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  • Inorganic Chemistry  (8,804)
  • Aircraft Design, Testing and Performance
  • 2020-2022  (5)
  • 1955-1959  (3,151)
  • 1950-1954  (1,695)
  • 1925-1929
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  • 1
    Publication Date: 2020-01-18
    Description: This paper presents a jig twist optimization study of Mach 0.745 Transonic Truss-Braced Wing (TTBW) aircraft using an in-house developed aero-structural analysis solver VSPAERO coupled to BEAM3D. A vortex-lattice model of the TTBW model is developed, and a transonic and viscous flow correction method is implemented in the VSPAERO model to account for transonic and viscous flow effects. A correction method for the wing-strut interference aerodynamics is developed and applied to the VSPAERO solver. Also, a structural dynamic finite-element model of the TTBW aircraft is developed. This finite-element model includes the geometric nonlinear effect due to the tension in the struts which causes a deflection-dependent nonlinear stiffness. The VSPAERO model is coupled to the corresponding finite-element model to provide a rapid aero-structural analysis. A design flight condition corresponding to Mach 0.745 at 42000 ft is selected for the TTBW aircraft jig twist optimization to reduce the drag coefficient. After the design is implemented, the drag coefficient of the twist optimized TTBW aircraft is reduced about 8 counts. At the end, a high-fidelity CFD solver FUN3D is used to validate the design.
    Keywords: Aircraft Design, Testing and Performance
    Type: AIAA 2020-0451 , ARC-E-DAA-TN76389 , AIAA Scitech 2020 Forum; Jan 06, 2020 - Jan 10, 2020; Orlando, FL; United States
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  • 2
    Publication Date: 2020-01-16
    Description: Urban Air Mobility (UAM) describes a new type of aviation focused on efficient flight within urban areas for moving people and goods. There are many different configurations of UAM vehicles, but they generally use an electric motor driving a propeller or ducted fan powered by batteries or a hybrid electric power generation system. Transmission cables are used to move energy from the storage or generation system to the electric motors. Though terrestrial power transmission cables are well established technology, aviation applications bring a whole host of new design challenges that are not typical considerations in terrestrial applications. Aircraft power transmission cable designs must compromise between resistance-per-length, weight-per-length, volume constraints, and other essential qualities. In this paper we use a multidisciplinary design optimization to explore the sensitivity of these qualities to a representative tiltwing turboelectric UAM aircraft concept. This is performed by coupling propulsion and thermal models for a given mission criteria. Results presented indicate that decreasing cable weight at the expense of increasing cable volume or cooling demand is effective at minimizing maximum takeoff weight (MTO). These findings indicate that subsystem designers should update their modeling approach in order to contribute to system-level optimality for highly-coupled novel aircraft. Mobility (UAM) vehicles have the potential to change urban and intra-urban transport in new and interesting ways. In a series of two papers Johnson et al.1 and Silva et al.2 presented four reference vehicle configurations that could service different niches in the UAM aviation category. Of those, this paper focuses on the Vertical Take-off and Landing (VTOL) tiltwing configuration shown in Figure 1. This configuration uses a turboelectric power system, feeding power from a turbo-generator through a system of transmission cables to four motors spinning large propellers on the wings. Previous work on electric cable subsystems leaves much yet to be explored, especially in the realm of subsystem coupling. Several aircraft optimization studies1, 3, 4 only considered aircraft electrical cable weight and ignored thermal effects. Electric and hybrid-electric aircraft studies by Mueller et al.5 and Hoelzen et al.6 selected a cable material but did not investigate alternative materials. Advanced cable materials have been examined by a number of authors: Alvarenga7 examined carbon nanotube (CNT) conductors for low-power applications. De Groh8, 9 examined CNT conductors for motor winding applications. Behabtu et al.,10 and Zhao et al.11 examined CNT conductors for a general applications. There were some studies that examined the thermal effects of cables but they did not allow the cable material to change; El-Kady12 optimized ground-cable insulation and cooling subject constraints. Vratny13 selected cable material based on vehicle power demand, and required resulting cable heat to be dissipated by the Thermal Management System (TMS). None of these previous studies allowed for the selection of the cable material based on a system level optimization goal. Instead, they focused on sub-system optimality such as minimum weight, which comes at the expense of incurring additional costs for other subsystems. Dama14 selected overhead transmission line materials using a weighting function and thermal constraints. However, that work was not coupled with any aircraft subsystems like a TMS. The traditional aircraft design approach, which relies on assembling groups of optimal subsystems, breaks down when considering novel aircraft concepts like the tiltwing vehicle. In a large part, this is because novel concepts have a much higher degree of interaction or coupling between subsystems. For example, when a cable creates heat, this heat needs to be dissipated by the TMS, which needs power supplied by the turbine, and delivering the power creates more heat. The cable, the TMS, and the turbine are all coupled. A change to one subsystem will affect all the other subsystems, much to the consternation of subsystem design experts. Multidisciplinary optimization is the design approach that can address these challenges. However, to fully take advantage of this, we must change the way we think about subsystem design. Specifically, we must move away from point design, and focus on creating solution spaces. The work presented in this paper uses the multidisciplinary optimization approach with aircraft level models to study the system-level sensitivity of cable traits: weight-per-length and resistance-per-length. Additionally, we examined the effects of vehicle imposed volume constraints on these traits. This is useful for three purposes: (1) to demonstrate a framework that can perform a coupled analysis between the aircraft thermal and propulsion systems, (2) to provide a method by which future cable designs can be evaluated against each other given a system-level design goal, (3) to provide insight into what cable properties may be promising for future research. This last element is explored given the caveat that the models contained in this analysis do not represent high-fidelity systems. Thus, while we can demonstrate coupling in between systems, the exact system-level sensitivity to a given parameter may change if a subsystem model or the assumptions governing that model change. The organization of this paper is as follows, in Sec II we outline a method to combine the VTOL vehicle design and cable information in order to produce cables sensitivity studies. Results analysis and discussion are contained in Sec III. Conclusions are presented in Sec IV.
    Keywords: Aircraft Design, Testing and Performance
    Type: GRC-E-DAA-TN75458 , SciTech2020; Jan 06, 2020 - Jan 10, 2020; Orlando, FL; United States
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  • 3
    Publication Date: 2020-01-24
    Description: This paper determined the feasibility of an adaptive hexapod simulator motion algorithm based on aircraft roll stability. An experiment was conducted that used a transport aircraft model in the Vertical Motion Simulator at NASA Ames Research Center. Eighteen general aviation pilots flew a heading-capture task and a stall task consecutively under four motion configurations: baseline hexapod, adaptive hexapod, optimized hexapod, and full motion. The adaptive motion was more similar to the baseline hexapod motion in the heading-capture task when the aircraft was more stable, and more similar to the optimized hexapod motion in the stall task when the aircraft was more unstable. Pilot motion ratings and task performance in the heading-capture task under the adaptive hexapod motion were more similar to baseline hexapod motion compared to optimized hexapod motion. However, motion ratings and task performance in the stall task under the adaptive motion were not significantly more similar to the optimized hexapod motion compared to baseline hexapod motion. Motion ratings and overall task performance under optimized hexapod motion as opposed to baseline hexapod motion were always more similar to the full motion condition. This paper showed that adaptive motion based on aircraft stability is feasible and can be implemented in a straightforward way. More research is required to test the adaptive motion algorithm in different tasks.
    Keywords: Aircraft Design, Testing and Performance
    Type: AIAA 2020-2268 , ARC-E-DAA-TN76664 , AIAA Scitech 2020 Forum; Jan 06, 2020 - Jan 10, 2020; Orlando, FL; United States
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  • 4
    Publication Date: 2020-01-23
    Description: This paper discusses a wind tunnel experiment of active gust load alleviation of a flexible wing which took place at University of Washington (UW) in 2019. The experiment performed under a NASA SBIR contract with Scientific Systems Company, Inc (SSCI). The objective of the experiment is to demonstrate active controls of the Variable Camber Continuous Trailing Edge Flap (VCCTEF) system for gust load alleviation and real-time drag optimization. The wind tunnel model is a 8.2% sub-scale Common Research Model (CRM) wing. The wing structure is designed to provide a substantial degree of flexibility to represent that of a modern high-aspect ratio wing. Eight active control surfaces are employed in the VCCTEF. A new gust generator system was designed and installed by UW under a sub-contract with SSCI. The first test entry started in July 2019 and ended in September 2019. During this test entry, many significant issues were found with the hardware and software. The significant issues with the servos prevented the test objective from being completed. A follow-up second test entry in 2020 is being planned. The wing system is being repaired by SSCI. This paper reports on the progress of this experimental effort and the aeroservoelastic (ASE) model validation which was conducted during the test entry.
    Keywords: Aircraft Design, Testing and Performance
    Type: AIAA 2020-0214 , ARC-E-DAA-TN76417 , AIAA Scitech 2020 Forum; Jan 06, 2020 - Jan 10, 2020; Orlando, FL; United States
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  • 5
    Publication Date: 2020-01-22
    Description: No abstract available
    Keywords: Aircraft Design, Testing and Performance
    Type: AFRC-E-DAA-TN76690 , SciTech Forum; Jan 06, 2020 - Jan 10, 2020; Orlando, FL; United States
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  • 6
    Publication Date: 2019-05-11
    Description: A flight investigation was made of the lift and drag of a sweptwing fighter airplane in the basic configuration and in a slats-locked-closed configuration over a Mach number range from about 0.63 to about 1.44. At a nominal lift coefficient of 0.1 negligible drag-coefficient difference existed between the two configurations over a comparable Mach number and altitude range. For the basic configuration at zero lift the supersonic drag level was about three times as great as the subsonic drag level, which was about 0.01, whereas the drag-due-to-lift factor increased about 137 percent over the test Mach number range. At comparable Mach numbers the high-altitude data produced a larger lift-curve slope and showed a more pronounced variation of lift-curve slope in the transonic region than did the low-altitude data. For the high-altitude data the lift-curve slope at a Mach number of 1.44 was approximately 62 percent of the value at a Mach number of 0.9.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-10-1-58H , AFRC-E-DAA-TN47945
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  • 7
    Publication Date: 2019-06-28
    Description: No abstract available
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-TN-D-89
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  • 8
    Publication Date: 2019-07-13
    Description: Turbojet engine reliability has long been an intense interest to the military users of this type of aircraft propulsion. With the recent inauguration of commercial jet transport this subject has assumed a new dimension of importance. In January l96 the Lewis Research Center of the NASA (then the MACA) published the results of an extensive study on the factors that affect the opera- center dot tional reliability of turbojet engines (ref. 1). At that time the report was classified Confidential. In July l98 this report was declassified. It is thus appropriate at this time to present some of the highlights of the studies described in the NASA report. In no way is it intended to outline the complete contents of the report; rather it is hoped to direct attention to it among those who are center dot directly concerned with this problem. Since the publication of our study over three years ago, the NASA has completed a number of additional investigations that bear significantly on this center dot subject. A second object of this paper, therefore, is to summarize the results of these recent studies and to interpret their significance in relation to turbojet operational reliability.
    Keywords: Aircraft Design, Testing and Performance
    Type: SAE National Aeronautic Meeting; Mar 31, 1959 - Apr 03, 1959; New York, NY; United States
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  • 9
    Publication Date: 2019-08-17
    Description: An investigation of the low-subsonic stability and control characteristics of a model of a flat-bottom hypersonic boost-glide configuration having 78 deg sweep of the leading edge has been made in the Langley full-scale tunnel. The model was flown over an angle-of-attack range from 10 to 35 deg. Static and dynamic force tests were made in the Langley free-flight tunnel. The investigation showed that the longitudinal stability and control characteristics were generally satisfactory with neutral or positive static longitudinal stability. The addition of artificial pitch damping resulted in satisfactory longitudinal characteristics being obtained with large amounts of static instability. The most rearward center-of-gravity position for which sustained flights could be made either with or without pitch damper corresponded to the calculated maneuver point. The lateral stability and control characteristics were satisfactory up to about 15 deg angle of attack. The damping of the Dutch roll oscillation decreased with increasing angle of attack; the oscillation was about neutrally stable at 20 deg angle of attack and unstable at angles of attack of about 25 deg and above. Artificial damping in roll greatly improved the lateral characteristics and resulted in flights being made up to 35 deg angle of attack.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-TM-X-201 , L-452
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  • 10
    Publication Date: 2019-08-17
    Description: Acceleration, airspeed, and altitude data obtained with an NACA VGH recorder from a four-engine commercial transport airplane operating over a northwestern United States-Alaska route were evaluated to determine the magnitude and frequency of occurrence of gust and maneuver accelerations., operating airspeeds, and gust velocities. The results obtained were then compared with the results previously reported in NACA Technical Note 3475 for two similar airplanes operating over transcontinental routes in the United States. No large variations in the gust experience for the three operations were noted. The results indicate that the gust-load experience of the present operation closely approximated that of the central transcontinental route in the United States with which it is compared and showed differences of about 4 to 1 when compared with that of the southern transcontinental route in the United States. In general, accelerations due to gusts occurred much more frequently than those due to operational maneuvers. At a measured normal-acceleration increment of 0.5g, accelerations due to gusts occurred roughly 35 times more frequently than those due to operational maneuvers.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-1-17-59L
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  • 11
    Publication Date: 2019-08-17
    Description: An analysis is made of wing deflection and streamwise twist measurements in rough-air flight of a large flexible swept-wing bomber. Random-process techniques are employed in analyzing the data in order to describe the magnitude and characteristics of the wing deflection and twist responses to rough air. Power spectra and frequency-response functions for the wing deflection and twist responses at several spanwise stations are presented. The frequency-response functions describe direct and absolute response characteristics to turbulence and provide a convenient basis for assessing analytic calculation techniques. The wing deformations in rough air are compared with the expected deformations for quasi-static loadings of the same magnitude, and the amplifications are determined. The results obtained indicate that generally the deflections are amplified by a small amount, while the streamwise twists are amplified by factors of the order of 2.0. The magnitudes of both the deflection velocities and the twist angles are shown to have significant effects on the local angles of attack at the various stations and provide the main source of aerodynamic loading, particularly at frequencies in the vicinity of the first wing-vibration mode.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-12-3-58L
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  • 12
    Publication Date: 2019-08-17
    Description: Analysis of the vortex model proposed by Kriebel, Seidel, and Schwind shows this representation of rotating stall satisfies, at least approximately, the requirements at the cascade. Cascade-parameter-variation effects on rotating stall were studied in a circular cascade and single-stage compressor. Modification of the single-stage compressor stopped the rotating-stall pattern and permitted observation of the pressure and velocity distribution around the annulus. Closer observation might be possible with proper flow-visualization techniques, such as a water pump.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-3-16-59W
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  • 13
    Publication Date: 2019-08-17
    Description: In an attempt to find an aerodynamic means of counteracting the transonic trim change of a fighter airplane, lower surface spoilers were tested on a 0.055-scale wind-tunnel model. The Mach number range of the tests was 0.8 to 1.2 at Reynolds numbers of approximately 4 million. Although the spoilers produced a moderate decrease in the trim change at low altitudes, they also produced a large increase in drag. Pressure-distribution tests with external fuel tanks showed large pressure changes on the lower surface of the wing due to the tanks.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-12-27-58A
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  • 14
    Publication Date: 2019-08-17
    Description: The Levy method which deals with an idealized structure was used to obtain the natural modes and frequencies of a large-scale built-up 45 deg. delta wing. The results from this approach, both with and without the effects of transverse shear, were compared with the results obtained experimentally and also with those calculated by the Stein-Sanders method. From these comparisons it was concluded that the method as proposed by Levy gives excellent results for thin-skin delta wings, provided that corrections are made for the effect of transverse shear.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-2-2-59L , L-153
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  • 15
    Publication Date: 2019-08-17
    Description: A cambered and twisted triangular wing of aspect ratio 2 in combination with a cambered body was investigated experimentally to determine the effectiveness of the camber in reducing the drag due to lift at trim at supersonic speeds. Four arrangements were tested comprising all combinations of a symmetrical and a cambered wing with a symmetrical and a cambered body. The camber shape investigated was derived by linearized lifting surface theory for triangular wings with sonic leading edges and satisfied the requirement that the wing be trimmed at the design Mach number and lift coefficient. The experimental results for the cambered wing and cambered body showed that the drag coefficient at trim was always greater, at the same lift coefficient, than that for the untrimmed symmetrical wing and body. The trim lift coefficient was positive and decreased with increasing Mach number. At the design Mach number of 2.24, the trim lift coefficient was somewhat lower and the drag coefficient was higher than values predicted by linearized lifting surface theory for the wing alone. A comparison of the trim lift-drag ratio of the cambered wing and cambered body with values obtained by trimming the symmetrical wing and symmetrical body either with a canard or a trailing-edge flap showed that, at approximately the design Mach number the cambered configuration developed a somewhat higher value than the trailing-edge flap configuration but a lower value than the canard configuration.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-2-3-59A
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  • 16
    Publication Date: 2019-08-17
    Description: The maximum Mach number and altitude capabilities of the Bell X-2 research airplane were achieved during a program conducted by the U.S. Air Force with Bell Aircraft Corp. providing operational support and the National Aeronautics and Space Administration providing instrumentation and advisory engineering assistance. A maximum geometric altitude of 126,200 feet was attained at a static pressure of 9.4 pounds per square foot and a dynamic pressure of 19.1 pounds per square foot. During the last flight of the airplane, a maximum Mach number of 3.20 was reached. The directionally divergent maneuver which terminated the final high Mach number flight was precipitated by the loss in directional stability that resulted from increasing the angle of attack. The yawing moment from the lateral control was sufficient to initiate the divergence and also to cause,, indirectly, rolling moments that were greater than the aileron capabilities of the airplane. The ensuing violent motions-resulting from inertial roll coupling caused the loss of the aircraft.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-TM-X-137
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  • 17
    Publication Date: 2019-08-16
    Description: The first flight of the North American X-15 research airplane was made on June 8, 1959. This was accomplished after completion of a series of captive flights with the X-15 attached to the B-52 carrier airplane to demonstrate the aerodynamic and systems compatibility of the X-15//B-52 combination and the X-15 subsystem operation. This flight was planned as a glide flight so that the pilot need not be concerned with the propulsion system. Discussions of the launch, low-speed maneuvering, and landing characteristics are presented, and the results are compared with predictions from preflight studies. The launch characteristics were generally satisfactory, and the X-15 vertical tail adequately cleared the B-52 wing cutout. The actual landing pattern and landing characteristics compared favorably with predictions, and the recommended landing technique of lowering the flaps and landing gear at a low altitude appears to be a satisfactory method of landing the X-15 airplane. There was a quantitative correlation between flight-measured and predicted lift-drag-ratio characteristics in the clean configuration and a qualitative correlation in the landing configuration. A longitudinal-controllability problem, which became severe in the landing configuration, was evident throughout the flight and, apparently, was aggravated by the sensitivity of the side-located control stick. In the low-to-moderate angle-of-attack range covered, the longitudinal and directional stability were indicated to be adequate.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-TM-X-195
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  • 18
    Publication Date: 2019-08-16
    Description: A study has been made of the subsonic pressure distributions and loadings for a 45 deg sweptback-wing and body combination at angles of attack up to 36 deg. The wing had an aspect ratio of 5.5, a taper ratio of 0.53, and NACA 64A010 sections normal to the quarter-chord line and was mounted on a slender body of fineness ratio 12.5. Test results are presented for Mach numbers of 0.30 and 0.50 with corresponding Reynolds numbers of 1.5 and 2.0 million, respectively. The stall patterns and spanwise loadings at high angles of attack for the present model are correlated with those for other 45 deg sweptback wing and body combinations having aspect ratios between 4.0 and 8.0. A tentative approach is presented for extrapolating the Weissinger span-loading method to higher angles of attack, and for deriving the spanwise-load distributions for 45 deg sweptback wings at angles of attack above 20 deg. The investigation also included tests of the body in combination with only one panel of the swept wing. The problem of estimating the normal-force coefficient for the single panel at high angles of attack is considered.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-1-18-59A
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  • 19
    Publication Date: 2019-08-16
    Description: Results of a cyclic load test made by NASA on an EB-47E airplane are given. The test reported on is for one of three B-47 airplanes in a test program set up by the U. S. Air Force to evaluate the effect of wing structural reinforcements on fatigue life. As a result of crack development in the upper fuselage longerons of the other two airplanes in the program, a longeron and fuselage skin modification was incorporated early in the test. Fuselage strain-gage measurements made before and after the longeron modification and wing strain-gage measurements made only after wing reinforcement are summarized. The history of crack development and repair is given in detail. Testing was terminated one sequence short of the planned end of the program with the occurrence of a major crack in the lower right wing skin.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-3-15-59L , AF-AM-171
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  • 20
    Publication Date: 2019-08-16
    Description: Flight tests were made to determine the capability of positioning a gliding airplane for a landing on a 5,000-foot runway with special reference to the gliding flight of a satellite vehicle of fixed configuration upon reentry into the earth's atmosphere. The lift-drag ratio and speed of the airplane in the glides were varied through as large a range as possible. The results showed a marked tendency to undershoot the runway when the lift-drag ratios were below certain values, depending upon the speed in the glide. A straight line dividing the successful approaches from the undershoots could be drawn through a lift-drag ratio of about 3 at 100 knots and through a lift-drag ratio of about 7 at 185 knots. Provision of a drag device would be very beneficial, particularly in reducing the tendency toward undershooting at the higher speeds.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-3-12-59L , L-406
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  • 21
    Publication Date: 2019-08-16
    Description: Several approximate procedures for calculating the bending-moment response of flexible airplanes to continuous isotropic turbulence are presented and evaluated. The modal methods (the mode-displacement and force-summation methods) and a matrix method (segmented-wing method) are considered. These approximate procedures are applied to a simplified airplane for which an exact solution to the equation of motion can be obtained. The simplified airplane consists of a uniform beam with a concentrated fuselage mass at the center. Airplane motions are limited to vertical rigid-body translation and symmetrical wing bending deflections. Output power spectra of wing bending moments based on the exact transfer-function solutions are used as a basis for the evaluation of the approximate methods. It is shown that the force-summation and the matrix methods give satisfactory accuracy and that the mode-displacement method gives unsatisfactory accuracy.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-2-18-59L , L-143
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  • 22
    Publication Date: 2019-08-15
    Description: The Bell D-188A VTOL airplane is a horizontal-attitude VTOL fighter with tilting engine nacelles at the tips of a low-aspect-ratio unswept wing and additional engines in the fuselage. The model could be flown smoothly in hovering and transition flight. In forward flight the model could be flown smoothly at the lower angles of attack but experienced an uncontrollable directional divergence at angles of attack above about 16 deg.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-3-16-59L , TED-AD-3147 , L-241
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  • 23
    Publication Date: 2019-08-15
    Description: Flapwise bending moments were calculated for a teetering rotor blade using a reasonably rapid theoretical method in which airloads obtained from wind-tunnel tests were employed. The calculated moments agreed reasonably well with those measured with strain gages under the same test conditions. The range of the tests included one hovering and two forward-flight conditions. The rotor speed for the test was very near blade resonance, and difficult-to-calculate resonance effects apparently were responsible for the largest differences between the calculated and measured harmonic components of blade bending moments. These differences, moreover, were largely nullified when the harmonic components were combined to give a comparison of the calculated and measured blade total- moment time histories. The degree of agreement shown is therefore considered adequate to warrant the use of the theoretical method in establishing and applying methods of prediction of rotor-blade fatigue loads. At the same time, the validity of the experimental methods of obtaining both airload and blade stress measurement is also indicated to be adequate for use in establishing improved methods for prediction of rotor-blade fatigue loads during the design stage. The blade stiffnesses and natural frequencies were measured and found to be in close agreement with calculated values; however, for a condition of blade resonance the use of the experimental stiffness values resulted in better agreement between calculated and measured blade stresses.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-2-28-59L , L-140
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  • 24
    Publication Date: 2019-08-15
    Description: As a continuation of an investigation of the release characteristics of an MB-1 rocket carried internally by the Convair F-106A airplane, six missile-bay baffle configurations and a rocket end plate have been investigated in the 27- by 27-inch preflight jet of the NASA Wallops Station. The MB-1 rocket used had retractable fins and was ejected from a missile bay modified by the addition of six different baffle configurations. For some tests a rocket end plate was added to the model. Dynamically scaled models (0.04956 scale) were tested at a simulated altitude of 22,450 feet and Mach numbers of 0.86, 1.59, and 1.98, and at a simulated altitude of 29,450 feet and a Mach number of 1.98. The results of this investigation indicate that the missile-bay baffle configurations and the rocket end plate may be used to reduce the positive pitch amplitude of the MB-1 rocket after release. The initial negative pitching velocity applied to the MB-1 rocket might then be reduced in order to maintain a near-level-flight attitude after release. As the fuselage angle of attack is increased, the negative pitch amplitude of the rocket is decreased.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-4-29-59L , AF-AM-57 , L-361
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  • 25
    Publication Date: 2019-08-15
    Description: A series of landings was performed with a straight-wing airplane to evaluate the effect of low lift-drag ratios on approach and landing characteristics. Landings with a peak lift-drag ratio as low as 3 were performed by altering the airplane configuration (extending speed brakes, flaps, and gear and reducing throttle setting). As lift-drag ratio was reduced, it was necessary either to make the landing pattern tighter or to increase initial altitude, or both. At the lowest lift-drag ratio the pilots believed a 270 deg overhead pattern was advisable because of the greater ease afforded in visually positioning the airplane. The values of the pertinent flare parameters increased with the reduction of lift-drag ratio. These parameters included time required for final flare; speed change during final flare; and altitude, glide slope, indicated airspeed, and vertical velocity at initiation of final flare. The pilots believed that the tolerable limit was reached with this airplane in the present configuration, and that if, because of a further reduction in lift-drag ratio, more severe approaches than those experienced in this program were attempted, additional aids would be required to determine the flare-initiation point.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-TM-X-31
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  • 26
    Publication Date: 2019-08-15
    Description: Values of the normal component of induced velocity throughout the entire field of a uniformly loaded r(rotor at high high speed are presented in the form of charts and tables. Many points were found by an electromagnetic analog, details of which are given. Comparisons of computed and analog values for the induced velocity indicate that the latter are sufficiently accurate for engineering purposes.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-TR-R-41
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  • 27
    Publication Date: 2019-08-15
    Description: This paper briefly summarizes available statistical data on airplane taxi operations, examines the profiles and power spectra of four selected runways and taxiways covering a wide range of surface roughness, considers (on the basis of theoretical and experimental results) the loads resulting from taxiing on such runways over a range of speeds and, by synthesis of the aforementioned results, proposes new criteria for runway and taxiway smoothness which are applicable to new construction and may also be used as a guide for determining when repairs are necessary.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-2-21-59L
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  • 28
    Publication Date: 2019-08-15
    Description: Flight tests have been conducted with a single-rotor helicopter, one blade of which was equipped at 14 percent and 40 percent of the blade radius with strain gages calibrated to measure moments rather than stresses, to determine the effects of transition, landing approaches, and partial-power vertical descents on the rotor-blade bending and torsional moments. In addition, ground tests were conducted to determine the effects of static droop-stop pounding on the rotor-blade moments. The results indicate that partial-power vertical descents and landing approaches produce rotor-blade moments that are higher than the moments encountered in any other flight condition investigated to date with this equipment. Decelerating through the transition region in level flight was found to result in higher vibratory moments than accelerating through this region. Deliberately induced static droop-stop pounding produced flapwise bending moments at the 14-percent-radius station which were as high as the moments experienced in landing approaches and partial-power vertical descents.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-5-7-59L
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  • 29
    Publication Date: 2019-08-15
    Description: Generalized influence coefficients are calculated by the method of NACA TN 3640 for a large-scale, built-up, 450 delta-wing specimen. These are used together with appropriate generalized masses to obtain the natural modes and frequencies in symmetric and antisymmetric free-free vibration. The resulting frequencies are compared with those obtained experimentally and are found to be consistently high. Possible sources of the disparities are discussed.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-2-1-59L
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  • 30
    Publication Date: 2019-08-15
    Description: Some blunt-body shapes considered suitable for entry into the earth's atmosphere were tested by both static and oscillatory methods in the Langley stability tunnel. In addition, free-fall tests of some similar models were made in the Langley 20-foot free-spinning tunnel. The results of the tests show that increasing the flare of the body shape increased the dynamic stability and that for flat-faced shapes increasing the corner radius increased the stability. The test data from the Langley stability tunnel were used to compute the damping factor for the models tested in the langley 20-foot free-spinning tunnel. For these cases in which the damping factor was low, -1/2 or less, the stability was critical and sensitive to disturbance. When the damping factor was about -2, damping was generally obtained.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-2-22-59L , L-157
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  • 31
    Publication Date: 2019-08-16
    Description: A preliminary investigation was conducted to determine whether a warhead stage of an antimissile missile could be placed within an arbitrary 2-nautical-mile-radius maneuver cylinder around an intercontinental-ballistic-missile (ICBM) flight path above an altitude of 140,000 feet, a horizontal range of 40 nautical miles, at a flight-path angle of approximately 20 deg, and within 50 seconds after take-off using only aerodynamic forces to turn the antimissile missile. The preliminary investigation indicated that an antimissile missile using aerodynamic forces for turning was capable of intercepting the ICBM for the stated conditions of this study although the turning must be completed below an altitude of approximately 70,000 feet to insure that the antimissile missile will be at the desired flight-path angle. Trim lift coefficients on the order of 2 to 3 and a maximum normal-acceleration force of from 25g to 35g were necessary to place the warhead stage in intercept position. The preliminary investigation indicated that for the two boosters investigated the booster having a burning time of 10 seconds gave greater range up the ICBM flight path than did the booster having a burning time of 15 seconds for the same trim lift coefficient and required the least trim lift coefficient for the same range.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-2-14-59L
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  • 32
    Publication Date: 2019-08-16
    Description: As a means of evaluating the roll utilization of a fighter airplane capable of supersonic speeds, an instrumented North American F-100A fighter airplane was flown by U.S. Air Force pilots at Nellis Air Force Base, NV, during 20 hours of service operational flying. Mach numbers up to 1.22 and altitudes up to 50,000 feet were realized in this investigation. Results of the study showed that except for high g barrel rolls performed as evasive maneuvers and rolls performed in acrobatic flying, rolling was utilized primarily as a means of changing heading. Acrobatic and air combat maneuvering produced the largest bank angles (1,200 deg), roll velocities (3.3 radians/sec), rolling accelerations (8 radians/sq sec) and sideslip angles (10.8 deg). Full aileron deflections were utilized on numerous occasions. Although high rolling velocities and accelerations also were experienced during several air-to-air gunnery missions, generally, air-to-air gunnery and air-to-ground gunnery and bombing required only two-thirds of maximum aileron deflection. The air-to-air gunnery and air combat maneuvers initiated from supersonic speeds utilized up to two-thirds aileron deflection and bank angles of less than 18 deg and resulted in rolling velocities and accelerations of 2 radians per second and 4.6 radians/sq sec, respectively. Rolling maneuvers were often initiated from high levels of normal acceleration, but from levels of negative normal acceleration only once.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-12-1-58H
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  • 33
    Publication Date: 2019-08-16
    Description: A flight investigation was undertaken to determine the effect of a fully controllable thrust reverser on the flight characteristics of a single-engine jet airplane. Tests were made using a cylindrical target-type reverser actuated by a hydraulic cylinder through a "beep-type" cockpit control mounted at the base of the throttle. The thrust reverser was evaluated as an in-flight decelerating device, as a flight path control and airspeed control in landing approach, and as a braking device during the ground roll. Full deflection of the reverser for one reverser configuration resulted in a reverse thrust ratio of as much as 85 percent, which at maximum engine power corresponded to a reversed thrust of 5100 pounds. Use of the reverser in landing approach made possible a wide selection of approach angles, a large reduction in approach speed at steep approach angles, improved control of flight path angle, and more accuracy in hitting a given touchdown point. The use of the reverser as a speed brake at lower airspeeds was compromised by a longitudinal trim change. At the lower airspeeds and higher engine powers there was insufficient elevator power to overcome the nose-down trim change at full reverser deflection.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-MEMO-4-26-59A , A-135
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  • 34
    Publication Date: 2019-08-16
    Description: The first landing of the X-15 airplane was made at 8:43 a.m., June 8, 1959, on the hard surface of Rogers Dry Lake. One purpose of the first-glide flight was to evaluate the effectiveness of the landing-gear system. Some results are presented of the landing-approach characteristics, the impact period, and the runout phase of the landing maneuver. The results indicate that the touchdown was accomplished at a vertical velocity of 2.0 feet per second for the main gear and 13.5 feet per second for the nose gear. These vertical velocities were within the values of sinking speeds established by structural design limitations. However, permanent structural deformation occurred in the main-landing-gear system as a result of the landing, and a reevaluation of the gear is being made by the manufacturer. The landing occurred at a true ground speed of 158 knots for main-gear touchdown at an angle of attack of 8.50. The incremental acceleration at the main gear was 2.7g and 7.39 at the nose gear as a result of the landing. The incremental acceleration at the center of gravity of the airplane was 0.6g for the main-gear impact and 2.4g for the nose-gear impact. The incremental acceleration at the main gear as a result of the nose-gear impact was 4.8g. The extreme rearward location of the main-gear skids appears to offer satisfactory directional stability characteristics during the run- out phase of the landing. No evidence of nosewheel shimmy was indicated during the impact and runout phase of the landing despite the absence of a shimmy damper on the nose gear. The maximum amount of skid wear as a result of the landing was on the order of 0.005 inch. No appreciable amount of tire wear was indicated for the dual, corotating nosewheels.
    Keywords: Aircraft Design, Testing and Performance
    Type: NASA-TM-X-207
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  • 35
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 298 (1959), S. 72-77 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: In addition to the formation of S4N4, greenish-yellow crystal sheets of S3N2F2 are deposited from a mixture containing SN2F2 and SNF at pressures form 600 to 700 mm Hg. S3N2F2 crystallizes in two polymorphic forms; the melting and decomposition points are 85 and 95 - 97° Cm, respectively; solubility in CCl4 at 20°C: 1.5 grs./100 grs. The observed formation of S3N2F2 is discussed in respect to the tendency of stable S—F-bond formation.
    Notes: Aus einem Gemisch von SN2F2 und SNF scheidet sich bei Drucken von 600 bis 700 Torr an der Wand des Reaktionskolbens ein gelber Beschlag ab, während gleichzeitig grüngelbe Kristallblättchen ins Innere des Kolbens wachsen. Bei letzteren handelt es sich um S3N2F2, das in zwei polymorphen Kristallarten auftritt. Fp. 85°C; Zers.-Pkt. 95-97°C. Löslichkeit in CCl4: 1,5 g/100 g bei 20°.Aus dem gelben Wandbeschlag wird durch Dekantieren mit Acetonitril S4N4 erhalten. Die Bildung von S3N2F2 wird diskutiert und festgestellt, daß die Tendenz zur Bildung stabiler S—F-Bindungen als Ursache für die Zersetzung von SN2F2 + SNF angesehen werden kann.
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  • 36
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 298 (1959), S. 142-151 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The reaction between 1 mol mercuric chloride and 1 mol ethylenediamine (I) leads in aqueous and in diluted alcoholic solutions to a mixture of mercuric chloride and mercuric ethylenediamine chloride, Hg(NH2CH2CH2NH2)Cl2 (II). It is possible to get the compound (II) in pure state in absolute alcolholic solution. X-ray and infrared investigations give evidence for a chain-structure of (II) with (I) bounded in the trans-form.
    Notes: In wäßrigen und verdünnten alkoholischen Lösungen reagieren 1 Mol Quecksilber(II)-chlorid und 1 Mol Äthylendiamin unter Bildung unlöslicher Produkte, die aus Gemischen von Hg(NH2—CH2—CH2—NH2)Cl2 und HgCl2 bestehen. Wird die Reaktion unter Wasserausschluß in absolutem Alkohol ausgeführt, so entsteht reines Quecksilber(II)-äthylendiaminchlorid, Hg(en)Cl2 (en = Äthylendiamin). Durch die Diskussionen des Debyeogramms und des Infrarotspektrums der Verbindung können Ringstrukturen ausgeschlossen werden; es liegt eine Kettenstruktur mit trans-Stellung der XH2-Gruppen (X = N oder C) der Äthylendiamin-Molekel vor.
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  • 37
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 298 (1959), S. 152-163 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Pure crystallizable dichlorophosphoric acid H[PO2Cl2] is prepared by reaction of dichlorophosphoric acid anhydride P2O3Cl4 with the calculated amount of water at temperatures below -30°C.When heated under reduced pressure (12 mm), and hydrogen chloride simultaneously is passed through, the dichlorophosphoric acid splits off water and is therefore again transformed into the dichlorophosphoric acid anhydride P2O3Cl4.Contrary to this the dichlorophosphoric acid decomposes, when heated under atmospheric pressure, mainly by splitting off HCl.
    Notes: Reine, kristallisierbare Dichlorphosphorsäure H[PO2Cl2] läßt sich durch Reaktion von Dichlorphosphorsäureanhydrid P2O3Cl4 mit der berechneten Menge Wasser bei Temperaturen unterhalb -30°C darstellen.Beim Erhitzen unter vermindertem Druck (12 mm) und gleichzeitigem Durchleiten von Chlorwasserstoff spaltet die Dichlorphosphorsäure Wasser ab und geht dadurch wieder in das Dichlorphosphorsäureanhydrid P2O3Cl4 über.Dagegen zersetzt sich die Dichlorphosphorsäure beim Erhitzen unter Atmosphärendruck vorwiegend unter HCl-Abspaltung.
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  • 38
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 298 (1959), S. 193-193 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 39
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 298 (1959), S. 194-201 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Vanadium(III)oxide, V2O3, is autocatalytically oxidized to vanadium(V)oxide or vanadates(V) by acid or neutral solutions of alkali metal chlorates, bromates, iodates, and periodates. By perchlorate ions, V2O3 is converted to vanadium(IV) compounds. The influence of pH and buffer systems has been investigated. The velocity of oxidation decreases from periodate, bromate, iodate, chlorate to perchlorate. In alkaline solutions the reaction of iodates is greater than that of bromates.
    Notes: Vanadin(III)-oxyd, V2O3, wird sowohl in saurer als auch ursprünglich neutraler Lösung der Alkalichlorate, -bromate, -jodate und -perjodate zu Vanadin(VI)-oxyd bzw. Vanadat und bei der Einwirkung von Perchlorationen langsam zur Vanadin(IV)-stufe oxydiert. Die Reaktionen verlaufen offenbar autokatalytisch. Die Halogenate wirken auch dann oxydierend, wenn der Einfluß der bei den Reaktionen gebildeten Wasserstoffionen durch Zusatz von Natriumhydrogencarbonat oder Calciumcarbonat zum Reaktionsgemisch aufgehoben wird und sogar unter alkalischen Bedingungen, wenn auch langsamer als in ungepufferten Lösung. Die Halogenate werden allgemein zur Halogenidstufe reduziert mit Ausnahme von Perjodat, das, falls reichlich von ihm vorhanden ist, zu Jodat reduziert wird. Die Oxydationsgeschwindigkeit nimmt in der Reihenfolge: Perjodat 〉 Bromat 〉 Jodat 〉 Chlorat 〉 Perchlorat ab. In alkalischen Lösungen oxydieren die Jodate schneller als die Bromate.
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  • 40
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 299 (1959), S. 78-86 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The Raman and infrared spectra of compounds of the type X (CH3)2SiOSi(CH3)2X (X = H, OH, Cl, C6H5 are reported and the frequencies are assigned. The shift of the valence frequencies of the framework is briefly discussed. The approximate valence force constant of the SiOSi bond in HO(CH3)2SiOSi(CH3)2OH is calculated to 4,97 mdyn/Å.
    Notes: Die Raman- und IR-Spektren der Verbindungen X(CH3)2SiOSi(CH3)2X (X = H, OH, Cl und C6H5) werden mitgeteilt und die Frequenzen den einzelnen Schwingungsformen zugeordnet. Der Gang der Valenzfrequenzen des Gerüstes wird kurz diskutiert. Für das Tetramethyldioxydisiloxan wird die angenäherte Valenzkraftkonstante für die Siloxanbindung zu 4,97 mdyn/Å berechnet.
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  • 41
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 299 (1959) 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 42
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 299 (1959), S. 151-152 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: A mechanism of the decomposition of the formic acid on a surface of nickel is proposed.
    Notes: Es wird ein Mechanismus der genannten Reaktion angegeben.
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  • 43
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 299 (1959), S. 138-150 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The bonds between silicium and elements of a great electronegativity are customary stronger than single bonds. This is shown by the valence force constants. The valence frequencies of substituted compounds indicate that strong electronegative substituends strengthen adjacent bonds. The mechanism of this strengthening is discussed.
    Notes: Die Valenzkraftkonstanten für Bindungen zwischen Silicium und stark elektronegativen Partnern zeigen, daß diese Bindungen in der Regel stärker als normale Einfachbindungen sind. Die Valenzfrequenzen in gemischt substituierten Verbindungen lassen erkennen, daß stark elektronegative Substituenten benachbarte Bindungen verstärken. Der Mechanismus dieser Bindungsverstärkungen wird diskutiert.
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  • 44
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 300 (1959), S. 41-50 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The compounds Pb5(XO4)3Z (with X = P, As, V and Z = F, Cl, Br, J) have been prepared and investigated by X-ray analysis. With the exception of Pb5(PO4)3J, all compounds crystallize in apatite structure which is orthorhombically deformed in the case of Pb5(AsO4)3J.
    Notes: Es wird die Synthese von Bleiapatiten der Zusammensetzung Pb5(XO4)3Z [X = P, As, V und Z = F, Cl, Br, J] beschrieben. Röntgenaufnahmen ergeben in allen Fällen außer Pb5(PO4)3J die Apatitstruktur, im Falle des Pb5(AsO4)3J ist sie rhombisch deformiert. Einige Strukturdaten dieser Verbindungen werden mitgeteilt.
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  • 45
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 300 (1959), S. 51-60 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: By interaction of alkali pentacarbonyl chromates(-II) with aromatic mono-, di-, and triamines at room temperature only pentacarbonyl amine chromium(0) compounds are formed. Wheras m- and p-phenylene diamine are linked with two and 1, 3, 5-triaminobenzene with three Cr(CO)5-groups, o-phenylene diamine forms a corresponding compound with only one Cr(CO)5-group. Unlike ethylene diamine or cyclohexane diamine(1,2) o-phenylene diamine does not give a tetracarbonyl chromium(0) compound.
    Notes: Bei der Umsetzung von Alkali-pentacarbonyl-chromaten(-II) mit wäßrigen Lösungen von aromatischen Mono-, Di- und Triaminen bei gewöhnlicher Temperatur erhält man stets Pentacarbonyl-amin-chrom(0)-verbindungen, die sich als echte Substitutions-produkte des Cr(CO)6 erweisen. Während m- und p-Phenylendiamin zwei und 1,3,5-Triaminobenzol drei Cr(CO)5-Gruppen zu binden vermögen, erhält man im Falle des o-Phenylendiamins eine entsprechende Verbindung mit nur einer Cr(CO)5-Gruppe. Insbesondere entsteht bei letzterem - im Gegensatz zum Äthylendiamin - keine Tetracarbonyl-chrom(0)-verbindung. Eine solche bildet sich hingegen, wenn man an Stelle des o-Phenylendiamins das hydrierte o-Phenylendiamin, also Cyclohexandiamin(1,2), zur Reaktion bringt.
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  • 46
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 300 (1959), S. 1-32 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The system niobium-chlorine has been investigated.The formation of niobiumtrichloride, with a composition range from NbCl2.67 to NbCl3.1, has been studied by thermal decomposition of niobium tetrachloride, reduction of NbCl5 with hydrogen, and the chemical transport reaction: \documentclass{article}\pagestyle{empty}\begin{document}$${\rm NbcL}_{\rm X} {\rm f + (4 - x)NbCl}_{\rm 5} {\rm g = (5 - x)NbCl}_{\rm 4} {\rm g}$$\end{document}.The thermal and chemical properties of the niobiumtrichloride phase are described.Niobium(II)-chloride which is a stoichiometric compound is formed in the reactions Nb+NbCla2.67, NbSNbCI5, and NbCl5+H. There is no evidence for the existence of niobium (I)-chloride.
    Notes: Das Niobtrichlorid besitzt einen großen Homogenitätsbereich. Die Phasengrenzen liegen bei den Zusammensetzungen NbCl3,1 und NbCl2,67. Diese Grenzzusammensetzungen fallen schon beim thermischen Abbau des Niobtetrachlorids und bei der Reduktion von NbCl5 mit H2 auf. Weiteren Aufschluß geben Experimente, bei denen die Trichloridphase NbClx durch eine chemische Transportreaktion \documentclass{article}\pagestyle{empty}\begin{document}$${\rm NbcL}_{\rm X} {\rm f + (4 - x)NbCl}_{\rm 5} {\rm g = (5 - x)NbCl}_{\rm 4} {\rm g}$$\end{document} als Gleichgewichtsbodenkörper gewonnen wird. Die Zusammensetzung der Trichloridphase hängt in der zu fordernden Weise vom NbCl5-Druck ab. Aus Pulverdiagrammen und aus der Farbe der Trichlorid-Präparate läßt sich ebenfalls die Breite der Trichloridphase und auch die Zusammensetzung eines im homogenen Gebiet liegenden Präparats ableiten.Angaben über das Niobtrichlorid hinsichtlich seines thermischen und chemischen Verhaltens werden zusammengestellt.Niob(II)-chlorid wird aus Nb + NbCl2,67 gewonnen. Auch beim Erhitzen von Nb im NbCl5-Argon-Strom und bei der Reduktion von NbCl5 mit H2 ist die NbCl2-Bildung nachweisbar. NbCl2 besitzt keine erhebliche Phasenbreite. Das chemische und thermische Verhalten des NbCl2 werden studiert.Das metallische Niob löst keine nachweisbaren Cl-Mengen. Ein Niob(I)-chlorid wurde nicht gefunden.Zusammenfassend werden die Phasenverhältnisse im System Niob-Chlor dargestellt und weitere Probleme der Trichloridphase erörtert.Das letzte Kapitel bringt Analysenverfahren.
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  • 47
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 300 (1959), S. 61-71 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The compound Li7VN4 containing vanadium(V) has been prepared by heating Li3N and VN in nitrogen atmosphere to a temperature of 680 °C. Li7VN4 crystallizes in an superstructure of fluorite lattice (space group T4d with a = 9.604 Å).Similarly, the compounds Li7NbN4 and Li7 TaN4 have been synthesized.
    Notes: 1. Durch Erhitzen von Li3N und VN in einer Stickstoffatmosphäre auf 680 °C wurde die Verbindung Li7VN4 hergestellt. Die Oxydationsstufe 5 des Vanadins wurde mit drei verschiedenen Methoden bestimmt. Die ternäre Verbindung ist thermisch beständiger als die zwei binären Nitride. Li7VN4 kristallisiert in einer Überstruktur des Flußspatgitters in der Raumgruppe T4d mit a = 9,604 Å. Ein ternäres Nitrid niedrigerer Oxydationsstufe konnte nicht hergestellt werden.2. Entsprechende Versuche führten zu den Verbindungen Li7NbN4 und Li7TaN4; diese Verbindungen sind chemisch und thermisch etwas stabiler als die Vanadinverbindung.
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  • 48
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 299 (1959), S. 213-226 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: A technical alteration of the TiCl3-preparation according to SHERFEY is described.The phase diagrams of the systems NaCl/TiCl3, KCl/TiCl3 and KBr/TiBr3 were investigated by thermal analysis. There exist the compounds: Na3TiCl6 (incongruent m. p. = 553° C), K3TiCl6 (m. p. = 783° C), K2TiCl5 (incongruent m. p. = 605° C), K3TiBr6 (m. p. = 662° C). The results were confirmed by microscopic and X-rax methods.In the NaCl- and KCl-rich melts exists the complex [TiCl6]3- probably.
    Notes: Eine technische Abänderung der TiCl3-Darstellung nach SHERFEY wird mitgeteilt.Die Untersuchung der Systeme NaCl/TiCl3, KCl/TiCl3 und KBr/TiBr3 mit Hilfe der Differential-Thermoanalyse ergab folgendes: Im System NaCl/TiCl3 existiert die Verbindung Na3TiCl6. Sie schmilzt inkongruent bei 553° C. Das Zustandsdiagramm KCl/TiCl3 zeigt die Verbindungen K3TiCl6 (Schmp. = 783° C) und K2TiCl5 an, wobei die letztere bei 605° C inkongruent schmilzt. Im System KBr/TiBr3 tritt die bei 662° C kongruent schmelzende Verbindung K3TiBr6 auf.Das Ergebnis der thermischen Analyse wird durch mikroskopische und röntgenographische Untersuchungen gesichert.Die Berechnung der Liquiduskurve auf der NaCl- bzw. KCl-reichen Seite der Zustandsdiagramme legt nahe, die Existenz von [TiCl6]3--Ionen in der Schmelze anzunehmen.
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  • 49
    Electronic Resource
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 299 (1959) 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 50
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 299 (1959), S. 241-251 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Tetraphosphorus-heptasulfide, P4S7, undergoes disproportionation in liquid ammonia at a temperature of -33° C according to the equation mentioned in „Inhaltsübersicht“.Tetraphosphorus-heptasulfide, P4S7, undergoes disproportionation in liquid ammonia at a temperature of -33° C according to the equation mentioned in „Inhalts-übersicht“.From the reaction products, the properties of which are described there is evidence for the structure of P4S7, determined by X-ray diffraction(4). The trimer orange-coloured [P3S3(NH)4]4-anion is supposed to have a cyclic structure.The thermal decomposition of (NH4)3[PS4] and (NH4)2[PS3NH2], yielding P4N5, is discussed.
    Notes: Während die beiden niederen Phosphorsulfide(2) P4S3 und P4S5 mit flüssigem Ammoniak bei -33° unter Bildung von Ammoniumverbindungen mit vier P-atomen in der Molekel reagieren und P4S10(3) einfach gebaute Thiophosphate bildet, unterliegt Tetraphosphor-heptasulfid in diesem Medium gemäß 2P4S7 + 17 NH3 → (NH4)3[PS4] + 2 (NH4)2[PS3NH2] + (NH4)3[P3S3(NH)3] + NH4[P2SN] der Disproportionierung.Der obige Reaktionsverlauf läßt sich einerseits durch quantitative Erfassung der sich in ihrer Löslichkeit unterscheidenden Thiophosphate (NH4)3[PS4] und (NH4)2[PS3NH2], andererseits durch Isolierung der Verbindung [P3S3(NH)3], in der der Phosphor die Oxydationszahl +III einnimmt, nachweisen. Die experimentellen Ergebnisse lassen sich aus der für das P4S7 röntgenographisch nachgewiesenen Struktur(4) ableiten.Die Eigenschaften der erhaltenen Verbindungen werden beschrieben und die Ergebnisse des thermischen Abbaus von (NH4)3[PS4] und (NH4)2[PS3NH2], der in beiden Fällen schließlich zu P3N5 führt, diskutiert.Dem trimeren orangefarbenen Thio-imidophosphit-anion [P3S3(NH)3]3- wird ringförmige Struktur zugeschrieben.
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  • 51
    Electronic Resource
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 299 (1959), S. 271-280 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The magnetic susceptibility of FeO1+x · 0,925 MgO (0 〈 x 〈 0,5) at 700, 750, 800, 850 and 900° C has been measured. The results are compared with values calculated under certain conditions and with the magnetic susceptibility of the system Fe—O, received in previous investigations.The isotherms of the susceptibility of magnesiowüstite (FeO1+y · 0,925 MgO) and wüstite (FeO1+y) allow to make some conclusions of the structure of the magnesiowüstite phase. It seems very probable that the ions Fe3+ both in magnesiowüstite and in wüstite occur in the form of accumulations. This „submicroheterogenity“ does not mean that magnesiowüstite from the point of view of thermodynamics consists of two solid phases.The homogeneity range of magnesiowüstite phase spreads at 700° C from FeO1,04 · 0,925 MgO to FeO1,09 · 0,925 MgO and at 900° C about FeO1,015 · 0,925 MgO to about FeO1,11 · 0,925 MgO.
    Notes: Im System FeO1+x · 0,925 MgO (0 〈 x 〈 0,5) wurde für 15 Präparate die magnetische Suszeptibilität bei 700°, 750°, 800°, 850° und 900°C gemessen. Die Ergebnisse werden mit den unter bestimmten Voraussetzungen berechneten Suszeptibilitäten und mit den für das System Fe—O früher erhaltenen experimentellen Werten verglichen. Aus dem Verlauf der Suszeptibilitätsisothermen in den Homogenitätsbereichen der „Magnesiowüstit“-Phase (feste Lösungen von FeO1+y und 0,925 MgO) und der Wüstitphase (FeO1+y) konnten gewisse Schlüsse in bezug auf die Struktur der „Magnesiowüstit“-Phase gezogen werden. Es ist wahrscheinlich, daß die Fe3+-Ionen im Magnesiowüstit, ähnlich wie im Wüstit, in Form von Ansammlungen vorhanden sind. Diese „Submikroinhomogenität“ bedeutet nicht, daß Magnesiowüstit im thermodynamischen Sinne aus zwei festen Phasen besteht.Der Homogenitätsbereich der Magnesiowüstitphase erstreckt sich bei 700° C von FeO1,04 · 0,925 MgO bis FeO1,09 ·0,925 MgO und bei 900° C von FeO1,015 · 0,925 MgO bis ungefähr FeO1,11 · 0,925 MgO.Das Curie-Weiss-Gesetz wird von den im Homogenitätsbereich der Magnesiowüstitphase liegenden Präparaten befolgt.Die Abhängigkeit der magnetischen Suszeptibilität von der Zusammensetzung bei höheren Sauerstoffgehalten (x 〉 1,1) ist infolge des Auftretens zweier fester Phasen veränderlicher Zusammensetzung kompliziert.
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  • 52
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Thiopicolinic acid anilide reacts with ions of heavy metals to form inner complex salts. Complexes of 12 metals have been prepared. The coordination compound with Fe(II)-ions is deep violet.
    Notes: Thiopicolinsäure-anilid fungiert gegenüber Schwermetallionen, besonders azo- und chalkophilen, als Innerkomplexligand wie als Neutralligand(1). Das Anilid wird als Anion der tautomeren Iminothiol-Form von dem betreffenden Metallion innerkomplex koordiniert, wobei je nach Ladungs- und charakteristischer Koordinationszahl des Zentrums entweder ladungslose oder Acido-Innerkomplexe entstehen. Analytisch definierte Komplexe wurden von 12 verschiedenen Metallen gewonnen, wobei die sehr intensive Violettfarbe der Eisen(II)-komplexe hervorzuheben ist.
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  • 53
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 301 (1959), S. 161-170 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The infrared spectra of some telluric acids, tellurates and antimonates are measured. The constitution of these compounds is discussed.
    Notes: Es werden die Ultrarotspektren der Verbindungen H6TeO6, (H2TeO4)x, Na2H4TeO6, K2H4TeO6 · 3 H2O, Na[Sb(OH)6], KSbO3 · 2,2 H2O, Na2HSb3O9 · 4 H2O, K2HSb3O9 · 5 H2O, NaSbO3 und KSbO3 im Bereich 400-4000 cm-1 angegeben und ausgedeutet. Die Konstitution dieser Verbindungen wird diskutiert.
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  • 54
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    Zeitschrift für anorganische Chemie 300 (1959), S. 194-204 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: From infrared spectra in the NaCl-region and Raman spectras of several cyanates of silicon (see „Inhaltsübersicht°“), the isocyanate structure for all these compounds has been demonstrated. There is a small multiple bond character of Si-N-bonds.
    Notes: Es wurden die Infrarot-Spektren im NaCl-Bereich und die Raman-Spektren von (CH3)3Si(NCO), (CH3)2Si(NCO)2, CH3Si(NCO)4, Si(NCO)4 und Si2O(NCO)6 aufgenommen und eine Zuordnung zu den Grundschwingungen dieser Molekel vorgenommen. Für alle Verbindungen konnte die Isocyanatstruktur spektroskopisch nachgewiesen werden, auch für die in der Literatur mit normaler Cyanatstruktur beschriebene Verbindung. Bei dieser handelt es sich um ein Gemisch von Si(NCO)4 + Si2O(NCO)6. Weiterhin ergab sich aus den Spektren der Isocyanate, daß die Si-N-Bindungen einen geringen Mehrfachbindungsanteil haben.
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  • 55
    Electronic Resource
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 300 (1959), S. 159-174 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The influence of coordination number, lattice expansion, and decreasing degree of symmetry or distortion of the coordination polyhedron on the light absorption of Ni2+-ions in various oxides (see „Inhaltsübersicht°“) have been studied by spectrophotometric determination of powder remission.As in the case of Co(II)-containing oxides, the main absorption band is shifted toward the UV-region by raising the coordination number from 4 to 6. Displacement toward the red sometimes occurs on lattice expansion.Stronger shiftings to the red and high intensities of absorption have been observed when the decrease of point symmetry of coordination polyhedron is accompanied by stronger distortion.The ranges of homogeneity in the system Zn2SiO4/Ni2SiO4 have been determined spectrometrically.
    Notes: Durch spektralphotometrische Bestimmung der Remission von Pulvern wurde die Abhängigkeit der Lichtabsorption des Ni2+ von folgenden Faktoren untersucht: 1. Koordinationszahl (Ni0,1Mg0,9Al2O4, KZ = 4, Ni0,1Mg0,9O, KZ = 6) 2. Gitterdehung (Ni0,1Mg0,9Al2O4 → Ni0,1Mg0,9Ga2O4), (Ni0,1Mg0,9O → Ni0,01Mg0,69Zn0,3O), (Ni0,1Mg0,9TiO3 → Ni0,1Cd0,9TiO3) 3. Symmetrieerniedrigung bzw. Verzerrung des Koordinationspolyeders (Ni0,1Zn1,9SiO4, Ni0,01Zn0,99O), (Ni0,25Mg1.75SiO4, Ni0,1Mg0,9TiO3). Wie im Fall des Co2+ bewirkt hier die Erhöhung der Koordinationszahl von 4 auf 6 bei einer Eigensymmetrie des Koordinationspolyeders Td bzw. Oh eine UV-Verschiebung der Hauptabsorptionsbanden. Eine Gitterdehnung kann, insbesondere bei einfachen Gittern, eine Rotverschiebung bewirken. Eine Erniedrigung der Punktsymmetrie des Koordinationspolyeders hat nur dann eine stärkere Rotverschiebung und Erhöhung der Absorptionsintensität zur Folge, wenn damit gleichzeitig eine stärkere Verzerrung des Koordinationsoktaeders verbunden ist. Das System Zn2SiO4/Ni2SiO4 wurde spektralphotometrisch untersucht und die Grenzen der Homogenitätsgebiete aus dem Vergleich der Spektren ermittelt.
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  • 56
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 300 (1959), S. 175-193 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Two isomeric hydroxy-cobalt(III)-amides, I and II, of the composition [Co(NH2)2OH]n have been prepared by interaction of KNH2 with [Co(NH3)5OH](NO3)2 and [Co2(NH3)8(OH)2]X4 (X = NO3- or SCN-), respectively, in liquid ammonia. The reactions of the amorphous amides, the structures of which are discussed, with a surplus of KNH2 and NH4NO3 in liquid ammonia and the thermal decomposition of II have been studied.The reaction between [Co(NH3)6](NO3)3 and KNH2 yields {[Co2(NH2)5NH3]n(NO3)n}.
    Notes: Durch Umsetzung von [Co(NH3)5(OH)](NO3)2 (I) und [Co2(OH)2(NH3)8]X4 (II) (X = NO3 oder SCN) mit KNH2 in flüssigem NH3 wurden zwei strukturisomere Mono-hydroxokobalt(III)-amide {Co(NH2)2OH}n (III bzw. IV) als unlösliche, amorphe Niederschläge erhalten. Das aus II gewonnene m̈-Monohydroxokobalt-(III)-amid (IV) besitzt noch die Di-m̈-hydroxogruppierung, sofern die Fällung bei tiefen Temperaturen (-20° C) erfolgt. Beide Verbindungen III und IV sind als Derivate des Kobalt(III)-amids zu betrachten und sind wie dieses mehr oder weniger hochpolymer. Unter Berücksichtigung des Strukturprinzips ist III als poly-m̈-Hydroxo-di-m̈-amino-kobalt(III) und IV als poly-[Di-m̈-hydroxo-m̈-amino-kobalt-tri-m̈-amino-kobalt(III)] zu bezeichnen. Der aus I resultierende Bodenkörper (III) reagiert mit NH4NO3 in flüssigem NH3 unter additiver Salzbildung zu {[Co2(OH)2NH2(NH3) 6]n(NO3)3n} (V), einem amorphen Nitrat, mit polymerem Kation, das noch alle OH-Gruppen enthält. IV reagiert ebenfalls mit NH4NO3 unter additiver Salzbildung, jedoch unter Eliminierung der Hälfte aller OH-Gruppen zu {[Co2(OH)(NH2)2(NH3)6]n(NO3)3n} (VIII). Mit KNH2 erfolgt ein Austausch von OH gegen NH2 sowohl in III als auch in IV unter Bildung von KOH. Bei der Reaktion von II mit KNH2 konnte ein definiertes Zwischenprodukt {[Co2(OH)2(NH2)3(NH3)2]n(NO3)n} (VI) gefaßt werden. Ein analoges; um 1 NH3 ärmeres Zwischenprodukt {[Co2(NH2)5(NH3)]n(NO3)n} (VII) - die OH-Gruppen sind durch NH2 ersetzt - entsteht auch bei der Reaktion von [Co(NH3)6](NO3)3 mit KNH2 in flüssigem NH3. Der thermische Abbau von IV führt unter NH3- und N2-Abspaltung schließlich zu CoO. Eine Wasserabspaltung wurde hierbei nicht beobachtet.
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  • 57
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    Zeitschrift für anorganische Chemie 300 (1959), S. 205-209 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The compound Si2P is formed at 450 °C from SiH4 and PH3, if the starting gas mixtures are containing SiH4 and PH3 in the ratio of 1 : 1 or 1 : 2. Si2P is a blue black non-crystalline substance. At 600 °C Si2P decomposes into Si and SiP as recognized from X-ray diagrams and IR-spectra. SiP formed from Si2P is identical with that prepared by Biltz1) from its elements.
    Notes: Aus SiH4 und PH3 bildet sich um 450 °C die Verbindung Si2P, wenn man von Gasmischungen SiH4:PH3 = 1 : 1 oder 1 : 2 ausgeht. Si2P ist ein blauschwarzes, röntgenamorphes Produkt. Um 600 °C zerfällt es in Si und SiP, wie aus den Röntgendiagrammen und den IR-Aufnahmen zu erkennen ist. Das aus dem Si2P entstehende SiP ist mit dem von Biltz1) aus den Elementen dargestellten SiP identisch.
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  • 58
    Electronic Resource
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 300 (1959) 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 59
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 300 (1959), S. 210-220 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The Raman and infrared spectra of [(CH3)2SiS]2 and [(CH3)2SiS]3 are reported and the frequencies are assigned as far as possible. [(CH3)2SiS]2 has the symmetrie D2h with a planar ring. The ring of [(CH3)2SiS]3 is puckered. The most probable symmetrie is here Cs (cis structure). The correlation of the SiXSi angle and the ring structure of siloxanes, silazanes and silthianes is discussed.
    Notes: Die Raman- und IR-Spektren des [(CH3)2SiS]2 und [(CH3)2SiS]3 werden mitgeteilt und die Frequenzen soweit wie möglich den einzelnen Schwingungsformen zugeordnet. Für das [(CH3)2SiS]2 ergibt sich eine ebene Ringstruktur nach D2h. Der Ring des [(CH3)2SiS]3 ist gewellt und hat höchstwahrscheinlich Cis-(Wannen-)Struktur, Punktgruppe Cs. Der Zusammenhang zwischen SiXSi-Winkel und Ringstruktur der Siloxane, Silazane und Silthiane wird diskutiert.
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  • 60
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    Zeitschrift für anorganische Chemie 300 (1959), S. 221-224 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Mixtures of amides of imidophosphoric acids with the composition PnOn(NH)n-1 · (NH2)n+2 are formed from OP(NH2)3 by heating at 100° C. - NaPO2)2 respectively Na2PO3NH2 looses all nitrogen by heating in the air at 900° resp. 1000° C and forms glassy (NaPO3)x resp. Na4P2O7.
    Notes: Amidophosphate werden beim Erhitzen infolge intermolekularer Abspaltung von Ammoniak zu Imidopolyphosphaten kondensiert. Aus Phosphoroxytriamid entstehen bei etwa 100° Gemische von Imidophosphorsäureamiden der Formel PnOn(NH)n-1(NH2)n+2 mit n = 2…5. Naturiumdiamidophosphat bzw. Natriummonoamidophosphat geben beim Erhitzen an der Luft auf 900° bzw. 1000° den gesamten Stickstoff ab und gehen in glasiges Natriumpolyphosphat (NaPO3)x bzw. Natriumdiphosphat über.
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  • 61
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    Zeitschrift für anorganische Chemie 300 (1959), S. 225-228 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: An abbreviated nomenclature is proposed for acids of phosphorus with lower oxydation number.
    Notes: Es wird eine abgekürzte Bezeichnungsweise für Phosphorsäuren niederer Oxydationszahl vorgeschlagen.
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  • 62
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    Zeitschrift für anorganische Chemie 300 (1959), S. 237-249 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Red phosphorus suspended in alkali hydroxyde solutions reacts with hypohalogenites under formation of salts of an acid \documentclass{article}\pagestyle{empty}\begin{document}${\rm (- P -)}_{\rm 6}$\end{document}. The oxidation number of phosphorus in this compound is 3+. The phosphorus atoms are linked together by P - P bonds. The compound has a ring structure.
    Notes: In Alkalihydroxydlösungen suspendierter roter Phosphor reagiert mit Hypohalogeniten unter Bildung von Salzen einer \documentclass{article}\pagestyle{empty}\begin{document}${\rm (- P -)}_{\rm 6}$\end{document}-Ringsäure. Die Oxydationszahl des Phosphors in der Verbindung ist 3+; die Phosphoratome sind über P - P-Bindungen miteinander verknüpft. Die Verbindung hat Ringstruktur.
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  • 63
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The preparation of salts of an acid of phosphorus in which 3 phosphorus atoms are linked together in a straight chain is described. The acid is prepared from oxidates of the acid \documentclass{article}\pagestyle{empty}\begin{document}${\rm (} - \mathop {\rm P}\limits^{\rm 3} -)_6$\end{document}, from oxidates of red phosphorus and from hydrolyzates of phosphorus tribromide.
    Notes: Die Herstellung von Salzen einer Säure des Phosphors, in der 3 Phosphor-Atome linear miteinander verbunden sind, aus Oxydaten der \documentclass{article}\pagestyle{empty}\begin{document}${\rm (} - \mathop {\rm P}\limits^{\rm 3} -)_6$\end{document}-Ringsäure, aus Oxydaten des roten Phosphors und aus Hydrolysaten des Phosphortribromids wird beschrieben.
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  • 64
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The \documentclass{article}\pagestyle{empty}\begin{document}$\mathop {\rm P}\limits^{\rm 4} {\rm - }\mathop {\rm P}\limits^{\rm 4}$\end{document}-acid is stable even towards 80% alkali hydroxide at 200°C. It is transformed to orthophosphate in molten anhydrous alkali hydroxide. The \documentclass{article}\pagestyle{empty}\begin{document}$\mathop {\rm P}\limits^{\rm 2} {\rm - }\mathop {\rm P}\limits^{\rm 4}$\end{document}-acid is also very stable towards alkali hydroxide. Under rigorous conditions it is oxidized to \documentclass{article}\pagestyle{empty}\begin{document}$\mathop {\rm P}\limits^{\rm 4} {\rm - }\mathop {\rm P}\limits^{\rm 4}$\end{document}-acid with yields up to 85% of theory under formation of hydrogen. High yields of \documentclass{article}\pagestyle{empty}\begin{document}$\mathop {\rm P}\limits^{\rm 4} {\rm - }\mathop {\rm P}\limits^{\rm 4}$\end{document}-acid can also be obtained by reacting iodine with \documentclass{article}\pagestyle{empty}\begin{document}$\mathop {\rm P}\limits^{\rm 2} {\rm - }\mathop {\rm P}\limits^{\rm 4}$\end{document}-acid in mineral acid solution. Copper catalyzed oxidation of \documentclass{article}\pagestyle{empty}\begin{document}$\mathop {\rm P}\limits^{\rm 4} {\rm - }\mathop {\rm P}\limits^{\rm 4}$\end{document}-acid by hypobromite in alkaline solution leads to mixtures of ortho- and pyrophosphate.
    Notes: Die \documentclass{article}\pagestyle{empty}\begin{document}$\mathop {\rm P}\limits^{\rm 4} {\rm - }\mathop {\rm P}\limits^{\rm 4}$\end{document}-Säure ist sogar gegen 80proz. Alkalihydroxyd bei 200°C beständig, erst schmelzendes wasserfreies Alkalihydroxyd verwandelt zu Orthophosphat. Auch die \documentclass{article}\pagestyle{empty}\begin{document}$\mathop {\rm P}\limits^{\rm 2} {\rm - }\mathop {\rm P}\limits^{\rm 4}$\end{document}-Säure ist gegen Alkalihydroxyd sehr beständig; bei verschärften Bedingungen wird sie mit Ausbeuten bis zu 85% unter Wasserstoffentwicklung zur \documentclass{article}\pagestyle{empty}\begin{document}$\mathop {\rm P}\limits^{\rm 4} {\rm - }\mathop {\rm P}\limits^{\rm 4}$\end{document}-Säure oxydiert. Auch bei der Einwirkung von Jod auf die \documentclass{article}\pagestyle{empty}\begin{document}$\mathop {\rm P}\limits^{\rm 2} {\rm - }\mathop {\rm P}\limits^{\rm 4}$\end{document}-Säure in mineralsaurer Lösung können hohe Ausbeuten der \documentclass{article}\pagestyle{empty}\begin{document}$\mathop {\rm P}\limits^{\rm 4} {\rm - }\mathop {\rm P}\limits^{\rm 4}$\end{document}-Säure erhalten werden. Die durch Kupfer katalysierte Oxydation der \documentclass{article}\pagestyle{empty}\begin{document}$\mathop {\rm P}\limits^{\rm 4} {\rm - }\mathop {\rm P}\limits^{\rm 4}$\end{document}-Säure in alkalischer Lösung durch Hypobromit führt zu Gemischen von Ortho- und Pyrophosphat.
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  • 65
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    Zeitschrift für anorganische Chemie 301 (1959), S. 316-322 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Solutions of antimonates give with H2O2 peroxy-antimonates. These are amorphous, polymeric, insoluble substances. The approximate composition of some of these compounds is KSbO4 · 1,7 H2O, NaSbO4 · 2 H2O, KSbO4 · 1,8 H2O2 and K2HSb3O12 · 3,5 H2O. The constitution of the peroxy-antimonates is discussed with help of their infrared spectra.
    Notes: Aus Lösungen von Kaliumantimonat entstehen mit H2O2 Peroxyantimonate. Diese sind amorphe, schwer lösliche, polymere Substanzen. Isoliert wurden unter anderem Verbindungen der annähernden Zusammensetzung KSbO4 · 1,7 H2O NaSbO4 · 2 H2O, KSbO4 v 1,8 H2O2 und K2HSb3O12 · 3,5 H2O. Die Konstitution der Peroxyantimonate wird an Hand ihrer Ultrarotspektren diskutiert.
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  • 66
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    Zeitschrift für anorganische Chemie 301 (1959), S. 326-335 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Reactions of surface hydroxyl groups have been investigated with finely divided amorphous silica (Aerosil). The hydroxyl groups react with calcium hydroxide; esters are formed by reaction with alcohols and diazomethane. Heating with thionyl chloride leads to substitution by chlorine. This reaction is especially suited for the quantitative determination of hydroxyl groups bound to silica surfaces.With lithium phenyl, chlorine bonded to surface silicon atoms can be substituted by phenyl groups.Quantitative determinations show that for Aerosil the number of surface hydroxyl groups is lower than the maximum amount estimated for silica surfaces; their surface concentration varied for different batches.
    Notes: An Aerosil, einem feinteiligen amorphen Siliciumdioxyd-Präparat der Degussa, wurden Umsetzungen mit den an der Oberfläche gebundenen Hydroxylgruppen durchgeführt. Die Hydroxylgruppen reagieren mit Calciumhydroxyd; mit Alkoholen und mit Diazomethan lassen sie sich verestern. Bei der Einwirkung von Thionylchlorid werden sie durch Chlor ersetzt. Diese Reaktion ist zur quantitativen Bestimmung der an Siliciumdioxyd-Oberflächen gebundenen Hydroxylgruppen besonders gut geeignet.Bei der Umsetzung mit Lithiumphenyl wird das am Silicium gebundene Chlor seinerseits durch Phenylgruppen ersetzt.Die quantitative Verfolgung der Reaktionen ergab, daß das Aerosil nicht die maximal mögliche Zahl oberflächenständiger Hydroxylgruppen besitzt. Ihre Menge pro Flächeneinheit ist vom jeweils gelieferten Muster abhängig.
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  • 67
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    Zeitschrift für anorganische Chemie 301 (1959), S. 336-338 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Pure anhydrous Ba(BF4)2 has been prepared by interaction between BaF2 and BF3 · 2 H2O and purification of the crude reaction product by means of acetone.The solubilities of Ba(BF4)2 in H2O, acetone, methanol, and ethanol have been determined.
    Notes: Das reine wasserfreie Ba(BF4)2 wird durch Umsetzung von BaF2 mit BF3 · 2 H2O und Behandlung des entstandenen Rohsalzes mit Aceton gewonnen.Die Löslichkeit von Ba(BF4)2 in Wasser, Aceton, Methanol und Äthanol wird bestimmt.
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  • 68
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    Zeitschrift für anorganische Chemie 301 (1959), S. 339-342 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Sb(OC2H5)5 is hydrolized on action with ½ mol of water yielding the dimeric ester (C2H5O)4Sb—O—Sb(OC2H5)4. By larger quantities of water polymeric chains and net works are formed.
    Notes: Durch Hydrolyse von Sb(OC2H5)5 mit einem halben Mol Wasser entsteht die kondensierte Verbindung (C2H5O)4SbOSb(OC2H5)4. Größere Mengen an Wasser führen zu ketten förmigen und vernetzten Produkten.
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  • 69
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    Zeitschrift für anorganische Chemie 298 (1959), S. 285-301 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The formation of alkali peroxides by reaction between molten alkali hydroxides and oxygen in the presence of water vapor at temperatures of 410 and 510°C has been investigated. Maximum yields of peroxides obtained in dry pure oxygen at 410°C are to be seen in „Inhaltsübersicht“.At definite low pressures of water vapor reproducible peroxide yields have been observed. From the dependence of equilibrium values from oxygen and water vapor pressures there is evidence that in molten NaOH mainly Na2O2 is formed, whereas in KOH, RbOH and CsOh the hyperoxides KO2, RbO2, and CsO2, respectively are the main reaction products.
    Notes: Es wurde das zur Bildung von Alkaliperoxyden führende Gleichgewicht zwischen Alkalihydroxydschmelzen und Sauerstoff in Gegenwart von Wasserdampf bei 410° und 510°C näher untersucht. In trockenem, reinem Sauerstoff wurden bei 410°C maximal folgende Mengen Peroxyd gebildet:.Während es sich bei diesen Zahlen um die in trockenem Sauerstoff, also bei undefiniertem Wasserdampfpartialdruck praktisch erreichbaren Höchstwerte handelt, stellen sich bei geringen Wasserdampfpartialdrucken gut reproduzierbare Gleichgewichte im Laufe von 6 - 15 Stunden ein. Identische Gleichgewichtswerte konnten auch von der anderen Seite her, ausgehend von KO2 erhalten werden.Die Abhängigkeit der Gleichgewichtswerte vom Sauerstoffpartialdruck und Wasserdampfpartialdruck wird an Hand logarithmischer Diagramme diskutiert. Man gelangt dabei zu dem Schluß, daß die NaOH-Schmelzen das Peroxyd Na2O2 gelöst enthalten, während bei den KOH-, RbOH- und CsOH-Schmelzen die Hyperoxyde KO2, RbO2 und CsO2 überwiegen.
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  • 70
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    Zeitschrift für anorganische Chemie 298 (1959), S. 316-336 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: In paper chromatography of condensed phosphates in acid medium the presence of little quantities of ammonia is necessary. For the explanation of this fact, which was not previously understood, it has been shown that ammonia can be replaced by other monovalent cations. The dependence of chromatographic separation on the cation type and cation concentration has been, therefore, investigated. Furthermore, it has been demonstrated that cations migrate independent of the phosphate anions. However, the presence of cations is necessary in order to differentiate between the solubilities of condensed phosphates by virtue of their molecular weight and their constitution.
    Notes: Bei der Papierchromatographie kondensierter Phosphate in saurem Medium erwies sich die Anwesenheit kleiner Mengen von Ammoniak als notwendig. Zur Aufklärung dieser bisher unverstandenen Tatsache wird gezeigt, daß das Ammoniak durch andere einwertige Kationen ersetzt werden kann, die Trennwirkung in Abhängigkeit von Kationenart und -menge untersucht und außerdem nachgewiesen, daß die Kationen unabhängig von den Phosphatanionen wandern. Die Gegenwart der Kationen ist aber notwendig, um die Löslichkeit der kondensierten Phosphate in Abhängigkeit von ihrem Molekulargewicht und ihrer Konstitution zu differenzieren.
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  • 71
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    Zeitschrift für anorganische Chemie 299 (1959), S. 1-2 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 72
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    Zeitschrift für anorganische Chemie 301 (1959), S. 350-354 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Die Rektion zwischen CrCl2 und K4Fe(CN)6 ist mittels potentiometrischer, konduktometrischer und amperometrischer Titrationen untersucht worden. Mit den ersten beiden Methoden wurde die Bildung von K2CrFe(CN)6 und Cr2Fe(CN)6 nachgewiesen; die amperometrische Titration gab nur Hinweise für die Existenz der ersteren Verbindung. Durch die Adsorptionsfähigkeit der Verbindungen entstehen Fehler, die in Gegenwart von Alkohol geringer sind als in rein wäßrigem Medium.
    Notes: Potentiometric, conductometric and amperometric titrations have been carried out between CrCl2 and K4Fe(CN)6 with varying concentrations of the reagents in aqueous and aqeous-alcoholic media. While evidence for the formation of both K2CrFe(CN)6 and Cr2Fe(CN)6 was obtained from the first two methods, the amperometric titrations gave evidence only for the formation of K2CrFe(CN)6. From the discrepancies in the titre values (theoretical and determined), evidence for the role of adsorption in influencing the composition is obtained. The titre values approach the theoretical when measurements are done in presence of alcohol.
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    Zeitschrift für anorganische Chemie 302 (1959), S. 17-36 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The systems TiS—Ti, TiSe—Ti, and TiTe—Ti have been investigated by X-ray analysis.The range of homogeneity of the TiX-phases in all these systems extends to the composition of TiX0.8. In the systems TiS—Ti and TiSe—Ti, a Ti3X2-phase with a limit composition of TiX0.5 follows, whereas in the tellurium system a Ti2Te-phase (limit composition TiTe0.25) occurs. In the case of both TiSe and TiTe, a new hexagonal modification has been manifested; furthermore, the TiSe-phase crystallizes in a third lattice being trigonal. These new modifications are the stable forms of the phases TiSe and TiTe representing overstructures of the NiAs-type. The structures of other phases are: \documentclass{article}\pagestyle{empty}\begin{document}$$ \begin{array}{l} {\rm Ti}_{\rm 3} {\rm S}_{\rm 2} \,\,{\rm WC - type;} \\ {\rm Ti}_{\rm 3} {\rm S}_{\rm 2} \,\,\,{\rm NiAs - type;} \\ {\rm Ti}_{\rm 2} {\rm Te}\,\,{\rm tetragonal}\,{\rm unknown}\,{\rm structure}{\rm.} \\ \end{array} $$\end{document}
    Notes: Es wurden die Systeme TiS/Ti, TiSe/Ti und TiTe/Ti röntgenographisch untersucht. Der Homogenitätsbereich der TiX-Phasen erstreckt sich in allen Systemen etwa bis zur Zusammensetzung TiX0,8. In den Systemen TiS/Ti und TiSe/Ti folgt eine Ti3X2-Phase mit einem Homogenitätsbereich bis zur Zusammensetzung TiX0,5, in dem System TiTe/Ti eine Ti2Te-Phase mit einem Homogenitätsbereich bis zur Zusammensetzung TiTe0,25. Die Löslichkeit der Chalkogene im Titanmetall nimmt zum Tellur hin stark ab.Bei der TiSe- und TiTe-Phase wurde außer der bereits bekannten NiAs-Form eine weitere hexagonal kristallisierende Modifikation festgestellt, bei der TiSe-Phase noch eine dritte trigonal kristallisierende. Beide neu gefundenen Modifikationen sind die stabilen Formen dieser Phasen und stellen Überstrukturen des NiAs-Typs dar. Die Ti3S2-Phase kristallisiert im WC-Typ, die Ti3Se2-Phase im NiAs-Typ und die Ti2Te-Phase in einer tetragonalen Struktur unbekannten Typs.
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  • 74
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    Zeitschrift für anorganische Chemie 302 (1959), S. 88-102 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On reaction of SbCl5 with NaOC2H5 salt-like compounds with cation co-ordination number 4 and anion co-ordination number 6 are formed: [SbCla(OC2H5)4-a] [SbClb(OC2H5)6-b]. In polar solvents these substances show electrolytical conductivity and their molecular weights in dilute solution prove complete dissociation into two particles. In nonpolar solvents the compounds are also dissolved but now in a molecular form SbClc(OC2H5)5-c. The latter solutions have no electrolytical conductivity. IR-spectra of the compounds in polar and nonpolar solutions are different from each other.
    Notes: Bei der Umsetzung von SbCl5 mit NaOC2H5 entstehen heteropolare Verbindungen mit 4fach koordiniertem Kation und 6fach koordiniertem Anion: [SbCla(OC2H5)4-a] [SbClb(OC2H5)6-b]. In polaren Lösungsmitteln zeigen diese Substanzen elektrolytische Leitfähigkeit und Molekulargewichte, die in verdünnter Lösung auf vollständige Dissoziation schließen lassen. In unpolaren Lösungsmitteln sind die Verbindungen in homöopolarer Form SbClc(OC2H5)5-c gelöst. Diese Lösungen zeigen nur sehr geringe Leitfähigkeit. Die Infrarotspektren der Verbindungen in polaren und unpolaren Lösungen unterscheiden sich stark voneinander.
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    Zeitschrift für anorganische Chemie 302 (1959) 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Zeitschrift für anorganische Chemie 299 (1959), S. 227-231 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The heat of reaction 2 La + 1,5 O2 = La2O3 was determined to 446 ± 2 kcal/Mol by measuring the heats of solution of La2O3 in 0,1 n HCl and comparing it with the heat of solution of La in 0,1 n HCl by BOMMER and HOHMANN. The older values of the heat of combustion were discussed and the mistake of the extreme value of Roth cleared up.The heat of hydratation 1/2 La2O3 + 1,5 H2O = La(OH)3 was determined to 20,2 ± 0,7 kcal/Mol by measuring the heat of solution of cristallised La(OH)3 in 0,1 n HCl.
    Notes: Die Bildungswärme von La2O3 wurde durch vergleichende Messung der Lösungswärmen von La2O3 und La in 0,1 n HCl zu 446 ± 2 kcal/Mol bestimmt und mit drei älteren direkten Messungen der Verbrennungswärme verglichen. Bei dem abnorm hohen Wert von ROTH (539) wurde eine Fehlerquelle nachgewiesen.Die Hydratisierungswärmen von La2O3 wurde durch vergleichende Messung der Lösungswärme von krist. La(OH)3 und La3O2 zu 20,2 ± 0,7 kcal/Mol bestimmt.
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    Zeitschrift für anorganische Chemie 299 (1959), S. 232-240 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: 1. Higher molecular siliconmethylene compounds have been prepared by thermic decomposition of Si(CH3)4. The composition of the reaction mixture relies on their stay period in the reaction tube. The experimental conditions of the forming of higher boiling and meltable silmethylene compounds are described.2. A number of compounds have been isolated from the reaction mixture, see „Inhaltsübersicht“. The common structure of the compounds has been found to consist of sixmembered rings which have a skeleton of alternate silicon and carbon atoms.
    Notes: 1. Aus Si(CH3)4 lassen sich durch thermische Zersetzung höhermolekulare Siliciummethylenverbindungen darstellen. Die Zusammensetzung der Reaktionsprodukte ist von ihrer Verweilzeit im Reaktionsgefäß abhängig. Es werden die experimentellen Bedingungen zur Darstellung höhersiedender und schmelzbarer Siliciummethylenverbindungen angegeben.2. Es wurden folgende Verbindungen aus dem Reaktionsgemisch isoliert. Si2C6H18, Si2C7H20, Si3C8H22, Si3C9H24, Si4C10H26, Si4C11H28, Si5C13H34, Si6C14H36, Si7C18H46, Si8C20H50, Si8C24H66, Si9C27H74. Die Si-Atome sind stets über je ein C-Atom verbunden. Das Gemeinsame im Aufbau der Verbindungen mit 3 und mehr Si-Atomen besteht darin, daß sie aus Sechsringen mit drei Si- und drei C-Atomen bestehen, die im Ring abwechselnd angeordnet sind.
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    Zeitschrift für anorganische Chemie 299 (1959), S. 252-270 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Fused antimony(III) chloride is a „water-like“ ionizing solvent for a considerable number of organic and inorganic compounds, especially for convalent ones.The specific conductivity of fused SbCl3 (in the range of 10-6 [Ohm-1 cm-1]) is increased by solving electrolytes. The proposed self-dissociation, (x + 1) SbCl3 ⇌ SbCl2+ + Cl- · x SbCl3, is discussed in regard to acid-base problems.The preparations of crystalline addition compounds are described.
    Notes: Das geschmolzene Antimon(III)-chlorid wird als ionisierendes Lösungsmittel in den Kreis der Solventien mit gewissen „wasserähnlichen“ Eigenschaften eingereiht.Es zeigt ein gutes Lösungsvermögen für viele organische Verbindungen. Von anorganischen Verbindungen ist ebenfalls eine beträchtliche Anzahl löslich; einige Salzgruppen sind weitgehend unlöslich.Kristallisierte Solvate sind sowohl von organischen als auch von anorganischen Verbindungen erhältlich. Eine Solvatation dieser Verbindungen in Lösung ist ebenfalls anzunehmen.Die elektrische Eigenleitfähigkeit des geschmolzenen Antimon(III)-chlorides in der Größenordnung von 10-6 Ohm-1 · cm-1 und der Anstieg der spezifischen Leitfähigkeit beim Auflösen von Elektrolyten in der Schmelze sowie der Verlauf dieser Leitfähigkeitskurven zeigen ein „wasserähnliches“ Verhalten des Solvens SbCl3 an. Die Eigenleitfähigkeit der Verbindung SbCl3 in geschmolzenem Zustande wird auf das folgende Dissoziationsschema zurückgeführt: (x + 1) SbCl3 ⇌ SbCl2+ + Cl- · x SbCl3.Danach sind, in Analogie zum Lösungsmittel Wasser, Verbindungen, die in Lösung die Konzentration der SbCl2+-Ionen erhöhen, Säurenanaloge; Verbindungen, welche die Konzentration der Cl--Ionen erhöhen, sind Basenanaloge. Das Verhalten solcher Verbindungen in geschmolzenem SbCl3 wird durch Leitfähigkeitsmessungen und kryoskopische Messungen untersucht.
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    Zeitschrift für anorganische Chemie 300 (1959), S. 261-274 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: An orange yellow substance the phosphorus content of which varies form 87 to 91 per cent is formed by oxidizing phosphorus vapour by atmospheric oxygen in the presence of water vapour. The compositions of the products with the lowest phosphorus content closely correspond to the formula P4nOnHn. Because of its insolubility in all common solvents and the chemical behaviour, the amorphous yellow solid is supposed to consist of a polymeric network of P-atoms to which OH-groups are fixed.When heated to 250-300°C in inert gas atmosphere the substance is decomposed to P(V)-compounds and products similar to red phosphorus. At normal atmosphere conditions it is slowly oxidized to H3PO2, H3PO3, and small amounts of H3PO4. In addition to PH3 and H2, the same hydroxy-acids are formed by treating the substance with cold N NaOH. Complete oxidation is achieved in aqueous suspension by means of hypoiodite yielding among others considerable amounts of the same very slightly soluble alkali“ ts of an acid of lower-valent phosphorus recently described by Blaser
    Notes: Bei der Oxydation von Phosphordampf mit Luftsauerstoff bildet sich in Gegenwart von Wasserdampf ein orangegelbes Produkt, dessen Phosphorgehalt zwischen 87 und 91% schwankt. Die Zusammensetzung der Produkte mit dem niedrigsten Phosphorgehalt kommt der Formel P4nOnHn nahe. Die Eigenschaften dieser Substanz wurden untersucht und mit denen des roten und des Schenckschen Phosphors verglichen. Auf Grund des physikalischen und chemischen Verhaltens wird vermutet, daß der erhaltene gelbe Stoff aus einem polymeren Netzwerk von Phosphoratomen aufgebaut ist, an welche OH-Gruppen gebunden sind.Die dargestellte Substanz ist amorph und in allen gebräuchlichen Lösungsmitteln unlöslich. Sie zersetzt sich bereits langsam an der Luft unter Oxydation zu H3PO2, H3PO3 und wenig H3PO4. Beim Erhitzen unter Inertgas auf 250 - 300°C zerfällt sie in P(V)-Verbb. und Produkte mit Phosphorgehalten über 90%, die mit steigendem P-Gehalt dem roten Phosphor immer ähnlicher werden. Behandeln der Substanz mit 1 n NaOH führt zur Zersetzung, wobei PH3, H2, H3PO2, H3PO3 und wenig H3PO4 gebildet werden. Durch Hypojodit erfolgt in wäßriger Aufschlämmung vollständige Oxydation, wobei unter anderem in beträchtlicher Menge schwerlösliche Alkalisalze einer Säure des Phosphors mit niederwertigem Phosphor gebildet werden. Diese Salze sind identisch mit den kürzlich von Blaser1) bei der Oxydation von rotem Phosphor mit Brom in alkalischem Medium erhaltenen Verbindungen.
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    Zeitschrift für anorganische Chemie 300 (1959), S. 288-294 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: According to recent investigations binuclear complexes are formed on treating chromium carbonyl with alkali. Methanolic alkali hydroxide leads to a product containing methoxyl groups, whereas with ethanolic alkaline solutions the alcohol-free K2[(CO)3Cr(OH)3Cr(CO)3H] is produced. The proposed structure is consistent with conductivity and magnetic measurements, potentiometric titrations in aqueous and non-aqueous solvents, as well as with its chemical behaviour. Former interpretations have to be corrected according to this paper.
    Notes: Nach neueren Untersuchungen entstehen bei der Basenreaktion des Chromhexacarbonyls 2 kernige Komplexe. Im methanol-alkalischen System erhält man ein methoxylhaltiges Produkt, während in Äthanol-Alkalilauge ein alkohol-freies Dikalium-hydrogen-hexacarbonyl-m̈-triol-dichromat(0), K2[(OC)3Cr(OH)3Cr(CO)3H], gebildet wird. Die Konstitution dieser Verbindungen wurde durch Leitfähigkeit, chemisches Verhalten, IR-Spektren und magnetische Messungen, sowie durch Titration in wäßrigem und wasserfreiem Medium gestützt. Eine frühere Formulierung für das Basenreaktions-produkt ist entsprechend zu revidieren.Mit Äthylendiaminhydrat erhält man aus den 2 kernigen Chromtricarbonyl-Verbindungen eine Substanz vom Tricarbonyltriammin-Typ.
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  • 81
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    Zeitschrift für anorganische Chemie 300 (1959), S. 275-287 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: [Fe(CO)4]2- reacts with compounds of arsenic, anitmony, and bismuth producing non-ionogenic iron carbonyl compounds, such as As2Fe3(CO)11, SbFe2(CO)8, and Bi2Fe5(CO)20. Similar reactions with tin, lead and thallium salts lead to the following intensively coloured complexes Sn2Fe5(CO)20, PbFe3(CO)12 and Tl2Fe3(CO)12.On the basis of infrared and magnetic susceptibility measurements the configuration of the compounds mentioned above is discussed. Linear structures result for the paramagnetic As2Fe3(CO)12 and SbFe(CO)8, whereas for the other compounds a centric configuration is proposed.
    Notes: Mit Verbindungen des Arsens, Antimons und Wismuts, vorwiegend in ihrer dreiwertigen Form, reagiert Tetracarbonylferrat unter Bildung nichtionogener Eisencarbonyl-verbindungen verschiedenartigen Bautyps, nämlich As2Fe3(CO)11, SbFe2(CO)8, SbFe(CO)4 sowie Bi2Fe5(CO)20. Entsprechende Umsetzungen mit Zinn-, Blei- und Thalliumsalz-Lösungen führen zu den tieffarbigen Komplexen Sn2Fe5(CO)20, PbFe3(CO)12 und Tl2Fe3(CO)12. Die in polaren Solventien gut löslichen Substanzen sind thermisch wie gegenüber Oxydationsmitteln wesentlich empfindlicher als die Eisencarbonylchalkogenide.Auf Grund IR-spektroskopischer und magnetischer Untersuchungen werden Strukturfragen erörtert. Lediglich die Verbindungen As2Fe3(CO)11 (I) und SbFe2(CO)8 (II) sind paramagnetisch; das „μ pro As“ von I stimmt mit dem μ von II überein. Daraus ergeben sich lineare Strukturen, während in anderen Fällen, wie bei der Bi-oder Sn-Ver-bindung, auch eine mehr zentrische Konstitution - in jedem Fall mit endständigen CO-Gruppen - zu diskutieren ist.
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  • 82
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 300 (1959), S. 304-310 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The reaction of tungsten carbonyl with alkali leads to the formation of an anion, the tungsten atoms being partially reduced and carrying a formal negative charge. With methanolic alkali a mixture of [W2(CO)6(OH)2(CH 3OH)2]2- and [W2(CO)6(OH)2(CH 3OH)2]1- results at 100° C, whereas at 130° C [w3(CO)9(OH)(OCH3)(CH3OH)]3- is formed. With ethanolic potassium hydroxide, however, at 100° C and above the corresponding alcohol free products result.
    Notes: Zum Unterschied von den bereits eingehend untersuchten Reaktionen des Chrom-, Molybdän- und Rheniumcarbonyls mit Alkalihydroxyd, die zu Reaktionsprodukten mit der Oxydationsstufe 0 oder +1 des Carbonylmetalls führen, hat man es bei den entsprechenden Reaktionen des Wolframcarbonyls mit einer teilweisen Reduktion unter Bildung eines Anions zu tun, in dem den Wolframatomen ein negativer Oxydationswert zukommt. Während bei 100° aus Methanol/KOH ein Gemisch von Hexacarbonyl-m̈-diol-dimethanol-diwolframat(0) und (-II) entsteht, bilden sich bei 130° im gleichen System 3kernige Enneacarbonyltriwolframate mit komplex gebundenem Methanol. Äthanol/Kalilauge reagiert hingegen mit W(CO)6 bei 100° und bei höherer Temperatur unter Bildung der gleichen 2kernigen alkoholfreien Verbindung. Aus den Lösungen der 2kernigen Basenreaktionsprodukte läßt sich das Wolfram(0) in Form des Tricarbonyltriammin wolframs nahezu quantitativ ausfällen.
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  • 83
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    Zeitschrift für anorganische Chemie 300 (1959), S. 295-303 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On treating molybdenum carbonyl with alcoholic KOH at higher temperatures binuclear hexacarbonyl-m̈-triol-dimolybdates(0) are formed. Using methanolic potassium hydroxide one of the OH groups is substituted by OCH3. Contrary to chromium carbonyl in this typical substitution reaction no hydrogen is evolved; carbon monoxide is converted into formiate. Precipitation, conductivity, infrared spectra, diamagnetism, and potentiometric titration are in agreement with the proposed structure of the binuclear complex.[Mo2(CO)6(OH)3H3] results by reaction of the m̈-triol-compound with two equivalents of acid. This hydride being a strong acid in aqueous solution forms secondary salts with potassium- and tetramethylammonium hydroxide. Complexing agents such as triphenylphosphine and- arsine or dimethylsulfoxide react with the hydride under formation of the corresponding tri-substitution products.
    Notes: Die Basenreaktion des Molybdänhexacarbonyls führt unter Verwendung von alkoholischen Kalilaugen bei höherer Temperatur zu 2kernigen Hexacarbonyl-m̈-trioldimolybdaten(0), wobei im Falle des aus Methanol anfallenden Produktes eine OH-Gruppe durch OCH3 ersetzt ist. Die Reaktion spielt sich zum Unterschied von derjenigen des Cr(CO)6 ohne Wasserstoffentbindung ab und stellt somit eine reine Substitutionsreaktion dar; das CO reagiert wiederum unter Formiatbildung. Durch Fällungsreaktionen, Leitfähigkeit, IR-Spektren, Diamagnetismus und Titration wird die Struktur der 2kernigen Komplexe, die mit wäßrigem NH3 und Aminen nichtionogene Verbindungen vom Tricarbonyltriammin-Typ liefern, sichergestellt.Durch Umsetzungen der alkoholfreien m̈-Triolverbindung mit dem doppelten Säureäquivalent gewinnt man ein Trihydrogen-hexacarbonyl-m̈-triol-dimolybdän(0), das in wäßriger Lösung als starke Säure fungiert und ein Dikalium- sowie ein Bis-[tetramethylammonium]-salz zu bilden vermag. Komplexbildner, wie Triphenylphosphin, -arsin und Dimethylsulfoxyd reagieren mit dem Hydrid unter Bildung der entsprechenden Trisubstitutionsprodukte, Mo(CO)3X3, mit Triphenylphosphinoxyd entsteht nur noch die Verbindung mit 1 Mol Basenoxyd, Mo(CO)3OPR3.
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  • 84
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    Zeitschrift für anorganische Chemie 301 (1959), S. 1-6 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The alterations of surface during double decompositions in solid state and spinel formation have been investigated by means of the BET-method.
    Notes: Die Veränderungen der Oberfläche im Verlauf der doppelten Umsetzung im festen Zustand und der Doppeloxydbildung wurden durch die Bestimmung der Oberflächengröße mittels physikalischer Adsorption (BET-Methode) untersucht.
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  • 85
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    Zeitschrift für anorganische Chemie 301 (1959), S. 36-53 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: K[AsF5OH] and K[AsF4(OH)2] are thermally decomposed yielding chain-like and net-like polyfluoroarsenates, respectively, by exclusive liberation of HF. The decompositions are discussed in regard to hydrogen bonds between OH-groups and F-atoms in the starting salts.Polymeric fluoroarsenates are very slowly hydrolyzed even in boiling 0.1 n KOH. The fluorine atoms linked to arsenic are hindering the hydrolytic cleavage of As—O—As-bonds. The hydrolysis has been investigated titrimetrically and by paper chromatography using 76As as radioactive indicator.The salts K[AsF4(OH)2], K[AsF5(OH)], and K[AsF6] are not isomorphous because of differing or lacking systems of hydrogen bonds.
    Notes: Bei der thermischen Behandlung gehen die Salze K[AsF5OH] und K[AsF4(OH)2] unter praktisch ausschließlicher HF-Abspaltung in kettenförmige bzw. überwiegend flächenförmig vernetzte Polyfluoroarsenate über. Die Reaktion wird zurückgeführt auf die in den Kristallen vorhandenen Wasserstoffbrückenbindungen zwischen OH-Gruppen und F-Atomen. Infolge verschiedener bzw. fehlender Wasserstoffbrückenbindungssysteme sind die Salze K[AsF4(OH)2], K[AsF5OH] und K[AsF6] nicht miteinander isomorph. Polymere Fluoroarsenate hydrolysieren selbst in siedender Lauge nur langsam. Fluoratome am Arsen schirmen die As—O—As-Bindungen gegenüber hydrolytischen Einflüssen wirksam ab. Die Hydrolyse der Polyfluoroarsenate wurde titrimetrisch und papierchromatographisch unter Zuhilfenahme von 76As untersucht.
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  • 86
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 298 (1959) 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 87
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    Zeitschrift für anorganische Chemie 298 (1959), S. 116-120 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The influence of crystallisation conditions upon the temporary triboluminescence of Arsenoliths has been examined.The experimental results show increasing activity of triboluminescence with decreasing velocity of growth and increasing temperature of growth respectively. This can be explained by assuming a concentration dependent formation of claudetite or hydroxyl within the crystal during the growth process.
    Notes: Es wird der Einfluß von Kristallisationsbedingungen auf die temporäre Tribolumineszenz des Arsenoliths untersucht. Die Versuchsergebnisse (zunehmende Tribolumineszenz-Aktivität mit abnehmender Wachstumsgeschwindigkeit und zunehmender Wachstumstemperatur) lassen sich an Hand eines konzentrationsbedingten Einbaus von claudetit-artigen Bereichen oder OH-Gruppen im Kristall deuten.
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  • 88
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    Zeitschrift für anorganische Chemie 298 (1959), S. 212-222 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The infrared and Raman-Spectra of (H3Si)3N are reported and the frequencies are assigned as for as possible. The valence force constant of the Si—N-bond is calculated to 4,1 mdyn/Å from the frequencies of the skeletal ≡Si3N. From this value it is seen, that the Si—N-bonds are inforced because the lone pair of electrons is involved. This strengthening of the bonds and the character of the whole spectrum make probable a planar or nearplanar structure of the ≡Si3N-skeletal.
    Notes: Das IR- und Raman-Spektrum des (H3Si)3N wird mitgeteilt; die Frequenzen wurden soweit als möglich den einzelnen Schwingungsformen zugeordnet. Aus den Frequenzen des Gerüstes ≡ Si3N wird die Valenzkraftkonstante für die Si—N-Bindung zu 4,1 mdyn/Å berechnet. Dieser Wert zeigt, daß die Si—N-Bindungen durch die Einbeziehung des freien Elektronenpaares am Stickstoff verstärkt sind. Diese Bindungsverstärkung und der allgemeine spektrale Habitus sprechen für eine ebene oder fast ebene Struktur des ≡Si3—N-Gerüstes.
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  • 89
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    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 298 (1959) 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 90
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    Zeitschrift für anorganische Chemie 298 (1959), S. 255-257 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Es wird dargelegt, daß die Vermutung einer fünften Modifikation des CaC2 auf einer irrtümlichen Deutung der Röntgenaufnahmen beruht. Angaben der Literatur über das Molekularvolumen von Kupferacetylid werden angezweifelt.
    Notes: A brief review of the literature is given. It is demonstrated that a recent suggestion regarding the alleged existence of a fifth crystal modification of calcium carbide was based on an erroneous interpretation of an X-ray pattern. Doubt is also expressed as to a suggested molar volume for cuprous acetylide.
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  • 91
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    Zeitschrift für anorganische Chemie 299 (1959), S. 292-296 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Telluric acid reacts with pyrocatechol both in aqueous solution and, partially, in fused state forming a very difficultly soluble Te(IV)-compound the structure of which, Te , has been confirmed by thermogravimetric and IR-spectrometric investigations.
    Notes: Es wird gezeigt, daß Tellursäure mit Brenzcatechin in wäßriger Lösung eine sehr schwer lösliche, kristallisierbare Te(IV)-Verbindung bildet, die nach thermogravimetrischen Untersuchungen die Struktur Te besitzt. Die thermischen Zersetzungsreaktionen dieser Verbindung werden diskutiert. Das IR-Spektrum des Chelates wird mit den Spektren des Brenzcatechins und der Tellursäure verglichen. Ferner werden die thermogravimetrischen Kurven von Tellursäure und Brenzcatechin dargestellt. Es konnte weiterhin thermogravimetrisch beobachtet werden, daß Tellursäure und Brenzcatechin auch in der Schmelze miteinander reagieren und geringe Mengen der erwähnten Te(IV)-Verbindung bilden.
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  • 92
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    Zeitschrift für anorganische Chemie 299 (1959), S. 297-301 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: After exposing white phosphorus to a pressure of 26000 kg/cm2 at room temperature for 33 days, the transition point for the conversion into black phosphorus at the same pressure is lowered from 158 to 142° C. By analogous preliminary treatment at about -43° C no depression is achieved.The effect of depression is discussed in regard to formation of crystallization nuclei.
    Notes: Nach den Untersuchungen über Druck-Temperaturumwandlungen des weißen Phosphors in schwarzen(1) wird die Frage nach dem Charakter dieser Umwandlung angeschnitten.Unter Benutzung einer Druckapparatur, die wochenlange Belastung mit 26000 kgcm-2 im Temperaturbereich von -40° bis -50° C ermöglicht, wird folgendes festgestellt:Der mit 26000 kgcm-2 während 33 Tagen im genannten tiefen Temperaturbereich belastete weiße Phosphor zeigt bei nachfolgender Aufheizung gegenüber einem nicht vorbehandelten Präparat keine Erniedrigung der Umwandlungstemperatur.Das unter Zimmertemperatur bei gleichem Druck 33 Tage lang vorbehandelte Material zeigt bei anschließender Aufheizung der Matrize eine Erniedrigung des Umwandlungspunktes um 15 Celsiusgrade. Somit ist eine Keimbildung in Richtung der schwarzen Modifikation innerhalb der Vorbehandlungszeit bei Zimmertemperatur anzunehmen, die bei der tiefen Temperatur nicht stattfindet.
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  • 93
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    Zeitschrift für anorganische Chemie 299 (1959), S. 316-321 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The absorption spectra of some cyclocarbosilanes have been measured in the range from 1000 to 200 mμ. Increasing molecular weight of the silicon compounds causes a steady shift of the absorption spectra to longer wave lengths. The colour of the silicon compounds is not effected by coloured organic impurities. It is a property of the substances.The solutions of the silicon compounds do not show the Tyndall effect.
    Notes: Es werden die Absorptionsspektren einiger Cyclocarbosilane im Bereich von 1000 bis 220 mμ gemessen. Mit steigendem Molekulargewicht der Siliciumverbindungen tritt eine gleichmäßige Verschiebung des Absorptionsspektrums zum längerwelligen Gebiet hin auf. Die Farbe der Siliciumverbindungen ist nicht durch farbgebende organische Verunreinigungen bedingt. Sie ist ein substanzeigenes Merkmal.Die Lösungen der Siliciumverbindungen zeigen keinen TYNDALL-Effekt.
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  • 94
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    Zeitschrift für anorganische Chemie 299 (1959), S. 302-315 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: 1. The hydrolysis of the Si-H group of Si7C18H46 has been investigated in alkali. The Si-H group of these compounds cannot be hydrolysed under normal conditions. This is due to steric effects. The behaviour of the Si-H group confirms the proposed structure.2. The Si-H group of Si7C18H46 can be transformed into a Si-Cl group by photochemical chlorination. Si7C18Cl16H30 is formed. The basic structure of Si7C18H46 is left intact. The chlorine which can be hydrolysed in acid solution corresponds to one Si-Cl bond or to one Si-H bond, respectively, in the compound Si7C18H46.The degree of chlorination which is represented by the compound Si7C18Cl16H30, is favored. IF the time of chlorination is increased from five to nine hours no further chlorine is absorbed. This is due to steric effects. The chlorination of Si7C18H46 gives evidence to the structure of Si7C18H46.3. The results of a cristallographic investigation of Si4Cl11H28 are discussed in connection with the structural formula.
    Notes: 1. Es wird die Hydrolyse der Si-H-Gruppe im Si7C18H46 und Si8C20H50 im alkalischen Medium untersucht. Die Si-H-Gruppe in diesen Verbindungen ist aus sterischen Gründen unter normalen Bedingungen der Hydrolyse nicht zugänglich. Das Verhalten der Si-H-Gruppe bestätigt die angegebene Strukturformel.2. Die Si-H-Gruppe im Si7C18H46 läßt sich über eine Photochlorierung in die Si-Cl. Gruppe überführen. Es bildet sich Si7C18Cl16H46 bleibt erhalten. Das im Si7C18Cl16H30 in saurer Lösung abspaltbare Chlor entspricht einer Si-Cl-Bindung und damit einer Si-H-Bindung im Si7C18H46.Die Chlorierungsstufe im Si7C18CL16H30 ist bevorzugt; denn eine Erhöhung der Chlorierungsdauer von 5 auf 9 Stunden bedingt keine weitere Chloraufnahme. Das ist sterisch bedingt. Die Chlorierung des Si7C18H46 ermöglicht Aussagen über die Strukturformel des Si7C18H46.3. Es werden die Ergebnisse der kristallographischen Untersuchung am Si4C11H28 im Zusammenhang mit der Strukturformel diskutiert.
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  • 95
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    Zeitschrift für anorganische Chemie 299 (1959), S. 322-327 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Es werden die Ergebnisse von Untersuchungen über die Komplexbildung zwischen CuCl und HCl bzw. KCl in Lösung und im Bodenkörper mitgeteilt. Zur Konzentrationsbestimmung der Komponenten im Bodenkörper wird eine indirekte Methode benutzt. Im System CuCl—HCl liegen in Lösung die Komplexe H2CuCl3 und H3CuCl4 vor, analoge Komplexe finden sich in Lösung im System CuCl—KCl, während im Bodenkörper KCuCl2 und K2CuCl2 vorliegen.
    Notes: Investigations have been carried out to determine the complex ion formation between cuprous chloride and hydrochloric acid and cuprous chloride and potassium chloride in the aqueous and solid phase. An indirect method to determine the concentration of the components in the solid phase was employed due to the highly oxidisable nature of cuprous ions. Rectangular curves were drawn. In the case of hydrochloric acid, complexes like H2CuCl3 and H3CuCl4 are formed in the liquid phase while H2CuCl3; H3CuCl4 are formed in the solid phase. For potassium chloride, complexes like K3CuCl4 and K2CuCl3 were found to exist in the aqueous phase and KCuCl2 and K2CuCl3 were obtained in the solid phase. The amount of cuprous chloride going into solution with increasing amount of KCl was found to be lesser for HCl under identical conditions.
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  • 96
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    Zeitschrift für anorganische Chemie 299 (1959), S. 338-340 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: A manganometric method for the determination of cobalt in commercial cobalt powder has been elaborated and checked by gravimetric methods.
    Notes: Eine früher beschriebene(1) maßanalytische Methode wurde auf Kobaltpulver angewendet, das einige Schwierigkeiten bietet. Durch gewichtsanalytische Bestimmungen einerseits durch Reduktion, andererseits durch Oxydation der Pulver wurde ein Vergleich geschaffen.
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  • 97
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    Zeitschrift für anorganische Chemie 300 (1959), S. 102-108 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Fluoroberyllate und saure Fluoroberyllate des dreiwertigen Chroms konnten dargestellt werden, sie sind den entsprechenden Alaunen ähnlich. Diese Fluoroberyllate sind violett gefärbt, es bilden sich jedoch rasch, vor allem bei erhöhter Temperatur, grün gefärbte Komplexe. Entsprechende Verbindungen des Aluminiums oder Eisens konnten nicht dargestellt werden, da diese Ionen sehr beständige komplexe Fluoride bilden.
    Notes: The present investigation has been successful in the preparation of trivalent complex chromic fluoberyllate. The preparation and properties of an acid chromic fluoberyllate alum and its dehydrated product acid chromic fluoberyllate dihydrate together with a violet rubidium chromium alum, analogous to corresponding sulphate compounds have been studied. The main difficulty encountered in the preparation of fluoberyllates of other trivalent elements was due to unique stability of the complex fluorides of the said trivalent metals. The fluoberyllate alums of the chromium are violet in colour, but it rapidly changes to green with time and also with the increase in temperature.
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  • 98
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    Zeitschrift für anorganische Chemie 300 (1959), S. 109-112 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Durch Umsatz von Äthylendiamin, Propylendiamin und Hexamethylentetramin mit Zink- bzw. Cadmium-Fluoroberyllat konnten die komplexen Fluoberyllate mit diesen organischen Basen als Liganden dargestellt werden. Die Eigenschaften dieser Verbindungen sind denen der entsprechenden komplexen Sulfate ähnlich.
    Notes: A few complex compounds of zinc and cadmium fluoberyllates with organic base were prepared. [Zn en3]BeF4 and [Cd en3]BeF4 were prepared by the addition of a concentrated solution of ethylenediamine to the concentrated solution of metal fluoberyllates. [Zn pn3]BeF4 was also isolated. The corresponding cadmium compound, however could not be prepared. ZnBeF4, C6H12N4, 8 H2O and CdBeF4, C6H12N4, 8 H2O were also prepared by following similar methods. In chemical compositions and also in their chemical properties these compounds resembles the corresponding sulphate compounds.
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  • 99
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 300 (1959), S. 98-101 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Durch Versetzen einer konzentrierten Lösung von Ammoniumfluoroberyllat mit Äthylendiamin, Propylendiamin bzw. Benzidin werden die Fluoroberyllate der betreffenden Basen in kristallisierter Form hergestellt; diese Salze sind beständig. Benzidinfluoroberyllat ist entsprechend dem Benzidinsulfat unlöslich in Wasser. Nach Ausweis der Röntgendiagramme sind Äthylendiaminfluoroberyllat und Äthylendiaminsulfat isomorph. Die thermische Stabilität des Äthylenfluoroberyllats wird thermogravimetrisch untersucht.
    Notes: Fluoberyllates of organic bases have been prepared. Ethylene diamine fluoberyllate NH2 · CH2 · CH2 · NH2, H2BeF4, propylenediamine fluoberyllate NH2 · CH · (CH3) · CH2 · NH2, H2BeF4 and benzidine fluoberyllate NH2 · C6H4 · C6H4 · NH2, H2BeF4 were prepared by the addition of these organic bases on a concentrated solution of ammonium fluoberyllate. These crystalline compounds were found to be stable. Benzidine fluoberyllate like benzidine sulphate is insoluble in water. The X-ray diffraction spectra of ethylene-diamine fluoberyllate and ethylene-diamine sulphate were taken and these compounds were proved to be isomorphous. The thermal stability of ethylene diamine fluoberyllate has also been studied.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 100
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 300 (1959) 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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