes (MED-SUV), by the Basque Government researcher training program BFI09.277 and by the Regional project ‘Grupo de Investigaci´on en Geof´ısica y Sismolog´ıa de la Junta de Andaluc´ıa, RNM104.’ Edoardo del Pezzo was partly supported by DPC-INGV projects UNREST SPEED and V2 (Precursori).
    Beschreibung: Published
    Beschreibung: 1957-1969
    Beschreibung: 3.1. Fisica dei terremoti
    Beschreibung: 3.6. Fisica del vulcanismo
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): Seismic attenuation; ; Seismic tomography ; Volcano seismology ; Wave scattering and diffraction ; Wave propagation ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Publikationsdatum: 2017-04-04
    Beschreibung: The peculiar source characteristics of long-period seismic events (time persistency of the source, low-frequency peaks in the source spectrum, absence of high-frequency radiation) prevent the formation of a definite high-frequency coda in the seismograms. In contrast, this is well formed in volcano–tectonic quakes. For this reason, the widely used duration magnitude scale that is based on the proportionality between the energy and the coda duration cannot be used for long-period estimation. In observatory practice, the long-period magnitude is sometimes estimated using the same duration magnitude scale, leading to confusing results. In this report, we show a new method to estimate the magnitude of long-period events that generally occur for volcanoes, with some application examples from data for Mt Etna (Italy), Colima Volcano (Mexico) and Campi Flegrei (Italy).
    Beschreibung: Published
    Beschreibung: 911-919
    Beschreibung: 3.1. Fisica dei terremoti
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): Earthquake source observations; ; Volcano monitoring ; Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Publikationsdatum: 2017-04-04
    Beschreibung: The coda normalization method is one of the most used methods in the inference of attenuation parameters Qα and Qβ . Since, in this method, the geometrical spreading exponent γ is an unknown model parameter, the most part of studies assumes a fixed γ , generally equal to 1. However γ and Q could be also jointly inferred from the non-linear inversion of codanormalized logarithms of amplitudes, but the trade-off between γ and Q could give rise to unreasonable values of these parameters. To minimize the trade-off between γ and Q, an inversion method based on a parabolic expression of the coda-normalization equation has been developed. The method has been applied to the waveforms recorded during the 1997 Umbria-Marche seismic crisis. The Akaike criterion has been used to compare results of the parabolic model with those of the linear model, corresponding to γ = 1. A small deviation from the spherical geometrical spreading has been inferred, but this is accompanied by a significant variation of Qα and Qβ values. For almost all the considered stations, Qα smaller than Qβ has been inferred, confirming that seismic attenuation, in the Umbria-Marche region, is controlled by crustal pore fluids.
    Beschreibung: Published
    Beschreibung: 1726-1731
    Beschreibung: 3.1. Fisica dei terremoti
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): Seismic attenuation ; coda normalization method ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Publikationsdatum: 2017-04-04
    Beschreibung: The complex volcanic system of Tenerife Island is known to have a highly heterogeneous character, as recently confirmed by velocity tomography.We present new information derived from intrinsic quality factor inverse maps (Qi −1), scattering quality factor inverse maps (Qs −1) and total quality factor inverse maps (Qt −1) obtained for the same region. The data set used in this work is the result of the analysis of an active seismic experiment carried out, using offshore shots (air guns) recorded at over 85 onshore seismic stations. The estimates of the attenuation parameters are based on the assumption that the seismogram energy envelopes are determined by seismic energy diffusion processes occurring inside the island. Diffusion model parameters, proportional to Qi −1 and to Qs −1, are estimated from the inversion of the energy envelopes for any source–receiver couple. They are then weighted with a new graphical approach based on a Gaussian space probability function, which allowed us to create ‘2-D probabilistic maps’ representing the space distribution of the attenuation parameters. The 2-D images obtained reveal the existence of a zone in the centre of the island characterized by the lowest attenuation effects. This effect is interpreted as highly rigid and cooled rocks. This low-attenuation region is bordered by zones of high attenuation, associated with the recent historical volcanic activity. We calculate the transport mean free path obtaining a value of around 4 km for the frequency range 6–12 Hz. This result is two orders of magnitude smaller than values calculated for the crust of the Earth. An absorption length between 10 and 14 km is associated with the average intrinsic attenuation parameter. These values, while small in the context of tectonic regions, are greater than those obtained in volcanic regions such as Vesuvius or Merapi. Such differences may be explained by the magnitude of the region of study, over three times larger than the aforementioned study areas. This also implies deeper sampling of the crust, which is evidenced by a change in the values of seismic attenuation. One important observation is that scattering attenuation dominates over the intrinsic effects, Qi being at least twice the value of Qs.
    Beschreibung: This work has been partially supported by the Spanish project Ephestos, CGL2011-29499-C02-01, by the EU project EC-FP7 MEDiterranean SUpersite Volcanoes (MED-SUV), by the Basque Government researcher training program BFI09.277 and by the Regional project ‘Grupo de Investigaci´on en Geof´ısica y Sismolog´ıa de la Junta de Andaluc´ıa, RNM104’. EdP has been partly supported by DPC-INGV projects UNREST SPEED and V2 (Precursori).
    Beschreibung: Published
    Beschreibung: 1942-1956
    Beschreibung: 3.1. Fisica dei terremoti
    Beschreibung: 3.3. Geodinamica e struttura dell'interno della Terra
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): Seismic attenuation ; ; Seismic tomography; ; Volcano seismology ; Wave propagation. ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 34-38 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Dielectric measurements made at 60 cycles per second over a temperature range of -40 to 200°C on small (0.2 g) samples arc most useful in studying acrylic polymers. Not only has this method elucidated structure, but the study of some structures has led to new interpretations emphasizing the value of this type of measurement. Data on a number of acrylic polymers are shown. Several copolymer systems are discussed. It is suggested that 60 c/s measurement of stereospecific PMMA samples can show more about molecular arrangements than has previously been revealed.
    Zusätzliches Material: 20 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 39-44 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: An investigation of the effect of sample dimensions on the oxidation of polypropylene is described. The results are used to select testing conditions. Two examples of the utility of the method are presented. First, a control method for uninhibited polypropylene and, secondly, an investigation of the synergistic effect between 2,6-di-t-butyl-p-cresol and dilaurylthiodipropionate.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 45-55 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Chemical structures limited to phosphines and their derivatives, including phosphine oxides, phosphonium salts and halogen-phosphorus compounds useful for fireproofing are discussed. In addition to these P-C bond containing compounds, structures containing P-O-C bonds are mentioned only if they are directly formed from halophosphorus substances. The general approaches to fireproofing are described. They include physical changes, unreactive additives, reactive comonomers, substitution of other functional groups and addition to a preformed polymer. Much of the literature is reviewed and the commercial importance of certain methods for both cloth and plastics are indicated.
    Materialart: Digitale Medien
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  • 10
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 72-72 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 11
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 66-71 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Much past confusion has originated from attempts to describe the complete optical properties of a plastic in terms of a few ill-defined parameters. Simple light-scattering theory and studies of morphology have been combined in this article to suggest the causes of polymer opacity; methods cited for the improvement of transparency and properties of reflectance have been re-examined in this light. It is concluded that the optical properties displayed by a polymer which is allowed to crystallize without external stress depend on fundamental molecular and morphological parameters. The extent to which these inherent characteristics can be modified depends on such widely different factors as the Tg of the polymer and the physical form of the desired article.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 12
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Four new fluoropolymers were pyrolyzed in a vacuum to study rates of volatilization and to identify decomposition products. The polymers thus studied were polyperfluoropropylene, polyperfluoroheptene, poly-4-chloroperfluoroheptadiene-1,6 and poly (1,2,2-triflluorovinyl phenyl ether). Polyperfluoropropylene yielded 100% monomer at temperatures of 300 to 400°C gave an activation energy of 56.6 Kcal/mole. Polyperfluoroheptenes of different molecular weights also yielded 100% monomer on heating. However, they had lower thermal stability than polyperfluoropropylene, but a higher activation energy and a higher pre-exponential factor. Poly-4-chloroperfluoroheptadiene volatilized at a rate of approximately 1% per minute at 380°C. There was very little monomer produced on thermal decomposition and an activation energy of 60 Kcal/mole was obtained from rates of volatilization at 362, 374, and 381°C. Poly (trifluorovinyl phenyl ether) showed a 25% carbonized residue at 500°C pyrolysis. The polymer decomposes into fragments containing very little monomer. Undesirable low molecular weight components in the polymer are still to be eliminated.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 13
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 77-78 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 14
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 133-136 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Unstable flow involving extrudate distortion have been observed in the extrusion of PVC. Two types of distortion have been isolated and the factors which are operative have been examined. These Factors are discussed in the light of existing knowledge of “melt fracture”.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 15
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 136-138 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The post extrusion swelling behavior of PVC has been studied as a function of the rheological flow variables and as a function of the molecular weight of the polymer. An expression which correlates the swelling with the apparent non-Newtonian viscosity has been found for each of the five molecular weight samples studied. No mechanism for this elastic effect was proposed.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 16
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 146-148 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 17
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 151-156 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Investigation of the crystallography of the thin platelike polymer crystals precipitated from dilute solution has led to the concept of chain folding in polymer crystallization. This unexpected and unusual phenomenon has produced much speculation about both its origin and its implications concerning the morphology of the polymer crystals. The theories which have been proposed to account for the observed effects fall into two categories: (a) equilibrium theories; and (b) kinetic theories. At the moment the kinetic theories appear to be the more successful in explaining the observed morphology and behavior of the polymer crystals. Essentially it is proposed that the plate-like habit of the crystals results from the formation of crystal uncleii from single polymer molecules followed by a growth process whose rate is controlled by nucleation of new crystal layers on existing completed crystal faces. Quantitative observations of crystal growth rates and of the influence of supercooling on the thickness of the crystals are consistent with the predictions of these theories.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 18
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 165-168 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Studies of polymer morphology under ideal conditions approaching equilibrium structures have been shown to be valuable in the development of an understanding of the relationship of properties to structure. Practical fabrication operations do not permit the achievement of equilibrium structures in commercial products and its is therefore necessary to study the effects of processing on the actual structures that result. In addition, an understanding of the effects of processing variables on properties permits the development of fabrication operations which can be directed toward the improvement of properties. Topics covered include the effects of hydrostatic pressure during processing, effects of combinations of pressure and thermal history, relationships between thermal history and crystallization rates in isotactic polymers and the kinetic and morphological effects of flow deformation on crystallizable plastics.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 19
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 157-164 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The relationship between crystallization and deformation is two-fold: (1) deformation or flow in polymers prior to crystallization has an important influence on the resultant crystalline morphology and (2) the morphology in turn largely determines the response of the structure to further deformation after crystallization. Thus, an understanding of deformation processes in crystalline polymers is intimately related to the crystallization processes and vice versa. The crystallization process may be approached by considering the observed morphological structures as being analogous to the usual crystal habits with the addition of various crystal-defects which add bending and twisting to the more common crystallographic variations. The crystal habit or morphology may be characterized by its surface to volume ratio. Crystallization of polymers may be considered as three steps (1) the formation of primary nuclei (2) crystallographic growth (also a nucleation controlled process) and (3) the introduction of crystal-defects which cause bending and twisting.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
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  • 20
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 169-177 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Mechanical and dielectric relaxation as related to the morphology of crystalline polymers is reviewed. The behavior with temperature of the imaginary part of the complex dielectric constant and the mechanical loss factor, tan δ, at constant frequency is discussed in detail for two typical crystalline polymers: poly(chlorotrifluoroethylene) and polypropylene. Three relaxations are typically observed: a low temperature relaxation occurring at temperatures below the dilatometric glass transition temperature; a glass temperature relaxation occurring near the glass transition temperature; and a high temperature relaxation occurring between the glass temperature and the melting point. The activation parameters are given for these relaxations, and the influence of morphology on them is discussed along with possible molecular interpretations.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 21
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 178-186 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Structural changes are considered in light of the two differing views of the structure of crystalline polymers involving either a two phase structure or a single phase structure involving detects. A compromise picture is proposed which appears consistent with existing experimental evidence. Optical methods are described for analyzing structural changes accompanying deformation of these polymers. These include x-ray diffraction, static and dynamic birefringence measurements and dynamic light scattering studies. The results are consistent with a two stage deformation process involving first the elastic deformation of a spherulitic or crystalline structure followed by an internal rearrangement of crystals within this structure, taking place by a number of mechanisms such as recrystallization, defect migration, plastic flow and crystal rotation. The time dependence of some of these processes is studied and related to structural features.
    Zusätzliches Material: 17 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 22
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 236-240 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The work carried out at Picatinny Arsenal on the weathering of plastics over the lat 15 years is briefly described. Although the perid of work was 15 years, individual systems were exposed for only three years. The need for running parallel tests on materials stored indoors for the three years is pointed out as a means of separating the effects of daging from weathering. Also brielfy discussed is the influence which the test method chosen can have on the judgment reached. The requirements of the application are as important as the inherent durability of the material. Improved compounds are becoming available and complete reporting of both favorable and unfavorable resuts is urged as a means of lending guidance in the search for still better compounds.
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 23
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 267-276 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The moduli of elasticity of reinforced plastics with uni-directional filaments either parallel or normal to an applied force are evaluated in terms of the material composition. Expressions are then derived which relate its moduli of elasticity and Poisson's ratios for an arbitrary filament orientation with its material properties in the direction of and normal to the unifilament orientation with its material properties in the direction of and normal to the unidirectional filaments. Filaments. The stress-strain relations of filament reinforced plastics are also derived.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 24
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 282-289 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Creep experiments under variable loading conditions are reported for tubular specimens of cellulose acetate butyrate. Experiments include the application of torque loading that corresponded to various loading programs. Results indicate that the material response in creep is nonlinear. The character of the results is described reasonably by assuming the behavior as linear and using the Botzmann superposition principle. However, the interpretation of the data based upon a non-liner creep law and modified superposition principle yields better agreement with experiments in certain cases.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 25
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 290-294 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Dupre's theory that work of rupture equals increase in surface energy, and Griffith's hypothesis (based upon Dupre's that a crack propagates when strain energy decrease equals or exceeds work required to creat two new surfaces are shown to be incorrect. Work is required for deformation to repture, not for the actual rupture.An alternative criterion, i. e., that crack propagation occurs when strain energy decrease exceeds the increase required for elastic deformation of the “critical domain” to the breaking point, offers the following advantages: (1) continuity between macro- and micro-effects, (2) avoidance of surface energy (unmeasurable for solids), (3) accounting for heat effect, (4) reasonable explanation of unexpectedly high “surface energy” values.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 26
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 315-362 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The Theory of Crystallization of bulk linear polymers with chain folding is discussed in terms of recent developments. Specific topics covered are: (a) Rate of crystal growth and size of folded nuclei, (b) theoretical and experimental estimates of the fold surface free energy, and estimates of the surface free energy of “friged micelle” and “switchbord” type crystals, (c) basic causes of essentially regular folding in bulk, (d) rejection of short chain species during crystallization, (e) melting behavior of thin chain-folded lamellae, (f) gradual thickening of lamellae on isothermal storage, (g) homogeneous, pseudohomogeneous, and heterogeneous nucleation, (h) voids and included point defects as a paret of the concept of the degree of crystallinity, and (i) phenomena occurring in stage 1 and stage 2 of bulk crystallization isotherms (annealing). A comparison of theory and experiment is carried out using data, some previously unpublished, on polyethylene and polychlorotrifluoroethylene. The theory with essentially regular golding is found to be satisfactory.
    Zusätzliches Material: 28 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 27
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 5-6 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 28
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 7-16 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The melt-filled portion of an extruder screw has been examined in a quantitative analytical fashion by numerous workers during recent years. The progress which has been made in defining flow patterns in this portion of the screw is reviewed, with special attention devoted to edge effects of the screw flights and the contribution of the circulatory cross-channel component of flow. More recent work on the complex problem introduced by the existence of curvature in the screw channel is presented, along with consideration of distortion of the streamlines caused by non-isothermal conditions and non-Newtonian fluid properties of the molten polymer.
    Zusätzliches Material: 29 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 29
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 187-192 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Oxidation of many polymers occurs by a free-radical, chain mechanism similar to that developed for the oxidation of volatile hydrocarbons. The rate at which various polymers oxidize and the extent of the reaction is influenced both by the physical and by the chemical structure of the particular polymer. Important morphological changes may also occur as a result of oxidation. Polymer degradation by oxidative reactions can be inhibited effectively at several stages in the over-all reaction. Synergistic combinations in which each component of a stabilizer system inhibits primarily at one of these stages are particularly effective.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 30
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 208-216 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Stress-strain relationships and evaluations thereof at testing and evaluation speeds from 1 to 50 inches per minute are presented. Behavior characteristics at “static” and dynamic strain rates are discussed and a brief reference to lateral critical velocity is made.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 31
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 217-223 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: In this brief review, environmental stress-cracking in polyethylene is taken as a typical example of the broad phenomenon of stress-cracking and the major variables affecting its operation are enumerated. In addition to stress, these include molecular weight, molecular weight distribution, the amount and nature of the crystalline phase present, the nature of the “environment,” the importance of its ability to alter the surface energy characteristics of the affected polymer, and the effects of temperatrue. The need for selecting an appropriate test procedure is stressed, and the probable significance of certain recent advances in comprehension of the crystallization mechanics of these materials is suggested.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 32
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 224-228 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Expanding interst in using plastics for structural pruposes immediately focuses attention on their poermanence. This desired quality is broadly defined as the persistence of a specific set of properties of a given asembly or manufactured product, in its appropriate environment, for an economically justified duration. Analysis of existing test methods, primarily those standardized by ASTM, shows no really applicable techniques for measuring permanence. By contrast, more advanced thinking presented by recent ASTM stmposia indicates two general routes to the porediction of performances. Whether a rigorous “micromechanistic” technique is used, or the empirical “macroanalytical” approach, or some combination of the two, is considered irrelevant. What is important is that experimental programs be started to provide better measures of permanence.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 33
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 245-250 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Poly-β-hydroxybutyric acid has been isolated in quantities sufficient for characterization and evaluation of mechanical properties from both Bacillus megaterium and a special strain of Rhizobium. Its presence in a larger variety of bacteria than previously suspected has been demonstrated by a screening method based on density-gradient centrifugation. The intrinsic viscosity of the isolated polymer has been shown to depend on the technique of isolation; basic solvents facilitate hydrolytic cleavage of the polyester. Mechanical properties of the polymer are based on the high crystallinity and polarity of the material; in a highly crystallized state, it is quite brittle, but its rigidity exceeds that of polypropylene. Thermal degradation of molecular weight, due to beta-eliminatin of the carboxyl group from the polyester structure, severely limits processing of the polymer in the melt.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 34
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 251-255 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Toluene diisocyanate was partially replaced by monobrominated toluene diisocyanate in conventional rigid polyurethane foam formulations, producing self-extinguishing foams for thermal insulation, with only moderate sacrifce of compressive strength, and with no significant effects upon reactivity, odor, density, cell structure, or resistance to aging.
    Zusätzliches Material: 8 Tab.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 35
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 263-266 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The combination fo dicyandiamide and diaminodiphenyl sulfone in the presence of a tertiary amine, like 2,4,6-tris (dimethyl amino methyl) phenol, will crosslink liquid epoxy resins (E.E.W. 180-200) of diglycidyl ether of Bisphenol A type, or brominated resins, and if used to impregnate glass cloth will produce printed circuit laminated boards combining interlaminar bond and flexural strength retention of NEMA-G-10 and G-11 grades.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 36
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 277-281 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Bueche and Harding [J. Polymer Sci. 32 177 (1958)] obtained an empirical “standard flow curve” to relate viscosity and shear rate by using a particular poly(styrene) solution and positioning the flow curve on a dimensionless rate of shear axis via the viscosity average molecular weight, MV and Bueche's expression for the relation time, τ, where \documentclass{article}\pagestyle{empty}\begin{document}$$ \tau = 12\eta _{\rm o} {\rm M}_{\rm R} /\pi ^2 {\rm RTC} $$\end{document} Here R is the gas constant, ηo is the low rate of shear Newtonian viscosity, T is the absolute temperature, C is the Concentration in grams per cubic centimeter, and MR is te molecular weight which determines the relaxation time. Bueche implies by his standard curve that MV correlates with MR. In Gereral, it was found that: 1) MR does not equal MV but it is usually significantly lower than MV or MW; (2) the value of MR increases with increasing polymer concentration and temperature; and (3) the shapes of the flow curves are slightly different from the shape of the standard curve. A survey of the data available in the lon the flow of polymer melts supports these conclusions. Thus, the Bueche-Harding method can only give semi-quantitative help I predicting the flow behavior of polymeric melts.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 37
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 295-305 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: It has been shown that a standard screw-extruder with a little modification is very useful for the measurement of flow properities of various plastics melt over a wide range. Results obtained are very interesting and it is expected that they have applicability to polymer processing. A range of flow rates covering both extrusion and injection molding applications were considered.
    Zusätzliches Material: 20 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 38
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 306-314 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Solid compositons studied included PTFE, PCFE, polyimides, both filled and unfilled, and fluorocarbon telomers. Evaporation experiments were conducted at ambient temperatures to fluorocarbon telomers. Evaporaton experiments were conducted at ambient temperatures to 1100°F and pressures to 10-8 mm Hg. Various molecular weights of different polymers were examined. Results indicate that evaporation rates in vacuum for polymers vary with molecular weight. Friction and wear experiments were conducted with a 3-16-inch-radius rider hemisphere (usually polymer) sliding on a flat disk (various materials) at speeds to 1480 feet per minute with a 1000-gram load on the rider specimen and at an ambient pressure of 10-9 mm Hg. Fillers were found to influence markedly the wear of PTFE and PCFE in vacuum as a result of changes in heat dissipation properties, but they showed little or no influence on friction.
    Zusätzliches Material: 18 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 39
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964) 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 40
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 2-4 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 41
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 79-82 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Previous work has demonstrated the possibility of obtaining curves of normal stress as a function of shearing stress for polymer solutions through the measurement of the swelling of a jet of the solution extruded from a long capillary. A new formulation of reduced variables is offered which allows results obtained at different concentrations to be correlated by a single curve for a given polymer system. Results are presented for water solutions of carboxymethylcellulose, and for xylene solutions of polyisobutylene. For polyisobutylene, the correlation is similar to those obtained by other investigators who measured normal stresses by standard techniques.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 42
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 90-97 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Attempts are made, in the light of published information, to decide the factors affecting network structure in commercial polyester resins and the effect of network variations on physical properties of polyfumarate-styrene copolymers. An approach towards the optimum in chemical and heat resistant polyester laminates is suggested by examination of the influence of polyester chain structural variations on these properties.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 43
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 98-101 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Recent dielectric measurements at 60 cycles per second have shown a good correlation amond α-peak, Vicat and dilatometric Tg temperatures. Other measurements of copolymer systems have suggested a re-examination of existing second-order transition temperature relationships. This study has revealed that the most common of these equations are mathematically equivalent and not fully satisfactory for explaining all observations. A relationship is proposed which is capable of fitting either linear or non-linear second-order transition data for compatible copolymer systems.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 44
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 127-128 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 45
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 129-133 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The melt flow properties of PVC Resins have been investigated. The Effects of molecular weight, temperature, and plasticizer (DOP) concentration on the Melt rheology have been examined and correlated with molecular properties of polymers.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 46
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 229-235 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The current status of weathering of plastics is reviewed. As a better understanding of the effective degradative parameters of weather are obtained, it is aparent that complex interactions occur. Present laboratory exposure tests do not simulate natural conditions sufficiently to provide the much neede reliable short term exposure test for predicting long term durability. While a major step forward occurred with the introduction of filtered xwnon lamps, which simulate terrestrial sunlight both in intensity and distribution, industry-wide support of fundamental studies of degradation is necessary if weathering studies are to be conducted scientifically.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 47
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964) 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 48
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 242-244 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 49
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 256-262 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The thickness of the adsorbed layer of two glass finishes, vinyl tris (2-methoxyethoxy) silane and gamma-aminopropyltriethoxysilane, was measured by ellipsometry. The vinyl silane was adsorbed on glass from solutions in water and in methyl ethyl ketone. The adsorption from water resulted in a film initially at least 50 Å thick, which increased in thickness with time. Adsorption from methyl ethyl ketone solution resulted in a film of about 10 Å. The amino silane was adsorbed on glass and on chrome from soutions in water. Adsorption on glass resulted in a film at least 60 Å in thickness, which remained constant over a period of about 5 hours. Adsorption on chrome resulted in a film about 10 Å in thickness. From the results it appears that a polymer, rather that small molecules of glass finish, is adsorbed from the water solution on glass and that small unpolymerized “finish” molecules are adsorbed from the methyl ethyl ketone solution.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 50
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 17-21 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The effect of a bimodal molecular weight distribution on the flow properties and stress crack resistance of polyethylene is investigated. It is found that the melt viscosity of a bimodal polyethylene is less shear dependent at high shear rates than a log normal distribution of equivalent weight average molecular weight and ratio of weight average to number average molecular weight. Spiral mold studies indicate that the bimodal polymer flows more readily under injection molding conditions. The stress crack resistance of the bimodal polymer is shown to be superior to other polyethylenes of the same weight average molecular weight.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 51
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 25-28 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The impact strength of a thermoplastic is shown to be a strong function of several variables. Among these are type of molding, molding conditions, molecular orientation, test temperature, and notches. Particularly significant is a maximum in the response of impact strength to molding temperature. The tensile impact test was used as a tool for these determinations.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 52
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 22-24 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Bicyclo [2.2.1] hepta-2,5-diene, the reaction product of acetylene and cyclopentadiene, and vinyl chloride readily copolymerized by a novel mechanism, to form copolymers containing the nortricyclene group whose softening points rapidly increase with increasing nortricycl one concentration. For each weight per cent copolymerized bicycloheptadiene, the softening point of the vinyl resin is increased about 1°C, making it the most effective comonomer known for this purpose. At the same time increasing nortricyclene concentration disrupts polymer crystallinity, lowers the resin's melting point, and hence its processing temperature, by about 3°C for each weight per cent copolymerized.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 53
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 29-33 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: There are several pieces of evidence in the published literature for the existence of a hexagonal crystalline form of polypropylene. Evidence obtained by infrared absorption, x-ray diffraction, differential thermal analysis, and annealing experiments is consistent with the view that the quenched state of polypropylene is a truly crystalline one (presumably of hexagonal type) with a very small crystallite size.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 54
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Pyrolysis in vacuum of gamma-irradiated polytrifluoroethylene indicates increased rates of volatilization with increased dosage. At the higher radiation doses, the rate curves no longer show a maximum but resemble those previously obtained with branched polyethylenes. Studies of swelling with acetone indicate crosslinking increases with radiation dose. It is estimated that for each chain fracture caused by radiation there are approximately seven crosslinks formed. However, in addition to the crosslinks a branched structure is also being produced as evidenced by the character of the thermal degradation rate curves. Alkali treatment of the polymer sensitizes it towards dehydrofluorination and double bond formation. Subsequent rate and pyrolysis studies showed the formation of very stable residues, indicating a relatively greater thermal stability of the main chain.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 55
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964) 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 56
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 74-76 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 57
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 83-89 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The paper presents the “Thermophysical Profiles” of selected plastics and discusses their significance in correlating the mechanical properties with the molecular and crystalline structure of these polymers. The profiles were obtained with a new instrument, by imposing a fixed, forced elastic vibration on the speciments' surface and by recording continuously the energy absorbed by the specimens through a temperature range from -200°F to +500°F The profiles locate the first and second order transition points of the test materials (defining, thus, the temperature limits of their use) and indicate the change in modulus with temperature in the viscoelastic region of the polymers. Profiles of the following materials are discussed, low and high density polyethylene, polypropylene and PVC films and unfilled samples of cast epoxy and polyester resins.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 58
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 102-106 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The basic requirements for optimization of filament-wound pressure vessels are a high strength-to-density ratio of the fiberglass-resin composite and an arrangement of the glass fibers in such fashion that each fiber carries, at a given pressure, the same constant load throughout the cylindrical portion as well as the end closures. The basic relations governing the isotensoidal design are derived, and the ideal shape of the end closure is defined. The relative merits of geodesic and “in-plane” wrapping are discussed. Structrual efficiencies accomplished in several practical applications are reviewed.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 59
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 107-112 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Studies of capillary extrusion measurements using an Instron rheometer show that certain types of high density polyethylene exhibit a discontinuity in the shear stress/shear rate curve. This behavior which is separate and distinct from the phenomenon of melt fracture is caused by a change in the flow regime. It is manifested by oscillation of the recorded load while the rheometer piston is operated at a constant rate. Therefore, this behavior has been termed “oscillating shear phenomenon”. The location and magnitude of the fluctuations are functions of the molecular parameters of the polymer as well as the melt temperature, capillary geometry, and other rheometer variables. Evidence is presented which indicates that the change in flow regime could result from the orientation of the melt as it enters the capillary.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 60
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 113-119 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Solution-grown crystals of polyethylene may reach lateral dimensions large enough for optical microscopy. Interference microscopy represents, in this case, a suitable method of observation of morphology and defects as well as quantitative determinations. The double-beam interference method used in the Baker type microscope has been applied to determine refractive indices and lamellar thicknesses. The Nomarski double-beam interferometer has been used for hot-stage experiments. Multiple-beam techniques involving silvering of crystal surfaces and using an ordinary light microscope for observation have been developed. The applicability of the different types of interference microscopy to polymer research is illustrated in a series of representative photomicrographs of polyethylene.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 61
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 120-127 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Carefully controlled experimental techniques were used to study the effect of variations in bulk E glass surfaces on bound life and wetting. Bond life (stability of the bound in the presence of moisture) was determined visually as the time required for hot water to remove an epoxy resin coating from the glass surface. Wetting was determined by the captive bubble technique. Both properties were significantly affected by variations of the glass surface. The bound life studies emphasized the importance of the coupling agent in promoting bound stability in a hot water environment. The only example of the glass surface not treated with a coupling agent that had a satisfactory bound life was the alkali-deficient glass surface prepared by acid leaching. The surprisingly poor bound lives of the degassed and freshly cleaved (high energy) glass surfaces indicated that the wet strength retention of laminates would be poor when prepared by instantaneously applying epoxy resin without a coupling agent to the glass fibers directly as the fibers are formed. Cleanliness and surface and surface roughness were the only two variables found that promoted wetting. This discrepancy with respect to cleanliness indicated that wetting was not the controlling factor for bond life.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 62
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 139-143 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The character of the residues from pyrolytic decomposition of organo-phosphorus polymers has suggested the use of such materials in ablative materials required for heat shields in reentry vehicles, rocket nozzles, etc.Phosphorus-containing phenolic resol and novolak resins were prepared by condensing di(p-hydroxyphenyl)-phenyl-(phosphine oxide) with aldehydes. The mechanical properties of the basic phosphorus-phenolics were improved by internal plasticization through chemical reaction of the resin in the early stages of polycondensation with acrylonitrile-butadiene copolymers (NBR) and with silences and slicone resins. To improve the compatibility of the phosphorus phenolics with NBR copolymers, the phosphorus-containing phenolics were initially etherified by “butanolization” in order to decrease their polarity.The preparation of coatings and molded discs from some modified and unmodified phosphorus-containing phenolic-resin formulations is described. Preliminary observations relating to the properties of the trial products are reported.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 63
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964) 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 64
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 149-150 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 65
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 193-207 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The deterioration of plastics by biological agents of considerable concern not only to the U. S. Department of Defense but to the national economy as a whole. Although the importance of the subject was recognized by some since the early days of the plastics industry, widespread investigation first began during World War II when serious problems were encountered in the tropics with electrical and electronic equipment. In the recent past the great developments in oceanography have emphasized that marine biodeterioration of plastics requires much more investigation. Biodeterioration of plastics is characterized according to that caused by microbiological agents, macrobiological agents, and marine biological agents. the important past and recent knowledge in each category is summarized.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 66
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 2-2 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 67
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 135-135 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 68
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 5-10 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 69
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 16-25 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 70
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 35-38 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 71
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 67-67 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 72
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 135-137 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 73
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 137-137 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 74
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 26-30 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 75
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 56-60 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 76
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 61-67 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The definition of filtration resistance is re-examined in view of the new theory (12) of the variation of flow rate with respect to distance through a filter cake. In the new definition it is shown that the filtration resistance depends upon slurry concentration as well as applied pressure. A correction factor modifying the specific filtration resistance previously defined by Ruth (5, 6) is developed.Where the hydraulic pressure variation within a cake is known, methods are presented for calculating the variation of flow rate with respect to distance and the change of filtration resistance in relation to slurry concentration.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 77
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 74-78 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: In the rotary drum crystallizer, solids are deposited from a molten liquid mixture on the cooled surface of a drum. Rotation of the drum carries the solids from the melt to a scraper blade which removes the crystal deposit in a liquid free, convenient form. The object of this investigation was to obtain data on the separation of binary mixtures over a range of melt temperature, drum coolant temperature, drum rotational rate, concentration of impurity in the liquid, and agitation of the liquid. Four systems were studied: naphthalene-benzoic acid, beta-naphthol-naphthalene, p-xylene-m-xylene, water-sodium chloride.The experimental results show that separation improved with increasing agitation, increasing coolant temperature, decreasing drum speed, and decreasing liquid impurity. For the naphthalene-benzoic acid system, the major system studied, the maximum stage efficiency was 96%. The results indicate that the vigor of agitation and the drum coolant temperature are the two most important variables which affect the separation. It was possible to calculate the rate of solid deposition with heat transfer data.The rotary drum crystallizer appears to be an effective device for industrial separation of organic chemicals.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 78
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 277-281 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 79
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 130-144 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 80
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 197-202 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 81
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 187-193 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Turbulent mixing of a dye solution injected at the center of a pipe was studied by means of a new light probe developed for the measurement of concentration fluctuations were made both along the axial distance and across the pipe. The concentration fluctuations persisted longer at the center-line region than anywhere else; this suggested the use of the decay of intensity at the center as an upper limit. Approximately 99% of the initial intensity decayed within 7.5 ft. (30 L/d). The concentration spectra along the axial distance indicated that the eddies initially undergo a scalar energy cascade. Because of the huge difference in the kinematic viscosity and molecular diffusivities the concentration spectra extend much farther toward high wave numbers than the velocity spectrum. Apparently a state of imbalance resulted between the supply of small eddies and their dissipation; this was marked by the appearance of a small hump in the spectra. The phenomenological approximations of Corrsin and of Beek and Miller could be used for the practical problem of predicting the decay of the intensity of the concentration fluctuations or mixing in the pipe geometry studied.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 82
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 202-205 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 83
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 206-213 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The adiabatic, evaporating, two-phase flow of steam and water in horizontal pipe including the critical flow was successfully described by a system of nonlinear differential equations which include different phase velocities, fluid acceleration, wall shear forces, interface shear forces, and mass and energy transfer between the phases. The solution of the differential equations by the method of Runge-Kutta was facilitated with a high-speed digital computer. Experimental data were obtained which included void fraction measurement by X-ray attenuation and showed that the theoretical equations described the complex flow phenomena to ± 10% when radial temperature gradients were small. Design charts based on the numerical solution of the theoretical equations are presented for rapid evaluation of the flow variables for the system steam-water including critical flow for inlet pressures from 30 to 150 lb./sq.in.abs., mass flow rates per unit area from 300 to 1,000 lb./sq. ft. sec., and L/D ratios from 25 to 1,000. The critical flow is defined as the maximum flow rate for a given pressure at the point of initial vaporization and L/D ratio.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 84
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 221-227 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The desorption of five sparingly soluble gases from water into air in a packed tower was studied at five different flow conditions. At 25°C. these systems represent a range of liquid-phase diffusivity from 1.4 × 10-5 to 6.3 × 10-5 sq. cm./sec. The mass transfer coefficient was found to vary as the 0.5 power of liquid-phase diffusivity in all cases. This result, obtained through the variation of diffusivity alone, is in agreement with the predictions of penetration theory and strongly suggests a penetration mechanism based on molecular processes and independent of eddy processes during a surface lifetime. A discussion of the nature of the diffusion and surface renewal process in flow over packing is included.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 85
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 266-269 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 86
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 98-105 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 87
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 125-129 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 88
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 115-124 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Experimental studies were made of fog formation in free jets containing glycerine and dibutyl phthalate. Visual and photographic observations showed that condensation took place near the nozzle in the mixing zone between the jet and the ambient air. Fog formation began at a well-defined location downstream from the nozzle depending on the initial velocity, temperature, and concentration of vapor. The location could be changed by inserting solid bodies or by adding foreign nuclei to the mixing zone. Measurements were made of mean temperature and concentration profiles in the mixing zone with noncondensable gases. These compared well with the predictions of turbulent boundary-layer theory. Calculations were made of the supersaturation to be expected in the case of glycerine. Downstream of the point where condensation first occurred fog filled most of the region where the calculated supersaturation was above unity. Based on the experimental evidence a mechanism is proposed for condensation in a free jet.
    Zusätzliches Material: 21 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 89
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 132-133 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 90
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 146-283 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 91
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 146-146 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 92
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 166-173 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 93
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 149-154 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A method is presented for using an adiabatic reactor to study the kinetics of reactions of gases on solid catalysts. The method is based on measurement of the steady state axial profile of temperature or composition in a specially designed adiabatic packed bed reactor. Reaction rates are calculated from these measured profiles by graphical differentitation. The method is applicable for multireaction systems and for any type of kinetic behavior.The method was demonstrated by an experimental study of cumene cracking an silica-alumina catalyst at 420° to 480°C. The measured reaction rates are in satisfactory agreement with results obtained by other investigators who used isothermal reactors. Areas of application of the adiabatic method are suggested.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 94
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 160-165 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 95
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 174-179 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 96
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 213-219 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 97
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 220-221 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 98
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 524-529 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The purpose of this study was to develop the use of semibatch operation of a recirculation reactor in kinetic studies. Ethylene hydrogenation over a supported copper catalyst was studied experimentally. In semibatch operation one of the reactants is fed at the rate necessary to hold the total pressure in the reactor constant. In ethvlene hydrogenation the reaction rate is directly equal to the feed rate, and the kinetics can be studied at constant partial pressure of either of the reactants. Since ethane is inert, this technique permitted the study of reaction rate as a function of one variable at a time.Although ethylene hydrogenation has been studied extensively, there is not general agreement regarding the kinetics over a copper catalyst. The results are themselves of interest because they indicate the reasons for the apparently conflicting data in the literature.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 99
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 548-550 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 100
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 551-557 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: To test the importance of visco-elastic properties of non-Newtonian fluids in an oscillatory system of low frequency the dynamic characteristics of a series of non-Newtonian fluids were studied in oscillating manometers. The manometer fluid behavior was simulated on a digital computer by numerically integrating the axial component of the equation of motion. In the simulation cone and plate steady state rheological data were represented mathematically with the Sisko rheological model. Good agreement between simulation and experimental data was obtained. This agreement implies that steady state rheological models can be utilized in the description of unsteady state non-Newtonian systems where the characteristic period of the system is many times greater than the relaxation and retardation times of the fluid. When this characteristic period approaches these times, then rheological models which incorporate viscoelastic terms explicitly probably should be used.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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