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  • General Chemistry  (22,629)
  • Inorganic Chemistry  (16,701)
  • Humans
  • 1985-1989  (10,443)
  • 1975-1979  (8,557)
  • 1965-1969  (10,501)
  • 1960-1964  (8,438)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of molecular evolution 27 (1988), S. 311-320 
    ISSN: 1432-1432
    Keywords: Genome composition ; Coding sequences ; Isochores ; Humans ; Murids
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Summary The compositional distributions of coding sequences and DNA molecules (in the 50-100-kb range) are remarkably narrower in murids (rat and mouse) compared to humans (as well as to all other mammals explored so far). In murids, both distributions begin at higher and end at lower GC values. A comparison of homologous coding sequences from murids and humans revealed that their different compositional distributions are due to differences in GC levels in all three codon positions, particularly of genes located at both ends of the distribution. In turn, these differences are responsible for differences in both codon usage and amino acids. When GC levels at first+second codon positions and third codon positions, respectively, of murid genes are plotted against corresponding GC levels of homologous human genes, linear relationships (with very high correlation coefficients and slopes of about 0.78 and 0.60, respectively) are found. This indicates a conservation of the order of GC levels in homologous genes from humans and murids. (The same comparison for mouse and rat genes indicates a conservation of GC levels of homologous genes.) A similar linear relationship was observed when plotting GC levels of corresponding DNA fractions (as obtained by density gradient centrifugation in the presence of a sequence-specific ligand) from mouse and human. These findings indicate that orderly compositional changes affecting not only coding sequences but also noncoding sequences took place since the divergence of murids. Such directional fixations of mutations point to the existence of selective pressures affecting the genome as a whole.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-0878
    Keywords: Skeletal muscles ; Ultrastructure ; Exercise ; Glycogen ; Humans
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary Distribution of glycogen particles in semithin and ultrathin sections of biopsy samples from human muscles subjected to either short- or long-term running were investigated using PAS and Periodic Acid-ThioSemiCarbazide-Silver Proteinate (PA-TSC-SP) staining methods. Glycogen particles were predominantly found immediately under the sarcolemma or aligned along the myofibrillar Iband. After long-term exhaustive exercise type-1 fibers with a few or no glycogen particles in the core of the fibers were frequently observed. The subsarcolemmal glycogen stores of these “depleted” type-1 fibers were about three times as large as after exhaustive short-time exercise. Another indication of utilization of subsarcolemmal glycogen stores during anaerobic exercise was that many particles displayed a pale, rudimentary shape. This observation suggests fragmental metabolization of glycogen. Thus, depending on type of exercise and type of fiber differential and sequential glycogen utilization patterns can be observed.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 93 (1960), S. 99-102 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 8-Alkyl- und 8-Alkenyl-theophylline werden aus 1.3-Dimethyl-4.5-diaminouracil und gesättigten Carbonsäuren bzw. β.γ- und γ.δ-ungesättigten Carbonsäuren durch Kondensation nach TRAUBE dargestellt; α.β-ungesättigte Säuren reagieren nicht.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 93 (1960), S. 280-282 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 7-Mercapto-cholesterin wurde durch Hydrogenolyse des aus 7-Brom-cholesterylbenzoat hergestellten 7-Acetylmercapto-cholesteryl-benzoats erhalten. Seine Konfiguration am Kohlenstoff 7 wird diskutiert.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 93 (1960), S. 286-288 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 93 (1960) 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 93 (1960), S. 137-140 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Synthese der 1.3.5-Triacetyl-2-desoxy-β-D-ribofuranose beschrieben. Die Struktur wird durch Messung der kernmagnetischen Resonanz unter Vergleich mit den beiden β-D-Ribose-tetraacetaten (1.3.4 bzw. 1.3.5) bewiesen.
    Additional Material: 2 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 93 (1960), S. 424-427 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Einwirkung von Silazanen auf Aminosäuren entstehen N-Trialkylsilyl-aminosäure-trialkylsilylester und Aminosäure-trialkylsilylester.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 93 (1960), S. 462-467 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In Fortführung der Versuche über phosphinhaltige Kobaltcarbonyle hat sich ergeben, daß der Reaktionsverlauf von der speziellen Art des Phosphins, d. h. den am Phosphor gebundenen organischen Resten, abhängt. So entstehen mit Triäthyl- und Tricyclohexyl-phosphin bevorzugt (ca. 10°) die 2-ionigen Verbindungen [Co(CO)3L2][Co(CO)4] (L = P(C2H5)3, P(C6H11)3); nur bei höherer Temperatur (ca. 35°) und in indifferenten Mitteln bildet sich das betr. echte Derivat des Kobaltcarbonyls [Co(CO)3L]2, das mit Triphenylphosphin auch schon bei tieferer Temperatur entsteht. Häufig liegen Gemische beider Verbindungstypen vor.  -  Mit Triphenyl-arsin und -stibin sind die gleichfalls bei tieferer Temperatur (0°) gebildeten 2-ionigen Verbindungen nur labil und wandeln sich spontan unter CO-Abgabe in die echten Derivate um.  -  Ergänzende weitere Versuche wurden mit Mangancarbonyl und der 2-zähligen Base Äthylen-bis-[diphenylphosphin] und mit Rheniumcarbonyl und Triphenylphosphin durchgeführt. Im letzteren Fall erhält man das diamagnetische Monosubstitutionsprodukt [Re(CO)4P(C6H5)3]2.
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 93 (1960), S. 397-405 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Eine Anzahl diazotierter heterocyclischer Amine wurde mit Phenoläthern und aromatischen Kohlenwasserstoffen auf ihr Kupplungsvermögen geprüft. Die Versuche zeigten, daß insbesondere Verbindungen aus der 1.2.4- und 1.3.4-Thiodiazol-Reihe eine sehr hohe Reaktivität besitzen, die diejenige des diazotierten 2.4-Dinitro-anilins deutlich übertrifft.
    Type of Medium: Electronic Resource
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