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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 1-2 
    ISSN: 1436-3259
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 3-16 
    ISSN: 1436-3259
    Schlagwort(e): Annual maximum ; partial duration series ; T-year estimate ; marshall-Olkin bivariate distribution ; Morgenstern bivariate distribution
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract As a basis for development of the annual maximum distribution the so-called partial duration series with Poissonian occurrence times and exponentially distributed peak exceedance values has been selected. The model is generalized by allowing for a Markov dependence between succeeding peak values. Correlation values from p=0 to p=1 can be accounted for by introducing the Marshall-Olkin bivariate exponential distribution, which is presented in detail. The developed distribution function for the annual maximum is throughly analysed and a variety of distribution forms depending on the value of the correlation coefficient and the intensity in the Poisson process is hereby recognized. To a certain extent this might be considered as parallel to the scattering of hydrological regions with different generating mechanisms for the annual maxima.
    Materialart: Digitale Medien
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  • 3
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 37-52 
    ISSN: 1436-3259
    Schlagwort(e): Cyclonic precipitation ; mathematical modeling ; simulation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract A stochastic description is developed for extratropical cyclonic precipitation fields at synoptic and meso scales as they are typically observed by radars over the Earth. This description attempts to account I) for the synoptic scale behavior of a cyclonic storm (its birth, its synoptic scale motion trajectory, and its dissipation) II) for the synoptic-scale organizational structure of subsynoptic precipitation areas (rainbands, precipitation cores and raincells) within a cyclonic storm; and III) for the behavior of subsynoptic precipitation areas, in terms of their births, their spatial configuration evolutions, their motions, and their deaths (dissipation). The precipitation cores and the raincells are taken as the building blocks of the subsynoptic precipitation, areas within a cyclonic rainfield.
    Materialart: Digitale Medien
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  • 4
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 81-100 
    ISSN: 1436-3259
    Schlagwort(e): Stochastic differential equations ; Itô calculus ; Stratovovich integrals ; Jump integrals
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract Fundamentals of the theory of stochastic calculus and stochastic differential equations (SDE's) which are finding increasing application in water resources engineering are reviewed. The basics of probability theory, mean square calculus and the Wiener, white Gaussian and compound Poisson processes are given in preparation for a discussion of the general Itô SDE with drift, diffusion and jump discontinuity terms driven by Gaussian white noise and compound Poissionian impulses. Also discussed are stochastic integration and the derivation of moment equations via the Itô differential rule. The lierature of SDE's is reviewed with an emphasis on the more accessible sources.
    Materialart: Digitale Medien
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  • 5
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 53-66 
    ISSN: 1436-3259
    Schlagwort(e): Hurst range ; conditioned exchangeable, variables
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract A new theoretical interpretation is proposed for Hurst's empirical law which is applicable to discrete-valued inflows and is consistent with the existing interpretation for continuous-valued inflows. This is applied to independent net inflows {X r} having values +1 and −1 with unequal probabilities. With the aid of a new result on the exchangeability of symmetrically conditioned exchangeable variables, values of the resulting range are obtained and tabulated. It is found that the effect of skewness is very slight for skewness values between (about) 3 and −3, and that Hurst's own approximation, the “conditioned range”, is remarkably accurate.
    Materialart: Digitale Medien
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  • 6
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 67-80 
    ISSN: 1436-3259
    Schlagwort(e): pattern analysis ; mixed-mode data ; event-covering ; discretization ; hydrometric data
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract This paper presents a pattern analysis technique that has been successfully applied to a set of hydrometric network data collected in British Columbia, Canada. This technique can extract information from a set of observed heterogeneous multivariate data. The data are represented as n-tuples of mixed discrete and continuous values. The technique is capable of screening out statistically irrelevant information. It is also able to detect inherent subgroups in the data through adopting an event-covering approach. The subgroup characteristics represent important empirical understanding even though there may be considerable probabilistic variation within each individual subgroup.
    Materialart: Digitale Medien
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  • 7
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 17-36 
    ISSN: 1436-3259
    Schlagwort(e): Stochastic hydrology ; multivariate analysis ; information extraction ; information transfer ; structure of time series ; time series analysis ; spatial characteristics ; simulation of processes
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract A stochastic approach to the analysis of hydrologic processes is defined along with a discussion of causes of tendency, periodicity and stochasticity in hydrologic series. Sources of temporal non-stationarity are described along with objectives and methods of analysis of processes and, in general, of information extraction from data. Transferred information as measured by correlation coefficients is compared with the transferable information as measured by entropy coefficients. Various multivariate approaches to hydrologic stochastic modeling are classified in light of complexities of spatial/temporal hydrologic processes. Alternatives of time series structural decomposition and modeling are compared. A special approach to modeling of space properties further contributes to approximate simulations of spatial/temporal processes over large areas. Several aspects of stochastic models in hydrology are concisely reviewed.
    Materialart: Digitale Medien
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  • 8
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 101-116 
    ISSN: 1436-3259
    Schlagwort(e): Soil moisture ; stochastic processes ; stochastic differential equations
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract The dynamics of water within the unsaturated root zone of the soil are represented by a pair of stochastic differential equations (SDE's), one representing the so-called “surplus” state of the moisture and the other the “deficit” condition. The inputs to the model are the climatically controlled random infiltration events and evapotranspiration which are modeled as a compound Poisson process and a Wiener (Brownian motion) process, respectively. The solutions to these SDE's are not in “close-form” but sample functions are obtained by numerical integration. The moment properties of the soil moisture evolution process have also been derived analytically including the mean, variance, covariance and autocorrelation functions. To illustrate the model, climatic parameters representing the “surplus” and “deficit” cases and properties of clay loam soil have been used to numerically derived the corresponding sample functions. With proper selection of all the parameters, physically realistic sample trajectories can be obtained for the model.
    Materialart: Digitale Medien
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  • 9
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 127-134 
    ISSN: 1436-3259
    Schlagwort(e): Upland erosion ; annual erosion losses
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract Point rainfall triggers the complex processes of overland flow and surface erosion. The probability density functions of rainfall duration and intensity are coupled with a physically based dynamic formulation of rainfall-runoff-sediment transport relationships for upland areas. When considering a single storm, rainfall depth alone is a poor predictor of sediment transport because of the dispersion introduced by the effect of rainfall intensity. On a long terms basis, however, the total amount of rainfall can be used to predict total erosion losses.
    Materialart: Digitale Medien
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  • 10
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 117-126 
    ISSN: 1436-3259
    Schlagwort(e): equi-risk line ; detention pond ; urban runoff ; frequency analysis ; flood risk
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract The expression of equi-risk line derived by the authors represents the relationship between discharge capacityy 0 u and storage capacityz 0 u to keep flood frequency under a certain risk level represented by the return periodT, i.e.,z 0/z 0 u ={(y 0 u −y 0 u )/y 0 u } S , wherey 0 u andz 0 u areT-year probability peak discharge and total volume of a hydrograph. The shape parametersS is evaluated in this paper for various release rules of the storage facilities and correlations of durations and peaks of hydrographs. The expression forS is: $$S = S_\infty + (S_0 - S_\infty )\exp ( - \sqrt p )$$ , whereS 0 andS ∞ are the values ofS forp=0 and ∞, andp is the exponent of a general storage-release relation,q=az' p, wherea is the storage constant, andz' andq are the volume of stored water and the corresponding release. The values ofS 0 andS ∞ are expressed in terms of the correlation coefficient ρ of durations and peaks of inflow hydrographs.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 11
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 135-140 
    ISSN: 1436-3259
    Schlagwort(e): Upland erosion ; annual soil losses
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract Annual erosion losses from 135 experimental plots under a variety of soil types, vegetation cover densities and conservation practices in Iraq have been measured over a period of four years. The first three years of this data set demonstrate that annual erosion losses can be predicted from annual rainfall depths. The results obtained from regression analysis were then validated with the fourth year of soil erosion data. These results corroborate the theoretical findings of the companion paper in that long term erosion losses can be predicted from the total amount of rainfall.
    Materialart: Digitale Medien
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  • 12
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 141-154 
    ISSN: 1436-3259
    Schlagwort(e): Contemporaneous ARMA models ; maximum likelihood estimation ; multivariate modelling ; stochastic hydrology ; time series analysis
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract In order to allow contemporaneous autoregressive moving average (CARMA) models to be properly applied to hydrological time series, important statistical properties of the CARMA family of models are developed. For calibrating the model parameters, efficient joint estimation procedures are investigated and compared to a set of uivariate estimation procedures. It is shown that joint estimation procedures improve the efficiency of the autoregressive and moving average parameter estimates, but no improvements are expected on the estimation of the mean vector and the variance covariance matrix of the model. The effects of the different estimation procedures on the asymptotic prediction error are also considered. Finally, hydrological applications demonstrate the usefulness of the CARMA models in the field of water resources.
    Materialart: Digitale Medien
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  • 13
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 155-160 
    ISSN: 1436-3259
    Schlagwort(e): Gamma Markov ; estimation ; maximum likelihood estimates
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract The linearly regressive Gamma Markov sequence is being increasingly used as a model for geophysical phenomena, one of the reasons being that it is possible to determine the distribution of (weighted or otherwise) cumulative sums of such a sequence. In this paper we show briefly how to simulate such a sequence and its seasonal extension; we also show how to estimate its parameters. It is shown that the estimates obtained by the method of moments do not have a high efficiency, whereas those obtained by a modified maximum likelihood method have an efficiency close to unity.
    Materialart: Digitale Medien
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  • 14
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 161-168 
    ISSN: 1436-3259
    Schlagwort(e): Inverse problem ; groundwater management ; groundwater response function ; stochastic control ; consistent parameter estimation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract The response of groundwater basins to natural and anthropogenic inputs depends on many interrelated factors such as the values of groundwater flow and mass transport parameters. This work presents a theoretical analysis of the impact of parameter uncertainty on groundwater management decisions. It is shown that under classical, Bayesian, and deterministic assumptions about the parameter structure, the resulting management decisions could be very different. This underscores the importance of adopting the proper parameter structure and the need for using consistent methods to solve the inverse problem.
    Materialart: Digitale Medien
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  • 15
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 185-198 
    ISSN: 1436-3259
    Schlagwort(e): Pattern matching ; tracking ; rainfall ; mesoscale ; radar
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract This paper presents a new feature-based matching algorithm for tracking mesoscale precipitation phenomena in radar image sequences. Distinct rainfall areas are identified in each image and characterized by a feature vector of shape descriptors, which provide a mathematical representation of the spatial characteristics of each identified area. Rainfall areas observed in consecutive images are matched by comparing the relative values of the features. Two match scoring algorithms are developed to generate the initial estimates of correct matches, which are then updated by likelihood measures based on relative location. The method is applied to mesoscale rainfall areas observed in sequences of radar-derived images of rainfall activity over Southwestern Ontario during the summers of 1980 and 1981.
    Materialart: Digitale Medien
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  • 16
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 199-208 
    ISSN: 1436-3259
    Schlagwort(e): Extreme value distribution ; two-component distribution ; maximum entropy principle ; parameter estimation ; regional estimation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract The two component extreme value (TCEV) distribution has recently been shown to account for most of the characteristics of the real flood experience. A new method of parameter estimation for this distribution is derived using the principle of maximum entropy (POME). This method of parameter estimation is suitable for application in both the site-specific and regional cases and appears simpler than the maximum likelihood estimation method. Statistical properties of the regionalized estimation were evaluated using a Monte Carlo approach and compared with those of the maximum likelihood regional estimators.
    Materialart: Digitale Medien
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  • 17
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 169-184 
    ISSN: 1436-3259
    Schlagwort(e): Stochastic control and programming ; real-time hydrologic forecasting ; reservoir theory
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract A new approximate method of solution for stochastic optimal control problems with many state and control variables is introduced. The method is based on the expansion of the optimal control into the deterministic feedback control plus a caution term. The analytic, small-perturbation calculation of the caution term is at the heart of the new method. The developed approximation depends only on the first two statistical moments of the random inputs and up to the third derivatives of the cost functions. Its computational requirements do not exhibit the exponential growth exhibited by discrete stochastic DP and can be used as a suboptimal solution to problems for which application of stochastic DP is not feasible. The method is accurate when the cost-to-go functions are approximately cubic in a neighbourhood around the deterministic trajectory whose size depends on forecasting uncertainty. Furthermore, the method elucidates the stochastic optimization problem yielding insights which cannot be easily obtained from the numerical application of discrete DP.
    Materialart: Digitale Medien
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  • 18
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 209-216 
    ISSN: 1436-3259
    Schlagwort(e): Transport ; sedimentation ; random walk ; Markov chain in continuous time ; distribution of maximum
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract A simple two-dimensional random walk model is developed for the motion of a particle in a fluid flow. Some earlier results for the persistent injection of particles into the flow are extended, and the distribution of the maximum number of particles in suspension over the period (0,t) is derived.
    Materialart: Digitale Medien
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  • 19
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 217-240 
    ISSN: 1436-3259
    Schlagwort(e): Transport of fluid ; random network ; macro-permeability ; micro-geometry ; statistical mechanics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract This paper presents a detailed statistical analysis of Hagen-Poiseuille flow in plane random isotropic networks of interconnected channels. The emphasis is on statistico-geometrical features of networks that affect macroscopic permeability. It is shown that permeability of a network depends on its average co-ordination number, the first two moments of the channel length distribution and other explicitly identifiable geometrical features. Distributions of flow rates in channels and average flow rates are established by minimization of the rate of energy dissipation. Theoretical developments are interpreted in the context of classical statistical mechanics. Analytical results are illustrated and verified using numerical analysis of flow in a simulated random network.
    Materialart: Digitale Medien
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  • 20
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 280-280 
    ISSN: 1436-3259
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Materialart: Digitale Medien
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  • 21
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 241-262 
    ISSN: 1436-3259
    Schlagwort(e): Martingale ; stochastic-convective ; stochastic-relativist ; spectral-integral ; perturbative ; statistical-mechanical
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract The use of stochastic models in subsurface hydrology is growing at a logistic pace. To tie together a number of different stochastic methodologies for deriving subsurface transport equations, we have put together a brief review of some of the more common techniques. Our attention is confined to a few select methodologies so that we might delve in detail into assumptions required by the various approaches and their strengths and weaknesses. The methods reviewed include: Martingale, stochastic-convective, stochastic-relativist, spectral-integral, perturbative, statistical-mechanical, and generalized hydrodynamics. Within this list, we also have included a few stochastic methodologies which have been used solely to develop expressions for the dispersion tensor.
    Materialart: Digitale Medien
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  • 22
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 297-302 
    ISSN: 1436-3259
    Schlagwort(e): Stochastic PDE ; Zakai equation ; nonlinear filtering ; distributed systems
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract We shall consider in this article a general class of stochastic PDE which in particular covers the Zakai equation of nonlinear filtering and natural formulations of distributed systems involving control variables. We use only fixed point arguments, hence we get uniqueness results. In the case of the Zakai equation, Galerkin approximations have been considered by Pardoux (1979) to derive the existence of the solution
    Materialart: Digitale Medien
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  • 23
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 281-296 
    ISSN: 1436-3259
    Schlagwort(e): Stochastic groundwater flow ; semigroups ; random in time Gaussian process ; random physical parameters ; stochastic partial differential equations
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract Two methods for the solution of partial differential equations (PDE) for the general case of random in time physical parameters are presented and their application to the solution of unsteady regional groundwater flow equations are illustrated. The first method is the semigroup approach which directly offers a solution without resorting to “closure approximations” (hierarchy techniques), perturbation techniques, or Montecarlo simulation techniques. The semigroup approach can also handle the general stochastic problem when randomness also appears as initial conditions, boundary conditions or forcing terms. The second method is an approximation scheme to obtain the semigroup solution in complex cases and permits the solution of equations with more than one random coefficient.
    Materialart: Digitale Medien
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  • 24
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 303-318 
    ISSN: 1436-3259
    Schlagwort(e): Rainfall-runoff models ; forecasting ; unit hydrograph
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract Here we review the main thrusts of rainfall-runoff modelling with an eye toward the advantageous use of the massive date sets being accumulated and the modern computers capable of dealing effectively with such sets. More than a tutorial, this study is aimed at providing a unifying structure for analyzing available techniques. The closing section draws attention to the existence of an alternative methodology.
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  • 25
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 1 (1987), S. 263-279 
    ISSN: 1436-3259
    Schlagwort(e): Porous media ; heterogeneity ; groundwater ; dispersion ; stochastic theory ; plume evolution
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract The migration of contaminants in heterogeneous aquifers involves dispersive processes that act at different scales. The interaction of these processes as a plume evolves can be studied by micro-scale modelling whereby two scales, a local- or micro-scale and an aquifer- or macro-scale, are covered simultaneously. Local-scale dispersive processes are represented through the local dispersion coefficient in the transport equation, while large-scale dispersion due to heterogeneities is represented through the resolution of the flow field and the diffusive exchange between streamtubes. The micro-scale model provides both the high degree of resolution compatible with local-scale processes, and the extent required for the approach to asymptotic conditions, using grids of up to a million nodal points. The model is based on the dual potential-streamfunction formulation for flow, and the transport problem is formulated in a natural coordinate system provided by the flownet. Simulations can be used to verify stochastic theories of dispersion, without the restrictive assumptions inherent in the theory. For the two-dimensional case, results indicate convergence of the effective dispersivity to the theoretical macrodispersivity value. Convergence takes place within a travel distance of about 50 correlation lengths of the hydraulic conductivity field. However, the approach taken to asymptotic conditions, as well as the macrodispersivity value, may differ for different realizations of the same medium. The influence of early-time events such as plume splitting on the asymptotic convergence remains to be investigated.
    Materialart: Digitale Medien
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  • 26
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 2 (1988), S. 17-33 
    ISSN: 1436-3259
    Schlagwort(e): River flow forecasting ; discrete linear cascade model ; ARMAX ; coupled models ; Kalman filtering ; Danube
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract The objective of the paper is to compare three recursive linear state space models used to forecast river flow. The three models are as follows: (i) Purely deterministic discrete linear cascade model (DLCM); (ii) Purely stochastic autoregressive moving average (ARMAX) time series model; and (iii) Coupled deterministic (DLCM) — stochastic (ARMA) model. Description of DLCM is given shortly. The state space formulation of the ARMAX model enables the recursive estimation of random walk parameters and the forecast of flows by linear Kalman filtering. The correlated error sequence of DLCM is described by an ARMA model. The DLCM and ARMA models are put together in a coupled deterministic-stochastic model. The recursive conditional forecasting of the augmented state vector is performed by the linear Kalman-filter. The conditional output forecast is given by linear projection of thea priori state vector. Numerical investigations on River Danube data lead to the conclusion that the coupled deterministic-stochastic model is the most efficient forecasting model of all the three recursive techniques compared.
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  • 27
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 2 (1988), S. 61-72 
    ISSN: 1436-3259
    Schlagwort(e): Binary data ; censored observations ; autocorrelations ; acid rain
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract The properties of the well known estimator of the transition probabilities in a binary time series are investigated. A formula for the variance is obtained, which generally involves a double integral. However, in the case when the binary series is obtained by hard clipping of an AR(1) process, a good and fairly simple approximation is derived. In the MA(1) or MA(2) case exact formulae for the variance is given. In the appendix an excellent approximation to the fourth order cumulant of a clipped AR(1) process is derived, which may be of interest in other applications as well.
    Materialart: Digitale Medien
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  • 28
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 2 (1988), S. 175-188 
    ISSN: 1436-3259
    Schlagwort(e): Reservoir storage ; range ; adjusted range
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract It was remarked by Hurst in 1951 that the adjusted range gives the size of the smallest reservoir capable of providing a constant discharge equal to the mean inflow. Since that time this range and its rescaled modification, the Hurst range, have been widely discussed, not however primarily with a view to applying them to reservoir design problems, but rather on account of their possible relevance to the simulation of geophysical time series. Acknowledging the well-known conceptual weaknesses of adjusted ranges and the theoretical difficulties that inhibit their direct utilisation in the design and operation of real reservoirs, the authors argue that the interest displayed on ranges during the past few decades justifies the effort of eliminating one in particular of these weakness, namely their non-implementability as operating policies, a consequence of the fact that they can only be retrospectively evaluated. The paper proposes modifications in which the unknowable mean and standard deviation of future samples are replaced by the known mean and sample standard deviation of historical data, leading to the historically adjusted range and the historically rescaled and adjusted range. The latter is produced as an implementable approximation to Hurst's (1951) solution to the optimal reservoir problem. The expected values of the new ranges are evaluated and numerically tabulated.
    Materialart: Digitale Medien
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  • 29
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 2 (1988), S. 245-261 
    ISSN: 1436-3259
    Schlagwort(e): Geostatistics ; areal rainfall distribution ; areal reduction factor ; Gumbel distribution
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract Areal rainfall statistics are more relevant in flood hydrology and water resources management than point rainfall statistics when it comes to help designing dams or hydraulic structures. This paper presents a geostatistically based method to derive the areal statistics from point statistics. Assuming that the distribution models of point rainfall and areal belong to the same class of models and that the rainfall process is stationary, it is shown how the parameters of the areal distribution model can directly be computed from the parameters of the point distribution models in case of a non stationary process, an approximation is derived that yielded good results when applied to a mountainous region in Southern France. The method also allows the computation of the areal reduction factors in a very general form.
    Materialart: Digitale Medien
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  • 30
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 2 (1988), S. 303-315 
    ISSN: 1436-3259
    Schlagwort(e): Physically based stochastic models ; stochastic dynamic models ; statistical predictability ; internannual variability ; ARMA models ; water level variations
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract Several physically based stochastic dynamic models (SDM) are described including year-to-year variations of water volume in terminal and non-terminal lakes, streamflow of lake-fed rivers, and salinity of an inland sea (the Sea of Azov). All of these models are based upon the SDM of water volume of terminal lakes developed by Kritzky and Menkel in 1946 in co-operation with Kolomogorov. Explicit formulae are derived for second order statistical moments of the output processes, including variance, correlation function, spectra, etc., under the assumption that the forcing functions from stationary random sequences. The least-squares prediction problem is solved for both stationary and non-stationary cases. Some of the processes are shown to possess high statistical predictability. Actual predictions are compared with independent observations. Problems for further study are stated.
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  • 31
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 3 (1989), S. 1-16 
    ISSN: 1436-3259
    Schlagwort(e): Width function ; instantaneous unit hydrograph ; peak ; regression ; birth-death process
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract We investigate optimal predictors of the peak (S) and distance to peak (T) of the width function of drainage networks under the assumption that the networks are topologically random with independent and exponentially distributed link lengths. Analytical results are derived using the fact that, under these assumptions, the width function is a homogeneous Markov birth-death process. In particular, exact expressions are derived for the asymptotic conditional expectations ofS andT given network magnitudeN and given mainstream lengthH. In addition, a simulation study is performed to examine various predictors ofS andT, includingN, H, and basin morphometric properties; non-asymptotic conditional expectations and variances are estimated. The best single predictor ofS isN, ofT isH, and of the scaled peak (S divided by the area under the width function) isH. Finally, expressions tested on a set of drainage basins from the state of Wyoming perform reasonably well in predictingS andT despite probable violations of the original assumptions.
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  • 32
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 3 (1989), S. 68-69 
    ISSN: 1436-3259
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 33
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 3 (1989), S. 281-292 
    ISSN: 1436-3259
    Schlagwort(e): Generalised Pareto distribution ; Peaks over threshold ; Probability weighted moments ; Regionalisation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract A peaks over threshold (POT) method of analysing daily rainfall values is developed using a Poisson process of occurrences and a generalised Pareto distribution (GPD) for the exceedances. The parameters of the GPD are estimated by the method of probability weighted moments (PWM) and a method of combining the individual estimates to define a regional curve is proposed.
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  • 34
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 2 (1988), S. 155-160 
    ISSN: 1436-3259
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 35
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 2 (1988), S. 161-174 
    ISSN: 1436-3259
    Schlagwort(e): Floods ; estimation ; quantiles ; generalized gamma ; generalized moments ; standard error
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract The generalized gamma (GG) distribution has a density function that can take on many possible forms commonly encountered in hydrologic applications. This fact has led many authors to study the properties of the distribution and to propose various estimation techniques (method of moments, mixed moments, maximum likelihood etc.). We discuss some of the most important properties of this flexible distribution and present a flexible method of parameter estimation, called the “generalized method of moments” (GMM) which combines any three moments of the GG distribution. The main advantage of this general method is that it has many of the previously proposed methods of estimation as special cases. We also give a general formula for the variance of theT-year eventX T obtained by the GMM along with a general formula for the parameter estimates and also for the covariances and correlation coefficients between any pair of such estimates. By applying the GMM and carefully choosing the order of the moments that are used in the estimation one can significantly reduce the variance ofT-year events for the range of return periods that are of interest.
    Materialart: Digitale Medien
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  • 36
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 2 (1988), S. 239-244 
    ISSN: 1436-3259
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 37
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 2 (1988), S. 201-212 
    ISSN: 1436-3259
    Schlagwort(e): Flood risk ; flood frequency analysis ; generalised extreme value distributions
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract Conventional flood frequency analysis is concerned with providing an unbiased estimate of the magnitude of the design flow exceeded with the probabilityp, but sampling uncertainties imply that such estimates will, on average, be exceeded more frequently. An alternative approach is therefore, to derive an estimator which gives an unbiased estimate of flow risk: the difference between the two magnitudes reflects uncertainties in parameter estimation. An empirical procedure has been developed to estimate the mean true exceedance probabilities of conventional estimates made using a GEV distribution fitted by probability weighted moments, and adjustment factors have been determined to enable the estimation of flood magnitudes exceeded with, on average, the desired probability.
    Materialart: Digitale Medien
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  • 38
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 2 (1988), S. 263-279 
    ISSN: 1436-3259
    Schlagwort(e): Cyclonic rain fields ; cyclone center behavior ; stochastic model
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract Earlier the authors have developed a stochastic geometric model for extratropical cyclonic precipitation fields at synoptic and meso scales as they are typically observed by weather radars over the mainland U S A (see Kavvas and Puri 1983; Kavvas et al. 1987). Here the earlier mathematical development of the model is further extended by incorporating the stochastic description of cyclone center births and their evolutions over U S A into the model.
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  • 39
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 2 (1988), S. 315-316 
    ISSN: 1436-3259
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 40
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 3 (1989), S. 31-49 
    ISSN: 1436-3259
    Schlagwort(e): Reservoir operation ; prediction ; Kalman filtering ; flood prevention ; fuzzy control
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract Japan has traditionally performed flood prevention through the construction and use of dikes, storage reservoirs, and basins which are costly and time consuming options. Another non-structural option is to operate the flood control system appropriately with a view to reducing flood damage. In this paper, a flood control system combining the runoff prediction model in the whole river basin with the reservoir operation is discussed. Different models of the runoff process are introduced in order to compare their accuracies and the computational time for the flood forecasting system. The reservoir operational rule is formulated in terms of fuzzy inference theory. Historical data are applied in a case study for verification of the proposed theories.
    Materialart: Digitale Medien
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  • 41
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 3 (1989), S. 69-69 
    ISSN: 1436-3259
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 42
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 3 (1989), S. 154-154 
    ISSN: 1436-3259
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 43
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 3 (1989), S. 155-178 
    ISSN: 1436-3259
    Schlagwort(e): Stochastic differential equations ; Stochastic Taylor formula ; Numerical methods ; Simulations ; Strong convergence ; Weak convergence
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract The development of numerical methods for stochastic differential equations has intensified over the past decade. The earliest methods were usually heuristic adaptations of deterministic methods, but were found to have limited accuracy regardless of the order of the original scheme. A stochastic counterpart of the Taylor formula now provides a framework for the systematic investigation of numerical methods for stochastic differential equations. It suggests numerical schemes, which involve multiple stochastic integrals, of higher order of convergence. We shall survey the literature on these and on the earlier schemes in this paper. Our discussion will focus on diffusion processes, but we shall also indicate the extensions needed to handle processes with jump components. In particular, we shall classify the schemes according to strong or weak convergence criteria, depending on whether the approximation of the sample paths or of the probability distribution is of main interest.
    Materialart: Digitale Medien
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  • 44
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 3 (1989), S. 217-226 
    ISSN: 1436-3259
    Schlagwort(e): Stochastic integral equation method ; rainfall-runoff models ; confidence interval
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract The stochastic integral equation method (S.I.E.M.) is used to evaluate the relative performance of a set of both calibrated and uncalibrated rainfall-runoff models with respect to prediction errors. The S.I.E.M. is also used to estimate confidence (prediction) interval values of a runoff criterion variable, given a prescribed rainfall-runoff model, and a similarity measure used to condition the storms that are utilized for model calibration purposes. Because of the increasing attention given to the issue of uncertainty in rainfall-runoff modeling estimates, the S.I.E.M. provides a promising tool for the hydrologist to consider in both research and design.
    Materialart: Digitale Medien
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  • 45
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 3 (1989), S. 241-260 
    ISSN: 1436-3259
    Schlagwort(e): Hat matrix ; Mahalanobis distance ; Additive outliers ; Innovation outliers ; Influential data ; Autoregressive models ; Threshold autoregression ; Lake Huron
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract A practical method is developed for outlier detection in autoregressive modelling. It has the interpretation of a Mahalanobis distance function and requires minimal additional computation once a model is fitted. It can be of use to detect both innovation outliers and additive outliers. Both simulated data and real data re used for illustration, including one data set from water resources.
    Materialart: Digitale Medien
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  • 46
    Digitale Medien
    Digitale Medien
    Springer
    Stochastic environmental research and risk assessment 3 (1989), S. 293-316 
    ISSN: 1436-3259
    Schlagwort(e): Confined aquifer ; Transmissivity identification ; Geostatistics ; Inverse problem ; Ill-posedness ; Ill-conditioning ; Stability analysis ; Regularization
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung , Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract In recent years, geostatistical concepts have been applied to the inverse problem of transmissivity estimation from piezometric head data. It has been claimed that such methods overcome various difficulties encountered in other approaches. However, the reconstruction of transmissivity from head measurements is ill-posed as it depends on derivatives of the head field. Consequently, any accurate method for its solution is likely to encounter numerically ill-conditioned systems. This paper reviews the geostatistical approach, and uses the stability analyses of linear algebra to show that, as the amount of available data increases and the discretization of the system is refined, both a numerically ill-conditioned parameter estimation problem and ill-conditioned cokriging equations may appear. Therefore, while the geostatistical approach does have conceptual appeal, it does not avoid the fundamental difficulties arising out of the ill-posed nature of transmissivity identification. Instead, the method is likely to be quite sensitive to these difficulties, so care must be taken in its formulation to minimize their effects. A means to stabilize the geostatistical method is suggested and numerical experiments that highlight key points of our analysis are given.
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  • 47
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary The sonic velocity of preoriented PET fibres as a function of temperature was measured in dependence on the degree of orientation, stress applied to the fibres, and heating rate. The results reflect the structural and orientation changes which take place in the range of and above the glass transition temperature.
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  • 48
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 13 (1985), S. 29-33 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary Natural rubber vulcanizates with high primary molecular weight were prepared by mixing raw rubber and dicumyl peroxide in benzene followed by freeze-drying. The stress-strain properties of these vulcanizates were quite different from those prepared by conventional mastication method. The important characteristics of these vulcanizates is high tensile modulus, high tensile strength, large hysteresis loss, and higher degree of strain-induced crystallization. The difference in the stress-strain behavior between these rubbers and conventional vulcanizates are discussed from the standpoint of the network structure.
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  • 49
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 50
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 13 (1985), S. 91-96 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary A modification of a theoretical model for the determination of the number average molecular weight between crosslinks, ¯Mc, is presented for the case of multifunctional junction functionalities in highly crosslinked, macromolecular systems.
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  • 51
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 13 (1985), S. 97-102 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary Three-arm star polyisobutylenes carrying tert.-chlorine end groups and a phenyl ring at the center of the star (see formula II in the Introduction) have been prepared by a continuous polymerization process. Thus into a stirred glass reactor were fed continuously a mixed feed of monomer plus trinifer (TCC) and a separate feed of BCl3 coinitiator in methyl chloride solvent at −40°C, and the product plus unreacted ingredients were removed continuously. Stationary conditions were maintained by keeping the rates of input and output (i.e., volumes) equal and constant. After a short induction phase (∼2–3 residence times) telechelic polymers of essentially theoretical number average end functionalities (¯Fn=3.0+0.1), close to theoretical molecular weights (¯Mn) and molecular weight distributions were obtained. The polymerization kinetics are discussed and compared to that of an earlier semicontinuous process used for the routine synthesis of telechelic polyisobutylenes.
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  • 52
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary A new series of thermotropic liquid crystalline poly(β-thioester)s was prepared by a Michael-type polyaddition of α,ω-polymethylenedithiols of different length to a mesogenic diacrylate containing two bis(p-oxybenzoate) units symmetrically connected through a dodecamethylene segment. The thermotropic behaviour was studied by combined DSC and thermal-optical analyses. All the poly(β-thioester)s investigated exhibited quite unusual monotropic mesomorphism.
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  • 53
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 13 (1985), S. 163-169 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary Composites of low-density polyethylene were prepared by the sorption of vinylic monomers and a photoinitiator into a polymer matrix, followed by UV irradiation. Gravimetric determinations showed that 2–4% incorporation of the polymer in the host matrix is possible by this method. Transmission and reflectance infrared spectra measurements showed that the vinylic polymer is lodged in the bulk of the polymer film with no surfacial deposition.
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  • 54
    Digitale Medien
    Digitale Medien
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    Polymer bulletin 13 (1985), S. 193-193 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 55
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 15 (1986), S. 517-524 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary Phase equilibria were investigated at 80°C for a ternary system involving a solvent benzyl alcohol, a rodlike polymer poly(γ-benzyl L-glutamate) (PBLG), and a flexible polymer polystyrene (PS). The fairly dilute solution of the two polymers was isotropic and monophasic. At greater concentrations, it was separated into two isotropic phases. Above an even higher critical concentration of the two polymers, three phases, a cholesteric (A1) and two isotropic phases (I1 and I2), coexisted at equilibrium. PBLG was contained exclusively in the phases A1 and I1, while PS was in the phase I2. The more concentrated solution was separated into a cholesteric phase and an isotropic phase. The latter contained PS but excluded PBLG, These features were discussed on the ground of the Flory theory by considering the polymer compatibility.
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  • 56
    Digitale Medien
    Digitale Medien
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    Polymer bulletin 15 (1986), S. 531-537 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary A study was made on the oxidation of a low density polyethylene and of an isotactic and an atactic polypropylene in solution. The solvent was 1,2, 4-trichlorobenzene and the process was investigated at different temperatures, with varying concentrations of the initiator and of the polymer. Under the experimental conditions, a non-accelerating chain reaction proceeds at the beginning of the process. The equation derived from the proposed simplified mechanism describes consistently the dependences of experimentally measured rates on the concentrations of the initiator and of the polymer.
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  • 57
    Digitale Medien
    Digitale Medien
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    Polymer bulletin 15 (1986), S. 547-549 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary Analysis of the hydroxyl content of a series of commercial poly(ethylene glycol)monomethy1 ethers by means of 360 MHz 1H NMR spectroscopy of the trichloroacetyl isocyanate modified polymers has shown that some compounds contain considerable amounts of poly(ethylene glycol).
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  • 58
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    Polymer bulletin 13 (1985), S. 463-467 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary Weight fraction activity coefficients (Ω1)∞ and interaction parameters x have been determined for seven different solvents in Polyarylate at three temperatures by the gas chromatographic method (inverse gas chromatography). Data have been used to calculate infinite dilution solubility parameters according to the method proposed by DiPaola-Baranyi and Guillet. The validity of the plots involved in the above mentioned method is also discussed.
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  • 59
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary 90 MHz-1H-NMR and 22.635 MHz-13C-NMR spectroscopy were used in a study of vinyl chloride-vinylidene chloride co-polymers. Triad sequence distribution of CCl2 and CHCl carbon was generated for these copolymers and compared to calculated distributions based on Bernoullian, first-order Markov and second-order Markov statistics. It was observed that for samples different in the conditions of preparation including commercial materials in each case different Markov models give the best fit in formally mathematical treatment without kinetic significance but with the aim of interpretation of physical and/or chemical properties of the copolymers. The 52–56 ppm region of the VC-VDC copolymer spectra is complicated by the superposition of the effects of tacticity, sequence distribution and the presence of both CH and CH2 carbons.
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  • 60
    Digitale Medien
    Digitale Medien
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    Polymer bulletin 16 (1986), S. 143-146 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary Aromatic polyureas and polythioureas are prepared from aromatic diamines and carbon dioxide or carbon disulfide, by a new direct polycondensation reaction with ethylene chlorophosphite as reagent in pyridine as solvent and acceptor for hydrochloric acid at 50–60° for 6–7 hours.
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  • 61
    Digitale Medien
    Digitale Medien
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    Polymer bulletin 14 (1985), S. 265-270 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary Two methods of the synthesis of tributyl ammonium derivatives of glycidyl methacrylate — ethylene dimethacrylate copolymers with various contents of the crosslinking agent were examined. While the two-step process which consists in a reaction with dibutyl amine followed by alkylation with butyl bromide gives products with up to 1.5 mmol/g of required groups, in the case of the single-step reaction of the epoxide group with tributyl amine the content does not exceed 0.4 mmol/g. The use of diamines for increasing the distance between the quaternary group and the polymer backbone does not yield a readily definable product, and cannor therefore become the method of choice.
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  • 62
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary A novel series of photoinitiators for cationic polymerization have been prepared which bear two and three photoactive triarylsulfonium groups in the same molecule. These compounds have been fully characterized by means of their UV and C-NMR spectra and liquid chromatography as well as by their elemental analyses. The multifunctional triarylsulfonium salts have been compared among themselves and against monofunctional triarylsulfonium salts in the photoinitiated cationic polymerization of dl-limonene dioxide.
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  • 63
    Digitale Medien
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    Polymer bulletin 14 (1985), S. 399-406 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary The miscibility of blends of poly(butylene terephthalate) and poly(bisphenol A-carbonate) was investigated using differential scanning calorimetry. Contrary to previously reported data, PBT and PC were found to be almost completely immiscible over the entire compostion range studied. The minor change in Tg's observed for samples quenched form the melt can be attributed to transesterification at elevated temperatures. The melting behavior and normalized enthalpy of fusion are somewhat dependent on composition but the behavior is erratic.
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  • 64
    Digitale Medien
    Digitale Medien
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    Polymer bulletin 14 (1985), S. 417-423 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary Two unsaturated ester-containing vinyl ethers, 2-vinyloxyethyl acrylate $$(\mathop 1\limits_ )$$ and sorbate $$(\mathop 2\limits_ )$$ , were polymerized by the hydrogen iodide/iodine (HI/I2) initiating system in toluene at −15 or −40°C, to give “living” polymers, having a very narrow molecular weight distribution (Mw/¯Mn=1.10–1.15) and crosslinkable via their pendant C=C double bonds. The number-average molecular weight of the polymers increased in direct proportion to conversion, and further increased on addition of a new monomer feed to a polymerized reaction mixture. According to 1H and 13C NMR structural analysis, the polymerization proceeds exclusively via the vinyloxyl group of the potentially bifunctional monomers without undesirable side reactions of the unsaturated ester pendants.
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  • 65
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary The radical copolymerization of methyl- and butyl methacrylates with an electrondonor monomer: N-(2-hydroxyethyl)-carbazolyl methacrylate and an electron-acceptor monomer: (β-hydroxyethyl)-3,5-dinitrobenzoyl-methacrylate respectively, in dioxane at 60°C was investigated. The reactivity ratios of the binary systems were computed by using the Kelen-Tüdös method. The azeothropic compositions were established according to the respective copolymerization diagrams.
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  • 66
    Digitale Medien
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    Polymer bulletin 14 (1985), S. 461-468 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary The small-angle X-ray scattering curves of carboxy-telechelic polymers exhibit very strong scattering at the lowest angles which points to the presence of large aggregates in the samples. Beyond the position of the main scattering maximum, common to all ionomers, a faint modulation is observed at a position corresponding to a second diffraction order. These observations are discussed with respect to other data in the litterature.
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  • 67
    Digitale Medien
    Digitale Medien
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    Polymer bulletin 14 (1985), S. 477-477 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
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  • 68
    Digitale Medien
    Digitale Medien
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    Polymer bulletin 14 (1985), S. 491-495 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary Bulk polymerizations of L,L-lactide were conducted at 120 and 180°C, but mainly at 150°C. Magnesium oxide, ethoxide, acetate, stearate, and 2,4-pentane dionate were used as catalysts. Time conversion curves show that at least a temperature of 150°C and a reaction time of 72 h is required for maximum conversion. The highest yields (up to 96 %) were obtained with magnesium oxide. However, all initiators, in particular magnesium oxide, caused racemization which increased with reaction time and temperature. Polymerizations in solutions at temperatures around 100°C failed regardless of the solvent.
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  • 69
    Digitale Medien
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    Polymer bulletin 14 (1985), S. 497-502 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary L,L-lactide was polymerized in bulk at 120°C, 150 or 180°C by means of various metal oxides, carbonates or carboxylates. Yield, viscosities and optical rotation were measured and compared. Several catalysts enable a nearly complete conversion even at 120°C indicating rapid diffusion of the monomer in the solid reaction mixture. At 180°C only SnO and Sb2O3 proved to be useful catalyst, because they gave within 12 h yields 〉 80% along with an optical purity around 97%. Longer reaction times lead at 180°C to substantial racemization in all cases.
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  • 70
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary It is shown that i-butyl vinyl ether, tetrahydrofuran, epichlorhydrin and cyclohexene oxide, which undergo typically cationic polymerisation, are polymerised by UV-irradiation in the presence of diacetoxyiodobenzene or bis(trifluoroacetoxy)iodobenzene.
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  • 71
    Digitale Medien
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    Polymer bulletin 14 (1985), S. 527-534 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary The preparation of high molecular weight nylon 4 with alkali metal pyrrolidonate catalysts, acyl initiators, and CO2 was studied. Isolated sodium pyrrolidonate and the appropriate amount of acyl initiator gave unusually high molecular weight nylon 4 (mw 〉200,000). The molecular weight-initiator concentration relationship indicates that acyl compounds play a dual role in the polymerization, acting both as initiators and scavengers for chain-terminating impurities. One potential chain terminator was identified as 4-aminobutyric acid. The high polymer molecular weights obtained in the presence of CO2 can also be explained by the scavenging of chain terminators by CO2. Determination of the number of growing chains, however, shows that CO2, unlike the acyl compounds, is not an initiator in nylon 4 polymerization.
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  • 72
    Digitale Medien
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    Polymer bulletin 14 (1985), S. A3 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
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  • 73
    Digitale Medien
    Digitale Medien
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    Polymer bulletin 15 (1986), S. 89-91 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary The distances of stacked bases of DNA in different conformations can-not be calculated by equilibrium potentials, since they exhibit not more than only one minimum. However, a double potential minimum is obtained by considering the most simple semiclassical model of excitons that are coupled adiabatically to lattice vibrations, hence forming polaritons. By use of Danilov's extended Hückel approximation of DNA excitons, stacked base distances can be calculated that agree fairly well with the experimental data. The errors of this approach are small as compared to the differences of the distances in various conformations. Consequently, this model may work as a first base of understanding molecular interactions in DNA.
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  • 74
    Digitale Medien
    Digitale Medien
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    Polymer bulletin 15 (1986), S. 491-495 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract N-(p-methylstyryl)-(1R,2S)-ephedrine is prepared by alkylation of p-chloromethylstyrene under conditions which do not favor quaternization. A series of Copolymerization reactions confirm that the new chiral monomer and styrene copolymerize in random fashion with r1=1.09 and r2=0.98. The optical rotation of the copolymers does not vary linearly with composition. Applications of the copolymer include its use as chiral ligand for asymmetric synthesis or as a separation medium.
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  • 75
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary To study the influence of dipolar moments on the permittivity of polymers, three isomeric polymers ortho, meta and para polymethoxystyrenes have been synthesized. Physical properties and NMR studies1H and13C are described.
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  • 76
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary Nitrile rubber (NBR) was reinforced by poly(p-phenylene terephthalamide) (PPTA) with a coprecipitation method from a common solvent of them. PPTA was converted to N-sodium PPTA with sodium hydride in DMSO, forming homogeneous solution. DMF dissolves NBR. Both solutions were blended to form an isotropic solution. The precipitant was NBR reinforced by PPTA which was regenerated from N-sodium PPTA at coagulation as reported previously. The molecular composite thus obtained was mill-blended with poly(vinyl chloride) (PVC) in order to enhance solvent resistant property. The vulcanized composite of NBR/PVC reinforced by PPTA showed higher modulus, higher strength and more improved solvent resistance than the gum stock and the black stock of NBR/PVC. The properties of the molecular composite containing 5phr PPTA found approximately comparable to those of the black stock of NBR/PVC with 30–40phr ISAF carbon black.
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  • 77
    Digitale Medien
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    Polymer bulletin 13 (1985), S. 65-70 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary Copolymers of 2-ethyl-2-oxazoline and phtalic anhydride without initiator in DMF at 60 °C were synthesized. The copolymers were statistical, rich in 2-ethyl-2-oxazo1ine. A partial hydrolisis of pendant groups -COCH2CH3 is observed. The composition and the hydrolisis degree of the copolymers was determined by 1H-NMR. A copolymerization scheme via zwitterion is proposed.
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  • 78
    Digitale Medien
    Digitale Medien
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    Polymer bulletin 13 (1985), S. 90-90 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
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  • 79
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary A R 401 Waters Assoc. differential refractometer has been modified to obtain the variation of refractive index increments, dn/dc, of polymer solutions at 633 nm. The introduced modifications were in the sample injection system and in the light source. The performance of the modified refractometer both with aqueous and organic solutions is analyzed. In order to localize a conformational transition in lysozyme, the dependence of dn/dc on temperature for lysozyme solutions in phosphate buffer is studied. Similarly, (dn/dc)k values for the ternary n-alkane/butanone/poly(dimethyl siloxane) systems over the whole composition range of the binary solvent mixtures are evaluated.
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  • 80
    Digitale Medien
    Digitale Medien
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    Polymer bulletin 13 (1985), S. 109-114 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary Diblock copolymers of acetylene and styrene were prepared by treating Ti(OBu)4 with polystyryl lithium followed by reaction with acetylene. Reliable evidence for the formation of block copolymers was derived from dual radiotagging experiments.
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  • 81
    Digitale Medien
    Digitale Medien
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    Polymer bulletin 13 (1985), S. 123-130 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary Poly (isobutylene-b-ethylene glycol) PIB-b-PEG diblock copolymers have been synthesized by reacting tolylene 2,4-diisocyanate-capped polyisobutylene with monohydroxyl-ended poly(ethylene glycol). The block copolymers form stable benzenewater emulsions and show surface activity decrease in interfacial surface tension, and existence of critical micelle concentration. Turbidimetry of the block copolymers indicates the expected wide range of solubility from nonpolar to polar solvents. The temperature dependence of the intrinsic viscosity of the block copolymers exhibits characteristic discontinuities. The intrinsic viscosity of the block copolymer as a function of solvent polarity was studied and the observations were explained as the sum of segment contributions based on the “segregated” conformation model. DSC also indicates microphase separation in the solid state due to segment incompatibility.
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  • 82
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary The nucleophilic substitution with C6H5SNa, at -30°C, is compared for five PVC samples with various contents of isotactic triads. The conversion curves consist of a very fast stage followed by a steady one. All the samples are found to behave in the same way except for the content of the structures involved in the fast period. This content is estimated by extrapolating the straight lines of the steady stages to zero time. The obtained values are found to be a linear function of the content of isotactic triads. The results, together with some earlier ones, allow for the content of the labile non-defect structures in PVC to be determined.
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  • 83
    Digitale Medien
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    Polymer bulletin 13 (1985), S. 185-192 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract The influence of non macroporous and macroporous supports on a test reaction is studied. t-BuOH reacts with tetra O-acetyl bromoglucose in presence of silver nitrate and a supported crown ether. Two reaction products are formed. Yield and selectivity are affected by the morphology of the support. The selectivity depends on the crosslinking degree. This dependence is explained by the rigidity of the matrix and by the variation of steric hindrance.
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  • 84
    Digitale Medien
    Digitale Medien
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    Polymer bulletin 14 (1985), S. 61-68 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary The influence of draw ratio on macroscopic and crystallographic density of polyethylene with different initial morphologies, has been investigated by solid-state extrusion. An initial drop followed by an increase in macroscopic density as a function of draw ratio has been observed. Since precision X-ray measurements of unit cell parameters showed no variation of crystallographic density, it was concluded that plastic deformation of polyethylene upon drawing proceeds with a decrease of the degree of crystallinity. This was confirmed by differential scanning calorimetry.
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  • 85
    Digitale Medien
    Digitale Medien
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    Polymer bulletin 14 (1985), S. 73-77 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary 2-lsopropenylquinoline has been synthesized, and anionic homopolymerization has been performed with n-butyllithium and with dibutylmagnesium, yielding polymers with high glass transition temperatures, with Mn ranging from 3700 to 210300. Molecular heterogeneities have been determined by GPC. Mw has been measured by light scattering. The glass transition temperature for infinite molecular weight is 475 K. The ceiling temperature, 367 K, was calculated from 1H-NMR spectra recorded from living poly-(2-isopropenylquinoline) at different temperatures. Two- and threeblock-copolymers have been obtained by initiating 2-isopropenylquinoline with living polybutadiene.
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  • 86
    Digitale Medien
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    Polymer bulletin 14 (1985), S. 99-104 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary Densitometric conformational studies were made on poly(1-vinyl-2-pyrrolidone-co-maleic acid) in the presence of LiCl, NaCl, KCl, CaCl2, and MgCl2, in order to control ion-binding of the polyanion in dilute aqueous solution. Experimental verification of principal role of deprotonation in the conformational transition of the polyacid chains during titration is given. Correlation was found between the apparent molar volume of the copolymer and the ionic radius of the bound cation.
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  • 87
    Digitale Medien
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    Polymer bulletin 15 (1986), S. 135-140 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary Polycarbonates of Bisphenol A were prepared with 2 (2, 4-dihydroxyphenyl) 2H-4-hydroxybenzotriazole or 2 (2, 4-di-hydroxyphenyl) 2H-1,3-di (4-hydroxybenzotriazole) ultraviolet stabilizers permanently incorporated into the polycarbonate main chain. Direct polycarbonate formation from Bisphenol A and diphenyl carbonate or transesterification using previously prepared polycarbonate in the melt with ultraviolet stabilizers 2 (2, 4-dihydroxyphenyl) 2H-4-hydroxybenzotriazole or 2 (2, 4-dihydrophenyl) 2H-1,3-di (4-hydroxybenzotriazole) or the corresponding acetyl compounds gave the final polycarbonates which were characterized.
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  • 88
    Digitale Medien
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    Polymer bulletin 15 (1986), S. 165-171 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary Infra-red dichroism has been used to measure the orientation of the different sequences of isotopically labelled block copolymers. We have determined the orientation from dichroic ratios of two bands of deuterated polystyrene, and compared in block copolymers the orientation of the central part of the chain with that of the ends. The relaxation of the ends is more rapid, than that of the center, which exhibits a “plateau”.
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  • 89
    Digitale Medien
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    Polymer bulletin 15 (1986), S. 173-179 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary By reacting polybutadiene with 4-Phenyl-1, 2, 4-triazoline-3, 5-dione (PTD) urazole groups are added to the polymer. The formation of hydrogen bonds between different urazole groups is investigated by IR-spectroscopy at various temperatures. The carbonyl stretching vibrations at 1700 and 1723 cm−1 could be attributed to hydrogen bonded and free urazole groups. With increasing temperature the fraction of bonded groups decreases. From the overall change in the absorption the ratio of the extinction coefficients of bonded and free C=O is determined. The stability of the hydrogen bonds is explained by a chelate like complex between two urazole groups.
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  • 90
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary Polymer pseudocrownethers based on polyphosphazene are active catalysts of nucleophilic substitution reactions. With respect to the catalytic activity, polyphosphazene is a more suitable carrier of oligo(oxyethylenes) than poly(styrene-co-divinylbenzene). With increasing length of oligo(oxyethylene) branches the catalytic activity of polymers increases. The favorable effect of the content of pseudocrownether structures is particularly visible in polymers having a longer oligo(oxyethylene) chain in those reactions in which the polymer acts as a solid cosolvent. The catalysts preserve their activity also if reused.
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  • 91
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    Polymer bulletin 15 (1986), S. 317-323 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract A new family of initiating systems has been discovered that efficiently induces the truly living polymerization of isobutylene (IB). The initiating systems are complexes of organic tertiary esters e.g., cumyl acetate, 2,4,4-trimethylpentane-2-acetate, with BCl3. Living polymerizations proceed very rapidly in a variety of solvents, i.e., CH3Cl, CH2Cl2, C2H5Cl, and mixtures of chlorinated solvents plus n-hexane, in the range from −10° to −50°C. The living nature of the polymerizations was demonstrated by linear ¯Mn versus WPIB (g of polymer formed) plots starting at the origin and horizontal N (number of PIB chains) versus WPIB plots. The DPn of the products obeys [Mo]/[Io] where [Mo] and [Io] are initial monomer and initiator concentrations, respectively. Conversions and initiator efficiencies are ∼100%. In carefully controlled experiments narrow molecular weight distribution polyisobutylenes (PIB) have been obtained, i.e., Mw/Mn=1.17 − 1.3. A mechanism is outlined that helps rationalize the findings. It is postulated that the living polymerization of IB initiated by organic tertiary ester·BCl3 complexes most likely proceeds by a two-component group transfer polymerization process.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 92
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 15 (1986), S. 349-352 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary Liquid crystalline polymers with mesogenic groups laterally attached to the polymer backbone were investigated by polarizing microscopy with respect to their optical properties. The nematic polymers were macroscopically oriented in a magnetic or electric field. Polarization microscopic investigations with convergent polarized light show optical biaxial behavior of the nematic phase.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 93
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract The surface orientation of polyester fibers has been studied by a modified sampling technique using Fourier transform infrared (FT-IR) diffuse reflectance spectroscopy. The fiber axes were arranged parallel to incident radiation first, and then perpendicular to it. The differences in total absorbance and relative intensity changes in the spectra obtained show the features of specular reflection. The technique has the advantage over ATR that there is no optical contact problem.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 94
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 15 (1986), S. 381-387 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract Elongational data on a series of polyethylenes with different structure and on their blends are presented in order to correlate the extensional behaviour with the long chain branching degree. The results show that the strain hardening effect increases with the number of branch points; the troutonian value is reached when the branching index is larger than 0.6. Empirical correlations between elongational viscosity and branching index are also presented.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 95
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 15 (1986), S. 405-409 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary New diamines containing alkaneoxy linkages have been prepared by hydrolysis of the corresponding diamides which were obtained by reaction of p-hydroxyacetanilide with different dibromo alkanes. These diamines were copolymerized with glyoxal to yield insoluble copolymers in solvents such as DMSO, CH3OH, CH3COCH3, CHCl3. The diamides and diamines were characterized by IR, 1H NMR spectroscopy and elemental analyses and the copolymers were characterized by IR spectroscopy and elemental analyses.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 96
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 15 (1986), S. 431-438 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Abstract A method of preparation giving high yields for 4-chloro-3-nitrostyrene and some derivatives is described. First trials of free radical polymerization and copolymerization are reported and show a deactivating influence of the nitro group.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 97
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 15 (1986), S. 445-447 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary It is shown that the heat capacities of semicrystalline poly(oxymethylene)s (POM) measured recently by Illers and published in this journal support, rather than refute, the existence of a “rigid, amorphous fraction”. The former was suggested by Illers, the latter was our proposal (Suzuki et al.).
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 98
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 15 (1986), S. 476-476 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 99
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 15 (1986), S. 479-484 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary Oxochloro(5,10,15,20-tetraphenylporphyrinate)molybdenum (V) was physically entrapped into poly (styrene) by lyophilizing a benzene solution including both complex and polymer. The functional ability of the obtained complex-containing resin to adsorb H2PO4 − from an aqueous solution was investigated in the presence of various anions. It was found that the selectivity of the resin for H2PO4 − is superior to those of conventional anion exchangers.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 100
    Digitale Medien
    Digitale Medien
    Springer
    Polymer bulletin 15 (1986), S. 525-530 
    ISSN: 1436-2449
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Summary The spin probe technique of electron spin resonance (ESR) spectroscopy has been applied for studying the plasticizer diffusion, migration, and redistribution processes in suspension polymerized PVC particles. In the first series of experiments six PVC powder samples with different K values (58, 61, 64, 67, 70, and 72) were mixed with diisooctyl phthalate (DOP) containing 10−4 M 2,2,6,6-tetramethyl-piperidine-1-oxyl (TEMPO) as stable free radical spin probe. In the second run TEMPO-doped dry PVC powders were mixed with DOP plasticizer. Finally we studied the plasticizer transport phenomena between plasticized and non-plasticized polymer particles in powder mixtures. The observed diffusion properties of different samples were interpreted in terms of the different porosities of powders.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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