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  • Elsevier  (503,396)
  • International Union of Crystallography (IUCr)
  • 2020-2022  (303,302)
  • 1980-1984  (203,451)
  • 1930-1934
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Year
  • 1
    Publication Date: 2020-10-07
    Description: Vulcano is one of the 7 volcanic islands and 6 seamounts forming the Aeolian volcanic district (Italy). Vulcano has a long eruptive record, and its last eruption (1888–90 AD) originated the definition of the Vulcanian eruptive style. Like most volcanic islands, Vulcano generates many potentially interconnected hazards, determining a potentially high risk. Here, we review the state of knowledge on its geology, eruptive activity, historical accounts, structural setting, geophysical and geochemical surveillance, and available hazard assessment, in order to have an updated picture of the state knowledge on volcanic hazard. We follow a prototypal reviewing scheme, based on three standardized steps: i) review of the volcanic system; ii) review of available eruptive and noneruptive hazard quantifications; iii) development of a conceptual interpretative model. We find that, while a rather vast literature is dedicated to the volcanic system of Vulcano and the reconstruction of past events, few quantitative hazard assessments exist. In addition, the range of natural variability considered for each hazard is potentially underestimated (e.g. limited range of considered eruption magnitude and style and of vent position), as it is the potential effect of multi-hazard impact. The developed conceptual model for the feeding system provides a synthetic picture of the present knowledge about the system, as emerged from the review. In addition, it allows for the identification of potential paths-to-eruption and provides a first order link among the main hazards. This review provides an up-to-date snapshot of existing knowledge on volcanic hazard at Vulcano on which to build future hazard quantifications as well as to support present and future decision making.
    Description: Published
    Description: 103186
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2020-10-16
    Description: Dikes and sills are the moving building blocks of the plumbing system of volcanoes and play a fundamental role in the accretionary processes of the crust. They nucleate, propagate, halt, resume propagation, and sometimes change trajectory with drastic implications for the outcome of eruptions (Sigmundsson et al., 2010). Their dynamics is still poorly understood, in particular when different external influencing factors are interacting. Here we apply a boundary element model to study dike and sill formation, propagation and arrest in different scenarios. We model dikes as finite batches of compressible fluid magma, propagating quasi-statically in an elastic medium, and calculate their trajectories by maximising the energy release of the magma-rock system. We consider dike propagation in presence of density layering, of density plus rigidity layering, of a weakly welded interface between layers, under the action of an external stress field (of tectonic or topographic origin). Our simulations predict sill formation in several situations: i) when a horizontal weak interface is met by a propagating dike; ii) when a sufficiently high compressive tectonic environment is experienced by the ascending dike and iii) in case a dike, starting below a volcanic edifice, propagates away from the topographic load with a low dip angle. We find that dikes halt and stack when they become negatively buoyant and when they propagate with low overpressure at their upper tip toward a topographic load. Neutral buoyancy by itself cannot induce dikes to turn into sills, as previously suggested.
    Description: Published
    Description: 39-50
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2021-01-11
    Description: Surface tension plays an important role in the nucleation of H2O gas bubbles in magmatic melts and in the time-dependent rheology of bubble-bearing magmas. Despite several experimental studies, a physics based model of the surface tension of magmatic melts in contact with H2O is lacking. This paper employs gradient theory to develop a thermodynamical model of equilibrium surface tension of silicate melts in contact with H2O gas at low to moderate pressures. In the last decades, this approach has been successfully applied in studies of industrial mixtures but never to magmatic systems. We calibrate and verify the model against literature experimental data, obtained by the pendant drop method, and by inverting bubble nucleation experiments using the Classical Nucleation Theory (CNT). Our model reproduces the systematic decrease in surface tension with increased H2O pressure observed in the experiments. On the other hand, the effect of temperature is confirmed by the experiments only at high pressure. At atmospheric pressure, the model shows a decrease of surface tension with temperature. This is in contrast with a number of experimental observations and could be related to microstructural effects that cannot be reproduced by our model. Finally, our analysis indicates that the surface tension measured inverting the CNT may be lower than the value measured by the pendant drop method, most likely because of changes in surface tension controlled by the supersaturation.
    Description: Published
    Description: 113-127
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2021-01-04
    Description: This paper reports the analysis of soil 222Rn data recorded over 7-years in the volcanic caldera of Campi Flegrei (Naples-Italy). The relationship between Radon activity concentration and several geophysical, geochemical and meteorological parameters, influencing the gas emissions, is estimated by the Artificial Neural Network (ANN) method. The analysis goals are: the estimation (replication) of the Radon time series from influencing parameters, the forecasting of an unknown part of it, and the search for anomalies. Results prove: (i) the effectiveness of the ANN method; (ii) Radon follow the periods of agitation of the caldera, demonstrated by the comparison with previous works using different methods.
    Description: Published
    Description: 109239
    Description: 6IT. Osservatori non satellitari
    Description: JCR Journal
    Keywords: Anomaly detection; Artificial neural network; Influencing parameter; Radon; Signal forecasting; Signal replication
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
    Publication Date: 2021-01-08
    Description: In their comments Bonini et al. argue that our seismotectonic interpretation of the Emilia 2012 seismic sequence does not agree with observations, and follow three lines of arguments to support their statement. These concern the structural interpretation of seismic reflection profiles, the relationship between seismogenic sources and seismicity patterns, and the fit of inferred fault geometry to InSAR observations. These lines of arguments are mostly repeating what has been previously presented by the same authors, and none of them, as discussed in detail in our reply, presents a strong case against our structural interpretation, that, we are convinced, does not conflict with the available data. The two adjacent rupture surfaces outlined by accurately relocated aftershocks are an indication of the presence of two different active fault planes. Interpretation of seismic profiles supports seismological observation and indicates the occurrence of relevant along-strike changes in structural style. These pieces of information have been integrated to build a new seismotectonic interpretation for the area of the Emilia 2012 seismic sequence. Analysis of geodetic data from the area of the Emilia earthquakes has produced very different models of the fault planes; unlike what has been stated by Bonini et al., who see a difficult fit to InSAR data for the fault planes we have identified, the most recent results are consistent with our interpretation that see a steep fault in the upper 8–10 km under the Mirandola anticline. We point out that the geological structures in the subsurface of the Ferrara Arc do change along strike, and the attempt of Bonini et al. to explain both the May 20 and May 29 sequences using a single cross section is not appropriate.
    Description: Published
    Description: 157-162
    Description: 1T. Struttura della Terra
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2021-01-04
    Description: Seismic microzonation represents a basic tool for prevention activity planning and land management. An extensive and detailed microzonation study was performed with reference to the territory of the Municipality of Cavezzo, damaged during the seismic sequence hitting Emilia-Romagna Region, Northern Italy, in 2012. In this paper, we discuss the work carried out to characterize the spatial variability of ground motion amplification due to local soil conditions in the municipality area. An inter- and multi-disciplinary approach is presented, involving geotechnical engineers, geophysicists, geologists and seismologists from different institutions, to thoroughly characterize the territory using complementary techniques with different level of resolution and confidence. A considerable amount of geomorphological, geological, hydrogeological, seismological, geotechnical and geophysical investigations was collected and processed for the purpose. A GIS-based (Geographic Information System) platform was initially setup to manage the gathered data, which now includes the results of about 1000 geotechnical and geophysical tests. Such an extended dataset was then used as a primary constraint for the creation of a comprehensive pseudo-3D geotechnical and seismo-stratigraphic model of the territory, consisting of a dense grid of one-dimensional vertical profiles to depict the variability of the soil properties over the area. The model was finally used as input for linear-equivalent ground response analysis. For the calculation of the amplification factors, special emphasis was given to the treatment and propagation of the uncertainties of the model parameters, whose different realizations have been accounted through a logic tree approach.
    Description: Published
    Description: 105722
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
    Publication Date: 2021-01-07
    Description: The largest earthquake in the Zagros Mountains struck the city of Azgeleh on the Iran–Iraq border on 12 November 2017. This Mw 7.3 earthquake was followed by an intense seismic sequence. Implementing the double-difference earthquake location technique, we relocate 1069 events recorded by our local seismic network, deployed after the mainshock. The spatial distribution of the epicenters indicates linear alignments of the events nucleated along at least four notable clusters. The clusters are characterized by at least one significant earthquake, such as the Tazehabad earthquake of 25 August 2018 (Mw 5.9) along a dense, east–west trending cluster and the Sarpol-e Zahab earthquake of 25 November 2018 (Mw 6.3) along the cluster with a northeast–southwest trend. We use two-pass differential SAR interferometry (DInSAR) and Small BAseline Subset (SBAS) methods to study the coseismic permanent displacements of the Azgeleh, Tazehabad and Sarpol-e Zahab events as well as the one-year postseismic deformation field of the 2017–2018 seismic sequence, respectively. We use non-linear and linear optimization algorithms to derive the source geometry and the slip distribution along the fault planes. The inversion is conducted by introducing also seismological constraints, leading to the definition of a listric geometry for the Azgeleh mainshock rupture that accommodates the slip area at depth of 10–16 km along a sub-horizontal plane (dipping ~3°) and a low-angle (~16°) ramp. The thrust and dextral movements along this NNW-striking (~345°) fault have triggered a tear fault responsible for the Tazehabad event ruptured an east–west trending (~267°), north-dipping (~78°) sinistral shear fault. We present the dextral slip distribution of the Sarpol-e Zahab event along a NE-striking (~34°) fault, as a synthetic Riedel structure for the southern segment of the Khanaqin fault, dipping 63° to the southeast. We find the postseismic deformation field associated with the seismic sequence is not confined only to the mainshock source (the Azgeleh fault), but also develops along the Tazehabad and Sarpol-e Zahab faults. We additionally propose afterslip along a duplex, flat-ramp-flat structure down-dip and up-dip of the Azgeleh coseismic slip area. The up-dip afterslip develops onto the shallow detachment (~3°) at depth of ~8 km and the down-dip afterslip propagate onto the mid-crustal décollement level within the Pan-African basement. The Azgeleh, Tazehabad, Sarpol-e Zahab and Khanaqin faults mark the Lurestan Arc–Kirkuk Embayment sharp margin in the Northwest Zagros and play a key role in the lateral escape of the Lurestan Salient and vertical strain partitioning in the Zagros front.
    Description: Published
    Description: 112224
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
    Publication Date: 2021-01-07
    Description: Reducing the impact of volcanic eruptions on society is a major challenge of volcanology. Although science is one basic component of risk reduction, the achievement of this goal requires competencies that go beyond natural sciences. Nowadays, the importance of non-scientific factors in reducing volcanic risks is often and dangerously overlooked, possibly leading to decision making that cannot be rationally justified. In this paper we explore the basic components of an ideal decision-making process, identifying the roles and responsibilities of the different partners/tasks that are involved. In particular, we advocate the use of the hazard/risk separation principle, which can help discern unambiguously the role of volcanology (and more in general of science) in the whole risk-reduction process. Although this distinction may be of low relevance in some real cases—for example, when the costs of mitigation actions are low and the likelihood of eruption is high—it becomes of paramount importance when dealing with high uncertainty on the eruption onset or size and expensive mitigation actions, such as the evacuation of a large city. Volcanologists can play different roles in the decision-making process, but they have to be aware that this demands competencies that go beyond being a good volcano scientist. The final intent of this paper is to encourage constructive cooperation between volcanologists and public-policy makers keeping separated their own tasks as defined by their roles and their competences, with the intent of establishing fully transparent decision-making protocols well before volcanic crises. These protocols can be very helpful to audit the decision-making process at any time, and they may be an excellent communication tool for the interested stakeholders, including society.
    Description: Published
    Description: 545-564
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 9
    Publication Date: 2021-01-18
    Description: Geological gas seepage in petroleum-bearing sedimentary basins is an important natural source of atmospheric methane. In methane budget models geological emissions are generally considered constant over time, not affecting decadal atmospheric methane changes. Here, we report the case of a considerable sub-decadal variation of methane seepage from one of the largest thermogenic gas seep sites in Europe, Katakolo Harbour (Western Peloponnese, Greece). Based on gas flux measurements by accumulation chamber performed in 2010 and 2018, methane emission from cracks and fissures throughout the asphalt and concrete pavement of the harbour increased about four times (from 57 to 225 kg d􀀀 1) with emission factor changing from ~4,000 to 15,000 t km􀀀 2 y􀀀 1. Multiple lines of evidence, including mechanical deformation and fissuring of concrete and asphalt pavement, increased exhalation with constant fissure conditions, and no significant cracking with operating corrosion from 2004 to 2010, suggest that the methane emission increase is mainly due to intensification of subsurface gas flow (seepage) after 2010. Deep gas pressure and fault permeability variations, likely induced by the numerous earthquakes of the region, might have played a role. We estimate that if similar short-term variations of emission factor occur in large seepage areas worldwide, the global geological methane emission can significantly change, contributing to decadal changes of atmospheric methane budget.
    Description: Published
    Description: 104578
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
    Publication Date: 2021-01-22
    Description: None
    Description: Published
    Description: 301-312
    Description: 2A. Fisica dell'alta atmosfera
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 11
    Publication Date: 2021-01-22
    Description: Integration of archaeoseismic observations, geological and geophysical surveys and a critical review of historical written sources contributed to shed light on the effects of the 847 earthquake AD that struck a large area of Southern-Central Italy. New archaeoseismic evidence of a strong earthquake comes from two Medieval archaeological sites along the Volturno Valley, between Campania and Molise regions, which occurred around the middle of the ninth century AD. Evidence includes the tilting of pillars in the Basilica of Santa Maria near Alvignano (northern Campania) and a collapsed masonry wall in the Abbey of San Vincenzo al Volturno near Isernia (northern Molise). At Alvignano, a site so far unrecorded in seismic catalogues for the 847 earthquake, geoelectrical and georadar investigations were used to explore the subsoil and study local site conditions, which could have influenced coseismic ground motion. Integrated interpretation of geophysical surveys and borehole logs document the presence of altered pyroclastic deposits, which certainly enhanced site effects at Alvignano. Analysis of damage descriptions and of archaeological reports indicate that the 847 seismic event documented by historical sources damaged a wide area between Latium, Campania and Molise, with destruction of the town of Isernia. Although historical sources did not explicitly mention damage in Rome, seismic effects attributed to the 847 event are recorded in the archaeological and seismological literature. Because the damaged area for this medieval earthquake is loosely defined due to the scanty documentation, the present study represents an important contribution to better define the shaking area and provide new hints on the extent and location of the possible seismogenic source.
    Description: Published
    Description: 228301
    Description: 4T. Sismicità dell'Italia
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 12
    Publication Date: 2021-02-02
    Description: The study of medium-large magnitude and intermediate-high intensity (VEI = 4/5; Column Height 15-20 km) eruptions fed by poorly evolved magmas is one of the main topics in volcanology. In this framework, the 472 CE (Pollena) eruption from Somma-Vesuvius (Italy) represents a key case study, as it is one of the subplinian eruptions used to constrain the reference scenario adopted by the Italian Department of Civil Protection in case of renewal activity at Somma-Vesuvius. The Pollena eruption experienced a complex dynamics, with abrupt shifts in eruptive style. This study focused on the fall products (L1- L8) of the magmatic eruptive phases (Phases I and II), which preceded the onset of the final phreatomagmatic phase (Phase III). Phase I was characterized by unsteady magma discharge resulting in an oscillating convective column, whereas Phase II involved pulsating activity with alternation of sustained and collapsing columns. To evaluate the role of textural variability in controlling magma rheology (and therefore variations in magma discharge), a detailed textural analysis of the juvenile products has been performed. Pyroclast textures record a variable degree of outgassing efficiency and lateral textural stratification of magma in the conduit, related to differential magma ascent rates and resulting in variable eruption intensity. Repetitive patterns of magma densification, achieved by progressive outgassing and crystallization, led to stages of decreasing ascent velocity resulting in the end of the eruptive pulse (during the oscillatory Phase I) or anticipating PDC emplacement (at the end of Phase I and during the pulsatory Phase II). Further decompression of the outgassed magma induced intense clinopyroxene microlite crystallization, that markedly increased magma viscosity and promoted the restoration of sustained columns during the eruption climaxes (L3 and L8). Magma densification patterns and consequent unsteadiness in magma discharge at the surface may derive from small heterogeneities in the initial volatile budget and/or represent a natural evolution of low viscosity magmas, as those feeding Pollena eruption, where efficient crystallization in the conduit can deeply and abruptly modify magma rheology, outgassing ability, conduit flow and, ultimately, eruptive style.
    Description: Published
    Description: 105658
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 13
    Publication Date: 2021-02-22
    Description: Radon monitoring represents an important investigation tool for environmental changes assessment and geochemical hazard surveillance. Despite anomalous radon emissions are commonly observed prior to earthquakes or volcanic eruptions, radon monitoring alone is not yet successful in correctly predicting these catastrophic events because contrasting radon signals are unexpectedly measured by lithologically distinct areas. This contribution aims to summarize and integrate natural and laboratory studies pertaining to the transport behavior of radon in different rock types experiencing variable stress and thermal regimes at subvolcanic conditions. The final purpose is to ignite novel and pioneer experimental researches exploring the causes and consequences of radon anomalous emissions, in order to elucidate in full the relationship between the physicochemical changes in substrate rocks and the radon signal.
    Description: Published
    Description: 309-328
    Description: 4V. Processi pre-eruttivi
    Keywords: deformation experiments ; radon monitoring ; radon signal and rock physicochemical changes ; radon transport and geochemical anomalies ; thermal experiments ; volcanic surveillance ; 04.08. Volcanology ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 14
    Publication Date: 2021-03-03
    Description: The origin and patterns of groundwater salinity of a shallow coastal aquifer pertaining to a reclaimed subsiding zone of the Po Delta are examined in this study. The aim is to identify the source of the hypersaline groundwater residing in the basal portion of the aquifer and to infer the mechanism of salinization of the remaining portion of the aquifer. To disentangle the possible sources of salinity the molar ratio of environmental tracers like Cl− and Br− were used in combination with the classical geochemical analyses of major and minor cations ratios. High-resolution multi-level sampling (MLS) allowed obtaining a robust and self-consistent hydrogeochemical database, which was statistically analysed via factor analysis and proved to be log-normally distributed. Thus, a common origin could be inferred for the elevated salinity that characterize most of the groundwater samples, this can be recognized in the organic rich fine-grained sediments, deposited in salty back barrier and marsh environments during the last transgression phase. This study proves that a detailed analysis of groundwater geochemistry can be considered a valuable tool to assess the origin of salinity in coastal Holocene aquifers, where the traditional conceptual model of a simple fresh/seawater interface may not be adequate.
    Description: Published
    Description: 130-137
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 15
    Publication Date: 2021-04-14
    Description: In February 2016, 47 ingots were found in the seabed of Contrada Bulala (Gela, CL, Italy) near the site where 40 ingots had previously been recovered. The ingots composition was determined to be a Cu - Zn alloy, dated by the archaeologist to the VI century B.C. This specific alloy was then known as Orichalcum. From an archaeological point of view, the first question raised about the new discovery was whether the ingots of the first and the second excavations belonged to the same shipwreck. Following the previous study, an elemental analysis was performed on the ingots from the second finding by using ICP-OS and ICP-MS techniques. The chemometric treatment of the analytical results obtained on both sets, i.e. ingots from first and second discovery, confirms their similarity. Therefore, the two findings can be considered to belong to the same naval load. The lead isotopic ratios were determined on selected/representative ingots to improve the knowledge about this treasure. Results can provide information about probable location of the lead sources, that could be very useful for the reconstruction of the ancient trade routes in the Mediterranean Sea.
    Description: Published
    Description: 102901
    Description: 2IT. Laboratori analitici e sperimentali
    Description: JCR Journal
    Keywords: Orichalcum ingots ; Lead Isotopic ratio ; ICP-OES ICP-MS ; Chemometric approach ; 05.09. Miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 16
    Publication Date: 2021-03-03
    Description: Shallow aquifers are the most accessible reservoirs of potable groundwater; nevertheless, they are also prone to various sources of pollution and it is usually difficult to distinguish between human and natural sources at the watershed scale. The area chosen for this study (the Campania Plain) is characterized by high spatial heterogeneities both in geochemical features and in hydraulic properties. Groundwater mineralization is driven by many processes such as, geothermal activity, weathering of volcanic products and intense human activities. In such a landscape, multivariate statistical analysis has been used to differentiate among the main hydrochemical processes occurring in the area, using three different approaches of factor analysis: (i) major elements, (ii) trace elements, (iii) both major and trace elements. The elaboration of the factor analysis approaches has revealed seven distinct hydrogeochemical processes: i) Salinization (Cl-, Na+); ii) Carbonate rocks dissolution; iii) Anthropogenic inputs (NO3-, SO42-, U, V); iv) Reducing conditions (Fe2+, Mn2+); v) Heavy metals contamination (Cr and Ni); vi) Geothermal fluids influence (Li+); and vii) Volcanic products contribution (As, Rb). Results from this study highlight the need to separately apply factor analysis when a large data set of trace elements is available. In fact, the impact of geothermal fluids in the shallow aquifer was identified from the application of the factor analysis using only trace elements. This study also reveals that the factor analysis of major and trace elements can differentiate between anthropogenic and geogenic sources of pollution in intensively exploited aquifers.
    Description: Published
    Description: 260-269
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Anthropogenic inputs; Factor analysis; Geogenic sources; Groundwater; Seawater intrusion; Trace elements
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 17
    Publication Date: 2021-03-18
    Description: Primitive basalticmagmas are crucial in the study of the geochemical heterogeneity documented in Etnamagmas and their inferred mantle sources. We undertook a systematic sampling of the less evolved basalts (Mg# N50) erupted over the last 15 ka, a time period which corresponds to the activity of the youngest volcanic edifice of Mt. Etna complex, i.e. Mongibello volcano. We focused on lava flows and pyroclastites emplaced during ‘deepdyke fed’ (DDF) eruptions which were driven by the rapid ascent of deeply-rooted magma intrusions that bypassed the shallow plumbing system of the volcano. All the samples were analyzed by the same laboratory to avoid analytical bias, to build a comprehensive dataset on their major and trace element compositions and to propose a coherent framework for interpreting the geochemical fingerprints of present-day Etna basalts. Trace element modeling, togetherwith literature data for Sr isotopes, gave insight into long-term magmatic processes related to different melting degrees of the heterogeneous mantle beneath Mt Etna. DDF magma batches provide good snapshots of their mantle source heterogeneities that point to the variable involvement of clinopyroxenitic lithology, Rb–87Sr–Cl-rich fluid component(s) possibly controlled by their source mineralogy, and slab-derived fluids selectively enriched in alkalis (Rb, K). The ongoing alkali (Rb, K) enrichment of the present-day magmas, well manifest since the 1970s, is decoupled from that of Sr and Cl. We propose that this process is linked to mantle source composition and is concomitant with changes in both volcanological and seismotectonic patterns of the volcano. There is no time evolution of DDF magma chemistry.
    Description: Published
    Description: 123-134
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 18
    Publication Date: 2021-05-12
    Description: We report on the geochemical and chronological characterization of a tephra layer, here called RdV-T1, recovered within a continental sequence at Riparo di Venere site in the Fucino Basin (central Italy). Textural, mineralogical, and detailed geochemical (major and trace elements on single glass shard) analyses indicate thatMt. Etna is the volcanic source. Radiocarbon dating of charred materials above and belowthis tephra layer result in 13,380±40 (16,260–15,920 cal yrs BP) and 13,620±40 (16,625–16,230 cal yrs BP) 14C years BP, respectively. This age points out that RdV-T1 tephra derives fromthe Late Pleistocene activity of the Ellittico caldera-forming phase of Mt. Etna that is significantly (up to 1750 yrs) younger than the Biancavilla Ignimbrites and upper Acireale fall, which are the last known events of this eruptive cycle. In addition, the RdV-T1 tephra geochemical signature is distinctwith respect to the Biancavilla Ignimbrites and upper Acireale fall. Therefore, the radiocarbon and geochemical data consistently indicate that the RdV-T1 tephra may represent an explosive event following the Biancavilla Ignimbritesand the upper Acireale fall not yet identified.
    Description: Published
    Description: 106992
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Keywords: Etna ; Tephra ; Late Glacial
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 19
    Publication Date: 2021-05-12
    Description: Mapping and luminescence aging of raised marine terraces and aeolian ridges along an ∼90 km coastal stretch in southwestern Sicily provide the first quantitative assessment of vertical tectonic deformation in this region, which spans the frontal part of an active thrust belt. We recognized a staircase of eleven terraces and nine related aeolian ridges. The elevation profile of terraces parallel to the coast shows a 〉90 km long bell-shaped pattern, onto which shorter-wavelength (∼10 km long) undulations are superimposed. Luminescence ages from terraced beach deposits and aeolian sediments constrain the position of paleoshorelines formed during MIS 5e, 7a and 7c, with a maximum uplift rate of ∼0.75 mm/a, and indicate a late Middle-Late Pleistocene (80–400 ka) age for the sequence of terraces. The elevation of Lower Pleistocene morpho-depositional markers points that uplift may have occurred at similar rates at the beginning of the Early Pleistocene, but almost zeroed between ∼1.5 and 0.4 Ma before the recent renewal. The uneven elevation of Middle-Upper Pleistocene paleoshorelines observed moving along the coast documents that uplift embeds both a regional and a local component. The regional, symmetric bell-shaped uplift is related to involvement in the thrust belt of thicker crustal portions of the northern African continental margin. The short-wavelength undulations represent the local component and correspond to actively growing bedrock folds. The present study contributes to unravel the different spatial and temporal scales of deformation processes at a collisional margin.
    Description: Published
    Description: 106812
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Marine terraces ; Aeolian ridges ; Luminescence dating ; Pleistocene ; Frontal thrust belt ; Fold growth ; Southwestern Sicily ; Mediterranean sea ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 20
    Publication Date: 2021-05-12
    Description: Monitoring of the water column in the vicinity of offshore Carbon Capture and Storage (CCS) sites is needed to ensure site integrity and to protect the surrounding marine ecosystem. In this regard, the use of continuous, autonomous systems is considered greatly advantageous due to the costs and limitations of periodic, ship-based sampling campaigns. While various geochemical monitoring tools have been developed their elevated costs and complexities mean that typically only one unit can be deployed at a time, yielding single point temporal data but no spatial data. To address this the authors have developed low-cost pCO2 sensors (GasPro-pCO2) that are small, robust, stable, and which have a low power consumption, characteristics which allow for the deployment of numerous units to monitor the spatial-temporal distribution of pCO2, temperature, and water pressure in surface water environments. The present article details the results of three field deployments at the natural, CO2-leaking site near Panarea, Island. While the first consisted of 6 probes placed on the sea floor for a 2.5 month period, the other two involved the deployment of 20 GasPro units along a transect through the water column in the vicinity of active CO2 seeps over 2 – 4 days. Results show both transport and mixing processes and highlight the dynamic nature of the leakage-induced marine geochemical anomalies. Implications for monitoring programs as well as potential impacts are discussed.
    Description: Published
    Description: 3840 – 3847
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: spatial-temporal monitoring ; pCO2 ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 21
    Publication Date: 2021-06-07
    Description: In this paper we summarize a number of risk pathway scenarios that are often claimed in literature as of priority for risk analyses in unconventional gas development. The resulting scenarios are structured in diagrams representing causal relationships between events. We argue that science is called to fill gaps regarding the main processes characterizing the involved events and defining the conditions under which their occurrence may be enhanced or inhibited. In this way, these scenarios can be more objectively parameterized, making their quantitative assessment a more feasible task and opening the way for the formulation of appropriate risk mitigation strategies.
    Description: Published
    Description: 116-125
    Description: European Geosciences Union General Assembly 2017 (Vienna) EGU Division Energy, Resources & Environment (ERE)
    Description: 1TR. Georisorse
    Description: N/A or not JCR
    Keywords: Multi-hazard risk ; unconventional gas development
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 22
    Publication Date: 2021-06-07
    Description: Analysis of natural and anthRopoGenic risks on Offshore platforms (ARGO) is a 3-years project, funded by the Italian Ministry of Economic Development. The project, coordinated by AMRA, a permanent Research Centre for the development of innovative technologies applied to environmental problems, aims at providing technical-support for the analysis of natural and anthropogenic risks on offshore oil-platforms. ARGO has developed methodologies for the probabilistic analysis of industrial accidents triggered by natural events (NA-TECH) on offshore platforms. The final analysis of the ARGO Project suggest a constant monitoring of exploitation activity, fluids re-injection and storage using high technology networks.
    Description: Published
    Description: 145–152
    Description: European Geosciences Union General Assembly 2017, EGU (Vienna) European Geosciences Union General Assembly 2017, Division Energy, Resources & Environment
    Description: 1TR. Georisorse
    Description: N/A or not JCR
    Keywords: Multi-hazard risk ; offshore oil platforms ; seismicity ; extreme meteo-marine events
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 23
    Publication Date: 2021-06-15
    Description: Sicily hosts many natural manifestations that include thermal waters, gas discharges and mud volcanoes. Due to the significant geodynamic and geological differences, the fluid discharges along a NE-WS–oriented transect that run from the Peloritani Mts. to the Sciacca Plain shows a large variability in water and gas chemical and isotopic compositions. The studied waters are characterized by Ca-HCO3, Ca(Mg)-SO4, Ca-Cl and Na-Cl compositions produced by distinct geochemical processes such as water-rock-gas interactions, mixing between deep and shallow aquifers and seawater and direct and reverse ion exchanges. The gas chemistry is dominated by CO2 to the east and CO2-N2 to the west of the study area, whereas the central part shows mud volcanoes discharging CH4-rich gases. Water isotopes suggest that the thermal waters are fed by a meteoric recharge, although isotopic exchange processes between thermal fluids and host rocks at temperature 〉150°C are recognized. Accordingly, liquid geothermometry suggests equilibrium temperatures up to 220°C. The carbon in CO2 and helium isotopes of the emissions from the westernmost sector of Sicily indicate that these two gases consists of up to 40 % of a mantle component, the latter decreasing to the east down to 10% where CO2 of thermometamorphic origin dominates. Accordingly, conceptual models of the fluid circulation for the western, central and eastern sectors are proposed. The regional geothermal reservoir, hosted in carbonates in the western sector and locally outcropping, is of low to medium temperature. Higher temperature conditions (up to 200-220°C) are suggested by geothermometry and probably related to deeper levels of the system. Sicily can be regarded as a potentially suitable area for future investigations to evaluate specific activities aimed at exploiting the geothermal resource.
    Description: Published
    Description: 102120
    Description: 9T. Geochimica dei fluidi applicata allo studio e al monitoraggio di aree sismiche
    Description: JCR Journal
    Keywords: Fluid geochemistry ; Stable isotopes ; Geothermal exploration ; Dissolved gases ; Tectonics ; 03. Hydrosphere
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 24
    Publication Date: 2021-06-30
    Description: composite stratigraphic section ranging from the Messinian to the Pliocene, recording the most important phases of the Messinian Salinity Crisis, is represented in the San Miguel de Salinas area (Bajo Segura basin, SE Spain). Detailed magnetostratigraphic and facies analyses and foraminifer and nannoplankton assemblage studies were carried out. Integration of the results has allowed the characterization of the pre-evaporitic (synthem Messinian I), syn-evaporitic (synthem Messinian II), and post-evaporitic phases (synthem Pliocene) from a paleoenvironmental and chronostratigraphic standpoint. The pre-evaporitic phase is late Messinian and records a shallowing-upward trend. The syn-evaporitic phase took place in chron C3r and is characterized by laminated marls with intercalated selenitic gypsum beds and sandstones. Variations in foraminifer and nannoplankton assemblages together with episodic gypsum precipitation record major changes in water salinity in a stressed marine environment. The pre- and syn-evaporitic phases are separated by the intra-Messinian unconformity, represented by an erosional surface related with a sea-level fall. After the evaporitic phase, a sea-level fall generates the end-Messinian unconformity, whose strongly erosional nature is evidenced by the deeply carved paleovalley of San Miguel de Salinas. The post-evaporitic phase begins in the earliest Pliocene and records the re-establishment of normal marine conditions in the basin. Since the San Miguel de Salinas composite section can be considered as a benchmark for the study of the evolution of marginal Mediterranean basins during the Messinian Salinity Crisis, the detailed characterization of these different phases is of great importance in understanding this event.
    Description: Published
    Description: 246-266
    Description: 4A. Oceanografia e clima
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 25
    Publication Date: 2021-07-02
    Description: While processes involved in the protohistoric briquetage at Puntone (Tuscany, Italy) have been reconstructed in detail, the age of this industry remained uncertain since materials suited for traditional dating (14C dating on charcoal and typological dating of ceramics) were very scarce. We attempted to assess its age by radiocarbon dating organic matter and carbonates in strata that were directly linked to the industry. Microbial DNA and C isotope analyses showed that the organic matter is dominantly composed of labile organic matter, of which the age is coeval with the briquetage industry. Carbonates had a complex origin and were overall unsuited for radiocarbon dating: Shells in process residues exhibited a large, uncertain ‘marine reservoir effect’, hampering their use for dating the industry; the secondary carbonates in these residues had a quite varied composition, including much more recent carbonate that precipitated from infiltrated lateral run-off, as could be concluded from C and Sr isotope analyses. Dates found that were deemed reliable (c. 1000–100 cal BCE) show that this ancient industry, which started in the Late Bronze Age - Early Iron Age (1107–841 cal BCE), extended into the Roman Republican period and was contemporary with the saltern-based larger scale salt industry in Central Lazio.
    Description: Published
    Description: 103055
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Briquetage ; Central Italy ; Early states ; Radiocarbon dating
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 26
    Publication Date: 2020-09-07
    Description: A statistical analysis of Loss of Lock (LoL) over Brazil throughout the 24th solar cycle is performed. Four geodetic GPS dual-frequency (L1, L2) receivers, deployed at different geographic latitudes ranging from about 25° to 2° South in the eastern part of the country, are used to investigate the LoL dependence on time of the day, season, solar and geomagnetic activity. The results of the analysis show that LoL is most likely in the post-sunset hours during summer and equinox, especially within the southern crest of the Equatorial Ionospheric Anomaly (EIA), in a region between about 10°S and 25°S of geographic latitude, matching the typical behaviour of scintillation over Brazil. This is confirmed by the correlation found between the relative occurrence of LoL (LoL (%)) and the Rate Of TEC Index (ROTI), used as a proxy of scintillation index and calculated for each receivers along the entire period of investigation. The LoL (%) for given solar and geomagnetic indices show some correlation with increasing the severity of the index. This correlation is strongest in the area of the southern crest of the EIA, while there is little to no apparent impact closer to the equator, depending on the index. LoL (%) increases with increasing geomagnetic disturbances, varying between ~1% and ~10% for AE ranged between 400 and 1200 nT, and exceeding 3% when Dst is around −100 nT, both related to moderate-severely disturbed conditions.
    Description: Published
    Description: 219-225
    Description: 2A. Fisica dell'alta atmosfera
    Description: JCR Journal
    Keywords: GPS Loss of Lock, Equatorial Ionosphere ; scintillation
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 27
    Publication Date: 2020-09-07
    Description: While mantle convection is a fundamental ingredient of geodynamics, the driving mechanism of plate tectonics remains elusive. Are plates driven only from the thermal cooling of the mantle or are there further astronomical forces acting on them? GPS measurements are now accurate enough that, on long baselines, both secular plate motions and periodic tidal displacements are visible. The now 〉20 year-long space geodesy record of plate motions allows a more accurate analysis of the contribution of the horizontal component of the body tide in shifting the lithosphere. We review the data and show that lithospheric plates retain a non-zero horizontal component of the solid Earth tidal waves and their speed correlates with tidal harmonics. High-frequency semidiurnal Earth's tides are likely contributing to plate motions, but their residuals are still within the error of the present accuracy of GNSS data. The low-frequency body tides rather show horizontal residuals equal to the relative motion among plates, proving the astronomical input on plate dynamics. Plates move faster with nu- tation cyclicities of 8.8 and 18.6 years that correlate to lunar apsides migration and nodal precession. The high- frequency body tides are mostly buffered by the high viscosity of the lithosphere and the underlying mantle, whereas low-frequency horizontal tidal oscillations are compatible with the relaxation time of the low-velocity zone and can westerly drag the lithosphere over the asthenospheric mantle. Variable angular velocities among plates are controlled by the viscosity anisotropies in the decoupling layer within the low-velocity zone. Tidal oscillations also correlate with the seismic release.
    Description: Published
    Description: 103179
    Description: 1T. Struttura della Terra
    Description: JCR Journal
    Keywords: Body tide ; Plate tectonics ; Geeodynamics ; 04.07. Tectonophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 28
    Publication Date: 2020-10-16
    Description: Many long-term monitoring sites in Antarctic regions, which deploy ground-based stratospheric remote sensors and fly radiosondes or ozonesondes on balloons, supported the Airborne Polar Experiment in September and October 1999. Support consisted of supplying data to the campaign in real time, and in some cases by increasing the frequency of measurements during the campaign. The results will strengthen scientific conclusions from the airborne measurements. But results from these sites are allowing important scientific studies of new aspects of the ozone hole in their own right, because like the aircraft and its campaign, many sites traverse the vortex edge and are close to the largest source of lee waves, or measure infrequently observed trace gases such as HNO3. Examples of such studies are the behaviour and value of NO2 in midwinter, ozone filamentation with no apparent horizontal advection, the frequency and amplitude of gravity waves over the Antarctic Peninsula, mixing in the lowest stratosphere in Antarctic spring, the mechanism and frequency of HNO3 enhancement above the ozone peak in midwinter, and trends in UV dose in southern South America.
    Description: Published
    Description: 835–845
    Description: 5A. Ricerche polari e paleoclima
    Description: JCR Journal
    Keywords: ozone depletion ; APE-GAIA ; Antarctic stratosphere ; 01.01. Atmosphere
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 29
    Publication Date: 2020-10-28
    Description: In the last decades, a growing number of works has increasingly focused on the study of thermal waters using the approach described by Giggenbach (1988). Based on the dependence on temperature of the equilibrium constants, the Na-K-Mg diagram is the combination of the Na-K and K-Mg geothermometers. The pristine approach proposed by Giggenbach (1988) included several constraints for its successful application. In spite of this, the Na-K-Mg diagram is often used out of the boundaries conditions of applicability. In order to promote a proper use of the diagram, a detailed description is given and several examples of mixing, dilution and concentration are discussed. The obtained findings highlight the need of cautiousness when using the diagram to estimate temperature of hydrothermal systems.
    Description: Published
    Description: 119577
    Description: 4V. Processi pre-eruttivi
    Description: 1TR. Georisorse
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 30
    Publication Date: 2020-12-18
    Description: Vesiculation of crystallising magma can produce either a mobile vesicular magma or a rigid network of crystals containing vesicular liquid. Where partially crystallized rigid mush underlies less-crystallized magma, such as near the base of a lava flow or in the cumulus pile of a magma chamber, evolved interstitial melt and/or gas may escape into the main body of magma. The consequences of this may include contamination of the overlying liquid with gas and interstitial melt, or intrusion of diapirs of vesicular evolved liquids to form vertical vesicle cylinders and other segregation features found in many basaltic lava flows and sills. Analog experiments were used to investigate some of the phenomena that can arise during vesiculation within a crystal mush, which was simulated by pumping air through a porous plate that formed the floor of a container filled with a viscous liquid floored with a layer of glass beads. Experiments used either a single liquid or two stably stratified liquids with a liquid interface either coincident with the top of the porous layer of beads or slightly above the porous layer. For a range of liquid viscosities and air flow rates (vesiculation rates), individual bubbles emerged from the top of the porous layer of beads and carried a thin trail of interstitial liquid into the overlying liquid. The number of bubble trains leaving the surface of the porous bed increased with decreasing liquid viscosity and flow rate, and with increasing bead size (and, hence, with increasing permeability). Analog vesicle cylinders, composed of diapirs of bubbly interstitial liquid, were produced only when a layer of buoyant bubbly liquid lay above the surface of the porous layer. The relative size of the bubbles and constrictions within the porous layer are argued to control whether individual bubbles (leading to bubble trains) or vesicular liquid (leading to vesicle cylinders) leaves the porous layer and hence whether vesicle cylinders can form.
    Description: Published
    Description: 287–300
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 31
    Publication Date: 2020-12-14
    Description: In the last few decades, advanced monitoring networks have been extended to the main active volcanoes, providing warnings for variations in volcano dynamics. However, one of the main tasks of modern volcanology is the correct interpretation of surface-monitored signals in terms of magma transfer through the Earth's crust. In this frame, it is crucial to investigate decompression-induced magma degassing as it controls magma ascent towards the surface and, in case of eruption, the eruptive style and the atmospheric dispersal of tephra and gases. Understanding the degassing behaviour is particularly intriguing in the case of poorly explored evolved alkaline magmas. In fact, these melts frequently feed hazardous, highly explosive volcanoes (e.g., Campi Flegrei, Somma-Vesuvius, Colli Albani, Tambora, Azores and Canary Islands), despite their low viscosity that usually promotes effusive and/or weakly explosive eruptions. Decompression experiments, together with numerical models, are powerful tools to examine magma degassing behaviour and constrain field observations from natural eruptive products and monitoring signals. These approaches have been recently applied to evolved alkaline melts, yet numerous open questions remain. To cast new light on the degassing dynamics of evolved alkaline magmas, in this study we present new results from decompression experiments, as well as a critical review of previous experimental works. We achieved a comprehensive dataset of key petrological parameters (i.e., 3D textural data for bubbles and microlites using X-ray computed microtomography, glass volatile contents and nanolite occurrence) from experimental samples obtained through high temperature-high pressure isothermal decompression experiments on trachytic alkaline melts at super-liquidus temperature. We explored systematically a range of final pressures (from 200 to 25 MPa), decompression rates (from 0.01 to 1 MPa s−1), and volatile (H2O and CO2) contents. On these grounds, we integrated coherently literature data from decompression experiments on evolved alkaline (trachytic and phonolitic) melts under various conditions, with the aim to fully constrain the degassing mechanisms and timescales in these magmas. Finally, we simulated numerically the experimental conditions to evaluate strengths and weaknesses in decrypting degassing behaviour from field observations. Our results highlight that bubble formation in evolved alkaline melts is primarily controlled by the initial volatile (H2O and CO2) content during magma storage. In these melts, bubble nucleation needs low supersaturation pressures (≤ 50–112 MPa for homogeneous nucleation, ≤ 13–25 MPa for heterogeneous nucleation), resulting in high bubble number density (~ 1012–1016 m−3), efficient volatile exsolution and thus in severe rheological changes. Moreover, the bubble number density is amplified in CO2-rich melts (mole fraction XCO2 ≥ 0.5), in which continuous bubble nucleation predominates on growth. These conditions typically lead to highly explosive eruptions. However, moving towards slower decompression rates (≤ 10−1 MPa s−1) and H2O-rich melts, permeable outgassing and inertial fragmentation occur, promoting weakly explosive eruptions. Finally, our findings suggest that the exhaustion of CO2 at deep levels, and the consequent transition to a H2O-dominated degassing, can crucially enhance magma vesiculation and ascent. In a hazard perspective, these constraints allow to postulate that time-depth variations of unrest signals could be significantly weaker/shorter (e.g., minor gas emissions and short-term seismicity) during major eruptions than in small-scale events.
    Description: Published
    Description: 103402
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 4V. Processi pre-eruttivi
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 32
    Publication Date: 2021-01-14
    Description: We present elemental maps and intra-crystal compositional profiles conducted on a representative clinopyroxene phenocryst from the 1974 eccentric lava flows at Mt. Etna volcano (Sicily, Italy). The eruption was fed by deep-seated and primitive magmas ascending through pathways bypassing the central volcanic conduits. These magmas show MgO and Cr contents higher (and REE + Y lower) than those characterizing younger and more evolved eruptions, albeit the bulk rock compositions of both primitive and more evolved products are invariably classified as trachybasalts in the TAS (total alkali vs. silica) diagram. Mafic recharge episodes are recorded by the complex textural features of the clinopyroxene, with a subrounded core enclosed within a concentrically zoned mantle. The core is enriched in Mg + Fe2++Na and depleted in Fe3++Ca relative to the mantle. The jadeite (Jd) component decreases from core to mantle and is counterbalanced by higher Ca-Tschermak (CaTs) contents, as the number of TAl cations in tetrahedral coordination increases. The Jd-rich core incorporates high proportions of rare earth elements and Y (REE + Y) and low concentrations of high field strength elements (HFSE) and transition elements (TE, such as Ni, Cr and Sc), whereas the opposite occurs for the CaTs-rich mantle. The decoupling of REE + Y and HFSE argues against simple changes in melt composition and indicates an additional mechanism driving trace element zonations. Thermobarometric calculations indicate that the early-formed Jd-rich core equilibrated with the host magma at mantle depths (750–950 MPa and 1190–1210 °C), whereas the later CaTs-rich mantle formed at shallower crustal levels (400–700 MPa and 1150–1180 °C) after magma recharge. Quantitative modeling of apparent cation partitioning between clinopyroxene and melt (Di) indicates that DHFSE increase from the Jd-rich core to the CaTs-rich mantle. In contrast, DREE+Y increase up to one order of magnitude at the Jd-rich core due to the enhanced stability of an Na0.5REE + Y0.5MgSiO6 end-member. We infer that compositional changes in clinopyroxene due to the different P-T conditions of the plumbing system may control the concentrations of REE + Y in residual melts derived after partial crystallization and differentiation of primitive magmas, such as those feeding the 1974 eccentric eruption. On this basis, we use DREE+Y measured across the core-mantle interface to constrain the geochemical evolution of recent 2000–2013 magmas at Mt. Etna volcano by Rayleigh fractional crystallization. Results indicate that magma dynamics proceed via a stepwise polybaric-polythermal process accounting for 1) crystallization of Jd-rich clinopyroxenes at high-P, high-T conditions, 2) upward migration of crystal-bearing magmas due to replenishment phenomena with input of fresh magmas and 3) crystallization of CaTs-rich clinopyroxene in low-P, low-T reservoirs. The resulting total amount (~40 vol%) of clinopyroxene fractionated agrees with geophysical data suggesting the presence of highly crystalline magmatic bodies at shallow to intermediate crustal levels below Mt. Etna.
    Description: Published
    Description: 105382
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
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  • 33
    Publication Date: 2021-01-05
    Description: Induced seismicity can be associated to the activity of fluid withdrawal and injection from/into the shallow crust (fracking, wastewater disposal into the deep crust, Enhanced Geothermal Systems technology, fluid extraction in oil fields and geothermal power plants). Long-term injection of large volumes of fluids is normally associated with induced seismicity, but the effect of withdrawal-reinjection in the same reservoir is less known, at least regarding its relation to simple injection. However, it is common experience worldwide that small (i.e. 10 MW or less) geothermal plants with withdrawal and re-injection of fluids in the same reservoir are mostly not associated with significant induced/triggered seismicity. This paper aims at understanding how to discriminate, on a numerical modelling basis, the seismogenic potential of withdrawal-reinjection with respect to injection only. With this aim, we analysed the induced pressure changes, the perturbed volumes of rocks and the potential for induced seismicity due to these operations. A set of simulations of injection or withdrawal-reinjection cycles, obtained by using the numerical code TOUGH2®, is applied to simple models of geothermal reservoirs, with varying permeability and lateral boundary constraints. For each permeability model, we then compare the time growth of perturbed volumes obtained with withdrawal-reinjection cycles to those obtained during simple injection, using the same flow rates. The size of perturbed volumes is then related to the maximum magnitude of induced/triggered seismicity, using models accredited in recent literature. Our results show that, for all models, withdrawal-reinjection is by far less critical than simple injection, because the perturbed volumes are remarkably smaller and remain constant over the simulated time, so minimizing the likelihood of interference with seismogenic faults. These results have significant implications for geothermal projects, and in the assessment of the potential risk related to fluid stimulation and induced seismicity.
    Description: Published
    Description: 101770
    Description: 1TR. Georisorse
    Description: JCR Journal
    Keywords: geothermal energy ; geothermal energy
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 34
    Publication Date: 2021-01-08
    Description: Archaeoseismological evidence of a strong earthquake, which probably occurred a year before the 252 CE Mt. Etna eruption, has been uncovered at Santa Venera al Pozzo site, located near to Acireale, along the lower eastern flank of the volcano. The site, known for its remarkable and peculiar hydrothermal fluids emissions exploited for thermal uses since the Greek and Roman age, has been investigated through a multidisciplinary approach by integrating archaeoseismological observations with geological and geochemical surveys. Analysis of the observed damage and deformation at the site suggest a capable fault zone through the area. Geochemical and geological surveys were performed in and around the site and have revealed anomalies of soil CO2 efflux along an known active fault and likely also along some unmapped hidden faults. The chemical and isotopic composition of the emitted fluids suggests that these have not a volcanic origin, but they could be related with a deep tectonic system. The data presented in this paper suggest the occurrence of both exposed and hidden active faults in the area of Santa Venera al Pozzo, which could be linked to the seismic activity that damaged the historical site.
    Description: Published
    Description: 228544
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Historical seismicity ; Archaeoseismology ; Geochemical survey ; Active tectonics ; Mt. Etna volcano ; Santa Venera al Pozzo
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 35
    Publication Date: 2021-01-04
    Description: Recently, an earthquake sequence formed by a series of subsequences characterized by large earthquakes (three events M ≥ 6.0 and five events M ≥ 5.0) occurred in the Central Apennines in 6–7 months during 2016–2017. Several studies interpreted this cascading type of earthquake occurrence as associated with fluid movements through an interconnected network of cracks around the active faults that triggered the subsequences in different time and location. In the present study we aim to verify if the presence of fluids is confirmed by the pattern of seismic wave attenuation. To do so we separately estimate the space-averaged parameters intrinsic Qi−1 and scattering Qs−1, proportional to the correspondent attenuation parameters, by applying a modified Multiple Lapse Time Window Analysis (MLTWA), in order to establish reference background values for the study region. MLTWA measures the decay of S-wave energy with distance and lapse time and fit it to the Energy Transport Equation solution for scattering, yielding the seismic albedo, B0 = Qs−1/Qt−1 and the extinction Length, Le,∝Qt−1 parameters as a function of frequency. The knowledge of the separated attenuation parameters allows determining which process of seismic energy dissipation dominates in the region. In the present study B0 results to be around0.6 (at 1.5 Hz) and decreases with increasing frequency down to 0.2 indicating that the attenuation of the seismic energy carried by S-wave is controlled by intrinsic dissipation rather than by scattering. Moreover, the intrinsic attenuation is frequency dependent (f −0.9 for the uniform model and f −0.4 for the crust/Moho model). This behavior well matches with the presence of fluids in the faults and fracture zones in the central Apennines, in agreement with results from other independent studies in the region. Finally, a comparison among the attenuation parameters estimated for this area and those measured in several areas of Italy and other parts of the world is presented together with a discussion on the comparison between the present MLTWA attenuation estimates and homologous results obtained for the same area with different approaches.
    Description: Published
    Description: 106498
    Description: 7T. Variazioni delle caratteristiche crostali e precursori sismici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 36
    Publication Date: 2021-01-12
    Description: Nowadays, electrical resistivity tomography (ERT) is able to furnish a global reconstruction of the main features of buried structures at a shallow scale, in a faster and cost-effective manner. The use of a controlled source makes ERT less sensitive to noise with respect to other geophysical methodologies based on natural sources, such as magnetotelluric. During field practice, the depth of exploration is limited by the relative distances between the source and receiver dipoles. The latest generation resistivimeters favor the simultaneous recording of signals in correspondence with multiple and physically separated receivers. These characteristics concur towards a more profitable application of ERT imaging in the case of deeper targets distributed within harsh or densely inhabited large areas. At the same time, the ease of placing a good number of receivers far from the electric sources enhances the need of tools apt for extracting weaker signals from background noise of both natural and anthropic nature. For this purpose, the use of the well-known method, i.e., principal component analysis (PCA) as a filtering tool is tested on the geoelectrical time series acquired in the Mt. Vesuvius area (Naples, Italy). A field and a test dataset have been derived from such recordings and subsequently processed through an original procedure based on PCA. Subsequently, the results have been compared with the ones obtained using more typical estimators, such as stacking or frequency filtering, thus evaluating the usefulness of PCA in the processing of the geoelectrical time series. A good estimate of the said parameters can also be obtained in the case of source-to-receiver distance of more than 5 km.
    Description: Published
    Description: 104038
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: 05.05. Mathematical geophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 37
    Publication Date: 2021-01-14
    Description: A high resolution set-up of a z-level ocean model has been implemented in the Adriatic Sea to investigate the impact of the Levantine Intermediate Water on the Adriatic Sea circulation and dense water formation. The period under investigation starts at the beginning of 2000 and ends at the end 2007. A twin experiment is performed in which the southern boundary conditions are derived from two different operational systems in the Mediterranean Sea. It is shown that the quantity and the characteristics of the Levantine Intermediate Water in the Mediterranean model introduced at the southern boundary may significantly impact the amount of the dense water formed in the Southern Adriatic and the accuracy of the model simulation even in the Northern Adriatic.
    Description: Published
    Description: 253-263
    Description: 4A. Oceanografia e clima
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 38
    Publication Date: 2021-01-07
    Description: The Fucino lacustrine basin in central Italy is a large flat area mostly devoted to agriculture, with urbanization along the perimeter of the ancient lake. In 1915 a strong earthquake struck the area (Mw 7.0), producing large damages and geological effects, including surface faulting, ground failures and liquefaction. A channel excavated in the lacustrine sediments exposed ground failure, with dykes of fine-grained sediment that we interpret as the result of earthquake-induced liquefaction. We present the results of a multidisciplinary work aimed at characterizing in detail the geology of the buried stratigraphic succession, its susceptibility to liquefaction and the likely source of the fine-grained liquefied material. The succession down to 20 m deep is formed by fine-grained sediments younger than ~170–180 kyrs (mostly Late Pleistocene - Holocene), prevailingly silt or silt-clay mixtures. The geological field analysis indicates that the dykes are filled by prevailing silt, liquefied and transported by upward-directed flow of short duration, as for earthquake-induced liquefaction. Tilting and lateral spreading accompanied the process. The overall liquefaction potential derived from the “simplified methods” is high. Correlations of X-Ray Powder Diffraction mineralogy of samples from drilling cores with those from dykes allowed us to identify the most likely source layer filling dykes, corresponding to a silt layer at 7–8 m depths. This layer and the dykes lack illite and montmorillonite clay particles. These results contribute to improve studies of liquefactions in sediments that differ from typical liquefiable loose sands. They have also implications for microzonation studies. Most samples show grain-size curves that do not fit within the field of potentially liquefiable soils, suggesting that criteria based on grain-size can be poorly significant in seismic microzonation studies of recent (Late Pleistocene-Holocene) lacustrine, fine-grained successions.
    Description: Published
    Description: 105621
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: JCR Journal
    Keywords: Seimic microzonation, liquefaction, 1915 earthquake
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 39
    Publication Date: 2021-01-19
    Description: Multiparametric observations integrate signals from different techniques into a unified time and space frame, and are key in understanding and monitoring the evolution of volcanic systems and eruptive activity. Mafic explosive eruptions, with a relatively high frequency of occurrence and low intensity, allow for detailed multiparametric observations at a relatively close distance. Typically, pyroclast ejection in these eruptions is not steady, but is characterized by the occurrence of ejection pulses, linked to pressure release events and featuring a characteristic nonlinear decay of pyroclasts exit velocity. Pulse frequency, duration, and exit velocity define the dominant eruptive style, function of the volume and pressure of the released gas, conduit size, and magma rheological-mechanical properties. No important differences in pressure and velocity divide eruptions with different magnitude and style. Ejection pulses influence the geophysical signature, plume development, and the emplacement of ballistic volcanic projectiles at eruptions from Strombolian to Vulcanian styles.
    Description: Published
    Description: 379-411
    Description: 4V. Processi pre-eruttivi
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Keywords: Mafic eruption, Multiparametric monitoring, Eruption imaging, Volcano acoustic, Strombolian, Plume, Vent, Ballistic ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 40
    Publication Date: 2021-01-20
    Description: Abstract There is evidence that the tsunami as a destructive natural phenomenon has been known since antiquity. Although rare, tsunamis can affect densely populated areas, provoking heavy destruction and extensive casualties. A deep knowledge of their characteristics, such as generation mechanism, propagation, and effects is fundamental to assess the tsunami hazard of a region. Therefore, as for all natural events, also for tsunamis the observation and analysis of past occurrences is the basis of understanding the phenomenon. The study of historical tsunami records is the first step for hazard evaluation and for the calibration and validation of numerical models aimed at tsunami mitigation. This work wishes to emphasize the importance and limitations of historical data and catalogue in tsunami hazard assessment and to underline problems related to the critical interpretation and evaluation of historical sources.
    Description: Published
    Description: 21-31
    Description: 6T. Studi di pericolosità sismica e da maremoto
    Keywords: Tsunami ; History ; Historical tsunami data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 41
    Publication Date: 2021-03-30
    Description: The dichotomy between explosive volcanic eruptions, which produce pyroclasts, and effusive eruptions, which produce lava, is defined by the presence or absence of fragmentation during magma ascent. For lava fountains the distinction is unclear, since the liquid phase in the rising magma may remain continuous to the vent, fragment in the fountain, then re-weld on deposition to feed rheomorphic lava flows. Here we use a numerical model to constrain the controls on basaltic eruption style, using Kilauea and Etna as case studies. Based on our results, we propose that lava fountaining is a distinct style, separate from effusive and explosive eruption styles, that is produced when magma ascends rapidly and fragments above the vent, rather than within the conduit. Sensitivity analyses of Kilauea and Etna case studies show that high lava fountains (〉50 m high) occur when the Reynolds number of the bubbly magma is greater than ∼0.1, the bulk viscosity is less than 10^6, and the gas is well-coupled to the melt. Explosive eruptions (Plinian and sub-Plinian) are predicted over a wide region of parameter space for higher viscosity basalts, typical of Etna, but over a much narrower region of parameter space for lower viscosity basalts, typical of Kilauea. Numerical results show also that the magma that feeds high lava fountains ascends more rapidly than the magma that feeds explosive eruptions, owing to its lower viscosity. For the Kilauea case study, waning ascent velocity is predicted to produce a progressive evolution from high to weak fountaining, to ultimate effusion; whereas for the Etna case study, small changes in parameter values lead to transitions to and from explosive activity, suggesting that eruption transitions may occur with little warning.
    Description: RCUK NERC DisEqm project
    Description: Published
    Description: 116658
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 42
    Publication Date: 2021-03-03
    Description: Groundwater resources constitute the main source of clean fresh water for domestic use and it is essential for food production in the agricultural sector. Groundwater has a vital role for water supply in the Campanian Plain in Italy and hence a future sustainability of the resource is essential for the region. In the current paper novel data mining algorithms including Gaussian Process (GP) were used in a large groundwater quality database to predict nitrate (contaminant) and strontium (potential future increasing) concentrations in groundwater. The results were compared with M5P, random forest (RF) and random tree (RT) algorithms as a benchmark to test the robustness of the modeling process. The dataset includes 246 groundwater quality samples originating from different wells, municipals and agricultural. It was divided for the modeling process into two subgroups by using the 10-fold cross validation technique including 173 samples for model building (training dataset) and 73 samples for model validation (testing dataset). Different water quality variables including T, pH, EC, HCO3-, F-, Cl-, SO42-, Na+, K+, Mg2+, and Ca2+ have been used as an input to the models. At first stage, different input combinations have been constructed based on correlation coefficient and thus the optimal combination was chosen for the modeling phase. Different quantitative criteria alongside with visual comparison approach have been used for evaluating the modeling capability. Results revealed that to obtain reliable results also variables with low correlation should be considered as an input to the models together with those variables showing high correlation coefficients. According to the model evaluation criteria, GP algorithm outperforms all the other models in predicting both nitrate and strontium concentrations followed by RF, M5P and RT, respectively. Result also revealed that model's structure together with the accuracy and structure of the data can have a relevant impact on the model's results.
    Description: Published
    Description: 136836
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Data mining; Gaussian process; Italy; Nitrate; Prediction; Strontium
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 43
    Publication Date: 2021-03-03
    Description: It has long since been noted that minor element (Me) partitioning into biogenic carbonates is sometimes different from Me partitioning into inorganically precipitated carbonates. The prime example is the partitioning coefficient, which might be lower or even higher than the one of inorganically precipitated carbonate. Such a difference is usually termed “vital effect” and is seen as indicative of a biologically modified minor element partitioning. Over the last three decades interest in conceptual biomineralization models compatible with minor element and isotope fractionation has been steadily increasing. However, inferring features of a biomineralization mechanism from Me partitioning is complicated, because not all partitioning coefficients show vital effects in every calcium carbonate producing organism. Moreover, the partitioning coefficient is not the only aspect of Me partitioning. Other aspects include polymorph specificity and rate dependence. Patellogastropod limpets are ideally suited for analysing Me partitioning in terms of biomineralization models, because they feature both aragonitic and calcitic shell parts, so that polymorph specificity can be tested. In this study, polymorph-specific partitioning of the minor elements Mg, Li, B, Sr, and U into shells of the patellogastropod limpet Patella caerulea from within and outside a CO2 vent site at Ischia (Italy) was investigated by means of LA-ICP-MS. The partitioning coefficients of U, B, Mg, and Sr (in aragonite) differed from the respective inorganic ones, while the partitioning coefficients of Li and Sr (in calcite) fell within the range of published values for inorganically precipitated carbonates. Polymorph specificity of Me partitioning was explicable in terms of inorganic precipitation in the case of Sr and Mg, but not Li and B. Seawater carbon chemistry did not have the effect on B partitioning that was expected on the basis of data on inorganic precipitates and foraminifera. Carbon chemistry did affect Mg (in aragonite) and Li, but only the effect on Mg was explicable in terms of calcification rate. On the one hand, these results show that Me partitioning in P. caerulea is incompatible with a direct precipitation of shell calcium carbonate from the extrapallial fluid. On the other hand, our results are compatible with precipitation from a microenvironment formed by the mantle. Such a microenvironment was proposed based on data other than Me partitioning. This is the first study which systematically employs a multi-element, multi-aspect approach to test the compatibility of Me partitioning with different conceptual biomineralization models.
    Description: Published
    Description: 218-229
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 44
    Publication Date: 2021-03-03
    Description: Groundwater resources are the main supply of freshwater for human activities. However, in the last fifty years aquifers have become more susceptible to chemical pollution due to human activities. The concept of groundwater vulnerability constitutes a worldwide accepted tool for water protection and planning. However, the existing methods and modified versions do not account for all the hydrogeochemical processes that drive anthropogenic pollution. The hydrogeochemical processes occurring within an aquifer can be determined using multivariate statistical analysis. In this study a specific vulnerability method named SVAP (Specific Vulnerability to Anthropogenic Pollution) is proposed. The index is based on seven quantitative parameters: depth to groundwater, recharge, nitrate losses, hydraulic resistance of the vadose zone, aquifer thickness, hydraulic conductivity of the aquifer, and slope. Weights of anthropogenic factors were determined by factor analysis and used to validate the SVAP methodology. The parameters' classification was selected according to the highest Pearson's correlation coefficient with factor weights and then grouped via a linear combination. The new index was applied in two watersheds: the Florina basin (Greece) and the Garigliano River basin (Italy), both of which possess complex hydrogeochemical regimes. The main hydrogeochemical processes acting in the study areas were identified via factor analysis, which revealed that the anthropogenic pollution in both sites was due mainly to chemical fertilizers and manure. Verification of the SVAP method produced correlation coefficients with nitrate concentrations of 0.75 and 0.62 in Florina and Garigliano, respectively. The proposed SVAP method is more reliable and flexible than standard vulnerability assessment methods and can be easily adapted for complex aquifers.
    Description: Published
    Description: 115386
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Anthropogenic pollution; Factor analysis; Florina basin; Garigliano plain; Groundwater protection; Mineralization processes
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 45
    Publication Date: 2021-05-12
    Description: In this study, the results of a continuous monitoring of (i) CO2 fluxes, and (ii) CO2 and CH4 concentrations and carbon isotopic ratios (δ13C-CO2 and δ13C-CH4) in air, carried out from 7 to 21 July 2017 and from October 10 to December 15, 2017 in the city centre of Florence, are presented. The measurements were performed from the roof of the historical building of the Ximenes Observatory. CO2 flux data revealed that the metropolitan area acted as a net source of CO2 during the whole observation period. According to the Keeling plot analysis, anthropogenic contributions to atmospheric CO2 were mainly represented by vehicular traffic (about 30%) and natural gas combustion (about 70%), the latter contributing 7 times more in December than in July. Moreover, the measured CO2 fluxes were about 80% higher in fall than in summer, confirming that domestic heating based on natural gas is the dominant CO2 emitting source in the municipality of Florence. Even though the continuous monitoring revealed a shift in the δ13C-CO2 values related to photosynthetic uptake of atmospheric CO2, the isotopic effect induced by plant activity was restricted to few hours in October and, to a lesser extent, in November. This suggests that urban planning policies should be devoted to massively increase green infrastructures in the metropolitan area in order to counterbalance anthropogenic emissions. During fall, the atmospheric CH4 concentrations were sensibly higher with respect to those recorded in summer, whilst the δ13C-CH4 values shifted towards heavier values. The Keeling plot analysis suggested that urban CH4 emissions were largely related to fugitive emissions from the natural gas distribution pipeline network. On the other hand, δ13C-CH4 monitoring allowed to recognize vehicular traffic as a minor CH4 emitting source.
    Description: Published
    Description: 134245
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Carbon isotopes; Cities; Greenhouse gases; Photosynthesis; Urban air quality
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 46
    Publication Date: 2021-05-12
    Description: The Late Quaternary benthic foraminiferal and ostracod assemblages from two continuous cores drilled in the Port of Salerno were studied to define their relationship with geochemical characteristics of the sediments and with the palaeoenvironmental evolution. The succession, ranging from Late Pleistocene to the 20th century, recorded the transition from a marine coastal environment under natural conditions to a depositional context affected by anthropogenic influence. In the lower part of the sequence, ecological and sedimentary changes were linked to sea-level changes due to Late Quaternary climatic phases, as well as to volcanic events such as the Campanian Ignimbrite eruption, represented by levels with high metal (Fe, Mn, Pb, Zn) concentrations, possibly leading to low pH phases. Later human activities, such as the construction of harbour facilities in the 18th century and the industrial development in the 19th century, influenced environmental variations, as shown in the upper part of the succession. High levels of heavy metal concentrations (Co, Cu, Fe, Pb, V) recorded in layers deposited in the 1800s suggest the presence of a pollution event which could be linked to manufacturing activities and might have occurred during the first part of the 19th century. Calcareous meiofaunal assemblages showed high diversity values, probably due to the occurrence of "rare short lived" species in an unstable environment. Assemblages were dominated by the foraminiferal species Ammonia aberdoveyensis and Haynesina depressula, and by the ostracods Pontocythere turbida and Semicytherura sulcata, which are considered as possibly stress-tolerant species.
    Description: Published
    Description: 101498
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Campania region (Italy) ; Late quaternary ; Benthic foraminifera ; Ostracoda ; Geochemistry ; Anthropogenic impact
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 47
    Publication Date: 2021-05-12
    Description: We present a review of the geomorphology of the Tyrrhenian Sea coast of central Italy integrated by a novel structural-geomorphological study coupled with statistical analysis of topographic culminations and comparison with a Digital Elevation Model, aimed at reconstructing a suite of paleo-surfaces corresponding to remnant portions of marine terraces. We performed geochronological, sedimentological, micromorphological and mineralogical investigations on the deposits forming the different paleo-surfaces between Civitavecchia and Anzio towns, in order to provide chronostratigraphical, paleogeographical and paleoenvironmental constraints. Using the newly achieved dataset we correlate these paleo-surfaces with the coastal terraces formed during past sea-level highstands, as recognized by previous studies, and we refine their correlation with the Marine Isotope Stage (MIS) timescale. In particular, we have extended our geomorphological analyses landward in the area between the Tiber River mouth and Anzio, in order to include the oldest paleo-surface developed above the deposits of the last large explosive eruption at 365 ± 4 ka in the Colli Albani Volcanic District. Results of this study allow us to recognize a set of higher paleo-surfaces at elevation ranging 108 thought 71 m a.s.l., which we interpret as one tectonically displaced, widespread coastal terrace originated during the MIS 9.1 highstand. We correlate the previously identified paleo-surfaces of 66–62 m a.s.l. and 56–52 m a.s.l. with the equivalent coastal terraces developed during the sea-level highstands of sub-stages 7.5 and 7.3/7.1. Moreover, based on data from literature on relative elevation of maximum sea level during the highstands of MIS 11 through MIS 5.1, we assess the regional uplift and the concurrent tectonic displacements that have occurred since 900 ka in this area.
    Description: Published
    Description: 106843
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 48
    Publication Date: 2021-05-12
    Description: CCS communication has proven a tough challenge, particularly for the difficulty in raising interest for the technology, which is still unknown to the majority of the population, and for the complexity of conveying information about its potential for reducing emissions. In this paper, we present a research based effort for bringing CCS nearer to people, through visual material developed taking into account emotional needs related to the technology. The production of a short introductory film on CCS is illustrated and its testing with a sample of 700 high school students.
    Description: Published
    Description: 7367 – 7378
    Description: 2TM. Divulgazione Scientifica
    Description: JCR Journal
    Keywords: CCS communication ; public perception ; 05.03. Educational, History of Science, Public Issues
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 49
    Publication Date: 2021-05-12
    Description: National Italian funding has recently been allocated for the construction of a 350 MWe coal-fired power plant / CCS demonstration plant in the Sulcis area of SW Sardinia, Italy. In addition, the recently approved EC-funded ENOS project (ENabling Onshore CO2 Storage in Europe) will use the Sulcis site as one of its main field research laboratories. Site characterization is already ongoing, and work has begun to design gas injection experiments at 100-200 m depth in a fault. This article gives an overview of results to date and plans for the future from the Sapienza University of Rome research group.
    Description: Published
    Description: 2742 – 2747
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: gas injection experiment ; monitoring baseline ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 50
    Publication Date: 2021-05-12
    Description: Continuous monitoring has been carried out at a fluvial flood-plain site near Rome for over a year. There is a mix of biogenic CO2 and deep geogenic CO2 at the site at relatively low concentrations and fluxes compared with other natural CO2 seepage sites studied previously. Factors such as temperature and soil moisture clearly affect the CO2 concentration and flux and seasonal and diurnal influences are apparent. Statistical approaches are being used to try to define these relationships and separate out the two gas components, which would be necessary in any quantification of leakage from CO2 storage.
    Description: Published
    Description: 3824 – 3831
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Continuous monitoring ; natural co2 release ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 51
    Publication Date: 2021-05-12
    Description: The Sulcis Basin is an area situated in SW Sardinia (Italy) and is a potential site for the development of CCS in Italy. This paper illustrates the preliminary results of geological characterization of fractured carbonate reservoir (Miliolitico Fm.) and the sealing sequence, composed by clay, marl, and volcanic rocks, with a total thickness of more than 900 m. To characterize the reservoir-caprock system an extensive structural-geological survey at the outcrop was conducted. It was also performed a study of the geochemical monitoring, to define the baseline conditions, measuring CO2 concentrations and flux in the study site.
    Description: Published
    Description: 549–555
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: CCS ; geochemical monitoring ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 52
    Publication Date: 2021-05-12
    Description: 3D geological models from multi-source data (cross-sections, geological maps, borehole logs and outcrops) are a critical tool to improve the interpretation of the spatial organization of subsurface structures that are not directly accessible. In this paper, we reconstruct the main geological structures and surfaces in three dimensions through the interpolation of closely and regularly spaced 2D seismic sections, constrained by wells data and surface geology. The methodology was applied in the Marche–Abruzzi sector of the Periadriatic basin, where the more external part of the Apennines fold-and-thrust belt is mostly buried under a syn- and post-orogenic, Plio–Pleistocene, siliciclastic sequence. The 3D model allowed us to correlate the main thrust fronts and related anticlines along strike, revealing a general ramp – flat – ramp trajectory characterizing the main structural trends. This geometric organization influences the sequence of thrust-system propagation and characterizes the evolution of syntectonic basins. The obtained 3D model points out several variation occurring along strike: i) main trends geometric relationships; ii) deformation chronology and iii) displacement distribution. In the northern sector, higher displacement and structural elevation are reached out by the Nereto–Bellante structure, whereas in the southern sector the Villadegna–Costiera Structure is the prevalent. All structures show a diachronic thrusts activity along strike, younger toward the north.
    Description: Published
    Description: 107-121
    Description: 9T. Geochimica dei fluidi applicata allo studio e al monitoraggio di aree sismiche
    Description: JCR Journal
    Keywords: 3d modeling ; structural geology ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 53
    Publication Date: 2021-05-12
    Description: Although CO2 capture and storage in deep, offshore reservoirs is a proven technology, as illustrated by over 15 years of operation of the Sleipner site in the Norwegian North Sea, potential leakage from such sites into the overlying water column remains a concern for some stakeholders. Therefore, we are obliged to carefully assess our ability to predict and monitor the migration, fate, and potential ecosystem impact of any leaked CO2. The release of bubbles from the sea floor, their upward movement, and their dissolution into the surrounding water controls the initial boundary conditions, and thus an understanding of the behavior of CO2 bubbles is critical to address such issues related to monitoring and risk assessment. The present study describes results from an in situ experiment conducted in 12 m deep marine water near the extinct volcanic island of Panarea (Italy). Bubbles of a controlled size were created using natural CO2 released from the sea floor, and their evolution during ascent in the water column was monitored via both video and chemical measurements. The obtained results were modelled and a good fit was obtained, showing the potential of the model as a predictive tool. These preliminary results and an assessment of the difficulties encountered are examined and will be used to improve experimental design for the subsequent phase of this research.
    Description: Published
    Description: 397–403
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: in situ bubble experiment ; CO2 ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 54
    Publication Date: 2021-05-12
    Description: The major processes that control the genesis of potassic volcanic rocks, like the timing of multi-stage mantle metasomatism, remain largely unclear. In an attempt to clarify the timing of the metasomatic process, a detailed geochronologic and geochemical study has been conducted on the ultrapotassic rocks of the Colli Albani Volcanic District (Central Italy). New 40Ar/39Ar data coupled with literature and newly performed 87Sr/86Sr, 143Nd/144Nd and chemical data allow us to precisely delineate the time-dependent geochemical variations of the magmas erupted at the Colli Albani Volcanic District and to better define mantle source processes responsible for their genesis. The temporal geochemical variations observed in the Colli Albani magmas indicate that: i) the ultrapotassic magmas originated from a metasomatized mantle source in which phlogopite is the potassium-bearing phase; ii) the partial melting of the mantle source involved mainly phlogopite and clinopyroxene (±olivine), whereas the role of accessory phases was less significant; and iii) the metasomatic process that led to the formation of the phlogopite in the mantle can be reasonably related to events that have occurred during the Paleozoic Era
    Description: Published
    Description: 151-164
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Mantle metasomatism ; Phlogopite ; Ultrapotassic magmas ; Colli Albani Volcanic District
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 55
    Publication Date: 2021-05-12
    Description: The Neapolitan volcanic area (Southern Italy), which includes the Phlegrean Volcanic District and the Somma– Vesuvius complex, has been the site of intense Plio-Quaternary magmatic activity and has produced volcanic rocks with a subduction-related geochemical and isotopic signature. High-Mg, K-basaltic lithic lava fragments dispersed within hydromagmatic tuff of the Solchiaro eruption (Procida Island) provide constraints on the nature and role of both the mantle source prior to enrichment and the subduction-related components. The geochemical data (Nb/Yb, Nb/Y, Zr/Hf) indicate a pre-enrichment source similar to that of enriched MORB mantle. In order to constrain the characteristics of subducted slab-derived components added to this mantle sector, new geochemical and Sr–Nd-isotopic data have been acquired on meta-sediments and pillow lavas from Timpa delle Murge ophiolites. These represent fragments of Tethyan oceanic crust (basalts and sediments) obducted during the Apennine orogeny, and may be similar to sediments subducted during the closure of the Tethys Ocean. Based on trace element compositions (e.g., Th/Nd, Nb/Th, Yb/Th and Ba/Th) and Nd-isotopic ratio, we hypothesize the addition of several distinct subducted slab-derived components to the mantle wedge: partial melts from shales and limestones, and aqueous fluids from shales, but the most important contribution is provided by melts from pelitic sediments. Also, trace elements and Sr–Nd-isotopic ratios seem to rule out a significant role for altered oceanic crust. Modeling based on variations of trace elements and isotopic ratios indicates that the pre-subduction mantle source of the Phlegrean Volcanic District and Somma–Vesuvius was enriched by 2–4% of subducted slab-derived components. This enrichment event might have stabilized amphibole and/or phlogopite in the mantle source. 6% degree of partial melting of a phlogopite-bearing enriched source, occurring initially in the garnet stability field and then in the spinel stability field can generate a melt with trace elements and Sr– Nd-isotopic features matching those of high-Mg, K-basalts of Procida Island. Furthermore, 2% partial melting of the same enriched source can reproduce the trace elements and isotopic features of the most primitive magmas of Somma–Vesuvius, subsequently modified by assimilation of continental crust during fractional crystallization processes at mid-lower depth. Combined trace element and Sr–Nd isotope modeling constrains the age of the enrichment event to 45 Ma ago, suggesting that the Plio-Quaternary magmatism of the Neapolitan area is postorogenic, and related to the subduction of oceanic crust belonging to the Tethys Ocean
    Description: Published
    Description: 165-183
    Description: 2T. Deformazione crostale attiva
    Description: 3T. Sorgente sismica
    Description: 4T. Sismicità dell'Italia
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Neapolitan volcanic area ; Phlegrean Volcanic District ; Somma–Vesuvius complex ; Basilicata ophiolites
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 56
    Publication Date: 2021-05-12
    Description: Persistent degassing of closed-conduit explosive volcanoes may be used to inspect and monitor magmatic processes. After interaction with shallow hydrothermal fluids, volcanic gases collected at surface can differ substantially from those exsolved from magma. We report here on an innovative approach to identify and separate the contribution of variable magmatic components from fumarolic gases, by processing the 30-year-long geochemical dataset from the Campi Flegrei caldera, Southern Italy. The geochemical record shows periodic variations, which are well correlated with geophysical signals. Such variations are interpreted as due to the time-varying interplay of two magma degassing sources, each differing in size, depth, composition, and cooling/crystallization histories. Similar multiple degassing sources are common at explosive volcanoes, with frequent ascent and intrusion of small magma batches. Our innovative method permits the identification of those magma batches, which contributes to the interpretation of unrest signals, forecasting and assessment of volcanic hazards
    Description: Published
    Description: 95-104
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: magmatic degassing ; hydrothermal systems ; explosive volcanism ; isotopic inversion
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 57
    Publication Date: 2021-05-06
    Description: Renewed seismic activity of Cotopaxi, Ecuador, began in January 2001 with the increased number of long-period (LP) events, followed by a swarm of volcano-tectonic (VT) earthquakes in November 2001. In late June 2002, the activity of very-long-period (VLP) (2 s) events accompanying LP (0.5–1 s) signals began beneath the volcano. The VLP waveform was characterized by an impulsive signature, which was accompanied by the LP signal showing non-harmonic oscillations. We observed temporal changes of both the VLP and LP signals from the beginning until September 2003: The VLP signal gradually disappeared and the LP signal characterized by decaying harmonic oscillations became dominant. Assuming possible source geometries, we applied a waveform inversion method to the observed waveforms of the largest VLP event. Our inversion and particle motion analyses point to volumetric changes of a sub-vertical crack as the VLP source, which is located at a depth of 2–3 km beneath the northeastern flank. The spectral analysis of the decaying harmonic oscillations of LP events shows frequencies between 2.0 and 3.5 Hz, with quality factors significantly above 100. The increased VT activity and deformation data suggest an intrusion of magma beneath the volcano. A release of gases with small magma particles may have repetitively occurred due to the pressurization, which was caused by sustained bubble growth at the magma ceiling. The released particle-laden gases opened a crack above the magma system and triggered the resonance of the crack. We interpret the VLP and LP events as the gas-release process and the resonance of the crack, respectively.
    Description: Published
    Description: 119–133
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 58
    Publication Date: 2021-05-06
    Description: Guagua Pichincha, located 14 km west of Quito, Ecuador, is a stratovolcano bisected by a horseshoe-shaped caldera. In 1999, after some months of phreatic activity, Guagua Pichincha entered into an eruptive period characterized by the extrusion of several dacitic domes, vulcanian eruptions, and pyroclastic flows. We estimated the three-dimensional (3-D) P-wave velocity structure beneath Guagua Pichincha using a tomographic inversion method based on finite-difference calculations of first-arrival times. Hypocenters of volcano-tectonic (VT) earthquakes and long-period (LP) events were relocated using the 3-D P-wave velocity model. A low-velocity anomaly exists beneath the caldera and may represent an active volcanic conduit. Petrologic analysis of eruptive products indicates a magma storage region beneath the caldera, having a vertical extent of 7–8 km with the upper boundary at about sea level. This zone coincides with the source region of deeper VT earthquakes, indicating that a primary magma body exists in this region. LP swarms occurred in a cyclic pattern synchronous with ground deformation during magma extrusions. The correlation between seismicity and ground deformation suggests that both respond to pressure changes caused by the cyclic eruptive behavior of lava domes.
    Description: Published
    Description: 333–351
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 59
    Publication Date: 2021-06-22
    Description: Rare Earth Elements (REE; lanthanides and yttrium) are elements with high economic interest because they are critical elements for modern technologies. This study mainly focuses on the geochemical behavior of REE in hyperacid sulphate brines in volcanic-hydrothermal systems, where the precipitation of sulphate minerals occurs. Kawah Ijen lake, a hyperacid brine hosted in the Ijen caldera (Indonesia), was used as natural laboratory. ∑REE concentration in the lake water is high, ranging from 5.86 to 6.52 mg kg-1. The REE pattern of lake waters normalized to the average local volcanic rock is flat, suggesting isochemical dissolution. Minerals spontaneously precipitated in laboratory at 25 °C from water samples of Kawah Ijen were identified by XRD as gypsum. Microprobe analyses and the chemical composition of major constituents allow to identify possible other minerals precipitated: jarosite, Al-sulphate and Sr, Ba-sulphate. ∑REE concentration in minerals precipitated (mainly gypsum) range from 59.53 to 78.64 mg kg-1. The REE patterns of minerals precipitated normalized to the average local magmatic rock show enrichment in LREE. The REE distribution coefficient (KD), obtained from a ratio of its concentration in the minerals precipitated (mainly gypsum) and the lake water, shows higher values for LREE than HREE. KD-LREE/KD-HREE increases in the studied samples when the concentrations of BaO, MgO, Fe2O3, Al2O3, Na2O and the sum of total oxides (except SO3 and CaO) decrease in the solid phase. The presence of secondary minerals different than gypsum can be the cause of the distribution coefficient variations. High concentrations of REE in Kawah Ijen volcanic lake have to enhance the interest on these environments as possible REE reservoir, stimulating future investigations. The comparison of the KD calculated for REE after mineral precipitation (mainly gypsum) from Kawah Ijen and Poás hyperacid volcanic lakes allow to generalize that the gypsum precipitation removes the LREE from water.
    Description: Published
    Description: 140133
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: 2IT. Laboratori analitici e sperimentali
    Description: JCR Journal
    Keywords: Gypsum precipitation ; Rare Earth Elements ; Hyperacid crater lake ; Kawah Ijen volcano ; Poás volcano ; REE fractionation ; Geochemistry ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 60
    Publication Date: 2021-06-22
    Description: Major, minor and rare earth elements were analyzed in the acid sulphate - chloride thermal springs associated to Puracé volcano – hydrothermal system. The waters of Puracé were classified in 2 different groups as a function of the physico-chemical parameters and element distributions. Group 1 is characterized by the highest pH (⁓ 3.5), an outlet temperature of ⁓ 81 °C and a strong depletion of Fe, Al, Si and Ba with respect to the isochemical dissolution of the average volcanic local rock. Group 2 waters have lower pH values ⁓ 1.9 and temperature (⁓ 48 °C) compared with Group 1. Moreover, Group 2 is not characterized by a typical pathway representing the congruent dissolution of the rock and shows a distribution of major and minor elements that is more close to the near-congruent dissolution of the average volcanic local rock with respect to Group 1. These geochemical features of major and minor elements allow to propose that the chemical composition of the waters of Group 1 is strongly affected by the precipitation of secondary minerals such as alunite, jarosite, kaolinite, barite and polymorphs of SiO2. The grouping of waters is also supported by the distribution of dissolved REE normalized to the average volcanic local rock. Group 1 shows REE patterns strongly depleted in light rare earth elements (LREE), typical of water that formed alunitic and/or kaolinitic rocks. On the contrary, Group 2 is characterized by flat patterns, in according to the near-congruent dissolution of the rocks. REE dissolved in waters of Puracé were compared with REE in the acidic waters of Nevado del Ruiz and Azufral Colombian volcanoes and with REE in minerals recognized in advanced argillic alteration (alunite, gypsum and kaolinite). Precipitation of secondary minerals is proposed as a common process depleting LREE in acidic sulphate – chlorine waters in volcano – hydrothermal systems. Furthermore, the chemical fractionation of the major and minor elements was interpreted together with the corresponding distributions of REE in order to trace the water – rock interaction processes. Saturation indexes of most common secondary minerals identified in advanced argillic alterations were calculated using PHREEQC software in a range of temperature from 25 to 250 °C. This geochemical approach allows to identify the possible mineral precipitation or dissolution of secondary minerals as well as the temperature at which the water reached equilibrium with a given set of minerals. In Group 1, the precipitation of secondary minerals LREE enriched (alunite minerals and kaolinite) was traced at temperature of precipitation higher than ⁓ 101 °C.
    Description: Published
    Description: 107106
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Puracé volcano Acidic waters Rare Earth elements fractionation Advanced argillic alteration Alunite Kaolinite ; 04.08. Volcanology ; 05. General ; Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 61
    Publication Date: 2021-06-21
    Description: During the August 25, 2018 geomagnetic storm, the new borne CSES-01 satellite and the Swarm A satellite detected a really large equatorial plasma bubble (EPB) in the post-midnight sector over western Africa. We investigated the features of this deep ionospheric plasma depletion using data from the Langmuir probes on-board CSES-01 and Swarm A satellites, and data from the high-precision magnetometer and the electric field detector instruments on-board CSES-01. Using also plasma and magnetic field data from THEMIS-E satellite we found that, during the passage of the magnetic cloud that drove the geomagnetic storm, an impulsive variation lasting about ten minutes characterized the solar wind (SW) pressure. The analysis of the delay time, between the occurrence of such impulsive variation and the detection of the plasma bubble, suggests a possible link between the SW pressure impulsive variation as identified by THEMIS-E and the generation of the EPB as detected by CSES-01 and Swarm A. We put forward the hypothesis that the SW pressure impulsive variation might have triggered an eastward prompt penetrating electric field that propagated from high to equatorial latitudes, overlapping in the nightside region to the zonal westward electric field, causing either a reduction or an inversion, at the base of the EPB triggering.
    Description: Published
    Description: 35-45
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: 2A. Fisica dell'alta atmosfera
    Description: 5IT. Osservazioni satellitari
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 62
    Publication Date: 2021-06-21
    Description: The purpose of this review study is to reappraise in a more comprehensive form the thermodynamic principles behind the partitioning of trace elements between clinopyroxene and melt. The original corollary is that the partitioning energetics controlling the crystal-melt exchange are described by two distinct but complementary contributions: ΔGpartitioning = ΔGstrain + ΔGelectrostatic. ΔGstrain is the excess of strain energy quantifying the elastic response of the crystallographic site to insertion of trace cations with radius different from that of the major cation at the site. ΔGelectrostatic is the excess of electrostatic energy requiring that an electrostatic energy penalty is paid when a trace cation entering the lattice site without strain has charge different from that of the resident cation. Lattice strain and electrostatic parameters for different isovalent groups of cations hosting the same lattice site from literature have been discussed in comparison with new partitioning data measured between Tschermak-rich clinopyroxenes and a primitive phonotephritic melt assimilating variable amounts of carbonate material. Through such a comparatively approach, we illustrate that the type and number of trace cation substitutions are controlled by both charge-balanced and -imbalanced configurations taking place in the structural sites of Tschermak-rich clinopyroxenes. A virtue of this complementary relationship is that the control of melt composition on the partitioning of highly charged cations is almost entirely embodied in the crystal chemistry and structure, as long as these crystallochemical aspects are the direct expression of both ΔGstrain and ΔGelectrostatic. A size mismatch caused by cation substitution is accommodated by elastic strain in the surrounding lattice of clinopyroxene, whereas the charge mismatch is enabled via increasing amounts of charge-balancing Tschermak components, as well as the electrostatic work done on transferring the trace cations from melt to crystallographic sites, and vice versa. The influence of the melt chemistry on highly-charged (3+ and 4+) cation partitioning is greatly subordinate to the lattice strain and electrostatic energies of substitutions, in agreement with the thermodynamic premise that both these energetic quantities represent simple-activity composition models for the crystal phase. The various charge-balanced and -imbalanced configurations change principally with aluminium in tetrahedral coordination and the clinopyroxene volume change produced by heterovalent cation substitutions. In contrast, for low-charged (1+ and 2+) cations, the role of melt chemistry cannot be properly deconvoluted from the structural changes of the crystal lattice. The incorporation of these cations into the clinopyroxene lattice depends on the number of structural sites critically important to accommodating network-modifying cations in the melt structure, implying that the partitioning energetics of monovalent and divalent cations are strictly controlled by both crystal and melt properties. We conclude that the competition between charge-balanced and charge-imbalanced substitutions may selectively change the ability of trace elements to be compatible or incompatible in the clinopyroxene structure, with important ramifications for the modeling of natural igneous processes in crustal magma reservoirs which differentiate under closed- and open-system conditions.
    Description: Published
    Description: 103351
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 63
    Publication Date: 2020-10-06
    Description: The partitioning of carbon dioxide (CO〈sub〉2〈/sub〉) released by soils at Vulcano Island (Aeolian Islands, Italy) was performed by combining the CO〈sub〉2〈/sub〉 flux and the carbon isotope measurements. Based on this method, the amount of CO〈sub〉2〈/sub〉 of volcanic origin was quantified six times during the period 2015–2018. The data analysis allowed us to establish the correlation between CO〈sub〉2〈/sub〉 soil degassing and changes in the contribution of volcanic fluids. Carbon isotope determinations were performed in situ to enhance the coverage of data collection in space and time. These data were combined with both the CO〈sub〉2〈/sub〉 contents in the ground gases and the soil CO〈sub〉2〈/sub〉 flux. The amount of volcanic CO〈sub〉2〈/sub〉 was distinguished from that of biogenic origin by implementing a three-component mixing model. The results of this study indicate that the increase in CO〈sub〉2〈/sub〉 output in September 2018 reflects the increase in volcanic gas emissions. The measurement method and analysis presented in this work are sufficiently general to be applicable to the monitoring programs of active volcanoes.
    Description: Published
    Description: 106972
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: Carbon dioxide ; CO2 flux ; CO2 isotope composition ; Volcano monitoring ; Volcanic unrest ; Volcanic degassing ; 04. Solid Earth ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 64
    Publication Date: 2020-10-16
    Description: Calderas are topographic depressions formed by the collapse of a partly drained magma reservoir. At volcanic edifices with calderas, eruptive fissures can circumscribe the outer caldera rim, be oriented radially and/or align with the regional tectonic stress field. Constraining the mechanisms that govern this spatial arrangement is fundamental to understand the dynamics of shallow magma storage and transport and evaluate volcanic hazard. Here we show with numerical models that the previously unappreciated unloading effect of caldera formation may contribute significantly to the stress budget of a volcano. We first test this hypothesis against the ideal case of Fernandina, Galápagos, where previous models only partly explained the peculiar pattern of circumferential and radial eruptive fissures and the geometry of the intrusions determined by inverting the deformation data. We show that by taking into account the decompression due to the caldera formation, the modeled edifice stress field is consistent with all the observations. We then develop a general model for the stress state at volcanic edifices with calderas based on the competition of caldera decompression, magma buoyancy forces and tectonic stresses. These factors control: 1) the shallow accumulation of magma in stacked sills, consistently with observations; 2) the conditions for the development of circumferential and/or radial eruptive fissures, as observed on active volcanoes. This top-down control exerted by changes in the distribution of mass at the surface allows better understanding of how shallow magma is transferred at active calderas, contributing to forecasting the location and type of opening fissures.
    Description: Published
    Description: 257-293
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 65
    Publication Date: 2020-11-18
    Description: Highlights -Gas blowouts from water wells are frequent in the southeastern zone of Rome -Emitted gas killed some pets and families had to be evacuated for security reasons -Gas has a magmatic origin with the highest helium R/Ra of Colli Albani gas discharges -Monitoring of soil CO2 flux and air gas concentration allowed to assess gas hazard -Gas diffusing in soil reached nearby houses creating dangerous indoor conditions
    Description: The southeastern zone of Rome city is located at the northwest periphery of the quiescent Colli Albano volcano. This zone is characterized by the presence of a shallow (depth ~ 45–50 m) gas pressurized aquifer that produces gas blowouts when it is reached by wells. Three gas blowouts occurred in this zone in 2003, 2008 (another one was discovered during the present study) and 2016 and in this paper we describe in detail the latter two. The emitted gas consists mostly of CO2 (〉90 vol%) and contains a low but significant quantity of H2S (0.3–0.5 vol%) and it has the highest helium isotopic R/Ra value (1.90) of all Colli Albani natural gas discharges, suggesting its likely magmatic origin. In both the described gas blowouts, dozens of families had to be prudentially evacuated from their houses and the emitted gas killed some animals. We monitored, continuously or by discrete surveys, the soil CO2 flux, the indoor and outdoor air concentration of CO2 and H2S, the environmental parameters and we checked whether the cementation of the gas releasing wells had been effective. In both cases, the upper part of the wells had been partly closed with an inflating packer to avoid free gas dispersion in atmosphere; as a consequence gas diffused laterally from the wells into the permeable surficial soil up to reach the nearest houses creating hazardous indoor conditions, particularly for CO2 in some basements. During the well cementation operations, and in one case because of the packer rupture, gas and nebulized water were freely discharged from the wells into the atmosphere, and high air CO2 and H2S concentrations were found. Fortunately gas was quickly dispersed by strong winds. The positive results obtained in all the studied gas blowouts demonstrate that our applied geochemistry approach represents a model of intervention useful for the assessment of the hazard associated to accidental endogenous gas release. This model is of fundamental importance also to overcome the risk problems created by accidental gas blowout from wells in an urbanized environment, up to the safe return of the people in their evacuated houses.
    Description: Published
    Description: 104769
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: Rome gas blowouts zone ; Hazard assessment of endogenous gas blowouts from wells ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 66
    Publication Date: 2020-11-23
    Description: In the world, volcanic systems exhibit a wide range of eruption styles threatening the lives of millions of people. Relatively slow effusive eruptions generate lava flows (low viscosity magma) and lava domes (high viscosity magma) and tend to evolve over days to decades. Alternatively, explosive eruptions can inject very large volumes of fragmented magma and volcanic gas high into the atmosphere over shorter periods (minutes to weeks to months). Mitigation of the associated risk to populations, the built environment, and the cultural heritage relies upon our ability to accurately assess volcanic hazards, and this, in turn, depends on our understanding of the processes that control the style and scale of volcanic eruptions. To this end, technological developments over the last couple of decades have greatly improved our ability to characterize magmatic systems and detect precursors at high spatial and temporal resolution through the use of analytical and observational volcanology, including monitoring-derived data, and volcano geophysics. Numerical modeling of magma ascent can serve to link all of these data and processes to build effective near-real-time strategies. The complexity of the volcanic system, derived from the multiphase, multicomponent character of the magmatic mixtures and from their interaction dynamics with the surrounding host rocks, is however manifested in the complexity of its mathematical representation, and numerical models able to describe several interdependent processes, eventually at disequilibrium conditions, are required to capture the nature of volcanic systems with fidelity. In this chapter, we present the main equations governing magma ascent, highlighting the multiphase and disequilibrium nature of volcanic flows, and the presence of complex feedback mechanisms between gas exsolution, outgassing, and crystallization that are able to influence the most important characteristics of the resulting volcanic events. Then, a suite of numerical simulations is described to show the effect of some parameters and processes in controlling eruption style and scale, and thus the potential eruption hazard.
    Description: Published
    Description: 239-284
    Description: 5V. Processi eruttivi e post-eruttivi
    Keywords: 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 67
    Publication Date: 2020-11-25
    Description: Active lava lakes – as the exposed upper part of magmatic columns – are prime locations to investigate the conduit flow processes operating at active, degassing volcanoes. Persistent lava lakes require a constant influx of heat to sustain a molten state at the Earth's surface. Several mechanisms have been proposed to explain how such heat transfer can operate efficiently. These models make contrasting predictions with respect to the flow dynamics in volcanic conduits and should result in dissimilar volatile emissions at the surface. Here we look at high-frequency SO2 fluxes, plume composition, thermal emissions and aerial video footage from the Villarrica lava lake in order to determine the mechanism sustaining its activity. We found that while fluctuations are apparent in all datasets, none shows a stable periodic behaviour. These observations suggest a continuous influx of volatiles and magma to the Villarrica lava lake. We suggest that ascending volatile-rich and descending degassed magmas are efficiently mixed within the volcanic conduit, resulting in no clear periodic oscillations in the plume composition and flux. We compare our findings to those of other lava lakes where equivalent gas emission time-series have been acquired, and suggest that gas flux, magma viscosity and conduit geometry are key parameters determining which flow mechanism operates in a given volcanic conduit. The range of conduit flow regimes inferred from the few studied lava lakes gives a glimpse of the potentially wide spectrum of conduit flow dynamics operating at active volcanoes.
    Description: This research was conducted as part of the “Trail By Fire” expedition (PI: Y. Moussallam). The project was supported by the Royal Geographical Society (with the Institute of British Geographers) with the Land Rover Bursary; the Deep Carbon Observatory DECADE Initiative; Ocean Optics; Crowcon; Air Liquide; Thermo Fisher Scientific; Santander; Cactus Outdoor; Turbo Ace and Team Black Sheep. We thank Sebastien Carretier and Rose-Marie Ojeda together with IRD South-America personnel for all their logistical help. We further thank the CONAF and DGAC for their help. YM acknowledges support from the Scripps Institution of Oceanography Postdoctoral Fellowship program. CIS acknowledges a research startup grant from Victoria University of Wellington
    Description: Published
    Description: 237-247
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: volcanic degassing ; Multi-GAS ; UAV ; Trail By Fire ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 68
    Publication Date: 2020-11-25
    Description: In this paper a new approach for processing arrays of data is proposed. It is based on fuzzy logic and the concepts of cellular computation. Arrays of simple, identical processing elements (called fuzzy cells) are defined by using fuzzy rules. Moreover, each fuzzy cell interacts with its local neighbors. The overall behavior of these locally interacting fuzzy systems is used to process arrays of data. Some examples of practical applications are proposed. Among these, the new approach is applied to image-processing problems, and to the simulation of heat diffusion phenomena.
    Description: This work was partially supported by the Italian National Research Council (C.N.R.) under the special project "Reti neurali per i sistemi di controllo".
    Description: Published
    Description: 47-52
    Description: 3IT. Calcolo scientifico
    Description: JCR Journal
    Keywords: fuzzy logic ; partial differential equations ; 05.09. Miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 69
    Publication Date: 2020-11-13
    Description: A review of seismic methods for monitoring and understanding active volcanoes
    Description: Published
    Description: 4V. Processi pre-eruttivi
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 70
    Publication Date: 2021-01-14
    Description: In this study, we present new mineralogical and petrological data from fifteen eruptive products erupted at Vulcano Island (Aeolian Arc, Italy) over a period of time from 54 to 8 ka and representative of the Eruptive Epochs from 5 to 8 of this volcanic system. These rocks show shoshonitic (SHO) to high-K calc-alkaline (HKCA) affinity, with compositions changing from primitive basalts-shoshonites (Mg#35–60) to intermediate latites (Mg#32–54) to evolved trachytes-rhyolites (Mg#23–40). The intensive variables driving the crystallization path of magmas were reconstructed through mineral-melt equilibrium and thermodynamic models, as well as barometers, thermometers, hygrometers and oxygen barometers. The stability of olivine (Fo59–91), as first phase on the liquidus, is more favored at low-P (100–300 MPa) and high-H2O (4 wt%) contents dissolved in the melt. Afterwards, the melt is co-saturated with clinopyroxene (Mg#92, diopside), whose composition progressively evolves (Mg#71, augite) as the temperature decreases to 1100 °C. The crystallization pressure recorded by clinopyroxene decreases from basalts (550–750 MPa) to shoshonites-latites-trachytes (100–450 MPa) to rhyolites (~50 MPa). The melt-H2O content (0.5–4.2 wt%) is sensitive to either pressure or melt composition, thereby controlling the plagioclase stability and chemistry (An13–77) within a thermal path of ~860–1100 °C. Titanomagnetite (Usp11–39) equilibrates with progressively more oxidized melts as the magma composition changes from basalt (ΔQFM+1.5) to rhyolite (ΔQFM+3). Mass balance calculations and trace element modeling indicate that basaltic to trachytic magmas are prevalently controlled by fractional crystallization processes, in concert with variable degrees of assimilation of crustal rocks. Conversely, rhyolitic and highly differentiated trachytic magmas are generated by extraction of interstitial melts from shallow mush zones dominated by feldspar and titanomagnetite saturation. We conclude that the architecture of the plumbing system at Vulcano Island is characterized by multiple reservoirs in which compositionally distinct magmas pond and undergo polybaric-polythermal differentiation, before erupting to the surface.
    Description: Published
    Description: 105715
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 71
    Publication Date: 2021-01-07
    Description: This work focuses on site response analyses in the Amatrice area (Central Italy), taking advantage of the 3A temporary seismic network, installed after the first shock (MW 6.0) of the 2016–2017 seismic sequence, and of a detailed site characterization. Classical empirical methods are applied on seismic signals to evaluate their capabilities to infer site response parameters. For about one-third of the stations, the H/V method fails in estimating the empirical SSR amplification function, as a consequence of the vertical amplification. Although the majority of sites belong to the EC8-B soil category, all the empirical methods show great variability in the site responses. For this reason, to find common features among the sites we perform a cluster analysis on SSR functions finding 5 clusters characterized by three site parameters: VS,30, f0 and Af0 (i.e microtremor H/V amplitude at f0). This result seems promising for site response estimation in Central Italy from velocity profiles and noise measurements.
    Description: Published
    Description: 106565
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 72
    Publication Date: 2021-01-07
    Description: In this chapter, some scintillation models are described, taking into account of the dynamical nature of the Earth's ionosphere and its “complexity.” After a short description of the problem, a detailed explanation is provided about the propagation model named WAM, after its authors Wernik, Alfonsi, and Materassi. WAM is a propagation model based on a phase screen approach, where the statistical characteristics of the screen are constructed according to in situ data of ionospheric irregularities. Then, the Ground-Based Scintillation Climatology (GBSC) model is presented; this is a tool based on a wide statistical database from high performance receivers.
    Description: Published
    Description: 277-299
    Description: 2A. Fisica dell'alta atmosfera
    Keywords: 01.02. Ionosphere
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 73
    Publication Date: 2021-01-04
    Description: Central Italy was affected by a long seismic sequence in 2016 and 2017, characterized by five main-shocks with Mw〉5.0. The Mw 6.5 mainshock occurred on 30 October 2016 close to the town of Norcia, located in the intra-Apennine Norcia basin. Different degrees of damages were observed during this seismic crisis, caused by a variable seismic shaking. This was also due to important 1D and 2D variation of Quaternary fluvio-lacustrine sediments infilling the basin. Following such considerations, a new geophysical dataset of seismic vibration measurements was acquired in the study area during the period April 2017-November 2019. We collected mainly single-seismic station noise data, to infer the distribution of resonance frequency (f0) of the basin. A total of 60 sites were measured to cover the entire extension in the basin. We deployed seismometers along three transects of a total length of 21 km, mostly along the main structural directions of the basin (i.e. NNW-SSE and NE-SW). Two 2D arrays of seismic stations with a elicoidal-shaped geometry, and a set of MASW active data were also acquired in the northern sector of the basin, in order to better constrain the seismic velocity of the sedimentary infilling. These new records have been integrated with available geological information in order to reconstruct the deep structure of the basin, as discussed in the research paper by [2]. The entire dataset used in [2] is here provided, together with 7 additional records recovered for the basin (i.e. N54-N60) and ancillary open-source geospatial data. The dataset can be used for different purposes: specific research on the Norcia basin, comparative studies on similar areas around the world, development of new data modeling and testing of new analysis software, and as a training dataset for machine learning applications.
    Description: Published
    Description: 105709
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: JCR Journal
    Keywords: Active seismic; GIS data; Norcia basin; Seismic ambient vibrations; Seismic array and ambient noise analysis; Site effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 74
    Publication Date: 2021-01-05
    Description: We use seismic data together with a subglacial bedrock relief from the BEDMAP2 database to obtain a new three- layer model of the consolidated (crystalline) crust of Antarctica that locally improves the global seismic crustal model CRUST1.0. We collect suitable data for constructing crustal layers, analyse them and build maps of the crustal layer thickness and seismic velocities. We use the subglacial relief according to a tectonic configuration and then interpolate data using a statistical kriging method. The P-wave velocity information from old seismic profiles have been supplemented with the new shear-wave velocity models. We adjust the thickness of crustal layers by multiplying a total crustal thickness by a percentage ratio of each individual layer at each point. Our re- sults reveal large variations in seismic velocities between different crustal blocks forming Antarctica. The most pronounced differences exist between East and West Antarctica. In East Antarctica, a high P-wave velocity (vP 〉 7 km/s) layer in the lower crust is absent. The P-wave velocity in the lower crust changes from 6.1 km/s beneath the Lambert Rift to 6.9 km/s beneath the Wilkes Basin. In West Antarctica, a thick mafic lower crust is characterized by large P-wave velocities, ranging from 7.0 km/s under the Ross Sea to 7.3 km/s under the Byrd Basin. In contrast, velocities in the lower crust beneath the Transantarctic and Ellsworth-Whitmore Mountains are ~6.8 km/s. The P-wave velocities in the upper crust in East Antarctica are within the range 5.5–6.4 km/s. The upper crust of West Antarctica is characterized by the P-wave velocities of 5.6–6.3 km/s. The P-wave veloc- ities in the middle crust vary within 5.9–6.6 km/s in East Antarctica and within 6.3–6.5 km/s in West Antarctica. A low-velocity layer (5.8–5.9 km/s) is detected at depth of ~20–25 km beneath the Princes Elizabeth Land.
    Description: Published
    Description: 1-18
    Description: 1T. Struttura della Terra
    Description: JCR Journal
    Keywords: Crustal structure ; Sediments ; Antarctica ; Gondwana ; 04.06. Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 75
    Publication Date: 2021-01-14
    Description: The Quaternary Fucino basin in the central Apennines of Italy was struck by one of the strongest Italian earthquakes of the last millennium (1915, Mw 7.0). The Avezzano town, ~ 9.0 km away from the epicentre, was completely destroyed. In the surrounding area sizable coseismic surface deformation were catalogued, attesting the severity of earthquake, the proximity to the causative fault and the geological and geomorphological complexity of a basin filled by thick lacustrine sediments. The Avezzano area provides a case study to understand how shallow subsurface geology influences site effects in a deep Quaternary continental basin environment, thus being of potential interest for similar geologic contexts worldwide. Within the investigated area, different possible earthquake-induced effects can occur, such as a) stratigraphic amplifications in a wide range of resonance frequencies (from 0.4 to 15–20 Hz); b) liquefaction; c) coseismic surface faulting; d) basin-edge effects; and e) slope instability. We present and discuss results of basic seismic microzonation study (SM) of the Avezzano area, focusing on geologic constraints aimed at the reconstruction of the shallow subsurface geology, and associated potential for local seismic hazard. We adopted an interdisciplinary approach based on detailed geological-structural, geophysical and seismic analyses to investigate the seismic response of high-seismic risk area, such as the Avezzano town, given the urban and industrial expansion since the last century. We discuss methodological approaches and their uncertainties.
    Description: Published
    Description: 105583
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 76
    Publication Date: 2021-01-22
    Description: The timing, duration and evolution of sea level during the Marine Isotope Stage 5e (MIS 5e) highstand is a subject of intense debate. A major problem in resolving this debate is the difficulty of chronologically constraining the sea level fall that followed the peak of the highstand. This was mainly controlled by icesheet dynamics, the understanding of which is relevant for assessing future sea-level behavior due to global warming. Here we use stratigraphical and geochoronological (U/Th dating and tephra fingerprinting) evidence from the Infreschi archaeological cave (Marina di Camerota, Southern Italy) to constrain relative sea level (RSL) evolution during the MIS 5e highstand and younger stages. Uraniumthorium dating of speleothem deposition phases places the maximum highstand RSL at 8.90 ± 0.6 m a.s.l., as indicated by the near-horizontal upper limit of Lithophaga boreholes measured for along a ~3.5 km coastal cliff section. Geochronological data show that RSL fell more than 6 m before ~120 ka, suggesting a duration of the Last Interglacial highstand significantly shorter than proposed in some previous studies. Modelling shows that the RSL trend predicted by the ICE-5G and ICE-6G ice-sheet simulations is consistent with our data, but requires an additional significant reduction of both Greenland and Antarctic ice sheets to match the height of the local maximum highstand if no correction for tectonics is applied. Reconciling field data and models requires an earlier and likely shorter duration of the MIS 5e highstand. This suggests that our new data can constrain global ice-volume variations during the penultimate deglaciation, as well as glacial inception at the end of the Last Interglacial. According to our chronology, there is no local evidence of higher-than-present-day sea levels after 120 ka.
    Description: Published
    Description: 106658
    Description: 5A. Ricerche polari e paleoclima
    Description: JCR Journal
    Keywords: MIS5-e ; U/Th dating ; Relative sea level ; Last glacial inception ; Middle palaeolithic
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 77
    Publication Date: 2021-01-18
    Description: Mid-ocean ridge basalts (MORBs) are the most abundant eruptive tholeiitic products on Earth. Many experiments have been performed to investigate the solidification of basalts but under limited thermal ranges of cooling (ΔTc) and cooling rates (ΔT/Δt). We analyze the experimental charges solidified from previous studies: the BIR1A basalt from USGS was solidified using ΔT/Δt of 1, 7, 60, 180, 1800 and 9000 °C/h, in the ΔTc between 1300 and 800 °C, at atmospheric conditions. The previous studies allowed determining the glass-forming ability (GFA) of sub-alkaline silicate liquids, but do not give information on their textures. Here, we quantify the evolution of sizes, shapes, number of crystals per area (#/A), CSDs and growth rates (Gs) of plg (plagioclase), cpx (clinopyroxene) and sp. (spinel). Textures were investigated by image analysis on thousands of crystals and are one of the most complete datasets ever obtained from laboratory studies: they reflect rapid, intermediate and sluggish cooled parts of MORB from liquidus to solidus. Faceted plg grows only at ΔT/Δt ≤ 60 °C/h, while cpx and sp. became dendritic at ΔT/Δt between 60 and 180 °C/h. As ΔT/Δt increase, crystal size ranges decrease from 1000 to 10 μm at 1 °C/h to 100–1 at 60 °C/h μm for plg, from 400 to 8 μm at 1 °C/h to 25–0.5 μm at 1800 °C/h μm for cpx, and from 90 to 6 μm at 1 °C/h to 6–0.5 at 1800 °C/h μm, for sp. The #/A increases with increasing ΔT/Δt, except for cpx between 60 and 180 °C/h. As ΔT/Δt increases, CSDs of plg, cpx and sp increase their slopes (m) and population densities per size (n0), reduce the size ranges and tend to be log-linear. At low ΔT/Δt, CSDs are composed of several log-linear segments, which slopes are related to different pulses of crystal nucleation, and subsequent growth by coarsening. The CSDs parameters (slope, m, and nucleation density per size, n0) linearly scale each other and both are highly correlated with ΔT/Δt. Maximum (Gmax) and average (GCSD) growth rates are computed respectively by averaged major axis (Lmax) of the five longest crystals and by the m of CSDs. Both the Gs are a function of experimental time (t) and increase with the increasing of ΔT/Δt, changing up to two orders of magnitude. The Gmax of cpx is correlated with m and n0 and can be used in natural MORB to retrieve either ΔT/Δt and Gmax. The plg and cpx crystals with sizes between 0.1 and 1 mm are abundant in the experimental charges obtained at low ΔT/Δt. In volcanic rocks, these crystal sizes are generally considered representative of intra-telluric conditions (phenocrysts and microphenocrysts). Our data demonstrate that crystals with mm-sizes may also grow in syn-topost- depositional conditions. The continuous evolution of textures in response to ΔT/Δt variations implies that kinetic effects can fully capture the solidification of MORBs. As a result, the widely accepted assumption that phenocrysts represent the products of evolution processes in volcanic conduits or magma reservoirs could be not valid for some basaltic lavas.
    Description: Published
    Description: 103165
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 78
    Publication Date: 2021-01-25
    Description: We analyze the age distribution provided by 113 sanidine crystals separated from six samples of pyroclastic products of the Bolsena-Orvieto phase of activity at the Vulsini Volcanic District, which were dated via the 40Ar/39Ar single crystal, total fusion method in a previous study. Moreover, we investigate the compositional and depositional features of the dated products, both at the outcrop scale and at the optical microscope, aimed at discriminating the juvenile vs. antecrystic vs. xenocrystic origin of the dated crystals. Results of this study provide insights on the magmatic process preceding the eruptions, as well as on the eruptive mechanisms of the primary deposits. The data also provide a geochronologic context to the his- tory of eruptive activity of the Vulsini Volcanic District, from 590 to 250 ka with greater detail than previously outlined by direct dating of several primary units. Indeed, most of the six samples analyzed in the present work yielded 19 distinct crystal population ages, 10 of which match those of previously dated eruptive units and the other 9 possibly corresponding to primary deposits so far undated.
    Description: Published
    Description: 106904
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 79
    Publication Date: 2021-01-25
    Description: The Paleolithic period in central Italy is currently undergoing an extensive revision due to a significant chronological re-examination of many archaeological sites. Recently, several lower Palaeolithic sites 20 km NW of Rome previously dated within MIS 9 (335–300 ka) (i.e. La Polledrara di Cecanibbio, Torre in Pietra, Castel di Guido, Malagrotta and four sites along Via Aurelia) have been geochronologically reassessed between 412 and 325 ka. These sites, in which abundant fauna, artifacts and hominin remains have been found, are remarkably well preserved. A combination of geological factors and the peculiar geodynamic conditions of this region, where tectonics, volcanism and glacio-eustatic forcing worked in concert, allowed for the exceptional conservation of the remains In this paper we provide a review of these sites and analyze their depositional contexts, showing that rapid filling of the fluvial incisions during glacial terminations, combined with sudden emplacement of volcanic deposits, caused the sealing of the archaeological materials accumulated at the bottom of the paleo-valleys. The aim of this paper is to contribute to a better understanding of these sites as well as to provide the archaeological implications of their new chronology and depositional contexts. Results allow to reconsider the hominin pre- sence in central Italy and highlight the importance to integrate archaeological investigations with modern geological studies, combining sedimentological, geochronological, geomorphological and chronostratigraphical methods.
    Description: Published
    Description: 119-132
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 80
    Publication Date: 2021-01-26
    Description: Hydrothermally-altered rocks collected at Solfatara volcano, Campi Flegrei caldera complex, Italy, are comparable to zones of steam-heated alterations found at low sulfidation epithermal deposits, and volcanic gases collected at Solfatara have temperatures and C-O-H isotopic compositions akin to those forming low sulfidation epithermal deposits. By contrast, hydrothermal alterations collected at La Fossa volcano, Vulcano island, Italy, are comparable to zones of residual vuggy silica formed in high sulfidation epithermal deposits, and volcanic gases collected at La Fossa have temperatures and C-O-H isotopic compositions comparable to those forming high sulfidation epithermal deposits. At Solfatara, amorphous and hydrous opal-A is responsible for shifts in δ7Li values, from +2.2‰ in fresher rocks, to −3.6‰ in most altered rocks, with increases in Au and Cu concentrations (up to 3 ppb and 96 ppm). The increase in Au and Cu concentrations in progressively-altered rocks resulted from the transport of Cu-Au in magmatic-hydrothermal fluids and their partitioning into pyrite, Fe oxides, phyllosilicates, sulfates, and/or opal-A. It is proposed that the combination of opal-A, decreases in δ7Li values, and increases in Cu and Au concentrations represent an exploration vector for low sulfidation epithermal veins. At La Fossa, α-cristobalite is responsible for shifts in δ7Li values, ranging from −0.9‰ in least-altered rocks, to +4.7‰ in most altered rocks, with decreases in Au-Cu concentrations. The decrease in Au and Cu concentrations in progressively-altered rocks may have resulted from the metasomatism of pyrite and Fe oxides, the dissolution of clinopyroxene and opal, and the invasion of the samples by α-cristobalite. The combination of α-cristobalite, increases in δ7Li values, and decreases in Cu and Au concentrations are proposed as proxies for potential high sulfidation epithermal disseminations. Alternating phases of high eruptive activity and quiescent degassing at volcanoes generally, and at Solfatara and La Fossa specifically, suggest that the physicochemical conditions of individual subvolcanic hydrothermal systems should also be alternating, between conditions that are characteristic of low- and high sulfidation epithermal ore-forming environments, and that the related zones of silicification should be alternating between low δ7Li and high Cu-Au values dominated by opal-A, and higher δ7Li and lower Cu-Au values dominated by α-cristobalite.
    Description: Published
    Description: 103934
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Keywords: Active ore-forming processes ; Opalization and cristobalization ; Lithium isotopes ; High and low sulfidation epithermal Au-Cu ore deposits ; La Fossa, Vulcano, Italy ; Solfatara, Campi Flegrei, Italy ; 04.08. Volcanology ; 05.04. Instrumentation and techniques of general interest ; Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 81
    Publication Date: 2021-01-29
    Description: Coniacian to Maastrichtian changes in calcareous nannofossil assemblages have been investigated in the eastern Tethyan Shahneshin section (central Zagros Basin, Iran). The nannofossil assemblages are mainly composed of Watznaueria spp. (avg. 54%), Retecapsa spp (avg. 7.9%), Cribrosphaerella ehrenbergii (avg. 7.7%) and Micula spp. (avg. 5.7%). Throughout the late Campanian, there is a trend to lower abundances in Watznaueria spp. together with increasing abundances of C. ehrenbergii and Arkhangelskiella cymbiformis, which are considered in this basin as the main cool-water taxa. Our results reveal that, despite a diagenetic impact on calcareous nannoflora, a number of primary paleoecological trends are preserved which depict well features of the progressive Late Cretaceous cooling. The first pronounced cooling episode occurs across the late Campanian to early Maastrichtian. The onset of pronounced cooling in the eastern Tethys appears to occur prior to the Campanian/Maastrichtian Boundary event (CMBE) δ13C negative excursion, in contrast with the Boreal realm where pronounced cooling only occurs in the early Maastrichtian, postdating the onset of the CMBE. The coincidence of this earlier cooling in the Zagros Basin with an interval characterized by a significant increase in benthic foraminifera suggests an amplified response of the assemblage due to a change to shallower environments. Hence, the late Campanian calcareous nannofossil assemblage turnover in central Zagros is either a response to an early cooling trend in the eastern Tethys or to sea-level fall or both. The mid-Maastrichtian warming and late Maastrichtian cooling episodes are also delineated in the nannofossil assemblage of Shahneshin and likely correlate with similar episodes in the Boreal Realm.
    Description: Published
    Description: 109418
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 82
    Publication Date: 2021-02-15
    Description: Tephra layers from six deep-sea cores, recovered between the Ionian and the Aegean Seas, and covering a time span between ~ 102 and ~ 8.2 ka BP, were investigated with the aim of identifying their volcanic source. The stratigraphic position of each tephra layer defined by means of nannofossil biostratigraphy and occurrence of sapropel layers was integrated with a thorough geochemical characterization of glass shards based on major oxides and trace elements content, and Sr-Nd isotope ratios. Major oxides composition permitted their subdivision into three groups (K-trachyte, peralkaline rhyolite, andesite), confirmed by Principal Component Analysis on trace elements data. Primordial mantle-normalized trace elements distribution patterns allowed for precise identification of the geochemical affinity and geodynamical setting of each group. Although the Sr isotopic composition of some investigated tephras was deeply affected by seawater alteration as expected, the 143Nd/144Nd values discriminate well the three groups of tephras in combination with major oxides and trace elements data. Therefore, La/Yb and Th/Y vs. 143Nd/144Nd discrimination diagrams are proposed for identification of potential volcanic sources active in the 102–8.2 ka BP time span in the Eastern Mediterranean area for unknown tephras.The obtained results have permitted the attribution of six K-trachytic tephras to the Y-5 stratigraphic marker (Campanian Ignimbrite eruption of Campi Flegrei, Southern Italy, ~ 39 ka BP), and two pantelleritic (= peralkaline rhyolite) tephras to the Y-6 stratigraphic marker (Green Tuff eruption of Pantelleria Island, Sicily Channel, ~ 46 ka BP). The andesitic tephra, stratigraphically constrained between ~ 39 and ~ 83–102 ka BP, might correspond to the X-1 stratigraphic marker, found in several deep-sea cores of the Eastern Mediterranean Sea, although its attribution is still debated in the literature. On the basis of trace elements content, supported by Sr-Nd isotopic features, it is here hypothesized that this tephra could be related to a volcanic source located in the Aegean Sea area, probably the island of Santorini. More generally, this study demonstrates that the combination of Sr-Nd isotopic with major oxide and trace element geochemical fingerprinting on selected and purified glass shards is a very effective tool for identifying nature and source of doubtful tephra layers.
    Description: Published
    Description: 121-136
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 4V. Processi pre-eruttivi
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Tephrostratigraphy ; Eastern Mediterranean Sea ; Stratigraphic markers ; Geochemical fingerprints ; Sr-Nd isotopes ; Laser ablation ; inductively coupled plasma ; mass spectrometry (LA-ICP-MS)
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 83
    Publication Date: 2021-03-02
    Description: ²²²Rn concentrations have been measured in a well located on the edge of a large Pleistocene-Holocene fan and belonging to the shallow pyroclastic aquifer of the Pietramelara Plain, southern Italy. The aim of this study has been both to characterise the hydrological inputs that determine the influx of ²²²Rn to the shallow aquifer and to understand the correlations between ²²²Rn, major ions, physical-chemical parameters and rainfall. Results obtained from the time series indicate that the studied well shows a ²²²Rn variability that is inconsistent with a mechanism of pure hydrological amplification, such as described in Radon hazard in shallow groundwaters: Amplification and long term variability induced by rainfall (De Francesco et al., 2010a). On the contrary, in this well hydrological amplification appears to be mainly tied to the upwelling of alluvial fan waters, rich in radon, in response to pistoning from recharge in the carbonate substrate. This upwelling of alluvial fan waters occurs during almost the whole period of the annual recharge and is also responsible of the constant increase in ²²²Rn levels during the autumn-spring period, when both the water table level and weekly rainfall totals drop. Furthermore, a rapid delivery mechanism for ²²²Rn likely operates through fracture drainage in concomitance with the very first late summer-early autumn rains, when rainfall totals appear largely insufficient to saturate the soil storage capacity. Results obtained from this study appear to be particularly significant in both radon hazard zoning in relation to the shallow aquifer and possibly also for indoor radon, owing to possible shallow aquifer-soil-building exchanges. Moreover, both the spike-like events and the long wave monthly scale background fluctuations detected can also have potential significance in interpreting ²²²Rn time series data as seismic and/or volcanic precursors. Finally, ²²²Rn has proved to be an excellent tracer for hydrological inputs to the shallow aquifer when combined with major ions, physical-chemical data and geological and geomorphological controls.
    Description: Published
    Description: 3352-3363
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 84
    Publication Date: 2021-03-02
    Description: (222)Rn concentrations have been determined with a RAD7 radon detector in shallow groundwaters of the Pietramelara Plain, north-western Campania, southern Italy, where pyroclastic deposits, along with recent stream alluvial sediments, come in contact with Mesozoic carbonate reservoirs. The aim of this study has been to study the annual variation of (222)Rn concentration in the shallow groundwaters, scarcely considered in the literature and of obvious relevance for radon hazard evaluation. Our results definitely show that (222)Rn levels are characterized by a clear annual periodicity, strictly related to rainfall and water table levels, with a pronounced difference between the dry and the wet season. In this last case with concentrations increasing up to two orders of magnitude (up to two times the lower threshold given in the Recommendation 2001/928/EURATOM for public waters). In relation to this, experimental field data will be presented to demonstrate that this variability is due to purely hydrological mechanisms, mainly rinse out and discharge that control leaching efficiency. The detected cycle (Radon Hydrological Amplification Cycle, RHAC) has been generalized for the Mediterranean Tyrrhenian climate. The marked and seasonally persistent amplification in (222)Rn levels poses the problem of evaluating the epidemiological risk brought up by this previously not yet reported mechanism. This mechanism, occurring in shallow groundwaters, very likely should strongly influence indoor radon levels via groundwater-soil-building exchange.
    Description: Published
    Description: 779–789
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 85
    Publication Date: 2021-03-02
    Description: Chemical composition of rainwater is strictly related to atmosphere scavenging. Active degassing volcanoes release acid gases and solid particulate in the surrounding environment. Nyiragongo Volcano (DRC) is characterized by a high degassing activity from an active lava lake hosted within the crater. Chemistry of rainwater in the area is clearly dependent on the influence of the volcanic plume, especially at the rim of the Nyiragongo summit crater. Rainwater collected from this zone has pH values as low as 2, high salinity (EC 28–1800 μS/cm), and high contents of F− and Cl− (up to 193 and 270 ppm, respectively), NH4+ (up to 146 ppm) and SO42− ions (up to 340 ppm) relative to worldwide rainwater. The chemical composition of rainwater after interaction with the volcanic plume tends to shift towards the condensable fraction of fumarolic fluids discharged from the summit crater. Rainwater acidified by the volcanic plume also removes metals from particulate suspended in the atmosphere, thus undergoing metal enrichment. Displacement of the Nyiragongo volcanic plume by predominantly westward-directed wind causes “natural” contamination of rainwater collected for drinking purposes in villages located on the western flank of the volcano. Rainwater falling in urban centers located S–SE of the Nyiragongo Volcano is not usually affected by the rain–plume interactions which strictly depends on wind directions. However, areas of possible contamination by the volcanic plume might create a further emergency and critical situations on top of an already existing severe humanitarian crisis. Rainwater is the principal drinking water supply in the Nyiragongo area, thus the geochemical monitoring of rainwater quality is of great importance to mitigate the hazard of natural contamination of this fundamental resource for the local communities.
    Description: Published
    Description: 69-79
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 86
    Publication Date: 2021-03-02
    Description: 222Rn concentrations have been monitored during the dry season in August 2009 and August 2010, in a reworked alluvial-pyroclastic soil of the Pietramelara Plain, in Southern Italy, with the aim of determining the role of atmospheric factors in producing the quasi-periodic oscillations in soil 222Rn concentrations reported in the literature. In this study we present the results of a detailed analysis and matching of soil 222Rn concentrations, meteorological and solar parameters where the observed oscillations feature a characteristic behavior with second order build-up and depletion limbs, separated by a daily maximum and minimum. All these features are clearly shown to be tied to sunrise and sunset timings and environmental radiative flux regimes. Furthermore, a significant, and previously unreported, second order correlation (r2 ¼ 0.73) between daily maximum hourly global radiation and the daily range of soil 222Rn concentrations has been detected, allowing estimates of the amplitude of these oscillations to be made from estimated or measured solar radiation data. The correlation has been found to be valid even in the presence of persistent patchy daytime cloudiness. In this case a daytime prolongation of the night-time build up stage and an attenuation or even suppression of daytime depletion is observed (a previously unreported effect). Neither soil cracking, nor precipitation, both suggested in some studies as causative factors for these oscillations, during the dry season appear to be necessary in explaining their occurrence.We also report the results of an artificial shading experiment, conducted in August 2009, that further support this conclusion. As soil 222Rn concentrations during the dry season show a characteristic daily cycle, radon monitoring in soils under these conditions necessarily has to be gauged to the timings of the daily maximum and minimum, as well as to the eventual occurrence of cloudiness and to its related effects, in order to avoid erroneous conclusions.
    Description: Published
    Description: 31-41
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 87
    Publication Date: 2021-03-02
    Description: A combination of noble and major gas composition and isotope geochemistry provides a window into the source of volatiles and the mechanisms of transport associated with a series of hot springs located near the Dallol volcano within the Danakil Depression along the Red Sea arm of the Afar triple junction. The helium isotopic composition of these gases range up to 11.9 times the atmospheric ratio (11.9 R/Ra), which suggests that the Afar plume interacts with the Afar depression across at least the 300 km transect from Tendaho-Gabo basin to Dallol within the Danakil Depression. The 4He/40Ar* of ~14 in the mantle-rich end-member at Dallol indicates significant degassing prior to emplacement at Dallol either during basaltic dyke intrusions beneath the Danakil Depression or during the release and transport of fluids from a degassed subsolidus source in the upper mantle along high permeability fracture zones. The CO2/3He of the magmatic end-member is ~2× higher (7.7×109) and more positive δ13C (CO2) (−2.1‰) than other archetypal plumes (e.g. Hawaii, Iceland, etc.). The Dallol composition is consistent with a hypothetical model that assumes a plume-type starting composition and experiences ~92% degassing (where helium is preferentially degassed with respect to CO2) and the addition of CO2 from the thermal degradation of carbonate. Non-atmospheric excess N2 with a δ15N (N2) of +3.5 to +4‰ dominates the Dallol volatiles and suggests interaction between mantle fluids and Proterozoic meta-sediments. By comparing and modeling the range in atmospherically (e.g. 20Ne, 36Ar, 84Kr) and mantle-derived (e.g. 4He/40Ar* and CO2/3He) components in Dallol volatiles, we propose that the coherent variations in these gases result from mixing of magmatic volatiles with extremely degassed remnant fluids present within the hydrothermal reservoir.
    Description: Published
    Description: 16-29
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 88
    Publication Date: 2021-05-12
    Description: eological storage is one of the solutions to avoid the emission of carbon dioxide to the atmosphere. This process requires a careful monitoring of the CO2 bubble, which can be performed by means of seismic and electromagnetic (EM) methods, on the basis of seismic velocity, attenuation and electrical conductivity contrasts before and after the injection. A successful monitoring depends on many factors, for instance the depth and properties of the reservoir. To test the feasibility of detecting the gas, we have performed cross-well seismic and EM tomographic inversions on a synthetic data set generated from a realistic aquifer partially saturated with CO2. We use two different algorithms based on traveltime picks. The method is novel regarding the EM inversion. Besides seismic velocity and conductivity, we have also obtained the seismic quality factor by performing attenuation tomography based on the frequency-shift approach. The RMS differences between the inverted and true initial models show that the methodology (and the adopted acquisition geometry) allows us to obtain reliable results which agree well with the true petrophysical model. Moreover, we have used a forward optimisation method to recover saturation, porosity and clay content from the tomographic seismic velocities, Q values and electric conductivity, with errors less than 15%
    Description: Published
    Description: 245-257
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 89
    Publication Date: 2021-05-12
    Description: A systematic multi-parameter and multi-platform approach to study the slow process of earthquake preparation is fundamental to gain some insights on this complex phenomenon. In particular, an important contribution is the integrated analysis between ground geophysical data and satellite data. In this paper we review some of the more recent results and suggest the next directions of this kind of research. Our intention is not to detect a particular precursor but to understand the physics underlying the various observations and to establish a reliable physical model of the preparation phase before an impending earthquake. In this way, future investigation will search for suitable fore-patterns, which the physical model of multi-layers coupling predicts and characterizes by quasi-synchronism in time and geo-consistency in space. We also present alternative explanations for some anomalies which are not actually related to earthquakes, rather to other natural or anthropic processes.
    Description: Published
    Description: 17-33
    Description: 2A. Fisica dell'alta atmosfera
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 90
    Publication Date: 2021-05-18
    Description: Anthropogenic emissions of greenhouse gases (GHGs) co-occur with emissions of these gases from volcanic and urban environments. Therefore, it remains a challenge for the scientific community to identify the contamination sources and quantify the specific contributions. Stable isotopes have many applications in different fields under geosciences, including volcanology, environmental surveying, and climatology. Isotopic surveys allow identification of photosynthetic fractionation in tree forests and gas sources in urban zones, and tracking of volcanic degassing. Thus, the stable isotopic composition of the local GHGs allows the evaluation of the environmental impacts and assists in mitigating the emissions. The present study aimed to distinguish the tropospheric sources of CO2 in the different ecosystems based on the stable isotopic composition of CO2. The study relies on field experiments performed in both volcanic and urban zones of the Mediterranean region. Experiments to identify the CO2 origins in the field were designed and conducted in the laboratory. The CO2 in the air in Palermo, the soil CO2 released at Vulcano (Aeolian Islands, Italy), and the CO2 emitted at Cava dei Selci (Rome, Italy) were selected for conducting case studies. Isotope surveying of the CO2-containing air in Palermo revealed that the CO2 content was correlated to human activity. Mobile-based measurements of carbon isotope were conducted to distinguish the different sources of CO2 at the district scale. In particular, the isotopic surveying process distinguished landfill-related CO2 emissions from the fossil fuel burning ones. The underlying geological reservoir was identified as the main source of air CO2 at Cava dei Selci. Finally, partitioning of soil CO2 enabled estimation of the geological CO2 estimation in the Vulcano Porto settled zones. The results of the present study revealed that detailed investigations on stable isotopes assist in tracking the CO2 sources and the fate of gas emissions. The fine-tuned experimental solutions assisted in broadening the research perspectives. In addition, deeper insights into the carbon cycle were obtained.
    Description: Published
    Description: 118446
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Stable isotopes ; Carbon dioxide ; Greenhouse gas emissions ; Volcanic gases ; Mediterranean region ; 01.01. Atmosphere ; 04.08. Volcanology ; 05.08. Risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 91
    Publication Date: 2021-06-25
    Description: Recent measurements of surface vertical displacements of the European Alps show a correlation between vertical velocities and topographic features, with widespread uplift at rates of up to ~2–2.5 mm/a in the North-Western and Central Alps, and ~1 mm/a across a continuous region from the Eastern to the South-Western Alps. Such a rock uplift rate pattern is at odds with the horizontal velocity eld, characterized by shortening and crustal thickening in the Eastern Alps and very limited deformation in the Central and Western Alps. Proposed me- chanisms of rock uplift rate include isostatic response to the last deglaciation, long-term erosion, detachment of the Western Alpine slab, as well as lithospheric and surface de ection due to mantle convection. Here, we assess previous work and present new estimates of the contributions from these mechanisms. Given the large range of model estimates, the isostatic adjustment to deglaciation and erosion are su cient to explain the full observed rate of uplift in the Eastern Alps, which, if correct, would preclude a contribution from horizontal shortening and crustal thickening. Alternatively, uplift is a partitioned response to a range of mechanisms. In the Central and Western Alps, the lithospheric adjustment to deglaciation and erosion likely accounts for roughly half of the rock uplift rate, which points to a noticeable contribution by mantle-related processes such as detachment of the European slab and/or asthenospheric upwelling. While it is di cult to independently constrain the patterns and magnitude of mantle contributions to ongoing Alpine vertical displacements at present, future data should provide additional insights. Regardless, interacting tectonic and surface mass redistribution processes, rather than an individual forcing, best explain ongoing Alpine elevation changes.
    Description: Published
    Description: 589-604
    Description: 1T. Struttura della Terra
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: 04. Solid Earth ; 04.03. Geodesy ; 04.07. Tectonophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 92
    Publication Date: 2021-06-24
    Description: The possibility of constraining the composition and evolution of specific portions of the Sub-Continental Lithospheric Mantle (SCLM) by means of an integrated study of petrography, mineral chemistry, and concentrations of volatiles in fluid inclusions (FI) is a novel approach that can provide clues on the recycling of volatiles within the lithosphere. This approach is even more important in active or dormant volcanic areas, where the signature of the gaseous emissions at the surface can be that of the underlying lithospheric mantle domains. In this respect, the ultramafic xenoliths brought to the surface in West Eifel (~0.5–0.01 Ma) and Siebengebirge (~30–6 Ma) volcanic fields (Germany) are ideal targets, as they provide direct information on one of the most intriguing portions of SCLM beneath the Central European Volcanic Province (CEVP). Five distinct populations from these localities were investigated using petrographic observations, mineral phase analyses and determination of He, Ne, Ar and CO2 contents in olivine-, orthopyroxene-, and clinopyroxene-hosted FI. The most refractory Siebengebirge rocks have highly forsteritic olivine, high-Mg#, low-Al pyroxene, and spinel with high Cr#, reflecting high extents (up to 30%) of melt extraction. In contrast, xenoliths from West Eifel are modally and compositionally heterogeneous, as indicated by the large forsterite range of olivine (Fo83–92), the Cr# range of spinel (0.1–0.6), and the variable Al and Ti contents of pyroxene. Equilibration temperatures vary from 870 ◦C to 1070 ◦C in Siebengebirge, and from ⁓900 ◦C to ⁓1190 ◦C in West Eifel xenoliths, at oxygen fugacity values generally between 􀀀 0.5 and + 1.3 ΔlogƒO2 [FMQ]. In both areas, the FI composition was dominated by CO2, with clinopyroxene, and most of the orthopyroxene had the highest concentrations of volatiles, while olivine was gas-poor. The noble gas and CO2 distributions suggest that olivine is representative of a residual mantle that experienced one or more melt extraction episodes. The 3He/4He ratio corrected for air contamination (Rc/Ra values) varied from 6.8 Ra in harzburgitic lithotypes to 5.5 Ra in lherzolites and cumulate rocks, indicating that the original MORB-like mantle signature was progressively modified by interaction with crustal-related components and melts having 3He/4He and 4He/40Ar* values consistent with those published for magmatic gaseous emissions. The Ne and Ar isotope systematics indicated that most of the data were consistent with mixing between a recycled atmospheric component and a MORB-like mantle, which does not necessarily require the involvement of a lower mantle plume beneath this portion of the CEVP. The major element distribution in mineral phases from West Eifel and Siebengebirge, together with the systematic variations in FI composition, the positive correlation between Al enrichment in pyroxene and equilibration temperatures, and the concomitant Rc/Ra decrease with increasing temperature, suggest that the SCLM beneath Siebengebirge represented the Variscan lithosphere in CEVP prior to the massive infiltration of melts/fluids belonging to the Quaternary Eifel volcanism. In contrast, West Eifel xenoliths reflect multiple heterogeneous metasomatism/refertilisation events that took place in the regional SCLM between ~6 and ~ 0.5 Ma.
    Description: Published
    Description: 120400
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Eifel ; Siebengebirge ; Noble gas and CO2 measurements ; Fluid inclusions ; Mantle xenoliths ; European SCLM ; Partial melting ; Metasomatism ; Refertilisation ; 04.01. Earth Interior ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 93
    Publication Date: 2020-09-01
    Description: We report on the Strombolian to Violent Strombolian eruption of Montaña Grande which occurred between 789 and 725 BCE in the Güimar Valley on the NE flank of Tenerife island. The eruption produced a ca. 180 m-high sco- ria cone, a thick fallout deposit mostly dispersed southwest and a vast lava flow field that extends east of the cone, towards the coast, for 3.3 × 2.2 km. The eruption occurred in an unusual geodynamic context, outside the North West Rift and North East Rift zones and out of Las Cañadas caldera which are the main geological structures of Tenerife, where the volcanic activity concentrated during the Holocene. The tephra and lava have a trachybasalt composition similar to products of the recent activity of Tenerife but characterized by a distinct trace element pattern (Ta depletion relative to Nb), that points to a distinct source for the magma feeding the eruption and an ascent history along the whole crust which is independent and different from the central feeding system of the Teide-Pico Viejo volcanic complex. The study of this eruption, which until now had been completely neglected, adds new significant data for the correct definition of volcanic risk in Tenerife.
    Description: Published
    Description: 106918
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 94
    Publication Date: 2020-09-28
    Description: Between February 6 and 12, 2016, an earthquake sequence affected the western sector of the Hyblean foreland domain in SE Sicily (Italy), a region characterized by several disastrous events, as the seismic history describes, of which little is still known about the seismogenic sources. Despite the low magnitude of most events (MLmax 4.3), the sequence represents one of the largest episodes of seismic strain release in the area over the last 30 years since the December 13, 1990 earthquake (ML = 5.4). Accurate seismic phase arrival times related to the seismic sequence were obtained by using a wave-correlation method which enabled a significant improvement in precision of earthquake locations, allowing to detect a N-S striking rupture area about 8 km deep. The N-S trending discontinuity well matches, in the near-surface, with the observed geological structures, in rather good agreement with the computed focal solutions which evidence a roughly N-S elongated structure characterized by a left-lateral kinematics. The detailed knowledge learned on the geometry of the fault surface activated by the seismic sequence, together with the characterization of earthquake source parameters, gave important constraints for a realistic estimation of seismic ground motion throughout stochastic simulations. The modeling technique was based on the comparison between instrumental signals of the strongest event of the sequence and the associated synthetic ones. This permitted to properly define the set of input parameters for the construction of a realistic scenario for a MW 6.1 earthquake, which provides the largest contribution to the seismic hazard for the investigated area.
    Description: Published
    Description: 106553
    Description: 4T. Sismicità dell'Italia
    Description: JCR Journal
    Keywords: Hyblean foreland ; Seismic sequence ; High-precision earthquake location ; Seismotectonics ; Seismic hazard
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 95
    Publication Date: 2020-09-21
    Description: Following on the discovery (in 2011) of a layer of distal tephra from the Pomici di Avellino eruption (Somma-Vesuvius, EU5) in the Agro Pontino (southern Lazio, Italy), further detailed study of the Holocene sediment archives in this graben and in the nearby Fondi coastal basin showed that distal tephra from this EU5 eruption occurs as a rather continuous, conspicuous layer. Two other, less conspicuous tephra layers were found, identified as the earlier Astroni 6 eruption from the Campi Flegrei (Fondi basin) and the later AP2 eruption of the Somma-Vesuvius (Agro Pontino). The identification of the distal tephra layers rests upon a combination of criteria, including stratigraphy, macro characteristics, mineralogy, geochemical data on glass composition, Sr-isotopic ratios, and the known tephrochronology for the period concerned, i.e. between c. 2500 and 1000 BCE. 14C datings serve to constrain their age. No significant spatial variation in the characteristics of the main tephra layer (EU5) was observed, other than distinct fining with increasing distance from the vent. Based on a detailed palaeogeographical reconstruction, the occurrence and preservation of these tephra are explained by the local environmental conditions governing their preservation during this time span (the Central Italian Bronze Age), and by the later evolution of the area. The observations underpin that multiple corings are needed to fully assess whether sedimentary hiatuses exist in palaeorecords, based on cores from sediment archives. Lastly, our study shows that hazard evaluations for future eruptions by Campanian volcanoes should pay more attention to their potential impacts on distal areas.
    Description: Published
    Description: 107041
    Description: 1V. Storia eruttiva
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: Distal tephra Central Italy ; Tephrochronology ; Geochemistry ; Radiocarbon dating Early ; Late Holocene ; Central Italy
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 96
    Publication Date: 2020-10-19
    Description: The Pleistocene (~460–265 ka) San Venanzo volcanic complex belongs to the IAP (Intra-Apennine Province) in central Italy, which comprises at least four small Pleistocene monogenetic volcanoes plus several unrooted pyroclastic deposits with peculiar mineralogical and whole-rock chemical compositions. San Venanzo products are strongly SiO2-undersaturated, CaO- and MgO-rich and show ultrapotassic serial character. The relatively common occurrence of calcite in the pyroclastic rocks and the overall high CaO content are interpreted in literature as primary mineral. The main rock facies at San Venanzo are calcite-rich scoria and lapilli tuffs, with minor massive lava flows, and a rare pegmatoid variant (melilitolitic pockets). All the San Venanzo rocks are feldspar-free, with a typical paragenesis of forsteritic olivine, non-stoichiometric Ca-rich diopside, melilite, leucite, kalsilite, opaque minerals, nepheline, phlogopite, calcite, apatite, cuspidine, wollastonite, kirschsteinite-monticellite s.s. ± glass and other minor and very rare minerals typical of agpaitic melts. Based on petrographic analyses, the studied rocks can be classified as olivine melilitites, olivine leucite melilitites, venanzites (a local variant of kamafugites), calcite leucite melilitolites and Ca-rich olivine leucite melilitite tuffs. Mass balance calculations indicate a direct genetic link between the lava bodies and the pegmatoid melilitolitic pocket through a fractional crystallization process characterized by the removal of ~74% of a melilite-bearing uganditic cumulate made up of melilite, leucite, olivine, kalsilite and chromite. Primitive mantle-normalized patterns of the lavas and tuffs are rather spiked and share negative anomalies for Ba, Nb, Ta, P and Ti resembling typical magmas generated by supra-subduction mantle wedge. These compositions are very different from the only two other kamafugite localities outside Italy (Toro Ankole and Virunga in the East Africa Rift and Alto Paranaiba Igneous Province in SE Brazil). The melilitolite sample is more incompatible element-enriched than the other San Venanzo volcanic rocks, coherently with its evolved liquid composition proposed here. Major and trace element contents indicate a general depletion proportional to the amount of CaO content. The negative trends in Harker-type diagrams with CaO as abscissa are compatible with a process of variable interaction between a silicate magma with sedimentary marly carbonates/limestones. The presence of Mg-rich (Fo97–92) and rim-ward CaO-enriched (up to 1.72 wt%) euhedral olivine, as well as the presence of thin kirschsteinite rim around olivine crystals agree with a process of crustal carbonate assimilation by an originally strongly SiO2-undersaturated silicate magma. On the other hand, the lack of feldspars even in the rocks with the highest SiO2, the high CaO content, and the extreme SiO2-undersaturation of San Venanzo rocks exclude their derivation from a simple peridotitic source. In order to generate these peculiar compositions, the presence of a SiO2-K2O-CaO-rich H2O-bearing component, identified in a carbonated phlogopite peridotite is required. The results of different isotopic systematics (Sr-Nd-Pb-He-Ne-Ar) presented here are compatible with a process of crustal contamination both at mantle source levels (to explain the general N-S isotopic trends recorded in Quaternary volcanic rocks of Italian peninsula and Sicily) and with interaction of ultrabasic melts with limestones at shallow crustal depths.
    Description: Published
    Description: 103256
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Keywords: carbonatite ; crustal assimilation ; petrography ; noble gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 97
    Publication Date: 2020-10-19
    Description: The chemical and isotopic features of the fluids (water and gases) in the Lucane thermal area (southern Italy) have been investigated in order to verify their origin, water temperature in the geothermal reservoir, and to recognize the main natural processes concerning the water composition during ascent towards the surface. The Lucane geothermal system is placed in the southern sector of the Apennines chains, a seismically active area, close to the southern base of the Mt. Alpi carbonate massif. Along the study area, two main sets of high-angle faults form an almost orthogonal fault system that, as suggested by local structural geology, acts as a preferential pathway for uprising deep fluids. Here, we recognized two different types of waters: (i) cold shallow waters having a meteoritic origin and interacting with carbonate rocks (dolomite and calcite), whose dissolved gases show a dominant atmospheric contribution and (ii) hypothermal waters (average temperature of 21 °C), having a meteoritic origin and interacting with both carbonate rocks and inter-bedded evaporitic deposit. Geochemical data allow estimating a geothermal reservoir temperature between 30 °C and 60 °C, according to silica and Ca/ Mg geothermometers, respectively. A heat discharge related to hypothermal groundwater flow between 7.75E +06 and 2.00E+07 J/s was computed. δ18O and δ2Η data allowed recognizing a meteoric origin for hypothermal (hereafter TL) waters, with mean recharge (infiltration) elevations between 1300 and 1700 m a.s.l. These waters are gas-rich (e.g., CO2 and He), which amounts are higher than those in air-saturated water (ASW). Carbon and helium isotope signature in the TL waters indicate their mainly crustal origin and involve a tectonic control on fluid migration through the crust. Furthermore, we observe that the He isotopic signature in gases dissolved in TL waters is stable over time and its monitoring could be a powerful tool to assess the seismogenetic processes since their preparatory phases.
    Description: Published
    Description: 106618
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: geochemistry ; tectonics ; geothermy ; earthquakes ; 04. Solid Earth
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  • 98
    Publication Date: 2020-10-16
    Description: Individual volcanoes can produce both effusive and explosive eruptions. A transition between these two eruption styles dramatically changes the hazards and can occur either between distinct eruption events or within one eruption episode. The causes of these transitions are difficult to determine due to the number of system parameters that can influence whether or not magma fragments in a runaway process. We apply a numerical model of magma ascent in a volcanic conduit to isolate and test the effects of key parameters related to magma rheology and system geometry. We find that for a given volcanic system, parameters that control magma viscosity, such as initial water mass fraction, initial crystal volume fraction, and temperature, have the greatest influence on whether or not magma fragments during ascent and erupts explosively. We also define a ‘critical condition’ for the full set of initial parameters under which a transition in eruption style, from effusive to explosive or the reverse, is more likely to occur. Under these conditions, small heterogeneities in the water or crystal content of the magma, or small perturbations to the conduit pressure gradient due to magma chamber overpressure or dome growth or collapse, can disrupt the magmatic conditions and cause a transition in eruption style. The 2010 VEI 4 eruption of Merapi Volcano included both effusive and explosive phases and was larger by an order of magnitude than its eruptions during the previous century. We constrain our model for the Merapi system using published literature values and show that between the previous eruption in 2006 and the 2010 eruption, the shallow magmatic system at Merapi reached critical conditions due to the ascent from depth of a large, hotter, more volatile-rich magma. Under these critical conditions and according to our model results, small changes in the volatile content of the magma, small dome collapses, subtle changes in degassing rate, or the addition of CO2 to the magma through decarbonation of the bedrock, are all feasible mechanisms for triggering rapid transitions between effusive and explosive activity during the 2010 eruption period.
    Description: Published
    Description: 106767
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Merapi ; Explosive-effusive transitions ; Eruption rate ; Fragmentation ; Lava domes ; Explosive eruptions ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 99
    Publication Date: 2020-11-02
    Description: Inspired by coarea formula in geometric measure theory, an occupation time formula for continuous semimartingales in R^N is proven. The occupation measure of a semimartingale, for N ≥ 2, is singular with respect to Lebesgue measure but it has a bounded density “transversal” to a foliation, under proper assumptions. In the particular case of the foliation given locally by the distance function from a manifold, the transversal density is related to a geometric local time of the semimartingale at the manifolds of the foliation.
    Description: Published
    Description: 3342–3361
    Description: 3IT. Calcolo scientifico
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 100
    Publication Date: 2020-11-30
    Description: Magma-carbonate interactions and the subsequent CO2 release can occur before and during an eruption, critically affecting magma storage and ascent processes. However, the mechanisms and timescales of those interactions are unclear, particularly during the fast magma withdrawal that feeds high-intensity eruptions. In order to better understand magma‑carbonate interactions, we selected the caldera-forming Pomici di Base plinian eruption, the oldest (22 ka) and largest (〉 4.4 km3) explosive event in the history of the Somma-Vesuvius volcanic system, as case study. During this event the emission of trachytic and latitic-shoshonitic (~25% and ~75% of the erupted magma volume respectively) magmas generated a long-lasting plinian column, hypothetically driven by CO2 liberation during magma‑carbonate interaction. In this study, we reconstruct in detail the evolution of the plumbing system during the Pomici di Base eruption combining geochemical (major/minor elements and radiogenic/stable isotopes) analyses of juvenile products with thermodynamic and kinetic calculations. Our results demonstrate that magmatic stoping (i.e., the formation and transport of host-rock pieces into a magma body) during caldera collapse evolution can promote rapid magma assimilation of carbonate blocks and CO2-rich fluids resulting from destabilization of the carbonate bedrock, thus triggering CO2 release and acting as a fuel for the eruption explosivity, especially when residual hot mafic magmas are involved. Our findings suggest that the accurate knowledge of these processes and their influence on eruptive dynamics are critical for improving the hazard assessments of volcanoes with plumbing systems located in carbonate bedrocks.
    Description: Published
    Description: 105628
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 4V. Processi pre-eruttivi
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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