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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Transport in porous media 7 (1992), S. 127-145 
    ISSN: 1573-1634
    Keywords: Miscible displacement ; dispersion ; in-situ concentration measurement ; computerized data acquisition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract A technique for measurement of thein-situ concentration in an unconsolidated porous medium has been developed. The method involves measurement of electrical conductivityin-situ, under dynamic conditions, for flow involving brine of differing concentrations, at selected locations along the porous medium and relating it to the brine strength. Data acquisition and analysis is carried out using a Hewlett — Packard micro-computer and its interface. A user-friendly software was designed and developed for the system. The measurement technique was evaluated by studying the effect of brine concentration, brine flow rate, and by conducting miscible displacements experiment. The experimentally measured dispersion coefficients for the porous medium agreed closely with the value predicted by the correlation available in the literature.
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  • 2
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    Transport in porous media 28 (1997), S. 109-124 
    ISSN: 1573-1634
    Keywords: seepage ; conductivity ; double-periodic structure ; advection ; dispersion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract A study is made of steady two-dimensional seepage in a porous massif composed by a double-periodic system of ‘white’ and ‘black’ chequers of arbitrary conductivity. Rigorous matching of Darcy's flows in zones of different conductivity is accomplished. Using the methods of complex analysis, explicit formulae for specific discharge are derived. Stream lines, travel times, and effective conductivity are evaluated. Deflection of marked particles from the ‘natural’ direction of imposed gradient and stretching of prescribed composition of these particles enables the elucidation of the phenomena of transversal and longitudinal dispersion. A model of pure advection is related with the classical one-dimensional vective dispersion equation by selection of dispersivity which minimizes the difference between the breakthrough curves calculated from the two models.
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  • 3
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    Transport in porous media 9 (1992), S. 25-37 
    ISSN: 1573-1634
    Keywords: Waves ; dispersion ; shock tube ; gas bubbles
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract The propagation of compressional waves in a porous medium is investigated in case the pore liquid contains a small volume fraction of gas. The effect of oscillating gas bubbles is taken into account by introducing a frequency-dependent fluid bulk modulus, which is incorporated in the Biot theory. Using a shock tube technique, new experimental data are obtained for a porous column subjected to a pressure step wave. An oscillatory behaviour is observed, consisting of two distinct frequency bands, which is predicted by the theoretical analysis.
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  • 4
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    Transport in porous media 23 (1996), S. 107-124 
    ISSN: 1573-1634
    Keywords: solute transport ; Fick's law ; dispersion ; dispersivity ; equation of motion ; non-Fickian dispersion equation ; scale effects
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract The Fickian dispersion equation is the basic relationship used to describe the nonconvective mass flux of a solute in a porous medium. This equation prescribes a linear relationship between the dispersive mass flux and the concentration gradient. An important characteristic of the Fickian relationship is that it is independent of the history of dispersion (e.g. the time rate of change of the dispersion flux). Also, the dispersivities are supposed to be medium constants and invariant with temporal and spatial scales of observation. It is believed that in general these restrictions do not hold. A number of authors have proposed various alternative relationships. For example, differential equations have been employed that prescribe a relationship between the dispersion flux and its time and space derivatives. Also, stochastic theories result in integro-differential equations in which dispersion tensor grow asymptotically with time or distance. In this work, three different approaches, which lead to three different non-Fickian equations with a transient character, are discussed and their primary features and differences are highlighted. It is shown that an effective dispersion tensor defined in the framework of the transient non-Fickian theory, grows asymptotically with time and distance; a result which also follows from stochastic theories. Next, principles of continuum mechanics are employed to provide a solid theoretical basis for the non-Fickian transient dispersion theory. The equation of motion of a solute in a porous medium is used to provide a rigorous derivation of various dispersion relationships valid under different conditions. Under various simplifying assumptions, the generalized theory is found to agree with the conventional Fickian theory as well as several other non-Fickian relationships found in the literature. Moreover, it is shown that for nonconservative solutes, the traditional dispersion tensor is affected by the rate of mass exchange of the solute.
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  • 5
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    Transport in porous media 3 (1988), S. 473-489 
    ISSN: 1573-1634
    Keywords: Advection ; dispersion ; particles ; characteristics ; finite-element ; continuous fluid velocity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract A Eulerian-Lagrangian scheme is used to solve the two-dimensional advection-dispersion equation. Concentration and its partial differential operator are decomposed into advection and dispersion terms. Thus, advection is formally decoupled from dispersion and solved by continuous forward particle tracking. Dispersion is handled by implicit finite elements on a fixed Eulerian grid. Translation of steep gradients of concentration in advection-dominated flow regimes, is done without numerical distortion. Continuous spatial distribution of velocities are evaluated by using Galerkin's approach in conjunction with Darcy's law based on hydraulic input data from each element. The method was implemented on coarse FE grid with linear shape functions, demonstrating no over/under shooting and practically no numerical dispersion. Simulations, covering a wide range of Peclet numbers, yield high agreement with analytic and practical results.
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  • 6
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    Transport in porous media 4 (1989), S. 85-96 
    ISSN: 1573-1634
    Keywords: Stability ; linear stability analysis ; miscible displacement ; aspect ratio ; mobility control ; dispersion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract Chang and Slattery (1986, 1988b) introduced a simplified model of dispersion that contains only two empirical parameters. The traditional model of dispersion (Nikolaevskii, 1959; Bear, 1961; Scheidegger, 1961; de Josselin de Jong and Bossen, 1961; Peaceman, 1966; Bear, 1972) has three empirical parameters, two of which can be measured in one-dimensional experiments while the third, the transverse dispersivity, must be measured in experiments in which a two-dimensional concentration profile develops. It is found that nearly the same linear stability behavior results from using either model.
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  • 7
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    Transport in porous media 23 (1996), S. 275-301 
    ISSN: 1573-1634
    Keywords: free convection ; through flow ; vadoze zone ; salinization ; dispersion ; multigrid
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract Evaporation of groundwater in a region with a shallow water table and small natural replenishment causes accumulation of salts near the ground surface. Water in the upper soil layer becomes denser than in the depth. This is a potentially unstable situation which may result in convective currents. When free convection takes place, estimates of the salinity profile, salt precipitation rate, etc., obtained within the framework of a 1-D (vertical) model fail. Very simplified model of the process is proposed, in which the unsaturated zone is represented by a horizontal soil layer at a constant water saturation, and temperature changes are neglected. The purpose of the model is to obtain a rough estimate of the role of natural convection in the salinization process. A linear stability analysis of a uniform vertical flow is given, and the stability limit is determined numerically as a function of evaporation rate, salt concentration in groundwater, and porous medium dispersivity. The loss of stability corresponds to quite realistic Rayleigh numbers. The stability limit depends in nonmonotonic way on the evaporation rate. The developed convective regime was simulated numerically for a 2-D vertical domain, using finite volume element discretization and FAS multigrid solver. The dependence of the average salt concentration in the upper layer on the Rayleigh number was obtained.
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  • 8
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    Transport in porous media 24 (1996), S. 275-296 
    ISSN: 1573-1634
    Keywords: chemical flooding ; ternary ; immiscible ; surfactant ; numerical simulation ; interfacial tension ; phase behavior ; miscibility ; capillarity ; numerical grid ; adsorption ; dispersion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract This is the second of two joint papers which study the influence of several physical properties on the transport phenomena in chemical flooding. To that aim, we use a previously reported ternary two-phase model into which representative physical properties have been incorporated as concentration-dependent functions. Physical properties such as phase behavior, interfacial tensions, residual saturations, relative permeabilities, phase viscosities and wettability have been analyzed in the first paper. In this paper, we discuss the influence of capillary pressure, adsorption of the chemical component onto the rock and dispersion. Although arising from different phenomenological sources, these transport mechanisms show some similar effects on concentration profiles and on oil recovery. They are studied for systems with different phase behavior. A numerical analysis is also presented in order to determine the relevance of the number of grid blocks taken in the discretization of the differential equations. This numerical analysis provides useful guidelines for the selection of the appropriate numerical grid in each type of displacement.
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  • 9
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    Transport in porous media 3 (1988), S. 217-256 
    ISSN: 1573-1634
    Keywords: Salinity ; advection ; dispersion ; aquifers ; flow model ; transport model ; simulation ; sea water ; connate water ; leakage
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract Historical information of the hydraulic and salinity aspect, detailed geological information, and information on the physical characteristics of the different layers comprising the formation, are needed for simulating the saltwater transport process in aquifers. In most simulation studies of field situations, there is an inadequacy of data and the modeller has to make justifiable assumptions to analyze a particular situation in order to provide an insight into the problem. A quasi-three-dimensional solute transport model is used to analyze the saltwater encroachment phenomena in aquifers underlying the City of Bangkok; first by calibrating the model's performance with available historical data and then by assessing the extent of future saltwater encroachment with the implementation of the regulatory pumpage to be followed in order to restrict the alarming rate of land subsidence. Model simulation indicates a substantial reduction in the rate of encroachment of the saltwater front with a reduction of pumpage after 1987.
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  • 10
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    Transport in porous media 3 (1988), S. 549-562 
    ISSN: 1573-1634
    Keywords: Adaptive mesh ; finite element method ; dispersion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract A Galerkin finite element method is used along with a self-adaptive strategy of domain discretisation to model dispersion in an axisymmetric cylindrical porous medium. A solution strategy is proposed based on the use of a Gear scheme for the time stepping and partial vectorisation of the code. The domain is highly discretised in the area of the sharp transient front, while the remainder is coarsely discretised. The area covered by the fine mesh is determined by the value of the local concentration gradients. Numerical results are presented for the one and two dimensional cases.
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  • 11
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    Transport in porous media 30 (1998), S. 57-73 
    ISSN: 1573-1634
    Keywords: groundwater ; nonergodic transport ; dispersion ; heterogeneous formations ; hydrogeology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract Flow of an inert solute in an heterogeneous aquifer is usually considered as dominated by large-scale advection. As a consequence, the pore-scale dispersion, i.e. the pore scale mechanism acting at scales lower than that characteristic of the heterogeneous field, is usually neglected in the computation of global quantities like the solute plume spatial moments. Here the effect of pore-scale dispersion is taken into account in order to find its influence on the longitudinal asymptotic dispersivity D11we examine both the two-dimensional and the three-dimensional flow cases. In the calculations, we consider the finite size of the solute initial plume, i.e. we analyze both the ergodic and the nonergodic cases. With Pe the Péclat number, defined as Pe=Uλ/D, where U, λ, D are the mean fluid velocity, the heterogeneity characteristic length and the pore-scale dispersion coefficient respectively, we show that the infinite Péclat approximation is in most cases quite adequate, at least in the range of Péclat number usually encountered in practice (Pe 〉 102). A noteworthy exception is when the formation log-conductivity field is highly anisotropic. In this case, pore-scale may have a significant impact on D11, especially when the solute plume initial dimensions are not much larger than the heterogeneities' lengthscale. In all cases, D11 appears to be more sensitive to the pore-scale dispersive mechanisms under nonergodic conditions, i.e. for plume initial size less than about 10 log-conductivity integral scales.
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  • 12
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    Transport in porous media 31 (1998), S. 133-143 
    ISSN: 1573-1634
    Keywords: transport ; solute ; flux-averaged concentration ; stratification ; conductivity ; distribution ; arrival time ; dispersion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract Two-dimensional and steady solute transport in a stratified porous formation is analysed under assumption that the effect of pore-scale dispersion is negligible. The longitudinal dispersion produced as a result of the vertical variation of hydraulic conductivity is analysed by averaging the variability of a solute flux concentration and conductivity. The evolution of the solute flux concentration is expressed with respect to the correlated variable, that is the travel (arrival) time τ at a fixed location and the averaging procedure is constructed to satisfy the boundary condition where the inlet concentration is a known function of time. In such a statement, a velocity-averaged solute flux concentration is described by a conventional dispersion model (CDM) with a dispersion coefficient which is a function of the arrival time. It is demonstrated that such CDM satisfies the assumption that hydraulic conductivity of the layers is gamma distributed with the parameter of distribution which is chosen to represent a reasonable value of the field scale solute dispersion. The overall behaviour of the model is illustrated by several examples of two-dimensional mass transport.
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  • 13
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    Transport in porous media 21 (1995), S. 175-188 
    ISSN: 1573-1634
    Keywords: diffusion ; dispersion ; percolation ; fractals ; scaling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract Two fundamental questions regarding the application of percolation theory to transport in porous media are addressed. First, when ‘critical path’ arguments (based on a sufficiently wide spread of microscopic transition rates) are invoked (in analogy to the case of transport in disordered semiconductors) to justify the application of percolation theory to the determination of relevant transport properties, then for long time scales (compared to the inverse of the ‘critical’ percolation rate), the fractal structure of the ‘critical’ path is relevant to transport, but not at short time scales. These results have been demonstrated concretely in the case of disordered semiconductors, and are in direct contradiction to the claims of the review. Second, the relevance of deterministic or stochastic methods to transport has been treated heretofore by most authors as a question of practicality. But, at least under some conditions, concrete criteria distinguish between the two types of transport. Percolative (deterministic) transport is temporally reproducible and spatially inhomogeneous while diffusive (stochastic) transport is temporally irreproducible, but homogeneous, and a cross-over from stochastic to percolative transport occurs when the spread of microscopic transition rates exceeds 4–5 orders of magnitude. It is likely that such conditions are frequently encountered in soil transport. Moreover, clear evidence for deterministic transport (although not necessarily percolative) exists in such phenomena as preferential flow. On the other hand, the physical limitation of transport to (fractally connected) pore spaces within soils (analogously to transport in metal-insulator composites) can make transport diffusive on a fractal structure, rather than percolative.
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  • 14
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    Transport in porous media 24 (1996), S. 1-33 
    ISSN: 1573-1634
    Keywords: unsaturated flow ; large-scale averaging ; dispersion ; high-resolution numerical simulations ; NAPL spills
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract Infiltration of water and non-aqueous phase liquids (NAPLs) in the vadose zone gives rise to complex two- and three-phase immiscible displacement processes. Physical and numerical experiments have shown that ever-present small-scale heterogeneities will cause a lateral broadening of the descending liquid plumes. This behavior of liquid plumes infiltrating in the vadose zone may be similar to the familiar transversal dispersion of solute plumes in single-phase flow. Noting this analogy we introduce a mathematical model for ‘phase dispersion’ in multiphase flow as a Fickian diffusion process. It is shown that the driving force for phase dispersion is the gradient of relative permeability, and that addition of a phase-dispersive term to the governing equations for multiphase flow is equivalent to an effective capillary pressure which is proportional to the logarithm of the relative permeability of the infiltrating liquid phase. The relationship between heterogeneity-induced phase dispersion and capillary and numerical dispersion effects is established. High-resolution numerical simulation experiments in heterogeneous media show that plume spreading tends to be diffusive, supporting the proposed convection-dispersion model. Finite difference discretization of the phase-dispersive flux is discussed, and an illustrative application to NAPL infiltration from a localized source is presented. It is found that a small amount of phase dispersion can completely alter the behavior of an infiltrating NAPL plume, and that neglect of phase-dispersive processes may lead to unrealistic predictions of NAPL behavior in the vadose zone.
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  • 15
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    Transport in porous media 1 (1986), S. 179-199 
    ISSN: 1573-1634
    Keywords: Stability ; linear stability analysis ; miscible displacement ; dispersion ; mobility control
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract A linear stability analysis has been performed for a miscible displacement in a semi-infinite system of finite thickness and unbounded width. A more general description of dispersion has been adopted than those used by previous workers. It is shown that, when there is a step change in concentration and the mobility ratio is unfavorable, the displacement can be unstable at the injection boundary. But, if the concentration is changed sufficiently slowly with time at the entrance to the system, the displacement is stable to infinitesimal perturbations, no matter how unfavorable the mobility ratio. When the mobility ratio is favorable, the displacement is unconditionally stable.
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  • 16
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    Transport in porous media 1 (1986), S. 319-338 
    ISSN: 1573-1634
    Keywords: heterogeneity ; dispersion ; saturated flow ; unsaturated flow
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract This invited lecture enumerates various categories of flow and transport in heterogeneous media with particular reference to this Symposium. Specific attention is given to five topics within these categories. (1) We explore the compounding of spatially variable local permeability K to produce an apparent permeability K * on a scale large compared with that of variation of K. An inverse method generates and analyzes flow systems with K spatially periodic in two and three dimensions. (2) Physical arguments indicate that apparent hydraulic properties of an unsaturated composite medium may not represent any conceivable mean of the properties of the component media. (3) Conventionally, buried holes are thought to stay empty during generally unsaturated soil-water flow. The hole, however, acts as an obstacle to flow so that water may seep through it. The larger the hole the more likely this will happen. (4) Dispersion in heterogeneous porous systems with no maximum scale of variation is explored using a Lagrangian mode of analysis. (5) Comments are offered on ‘geostatistics’ and its application to heterogeneous soils and aquifers.
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  • 17
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    Transport in porous media 18 (1995), S. 231-243 
    ISSN: 1573-1634
    Keywords: Stratified formations ; kinematic mixing ; dispersion ; random fields
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract The mixing process in fluid flow is presented as the bending and stretching of material lines or filaments. A mixing exponent, which quantifies their specific rate of stretching, is defined and analyzed for the case of groundwater flow though stratified formations characterized by a Gaussian autocovariance function. The analysis is performed for purely advective mixing as well as for advective-dispersive mixing. The mixing exponent was found to be proportional to the variance of hydraulic conductivity and inversely proportional to the correlation scale of hydraulic conductivity and to the pore-level dispersion coefficient.
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  • 18
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    Transport in porous media 6 (1991), S. 607-626 
    ISSN: 1573-1634
    Keywords: dispersion ; dispersivity ; heterogenity ; miscible ; porous media ; scaling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract This paper discusses scaling of mixing during miscible flow in heterogeneous porous media. In large field systems dispersivity appears to depend on system length due to heterogeneities. Three types of scaling are discussed to investigate the heterogeneous effects. Dimensional analysis of mixing during flow through geometerically scaled heterogeneous models is illustrated using measured dispersion. Fractal analysis of mixing in statistically scaled heterogeneous porous media is discussed. Analog scaling of pressure transients in heterogeneous porous media is suggested as an in-situ method of estimating dispersion.
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  • 19
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    Transport in porous media 12 (1993), S. 143-159 
    ISSN: 1573-1634
    Keywords: Heterogeneity ; layers ; displacement ; numerical simulation ; flow in porous media ; dispersion
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    Topics: Geosciences , Technology
    Notes: Abstract Beadpack experiments and numerical simulations have been carried out to study flow displacements, effluent profiles and streamline patterns for layered systems with flow not parallel to the layers. The effects of layer thickness, permeability contrast, angle of layer to flow direction, mobility ratio and flood rate have been examined. Each of these parameters influence the displacement profiles, and disperse the flood front. Such real effects must be considered when subsuming reservoir heterogeneities in average reservoir parameters in simulation studies, or interpreting core tests.
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  • 20
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    Transport in porous media 13 (1993), S. 3-40 
    ISSN: 1573-1634
    Keywords: Diffusion ; dispersion ; percolation ; fractals ; scaling
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    Topics: Geosciences , Technology
    Notes: Abstract We review and discuss diffusion and hydrodynamic dispersion in a heterogeneous porous medium. Two types of heterogeneities are considered. One is percolation disorder in which a fraction of the pores do not allow transport to take place at all. In the other type, the permeabilities of various regions of the pore space are fractally distributed with long-range correlations. Both systems give rise to unusual transport in which the mean square displacement 〈r 2(t)〉 of a particle grows nonlinearly with time. Depending on the heterogeneities and the mechanism of diffusion and disperison, we may havefractal transport in which 〈r 2〉 growsslower than linearly with time, orsuperdiffusive transport in which 〈r 2〉 growsfaster than linearly with time. We show that percolation models can give rise to both types of transport with scale-dependent transport coefficients such as diffusivity and dispersion coefficients, which are consistent with many experimental observations.
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  • 21
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    Transport in porous media 13 (1993), S. 97-122 
    ISSN: 1573-1634
    Keywords: Scale up ; dispersion ; porous media ; random field
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    Topics: Geosciences , Technology
    Notes: Abstract Dispersion is the result, observable on large length scales, of events which are random on small length scales. When the length scale on which the randomness operates is not small, relative to the observations, then classical dispersion theory fails. The scale up problem refers to situations in which randomness occurs on all length scales, and for which classical dispersion theory necessarily fails. The purpose of this article is to present non-Fickian, theories of dispersion, which do not assume a scale separation between the randomness and the observed consequences, and which do not assume a single length scale. Porous media flow properties are heterogeneous on all length scales. The geological variation on length scales below the observational length scale can be regarded as unknown and unknowable, and thus as a random variable. We develop a systematic theory relating scaling behavior of the geological heterogeneity to the scaling behavior of the fluid dispersivity. Three qualitatively distinct regimes (Fickian, non-Fickian and nonrenormalizable) are found. The theory gives consistent answers within several distinct analytic approximations, and with numerical simulation of the equations of porous media flow. Comparison to field data is made. The use of Kriging to generate constrained ensembles for conditional simulation is discussed.
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  • 22
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    Transport in porous media 15 (1994), S. 15-30 
    ISSN: 1573-1634
    Keywords: Experiment ; dispersion ; layered heterogeneity ; permeability ; averaging ; permutation
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    Notes: Abstract Experiments were run in three linear, homogeneous, nonuniform porous media constructed in lucite columns using spherical glass beads. The columns were also joined end to end to create an in series layered heterogeneous porous media. Each column, all combinations of columns and several permutations were studied with a factorial experimental design to determine the effects of porosity, permeability, velocity, length, and column order upon dispersion. Attempts to predict the heterogeneous results from the homogeneous results were made, and a statistical regression based on the factorial design was calculated. Results showed that no simple averaging procedure accurately predicted the heterogeneous results. The statistical regression showed permeability, velocity, viscosity, length and column order to be significant.
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  • 23
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    Transport in porous media 17 (1994), S. 19-32 
    ISSN: 1573-1634
    Keywords: LGA model ; heterogeneous porous media ; miscible displacement ; dispersion ; tracer
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    Topics: Geosciences , Technology
    Notes: Abstract The lattice gas automaton (LGA) model proposed in the previous paper is applied to the problem of simulating dispersion and mixing in heterogeneous porous media. We demonstrate here that tracer breakthrough profiles and longitudinal dispersion coefficients can be computed for heterogeneous porous media.
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  • 24
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    Transport in porous media 18 (1995), S. 245-261 
    ISSN: 1573-1634
    Keywords: Porous media ; miscible flow ; tracer ; dispersion ; convective flow ; stochastic ; stream tube ; continuous time random walk
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract A simple theoretical model is described for deriving a 1-dimensional equation for the spreading of a tracer in a steady flow at the field scale. The originality of the model is to use a stochastic appoach not in the 3-dimensional space but in the 1-D space of the stream tubes. The simplicity of calculation comes from the local relationship between permeability and velocity in a 1-D flow. The spreading of a tracer front is due to local variations in the cross-sectional area of the stream tubes, which induces randomness in travel time. The derived transport equation is averaged in the main flow direction. It differs from the standard dispersion equation. The roles of time and space variables are exchanged. This result can be explained by using the statistical theory of Continuous Time Random Walk instead of a standard Random Walk. However, the two equations are very close, since their solutions have the same first and second moments. Dispersivity is found to be equal to the product of the correlation length by the variance of the logarithm of permeability, a result similar to Gelhar's macrodispersion.
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  • 25
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    Transport in porous media 18 (1995), S. 263-282 
    ISSN: 1573-1634
    Keywords: Porous media ; dispersion ; miscible flow ; heterogeneities ; stochastic ; stream tube ; layered ; fractal
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract Large-scale dispersion in heterogeneous porous media is studied by using a simple model based on stochastic calculation of convective flow in a bundle of stream tubes. The advantage of this approach is that there is a local relationship between velocity and permeability in the 1-dimensional space of the stream tubes. Dispersion is due to the variation in stream tube cross-section, related to the permeability field. First, the arrival times of the tracer in the stream tubes are related to the stochastic properties of the permeability field (variance and covariance). Then, transport equations are derived from the moments of the arrival times. The results agree with more complicated studies. For a permeability field with long-range correlation, the transport equation is not unique. It depends on the assumptions involving moments higher than two. Assuming a Gaussian shape for the tracer flux leads to equations similar to the ones obtained in previous studies of time-dependent dispersivity. Without this approximation, the equation is non-local (integrodifferential) and leads to a memory effect. In the last part of this paper, the general results are illustrated with several correlation functions for the permeability field: purely random, exponential and power law covariance, and perfectly layered media.
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  • 26
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    Transport in porous media 18 (1995), S. 283-302 
    ISSN: 1573-1634
    Keywords: Solute transport experiments ; heterogeneous media ; dispersion ; scale-dependency
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract Laboratory tracer experiments were conducted to investigate solute transport in 12.5-m long, horizontally placed soil columns during steady saturated water flow. Two columns having cross-sectional areas of 10×10cm2 were used: a uniformly packed homogeneous sandy column and a heterogeneous column containing layered, mixed, and lenticular formations of various shapes and sizes. The heterogeneous soil column gradually changed, on average, from coarse-textured at one end to fine-textured at the other end. NaCl breakthrough curves (BTC's) in the columns were measured with electrical conductivity probes inserted at 50- or 100-cm intervals. Observed BTC's in the homogeneous sandy column were relatively smooth and sigmoidal (S-shaped), while those in the heterogeneous column were very irregular, nonsigmoidal, and exhibited extensive tailing. Effective average pore-water velocities (v eff) and dispersion coefficients (D eff) were estimated simultaneously by fitting an analytical solution of the convection-dispersion equation to the observed BTC's. Velocity variations in the heterogeneous medium were found to be much larger than those in the homogeneous sand. Values of the dispersivity,α=D eff/v eff, for the homogeneous sandy column ranged from 0.1 to 5.0 cm, while those for the heterogeneous column were as high as 200cm. The dispersivity for transport in both columns increased with travel distance or travel time, thus exhibiting scale-dependency. The heterogeneous soil column also showed the effects of preferential flow, i.e., some locations in the column showed earlier solute breakthrough than several locations closer to the inlet boundary. Spatial fluctuations in the dispersivity could be explained qualitatively by the particular makeup of the heterogeneities in the column.
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    Transport in porous media 19 (1995), S. 37-66 
    ISSN: 1573-1634
    Keywords: dispersion ; sandstone ; radial flow
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract This paper presents some experimental and theoretical results for dispersion processes occurring in consolidated Berea sandstone with radial flow geometry. A comprehensive review of the derivation and application of several analytical solutions is also presented. The Galerkin finite element method is applied to solve the advection-dispersion equation for unidimensional radial flow. Individual and combined effects of mechanical dispersion and molecular diffusion are examined using velocity-dependent dispersion models. Comparison of simulated results with experimental data is made. The effect of flow rates is examined. The results suggest that a linear dispersion model,D=αu, whereD is the dispersion coefficient,u the velocity andα a constant, is not a good approximation despite its wide acceptance in the literature. The most suitable mathematical formulation is given by an empirical form of $$D = D_0 + \mathop \alpha \limits^` u^m$$ , whereD ois the molecular diffusion coefficient. For the range of Péclet number (Pe=vd/D m,wherev is the characteristic velocity,d the characteristic length andD mthe molecular diffusion coefficient in porous media) examined (Pe=0.5 to 285), a power constant ofm=1.2 is obtained which agrees with the value reported by some other workers for the same regime. From the results of experiments and numerical modelling, the effect of mobility ratios (defined as the ration of viscosities of displaced and displacing fluids) on dispersion is found to be negligible, provided that the ratio is favourable.
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    Transport in porous media 29 (1997), S. 207-223 
    ISSN: 1573-1634
    Keywords: dispersion ; attenuation ; surface waves ; Rayleigh wave ; Love wave
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract An investigation is conducted of propagation of surface waves in a porous medium consisting of a microscopically incompressible solid skeleton in which a microscopically incompressible liquid flows within the interconnected pores, and particularly the case where the solid skeleton deforms linear elastically. The frequency equations of Rayleigh- and Love-type waves are derived relating the dependence of wave numbers, being complex quantities, on frequency, as a result those waves are dispersive as well as inhomogeneous. Nevertheless, the amplitudes of both surface waves attenuate along the surface of the porous medium, whereas they decay exponentially receding from the surface of the medium.
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  • 29
    ISSN: 1573-1634
    Keywords: solute transport ; nonequilibrium ; heterogeneous porous media ; dispersion ; diffusion ; experiments ; modelling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract Two region models for solute transport in porous media assume that hydrodynamic dispersion in mobile water and solute diffusion within immobile water regions are independent. Experimental and theoretical results for transport through a macropore indicate that hydrodynamic dispersion and solute exchange are interdependent. Experiments were carried out to investigate this problem for a column packed with spherical porous aggregates. The effective diffusion coefficient of a tracer within the agreggates was determined from specific experiments. The dispersivity of the bed was determined from experiments carried out with a column filled with nonporous beads. We took advantage of the dependence of hydrodynamic dispersion on density ratios between the invading and displaced solutions to obtain a set of breakthrough curves corresponding to situations where the diffusion coefficient remains constant, whereas the dispersivity varies. Simulations reproduce correctly the experiments. Small discrepancies are noted that can be corrected either by increasing the dispersion coefficient or by fitting the external mass transfer coefficient. Increased dispersion coefficients probably reveal a modification of Taylor dispersion due to solute exchange. The fitted external mass transfer coefficients are close to the values obtained with classical correlations of the chemical engineering literature.
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    Transport in porous media 3 (1988), S. 277-297 
    ISSN: 1573-1634
    Keywords: Stability ; linear stability analysis ; miscible displacement ; aspect ratio ; mobility control ; dispersion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract Viscous fingering and gravity tonguing are the consequences of an unstable miscible displacement. Chang and Slattery (1986) performed a linear stability analysis for a miscible displacement considering only the effect of viscosity. Here the effect of gravity is included as well for either a step change or a graduated change in concentration at the injection face during a downward, vertical displacement. If both the mobility ratio and the density ratio are favorable (the viscosity of the displacing fluid is greater than the viscosity of the displaced fluid and, for a downward vertical displacement, the density of the displacing fluid is less than the density of the displaced fluid), the displacement will be stable. If either the mobility ratio or the density ratio is unfavorable, instabilities can form at the injection boundary as the result of infinitesimal perturbations. But if the concentration is changed sufficiently slowly with time at the entrance to the system, the displacement can be stabilized, even if both the mobility ratio and the density ratio are unfavorable. A displacement is more likely to be stable as the aspect ratio (ratio of thickness to width, which is assumed to be less than one) is increased. Commonly the laboratory tests supporting a field trial use nearly the same fluids, porous media, and displacement rates as the field trial they are intended to support. For the laboratory test, the aspect ratio may be the order of one; for the field trial, it may be two orders of magnitude smaller. This means that a laboratory test could indicate that a displacement was stable, while an unstable displacement may be observed in the field.
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    Transport in porous media 3 (1988), S. 591-618 
    ISSN: 1573-1634
    Keywords: Polymer flooding ; viscous fingering ; multiphase flow ; dispersion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract The concept of improving oil recovery through polymer flooding is analysed. It is shown that while the injection of a polymer solution improves reservoir conformance, this beneficial effect ceases as soon as one attempts to push the polymer solution with water. Once water injection begins, the water quickly passes through the polymer creating a path along which all future injected water flows. Thus, the volume of the polymer slug is important to the process and an efficient recovery would require that the vast majority of the reservoir be flooded by polymer. It is also shown that the concept of grading a polymer slug to match the mobilities of the fluids at the leading and trailing edges of a polymer slug does not work in a petroleum reservoir. While this process can supply some additional stability to the slug, it is shown that for the purposes of enhanced oil recovery this additional stability is not great enough to be of any practical use. It is found that in this case the instability has simply been hidden in the interior of the slug and causes the same sort of instability to occur as was the case for the uniform slug.
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    Transport in porous media 32 (1998), S. 97-116 
    ISSN: 1573-1634
    Keywords: dispersion ; anomalous diffusion ; Taylor dispersion ; roughness ; self-affine
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract Tracer dispersion is studied in an open crack where the two rough crack faces have been translated with respect to each other. The different dispersion regimes encountered in rough-wall Hele-Shaw cell are first introduced, and the geometric dispersion regime in the case of self-affine crack surfaces is treated in detail through perturbation analysis. It is shown that a line of tracer is progressively wrinkled into a self-affine curve with an exponent equal to that of the crack surface. This leads to a global dispersion coefficient which depends on the distance from the tracer inlet, but which is still proportional to the mean advection velocity. Besides, the tracer front is subjected to a local dispersion (as could be revealed by point measurements or echo experiments) very different from the global one. The expression of this anomalous local dispersion coefficient is also obtained.
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    Transport in porous media 32 (1998), S. 187-198 
    ISSN: 1573-1634
    Keywords: diffusion ; dispersion ; miscible ; automaton
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract A thermodynamic lattice gas (automaton) model is used to simulate dispersion in porous media. Simulations are constructed at two distinctly different scales, the pore scale at which capillary models are constructed and large scale or Darcy scale at which probabilistic collision rules are introduced. Both models allow for macroscopic (pore scale) phase separation. The pore scale models clearly show the effect of pore structure on dispersion. The large scale (mega scale) simulations indicate that when the pressure difference between the displacing phase and displaced phase is properly chosen (representing the average pressure gradient between the phases). The simulation results are consistent with both theoretical predictions and experimental observations.
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    ISSN: 1573-1634
    Keywords: dispersion ; reaction ; perturbation theory ; stochastic modeling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract We carry out a stochastic-perturbation analysis of a one-dimensional convection–dispersion-reaction equation for reversible first-order reactions. The Damköhler number, Da, is distributed randomly from a distribution that has an exponentially decaying correlation function, controlled by a correlation length, ξ. Zeroth- and first-order approximations of the dispersion coefficient, D are computed from moments of the residence-time distribution obtained by solving a one-dimensional network model, in which each unit of the network represents a Darcy-level transport unit, and the solution of the transfer function in zeroth- and first-order approximations of the transport equation. In the zeroth-order approximation, the dispersion coefficient is calculated using the convection–dispersion-reaction equation with constant parameters, that is, perturbation corrections to the local equation are ignored. This zeroth-order dispersion coefficient is a linear function of the variance of the Damköhler number, 〈(ΔDa)2〉. A similar result was reported in a two-dimensional network simulation. The zeroth-order approximation does not give accurate predictions of mixing or spreading of a plume when Damköhler numbers, Da ≪ 1 and its variance, 〈(ΔDa)2〉 〉 0.25 〈Da2〉. On the other hand, the first-order theory leads to a dispersion coefficient that is independent of the reaction parameters and to equations that do accurately predict mixing and spreading for Damköhler numbers and variances in the range √〈(ΔDa)2〉/〈Da〉≤0.3
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    Transport in porous media 36 (1999), S. 307-339 
    ISSN: 1573-1634
    Keywords: dispersion ; chromatography ; porous media ; adsorption ; homogenization ; multiple scales expansions.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract This paper is devoted to the computation of effective equations for the transport of a solute in a chromatograph. We focus our attention on models that retain dispersion effects. A chromatograph is a biporous periodic heterogeneous medium, made up of macropores, and of small porous adsorbing crystals that have a retention effect on the solute. We use the method of multiple scales expansions. Various macroscopic behaviours appear, according to the respective orders of magnitude of the dimensionless characteristic parameters: Peclet number in the macropores, ratio of the characteristic time of diffusion in the macropores to the characteristic time of diffusion in the crystals, adsorption coefficient. Dispersion occurs for a Peclet number of order ε−1. We then discuss the effective behaviour of the solute, with respect to the orders of magnitude of the other characteristic parameters. To our knowledge, most of the models are new. Our modelling is not restricted to chromatographs. It applies to various situations of physic and chemical engineering: fixed bed reactors, catalytic cracking, ground water for instance.
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  • 36
    ISSN: 1573-1634
    Keywords: experiment ; aperiodic heterogeneity ; dispersion ; stochastic modeling.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract An electrochemical technique was used to measure concentration distributions in an aperiodic heterogeneous model for comparison with a stochastic transport theory. Four identical columns, each filled with a homogeneous distribution of glass beads, were threaded together to create a single model with aperiodic heterogeneity. The layers in the model were arranged in different ways providing 24 realizations of the permeability distribution. Comparisons between experimental moment data and moments of simulated mean concentration distributions showed that the model was not able to accurately predict experimentally observed mixing behavior.
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    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Developments of metallic materials in view of their use for chemical plants. The demands placed on materials of construction for chemical plants are becoming more and more stringent due to the steady increase in mechanical, thermal, and chemical loading. Molten metallurgical improvements, alloying steps, new methods of plastic deformation and heat treatment, and facilitation of workability are implemented in attempts to optimize the properties of construction materials and to achieve better adaptation to the service conditions. Progress achieved by research and developments during recent years in the above mentioned field is apparent in practical applications of some groups of materials which are important for construction of apparatus; these are high-strength fine grained steels, high-alloyed ferritic and austenitic stainless steels, as well as duplex steels. Moreover, the improvements - especially in corrosion restistance - are considered which can be obtained by special melting techniques and new fabrication processes. In addition, the advantages of electroslag remelting (ESR) and powdermetallurgical fabrication of semi-finished products of corrosion resistant alloys and the possibilities of hotisostaticpressing (HIP) of structural components are discussed.
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    Chemie Ingenieur Technik - CIT 54 (1982), S. 119-129 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Solvent extraction (SX). SX is widely used to separate metals from diluted leaching liquors, wastes, and effluents. The composition of the organic phase has great influence in this type of extraction with chemical reaction. Some trends and rules can be given. Another major problem is the aqueous phase. A systematic study is undertaken to up-date the parameters which are changing with aqueous phase composition. Step-by-step development of a process is shown.
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: Production of petrol from coal and natural gas. This article assumes an adequate knowledge of the Fischer-Tropsch process in its original form and as its modern variant, the Synthol process, and adopts the view that coal hydrogenation will only become implementable on an industrial scale in the early 1990. In detail, it considers the integration of the Mobil MTG process in the proven area of methanol production; operation of pilot plant has shown that this process is indeed suitable for industrial scale operation. The production of methanol from natural gas and coal is discussed, as is the subsequent conversion of methanol to petrol; emphasis is placed on the best possible integration of all process plant. Apart from the conventional steam reforming route for methanol production from natural gas, the alternative approach of combing a steam reforming plant with an autothermal cleavage step is also considered; the latter leads to a significant increase in efficiency and a reduction in investment costs. It is also shown for coal as raw material that simultaneous generation of petrol and SNG has considerable advantages of a thermal and financial nature. The principal process steps are described after the manner of keywords and the product costs are presented as functions of the various raw material costs.
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    Chemie Ingenieur Technik - CIT 54 (1982), S. 153-155 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: Present tendency in rectification: energy economizing. Rectification columns are the greatest consumers of energy in many chemical plants. Decreasing their energy consumption has been a long term aim in process engineering. These considerations have culminated, for example, in the splitting of a separation between two columns operating at different pressures to make an energy match feasible, the application of heat pumps, of intermediate evaporators and condensers, and also the joint execution of different separations in one column with several feeds and side streams. These ideas were formerly often thwarted by high investment costs and (supposed) reduced flexibility; in recent years, however, the design of complex plants with extensive energy matching has become commonplace. A prerequisite is the feasibility of calculating sufficiently exactly the necessary separation units; moreover, there is also a need for efficient column intervals and heat exchangers which can operate with small pressure drops and modest temperature gradients. A general energy-saving strategy also leads to process modifications in other separation techniques such as liquid-liquid extraction.
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    Keywords: Chemistry ; Polymer and Materials Science
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  • 43
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    Keywords: Destillation ; Gleichgewichts-Flüssigphasenreaktion ; Ionenaustauscher ; Katalyse ; Chemistry ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    ISSN: 0009-286X
    Keywords: Blasensäule ; Kaskaden-Abstromreaktor ; Absorption ; Desorption ; Chemistry ; Polymer and Materials Science
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    Keywords: Dispersions-Modelle ; Schüttungen ; Temperaturprofile ; Einzelpartikel-Modell ; Einphasen-Modell ; Zweiphasen-Modell ; Festbettreaktor ; Chemistry ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 46
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    Keywords: Abwasser ; Kläranlage ; Belebungsbecken ; Belebungsgraben ; Belebungssystem ; Belüftung ; Strahldüse ; Sauerstoff-Eintrag ; Schlammablagerungen ; Chemistry ; Polymer and Materials Science
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    ISSN: 0009-286X
    Keywords: Airlift-Schlaufenreaktor ; Flüssigkeitsumlauf ; Fermentation ; Zellwachstum ; Stoffwechsel ; Chemistry ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    Keywords: Wärmeübergang ; Schmelzen ; Sublimieren ; Filmsieden ; freie Konvektion ; Strömung ; Chemistry ; Polymer and Materials Science
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    Keywords: Strahlmischer ; Umlaufhäufigkeit ; Mischzeit ; Chemistry ; Polymer and Materials Science
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    Keywords: Wärmeleitfähigkeit ; Böden ; Temperatur-Abhängigkeit ; Chemistry ; Polymer and Materials Science
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    Chemie Ingenieur Technik - CIT 54 (1982), S. 181-181 
    ISSN: 0009-286X
    Keywords: Prozeßüberwachung ; Sicherheitstechnik ; Chemistry ; Polymer and Materials Science
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    Chemie Ingenieur Technik - CIT 54 (1982), S. 185-185 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Chemie Ingenieur Technik - CIT 54 (1982), S. 182-185 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Chemie Ingenieur Technik - CIT 54 (1982), S. 202-202 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Keywords: Chemistry ; Polymer and Materials Science
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    Chemie Ingenieur Technik - CIT 51 (1979), S. 1184-1190 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Chemie Ingenieur Technik - CIT 51 (1979), S. 1213-1215 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Chemie Ingenieur Technik - CIT 51 (1979), S. 1241-1241 
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    Keywords: Ultrafiltration ; konzentrationsabhängige Stoffwerte ; makromolekulare Stoffe ; Konzentrationspolarisation ; Chemistry ; Polymer and Materials Science
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    Keywords: Adsorption ; Mehrkomponentengleichgewicht ; Phasengleichgewicht ; Langmuir-Gleichung ; Chemistry ; Polymer and Materials Science
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    Chemie Ingenieur Technik - CIT 51 (1979), S. 1255-1255 
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    Keywords: Tropfenabsceidung ; Lamellenabsceider ; Chemistry ; Polymer and Materials Science
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 67
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    Chemie Ingenieur Technik - CIT 52 (1980), S. 12-19 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Ruhrchemie/Ruhrkohle variant of the Texaco coal gasification process - a status report. In pilot operation since January 1978, the Ruhrkohle/Ruhrchemie variant of the Texaco coal gasification process has produced a total of 20 million mN3 of synthesis gas having an average composition of 46% CO, 34% H2, 19% CO2, 0.3% H2S, 0.6% N2, and 0.1% CH4 from ca. 12 000 tonnes of coal. As the first of the „second generation“ coal gasification processes, the Texaco process has proved itself capable of gasifying pulverized coal of all grades at high temperatures and pressures. The next goal is an increase in capacity from that of the demonstration plant at Oberhausen-Holten (12 000 mN3/h) to ca. 100 000 mN3/h.
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    Keywords: Chemistry ; Polymer and Materials Science
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  • 69
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 70
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    Chemie Ingenieur Technik - CIT 52 (1980), S. 75-75 
    ISSN: 0009-286X
    Keywords: Tröpfchen-Abscheidung ; Filterkerzen ; Glasfritten ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 71
    ISSN: 0009-286X
    Keywords: Blasengrößenverteilung ; Phasengrenzfläche ; Gasgehalt ; Stoffübergang ; Airlift-Fermenter ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 72
    ISSN: 0009-286X
    Keywords: Extraktion ; Verweilzeit-Verteilung ; Vermischung ; pulsierte Siebbodenkolonne ; Fluiddynamik ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 73
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    Chemie Ingenieur Technik - CIT 52 (1980), S. 87-87 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
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  • 74
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    Chemie Ingenieur Technik - CIT 52 (1980), S. 98-98 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 75
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Explosion hazard analysis of inflammable gas released spontaneously into the atmosphere. The processes of flash evaporation, atmospheric vapour cloud formation ignition and explosion after the bursting of vessels containing liquefied gas have been studied by model experiments with propylene heated up to 70°C and pressurized to 60 bar. The experiments have shown that a blast wave with considerable peak pressure in the vicinity of the vessel is produced already by flash expansion of the propylene. The experimentally determined decrease of peak pressure with growing distance could be scaled up to vessels of arbitrary size and different propylene temperatures. Scaling laws could be established as well for the calculation of peak pressure and positive pressure duration of the deflagration wave as functions of released mass and distance. The experiments have not revealed any evidence of a detonation process even when the cloud was ignited by an explosive charge.
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  • 76
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 77
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    Chemie Ingenieur Technik - CIT 52 (1980), S. 170-171 
    ISSN: 0009-286X
    Keywords: Füllkörperkolonne ; Stoffübergang ; Hydraulik ; Extraktion ; Grenzbelastung ; Hold-up ; Tropfendurchmesser ; Phasengrenzfläche ; Stoffübergangskoeffizient ; Rohrkolonne ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 78
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    Chemie Ingenieur Technik - CIT 52 (1980), S. 178-179 
    ISSN: 0009-286X
    Keywords: Dekantierzentrifugen ; Versuchsbedingungen ; Scaleup ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Additional Material: 3 Ill.
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  • 79
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    Chemie Ingenieur Technik - CIT 52 (1980), S. 199-209 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Heat and mass transfer in fluidized beds. Methods of calculation are presented which enable reasonably accurate prediction of heat and mass transfer coefficients in fluidized beds. Some well established equations already given in the literature could be used for estimating the range of existence of the fluidized bed and for calculating maximum fluidization velocities, bed expansion, and particle-to-fluid heat and mass transfer. However, a new model had to be developed for the wall-to-bed heat transfer from solid surfaces immersed in fluidized beds. This model makes use of some basic ideas adopted from the kinetic theory of gases in order to describe the mechanism of energy transfer through the moving particles. Predictions with this new model are in good agreement with most of the experimental observations, particularly regarding the effects of particle diameter, temperature, pressure, physical properties of gas and particles, and gas velocity.
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  • 80
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    Chemie Ingenieur Technik - CIT 52 (1980), S. 244-246 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 81
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    Chemie Ingenieur Technik - CIT 52 (1980), S. 249-251 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 82
    ISSN: 0009-286X
    Keywords: Rühren ; Reaktor ; Dispergieren ; Leistungscharakteristik ; Suspendiercharakteristik ; Überflutungscharakteristik ; gerührte ; begaste Suspensionsreaktoren ; Leistungsbedarf ; Dreiphasen-system ; Dreiphasenreaktor ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 83
    ISSN: 0009-286X
    Keywords: Airlift-Schlaufenreaktor ; Gasgehalt ; Stoffübergang ; Längsvermischung ; Mischzeit ; Umlaufgeschwindigkeit ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 84
    ISSN: 0009-286X
    Keywords: Begasen ; Belüften ; selbstansaugender Rührer ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 85
    ISSN: 0009-286X
    Keywords: Schlammentwässerung ; Schlammcharakterisierung ; Flockungsmittel ; Flockungsreaktion ; Flockungsreaktoren ; Entwässerungsmaschinen ; Siebtrommeln ; Kammerfilterpressen ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 86
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A clean environment - responsibility of society. The need for environmental protection was previously beyond question and is more so than ever today. Discussions or controversy centers on the extent of measures needed to protect our environment. Such discussion is conducted by pressure groups while decisions are made by society for environmental protection is a function of society. Whereas the aversion of danger was formerly the main consideration prevention is becoming increasingly important. The potential dangers have been essentially eliminated. It is our present task to ensure living space for future generations and to preserve space for tomorrow's industry. This is possible only with the aid of technology, provided that technologists are prepared to adopt new approaches. We must do away with a mere technology of reduction, i. e. peripheral environmental protection. Tomorrow's task is integrated invironmental protection.
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  • 87
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Clean air - technical possibilities and economic consequences. Starting from the historical development of measures for maintaining clean air in the course of the industrial revolution, the article outlines advances in dust removal which have been accomplished in close, trusting cooperation between legislature, experts and plant operators. The interactions between mankind, technically modified and natural environment, and atmosphere, which have arisen as a consequence of the growth in population, are described and an attempt is made to assign the principal contaminants in the atmosphere to their causers on a global and a national basis. The relationship between rational use of energy and clean air maintenance becomes clear. Additive and integrated air purification procedures are explained with the aid of environmental protection measures adopted in coal-fired power plant and the costs of excessively low emission level demands pointed out. Examples of gas purification plant in the cellulose industry and the printing trade illustrate the possibilities offered by recycling.
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  • 88
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Clean water - technical possibilities and economic consequences. Water pollution by industrial effluent is becoming more and more of a political warcry which creates a fear of technology - precisely that technology which is largely responsible for the present quality of life. It has so far gone largely unrecognized by the public that industry and municipal authorities have accomplished a great amount in the area of waste water purification. The versatile techniques developed in recent years are summarized, and biological purification is treated in somewhat greater detail. Annual investment in waste water treatment runs at several thousand million DM, and represent a considerable financial burden on industry and municipal authorities. The thesis that economic considerations should play no role in environmental protection is not acceptable in that unqualified form, and would mean that German industry would no longer be competitive in an international arena. Ecological demands cannot be separated from economic considerations. All participants will have to make some compromises on our way to our desired goal of a flourishing economy in an almost intact environment.
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  • 89
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    Chemie Ingenieur Technik - CIT 54 (1982), S. 303-313 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Assessment, acquisition, and assembly of pipe components. Pipe technology accounts for ca. 30 to 35% of the planning of chemical plant and refineries. The reason for this high proportion lies in the numerous possibilities of variation. Each part must be defined, assessed and executed. The programme system developed consists of an assembly of several individual programmes which utilize available data. The overall procedure, from specification to assembly, is performed or supported by this programme system. The “general text system” (ATS) stores all pipe texts and pipe classes in several languages. With the aid of the “Lurgi piping macro-system” (LUROMAK) the piping components are processed on the basis of flow charts, assembly plans and isometric drawings. The materials determined are transformed into buying information by the “execution system” (DISPO). Registration of material entering and leaving stores in the “assembly organization system” (MOS) permits work preparation for assembly on the basis of the resulting stocks. It is also possible to assess the progress of assembly and to prepare costing information. The continuous processing of piping is permitted by a systematic standardization and classification, accomplished in particular by uniform definition of piping components in the ATS programme system.
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  • 90
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    Chemie Ingenieur Technik - CIT 54 (1982), S. 351-362 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Gas Separation with membranes. Gas separation with membranes has already been tested in numerous fields of application, e. g. uranium enrichment or H2 separation. In many of these processes the mass transfer units, so-called permeators, have to be connected in tandem in order to achieve high concentrations. A most economical operating method provides for each case an optimization of the cascades with regard to the membrane materials, construction and design of module. By utilization of the concentration gradient along the membrane a new process development has been accomplished - the continuously operating membrane rectification unit. Investment and operating costs can be reduced considerably for a number of separating processes by combining a membrane rectification unit with a conventional recycling cascade. However, the new procedure requires that the specifications for the module construction, flow design, and membrane properties be reconsidered.
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    Chemie Ingenieur Technik - CIT 54 (1982), S. 313-328 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Design of single substance pressure jets. The single substance pressure jet most commonly used produces liquid lamellae. These then degenerate to drops in the surrounding gas as a consequence of aerodynamic wave formation. The size of the droplets generated decreases according to Δp-1/3. Calculation of droplet size can be unified by defining a lamella number. The lamella number expresses the drop in lamella thickness with increasing jet distance relative to the diameter of the jet. The smaller the geometry-dependent lamella number, the smaller the droplets relative to the diameter of the jet. The hollow cone jet produces the smallest lamella number and thus generates the smallest droplets. However, the liquid in the twist chamber of hollow conical jets at higher viscosities are decelerated much slower than in fan-shaped jets. Measuring methods for determining the principal characteristics of jets are demonstrated for hollow conical and fanshaped jets. Turbulence jets, such as solid conical jets, produce droplets some 5 to 10 times larger than those in hollow conical jets at the same jet diameter and pressure. Droplet formation occurs mainly by turbulence in the jet. It is important to minimize the danger of blockage when operating jets. For this reason, preference is often given to that jet which gives the smallest droplet size for a given pressure and a given narrowest orifice diameter. This is particularly significant at droplet sizes d 〈 20 μm. Comparison and choice of jets is accomplished with the aid of a diagram representing the relative droplet size d32/D in terms of the jet pressure number Δp = ΔpD/σ and the Ohnesorge number. However, a characteristic field representation containing only characteristic quantities formed with the characteristic droplet size, apart from the relative droplet size, is suitable for determining the jet dimensions.
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    Chemie Ingenieur Technik - CIT 53 (1981), S. 127-127 
    ISSN: 0009-286X
    Keywords: Isostatisches Heißpressen ; SiC ; Gefüge ; Dichte ; Porosität ; Festigkeit ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 93
    ISSN: 0009-286X
    Keywords: NOx-Bildung ; Brennstoffstickstoff ; Stufenverbrennung ; Stufenmischbrenner ; Feuerungen ; Umsatzgrade zu NO ; Stickoxide ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    Chemie Ingenieur Technik - CIT 52 (1980), S. 451-453 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 95
    ISSN: 0009-286X
    Keywords: Rauchgasentschwefelung ; NOx-Reduktion ; Adsorption ; heterogene Katalyse ; Aktivkoks ; Schwefeldioxid ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 96
    ISSN: 0009-286X
    Keywords: Trennkurve ; Differenzenformel ; Fehleranalyse ; Meßwertausgleich ; Fehlerabschätzung ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    Chemie Ingenieur Technik - CIT 52 (1980), S. 472-473 
    ISSN: 0009-286X
    Keywords: Sicherheit ; Explosionsschutz ; Sauerstoff ; Inertgas ; Sp¨lung ; Behälter ; Druckwechsel ; Durchströmung ; Schiittgüt ; Eintrag ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    Chemie Ingenieur Technik - CIT 52 (1980), S. 504-515 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Methanization of carbon monoxide-rich gases for energy-transport. The partners of the NFE project (Nukleare Fernenergie, Remote nuclear energy) - Kernforschungsanlage Jülich GmbH (Germany) and Rheinische Braunkohlenwerke AG, Köln (Germany) - in collaboration with Haldor Topsøe A/S, Copenhagen (Denmark), have investigated various problems of the methanization of synthesis gases rich in carbon monoxide. Preliminary results obtained from trial operations with the pilot-scale methanization plant ADAM I at KFR Jülich and from the catalyst-development project at Haldor Topsøe A/S are reported. A detailed account is given of the catalyst investigations carried out on the Haldor Topsøe pilot plant for the further development of the TREMP process for SNG manufacture and of the complementary catalyst investigation in the NFE project at the Union Rheinische Braunkohlen Kraftstoff AG and the Kernforschungsanlage Jülich GmbH for the optimization of the methanization process in the remote energy system EVA-ADAM. In the pilot plant ADAM I, a three-stage methanization process with product gas recycling and maximum temperature of 600 °C utilizing synthesis gas from methane vapour reforming (EVA) has been demonstrated for the first time. In further experiments to be carried out with ADAM I the influence of operating irregularities on the behaviour of the methanization plant and the dynamics of the remote energy system will be investigated, data for the preparation of mathematical models collected, new components tested, and the process of methanization optimized.
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    Chemie Ingenieur Technik - CIT 52 (1980), S. 520-522 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 100
    ISSN: 0009-286X
    Keywords: Chargenkristallisation ; Kühlungskristallisation ; Leitrohr-Rührwerkskristallisator ; Korngrößenverteilung ; mittlerer Korndurchmesser ; Kornform ; sekundäre Keimbildung ; Maßstabsvergrößerung ; Kaliumchlorid ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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