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  • 1
    Publication Date: 2021-03-16
    Description: The Nevado del Ruiz volcano is considered one of the most active volcanoes in Colombia, which can potentially threaten approximately 600,000 inhabitants. The existence of a glacier and several streams channelling in some main rivers, flowing downslope, increases the risk for the population living on the flank of the volcano in case of unrest, because of the generation of lahars and mudflows. Indeed, during the November 1985 subplinian eruption, a lahar generated by the sudden melting of the glacier killed twenty thousand people in the town of Armero. Moreover, the involvement of the local hydrothermal system has produced in the past phreatic and phreatomagmatic activity, as occurred in 1989. Therefore, the physico-chemical conditions of the hydrothermal system as well as its contribution to the shallow thermal groundwater and freshwater in terms of enthalpy and chemicals require a close monitoring. The phase of unrest occurred since 2010 and culminated with an eruption in 2012, after several years of relative stability, stillmaintains amoderate alert, as required by the high seismicity and SO2 degassing. In October 2013, a sampling campaign has been performed on thermal springs and stream water, located at 2600–5000 m of elevation on the slope of Nevado del Ruiz, analyzed for water chemistry and stable isotopes. Some of these waters are typically steam-heated (low pH and high sulfate content) by the vapour probably separating from a zoned hydrothermal system. By applying a model of steam-heating, based on mass and enthalpy balances, we have estimated themass rate of hydrothermal steam discharging in the different springs. The composition of the hottest thermal spring (Botero Londono) is probably representative of a marginal part of the hydrothermal system, having a temperature of 250 °C and low salinity (Cl ~1500 mg/l), which suggest, along with the retrieved isotope composition, a chiefly meteoric origin. The vapour discharged at the steam vent “Nereidas” (3600 m asl) is hypothesized to be separated from a high temperature hydrothermal system. Based on its composition and on literature data on fluid inclusions, we have retrieved the P-T-X conditions of the deep hydrothermal system, aswell as its pH and fO2. The vapour feeding Nereidas would separate from a biphasic hydrothermal system characterized by the following parameters: t= 315 °C, P= 15 MPa, NaCl = 10 wt%, CO2=5 wt%, and similar proportion between liquid and vapour. Considering also the equilibria involving S-bearing gases and HCl, pH would approach the value of 1.5 while fO2 would correspond to the FeO-Fe2O3 buffer. Chlorine content is estimated at 10,300mg/l. Changes in the magmatic input into the hydrothermal system couldmodify its degree of vapourization and/or P-T-X conditions, thus inducing corresponding variations in vapour discharges and thermal waters. These findings, paralleled by contemporary measurements of water flow rates, could give significant clues on risk evaluation.
    Description: Published
    Description: 40-53
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: Nevado del Ruiz ; Water isotopes ; Geothermal system ; Equilibrium modelling ; Water chemistry ; 04.08. Volcanology ; 03.02. Hydrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-12-13
    Description: This study focuses on the interaction among deep volcanic/hydrothermal gases, groundwater and soil gases at Vulcano Island (Aeolian Archipelago, Italy). The chemical-physical parameters of the groundwater, the total dissolved inorganic carbon (TDIC) and the isotopic composition of the CO2 dissolved in groundwater are reported and discussed. Furthermore, a comparison between soil gases and groundwater indicates that groundwater and soil gases show the same qualitative information, giving a good overall picture of the main degassing zones of a volcanic system, whereas the soil gas discharge provides an evaluation of the mass released by the deep feeding system. This approach can be a useful tool both to characterize mixing and/or interaction processes among different sources and for a monitoring of degassing activity of a volcanic system.
    Description: Published
    Description: 116-119
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 4V. Dinamica dei processi pre-eruttivi
    Description: N/A or not JCR
    Keywords: Soil CO2 flux ; Dissolved gases ; Isotope composition of CO2 ; Groundwaters ; Vulcano Island ; 03.02. Hydrology ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2022-06-08
    Description: Graciosa Island is located in the Azores Archipelago, along the so-called Terceira Rift, NE boundary of the Azores Plateau. From the hydrochemical point of view, two types of Na-Cl groundwater systems were identified: a cold aquifer system emerging at springs and exploited through boreholes for public water supply with different degrees of mineralization, and a hydrothermal system with issuing temperatures around 45 ºC. Geothermometers applied to the thermal waters point to deep temperature around 167 ºC and to immature waters, not reaching complete equilibrium with the reservoir rock. The isotopic composition and geochemistry of the thermal waters indicate mixture groundwater - seawater in different percentages and ion-exchange mechanisms that will be able to: i) increase groundwater salinity, ii) strongly change the isotopic composition to more enriched values, with different degrees of mixing.
    Description: Published
    Description: 630-633
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: N/A or not JCR
    Keywords: Thermal waters ; Volcanic island ; seawater-groundwater mixture ; Azores (Portugal) ; 03.02. Hydrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2023-02-28
    Description: The carbon isotopic composition of dissolved C-bearing species is a powerful tool to discriminate the origin of carbon in thermal waters from volcanic and hydrothermal systems. However, the δ13C values of dissolved CO2 and TDIC (Total Dissolved Inorganic Carbon) are often different with respect to the isotopic signature that characterizes the potential carbon primary sources, i.e. deep hydrothermal reservoirs, magmatic gases and organic activity. The most commonly invoked explanation for such isotopic values is related to mixing processes between deep and shallow end-members. Nevertheless, experimental and empirical investigations demonstrated that isotopic fractionation due to secondary processes acting on the uprising fluids from the hydrothermal reservoirs is able to reproduce the measured isotopic values. In this paper,we investigated the chemistry of thermalwaters, collected at Campi Flegrei and Vulcano Island (southern Italy),whose origin is related to interaction processesamongmagmatic gases, meteoric water, seawater and hosting rocks. A special focus was dedicated to the δ13C values of dissolved CO2 (δ13CCO2(aq)) and total dissolved inorganic carbon (δ13CTDIC). The δ13CCO2(aq) and δ13CTDIC values in the water samples fromboth these systems ranged from(i) those measured in fumarolic gases, likely directly related to the deep hydrothermal-magmatic reservoir, and (ii) those typically characterizing biogenic CO2, i.e. produced by microbially-driven degradation of organic matter. A simple mixingmodel of the two end-members, apparently explaining these intermediate carbon isotopic values, contrastswith the chemical composition of the dissolved gases. On the contrary, isotopic fractionation due to secondary processes, such as calcite precipitation, affecting hydrothermal fluids during their underground circulation, seems to exhaustively justify both the chemical and isotopic data. If not recognized, these processes, which frequently occur in volcanic and hydrothermal systems, may lead to an erroneous interpretation of the carbon source, causing an underestimation of the contribution of the hydrothermal/magmatic fluids to the dissolved carbon species. These results pose extreme caution in the interpretation of intermediate δ13CCO2(aq) and δ13CTDIC values for the assessment of the carbon budget of hydrothermal- volcanic systems.
    Description: Published
    Description: 46–57
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 4V. Dinamica dei processi pre-eruttivi
    Description: JCR Journal
    Keywords: Thermal waters ; Carbon isotopes ; Dissolved CO2 ; TDIC ; Volcanic-hydrothermal systems ; Secondary fractionation processes ; 04.08. Volcanology ; 03.02. Hydrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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