ALBERT

Description: In order to better understand the role of fluids during subduction and subsequent exhumation, we have investigated whole-rock and mineral chemistry (major and trace elements) and Li, B as well as O, Sr, Nd, Pb isotopes on selected continuous drill-core profiles through contrasting lithological boundaries from the Chinese Continental Scientific Drilling Program (CCSD) in Sulu, China. Four carefully selected sample sets have been chosen to investigate geochemical changes as a result of fluid mobilization during dehydration, peak metamorphism, and exhumation of deeply subducted continental crust. Our data reveal that while O and Sr-Nd-Pb isotopic compositions remain more or less unchanged, significant Li and/or B isotope fractionations occur between different lithologies that are in close contact during various metamorphic stages. Samples that are supposed to represent prograde dehydration as indicated by veins formed at high pressures (HP) are characterized by element patterns of highly fluid-mobile elements in the veins that are complementary to those of the host eclogite. A second sample set represents a UHP metamorphic crustal eclogite that is separated from a garnet peridotite by a thin transitional interface. Garnet peridotite and eclogite are characterized by a 〉10% difference in MgO, which, together with the presence of abundant hydroxyl-bearing minerals and compositionally different clinopyroxene grains demonstrate that both rocks have been derived from different sources that have been tectonically juxtaposed during subduction, and that hydrous silicate-rich fluids have been added from the subducting slab to the mantle. Two additional sample sets, comprising retrograde amphibolite and relatively fresh eclogite, demonstrate that besides external fluids, internal fluids can be responsible for the formation of amphibolite. Li and B concentrations and isotopic compositions point to losses and isotopic fractionation during progressive dehydration. On the other hand, fluids with isotopically heavier Li and B are added during retrogression. On a small scale, mantle-derived rocks may be significantly metasomatized by fluids derived from the subducted slab. Our study indicates that during high-grade metamorphism, Li and B may show different patterns of enrichment and of isotopic fractionation.

Description: The Itajaí Basin located in the southern border of the Luís Alves Microplate is considered as a peripheral foreland basin related to the Dom Feliciano Belt. It presents an excellent record of the Ediacaran period, and its upper parts display the best Brazilian example of Precambrian turbiditic deposits. The basal succession of Itajaí Group is represented by sandstones and conglomerates (Baú Formation) deposited in alluvial and deltaic-fan systems. The marine upper sequences correspond to the Ribeirão Carvalho (channelized and non-channelized proximal silty-argillaceous rhythmic turbidites), Ribeirão Neisse (arkosic sandstones and siltites), and Ribeirão do Bode (distal silty turbidites) formations. The Apiúna Formation felsic volcanic rocks crosscut the sedimentary succession. The Cambrian Subida leucosyenogranite represents the last felsic magmatic activity to affect the Itajaí Basin. The Brusque Group and the Florianópolis Batholith are proposed as source areas for the sediments of the upper sequence. For the lower continental units the source areas are the Santa Catarina, São Miguel and Camboriú complexes. The lack of any oceanic crust in the Itajaí Basin suggests that the marine units were deposited in a restricted, internal sea. The sedimentation started around 600 Ma and ended before 560 Ma as indicated by the emplacement of rhyolitic domes. The Itajaí Basin is temporally and tectonically correlated with the Camaquã Basin in Rio Grande do Sul and the Arroyo del Soldado/Piriápolis Basin in Uruguay. It also has several tectono-sedimentary characteristics in common with the African-equivalent Nama Basin.

Description: Most studies dealing with material properties of sandstones are based on a small data set. The present study utilizes petrographical and petrophysical data from 22 selected sandstones and ~300 sandstones from the literature to estimate/predict the material and weathering behaviour of characteristic sandstones. Composition and fabric properties were determined from detailed thin section analyses. Statistical methods applied consist of data distributions with whisker plots and linear regression with confidence regions for the petrophysical and weathering properties. To identify similarities between individual sandstones and to define groups of specific sandstone types, principal component and cluster analyses were applied. The results confirm an interaction between the composition, depositional environment, stratigraphic association and diagenesis, which leads to a particular material behaviour of sandstones. Three different types of pore radii distributions are observed, whereby each is derived from different pore space modifications during diagenesis and is associated with specific sandstone types: (1) bimodal with a maximum in capillary and micropores, (2) unimodal unequal with a maximum in smaller capillary pores and (3) unimodal equable with a maximum in larger capillary pores. Each distribution shows specific dependencies to water absorption, salt loading and hygric dilatation. The strength–porosity relationship shows dependence on the content of unstable lithic fragments, grain contact and type of pore radii distribution, cementation and degree of alteration. Sandstones showing a maximum of capillary pores and micropores (bimodal) exhibit a distinct hygric dilatation and low salt resistance. These sandstones are highly immature sublitharenites–litharenites, characterized by altered unstable rock fragments, which show pointed-elongated grain contacts, and some pseudomatrix. Quartz arenites and sublitharenites–litharenites which are strongly compacted and cemented, show unimodal unequal pore radii distributions, low porosity, high strength and a high salt resistance. The presence of swellable clay minerals in sublitharenites–litharenites leads to a medium to high hygric dilatation, whereas quartz arenites show little hygric dilatation. Sandstones with unimodal equal pore radii distribution mostly belong to weakly compacted and cemented mature quartz arenites. These are characterized by high water absorption and high porosity, low to medium strength and a low salt resistance. The data compiled in this study are used to create a sandstone quality catalogue. Since material properties are dependent on many different parameters of influence, the transition between different lithotypes is fluent.

Description: The lattice-preferred orientation (LPOs) of two late-Variscan granitoids, the Meissen monzonite and the Podlesí dyke granite, were determined from high-resolution time-of-flight neutron diffraction patterns gained at the diffractometer SKAT in Dubna, Russia. The results demonstrate that the method is suitable for the LPO analysis of polyphase, relatively coarse-grained (0.1–6 mm) rocks. The Meissen monzonite has a prominent shape-preferred orientation (SPO) of the non-equidimensional minerals feldspar, mica and amphibole, whereas SPO of the Podlesí granite is unapparent at the hand-specimen scale. The neutron diffraction data revealed distinct LPOs in both granitoids. The LPO of the non-equidimensional minerals feldspar, mica and amphibole developed mainly during magmatic flow. In the case of the Meissen monzonite, the magmatic flow was superimposed by regional shear tectonics, which, however, had no significant effect on the LPOs. In both samples, quartz shows a weak but distinct LPO, which is atypical for plastic deformation and different in the syn-kinematic Meissen monzonite and the post-kinematic Podlesí granite. We suggest that, first of all, the quartz LPO of the Meissen monzonite is the result of oriented growth in an anisotropic stress field. The quartz LPO of the Podlesí granite, which more or less resembles a deformational LPO in the flattening field of the local strain field, developed during magmatic flow, whereby the rhombohedral faces of the quartz crystals adhered to the (010) faces of aligned albite and to the (001) faces of zinnwaldite. Due to shape anisotropy of their attachments, the quartz crystals were passively aligned by magmatic flow. Thus, magmatic flow and oriented crystal growth are the major LPO-forming processes in both granitoids. For the Meissen monzonite, the solid-state flow was too weak to cause significant crystallographic re-orientation of the minerals aligned by magmatic flow. Finally, the significance of our results for the evaluation of the regional tectonic environment during magma emplacement is discussed. The discussion on the regional implications of the more methodologically oriented results provides the basis for future, more regionally aimed studies in view of the fabric characteristics of such plutons and their developing mechanisms.

Description: The Eastern Sierras Pampeanas were structured by three main events: the Ediacaran to early Cambrian (580–510 Ma) Pampean, the late Cambrian–Ordovician (500–440 Ma) Famatinian and the Devonian-Carboniferous (400–350 Ma) Achalian orogenies. Geochronological and Sm–Nd isotopic evidence combined with petrological and structural features allow to speculate for a major rift event (Ediacaran) dividing into two Mesoproterozoic major crustal blocks (source of the Grenvillian age peaks in the metaclastic rocks).This event would be coeval with the development of arc magmatism along the eastern margin of the eastern block. Closure of this eastern margin led to a Cambrian active margin (Sierra Norte arc) along the western margin of the eastern block in which magmatism reworked the same crustal block. Consumption of a ridge segment (input of OIB signature mafic magmas) which controlled granulite-facies metamorphism led to a final collision (Pampean orogeny) with the western Mesoprotrozoic block. Sm–Nd results for the metamorphic basement suggest that the TDM age interval of 1.8–1.7 Ga, which is associated with the less radiogenic values of εNd(540) (−6 to −8), can be considered as the mean average crustal composition for the Eastern Sierras Pampeanas. Increasing metamorphic grade in rocks with similar detrital sources and metamorphic ages like in the Sierras de Córdoba is associated with a younger TDM age and a more positive εNd(540) value. Pampean pre-540 Ma granitoids form two clusters, one with TDM ages between 2.0 and 1.75 Ga and another between 1.6 and 1.5 Ga. Pampean post-540 Ma granitoids exhibit more homogenous TDM ages ranging from 2.0 to 1.75 Ga. Ordovician re-activation of active margin along the western part of the block that collided in the Cambrian led to arc magmatism (Famatinian orogeny) and related ensialic back-arc basin in which high-grade metamorphism is related to mid-crustal felsic plutonism and mafic magmatism with significant contamination of continental crust. TDM values for the Ordovician Famatinian granitoids define a main interval of 1.8–1.6, except for the Ordovician TTG suites of the Sierras de Córdoba, which show younger TDM ages ranging from 1.3 to 1.0 Ga. In Devonian times (Achalian orogeny), a new subduction regime installed west of the Eastern Sierras Pampeanas. Devonian magmatism in the Sierras exhibit process of mixing/assimilation of depleted mantle signature melts and continental crust. Achalian magmatism exhibits more radiogenic εNd(540) values that range between 0.5 and −4 and TDM ages younger than 1.3 Ga. In pre-Devonian times, crustal reworking is dominant, whereas processes during Devonian times involved different geochemical and isotopic signatures that reflect a major input of juvenile magmatism.

Description: The expansion processes that develop in building stones upon changes of moisture content may be an important contributing factor for their deteriorations. Until recently, few data could be found in the literature concerning this parameter and weathering processes. Moreover, the processes that may be responsible for the moisture related expansion of natural building stones are not yet completely understood. To further elucidate this process, extensive mineralogical, petrophysical and fabric investigations were performed on eight German sandstones in order to obtain more information regarding the weathering process and its dependence on the rock fabric. The analysed sandstones show a wide range of pore size distributions and porosities. A positive correlation with the fabric and the pore space can be found for all studied petrophysical parameters. The intensity of the expansion and related swelling pressure cannot be attributed only to the swelling of clay minerals. The investigations suggest that the micropores and the resulting disjoining pressure during wet/dry cycles also play an important role. The results obtained suggest that the mechanism is related to the presence of liquid water within the porous material.

Description: The profitable production of dimension stone mainly depends on the extractable block size. The regularity and volume of the blocks are of critical importance, and are controlled by the three-dimensional pattern of the discontinuity system. Therefore, optimization of block size has to be the aim when quarrying for natural stone. This is mainly connected to the quantification of joints and fractures, i.e., their spacing and orientation. The problem of finding unfractured blocks within arbitrarily oriented and distributed planes can be solved effectively by a numerical algorithm. The main effects of joint orientations on block sizes and shapes will be presented in this article. Quantification of unfractured blocks with the aim of optimization is illustrated by detailed studies on several quarries. The algorithm used in this study can be applied as a powerful tool in the planning of a quarry and the future exploitation of dimension stone. Application of the described approach is demonstrated on practical examples of quarrying natural stones, namely, sandstone, granite, rhyolite, etc. Block quarrying can be optimized by using the new 3D-BlockExpert approach. The quantification of unfractured rock masses is also shown to contribute to a more ecological protection and the sustainable use of natural resources.

Description: Damages to natural building stones induced by the action of frost are considered to be of great importance. Commonly, the frost resistance of building stones is checked by standardised freeze–thaw tests before using. Corresponding tests normally involve 30–50 freeze–thaw action cycles. In order to verify the significance of such measurements, we performed long-term tests on four selected rocks over 1,400 freeze–thaw action cycles. Additionally, numerous petrophysical parameters were analysed to compare the behaviour of rocks in the weathering tests according to the current explanatory models of stress formation by growing ice crystals in the pore space. The long-term tests yield more information about the real frost sensibility of the rocks. A clear deterioration cannot be determined in most cases until 50 weathering cycles have been completed. In the freeze–thaw tests, the samples are also stressed by changing temperature and moisture, indicating that different decay mechanisms can interfere with each other. Thus, thermohygric and moisture expansion are important damage processes.

Description: Owing to its long building history, different types of building stones comprised the construction of the Cologne Cathedral. Severe damage is observed on the different stones, e.g., sandstones, carbonate, and volcanic rocks, especially when the different stone materials neighbor the medieval “Drachenfels trachyte” from the “Siebengebirge”. The question arises, “Is the insufficient compatibility of the implemented building materials causatively related to the strong decay of the Drachenfels trachyte?” The present investigations focus on the petrography and mineralogical composition of eight different stones from the Cologne Cathedral. Petrophysical data, i.e., phase content, moisture and thermal characteristics as well as strength properties are determined and discussed in correlation to each other, showing that not only in terms of lithology great differences exist, but also the petrophysical properties strongly diverge. The ascertained parameters are discussed in view of the deterioration behavior and decay mechanisms of the different stones. To evaluate the compatibility of original, replacement and modern building materials, the properties of the investigated stones are compared to those of Drachenfels trachyte by means of constraints given in the literature. Besides optical properties, petrophysical criteria are also defined as well as strength values. It could be shown that primarily moisture properties, i.e., capillary and sorptive water uptake, water saturation, drying processes and moisture dilatation can be addressed to the deterioration processes.

Description: The range of substrates that the bone-eating marine worm Osedax is able to consume has important implications for its evolutionary history, especially its potential link to the rise of whales. Once considered a whale specialist, recent work indicates that Osedax consumes a wide range of vertebrate remains, including whale soft tissue and the bones of mammals, birds and fishes. Traces resembling those produced by living Osedax have now been recognized for the first time in Oligocene whale teeth and fish bones from deep-water strata of the Makah, Pysht and Lincoln Creek formations in western Washington State, USA. The specimens were acid etched from concretions, and details of the borehole morphology were investigated using micro-computed tomography. Together with previously published Osedax traces from this area, our results show that by Oligocene time Osedax was able to colonize the same range of vertebrate remains that it consumes today and had a similar diversity of root morphologies. This supports the view that a generalist ability to exploit vertebrate bones may be an ancestral trait of Osedax.

Description: Forests in lowland Bolivia suffer from severe deforestation caused by different types of agents and land use activities. We identify three major proximate causes of deforestation. The largest share of deforestation is attributable to the expansion of mechanized agriculture, followed by cattle ranching and small-scale agriculture. We utilize a spatially explicit multinomial logit model to analyze the determinants of each of these proximate causes of deforestation between 1992 and 2004. We substantiate the quantitative insights with a qualitative analysis of historical processes that have shaped land use patterns in the Bolivian lowlands to date. Our results suggest that the expansion of mechanized agriculture occurs mainly in response to good access to export markets, fertile soil, and intermediate rainfall conditions. Increases in small-scale agriculture are mainly associated with a humid climate, fertile soil, and proximity to local markets. Forest conversion into pastures for cattle ranching occurs mostly irrespective of environmental determinants and can mainly be explained by access to local markets. Land use restrictions, such as protected areas, seem to prevent the expansion of mechanized agriculture but have little impact on the expansion of small-scale agriculture and cattle ranching. The analysis of future deforestation trends reveals possible hotspots of future expansion for each proximate cause and specifically highlights the possible opening of new frontiers for deforestation due to mechanized agriculture. Whereas the quantitative analysis effectively elucidates the spatial patterns of recent agricultural expansion, the interpretation of long-term historic drivers reveals that the timing and quantity of forest conversion are often triggered by political interventions and historical legacies.

Description: Characeae, a family of calcifying green algae, are common in carbonate-rich freshwaters. The southwestern shoreline of Lake Ganau (Kurdistan Region, northeastern Iraq) harbors dense and thick mats of these algae (genus Chara). On the lake bottom and along the shore, carbonate sands and rocks rich in the remains of stems, branches, nodes, and whorls of Chara are deposited. These deposits show all stages of growth and degradation of characean algae, including replacement and lithification into limestone. The replacement of the fragments by fine-grained calcite preserved delicate microstructures of Chara, such as cortical walls, cell shape, inner and outer layers of the stems, and reproductive organs. Based on roundness, sorting, the degree of lithification, and preserved microstructures of the grains (fragments), three facies were recognized. The first is represented by a newly formed lime sand facies showing elongated grains, poor sorting, and reduced roundness, with pristine preservation of characean surface microstructures. The second is a weathered lime sand facies, which shows better sorting and good roundness, whereas internal structures of characean fragments are still well preserved. The third is comprised of a lithified lime sand facies (grainstone), with very well sorted and rounded grains, and poorly preserved external and internal structures of the characeans. As compared to the newly formed lime sand facies, the grainstone facies shows an increase in grain size by more than 30 %, owing to precipitation of micritic lamina of possible microbial origin. Eventually, the Characeae-derived lime sands are lithified into oolitic limestones with sparry calcite cement, forming a grainstone microfacies. The present study has important implications for the interpretation of pre-Quaternary environments, as it records all stages of the fossilization process of characean green algae and highlights the role of these algae in the formation of oolitic carbonate rocks.

Description: The Mantiqueira Province represents a series of supracrustal segments of the South-American counterpart formed during the Gondwana Supercontinent agglutination. In this crustal domain, the process of escape tectonics played a conspicuous role, generating important NE–N–S-trending lineaments. The oblique component of the motions of the colliding tectonic blocks defined the transpressional character of the main suture zones: Lancinha-Itariri, Cubatão-Arcádia-Areal, Serrinha-Rio Palmital in the Ribeira Belt and Sierra Ballena-Major Gercino in the Dom Feliciano Belt. The process as a whole lasted for ca. 60 Ma, since the initial collision phase until the lateral escape phase predominantly marked by dextral and subordinate sinistral transpressional shear zones. In the Dom Feliciano Belt, southern Brazil and Uruguay, transpressional event at 630–600 Ma is recognized and in the Ribeira Belt, despite less coevally, the transpressional event occurred between 590 and 560 Ma in its northern-central portion and between ca. 625 and 595 Ma in its central-southern portion. The kinematics of several shear zones with simultaneous movement in opposite directions at their terminations is explained by the sinuosity of these lineaments in relation to a predominantly continuous westward compression.

Description: The Sierras Pampeanas in central and north-western Argentina constitute a distinct morphotectonic feature between 27°S and 33°S. The last stage of uplift and deformation in this area are interpreted to be closely related to the Andean flat-slab subduction of the Nazca plate beneath the South American plate. K–Ar fault gouge dating and low-temperature thermochronology along two transects within the Sierra de Comechingones reveal a minimum age for the onset of brittle deformation about 340 Ma, very low exhumation rates since Late Paleozoic time, as well as a total exhumation of about 2.3 km since the Late Cretaceous. New Ar–Ar ages (7.54–1.91 Ma) of volcanic rocks from the San Luis volcanic belt support the eastward propagation of the flat-slab magmatic front, confirming the onset of flat-slab related deformation in this region at 11.2 Ma. Although low-temperature thermochronology does not clearly constrain the signal of the Andean uplift, it is understood that the current structural relief related to the Comechingones range has been achieved after the exhumation of both fault walls (circa 80–70 Ma).

Description: The Palaeogene was the most recent greenhouse period on Earth. Especially for the Late Palaeocene and Early Eocene, several superimposed short-term hyperthermal events have been described, including extremes such as the Palaeocene–Eocene Thermal Maximum. Major faunal and floral turnovers in the marine and terrestrial realms were recorded in association with these events. High-resolution palynological analysis of the early Middle Eocene maar lake sediments at Messel, near Darmstadt, Germany, provides an insight into the dynamics of a climax vegetation during the Middle Eocene greenhouse climate in a time span without significant climatic excursions. Numerical techniques like detrended correspondence analysis and wavelet analysis have been applied to recognize cyclic fluctuations and long-term trends in the vegetation through a time interval of approximately 640 kyr. Based on the numerical zoning of the pollen diagram, three phases in the development of the vegetation may be distinguished. Throughout these phases, the climax vegetation did not change substantially in qualitative composition, but a trend towards noticeably less humid conditions probably in combination with a drop of the water level in the lake may be recognized. A shift in algal population from the freshwater dinoflagellate cyst Messelodinium thielepfeifferae to a dominance of Botryococcus in the uppermost part of the core is interpreted as a response to changes in acidity and nutrient availability within the lake. Time series analyses of pollen assemblages show that variations in the Milankovitch range of eccentricity, obliquity and precession can be distinguished. In addition, fluctuations in the sub-Milankovitch range are indicated. This demonstrates that floral changes during steady depositional conditions in the Middle Eocene of Messel were controlled by orbital forcing.

Description: In the presented case study, ascomycete fungi and green algae on a marble monument were identified by comparisons of the 18S rRNA gene sequences, which were obtained from DNA either from environmental samples or from enrichment cultures. The organisms were found to be responsible for either black or green surface coverings on different areas of the monument surface. Most fungi were related to plant-inhabiting genera, corresponding to a heavy soiling of the marble surface with honeydew. Whereas green algae of the genera Stichococcus, Chloroidium and Apatococcus were found to be dominant in all samples, isolates of two additional genera were recovered only from enrichment cultures. A reference strain of Apatococcus lobatus and an isolate of Prasiolopsis sp. were investigated with respect to putative surface adhesive structures of the cell envelope. The Prasiolopsis cell walls were covered with a thin adhesive exopolysaccharide layer involved in biofilm formation.

Description: Bowing is a well-known phenomenon seen in marbles used as building veneers. This form of rock weathering occurs as a result of external factors such as temperature, humidity, the system for anchoring the marble slabs or the panel dimensions. Under the same external conditions, many factors will determine the degree of deformation including petrography, thermal properties and residual locked stresses. The usual way to solve the problem of bowed marble slabs is to replace them with other materials, such as granites, in which the deformation still exists but is less common. In this study, eight ornamental granites with different mineralogy, grain size, grain shape, porosity and fabric were tested in a laboratory to assess their susceptibility to bowing. Three slabs of granite, each cut with a different orientation, were studied under different conditions of temperature (90 and 120°C) and water saturation (dry and wet) to investigate the influence of these factors together with that of anisotropy. At 90°C, only the granite with the coarsest grain size and low porosity exhibited deformation under wet conditions. At 120°C and wet conditions, three of the granites showed evident signs of bowing. Again, the granite with the coarsest grain size was the most deformed. It was concluded that the wide grain size distribution influences microcracking more than other expected factors, such as the quartz content of the rock. Also, mineral shape-preferred orientation and porosity play an important role in the bowing of the studied granites.

Description: The emplacement of the Mesoproterozoic Götemar Pluton into Paleoproterozoic granitoid host rocks of the Transscandinavian Igneous Belt is re-examined by microfabric analysis, including cathodoluminescence microscopy. Field data on the pluton-host rock system are used to strengthen the model. The Götemar Pluton, situated on the Baltic Shield of SE Sweden, is a horizontally zoned tabular structure that was constructed by the intrusion of successive pulses of magma with different crystal/melt ratios, at an estimated crustal depth of 4–8 km. Initial pluton formation involved magma ascent along a vertical dike, which was arrested at a mechanical discontinuity within the granitoid host rocks; this led to the formation of an initial sill. Subsequent sill stacking and their constant inflation resulted in deformation and reheating of existing magma bodies, which also raised the pluton roof. This multi-stage emplacement scenario is indicated by complex dike relationships and the occurrence of several generations of quartz (Si-metasomatism). The sills were charged by different domains of a heterogeneous magma chamber with varying crystal/melt ratios. Ascent or emplacement of magma with a high crystal/melt ratio is indicated by syn-magmatic deformation of phenocrysts. Complex crystallization fabrics (e.g. oscillatory growth zoning caused by high crystal defect density, overgrowth and replacement features, resorbed and corroded crystal cores, rapakivi structure) are mostly related to processes within the main chamber, that is repeated magma mixing or water influx.

Description: Slates are internationally known as roof and façade-cladding material since prehistoric times. The methods required to mine and manufacture these dimensional stones are relatively simple in comparison to those utilized in granitic dimensional stones. This has led to a worldwide rentable commercialization of slate in the last centuries and also to the development of characteristic cultural landscapes. In Uruguay several slates are mined and used in architecture, especially as façade cladding and floor slabs. The most important slates regarding their production and utilization are the dolomitic slates. These dolomitic slates are associated with the Neoproterozoic thrust and fold belt of the Dom Feliciano belt. Representative samples have been geochemically and petrographically characterized, as well as petrophysically and petromechanically analyzed. The petrophysical and petromechanical properties were investigated in a very systematic way with respect to the new European standards, showing values comparable to those registered for internationally known slates. Detailed structural and deposit analysis were carried out in Uruguay in order to evaluate the dolomitic slate deposits. The slates are linked to calc-silicate strata in a greenschist facies volcano-sedimentary sequence and the deposits are located in the limb of a regional fold, where bedding and cleavage are parallel. The main lithotype is a layered and fine-grained dolomitic slate with a quite diverse palette of colors: light and dark green, gray, dark gray, reddish and black. The mined slate is split into slabs 0.5–2 cm thick. In the past, the average production in Uruguay was around 4,000 tons/year and a historical maximum of 13,000 tons was reached in 1993 (Oyhantçabal et al. in Z dt Ges Geowiss 158(3):417–428, 2007). The oscillations in the regional demand were the cause of several flourishing and decay cycles in the activity, but our investigation shows a considerable volume of indicated resources and therefore a very good potential.

Description: Microstructure‐based finite-element analysis with a microcracking algorithm was used to simulate an actual degradation phenomenon of marble structures, i.e., microcracking. Both microcrack initiation and crack propagation were characterized, as were their dependence on lattice preferred orientation (LPO), grain shape preferred orientation (SPO), grain size, marble composition (calcite and dolomite) and grain‐boundary fracture toughness. Two LPOs were analyzed: a random orientation distribution function and an orientation distribution function with strong directional crystalline texture generated from a March–Dollase distribution. Three SPOs were considered: equiaxed grains; elongated grains and a mixture of equiaxed and elongated grains. Three different grain sizes were considered: fine grains of order 200 μm (only calcitic marble); medium size grains of order 1 mm (calcitic and dolomitic marbles); and large grains of order 2 mm (only dolomitic marble). The fracture surface energy for the grain boundaries, γig, was chosen to be 20 and 40 % of the fracture surface energy of a grain, γxtal, so that both intergranular and transgranular fracture were possible. Studies were performed on these idealized marble microstructures to elucidate the range of microcracking responses. Simulations were performed for both heating and cooling by 50 °C in steps of 1 °C. Microcracking results were correlated with the thermoelastic responses, which are indicators related to degradation. The results indicate that certain combinations of LPO, SPO, grain size, grain‐boundary fracture toughness and marble composition have a significant influence on the thermal-elastic response of marble. Microstructure with the smallest grain size and the highest degree of SPO and LPO had less of a tendency to microcrack. Additionally, with increasing SPO and LPO microcracking becomes more spatially anisotropic. A significant observation for all microstructures was an asymmetry in microcracking upon heating and cooling: more microcracking was observed upon cooling than upon heating. Given an identical microstructure and crystallographic texture, calcite showed larger thermal stresses than dolomite, had an earlier onset of microcracking upon heating and cooling, and a greater microcracked area at a given temperature differential. Thermal expansion coefficients with and without microcracking were also determined.

Description: In Uruguay commercial granite varieties comprise mafic rocks, granitoids, and syenitoids. There is a long tradition in Uruguay, as well as worldwide, of using dimensional stones in architecture and art, specially granitic ones. Some of the present applications of these dimensional stones are as façade cladding, countertops, and outdoor and indoor floor slabs. The color spectrum of the Uruguayan granitic dimensional stones varies from black to light gray, covering a wide variety of red and pink and minor greenish-gray. The décor of these granitic dimensional stones is mainly determined by their fabric, fundamentally the grain size and the color distribution between the different minerals that compose the rocks. In the present research the most important commercial granites were sampled to analyze their petrography and petrophysical properties. A detailed structural analysis has been performed in several deposits, as well as the application of the software 3D Block Expert for modeling the possible raw block size distribution. Other factors controlling the mining viability of the deposits were also studied (e.g., homogeneity/heterogeneity of color and décor) and the possible reserves were calculated.

Description: The old mining city of Guanajuato in middle Mexico preserves one of the most important historical legacies in colonial buildings, the UNESCO declared the city World Heritage Site in 1988. Practically all the colonial constructions were built with natural stones from the neighbourhood, of which stands a greenish to reddish vulcanite, called Loseros Tuff. Although the Loseros Tuff is widely used in historical buildings in the city. It shows significant deterioration and weathering effects, principally in the parts where the tuff shows a coarse grain size. The petrographic, petrophysical, mineralogical and geochemical properties of the Loseros Tuff were analysed in order to determine the causes, effects, behaviour and response to deterioration of this volcanic rock. The results of the investigations suggest that in addition to the parameters like the grain size and the porosity properties, the pore radii distribution is decisive for the effectiveness of porosity and the water transport into the rock. It is recognized that once the liquid water invades the rock the dissolution of the matrix occurs, which is accompanied by a sudden moisture expansion favoured by the newly formed secondary porosity and the high content of expandable clay minerals.

Description: The degree of weathering in natural stones on buildings and sculptures has been determined for many years in numerous cases by means of ultrasonic measurements. Conclusions concerning the strength of the rock and the type of weathering can thus be drawn. This relationship has not been established for all rock types. Most of the progress utilizing this method has been made in the analysis of marbles, where an increasing degree of weathering shows lower ultrasonic velocities. In the present study, four Carrara marble samples showing similar rock fabrics, but with respect to weathering exhibit considerable differences are investigated. Porosity varies between 0.2 vol. % and ca. 2.4 vol. %, whereby with increasing porosity the pore radii changes as well. Parallel to this the ultrasonic velocities change in dry samples from about 5.5 to 1.6 km/s, respectively. Model calculations reveal that the velocity reduction is caused by cracks with an extremely small aspect ratio of about 0.005 or even less. After a specific loss of strength, however, solution processes can become active, which modify the microcracks and generate an opposite trend. In the process a strong porosity increase correlates to a relatively small velocity reduction. With the presence of water the Vp porosity weathering relationship experiences a considerable modification. Parallel to the reduction of the ultrasonic velocities, it was determined that the mechanical strength (compressive strength, flexural strength, etc.) as well as the static Young’s modulus is reduced almost equally by a progressive advancement of the weathering front. In one case study dealing with tensile strengths, it was clearly documented how tensile cracks develop and propagate in dependence of the rock fabric. The rock mechanical and ultrasonic velocity data were used for stability assessments applied to the marble statuaries from the Schlossbrücke in Berlin. Stability assessments of the sculpture group 4 reveal that some critical parts must be replaced due to safety reasons.

Description: Fabrics of Cambrian sedimentary dykes formed in Proterozoic granites of the Västervik area (Southeast Sweden) evidence repeated opening/filling and mineralisation/cementation events under varying conditions. Diagnostic features include (1) wall-parallel boundaries between epiclastic fillings and (2) early formed dyke sediments that appear as lithoclasts in subsequently formed sedimentary fillings. The psammitic components mostly consist of well-rounded quartz grains related to a coastal environment and fragments from the granitic host rock. Platy calcitic fragments embedded in the epiclastic matrix originally formed as microveins within already-lithified dyke sediments and the adjacent host rock. Convex downward-pointing, internal sagging structures, together with the preferred orientation of compositional boundaries and long axes of grains/rock fragments parallel to the dyke walls, are interpreted as the result of suction-controlled flow of unconsolidated fillings during episodes of downward dyke growth. Pressure solution of quartz grains are evidence of extensional phases with dyke propagation that were interrupted by phases of horizontal compression normal to the dyke walls. The N–S and NE–SW striking sedimentary dykes formed by opening of a pre-existing joint set during NW–SE oriented rifting during the Cambrian.

Description: Moisture expansion in natural building stones is considered one of the most important factors affecting their weathering and deterioration. The processes that may be responsible for the expansion under determinate relative humidity (hygric dilatation) and water-saturated conditions (hydric dilatation) are generally attributed to the presence of swellable clay minerals. In contrast to this assumption, our investigations show that moisture expansion also takes place in volcanic tuff building stones almost free from clay minerals. To provide a deeper understanding of the processes, swelling and deterioration were performed on 14 volcanic tuffs used as important building stones of different ages, compositions and weathering stages from Mexico, Germany and Hungary. The investigations undertaken include extensive chemical, petrophysical and fabric analyses. The samples show a wide range of effective porosity, microporosity, capillary water absorption, moisture expansion, and CEC values. High moisture expansion does not seem to depend on clay mineral content alone. We also observed that there is no significant effect on dilatation if clay minerals are present but only form a thin coat on the outer shell of bigger pores. Moreover, we identified a correlation between microporosity, average pore radius and moisture expansion. The investigations highlight the fact that moisture expansion cannot only be attributed to swellable clay minerals, and suggest that the presence and accumulation of micropores and their average radius and distribution play an important role for non-clay associated swelling intensity, which can most probably be attributed to the disjoining pressure.

Description: Investigation by Raman spectroscopy of samples from different geological settings shows that the occurrence of TiO2 polymorphs other than rutile can hardly be predicted, and furthermore, the occurrence of anatase is more widespread than previously thought. Metamorphic pressure and temperature, together with whole rock chemistry, control the occurrence of anatase, whereas variation of mineral assemblage characteristics and/or fluid occurrence or composition takes influence on anatase trace element characteristics and re-equilibration of relict rutiles. Evaluation of trace element contents obtained by electron microprobe in anatase, brookite, and rutile shows that these vary significantly between the three TiO2 phases. Therefore, on the one hand, an appropriation to source rock type according to Nb and Cr contents, but as well application of thermometry on the basis of Zr contents, would lead to erroneous results if no phase specification is done beforehand. For the elements Cr, V, Fe, and Nb, variation between the polymorphs is systematic and can be used for discrimination on the basis of a linear discriminant analysis. Using phase group means and coefficients of linear discriminants obtained from a compilation of analyses from samples with well-defined phase information together with prior probabilities of groupings from a natural sample compilation, one is able to calculate phase grouping probabilities of any TiO2 analysis containing at least the critical elements Cr, V, Fe, and Nb. An application of this calculation shows that for the appropriation to the phase rutile, a correct-classification rate of 99.5% is obtained. Hence, phase specification by trace elements proves to be a valuable tool besides Raman spectroscopy.

Description: A new U–Pb SHRIMP age of 551 ± 4 Ma on a mylonitic porphyry that intruded into the Sierra Ballena Shear Zone (Southernmost Dom Feliciano Belt, Uruguay) and a review of relevant published data make possible a more refined correlation and reconstruction of Brasiliano/Pan-African transpressional events. Paleogeographic reconstruction, kinematics and timing of events indicate a connection between the shear systems of the Dom Feliciano and Kaoko Belts at 580–550 Ma. Sinistral transpression recorded in shear zones accommodates deformation subsequent to collision between the Congo and Río de la Plata Cratons. The correlation is strengthened by the similarity of magmatic and metamorphic ages in the Coastal Terrane of the Kaoko Belt and the Punta del Este Terrane of the Dom Feliciano Belt. This post-collisional sinistral transpression brought these units near to their final position in Gondwana and explains the different evolution at 550–530 Ma. While in the Kaoko Belt, an extensional episode resulted in exhumation as a consequence of collision in the Damara Belt, in the Dom Feliciano Belt, sinistral transpression occurred associated with the closure of the southern Adamastor Ocean due to Kalahari-Río de la Plata collision.

Description: This study documents the chemical and textural responses of zircon in the Elba igneous complex, with particular reference to the 7- to 7.8-Ma-old Monte Capanne pluton in relation to its coeval volcanic counterpart (Capraia), using BSE imaging and quantitative electron microprobe analyses. The Monte Capanne pluton displays multiple field and geochemical evidence for magma mixing. The samples we have investigated (including monzogranitic, mafic enclave and dyke samples) display similar zircon textures and are associated with an extremely large range of trace and minor element (Hf, Y, HREE, Th, U) compositions, which contrast with relatively simple textures and zoning patterns in zircons from a Capraia dacite. We have used a relatively simple textural classification (patchy zoning, homogenous cores, oscillatory zoning and unzoned zircon) as the basis for discussing the chemical composition and chemical variation within zircons from the Monte Capanne pluton. Based on these data and other works (Dini et al. 2004 in Lithos 78:101–118, 2004) , it is inferred that mixing between metaluminous and peraluminous melts occurred early in the evolution of the Monte Capanne magma chamber. In particular, mixing was responsible for the development of the patchy-zoning texture in the zircon cores, which was associated with reactions between other accessory phases (including monazite, apatite, allanite), which we infer to have significantly affected the Th distribution in zircon. Zircons from the MC pluton displaying “homogeneous cores” have chemical affinities with zircons in the coeval Capraia volcanic system, consistent with the participation of a Capraia-like mantle end-member during mixing. Further zircon growth in the MC pluton produced the oscillatory zoning texture, which records both long-term (crystal fractionation) and transient (recharge with both silicic and mafic magmas) events in a hybrid magma chamber. It is inferred that Hf and the Th/U ratio cannot be used alone to infer magmatic processes due to their dependency on temperature, nor are they a diagnostic feature of xenocrystic grains. This study shows that zircon chemistry coupled with detailed textural analysis can provide a powerful tool to elucidate the complex evolution of a magma system.

Description: The bowing of natural stone panels is especially known for marble slabs. The bowing of granite is mainly known from tombstones in subtropical humid climate. Field inspections in combination with laboratory investigations with respect to the thermal expansion and the bowing potential was performed on two different granitoids (Cezlak granodiorite and Flossenbürg granite) which differ in the composition and rock fabrics. In addition, to describe and explain the effect of bowing of granitoid facade panels, neutron time-of-flight diffraction was applied to determine residual macro- and microstrain. The measurements were combined with investigations of the crystallographic preferred orientation of quartz and biotite. Both samples show a significant bowing as a function of panel thickness and destination temperature. In comparison to marbles the effect of bowing is more pronounced in granitoids at temperatures of 120°C. The bowing as well as the thermal expansion of the Cezlak sample is also anisotropic with respect to the rock fabrics. A quantitative estimate was performed based on the observed textures. The effect of the locked-in stresses may also have a control on the bowing together with the thermal stresses related to the different volume expansion of the rock-forming minerals.

Description: Multi-isotope study including whole-rock Nd–Sr, single zircon Hf, and SIMS δ18O analyses of zircons sheds light on magma sources in the northernmost Arabian–Nubian Shield (ANS) during ~820–570 Ma. Reconnaissance initial Nd and Sr isotope data for the older rocks (~820–740 Ma) reaffirms previous estimates that early crustal evolution in this part of the shield involved some crustal contamination by pre-ANS material. Prominent isotope provinciality is displayed by post-collisional calc-alkaline and alkaline igneous rocks of ~635–570 Ma across a NW-SE transect across basement of the Sinai Peninsula (Egypt) and southern Israel. Silicic rocks of the NW-region are characterized by lower εNd(T)–εHf(T) and higher Sri and δ18O compared with rocks of the SE-region, and the transition between the regions is gradual. Within each region isotope ratios are independent of the extent of magma fractionation, and zircon cores and rims yield similar δ18O values. Comparison with southern segments of the ANS shows that the source for most ~635–570 Ma rocks can be modeled as the isotopically aged lower-intermediate crust in the ANS core (SE-region) and its northern, more contaminated ANS margins (NW-region). Nevertheless, Nd–Sr isotope enrichment of the lithospheric mantle is indicated by some basic magmas of the NW-region displaying the most enriched Nd–Sr isotope compositions. Comparison of Nd and Hf depleted mantle model ages for rocks of the SE-region may indicate that crustal formation events in the ANS geographical core took place at 1.1–1.2 Ga and were followed by crustal differentiation starting at ~0.9 Ga.

Description: Oligoclase and labradorite crystals have been experimentally replaced by albite in an aqueous sodium silicate solution at 600°C and 2 kbars. The replacement is pseudomorphic and is characterised by a sharp chemical interface which progresses through the feldspar while preserving the crystallographic orientation. Reaction rims of albite, up to 50 μm thick, can be readily achieved within 14 days. Re-equilibration of plagioclase in an 18O-enriched sodium- and silica-bearing solution results in oxygen isotope redistribution within the feldspar framework structure. The observed characteristics of the reaction products are similar to naturally albitised plagioclase and are indicative of an interface-coupled dissolution–reprecipitation mechanism. Chemical analyses demonstrate that the albitisation is accompanied by the mobilisation of major, minor and trace elements also including elements such as Al and Ti which are commonly regarded as immobile during hydrothermal alteration. The results contribute to developing our understanding of the close association between large-scale albitisation and secondary ore mineralisation which is common in nature.

Description: The Sierra de San Luis forms the southern tip of the Eastern Sierras Pampeanas in central Argentina. Two narrow belts of low-grade phyllites and quartz arenites, i.e. the San Luis Formation, have accommodated part of the strain-related differential exhumation of the medium- to high-grade metamorphic domains that constitute to the basement complex of the sierra. Eleven phyllite samples were subjected to the K/Ar fine-fraction dating technique. Results are interpreted in relation to the Kübler index of the illites, which indicate epimetamorphic conditions for the majority of the samples. Obtained ages between 330 and 290 Ma cover a period of compressional tectonics in the late Mississippian (Visean/Serpukhovian boundary) followed by the subsidence during the formation of the Paganzo Basin in the provinces of La Rioja and San Luis. These tectonic movements are coincident with the Toco orogeny in northern Chile and southern Bolivia. This suggests that the older K/Ar ages document the compressional stage and that younger ages record the cooling of the basement during the subsequent extensional uplift of the basement.

Description: A review of the lithostratigraphic units in the Río de la Plata Craton and of new and previously published geochronological, isotopic and geophysical data is presented. Sm–Nd TDM model ages between 2.6 and 2.2 Ga characterize the Piedra Alta Terrane of this craton. Crystallization ages between 2.2 and 2.1 Ga for the metamorphic protoliths and 2.1–2.0 Ga for the post-orogenic granitoids indicate juvenile crust, followed by a short period of crustal recycling. Cratonization of this terrane occurred during the late Paleoproterozoic. Younger overprinting is not observed, suggesting it had a thick and strong lithosphere in the Neoproterozoic. A similar scenario is indicated for the Tandilia Belt of Argentina. Sm–Nd TDM model ages for the Nico Pérez Terrane show two main events of crustal growth (3.0–2.6 and 2.3–1.6 Ga). The crystallization ages on zircon ranges between 3.1 and 0.57 Ga, which is evidence for long-lived crustal reworking. The age for cratonization is still uncertain. In the Taquarembó Block, which is considered the prolongation of the Nico Pérez Terrane in southern Brazil, a similar scenario can be observed. These differences together with contrasting geophysical signatures support the redefinition of the Río de la Plata Craton comprising only the Piedra Alta Terrane and the Tandilia Belt. The Sarandí del Yí Shear Zone is regarded as the eastern margin of this Craton.

Description: The volcaniclastic Tepoztlán Formation (TF) represents an important rock record to unravel the early evolution of the Transmexican Volcanic Belt (TMVB). Here, a depositional model together with a chronostratigraphy of this Formation is presented, based on detailed field observations together with new geochronological, paleomagnetic, and petrological data. The TF consists predominantly of deposits from pyroclastic density currents and extensive epiclastic products such as tuffaceous sandstones, conglomerates and breccias, originating from fluvial and mass flow processes, respectively. Within these sediments fall deposits and lavas are sparsely intercalated. The clastic material is almost exclusively of volcanic origin, ranging in composition from andesite to rhyolite. Thick gravity-driven deposits and large-scale alluvial fan environments document the buildup of steep volcanic edifices. K-Ar and Ar-Ar dates, in addition to eight magnetostratigraphic sections and lithological correlations served to construct a chronostratigraphy for the entire Tepoztlán Formation. Correlation of the 577 m composite magnetostratigraphic section with the Cande and Kent (1995) Geomagnetic Polarity Time Scale (GPTS) suggests that this section represents the time intervall 22.8–18.8 Ma (6Bn.1n-5Er; Aquitanian-Burdigalian, Lower Miocene). This correlation implies a deposition of the TF predating the extensive effusive activity in the TMVB at 12 Ma and is therefore interpreted to represent its initial phase with predominantly explosive activity. Additionally, three subdivisions of the TF were established, according to the dominant mode of deposition: (1) the fluvial dominated Malinalco Member (22.8–22.2 Ma), (2) the volcanic dominated San Andrés Member (22.2–21.3 Ma) and (3) the mass flow dominated Tepozteco Member (21.3–18.8 Ma).

Description: The Sierra Ballena Shear Zone (SBSZ) is part of a high-strain transcurrent system that divides the Neoproterozoic Dom Feliciano Belt of South America into two different domains. The basement on both sides of the SBSZ shows a deformation stage preceding that of the transcurrent deformation recognized as a high temperature mylonitic foliation associated with migmatization. Grain boundary migration and fluid-assisted grain boundary diffusion enhanced by partial melting were the main deformation mechanisms associated with this foliation. Age estimate of this episode is 〉658 Ma. The second stage corresponds to the start of transpressional deformation and the nucleation and development of the SBSZ. During this stage, pure shear dominates the deformation, and is characterized by the development of conjugate dextral and sinistral shear zones and the emplacement of syntectonic granites. This event dates to 658–600 Ma based on the age of these intrusions. The third stage was a second transpressional event at about 586 to 〈560 Ma that was associated with the emplacement of porphyry dikes and granites that show evidence of flattening. Deformation in the SBSZ took place, during the late stages, under regional low-grade conditions, as indicated by the metamorphic paragenesis in the supracrustals of the country rocks. Granitic mylonites show plastic deformation of quartz and brittle behavior of feldspar. A transition from magmatic to solid-state microstructures is also frequently observed in syntectonic granites. Mylonitic porphyries and quartz mylonites resulted from the deformation of alkaline porphyries and quartz veins emplaced in the shear zone. Quartz veins reflect the release of silica associated with the breakdown of feldspar to white mica during the evolution of the granitic mylonites to phyllonites, which resulted in shear zone weakening. Quartz microstructures characteristic of the transition between regime 2 and regime 3, grain boundary migration and incipient recrystallization in feldspar indicate deformation under lower amphibolite to upper greenschist conditions (550–400°C). On the other hand, the mylonitic porphyries display evidence of feldspar recrystallization suggesting magmatic or high-T solid-state deformation during cooling of the dikes.

Description: Movement within the Earth’s upper crust is commonly accommodated by faults or shear zones, ranging in scale from micro-displacements to regional tectonic lineaments. Since faults are active on different time scales and can be repeatedly reactivated, their displacement chronology is difficult to reconstruct. This study represents a multi-geochronological approach to unravel the evolution of an intracontinental fault zone locality along the Danube Fault, central Europe. At the investigated fault locality, ancient motion has produced a cataclastic deformation zone in which the cataclastic material was subjected to hydrothermal alteration and K-feldspar was almost completely replaced by illite and other phyllosilicates. Five different geochronological techniques (zircon Pb-evaporation, K–Ar and Rb–Sr illite, apatite fission track and fluorite (U-Th)/He) have been applied to explore the temporal fault activity. The upper time limit for initiation of faulting is constrained by the crystallization age of the primary rock type (known as “Kristallgranit”) at 325 ± 7 Ma, whereas the K–Ar and Rb–Sr ages of two illite fractions 〈2 μm (266–255 Ma) are interpreted to date fluid infiltration events during the final stage of the cataclastic deformation period. During this time, the “Kristallgranit” was already at or near the Earth’s surface as indicated by the sedimentary record and thermal modelling results of apatite fission track data. (U–Th)/He thermochronology of two single fluorite grains from a fluorite–quartz vein within the fault zone yield Cretaceous ages that clearly postdate their Late-Variscan mineralization age. We propose that later reactivation of the fault caused loss of helium in the fluorites. This assertion is supported by geological evidence, i.e. offsets of Jurassic and Cretaceous sediments along the fault and apatite fission track thermal modelling results are consistent with the prevalence of elevated temperatures (50–80°C) in the fault zone during the Cretaceous.

Description: The application of the SHRIMP U/Pb dating technique to zircon and monazite of different rock types of the Sierras de Córdoba provides an important insight into the metamorphic history of the basement domains. Additional constraints on the Pampean metamorphic episode were gained by Pb/Pb stepwise leaching (PbSL) experiments on two titanite and garnet separates. Results indicate that the metamorphic history recorded by Crd-free gneisses (M2) started in the latest Neoproterozoic/earliest Cambrian (553 and 543 Ma) followed by the M4 metamorphism at ~530 Ma that is documented in the diatexites. Zircon ages of 492 Ma in the San Carlos Massif correlate partly with rather low Th/U ratios (〈0.1) suggesting their growth by metamorphic fluids. This age is even younger than the PbSL titanite ages of 506 Ma. It is suggested that the fluid alteration relates to the beginning of the Famatinien metamorphic cycle in the neighbouring Sierra de San Luis and has not affected the titanite ages. The PTt evolution can be correlated with the plate tectonic processes responsible for the formation of the Pampean orogene, i.e., the accretion of the Pampean basement to the Río de La Plata craton (M2) and the later collision of the Western Pampean basement with the Pampean basement.

Description: Aspidochirote holothurian ossicles were discovered in Upper Ordovician-aged Öjlemyr cherts from Gotland, Sweden. The well-preserved material allows definitive assignment to the family Synallactidae, a deep-sea sea cucumber group that is distributed worldwide today. The new taxon Tribrachiodemas ordovicicus gen. et sp. nov. is described, representing the oldest member of the Aspidochirotida. The further fossil record of Synallactidae and evolutionary implications are also discussed.

Description: The configurational heat capacity, shear modulus and shear viscosity of a series of Na2O–Fe2O3–Al2O3–SiO2 melts have been determined as a function of composition. A change in composition dependence of each of the physical properties is observed as Na2O/(Na2O + Al2O3) is decreased, and the peralkaline melts become peraluminous and a new charge-balanced Al-structure appears in the melts. Of special interest are the frequency dependent (1 mHz–1 Hz) measurements of the shear modulus. These forced oscillation measurements determine the lifetimes of Si–O bonds and Na–O bonds in the melt. The lifetime of the Al–O bonds could not, however, be resolved from the mechanical spectrum. Therefore, it appears that the lifetime of Al–O bonds in these melts is similar to that of Si–O bonds with the Al–O relaxation peak being subsumed by the Si–O relaxation peak. The appearance of a new Al-structure in the peraluminous melts also cannot be resolved from the mechanical spectra, although a change in elastic shear modulus is determined as a function of composition. The structural shear-relaxation time of some of these melts is not that which is predicted by the Maxwell equation, but up to 1.5 orders of magnitude faster. Although the configurational heat capacity, density and shear modulus of the melts show a change in trend as a function of composition at the boundary between peralkaline and peraluminous, the deviation in relaxation time from the Maxwell equation occurs in the peralkaline regime. The measured relaxation times for both the very peralkaline melts and the peraluminous melts are identical with the calculated Maxwell relaxation time. As the Maxwell equation was created to describe the timescale of flow of a mono-structure material, a deviation from the prediction would indicate that the structure of the melt is too complex to be described by this simple flow equation. One possibility is that Al-rich channels form and then disappear with decreasing Si/Al, and that the flow is dominated by the lifetime of Si–O bonds in the Al-poor peralkaline melts, and by the lifetime of Al–O bonds in the relatively Si-poor peralkaline and peraluminous melts with a complex flow mechanism occurring in the mid-compositions. This anomalous deviation from the calculated relaxation time appears to be independent of the change in structure expected to occur at the peralkaline/peraluminous boundary due to the lack of charge-balancing cations for the Al-tetrahedra.

Description: The giant ignimbrites that erupted from the Cerro Galán caldera complex in the southern Puna of the high Andean plateau are considered to be linked to crustal and mantle melting as a consequence of delamination of gravitationally unstable thickened crust and mantle lithosphere over a steepening subduction zone. Major and trace element analyses of Cerro Galán ignimbrites (68–71% SiO2) that include 75 new analyses can be interpreted as reflecting evolution at three crustal levels. AFC modeling and new fractionation corrected δ18O values from quartz (+7.63–8.85‰) are consistent with the ignimbrite magmas being near 50:50 mixtures of enriched mantle (87Sr/86Sr ~ 0.7055) and crustal melts (87Sr/86Sr near 0.715–0.735). Processes at lower crustal levels are predicated on steep heavy REE patterns (Sm/Yb = 4–7), high Sr contents (〉250 ppm) and very low Nb/Ta (9-5) ratios, which are attributed to amphibolite partial melts mixing with fractionating mantle basalts to produce hybrid melts that rise leaving a gravitationally unstable garnet-bearing residue. Processes at mid crustal levels create large negative Eu anomalies (Eu/Eu* = 0.45–0.70) and variable trace element enrichment in a crystallizing mush zone with a temperature near 800–850°C. The mush zone is repeatedly recharged from depth and partially evacuated into upper crustal magma chambers at times of regional contraction. Crystallinity differences in the ignimbrites are attributed to biotite, zoned plagioclase and other antecrysts entering higher level chambers where variable amounts of near-eutectic crystallization occurs at temperatures as low as 680°C just preceding eruption. 40Ar/39Ar single crystal sanidine weighted mean plateau and isochron ages combined with trace element patterns show that the Galán ignimbrite erupted in more than one batch including a ~ 2.13 Ma intracaldera flow and outflows to the west and north at near 2.09 and 2.06 Ma. Episodic delamination of gravitationally unstable lower crust and mantle lithosphere and injection of basaltic magmas, whose changing chemistry reflects their evolution over a steepening subduction zone, could trigger the eruptions of the Cerro Galán ignimbrites.

Description: The construction suitability of a dimension stone depends on its weathering properties along with the petrology and the petrophysical properties. The aim of this study was to evaluate the suitability of the dimension stones from the “Drei Gleichen” area for construction and replacement purposes. In total, six sandstones (Ingersleben, Wachsenburg, Hindfelden, Seeberg, Röhnberg, Gleichenberg; Upper Triassic) as well as two carbonates (Wachsenburg sinter; Quaternary, Wandersleben dolomite; Middle Triassic) were analysed. The results from our laboratory and on-site studies of the dimension stones show that rocks from the same stratigraphic layer, like the sandstones from the upper Triassic, can show major differences in their petrophysical and weathering properties. These differences are attributed to their different diagenesis, resulting, e.g. in varying pore space, water balance and strength properties. The pore size distribution can be divided into four different groups based on their occurring maxima and micropore content. The determined water balance properties as well as moisture expansion and salt attack depend on these groups. Next to this, the mineralogical composition significantly influences the weathering resistance. Sandstones with a high content of altered lithoclasts show a high amount of moisture expansion, low strength and, in consequence, a low weathering resistance against salt attack. Based on the results of the present study, an evaluation of construction suitability could be accomplished. From the analysed sandstones, only the Seebergen sandstone is suitable for construction purposes due to its good availability, good strength properties (high compressive and tensile strength, low softening degree) as well as a low porosity. Furthermore, the Wachsenburg sandstone also shows good petrophysical and petrological properties, but exploitable deposits are too sparse to be of commercial interest. From the carbonates, the Wachsenburg sinter shows very suitable rock parameters, but only sparse outcrops occur, which are not appropriate for mining.

Description: In the Aztec period and in colonial times different natural stones originating in the Valley of Mexico were used for building construction. Stone weathering was investigated onsite at various historical buildings within the old quarter of Mexico City. In this study, different aspects of weathering and deterioration at three significant historical buildings will be presented, the Aztec excavation site Templo Mayor, the Metropolitan Cathedral, and the colonial palace of the dukes of Heras Soto. Petrophysical properties of the main building stones of these structures were investigated like density, porosity, pore radii distribution, water uptake rate and coefficient, thermal and hygric expansion, and the mechanical properties of uniaxial compressive strength. A relationship between single critical property values, according to anisotropy fabric characteristics, and specific weathering forms could be deduced.

Description: A 782 d solubilization study using not shaken batch experiments and involving one uranium-bearing rock and three natural carbonate minerals was conducted to characterize uranium (U) leaching under oxic conditions. Results showed that aqueous U concentration increased continuously with a solubilization rate of 0.16 mgm-2h-1 for the first 564 d (1.5 y). After 1.5 y, U concentration reached a maximum value (saturation) and decreased afterwards. The saturation concentration of 54 mgL-1 (mean value) was influenced to various extent by the presence of carbonate minerals. Dissolution/precipitation, adsorption or ion exchange processes appear to control U solubilization.

Description: The northern German Lower Cretaceous Bückeberg Formation yields numerous dinosaur tracksites, some of which have produced material of impressive quality. Stratigraphically, the localities are concentrated in the Obernkirchen Sandstone, a thin subunit within this formation. The Obernkirchen Sandstone represents mainly a sandy barrier to back-barrier and lagoonal setting within a limnic deltaic facies complex, which was deposited during the late Berriasian (Cypridea alta formosa ostracod subzone) in the southeast of the Lower Saxony Basin, northwest Germany. A few tracksites occur more proximally in coeval fluvial deposits. Dinosaur footprint assemblages were left by ornithopods, theropods, sauropods, ankylosaurs, and small, bipedal ornithischians. Other vertebrate tracks are those of turtles and, possibly, crocodilians. Due to the decrease in sandstone quarrying in recent decades, many old tracksites are inaccessible today. Additionally, historical descriptions of the tracks were of highly variable quality and often published in remote and today nearly unobtainable sources. Here we provide a catalogue of 13 tracksites compiled from the literature and some new observations. Of these 13 tracksites, only five are still accessible and currently under study. Descriptions of each locality are provided, with a comprehensive compilation of existing data on lithofacies, stratigraphy, palaeogeography and palaeoecology of the Obernkirchen Sandstone and equivalent strata. A short review of the track-bearing lithofacies assemblage indicates that the outcrop areas have distinctly different facies and environments, and, therefore, track-bearing horizons can only be correlated stratigraphically between adjacent outcrops. For this reason, the identification of a megatracksite in the Obernkirchen Sandstone is currently regarded as premature and uncertain.

Description: Many of the reasons behind the anthropogenic contamination problems in rural environments of developing countries lie in changes in the traditional way of life and the ignorance on the toxic potential of introduced manufactured products. A generalization trend exists within the international community suggesting that water in developing countries is of poor quality. However, the water quality is rarely analytically determined. Existing potabilization solutions may be prohibitively expensive for the rural populations. Therefore, efficient and affordable technologies are still needed to ameliorate the water quality. In the recent two decades,elemental iron has shown the capacity to remove all possible contaminants (including viruses) from the groundwater. This paper presents a concept to scale down the conventional iron barrier technology to meet the requirements of small communities and households in rural environments worldwide.

Description: The morphologically conspicuous bivalve Oxytoma (Palmoxytoma) cygnipes (Young & Bird, 1822), known for its palaeogeographically bipolar distribution, from a limestone bed in the boundary “Belemniten–Schichten”/Amaltheenton formation, Lower Jurassic, in N Germany is described. The occurrence of this palaeoceanographically significant bivalve points to an influx of cool seawater from the Arctic to the North-German Basin at the base of the Upper Pliensbachian, just before the deposition of the Amaltheenton formation. A review of previously reported occurrences on the NW European Shelf indicates two distinct stratigraphic intervals of occurrence of this taxon: the Rhaetian–Hettangian boundary and the Upper Pliensbachian. Whereas the former interval of occurrence may be related to short-term cooling in the course of the end-Triassic extinction event, the latter is interpreted as reflecting the influx of a cool water current to the eastern part of the NW European Shelf, which continued southwards parallel to the coast of the Bohemian–Vindelician High.

Description: In the present study, the diversity of ascomycete fungi was investigated on two wall areas of the “Burg Gleichen”, Thuringia (Germany), made of various types of sandstones, travertine and Grenzdolomit. From a W-exposed, shaded wall area, free-living ascomycetes (mainly “black fungi”) and green algae could be retrieved from sandstone lithologies. Sandstone from an ESE-exposed area was mainly colonized by lichen ascomycetes and the lichen alga Trebouxia. Both areas share a small number of generalist species, related to the ascomycete black fungi Sarcinomyces petricola, Phaeococcomyces chersonesos and Stichococcus mirabilis. Free-living black fungi were isolated and characterized with respect to cell wall morphology and melanin content. A remarkably rigid melanin layer, incorporated in the cell wall of a Cladosporium isolate is presented in detail.

Description: Microstructure-based finite element simulations were used to study the influence of grain shape fabric and crystal texture on thermoelastic responses related to marble degradation phenomena. Calcite was used as an illustrative example for studying extremes of shape preferred orientation (SPO) in shape fabric and lattice preferred orientation (LPO) in crystal texture. Three SPOs were analyzed: equiaxed grains, elongated grains, and a mixture of equiaxed and elongated grains. Three LPOs were considered: a random orientation distribution function and two degrees of strong directional crystal texture. Finally, the correlation between the direction of the LPO with respect to that of the SPO was examined. Results show that certain combinations of SPO, LPO, and their directional relationship have significant influence on the thermomechanical behavior of marble. For instance, while there is no major dependence of the elastic strain energy density and the maximum principal stress on SPO for randomly textured microstructures, there is a strong synergy between LPO and its directional relationship with respect to the SPO direction. Microcracking precursors, elastic strain energy density, and maximum principal stress, decrease when the crystalline c-axes have fiber texture perpendicular to the SPO direction, but increase significantly when the c-axes have fiber texture parallel to the SPO direction. Moreover, the microstructural variability increases dramatically for these latter configurations. In general, the influence of LPO was as expected, namely, the strain energy density and the maximum principal stress decreased with more crystal texture, apart from for the exception noted above. Spatial variations of these precursors indicated regions in the microstructure with a propensity for microcracking. Unexpectedly, important variables were the microstructural standard deviations of the spatial distributions of the microcracking indicators. These microstructural standard deviations were as large as or larger than the variables themselves. The elastic misfit-strain contributions to the coefficients of thermal expansion were also calculated, but their dependence was as expected.

Description: The present study documents the results of an inter-disciplinary model project that was planned with the aim of developing an innovative winter covering system for marble statuaries located on the Schlossbrücke (Berlin). Such a system would need to fulfil the various requirements for structural stability, aesthetics, climate and practical use. This applied research represents the first complex scientific study of the sustainability of a winter covering system. The study is characterised by the use of complex scientific instruments such as special laboratory analysis and numerical simulation tools. The interaction between the environment and the artefacts in connection with the innovative winter covering structures were studied by extensive climatic monitoring.

Description: This study evaluates and compares the trends in CO2 emissions for the manufacturing industries of three countries: two developed countries (Germany and Sweden) that have applied several measures to promote a shift towards a low-carbon economy and one developing country (Colombia) that has shown substantial improvements in the reduction of CO2 emissions. This analysis is conducted using panel data cointegration techniques to infer causality between CO2 emissions, production factors and energy sources. The results indicate a trend of producing more output with less pollution. The trends for these countries’ CO2 emissions depend on investment levels, energy sources and economic factors. Furthermore, the trends in CO2 emissions indicate that there are emission level differences between the two developed countries and the developing country. Moreover, the study confirms that it is possible to achieve economic growth and sustainable development while reducing greenhouse gas emissions, as Germany and Sweden demonstrate. In the case of Colombia, it is important to encourage a reduction in CO2 emissions through policies that combine technical and economic instruments and incentivise the application of new technologies that promote clean and environmentally friendly processes.

Description: Severe stone deterioration is evident at the Cologne cathedral. In particular, the “Drachenfels” trachyte, which was the building material of the medieval construction period, shows significant structural deterioration as well as massive formation of gypsum crusts. The present article investigates crust formation on limestone, sandstone, and volcanic rock from the Cologne cathedral as well as from the Xanten and Altenberg cathedrals. These three buildings, showing varying degrees of deterioration, are located in different areas and exposed to varying industrial, urban, and rural pollution. Thin laminar and black framboidal crusts form on calcareous as well as silicate stone. The lack of a significant intrinsic calcium and sulfur source for the formation of the gypsum crusts on the Drachenfels trachyte indicates major extrinsic environmental impact: a sufficient offer of SOx from pollutant fluxes as well as external calcium sources (e.g., pollution, mortars, neighboring calcite stones). Chemical analyses reveal strong gypsum enrichment within the crusts as well as higher concentrations of lead and other pollutants (arsenic, antimony, bismuth, tin, etc.), which generally can be linked to traffic and industry. The formation of weathering crusts in an industrial environment is clearly distinguishable from that in rural areas. Scanning electron microscopy observations confirm that the total amount of pollution is less at the Altenberg cathedral than at the Cologne and Xanten cathedrals. XRF analyses show that the formation of gypsum occurs in lower amounts at Altenberg. This correlates well with the measured SO2 content and the intensity of the decay at the different locations. Furthermore, the different types of crusts, e.g., framboidal and laminar, can be differentiated and assigned to the different locations. The black weathering crusts on the silicate Drachenfels trachyte contribute to the degradation of the historic building material. They enhance mechanical moisture-related deterioration processes and the decay by chemical corrosion of rock-forming minerals. Although SO2 concentrations in air have shown a strong decrease over the past 30 years, degradation in connection with weathering crusts is still observed. This indicates that not only contemporary or recent emissions, but also past pollutant concentrations have to be considered.

Description: The St. Servatius Church in Quedlinburg (UNESCO’s World Heritage Site, Germany) is characterised by long-standing stability problems and structural damages, which have been known over the last several centuries. The monotonous Cretaceous sandstone with its poor lithification is considered to be the main factor. The sandstone is characterised by a high porosity of around 30 Vol.% (max. ca. 35 Vol.%) and a corresponding high w-value. The porosity and the degree of cementation are responsible for the very low compressive strength of around 8 MPa at maximum, whereas under moisture these values are significantly reduced up to 40%. The freeze–thaw tests indicate a very poor resistance to frost weathering, which may explain the near-surface softening of the sandstone. Direct shear experiments with an approximate 60° angle of friction on the sandstone clearly demonstrate the safety margins. Initial geotechnical modelling does not favour the hypothesis that a landslide of the hill parallel to the southward dipping bedding planes (i.e. shear failure along weak zones) can occur. A prominent clay layer (also with a southward dip) below the entire castle hill is monitored to determine the possible amount of movement with respect to the geological discontinuities (e.g. joints, fractures). At present, a combination of foundation problems are being considered for the stability situation at the church. These include construction deficiencies due to deformation or softening of the foundation of the forerunner churches and missing or faulty connections from building additions. Geological factors responsible for the stability problems include the softening of the sandstone by the influence of weathering and penetrating water as well as the presence of possible shear planes and joints.

Description: Dimensional stones with a black color occupy a prominent place on the international market. Uruguayan dolerite dikes of andesitic and andesitic–basaltic composition are mined for commercial blocks of black dimensional stones. A total of 16 dikes of both compositions were studied and samples collected for geochemical and petrographical analysis. Color measurements were performed on different black dimensional stones in order to compare them with the Uruguayan dolerites. Samples of the two commercial varieties (Absolute Black and Moderate Black) were obtained for petrophysical analysis (e.g. density, porosity, uniaxial compressive strength, tensile strength, etc.). Detailed structural analyses were performed in several quarries. Geochemistry and petrography determines the intensity of the black color. The Uruguayan dolerite Absolute Black is the darkest black dimensional stone analyzed in this study. The petrophysical properties of Uruguayan dolerites make them one of the highest quality black dimensional stones. Structural analyses show that five joint sets have been recognized: two sub-vertical joints, one horizontal and two diagonal. These joint sets are one of the most important factors that control the deposits, since they control the block size distribution and the amount of waste material.

Description: One of the properties that makes marble such an excellent construction and ornamental material is its low porosity. It is very difficult for water or decay agents to penetrate the internal structure of materials with no or few pores, so enhancing the durability of these materials. However, environmental temperature fluctuations bring about significant physical changes in marbles that result in an increase in porosity, due to the appearance of new microcracks and the expansion of existing ones. These cracks offer new paths into the marble which make it easier for solutions containing pollutants to penetrate the material. Thermal expansion tests were performed on three different types of marble known as White, Tranco, and Yellow Macael (Almeria, Spain), after which an increase in porosity (from 17 to 73% depending on marble type) was observed, mainly due to crack formation. The structural changes occurring during thermal expansion tests were more significant in the case of White Macael samples, a fact that is not only related to its mineralogical composition but also to the morphology of the grains, grain boundaries and crystal size. Our research suggests that thermally weathered White Macael marble could be more susceptible to decay by other contaminant agents than Tranco or Yellow Macael. The use of hot-stage environmental scanning electron microscopy is proposed as a valid tool for observing, both in situ and at high magnification, changes in the fracture system of building stones induced by thermal stress.