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  • 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry  (15)
  • 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions  (14)
  • ddc:551.9
  • AGU  (15)
  • Springer-Verlag  (10)
  • Blackwell Publishing Ltd  (6)
  • American Chemical Society
  • American Physical Society
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  • 1
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    Soil CO2 emissions at Furnas volcano (São Miguel Island, Azores archipelago) - volcano monitoring perspectives, geomorphologic studies and land-use planning application (2011)
    AGU
    Details
    Publication Date: 2020-11-12
    Description: Accepted for publication in Journal of Geophysical Research. Copyright (2010) American Geophysical Union.
    Description: Carbon dioxide (CO2) diffuse degassing structures (DDS) at Furnas Volcano (São Miguel Island, Azores) are mostly associated with the main fumarolic fields, evidence that CO2 soil degassing is the surface expression of rising steam from the hydrothermal system. Locations with anomalous CO2 flux are mainly controlled by tectonic structures oriented WNW-ESE and NW-SE and by the geomorphology of the volcano, as evidenced by several DDS located in depressed areas associated with crater margins. Hydrothermal soil CO2 emissions in Furnas volcano are estimated to be ~ 968 t d-1. Discrimination between biogenic and hydrothermal CO2 was determined using a 1 statistical approach and the carbon isotope composition of the CO2 efflux. Different sampling densities were used to evaluate uncertainty in the estimation of the total CO2 flux, and showed that a low density of points may not be adequate to quantify soil emanations from a relatively small DDS. Thermal energy release associated to diffuse degassing at Furnas caldera is about 118 MW (from an area of ~ 4.8 km2) based on the H2O/CO2 ratio in fumarolic gas. The DDS affect also Furnas and Ribeira Quente villages, which are located inside the caldera and in the south flank of the volcano, respectively. At these sites, 58% and 98% of the houses are built over hydrothermal CO2 emanations, and the populations are at risk due to potential high concentrations of CO2 accumulating inside the dwellings. Keywords: Soil diffuse degassing; soil CO2 flux; emission rates; Azores archipelago 2
    Description: Published
    Description: B12208
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Description: open
    Keywords: Soil CO2 emissions ; Furnas volcano ; volcano monitoring. ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
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    Deep explosive focal depths during maar forming magmatic-hydrothermal eruption: Baccano Crater, Central Italy (2012)
    Springer-Verlag
    Details
    Publication Date: 2020-12-14
    Description: We describe the eruptive activity of the Pleistocene composite Baccano maar crater in the Sabatini Volcanic Complex (Central Italy) combining stratigraphy, grain size/componentry and rare earth element and Yttrium (REY) composition of its eruptive products with the stratigraphy and geothermal data derived from deep wells drilled on the Baccano structural high. The main lithological characteristics of the basal Baccano maar pyroclastic deposit, composed of more than 60% wt of non-thermometamorphosed lithic clasts from the sedimentary basement, show that the first eruption was magmatic-hydrothermal in nature. The lithology of the sedimentary lithic clasts indicates that the fragmentation level was at a depth of −1,000 to −1,200 m, with fragment depth verified by deep well stratigraphy. The 15% wt juvenile non-vesicular glass components suggest that magma played a minor role in powering the eruption. Assuming that the high-salinity hot hydrothermal fluids (365〈T〈410°C and P∼25 MPa), hosted in the highly permeable and confined aquifer below the Baccano maar are representative of those at the time of the eruption, we propose that hydrofracturing would have triggered the eruption caused by overpressure at the top of the geothermal aquifer. REY analysis performed on pyroclastic fragments and basement rocks suggest that partial dissolution of the deeper limestones (〉−1,400 m) by the aggressive hydrothermal fluids enriched in acid components (HF, HCl, and H2SO4) may have contributed to increased CO2 partial pressure that helped to drive the hydrofracturing. This could have caused rapid vapour separation and pressure drop, allowing the almost simultaneous breaking of the aquifer cover and brecciation of the calcareous units down to −1,000 to −1,200 m depth. The relative abundance of calcareous lithics in the basal part of the first Baccano eruptive unit, representing about the upper 200 m of stratigraphy below the top of the Baccano structural high, reveals the descent of the piezometric surface during the eruption. Combining deep well information and maar product stratigraphy, using also REY data from maar pyroclastic fragments and the basement rocks we draw an interpretative model for the Baccano maar forming eruption, concluding that a) magmatic-hydrothermal eruptions may originate deeper than previously thought, and b) hydrothermal fluids circulating in limestone aquifers may play an important role in triggering such eruptions.
    Description: Published
    Description: 899-915
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Hydrothermal eruptions ; Hydromagmatism ; Explosion depth ; REY ; Hydrothermal fluids ; Baccano maar ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
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    Textural and geophysical characterization of explosive basaltic activity at Villarrica volcano (2008)
    AGU
    Details
    Publication Date: 2021-06-15
    Description: Villarrica volcano (Chile) is one of the most active volcanoes in South America. Its activity is currently characterized by continuous degassing from a summit lava lake/vent punctuated by explosive events. During November 2004 a multidisciplinary experiment was deployed for a 10-d period to define the style of emission and infer shallow conduit dynamics at this basaltic center. This involved collection of thermal, seismic and infrasonic data to describe the background activity confined inside the crater, and use of samples to texturally and chemically characterize the ejecta from more energetic explosions able to attain the crater rim. The background activity was characterized by gas bursting with a frequency of 9 events per minute. This involved emission of gas puffs fed by bubble bursting, with larger bursts emplacing sheets of magma onto the lower crater walls. The ejecta population from the more energetic events was characterized by the coexistence of both scoriae and golden pumice. These two types of clasts have different textures but identical glass compositions, suggesting that they underwent different conduit histories. The golden pumice is interpreted as the expanding inner part of a short-lived jet fed by a rapidly ascending, magma batch. The scoria forms the outer portion of the jet and comprises degassed material entrained during passage of the fresh batch through material residing in the upper-most portion of the conduit. We thus have a largely degassed upper column that feeds persistent bubble bursting, through which fresh batches occasionally rise to feed events of relatively higher energy.
    Description: Published
    Description: B08206
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: reserved
    Keywords: basaltic activity ; remote sensing ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
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    Relationships between diffuse CO2 emissions and volcanic activity on the island of Vulcano (Aeolian Islands, Italy) during the period 1984–1994 (2006)
    Springer-Verlag
    Details
    Publication Date: 2017-04-04
    Description: Measurements of CO2 flux from the ground were periodically carried out on the island of Vulcano (Aeolian Islands, Italy) between 1984 and 1994. Three high-flux areas were identified at the foot of the volcanic cone (La Fossa), either inside or very close to the main village. Effect of the choice of the sampling grid was evaluated. A different sampling grid resulted in similar distribution patterns, but with different CO2 fluxes. Therefore, the absolute estimate of the total flux from the investigated area includes a large degree of uncertainty, but repeated measurements with permanent sampling sites are accurate and can detect small changes. No correlation of the flux with atmospheric parameters was found at sites with high fluxes. Some periods characterized by high CO2 fluxes were observed, and a close correlation was found between the gas emissions from the ground and other geochemical and geophysical parameters such as temperature, chemical composition, steam, and SO2 flux from fumaroles, seismic energy release, and ground deformations. The results show that major temporal variations of diffuse CO2 flux are related to variations in volcanic activity.
    Description: Gruppo Nazionale per la Vulcanologia CNR Italy.
    Description: Published
    Description: 219–228
    Description: partially_open
    Keywords: CO2 ; Flux measurements ; Gas emissions ; Soil gas ; Volcanic activity ; Vulcano ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
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    The July-August 2001 eruption of Mt. Etna (Sicily) (2008)
    Springer-Verlag
    Details
    Publication Date: 2017-04-04
    Description: The July-August 2001 eruption of Mt. Etna stimulated widespread public and media interest, caused significant damage to tourist facilities, and for several days threatened the town of Nicolosi on the S flank of the volcano. Seven eruptive fissures were active, five on the S flank between 3050 and 2100 m altitude, and two on the NE flank between 3080 and 2600 m elevation. All produced lava flows over various periods during the eruption, the most voluminous of which reached a length of 6.9 km. Mineralogically the 2001 lavas fall into two distinct groups, indicating that magma was supplied through two different and largely independent pathways, one extending laterally from the central conduit system through radial fissures, the other being a vertically ascending eccentric dike. Furthermore one of the eccentric vents, at 2570 m elevation, was the site of vigorous phreatomagmatic activity as the dike cut through a shallow aquifer, both during the intial and closing stages of the eruption. For six days the magma column feeding this vent was more or less effectively sealed from the aquifer, permitting powerful explosive and effusive magmatic activity. While the eruption was characterized by a highly dynamic evolution, complex interactions between some of the eruptive fissures, and changing eruptive styles, its total volume (~25 x 106 m3 of lava and 5-10 x 106 m3 of pyroclastics) was relatively small in comparison with other recent eruptions of Etna. Effusion rates were calculated on a daily basis and reached peaks of 14-16 m3 s-1 while the average effusion rate at all fissures was about 11 m3 s-1, which is not exceptionally high. The eruption showed a number of peculiar features, but none of these (except the contemporaneous lateral and eccentric activity) represented a significant deviation from Etna's eruptive behavior in the long term. However, the 2001 eruption could be but the first in a series of flank eruptions, some of which might be more voluminous and hazardous. Placed in a long-term context, the eruption confirms a distinct trend, initiated during the past 50 years, toward higher production rates and more frequent eruptions, which might bring Etna back to similar levels of activity as during the early to mid 17th century.
    Description: Published
    Description: 461-476
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Mt. Etna ; 2001 eruption ; Lava flow-field evolution ; Central-lateral vs. eccentric activity ; Phreatomagmatism ; Eruption dynamics ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 6
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    Anomalies of mantle-derived helium during the 1997-1998 seismic swarm of Umbria-Marche, Italy (2009)
    AGU
    Details
    Publication Date: 2017-04-04
    Description: More than 100 3 ~ e / 4i~soeto pe ratios were measured in CO,-dominated gas samples collected during the 1997-1 998 seismic crisis that shook the Umbria-Marche, Central Apennines, Italy. Although the gas emissions were located in a typical "crustal" environment the measured values delineate variable mixing proportions between mantle-derived and crustal helium. During the monitoring period anomalous 3 ~ e P r~atieos were observed, together with a significant increase of fluid outflows. The observed 3 ~ e Pa~noema lies appear to be driven by stress-induced crustal deformations affecting micro-fracturing and bulk permeability and, in turn, by a seismogenic-induced modification of the crustal permeability of rocks. Since crustal deformations can also occur aseismically, the geochemical anomalies must be considered indicators of processes occurring below the surface, which could eventually help to estimate the probability increase of an impending earthquake, instead of pure empirical precursors.
    Description: Published
    Description: 839-842
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: helium ; earthquakes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 7
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    The occurrence of Mt Barca flank eruption in the evolution of the NW periphery of Etna volcano (Italy) (2009)
    Springer-Verlag
    Details
    Publication Date: 2017-04-04
    Description: Geological surveys, tephrostratigraphic study, and 40Ar/39Ar age determinations have allowed us to chronologically constrain the geological evolution of the lower NW flank of Etna volcano and to reconstruct the eruptive style of the Mt Barca flank eruption. This peripheral sector of the Mt Etna edifice, corresponding to the upper Simeto valley, was invaded by the Ellittico volcano lava flows between 41 and 29 ka ago when the Mt Barca eruption occurred. The vent of this flank eruption is located at about 15 km away from the summit craters, close to the town of Bronte. The Mt Barca eruption was characterized by a vigorous explosive activity that produced pyroclastic deposits dispersed eastward and minor effusive activity with the emission of a 1.1-km-long lava flow. Explosive activity was characterized by a phreatomagmatic phase followed by a magmatic one. The geological setting of this peripheral sector of the volcano favors the interaction between the rising magma and the shallow groundwater hosted in the volcanic pile resting on the impermeable sedimentary basement. This process produced phreatomagmatic activity in the first phase of the eruption, forming a pyroclastic fall deposit made of high-density, poorly vesicular scoria lapilli and lithic clasts. Conversely, during the second phase, a typical strombolian fall deposit formed. In terms of hazard assessment, the possible occurrence of this type of highly explosive flank eruption, at lower elevation in the densely inhabited areas, increases the volcanic risk in the Etnean region and widens the already known hazard scenario.
    Description: Published
    Description: 79-94
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Etna volcano ; Unconformity ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 8
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    Carbon dioxide diffuse emission from the soil: ten years of observations at Vesuvio and Campi Flegrei (Pozzuoli), and linkages with volcanic activity (2010)
    Springer-Verlag
    Details
    Publication Date: 2017-04-04
    Description: Carbon dioxide flux from the soil is regularly monitored in selected areas of Vesuvio and Solfatara (Campi Flegrei, Pozzuoli) with the twofold aim of i) monitoring spatial and temporal variations of the degassing process and ii) investigating if the surface phenomena could provide information about the processes occurring at depth. At present, the surveyed areas include 15 fixed points around the rim of Vesuvio and 71 fixed points in the floor of Solfatara crater. Soil CO2 flux has been measured since 1998, at least once a month, in both areas. In addition, two automatic permanent stations, located at Vesuvio and Solfatara, measure the CO2 flux and some environmental parameters that can potentially influence the CO2 diffuse degassing. Series acquired by continuous stations are characterized by an annual periodicity that is related to the typical periodicities of some meteorological parameters. Conversely, series of CO2 flux data arising from periodic measurements over the arrays of Vesuvio and Solfatara are less dependent on external factors such as meteorological parameters, local soil properties (porosity, hydraulic conductivity) and topographic effects (high or low ground). Therefore we argue that the long-term trend of this signal contains the “best” possible representation of the endogenous signal related to the upflow of deep hydrothermal fluids.
    Description: Published
    Description: 103-118
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Carbon dioxide ; Soil diffuse degassing ; Monitoring ; Vesuvio . Campi Flegrei ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 9
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    Volcanic ash and SO2 in the 2008 Kasatochi eruption: Retrievals comparison from different IR satellite sensors (2011)
    AGU
    Details
    Publication Date: 2012-02-03
    Description: The Kasatochi 2008 eruption was detected by several infrared satellite sensors including Moderate Resolution Imaging Spectroradiometer (MODIS), Advanced Very High Resolution Radiometer (AVHRR), and Atmospheric Infrared Sounder (AIRS). In this work a comparison between the volcanic cloud SO2 and ash retrievals derived from these instruments has been undertaken. The SO2 retrieval is carried out by using both the 7.3 and 8.7 micron absorption features while ash retrieval exploits the 10–12 micron atmospheric window. A radiative transfer scheme is also used to correct the volcanic ash effect on the 8.7 micron SO2 signature. As test cases, three near‐contemporary images for each sensor, collected during the first days of the eruption, have been analyzed. The results show that the volcanic SO2 and ash are simultaneously present and generally collocated. The MODIS and AVHRR total ash mass loadings are in good agreement and estimated to be about 0.5 Tg, while the AIRS retrievals are slightly lower and equal to about 0.3 Tg. The AIRS and MODIS 7.3 micron SO2 mass loadings are also in good agreement and vary between 0.3 and 1.2 Tg, while the MODIS ash corrected 8.7 micron SO2 masses vary between 0.4 and 2.7 Tg. The mass increase with time confirms the continuous SO2 injection in the atmosphere after the main explosive episodes. Moreover the difference between the 7.3 and 8.7 micron retrievals suggests a vertical stratification of the volcanic cloud. The results also confirm the importance of the ash correction; the corrected 8.7 micron SO2 total masses are less than 30–40% of the uncorrected values.
    Description: Published
    Description: D00L21
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 1.10. TTC - Telerilevamento
    Description: JCR Journal
    Description: reserved
    Keywords: Remote sensing ; ash retrieval ; SO2 retrieval ; multispectral satellite instruments ; MODIS ; AVHRR ; AIRS ; hyperspectral satellite instruments ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 10
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    Chronology and complex volcanic processes during the 2002–2003 flank eruption at Stromboli volcano (Italy) reconstructed from direct observations and surveys with a handheld thermal camera (2005)
    AGU
    Details
    Publication Date: 2017-04-04
    Description: Effusive activity at Stromboli is uncommon, and the 2002–2003 flank eruption gave us the opportunity to observe and analyze a number of complex volcanic processes. In particular, the use of a handheld thermal camera during the eruption allowed us to monitor the volcano even in difficult weather and operating conditions. Regular helicopter-borne surveys with the thermal camera throughout the eruption have significantly improved (1) mapping of active lava flows; (2) detection of new cracks, landslide scars, and obstructions forming within and on the flanks of active craters; (3) observation of active lava flow field features, such as location of new vents, tube systems, tumuli, and hornitos; (4) identification of active vent migration along the Sciara del Fuoco; (5) monitoring of crater's inner morphology and maximum temperature, revealing magma level changes within the feeding conduit; and (6) detection of lava flow field endogenous growth. Additionally, a new system developed by A. J. L. Harris and others has been applied to our thermal data, allowing daily calculation of effusion rate. These observations give us new insights on the mechanisms controlling the volcanic system.
    Description: Published
    Description: 1-23
    Description: partially_open
    Keywords: volcano monitoring ; thermal mapping ; flank eruption ; Stromboli volcano ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 11
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    What makes flank eruptions? The 2001 Etna eruption and its possible triggering mechanisms (2008)
    Springer-Verlag
    Details
    Publication Date: 2017-04-04
    Description: Most flank eruptions within a central stratovolcano are triggered by lateral draining of magma from its central conduit, and only few eruptions appear to be independent of the central conduit. In order to better highlight the dynamics of flank eruptions in a central stratovolcano, we review the eruptive history of Etna over the last 100 years. In particular, we take into consideration the Mount Etna eruption in 2001, which showed both summit activity and a flank eruption interpreted to be independent from the summit system. The eruption started with the emplacement of a ~N-S trending peripheral dike, responsible for the extrusion of 75% of the total volume of the erupted products. The rest of the magma was extruded through the summit conduit system (SE crater), feeding two radial dikes. The distribution of the seismicity and structures related to the propagation of the peripheral dike and volumetric considerations on the erupted magmas exclude a shallow connection between the summit and the peripheral magmatic systems during the eruption. Even though the summit and the peripheral magmatic systems were independent at shallow depths (〈3 km b.s.l.), petro-chemical data suggest that a common magma rising from depth fed the two systems. This deep connection resulted in the extrusion of residual magma from the summit system and of new magma from the peripheral system. Gravitational stresses predominate at the surface, controlling the emplacement of the dikes radiating from the summit; conversely, regional tectonics, possibly related to N-S trending structures, remains the most likely factor to have controlled at depth the rise of magma feeding the peripheral eruption.
    Description: Published
    Description: 517-529
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Central volcanoes ; Summit and flank eruptions ; Dikes ; Tectonics ; Volcano load ; Mount Etna ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 12
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    Geochemical evidence of the renewal of volcanic activity: the 2007 Stromboli (Italy) eruption (2008)
    AGU
    Details
    Publication Date: 2017-04-04
    Description: Geochemical surveillance has been carried out at Stromboli since 1999 using discrete and continuous monitoring of thermal waters and soil degassing. On 27 February 2007 a new eruption began which lasted until 2 April; it was characterized by effusive activity on the Sciara del Fuoco and also by a paroxistic event (15 March). This crisis represented an opportunity to refine the model developed previously and to improve our understanding of the relationship between the magmatic dynamics of the volcano and geochemical variations. The main aim of this research was to evaluate the level of criticality of the volcanic activity. The SO2 fluxes of the degassing plume and the CO2 fluxes emitted from the soil at Pizzo Sopra la Fossa are herein presented. Furthermore, we propose a refined geochemical model of fluids circulation, including plume and summit fumarolic soil degassing. Noteworthy geochemical signals of volcanic unrest were also clearly identified (before, during and after the effusive activity) in the degassing plume as well as in the degassing from the soil at the summit.
    Description: Published
    Description: San Francisco, CA,USA
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: open
    Keywords: CO2 flux ; Stromboli volcano ; SO2 Flux ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 13
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    HELIUM ISOTOPES AND TECTONICS IN SOUTHERN ITALY (2009)
    AGU
    Details
    Publication Date: 2017-04-04
    Description: Geodynamic evolution of southern Italy can be understood within the framework of the Mediterranean- Alpine System. Subduction of a plate along the Sicily- Calabrian forearc under the Tyrrhenian Sea has been suggested by many geophysicists, although it is not yet confirmed and remains somewhat controversial. Helium isotope ratios provide useful information on the geotectonic structure of the region. We report here the 3He/4He ratios of terrestrial gas samples from southern Italy. The observed 3He/4He ratios are relatively high in the Eolian volcanic arc region and low in the other areas. Dichotomous explanations are presented. Firstly volcanic arc-forearc hypothesis suggests the subduction along the Sicily-Calabrian forearc. Secondly horizontal transport hypothesis is described based on the relationship between the ratios and radial distance from the recent spreading basin in Southern Tyrrhenian Sea.
    Description: Published
    Description: 511-514
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: helium isotopes ; tectonics ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 14
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    Geochemical monitoring of the 2002–2003 eruption at Stromboli volcano (Italy): precursory changes in the carbon and helium isotopic composition of fumarole gases and thermal waters (2006)
    Springer-Verlag
    Details
    Publication Date: 2017-04-04
    Description: Significant changes in the helium and carbon isotopic composition of shallow thermal waters vs. gas and a crater fumarolic gas have been recorded at Stromboli prior and during the 2002–2003 eruption. The 3He/4He ratios corrected for air contamination (Rc/Ra), and δ13C of fumarolic gases gradually increased from May to November 2002 before the eruption onset. These variations imply early degassing of a gas-rich magma at depth that likely fed both the intense Strombolian activity and small lava overflows recorded during that period. The lava effusion of late December 2002 was shortly preceded by a marked Rc/Ra decrease both in water and fumarolic gases. Comparison of He/CO2 and CH4/CO2 ratios in dissolved gas and with δ13CCO2 values rules out the Rc/Ra decrease due to an increasing input of radiogenic 4He. The Rc/Ra decrease is attributed to the He isotope fractionation during rapid magma ascent and degassing. A new uprising of 3He-rich magma probably occurred in January to February 2003, when Rc/Ra ratios displayed the highest values in dissolved gases ever measured before (4.56 Rc/Ra). The increase in He/CO2 and CH4/CO2 ratios and decrease in δ13C of dissolved CO2 was recorded after the 5 April 2003 explosive paroxysm, likely caused by enhanced gas-water interaction inducing CO2 dissolution. No anomalous Rc/Ra values were recorded in the same period, when usual Strombolian activity gradually resumed.
    Description: Published
    Description: 118–134
    Description: partially_open
    Keywords: Stromboli ; Eruption ; Geochemistry ; Helium ; Isotopes ; Magma ascent ; Dissolved gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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    Type: article
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  • 15
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    Crustal dynamics of Mount Vesuvius from 1998 to 2005: Effects on seismicity and fluid circulation (2008)
    AGU
    Details
    Publication Date: 2017-04-04
    Description: This paper presents the results of hydrogeochemical and seismological studies carried out at Mt. Vesuvius during the period June 1998 – December 2005. Hydrogeochemical data show the occurrence of slowly varying long-term variations in the total dissolved salts and bicarbonate contents of the groundwaters, accompanied by a general decline in water temperatures. The temporal distributions of air temperature and rainfall in the Vesuvius area suggest that these variations do not depend on changes in the hydrological regime. The changes in the geochemical parameters are accompanied by slight variations in both the seismicity rate and energy release. A further relationship between seismic activity and fluid discharge rate is highlighted by a particular episode that occurred in August 2005, when a soil thermal anomaly was observed a few weeks before the occurrence of a very shallow earthquake. Moment-tensor analysis of this earthquake suggests that the most plausible source mechanism is a shear faulting combined with the opening of tensile crack. This feature is often observed in volcanic areas and it is usually related to fluid-/gas-driven rock fracturing. The observed seismological, hydrological, and geochemical temporal changes are interpreted not as changes of the volcanic system, but in terms of an external forcing as identified in the variation of the regional and local stress field acting on the volcano. This study has inferences onto the evaluation of the state of activity of volcanic systems and the eventual detection of unrest phenomena.
    Description: Published
    Description: B05206
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Vesuvius ; seismicity ; fluid circulation ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
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  • 16
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    Mercury and halogen emissions from Masaya and Telica volcanoes, Nicaragua (2008)
    AGU
    Details
    Publication Date: 2017-04-04
    Description: We report measurements of Hg, SO2, and halogens (HCl, HBr, HI) in volcanic gases from Masaya volcano, Nicaragua, and gaseous SO2 and halogens from Telica volcano, Nicaragua. Mercury measurements were made with a Lumex 915+ portable mercury vapor analyzer and gold traps, while halogens, CO2 and S species were monitored with a portable multi gas sensor and filter packs. Lumex Hg concentrations in the plume were consistently above background and ranged up to 350 ng/m3. Hg/SO2 mass ratios measured with the real-time instruments ranged from 1.1*10-7 to 3.5*10-5 (mean 2*10-5). Total gaseous mercury TGM)concentrations measured by gold trap ranged from 100 to 225 ng/m3. Reactive gaseous mercury accounted for 1% of TGM, while particulate mercury was 5% of the TGM. Field measurements of Masaya’s SO2 flux, combined with the Hg/SO2 ratio, indicate a Hg flux from Masaya of 7.2 Mg/a-1. At Masaya’s low temperature fumaroles, Hg/CO2 mass ratios were consistently around 2*10-8, lower than observed in the main vent (Hg/CO2 10-7). Low-temperature fumarole Hg fluxes from Masaya are insignificant (150 g a-1). Ratios of S, C and halogen species were also measured at Masaya and Telica volcanoes. CO2/SO2 ratios at Masaya ranged from 2.8 to 3.9, comparable to previously published values. At Masaya molar Br/SO2 was 3*10-4 and I/SO2 was 2*10-5, suggesting fluxes of 0.2–0.5 Mg HBr d-1 and 0.02–0.05 Mg HI d-1. At Telica the Br/SO2 ratio was also 3*10-4 and the I/SO2 ratio was 5.8*10-5, with corresponding fluxes of 0.2 Mg HBr d-1 and 0.06 Mg HI d-1. Gases at both volcanoes are enriched in I relative to Br and Cl, compared to gases from volcanoes elsewhere.
    Description: This work was funded by NERC grant NE/ C511180/1/.
    Description: Published
    Description: B06203
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Mercury ; Halogen ; Volcanic emissions ; Masaya volcano ; Telica volcano ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 17
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    Dike propagation within active central volcanic edifices: constraints from Somma-Vesuvius, Etna and analogue models (2009)
    Springer-Verlag
    Details
    Publication Date: 2017-04-04
    Description: Dikes within stratovolcanoes are commonly expected to have radial patterns. However, other patterns may also be found, due to regional stresses, magmatic reservoirs and topographic variations. Here, we investigate dike patterns within volcanic edifices by studying dike and fissure complexes at Somma-Vesuvius and Etna (Italy) using analogue models. At the surface, the dikes and fissures show a radial configuration. At depths of tens to several hundreds of metres, in areas exposed by erosion, tangential and oblique dikes are also present. Analogue models indicate that dikes approaching the flanks of cones, regardless of their initial orientation, reorient to become radial (parallel to the maximum gravitational stress). This re-orientation is a significant process in shallow magma migration and may also control the emplacement of dikefed fissures reaching the lower slopes of the volcano.
    Description: This work was partly financed with DPC-INGV LAVA Project.
    Description: Published
    Description: 219-223
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Dike propagation ; Central volcanic edifices ; Stress ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
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  • 18
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    The summit hydrothermal system of Stromboli. New insights from self-potential, temperature, CO2 and fumarolic fluid measurements, with structural and monitoring implications (2005)
    Springer-Verlag
    Details
    Publication Date: 2017-04-04
    Description: Accurate and precisely located self-potential (SP), temperature (T) and CO2 measurements were carried out in the summit area of Stromboli along 72 straight profiles. SP data were acquired every metre and T data every 2.5 m. CO2 concentrations were acquired with the same density as T, but only along seven profiles. The high density of data and the diversity of the measured parameters allows us to study structures and phenomena at a scale rarely investigated. The shallow summit hydrothermal activity (Pizzoâ Fossa area) is indicated by large positive SP, T and CO2 anomalies. These anomalies are focused on crater faults, suggesting that the fracture zones are more permeable than surrounding rocks at Stromboli. The analysis of the distribution of these linear anomalies, coupled with the examination of the geologic, photographic and topographic data, has led us to propose a new structural interpretation of the summit of Stromboli. This newly defined structural framework comprises (1) a large Pizzo circular crater, about 350 m in diameter; (2) a complex of two concealed craters nested within the Pizzo crater (the Large and the Small Fossa craters), thought to have formed during the eruption of the Pizzo pyroclastites unit; the Small Fossa crater is filled with highly impermeable material that totally impedes the upward flow of hydrothermal fluids; and (3) The present complex of active craters. On the floor of the Fossa, short wavelength SP lows are organized in drainage-like networks diverging from the main thermal anomalies and converging toward the topographic low in the Fossa area, inside the Small Fossa crater. They are interpreted as the subsurface downhill flow of water condensed above the thermal anomalies. We suspect that water accumulates below the Small Fossa crater as a perched water body, representing a high threat of strong phreatic and phreatomagmatic paroxysms. T and CO2 anomalies are highly correlated. The two types of anomalies have very similar shapes, but the sensitivity of CO2 measurements seems higher for lowest hydrothermal flux. Above T anomalies, a pronounced high frequency SP signal is observed. Isotopic analyses of the fluids show similar compositions between the gases rising through the faults of the Pizzo and Large Fossa craters. This suggests a common origin for gases emerging along different structural paths within the summit of Stromboli. A site was found along the Large Fossa crater fault where high gas flux and low air contamination made gas monitoring possible near the active vents using the alkaline bottle sampling technique.
    Description: Published
    Description: 486â 504
    Description: partially_open
    Keywords: Carbon dioxide ; Hydrothermal system ; Soil gas ; Stromboli ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.03. Physical::03.03.02. General circulation ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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    Type: article
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  • 19
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    Seismological insight into the kinematics of the 5 April 2003 vulcanian explosion at Stromboli volcano (southern Italy) (2007)
    AGU
    Details
    Publication Date: 2017-04-04
    Description: On 5 April 2003 at 07:13 GMT (09:13 local time) a violent vulcanian explosion occurred at Stromboli volcano. At the time of the event an eruptive crisis was ongoing at the volcano with a lava flow outpouring along the Sciara del Fuoco flank. The seismic signals related to the event were recorded by 8 permanent broadband stations and gives information about the eruption kinematics. An ultra-longperiod signal (period 〉 20 s), that we interpret as the effect of the ground tilt on the broadband sensors, starts about 4 min before and terminates about 1 min after the explosion. On the basis of the radial pattern of tilt directions we conclude that this signal is the effect of the deformation of the volcanic edifice, due to the rapid rising of a batch of magma, its ejection and the magma column readjustment. About 1 min before the explosion we observe an high frequency signal (period 〈 0.1 s) that we believe to be related to the vesiculation of the rising batch of gas-rich magma. At 07:13:35 GMT a powerful very-long-period signal (period 2 20 s), marking the onset of the explosive fragmentation, is recorded. This is confirmed by a blast wave following few seconds later. The remaining seismic signal (more than 3 min), shows an higher frequency content being related only to the fall of ballistic ejecta and to landslides along Sciara del Fuoco.We propose the implementation of an early warning system for the short-term forecast of such explosions, based on the real-time automatic detection of the tilt signals preceding such events.
    Description: Published
    Description: L08308
    Description: reserved
    Keywords: NONE ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 20
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    Analysis of the 2001 lava flow eruption of Mt. Etna from three-dimensional mapping (2007)
    AGU
    Details
    Publication Date: 2017-04-04
    Description: The 2001 Etna eruption was characterized by a complex temporal evolution with the opening of seven eruptive fissures, each feeding different lava flows. This work describes a method adopted to obtain the three-dimensional geometry of the whole lava flow field and for the reconstruction, based on topographic data, of the temporal evolution of the largest lava flow emitted from a vent located at 2100 m a.s.l. Preeruption and posteruption Digital Elevation Models (DEM) were extracted from vector contour maps. Comparison of the two DEMs and analysis of posteruption orthophotos allowed us to estimate flow area, thickness, and bulk volume. Additionally, the two-dimensional temporal evolution of the 2100 flow was precisely reconstructed by means of maps compiled during the eruption. These data, together with estimates of flow thickness, allowed us to evaluate emitted lava volumes and in turn the average volumetric flow rates The analysis performed in this paper provided, a total lava bulk volume of 40.1 106 m3 for the whole lava flow field, most of which emitted from the 2100 vent (21.4 106 m3). The derived effusion rate trend shows an initial period of waxing flow followed by a longer period of waning flow. This is in agreement not only with the few available effusion rate measurements performed during the eruption, but also with the theoretical model of Wadge (1981) for the temporal variation in discharge during the tapping of a pressurized source
    Description: Published
    Description: F02029
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: Etna ; 2001 eruption ; three-dimensional mapping ; lava volume ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 21
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    The Most Ancient Maps of Erupting Mount Etna (2008)
    AGU
    Details
    Publication Date: 2017-04-04
    Description: Two previously unpublished maps were retrieved during historical research concerning the historical activity of Etna depicting the eruption which started in December 1634 and continued until 1636. The two drawings, one of which is in colour and the other in ink and sepia water colour, accompany two reports by Jesuits, who were eye-witnesses to the phenomenon. The description of the volcano and the ongoing lava flows was made independently by the two Jesuits, with the help of expert local guides. These two maps represent the first cartography of active Etna hitherto known of.
    Description: Published
    Description: 2-5
    Description: 3.10. Sismologia storica e archeosismologia
    Description: N/A or not JCR
    Description: open
    Keywords: historical volcanology ; Etna ; Ancient eruption Maps ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 22
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    Geochemical Evidence of Melt Intrusions Along Lithospheric Faults of the Southern Apennines (Italy): Geodynamic and Seismogenic Implications (2010)
    AGU
    Details
    Publication Date: 2017-04-04
    Description: Several gas emissions, distributed along 200 km of the Southern Apennine axial zone, have been investigated. This portion of the sedimentary chain, which constitutes the accretionary prism of the westward subduction of the Adriatic plate, is subjected to a tensile stress field responsible of high-magnitude earthquakes. The studied emissions are generally CO2-dominated, have 3He/4He ratios in the range of 0.09-2.84 Ra, and display both 3He and 4He outputs in the range of those reported for the Italian active volcanoes Phlegrean Fields and Vulcano. The helium isotope ratios, together with the amount of released gas, indicate that a huge amount of mantle-derived helium is released over all the investigated area. Our geochemical data and the geophysical peculiarities of the region, such as the high heat flow and the low resistivity of rocks below a depth of 15 km, coherently indicate the presence of melt intruded into the crust along lithospheric faults. Magma intrusions along the axial part of the Southern Apennine sedimentary chain are certainly unusual, since volcanism in Central and Southern Italy is concentrated along the perityrrhenian margin of the peninsula. We suggest that melt is promoted by adiabatic uprise of the asthenosphere in the mantle wedge beneath the Apennines and it is subsequently intruded along tensile lithospheric faults, strongly affecting the thermal state of the lower crust. An inter-relation between the geodynamics, the melt intrusions and the genesis of the large earthquakes (up to M = 7.1) in the region is suggested.
    Description: Published
    Description: 13569-13578
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: melt intrusions ; gas geochemistry ; tectonic structures ; seismicity ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 23
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    Wind as a main driver of the net ecosystem carbon balance of a semiarid Mediterranean steppe in the South East of Spain (2012)
    Blackwell Publishing Ltd
    Details
    Publication Date: 2017-04-04
    Description: Despite the advance in our understanding of the carbon exchange between terrestrial ecosystems and the atmosphere, semiarid ecosystems have been poorly investigated and little is known about their role in the global carbon balance. We used eddy covariance measurements to determine the exchange of CO2 between a semiarid steppe and the atmosphere over 3 years. The vegetation is a perennial grassland of Stipa tenacissima L. located in the SE of Spain. We examined diurnal, seasonal and interannual variations in the net ecosystem carbon balance (NECB) in relation to biophysical variables. Cumulative NECB was a net source of 65.7, 143.6 and 92.1 g C mˉ2 yrˉ1 for the 3 years studied, respectively. We separated the year into two distinctive periods: dry period and growing season. The ecosystem was a net source of CO2 to the atmosphere, particularly during the dry period when large CO2 positive fluxes of up to 15 μmol mˉ2 sˉ1 were observed in concomitance with large wind speeds. Over the growing season, the ecosystem was a slight sink or neutral with maximum rates of -2.3 μmol mˉ2 sˉ1. Rainfall events caused large fluxes of CO2 to the atmosphere and determined the length of the growing season. In this season, photosynthetic photon flux density controlled day-time NECB just below 1000 μmol mˉ2 sˉ1. The analyses of the diurnal and seasonal data and preliminary geological and gas-geochemical evaluations, including C isotopic analyses, suggest that the CO2 released was not only biogenic but most likely included a component of geothermal origin, presumably related to deep fluids occurring in the area. These results highlight the importance of considering geological carbon sources, as well as the need to carefully interpret the results of eddy covariance partitioning techniques when applied in geologically active areas potentially affected by CO2-rich geofluid circulation.
    Description: Published
    Description: 539–554
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: alpha grass ; carbon sequestration ; ecosystem respiration ; eddy covariance ; geogas ; geothermal activity ; grasslands ; net ecosystem carbon balance ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 24
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    Hydrogen in the gas plume of an open‐vent volcano, Mount Etna, Italy (2011)
    AGU
    Details
    Publication Date: 2017-04-04
    Description: We report here on the first hydrogen determinations in the volcanic gas plume of Mount Etna, in Italy, which we obtained during periodic field surveys on the volcano’s summit area with an upgraded MultiGAS. Using a specific (EZT3HYT) electrochemical sensor, we resolved H2 concentrations in the plume of 1–3 ppm above ambient (background) atmosphere and derived H2‐SO2 and H2‐H2O plume molar ratios of 0.002–0.044 (mean 0.013) and 0.0001–0.0042 (mean 0.0018), respectively. Taking the above H2‐SO2 ratios in combination with a time‐averaged SO2 flux of 1600 Gg yr−1, we evaluate that Etna contributes a time‐averaged H2 flux of ∼0.65 Gg yr−1, suggesting that the volcanogenic contribution to the global atmospheric H2 budget (70,000–100,000 Gg yr−1) is marginal. We also use our observed H2‐H2O ratios to propose that Etna’s passive plume composition is (at least partially) representative of a quenched (temperatures between 750°C and 950°C) equilibrium in the gas‐magma system, at redox conditions close to the nickel‐nickel oxide (NNO) mineral buffer. The positive dependence between H2‐SO2, H2‐H2O, and CO2‐SO2 ratios suggests that H2 is likely supplied (at least in part) by deeply rising CO2‐rich gas bubbles, fluxing through a CO2‐depleted shallow conduit magma.
    Description: Published
    Description: B10204
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: restricted
    Keywords: Hydrogen ; Mount Etna ; Open-vent volcano ; plume ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 25
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    Diffuse hydrothermal methane output and evidence of methanotrophic activity within the soils at Sousaki (Greece) (2011)
    Blackwell Publishing Ltd
    Details
    Publication Date: 2017-04-04
    Description: Methane soil flux measurements have been made in 38 sites at the geothermal system of Sousaki (Greece) with the closed chamber method. Fluxes range from –47.6 to 29,150 mg m-2 d-1 and the diffuse CH4 output of the system has been estimated at 19 t a-1. Contemporaneous CO2 flux measurements showed a moderate positive correlation between CO2 and CH4 fluxes. Comparison of the CO2/CH4 soil flux ratios with the CO2/CH4 ratio of the gases of the main gas manifestations provided evidence for methanotrophic activity within the soil. Laboratory CH4 consumption experiments confirmed the presence of methanotrophic microorganisms in soil samples collected at Sousaki. Consumption was generally in the range from –4.9 to –38.9 pmolCH4 h-1 g-1 but could sometimes reach extremely high values (–33,000 pmolCH4 h-1 g-1.). These results are consistent with recent studies on other geothermal systems that revealed the existence of thermoacidophilic bacteria exerting methanotrophic activity in hot, acid soils, thereby reducing methane emissions to the atmosphere.
    Description: Published
    Description: 97–107
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Sousaki ; accumulation chamber ; soil degassing ; hydrothermal systems ; methane output ; methanotrophic activity ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 26
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    Geofluids and natural gas in Romania, and the 10th International Conference on Gas Geochemistry (2010)
    Blackwell Publishing Ltd
    Details
    Publication Date: 2017-04-04
    Description: This thematic issue of Geofluids includes 11 papers representing the three main topics discussed in the 10th edition of the International Conference on Gas Geochemistry (ICGG-10): (i) gas in petroleum systems and seepage, (ii) gas in geothermal systems and volcanoes and (iii) gas, seismicity and geohazards. ICGG-10 was held in 2009 in Romania, a country extraordinarily rich in surface gas manifestations, that offers innumerable opportunities for innovative studies on gas geochemistry. We briefly describe the present knowledge on gases occurring both in petroliferous sedimentary basins and geothermal areas of Romania. The 11 contributions of this special issue, which include data from eight countries, are then summarised. Based on these papers and other works presented at the ICGG-10, we find that significant advances in analytical capabilities, data treating and interpretation have led to innovative insights into the origin, distribution and environmental impact of gases migrating to the Earth’s surface. It is increasingly clear, in particular, that gas geochemistry can be more effective for petroleum exploration, volcano-tectonic, geodynamic and environmental studies, if multiparametric studies are performed and the data are interpreted in the geological context.
    Description: Published
    Description: 457-462
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: geothermal gas ; international conference on gas geochemistry ; natural gas ; romania ; seeps ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 27
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    Do tree species affect decadal changes in soil organic carbon and total nitrogen stocks in Danish common garden experiments? (2021)
    Blackwell Publishing Ltd | Oxford, UK
    Details
    Publication Date: 2022-04-01
    Description: Temperate forest soils are often considered as an important sink for atmospheric carbon (C), thereby buffering anthropogenic CO2 emissions. However, the effect of tree species composition on the magnitude of this sink is unclear. We resampled a tree species common garden experiment (six sites) a decade after initial sampling to evaluate whether forest floor (FF) and topsoil organic carbon (Corg) and total nitrogen (Nt) stocks changed in dependence of tree species (Norway spruce—Picea abies L., European beech—Fagus sylvatica L., pedunculate oak—Quercus robur L., sycamore maple—Acer pseudoplatanus L., European ash—Fraxinus excelsior L. and small‐leaved lime—Tilia cordata L.). Two groups of species were identified in terms of Corg and Nt distribution: (1) Spruce with high Corg and Nt stocks in the FF developed as a mor humus layer which tended to have smaller Corg and Nt stocks and a wider Corg:Nt ratio in the mineral topsoil, and (2) the broadleaved species, of which ash and maple distinguished most clearly from spruce by very low Corg and Nt stocks in the FF developed as mull humus layer, had greater Corg and Nt stocks, and narrow Corg:Nt ratios in the mineral topsoil. Over 11 years, FF Corg and Nt stocks increased most under spruce, while small decreases in bulk mineral soil (esp. in 0–15 cm and 0–30 cm depth) Corg and Nt stocks dominated irrespective of species. Observed decadal changes were associated with site‐related and tree species‐mediated soil properties in a way that hinted towards short‐term accumulation and mineralisation dynamics of easily available organic substances. We found no indication for Corg stabilisation. However, results indicated increasing Nt stabilisation with increasing biomass of burrowing earthworms, which were highest under ash, lime and maple and lowest under spruce. Highlights We studied if tree species differences in topsoil Corg and Nt stocks substantiate after a decade. The study is unique in its repeated soil sampling in a multisite common garden experiment. Forest floors increased under spruce, but topsoil stocks decreased irrespective of species. Changes were of short‐term nature. Nitrogen was most stable under arbuscular mycorrhizal species.
    Description: Deutsche Forschungsgemeinschaff (DFG)
    Keywords: ddc:551.9 ; ddc:631.41
    Language: English
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    Slope Failures Induced by the December 2002 Eruption at Stromboli Volcano (2008)
    AGU
    Details
    Publication Date: 2019-10-15
    Description: We reconstruct the sequence of landslides that occurred soon after the beginning of the December 2002 eruption on the NW flank of Stromboli volcano. Landslides involved the northeastern part of the Sciara del Fuoco (SdF) slope, an old collapse scar filled by products of volcanic activity, producing tsunami waves that severely damaged the coast of the island of Stromboli. Volumes of the mass detached from the subaerial and submarine slope were quantified by comparing preslide and postslide slope surfaces obtained by aerophotogrammetric and bathymetric data, which also allowed, in conjunction with field observations and helicopter surveys, the reconstruction of geometry and kinematics of landslides. According to the reconstructed sequence, 2 d after the beginning of the eruption, the upper part of the NE sector of the SdF slope experienced major displacements (few tens of meters). Movements propagated downslope and affected the nearshore portion of the submerged slope without a rapid sliding of the displaced mass into the sea. The following hours were characterized by a progressive increase of deformations, localized along shear zones extending over two thirds of the subaerial slope. This phase proceeded until a submarine slide about 6 ´ 106 m3 in volume occurred, causing a first tsunami wave. The subaerial mass delimited by the shear zones and unbuttressed at its foot, then slipped into the sea producing a second tsunami wave. The main landslide event (and the minor slumps which followed) removed a volume of about 10 ´ 106 m3 of the infilling deposit, to a thickness of at least 65 m. Hypotheses were formulated on the mechanisms that controlled the different phases of the instability sequence. Since hydraulic and stress/strain conditions progressively changed during the slope evolution, the formulated mechanisms are also based on geotechnical analyses and considerations on the mechanical behavior of volcaniclastic materials. The process that led to the landslide events was initiated by forces exerted by magma intruded into the slope, while further steps of the evolution of slope stability conditions (especially the submarine failure) were controlled by the particular shear behavior of the volcaniclastic material, mainly influenced by grain crushability. In fact, strength progressively decreased as shear strains proceeded, and the intensely sheared saturated material forming the submarine slope may have become susceptible of failure when sudden strain/ stress increments occurred.
    Description: Published
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: reserved
    Keywords: Slope Failures Induced by Eruption ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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    Origin and flux of a gas seep in the Northern Alps (Giswil, Switzerland) (2010)
    Blackwell Publishing Ltd
    Details
    Publication Date: 2017-04-04
    Description: Natural gas seeps in the Alpine region are poorly investigated. However, they can provide useful information regarding the hydrocarbon potential of sedimentary Alpine units and related geofluid migration, typically controlled by pressurized gas accumulations and tectonics. A gas seep located near Giswil, in the Swiss Northern Alps, was investigated, for the first time, for molecular and isotopic gas composition, methane flux to the atmosphere, and gas flux variations over time. The analyses indicated that the gas was thermogenic (CH4 〉 96%; d13C1: )35.5& to )40.2&) and showed evidence of subsurface petroleum biodegradation (13C-enriched CO2, and very low C3+ concentrations). The source rock in the region is marine Type II kerogen, which is likely the same as that providing thermogenic gas in the nearby Wilen shallow well, close to Lake Sarnen. However, the lack of d13CCO2 and d13C3 data for that well prevented us from determining whether the Wilen and Giswil seeps are fed by the same reservoir and seepage system. Gas fluxes from the Giswil seep, measured using a closedchamber system, were significant and mainly from two major vents. However, a substantial gas exhalation from the soil occurs diffusely in an area of at least 115 m2, leading to a total CH4 output conservatively estimated to be at least 16 tonnes per year. Gas flux variations, monitored over a 1-month period by a special tent and flowmeter, showed not only daily meteorological oscillations, but also an intrinsic ‘pulsation’ with periods of enhanced flux that lasted 2–6 h each, occurring every few days. The pulses are likely related to episodes of gas pressure build-up and discharge along the seepage system. However, to date, no relationship to seismicity in the active Sarnen strike-slip fault system has been established.
    Description: Published
    Description: 476-485
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Alps ; isotopes ; methane ; organic geochemistry ; seeps ; Switzerland ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 30
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    CO2-driven large mafic explosive eruptions: the Pozzolane Rosse case study from the Colli Albani Volcanic District (Italy) (2010)
    Springer-Verlag
    Details
    Publication Date: 2017-04-04
    Description: Generally, the intensity and magnitude of explosive volcanic activity increase in parallel with SiO2 content. Pyroclastic-flow-forming eruptions in the Colli Albani ultrapotassic volcanic district (Italy) represent the most striking exception on a global scale, with volumes on the order of tens of cubic kilometres and K-foiditic compositions (SiO2 even 〈42 wt.%). Here, we reconstruct the preeruptive scenario and event dynamics of the ~456 ka Pozzolane Rosse (PR) eruption, the largest mafic explosive event of the Colli Albani district. In particular, we focus on the driving mechanisms for the unusually explosive eruption of a low-viscosity, mafic magma. Geologic, petrographic and geochemical data with mass balance calculations, supported by experimental data for Colli Albani magma compositions, provide evidence for significant ingestion of carbonate wall rocks by the Pozzolane Rosse K-foiditic magma. Moreover, the scattered occurrence of cored bombs in Pozzolane Rosse pyroclastic-flow deposits records carbonate entrainment even at the eruptive time scale, as also tested quantitatively by thermal modelling of magma–carbonate interaction and carbonate assimilation experiments. We suggest that the addition of free CO2 from decarbonation of country rocks was the major factor controlling magma explosivity. High CO2 activity in the volatile component, coupled with magma depressurisation, produced extensive leucite crystallisation at short time scales, resulting in a dramatic increase in magma viscosity and volatile pressurisation, which was manifested a change of eruptive dynamics from early effusion to the Pozzolane Rosse's highly explosive eruption climax.
    Description: INGV
    Description: In press
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: restricted
    Keywords: Mafic explosive eruptions ; Eruption magnitude ; Pyroclastic flow ; Colli Albani ; Potassic volcanism ; Carbonate assimilation ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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    Inspecting the Reliability of Geochemical Facies Identified for the Waterworks' Capture Zone in Germany (2022)
    Blackwell Publishing Ltd | Malden, US
    Details
    Publication Date: 2022-09-27
    Description: Little research attention has been given to validating clusters obtained from the groundwater geochemistry of the waterworks' capture zone with a prevailing lake‐groundwater exchange. To address this knowledge gap, we proposed a new scheme whereby Gaussian finite mixture modeling (GFMM) and Spike‐and‐Slab Bayesian (SSB) algorithms were utilized to cluster the groundwater geochemistry while quantifying the probability of the resulting cluster membership against each other. We applied GFMM and SSB to 13 geochemical parameters collected during different sampling periods at 13 observation points across the Barnim Highlands plateau located in the northeast of Berlin, Germany; this included 10 observation wells, two lakes, and a gallery of drinking production wells. The cluster analysis of GFMM yielded nine clusters, either with a probability ≥0.8, while the SSB produced three hierarchical clusters with a probability of cluster membership varying from 〈0.2 to 〉0.8. The findings demonstrated that the clustering results of GFMM were in good agreement with the classification as per the principal component analysis and Piper diagram. By superimposing the parameter clustering onto the observation clustering, we could identify discrepancies that exist among the parameters of a certain cluster. This enables the identification of different factors that may control the geochemistry of a certain cluster, although parameters of that cluster share a strong similarity. The GFMM results have shown that from 2002, there has been active groundwater inflow from the lakes towards the capture zone. This means that it is necessary to adopt appropriate measures to reverse the inflow towards the lakes.
    Description: Article impact statement: The probability of cluster membership quantified using an algorithm should be validated against another probabilistic‐based classifier.
    Description: Federal Ministry of Education and Research http://dx.doi.org/10.13039/501100002347
    Keywords: ddc:551.9 ; ddc:551.49
    Language: English
    Type: doc-type:article
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