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  • Articles  (625)
  • Polymers
  • energy economics
  • environmental policy
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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2017. This is the author's version of the work. It is posted here under a nonexclusive, irrevocable, paid-up, worldwide license granted to WHOI. It is made available for personal use, not for redistribution. The definitive version was published in Journal of the American Oil Chemists' Society 94 (2017): 831-840, doi: 10.1007/s11746-017-2997-8.
    Description: Polyunsaturated long-chain alkenones are a unique class of lipids biosynthesized in significant quantities (up to 20% of cell carbon) by several algae including the industrially grown marine microalgae Isochrysis. Alkenone structures are characterized by a long linear carbon-chain (35-40 carbons) with one to four trans-double bonds and terminating in a methyl or ethyl ketone. Alkenones were extracted and isolated from commercially obtained Isochrysis biomass and then subjected to cross-metathesis (CM) with methyl acrylate or acrylic acid using the Hoveyda-Grubbs metathesis initiator. Within 1 h at room temperature alkenones were consumed, however complete fragmentation (i.e. conversion to the smallest subunits by double bond cleavage) required up to 16 h. Analysis of the reaction mixture by gas chromatography and comprehensive two-dimensional gas chromatography revealed a predictable product mixture consisting primarily of long-chain (mostly C17) acids (or methyl esters from CM with methyl acrylate) and diacids (or diesters), along with smaller amounts (~5%) of the honey bee “queen substance” (E)-9-oxo-decenoic acid. Together, these compounds comprise a diverse mixture of valuable chemicals that includes surfactants, monomers, and an agriculturally relevant bee pheromone.
    Description: This work was supported by the National Science Foundation (CHE- 1151492) and through a private donation from friends of WHOI.
    Keywords: Algae ; Isochrysis ; Alkenones ; Metathesis ; Surfactants ; Polymers ; Pheromones
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
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  • 2
    Publication Date: 2021-05-19
    Description: In the present study seven synthetic polymers were used as adsorbents for the removal of Cd(II) from aqueous solution. The equilibrium studies were systematically carried out in a batch process, covering various process parameters that include agitation time, adsorbent dosage, and pH of the aqueous solution. The analyzing system was an atomic absorption spectrometer (Perkin-Analyst 100). It was observed in adsorption and desorption tests that synthetic polymers showed significant pH dependence, which affected the removal efficiency, robustly. Adsorption behavior was found to follow Freundlich and Longmuir isotherms. A regeneration study was also carried out.
    Description: Published
    Keywords: Application ; Synthetic ; Adsorption ; Synthetic polymers ; Wastewater treatment ; Polymers ; Cadmium ; Heavy metals
    Repository Name: AquaDocs
    Type: Journal Contribution , Refereed
    Format: pp.1-8
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  • 3
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    In:  michael.haarich@vti.bund.de | http://aquaticcommons.org/id/eprint/3781 | 1240 | 2012-11-10 12:53:50 | 3781 | Bundesforschungsanstalt für Fischerei
    Publication Date: 2021-06-25
    Description: Das am 16. November 1994 in Kraft getretene Seerechtsübereinkommen der Vereinten Nationen(United Nations Convention on the Law of the Sea) regeltvölkerrechtlich alle Nutzungsarten der Meere. Die dort erlassenen Vorschriften beschränken sich auf allgemeine Rechtsgrundsätze, seerechtliche Kompetenzregelungen und Staatenverpflichtungen zum Erlaß internationaler und nationaler Regelungen. Das Vertragswerk bezieht den marinen Umweltschutz, einen Kernbereich globaler Umweltpolitik, ausdrücklich mit ein. Wesentlich konkreter in der Umsetzung umweltpolitischer Ziele sind die internationalen Übereinkommen zum Schutz der Meeresumwelt. Für den in Abbildung 1 gezeigten Teil des Nordostatlantiks einschließlich der Nordsee existieren derartige Übereinkommen bereits seit 1972 durch das OSLO und PARIS Übereinkommen und für die gesamte Ostsee seit 1974 durch das HELSINKI Übereinkommen. Im Lichte des heutigen Umweltverständnisses und unter Berücksichtigung des weiterentwickelten Seerechts wurden beide Übereinkommen 1992 neu gefaßt. Die politischen Veränderungen haben insbesondere im Ostseeraum auch zu geographischen Erweiterungen geführt. Die mit der Novellierung der jeweiligen Übereinkommen verbundene Neuorganisation ist weiterhin selbstverständlich von den Erfahrungen aus der zwanzigjährigen Überwachungstätigkeit und dem in dieser Zeit durch die Meeresforschung gewachsenen Wissen geprägt.
    Description: Johann Heinrich von Thünen-Institute, Federal Research Institute for Rural Areas, Forestry and Fisheries began publishing the Informationen aus der Fischereiforschung = Information on Fishery research in 2010.
    Keywords: Environment ; Policies ; regulations ; OSPAR ; North Sea ; Atlantic ; marine environment ; ecosystem effects ; environmental policy ; Baltic Sea ; conservation
    Repository Name: AquaDocs
    Type: article , FALSE
    Format: application/pdf
    Format: application/pdf
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  • 4
    Publication Date: 2022-02-18
    Description: The Ligurian Sea is a deep basin in the northernmost sector of the western Mediterranean which shows peculiar hydrodynamic and meteo-oceanographic features. The coasts of the Ligurian Sea are among the most urbanised and industrialised along the Italian coastline: the main causes of disturbance being littoral urban development and harbour activities, the building of littoral rail- and highways, and the presence of several polluted discharges. This review, by evaluating the huge scientific output published in the last three decades, describes and discusses the most important geological, hydrological and biological characteristics of the Ligurian Sea.We show that this regional sea has largely been investigated in terms of its geological and structural evolution, as well as in terms of the sedimentation dynamics of the littoral and deep bottoms, with particular attention to the sedimentation balance of the beaches and their erosive processes.We report that the prevalent hydrodynamic and meteo-oceanographic conditions favour a continuous exchange of coastal water masses, and that the seasonal and interannual dynamics of water masses can effects the local climate, with direct and indirect consequences on fish and benthic communities documented in the last decade. We stress that although recent studies offer good knowledge of the distribution of coastal benthic communities, only scant information is available for the whole continental shelf, the submarine canyons and the rocky bathyal bottoms. Our meta-analysis reveals that significant fishing activities are monitored, but also that certain sectors of the biological resource are suffering, and suggests the set up of appropriate management measures. The Ligurian Sea hosts a number of Marine Protected Areas (MPAs) of high relevance, while the institution of the Whale Sanctuary completes the protection policy of the Regione Liguria. Our meta-analysis points out the need for long-term studies, based primarily on the analysis of those areas of the Ligurian Sea that have been little investigated to date. Finally, only properly addressed studies, using experimental approaches and along appropriate spatial and temporal scales, might allow us to understand the functioning of the Ligurian marine ecosystems, evaluate their health conditions and the dynamics of the main variables that affect the distribution of the single species (including species of high economic value) and benthic communities.
    Description: Published
    Description: 319-340
    Description: 3.7. Dinamica del clima e dell'oceano
    Description: JCR Journal
    Description: restricted
    Keywords: Mediterranean Sea ; Ligurian Sea ; geomorphology ; hydrology ; plankton ; benthos ; necton ; fisheries ; biodiversity ; introduced species ; Marine Protected Areas ; environmental policy ; 03. Hydrosphere::03.01. General::03.01.07. Physical and biogeochemical interactions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
    Publication Date: 2022-10-20
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Blevins, M. G., Allen, H. L., Colson, B. C., Cook, A.-M., Greenbaum, A. Z., Hemami, S. S., Hollmann, J., Kim, E., LaRocca, A. A., Markoski, K. A., Miraglia, P., Mott, V. L., Robberson, W. M., Santos, J. A., Sprachman, M. M., Swierk, P., Tate, S., Witinski, M. F., Kratchman, L. B., & Michel, A. P. M. Field-portable microplastic sensing in aqueous environments: a perspective on emerging techniques. Sensors, 21(10), (2021): 3532, https://doi.org/10.3390/s21103532.
    Description: Microplastics (MPs) have been found in aqueous environments ranging from rural ponds and lakes to the deep ocean. Despite the ubiquity of MPs, our ability to characterize MPs in the environment is limited by the lack of technologies for rapidly and accurately identifying and quantifying MPs. Although standards exist for MP sample collection and preparation, methods of MP analysis vary considerably and produce data with a broad range of data content and quality. The need for extensive analysis-specific sample preparation in current technology approaches has hindered the emergence of a single technique which can operate on aqueous samples in the field, rather than on dried laboratory preparations. In this perspective, we consider MP measurement technologies with a focus on both their eventual field-deployability and their respective data products (e.g., MP particle count, size, and/or polymer type). We present preliminary demonstrations of several prospective MP measurement techniques, with an eye towards developing a solution or solutions that can transition from the laboratory to the field. Specifically, experimental results are presented from multiple prototype systems that measure various physical properties of MPs: pyrolysis-differential mobility spectroscopy, short-wave infrared imaging, aqueous Nile Red labeling and counting, acoustophoresis, ultrasound, impedance spectroscopy, and dielectrophoresis.
    Description: We greatly thank our funding agencies: Gerstner Philanthropies (to A.P.M.M.), the Richard Saltonstall Charitable Foundation (to A.P.M.M.), and the Wallace Research Foundation (to A.P.M.M. and S.S.H.). Funding for M.G.B. was provided by a Draper Fellowship and to B.C.C. by an MIT Martin Fellowship. Draper thanks EPA region 9 for their partnership and support through a Cooperative Research and Development Agreement, an industry/government agreement regarding funding and personnel contributions of time and expertise.
    Keywords: Microplastics ; Plastic pollution ; Sensors ; Analytical chemistry ; Environment ; Water ; Ocean ; Marine pollution ; Polymers ; Freshwater ; Aqueous solutions
    Repository Name: Woods Hole Open Access Server
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  • 6
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    International Journal of Radiation Applications & Instrumentation. Part D, 19 (1991), S. 825-828 
    ISSN: 1359-0189
    Keywords: Biomaterials ; Friction and Wear ; Polymers ; Radiation ; Surface Modification ; Track Etching
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
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  • 7
    ISSN: 0003-2670
    Keywords: Enzymatic methods ; Polymers ; Sugars ; Zinc
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
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  • 8
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    Analytica Chimica Acta 283 (1993), S. 997-1005 
    ISSN: 0003-2670
    Keywords: Nuclear magnetic resonance spectrometry ; Polymers ; Review ; Solid state NMR
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
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  • 9
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    Amsterdam : Elsevier
    Journal of Physics and Chemistry of Solids 54 (1993), S. 1613-1620 
    ISSN: 0022-3697
    Keywords: Polymers ; composites ; electrical conductivity
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Physics
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  • 10
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    Journal of Physics and Chemistry of Solids 50 (1989), S. 735-738 
    ISSN: 0022-3697
    Keywords: Polymers ; electrical conductivity ; irradiation ; radical density
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Physics
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  • 11
    ISSN: 0924-2031
    Keywords: Calibration ; Infrared spectrometry ; Interpretation rules ; Polymers ; Preprocessing ; Sampling
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Physics
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  • 12
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    Vibrational Spectroscopy 2 (1991), S. 183-186 
    ISSN: 0924-2031
    Keywords: Force constants ; Fragment method ; Hydrogen bonding ; Infrared spectrometry ; Polymers ; Polyurethane
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Physics
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  • 13
    ISSN: 0924-2031
    Keywords: Infrared spectrometry ; Interpretation rules ; Knowledge base ; Polymers ; Spectral windows
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Physics
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  • 14
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    Vibrational Spectroscopy 6 (1994), S. 185-191 
    ISSN: 0924-2031
    Keywords: Anisotropic samples ; Dichroism ; Infrared spectrometry ; Poly(vinylidene fluoride) ; Polymers ; Surface characterization
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Physics
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  • 15
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    Vibrational Spectroscopy 3 (1992), S. 23-33 
    ISSN: 0924-2031
    Keywords: Ethylene-propylene copolymers ; Infrared spectrometry ; Polymers
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Physics
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  • 16
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    Analytica Chimica Acta 279 (1993), S. 209-212 
    ISSN: 0003-2670
    Keywords: Amperometry ; Antibodies ; Polymers ; Proteins
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
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  • 17
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    Journal of Organometallic Chemistry 483 (1994), S. 183-186 
    ISSN: 0022-328X
    Keywords: Chlorination ; Chloropoly(carbosilanes) ; Photochemistry ; Poly(carbosilanes) ; Polymers ; Silicon
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
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  • 18
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    Nuclear Tracks and Radiation Measurements (1982) 8 (1984), S. 133-137 
    ISSN: 0735-245X
    Keywords: Polymers ; chemical etching ; new material
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
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  • 19
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    Analytica Chimica Acta 298 (1994), S. 259-266 
    ISSN: 0003-2670
    Keywords: Amperometry ; Flow system ; Polymers ; Water soluble polymers
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
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  • 20
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    Analytica Chimica Acta 260 (1992), S. 13-17 
    ISSN: 0003-2670
    Keywords: Degree of neutralization ; Ion-selective electrodes ; Polymers ; Sodium ; Superabsorbent polymers
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
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  • 21
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    Analytica Chimica Acta 276 (1993), S. 235-245 
    ISSN: 0003-2670
    Keywords: Blood ; Food ; Gas chromatography ; Headspace analysis ; Petrochemicals ; Polymers
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
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  • 22
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    Analytica Chimica Acta 253 (1991), S. 183-186 
    ISSN: 0003-2670
    Keywords: Force constants ; Fragment method ; Hydrogen bonding ; Infrared spectrometry ; Polymers ; Polyurethane
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
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  • 23
    ISSN: 0003-2670
    Keywords: Chromatography ; Crown ethers ; Polymers ; Strontium, Yttrium
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
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  • 24
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    Nuclear Tracks And Radiation Measurements (1993) 22 (1993), S. 221-224 
    ISSN: 0969-8078
    Keywords: Dielectric track detectors ; Polymers
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
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  • 25
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    Nuclear Tracks And Radiation Measurements (1993) 22 (1993), S. 97-100 
    ISSN: 0969-8078
    Keywords: Polymers ; atomic hydrogen ; track detectors ; track structure
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
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  • 26
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    Nuclear Tracks And Radiation Measurements (1993) 22 (1993), S. 419-422 
    ISSN: 0969-8078
    Keywords: Calibration ; Dielectric track detectors ; Polymers ; ^2^2^2Rn
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
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  • 27
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    Microelectronic Engineering 20 (1993), S. 73-88 
    ISSN: 0167-9317
    Keywords: Electrical conductivity ; Laser ablation ; Nanofabrication ; Polymers ; Ultraviolet lasers
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Electrical Engineering, Measurement and Control Technology
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  • 28
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    Colloid & polymer science 261 (1983), S. 656-660 
    ISSN: 1435-1536
    Keywords: Polymers ; Paracrystal ; Lattice distortion ; Dislocations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract It is shown, that paracrystallinity in polymers can be explained by assuming a statistical dislocation distribution inside the crystal lattice. This conclusion is based on X-ray scattering results (line width measurements).
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  • 29
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    Annals of operations research 97 (2000), S. 203-212 
    ISSN: 1572-9338
    Keywords: conflict ; cooperation ; energy economics ; environmental control ; game theory ; resource allocation ; system dynamics ; 90-99 ; 90A16 ; 90A30 ; 90D50 ; 93C55 ; 93C95
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Economics
    Notes: Abstract The Framework Convention on Climate Change (FCCC) demands reductions in greenhouse gas emissions by the industrialized countries, while developing countries are still permitted to expand their energy consumption and greenhouse gas emissions. To identify, assess and compare options for avoiding and minimizing anthropogenic climate change, the framework of dynamic-game models (the SCX conflict model and the problem-specific TEM model) is applied to analyze the interaction between energy technologies, emission reductions and economic output with regard to energy use and the relationship between conflict and cooperation in climate policy. Basic variables are energy production, emissions into the enviroment, the energy price and the economic output. Major control parameters are the allocation of funding with regard to various energy options and the degree of international cooperation through technology transfer and capital flow. In particular, the impact of cooperation between industrialized and developing countries is evaluated to understand the role of governments in the transition to sustainable market economies. Simulations and numerical results are presented which can be used in a constructive way to implement a Joint-Implementation Program as an advanced market institution.
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  • 30
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    Annals of operations research 54 (1994), S. 79-96 
    ISSN: 1572-9338
    Keywords: Core ; Lindahl equilibrium ; environmental policy ; JEL C72 ; H41 ; Q38
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Economics
    Notes: Abstract This paper investigates properties of an environmental policy based on the concept of a Lindahl equilibrium. Such a policy results in a system of “effluent” charges, if the economy is composed of homogeneous jurisdictions, each inhabited by a continuum of households. The supply of the environmental commodities in the jurisdictions generates spillovers, and consumption of the environmental commodities is subject to congestion. In such an economy, the set of equal treatment Lindahl equilibria coincides with the core, if congestion effects exhibit “constant returns to group size” locally in each jurisdiction. This is insofar important, since the federal government typically has the possibility to modify spillover effects and congestion effects by appropriate environmental regulations. Thus, there are policy implications which go beyond the recommendation of environmental policy instruments, and which also affect the design of an economically sound system of effluent charges.
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  • 31
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    Annals of operations research 54 (1994), S. 237-262 
    ISSN: 1572-9338
    Keywords: Optimal control ; differential games ; environmental policy ; JEL C61 ; C73 ; Q28
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Economics
    Notes: Abstract This paper provides some differential game models of natural resource exploitation when environmental pollution takes place. The “classical” approach to determine optimal harvest rates of renewable resources utilizes Optimal Control models, i.e. there is either a monopolistic market structure or there is pure competition. In case of pollution, however, all agents can be put together, forming the groups of the resource harvesters on one side and of polluters on the other side. So differential games can be used to analyze environmental problems. The models introduced in this paper are put together in order to showdifferent problems that can all be analyzed using differential games.
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  • 32
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    Annals of operations research 54 (1994), S. 57-78 
    ISSN: 1572-9338
    Keywords: Principal-agent ; multi-agents ; linear incentive schemes ; firm organization ; environmental policy ; JEL D82 ; L22 ; Q28
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Economics
    Notes: Abstract Two types of linear-quadratic principal-agent models will be considered: one in which a single agent has to perform several tasks and one in which several agents have to perform a certain task. For both models, we derive optimal contractual principal-agent relations. It turns out that under certain conditions (concerning risk-aversion and the correlation of the agents' outcome) the multiple-agent problem reduces to a multiple-task one-agent problem. Our results will be discussed within the framework of (multiple-) point pollution to which, in addition, also the results of the standard principal-agent model will be applied.
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  • 33
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    Annals of operations research 54 (1994), S. 119-127 
    ISSN: 1572-9338
    Keywords: Input-output ; multiple criteria decision making ; environmental policy ; JEL C44 ; C67 ; Q28
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Economics
    Notes: Abstract It is often claimed that there is a trade-off between economic goals and the quality of the environment. For this reason, an environmental input-output optimization model with multiple objectives is formulated. The criteria are the minimization of factor costs to produce the Gross National Product and the minimization of net pollution for a given level of final demand. Using the LeChatelier-Samuelson principle, we analyze the changes in the production of the sectors and in the prices of the goods (described by the dual model) due to the change in the preferences of the decision makers. It can be shown that higher weights for the environmental objectives imply — in tendency —non-decreasing production of the sectors andnon-decreasing abatement activities. The changes of prices are ambiguous. The condition for increasing prices is given. To some degree, the opposite results can be achieved, if maximization of the value of final demand (or of private consumption) and minimization of net pollution under the constraints for primary input are taken as objective functions. In this case, increasing weights for environmental goals will leadin tendency tonon-increasing final demand and tonon-increasing net pollution. Under given conditions, higher environmental quality will be achieved bynon-increasing gross production and abatement activities.
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  • 34
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    Annals of operations research 95 (2000), S. 285-312 
    ISSN: 1572-9338
    Keywords: environmental policy ; pollution permits ; oligopolistic markets ; noncompliance ; variational inequalities ; projected dynamical systems
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Economics
    Notes: Abstract In this paper, we consider the modeling, analysis, and computation of solutions to both static and dynamic models of multiproduct, multipollutant noncompliant oligopolistic firms who engage in a market for pollution permits. In the case of the static model, we utilize variational inequality theory for the formulation of the governing equilibrium conditions as well as the qualitative analysis of the equilibrium pattern, including sensitivity analysis. We then propose a dynamic model, using the theory of projected dynamical systems, whose set of stationary points coincides with the set of solutions to the variational inequality problem. We propose an algorithm, which is a discretization in time of the dynamic adjustment process, and provide convergence results using the stability analysis results that are also provided herein. Finally, we apply the algorithm to several numerical examples to compute the profit-maximized quantities of the oligopolistic firms' products and the quantities of emissions, along with the equilibrium allocation of licenses and their prices, as well as the possible noncompliant overflows and underflows. This is the first time that these methodologies have been utilized in conjunction to study a problem drawn from environmental policy modeling and analysis.
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  • 35
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    Monatshefte für Chemie 112 (1981), S. 1279-1296 
    ISSN: 1434-4475
    Keywords: Catalytic hydrogenation ; Coordination polymerization ; Glass transition temperature ; 1,4-Poly(2,3-dimethylbutadiene), cis- and trans- ; Polymers
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Kopf-zu-Kopf-Polypropylen wurde mittels katalytischer Hydrierung voncis-1,4-Poly(2,3-dimethylbutadien) bzw.trans-1,4-Poly(2,3-dimethylbutadien) mit Kobalt-2-ethylhexanoat/Triethyl-aluminium als Katalysator dargestellt. Die Hydrierung verlief überwiegend übercis-Addition, war aber nicht stereospezifisch. Die Polymerproben wurden mittels IR und NMR, insbesondere13C, charakterisiert. Die erhaltenen Polymeren waren amorph und zeigten Glasübergangstemperaturen, die um etwa 20°C niedriger waren als bei Kopf-zu-Schwanz-Polypropylen. Die thermische Stabilität von Kopf-zu-Kopf-Polypropylen ist nicht signifikant verschieden von ataktischem oder isotaktischem Kopf-zu-Schwanz-Polypropylen.
    Notes: Abstract Head to head polypropylene was prepared by catalytic hydrogenation of eithercis-1,4-poly(2,3-dimethylbutadiene) ortrans-1,4-poly(2,3-dimethylbutadiene) with cobalt 2-ethylhexanoate/triethylaluminium as the hydrogenation catalyst in decahydronaphthalene solution. The hydrogenation occurred predominantly bycis hydrogen addition, but was not stereospecific. The samples of head to head polypropylene were characterized by IR and NMR, particularly by13C-NMR spectroscopy. The polymers were amorphous and exhibited glass transition temperatures about 20°C lower than that of head to tail poly-propylene; the glass transition temperatures were measured by DSC and varied somewhat from sample to sample (sufficiently high molecular weight) according to their stereochemistry. TheT gvalues were confirmed by Rheovibron measurements. The thermal stability of head to head polypropylene is not significantly different from that of either atactic or isotactic head to tail polypropylene.
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    Monatshefte für Chemie 119 (1988), S. 1125-1141 
    ISSN: 1434-4475
    Keywords: Significant electron structures ; Condensed hydrocarbons ; Polymers ; Stabilization energy
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Superposition of significant electron structures is used to estimate the mesomerism stabilization of polycyclic benzenoid systems by consideration of the number ofKekulé structures and of benzenoid interactions between them. General formulae and stability rules are given for many classes of cata and pericondensed molecules. The decoupling of large benzenoid systems into isolated subsystems is described. Three distinct types of polymeric benzenoid systems exist: unstable systems with vanishing mesomerism energy per monomeric umit, and stable systems with nonvanishing mesomerism energy, which are or are not decoupled into isolated subsystems.
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    Applied physics 7 (1975), S. 171-174 
    ISSN: 1432-0630
    Keywords: Positron annihilation ; Polymers
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The decay time τl ofo-Ps by the electron pickoff process has been measured in polystyrene as a function of molecular weight. For samples below their glass transition temperature τl is essentially independent of $$\bar M_n $$ . In the low molecular weight region, $$\bar M_n〈 850$$ , τl increased with decreasing $$\bar M_n $$ in line with earlier theoretical predictions. The overall behaviour reflects closely the dependence of free volume on $$\bar M_n $$ . The effects of molecular motion on τl are examined and it is concluded that the decay time is insensitive to such motions in polystyrene below the melting point, in contrast to what is observed in polytetrafluoroethylene.
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    Journal of molecular evolution 35 (1992), S. 190-195 
    ISSN: 1432-1432
    Keywords: Origin of life ; Adenine ; Catalysts ; Nucleic acids ; Polymers ; Poly(allylamine) ; p-Nitrophenylacetate
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    Topics: Biology
    Notes: Summary An important issue in the problem of the origins of life is whether or not nucleic acids may exert catalytic activities. In order to study the possible role of the adenine ring in catalysis, we have synthesized polymers containing aliphatic amino groups and the nucleic base adenine linked to macromolecules by its 6-amino group. These polymers exhibit pronounced catalytic activities in the hydrolysis of p-nitrophenylacetate. In mild basic conditions, the strong increase in the activities observed can be related to a cooperative effect between the amino groups and the adenine rings of the polymers. These properties and our previous results on the catalytic activity of N6-ribosyl-adenine are consistent with a possible role for the adenine ring in prebiotic catalysis.
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    International Journal of Biological Macromolecules 6 (1984), S. 45-50 
    ISSN: 0141-8130
    Keywords: Polymers ; circular dichroism spectrum ; conformation ; perchlorate ; poly(N-δ-trimethyl-l-ornithine) ; salt effects ; surfactants ; α-helix ; β-structure
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    Topics: Biology , Chemistry and Pharmacology
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    International Journal of Biological Macromolecules 7 (1985), S. 182-186 
    ISSN: 0141-8130
    Keywords: Polymers ; X-ray diffraction ; cellulose regeneration ; conformation ; phosphoric acid ; polymorph
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    ISSN: 0141-8130
    Keywords: Polymers ; peptide synthesis ; phenolic polymer ; solid (gel) phase ; ultra-high load
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    International Journal of Biological Macromolecules 15 (1993), S. 189-192 
    ISSN: 0141-8130
    Keywords: Polymers ; Trichoderma reesei ; adhesion
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    International Journal of Biological Macromolecules 5 (1983), S. 329-341 
    ISSN: 0141-8130
    Keywords: Polymers ; X-ray diffraction ; alginate ; calcium coordination ; computer modelling ; conformation ; nuclear magnetic resonance ; polyguluronate
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    Thin Solid Films 253 (1994), S. 430-434 
    ISSN: 0040-6090
    Keywords: Polymers ; Radiation damage ; X-ray photoelectron spectroscopy
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    Thin Solid Films 251 (1994), S. 110-115 
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    Keywords: Elastic properties ; Polymers
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    Thin Solid Films 252 (1994), S. 131-134 
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    Keywords: Adhesion ; Polymers ; Stress
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    Thin Solid Films 252 (1994), S. 145-151 
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    Keywords: Insulators ; Interfaces ; Polymers ; Sensors
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    Thin Solid Films 251 (1994), S. 36-39 
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    Keywords: Fourier transform infrared spectroscopy ; Physical vapour deposition ; Polymers
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    Thin Solid Films 253 (1994), S. 228-232 
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    Keywords: Optical spectroscopy ; Polymers
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    ISSN: 0040-6090
    Keywords: Cadmium sulphide ; Deposition process ; Polymers
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    Thin Solid Films 252 (1994), S. 54-60 
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    Keywords: Gold ; Nickel oxide ; Polymers ; Surface energy
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    Journal of Analytical and Applied Pyrolysis 30 (1994), S. 73-90 
    ISSN: 0165-2370
    Keywords: CO"2 laser ; Chemical vapour deposition ; Polymers ; Pyrolysis ; Thermal
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    ISSN: 0165-2370
    Keywords: Polymers ; polypropylene ; polystyrene ; polytetrafluoroethylene ; pyrolysis ; thermal decomposition.
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    Journal of Analytical and Applied Pyrolysis 15 (1989), S. 249-259 
    ISSN: 0165-2370
    Keywords: Polymers ; polystyrene ; pyrolysis ; reaction mechanism.
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    Monatshefte für Chemie 125 (1994), S. 25-34 
    ISSN: 1434-4475
    Keywords: Polymers ; Energy transfer
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    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Die Triplet-Triplet-Auslöschung von nach Masse fraktioniertenPVCA (M=3.6·103−1.4·106)-Toluol-Gläsern wurde mittels Phosphoreszenzmessungen untersucht, für Gläser vonPVCA undP2VN (M im Bereich 106) inMTHF wurde die Intensität der Phosphoreszenz und der verzögerten Fluoreszenz als Funktion der Anregungs-intensität untersucht. Es wird ein Überblick über T-T-Auslöschung in festen Lösungen aromatischer Polymerer gegeben und die Voraussetzungen für eine Theorie des Energietransportes und der Exciton-Exciton-Auslöschung diskutiert.
    Notes: Summary The triplet-triplet annihilation of mass fractionatedPVCA (M=3.6·103−1.4·106) in toluene glasses was studied by phosphorescence, for glasses ofPVCA andP2VN (order of M=106) inMTHF the intensity of phosphorescence and delayed fluorescence were studied as a function of the excitation intensity. A survey of T-T annihilation in solid solutions of aromatic polymers is given and requirements for a theory explaining low dimensional energy transport and exciton-exciton annihilation are pointed out.
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    Journal of risk and uncertainty 8 (1994), S. 111-122 
    ISSN: 1573-0476
    Keywords: health-health analysis ; regulatory review ; environmental policy ; I18 ; L51 ; Q28
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    Topics: Economics
    Notes: Abstract Health-health analysis (HHA) posits a seemingly unassailable criterion for regulatory assessment: policies intended to protect human health ought to exhibit positive health benefits. Despite the apparent logic of this criterion, it is important to ask whether it would aid in the quest for better public policies. In the context of environmental issues, we find that HHA can be useful by reminding us that it is thenet health impact of a proposed regulation that can be important. However, we also find that in most applications the health impacts of regulatory compliance costs are unlikely to be significant. Conventional benefit-cost analysis ought to remain the principal tool of economic assessment of environmental laws and regulations.
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    Journal of statistical physics 8 (1973), S. 367-371 
    ISSN: 1572-9613
    Keywords: Polymers ; Brownian motion ; velocity autocorrelation ; short-range interactions ; quasielastic broadening for incoherent neutron scattering
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    Topics: Physics
    Notes: Abstract The thermal motion of a long-chain molecule dispersed in a solvent is examined in terms of the velocity autocorrelation, in a reference frame attached to a subunit of the chain.
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    Journal of statistical physics 53 (1988), S. 1073-1080 
    ISSN: 1572-9613
    Keywords: Polymers ; path integrals ; constraints
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    Topics: Physics
    Notes: Abstract The statistical mechanical properties of plane polymer loops enclosing a constant area are investigated, using a continuous model from the start. For this purpose an analytic expression for the generating functional is obtained, which in turn is used to derive (1) the distribution function for the enclosed area, (2) the average squared distance of a given repeating unit from the origin, and (3) the entropic force on a repeating unit.
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    European biophysics journal 26 (1997), S. 471-476 
    ISSN: 1432-1017
    Keywords: Key words Ion channel ; Transport ; Polymers ; Hydration ; Water structure ; Alpha hemolysin ; Poly(ethylene glycol)
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    Topics: Biology , Physics
    Notes: Abstract Electrostatic potentials created by fixed or induced charges regulate many cellular phenomena including the rate of ion transport through proteinaceous ion channels. Nanometer-scale pores of these channels also play a critical role in the transport of charged and neutral macromolecules. We demonstrate here that, surprisingly, changing the charge state of a channel markedly alters the ability of nonelectrolyte polymers to enter the channel's pore. Specifically, we show that the partitioning of differently-sized linear nonelectrolyte polymers of ethylene glycol into the Staphylococcus aureus α-hemolysin channel is altered by the solution pH. Protonating some of the channel side chains decreases the characteristic polymer size (molecular weight) that can enter the pore by ∼25% but increases the ionic current by ∼15%. Thus, the “steric” and “electric” size of the channel change in opposite directions. The results suggest that effects due to polymer and channel hydration are crucial for polymer transport through such pores.
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    Theoretical chemistry accounts 77 (1990), S. 253-261 
    ISSN: 1432-2234
    Keywords: Polymers ; Bulk properties of ; Finite cluster MO calculations ; Hydrogen fluoride
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    Topics: Chemistry and Pharmacology
    Notes: Summary Geometries of linear hydrogen fluoride clusters with 1–10 unit cells are optimized at the HF/6-31G** level. MP2/6-31G** energies at the HF/6-31G** optimized geometries are calculated for clusters with 1–6 unit cells. Application of Padé approximants to the electronic properties of finite clusters results in the following estimated bulk properties: dipole moment per unit cell: 2.66±0.01 [D], bond lengths: 0.913±0.001/1.686±0.001 [Å], stabilization energy per unit cell relative to the HF molecule: −7.44±0.01 [kcal/mol] (HF), −8.66±0.02 [kcal/mol] (MP2). The extrapolated atomic charges based on the generalized atomic polar tensors (GAPT) are 0.61±0.01 as compared to the value of 0.42 for the monomer.
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    ISSN: 1432-2234
    Keywords: Polymers ; Oligomers ; Benzenoids ; Resonance ; Conjugation
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    Topics: Chemistry and Pharmacology
    Notes: Summary We have initiated a comparative study of several families of structurally closely related large benzenoid hydrocarbons of increasing number of fused benzene rings. Local and global properties of such molecules have been studied with a particular interest in investigating the closeness of finite-size molecules for modelling infinite polymeric structures having the same structural patterns. We focus in this report on two questions: (1) how large is a finite molecule which well approximates an infinite system? and (2) how do terminal groups influence local properties in the central part of the molecule as we approach the infinite system. Emphasis in this report is on extraction of high-accuracy limiting values for selected molecular properties from limited data on a few smaller members of structurally related molecules.
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    Theoretical chemistry accounts 93 (1996), S. 191-197 
    ISSN: 1432-2234
    Keywords: Spectral moments ; Molecular graph ; Graph theory ; Polymers
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    Topics: Chemistry and Pharmacology
    Notes: Summary It is shown that for anyk, thekth spectral moment of a polymer graph composed ofn monomer units is an exact linear function of the parametern. This linear relation holds for all values ofn, greater than a critical value ξ0=ξ0(k).
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    Theoretical chemistry accounts 98 (1998), S. 155-164 
    ISSN: 1432-2234
    Keywords: Key words: Restricted Hartree-Fock ; Fourier space ; Floating spherical Gaussian orbital ; Polymers ; Band structure
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    Topics: Chemistry and Pharmacology
    Notes: Abstract. The performance of floating spherical Gaussian orbital basis sets in the description of specific but subtle cooperative interactions such as those occurring between hydrogen atoms (hyperconjugation) or between lone pairs is discussed. The calculations on infinite chains are performed using a Fourier representation of the restricted Hartree-Fock equations. The principle advantage of the method is to ensure that the lattice summations appearing in the Coulomb and exchange terms are carried out accurately and efficiently.
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    Theoretical chemistry accounts 75 (1989), S. 261-270 
    ISSN: 1432-2234
    Keywords: Polymers ; XPS ; ESCA ; Ab initio ; Oxygen
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    Topics: Chemistry and Pharmacology
    Notes: Abstract This letter reports the results of ab initio quantum chemical calculations on the C1s core levels of model systems for a number of oxygen containing polymers. Conformational effects were studied. SCF calculations have been carried out with STO-3G and 4-31G basis sets, and Koopmans' theorem was applied to obtain the core-level binding energies. To evaluate the performance of the procedure ΔSCF calculations were carried out on polyacrylic acid. The existence of oxygen-induced secondary substituent effects in the XPS-(ESCA-)spectra is discussed. A comparison with semi-empirical CNDO/2 results from Clark and Thomas has been made.
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    ISSN: 1432-2234
    Keywords: Key words: Restricted Hartree ; Fock ; Fourier space ; Gaussian-type functions ; Polymers ; Band structure
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    Topics: Chemistry and Pharmacology
    Notes: Abstract.  Formulas are presented for restricted Hartree–Fock (RHF) calculations on systems with periodicity in one dimension using a basis set of contracted spherical Gaussians. Applying Fourier-space and Ewald-type methods, all lattice sums appearing in the formulation have been brought to forms exhibiting accelerated convergence. Calculations have been carried out for infinite chains of Li2 molecules and a poly(oxymethylene) chain. The methods used here yield results that are far more precise than corresponding direct-space calculations and for the first time show the vanishing of the RHF density of states at the Fermi level for situations of partial band occupancy. Our initial computational implementation was about 5 times slower than the fastest direct-space RHF code, but improvements in special-function evaluations and numerical integrations over the Brillouin zone are shown to remove this disparity in computing speed.
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    Journal of industrial microbiology and biotechnology 13 (1994), S. 172-176 
    ISSN: 1476-5535
    Keywords: Immobilization ; Hydrophobic ; Hydrophilic ; Polymers ; Yeast
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    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Summary Biotransformation of benzaldehyde to benzyl alcohol bySaccharomyces cerevisiae immobilized in different support matrices was investigated. Polymers with intrinsic hydrophobic and/or hydrophilic nature as well as mixed hydrophobic and hydrophilic supports were examined both in aqueous and bisphasic aqueous-organic systems. The hydrophobic support material ENTP-2000 or mixed silicone:alginate (50-25∶50-75) proved to be most suitable not only for nonconventional media but also for conventional aqueous media for production of benzyl alcohol. With ENTP-2000, catalytic activity and maximum yield were 159 μmol h−1 g−1 dry weight catalyst and 0.89 mM, respectively, in hexane containing 2% moisture. Corresponding values in aqueous media were 246 μmol h−1 g−1 dry weight catalyst and 1.53 mM. With 50∶50 silicone:alginate, catalytic activity and maximum yield were 177 μmol h−1 g−1 dry weight catalyst and 1.18 mM, respectively, in hexane containing 2% moisture. Corresponding values in aqueous media were 192 μmol h−1 g−1 dry weight catalyst and 0.8 mM.
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    Journal of computer-aided materials design 3 (1996), S. 273-280 
    ISSN: 1573-4900
    Keywords: Thermal conductivity ; Polymers ; Orientation ; Phonon focussing ; Boundary resistance
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Summary Using the simple kinetic formula of thermal conductivity, it is shown that the mean free path is the limiting factor of thermal conductivity. Standard arguments on phonon-phonon interaction lead to realize that isotropic polymers cannot exceed thermal conductivities k ∼ 1 W/mK. Orientation of polymers gives a strong enhancement of k in orientation direction, due to the effect of phonon focussing. For the simplest chain, the polyethylene molecule, up to 37 W/mK have been measured. Possible values of 70 W/mK can be extrapolated for material with the modulus of the chain. Even higher values can be envisaged for perfect crystalline material. The integration of such a material must take care of minimizing the boundary resistance to the adjacent solid.
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    Journal of computer-aided materials design 3 (1996), S. 369-378 
    ISSN: 1573-4900
    Keywords: Miscibility ; Blends ; Diffusion ; Liquid crystals ; Dynamics ; Statistical mechanics ; Atomistic ; Polymers ; Modeling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Summary A number of molecular modeling techniques have been applied for the prediction of polymer properties and behavior. Five examples illustrate the range of methodologies used. A simple atomistic simulation of small polymer fragments is used to estimate drug compatibility with a polymer matrix. The analysis of molecular dynamics results from a more complex model of a swollen hydrogel system is used to study gas diffusion in contact lenses. Statistical mechanics are used to predict conformation dependent properties — an example is the prediction of liquid-crystal formation. The effect of the molecular weight distribution on phase separation in polyalkanes is predicted using thermodynamic models. In some cases, the properties of interest cannot be directly predicted using simulation methods or polymer theory. Correlation methods may be used to bridge the gap between molecular structure and macroscopic properties. The final example shows how connectivity-indices-based quantitative structure-property relationships were used to predict properties for candidate polyimids in an electronics application.
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    Environmental and resource economics 13 (1999), S. 415-433 
    ISSN: 1573-1502
    Keywords: environmental policy ; political competition ; pollution taxes ; rent seeking
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    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract This paper investigates the impact of political lobbying on the choice of environmental policy instruments. It is argued that the prevalence of pollution emission standards over more efficient policy instruments may result from rent seeking behaviour. The model further predicts that when an emission standard is used to control pollution, rival political parties have an incentive to set the same standard. There is therefore a convergence of policies. Moreover, it is shown that emission taxes are more likely to be supported and proposed by political parties which represent environmental interest groups. This feature appears to accord with the observed support for environmental taxes by ‘Green’ parties in Europe, Australia, New Zealand and elsewhere.
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    Environmental and resource economics 10 (1997), S. 285-300 
    ISSN: 1573-1502
    Keywords: environmental policy ; technological change ; irreversibility
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    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract The paper explores the relationships between the design of public incentives and the policy-maker's desired timing of abandonment of a polluting technology, when this requires an irreversible private investment and the firm faces uncertain appropriable benefits from the technological change. Two regulatory approaches are examined. Firstly, we consider the quite common one of lowering the private investment cost, through a subsidy, in order to bridge the gap between the private and the policy-maker's desired timing of environmental innovation. Secondly, we consider a policy scenario where the regulator, instead of simply lowering the investment's rental price, also stimulates abandonment of the polluting technology by reducing – through appropriate announcements – the uncertainty surrounding the technological switch's private profitability. We then compare the two approaches and show the latter's benefits, in terms of the policy's effectiveness and/or budgetary savings.
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    Environmental and resource economics 11 (1998), S. 489-501 
    ISSN: 1573-1502
    Keywords: cost-benefit analysis ; environmental policy ; precautionary principle ; risk assessment ; sustainable development
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    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract Revisions to the European Treaty of Union require some form of environmental appraisal – primarily risk assessment and cost-benefit analysis – of regulatory initiatives by the European Commission. A retrospective look at the emergence of environmental appraisal also shows that, while the Commission has made great advances in introducing cost-benefit or cost-effectiveness appraisals in recent years, past environmental decisions and overall environmental policy have not been informed by systematic appraisal techniques. Nor is it clear what role is now being played by risk assessments. While it is impossible to gauge the extent to which systematic appraisal procedures will save on regulatory and compliance expenditures, some indications are provided of the costs of past neglect of these procedures.
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    Environmental and resource economics 9 (1997), S. 199-224 
    ISSN: 1573-1502
    Keywords: environmental policy ; pulp and paper ; life cycle ; optimization ; technology lock-in ; recycling ; geography of production ; environment-trade conflict
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    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract In this paper, we propose a methodology, based on materials accounting and operational research techniques, to assess different industry configurations according to their life cycle environmental impacts. Rather than evaluating a specific technology, our methodology searches for the feasible configuration with the minimum impact. This approach allows us to address some basic policy-relevant questions regarding technology choice, investment priorities, industrial structures, and international trade patterns. We demonstrate the methodology in the context of the European pulp and paper industry. We are able to show that current environmental policy's focus on maximizing recycling is optimal now, but that modest improvements in primary pulping technology may shift the optimal industry configuration away from recycling toward more primary pulping with incineration. We show that this will have significant implications for the amount and type of environmental damage, for the location of different stages in the production chain, and for trade between European member states. We caution policy makers that their single-minded focus on recycling may foreclose investment in technologies that could prove environmentally superior. Finally, we hint that member state governments may be fashioning their environmental policy positions at least in part on some of the trade and industrial implications we find.
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    Environmental and resource economics 15 (2000), S. 179-197 
    ISSN: 1573-1502
    Keywords: carbon dioxide ; double dividend ; employment ; energy tax ; EU ; environmental policy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract In March 1997 the European Commission adopted aproposal that increases existing minimum levels oftaxation on mineral oils by around 10 to 25% andintroduces excises for other energy products. Thispaper analyses the macroeconomic impacts of theproposal. It employs three models: HERMES, GEM-E3, andE3ME. All models confirm that the proposal will havepositive macroeconomic impacts when the tax revenuesare used to reduce social security contributions paidby employers. For the EU as a whole, both GDP andemployment are expected to be higher and CO2emissions are 0.9 to 1.6 percent lower. The positiveEU-wide effects can be observed in practically allmember states. The sector impacts are modest, with theenergy sector expected to face the most negativeimpacts. Differences between model results are due tothe model type (general equilibrium ormacro-econometric), the EU countries covered and theway tax exemptions were handled. Crucial assumptionsto obtain the ``double dividend'' are the modelling ofthe labour market and the impacts on EU externaltrade. The sensitivity of the results for the use oftax revenues, tax exemptions and tax rate increases isassessed.
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    Environmental and resource economics 2 (1992), S. 615-634 
    ISSN: 1573-1502
    Keywords: Cleaner technologies ; environmental policy ; economic instruments ; efficiency ; innovation ; diffusion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract This article identifies and analyzes factors that affect the willingness of firms and consumers to develop and adopt cleaner technologies. “Cleaner technologies” is used as a general term for pollution abatement technologies, re-use systems, and environmentally sound consumer products and materials. The article also contains the findings of three case studies on cleaner technologies (CFC substitutes, low-solvent paints and coatings, and membrane technology), in which the importance of the identified factors is investigated. From the case studies some general conclusions are drawn about these factors, and the way in which policy instruments can be used to stimulate innovation in and diffusion of cleaner technologies. No single policy instrument is considered to be optimal. Instead a policy mix is needed, involving a much wider use of economic instruments.
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    Environmental and resource economics 3 (1993), S. 245-262 
    ISSN: 1573-1502
    Keywords: Incentives ; Principal-agent ; environmental policy ; emission taxes ; abatement subsidies
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    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract The objective of this paper is to present environmental policy as a simple game in two stages within a principal-agent framework. At the outset the authority adopts a transfer payment rule. Then the firms react by carrying out abatement activities, based on their chosen levels of emission and output. Next the authority measures the emissions (and residual profit of the industry) and revises the level of its instrument. Then the game starts again. Our purpose is to narrow the scope of ad hoc incentive schemes by characterizing families of optimal linear schemes.
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    Mitigation and adaptation strategies for global change 1 (1997), S. 289-309 
    ISSN: 1573-1596
    Keywords: administrative regulation ; consumption ; emissions ; global environment ; environmental policy ; tradeable permits ; tradeable quotas ; ‘sin’ tax
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Abstract The paper reviews various policy tools that have been discussed in the literature, including legal, administrative and fiscal (tax) schemes, as well as tradeable emission permits, and concludes that none of them are really suitable for dealing with global problems. An alternative is suggested, namely the use of tradeable individual consumption quotas for traded commodities at the national level, to be extended later to the global level by trading quotas among nations (assuming agreement can be reached on the basis for determining quotas).
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    International journal of fracture 101 (2000), S. 33-72 
    ISSN: 1573-2673
    Keywords: Polymers ; brittle fracture ; shear banding ; impact.
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A rather unusual failure mode transition from brittle to ductile at high strain rates occurs under a combined pressure and shear loading. This transition also represents a change in the failure mode from a normal stress dominated fracture mode at low loading rates to a shear stress dominated shear banding failure at high strain rates. While most such observations have been in metallic materials, where such transitions are attributed to thermal softening caused by adiabatic heating, in this paper we present evidence of such mode transitions in a polymer. Experimental observations of the pressure-shear loading experiments are reported in two polymers; polycarbonate (PC) and polymethylmethacrylate (PMMA). Dynamic photomechanics techniques were used in obtaining information regarding the crack tip state in these experiments. While PC exhibits a failure mode transi- tion to shear banding, PMMA changes to a shear mode of fracture; dynamic shear fracture has been observed in real-time using high speed photography for the first time. A numerical simulation of the experiment using a simple constitutive description of the material is performed in order to gain an understanding of the evolution of the crack tip fields that generate the observed mode transitions. The results of the simulation suggest that thermal softening may not play a significant role in the failure mode transitions in polymers. On the other hand, it is shown that the competition between shear yielding and normal stress dominated fracture mechanisms is the key to the failure mode transitions in these polymers.
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    Chromatographia 40 (1995), S. 296-302 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Structural isomer separation ; Cyclodextrin ; Polymers
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    Topics: Chemistry and Pharmacology
    Notes: Summary Several β-cyclodextrin (CD)-bonded stationary phases for high performance liquid chromatography (HPLC) were prepared, based on silica beads coated with a poly(alkylamine), [poly(ethyleneimine)(PEI)]. In order to obtain stationary phases with a high content of CD and maximum accessibility of the CD cavity, the functionalization was carried out after the coating, using the mono-tosyl derivative of CD as the intermediate. The ability of these supports to separate ortho, meta and para isomers of some disubstituted benzene derivatives was examined. The contribution of the amino groups of the polymer and of the CD cavity to the separation process is discussed. The resolution is mainly based on the difference in the stability of the complexes of the various isomers with CD. The influence of the amount of CD on the height of the theoretical plate is also studied.
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    Computational economics 9 (1996), S. 363-384 
    ISSN: 1572-9974
    Keywords: environmental policy ; pollution permits ; variational inequalities
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    Topics: Computer Science , Economics
    Notes: Abstract In this paper, we present a variational inequality framework for the modeling, qualitative analysis, and computation of equilibria in markets in pollution permits. The models developed herein allow for different modes of competitive behavior, including oligopolistic behavior, while taking into account the cost of polluting plus the prices of the licenses to pollute at different receptor points. The models deal explicitly with spatial differentiation and also ensure that the imposed environmental quality standards are met through the initial allocation of licenses. An algorithm is proposed, along with convergence results, to compute the profit-maximized quantities of the firms' products and quantities of emissions, as well as the equilibrium allocation of licenses and their prices. Numerical examples are included to illustrate the approach. This is the first time that this methodology is utilized in environmental economics.
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    Pharmacy world & science 8 (1986), S. 165-189 
    ISSN: 1573-739X
    Keywords: Biocompatible materials ; Chemistry, analytical ; Chemistry, physical ; Drug delivery ; Hydrogels ; Polymers ; Release, sustained ; Review ; Structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Hydrogels are widely studied materials for the preparation of sustained release drug dosage forms. Their soft, tissue-like consistency and their high biocompatibility in a number of applications make them promising candidates for this purpose. The water and the polymer in the gel form intricate structures and much research has been devoted to the elucidation of these structures, and of the interactions involved in their formation. Simple, drug-loaded hydrogels normally give a matrix-type delivery profile, in which the release rate is proportional to the square root of time; a number of approaches has been used to change this profile to other types of delivery, for instance to zero-order release. A number ofin vivo tests using hydrogel delivery systems has given favourable results.
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    Urban ecosystems 3 (1999), S. 131-147 
    ISSN: 1573-1642
    Keywords: growth management ; smart growth ; land use ; planning ; environmental policy
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    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Over the last 25 years, momentum has grown for a policy response to issues raised by development and land use patterns at the urban-suburban-rural interface. Various states and municipalities throughout the country have experimented with legislative and planning approaches, often referred to as “growth management,” to address these land use issues. This paper examines one of the most recent steps in the evolution of growth management, the Smart Growth Initiative enacted by Maryland in April 1997. The paper addresses several questions: What is the Smart Growth Initiative and where does it fit in the evolution of growth management? What processes were used to incorporate diverse values and perspectives in developing the initiative? What are the prospects for its implementation? The paper briefly reviews growth management, its evolution over the last quarter century, and the use of stakeholder involvement and consensus-building processes for policy development. With this background, the Smart Growth Initiative is examined in detail, including the group processes employed to incorporate diverse values in both developing and implementing the initiative. Finally, the paper closes by placing the Smart Growth Initiative in the context of evolving growth management approaches.
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    International tax and public finance 2 (1995), S. 245-260 
    ISSN: 1573-6970
    Keywords: environmental policy ; mobility ; regional economics
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    Topics: Economics
    Notes: Abstract The paper studies the role of household mobility for efficiency of decentralized environmental policy. Pollutants may travel across regional boundaries, and regions can influence their capital income from abroad as well as the rent outflow to nonresidents by means of their environmental policy. Different degrees of interregional household mobility are analyzed within this framework. While regional governments internalize all externalities in their own self-interest in the case of perfect household mobility, only a region that voluntarily makes an interregional transfer to the other region has incentives to internalize interregional externalities if households are imperfectly mobile.
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    ISSN: 1435-1536
    Keywords: Polymers ; adsorption ; networks ; swelling ; macroreticular resins
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Two groups of polymer networks (polymer resins) are investigated by selective liquid sorption fromn-propanol-water mixtures. Group 1 consists of gel polymerized polar (hydrophilic) ion exchangers which swell in the binary liquid mixture. Group 2 consists of non-polar, non-swelling, macroporous resins. The free energy isotherms accompanying the sorption processes are calculated from the excess isotherms and the bulk activities. The adsorption excess free energies reveal the differences in polarity of the polymer network.
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    Colloid & polymer science 261 (1983), S. 825-833 
    ISSN: 1435-1536
    Keywords: Polymers ; Slow-brittle-fracture ; Toughness ; Caustics
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A slow crack growth was achieved in initially edge-cracked specimens made of a high-molecular weight PMMA by regulating the cross-head speed of loading by a computer-driven testing machine. The strain rate $$\dot \varepsilon $$ used during the tests varied between $$\dot \varepsilon $$ =1× l0−6 s−1 and 1×10−4 s−1. It was shown that, in this zone of slow quasi-static loading of brittle polymethylmethacrylate specimens under conditions of plane stress, the crack initiated for a critical value of loading, at some characteristic zone of strain-rate variation at the crack tip. It was established that for strain rate between $$\dot \varepsilon $$ =0.18×10−5 s−1 and $$\dot \varepsilon $$ =0.45×10−4 s−1 brittle cracks were propagating always slowly with velocities in the range ofc=3 to 5×10−2 m/s. For values ofv s outside this transition zone fracture was typically brittle with high crack-propagation velocities. As the strain rate was varying beyond the stable low-velocity region, a two-step crack velocity pattern was operative, where the one step took always low values, and the other step corresponded to crack-propagation velocities significantly higher than these limits, tending to typical brittle-fracture velocities of the material. Oscillations of the velocityc at the transition zones, or, in many cases all over the zone of slow propagation of the crack, indicated the unstable character of crack propagation, influenced by different stress raisers and especially by the opposite longitudinal boundary of the specimen. Stress intensity factor values during crack propagation, evaluated from the front (cuspoid) and the rear (external) caustic, which remained alwaysk g-dominant, were following similar trends as the variation of the crack propagation velocity.
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    Colloid & polymer science 274 (1996), S. 1033-1043 
    ISSN: 1435-1536
    Keywords: Polymers ; concentrated solutions ; entanglements ; dynamics ; photon correlation spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Photon correlation spectroscopy in the polarized geometry has been used to systematically investigate the complex dynamics of a highly concentrated entangled polymer solution in a nominally good solvent, poly(butylacrylate) in dioxane. In addition to the well known fast cooperative diffusion process, a slow virtuallyq-independent mode is detected, whereq is the scattering wavevector, in agreement with previous experimental works on semidilute solutions. This mode is attributed to the viscoelastic nature of the transient physical network, formed by the entanglements, which relaxes its elastic stress induced by the concentration fluctuations, as confirmed by small amplitude oscillatory shear measurements; the latter reveal a terminal relaxation time comparable to the characteristic time of the slow relaxation process. Results, especially in terms of concentration and temperature dependence, are evaluated and discussed in view of the existing theoretical treatments in the field, predicting the existence of the slow viscoelastic relaxation. The relationship between dynamic light scattering and mechanical spectroscopy is established.
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    Plant and soil 70 (1983), S. 107-124 
    ISSN: 1573-5036
    Keywords: Citrate ; Iron ; Lupins ; Lupinus albus L. ; Phosphorus ; Polymers
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Large quantities of citrate ions have been shown to be secreted by the roots ofLupinus albus. It is postulated that these react in the soil to form ferric hydroxy phosphate polymers which diffuse to the root surface where they are degraded by the action of reducing agents in the presence of an Fe II uptake mechanism balanced by hydrogen ion secretion. Some known chemical behaviour of Fe III and citrate which supports this postulate is reviewed. Evidence is also presented which suggests that much of the Fe absorbed circulates within the root system and is subsequently precipitated.
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    International tax and public finance 2 (1995), S. 229-244 
    ISSN: 1573-6970
    Keywords: environmental policy ; international capital movements ; imperfect competition ; tax competition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Economics
    Notes: Abstract Does international tax competition in the environmental field lead to undesirably low levels of environmental regulation and to unacceptable disruptions of environmental quality? The paper tries to answer this question in a noncompetitive partial-equilibrium framework. There is one firm that wishes to establish a plant in one ofn countries. The paper shows that tax competition may lead to emission taxes that are either too low or too high. They may be so high that the investment is not undertaken, although this would be optimal if the countries cooperated. On the other end of the spectrum, a scenario in which taxes are driven to zero becomes possible if there are substantial transfrontier pollution effects.
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    Environmental and resource economics 1 (1991), S. 17-41 
    ISSN: 1573-1502
    Keywords: Single European Market ; environmental policy ; product standards ; environmental taxes ; transfrontier pollution ; border controls ; subsidiary principle
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract The paper analyzes the direct and indirect environmental impacts of the completion of the Single European Market, both internally and with respect to the Rest of the World. Moreover, the principles of environmental policy are described. The main conclusion is that if the European Community and the member states develop effective and efficient policy instruments the positive effects of the completion of the Single Market could substantially outweigh the negative impacts.
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    Environmental and resource economics 4 (1994), S. 495-509 
    ISSN: 1573-1502
    Keywords: Environmental accidents ; moral hazard ; environmental policy
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    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract We study optimal government policy when firms' operations involve a risk of a large environmental accident, firms do not have sufficient assets to cover such costs, and the risk is affected by firms' efforts which are unobservable to outsiders. When firms' profits and government revenues have equal weights in the social welfare function, a first best can be implemented and requires that the firm be subsidized heavily when operating with no accident, and all its assets confiscated in the event of an accident. With a lower weight on firm profits the solution is always second best, with lower subsidies to the firm, and a firm effort lower than at the first-best solution. When firm investments affect both the required accident-preventing effort for given risk and the work effort required for a given output, the first best never involves specific investment subsidies, while a second-best solution generally always does.
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    Environmental and resource economics 11 (1998), S. 557-570 
    ISSN: 1573-1502
    Keywords: endangered species ; environmental policy ; pollution ; risk
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract Behavior matters more to environmental policy than most people think. This paper illustrates why this point needs repeating in four ongoing policy debates in the United States – Children's health risk, ozone/particulate matter (PM), climate change, and endangered species.
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    Environmental and resource economics 16 (2000), S. 121-160 
    ISSN: 1573-1502
    Keywords: electric utilities ; environmental policy ; power generation
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    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract This paper discusses the effects of alternative waysof using external cost estimates to regulateinvestments and generation in the electricityproduction sector. Starting from the existing system,four alternatives are considered: emission taxes forthe utility and for independent producers, emissiontaxes limited to the electric utility, emissionpermits limited to the electric utility and finally asystem where only investments are regulated, anddispatch is not. Taking external damage estimates fromthe literature, these alternatives are compared usinga dynamic partial equilibrium model of the Belgianelectricity market for the period 1995–2034. Theefficiency and distribution effects of the alternativeenvironmental policy instruments are quantified.
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    Environmental and resource economics 16 (2000), S. 229-251 
    ISSN: 1573-1502
    Keywords: environmental policy ; externalities ; integrated production systems ; joint production ; sulphuric acid
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract Real production systems are often vertically integrated in thesense that one production process uses the unwanted joint product of another production process as input.This interrelationship links in a non-obvious way the different negative externalities stemming from theproduction processes. An empirical example is the sulphuric acid industry. Our model of a vertically integratedproduction system shows how internalising one currently existing externality may create another externalitywhich has thus far not been existent. We also discuss how environmental policy could deal with this problemwhen regulating integrated production systems.
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    Environmental and resource economics 3 (1993), S. 41-61 
    ISSN: 1573-1502
    Keywords: Climate change ; environmental policy ; dynamic control ; stock pollutant ; greenhouses gases
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract Efficient policies to control trace gas emissions require estimation of an appropriate “exchange rate” among these gases; i.e. the relative value of reducing emissions of each gas. A dynamic stock pollutant model is developed that considers damages associated with both non-climatic and climatic effects of the gases, differing atmospheric lifetimes of the gases, the discount rate, and non-linear damages. The index value and shadow value of control are estimated for carbon dioxide, carbon monoxide, methane, nitrous oxide and the 4 major chlorofluorocarbons (CFCs). The value of control for short-lived relative to long-lives gases is lower for low discount rates and quadratic compared with linear damages. The relative value of control for all gases falls relative to carbon dioxide if one considers the direct beneficial effects of carbon dioxide on agriculture. The general approach developed in the paper may have application for other environmental problems where multiple substances pose individual risks but also jointly contribute to a single risk.
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    Environmental and resource economics 9 (1997), S. 199-224 
    ISSN: 1573-1502
    Keywords: environmental policy ; pulp and paper ; life cycle ; optimization ; technology lock-in ; recycling ; geography of production ; environment-trade conflict
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract In this paper, we propose a methodology, based on materials accounting and operational research techniques, to assess different industry configurations according to their life cycle environmental impacts. Rather than evaluating a specific technology, our methodology searches for the feasible configuration with the minimum impact. This approach allows us to address some basic policy-relevant questions regarding technology choice, investment priorities, industrial structures, and international trade patterns. We demonstrate the methodology in the context of the European pulp and paper industry. We are able to show that current environmental policy's focus on maximizing recycling is optimal now, but that modest improvements in primary pulping technology may shift the optimal industry configuration away from recycling toward more primary pulping with incineration. We show that this will have significant implications for the amount and type of environmental damage, for the location of different stages in the production chain, and for trade between European member states. We caution policy makers that their single-minded focus on recycling may foreclose investment in technologies that could prove environmentally superior. Finally, we hint that member state governments may be fashioning their environmental policy positions at least in part on some of the trade and industrial implications we find.
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    Environmental and resource economics 7 (1996), S. 333-355 
    ISSN: 1573-1502
    Keywords: environmental policy ; pollution ; strategic behaviour
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract Policy makers, industrialists and environmentalists express concern that the imposition of tough environmental policies in some countries displaces production, and hence pollution, to countries which impose less tough environmental policies. Yet empirical studies of such impacts suggest they are small. However, these findings are derived from models in which international trade is modelled as being perfectly competitive. In this paper I model trade as imperfectly competitive with scope for strategic behavior by producers, in this case investment in capital. I show that the choice of environmental policy instrument can have a marked impact on the incentives for producers to act strategically, with environmental standards significantly reducing the incentives for strategic overinvestment relative to environmental taxes or no environmental policy at all. Whether welfare is higher using standards or taxes depends on whether producing countries are also significant consumers of the polluting product, and on whether all producing governments act to reduce emissions or only some subset of governments. To assess the quantitative significance of these theoretical results I conduct policy simulations on a calibrated model of the world fertilizer industry. These simulations show that the impact of environmental policy on strategic behaviour can be large.
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    Environmental and resource economics 9 (1997), S. 43-63 
    ISSN: 1573-1502
    Keywords: carbon pollution credits ; carbon taxes ; environmental policy ; externalities ; hybrid instruments ; tradeable carbon permits
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract This paper analyses how hybrid systems of carbon taxes and tradeable permits optimize some conflicting dimensions of political acceptability related to the design of these instruments. Pure systems like taxes without exemptions or auctioned tradeable permits cause problems for political acceptability in open economies due to high overall costs (abatement cost plus payments on the tax or auctions) for current polluters. Unfortunately, pure systems based on grandfathering of emission rights across the board do not provide a feasible alternative because of monitoring and enforcement problems. In contrast, consciously designed hybrid systems employ grandfathering of emission rights together with either carbon taxes or auctioned carbon permits in order to overcome acceptability problems of pure systems, while leaving incentives to reduce emissions at the margin untouched. Moreover, monitoring and enforcement costs of the hybrid systems are less due to the lower number of participating agents compared with the pure systems, while opportunities for costor burden-sharing exist as well.
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    Environmental and resource economics 8 (1996), S. 97-118 
    ISSN: 1573-1502
    Keywords: materials balance ; recycling ; substitution ; economic modelling ; environmental policy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract A framework is presented for the analysis of economic and environmental impacts of policies applied to materials-product (MP) chains. This is based on materials flows, product flows, costs, prices and optimal management of an MP chain. The main differences compared with other studies focusing on materials flows is that here the link between products or services and materials is explicitly dealt with. The framework is developed on the basis of materials balance conditions, production functions allowing for substitution, and recycling of both materials and products. After presenting theoretical MP chain-models and analytical results, an application to the problem of choosing between zinc and PVC gutters is discussed. Here optimal MP chain management decisions are presented for various policy and strategy scenarios.
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    Mitigation and adaptation strategies for global change 1 (1997), S. 289-309 
    ISSN: 1573-1596
    Keywords: administrative regulation ; consumption ; emissions ; global environment ; environmental policy ; tradeable permits ; tradeable quotas ; ‘sin’ tax
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Abstract The paper reviews various policy tools that have been discussed in the literature, including legal, administrative and fiscal (tax) schemes, as well as tradeable emission permits, and concludes that none of them are really suitable for dealing with global problems. An alternative is suggested, namely the use of tradeable individual consumption quotas for traded commodities at the national level, to be extended later to the global level by trading quotas among nations (assuming agreement can be reached on the basis for determining quotas).
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    Colloid & polymer science 273 (1995), S. 413-420 
    ISSN: 1435-1536
    Keywords: Polymers ; glass transition ; neutron scattering ; polystyrene
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Atactic polystyrene, both side group and main chain deuterated, was investigated by inelastic neutron scattering in a wide temperature range around the glass transition from 2 to 450 K. In the glass the Boson peak position is only very weakly influenced by the deuteration of the phenyl group. In the neighborhood of the glass transition temperatureT g we find a fast relaxation process similar to other glasses. The onset of the fast relaxation in polystyrene, however, is observed already at temperaturesT g — 200 K. Results from partially deuterated polystyrene suggest a change of the phenyl ring dynamics already far belowT g.
    Type of Medium: Electronic Resource
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  • 100
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 266 (1988), S. 1087-1094 
    ISSN: 1435-1536
    Keywords: Polymers ; shear flow ; crystallization ; induction time ; relaxation ; injection molding
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract In the presented model elements of polymer melt rheology and polymer crystallization kinetics are combined. In particular, the proneness of the melt to the special type of crystallization which is characteristic for shear treatment is supposed to emerge only gradually during shear flow. Following Avrami's early ideas on crystal growth, an induction time is introduced. In principle, the model can be applied to any flow and temperature history. The special case of isothermal flow at constant shear rate is covered in greater detail: A favorable comparison is made with experimental results, as published by Lagasse and Maxwell [10].
    Type of Medium: Electronic Resource
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