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  • Articles  (295)
  • Polymer and Materials Science  (295)
  • Wiley-Blackwell  (295)
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  • Architecture, Civil Engineering, Surveying  (295)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 17 (1993), S. 185-190 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Different types of floor coverings were tested using three different methods: the Cone Calorimeter (ISO 5660), the Nordtest floor covering test NT FIRE 007 and the German Radiant Panel Method (DIN 4102 Teil 14). The results of the comparisons between both flame spread and smoke production are given. Some correlation is found between the results of the Cone Calorimeter and the NT FIRE 007. Between other methods, no correlations seem to exist.
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  • 2
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    Fire and Materials 17 (1993), S. 249-254 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: External radiation in enclosure fires can significantly enhance flame spread and fire growth. One of the effects of external radiation is to increase the mass loss rate of the fuel, which in turn produces larger flames. In this work, a measurement of mass loss with and without applied radiation was made as a function of time for three types of materials: a plastic (polymethylmethacrylate), wood-based products (particle board and hardboard), and a paper-based product (cardboard). The levels of applied radiation ranged from 0 to nearly 12 kWm-2. The purpose of the investigation was to (1) quantitatively determine the effect of external radiation on the mass loss of various materials,(2) measure various parameters which may be used to characterize the mass loss rate history of the materials and (3) determine a method for expressing the mass loss rate as a function of time for input into numerical models. Higher levels of external radiation resulted in higher peak mass loss rates and quicker consumption of the material. Quantities which are useful for ranking the flammability of materials have been measured for the samples tested and are tabulated.
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  • 3
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 17 (1993) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 4
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    Fire and Materials 17 (1993), S. 259-263 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A new Intermediate Scale Heat Release Rate Test Method is being developed primarily for testing assemblies in the vertical mode. Using the oxygen consumption calorimetry methodology and exhaust collection systems that already exist in many laboratories in the US and around the world, the apparatus is very economical to install. The sample size lends itself to reptitive testing in a short period of time. Sample preparation is generally quick and easy. Further development of the method should progress now that the method has been introduced at ASTM and will be introduced formally into ISO in the near future. There has been a favorable response by several laboratories who are considering construction of the apparatus. Additional assemblies tests are already underway and additional data will be presented in the near future.
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  • 5
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    Fire and Materials 17 (1993), S. 271-277 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In the study of smoke suppressants the measurement of gross amount of smoke from a given sample is essential. However, smoke being a complex phenomenon, its measurement with optical methods presents practical problems. The paper describes a flow system for the measurement of smoke production. Effectiveness of smoke-suppressant formulations for poly(vinyl chloride) as assessed in a flow system is reported. Results of experiments conducted to probe and establish the capability of smoke measurement in a flow system using a helium-neon laser are discussed.
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  • 6
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    Fire and Materials 18 (1994), S. 231-241 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper extends previously reported work 1,2 and describes the influence that a range of selected flame retardants have on the burning behaviour and pyrolyses of homo-and copolymers of acrylonitrile. Various inorganic and organic phosphorus and nitrogen- or sulphur-containing, halogen-containing (in the absence and presence of halogen or antimony (III) oxide) and nitrogen-containing flame retardants and red phosphorus were studied using LOI, TGA, DSC and residual char measuring techniques. Flame retardancy relates directly to char-forming tendency for all retardants and their ability to reduce the dominance of flammable volatiles formed during the first stage of acrylic polymer pyrolysis. Ammonium phosphates are particularly effective flame retardants for the selected copolymers. Possible mechanisms of retardant activity are discussed, including the char-forming tendency of antimony-bromine combiniations.
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  • 7
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 18 (1994), S. 263-265 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 8
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Much of the information accumulated on the fire resistance of ‘dividing’ elements can be utilized in the design of buildings for fire safety, if the fire tolerance values are converted into fire resistance. Three methods of conversion, one based on the concept of equal temperature-time areas, the second on the concept of equal maximum temperatures, and the third, Law method, are critically examined and handy conversion tools presented. In the case of the ‘key’ elements of buildings, basing the fire safety design on fire resistance information is not recommended.
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  • 9
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    Fire and Materials 1 (1976), S. 2-8 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The flammability and smoke generation properties of a number of organic materials used in ships, including laminated materials, rigid and flexible cellular polymers, cable insulting materials and adhesives, have been evaluated. The relative flammabilities were determined by the limiting oxygen index method that gives convenient, reproducible, numerical ratings of materials. Smoke generation was assessed photometrically by measuring light attenuation under standard conditions and is reported in terms of the total amount of smoke generated, as well as the times for the smoke density to reach an arbitrary ‘critical’ level and the maximum value. Materials with low flammability and low smoke generation characteristics have been identified, as well as those that would be hazardous in the event of a fire.
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  • 10
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    Fire and Materials 1 (1976), S. 24-28 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An apparatus based on the BS 476 Part 7 small scale flame-spread specification, which has evolved over a number of years, is described. Many changes from the original simple gas/air furnace have been introduced, which have led to the development of a very useful flame-spread test apparatus where all known variables are precisely controlled. The work has shown that the radiometers described in the standard do not monitor all the variables which affect flame-spread results, and reported problems of reproducibility and variation on the large scale test, may be due to inadequate control of the furnace. The significance of the results is that the use of gas/air radian panels as the basis for flame-spread tests needs to be re-examined. All parameters should be carefully controlled and the entire procedure, particularly regarding the use of pilot ignition sources, needs to be reconsidered. There is an increasing need for test methods which assess materials at radiation intensities beyond that given by small ignition sources. The type of flame-spread apparatus described in the paper may help fulfil this important requirement.
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  • 11
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    Fire and Materials 1 (1976), S. 42-42 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 12
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    Fire and Materials 1 (1976), S. 36-41 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Quantitative pyrolysis gas chromatography studies have been conducted on three grades of cross-linked polyester resin formulated for improved resistance to surface spread of flame. Pyrolysis temperatures from 723 to 1273 K were used, and these values correspond to ‘surface’ temperatures of materials exposed to heat fluxed of 15-149 kW m-2 which are typical of conditions experienced in real fires. Comparison is made with earlier macro studies on the evolution of smoke from plastics materials exposed to similar heat fluxes under an inert atmosphere. There is some correlation between the smoke obscuration data obtained in previous macro studies and the yield of volatile aromatic products evolved on pyrolysis. The presence of flame retardants increases the formation of carbon in the pyrolysis residue and decreases the yield of volatile aromatic products isolated. The results are considered in the context of mechanisms of smoke formation.
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  • 13
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    Fire and Materials 1 (1976), S. i 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 14
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    Fire and Materials 1 (1976), S. i 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 15
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    Fire and Materials 1 (1976) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 16
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    Fire and Materials 1 (1976), S. 43-47 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Smoke evolved from burning poly-(vinychloride) plasticized with diisooctylphthalate has been studied using a light absorption method. It has been shown that the quantity of smoke produced depends upon the oxygen concentration of the oxidizing gas as well as on the concentration of diisooctylphthalate present in the polymer. The results of this work have been analysed using an empirical equation proposed by the authors, which correlates the maximum smoke density (σmax) with oxygen concentration. This equation may be written \documentclass{article}\pagestyle{empty}\begin{document}$$ \sigma _{\max } = \sigma _{LOI} \exp (- k(No_2 - LOI)) $$\end{document} where No2 is the molar concentration of oxygen in the oxidizing gas, and LOI refers to the limiting or critical concentration of oxygen at which at the polymer will just burn, as defined by the ASTM test 2863. The effect of various additives, particularly organic iodine compounds, as smoke suppressants has also been investigated.
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  • 17
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    Fire and Materials 1 (1976), S. 57-62 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The pyrolysis and combustion products of poly-(vinyl chloride) and those of some of its polymer, especially of vinyl chloride with vinylidene chloride, were analysed using gas chromatography and gas chromatography mass spectrometry. The toxic effect of the individual products on the human organism was evaluated and presumed total toxicity of the poly-(vinyl chloride) combustion products (0.3g PVC products per m3) was determined.
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  • 18
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    Fire and Materials 15 (1991), S. 47-49 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 19
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    Fire and Materials 15 (1991), S. 43-46 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Three small-scale flammability tests were evaluated for potential use in quality control. The small-scale flame test produced excessive scatter of data, the hot-plate ignition test gave reasonably reproducible data, but the critical oxygen index yielded superior results and is recommended for quality control testing.
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  • 20
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    Fire and Materials 15 (1991), S. 37-42 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The fire-retardant effectiveness of mixtures of hexabromocyclododecane (HBCD) and artimony oxide (Sb2O3) in polyethylene (PE) was examined utilizing differential thermal analysis (DTA), gas chromatography/mass spectroscopy (GC/MS) and limited oxygen index (LOI) techniques. It was determined that the normal practice of mixing Sb2O3 with HBCD induced a synergistic chemical reaction at 250°C whose main product, SbBr3, was responsible for enhanced fire retardancy. The mixing of SbBr3 directly into the PE produces a superior fire-retardant polyethylene.
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  • 21
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    Fire and Materials 15 (1991) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 22
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    Fire and Materials 15 (1991), S. 51-51 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 23
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    Fire and Materials 15 (1991), S. 65-84 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An evaluation of the cone calorimeter by the Association of Plastic Manufacturers in Europe (APME) involved testing of 25 plastic materials together with two natural polymers. Specimen preparation is identified as having an important influence on the results, especially for certain types of material. Ignition time, rate of heat release (RHR) and smoke results are presented to show the influence of external heat flux. The dynamic smoke results (which should be measured from the time of exposure) are only relevant to well-ventilated fires unless the cone calorimeter is specially modified. For a complete evaluation a cumulative smoke measurement may be needed in addition. Although the cone calorimeter is a valuable research tool, and may be used frequently in industry, it needs to be made more robust and user friendly to avoid excessive downtime and to reduce calibration time. If the instrument is to be used for routine development and quality assurance, only one or two heat flux levels should be selected. These could represent a developing and a developed fire and should depend on the product application.
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  • 24
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    Fire and Materials 15 (1991), S. 93-96 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Combustible dusts, based on tests conducted in the Setchkin Furnace on five representative dusts, are shown to have two distinct layer minimum ignition temperatures, designated MITnon-flaming and MITflaming. The MITnon-flaming is the one usually reported in the literature; the MITflaming is determined by starting at a much higher temperature and working downwards. MITflaming can yield a different ranking of dust flammability than MITnon-flaming. The MITflaming appears to be more closely correlated to the MIT of dust clouds and to the test prescribed for flammable solids in the US Code of Federal Regulations than the MITnon-flaming.
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  • 25
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    Fire and Materials 15 (1991), S. 127-130 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The flammability and ignitability of polyethylene using antimony trihalide compounds as fire retardants was evaluated by standard methods to determine retardant effectiveness. Compared with other retardants, the antimony trihalide compounds, antimony tribromide and antimony trichloride, substantially reduced both the flammability and the ignitability of the polyethylene. The influence of retardant concentration, heat flux and type of polyethylene was also studied.
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  • 26
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    Fire and Materials 15 (1991), S. 117-125 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A study of the behaviour of aluminium building products in bushfires was carried out to test the validity of assertions that they perform poorly under bushfire conditions. The work was conducted in two parts: an examination of data from bushfire damage surveys and laboratory experiments in which window assemblies were exposed to radiant heat from a furnace. Data from surveys conducted after major bushfires were augmented with information from a questionnaire related specifically to this work. Analysis of these data did not provide any support for the belief that houses incorporating aluminium building products are at greater risk of being destroyed. The laboratory experiments on both timber- and aluminium-framed windows showed their performance under simulated bushfire conditions to be similar. It was found that bending of glass through distortion of the frames was not a factor in crack initiation.
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  • 27
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    Fire and Materials 15 (1991), S. 105-115 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A study of the fire behaviour of polypropylene plastics trays being considered for letter handling has been carried out. Various ignition sources and configurations of trays (both empty and filled with letters) were examined. In particular, stacks of trays contained in large steel-mesh unit load devices (ULDs), protected by automatic sprinklers, were ignited and the progress of the fires, release of heat and smoke, and sprinkler activation recorded. It was found that, when examined singly or in stacks in scenarios which might be encountered in sorting areas and post offices, the trays made from fire-retardant plastics were more difficult to ignite and took longer to become involved in fire than those made from standard grade plastics. The benefits of this slower build-up fire with the retarded plastics formulation were reduced to some extent by the greater amounts of smoke released by the burning of the retarded plastics. For stacks of ULDs filled with trays, typical of a scenario in a mail exchange, the fire-retardant plastics gave significant benefits in terms of life safety and fire damage to the trays and mail.
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  • 28
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    Fire and Materials 15 (1991), S. 131-136 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Until the 1960s ASTM E136 and CAN/ULC-S114 test methods were adequate for determination of non-combustibility in materials being used to construct most buildings. However, since then there has been a very large increase in the use of products that are considered safe for construction of buildings required to be noncombustible but which are classified as combustible by these simple pass/fail tests. Therefore, Forintek Canada Corp. have developed an approach to define the combustibility of these new materials, based upon their release of heat when tested using the ASTM E1354 cone calorimeter.
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  • 29
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    Fire and Materials 15 (1991), S. 147-147 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 30
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    Fire and Materials 15 (1991), S. 149-149 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 31
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    Fire and Materials 15 (1991), S. 137-143 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper describes a comprehensive experimental investigation of the fire performance of nailed gusset connections between large glue-laminated timber members. Both plywood and steel gusset plates were investigated with a range of loaded and unloaded test methods. The principal conclusions are that unprotected gussets have poor fire performance, but that a layer of solid wood or gypsum plasterboard will provide at least one hour of fire protection to typical joints.
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  • 32
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    Fire and Materials 15 (1991), S. 145-146 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The thermal behaviour of cellulose obtained from both the pith and rind of papyrus was studied and the flammability properties of paper produced from papyrus and other papers were measured. The use of flame retardants did not significantly alter the flammability properties of the papyrus paper.
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    Fire and Materials 16 (1992), S. 29-35 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The post-cooling properties of reinforced concrete constituents are of great relevance in the assessment of a structure for re-use after fire. The expansive rehydration of dissociated calcium hydroxide on post-cooling exposure to air can cause a total loss in strength if cement paste specimens are heated to and maintained at 400°C or above. The use of cement replacement agents can mitigate this effect. The strength and ductility of hot-rolled mild steel and cold twisted steel on gradual cooling or quenching from various temperatures can be correlated with microstructural phenomena. There is a significant increase in strength and loss of ductility when both types of steel are quenched from temperatures above 723°C. Some practical implications of these properties are described, using examples of fire-damaged structures.
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    Fire and Materials 16 (1992), S. 159-167 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An investigation has been carried out of the limiting oxygen index (LOI) test. A review of the literature shows that, although there is abundant information on the test, it is not clear that its results correlate well with those of any other test, or indeed with those of real fires. Theoretical considerations indicate that the test could be improved by using it with bottom ignition rather than with the standard top ignition. A number of materials were tested in the cone calorimeter and in the LOI, and various correlations were attempted. In general, correlations between some of the cone calorimeter properties measured and the inverse of the LOI made sense. These correlations were not, however, sufficiently sensitive, even when investigating small effects on a single base polymer system, to justify using the LOI as a proxy for the cone in any way. The LOI is likely to continue to be used extensively. This work suggests that quality control and, possibly, mechanistic or other flame-retardant additive studies, are its only applications where the results can be justified.
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    Fire and Materials 16 (1992), S. 181-186 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The authors have conducted a laboratory-scale gallery fire test on eight different samples of electric cable in a horizontal airflow. The number of speciments and the distances between them on the trestle were varied for each test. As a result, it was found that both ignitability and flame-propagation properties depended on the distance between the specimens as well as on their number. Such flammability properties obtained for each cable sample were also found to be considerably consistent with the critical oxygen index. In addition, it is proposed that the flammability should be classified largely into five categories in this laboratory-scale gallery fire test for fire-retardance evaluation of solid combustible materials such as electric cables.
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    Fire and Materials 16 (1992), S. 187-196 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Wood fiberboard-based, cellulose ceiling tiles have been used for many years. While various fire-retardant technologies have been developed to reduce the surface flammability of these products to acceptable levels, questions of their suitability for use due to their intrinsic fuel value and the impact of attachment methods used on fire performance have been raised from time to time. This paper reviews the history of these products from a fire-performance perspective and presents materials property data on surface flamespread, thermal conductivity and ignition phenomena. In addition, large-scale room fire test results are presented including compartment tests conducted on a variety of assemblies (including those installed with mastic construction adhesives) according to ASTM E 603 - Standard Guide for Room Fire Experiments.
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    Fire and Materials 16 (1992), S. 169-180 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An experimental facility based on the Quasi-stationary Flame Front Technique for determination of steady flame spread rate of materials at discrete levels of external radiant heat flux was developed. The method employs an external radiant heat source in front of which an element of a specimen of the material is positioned at a location corresponding to the desired level of external radiant heat flux. A specimen movement assembly, which can be operated manually, was designed for moving the specimen towards the stationary external radiant heat source such that the flame front could be maintained quasi-stationary. The experimental technique employed is simple in operation yet is capable of yielding reliable flame fornt displacement-time data. In the paper the design considerations of the experimental facility, details of its components, calibration and typical experimental results obtained are presented.
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    Fire and Materials 16 (1992), S. 207-208 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 17 (1993) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 16 (1992), S. 197-206 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Burning rate is a key factor in modeling fire growth and fire endurance of wood structures. This study investigated the burning rate of selected wood materials as determined by heat release, mass, loss and charring rates. Thick samples of redwood, southern pine, red oak and basswood were tested in a heat release rate calorimeter. Results on ignitability and average heat release, mass loss and charring rates are reported for a heat flux range between 15 and 55 kw m-2. In this range, burning rate increased linearly with heat flux. Burning rate was very species dependent. Heat release rate was related to mass loss by effective heat of combustion, which also increased with heat flux. Charring rate was related to mass loss rate and original wood density. Important char property data such as yield, density and contraction are reported. A simplified calculation method is proposed for calculating mass loss rate and charring rate based on heat release rate.
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    Fire and Materials 17 (1993), S. 1-6 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: An investigation of the burning behaviour of a series of halogenated polyester resin formulations has been carried out using the Cone Calorimeter technique. The data obtained clearly indicate that zinc hydroxystannate (ZHS) is more effective than antimony trioxide (Sb2O3) in reducing the average and peak rates of heat release in a chlorinated resin and in decreasing the peak rate of heat release in a brominated resin. The decreases in average heat release rate in the brominated resin are similar for ZHS and Sb2O3. Hence, at an addition level of 2 phr (parts per hundred of resin), ZHS reduces the average heat release rates of a chlorinated and a brominated resin by 41% and 26%, respectively, and the peak heat release rates of the same resins by 38% and 39%, respectively. The degree of smoke suppression exhibited by ZHS in these Cone experiments is significantly greater than that given by Sb2O3. In general, the correlation between Cone Calorimeter data and results obtained using other laboratory fire tests (UL-94, LOI) is poor, except in the case of smoke density measurements, where the correlation with NBS Smoke Box data is remarkably good. No correlation is observed between the measured values of CO and CO2 output by different test methods, although it is now generally considered that small-scale fire tests cannot be used to predict gaseous concentrations in real-fire situations.
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    Fire and Materials 17 (1993), S. 21-24 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A series of cellulose-polysilicic acid hybrid fibres with 15-35% silica contents were spun and their flammabilities were assessed by the LOI oxygen index test. Also, the rate of heat release and toxicities of fumes evolved during the combustion process for hybrid fibre with 33% SiO2 loading was obtained using the cone calorimeter and FT-IR techniques. The low flammability and toxicity indices indicate that this hybrid fibre can be used as a flame-retardant fibre.
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    Fire and Materials 17 (1993), S. 25-32 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Three timber-based materials were investigated by subjecting them to a constant uniform heat flux in the range 20-70 kW m-2 using a Cone Calorimeter and the ISO Ignitability Apparatus. The specimens were examined in the vertical and horizontal orientations in the Cone Calorimeter using gas flame pilot, spark pilot and spontaneous methods of ignition. They were also studied using the ISO Ignitability Apparatus in the normal and inverted horizontal orientations using gas flame pilot and spontaneous methods of ignition. The results obtained are compared by specimen, orientation and mode of ignition.
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    Fire and Materials 17 (1993), S. 103-110 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The rate of heat release from a thermally thin material burning on both sides will be more than twice the value seen when only one side is burning. Two simplified models demonstrate that this is a consequence of the Arrhenius temperature dependence of the gasification rate of the solid. Experiments carried out on three composite materials over a range of incident heat fluxes confirm this effect. It is inferred that a further consequence of this heat release enhancement is an increased tendency for concurrent flame spread in the two-sided burning case. Materials whose application could lead to two-sided burning should thus be assessed in this mode to obtain a true picture of their flammability potential.
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    Fire and Materials 17 (1993), S. 91-102 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: Several -i-isocyanates have become commercially important materials, used as intermediates in the manufacture of a wide variety of polyurethane products, yet little is recorded on their behaviour if involved in fire. This paper describes a series of programmes carried out under the auspices of the International Isocyanate Institute Inc. First, a small-scale laboratory investigation of the ignition, heat release, smoke and toxic gas production characteristics of di-isocyanates was carried out. Second, their behaviour in drumstock and pool fires, respectively, was examined, using full-sized samples and selected real-fire scenarios. Part 1 records the results for toluene di- isocyanate (TDI) showing the need for a modest energy input to ignite it from a pilot flame. It then burns in a steady rather than vigorous manner, leaving no residues. Toxic gases evolved are mainly carbon monoxide, while free isocyanate is likely in the early stages of the fire, and hydrogen cyanide may be important in well-developed fires. Drumstock material behaviour in a fire is dictated mainly by the rupture characteristics of the containers, which can be violent. A series of simple guidelines is suggested, which includes the need for firefighters to wear full protective clothing and fresh-air breathing equipment. It is also recommended that drumstock TDI should be stored away from easily ignitable materials.
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    Fire and Materials 17 (1993), S. 111-117 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The flame height behavior of merged or inclined flames from two rectangular fire sources in a parallel configuration and from three and four circular pools of 120 mm diameter in a symmetrical configuration were studied experimentally. A rectangular gas diffusion burner, 20 mm × 400 mm or 20 mm × 800 mm was used as line fire sources. Propane gas gave 9.5-57 kW per meter for each burner. Hexane was utilized for the flame merging test using circular pool fires. The height of the flame tip when merged or inclined due to interaction of the flames and|or convective flow was estimated from picture analysis of 300 successive frames of video-recorded data. The flame extension behavior was expressed in dimensionless form as L/Lm = (fs)2/5 for square pool fires and L/Lm = (f1)2/3 for rectangular fires. The correction factors of fs and f1 are fs = (nD2 + S2) / n(D2 + S2) and f1 = (2DW + S2) / 2(DW + S2), respectively. When a rectangular or a circular fire source approaches the wall, the same correlation on flame extension behavior was obtained and simulated successfully considering an imaginary fire source inside a wall.
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    Fire and Materials 17 (1993), S. 119-123 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Wall-fire spread models require heat of gasification or non-dimensional heat of gasification to calculate mass loss rate or rate of heat release from the wall material. An intermediate scale rate of heat release apparatus was used to measure all the parameters needed to calculate non-dimensional heat of gasification for wood materials. An infra-red pyrometer was used to measure surface temperature. The results of measurements on six wood materials indicate that non-dimensional heat of gasification, if plotted against mass remaining, does not change significantly with external heat flux, but is material dependent.
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    Fire and Materials 17 (1993), S. 125-129 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The temperature distribution in the condensed and gas phase during combustion of polymer materials in fire tests was measured by means of thermography. It is shown that these data are very useful for mechanistic rationalization of the diagnostically poor, fail-pass rating of most of these tests. Preliminary data were obtained for polymer materials, fire retarded or not, burning in the widely used Glow Wire and UL 94 tests. It is shown that the relative fire hazard and test rating may depend strongly on the combustion parameter on which the rating is based. Furthermore, detailed data on temperature distribution are helpful in eliminating intrinsic ambiguity of the UL 94 classification in the case of fire-retarded materials burning with dripping.
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    Fire and Materials 17 (1993), S. 131-138 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The fast and precise transient hot-strip (THS) method is well suited for thermal conductivity measurements on solid materials. The THS method may, however, give large experimental errors when applied to thermally insulating materials of low heat capacity per unit volume. Models to deal with those potential error sources and some indications about the precautions to be taken in order to minimize them are described in the present work. Measurements of thermal conductivity of a styrofoam insulating material (thermal conductivity 0.036 W m-1K-1, density 25.4 kg m-3) was performed to verify the models. The result obtained is in good agreement with the standard hot plate method, indicating that the THS method is also well suited for thermal conductivity measurements of thermal insulators.
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    Fire and Materials 17 (1993), S. 145-145 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 17 (1993), S. 265-270 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: This paper outlines the flammability test methods and requirements for electric cables specified in some Japanese standards. Only two different methods of a small-scale flame test as specified in Clause 28 of JIS C 3005 are applied to electric cables for general use, and whether or not the flammability test should be conducted and which method should be adopted depends on the type of cables, both of which are specified in each separate standard. Cables for electrical equipment of ships have to pass another small-scale flame test as prescribed in Section 6.7 of JIS C 3410. A flame test method for flame-retardant telecommunication cables has been introduced in JIS C 3521. This specifies a vertical open tray flame test on grouped cables, almost in accordance with IEEE Standard 383. In addition to the method for a vertical open tray flame test, one for a vertical closed duct flame test on grouped cables is also specified in a Japanese Cable Makers' Association Standard, i.e. JCS 366. Some flame-retardance requirements for electric cables in Japan are listed and discussed.
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    Fire and Materials 17 (1993), S. 279-292 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper reports an experimental study on the physical properties of a sprinkler water spray. The mass flux density, shape of spray pattern, size distribution and velocity of water droplets discharged from two types of 15 mm orifice sprinkler heads were measured. Three operating flow conditions of the sprinkler system, including one specified for the Ordinary Hazard class under the LPC rules for sprinkler design, were set. The sprinkler head was installed above finished floor levels of either 2 m or 2.2 m. The median droplet size was found to be related to the water pressure and the orifice diameter of the sprinkler head as proposed by Dundas. The droplet size distribution function can be fitted by a Rosin-Rammler function.
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    Fire and Materials 18 (1994) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 17 (1993), S. 293-303 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A small-scale enclosure was constructed for characterizing the contribution of interior finish wall-lining materials to fire growth in compartments. The enclosure was based upon refinements to a design devised by scientists at the National Institute for Standards and Technology for quarter-scale modelling of room fire tests on interior-finish materials. A large volume of evidence is presented demonstrating how this small-scale enclosure could provide the information about surface flammability, heat release, smoke generation and contribution to fire growth that is required for a reasonable assessment of the fire performance of interior wall-finish materials.
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    Fire and Materials 18 (1994), S. 1-7 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Phospham is an iminophosphazene polymer of unusually high thermal stability. We have found that phospham imparts a substantial level of flame retardancy to nylon-4,6, a high-melting crystalline engineering thermoplastic. It did not appear to produce degradation of the polyamide in the processing temperature range. The flame retardant efficacy of phospham in nylon-4,6 was similar to that of stabilized red phosphorus, when compared on an equal phosphorus basis. In nylon-4,6, it did not display nitrogen-phosphorus synergism. Limited evidence from TGA suggested a condensed phase mode of action in nylon-4,6. Phospham showed orders-of-magnitude better hydrolytic stability than did ammonium polyphosphate, and did not produce detectable phosphine on processing as did red phosphorus.
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    Fire and Materials 18 (1994), S. 17-30 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The behaviour of polymeric diphenyl methane-4,4′-diisocyanate (PMDI) is described when examined in a laboratory small-scale test for its reaction to fire (ease of ignition; heat release and toxic gas production). Full-scale real fire scenarios have also been staged to predict events if (1) drumstock PMDI and (2) sizeable pools of liquid PMDI become enveloped in a fire. PMDI requires a stimulus (e.g. heat) before it will ignite from an applied flame. It then burns in a self-sustaining manner for a few minutes, during which main emissions take place. Then a polymerization reaction begins, producing a low density non-burning residue, which progressively dampens down the burning events by blanket action. Residues of 30-80% sample weight were recorded. The major toxic gas produced is carbon monoxide, though free isocyanate is to be expected in the early stages of the fire, and hydrogen cyanide could be important, especially in well-developed fire conditions. Firefighters should therefore wear full protective clothing and fresh-air breathing equipment. Events when drums of PMDI are exposed to fire depend heavily on the characteristics of the containers, with some rupture steps proceeding with considerable violence. Drumstock PMDI should be stored separately from easily ignitable materials.
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    Fire and Materials 18 (1994), S. 45-50 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A small-scale test series was carried out using the heating system (radiant exposure) of a cone calorimeter to detect any differences in the way different fibres affect the thermal properties of a standard mortar. The fibres were different polypropylene, polyacrylonitrile, aramide, carbon or steel. Fibres affect the release of moisture from the fibre mortar material. Local pressures caused by water vaporization due to rapid heating can be decreased by incorporating fibres. Fibres have a weak insulating effect. However, use of polyacrylonitrile fibres in mortar may increase the risk to spalling under rapid thermal exposure such as fire. The moisture level in specimens is highly significant for their thermal properties and hence their fire behavior.
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    Fire and Materials 18 (1994), S. 51-55 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Experimental investigations were made to assess the fire behaviour of rice husk particleboard, a potential substitute for wood particleboards. Releveant fire properties, namely non-combustibility, ignitability, fire propagation index, surface spread of flame classification, specific optical density of smoke generated, flammability and flame penetration were determined in accordance with existing standard methods. In this paper the salient results obtained are discussed.
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In a total of 63 experiments, all of them carried out in a 200 L Plastic chamber, a large amount of HCI (800-1000 ml) was injected. In no case was the HCI generated from decomposition of poly(vinyl chloride). The chamber contained a variety of surfaces. Furthermore, various fluids were injected into the chamber together with the HCI. The fluids used were: water, ethylene glycol, ethylene glycol/water 50/50 mixture, a model for airborne smoke particulates (and several partial models for such synthetic smoke) and mineral oil. The surfaces used were PMMA, painted gypsum board, ceiling tile and soot. The results showed the efficiency of many of these fluids as sinks for HCI: hydrophilic fluids are good HCI sinks, with water and synthetic smoke being the most effective. A previously developed zone model for HCI transport and decay, contained within the NIST fire model Hazard 1.1 and used most often to investigate HCI formation from PVC combustion or pyrolysis, was used to predict the results of the experiments in this work. The correlation between experimental and predicted atmospheric HCI concentrations was made without fitting any new parameters. The results were excellent. This work shows that the HCI transport and decay model is robust enough to be applied to a number of scenarios where HCI is present, even in the absence of PVC. The model is thus of particular use in fire hazard assessment.
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  • 60
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    Fire and Materials 18 (1994), S. 131-149 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A review is given of the various national requirements and test procedures concerning testing and classification of smoke produced in the case of a fire in rolling stock. A comparison of the various test methods is made using the relevant available literature. The toxic potency philosophy of SC3 ‘Toxic Hazard in Fire’ from ISO TC92 is used to provide a concept for assessing the possible smoke hazard in the case of a fire.
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  • 61
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    Fire and Materials 18 (1994), S. 151-166 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The flammability and smoke generated from burning blends of acrylonitrile-butadiene-styrene (ABS) and polyvinylchloride (PVC) are discussed. Flammability was measured using standard oxygen index techniques and smoke production determined by the NBS method. The incorporation of some specific iron containing inorganic compounds into a range of blends of ABS and PVC considerably changes the burning characteristics of the polymer blend. Thermal stability at elevated temperatures and carbonaceous char formation are also discussed. The chemical role of iron compounds in reducing both the flammability and smoke production in ABS/PVC is considered.
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  • 62
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    Fire and Materials 18 (1994), S. 205-209 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Correlations based on linear regressions between data as time to ignition and heat release in the cone calorimeter and time to flashover in the room fire test have been developed. They are a further development of an earlier approach which has been modified and extended to a wider range of surface linings. The correlations apply so far only to surface linings on both walls and ceilings. When the density of the linings as a simplified measure of the thermal inertia is included, the correlations are improved significantly.The new correlations are based on data readily available from the cone calorimeter test at one heat flux level, 50 kWm-2. The correlation coefficient for the basic relationship, including the density of the linings, is now 0.98 when applied to the 13 linings investigated earlier. This is slightly better than the previous study, in which the best correlation coefficient was 0.96. When applied to 28 linings, the correlation coefficient remains about the same (0.97).Very similar regression equations have been obtained when analysing only 13 products and all 28. This is a strong indication of the general predictive capacity of this approach. The inclusion of other data such as thickness of linings or mass loss during fire does not improve the correlation coefficients. The approach is quite straightforward and simple. However, it has provided a useful prediction which is also valid for an extended range of linings.
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    Fire and Materials 18 (1994), S. 261-262 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 64
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    Notes: The object of this study was to identify, for future large-scale testing, and adequate fire-protective coating for the substrate, polyvinyl chloride (PVC) nitrile rubber (MIL-P-15280 Rev H). Fifteen fire protective coatings which included ten intumescent, two ablatives, two fire retardants and one photon diffusive coatings were evaluated using bench-scale thermal insults. To discern the possible mechanism(s) whereby the coatings offer fire protection, the effect of radiant heat versus the flame source employed was investigated and thermogravimetric analysis (TGA) of the neat coatings was performed. In selected cases, the effect of coating thickness and repeatability of the results were evaluated. The differences in coating effectiveness, and the varied repeatability in three of the four cases examined, focus on the inherent complexity of intumescence, as well as on the importance of scaled-up testing of coatings that appeared promising. Thermogravimetric analyses of the coatings indicate that two selected TGA measurements/parameters, when used in conjunction, appear useful in characterizing mechanistic differences between the less effective and more effective coatings. Based on the rigorous criterion adopted, one candidate (a water-based intumescent coating at 100 mil (2.54 mm) thickness) appears promising for the substrate, PVC nitrile rubber. Its effectiveness is attributable to it exhibiting good insulative and re-radiative properties and an apparent low susceptibility to crack formation.
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    Fire and Materials 18 (1994), S. 359-379 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper reports a study of the interaction of a sprinkler water spray with the fire-induced hot layer using the field modelling technique. Data obtained in the large test room of the recent Swedish experiments reported by Ingason and Olsson (1992) are used to validate the results. The problem is divided into a gas phase and a liquid phase. For the gas phase, the set of conservation equations for mass, momentum and enthalpy of air flow induced by the fire is solved numerically using the Pressure Implicit Splitting Operator (PISO) algorithm. For the liquid phase, the sprinkler water spray is described by a number of droplets with initial velocity and diameter calculated by empirical expressions for the nozzle at different operating water pressures and flow rates. The trajectory of each droplet is calculated by solving the equation of motions, by including the dragging and heat transfer with the hot layer. The water droplet is assumed to be non-evaporating and only the source terms in the gas momentum and enthalpy equations of the air flow included the interaction effects with water droplets, i.e. the ‘Particle-Source-in-Cell’ method. The predicted results include the gas flow, temperature and smoke concentration field; the shape of the water spray; and some relevant macroscopic parameters such as amount of convective cooling, drag-to-buoyancy ratio, etc. The average smoke layer temperature and the smoke layer interface height are also calculated. The effect of the mean droplet size on those parameters is illustrated. Finally, a comparison of the water density received at floor level in cases with and without the fire is made.
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    Fire and Materials 18 (1994), S. 351-358 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Fire accidents caused by the use of open gas torching during roof-installation work have led to considerable costs, and between 1985 and 1990 such costs reached 249 Million SKr. The Swedish Fire Protection Association together with the roofing contractors association reached agreement on the education and certification of roofers. Meanwhile, the insurance companies started to demand welding methods with lower temperatures and less fire hazard. This resulted in a marked decrease in fires and in a sharp decrease in the amounts paid out by insurance companies (187 million SKr in 1989, 25 million SKr in 1990 and 2.4 million SKr in 1991). This paper summarises the results of a study of the new welding methods, replacing conventional gas torching, for the installation of polymer-modified bituminous roof-coverings on flat roofs. In all eight different welding methods were evaluated in Stockholm during the installation in October 1992. Four different products of single-ply roof-coverings, namely one of atactic polypropylene (APP)-modified bitumen and three of styrene-butadiene-styrene copolymer (SBS)-modified bitumen, were studied. The study comprises temperature measurements during welding jobs on-site to evaluate fire hazard, and laboratory measurements of T-peel strength of the seams in order to evaluate the quality of the seam samples prepared on-site. The results showed that by these new welding methods a remarkable decrease in temperatures by weld was made without any significant change in the quality of the seams. However, the mechanical strength of the seam was related to welding speed, which should be limited to form sufficiently strong seams using heat welding.
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    Fire and Materials 18 (1994), S. 385-387 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Fire and Materials 18 (1994), S. i 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 18 (1994), S. 389-391 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The autoignition temperature and composition of 15 carbon-filled fluoroelastomers have been determined. These experimental data and three sets of literature data are used to examine the relationship between autoignition temperature and rubber composition. The autoignition temperature at an elevated oxygen pressure is strongly affected by the carbon black content in rubbers. An empirical equation is derived and can be used to predict the autoignition temperature of carbon-filled fluoroelastomers based on the carbon black content.
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    Fire and Materials 2 (1978), S. 184-184 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 2 (1978), S. 173-176 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Various celloulosic materials were evaluated for ignitability and flash-fire propensity, using screening test methods developed at the University of San Francisco. Time to ignition, using radiation from a high-temperature radiant source without a pilot flame, appeared to be primarily a function of heat flux and material density, rather than of type of wood or celloulosic board. At heat flux levels from 5.8 to 10.5 W cm-2, time to ignition was shortest for cellulose fiberboard with a density of 0.2225 g ml-1, followed by western red cedar at 0.314 g ml-1, eastern white pine at 0.348 g ml-1, southern yellow pine at 0.422 g ml-1, Douglas fir at 0.565 g ml -1, and longest for hardboard at 0.878 g ml-1. For the cotton and rayon woven-pile upholstery fabrics, time to ignition appeared to increase with increasing fabric weight.For Cellulose insulation treated with boron-containing additives, flash-fire magnitude decreased with increasing additive content. Flash-fire magnitude decreased more that could be accounted for by decreasing weight loss alone, indication reduction in the combustibility of the volatiles produced. Reduction in flash-fire propensity of cotton bating by treatment with boron-containing additives was also observed.
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  • 72
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    Notes: The Australian Children's Nightwear Standards have been accepted as the basis of legislation in all States of Australia and by the Commonwealth Government. The standards are based on the philosophy that garment design as well as combustion characteristics of the material is an important consideration in assessing the fire hazard of nightwear. Using this approach a classification system has been devised which place children's nightwear into three categories of potential fire hazard. If a garment cannot be classified then it cannot be legally sold in Australia. The combustion characteristics tested are ease of ignition, rate of flame propagation and surface burn properties. For classification all materials used for children's nightwear must pass the latter test. The design of the standard test methods, criteria for classification and the concepts of safe design were developed by collection data from burns accidents and burnt clothing from accident victims from the burns research unit of a large children's hospital and by the study of the burning behavior of clothing on a manikin. The combustion criteria are not so stringent as to require the use of inherently flame resist materials or the use of flame retardant finishes. This approach in combination with safe design criterial enable commercially available textiles to meet the legislative requirements for children's nightwear. This mean that the nightwear standards are inexpensive to attain and do not require a sophisticated textile technology. A consumer labeling system has been designed to describe the three categories but yet there is no evidence to suggest that this had had any effect in reducing the number of burns accidents - consumers apparently regrading safe nightwear as a low priority. An inconsistent aspect of the calssification system is the incorporation into the standards in 1977 of criteria to prevent the classification of cotton flannelette nightdresses and the incorporation of arbitrary requirements for other nightdress containing cotton. These inconsistencies have been caused fundamentally by a problem which continues to bedevil the writing of good standards in Australia - that is, the lack of nationwide statistics on burns accidents.
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    Fire and Materials 2 (1978), S. 177-183 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A Collaborative Programme of work was carried out by two laboratories to asscess a procedure for identifying paint systems which possess poor ‘in service’ lives by virtue of being repeatedly washed. The small scale surface spread of flame apparatus as described in BS 476 part 7 was used to measure any change in the surface spread of flame characteristic of eight coating system, applied to two substrates, as a result of washing the coated surfaces. The results indicate that both laboratories ranked the paints in the same order and the reproducibility of the proposed washing procedure was good. The most consistent results were obtained when the coating systems were applied to standard hardboard. It is suggested that flame retardant coating system having poor resistance to washing would be identified if a limit of changes of average spread of flame were set at 75 mm. This investigation was carried out in support of the activities of BSI committee PVC/12, Fire Retardant Paints.
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    Fire and Materials 2 (1978), S. iii 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 3 (1979) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 3 (1979), S. 1-7 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Numerical solutions of the post-flashover fire are considered and a computer program is presented. The solutions are compared with experiment and the sensitivity of the solutions to a number of variables is discussed. It is shown that increasing the ventilation may either increase or decrease fire intensity, and the importasnce of the ventilation controlled phase of the fire is discussed. Application of the model to calculate the expected time-temperature history is illustrated and its significance is discussed. The deterministic approach is compared with a new method for calculating the most severe fire by letting one variable take any value between certain limits. The latter method is called pessimization. The significance for designers is noted.
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  • 77
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    Fire and Materials 3 (1979), S. 8-14 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Samples of current Australian production of unplasticized polyvinyl chloride pipe and fitting materials have been examined in relation to combustion characteristics. Small scale laboratory assessment of piloted radiant ignition flame propagation and smoke generation have been investigated. Where necessary, improvements to methods of test or analysis of data have been developed and factors that influence results have been investigated. Piloted radiant ignititon and smoke production under flaming conditions are shfown to be the important combustion characteristics of UPVC materials for improvement.
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  • 79
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    Notes: Data are presented which show the effect of elevated environmental temperature upon smoke particle characteristics of wood (Douglas fir) and a rigid PVC, under both flaming and nonflaming combustion in air. The physical data obtainbed include the smoke particle average diameter, the smoke optical densities in red and blue light, and the weight loss of the sample. The average particle dimeter, the smoke optical densities in red and blue light, and the weight loss of the sample. The average particle diameter and optical densities in red and blue light, and the weight loss of the sample. The average particle dimater and optical densities were obtained uwing in in situ optical system which measures forward scattered light at two angles and transmitte light at two wavelengths. Data were taken for vertically mounted samples exposed to a radiant flux of 5 W cm-2 in environments at a room temperatures, 100°C, 200°C and 300°C. The result indicate that in flaming test higher environmental temperatures general result in greater smoke optical densities and larger smoke particles, while in nonflaming tests higherl temperatures in lower smoke densities and smaller smoke particles, for wood. These results may explain why small-scale test data (room temperature environment) do not often correlate well with full-scale data (often at elevated environmental temperatures).
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    Fire and Materials 3 (1979), S. 27-33 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A theory is developed for calculating the heat transferred from a buoyant layer of fire gases and smoke, to a sprinkler spray. The theory involves calculating the heat transfer to a single water drop as it describes its trajectory, and uses experimentally derived information on the nature and structure of such sprays to calculate heat transfer to the whole spray. Because such experimental information is sparse for sprinklers, a very simple model of the ballistic properties of a sprinkler spray is adopted. Calculations using the teory suggest that the practive of installing sprinklers in the smoke reservoirs of shopping malls would, in some cases at least, reduce the effectiveness of natural venting of smoke by reducing the buoyancy of the hot smoky gases.
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    Fire and Materials 3 (1979), S. 34-38 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An experiment is described which measures the heat transferred from a hot, flowing, buoyant gas layer in a mall, to a sprinkler spray. Interpolation techniques are described which allow for the large heat losses occurring within the apparatus (a large-scale model mall). The results are compared with predictions based on the method developed in Part 1 and found to be consistently 150% of the predicted heat transfer rates. Given the assumptions required by the predictive calculations this is thought to be reasonable degree of agreement. The largest heat transfer rate to the one sprinkler spray in this experiment was 157 kW ± 38 kW.
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    Fire and Materials 3 (1979), S. iii 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: The coupling between the constituent reactions of a burning process, namely pyrolysis, combustion of volatiles, and (possibly) oxidation of char, is on the whole quite different for fires occurring in the open and for those that develop in an enclosure. Consequently, knowledge of the characteristics of free burning fires is of only limited value in studies related to compartment fire. Since the singe-rout communication between the fire compartment and its environment, always assumed in classical fire studies, is not at all common in real world fires, great sophistication in the mathematical modeling of classical fires is rarely warranted. An examination of pool-like fires and pile fires of noncharring fuels has shown that the severity of such fires in the fire compartment, as characterized by the so-called ‘fire severity product’, decreases slightly with an increase in ventilation. The principal danger presented by these fires, however, is not so much to the fire compartment itself as to the surrounding spaces.An interesting feature of fires involving charring fuels, cellulosies in particular, is that the rate of consumption of fuel, the so-called ‘rate of burning’, is practically independent of all process variables except ventilation. The severity of fires of cellulosics is, as a rule, much higher than that of fires of noncharring fuels. It exhibits a maximum at relatively low ventilations. From the point of view of spread of fire to the surrounding spaces, cellulosics are generally less dangerous than noncharring plastics. Fires involving cellulosics mixed with smaller amounts of noncharring plastics can be characterized as basically cellulosics fires, with a superimposed initial period of very high spread liability.
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    Fire and Materials 3 (1979) 
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    Fire and Materials 3 (1979), S. iv 
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    Fire and Materials 3 (1979), S. iv 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 3 (1979), S. 39-48 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The Critical Oxygen Index test has been used as a measure of the flammability of a wide range of substances, including plastics, textiles and liquids, since its introduction in 1966. The index, however, is only appropriate to the configuration and conditions used in the test, and extrapolation in order to predict the flammability of materials in a large-scale fire is not valid. The index is dependent on a number of sample and test parameters and these are reviewed; the ASTM test standard, the reproducibility of the results, and certain theoretical aspects are also discussed.
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  • 89
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    Fire and Materials 3 (1979), S. 74-79 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The influence of the various factors that determine temperatures in fire-exposed concrete slabs is examined, in particular that of material properties. Both experimental and theoretical studies have been carried out. From these a set of thermal properties has been derived that is representative of the properties of siliceous concrete and suitable for use in fire resistance calculations.
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  • 90
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    Fire and Materials 3 (1979), S. 68-73 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The role of the product of the thermal properties of thermal conductivity and thermal capacity per unit volume in fire growth is explored in relation to a simple model of a room fire. The calculated differences between flashover times for two different lining materials are plausible; the main conclusion is to show that the flashover time depends on KρC in a weaker relationship than simple proportionality.
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  • 91
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The synergistic action of antimony (Sb) with bromine (Br) was studied for polypropylene-2,3-dibromopropylpentabromophenyl ether-Sb2O3 systems at various Sb/Br molar ratios. Oxygen index, weight loss rate and heating value were used to evaluate the retardant effect. Bromine and antimony emission and their material balances were measured by gravimetric and X-ray fluorometric analysis of heated samples at each reaction time. Retarded HBr formation in the gaseous phase through SbBr3, SbOBr and Sb4O5Br2 was proved by X-ray diffraction analysis of heated residues and model products. SbBr3 and HBr formation were greatest at Sb/Br ratios of 1/3 and 1/4, respectively, while the highest oxygen index and the lowest weight loss rate and heating value were obtained at 1/4. Consequently, HBr will most probably produce the retardant effect rather than SbBr3. Effective synergistic action at the Sb/Br ratio of 1/4 is explained by presuming the formation of an acidic HBr.SbBr3 complex in the molten phase for the particular reaction pattern of bromine in 2,3-dibromopropylpentabromophenyl either.
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  • 92
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    Fire and Materials 3 (1979), S. 84-90 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: With increasing use of electric trains carrying very high passenger loads it is important to assess the risks involved in using combustible materials. An approach using decision tree methods to analyse the resulting fire growth and passenger action combinations has been developed. Clear statement of objectives, mainly preservation of life and property, is essential. Systems analysis models can then be used to define the nature of quantitative information needed to assess probabilities of the lines of action shown by the decision tree. The current situation is not fully defined since there isdifficulty in using test report and behavioural information in the on-off mode needed for Boolean logic which is required by decision tree methods. Some preliminary probabilities are given for state transitions, such as ignition to flame spread, based on reported data. A basis for a possible approach to human behaviour variables and the effect of combustion products is given.
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  • 93
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    Fire and Materials 3 (1979), S. 100-105 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The numbers and severities of burn casualties are described by reference to national data and a more detailed analysis of causes of burns in Birmingham. The important dimensions of any burn are area and depth, both are relevant to severity of injury and mortality. Personal factors, such as age, disability, unconsciousness, drugs and alcohol, can influence depth and area of burning. There is a relation between exposure time and thermal flux to cause burning, this is described for hot metal and radiant heat. The data can be used to predict likelihood of sustaining burns in specified situation. Such prediction is less easy with poor heat conductors; the reasons for this are discussed. The relevance of this information for advising on safety in a variety of situations is outlined.
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  • 94
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    Fire and Materials 3 (1979), S. 91-99 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A study of fire deaths in the Glasgow area has been in operation for 2½ years. Detailed pathological and toxicological examinations have been carried out on 127 fatalities, arising primarily in domestic fires. Cyanide and thiocyanate, the principal metabolite of cyanide in blood, were measured in blood samples from 100 fatalities and from groups of non-fatal fire casualties, firemen and normal and post-mortem controls. Cyanide concentrations in the blood of fatal and non-fatal casualties were elevated to statistically significant levels compared to controls and 6% of fatalities had cyanide levels above 100 μmol 1-1 blood. No evidence was obtained for the operation of additive or synergistic effects in fire deaths between cyanide, carbon monoxide and ethyl alcohol. Thiocyanate was of value as an index of metabolized cyanide in non-fatal subject groups but not in fatalities. Organic volatiles in blood from fire victims were analysed with a gas chromatograph mass spectrometer computer system and for the first time the presence of toxic nitriles other than cyanide has been demonstrated.
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  • 95
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    Fire and Materials 3 (1979), S. 106-109 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In this paper an apparatus is presented by means of which it is possible to measure the ignition time with a very high accuracy, namely 0.01 s. This apparatus has been developed not only for determining the ignition time of fabrics and end products such as curtains, garments, beds, upholstered chairs and toys, but also as an igniting source for use in studying the flame propagation. By using the apparatus it is possible to separate the burning phase from the ignition phase.
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  • 96
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    Fire and Materials 3 (1979), S. iii 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 97
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    Fire and Materials 3 (1979), S. 110-120 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This report describes work currently being carried out at the Fire Research Station, Borehamwood to Study the role of the fire atmosphere in causing incapacitation, injury and death of building occupants in fires. The work includes a detailed study of polymer degradation mechanisms (particularly synthetic) and product formation under carefully controlled laboratory conditions and fires, together with pathological and bioassay (in vivo) work being carried out elsewhere under contract. Analytical studies are reported using gas chromatography and mass spectrometry to identify the complex products formed during the controlled pyrolysis and thermal oxidative decomposition of butadiene-styrene latex rubber foam, polyacrylonitrile and polypropylene under low (30-400°C), medium (400-650°C) and high (700-900°C) temperature conditions. Studies are reported of the products formed during smouldering and flaming fires in an experimental 0.4 m3 fire chamber in an attempt to reproduce conditions relevant to the early stages of fires. In this way, chromatographic fingerprinting of the smouldering products from BS latex rubber foam, and the flaming products of wood wool and polypropylene are given and where possible the major components identified. The relevance of this analytical work in predicting the types of products likely to be encountered during various stages of burning is discussed. General information on the pathological studies and bioassay work being carried out at the Department of Forensic Medicine, University of Glasgow and at the Huntingdon Research Centre respectively are given in order to integrate the overall research programmes and methods of approach being adopted to give an insight into the very difficult area of toxicity assessment.
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  • 98
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    Fire and Materials 3 (1979), S. 80-83 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Adult male Wistar rats were exposed for 2-5 weeks, 6 h nightly, 5 nights a week, to oxidative thermal degradation products of low density polyethylene derived by heating (325°C) under an airstream in a tube oven. Chemical analysis of the degradation products in the gaseous fraction revealed a wide variety of potentially toxic molecules which included carbon monoxide (〈20 ppm), formaldehyde (1.4 ppm), acrolein (0.5 ppm) and various other aldehydes (total concentration 18 ppm expressed as formaldehyde). The mean oxygen concentration was 20%. The total particulate fraction amounted to 8 mg m-3. The latter particles might have caused the detected discoloration of the rat fur. Similarly this contamination might have been the cause of a very significant increase in the duration and frequency of preening of the rats. The neurochemical effects associated with the exposure included an increase in the cerebral RNA concentration as well as initial increase in the glycosylation of cerebral protein in vitro. NADPH-diaphorase activity was below the control range throughout the exposure while the superoxide dismutase activity displayed an increasing trend five weeks after the beginning of the experiment. The latter effects were taken as a response to potentially harmful molecules in the brain whereas the effects on the RNA and glycosylation might have resulted from a more peripheral nervous irritation.
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  • 99
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 100
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    Fire and Materials 3 (1979), S. iii 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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