ALBERT

Beschreibung: We study the quasi-geostrophic merging dynamics of axisymmetric baroclinic vortices to understand how baroclinicity affects merging rates and the development of the nonlinear cascade of enstrophy. The initial vortices are taken to simulate closely the horizontal' and vertical structure of Gulf Stream rings. A quasigeostrophic model is set with a horizontal resolution of 9 km and 6 vertical levels to resolve the mean stratification of the Gulf Stream region. The results show that the baroclinic merging is slower than the purely barotropic process, The merging is shown to occur in two phases: the tirst, which produces clove-shaped vortices and diffusive mixing of vorticity contours; and the second, which consists of the sliding of the remaining vorticity cores with a second diffusive mixing of the intemal vorticity field. Comparison among Nof, Cushman-Roisin, Polvani et al, and Dewar and Killworth merging events indicates a substantial agreement in the kinematics of the DYOCRSS. Parameter sensitivity experiments show that the decrease of the baroclinicity parameter of the system, Γ^2, [defined as Γ^2 = (D^2 fo^2)/ (No^2 H^2)], increases the speed of merging while its increase slows down the merging. However, the halting elfect of baroclinicity (large Γ^2 or small Rossby radii of deformation) reaches a saturation level where the merging becomes insensitive to larger F2 values. Furthermore, we show that a regime of small Γ^2 exists at which the merged baroclinic vortex is unstable (metastable) and breaks again into two new vortices, Thus, in the baroelinic case the range of Γ^2 detemines the stability of the merged vortex. We analyze these results by local energy and vorticity balances, showing that the horizontal divergence of pressure work term [∇ *(pv)] and the relative-vorticity advection term (v * ∇ (∇ ^2 φ) trigger the merging during the first phase. Due to this horizontal redistribution process, a net kinetic to gravitational energy conversion occurs via buoyancy work in the region external to the cores of the vortices. The second phase of merging is dominated by a direct baroclinic conversion of available gravitational energy into kinetic energy, which in tum triggers a horizontal energy redistribution producing the final fusion of the vortex centers. This energy and vorticity analysis supports the hypothesis that merging is an internal mixing process triggered by a horizontal redistribution of kinetic energy.

Beschreibung: The work has been financed by a grant from the Progetto Finalizzato "Calcolo Parallelo"

Beschreibung: Published

Beschreibung: 1618/1637

Beschreibung: 4A. Clima e Oceani

Beschreibung: JCR Journal

Beschreibung: restricted

Beschreibung: The continental shelf off the northeastern coast of the United States was the first of our offshore coastal areas to be charted in detail by the Coast and Geodetic Survey, starting on Georges Bank in 1930. The techniques responsible for this increased accuracy in offshore waters were first described by Rudé (1938) and have been constantly improved. From these soundings Veatch and Smith (1939) compiled their set of contour charts aided by a grant from the Penrose Bequest of the Geological Society of America. These soundings reopened the submarine canyon problem first commented upon by Dana (1863), which had gradually lapsed into obscurity from insuffcient data. The reader is, of course, well aware of the major controversy, with all its far reaching implications, which has been precipitated since the 1930 surveys of Georges Bank were brought to the attention of geologists by Shepard (1933). As more of the new surveys were completed, data from the field sheets were kindly furnished by the U. S. Coast and Geodetic Survey to the Woods Hole Oceanographic Institution for use in dredging and coring operations. This field work, first reported in 1936, was continued from time to time until 1941 as new soundings became available. Rock dredging and coring has been carried out in every major canyon on the slope from Corsair Canyon at the tip of Georges Bank to Norfolk Canyon off the entrance to the Chesapeake (Fig. I). Numerous cores have also been taken from the areas in between; and while the whole slope from Georges to the Chesapeake has not been covered, it is believed that no significant areas have been missed. In fact, cores from the slope taken during the summers of 1940 and 1941 have yielded results that are corroborative rather than new. In 1938 on a cruise from Hudson Gorge to Norfolk Canyon, cores were taken on the slope in areas which Veatch had considered to be the most important (personal communication). In the following report the tows and cores will be described by areas from Georges Bank southwards, as the same region was revisited in successive years. The various samples, however, will be referred to by number followed by the year in which they were taken. The material is in storage in the Woods Hole Oceanographic Institution and in the Museum of Comparative Zoology at Harvard University. The late Joseph A. Cushman was kind enough to identify the Foraminifera which have been obtained in tows from the canyon walls and in cores, except for those described in Appendix A which is contributed by Fred B Phleger, Jr. Most of the type material is in storage in the Museum of Comparative Zoology, although at the present writing some is in the Cushman Laboratory in Sharon, Massachusetts. I am indebted to Lloyd W. Stephenson for identifying a molluscan fauna from one of the canyons, and to W. C. Mansfield who has reported on another formation. Numerous discussions with Percy E. Raymond have, as usual, proved most helpful, and thanks are also due to Eugenia C. Lambert for performing the mechanical analyses and to Constance French for other laboratory assistance. Phleger (1939, 1942, 1946) has previously published on the Foraminifera from the slope and deep water cores. This material is, at present, at Scripps Institution of Oceanography.

Beschreibung: Submitted in partial fulfillment of the requirements of the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 2006

Beschreibung: Two years of moored oceanographic and automatic weather station data which span the winter ice seasons of 2001-2003 within Marguerite Bay on the western Antarctic Peninsula (wAP) shelf were collected as part of the Southern Ocean Global Ocean Ecosystems Dynamics program. In order to characterize the ice environment in the region, a novel methodology is developed for determining ice coverage, draft and velocity from moored upward-looking acoustic Doppler current profiler data. A linear momentum balance shows the importance of internal ice stresses in the observed motion of the ice pack. Strong inertial, not tidal, motions were observed in both the sea ice and upper ocean. Estimates of upward diapycnal fluxes of heat and salt from the Upper Circumpolar Deep Water to the surface mixed layer indicate almost no contribution from double diffusive convection. A one-dimensional vertical mixed layer model adapted for investigation of mixing beneath an ice-covered ocean indicates that the initial wind event, rather than subsequent inertial shear, causes the majority of the mixing. This work points towards episodic wind-forced shear at the base of the mixed layer coupled with static instability from brine rejection due to ice production as a major factor in mixing on the wAP shelf.

Beschreibung: The work described in this thesis was funded by the National Science Foundation Office of Polar Programs grant # 99-100092. Additional funding came from the MIT Houghton Fund, the WHOI Ocean Venture Fund and the WHOI Education Office.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February, 2006

Beschreibung: In this thesis, I present high-resolution stable-isotope and planktonic-fauna records from Bering Sea sediment cores, spanning the time period from 50,000 years ago to the present. During Marine Isotope Stage 3 (MIS3) at 30-20 ky BP (kiloyears before present) in a core from 1467m water depth near Umnak Plateau, there were episodic occurrences of diagenetic carbonate minerals with very low δ13C (-22:4h), high δ18O (6.5h), and high [Mg]/[Ca], which seem associated with sulfate reduction of organic matter and possibly anaerobic oxidation of methane. The episodes lasted less than 1000 years and were spaced about 1000 years apart. During MIS3 at 55-20 ky BP in a core from 2209m water depth on Bowers Ridge, N. pachyderma (s.) and Uvigerina δ18O and δ13C show no coherent variability on millennial time scales. Bering Sea sediments are dysoxic or laminated during the deglaciation. A high sedimentation rate core (200 cm/ky) from 1132m on the Bering Slope is laminated during the Bolling warm phase, Allerod warm phase, and early Holocene, where the ages of lithological transitions agree with the ages of those climate events in Greenland (GISP2) to well within the uncertainty of the age models. The subsurface distribution of radiocarbon was estimated from a compilation of published and unpublished North Pacific benthic-planktonic 14C measurements (475-2700 m water depth). There was no consistent change in 14C profiles between the present and the Last Glacial Maximum, Bolling-Allerod, or the Younger Dryas cold phase. N. pachyderma (s.) δ18O in the Bering Slope core decreases rapidly (in less than 220 y) by 0.7-0.8% at the onset of the Bolling and the end of the Younger Dryas. These isotopic shifts are accompanied by transient decreases in the relative abundance of N. pachyderma (s.), suggesting that the isotopic events are transient warmings and sustained freshenings.

Beschreibung: The work in this thesis was supported by the National Science Foundation award OPP-9912122 to Lloyd Keigwin, the Oak Foundation of Boston, Massachusetts, the Stanley Watson Fellowship, the Paul Fye Fellowship, and the Academic Programs Office at WHOI.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution October, 1977.

Beschreibung: Sediment traps designed to yield quantitative data of particulate fluxes have been deployed and successfully recovered on four moorings in the deep sea. The traps were designed after extensive calibration of different shapes of containers. Further intercalibration of trap design was made in field experiments over a range of current velocities. Experiments with Niskin bottles showed that concentrations of suspended particulate matter obtained with standard filtration methods were low and had to be increased by an average factor of 1.5 to correct for particles settling below the sampling spigot. The trap arrays were designed to sample the particulate fluxes both immediately above and within the nepheloid layer. The data derived from the traps have been used to estimate vertical fluxes of particles including, for the first time, an attempt to distinguish between the flux of material settling from the upper water column (the "primary flux") and material which has been resuspended from some region of the sea floor (resuspension flux). From these data and measurements of the net nepheloid standing crop of particles one can also estimate a residence time for particles resuspended in the nepheloid layer. This residence time appears to be on the order of days to weeks in the bottom 15 m of the water column and weeks to months in the bottom 100 m. Between 80% and 90% of the particles collected in the six traps where particle size was measured were less than 63 μm. The mean size of particles collected in the nepheloid layer was about 20 μm, and above the nepheloid layer the mean was 11 μm. Less than 3% of the organic carbon produced in the photic zone at the trap sites was collected as primary flux 500 m above the sea floor. The primary flux measured at two sites was enough to supply 75% on the upper Rise and 160% on the mid Rise of the organic carbon needed for respiration and for burial in the accumulating sediments. From an intercomparison of the composition of particles falling rapidly (collected in traps), falling slowly or not at all (collected in water bottles), and resting on the sea floor (from a core top), it was determined that elements associated with biogenic matter, such as Ca, Sr, Cu, and I, were carried preferentially by the particles falling rapidly. Once the particles reached the bottom, the concentration of those elements was decreased through decomposition, respiration, or dissolution. Dissolution appears rapid in the vicinity of the sea floor, because despite an abundance of radiolarians, diatoms, and juvenile foraminifera collected in all traps, these forms were rare in core samples. The dynamic nature of thenepheloid layer makes it possible for particles to be resuspended many times before they are finally buried. This enables sediment to be carried long distances from its origin. The recycling of particles near the sea floor may increase dissolution of silicious and carbonate matter.

Beschreibung: Financial aid was provided in the form of a research assistantship from the Office of Naval Research through MIT and WHOI.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September, 1975

Beschreibung: Erosion processes involving fine-grained marine sediments were studied by using an in situ flume to erode undisturbed bottom sediments on the sea floor in Buzzards Bay, a shallow marine embayment off the Massachusetts coast. Tte muddy sea floor in that area is characterized by a deposit-feeding infauna that reworks the sediments. Observations made with the in situ flume suggest that erosion resistance of compacted bottom sediments is up to twice as great as the erosion resistance of biogenically reworked sediments. Estimates of erosional bed shear stress from the in situ flume experiments are similar to estimates made during this study of bed shear stress developed in near-bottom tidal currents. It is inferred that erosion by the in situ flume produces reasonable estimates of bed shear stress necessary to erode undisturbed bottom sediments on the sea floor. Buzzards Bay muds were redeposited in a laboratory flume and eroded after various periods of reworking by the deposit-feeding organisms contained in them. Other Buzzards Bay mud samples were treated to remove organic matter, and the erosion resistance of flat beds of these sediments was also investigated in a laboratory flume. The surface of a biogenically reworked bed after two months was covered with mounds, burrows, trails, and aggregates composed of sediments and organic material. This bed was similar in appearance to many of the beds eroded by the in situ flume. The two month bed eroded at an erosional shear stress similar to the erosional shear stress necessary to erode the in situ Buzzards Bay muds (0.8 dynes/cm2 ) . Beds biogenically reworked for shorter periods had high values of erosional shear stress, up to twice that of the two month bed. The bed shear stress necessary to erode flat beds of Buzzards Bay sediments increased as the concentration of organic matter in the sediments increased. Deposit-feeders were absent in these beds, and the mode of deposition was kept uniform, so the increase of erosion resistance with increase in organic content is considered a reliable indication of sediment behavior, and not an artifact of experimental conditions. During the in situ experiments, lee drifts were created behind resistant roughness elements on the sea floor. A brief study of lee drift formation in the laboratory suggests that the formation of lee drifts from fine-grained sediments can be predicted to take place when the body Reynolds number of the resistant roughness elements is below a critical value.

Beschreibung: The Office of Naval Research supported this research and provided salary support through grants to the Woods Hole Oceanographic Institution and the Massachusetts Institute of Technology.

Beschreibung: Submitted to the Department of Mechanical Engineering in partial fulfillment of the requirements for the degree of Doctor of Philosophy in Applied Ocean Sciences at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February 2007

Beschreibung: This thesis introduces an algorithm for inverting for the geoacoustic properties of the seafloor in shallow water. The input data required by the algorithm are estimates of the amplitudes of the normal modes excited by a low-frequency pure-tone sound source, and estimates of the water column sound speed profiles at the source and receiver positions. The algorithm makes use of perturbation results, and computes the small correction to an estimated background profile that is necessary to reproduce the measured mode amplitudes. Range-dependent waveguide properties can be inverted for so long as they vary slowly enough in range that the adiabatic approximation is valid. The thesis also presents an estimator which can be used to obtain the input data for the inversion algorithm from pressure measurements made on a vertical line array (VLA). The estimator is an Extended Kalman Filter (EKF), which treats the mode amplitudes and eigenvalues as state variables. Numerous synthetic and real-data examples of both the inversion algorithm and the EKF estimator are provided. The inversion algorithm is similar to eigenvalue perturbation methods, and the thesis also presents a combination mode amplitude/eigenvalue inversion algorithm, which combines the advantages of the two techniques.

Beschreibung: The funding that made this research possible came from the Office of Naval Research, and the WHOI Academic Programs Office.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September, 2005

Beschreibung: Minor and trace element records from planktic and benthic foraminifera from Atlantic sediment cores, as well as outputfrom a coupled OA·GCM, were used to investigate the magnitude and distribution of the oceanic response to abrupt Climate events.of the past 20,000 years. The study addressed three major questions: 1) What is the magnitude of high-latitude sea surface temperature and salinity variability during abrupt climate events? 2) Does intermediate depth ventilation change in conjunction with high-latitude climate variability? 3) Are the paleoclimate data consistent with the response of a coupled OAGCM to a freshwater perturbation? To address these questions, analytical methods were implemented for the simultaneous measurement of Mg/Ca, Zn/Ca, Cd/Ca, Mn/Ca and All Ca in foraminiferal samples using inductively-coupled plasma mass spectrometry. Paired records of planktic foraminiferal ()IRO and Mg/Ca from the subpolar North Atlantic reveal trends of increasing temperatures (-3°C) and salinities over the course of the Holocene. The records provide the first evidence of open':'ocean cooling (nearly 2°C) and freshening during the 8.2 kyr event, and suggest similar conditions at 9.3 ka. Benthic foraminiferal Cd/Ca results from an intermediate depth, western South Atlantic core (l,268 ni) are consistent with reduced export into the South Atlantic of North Atlantic Intermediate Water during the Younger Dryas. Paired records. of benthic foraminiferal Mg/Ca and bIRO from two intermediate depth low latitude western Atlantic sites - one from the Florida Current (751 m) and one from the Little Bahama Bank (l,057 m) - provicie insights into the spatial distribution of intermediate depth temperature and sii!.inity variability during" the Younger Dryas. The intermediate depth paleoceanographic temperature and salinity data are consistent with the results of a GFDL R30 freshwater forced model simulation, suggesting that freshwater forcing is a possible driver or amplifier for B011ing-Aller0d to Younger Dryas climate variability. Benthic foraminiferal Cd/Ca results from an intermediate depth Florida Current core (751 m) are consistent with a decrease in the northward penetration of southern source waters within the return flow of the Atlantic meridional overturning circulation (MOC) and an increase in the influence of intermediate depth northern source waters during the Younger Dryas.

Beschreibung: This work was funded by a John Lyons Fellowship and a WHOI Ocean and Climate Change Institute Fellowship. Analyses were funded by the Ocean and Climate Change Institute and the following grants from the National Science Foundation: OCE98-86748, OCE02- 20776, OCE96-33499,ATM05-01391, and OCE04-02565.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Science at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution March, 1980

Beschreibung: The Southern Ocean as defined here is the body of water between the Antarctic Continent and the Antarctic Polar Front, (APF). This ocean is considered important in the global thermodynamic balance of the ocean-atmosphere system because large planetary heat losses are believed to occur at high latitudes. The ocean and atmosphere must transport heat poleward to balance these losses. In the Southern Hemisphere, the oceanic contribution to this flux involves a southward transport of heat across the APF into the Southern Ocean where it is given up to the atmosphere through air-sea interactions. In Part I, the air-sea interactions and structure of the near surface waters of the Southern Ocean are investigated with a three dimensional time dependent numerical model. The surface waters in this region in summer are characterized by a relatively warm surface mixed layer with low salinity. Below this layer, a cold temperature extremum is usually observed in vertical profiles which is believed to be the remnant of a deep surface mixed layer produced in winter. The characteristics of this layer, the surface mixed layer and the observed distribution of wintertime sea ice are reproduced well by this model. Unlike some other sea-ice models the air-sea heat exchange is a free variable. Model estimates of the annual heat loss by the Southern Ocean exhibit the observed meridional variation of heat gained by the ocean along the APF with heat lost further south. The model's area average heat loss is much smaller than that estimated with direct observations. While several model parameterizations were made which could be in error, the model results suggest that the Southern Ocean does give up vast amounts of heat to the atmosphere away from the continental margins. The model results and direct calculations of air-sea exchanges suggest a southward heat flux must occur across the APF. The lateral water mass transition across the front is not discontinuous but occurs over a finite sized zone of fluid which is dominated by intrusive finestructure. The characteristics and dynamics of these features are investigated in Part II to try and assess their importance in the meridional heat budget. Observations made on two cruises to the APF are presented and the space-time scales of the features and thermohaline characteristics are discussed. It is suggested that double diffusive processes dominated by salt fingering are active within the intrusions. An extension of Stern's (1967) model of the stability of a thermohaline front to intrusive finestructure driven by saltfingering where small scale viscous processes are included, is presented to explain why intrusions are observed in frontal zones. The model successfully predicts vertical scales of intrusions observed in the ocean and the observed dependence of the intrusions' slopes across density surfaces on the vertical scale. Since the fastest growing intrusion is not strongly determined by the model, though, it is likely that finite amplitude effects determine the dominant scale of interleaving in the ocean. The analysis predicts that intrusions transport heat, salt and density down the mean gradients of the front. For the APF, this heat flux is poleward which is the direction required by the global heat budget. This model does not describe intrusions at finite amplitude or in steady state and so cannot be used to estimate the magnitude of the poleward heat flux due to intrusions in the APF.

Beschreibung: The research reported on here, and my support as a graduate student was provided by the National Science Foundation through grants OCE 75 14056. OCE 76 82036 and OCE 77 28355.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February, 2006

Beschreibung: Benthic and planktonic foraminiferal δ18O (δ18Oc) from a suite of well-dated, high-resolution cores spanning the depth and width of the Straits of Florida reveal significant changes in Gulf Stream cross-current density gradient during the last millennium. These data imply that Gulf Stream transport during the Little Ice Age (LIA: 1200-1850 A.D.) was 2-3 Sv lower than today. The timing of reduced flow is consistent with cold conditions in Northern Hemisphere paleoclimate archives, implicating Gulf Stream heat transport in centennial-scale climate variability of the last 1,000 years. The pattern of flow anomalies with depth suggests reduced LIA transport was due to weaker subtropical gyre wind stress curl. The oxygen isotopic composition of Florida Current surface water (δ18O w) near Dry Tortugas increased 0.4% during the course of the Little Ice Age (LIA: ~1200-1850 A.D.), equivalent to a salinity increase of 0.8-1.5 psu. On the Great Bahama Bank, where smface waters are influenced by the North Atlantic subtropical gyre, δ18Ow increased by 0.3% during the last 200 years. Although a portion (~0.1%) of this shift may be an artifact of anthropogenically-driven changes in surface water ΣCO2, the remaining δl8Ow signal implies a 0.4 to 1 psu increase in salinity after 200 yr BP. The simplest explanation of the δ18Ow data is southward migration of the Atlantic Hadley circulation during the LIA. Scaling of the δ18Ow records to salinity using the modern low-latitude δ18Ow-S slope produces an unrealistic reversal in the salinity gradient between the two sites. Only if C180 w is scaled to salinity using a high-latitude δ18Ow-S slope can the records be reconciled. Changes in atmospheric 14C paralleled shifts in Dry Tortugas δ18Ow , suggesting that variable solar irradiance paced centennial-scale Hadley cell migration and changes in Florida Current salinity during the last millennium.

Beschreibung: I would also like to thank the National Science Foundation (NSF grant OCE-0096469) and WHOI Academic Programs for supporting this work.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution August 1982

Beschreibung: In an effort to understand the more general mechanisms and rates of pre-depositional reactions that transform organic matter, the types and relevant time scales of reactions that transform carotenoid pigments in the oceanic water column were studied. Suspended particulate matter collected from surface waters of Buzzards Bay, Massachusetts and the Peru upwelling system has a carotenoid distribution reflecting the phytoplanktonic source of the material. The carotenoid distribution of sediment trap samples collected in these same areas was dominated by transformation products. Fucoxanthin, the primary carotenoid of marine diatoms, typically constituted 77-100% of the total fucopigments in suspended particulate material. In sediment trap samples this pigment constituted only 4-85% of the total. The remaining 15-96% of the pigments consisted of the fucoxanthin transformations products: free alcohols (2-94%), dehydrates (0-6%), and opened epoxides (0-19%). Preliminary results suggest that carotenoid esters are hydrolyzed to free alcohols at a rate determined by the turnover of primary productivity. The dehydrated and epoxide opened intermediates of fucoxanthin represent products of transformation reactions that operate over much longer time scales (0.1-10 yrs). Dehydration and epoxide opening are not significant water column transformations, but are important in surface sediments.

Beschreibung: This research was supported by the Ocean Sciences Section, National Science Foundation grants OCE 79-25352 and OCE 81-18436, the Office of Naval Research Contract N00014-74-Co-262NR 083-004, the Woods Hole Coastal Research Center project 25 000067 04, and a Woods Hole Oceanographic Institution Student Fellowship.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution May 1980

Beschreibung: This study of particulate matter in the water column and the underlying surface sediments verifies the occurrence of local, present-day resuspension in the deep sea. The location of the major portion of this work was the South Iceland Rise, a region influenced by the flow of Norwegian Sea Overflow Water. Measured current velocities exceeded 20 cm/sec in the axis of the bottom current for the duration of the deployments, approximately two weeks. Particulate matter was sampled with Niskin bottles, to obtain the standing crop of suspended matter and with sediment traps, to obtain the material in flux through the water column. Box cores were taken to obtain surface sediment samples for comparison with the trap samples. Suspended particulate matter (SPM) and light-scattering studies demonstrate that in the Iceland Rise area the correlation of the L-DGO nephelometer to concentration of SPM differs between clear water and the nepheloid layer. Correlations of light scattering to SPM concentration also differ regionally, but for predicting concentration from light scattering, regression lines at two locations are indistinguishable. Particle size distributions have lower variance in the nepheloid layer than those in clear water which have roughly equal volumes of material in logarithmically increasing size grades from 1-20 μm. Apparent density differences between SPM in clear water and the nepheloid layer are not distinguishable in the Iceland Rise study; apparent densities increase in the nepheloid layer in the western North Atlantic. An apparent density of 1.1 g/cm3 adequately separates clear water from nepheloid layer samples in this region. Compositional variations seen between clear water and the nepheloid layer include a decrease in small coccoliths and an increase in clays and mineral matter. These compositional variations are more dramatic in the western North Atlantic region, due to dissolution of carbonate at the seafloor, later resuspended into the nepheloid layer. Sedimentological evidence of resuspension and redistribution of material are: 1) presence of sediment drifts throughout the Iceland Basin; 2) occurrence of coarse, glacial age sediments beneath the axis of the bottom current; and 3) differences in mineralogy, carbonate and organic carbon contents between surface sediments beneath the bottom current and those in a channel. A comparison of the vertical flux of material measured by sediment traps at 500 meters above bottom (mab) with the accumulation rate in cores, shows that the present-day surface input is an order of magnitude smaller than the accumulation rate. This observation suggests transport of material into some sections of the region by bottom currents or by turbidity currents. The horizontal flux of particulate matter into and out of the region by the bottom current is 100 kg/sec. This material may contribute to the formation of Gardar sediment drift downstream. The trends in % CaC03 and % organic carbon through the water column and in the surface sediments suggest that dissolution of carbonate and decomposition and consumption of organic carbon occurs primarily at the seafloor. These data also suggest preferential preservation at channel stations and/or preferential erosion beneath the bottom current. A comparison of sediment-trap samples with box-core surface samples further supports present-day resuspension. Benthic foraminifera, iron-oxidicoated planktonic foraminifera and the glacial, subpolar planktonic foraminifera (Neogloboquadrina pachyderma (sinistral)) in traps at 10,100 and a few specimens at 500 mab, provide conclusive evidence for local resuspension. The coarse fraction (〉125 μm) of the sediment trap material collected at 10 mab comprises 21-34% of the samples Calculations indicate that this material is locally derived (few kilometers) resuspended material.

Beschreibung: This work was financially supported by the Woods Hole Oceanographic Institution, ONR through contracts N00014-79-C-00-7l NR 083-004, N00014-74-C0262 NR 083-004, and N00014-75-C-029l and ERDA through contracts 13-7923 and 13-2559.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 2007.

Beschreibung: The water circulation and evolution of water temperature over the inner continental shelf are investigated using observations of water velocity, temperature, density, and bottom pressure; surface gravity waves; wind stress; and heat flux between the ocean and atmosphere during 2001-2007. When waves are small, cross-shelf wind stress is the dominant mechanism driving cross-shelf circulation. The along-shelf wind stress does not drive a substantial cross-shelf circulation. The response to a given wind stress is stronger in summer than winter. The cross-shelf transport in the surface layer during winter agrees with a two-dimensional, unstratified model. During large waves and onshore winds the cross-shelf velocity is nearly vertically uniform, because the wind- and wave-driven shears cancel. During large waves and offshore winds the velocity is strongly vertically sheared because the wind- and wave-driven shears have the same sign. The subtidal, depth-average cross-shelf momentum balance is a combination of geostrophic balance and a coastal set-up and set-down balance driven by the cross-shelf wind stress. The estimated wave radiation stress gradient is also large. The dominant along-shelf momentum balance is between the wind stress and pressure gradient, but the bottom stress, acceleration, Coriolis, Hasselmann wave stress, and nonlinear advection are not negligible. The fluctuating along-shelf pressure gradient is a local sea level response to wind forcing, not a remotely generated pressure gradient. In summer, the water is persistently cooled due to a mean upwelling circulation. The cross-shelf heat flux nearly balances the strong surface heating throughout midsummer, so the water temperature is almost constant. The along-shelf heat flux divergence is apparently small. In winter, the change in water temperature is closer to that expected due to the surface cooling. Heat transport due to surface gravity waves is substantial.

Beschreibung: My last three years of thesis work were supported by National Aeronautics and Space Administration Headquarters under the Earth System Science Fellowship Grant NNG04GQ14H, and by WHOI Academic Programs Fellowship Funds. I also benefited from the freedom of a Clare Boothe Luce Fellowship during my first year in the Joint Program, which allowed me more time than is usual to explore different research topics before choosing an advisor. This research was also funded by the National Aeronautics and Space Administration under grant NNG04GL03G and the Ocean Sciences Division of the National Science Foundation under grants OCE-0241292 and OCE-0548961. The Martha's Vineyard Coastal Observatory is partly funded by the Woods Hole Oceanographic Institution and the Jewett/EDUC/Harrison Foundation. The ADCP deployments at CBLAST site F were funded by National Science Foundation Small Grant for Exploratory Research OCE-0337892. Ship time for deployment and recovery of the F ADCP was provided by Robert Weller through Office of Naval Research contracts N00014-01-1-0029 and N00014-05-10090 for the Low-Wind Component of the Coupled Boundary Layers Air-Sea Transfer Experiment.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Master of Science at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 2003

Beschreibung: In this thesis I have endeavored to determine the factors and physical processes that controlled SST and thermocline depth at 10°N, 125°W during the Pan American Climate Study (PACS) field program. Analysis based on the PACS data set, TOPEX/Poseidon sea surface height data, European Remote Sensing satellite wind data, and model simulations and experiments reveals that the dominant mechanisms affecting the thermocline depth and SST at the mooring site during the measurement period were local surface fluxes, Ekman pumping, and vertical mixing associated with enhancement of the vertical shear by strong near-inertial waves in the upper ocean superimposed upon intra-seasonal baroclinic Rossby waves and the large scale zonal flow.

Beschreibung: This work was funded under NOAA Grant NA17RJ1223 and I also gratefully acknowledge receipt of an MIT Presidential Fellowship in 2000-2001.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 2003

Beschreibung: The cosmogenic radionuclide 10Be is a unique tracer of shallow sediment subduction in volcanic arcs. The range in 10Be enrichment in the Central American Volcanic Arc between Guatemala and Costa Rica is not controlled by variations in 10Be concentrations in subducting sediment seaward of the Middle America Trench. Sedimentary 10Be is correlated negatively with 143Nd/144Nd, illustrating that 10Be concentrations varied both between and within cores due to mixing between terrigenous clay and volcanic ash endmember components. This mixing behavior was determined to be a function of grain size controls on 10Be concentrations. A negative correlation of bulk sedimentary 10Be concentrations with median grain size and a positive correlation with the proportion of the sediment grains that were 〈32 μm in diameter demonstrated that high concentrations of 10Be in fine-grained, terrigenous sediments were diluted by larger grained volcanogenic material. The sharp decrease in 10Be enrichment in the Central American Volcanic Arc between southeastern Nicaragua and northwestern Costa Rica correlates with changes in fault structure in the subducting Cocos plate. Offshore of Nicaragua, extensional faults associated with plate bending have throw equal to or greater than the overlying subducting sediment thickness. These faults enable efficient subduction of the entire sediment package by preventing relocation of the décollement within the downgoing sediments. Offshore of Costa Rica, the reduction of fault relief results in basement faults that do not penetrate the overlying sediment. A conceptual model is proposed in which the absence of significant basement roughness allows the décollement to descend into the subducting sediment column, leading to subsequent underplating and therefore removal of the bulk of the sediment layer that contains 10Be. Basement fault relief was linearly related to plate curvature and trench depth. The systematic shoaling of the plate from southeastern Nicaragua to northwestern Costa Rica is not explained by changes in plate age for this region. Instead, it is hypothesized that the flexural shape of the plate offshore of southeastern Nicaragua and northwestern Costa Rica represents a lateral response to a buoyant load caused by the thick crust and elevated thermal regime in the Cocos plate offshore of southeastern Costa Rica.

Beschreibung: Funding for this work was provided by the National Science Foundation Graduate Research Fellowship, the WHOI Ocean Ventures Fund, the WHOI Deep Ocean Institute Graduate Fellowship, and Geological Society of America Graduate Research Grant #7179-02.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution June 2003

Beschreibung: This thesis examines the evolution of a mud-dominated coastal sedimentary system on multiple time scales. Fine-grained systems exhibit different properties and behavior from sandy coasts, and have received relatively little research attention to date. Evidence is presented for shoreline accretion under energetic conditions associated with storms and winter cold fronts. The identification of energetic events as agents of coastal accretion stands in contrast to the traditional assumption that low-energy conditions are required for deposition of fine-grained sediment. Mudflat accretion is proposed to depend upon the presence of an unconsolidated mud sea floor immediately offshore, proximity to a fluvial sediment source, onshore winds, which generate waves that resuspend sediment and advect it shoreward, and a low tidal range. This study constrains the present influence of the Atchafalaya River on stratigraphic evolution of the inner continental shelf in western Louisiana. Sedimentary and acoustic data are used to identify the western limit of the distal Atchafalaya prodelta and to estimate the proportion of Atchafalaya River sediment that accumulates on the inner shelf seaward of Louisiana's chenier plain coast. The results demonstrate a link between sedimentary facies distribution on the inner shelf and patterns of accretion and shoreline retreat on the chenier plain coast.

Beschreibung: Among my funding sources was a two-year fellowship from the Clare Booth Luce Foundation. I have received research grants from the Geological Society of America Foundation (Grant 6873-01) and the American Association of Petroleum Geologists (Kenneth H. Crandall Memorial grant).

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution June 2003

Beschreibung: Inertial terms dominate the single-gyre ocean model and prevent western-intensification when the viscosity is small. This occurs long before the oceanically-appropriate parameter range. It is demonstrated here that the circulation is controlled if a mechanism for ultimate removal of vorticity exists, even if it is active only in a narrow region near the boundary. Vorticity removal is modeled here as a viscosity enhanced very near the solid boundaries to roughly parameterize missing boundary physics like topographic interaction and three dimensional turbulence over the shelf. This boundary-enhanced viscosity allows western-intensified mean flows even when the inertial boundary width, is much wider than the frictional region because eddies flux vorticity from within the interior streamlines to the frictional region for removal. Using boundary-enhanced viscosity, western-intensified calculations are possible with lower interior viscosity than in previous studies. Interesting behaviors result: a boundary-layer balance novel to the model, calculations with promise for eddy parameterization, eddy-driven gyres rotating opposite the wind, and temporal complexity including basin resonances. I also demonstrate that multiple-gyre calculations have weaker mean circulation than single-gyres with the same viscosity and subtropical forcing. Despite traditional understanding, almost no inter-gyre flux occurs if no-slip boundary conditions are used. The inter-gyre eddy flux is in control only with exactly symmetric gyres and free slip boundaries. Even without the inter-gyre flux, the multiple-gyre circulation is weak because of sinuous instabilities on the jet which are not present in the single-gyre model. These modes efficiently flux vorticity to the boundary and reduce the circulation without an inter-gyre flux, postponing inertial domination to much smaller viscosities. Then sinuous modes in combination with boundary-enhanced viscosity can control the circulation.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Master of Science at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 2008

Beschreibung: The work was motivated by studies of Austin and Lentz (2002) and Pedlosky (2007). The above mentioned works considered two different responses of the stratified flow to a downwelling favorable wind forcing. The first study investigated a time dependent flow with a formation of a constantly expanding relatively well mixed region near the shore and the second considered a steady flow that arises when an offshore varying wind is applied. In my thesis I use ROMS to determine which type of response will take place based on the wind amplitude near the coast. It was demonstrated that if the value of the wind is much smaller than the critical value (determined by the stratification, the rotation rate and the horizontal diffusivity) then the flow is steady (the bbl case) and similar to the one investigated by Pedlosky. If the wind is of the order, or larger than, the critical value then the response is time dependent (the pool case) and similar to the one described by Austin and Lentz. The resulting flow structure of each response was also investigated. I examined the sensitivity of the bbl response to variations in the background vertical diffusivity, the initial stratification and the bottom slope. It was shown that a higher background vertical diffusivity, a higher stratification and a shallower bottom slope correspond to thinner (vertically) and narrower (horizontally) bbl. For the pool case the time dependent structure was also examined, using a number of idealized models. It was shown that the rate of the pool region expansion is a complex function of the local wind stress amplitude and the local depth.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Master of Science at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 2008

Beschreibung: Coupled ocean/atmosphere simulations exhibit systematicwarm biases over the SouthWest African (SWA) coastal region. Recent investigations indicate that coastal ocean dynamics may play an important role in determining the SST patterns, but none of them provide a detailed analysis. In this study, I analyze simulations produced both by coupled models and by idealized models. Then results are interpreted on the basis of a theoretical framework. Finally the conclusion is reached that the insufficient resolution of the ocean component in the coupled model is responsible for the warm biases over the SWA coastal region. The coarse resolution used in the ocean model has an artificially stretched coastal side-wall boundary layer, which induces a smaller upwelling velocity in the boundary layer. The vertical heat transport decreases even when the volume transport is unchanged because of its nonlinear relationship with the magnitude of the upwelling velocity. Based on the scaling of the idealized model simulations, a simplified calculation shows that the vertical heat transport is inversely proportional to the zonal resolution over the coastal region. Therefore, increasing the horizontal resolution can considerably improve the coastal SST simulation, and better resolve the coastal dynamics.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Master of Science at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution May 2001

Beschreibung: A comparison of monthly biogeochemical measurements made from 1993 to 1995, combined with hydrography and satellite altimetry, was used to observe the impacts of nine eddy events on primary productivity and particle flux in the Sargasso Sea. Measurements of primary production, thorium-234 flux, nitrate+nitrite, and photosynthetic pigments made at the US JGOFS Bermuda Atlantic Time-series Study (BATS) site were used. During the three years of this study, four out of six high thorium- 234 flux events over 1000 dpm/m2/d occurred during the passage of an eddy. Primary production nearly as high as the spring bloom maximum was observed in two modewater eddies (May 1993 and July 1995). The 1994 spring bloom at BATS was suppressed by the passage of an anticyclone. Distinct phytoplankton community shifts were observed in mode-water eddies, which had an increased percentage diatoms and dinoflagelletes, and in cyclones, which had an increased percentage cyanobacteria (excluding Prochlorococcus). The difference in the observations of mode-water eddies and cyclones may result from the age of the eddy, which was very important to the biological response. In general, eddies that were one to two months old elicited a large biological response; eddies that were three months old may show a biological response and were accompanied by high thorium flux measurements; eddies that were four months old or older did not show a biological response or high thorium flux. Our conceptual model depicting the importance of temporal changes during eddy upwelling and decay fit the observations well in all 7 upwelling eddies. Additional information is needed to determine the importance of deeper mixed layers and winter mixing to the magnitude of the eddy impacts. Also, sampling generally captured only the beginning, end, and lor edge of an eddy due to the monthly to semi-monthly frequency of the measurements made at BATS. Lagrangian studies, higher resolution time-series, and/or more spatial coverage is needed to provide additional information for improved C and N budgets in the Sargasso Sea and to complete our understanding of the temporal changes that occur in an eddy.

Beschreibung: Funding for this work was provided by NASA and NSF through the JGOFS Synthesis and Modeling Program.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 2009

Beschreibung: Estimates of natural climate variability during the past millennium provide a frame of reference in which to assess the significance of recent changes. This thesis investigates new methods of reconstructing low-latitude sea surface temperature (SST) and hydrography, and combines these methods with traditional techniques to improve the present understanding of western North Atlantic climate variability. A new strontium/calcium (Sr/Ca) - SST calibration is derived for Atlantic Montastrea corals. This calibration shows that Montastrea Sr/Ca is a promising SST proxy if the effect of coral growth is considered. Further analyses of coral growth using Computed Axial Tomography (CAT) imaging indicate growth in Siderastrea corals varies inversely with SST on interannual timescales. A 440-year reconstruction of low-latitude western North Atlantic SST based on this relationship suggests the largest cooling of the last few centuries occurred from ~1650-1730 A.D., and was ~1ºC cooler than today. Sporadic multidecadal variability in this record is inconsistent with evidence for a persistent 65-80 year North Atlantic SST oscillation. Volcanic and anthropogenic radiative forcing are identified as important sources of externally-forced SST variability, with the latter accounting for most of the 20th century warming trend. An 1800-year reconstruction of SST and hydrography near the Gulf Stream also suggests SSTs remained within about 1ºC of modern values. This cooling is small relative to other regional proxy records and may reflect the influence of internal oceanic and atmospheric circulation. Simulations with an atmospheric general circulation model (AGCM) indicate that the magnitude of cooling estimated by proxy records is consistent with tropical hydrologic proxy records.

Beschreibung: Funding for this research was provided by a National Science Foundation Graduate Student Fellowship, National Science Foundation grants OCE-0402728, OCE-0623364, ATM-033746, the WHOI Ocean and Climate Change Institute, the WHOI Ocean Ventures Fund, the WHOI Ocean Life Institute, the MIT Student Assistance Fund, award number USA-0002, made by King Abdullah University of Science and Technology (KAUST), and the Inter-American Institute for Global Change Research.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution December 1985

Beschreibung: Samples from time-series sediment traps deployed in three distinct oceanographic settings (North Pacific, Panama Basin, and Black Sea) provide strong evidence for rapid settling of marine particles by aggregates. Particle water column residence times were determined by measuring the time lag between the interception of a flux event in a shallow trap and the interception of the same event in a deeper trap at the same site. Effective sinking speeds were determined by dividing the vertical offset of the traps (meters) by the interception lag time (days). At station Papa in the North Pacific, all particles settle at 175 m day-1, regardless of their composition, indicating that all types of material may be settling in common packages. Evidence from the other two sites (Panama Basin and Black Sea) shows that particle transport may be vertical, lateral, or a combination of directions, with much of the Black Sea flux signal being dominated by lateral input. In order to ascertain whether marine snow aggregates represent viable transport packages, surveys were conducted of the abundance of these aggregates at several stations in the eastern North Atlantic and Panama Basin using a photographic technique. Marine snow aggregates were found in concentrations ranging from ~1 mm3 liter-1 to more than 500 mm3 liter-1. In open ocean environments, abundances are higher near the surface (production) and decline with depth (decomposition). However, in areas near sources of deep input of resuspended material, concentrations reach mid-water maxima, reflecting lateral transport. A model is proposed to relate the observed aggregate abundances, time series sediment flux and inferred circulation. In this model, depthwise variations in sediment flux and aggregate abundance result from suspension from the sea floor and lateral transport of suspended aggregates which were produced or modified on the sea floor. Temporal changes in sediment flux result from variations in the input of fast-sinking material which falls from the surface, intercepts the suspended aggregates, and transports them to the sea floor. A new combination sediment trap and camera system was built and deployed in the Panama Basin with the intent of measuring the flux of marine snow aggregates. This device consists of a cylindrical tube which is open at the top and sealed at the bottom by a clear plate. Material lying on the bottom plate is illuminated by strobe lights mounted in the wall of the cylinder and photographed by a camera which is positioned below the bottom plate. Flux is determined as the number of aggregates arriving during the time interval between photographic frames (# area-1 time-1). Results show that essentially all material arrives in the form of aggregates with minor contributions of fecal pellets and solitary particles. Sinking speeds (m day-1), calculated by dividing the flux of aggregates (# m-2 day-1) by their abundance (# m-3), indicate that the larger (4-5mm) aggregates are flocculent and sink slowly (~1m day-1) while the smaller aggregates (1-2.5mm) are more compact and sink more quickly (~36m day-1). These large, slow-sinking aggregates may have been re-suspended from the sediment water interface at nearby basin margins.

Beschreibung: This research was supported by ONR contract numbers N00014-82-C-0019 and N00014-85-C-0001, NSF grant numbers OCE-83-09024, OCE-84-17106, and DPP-85-01152 and the WHO1 education office.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 1986

Beschreibung: A study of the remineralization of organic carbon was conducted in the organic-rich sediments of Buzzards Bay, MA. Major processes affecting the carbon chemistry in sediments are reflected by changes in the stable carbon isotope ratios of dissolved inorganic carbon (ΣCO2) in sediment pore water. Six cores were collected seasonally over a period of two years. The following species were measured in the pore waters: ΣCO2, δ13C-ΣCO2, PO4, ΣH2S, Alk, DOC, and Ca. Measurements of pore water collected seasonally show large gradients with depth, which are larger in summer than in winter. The δ13C (PDB) of ΣCO2 varies from 1.3 o/oo in the bottom water to approximately -10 o/oo at 30 cm. During all seasons, there was a trend towards more negative values with depth in the upper 8 cm due to the remineralization of organic matter. There was a trend toward more positive values below 8 cm, most likely due to biological irrigation of sediments with bottom water. Below 16-20 cm, a negative gradient was re-established which indicates a return to remineralization as the main process affecting pore water chemistry. Using the ΣCO2 depth profile, it was estimated that 67-85 gC/m2 are oxidized annually and 5 gC/m2-yr are buried. The amount of carbon oxidized represented remineralization occurring within the sediments. This estimate indicated that approximately 20% of the annual primary productivity reached the sediments. The calculated remineralization rates varied seasonally with the high of 7.5 x 10-9 mol/L-sec observed in August 84 and the low (0.6 x 10-9) in December 83. The calculated remineralization rates were dependent on the amount of irrigation in the sediments; if the irrigation parameter is known to ±20%, then the remineralization rates are known to this certainty also. The amount of irrigation in the sediments was estimated using the results of a seasonal study of 222Rn/22R6a disequilibria at the same study site (Martin, 1985). Estimates of the annual remineralization in the sediments using solid-phase data indicated that the solid-phase profiles were not at steady-state concentrations. The isotopic signature of ΣCO2 was used as an indicator of the processes affecting ΣCO2 in pore water. During every month, the oxidation of organic carbon to CO2 provided over half of the carbon added to the ΣCO2 pool. However, in every month, the δ13C of ΣCO2 added to the pore water in the surface sediments was greater than -15 o/oo, significantly greater than the δ13C of solid-phase organic carbon in the sediments (-20.6 o/oo). The δ13C of ΣCO2 added to the pore water in the sediments deeper than 7 cm was between -20 and -21 o/oo, similar to the organic carbon in the sediments. Possible explanations of the 13C-enrichment observed in the surface sediments were: a) significant dissolution of CaC0, (δ13C = + 1.7 o/oo), b) the addition of significant amounts of carbonate ion from bottom water to pore water, c) an isotopic difference between the carbon oxidized in the sediments and that remaining in the sediments. The effect of CaCO3 dissolution was quantified using measured dissolved Ca profiles and was not large enough to explain the observed isotopic enrichment. An additional source of 13C-enriched carbon was bottom water carbonate ion. In every month studied, there was a net flux of ΣCO2 from pore water to bottom water. The flux of pore water ΣCO2 to bottom water ranged from a minimum of 10 x 10-12 mol/cm2-sec in December 83 to a maximum of 50 x 10-12 mol/cm2-sec in August 84. However, because the pH of bottom water was about 8 while that of the pore water was less than or equal to 7, the relative proportion of the different species of inorganic carbon (H2CO*3, HCO-3, CO2-3 was very different in bottom water and pore water. Thus, while there was a net flux of ΣCO2 from pore water to bottom water, there was a flux of carbonate ion from bottom water to pore water. Because bottom water ΣCO2 was more 13C-enriched than pore water ΣCO2, the transfer of bottom water carbonate ion to pore water was a source of 13C-enriched carbon to the pore water. If the δ13C of CO2 added to the pore water from the oxidation of organic carbon was -20.6 o/oo, then the flux of Co2-3 from bottom water to pore water must have been 10-30% of the total flux of ΣCO2 from pore water to bottom water. This is consistent with the amount calculated from the observed gradient in carbonate ion. Laboratory experiments were conducted to determine whether the δ13C of CO2 produced from the oxidation of organic carbon (δ13C-OCox) was different from the δ13C of organic carbon in the sediments (δ13C-SOC). In the laboratory experiments, mud from the sampling site was incubated at a constant temperature. Three depths were studied (0-3, 10-15, and 20-25 cm). For the first study (IE1), sediment was stirred to homogenize it before packing into centrifuge tubes for incubation. For the second study (IE2), sediment was introduced directly into glass incubation tubes by subcoring. The second procedure greatly reduced disturbance to the sediment. Rates of CO2 production were calculated from the concentrations of ΣCO2 measured over up to 46 days. In both studies, the values of Rc in the deeper intervals were about 10% of the surface values. This was consistent with the field results, although the rates decreased more rapidly in the field. In all cases, the remineralization rates during the beginning of IE1 were much greater than those at the beginning of IE2. The sediment for IE1 was collected in February 84. The measured value of Rc in the surface sediment of the laboratory experiment (24 x 10-9 mol/L-sec) was much greater than the value of Rc observed in the field in another winter month, December 83 (.62 x 10-9). The sediment for IE2 was collected in August 85. The measured values of Rc in the surface sediment (6.6-12 x 10-9 mol/L-sec) were consistent with the field values from August 84 (7.5 x 10-9). The ΣCO2 results indicated that IE2 reproduced field conditions more accurately than IE1 did. The isotopic results from the experiments strongly suggested that δ13C-OCox in the surface sediments (-17.8 o/oo ± 1.9 o/oo) was greater than δ13C-SOC (-20.6 ± 0.2 o/oo). The magnitude of the observed fractionation was small enough that the observed values of δ13C-ΣCO2 in the pore waters could be explained by fractionated oxidation coupled with the diffusion of carbonate ion from bottom water to pore water. The observed fractionation was most likely due to the multiple sources of organic carbon to coastal sediments. A study of the natural levels of radiocarbon In these sediments indicated that the carbon preserved in the sediments is approximately 30% terrestrial while the rest is from phytoplankton.

Beschreibung: Financial support was provided by the Education Office of the Massachusetts Institute of Technology/Woods Hole Oceanographic Institution Joint Program In Oceanography, by an Andrew W. Mellon Foundation grant to the Coastal Research Center, WHOI, and by the National Science foundation under grant NSF OCE83-15412.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution April 1975

Beschreibung: The influence of natural short-term fluctuations in environmental parameters on three components of transient benthic invertebrate community structure: abundance of individuals and species, biomass of individuals, and species diversity, were investigated in this study. The effect of low dissolved-oxygen on transient benthic community structure was studied with samples from Golfo Dulce, an intermittently anoxic basin off the west coast of Costa Rica and the Posa de Cariaco, an anoxoic trench off the north coast of Venezuela. Periodic fluctuations in oxygen concentration were accompanied by a community numerically dominated by a single polychaete species and low species diversity. As the frequency of fluctuations in oxygen concentration decreased, the number of species and individuals in the community increased with a corresponding increase in species diversity. In contrast to fluctuating oxygen conditions which eliminated many species from the community, fluctuating amounts of suspended matter in the bottom water allowed one species to proliferate while maintaining the total species list length. High rates of terrigenious sedimentation occurring naturally off the Spanish Sahara coast produced conditions which apparently hampered the feeding mechanisms of a spionid polychaete. Further offshore, where the diversity should be expected to increase, the spionids were able to flourish. The result was greater numerical abundance and biomass offshore and a lower transient diversity value. Results of simulation of catastophic burial by in situ burial of small isolated portions of Buzzards Bay sediment indicated that sedimentation rates recorded off Spanish Sahara would not eliminate species by burial. However, the small size of the organisms found off Spanish Sahara is probably a result of the constant expenditure of energy for escape. In regions of fluctuating environmental conditions, diversity values are low, principally because of dominance by a single species. Increasingly stable conditions, even though stressful, result in a more even distribution of individuals among the species present and a correspondingly high transient value.

Beschreibung: This work was funded by a Woods Hole Oceanographic Institution Predoctoral Fellowship, N.S.F. Grant GA-3655l, and N.S.F. Grant GA-33502.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution August 1984

Beschreibung: This thesis addresses several aspects of the problem of determining the effect of the low-frequency eddy variability on the mean circulation of the Western North Atlantic. A framework for this study is first established by scale analysis of the eddy and mean terms in the mean momentum, vorticity, and heat balances in three regions of the Western North Atlantic -- the northern recirculation, the southern recirculation, and the mid-ocean. The data from the last decade of field experiments suggest somewhat different conclusions from the earlier analysis of Harrison (1980). In the momentum balance we confirm that the eddy terms are negligible compared to the lowest order mean geostrophic balance. The eddy term may be an 0(1) term in the vorticity balance only in the northern recirculation region where the mean flow is anisotropic. In the mean heat balance, if the mean temperature advection is scaled using the thermal wind relation, then the eddy heat flux is negligible in the mid-ocean, but it may be important in the recirculation areas. For all the balances the eddy terms are comparable to or an order of magnitude larger than the mean advective terms. We conclude from the scale analysis that the eddy field is most likely to be important in the Gulf Stream recirculation region. These balances are subsequently examined in more detail using data from the Local Dynamics Experiment (LDE). Several inconsistencies are first shown in McWilliams' (1983) model for the mean dynamical balances in the LDE. The sampling uncertainties do not allow us to draw conclusions about the long-term dynamical balances. However, it is shown that if we assume that the linear vorticity balance holds between the surface and the thermocline for a finite record, then the vertical velocity induced by the eddy heat flux divergence is non-zero. The local effect of the mesoscale eddy field on the mean potential vorticity distribution of the Gulf Stream recirculation region is determined from the quasigeostrophic eddy potential vorticity flux. This flux is calculated by finite difference of current and temperature time series from the Local Dynamics Experiment. This long-term array of moorings is the only experimental data from which the complete eddy flux can be calculated. The total eddy flux is dominated by the term due to the time variation in the thickness of isopycnal layers. This thickness flux is an order of magnitude larger than the relative vorticity flux. The total flux is statistically significant and directed 217° T to the southwest with a magnitude of 1.57 x 10 -5 cm/2s. The direction of the eddy flux with respect to the mean large scale potential vorticity gradient from hydrographic data indicates that eddies in this region tend to reduce the mean potential vorticity gradient. The results are qualitatively consistent with numerical model results and with other data from the Gulf Stream recirculation region. We find that the strength of the eddy transfer in the enstrophy cascade is comparable to the source terms in the mean enstrophy balance. The Austauch coefficient for potential vorticity mixing is estimated to be 0(107cm2/sec). An order of magnitude estimate of the enstrophy dissipation due only to the internal wave field shows that other processes must be important in enstrophy dissipation. The measured eddy potential vorticity fluxes are compared to the linear stability model of Gill, Green, and Simmons (1974). An earlier study (Hogg, 1984) has shown agreement between the empirical orthogonal modes of the data and the predicted wavenumbers, growth rates, and phase speeds of the most unstable waves. However, we show substantial disagreement in a comparison of the higher moments the eddy heat and potential vorticity fluxes. Because the critical layer of the model is located near the surface, the model predicts that most of the eddy potential vorticity and eddy heat flux should occur within about 300 meters of the surface. The data show much greater deep eddy heat flux than predicted by the model. It is suggested that the unstable modes in the ocean have a longer vertical scale because of the reduction in the buoyancy frequency near the surface. The evidence for in situ instability is also examined in the decay region of the Gulf Stream from an array of current and temperature recorders. Although there is vertical phase propagation in the empirical orthogonal modes for some of the variables at some of the moorings, there is not much evidence for a strong ongoing process of wave generation.

Beschreibung: This research has been conducted under NSF contract numbers OCE 77-19403, ATM 79-21431, and OCE 82-00154.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Science at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution August 1987

Beschreibung: Several problems connected by the theme of thermal forcing are addressed herein. The main topic is the stratification and flow field resulting from imposing a specified heat flux on a fluid that is otherwise confined to a rigid insulating basin. In addition to the traditional eddy viscosity and diffusivity, turbulent processes are also included by a convective overturning adjustment at locations where the local density field is unstable. Two classes of problems are treated. The first is the large scale meridional pattern of a fluid in an annulus. The detailed treatment is carried out in two steps. In the beginning (chapter 2) it is assumed that the fluid is very diffusive, hence, to first approximation no flow field is present. It is found that the convective overturning adjustment changes the character of the stratification in all the regions that are cooled from the top, resulting in a temperature field that is nearly depth independent in the northernmost latitudes. The response to a seasonal cycle in the forcing, and the differences between averaging the results from the end of each season compared to driving the fluid by a mean forcing are analyzed. In particular, the resulting sea surface temperature is warmer in the former procedure. This observation is important in models where the heat flux is sensitive to the gradient of air to sea surface temperatures. The analysis of the problem continues in chapter 5 where the contribution of the flow field is included in the same configuration. The dimensionless parameter controlling the circulation is now the Rayleigh number, which is a measure of the relative importance of gravitational and viscous forces. The effects of the convective overturning adjustment is investigated at different Rayleigh numbers. It is shown that not only is the stratification now always stable, but also that the vigorous vertical mixing reduces the effective Rayleigh number; thereby the flow field is more moderate, the thermocline deepens, and the horizontal surface temperature gradients are weaker. The interior of the fluid is colder compared to cases without convective overturning, and, because the amount of heat in the system is assumed to be fixed, the surface temperature is warmer. The fluid is not only forced by a mean heat flux, or a seasonally varying one, but its behavior under permanent winter and summer conditions is also investigated. A steady state for the experiments where the net heat flux does not vanish is defined as that state where the flow field and temperature structure are not changing with time except for an almost uniform temperature decrease or increase everywhere. It is found that when winter conditions prevail the circulation is very strong, while it is rather weak for continuous summer forcing. In contrast to those results, if a yearly cycle is imposed, the circulation tends to reach a minimum in the winter time and a maximum in the summer. This suggests that, depending on the Rayleigh number, there is a phase leg of several months between the response of the ocean and the imposed forcing. Differences between the two averaging procedures mentioned before are also observed when the flow field is present, especially for large Rayleigh numbers. The circulation is found to be weaker and the sea surface temperature colder in the mean of the seasonal realizations compared to the steady state derived by the mean forcing. As an extension to the numerical results, an analytic model is presented in chapter 4 for a similar annular configuration. The assumed dynamics is a bit different, with a mixed layer on top of a potential vorticity conserving interior. It is demonstrated that the addition of the thermal wind balance to the conservation of potential vorticity in the axially symmetric problem leads to the result that typical fluid trajectories in the interior are straight lines pointing downward going north to south. The passage of information in the system is surprisingly in the opposite sense to the clockwise direction of the flow. A model for water mass formation by buoyancy loss in the absence of a flow field is introduced in chapter 3. The idea behind it is to use the turbulent mixing parameterization to generate chimney-like structures in open water, followed by along-isopycnal advection and diffusion. This model can be applied to many observations of mode water. In particular, in this work it is related to the chimneys observed by the MEDOC Group (1970), and the Levantine Intermediate Water in the Eastern Mediterranean Basin. An analytic prediction of the depth of the water mass is derived and depends on the forcing and initial stratification. It suggests that the depth of shallow mode water like the 18°C water or the Levantine Intermediate Water would not be very sensitive to reasonable changes in atmospheric forcing. Similar conclusions were also reached by Warren (1972) by assuming that the temperature in the thermocline decreases linearly with depth, and by approximating the energy balance in a water column by a Newtonian cooling law.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution June 2010

Beschreibung: Observational and modeling techniques are employed to investigate the thermal and inertial upper ocean response to wind and buoyancy forcing in the North Atlantic Ocean. First, the seasonal kinetic energy variability of near-inertial motions observed with a moored profiler is described. Observed wintertime enhancement and surface intensification of near-inertial kinetic energy support previous work suggesting that near-inertial motions are predominantly driven by surface forcing. The wind energy input into surface ocean near-inertial motions is estimated using the Price-Weller- Pinkel (PWP) one-dimensional mixed layer model. A localized depth-integrated model consisting of a wind forcing term and a dissipation parameterization is developed and shown to have skill capturing the seasonal cycle and order of magnitude of the near-inertial kinetic energy. Focusing in on wintertime storm passage, velocity and density records from drifting profiling floats (EM-APEX) and a meteorological spar buoy/tethered profiler system (ASIS/FILIS) deployed in the Gulf Stream in February 2007 as part of the CLIvar MOde water Dynamics Experiment (CLIMODE) were analyzed. Despite large surface heat loss during cold air outbreaks and the drifting nature of the instruments, changes in the upper ocean heat content were found in a mixed layer heat balance to be controlled primarily by the relative advection of temperature associated with the strong vertical shear of the Gulf Stream. Velocity records from the Gulf Stream exhibited energetic near-inertial oscillations with frequency that was shifted below the local resting inertial frequency. This depression of frequency was linked to the presence of the negative vorticity of the background horizontal current shear, implying the potential for near-inertial wave trapping in the Gulf Stream region through the mechanism described by Kunze and Sanford (1984). Three-dimensional PWP model simulations show evidence of near-inertial wave trapping in the Gulf Stream jet, and are used to quantify the resulting mixing and the effect on the stratification in the Eighteen Degree Water formation region.

Beschreibung: This work was supported by National Science Foundation grants OCE-0241354 and OCE-0424865, as well as the Woods Hole Oceanographic Institution's Ocean and Cli- mate Change Institute. Funding to initiate the McLane Moored Pro ler observations at Line W were provided by grants from the G. Unger Vetlesen Foundation and the Comer Charitable Fund to the Woods Hole Oceanographic Institutions Ocean and Climate Change Institute.

Beschreibung: Author Posting. © American Meteorological Society, 2010. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 40 (2010): 789-801, doi:10.1175/2009JPO4039.1.

Beschreibung: The issue of internal wave–mesoscale eddy interactions is revisited. Previous observational work identified the mesoscale eddy field as a possible source of internal wave energy. Characterization of the coupling as a viscous process provides a smaller horizontal transfer coefficient than previously obtained, with vh 50 m2 s−1 in contrast to νh 200–400 m2 s−1, and a vertical transfer coefficient bounded away from zero, with νυ + (f2/N2)Kh 2.5 ± 0.3 × 10−3 m2 s−1 in contrast to νυ + (f2/N2)Kh = 0 ± 2 × 10−2 m2 s−1. Current meter data from the Local Dynamics Experiment of the PolyMode field program indicate mesoscale eddy–internal wave coupling through horizontal interactions (i) is a significant sink of eddy energy and (ii) plays an O(1) role in the energy budget of the internal wave field.

Beschreibung: Author Posting. © American Meteorological Society, 2008. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 38 (2008): 2556-2574, doi:10.1175/2008JPO3666.1.

Beschreibung: Vertical profiles of horizontal velocity obtained during the Mid-Ocean Dynamics Experiment (MODE) provided the first published estimates of the high vertical wavenumber structure of horizontal velocity. The data were interpreted as being representative of the background internal wave field, and thus, despite some evidence of excess downward energy propagation associated with coherent near-inertial features that was interpreted in terms of atmospheric generation, these data provided the basis for a revision to the Garrett and Munk spectral model. These data are reinterpreted through the lens of 30 years of research. Rather than representing the background wave field, atmospheric generation, or even near-inertial wave trapping, the coherent high wavenumber features are characteristic of internal wave capture in a mesoscale strain field. Wave capture represents a generalization of critical layer events for flows lacking the spatial symmetry inherent in a parallel shear flow or isolated vortex.

Beschreibung: Salary support for this analysis was provided by Woods Hole Oceanographic Institution bridge support funds.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 1997

Beschreibung: In order to constrain the processes controlling the cycles of biogeochemically important gases such as 02 and C02, and thereby infer rates of biological activity in the upper ocean or the uptake of radiatively important "greenhouse" gases, the noble gases are used to characterize and quantify the physical processes affecting the dissolved gases in aquatic environments. The processes of vertical mixing, gas exchange, air injection, and radiative heating are investigated using a 2 year time-series of the noble gases, temperature, and meteorological data from Station S near Bermuda, coupled with a 1- dimensional upper ocean mixing model to simulate the physical processes in the upper ocean. The rate of vertical mixing that best simulates the thermal cycle is 1.1±0.1 x104 m The gas exchange rate required to simulate the data is consistent with the formulation of Wanninkhof (1992) to ± 40%, while the formulation of Liss and Merlivat 1986 must be increased by a factor of 1.7± 0.6. The air injection rate is consistent with the formulation of Monahan and Torgersen (1991) using an air entrainment velocity of 3±1 cm s1. Gas flux from bubbles is dominated on yearly time-scales by larger bubbles that do not dissolve completely, while the bubble flux is dominated by complete dissolution of bubbles in the winter at Bermuda. In order to obtain a high-frequency time-series of the noble gases to better parameterize the gas flux from bubbles, a moorable, sequential noble gas sampler was developed. Preliminary results indicate that the sampler is capable of obtaining the necessary data. Dissolved gas concentrations can be significantly modified by ice formation and melting, and due to the solubility of He and Ne in ice, the noble gases are shown to be unique tracers of these interactions. A three-phase equilibrium partitioning model was constructed to quantify these interactions in perennially ice-covered Lake Fryxell, and this work was extended to oceanic environments. Preliminary surveys indicate that the noble gases may provide useful and unique information about interactions between water and ice.

Beschreibung: This work has been supported by the National Science Foundation - OCE 9302812 and DPP 9118363, the Ocean Ventures Fund Ditty Bag Fund and Westcott Fund and the WHOI Education Office.

Beschreibung: Author Posting. © American Meteorological Society, 2011. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 41 (2011): 889–910, doi:10.1175/2010JPO4496.1.

Beschreibung: This paper examines interaction between a barotropic point vortex and a steplike topography with a bay-shaped shelf. The interaction is governed by two mechanisms: propagation of topographic Rossby waves and advection by the forcing vortex. Topographic waves are supported by the potential vorticity (PV) jump across the topography and propagate along the step only in one direction, having higher PV on the right. Near one side boundary of the bay, which is in the wave propagation direction and has a narrow shelf, waves are blocked by the boundary, inducing strong out-of-bay transport in the form of detached crests. The wave–boundary interaction as well as out-of-bay transport is strengthened as the minimum shelf width is decreased. The two control mechanisms are related differently in anticyclone- and cyclone-induced interactions. In anticyclone-induced interactions, the PV front deformations are moved in opposite directions by the point vortex and topographic waves; a topographic cyclone forms out of the balance between the two opposing mechanisms and is advected by the forcing vortex into the deep ocean. In cyclone-induced interactions, the PV front deformations are moved in the same direction by the two mechanisms; a topographic cyclone forms out of the wave–boundary interaction but is confined to the coast. Therefore, anticyclonic vortices are more capable of driving water off the topography. The anticyclone-induced transport is enhanced for smaller vortex–step distance or smaller topography when the vortex advection is relatively strong compared to the wave propagation mechanism.

Beschreibung: Y. Zhang acknowledges the support of theMIT-WHOI Joint Programin Physical Oceanography, NSF OCE-9901654 and OCE-0451086. J. Pedlosky acknowledges the support of NSF OCE- 9901654 and OCE-0451086.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Master of Science at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 2011

Beschreibung: Remote sensing and in situ observations are used to investigate the ocean response to the Tokar Wind Jet in the Red Sea. The wind jet blows down the pressure gradient through the Tokar Gap on the Sudanese coast, at about 18°N, during the summer monsoon season. It disturbs the prevailing along-sea (southeastward) winds with strong cross-sea (northeastward) winds that can last from days to weeks and reach amplitudes of 20-25 m/s. By comparing scatterometer winds with along-track and gridded sea level anomaly observations, it is shown that an intense dipolar eddy spins up in less than seven days in response to the wind jet. The eddy pair has a horizontal scale of 140 km. Maximum ocean surface velocities can reach 1 m/s and eddy currents extend at least 200 m into the water column. The eddy currents appear to cover the width of the sea, providing a pathway for rapid transport of marine organisms and other drifting material from one coast to the other. Interannual variability in the strength of the dipole is closely matched with variability in the strength of the wind jet. The dipole is observed to be quasi-stationary, although there is some evidence for slow eastward propagation—simulation of the dipole in an idealized high-resolution numerical model suggests that this is the result of self-advection. These and other recent in situ observations in the Red Sea show that the upper ocean currents are dominated by mesoscale eddies rather than by a slow overturning circulation.

Beschreibung: This work is supported by Award Nos. USA 00002, KSA 00011 and KSA 00011/02 made by King Abdullah University of Science and Technology (KAUST).

Beschreibung: Author Posting. © American Meteorological Society, 2011. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 24 (2011): 4844–4858, doi:10.1175/2011JCLI4130.1.

Beschreibung: The factors that determine the heat transport and overturning circulation in marginal seas subject to wind forcing and heat loss to the atmosphere are explored using a combination of a high-resolution ocean circulation model and a simple conceptual model. The study is motivated by the exchange between the subpolar North Atlantic Ocean and the Nordic Seas, a region that is of central importance to the oceanic thermohaline circulation. It is shown that mesoscale eddies formed in the marginal sea play a major role in determining the mean meridional heat transport and meridional overturning circulation across the sill. The balance between the oceanic eddy heat flux and atmospheric cooling, as characterized by a nondimensional number, is shown to be the primary factor in determining the properties of the exchange. Results from a series of eddy-resolving primitive equation model calculations for the meridional heat transport, overturning circulation, density of convective waters, and density of exported waters compare well with predictions from the conceptual model over a wide range of parameter space. Scaling and model results indicate that wind effects are small and the mean exchange is primarily buoyancy forced. These results imply that one must accurately resolve or parameterize eddy fluxes in order to properly represent the mean exchange between the North Atlantic and the Nordic Seas, and thus between the Nordic Seas and the atmosphere, in climate models.

Beschreibung: This study was supported by the National Science Foundation under Grants OCE-0726339 and OCE-0850416.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution June 2012

Beschreibung: Observations from a three-year field program on the inner shelf south of Martha's Vineyard, MA and a numerical model are used to describe the effect of stratification on inner shelf circulation, transport, and sediment resuspension height. Thermal stratification above the bottom mixed layer is shown to cap the height to which sediment is resuspended. Stratification increases the transport driven by cross-shelf wind stresses, and this effect is larger in the response to offshore winds than onshore winds. However, a one-dimensional view of the dynamics is not sufficient to explain the relationship between circulation and stratification. An idealized, cross-shelf transect in a numerical model (ROMS) is used to isolate the effects of stratification, wind stress magnitude, surface heat flux, cross-shelf density gradient, and wind direction on the inner shelf response to the cross-shelf component of the wind stress. In well mixed and weakly stratified conditions, the cross-shelf density gradient can be used to predict the transport efficiency of the cross-shelf wind stress. In stratified conditions, the presence of an along-shelf wind stress component makes the inner shelf response to cross-shelf wind stress strongly asymmetric.

Beschreibung: This work was supported through National Science Foundation grant no. OCE-0548961, the WHOI Academic Programs Office, and the WHOI Coastal Ocean Institute.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Master of Science at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 1990

Beschreibung: An acoustic tomography experiment consisting of a source near Hawaii and seven receivers along the west coast of North America was conducted from November 1987 to May 1988 and from February 1989 to July 1989. In this thesis, the acoustic ray travel times are analyzed in order to investigate inter-annual basin-scale thermal variability. These thermal fluctuations may help detect any greenhouse warming and greater understanding of them will increase knowledge of ocean-atmosphere interactions which affect weather and climate. A discussion of the program for finding the travel times is included along with a comparison of two methods of measuring travel times.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution June 1990

Beschreibung: A recently developed technique for determining past sea surface temperatures (SST), based on an analysis of the unsaturation ratio of long chain C37 methyl alkenones (Uk37) produced by Prymnesiophyceae phytoplankton, has been applied to late Quaternary sediment cores. Previous studies have shown that the Uk37 ratio of these alkenones is linearly proportional to the sea-water temperature in which the plankton grow, both in culture and water column samples. Furthermore, a reasonable correlation has been found between open ocean paleo-SST estimates based on Uk37 values and those derived from δ180, for the period spanning approximately the last 100,000 years (Brassell, 1986b). These results indicate this technique has potential for determining paleo-SST from analysis of alkenones extracted from marine sediments. In order to apply the Uk37 method quantitatively, it is necessary to calibrate the method for sediment samples, and to assess how well the alkenones maintain their temperature signal under some common conditions of sediment deposition and sample handling. It is also necessary to determine the method's usefulness downcore, that is, back in time, by comparing it to established methods. This study examined the effect on Uk37 of conditions that cause dissolution of carbonates in the sediment, and methods of storage and 'sample handling. These are two problems that must be resolved before the method can be applied rigorously and quantitatively to sediments for paleotemperature estimations. A comparison of duplicate samples collected and stored frozen versus those stored at room temperature for up to four years showed no resolvable differences in Uk37. Laboratory experiments of carbonate dissolution indicated there is no effect on Uk37 values under the acidic conditions that dissolve carbonates. Initial field results support this, but indicate more studies are necessary. The Uk37 "thermometer" was calibrated by analyzing Uk37 in coretops from widely varying open ocean sites. Sediment values of Uk37 reflected overlying SST for the appropriate season of the phytoplankton bloom, which for this study was assumed to be summer in high latitudes. These results fall on the same regression line for culture and water column samples derived by Prahl and Wakeham (1987), indicating that their equation (Uk37 = 0.033 T + 0.043) is suitable for use in converting Uk37 values in sediments to overlying SST for the season of coccolith bloom. Using this calibration for sediments, the Uk37 paleotemperature method can be quantitatively applied down core to open ocean sediments. In the Equatorial Atlantic, Uk37 temperature estimates were compared to those obtained from δ18O of the planktonic foraminifer Globigerinoides sacculifer, and planktonic foraminiferal assemblages for the last glacial cycle. The alkenone method showed ~1.56°C cooling at the last glacial maximum. This is about half the decrease shown by both the isotopic method ( ~3.40°C) and foraminiferal assemblages (~3.75°C), implying that, if Uk37 estimates are correct, SST in the equatorial Atlantic was only reduced slightly in the last glaciation. In the Northeast Atlantic, Uk37 temperature estimates show a profile downcore which is similar to the estimates from foram assemblages but with a constant offset toward warmer values throughout the core. Uk37 SST estimates are substantially warmer than foraminiferal estimates at all times, which may indicate inaccuracy in Uk37 temperatures at this site. Uk37 indicates a SST of 12°C for the late glacial and 18°C for the Recent, whereas assemblages give estimates of 9°C and 13°C, respectively. At 12,700 yrs BP, the Uk37 and foram assemblage methods indicate a 2°C warming. A temperature change of 2°C can account for only 0.44°/oo of the observed 1.2°/oo δ18O signal, indicating that the additional 0.8°/oo change in δ18O must result from changes in surface salinity most likely due to a meltwater lid. Uk37 estimates show the major temperature shift from glacial to interglacial temperatures occured at about 9,000 yrs BP disagreeing with assemblage data which shows the shift to Holocene values at about 12,700 yrs BP. If Uk37 temperature estimates are accurate, this disagreement may reflect differing habitats of flora and fauna under the unusual sea surface conditions in this area during the deglaciation.

Beschreibung: Primary financial support for this research came from the Ocean Ventures Fund (grant 25/ 85.08), without which this project would not have been possible. Funding supporting the labs of John Farrington (OCE 88-11409) and Lloyd Keigwin (OCE 83-08893 and ATM 84-14335) in which I worked also provided funding for part for this research.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 1996

Beschreibung: This thesis addresses the question of how a highly energetic eddy field could be generated in the interior of the ocean away from the swift boundary currents. The energy radiation due to the temporal growth of non-trapped (radiating) disturbances in such a boundary current is thought to be one of the main sources for the described variability. The problem of stability of an energetic current, such as the Gulf Stream, is formulated. The study then focuses on the ability of the current to support radiating instabilities capable of significant penetration into the far-field and their development with time. The conventional model of the Gulf Stream as a zonal current is extended to allow the jet axis to make an angle to a latitude circle. The linear stability of such a nonzonal flow, uniform in the along-jet direction on a beta-plane, is first studied. The stability computations are performed for piece-wise constant and continuous velocity profiles. New stability properties of nonzonal jets are discussed. In particular, the destabilizing effect of the meridional tilt of the jet axis is demonstrated. The radiating properties of nonzonal currents are found to be very different from those of zonal currents. In particular, purely zonal flows do not support radiating instabilities, whereas flows with a meridional component are capable of radiating long and slowly growing waves. The nonlinear terms are then included in the consideration and the effects of the nonlinear interactions on the radiating properties of the solution are studied in detail. For these purposes, the efficient numerical code for solving equation for the QG potential vorticity with open boundary conditions of Orlanski's type is constructed. The results show that even fast growing linear solutions, which are trapped during the linear stage of developement, can radiate energy in the nonlinear regime if the basic current is nonzonal. The radiation starts as soon as the initial fast exponential growth significantly slows. The initial trapping of those solutions is caused by their fast temporal growth. The new mechanism for radiation is related to the nonzonality of a current.

Beschreibung: This work was supported by NSF Grant OCE 9301845.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February 2013

Beschreibung: Studying oceanic eddies is important for understanding and predicting ocean circulation and climate variability. The central focus of this dissertation is the energy exchange between eddies and mean flow and banded structures in the low-frequency component of the eddy field. A combination of a realistic eddy-permitting ocean state estimate and simplified theoretical models is used to address the following specific questions. (1) What are the major spatial characteristics of eddy-mean flow interaction from an energy perspective? Is eddy-mean flow interaction a local process in most ocean regions? (2) The banded structures in the low-frequency eddy field are termed striations. How much oceanic variability is associated with striations? How does the time-mean circulation, for example a subtropical gyre or constant mean flow, influence the origin and characteristics of striations? How much do striations contribute to the energy budget and tracer mixing?

Beschreibung: This research was supported by the National Aeronautics and Space Administration contracts NNX09AI87G and NNX08AR33G.

Beschreibung: Author Posting. © American Meteorological Society, 2013. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 43 (2013): 283–300, doi:10.1175/JPO-D-11-0240.1.

Beschreibung: Motivated by the recent interest in ocean energetics, the widespread use of horizontal eddy viscosity in models, and the promise of high horizontal resolution data from the planned wide-swath satellite altimeter, this paper explores the impacts of horizontal eddy viscosity and horizontal grid resolution on geostrophic turbulence, with a particular focus on spectral kinetic energy fluxes Π(K) computed in the isotropic wavenumber (K) domain. The paper utilizes idealized two-layer quasigeostrophic (QG) models, realistic high-resolution ocean general circulation models, and present-generation gridded satellite altimeter data. Adding horizontal eddy viscosity to the QG model results in a forward cascade at smaller scales, in apparent agreement with results from present-generation altimetry. Eddy viscosity is taken to roughly represent coupling of mesoscale eddies to internal waves or to submesoscale eddies. Filtering the output of either the QG or realistic models before computing Π(K) also greatly increases the forward cascade. Such filtering mimics the smoothing inherent in the construction of present-generation gridded altimeter data. It is therefore difficult to say whether the forward cascades seen in present-generation altimeter data are due to real physics (represented here by eddy viscosity) or to insufficient horizontal resolution. The inverse cascade at larger scales remains in the models even after filtering, suggesting that its existence in the models and in altimeter data is robust. However, the magnitude of the inverse cascade is affected by filtering, suggesting that the wide-swath altimeter will allow a more accurate determination of the inverse cascade at larger scales as well as providing important constraints on smaller-scale dynamics.

Beschreibung: BKA received support from Office of Naval Research Grant N00014-11-1-0487, National Science Foundation (NSF) Grants OCE-0924481 and OCE- 09607820, and University of Michigan startup funds. KLP acknowledges support from Woods Hole Oceanographic Institution bridge support funds. RBS acknowledges support from NSF grants OCE-0960834 and OCE-0851457, a contract with the National Oceanography Centre, Southampton, and a NASA subcontract to Boston University. JFS and JGR were supported by the projects ‘‘Global and remote littoral forcing in global ocean models’’ and ‘‘Agesotrophic vorticity dynamics of the ocean,’’ respectively, both sponsored by the Office of Naval Research under program element 601153N.

Beschreibung: 2013-08-01

Beschreibung: Author Posting. © American Geophysical Union, 2013. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 118 (2013): 762–773, doi:10.1002/jgrc.20081.

Beschreibung: Laboratory experiments are conducted to investigate the interactions of self-propagating barotropic cyclones and baroclinic anticyclones with an island. Results are interpreted in the context of observations around Okinawa Island, Japan, where ubiquitous arrivals of cyclones and anticyclones on the southeastern side of the island influence the flow around it, thereby impacting both the Ryukyu Current's and the Kuroshio's transport. In the laboratory, baroclinic anticyclones generate a buoyant current that flows clockwise around an island whereas barotropic cyclones generate a counterclockwise current. In both cases, the interaction is governed by conservation of circulation Γ around the island, which establishes a balance between the dissipation along the island in contact with the eddy and the dissipation along the island in contact with the generated current. Laboratory results and scaling analysis suggest that the interaction between an anticyclone (cyclone) and Okinawa Island should result in an instantaneous increase (decrease) of the Ryukyu Current transport and a delayed increase (decrease) of the Kuroshio transport. The estimated delays are in good agreement with those obtained with field measurements suggesting that the dynamics at play in the laboratory may be relevant for the flow around Okinawa Island.

Beschreibung: M.A.was supported by the Postdoctoral Scholar Program at the Woods Hole Oceanographic Institution, with funding provided by the Ocean and Climate Change Institute and by the Penzance Endowed Fund in Support of Assistant Scientists.

Beschreibung: 2013-08-13

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Master of Science at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 2013

Beschreibung: Between 2002 and 2011 a single mooring was maintained in the core of the Pacific Water boundary current in the Alaskan Beaufort Sea near 152° W. Using velocity and hydrographic data from six year-long deployments during this time period, we examine the interannual variability of the current. It is found that the volume, heat, and freshwater transport have all decreased drastically over the decade, by more than 80%. The most striking changes have occurred during the summer months. Using a combination of weather station data, atmospheric reanalysis fields, and concurrent shipboard and mooring data from the Chukchi Sea, we investigate the physical drivers responsible for these changes. It is demonstrated that an increase in summertime easterly winds along the Beaufort slope is the primary reason for the drop in transport. The intensification of the local winds has in turn been driven by a strengthening of the summer Beaufort High in conjunction with a deepening of the summer Aleutian Low. Since the fluxes of mass, heat, and freshwater through Bering Strait have increased over the same time period, this raises the question as to the fate of the Pacific water during recent years and its impacts. We present evidence that more heat has been fluxed directly into the interior basin from Barrow Canyon rather than entering the Beaufort shelfbreak jet, and this is responsible for a significant portion of the increased ice melt in the Pacific sector of the Arctic Ocean.

Beschreibung: The majority of the data for this project was funded by grant # ARC-0856244 from the O ce of Polar Programs of the National Science Foundation. My time at WHOI was funded by the United States Navy, the National Science Foundation Graduate Research Fellowship Program and the WHOI Academic Programs O ffice.

Beschreibung: The series of observations described in this report were planned with the double purpose of measuring the evaporation and transport of water vapor from the ocean into an unstable atmosphere, and of studying the diffusion processes operating in air of this stability class. Measured values of the evaporation from ocean surfaces were conspicuously absent from the meteorological literature until Craig and Montgomery (1949) published values for hydrostatically stable air. The present set of measurements extends our knowledge to include evaporation into a hydrostatically unstable air mass. In addition to evaporation values at the surface, net transports of water vapor at many levels up to 2000 meters have been measured.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution August, 1978

Beschreibung: A two-layer linear analytic model is used to study the response of the mid-latitude ocean to the seasonal variation of the windstress. The most important component of the response is a barotropic quasi-steady Sverdrup balance. A meridional ridge such as the Antilles Arc is modeled as an infinitely thin meridional barrier that blocks the lower layer but does not protrude into the upper layer. It is found that such a barrier has little effect on the upper layer flow across the barrier. This result is obtained provided the frequency of the motion is low enough so that free short Rossby waves are essentially nondivergent. In this case there is little coupling between the layers for energy propagating to the east away from the barrier. A study of the dynamics of flow over a sloping bottom is made and the results are used to determine the effect on seasonal oscillations of eastern boundary slopes and triangular ridges. It is found that the presence of a slope at the eastern boundary has little effect. A meridional ridge that does not reach the interface may cause substantial scattering of free Rossby waves, but unless the ridge is steep its effect on the quasi-steady Sverdrup balance is minimal. However, if the ridge height is a substantial fraction of the lower layer depth and the width is comparable to the scale of free short Rossby waves, the ridge will tend to block flow in the lower layer, acting like the infinitely thin barrier. The theory suggests that the Antilles Arc should have the effect of a thin barrier, while the Mid-Atlantic Ridge should have little effect on the response of the ocean to seasonal wind variations.

Beschreibung: For three and a half years of generous financial support I am grateful to the John and Fannie Hertz Foundation, from which I received a Graduate Fellowship. Research money and other support were provided by the National Science Foundation under contract OCE 77 15600.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution October, 1971

Beschreibung: The objective of this study was to describe the mechanics of wind wave generation and spectral development. Intermittency, high frequency microstructure in wind and wave fields, and strong nonlinear coupling involving a wide range of scales are shown to be crucial elements in the transfer of momentum to, from, and within the wave field. None of these elements are included in available theories. Measurements of wave height and of the turbulent atmospheric and subsurface boundary layers were made, from a small surface following platform and from a stable 38.5m spar buoy. The structure of moving gust patterns (cat's paws) is described and related to the generation of surface waves. Results from this and other background studies are then applied to a discussion of spectral growth during a two day period of active wave generation. Cat's paws contain 'bursts' of intense turbulent stress and buoyancy fluctuations separated by quiescent 'intervals'. There is a difference of over three orders of magnitude in fluctuation strength between these features. Rapid growth rate generation of high frequency surface waves and atmospheric turbulence occurs during the bursts. The resultant microscale components aid the growth of lower frequency instabilities by strong nonlinear coupling between scales of motion and by acting as drag or roughness elements. Evidence of strong coupling between frequency bands and of weakly resonant capillary-gravity wave interactions is presented. Thermal stratification has a strong influence on fluctuation magnitude and can delay the onset of surface wave generation. Major spectral growth is highly unsteady. Much of the momentum flux from air to sea occurs during intermittent events that are similar in nature to cat's paws, and goes directly into high frequency waves. The bursts occur predominantly over large groups of surface waves and involve strong nonlinear interactions between media and frequency bands. The long-term equilibrium balance between wind and water is disrupted by variations in surface currents. There are 'critical' wind speeds characterized by anomalous relationships between parameters of the predominantly logarithmic velocity profile.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution June, 1980

Beschreibung: This thesis consists of three papers applying the techniques of time series analysis to geophysical data. Surface wave dispersion along the Walvis Ridge, South Atlantic Ocean, is obtained by bandpass filtering the recorded seismogram in the frequency domain. The group velocity is anomalously low in the period range of 15-50 s, and formal inversion of the data indicates both crustal thickening to 12.5 km and low shear velocity (4.25-4.35 km/s) to depths of 40-50 km. The electromagnetic induction fields at a deep ocean site northeast of Hawaii were used to determine the electrical conductivity of the earth to 400 km depth. Singular value decomposition of the data matrix indicates three degrees of freedom, suggesting source field complications and a two dimensional conductive structure. Inversion of one of the principal terms in the response function shows an abrupt rise in electrical conductivity to 0.05 mho/m near 160 km with no resolvable decrease below this. A model study suggests that moving source fields influence the induction appreciably in the other principal response tunction. A set of piston cores from the northeast Atlantic Ocean are used to construct paleomagnetic time series covering the interval 25-127 kybp. Stratigraphic control is provided by counts of planktonic toraminifera, and empirical orthogonal function analysis shows a significant decrease in sedimentation rate at the interglaciai/glacial transition. The sediments are magnetically stable and reliable relative paleointensity measurements could be obtained. Spectral analysis of the directions reveals a predominant 10 ky periodicity and no dominant looping direction.

Beschreibung: I was supported for the early parts of this work by a NSF Graduate Fellowship. The Walvis Ridge study was supported by the WHOI Education Office and the Defense Advanced Research Projects Agency. The induction study was funded by the NSF under grants OCE74-12730 and OCE77-8633, and by the WHOI Ocean Industries Program. The paleomagnetic study was supported by NSF contracts OCE77-82255 and ÖCE79-19258.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Master of Science at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 2006

Beschreibung: The impact of the Greenland tip jet on the wintertime mixed-layer of the southwest Irminger Sea is investigated using in-situ moored profiler data and a variety of atmospheric data sets. The mixed-layer was observed to reach 400 m in the spring of 2003, and 300 m in the spring of 2004. Both of these winters were mild and characterized by a low North Atlantic Oscillation (NAO) index. All of the storms that were advected through the region were tracked, and the tip jet events that occurred throughout the two winters were identified. Composite images of the tip jets elucidated the conditions during which tip jets were likely to take place, which led to an objective method of determining tip jet occurrences by taking into account the large-scale pressure gradients. Output from a trajectory model indicates that the air parcels entering a tip jet accelerate and descend as they are deflected around southern Greenland. A heat flux timeseries for the mooring site was constructed that includes the enhancing influence of the tip jet events. This was used to drive a one-dimensional mixed-layer model, which was able to reproduce the observed mixed-layer deepening in both winters. All of the highest heat flux events took place during tip jets, and removal of the tip jets from the heat flux timeseries demonstrated their importance in driving convection east of Greenland. The deeper mixed-layer of the first winter was in large part due to a higher number of robust tip jet events, which in turn was caused by a greater number of storms passing northeast of southern Greenland. This interannual change in storm tracks was attributable to a difference in upper level steering currents. Application of the mixed-layer model to the winter of 1994-l995, during a period characterized by a high NAO index, resulted in convection reaching 1600 m. This predict ion is consistent with concurrent hydrographic data, supporting the notion that deep convection can occur in the Irminger Sea during strong winters.

Beschreibung: Financial support for this work was provided by National Science Foundation grant OCE-0450658.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Master of Science at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution June 2006

Beschreibung: The continuous supply of heat and fresh water from the boundaries to the interior of the Labrador Sea plays an important role for the dynamics of the region and in particular, for the Labrador Sea Water formation. Thus, it is necessary to understand the factors governing the exchange of properties between the boundary and interior. A significant fraction of heat and fresh water, needed to balance the annual heat loss and to contribute to the seasonal freshening of the Labrador Sea, is thought to be provided by coherent long-lived anticyclonic eddies shed by the Irminger Current. The population, some properties, rates and direction of propagation of these anomalies are known but the evolution and the mechanism of their decay are still far from obvious. In this work I investigated their water mass properties and evolution under the strong wintertime forcing using hydrographic data from 1990-2004 and a 1-dimensional mixed layer model. There were 50 eddies found in the hydrographic data record, 48 of which were identified as anticyclones. Vertical structure of the eddies was investigated, leading to the categorization of all the anticyclones into three classes: 12 - with a fresh surface layer and no mixed layer, 18 - without a fresh layer and at least one mixed layer, and 18 with ambiguous vertical structure. Four eddies of the second group appeared to have cores extending to as deep as 1500 m vertically and an isopycnal displacement of 400-600 m. A number of eddies without a fresh water cap contained Labrador Sea Water from the previous year at mid-depths.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 2005

Beschreibung: The fate of trace metals in contaminated coastal sediments is poorly understood, yet critical for effective coastal management. The aim of this thesis is to investigate and quantify the mechanisms leading to the release of silver, lead and copper across the sediment-water interface. Two contrasting sites were investigated, a heavily contaminated site in Boston Harbor and a less impacted, offshore site in Massachusetts Bay. High-resolution porewater and solid phase samples were collected in each season to determine the diagenetic cycles and chemistry controlling the fate of these metals. The trace metals are scavenged by iron oxyhydroxides and released to the porewaters when these oxides are reduced. At the strongly reducing site in Boston Harbor, there is seasonal transfer of trace metals from oxide phases in winter, to sulfides phase in summer. At the Massachusetts Bay site, due to the lack of sulfide, the metals are focused into the surface oxide layer, giving a solid phase enrichment. There is a diffusive flux of copper to the water column throughout the year, while silver is released only in winter. Lead is strongly scavenged and is rarely released to the overlying waters. Analysis of reduced sulfur compounds in the porewaters has shown that there is also a significant flux of these strong ligands to the overlying waters. Polysulfide species enhance the solubility of copper within the porewaters. Sediment resuspension fluxes were quantified using an erosion chamber. Sediment resuspension leads to enhanced release of dissolved metals and is especially important in redistributing contaminants as the first particles to be eroded are enriched in trace metals. The total release of dissolved metals from the sediments by diffusion and sediment resuspension is estimated to be 60% and 10% of the riverine flux for copper and lead respectively. With continued pollution control reducing the discharge of metals from other sources, the benthic release of metals will become increasingly important terms in the metal budget of Boston Harbor.

Beschreibung: Tills work is a result of research sponsored by the NOAA National Sea Grant College Program Office, Department of Commerce, under Grant. No. NA16RG2273, Woods Hole Oceanographic Institution Sea Grant Project Nos. 1-01-22227310 and 1-01-22227338. Additional funding was provided by the University of Western Australia Hackett Scholarship, the United States Geological Survey under Cooperative Agreement Number OOHQAGOOOI and the National Science Foundation under Grant OCE-0220892.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution August 1980

Beschreibung: Observational evidence of seasonal variability below the main thermocline in the eastern North Atlantic is described, and a theoretical model of oceanic response to seasonally varying windstress forcing is constructed to assist in the interpretation of the observations. The observations are historical conductivity-temperature-depth data from the Bay of Biscay region (2° to 20°W, 42° to 52°N), a series of eleven cruises over the three years 1972 through 1974, spaced approximately three months apart. The analysis of the observations utilizes a new technique for identifying the adiabatically leveled density field corresponding to the observed density field. The distribution of salinity anomaly along the leveled surfaces is examined, as are the vertical displacements of observed density surfaces from the leveled reference surfaces, and the available potential energy. Seasonal variations in salinity anomaly and vertical displacement occur as westward propagating disturbances with zonal wavelength 390 (±50) km, phase 71 (±30) days from 1 January, and maximum amplitudes of ±30 ppm and ±20 db respectively. The leveled density field varies seasonally with an amplitude corresponding to a thermocline displacement of ±15 db. The observations are consistent with the predictions of a model in which an ocean of variable stratification with a surface mixed layer and an eastern boundary is forced by seasonal changes in a sinusoidal windstress pattern, when windstress parameters calculated from the observations of Bunker and Worthington (1976) are applied.

Beschreibung: This work was supported by the Office of Naval Research under contract N00014~76-C-197, NR 083-400.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution November 1981

Beschreibung: Radiolarians which settle through the oceanic water column were recovered from three stations (western Tropical Atlantic-Station E, central Tropical Pacific-Pi and Panama Basin-PB) using PARLUX sediment traps in moored arrays at several depths. The taxonomic diversities of the radiolarian assemblages in the sediment traps were very high. A total of 420 taxa, including 23 newly identified taxa, were found at the three stations; of these, 208 taxa were found at station E. The polycystine radiolarians generally reach the sea floor with little change in abundance or species composition, although slight skeletal dissolution occurs throughout their descent. The phaeodarian radiolarians, on the other hand, are largely dissolved within the water column; only a few species reach the sea-floor and these dissolve rapidly at the sediment-water interface. Most radiolarian skeletons sink as individuals through deep water columns without being incorporated into large biogenic aggregates. Because significant numbers of nassellarian and phaeodarian species are deep-water dwelling forms the diversity index of radiolarians increases with increasing depth in the mesopelagic zone. The vertical flux of the total radiolarians arriving at the trap depths (in x 103 individuals/m2/day) ranged from 16-24 (E), 0.6-17 (Pl), and 29-53 (PB). Of these on the average 25% and 69% of the total radiolarian flux is transported by Spumellaria and Nassellaria, respectively, while 5% is carried by Phaeodaria. The measured Si02 content of the skeletons averaged 91, 98 and 71% of measured weight for Spumellaria, Nassellaria and Phaeodaria, respectively. The supply of radiolarian silica (mg Si02/m2/day) to each trap depth ranged from 2.5-4.0 (E), 0.9-3.2 (Pl), and 5.7-10.4 (PB). The Radiolaria appear to be a significantly large portion of the Si02 flux in 〉63 pm size fraction and thus play an important role in the silica cycle. When the radiolarian fluxes at the three Stations are compared with Holocene radiolarian accumulation rates in the same areas it became apparent that several percent or less of the fluxes are preserved in the sediments in all cases and the rest is dissolved on the sea-floor. Estimated excess Si which is derived from Si02 dissolution on the sea-floor is fairly small relative to advective Si in the western North Atlantic and thus it appears to be insignificant to show any deviation in a simple mixing curve of deep water masses. Weight, length, width, projected area and volume of 58 radiolarian taxa were measured. The density contrast of radiolarians, relative to seawater, generally falls between 0.01 and 0.5 g/cm3. The sinking speed of 55 radiolarian taxa, measured in the laboratory at 3°C, ranged from 13 to 416 m/day. Despite the wide variety of morphology between the species, sinking speeds were best correlated with weight/shell among all the possible combinations of the examined variables. The estimated residence times of these taxa in the 5 km pelagic water column ranged from 2 weeks to 14 months. Large phaeodarians reached the water-sediment interface relatively quickly and ultimately dissolved on the sea floor. Small-sized taxa dissolved en route during sinking. The standing stock of 26 examined abundant taxa is on the order of 1 to 100 shells/m3. Total radiolarian standing stock ranges from about 450 shells/m3 at Stations Pl and E to 1200 shells/m3 at Station PB. The rate of production of total Radiolaria is calculated to be 77 to 225 shells/m3 /day. The turnover time for these species ranges from several days to one month depending on the species and the assumption of the depth interval used for the estimation.

Beschreibung: This thesis work has been supported by the National Science Foundation, Submarine Geology and Geophysics Program, Grant OCE80-l9386 and the Woods Hole Oceanographic Institution Education Office.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February 2003

Beschreibung: Prevailing wisdom holds that the vertical distribution of molybdenum (Mo) in the open ocean is conservative, despite Mo's important biological role and association with Mn oxides and anoxic sediments. Mo is used in both nitrogenase, the enzyme responsible for Nz fixation, and nitrate reductase, which catalyzes assimilatory and dissimilatory nitrate reduction. Laboratory culture work on two Nz fixing marine cyanobacteria, Trichodesmium and Crocosphaera, and a marine facultative denitrifier, Marinobacter hydrocarbanoclasticus, showed that Mo cell quotas in these organisms were positively correlated with Mo-containing enzyme activity. Mo concentrations in Crocosphaera dropped almost to blank levels when not fixing Nz suggesting daily synthesis and destruction of the entire nitrogenase enzyme and release of Mo. Trichodesmium cultues, however, retained a pool of cellular Mo even when not fixing Nz. Colonies of Trichodesmium collected in the field have Mo:C tenfold higher than seen in culture, these Mo:C ratios were reflected in SPM samples from the same region. Fe:C ratios for Trichodesmium were between 12-160 μmol:mol in field and cultured samples. The Fe:C ratio of Crocosphaera was established to be 15.8±11:3 under Nz fixing conditions. Mo cellular concentrations in cultured organisms were too small to significantly influence dissolved Mo distributions, but may slightly affect Suspended Particulate Matter (SPM) distributions. Mean SPM Mo:C ratios were slightly elevated in regions of Nz fixation and denitrification. A high precision (±0.5%) isotope dilution ICP-MS method for measuring Mo was developed to re-evaluate the marine distribution of Mo in the dissolved and particulate phase. Mn oxides were not found to significantly influence either the dissolved or SPM Mo distribution. Dissolved Mo profiles from the Sargasso and Arabian Sea were conservative. However, dissolved Mo profiles from the Eastern Tropical Pacific showed both depletion and enrichment of dissolved Mo possibly associated with interaction of Mo with coastal sediments. Dissolved Mo profiles in several California Borderland Basins showed 1-2 nM Mo depletions below sill depth. A more focused study of water column response to sediment fluxes using the high precision Mo analyses is necessary to determine whether these phenomena are related.

Beschreibung: This work was funded by a grant from the National Science Foundation (#OCE-0096453) and the WHOI Academic Programs Ocean Ventures Fund. I have also been supported through WHOI by a NSF coastal traineeship #DGE-9454129, by the US GS Cooperative Agreement #USGS-OOHQAG001 and by WHOI Academic Programs.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution November 1992

Beschreibung: This thesis examines the degradation pathways of chlorophyll in the Black Sea water column and sediments. Measurements are made of total chlorophyll in sediment traps from two locations and depths in the water column, and at two locations in surface sediments. Individual chlorophyll degradation products are also identified. This data is used to construct a mass balance of chlorophyll production and sedimentation showing the major pathways for chlorophyll loss and the ultimate sedimentary sinks. The distribution of chlorophyll degradation products is also analyzed down core and related to environmental changes in the Black Sea Several new sinks for chlorophyll degradation products are identified. Steryl esters of pyropheophorbide-a are identified in sediment trap and sediment samples. It is thought that these compounds are formed during grazing. In sediment traps it is found that the distribution of the sterols esterified to pyropheophorbide-a change with season and that the sterols esterified are related to the distribution of sterols synthesized by the phytoplankton living in the photic zone at the time of production. Analysis of pyropheophorbide-a steryl esters in sediments shows the distribution of sterols to be quantitatively and qualitatively more similar to the distribution of free sterols in sediment traps than in sediments. The esterification of the sterols to pyropheophorbide-a apparently prevents the preferential removal of 4-desmethylsterols relative to 4-methylsterols during degradation of the sterol esters. Chlorophyll degradation products which are incorporated into high molecular weight material and material which is only accessible with strong acid are also identified. The chlorophyll degradation products incorporated into these structures represent only a few percent of the total structure. In the high molecular weight material, only phorbins derived from chlorophyll-a are identifies, where as in the acid extractable material, porphyrins are also identified. In surface sediments, the acid extractable chlorophyll degradations products and the solvent extractable macromolecular chlorophyll degradation products each comprise approximately 30% of total sedimentary chlorophyll degradation products. The acid extractable chlorophyll degradation products are identified in sediment trap samples, and evidence is presented for the occurrence of the solvent extractable macromolecular chlorophyll degradation products in sediment trap samples. Using data from sediment traps, sediments, and the literature, a mass balance of chlorophyll flux, degradation, and accumulation in the Black Sea is presented. In the photic zone, chlorophyll degradation products are either destroyed by photo-oxidation and grazing, or they are transported into the anoxic water column in large, rapidly sinking particles. Once the chlorophyll degradation products have reached the anoxic water column, they survive to be deposited in the underlying sediments. As a comparison, 25 times more total organic carbon reaches the anoxic water column than does total phorbin, but 75% of total organic carbon which reaches the anoxic water column is degraded, either in the anoxic water column or in the very surface sediments. Though a larger percentage of total organic carbon passes out of the photic zone, the phorbin macrocycle appears to be more stable under anoxic conditions than is total organic carbon. The chlorophyll which can be detected below the chemocline of the Black Sea in the form of chlorophyll degradation products will survive to be deposited in surface sediments. Once in sediments, chlorophyll degradation products are found in four different reservoirs: phorbin steryl esters, free phorbins, solvent extractable macromolecular chlorophyll degradation products, and acid extractable chlorophyll degradation products. Evidence for the occurrence of porphyrins in surface Black Sea sediments is also presented. The distribution of chlorophyll degradation products in Unit I Black Sea sediments varies greatly with sediment depth. The concentration of total phorbin generally increases with increasing burial depth, but the concentrations of the individual chlorophyll degradation products vary in a manner which is both dissimilar to total phorbin and to each other. No parent/daughter relationships for the chlorophyll degradation products are indicated by the data. The distribution of sterols esterified to pyropheophorbide-a changes with sediment depth with the largest qualitative changes occurring in strata where the total phorbin concentration shows the largest quantitative changes. It is suggested that the variations seen in the esterified sterols are related to changes in the phytoplankton community over time. From the presented data, it is also suggested that total phorbin concentration, normalized to total organic carbon, in Black Sea Unit I sediments is related to paleoprimary production. Several conclusions are drawn from the work presented in this thesis. There is approximately 3 times more chlorophyll-derived phorbin in Black Sea sediments than can be accounted for when considering only individual pheopigments, and therefore the sedimentary degradation of chlorophyll is much more complex than previously thought. In the anoxic sediments of the Black Sea, the total phorbin distribution can be accounted for with organically extractable high molecular weight degradation products, pyropheophorbide steryl esters, pheopigments, and acid extractable chlorophyll degradation products. The sterol distribution in the pyropheophorbide steryl esters may preserve the sterol distribution in surface waters as synthesized by the phytoplankton, and pyropheophorbide steryl esters are preserved in sediments over the long term.

Beschreibung: The work in this thesis was funded by grants from the Woods Hole Oceanographic Institution's Ocean Ventures Fund and the National Science Foundation contract numbers OCE88-14398, OCE90-17626, and OCE92-01178.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution August 1980

Beschreibung: Dissolved free amino acids (DFAA) were measured in interstitial water samples squeezed from sediments collected in a variety of depositional environments. These sediments were further characterized by measurements of total organic carbon, total nitrogen, dissolved organic carbon, total hydrolyzable amino acids, and pore water-dissolved remineralization products. Surface sediments from the oxygen minimum zone of the Peru Upwelling Region, which consisted of a filamentous bacterial mat, were sampled at three locations. DFAA concentrations within the mat ranged from 5 to 220 μM, with the highest concentrations found in the upper 4 cm at two stations on the landward and seaward edges of the zone, and lower concentrations at a station in the middle of the oxygen minimum zone. Within cores, lower concentrations were found at depths below the mat; and below 30 cm depth concentrations were between 0.7 and 3 μM. Two short cores of offshore sediments had concentrations between 14 and 40 μM (1400 m depth) and between 3 and 8 μM (5200 m). Glutamic acid was the predominant amino acid in nearly all surface sediments samples, making up 30 to 70 mole %. In sediments below 15 cm depth, β-aminoglutaric acid was often more abundant than glutamic acid and other amino acids were virtually absent. Glutamic acid, both from several analyses performed during this work and from data available in the literature is a major DFAA of bacterial pools, and bacteria are a likely source for the high concentrations seen in interstitial water samples. DFAA may be extracted from living cells by the squeezing process, or may be excreted by the bacteria under natural conditions. β-Aminoglutaric acid is s non-protein amino acid isomer of glutamic acid which has not been previously reported as a natural product. However, this work has shown it to be a constituent of the free amino acid pools of some bacteria at about 5 mole %. Its much larger relative abundance in sediments could stem from organisms which biosynthesize greater amounts than those analyzed, or from relatively slow biodegradation. Buzzards Bay, Massachusetts surface sediments (17 m water depth) also contained high DFAA concentrations, near; 50 μM, which decreased gradually with depth to about 5 μM at 30 cm. Glutamic acid and β-aminoglutaric acid were the major components, with β-aminoglutaric acid becoming relatively more abundant with depth in core. Repeated sampling of this station was carried out, and both the concentration and composition of DFAA in replicate samples was very similar. Sediments from the Pettaquamscutt River Estuary, Rhode Island (an anoxic basin), had low DFAA concentrations ranging from 2 to 6 μM. Glutamic and β-aminoglutaric acids made up 30 to 50 % of the total. Three cores of Gulf of Maine basin sediments had DFAA concentrations and compositions which were similar to each other and to Buzzards Bay sediments, except that glycine was a major constituent of some of the samples. Its distribution was irregular over the less than 30 cm depth intervals sampled. Glycine is the major DFAA in the pools of many benthic invertebrates. Its presence in these cores is consistent with independent evidence that Gulf of Maine basin sediments are extensively bioturbated. Two cores of carbonate-rich sediments from the continental rise to the east of the Gulf of Maine and from the Bermuda Rise had surface sediment DFAA concentrations of 33 and 0.9 μM, respectively. Despite the large difference in concentration, compositions were very similar, with glycine and glutamic acid the major constituents. The very low concentrations in the Bermuda Rise sediments may be related to very low metabolizable organic carbon concentrations. Two nonprotein amino acids, γ-aminobutyric acid and β-alanine, were major constituents of the total hydrolyzable amino acids in the Bermuda Rise sediments. Biological processes, specifically microbial, appear to be responsible for the major features of DFAA concentration and composition in the sediments studied. The concentrations of DFAA measured could be of significance to the nutrition of benthic organisms via transepidermal uptake or to the formation of humic substances in sediments, if these levels are found outside cells . However, as a sink for DFAA in sediments, the latter two processes are slow relative to microbial uptake.

Beschreibung: Financial support was provided by the Woods Hole Oceanographic Institution Education Office, the Paul M. Fye Fellowship, ONR Contract N00014-79-C-0071, and NSF Grant No. OCE 79-08665. Travel funds to Peru were provided by NSF Grant No. OCE 77-26180.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 2000

Beschreibung: Estimation of the upper ocean heat budget from one year of observations at a moored array in the north central Arabian Sea shows a rough balance between the horizontal advection and time change in heat when the one-dimensional balance between the surface heat flux and oceanic heat content breaks down. The two major episodes of horizontal advection, during the early northeast (NE) and late southwest (SW) monsoon seasons, are both associated with the propagation of mesoscale eddies. During the NE monsoon, the heat fluxes within the mixed layer are not significantly different from zero, and the large heat flux comes from advected changes in the thermocline depth. During the SW monsoon a coastal filament exports recently upwelled water from the Omani coast to the site of the array, 600 km offshore. Altimetry shows mildly elevated levels of surface eddy kinetic energy along the Arabian coast during the SW monsoon, suggesting that such offshore transport may be an important component of the Arabian Sea heat budget. The sea surface temperature (SST) and mixed layer depth are observed to respond to high frequency (HF, diurnal to atmospheric synoptic time scales) variability in the surface heat flux and wind stress. The rectified effect of this HF forcing is investigated in a three-dimensional reduced gravity thermodynamic model of the Arabian Sea and Indian Ocean. Both the HF heat and wind forcing act locally to increase vertical mixing in the model, reducing the SST. Interactions between the local response to the surface forcing, Ekman divergences, and remotely propagated signals in the model can reverse this, generating greater SSTs under HF forcing, particularly at low latitudes. The annual mean SST, however, is lowered under HF forcing, changing the balance between the net surface heat flux (which is dependent on the SST) and the meridional heat flux in the model. A suite of experiments with one-dimensional upper ocean models with different representations of vertical mixing processes suggests that the rectified effect of the diurnal heating cycle is dependent on the model, and overstated in the formulation used in the three-dimensional model.

Beschreibung: Funded by the Office of Naval Research (ONR), grant NOOO14-94-1-0161 and National Defense Science and Engineering Graduate Fellowship and by ONR grant NOOO14-99-1-0090.

Beschreibung: Author Posting. © American Meteorological Society, 2008. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 38 (2008): 133–145, doi:10.1175/2007JPO3782.1.

Beschreibung: Five ice-tethered profilers (ITPs), deployed between 2004 and 2006, have provided detailed potential temperature θ and salinity S profiles from 21 anticyclonic eddy encounters in the central Canada Basin of the Arctic Ocean. The 12–35-m-thick eddies have center depths between 42 and 69 m in the Arctic halocline, and are shallower and less dense than the majority of eddies observed previously in the central Canada Basin. They are characterized by anomalously cold θ and low stratification, and have horizontal scales on the order of, or less than, the Rossby radius of deformation (about 10 km). Maximum azimuthal speeds estimated from dynamic heights (assuming cyclogeostrophic balance) are between 9 and 26 cm s−1, an order of magnitude larger than typical ambient flow speeds in the central basin. Eddy θ–S and potential vorticity properties, as well as horizontal and vertical scales, are consistent with their formation by instability of a surface front at about 80°N that appears in historical CTD and expendable CTD (XCTD) measurements. This would suggest eddy lifetimes longer than 6 months. While the baroclinic instability of boundary currents cannot be ruled out as a generation mechanism, it is less likely since deeper eddies that would originate from the deeper-reaching boundary flows are not observed in the survey region.

Beschreibung: The engineering design work for the ITP was initiated by the Cecil H. and Ida M. Green Technology Innovation Program (an internal program at the Woods Hole Oceanographic Institution). Prototype development and construction were funded jointly by the U.S. National Science Foundation (NSF) Oceanographic Technology and Interdisciplinary Coordination Program and Office of Polar Programs (OPP) under Award OCE-0324233. Continued support has been provided by the OPP Arctic Sciences Section under Award ARC-0519899 and internal WHOI funding.

Beschreibung: Author Posting. © American Meteorological Society, 2008. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 38 (2008): 1644-1668, doi:10.1175/2007JPO3829.1.

Beschreibung: The mean structure and time-dependent behavior of the shelfbreak jet along the southern Beaufort Sea, and its ability to transport properties into the basin interior via eddies are explored using high-resolution mooring data and an idealized numerical model. The analysis focuses on springtime, when weakly stratified winter-transformed Pacific water is being advected out of the Chukchi Sea. When winds are weak, the observed jet is bottom trapped with a low potential vorticity core and has maximum mean velocities of O(25 cm s−1) and an eastward transport of 0.42 Sv (1 Sv ≡ 106 m3 s−1). Despite the absence of winds, the current is highly time dependent, with relative vorticity and twisting vorticity often important components of the Ertel potential vorticity. An idealized primitive equation model forced by dense, weakly stratified waters flowing off a shelf produces a mean middepth boundary current similar in structure to that observed at the mooring site. The model boundary current is also highly variable, and produces numerous strong, small anticyclonic eddies that transport the shelf water into the basin interior. Analysis of the energy conversion terms in both the mooring data and the numerical model indicates that the eddies are formed via baroclinic instability of the boundary current. The structure of the eddies in the basin interior compares well with observations from drifting ice platforms. The results suggest that eddies shed from the shelfbreak jet contribute significantly to the offshore flux of heat, salt, and other properties, and are likely important for the ventilation of the halocline in the western Arctic Ocean. Interaction with an anticyclonic basin-scale circulation, meant to represent the Beaufort gyre, enhances the offshore transport of shelf water and results in a loss of mass transport from the shelfbreak jet.

Beschreibung: This study was supported by the National Science Foundation Office of Polar Programs under Grants 0421904 and 035268 (MS), and by the Office of Naval Research Grant N00014-02-1-0317 (RP and PF). Analysis by AJP was supported by the Office of Naval Research under Grant N00014-97-1-0135 and by the National Science Foundation under Grant OPP-9815303.

Beschreibung: Author Posting. © American Meteorological Society, 2008. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 38 (2008): 1992-2002, doi:10.1175/2008JPO3669.1.

Beschreibung: This paper extends A. Bracco and J. Pedlosky’s investigation of the eddy-formation mechanism in the eastern Labrador Sea by including a more realistic depiction of the boundary current. The quasigeostrophic model consists of a meridional, coastally trapped current with three vertical layers. The current configuration and topographic domain are chosen to match, as closely as possible, the observations of the boundary current and the varying topographic slope along the West Greenland coast. The role played by the bottom-intensified component of the boundary current on the formation of the Labrador Sea Irminger Rings is explored. Consistent with the earlier study, a short, localized bottom-trapped wave is responsible for most of the perturbation energy growth. However, for the instability to occur in the three-layer model, the deepest component of the boundary current must be sufficiently strong, highlighting the importance of the near-bottom flow. The model is able to reproduce important features of the observed vortices in the eastern Labrador Sea, including the polarity, radius, rate of formation, and vertical structure. At the time of formation, the eddies have a surface signature as well as a strong circulation at depth, possibly allowing for the transport of both surface and near-bottom water from the boundary current into the interior basin. This work also supports the idea that changes in the current structure could be responsible for the observed interannual variability in the number of Irminger Rings formed.

Beschreibung: AB is supported by WHOI unrestricted funds, JP by the National Science Foundation OCE 85108600, and RP by 0450658.

Beschreibung: Author Posting. © American Meteorological Society, 2007. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 37 (2007): 1103-1121, doi:10.1175/jpo3041.1.

Beschreibung: The role of mesoscale oceanic eddies is analyzed in a quasigeostrophic coupled ocean–atmosphere model operating at a large Reynolds number. The model dynamics are characterized by decadal variability that involves nonlinear adjustment of the ocean to coherent north–south shifts of the atmosphere. The oceanic eddy effects are diagnosed by the dynamical decomposition method adapted for nonstationary external forcing. The main effects of the eddies are an enhancement of the oceanic eastward jet separating the subpolar and subtropical gyres and a weakening of the gyres. The flow-enhancing effect is due to nonlinear rectification driven by fluctuations of the eddy forcing. This is a nonlocal process involving generation of the eddies by the flow instabilities in the western boundary current and the upstream part of the eastward jet. The eddies are advected by the mean current to the east, where they backscatter into the rectified enhancement of the eastward jet. The gyre-weakening effect, which is due to the time-mean buoyancy component of the eddy forcing, is a result of the baroclinic instability of the westward return currents. The diagnosed eddy forcing is parameterized in a non-eddy-resolving ocean model, as a nonstationary random process, in which the corresponding parameters are derived from the control coupled simulation. The key parameter of the random process—its variance—is related to the large-scale flow baroclinicity index. It is shown that the coupled model with the non-eddy-resolving ocean component and the parameterized eddies correctly simulates climatology and low-frequency variability of the control eddy-resolving coupled solution.

Beschreibung: Funding for this work came from NSF Grants OCE 02-221066 and OCE 03-44094. Additional funding for PB was provided by the U.K. Royal Society Fellowship and by WHOI Grants 27100056 and 52990035.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution January 1988

Beschreibung: Analysis of vertical profiles of absolute horizontal velocity collected in January 1981, February 1982 and April 1982 in the central equatorial Pacific as part of the Pacific Equatorial Ocean Dynamics (PEQUOD) program, revealed two significant narrow band spectral peaks in the zonal velocity records, centered at vertical wavelengths of 560 and 350 stretched meters (sm). Both signals were present in all three cruises, but the 350 sm peak showed a more steady character in amplitude and a higher signal-to-noise ratio. In addition, its vertical scales corresponded to the scales of the conspicuous alternating flows generically called the equatorial deep jets in the past (the same terminology will be used here). Meridional velocity and vertical displacement spectra did not show any such energetic features. Energy in the 560 sm band roughly doubled between January 1981 and April 1982. Time lagged coherence results suggested upward phase propagation at time scales of about 4 years. East-west phase lines computed from zonally lagged coherences, tilted downward towards the west, implying westward phase propagation. Estimates of zonal wavelength (on the order of 10000 km) and period based on these coherence calculations, and the observed energy meridional structure at this vertical wavenumber band, seem consistent, within experimental errors, with the presence of a first meridional mode long Rossby wave packet, weakly modulated in the zonal direction. The equatorial deep jets, identified with the peak centered at 350 sm, are best defined as a finite narrow band process in vertical wavenumber (311-400 sm), accounting for only 20% of the total variance present in the broad band energetic background. At the jets wavenumber band, latitudinal energy scaling compared well with Kelvin wave theoretical values and a general tilt of phase lines downward towards the east yielded estimates of 10000-16000 km for the zonal wavelengths. Time-lagged coherence calculations revealed evidence for vertical shifting of the jets on interannual time scales. Interpretation of results in terms of single frequency linear wave processes led to inconsistencies, but finite bandwidth (in frequency and wavenumber) Kelvin wave processes of periods on the order of three to five years could account for the observations. Thus, the records do not preclude equatorial waves as a reasonable kinematic description of the jets.

Beschreibung: This research was supported by grant OCE-8600052 from the National Science Foundation, through the Woods Hole Oceanographic Institution.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February 1999

Beschreibung: This thesis addresses the parameterization of the heat and momentum transporting properties of eddy motions for use in three-dimensional, primitive equation, z-coordinate atmosphere and ocean models. Determining the transport characteristics of these eddies is fundamental to understanding their effect on the large-scale ocean circulation and global climate. The approach is to transform the primitive equations to yield the altered 'transformed Eulerian mean' (TEM) equations. The assumption is made that the eddy motions obey quasigeostrophic dynamics while the mean flow obeys the primitive equations. With this assumption, the TEM framework leads to the eddies appearing as one term, which acts as a body force in the momentum equations. This force manifests itself as a flux of potential vorticity (PV) - a quantity that incorporates both eddy momentum and heat transporting properties. Moreover, the dynamic velocities are those of the residual mean circulation, a much more relevant velocity for understanding heat and tracer transport. Closure for the eddy PV flux is achieved through a flux-gradient relationship, which directs the flux down the large scale PV gradient. For zonal flows, care is taken to ensure that the resulting force does not generate any net momentum, acting only to redistribute it. Neglect of relative vorticity fluxes in the PV flux yields the parameterization scheme of Gent and McWilliams. The approach is investigated by comparing a zonally-averaged parameterized model with a three dimensional eddy-resolving calculation of flow in a stress-driven channel. The stress at the upper surface is communicated down the water column to the bottom by eddy form drag. Moreover, lateral eddy momentum fluxes act to strengthen and sharpen the mean flow, transporting eastward momentum up its large scale gradient. Both the vertical momentum transfer and lateral, upgradient momentum transfer by eddies, are captured in the parameterized model. The advantages of this approach are demonstrated in two further zonal cases: 1) the spin-down of a baroclinic zone, and 2) the atmospheric jet stream. The time mean TEM approach and the eddy PV flux closure are explored in the context of an eddy-resolving closed basin flow which breaks the zonal symmetry. Decomposition of eddy PV fluxes into components associated with advective and dissipative effects suggest that the component associated with eddy flux divergence, and therefore forcing of the mean flow, is mainly directed down the large scale gradient and can be parameterized as before. Thus, the approach can be used to capture eddy transport properties for both zonal mean and time mean flows. The PV flux embodies both the eddy heat and momentum fluxes and so presents a more unified picture of their transferring properties. It therefore provides a powerful conceptual and practical framework for representing eddies in numerical models of the atmsophere and ocean.

Beschreibung: The work in this thesis was funded by grants from NSF, (OCE-9634331, OCE- 9503895), ONR (NOOOI4-95-1-0967), and by a fellowship from the Joint Program on the Science and Policy of Global Change at MIT.

Beschreibung: Author Posting. © American Meteorological Society, 2011. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 41 (2011): 2168–2186, doi:10.1175/JPO-D-11-08.1.

Beschreibung: This paper studies the interaction of an Antarctic Circumpolar Current (ACC)–like wind-driven channel flow with a continental slope and a flat-bottomed bay-shaped shelf near the channel’s southern boundary. Interaction between the model ACC and the topography in the second layer induces local changes of the potential vorticity (PV) flux, which further causes the formation of a first-layer PV front near the base of the topography. Located between the ACC and the first-layer slope, the newly formed PV front is constantly perturbed by the ACC and in turn forces the first-layer slope with its own variability in an intermittent but persistent way. The volume transport of the slope water across the first-layer slope edge is mostly directly driven by eddies and meanders of the new front, and its magnitude is similar to the maximum Ekman transport in the channel. Near the bay’s opening, the effect of the topographic waves, excited by offshore variability, dominates the cross-isobath exchange and induces a mean clockwise shelf circulation. The waves’ propagation is only toward the west and tends to be blocked by the bay’s western boundary in the narrow-shelf region. The ensuing wave–coast interaction amplifies the wave amplitude and the cross-shelf transport. Because the interaction only occurs near the western boundary, the shelf water in the west of the bay is more readily carried offshore than that in the east and the mean shelf circulation is also intensified along the bay’s western boundary.

Beschreibung: Y. Zhang acknowledges the support of the MIT-WHOI Joint Program in Physical Oceanography and NSF OCE-9901654 and OCE- 0451086. J. Pedlosky acknowledges the support of NSF OCE-9901654 and OCE-0451086.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Master of Science at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution May 1996

Beschreibung: TOPEX/POSEIDON altimetry data are employed in the analysis of the global ocean response to atmospheric forcing. We use two different approaches to test the hypothesis that the global sea surface height variability can be adequately described by linear barotropic ocean models: the multichannel regression and the optimal smoothing techniques. We start with the simplest linear vorticity balance and continue by building a hierarchy of more complicated models by including effects of topography and time dependence. We use auto-regressive external (ARX) time-series models to test the hypothesis in all of the Pacific Ocean. We also test whether any significant residual regression on the atmospheric loading is left after the inverted barometer effect is corrected for. We find that no linear barotropic model is consistent with the data. We provide a check on the results of the multichannel regression by using a Kalman filter and optimal smoother. We use sequential estimation in the form of filteringsmoothing algorithm. We run the estimate for an area of 4000 km by 2000 km in the Northeast Pacific. We analyze model and data error structures by simulating the model without data assimilation. The results show that the model forecast on average explains 33% of the data variability. The Kalman filter updates the model very efficiently and produces an estimate which explains 76% of the data variance. The optimal smoother estimate is very similar to the Kalman filter estimate. Running the model in other regions of the Pacific produced worse fits of the model to the data. This supports the conclusion that the linear barotropic dynamics fails to describe the SSH variability.

Beschreibung: This research was partially funded by a NASA Global Change Fellowship.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February 1997

Beschreibung: The goals of this thesis were: (1) to establish methods for the determination of nitrogen and carbon isotope ratios in marine particulate and sedimentary chlorophyll derivatives; (2) to establish chlorophyll δ15N and δl3C as proxies for the nitrogen and carbon isotopic composition of marine phytoplankton; and (3) to use chlorophyll nitrogen isotopic ratios to understand the origin of Late Quaternary Eastern Mediterranean sapropels. Techniques are presented for the determination of chlorin nitrogen and carbon isotopic ratios in marine particles and sediments with a precision greater than 0.15 per mil for both isotopes. The procedure can be performed in about 4 hours for particulate and 8 hours for sediment samples, and relies on multiple chromatographic purifications. About 20 g of a moderately organic-rich sediment are required. A technique is also presented for the determination of chlorin nitrogen and carbon isotopic ratios by isotope-ratio monitoring gas chromatography-mass spectrometry (irmGC-MS) by synthesizing bis-(tert.-butyldimethylsiloxy)Si(IV) chlorin derivatives. However, yields for the 4-step synthesis were only about 5-6% and there was a net isotopic depletion of 1.2 (± 0.3) per mil in the derivative, relative to the starting material. These techniques are then used to show that the nitrogen isotopic difference between chlorophyll and whole cells in six species of marine phytoplankton is 5.16 ± 2.40 per mil. For carbon, the isotopic difference between chlorophyll and whole cells in five species of marine phytoplankton is -0.02 ± 2.12 per mil. A model of the distribution of 15N in phytoplankton is constructed and it is demonstrated that the interspecies variability observed for the nitrogen isotopic difference between chlorophyll and whole cells can be attributed to differences in the partitioning of cellular nitrogen between non-protein biochemicals. In the field, where mixed assemblages of phytoplankton prevail, the isotopic difference beween chlorophyll and whole cells is expected to tend toward the average value of 5.16 per mil. Finally, the average nitrogen isotopic composition of chlorins from six Late Quaternary Eastern Mediterranean sapropels (-5.01 + 0.38 per mil) was found to be very similar to the δ15N of chlorophyll from the modem deep chlorophyll maximum (-6.38 ± 1.80 per mil) in the Eastern Mediterranean. In addition, sapropel photoautotrophic material, calculated from the chlorin δ15N, had the same isotopic composition (0.15 per mil) as both bulk sapropel sediments (-0.08 ± 0.53 per mil) and deep water nitrate (-0.05 per mil). These data suggest (a) that bottom waters were anoxic, (b) that organic matter burial efficiency was enhanced, and (c) that oligotrophic conditions similar to today persisted, in the Eastern Mediterranean during sapropel deposition. These results contradict earlier interpretations of Late Quaternary bulk sedimentary δ15N in the Eastern Mediterranean. The latter concluded that the pattern of high δ15N values in intercalated marl oozes and low values in sapropels was the result of decreased nutrient utilization, and hence, increased primary production, during sapropel events. The low δ15N of deep water nitrate in the Eastern Mediterranean suggests a significant source of new nitrogen from biological N2-fixation. It is suggested that attempts to reconstruct the nitrogen isotopic composition of marine organic matter in the past by measuring the δ15N of whole sediments may be subject to misinterpretation due to the alteration of isotopic ratios during diagenesis. The partial oxidation of marine organic matter can result in significant isotopic enrichment of the preserved residual. The magnitude of this enrichment appears to be large when bottom waters are well-oxygenated, and small when bottom waters are anoxic. Environments where large temporal reqox changes have occurred are expected to be the most problematic for the interpretation of bulk sedimentary δ15N. In these environments, the diagenetic signal can be at least as large as the primary isotopic signal being sought. The Eastern Mediterranean Sea during the Late Quaternary appears to be one such environment.

Beschreibung: Funding for this work came from an Office of Naval Research Graduate Fellowship, the Woods Hole Oceanographic Institution Ocean Ventures Fund, and a Petroleum Research Grant(# 30124-AC2).

Beschreibung: Author Posting. © American Meteorological Society, 2012. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 42 (2012): 2206–2228, doi:10.1175/JPO-D-11-0191.1.

Beschreibung: This study investigates the anisotropic properties of the eddy-induced material transport in the near-surface North Atlantic from two independent datasets, one simulated from the sea surface height altimetry and one derived from real-ocean surface drifters, and systematically examines the interactions between the mean- and eddy-induced material transport in the region. The Lagrangian particle dispersion, which is widely used to characterize the eddy-induced tracer fluxes, is quantified by constructing the “spreading ellipses.” The analysis consistently demonstrates that this dispersion is spatially inhomogeneous and strongly anisotropic. The spreading is larger and more anisotropic in the subtropical than in the subpolar gyre, and the largest ellipses occur in the Gulf Stream vicinity. Even at times longer than half a year, the spreading exhibits significant nondiffusive behavior in some parts of the domain. The eddies in this study are defined as deviations from the long-term time-mean. The contributions from the climatological annual cycle, interannual, and subannual (shorter than one year) variability are investigated, and the latter is shown to have the strongest effect on the anisotropy of particle spreading. The influence of the mean advection on the eddy-induced particle spreading is investigated using the “eddy-following-full-trajectories” technique and is found to be significant. The role of the Ekman advection is, however, secondary. The pronounced anisotropy of particle dispersion is expected to have important implications for distributing oceanic tracers, and for parameterizing eddy-induced tracer transfer in non-eddy-resolving models.

Beschreibung: IR was supported by Grant NSF-OCE-0725796. IK would like to acknowledge support by the National Science foundation Grant OCE-0842834.

Beschreibung: 2013-06-01

Beschreibung: Author Posting. © American Meteorological Society, 2013. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 43 (2013): 905–919, doi:10.1175/JPO-D-12-0150.1.

Beschreibung: Interactions between vortices and a shelfbreak current are investigated, with particular attention to the exchange of waters between the continental shelf and slope. The nonlinear, three-dimensional interaction between an anticyclonic vortex and the shelfbreak current is studied in the laboratory while varying the ratio ε of the maximum azimuthal velocity in the vortex to the maximum alongshelf velocity in the shelfbreak current. Strong interactions between the shelfbreak current and the vortex are observed when ε 〉 1; weak interactions are found when ε 〈 1. When the anticyclonic vortex comes in contact with the shelfbreak front during a strong interaction, a streamer of shelf water is drawn offshore and wraps anticyclonically around the vortex. Measurements of the offshore transport and identification of the particle trajectories in the shelfbreak current drawn offshore from the vortex allow quantification of the fraction of the shelfbreak current that is deflected onto the slope; this fraction increases for increasing values of ε. Experimental results in the laboratory are strikingly similar to results obtained from observations in the Middle Atlantic Bight (MAB); after proper scaling, measurements of offshore transport and offshore displacement of shelf water for vortices in the MAB that span a range of values of ε agree well with laboratory predictions.

Beschreibung: Laboratory work was supported by the National Science Foundation through Grant OCE- 0081756. Glider observations in March–April 2006 were supported by the National Science Foundation through Grant OCE-0220769. Glider observations in July– October 2007 were supported by a grant from Raytheon. RET was supported by the Postdoctoral Scholar Program at the Woods Hole Oceanographic Institution, with funding provided by the Cooperative Institute for the North Atlantic Region. The REMUS observations were funded by the Office of Naval Research. GGG was supported by the National Science Foundation through Grant OCE-1129125 for analysis and writing.

Beschreibung: 2013-11-01

Beschreibung: Author Posting. © American Meteorological Society, 2013. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 26 (2013): 9839–9859, doi:10.1175/JCLI-D-12-00647.1.

Beschreibung: Spatial and temporal covariability between the atmospheric transient eddy heat fluxes (i.e., υ′T′ and υ′q′) in the Northern Hemisphere winter (January–March) and the paths of the Gulf Stream (GS), Kuroshio Extension (KE), and Oyashio Extension (OE) are examined based on an atmospheric reanalyses and ocean observations for 1979–2009. For the climatological winter mean, the northward heat fluxes by the synoptic (2–8 days) transient eddies exhibit canonical storm tracks with their maxima collocated with the GS and KE/OE. The intraseasonal (8 days–3 months) counterpart, while having overall similar amplitude, shows a spatial pattern with more localized maxima near the major orography and blocking regions. Lateral heat flux divergence by transient eddies as the sum of the two frequency bands exhibits very close coupling with the exact locations of the ocean fronts. Linear regression is used to examine the lead–lag relationship between interannual changes in the northward heat fluxes by the transient eddies and the meridional changes in the paths of the GS, KE, and OE, respectively. One to three years prior to the northward shifts of each ocean front, the atmospheric storm tracks shift northward and intensify, which is consistent with wind-driven changes of the ocean. Following the northward shifts of the ocean fronts, the synoptic storm tracks weaken in all three cases. The zonally integrated northward heat transport by the synoptic transient eddies increases by ~5% of its maximum mean value prior to the northward shift of each ocean front and decreases to a similar amplitude afterward.

Beschreibung: Support from the National Aeronautics and Space Administration (NASA) Physical Oceanography Program (NNX09AF35G to TJ and Y-OK) and the Department of Energy (DOE) Climate and Environmental Sciences Division (DE-SC0007052 to Y-OK) is gratefully acknowledged.

Beschreibung: 2014-06-15

Beschreibung: Author Posting. © American Meteorological Society, 2015. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 45 (2015): 606–612, doi:10.1175/JPO-D-14-0221.1.

Beschreibung: Mesoscale intrathermocline lenses are observed throughout the World Ocean and are commonly attributed to water mass anomalies advected from a distant origin. An alternative mechanism of local generation is offered herein, in which eddy–wind interaction can create lens-shaped disturbances in the thermocline. Numerical simulations illustrate how eddy–wind-driven upwelling in anticyclones can yield a convex lens reminiscent of a mode water eddy, whereas eddy–wind-driven downwelling in cyclones produces a concave lens that thins the mode water layer (a cyclonic “thinny”). Such transformations should be observable with long-term time series in the interiors of mesoscale eddies.

Beschreibung: Support of this research by the National Science Foundation and National Aeronautics and Space Administration is gratefully acknowledged.

Beschreibung: 2015-08-01

Beschreibung: Author Posting. © American Meteorological Society, 2015. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 45 (2015): 2820–2835, doi:10.1175/JPO-D-15-0101.1.

Beschreibung: The response of a convective ocean basin to variations in atmospheric temperature is explored using numerical models and theory. The results indicate that the general behavior depends strongly on the frequency at which the atmosphere changes relative to the local response time to air–sea heat flux. For high-frequency forcing, the convective region in the basin interior is essentially one-dimensional and responds to the integrated local surface heat flux anomalies. For low-frequency forcing, eddy fluxes from the boundary current into the basin interior become important and act to suppress variability forced by the atmosphere. A theory is developed to quantify this time-dependent response and its influence on various oceanic quantities. The amplitude and phase of the temperature and salinity of the convective water mass, the meridional overturning circulation, the meridional heat flux, and the air–sea heat flux predicted by the theory compare well with that diagnosed from a series of numerical model calculations in both strongly eddying and weakly eddying regimes. Linearized analytic solutions provide direct estimates of each of these quantities and demonstrate their dependence on the nondimensional numbers that characterize the domain and atmospheric forcing. These results highlight the importance of mesoscale eddies in modulating the mean and time-dependent ocean response to atmospheric variability and provide a dynamical framework with which to connect ocean observations with changes in the atmosphere and surface heat flux.

Beschreibung: This study was supported by the National Science Foundation under Grant OCE-1232389.

Beschreibung: 2016-05-01

Beschreibung: Author Posting. © American Meteorological Society, 2016. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 46 (2016): 2645-2662, doi:10.1175/JPO-D-15-0191.1.

Beschreibung: The occurrence, drivers, and implications of small-scale O(2–5) km diameter coherent vortices, referred to as submesoscale eddies, over the inner shelf south of Martha’s Vineyard, Massachusetts, are examined using high-frequency (HF), radar-based, high-resolution (400 m) observations of surface currents. Within the 300 km2 study area, eddies occurred at rates of 1 and 4 day−1 in winter and summer, respectively. Most were less than 5 h in duration, smaller than 4 km in diameter, and rotated less than once over their lifespan; 60% of the eddies formed along the eastern edge of study area, adjacent to Wasque Shoal, and moved westward into the interior, often with relative vorticity greater than f. Eddy generation was linked to vortex stretching on the ebb and flood tide as well as the interaction of the spatially variable tide and the wind-driven currents; however, these features had complex patterns of surface divergence and stretching. Eddies located away from Wasque Shoal were related to the movement of wind-driven surface currents, as wind direction controlled where eddies formed as well as density effects. Using an analysis of particles advected within the radar-based surface currents, the observed eddies were found to be generally leaky, losing 60%–80% of particles over their lifespan, but still more retentive than the background flow. As a result, the combined translation and rotational effects of the observed eddies were an important source of lateral exchange for surface waters over the inner shelf.

Beschreibung: The HF radar data utilized here were obtained using internal funding from the Woods Hole Oceanographic Institution. The analysis was supported by NSF OCE Grant 1332646.

Beschreibung: 2017-02-19

Beschreibung: Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 122 (2017): 3519–3542, doi:10.1002/2016JC012519.

Beschreibung: Observations from two companion field programs—Origins of the Kuroshio and Mindanao Current (OKMC) and Observations of Kuroshio Transport Variability (OKTV)—are used here to examine the Kuroshio's temporal and spatial evolution. Kuroshio strength and velocity structure were measured between June 2012 and November 2014 with pressure-sensor equipped inverted echo sounders (PIESs) and upward-looking acoustic Doppler current profilers (ADCPs) deployed across the current northeast of Luzon, Philippines, and east of Taiwan with an 8 month overlap in the two arrays' deployment periods. The time-mean net (i.e., integrated from the surface to the bottom) absolute transport increases downstream from 7.3 Sv (±4.4 Sv standard error) northeast of Luzon to 13.7 Sv (±3.6 Sv) east of Taiwan. The observed downstream increase is consistent with the return flow predicted by the simple Sverdrup relation and the mean wind stress curl field over the North Pacific (despite the complicated bathymetry and gaps along the North Pacific western boundary). Northeast of Luzon, the Kuroshio—bounded by the 0 m s−1 isotach—is shallower than 750 dbar, while east of Taiwan areas of positive flow reach to the seafloor (3000 m). Both arrays indicate a deep counterflow beneath the poleward-flowing Kuroshio (–10.3 ± 2.3 Sv by Luzon and −12.5 ± 1.2 Sv east of Taiwan). Time-varying transports and velocities indicate the strong influence at both sections of westward propagating eddies from the ocean interior. Topography associated with the ridges east of Taiwan also influences the mean and time-varying velocity structure there.

Beschreibung: Office of Naval Research (ONR) Grant Numbers: N00014-15-12593 , N00014-16-13069; Taiwan's Ministry of Science and Technology Grant Numbers: NSC 101-2611-M-002-018-MY3 , MOST 103-2611-M-002-011 , MOST 105-2119-M-002-042; ONR Grant Numbers: N00014-10-1-0308 , N00015-10-1-0469

Beschreibung: 2017-11-02

Beschreibung: Author Posting. © American Meteorological Society, 2017. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 47 (2017): 1291-1305, doi:10.1175/JPO-D-16-0160.1.

Beschreibung: Along-stream variations in the dynamics of the Antarctic Circumpolar Current (ACC) impact heat and tracer transport, regulate interbasin exchange, and influence closure of the overturning circulation. Topography is primarily responsible for generating deviations from zonal-mean properties, mainly through standing meanders associated with regions of high eddy kinetic energy. Here, an idealized channel model is used to explore the spatial distribution of energy exchange and its relationship to eddy geometry, as characterized by both eddy momentum and eddy buoyancy fluxes. Variations in energy exchange properties occur not only between standing meander and quasi-zonal jet regions, but throughout the meander itself. Both barotropic and baroclinic stability properties, as well as the magnitude of energy exchange terms, undergo abrupt changes along the path of the ACC. These transitions are captured by diagnosing eddy fluxes of energy and by adopting the eddy geometry framework. The latter, typically applied to barotropic stability properties, is applied here in the depth–along-stream plane to include information about both barotropic and baroclinic stability properties of the flow. These simulations reveal that eddy momentum fluxes, and thus barotropic instability, play a leading role in the energy budget within a standing meander. This result suggests that baroclinic instability alone cannot capture the dynamics of ACC standing meanders, a challenge for models where eddy fluxes are parameterized.

Beschreibung: The authors all acknowledge support from NSF OCE-1235488. MKY also acknowledges support from the AMS Graduate Student Fellowship.

Beschreibung: 2017-10-12

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February 2006

Beschreibung: South American climate has undergone dramatic changes since the last glacial period, as evidenced from Cariaco Basin (Venezuelan coast) and Peru Margin marine sediment biomarker records. Compounds derived from vascular plant leaf waxes and delivered to the marine sedimentary environment, including long-chain (C24-C32) nalkanoic acids, were used as proxies for terrestrial vegetation type, aridity, and atmospheric circulation. Marine biomarkers, such as sterols and phytol, were used to reconstruct productivity in the Peru Margin upwelling zone, where sedimentary conditions are not conducive to the preservation of foraminifera. Through the use of organic molecular isotopic techniques and multi-molecular stratigraphy, a great deal can be learned about communities of marine organisms and terrestrial plants that existed in the past and the environments in which they lived. Vascular plant leaf wax carbon and hydrogen isotopic records were generated from n-alkanoic acids preserved in Cariaco Basin marine sediments. These records were compared to previously established pollen and climate records and were found to parallel local millennial-scale climate changes between the late Glacial and Preboreal periods, which were characterized by migrations of the inter-tropical convergence zone. Differences in δD between C16-C18 and C24-C30 n-alkanoic acids suggest a marine source for the shorter chain lengths and a terrestrial source for the longer chains. Stacked δD and δ13C records both exhibited isotopic enrichment during the late Glacial and Younger Dryas periods and depletion during the Bølling-Allerød and Preboreal periods. If interpreted as an aridity proxy, the δD record is in agreement with Cariaco Basin sediment grey scale records, suggesting that the late Glacial and Younger Dryas were more arid than the Bølling-Allerød and Preboreal periods. n-Alkanoic acid δ13C, which is a proxy for C3 versus C4 plant type, indicates that C3 plants predominated in this area of the tropics during warm and wet periods, such as the Bølling-Allerød and the Holocene, and C4 plants proliferated during cooler and more arid periods, such as the Glacial and Younger Dryas. The biomarker δ13C record agrees with pollen data previously developed from Cariaco Basin sediments, confirming that leaf wax compounds preserved in marine sediments can accurately record terrestrial vegetation changes. Analytical methods utilizing stir bar sorptive extraction (SBSE) and thermal desorption were developed and applied to investigate lipid organic matter in a suite of alpine ice cores. These methods permit use of small volume (10-30 ml) samples, as would be required for high-resolution down-core analyses. SBSE involves using a polymer coated stir bar to extract organic matter from aqueous samples, after which it is loaded directly into a thermal desorption unit and the organic matter transferred in its entirety to a gas chromatograph inlet. To test these methods and the organic content of tropical ice, post-industrial samples from two South American, two Asian, and one African ice core were analyzed. Compounds identified in the modern ice core samples included natural and anthropogenic biomarkers such as n-alkanes, n-alkanoic acids, nalkyl amides and nitriles, polycyclic aromatic hydrocarbons (PAHs), and diterpenoids. Variability in the distributions of these compounds between different cores demonstrated that the lipid organic fraction in each core was representative of mostly local inputs. To further investigate natural inputs, several pre-industrial samples were analyzed from the Sajama ice core in the Andes and The Puruogangri core on the Tibetan Plateau. Inputs of terrestrial vegetation combustion biomarkers such as PAHs, diterpenoids, and alkyl amides were consistent with periods of enhanced aridity in each core. The results of this investigation demonstrate the utility of the methodology, which could now be applied to generate very high-resolution biomarker records from tropical ice cores. Gas chromatography/time-of-flight mass spectrometry (GC/TOF-MS) was used to generate a high-resolution, multi-molecular organic biomarker record from Peru Margin sediments (~11oS, 252 m water depth) for the last 15 ka. Because of their position beneath the oxygen minimum zone of a productive upwelling region, these sediments contain a wealth of compounds that can be exploited as paleoclimate indicators. TOF-MS and fast GC techniques allowed me to generate this record in a short amount of time and without employing the traditional suite of purification techniques. Before about 9 ka, organic carbon and biomarker concentration records exhibited similar variability, implying a forcing mechanism that affected input and/or preservation of both marine and terrestrial organic matter, such as large-scale climate change. Organic carbon and biomarker abundances then systematically increased throughout the Holocene and exhibited higher frequency variability, suggesting overall enhanced productivity from rapidly evolving planktonic communities. Similar patterns of variability between bacterial hopanol, sterol degradation product, and primary productivity biomarker records suggest that the productivity biomarkers are recording sea surface and water column processes, and are not significantly biased by sedimentary diagenesis. Low bound sulfur content in lipid extracts and a lack of observed sulfur-containing compounds argue against significant sulfurization and resultant biomarker sequestration in 1228D sediments. Factor analysis provided a statistical means of separating terrestrial and marine organic inputs, and reinforced the interpretations that very long chain n-alkanoic acids (C30-C32) are terrestrially derived and sterol compounds primarily represent marine algal inputs. In all, the biomarker records suggest millennial-scale changes in upwelling strength superimposed on longer-term trends, with additional variability in contributions from specific precursors, such as dinoflagellates. Terrestrial leaf wax compounds also exhibited high-amplitude, millennial-scale variability, but with a different pattern of change than the marine inputs. GC/TOF-MS was shown to be a useful tool for generating high-resolution records of the type necessary to understand the relationships between biomarkers in a complex and sensitive depositional environment such as the Peru Margin. Climate signals embedded in the Peru Margin biomarker records provided clues as to the productivity and upwelling histories of the Peru Margin, as well as regional terrestrial vegetation. Elevated concentrations of marine biomarkers suggest enhanced upwelling and productivity from about 6.5 ka to the present on the Peru Margin, with lower-amplitude millennial-scale variations occurring throughout this period. Enhanced dinosterol abundances after 6.5 ka are consistent with greater occurrences and/or strength of El Niño, while concurrently enhanced upwelling suggests a parallel increase in La Niña activity. Similar timing of mid to late Holocene variability between Peru Margin marine biomarker records, a faunal sea surface temperature record from the eastern tropical Atlantic, and Andean paleoclimate records suggests strong climate links between these regions of the tropics, likely driven by broad-scale changes in El Niño and the Southern Oscillation (ENSO) and trade wind strength. The C30 n-alkanoic acid, which is representative of vascular plant leaf wax inputs, exhibited millennial-scale variability superimposed on longer-term trends that may be related to aridity, assuming fluvial transport of terrestrial material. n-Alkanoic acid δ13C is generally enriched during periods of enhanced leaf wax abundance, consistent with increased inputs of C4 plant material at these times.

Beschreibung: Funding for this research was provided by a Schlanger Ocean Drilling Fellowship, which is part of the NSF-sponsored U.S. Science Support Program (USSSP). An NSF grant to TIE (OCE-0402533) provided additional funding for the research presented in Chapters 3-5. Funding for the Cariaco Basin isotopic analyses was provided by the Frank and Lisina Hoch Endowed Fund and the Woods Hole Oceanographic Institution Director’s General Discretionary Fund.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February 2006

Beschreibung: To provide a new perspective on the fate of both natural organic matter and hydrophobic organic contaminants (HOCs) in marine sediments, we have investigated the relationship between radiocarbon (14C) age and the different modes of association in aquatic sediments and soils. Radiocarbon is a sensitive tracer of OM provenance, with variations in its natural abundance reflecting the age and origin of material. The main objective has been to determine the significance of these associations, and to assess how they affect the transport, bioavailability, preservation and residence times of organic compounds in the environment. Our results indicate that the majority of HOCs that persist in marine sediments are solvent-extractable and incorporation into insoluble sediment residues is not quantitatively significant. For pristine sediments, systematic variations in 14C content are observed between different chemically defined sedimentary organic fractions. These variations are dependent on organic matter inputs and/or the affects of diagenesis. Our observations also provide evidence for the protection of labile marine carbon by chemical binding. Finally, the persistence of n-alkanes from biogenic sources compared to those derived from petroleum indicates that protective matrix association can play a crucial role in determining the long-term fate of a compound. Overall, it is clear that both natural organic compounds and HOCs can undergo very different fates depending on their mode of introduction to, and physical disposition in environmental matrices.

Beschreibung: Funding for this research was provided by the National Science Foundation, CHE-0089172 to T.I. Eglinton and C.M. Reddy, and OCE-82567700 to T.I. Eglinton. I received support from a Charles Davis Hollister Fellowship from Woods Hole Oceanographic Institution.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution January, 1978

Beschreibung: Many of the small-scale topographic features (dimensions of centimeters to kilometers) found on the Blake-Bahama Outer Ridge (western North Atiantic, water depth greater than 4000 m) and in the Rockall Trough (northeastern North Atlantic, water depth greater than 2000 m) have been formed as bed forms of deep currents. These bed forms, all developed in cohesive sediments, include current ripples (spacings of tens of centimeters, formed transverse to the flow), longitudinal triangular ripples (spacings of meters, formed in sandy muds and parallel to the flow), furrows (spacings of tens to 100's of meters, formed parallel to the flow and presently either erosional or depositional), and regular sediment waves (spacings of a few kilometers, now found oblique to the flow and migrating either upstream or downstream). The local distribution of any given bed form is influenced by the presence of larger features. Bed forms are often found in zones which strike parallel to the regional contours. Debris flows, affecting areas of 1000's to 10,000's of square kilometers, are also present in these areas. A debris flow studied in the Rockall Trough is erosional at its shallowest depths and depositional at greater depths. Gravitational flows strike perpendicular to the contours. Pockmarks (tens of meters in diameter, marking fluid seeps) are also found on the Blake-Bahama Outer Ridge. The larger topographic features (greater than several meters) with steep slopes (greater than about 20°) can be observed on surface echo-sounding profiles either as fields of regular hyperbolic echoes (e.g., echoes from regularly spaced furrows), fields of irregularly spaced, dissimilar hyperbolae (e.g., echoes from blocks, ridges, and folds in debris flows), or as regular features whose structure is often obscured by side echoes (e.g., echoes from sediment waves). Although near-bottom investigations are required to describe the features, the nature of the sea floor can often be inferred from the character of the echo-sounding profile. Similar echo-sounding records in different areas of the ocean indicate the presence of similar sea-floor features. The morphology of the bed forms studied and the current and temperature structure of the overlying water column lead to conclusions about bed form origin and present-day interactions with deep currents. Furrows form as erosional bed forms during high-velocity (〉20? cm/sec) current events by large, helical secondary circulations in the bottom boundary layer. Once formed, furrows may develop into depositional features, or they may continue as erosional ones, depending on the local currents and the sediment supply. Large, regular sediment waves may be formed at current speeds of 5 to 10 cm/sec by lee waves generated by topographic irregularities on the sea floor, such as submarine canyons, or by instabilities in the flow of deep, contour-following currents. Sediment waves develop where there is an abundant supply of sediment and steady mean currents. Waves appear to migrate upstream where tidal current fluctuations are smaller than the mean velocity, and downstream where they are larger. Near-bottom currents appear to be faster on the downstream side of upstream-migrating sediment waves than on their upstream side. The resulting variations in bed shear stress lead to higher sedimentation rates on the upstream side and bed form migration in that direction.

Beschreibung: This research was made possible by National Science Foundation grants DES 73-06657 and OCE 76-22152, and Office of Naval Research contract N00014-74-C-0262; NR083-004 to Woods Hole Oceanographic Institution, NSF grant OCE 74-01671 to Lamont-Doherty Geological Observatory, and numerous NSF grants and ONR contracts to Scripps Institution of Oceanography.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February 2007

Beschreibung: The role of ocean dynamics in driving air-sea interaction is examined at two contrasting sites on 125°W in the eastern tropical Pacific Ocean using data from the Pan American Climate Study (PACS) field program. Analysis based on the PACS data set and satellite observations of sea surface temperature (SST) reveals marked differences in the role of ocean dynamics in modulating SST. At a near-equatorial site (3°S), the 1997-1998 El Nino event dominated the evolution of SST and surface heat fluxes, and it is found that wind-driven southward Ekman transport was important in the local transition from El Nino to La Nina conditions. At a 10°N site near the summertime position of the Inter-tropical Convergence Zone, oceanic mesoscale motions played an important role in modulating SST at intraseasonal (50- to 100-day) timescales, and the buoy observations suggest that there are variations in surface solar radiation coupled to these mesoscale SST variations. This suggests that the mesoscale oceanic variability may influence the occurrence of clouds. The intraseasonal variability in currents, sea surface height, and SST at the northern site is examined within the broader spatial and temporal context afforded by satellite data. The oscillations have zonal wavelengths of 550-1650 km and propagate westward in a manner consistent with the dispersion relation for first baroclinic mode, free Rossby waves in the presence of a mean westward flow. The hypothesis that the intraseasonal variability and its annual cycle are associated with baroclinic instability of the North Equatorial Current is supported by a spatio-temporal correlation between the amplitude of intraseasonal variability and the occurrence of westward zonal flows meeting an approximate necessary condition for baroclinic instability. Focusing on 10°N in the eastern tropical Pacific, the hypothesis that mesoscale oceanic SST variability can systematically influence cloud properties is investigated using several satellite data products. A statistically significant relationship between SST and columnar cloud liquid water (CLW), cloud reflectivity, and surface solar radiation is identified within the wavenumber-frequency band corresponding to oceanic Rossby waves. Analysis of seven years of CLW data and 20 years surface solar radiation data indicates that 10-20% of the variance of these cloud-related properties at intraseasonal periods and wavelengths on the order of 10° longitude can be ascribed to SST signals driven by oceanic Rossby waves.

Beschreibung: I gratefully acknowledge support from the following sources: NOAA Grants NA87RJ0445 (2002-2003) and NA17RJ1223 (2005-2006), and an MIT Presidential Fellowship (2000-2001). I also received support from The Cooperative Institute for Climate and Ocean Research, a NOAA-WHOI joint institute (NOAA Grant NA17RJ1223).

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution October 1982

Beschreibung: Four different problems concerning Gulf Stream Rings are considered. The first deals with the particle trajectories of, and advection-diffusion by, a dynamic model of a Ring. It is found that the streaklines computed from the assumptions that the Ring is a steadily propagating and permanent form structure accurately describe its Lagrangian trajectories. The dispersion field of the Ring produces east-west asymmetries in the streaklines, not contained in earlier kinematic studies, which are consistent with observed surface patterns. In the second problem, we compute the core mixed layer evolution of both warm and cold Rings, and compare them to the background SST, in an effort to explain observed SST cycles of Rings. We demonstrate that warm Rings retain their anomalous surface identity, while cold Rings do not, because of differences in both the local atmospheric states of the Sargasso and the Slope and the typical mixed layer structures appropriate to each. The third and fourth problems concern the forced evolution of Gulf Stream Rings as effected by atmospheric interactions. First, we compute the forced spin down of a Gulf Stream Ring. The variations in surface stress across the Ring necessary to spin it down are caused by the variations in relative air-sea velocity, of which the stress is a quadratric function. From numerical simulations, we find the forced decay rates are comparable to those inferred from Ring observations. In the final problem, it is suggested that a substantial fraction of meridional Ring migration is a forced response, caused by Ring SST and the temperature dependence of stress. The warm central waters of anticyclonic Rings are regions of enhanced stress, producing upwelling to the north, and downwelling to the south, which shifts the Ring to the south. A similar, southward shift is computed for cyclonic Rings with cold centers, which tends to reconcile their numerically computed propagation with observations.

Beschreibung: The present research has been conducted under NOAA contract # NA80AA-D-0057 and NSF contract II OCE-8240455

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February 2002

Beschreibung: Sound propagation in shallow water is highly dependent on the interaction of the sound field with the bottom. In order to fully understand this problem, it is necessary to obtain reliable estimates of bottom geoacoustic properties that can be used in acoustic propagation codes. In this thesis, perturbative inversion methods and exact inverse methods are discussed as a means for inferring geoacoustic properties of the bottom. For each of these methods, the input data to the inversion is the horizontal wavenumber spectrum of a point-source acoustic field. The main thrust of the thesis work concerns extracting horizontal wavenumber content for fully three-dimensionally varying waveguide environments. In this context, a high-resolution autoregressive (AR) spectral estimator was applied to determine wavenumber content for short aperture data. As part of this work, the AR estimator was examined for its ability to detect discrete wavenumbers in the presence of noise and also to resolve closely spaced wavenumbers for short aperture data. As part of a geoacoustic inversion workshop, the estimator was applied to extract horizontal wavenumber content for synthetic pressure field data with range-varying geoacoustic properties in the sediment. The resulting wavenumber content was used as input data to a perturbative inverse algorithm to determine the sound speed profile in the sediment. It was shown using the high-resolution wavenumber estimator that both the shape and location of the range-variability in the sediment could be determined. The estimator was also applied to determine wavenumbers for synthetic data where the water column sound speed contained temporal variations due to the presence of internal waves. It was shown that reliable estimates of horizontal wavenumbers could be obtained that are consistent with the boundary conditions of the waveguide. The Modal Mapping Experiment (MOMAX), an experimental method for measuring the full spatial variability of a propagating sound field and its corresponding modal content in two-dimensions, is also discussed. The AR estimator is applied to extract modal content from the real data and interpreted with respect to source/receiver motion and geometry. For a moving source, it is shown that the wavenumber content is Doppler shifted. A method is then described that allows the direct measure of modal group velocities from Doppler shifted wavenumber spectra. Finally, numerical studies are presented addressing the practical issues associated with using MOMAX type data in the exact inversion method of Gelfand-Levitan.

Beschreibung: I am especially grateful to ONR for providing the funding for me to do this work.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February 2002

Beschreibung: Predictions of deposition rate are integral to the transport of many constituents including contaminants, organic matter, and larvae. Review of the literature demonstrates a general appreciation for the potential control of deposition by bed roughness, but no direct tests involving flat sediment beds. Understanding the mechanisms at work for flat sediment beds would provide the basis for exploring more complicated bed conditions and the incorporation of other transport processes, such as bioturbation and bedload transport. Generally, fine particle deposition rates are assumed to be equivalent to the suspension settling velocity, therefore, deposition rates in excess of settling are considered enhanced. Flume observations of deposition were made using treatments that covered a wide range of flow, particle, and bed conditions. Specific treatments demonstrated large enhancements (up to eight times settling). Delivery of particles to the interface is important, but models based on delivery alone failed to predict the observed enhancement. This necessitated the development of a new model based on a balance between delivery and filtration in the bed. Interfacial diffusion was chosen as a model for particle delivery. Filtration of particles by the bed is a useful framework for retention, but the shear in the interstitial flow may introduce additional factors not included in traditional filtration experiments. The model performed well in prediction of flow conditions, but there remained a discrepancy between predictions and observed deposition rate, especially for treatments with significant enhancement. Fluid flow predictions by the model,; such as slip at the sediment water interface and fluid penetration into the sediment, appeared to be supported by flume experiments. Therefore, failure to predict the magnitude of enhancement was attributed to far greater filtration efficiencies for the sediment water interface than those measured in sediment columns. Emerging techniques to directly measure fluid and particle motion at the interface could reveal these mechanisms. The observation of enhanced deposition to flat sediment beds reinforces the importance of permeable sediments to the mediation of transport from the water column to the sediment bed.

Beschreibung: The Education Office at the Woods Hole Oceanographic Institution coordinated and provided funding for much of my time here. Additional support has been provided by the Andrew W. Mellon Foundation, the Cooperative Institute for Climate and Ocean Research (CICOR), and the Offce of Naval Research under grant numbers N00014-97-1-0556 (STRATAFORM Plume Study Moored Observations: Data Analysis and Modeling), N00014-96-1-0953 (Graduate Student Training in Engineering: Instrumenting the Continental Shelf Wave Bottom Boundary Layer), and N00014-94-1-0713 (Coupled Biological, Geological and Hydrodynamical Processes Associated with Fine-Particle Transport & Accumulation in the Coastal Ocean).

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Master of Science at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February 2010

Beschreibung: Wind waves in the ocean are a product of complex interaction of turbulent air flow with gravity driven water surface. The coupling is strong and the waves are non-stationary, irregular and highly nonlinear, which restricts the ability of traditional phase averaged models to simulate their complex dynamics. We develop a novel phase resolving model for direct simulation of nonlinear broadband wind waves based on the High Order Spectral (HOS) method (Dommermuth and Yue 1987). The original HOS method, which is a nonlinear pseudo-spectral numerical technique for phase resolving simulation of free regular waves, is extended to simulation of wind forced irregular broadband wave fields. Wind forcing is modeled phenomenologically in a linearized framework of weakly interacting spectral components of the wave field. The mechanism of wind forcing is assumed to be primarily form drag acting on the surface through wave-induced distribution of normal stress. The mechanism is parameterized in terms of wave age and its magnitude is adjusted by the observed growth rates. Linear formulation of the forcing is adopted and applied directly to the nonlinear evolution equations. Development of realistic nonlinear wind wave simulation with HOS method required its extension to broadband irregular wave fields. Another challenge was application of the conservative HOS technique to the intermittent non-conservative dynamics of wind waves. These challenges encountered the fundamental limitations of the original method. Apparent deterioration of wind forced simulations and their inevitable crash raised concerns regarding the validity of the proposed modeling approach. The major question involved application of the original HOS low-pass filtering technique to account for the effect of wave breaking. It was found that growing wind waves break more frequently and violently than free waves. Stronger filtering was required for stabilization of wind wave simulations for duration on the time scale of observed ocean evolution. Successful simulations were produced only after significant sacrifice of resolution bandwidth. Despite the difficulties our modeling approach appears to suffice for reproduction of the essential physics of nonlinear wind waves. Phase resolving simulations are shown to capture both - the characteristic irregularity and the observed similarity that emerges from the chaotic motions. Energy growth and frequency downshift satisfy duration limited evolution parameterizations and asymptote Toba similarity law. Our simulations resolve the detailed kinematics and the nonlinear energetics of swell, windsea and their fast transition under wind forcing. We explain the difference between measurements of initial growth driven by a linear instability mechanism and the balanced nonlinear growth. The simulations validate Toba hypothesis of wind-wave nonlinear quasi-equilibrium and confirm its function as a universal bound on combined windsea and swell evolution under steady wind.

Beschreibung: Author Posting. © American Meteorological Society, 2009. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 39 (2009): 1551-1573, doi:10.1175/2008JPO4152.1.

Beschreibung: A conceptually simple model is presented for predicting the amplitude and periodicity of eddies generated by a steady poleward outflow in a 1½-layer β-plane formulation. The prediction model is rooted in linear quasigeostrophic dynamics but is capable of predicting the amplitude of the β plume generated by outflows in the nonlinear range. Oscillations in the plume amplitude are seen to represent a near-zero group velocity response to an adjustment process that can be traced back to linear dynamics. When the plume-amplitude oscillations become large enough so that the coherent β plume is replaced by a robust eddy field, the eddy amplitude is still constrained by the plume-amplitude prediction model. The eddy periodicity remains close to that of the predictable, near-zero group-velocity linear oscillations. Striking similarities between the patterns of variability in the model and observations south of Indonesia’s Lombok Strait suggest that the processes investigated in this study may play an important role in the generation of the observed eddy field of the Indo-Australian Basin.

Beschreibung: This work was completed at the Woods Hole Oceanographic Institution while TS Durland was supported by the Ocean and Climate Change Institute. MA Spall was supported by NSF Grant OCE-0423975 and J Pedlosky by NSF Grant OCE-0451086. TS Durland acknowledges additional report preparation support from NASA Grant NNG05GN98G.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution August 2000

Beschreibung: The plausibility of local baroclinic instability as a generation mechanism for midocean mesoscale eddies is examined with a two-layer, quasi-geostrophic (QG) model forced by an imposed, horizontally homogeneous, vertically sheared mean flow and dissipated through bottom Ekman friction, Explanations are sought for two observed features of mid-ocean eddies: 1) substantial energy is retained in the baroclinic mode and in the associated deformation radius (Rd) scale, and 2) the ratio of eddy to mean kinetic energy is much larger than one, The tendency of QG to cascade energy into the barotropic mode and into scales larger than Rd can be counteracted when stratification is surface-trapped, for then the baroclinic mode is weakly damped, and hence enhanced, Numerical experiments are performed with both surface-trapped and uniform stratification to quantify this, Experiments with equal Ekman frictions in the two layers are also performed for purposes of contrast, Interpretation is aided with an inequality derived from the energy and enstrophy equations, The inequality forbids the simultaneous retention of substantial energy in the baroclinic mode and in scales near Rd when Ekman friction is symmetric, but points towards surface-trapped stratification and bottomtrapped friction as an environment in which both of these can be achieved, The dissertation also contains a systematic study of geostrophic turbulence forced by nonzonal flows, Narrow zonal jets emerge when shear-induced mean potential vorticity (PV) gradients are small compared to the planetary gradient (β), and energy is a strong function of the angle shear presents to the east-west direction, When shear-induced PV gradients are comparable to β, and the mean shear has a westward component, fields of monopolar vortices form and persist, Energy is asymmetric between fields of cyclones and anticyclones, Such asymmetry was commonly thought not to occur in QG, but is shown here to be introduced by the nonzonal basic state, In both jet and vortex regimes, eddy energy can be much larger than mean kinetic energy, contrary to the expectation that β stabilizes weak shear flows,

Beschreibung: My first three years here were funded by an Office of Naval Research/National Defense Science and Engineering Graduate Fellowship administered by Jeff Jarocz at the American Society for Engineering Education. During the last three years, most of my support has come the National Science Foundation via grant OCE-9617848, with some additional support coming from the Office of Naval Research via grant N00014-95-1-0824.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Master of Science at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 2012

Beschreibung: The purpose of this study is to understand the interactions of tropical cyclones with ocean eddies. In particular we examine the influence of a cold-core eddy on the cold wake formed during the passage of Typhoon Fanapi (2010). The three-dimensional version of the numerical Price–Weller–Pinkel (PWP) vertical mixing model has previously been used to simulate and study the cold wakes of Atlantic hurricanes. The model has not been used in comparison with observations of typhoons in the Western Pacific Ocean. In 2010 several typhoons were studied during the Impact of Typhoons on the Ocean in the Pacific (ITOP) field campaign and Fanapi was particularly well observed. We use these observations and the 3DPWP to understand the ocean cold wake generated by Fanapi. The cold wake of Fanapi was advected by a cyclonic eddy that was south of the typhoon track. The 3DPWP model outputs with and without an eddy are compared with observations made during the field campaign. These observations are compared to model outputs with eddies in a series of positions right and left of the storm track in order to study effects of mesoscale eddies on ocean vertical mixing in the cold wake of typhoons.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution January 1993

Beschreibung: Although the association between soft-sediment invertebrates and a specific sediment type has been documented for many habitats, most studies have been correlative and have failed to convincingly demonstrate any single mechanism to explain this association. Sediment type has generally been characterized by grain size, however, many other potential causal factors correlate with grain size, including organic content, microbial content, stability, food supply, and larval supply. One hypothesis for animal-sediment associations is that settling larvae are transported as passive particles and are sorted into different sedimentary habitats much like sediment grains. To test the hypothesis that near-bed hydrodynamics may modify larval settlement, field and flume experiments were conducted where larval settlement was compared between microdepositional environments (small depressions) and non-trapping environments (flush treatments). Depressions have been observed to trap passive particles, and these experiments were therefore designed to test whether settling larvae would be trapped in depressions like passive particles. Flume flow simulations were carried out with the polychaete Capitella sp. I and the bivalve Mulinia latera/is. Experiments with flush and depression sediment treatments were conducted in the absence of the potentially confounding effects of suspended sediment and organic matter and therefore offered a highly controlled, explicit test of passive hydrodynamic deposition of larvae in depressions. Although larvae of both species were generally able to actively select a high-organic sediment over a low-organic alternative with a comparable grain size, elevated densities of both species were observed in depressions for a given sediment treatment. Thus, both species appeared to be vulnerable to hydrodynamic trapping. M. latera/is larvae, however, often made a "poor choice" by settling in high numbers in depressions containing the low-organic sediment while Capitella sp. I larvae were generally able to "escape" from depressions if the sediment was unsuitable. In field experiments carried out at Station R in Buzzards Bay, Massachusetts, significantly higher densities of Mediomastus ambiseta juveniles, spionid polychaete juveniles, bivalves, gastropod larvae, and nemerteans were observed in depressions compared with flush treatments over 5 relatively short experimental periods (3 or 4 days each) during the summer of 1990. Of the abundant taxa, only Capitella spp. was not significantly more abundant in depressions compared with flush treatments, although numbers tended to be higher in depressions. Experiments were conducted over a short time period to minimize potential biological interactions between taxa and reduce the likelihood that organic material would accumulate in depressions and provide a cue for settling larvae. Thus, higher numbers in depressions suggest that larvae were passively entrained. These flume and field experiments suggest that near-bed hydrodynamics may modify settlement at some scales, and that both active and passive processes may operate in determining larval distributions in shallow-water, muddy habitats. In deep-sea ecosystems, the role of near-bed hydrodynamics is also of interest because of the potential role that larval settlement in organic patches may play in maintaining the immense species diversity characteristic of many deep-sea ecosystems. To try to understand the role of organic patches in deep-sea communities, several investigators have used colonization trays containing sediments that have been treated in different ways. These experiments have been criticized in the past because the sediment surface in the trays was elevated above the bottom and may therefore have interfered with natural boundary layer flow. Flume simulations of flow over these colonization trays revealed serious flow artifacts generated by the trays, and that flow across the sediment surface of the trays was characterized by turbulent eddies, accelerated velocities and boundary layer thickening. These sorts of flow characteristics would not be expected over natural sediments, and an alternative colonization tray was designed to eliminate these artifacts. To test the hypothesis that different types of food patches would result in different types of larval response, and determine how near-bed hydrodynamics may influence larval settlement, flush colonization trays filled with prefrozen sediment were deployed in tandem with artificial depressions south of St. Croix, U.S.V.I at 900 m depth. Colonization trays and artificial depressions were either unenriched or enriched with Thalassiosira sp. and Sargassum sp. two types of algae chosen to mimic natural food patches on the sea floor. Unexpectedly high densities of organisms colonized trays after only 23 days. The Thalassiosira trays were colonized by high densities of a relatively low diversity, opportunistic fauna, Sargassum trays were colonized by lower densities of a higher diversity fauna, and unenriched trays were colonized by very low numbers of a very diverse fauna. All tray faunas were markedly different in composition from the natural, ambient fauna. These fmdings suggest that different patch types did, indeed, result in a specialized faunal response to each of the "patch" types. Depressions on the sea floor provide a natural mechanism for food patch formation because passive particles such as detritus and algae tend to be entrained in the depressions. To determine whether dominant colonizers would be entrained in depressions like passive particles or could differentiate between depression "patch" types in a flow environment that might be expected to make active selection more difficult, artificial depressions were unenriched or enriched with Sargassum sp. or Thalassiosira sp. Total densities of organisms and densities of the most abundant species were substantially lower in artificial depressions than in trays. Densities in Thalassiosira depressions were lower than in Sargassum depressions and densities in unenriched depressions were extremely low, suggesting that dominant colonizers were not passively entrained in depressions and that colonization was specialized and highly active for these taxa. A different fauna was also observed in natural depressions compared with flush sediments, suggesting that natural depressions do contribute to species coexistence. Long-term tray deployments designed to test whether different faunas would be present in "patches" of different ages indicated that time may also play an important part in a deep-sea patch mosaic.

Beschreibung: This was funded by NSF and ONR, NOAA, NSERC (Canada), WHOI Ocean Ventures Fund and the WHOI Ditty Bag Fund.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 2012

Beschreibung: This thesis focuses on ocean circulation and atmospheric forcing in the Atlantic Ocean at the Last Glacial Maximum (LGM, 18-21 thousand years before present). Relative to the pre-industrial climate, LGM atmospheric CO2 concentrations were about 90 ppm lower, ice sheets were much more extensive, and many regions experienced significantly colder temperatures. In this thesis a novel approach to dynamical reconstruction is applied to make estimates of LGM Atlantic Ocean state that are consistent with these proxy records and with known ocean dynamics. Ocean dynamics are described with the MIT General Circulation Model in an Atlantic configuration extending from 35°S to 75°N at 1° resolution. Six LGM proxy types are used to constrain the model: four compilations of near sea surface temperatures from the MARGO project, as well as benthic isotope records of δ18O and δ13C compiled byMarchal and Curry; 629 individual proxy records are used. To improve the fit of the model to the data, a least-squares fit is computed using an algorithm based on the model adjoint (the Lagrange multiplier methodology). The adjoint is used to compute improvements to uncertain initial and boundary conditions (the control variables). As compared to previous model-data syntheses of LGM ocean state, this thesis uses a significantly more realistic model of oceanic physics, and is the first to incorporate such a large number and diversity of proxy records. A major finding is that it is possible to find an ocean state that is consistent with all six LGM proxy compilations and with known ocean dynamics, given reasonable uncertainty estimates. Only relatively modest shifts from modern atmospheric forcing are required to fit the LGM data. The estimates presented herein successfully reproduce regional shifts in conditions at the LGM that have been inferred from proxy records, but which have not been captured in the best available LGM coupled model simulations. In addition, LGM benthic δ18O and δ13C records are shown to be consistent with a shallow but robust Atlantic meridional overturning cell, although other circulations cannot be excluded.

Beschreibung: Primary support was provided by a National Defense Science and Engineering Graduate Fellowship and two National Science Foundation awards: Award #OCE-0645936: “Beyond the Instrumental Record: the Case of Circulation at the Last Glacial Maximum” and Award #OCE-1060735: “Collaborative Research: Beyond the Instrumental Record - the Ocean Circulation at the Last Glacial Maximum and the de-Glacial Sequence”. Important secondary support came from the National Ocean Partnership Program and the National Aeronautics and Space Administration via the ECCO effort at MIT.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February 2014

Beschreibung: Recent work has documented dramatic changes in the West Antarctic Ice Sheet (WAIS) over the past 30 years (e.g., mass loss, glacier acceleration, surface warming) due largely to the influence of the marine environment. WAIS is particularly vulnerable to largescale atmospheric dynamics that remotely influence the transport of marine aerosols to the ice sheet. Understanding seasonal- to decadal-scale changes in the marine influence on WAIS (particularly sea-ice concentration) is vital to our ability to predict future change. In this thesis, I develop tools that enable us to reconstruct the source and transport variability of marine aerosols to West Antarctica in the past. I validate new firn-core sea-ice proxies over the satellite era; results indicate that firn-core glaciochemical records from this dynamic region may provide a proxy for reconstructing Amundsen Sea and Pine Island Bay polynya variability prior to the satellite era. I next investigate the remote influence of tropical Pacific variability on marine aerosol transport to West Antarctica. Results illustrate that both source and transport of marine aerosols to West Antarctica are controlled by remote atmospheric forcing, linking local dynamics (e.g., katabatic winds) with large-scale teleconnections to the tropics (e.g., Rossby waves). Oxygen isotope records allow me to further investigate the relationship between West Antarctic firn-core records and temperature, precipitation origin, sea-ice variability, and large-scale atmospheric circulation. I show that the tropical Pacific remotely influences the source and transport of the isotopic signal to the coastal ice sheet. The regional firn-core array reveals a spatially varying response to remote tropical Pacific forcing. Finally, I investigate longer-term (~200 year) ocean and ice-sheet changes using the methods and results gleaned from the previous work. I utilize sea-ice proxies to reconstruct long-term changes in sea-ice and polynya variability in the Amundsen Sea, and show that the tropics remotely influence West Antarctica over decadal timescales. This thesis utilizes some of the highest-resolution, most coastal records in the region to date, and provides some of the first analyses of the seasonal- to decadal-scale controls on source and transport of marine aerosols to West Antarctica.

Beschreibung: This research was supported by an award from the Department of Energy Office of Science Graduate Fellowship Program (DOE SCGF) to ASC, a James E. and Barbara V. Moltz Research Fellowship, and by grants from the National Science Foundation Office of Polar Programs (NSF-OPP; #ANT-0632031 & #ANT-0631973), the National Science Foundation Major Research Instrumentation Program (NSF-MRI; #EAR-1126217), the NASA Cryosphere Program (#NNX10AP09G), and a WHOI Andrew W. Mellon Foundation Award for Innovative Research.

Beschreibung: Author Posting. © American Meteorological Society, 2014. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 44 (2014): 229–245, doi:10.1175/JPO-D-12-0218.1.

Beschreibung: Data from a mooring deployed at the edge of the East Greenland shelf south of Denmark Strait from September 2007 to October 2008 are analyzed to investigate the processes by which dense water is transferred off the shelf. It is found that water denser than 27.7 kg m−3—as dense as water previously attributed to the adjacent East Greenland Spill Jet—resides near the bottom of the shelf for most of the year with no discernible seasonality. The mean velocity in the central part of the water column is directed along the isobaths, while the deep flow is bottom intensified and veers offshore. Two mechanisms for driving dense spilling events are investigated, one due to offshore forcing and the other associated with wind forcing. Denmark Strait cyclones propagating southward along the continental slope are shown to drive off-shelf flow at their leading edges and are responsible for much of the triggering of individual spilling events. Northerly barrier winds also force spilling. Local winds generate an Ekman downwelling cell. Nonlocal winds also excite spilling, which is hypothesized to be the result of southward-propagating coastally trapped waves, although definitive confirmation is still required. The combined effect of the eddies and barrier winds results in the strongest spilling events, while in the absence of winds a train of eddies causes enhanced spilling.

Beschreibung: The authors wish to thank Paula Fratantoni, Frank Bahr, and Dan Torres for processing the mooring data. The mooring array was capably deployed by the crew of the R/V Arni Fridriksson and recovered by the crew of the R/V Knorr. We thank Hedinn Valdimarsson for his assistance in the field work. Ken Brink provided valuable insights regarding the dynamics of shelf waves. Funding for the study was provided by National Science Foundation Grant OCE-0722694, the Arctic Research Initiative of the Woods Hole Oceanographic Institution. We also wish to thank the Natural Environment Research Council for Ph.D. studentship funding, and the University of East Anglia’s Roberts Fund and Royal Meteorological Society for supporting travel for collaboration.

Beschreibung: 2014-07-01

Beschreibung: Author Posting. © American Meteorological Society, 2015. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 45 (2015): 1822–1842, doi:10.1175/JPO-D-14-0147.1.

Beschreibung: Influences of time-dependent precipitation on water mass transformation and heat budgets in an idealized marginal sea are examined using theoretical and numerical models. The equations proposed by Spall in 2012 are extended to cases with time-dependent precipitation whose form is either a step function or a sinusoidal function. The theory predicts the differences in temperature and salinity between the convective water and the boundary current as well as the magnitudes of heat fluxes into the marginal sea and across the sea surface. Moreover, the theory reveals that there are three inherent time scales: relaxation time scales for temperature and salinity and a precipitation time scale. The relaxation time scales are determined by a steady solution of the theoretical model with steady precipitation. The relaxation time scale for temperature is always smaller than that for salinity as a result of not only the difference in the form of fluxes at the surface but also the variation in the eddy transport from the boundary current. These three time scales and the precipitation amplitude determine the strength of the ocean response to changes in precipitation and the phase relation between precipitation, changes in salinity and temperature, and changes in heat fluxes. It is demonstrated that the theoretical predictions agree qualitatively well with results from the eddy-resolving numerical model. This demonstrates the fundamental role of mesoscale eddies in the ocean response to time-dependent forcing and provides a framework with which to assess the extent to which observed variability in marginal sea convection and water mass transformation are consistent with an external forcing by variations in precipitation.

Beschreibung: This work was initiated at the 2013 WHOI Geophysical Fluid Dynamics Summer Program, which was supported by the National Science Foundation and the Office of Naval Research. This work was also supported by Grant-in-Aid for Research Fellow (25·8466) of the Ministry of Education, Culture, Sports and Technology (MEXT), Japan, the Program for Leading Graduate Schools, MEXT, Japan (YY), and by the National Science Foundation Grant OCE-1232389 (MAS).

Beschreibung: 2016-01-01

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 2016

Beschreibung: Eddies in the ocean move westwards. Those shed by western boundary currents must then interact with continental shelf-slope topography at the western boundary. The presence of other eddies and mean lows complicates this simple picture, yet satellite images show that mesoscale eddies translating near the shelfbreak routinely affect the continental shelves of the Mid-Atlantic Bight, the Gulf of Mexico etc. The consequent cross-shelfbreak transports are currently of unknown importance to shelf budgets of heat, salt and volume. Thus motivated, this thesis uses idealized continuously stratified numerical experiments to explore eddy-slope interactions under four questions: 1. Can the continental slope prevent an eddy from reaching the shelfbreak? 2. What is the structure of the eddy-driven offshore low? 3. How is the continental shelf affected by an eddy at the shelfbreak? 4. Given surface observations, can one estimate the volume of water transported across the shelfbreak? The experiments show that the efficiency of Rossby wave radiation from the eddy controls whether it can cross isobaths: by radiating energy the eddy becomes shallow enough to move into shallower water. For wide continental slopes, relative to an eddy diameter, a slope can prevent an anticyclone from reaching the shelfbreak by shutting down such radiation. For narrow continental slopes, the interaction repeatedly produces dipoles, whose cyclonic halves contain shelf-slope water stacked over eddy water. The formation of such cyclones is explained. Then, the structure of shelf lows forced by the eddy are studied: their vertical structures are rationalized and scalings derived for their cross-isobath scales; for example, the extent to which the eddy influences the shelf. A recipe for estimating cross-isobath transports based on eddy surface properties is put forward. Finally, the findings are tested against observations in the Middle Atlantic Bight of the northeastern United States.

Beschreibung: I acknowledge high-performance computing support from Yellowstone (ark:/85065/d7wd3xhc) provided by NCAR’s Computational and Information Systems Laboratory, sponsored by the National Science Foundation. The research presented here was funded by National Science Foundation grants OCE-1059632 and OCE-1433953. Funding support from the Academic Programs Oice, WHOI is also gratefully acknowledged.

Beschreibung: Author Posting. © American Meteorological Society, 2018. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 48 (2018): 773-794, doi:10.1175/JPO-D-17-0205.1.

Beschreibung: Fourteen autonomous profiling floats, equipped with CTDs, were deployed in the deep eastern and western basins of the Gulf of Mexico over a four-year interval (July 2011–August 2015), producing a total of 706 casts. This is the first time since the early 1970s that there has been a comprehensive survey of water masses in the deep basins of the Gulf, with better vertical resolution than available from older ship-based surveys. Seven floats had 14-day cycles with parking depths of 1500 m, and the other half from the U.S. Argo program had varying cycle times. Maps of characteristic water masses, including Subtropical Underwater, Antarctic Intermediate Water (AAIW), and North Atlantic Deep Water, showed gradients from east to west, consistent with their sources being within the Loop Current (LC) and the Yucatan Channel waters. Altimeter SSH was used to characterize profiles being in LC or LC eddy water or in cold eddies. The two-layer nature of the deep Gulf shows isotherms being deeper in the warm anticyclonic LC and LC eddies and shallower in the cold cyclones. Mixed layer depths have an average seasonal signal that shows maximum depths (~60 m) in January and a minimum in June–July (~20 m). Basin-mean steric heights from 0–50-m dynamic heights and altimeter SSH show a seasonal range of ~12 cm, with significant interannual variability. The translation of LC eddies across the western basin produces a region of low homogeneous potential vorticity centered over the deepest part of the western basin.

Beschreibung: The authors were supported by the Department of the Interior, Bureau of Ocean Energy Management (BOEM), Contract M08PC20043 to Leidos, Inc., Raleigh, North Carolina.

Beschreibung: 2018-10-04

Beschreibung: Our knowledge of clastic, shallow-water sediments over any considerable area of ocean floor is very generalized and leaves much to be desired. The notations concerning the character of the bottom found on all charts are necessarily limited to a descriptive word or two, and although suffcient for navigational purposes, are of little use to the stratigrapher. Of all the marine sediments in the geologic column, those laid down in the neritic zone bulk the largest. They grade slowly into the sediments of the bathyal zone with no sharp line of demarcation. The early oceanographers were more interested in the clays and organic oozes of the deep sea and they added but little information concerning those materials which to the geologist are the most important. From the charts one is apt to obtain the impression that bottom deposits, excepting those of the deep sea, are very patchy in their distribution, and that there is little rhyme or reason in their arrangement. On the other hand the geological text books are apt to make it appear that there is an orderly gradation of sediments from coarse to fine in an offshore direction, and that a sandstone is always an indication of shallow water deposition, with a shale the reverse. Twenhofel has called attention to the role of environment in sedimentation. Like organisms, sediments are the resultants of a long sequence of environmental factors to which they have been exposed: action by currents, wave generated and otherwise, availability of supply and its type, distance from shore, and depth of water, plus their combined effect during times of changing sea level in the past. These factors have operated in the regions of production, during the period of transportation, and at the place of deposition, and the retention of older characteristics further complicates the record. The following study was undertaken with the hope that through a detailed and systematic series of samples not only might something be learned about the characteristics and distribution of the sediments of a particular area, but something also of the environmental factors which govern conditions of sedimentation in a major ocean.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Woods Hole Oceanographic Institution February 1980

Beschreibung: The existence of resonant, baroclinic, equatorially-trapped inertia-gravity waves (discovered by Wunsch and Gill (1976)) is confirmed in the mid-Pacific by spectral analysis of long sea level records. The energy of the low-mode inertia-gravity waves is found to decrease toward the meridional boundaries. A simple spectral model, acknowledging the dispersive characteristics of the equatorial waves, adequately reproduces the observed mid-Pacific sea level spectra in the 1-6 day band. Model spectra computed at latitudes outside the equatorial waveguide of the gravest meridional modes suggest the presence of "inertial" peaks in several observed sea level spectra. Resonant, low-mode inertia-gravity waves may also exist in the Indian Ocean. Sea level fluctuations along the Pacific equator are found to have Kelvin wave characteristics in the 35-80 day band, and, in particular, propagation from the western Pacific to the coast of South America is observed. The Kelvin waves are atmospherically-forced in the central- western Pacific and have a computed equivalent depth corresponding to the first-baroc1inic mode. Outside of the equatorial mid-Pacific, a non-static ocean response to air pressure in the 4-6 day band is dominated by a basin-wide, barotropic, planetary mode. The low Q of this mode suggests that the ocean is viscous with respect to large-scale barotropic oscillations. The dynamical components of the observed long-period tides have been isolated for the first time using the "self-consistent" equilibrium tide of Agnew and Farrell (1978). The tides are slightly non-equilibrium with large horizontal scales. The relatively short-scale Rossby modes predicted by Wunsch (1967) are not observed, perhaps because of the poor spatial coverage of the dataset. Considering the low Q of the 4-6 day planetary basin mode, it is suggested that the long-period tides are frictionally-controlled. The 4- and 5-day equatorial inertia-gravity waves, the 35-80 day Kelvin waves and the 4-6 day planetary basin mode are clearly atmospherically forced, and, perhaps surprisingly, they are forced by atmospheric waves that have similar horizontal structures, i.e., 4-5 day Rossby-gravity waves, 40-50 day Kelvin waves and a 5-day global barotropic mode. The surface expressions of these atmospheric waves are determined in order to understand the nature of the oceanic response, e.g., resonant or forced. Much of the information about the surface atmospheric fields that has been collected, including frequency-wavenumber descriptions, awaits an accurate model of the coupling between wind stress and internal ocean waves.

Beschreibung: Monetary support for this research was provided by the National Science Foundation through contract OCE73-0l384. At various times, tuition and living expenses were paid by funds from the NSF contract above, the Office of Naval Research (contract N00014-C-75-029l), the Cecil and Ida Green Professorship in Earth Sciences, the J. P. Luther Educational Fund and by an M.I.T. Educational Tuition Award.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September, 2005

Beschreibung: This thesis evaluates the nature and magnitude of tropical climate variability from the Last Glacial Maximum to the present. The temporal variability of two specific tropical climate phenomena is examined. The first is the position of the Intertropical Convergence Zone (ITCZ) in the Atlantic basin, which affects sea surface temperature (SST) and precipitation patterns throughout the tropical Atlantic. The second is the strength of the Indian Monsoon, an important component of both tropical and global climate. Long-term variations in the position of the ITCZ in the Atlantic region are determined using both organic geochemical techniques and climate modeling. Upwelling in Cariaco Basin is reconstructed using chlorin steryl esters as proxies for phytoplankton community structure. We find that the diatom population was larger during the Younger Dryas cold event, indicating that upwelling was enhanced and the mean position of the ITCZ was farther south during the Younger Dryas than it is today. A climate simulation using an ocean-atmosphere general circulation model confirms these results by demonstrating that the ITCZ shifts southward in response to high-latitude cooling. The climate of the Arabian Sea region is dominated by the Indian Monsoon. Results from modem sediments from a suite of cores located throughout the Arabian Sea suggest that wind strength is well represented by the accumulation rate and carbon isotopic composition of terrestrially-derived plant waxes in sediments. Arabian Sea SST patterns, reconstructed from a suite of sediment cores representing four time slices utilizing the Mg/Ca SST proxy, suggest that both the summer and winter monsoons were enhanced 8,000 yr BP relative to today while the summer monsoon was weaker and the winter monsoon stronger at 15,000 and 20,000 yr. These results are confirmed by a time-series reconstruction of SST on the Oman Margin that reveals that SST at this site is sensitive to both regional and global climate processes. The results of this thesis demonstrate that tropical climate, as evaluated by a number of different proxies as well as climate models, has varied substantially over the past 20,000 years and is closely coupled to climate at high-latitudes.

Beschreibung: This work was funded by the National Science Foundation (OCE02-20776 and OCE0334598 to D. Oppo), a Schlanger Ocean Drilling Program Fellowship, a WHOI Watson Fellowship, and a Fye Teaching Fellowship.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Master of Science at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 2003

Beschreibung: The importance of eddies and nonlinearities in ß-plume dynamics in the deep ocean was investigated using reduced gravity models of the deep ocean forced by a small region of cross isopycnal transport in the interior. The effect of topography on ß-plumes was also examined by placing a Gaussian bump in the forcing region. Despite the fact that the mean flow is weak in the deep ocean interior, it was found that the nonlinearity and instabilities are still important for realistic parameter and forcing values. The flow was dominated by eddies and was remarkably different from what would be expected from a linear solution.

Beschreibung: This study was supported by Woods Hole Oceanographic Institution Academic Programs Office Fellowship and National Science Foundation Grant 89542700.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 2007

Beschreibung: Observations of current velocity, temperature, salinity and pressure from a 2-year moored array deployment and four hydrographic cruises conducted by the United States Southern Ocean GLOBEC program on the western Antarctic Peninsula continental shelf are used to characterize the ocean circulation and its connection to fresh water and heat fluxes on the shelf. Mean velocities on the shelf are of the order of 5 cm/s or less. Tidal motions are dominated by the M2 and S2 semi-diurnal tides and the O1 and K1 diurnal tides, although the tidal velocities are typically less than 2 cm/s. Near-inertial motions are relatively large, with current velocities as high as 26 cm/s. It is shown that Marguerite Trough, a large bathymetric feature connecting the shelf-break to Marguerite Bay, plays a critical role in determining the circulation. The mean flow is strongly steered in the along-slope direction, and the tidal currents also show increasing current polarization at depth in Marguerite Trough. At timescales of 5 to 20 days, the observations show bottom-intensified motion in Marguerite Trough consistent with bottom-trapped topographic Rossby waves. The subtidal circulation in the trough has a significant wind-driven component in Marguerite Trough, with downwelling-favorable winds forcing cross-shelf flow on the northern side of the trough and along the shore on the outer shelf. Upwelling-favorable winds force roughly the opposite circulation. The cyclonic circulation on the trough helps advect blobs of salty, warm and nutrient-rich water across the shelf. These intrusions are small (≈4 km) and frequent (4 events/month). Also, the Antarctic Peninsula Coastal Current (APCC), a coastal buoyant current which is described for the first time here. The APCC is a seasonal current which is only present during the ice-free season and is forced by freshwater fluxes associated with large glacier melt and precipitation rates in the region.

Beschreibung: Thanks goes to the agencies who made this thesis possible: the National Science Foundation Office of Polar programs through U.S. Southern Ocean GLOBEC grants OPP 99-10092 and 06-23223, the Chilean government through its Presidential Fellowship program and the Coastal Ocean Institute and the Cooperative Institute for Climate and Ocean Research.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 1996

Beschreibung: Nonlinear quasigeostrophic flows in two layers over a topographic slope are considered. The evolution depends on the size of two parameters which indicate the degree of nonlinearity at depth. The first measures the importance of relative vorticity advection and the second of stretching vorticity. Two types of isolated vortex are used to examine the parameter dependence. An initially barotropic vortex remains barotropic only when the first parameter is large, otherwise topographic waves dominate at depth. An Initially surface-trapped vortex larger than deformation scale is baroclinically unstable when the second is large, but is stabilized by the slope otherwise. Both parameters are also relevant to cascading geostrophic turbulence. If the stretching parameter is large, a "barotropic cascade" occurs at the deformation radius (Rhines, 1977) and the cascade "arrests" when the relative vorticity parameter is order unity. If small, layer coupling is hindered and the cascade is arrested at the deformation scale, with the flow dominated by isotropic surface vortices. In both cases, the distinction between vortices and waves is transparent when viewing potential vorticity. It is more difficult to identify waves and vortices from the streamfunction fields, because the waves are present in both layers.

Beschreibung: Funding for this research was provided by Office of Naval Research Coastal Science Code, grants N00014-92-J-1643 and N00014-92-J-1528.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution June 2008

Beschreibung: This study presents observations of turbulence dynamics made during the low winds portion of the Coupled Boundary Layers and Air-Sea Transfer experiment (CBLAST-Low). Observations were made of turbulent fluxes, turbulent kinetic energy, and the length scales of flux-carrying and energy-containing eddies in the ocean surface boundary layer. A new technique was developed to separate wave and turbulent motions spectrally, using ideas for turbulence spectra that were developed in the study of the bottom boundary layer of the atmosphere. The observations of turbulent fluxes allowed the closing of heat and momentum budgets across the air-sea interface. The observations also show that flux-carrying eddies are similar in size to those expected in rigid-boundary turbulence, but that energy-containing eddies are smaller than those in rigid-boundary turbulence. This suggests that the relationship between turbulent kinetic energy, depth, and turbulent diffusivity are different in the ocean surface boundary layer than in rigid-boundary turbulence. The observations confirm previous speculation that surface wave breaking provides a surface source of turbulent kinetic energy that is transported to depth where it dissipates. A model that includes the effects of shear production, wave breaking and dissipation is able to reproduce the enhancement of turbulent kinetic energy near the wavy ocean surface. However, because of the different length scale relations in the ocean surface boundary layer, the empirical constants in the energy model are different from the values that are used to model rigid-boundary turbulence. The ocean surface boundary layer is observed to have small but finite temperature gradients that are related to the boundary fluxes of heat and momentum, as assumed by closure models. However, the turbulent diffusivity of heat in the surface boundary layer is larger than predicted by rigid-boundary closure models. Including the combined effects of wave breaking, stress, and buoyancy forcing allows a closure model to predict the turbulent diffusivity for heat in the ocean surface boundary layer.

Beschreibung: This work was supported by Office of Naval Research grants N00014-00-1-0409, N00014-01-1-0029, and N00014-03-1-0681, the Woods Hole Oceanographic Institution Academic Programs Office, and National Aeronautics and Space Administration grant NAG5-11933.

Beschreibung: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution January 1983

Beschreibung: Isotope studies of nitrogen and carbon were undertaken to investigate the fate of particulate organic matter (POM) during its residence in the water column and after deposition on the seafloor. The processes focused on were water-column transformations and sedimentary diagenesis. Sampling sites were chosen to provide POM subject to different specific mineralization processes (nitrification, denitrification, and sulfate reduction), different lengths of water column (duration of the mineralization process), and differences in the size of the organic-matter flux. The δl5N and δ13C of plankton, POM, and sediments from several oceanic sites were related to biological and hydrographic processes identified from nutrient, temperature, and salinity profiles. This was done to determine what effect these processes have on the δ15N of POM. Four stations were studied in the upwelling area off the coast of Peru and one station was studied in the Gulf of Maine. Important factors controlling the δ15N of plankton appear to be the concentration and δl5N of nitrate in the surface waters, and the relative zooplankton and phytoplankton abundances. Plankton from the Peru Upwelling Area are enriched in 15N as compared to plankton from other parts of the world's oceans where denitrification is absent. This enrichment may be due to the assimilation of 15N-enriched nitrate, produced by the selective reduction of 14N during denitrification. Zooplankton are 3 to 4% enriched in 15N as compared with phytoplankton. Production of 14N -enriched fecal pellets is suggested as a mechanism for this trophic enrichment. In the surface waters, the δl5N of POM is similar to that of plankton. In the Peru Upwelling Area, the δ15N of POM from the oxygen-deficient waters decreases with increasing depth. In the Gulf of Maine, below the euphotic zone in the oxic deep waters, the δ15N of POM increases with increasing depth. The difference in isotopic alteration may be due to the effect of different redox conditions on the mechanism and sequence by which specific organic nitrogen compounds, variably enriched in 15M, undergo degradation. Furthermore, bacterial growth on nitrogen-poor particles in the deep waters of the Peru Upwelling Area may contribute to the low δ15N of POM. In contrast to the large range in δ15N (-2 to +17%) of the POM, the range of δ15N in the sediments is small (+5 to +9%). Within a core, the average variation in δ15N was only 1.8%. Temporal variability in the δ15N of sedimenting POM and benthic activity appear to be important in determining the δ15N of the sediments. The large changes in POM concentration and isotope content at the sediment/water interface as compared with the more constant values found down-core, suggest that processes occuring at the sediment/water interface are critical, although bioturbation may also be important in determining the δ15N of oxic sediments. If diagenesis causes a significant loss of organic matter, profiles of organic carbon and nitrogen contents should show decreases with increasing depth and C/N ratios should increase with increasing depth (Reimers, 1981). Since none of the sedimentary profiles exhibited such trends, it is concluded that diagenesis was insufficient to erase the percent carbon, nitrogen and C/N ratio signatures generated by the POM flux and alterations at the sediment/water interface. Temporal variability in the δ15N of bottom-water POM may be caused by changes in deep-water currents which transport POM horizontally and to changes in bacterial and possibly other biological activity in the water column. This thesis work suggests that δ15N may be a useful tool in studying the geochemistry of POM in the marine environment. In addition, this research has shown that interpretation of the sedimentary 15N record must include consideration of isotopic alteration associated with bacterial remineralization of POM and benthic activity.

Beschreibung: Funds for this research were provided by the Massachusetts Institute of Technology / Woods Hole Oceanographic Institution Joint Program in Oceanography, the National Science Foundation under Grant No. OCE-8024442, and the Andrew W. Mellon Foundation through the Center for Coastal Research of the Woods Hole Oceanographic Institution.

Beschreibung: Author Posting. © American Meteorological Society, 2010. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 40 (2010): 2341–2347, doi:10.1175/2010JPO4465.1.

Beschreibung: The mean downwelling in an eddy-resolving model of a convective basin is concentrated near the boundary where eddies are shed from the cyclonic boundary current into the interior. It is suggested that the buoyancy-forced downwelling in the Labrador Sea and the Lofoten Basin is similarly concentrated in analogous eddy formation regions along their eastern boundaries. Use of a transformed Eulerian mean depiction of the density transport reveals the central role eddy fluxes play in maintaining the adiabatic nature of the flow in a nonperiodic region where heat is lost from the boundary current. The vorticity balance in the downwelling region is primarily between stretching of planetary vorticity and eddy flux divergence of relative vorticity, although a narrow viscous boundary layer is ultimately important in closing the regional vorticity budget. This overall balance is similar in some ways to the diffusive–viscous balance represented in previous boundary layer theories, and suggests that the downwelling in convective basins may be properly represented in low-resolution climate models if eddy flux parameterizations are adiabatic, identify localized regions of eddy formations, and allow density to be transported far from the region of eddy formations.

Beschreibung: This study was supported by the National Science Foundation under Grants OCE-0726339 and OCE-0850416.

Beschreibung: Author Posting. © American Meteorological Society, 2009. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 39 (2009): 3162-3175, doi:10.1175/2009JPO4239.1.

Beschreibung: This study analyzes anisotropic properties of the material transport by eddies and eddy-driven zonal jets in a general circulation model of the North Atlantic through the analysis of Lagrangian particle trajectories. Spreading rates—defined here as half the rate of change in the particle dispersion—in the zonal direction systematically exceed the meridional rates by an order of magnitude. Area-averaged values for the upper-ocean zonal and meridional spreading rates are approximately 8100 and 1400 m2 s−1, respectively, and in the deep ocean they are 2400 and 200 m2 s−1. The results demonstrate that this anisotropy is mainly due to the action of the transient eddies and not to the shear dispersion associated with the time-mean jets. This property is consistent with the fact that eddies in this study have zonally elongated shapes. With the exception of the upper-ocean subpolar gyre, eddies also cause the superdiffusive zonal spreading, significant variations in the spreading rate in the vertical and meridional directions, and the difference between the westward and eastward spreading.

Beschreibung: Funding for IK was provided by NSF Grants OCE 0346178, 0749722, and 0842834. Funding for PB was provided by NSF Grants OCE 0344094 and OCE 0725796 and by the research grant from the Newton Trust of the University of Cambridge. For JP the acknowledgement is to NSF OCE-0451086.

Beschreibung: Author Posting. © American Meteorological Society, 2009. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 39 (2009): 1361-1379, doi:10.1175/2008JPO4096.1.

Beschreibung: Multiple zonal jets are observed in satellite data–based estimates of oceanic velocities, float measurements, and high-resolution numerical simulations of the ocean circulation. This study makes a step toward understanding the dynamics of these jets in the real ocean by analyzing the vertical structure and dynamical balances within multiple zonal jets simulated in an eddy-resolving primitive equation model of the North Atlantic. In particular, the authors focus on the role of eddy flux convergences (“eddy forcing”) in supporting the buoyancy and relative/potential vorticity (PV) anomalies associated with the jets. The results suggest a central role of baroclinic eddies in the barotropic and baroclinic dynamics of the jets, and significant differences in the effects of eddy forcing between the subtropical and subpolar gyres. Additionally, diabatic potential vorticity sources and sinks, associated with vertical diffusion, are shown to play an important role in supporting the potential vorticity anomalies. The resulting potential vorticity profile does not resemble a “PV staircase”—a distinct meridional structure observed in some idealized studies of geostrophic turbulence.

Beschreibung: Funding for IK was provided by NSF Grants OCE 0346178 and 0749722. Funding for PB was provided by NSF Grants OCE 0344094 and OCE 0725796 and by the research grant from the Newton Trust of the University of Cambridge. For JP the acknowledgement is to NSF OCE-0451086.