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  • Articles  (331)
  • Chemistry  (331)
  • Signal Transduction
  • 1995-1999  (163)
  • 1990-1994  (168)
  • Architecture, Civil Engineering, Surveying  (331)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 17 (1993), S. 185-190 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Different types of floor coverings were tested using three different methods: the Cone Calorimeter (ISO 5660), the Nordtest floor covering test NT FIRE 007 and the German Radiant Panel Method (DIN 4102 Teil 14). The results of the comparisons between both flame spread and smoke production are given. Some correlation is found between the results of the Cone Calorimeter and the NT FIRE 007. Between other methods, no correlations seem to exist.
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  • 2
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 17 (1993), S. 249-254 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: External radiation in enclosure fires can significantly enhance flame spread and fire growth. One of the effects of external radiation is to increase the mass loss rate of the fuel, which in turn produces larger flames. In this work, a measurement of mass loss with and without applied radiation was made as a function of time for three types of materials: a plastic (polymethylmethacrylate), wood-based products (particle board and hardboard), and a paper-based product (cardboard). The levels of applied radiation ranged from 0 to nearly 12 kWm-2. The purpose of the investigation was to (1) quantitatively determine the effect of external radiation on the mass loss of various materials,(2) measure various parameters which may be used to characterize the mass loss rate history of the materials and (3) determine a method for expressing the mass loss rate as a function of time for input into numerical models. Higher levels of external radiation resulted in higher peak mass loss rates and quicker consumption of the material. Quantities which are useful for ranking the flammability of materials have been measured for the samples tested and are tabulated.
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  • 3
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 17 (1993) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 4
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 17 (1993), S. 259-263 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A new Intermediate Scale Heat Release Rate Test Method is being developed primarily for testing assemblies in the vertical mode. Using the oxygen consumption calorimetry methodology and exhaust collection systems that already exist in many laboratories in the US and around the world, the apparatus is very economical to install. The sample size lends itself to reptitive testing in a short period of time. Sample preparation is generally quick and easy. Further development of the method should progress now that the method has been introduced at ASTM and will be introduced formally into ISO in the near future. There has been a favorable response by several laboratories who are considering construction of the apparatus. Additional assemblies tests are already underway and additional data will be presented in the near future.
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  • 5
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 17 (1993), S. 271-277 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In the study of smoke suppressants the measurement of gross amount of smoke from a given sample is essential. However, smoke being a complex phenomenon, its measurement with optical methods presents practical problems. The paper describes a flow system for the measurement of smoke production. Effectiveness of smoke-suppressant formulations for poly(vinyl chloride) as assessed in a flow system is reported. Results of experiments conducted to probe and establish the capability of smoke measurement in a flow system using a helium-neon laser are discussed.
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  • 6
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 18 (1994), S. 231-241 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper extends previously reported work 1,2 and describes the influence that a range of selected flame retardants have on the burning behaviour and pyrolyses of homo-and copolymers of acrylonitrile. Various inorganic and organic phosphorus and nitrogen- or sulphur-containing, halogen-containing (in the absence and presence of halogen or antimony (III) oxide) and nitrogen-containing flame retardants and red phosphorus were studied using LOI, TGA, DSC and residual char measuring techniques. Flame retardancy relates directly to char-forming tendency for all retardants and their ability to reduce the dominance of flammable volatiles formed during the first stage of acrylic polymer pyrolysis. Ammonium phosphates are particularly effective flame retardants for the selected copolymers. Possible mechanisms of retardant activity are discussed, including the char-forming tendency of antimony-bromine combiniations.
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  • 7
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 18 (1994), S. 263-265 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 8
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 19 (1995), S. 89-94 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In this study, a protocol was developed to increae accuracy, generality and efficiency when determining piloted ignition properties. A new procedure for calibrating the radiative and convective heat flux protiels on exposed speciments, such as Douglas-fir plywood, has been implemented for the lateral ignition and flame spread test (LIFT) apparatus. The boundary conditions needed for heat transfer anylysis are made unambiguous by including a simple, direct measure f surface emissivity. A new aluminum foil shutter improves accuracy for measuring ignition time. A recently developed theroy of ignitanility provides a formula to account for the transition form thick to thin thermal behaior, allowing specimens of finite thicknesses and a fuln range of test irradiances.
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  • 9
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Recent advances in passenger rail transportation, fire test methods, and hazard analysis necessitate re-examination of requirements for fire safety. Several studies have indicated nearly random ability of current bench-scale tests to predicts actual fire behavior. Fire safety in any application, including transportation, requires a multi-faceted approach. The effects of vehicle design, material selection, detection and suppression systems, and emergency egress and their interaction, on the overall fire safety of the passenger trains must all be considered. The strengths and weakness of current methods for measuring the fire performance of rail transportation systems are evaluated. A systems approach to fire safety which address typical passenger train fire scenatios is analyzed. A rationale is presented for the direction in which most fire science-oriented organizations in the world are clearly headed - the use of fire hazard and fire risk assessment methods supported by measurement methods based on heat release rate.
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  • 10
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 19 (1995) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 11
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 19 (1995) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 12
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 19 (1995), S. 253-258 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A comparison is presented of cone calorimeter heat release data between fire retardant treated and untreated wood products. The test results show significant differences between these two groups. The parameters included in the comparison are time to ignition, rate of heat release (peak and average values) and total heat release. The wood-based products were also tested in different small-scale national standard fire tests and in the full-scale room fire test. Fire retardant wood products achieve an improved classification both in present national systems and in possible new systems based on the cone calorimeter and the room fire test.
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  • 13
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 19 (1995), S. 243-252 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: When a specimen is testd for its heat release rate (HRR) behaviour using a bench-scale such as ISO 5660 or equivalent, one very important test condition is not pre-standaridized and must be set: the heat flux to be imposed on the specimen by the heater. The heat flux cannot be ligitimately standardized, since the value appropriately to be used will differ according to purpose or application. The present paper sets forth the considerations which should govern the correct choice of heat flux. A discussion is given of minimum ignitiability level; statistical variability at low heat fluxes; the ranges of heat fluxes associated with small actual ignition sources; the heat fluxes associated with fires away from the ignition sources, all the way up to fully-involved room fires; the application of the product; and the needs associated with mathematical modeling of room fires. Correlational approaches are also illustrated and contrasted to physics-based ones. Finally, the empirical nature of the present situation is emphasized. Judged from first principles, it would appear that successful prediction of room fire results from bench-scale test data would require both the testing at a large number of different heat fluxes and the use of algorithms to permit time-dependent interpolation. Such algorithms have been proposed; however, some very successful predictions are noted with much simpler techniques.
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  • 14
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 19 (1995), S. 283-285 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A simultaneous TG-DSC system (STA-625) has been used to investigate the suitability of using magnesium hydroxide (MH) as a flame retardant and smoke suppressant in polypropylene (PP) formulations. Several MH/PP formulations were examined at differing concentrations. The presence of MH in the system greatly alters the thermal degradation character of PP. This work forms the first in a series of application notes using various Theometric Scientific Thermal Analysis instruments.
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  • 15
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 19 (1995), S. 265-273 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Forest fires involve a wide range of unknown variables, e.g. wind flow over complex terrain, atmospheric stability, vegetation burning characteristics, location and fuel type, etc. The main objective of the present work is to incorporate the Rothermel simplified combustible model into a 3D unsteady flow solver appropriated for convective atmospheric flows over complex terrain. The released combustion energy is taken into account in the enthalpy equation. The unsteady byouant plume strongly influences the local wind speed direction and magnitude. A speical interactive coupling procedure was developed that links the calculated location of fire front and fire energy release to the momentum and energy transport for each time step. The general computer algorithm includes several other features such as the effect-drag of trees on the momentum transport and the consequent modifications in the k and ε turbulence model employed. The results include the prediction of fire development in flat terrain and in a valley and over hills covered by vegetation. A parametric study was conducted to detect the influence of wind speed, vegetation and fuel content on burning area, burning speed and wind speed direction.
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  • 16
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 19 (1995), S. 275-281 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The flame spread process is driven by the net heat flux to the specimen surface, including the flux from the flame itself. This flame flux is important since it comprises a major part of the driving force causing flame fluxes were obtained. The values which are reported do not appear consistent and show more deviation among materials than would be anticipated. The most common fire test used for obtaining engineering data on flame spread (ASTM E 1321) also is not formulated in terms of flame flux as a driving force. This motivated an experimental programme, whereby six materials have been studied using the flame spread geometry of the ASTM E 1321 test, but with additional instrumentation for recording heat fluxes. The flame fluxes obtained experimentally in this study show much less variation among materials than the comparable data from the literature survey.
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  • 17
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Addition of natural clay materials in intumescent polypropylene-based formulations (additive: ammonium polyphosphate and pentaerythritol) leads either to a decrease or to an increase of their fire retardant performances versus the chemical or the physical characteristics of the clay materials. A study of the factors affecting these performances has been carried out using linear and principal components analysis. This analysis shows that the results of the evaluation tests (LOI and UL 94) are affected in different ways by the adduct of the different clay material and that an increase in the LOI is not necessarily related to an increase in the UL 94 classification. LOI values are improved by the presence of the montmorillonite and of illite clay minerals which may react with acidic phosphate to form active carbonization catelysts, in addition, the results of the LOI test are improved by the presence of quartz and other foreign minerals in the clay materials. This study discusses the part played by the different constitutive minerals in the formation of defects in the polymer chain during the mixing process. It is proposed that the presence of these defects leads to a change in fire retardant performance.
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  • 18
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 20 (1996) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 19
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    Fire and Materials 20 (1996), S. 111-111 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: No Abstract
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  • 20
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A total of 21 electrical cables were made, all with essentially identical construction but differing in the chemical composition of sheath and/or insulatiòn, which were all commercially available materials, both halogenated and non-halogenated. All cables were tested in two large-scale cable tray tests, ASTM D5424 (CSA FT-4 protocol), with a total length of 2.44 m and IEC 332-3, with a total length of 3.5 m. The cables were also tested in a number of small- and medium-scale tests for flame spread (IEC 695-2-2, IEC 332-1, UL 1581 Part VW1, BS 476 Part 12E, DIN 4102 Part 16), temperature increase (DIN 4102 Part 16) and smoke obscuration (IEC 1034-2, BS 476 Part 12E). Finally, all cables were tested in the cone calorimeter (ISO 5660), horizontally, at incident fluxes of 20, 40 and 70 kW m-2. All the cables passed the mild flammability tests, but distinctions could be made based on the afterflame time observed, where halogenated cables outperformed non-halogenated cables by a significant margin. It was also possible to distinguish between the halogenated and non-halogenated cables on the basis of the cable length charred in some tests. In terms of smoke obscuration, it was found that the rankings offered by the various tests were very different. While non-halogenated cables had improved smoke performance over traditional vinyl types, fluorinated cables performed very well. This confirms the importance of material selection by performance rather than by chemical composition. Almost all cables performed sufficiently well that they generated relatively limited amounts of smoke under realistic end-use fire test conditions. The peak heat release rate in the large-scale cable tray test (ASTM D5424) served as an excellent criterion for discriminating between the fire performance of the various cables (the traditional criterion being char length). The average rate of heat released also served to distinguish between different levels of cable fire performance. Moreover, cables passing the test tended to release less heat and smoke than those that failed. The trends observed in the cone calorimeter heat release test were similar to those in the large-scale test and show good correlation between cable tray char length and cone calorimeter heat release. It was observed that the halogenated cables tested performed better than the non-halogenated cables in terms of heat release rate by factors ranging from two to greater than five. The results indicate that cables with excellent fire performance can be constructed by using a variety of materials. It is thus important to specify fire performance and leave material choice to manufacturers.
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  • 21
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 20 (1996), S. 107-109 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In this paper a possible explanation is presented for the differences found between the fire behaviour of materials in small-scale cone calorimeter tests and the large-scale furniture calorimeter. The results obtained with cone calorimeter/FTIR equipment at 35 kW m-2 will show that the early flash ignitions of typical materials like cotton and wool are due to the liberation of flammable gases during the pyrolysis phase and the typical ignition situation on the cone calorimeter, that is, the presence of a sparking igniter above the sample. This fast flash ignition and the early heat release behaviour on the cone calorimeter may be in contradiction to the early fire growth in other fire tests where the ignition conditions are clearly different from pyrolysis circumstances, that is, ignition via a burning newspaper, match, gas flame, etc.
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  • 22
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    Fire and Materials 20 (1996), S. 61-67 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: When measuring the production rates of heat and smoke of upholstered furniture the ignition source must not influence the test results. In this paper variations in the strength, application time and geometry of the ignition burner used in the furniture calorimeter are studied. Results from replicate furniture calorimeter chair test show that the burning behaviour is almost independent of the burner intensity in the applied regime.Tests on six different furniture items were performed in the furniture calorimeter. The test objects were exposed to three intensity levels of ignition source. The sources were: a large propane burner giving 30 kW during 120 s and a smaller propane burner used at two levels of heat output, 1.7 and 5.8 kW during 90 s. The results showed that the burning behaviour of the furniture was very similar regardless of which burner was used. This was especially evident when the time regime between 50 and 400 kW was studied. The length of this period is a measurement on how quick untenable conditions are developing in a single, well-ventilated compartment.
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  • 23
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    Fire and Materials 20 (1996) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 24
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    Fire and Materials 20 (1996), S. 79-96 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Light steel-frame building systems are becoming more prevalent in commercial, industrial and residential construction in New Zealand. Tested fire resistance ratings are generally available for non-load-bearing systems, but not for load-bearing applications. This study investigates the performance of load-bearing light steel-frame systems exposed to fire. Methods are presented for calculating the reduction of steel strength and stiffness at elevated temperatures, and for predicting the deflections resulting from temperature gradients and P-Δ effects. Heat transfer modelling by computer is used to predict steel framing temperatures for systems exposed to the standard ISO 834 time-temperature curve and real fires. Three full-scale furnace tests were carried out to evaluate analytical predictions. A design procedure is proposed.
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  • 25
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    Fire and Materials 20 (1996), S. 133-143 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Nailed joints with wood members were exposed simultaneously to standard fire and constant load. Different loads were applied in the range of 0.1 to 0.6 of the estimated failure load at normal temperature. Measurements of the rate of charring and the temperature were used to determine the temperature profiles and further to estimate the reduction in the strength properties. The test results are compared with calculations based on the theory of K. W. Johansen. Three different relations between the reduction of embedding strength and the temperature were investigated. For one of these relations, the theory agrees well with the results obtained in the fire tests. The results of the calculations also show that there is a considerable reduction of the embedding strength during the first period of fire.
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  • 26
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    Fire and Materials 20 (1996), S. 161-166 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An estimate of the annual generation of polychlorodibenzodioxins and furans (PCDD/F) in the United States as a result of PVC burning in house fires is made using building data and fire loss statistics and soot and ash samples obtained from laboratory experiments and building fires involving PVC. Using conservative estimates for construction, fire involvement and formation, dioxin generation from PVC in house fires is estimated to be in the range of 0.074 to 8.6g TEQ yr-1 as soot, 0.4 to 14g TEQ yr-1 as ash, and thus 0.47 to 23g TEQ yr-1 total. The maximum likelihood estimate is approximately 0.3g TEQ yr-1 as soot and 1g TEQyr-1 as ash. Any of these estimates constitutes a minuscule fraction of the 9300g annual air emissions or the 20000-50000g (TEQ) annual deposition from the air estimated by EPA.
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  • 27
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    Fire and Materials 20 (1996), S. 167-172 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The purpose of this study is to evaluate the effect of different oil contaminants on the spontaneous ignition behavior of cotton fabric. A series of treated fabrics with different oil contamination percentages was investigated and compared. Measurements were designed and carried out to determine the average time-to-ignition and to study the thermal behavior of systems containing cellulose. The results showed that the time-to-ignition of the contaminated samples has notably decreased, particularly at relatively low temperatures (350-450°C). However, at higher temperatures such effects became insignificant. Differential Thermal Analysis measurements were used to explain the mechanism by which the oils affect the thermal behavior of the sample. The heat evolved due to the oxidation of the oil content is sufficient to increase the rate of cotton depolymerization at the expense of the dehydration mechanism. In other words, the heat evolved promotes the formation of volatiles which are not char precursors.
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  • 28
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    Fire and Materials 20 (1996), S. 173-181 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A number of common tropical timbers have been subjected to thermal analytical investigation as part of a wider research programme under air atmospheric conditions. Thermal parameters obtained were correlated with oven-dry densities of the timbers. Two well-defined pyrolysis stages have been observed which occur over the temperature ranges 201-426°C and 397-557°C. The kinetics of the thermal degradation of the timbers were obtained using Broido's analytical procedure. These results were interpreted on the basis of the known mechanism of pyrolysis and the calculated kinetic parameters were discussed within the context of other published values for cellulose.
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    Fire and Materials 20 (1996) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Fire and Materials 20 (1996), S. 297-299 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The fire retardancy properties of hardboard treated with ammonium hydrogen carbonate (AHC) and sodium bromide were investigated by measuring their ignition time and flame temperature. An increase in ignition time and lowered flame temperature were observed with increased flame retardant (FR) concentration. AHC was found to be less effective as a fire retardant for this material. © 1996 by John Wiley & Sons, Ltd.
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    Fire and Materials 20 (1996), S. 305-305 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Fire and Materials 20 (1996), S. 301-303 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Autoignition temperature and heat of combustion are two important parameters in determining the oxygen compatibility of materials. This study investigates the autoignition temperature of 32 polymers at an elevated oxygen pressure of 10.3 MPa and reports their heat of combustion. © 1996 by John Wiley & Sons, Ltd.
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    Fire and Materials 20 (1996) 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Notes: The philosophy behind research into personal protection from flame and intense heat for UK military personnel is addressed. The threat is examined as are methods of measurement and assessment. Finally an overview of the novel techniques which are being pursued at the Science and Technology Division is given. © British Crown Copyright 1996/MOD.
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    Fire and Materials 21 (1997), S. 7-16 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The modelling of the spread of fire and its extinguishment still represents a significant challenge. As part of a combined experimental and computational study of fires we have developed a general Computational Fluid Dynamics (CFD) model of fire spread and extinguishment. The primary objective was to produce a flexible computational tool which can be used by engineers and scientists for design or research purposes. The present paper deals with the description and validation of a solid pyrolysis model which has been applied, as a sub-model, in this general computer fire code. The pyrolysis model has been formulated using the heat-balance integral method. The model can be applied to slabs of char forming solids, such as wood, as well as non-charring thermoplastic materials, such as PMMA. Results are compared with analytical solutions, numerical simulations and experimental data. In all cases the integral model performs well. © 1997 by John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 17-22 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An investigation of cone calorimeter test procedures was performed using two types of mattress composites with various specimen preparations and equipment configurations. The objective was to discover suitable procedures for testing mattress composites. Concurrent with this work a much larger and more sophisticated project known as CBUF was underway in Europe. One of CBUF's secondary objectives was to provide an appropriate test protocol for testing upholstered furniture composites, including mattresses. Most of the CBUF protocol was available at the time of this study and a modified form of the specimen preparation technique was used in this investigation. Preliminary tests found unacceptable test performance with some configurations. Subsequent testing examined variations of the established test protocols and other test procedures. The data sample was small, but observations of the data indicate trends that might be attributable to the use of the different procedures. Significantly it was determined that the edge frame used to hold specimens in place during the test does affect the test results. A modified CBUF protocol proved to be the best procedure, but it requires extensive experience with the CBUF specimen preparation method in order to be able to produce satisfactory specimens. © 1997 by John Wiley & Sons, Ltd.
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    Fire and Materials 20 (1996), S. 261-271 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: This paper reviews the past research, experimental techniques and scaling relationships used in the studies of oscillatory buoyant diffusion flames and reports an experimental investigation conducted to determine the pulsating characteristics of such flames. The experimental data were obtained by using three techniques, namely, pressure fluctuation measurements, thermal imaging and high-speed video photography. Present findings are compared with data sets reported in the literature and correlations for pulsation frequency suggested by previous studies are independently verified. Analysis of the experimental data on frequency of pulsations in different burners shows that for a fixed-diameter flame the pulsation frequency is almost independent of fuel flow rate. The equation f=1.68D-0.5 gives the best approximation for the relationship between pulsating frequency and diameter over a wide range of data. An alternative way of expressing the relationship between the key variables is St=0.52*(1/Fr)0.505. This proves to be a better way of expressing the relationship since it can include the effect of the fuel flow rate. Slight modifications to this expression allows prediction of flame oscillations under elevated/reduced gravity and isothermal buoyant plumes. This relationship and the observations of the present study confirm the hydrodynamic nature of flame puffing: interplay of buoyancy and fluid motion. © 1996 by John Wiley & Sons, Ltd.
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    Fire and Materials 20 (1996), S. 273-291 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: In this paper an overview is given of several methods for quantitative analysis of FTIR spectra. Each method has its particular advantages and disadvantages. Therefore, depending on the gas component to be analysed in smoke gas spectra, an optimal choice of method has to be made. This choice depends on several different aspects:• Is the spectral band of interest free of interfering components?• Does the absorption-concentration relation show strong deviations from Beer's law?• Are significant baseline corrections necessary?• Does the applied model need to warn for the presence of unexpected components?• Is it sufficient to use only a few wavenumbers or is a full-spectrum method necessary?It will not be easy to make the appropriate choice. However, in some cases, statistics can help, in others, a good rule of thumb is to keep the choice as simple as possible. © 1996 by John Wiley & Sons, Ltd.
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    Fire and Materials 20 (1996), S. 306-306 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 21 (1997), S. 1-6 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The effect of melting behaviour on upward flame spread of thermoplastic materials when subjected to small ignition sources and considered to suffer no external flux was studied using large-scale tests. For moderate fire conditions the cone calorimeter was utilized, with the sample set in a vertical orientation to study the melting behaviour of the specimens. Under these conditions the results indicate that the melting behaviour significantly affects upward flame spread behaviour. A pool of the melt which formed at the base of the vertically oriented sample tested creates a pool fire which then controls the fire growth and flame spread. In contrast, it was found that some thermoplastic materials which have higher glass transition temperatures or undergo a special pyrolysis process such as depolymerization, intumescing or charring do not experience significant melting behaviour when exposed to the same thermal insult. As a result, they behave very differently in terms of upward flame spread. The study also indicates that the melting behaviour of thermoplastic materials is an important characteristic in fires which should be taken into account in the development of modelling, in particular for upward flame spread models. © 1997 by John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 51-51 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: No Abstract
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    Fire and Materials 21 (1997), S. 33-39 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: A series of 37 cigarettes were analysed to develop a model, based on cigarette physical properties, to predict the ignition propensity of the cigarettes towards cellulosic fabrics. The properties used were: cigarette circumference (in mm), tobacco packing density (in g cm-2), paper permeability (in CORESTA units) and the presence or absence of citrate additives in the paper (used independent of concentration, although typical additions range from 0.5 to 0.8 wt%). Two empirical models were developed, one for low and medium paper permeabilities, and one for very high paper permeabilities (above 50 CORESTA units). The latter exceed the paper permeability of most commercial cigarettes, and have medium to high ignition propensities. Thus, they are probably only of interest from the point of view of a mathematical curiosity. The former model, however, addresses cigarettes in the range where commercial cigarettes are potentially viable. The resulting ignition propensities exhibited cover the entire feasible range, from 0% to 100%. Both models predicted the ignition propensities of the tested cigarettes quite well, within an error range which did not exceed 30% for any cigarette. Physical rationales are presented for the effects of the variables used. However, the rationale for the discontinuity in ignition propensity found for the cigarettes with extremely high paper permeability is less clear. One explanation is that there is probably excess oxygen present so that a fuel/oxygen mixture is obtained with a ratio which is less than the lower flammability limits and is too lean to support combustion. However, further analysis of this issue is warranted. The empirical model for low and medium paper permeability cigarettes is potentially useful for developing cigarettes with lower ignition propensity, since it is a practical way of combining the individual properties that most heavily affect cigarette ignition propensity. © 1997 by John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 53-65 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Fire hazard assessments must be primarily driven by life safety variables. Concern is often highly focused on toxicity issues, since fire deaths, in the majority of cases, are found (in whole or in part) to be due to toxic gas inhalation. Procedures have recently been published by ISO, wherein the toxicity assessment of fire products is focused primarily on bench-scale testing for toxic potency (the ‘per-gram toxicity’). Yet hazards of products with regards to fire toxicity may be determined much more by their differences in burning rates than by any differences in toxic potency. Burning rates are not assessed in the pertinent standards (ISO 13344 and ISO TR 9122). For most product categories, techniques for predicting full-scale burning rates from bench-scale data are not yet in hand. Thus, today the best means of comparing actual, full-scale toxic fire hazards is the full-scale fire test, equipped with additional gas measuring instrumentation. Such an approach is not among the recommended methods of the international standards, yet it is the only one with innate validity. In the present work, a series of sandwich panel products were tested in a full-scale room configuration. Bench-scale comparison was made to the ISO 5660 Cone Calorimeter and the DIN 53436 tube furnace. The toxic gases were quantified in all cases by chemical analysis. The product which showed the best performance in the full-scale tests (rock wool insulated sandwich panel) did not achieve a good fire toxicity performance due to minimization of toxic potency. Instead, the successful performance was attributed wholly to reduction of burning rate. Bench-scale measurements of toxic potency were shown to lack relevance to reality in such cases where even the full-scale toxic potency is not a determining factor. © 1997 John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 179-185 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Zinc hydroxystannate (ZHS), at levels of 2-5 phr, and the hydrated fillers, magnesium hydroxide (MH) and alumina trihydrate (ATH), at levels of 20-50 phr, are effective flame retardants and smoke suppressants for flexible PVC. Novel ZHS-coated hydrated fillers are found to exhibit markedly improved fire-retardant properties, particularly with regard to increasing LOI values, reducing heat release rates and suppressing smoke generation, when compared with conventional uncoated forms. The ZHS coating appears to change the filler particle morphology and there is evidence that the coating is largely retained on the filler surface after melt processing into the PVC. The improved dispersion of the active tin compound in the polymer matrix leads to enhanced fire retardancy and this, in turn, allows significant reductions to be made in overall filler loading, with no loss in flame-retardant or smoke-suppressant performance. © 1997 John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 95-105 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In the EC-sponsored CBUF (Combustion Behaviour of Upholstered Furniture) study three different models were developed for using Cone Calorimeter results to predict full-scale furniture burning. Model I is a correlation-based approach and has the most comprehensive coverage of styles and furniture types. Model II is based on area-convolution. It has been developed, so far, for several of the common upholstered furniture styles. Model III is based on an extension of a thermal flame spread model and is here developed only for mattresses. Models II and III offer the prediction of the burning item's time history, while Model I computes the peak HRR, the time to peak, and several other primary characteristics. The predictability of all three models is good. At present, the models presented do not consider furniture with plastic frames, and only a limited predictability is offered for office-type furnitures items which contain a hard-plastic shell. The models offer a very significant improvement over the existing state of the art. © 1997 John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 277-282 
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    Notes: A correlation has been developed between closed-cup flash points and normal boiling points for silicone compounds. In addition, a more general correlation has been developed between these two properties for the general organic compounds, including silicone compounds. The closed-cup flash points can be predicted using empirical equations. The standard errors of estimate are 11.06 and 11.66°C for silicone compounds and general organic compounds (including silicone compounds), respectively. © 1997 John Wiley & Sons, Ltd.
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    Notes: The incorporation of two brominated compounds/antimony trioxide blends into a PP-PE copolymer were studied. Both brominated trimethylphenyl indane (FR 1808) and poly(pentabromobenzyl acrylate) (FR 1025) confer good flame retardancy at 40% loading. A comparison was made with the incorporation of magnesium hydroxide at higher loadings (up to 64%) in the same copolymer. The mineral filler improves both fire resistance and stiffness of the copolymer, nevertheless the high loading causes a dramatic decrease in impact resistance. Moreover, the necessary surface treatment of the filler significantly lowers the maximal tensile strength. In order to maximize both fire resistance and mechanical properties, we combined each brominated flame-retardant system (20% in weight) with magnesium hydroxide or talc (20% in weight). Talc is used as reference. These composites show interesting fire-retardant properties in comparison with the copolymers containing only 40% of the brominated flame-retardant systems. In addition, the mechanical properties are on the whole improved. © 1997 John Wiley & Sons, Ltd.
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    Fire and Materials 21 (1997), S. 271-276 
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    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Results are presented of a project to evaluate the combustibility and surface flammability of building interior finish materials commonly used in Taiwan. The project was conducted at the Fire Laboratory of the Architecture and Building Research Institute in Taipei. Eighteen different wall-covering materials were tested according to Chinese National Standard (CNS) 6532, which is equivalent to Japanese Industry Standard (JIS) 1321, and according to ASTM E 1354-92 (Cone calorimeter). A comparison of test results is presented, and a qualitative relationship is developed between the performance in the two methods. The classification system for degrees of combustibility developed in Canada by Richardson and Brooks was hereby used to group materials based in performance in the ASTM test method. © 1997 John Wiley & Sons, Ltd.
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    Fire and Materials 22 (1998), S. 43-43 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 22 (1998), S. 44-44 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 22 (1998), S. 39-42 
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    Notes: Heat Release Rates of organic materials are studied in many countries, but there is no mathematical formula to represent their shape. We considered a mathematical expression of the Heat Release Rate Curve by a simple equation. And we also derived the index of degree of combustibility, named ‘Burning Index (BI)’. The Heat Release Rate Curve is expressed by the derivative of a probability function of maximum value and has three parameters; an amplitude coefficient, a time width coefficient and an ignition index. BI is in proportion to an amplitude and a time width and in inverse proportion to an ignition index. BI values of cable plastic compounds with flame-retardant material had good relations with the quantity of non-organic ingredients. © 1998 John Wiley & Sons, Ltd.
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    Fire and Materials 22 (1998), S. 47-54 
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    Notes: High-temperature pyrolysis of various classes of polymers have been discussed. For the non-carbonizing polymers it was shown that polymer structure can affect the pyrolysis characteristics. Data on the high-temperature pyrolysis of some polypropylene samples with different crystallinity have been presented. Modification of the standard method allowing one to obtain kinetic data from the single experiment was discussed. A kinetic model for the degradation of char-forming polymers in conditions of high-temperature pyrolysis has been suggested. It has been supposed that pyrolysis of carbonizing polymers proceeds in some (two in present work) parallel stages with different activation energies, temperatures and pyrolysis rates. Questions of the applicability of the suggested model to describe the various types of charring systems have been discussed. High-temperature pyrolysis for a number of epoxy resin-based polymeric compositions have been investigated. Kinetic parameters of the pyrolysis have been computed. © 1998 John Wiley & Sons Ltd.
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    Fire and Materials 22 (1998), S. 77-83 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Fire-retardant wood treatment with fire-retardant chemicals consisting of basic nitrogen compounds and phosphoric acid have been thoroughly examined. The fire retardance and endurance of wood were influenced by the treatment method. Here two treatment methods were compared, heat-pressed treatment method improved these qualities more than heat-dried treatment method. Furthermore, to gain lasting fire retardance, it was considered necessary to react basic nitrogen compounds and phosphoric acid with formaldehyde as in the dicyandiamide-formaldehyde-phosphoric acid or melamine-dicyandiamide-formaldehyde-phosphoric acid system. In the treated wood, the concentration of chemicals gradually decreased as it approached the center. The functional fire retardance could be graded in accordance with the chemical content. © 1998 John Wiley & Sons, Ltd.
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    Fire and Materials 22 (1998), S. 103-108 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: The thermal decomposition of six different samples of wood and leaves in nitrogen has been studied by using dynamic thermogravimetry. In the experiments two main weight loss processes took place and the total weight loss at 500°C was over 95% in all six cases. By means of the Doyle method, the two processes were found to fit most closely the plot for the second-order equation in the form dα/dt=k(1-α)2, and each of the weight loss processes was found to be controlled, respectively, by two dominant reactions as the temperature increases. It was inferred that competing reactions occur during the overall temperature interval for all the six samples. By comparing the activation energies using this model with those by the method of Moll et al., and by comparing the experimental and theoretical thermogravimetric curves, the ‘second-order’ model was tested to be able to predict the weight loss processes of the samples with very good accuracy. It can be concluded that the ‘second-order’ kinetic model acts much better than the conventionally adopted first-order model. © 1998 John Wiley & Sons, Ltd.
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    Fire and Materials 22 (1998), S. 119-128 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This work compares the fire degradation of ethylene-vinyl acetate 8% copolymer (EVA8) with two flame-retarded formulations, using the cone calorimeter. The first one, EVA8/ammonium polyphosphate (APP) leads to the protection of the material, in the conditions of a fire, by means of blowing up and weak carbonization. The addition of polyamide-6 (PA-6) in EVA8/APP improves the protection by forming an intumescent carbonaceous shield. The fire hazard of the virgin polymer and of the FR systems are quantified, in terms of rate of heat release, weight loss, effective heat of combustion, volume of smoke production and CO and CO2 production. It assesses the effectiveness of the fire retardant additives APP and APP/PA-6 in EVA8-based materials under simulated real fire test conditions.The respective temperatures of the degradation front are deduced from the weight loss data recorded in the course of the cone calorimeter experiments and the results of the invariant kinetic parameters method applied to the different specimens. The addition of APP/PA-6 in EVA8 leads to a superficial phenomenon; the degradation zone is thus located on the upper volume of the specimen during all the exposure to the heat flux. © 1998 John Wiley & Sons, Ltd.
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    Fire and Materials 22 (1998), S. 155-165 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A set of small-scale experiments was carried out to study the effects of material structural properties on the re-ignition characteristics of solid fuels. The influence of other key parameters, such as the incident heat flux and pre-burn, was also carefully investigated. The experiments were conducted on specimens of wood and PMMA using a cone calorimeter. As expected, the effect of water on the re-ignition time was found to be significant. It was also found that the re-ignition characteristics of charring materials, such as wood, are quite different from non-charring materials, mainly due to the structural differences. Based on the experimental observations two different mathematical models were developed to analyse the data for both wood and PMMA samples. Calculations of the re-ignition time made using these models agree generally well with the measurements and confirm that the material structure plays a vital role in its re-ignition behaviour. © 1998 John Wiley & Sons, Ltd.
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    Fire and Materials 15 (1991), S. 47-49 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 15 (1991), S. 43-46 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Three small-scale flammability tests were evaluated for potential use in quality control. The small-scale flame test produced excessive scatter of data, the hot-plate ignition test gave reasonably reproducible data, but the critical oxygen index yielded superior results and is recommended for quality control testing.
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    Fire and Materials 15 (1991), S. 37-42 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The fire-retardant effectiveness of mixtures of hexabromocyclododecane (HBCD) and artimony oxide (Sb2O3) in polyethylene (PE) was examined utilizing differential thermal analysis (DTA), gas chromatography/mass spectroscopy (GC/MS) and limited oxygen index (LOI) techniques. It was determined that the normal practice of mixing Sb2O3 with HBCD induced a synergistic chemical reaction at 250°C whose main product, SbBr3, was responsible for enhanced fire retardancy. The mixing of SbBr3 directly into the PE produces a superior fire-retardant polyethylene.
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    Fire and Materials 15 (1991) 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 15 (1991), S. 51-51 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 22 (1998), S. 44-44 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 22 (1998), S. 25-37 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: An analysis has been made to compare the repeatability and reproducibility of three tests for cigarette ignition of upholstered furniture composites: ASTM E1352, ASTM E1353 and NIST 851 mock-up. The first two of these tests are traditional methods designed to assess the potential of upholstered furniture components to being ignited by cigarettes while the last one, NIST 851 mock-up, is a new method designed to assess the propensity of cigarettes to ignite upholstered furniture composites. The traditional methods, ASTM E1352 and ASTM E1353 use a single cigarette for each determination and can be run in two ways: to obtain a numerical output of char length on the substrate (following the standard) or to obtain a pass/fail result for the substrate (practical use); the precision was analysed in both fashions. The new method, NIST 851 mock-up, uses 144 cigarettes for each determination (48 each on three substrate composites), and assesses the fraction of substrates that have been ignited (char length exceeding 10 mm), i.e. by a combination of pass/fail data. The analysis for actual char length was made according to ASTM E691 guidelines, while the analysis of the pass/fail was made according to a modification applicable to binary data. The precision of the test methods was as follows (in descending order):NIST 851〉ASTM E1353 P/F〉ASTM E1352 P/F〉ASTM E1353〉ASTM E1352© 1998 John Wiley & Sons, Ltd.
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    Fire and Materials 15 (1991), S. 65-84 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: An evaluation of the cone calorimeter by the Association of Plastic Manufacturers in Europe (APME) involved testing of 25 plastic materials together with two natural polymers. Specimen preparation is identified as having an important influence on the results, especially for certain types of material. Ignition time, rate of heat release (RHR) and smoke results are presented to show the influence of external heat flux. The dynamic smoke results (which should be measured from the time of exposure) are only relevant to well-ventilated fires unless the cone calorimeter is specially modified. For a complete evaluation a cumulative smoke measurement may be needed in addition. Although the cone calorimeter is a valuable research tool, and may be used frequently in industry, it needs to be made more robust and user friendly to avoid excessive downtime and to reduce calibration time. If the instrument is to be used for routine development and quality assurance, only one or two heat flux levels should be selected. These could represent a developing and a developed fire and should depend on the product application.
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    Fire and Materials 15 (1991), S. 93-96 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Combustible dusts, based on tests conducted in the Setchkin Furnace on five representative dusts, are shown to have two distinct layer minimum ignition temperatures, designated MITnon-flaming and MITflaming. The MITnon-flaming is the one usually reported in the literature; the MITflaming is determined by starting at a much higher temperature and working downwards. MITflaming can yield a different ranking of dust flammability than MITnon-flaming. The MITflaming appears to be more closely correlated to the MIT of dust clouds and to the test prescribed for flammable solids in the US Code of Federal Regulations than the MITnon-flaming.
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    Fire and Materials 15 (1991), S. 127-130 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: The flammability and ignitability of polyethylene using antimony trihalide compounds as fire retardants was evaluated by standard methods to determine retardant effectiveness. Compared with other retardants, the antimony trihalide compounds, antimony tribromide and antimony trichloride, substantially reduced both the flammability and the ignitability of the polyethylene. The influence of retardant concentration, heat flux and type of polyethylene was also studied.
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    Fire and Materials 15 (1991), S. 117-125 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: A study of the behaviour of aluminium building products in bushfires was carried out to test the validity of assertions that they perform poorly under bushfire conditions. The work was conducted in two parts: an examination of data from bushfire damage surveys and laboratory experiments in which window assemblies were exposed to radiant heat from a furnace. Data from surveys conducted after major bushfires were augmented with information from a questionnaire related specifically to this work. Analysis of these data did not provide any support for the belief that houses incorporating aluminium building products are at greater risk of being destroyed. The laboratory experiments on both timber- and aluminium-framed windows showed their performance under simulated bushfire conditions to be similar. It was found that bending of glass through distortion of the frames was not a factor in crack initiation.
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    Fire and Materials 15 (1991), S. 105-115 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A study of the fire behaviour of polypropylene plastics trays being considered for letter handling has been carried out. Various ignition sources and configurations of trays (both empty and filled with letters) were examined. In particular, stacks of trays contained in large steel-mesh unit load devices (ULDs), protected by automatic sprinklers, were ignited and the progress of the fires, release of heat and smoke, and sprinkler activation recorded. It was found that, when examined singly or in stacks in scenarios which might be encountered in sorting areas and post offices, the trays made from fire-retardant plastics were more difficult to ignite and took longer to become involved in fire than those made from standard grade plastics. The benefits of this slower build-up fire with the retarded plastics formulation were reduced to some extent by the greater amounts of smoke released by the burning of the retarded plastics. For stacks of ULDs filled with trays, typical of a scenario in a mail exchange, the fire-retardant plastics gave significant benefits in terms of life safety and fire damage to the trays and mail.
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    Fire and Materials 15 (1991), S. 131-136 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Until the 1960s ASTM E136 and CAN/ULC-S114 test methods were adequate for determination of non-combustibility in materials being used to construct most buildings. However, since then there has been a very large increase in the use of products that are considered safe for construction of buildings required to be noncombustible but which are classified as combustible by these simple pass/fail tests. Therefore, Forintek Canada Corp. have developed an approach to define the combustibility of these new materials, based upon their release of heat when tested using the ASTM E1354 cone calorimeter.
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    Fire and Materials 15 (1991), S. 147-147 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 15 (1991), S. 149-149 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 15 (1991), S. 137-143 
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    Notes: This paper describes a comprehensive experimental investigation of the fire performance of nailed gusset connections between large glue-laminated timber members. Both plywood and steel gusset plates were investigated with a range of loaded and unloaded test methods. The principal conclusions are that unprotected gussets have poor fire performance, but that a layer of solid wood or gypsum plasterboard will provide at least one hour of fire protection to typical joints.
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    Fire and Materials 15 (1991), S. 145-146 
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    Notes: The thermal behaviour of cellulose obtained from both the pith and rind of papyrus was studied and the flammability properties of paper produced from papyrus and other papers were measured. The use of flame retardants did not significantly alter the flammability properties of the papyrus paper.
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    Fire and Materials 16 (1992), S. 29-35 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The post-cooling properties of reinforced concrete constituents are of great relevance in the assessment of a structure for re-use after fire. The expansive rehydration of dissociated calcium hydroxide on post-cooling exposure to air can cause a total loss in strength if cement paste specimens are heated to and maintained at 400°C or above. The use of cement replacement agents can mitigate this effect. The strength and ductility of hot-rolled mild steel and cold twisted steel on gradual cooling or quenching from various temperatures can be correlated with microstructural phenomena. There is a significant increase in strength and loss of ductility when both types of steel are quenched from temperatures above 723°C. Some practical implications of these properties are described, using examples of fire-damaged structures.
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    Fire and Materials 16 (1992), S. 159-167 
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    Notes: An investigation has been carried out of the limiting oxygen index (LOI) test. A review of the literature shows that, although there is abundant information on the test, it is not clear that its results correlate well with those of any other test, or indeed with those of real fires. Theoretical considerations indicate that the test could be improved by using it with bottom ignition rather than with the standard top ignition. A number of materials were tested in the cone calorimeter and in the LOI, and various correlations were attempted. In general, correlations between some of the cone calorimeter properties measured and the inverse of the LOI made sense. These correlations were not, however, sufficiently sensitive, even when investigating small effects on a single base polymer system, to justify using the LOI as a proxy for the cone in any way. The LOI is likely to continue to be used extensively. This work suggests that quality control and, possibly, mechanistic or other flame-retardant additive studies, are its only applications where the results can be justified.
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    Fire and Materials 16 (1992), S. 181-186 
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    Notes: The authors have conducted a laboratory-scale gallery fire test on eight different samples of electric cable in a horizontal airflow. The number of speciments and the distances between them on the trestle were varied for each test. As a result, it was found that both ignitability and flame-propagation properties depended on the distance between the specimens as well as on their number. Such flammability properties obtained for each cable sample were also found to be considerably consistent with the critical oxygen index. In addition, it is proposed that the flammability should be classified largely into five categories in this laboratory-scale gallery fire test for fire-retardance evaluation of solid combustible materials such as electric cables.
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    Fire and Materials 16 (1992), S. 187-196 
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    Notes: Wood fiberboard-based, cellulose ceiling tiles have been used for many years. While various fire-retardant technologies have been developed to reduce the surface flammability of these products to acceptable levels, questions of their suitability for use due to their intrinsic fuel value and the impact of attachment methods used on fire performance have been raised from time to time. This paper reviews the history of these products from a fire-performance perspective and presents materials property data on surface flamespread, thermal conductivity and ignition phenomena. In addition, large-scale room fire test results are presented including compartment tests conducted on a variety of assemblies (including those installed with mastic construction adhesives) according to ASTM E 603 - Standard Guide for Room Fire Experiments.
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    Fire and Materials 16 (1992), S. 169-180 
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    Notes: An experimental facility based on the Quasi-stationary Flame Front Technique for determination of steady flame spread rate of materials at discrete levels of external radiant heat flux was developed. The method employs an external radiant heat source in front of which an element of a specimen of the material is positioned at a location corresponding to the desired level of external radiant heat flux. A specimen movement assembly, which can be operated manually, was designed for moving the specimen towards the stationary external radiant heat source such that the flame front could be maintained quasi-stationary. The experimental technique employed is simple in operation yet is capable of yielding reliable flame fornt displacement-time data. In the paper the design considerations of the experimental facility, details of its components, calibration and typical experimental results obtained are presented.
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    Fire and Materials 16 (1992), S. 207-208 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 17 (1993) 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 16 (1992), S. 197-206 
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    Notes: Burning rate is a key factor in modeling fire growth and fire endurance of wood structures. This study investigated the burning rate of selected wood materials as determined by heat release, mass, loss and charring rates. Thick samples of redwood, southern pine, red oak and basswood were tested in a heat release rate calorimeter. Results on ignitability and average heat release, mass loss and charring rates are reported for a heat flux range between 15 and 55 kw m-2. In this range, burning rate increased linearly with heat flux. Burning rate was very species dependent. Heat release rate was related to mass loss by effective heat of combustion, which also increased with heat flux. Charring rate was related to mass loss rate and original wood density. Important char property data such as yield, density and contraction are reported. A simplified calculation method is proposed for calculating mass loss rate and charring rate based on heat release rate.
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    Fire and Materials 17 (1993), S. 1-6 
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    Notes: An investigation of the burning behaviour of a series of halogenated polyester resin formulations has been carried out using the Cone Calorimeter technique. The data obtained clearly indicate that zinc hydroxystannate (ZHS) is more effective than antimony trioxide (Sb2O3) in reducing the average and peak rates of heat release in a chlorinated resin and in decreasing the peak rate of heat release in a brominated resin. The decreases in average heat release rate in the brominated resin are similar for ZHS and Sb2O3. Hence, at an addition level of 2 phr (parts per hundred of resin), ZHS reduces the average heat release rates of a chlorinated and a brominated resin by 41% and 26%, respectively, and the peak heat release rates of the same resins by 38% and 39%, respectively. The degree of smoke suppression exhibited by ZHS in these Cone experiments is significantly greater than that given by Sb2O3. In general, the correlation between Cone Calorimeter data and results obtained using other laboratory fire tests (UL-94, LOI) is poor, except in the case of smoke density measurements, where the correlation with NBS Smoke Box data is remarkably good. No correlation is observed between the measured values of CO and CO2 output by different test methods, although it is now generally considered that small-scale fire tests cannot be used to predict gaseous concentrations in real-fire situations.
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    Fire and Materials 17 (1993), S. 21-24 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A series of cellulose-polysilicic acid hybrid fibres with 15-35% silica contents were spun and their flammabilities were assessed by the LOI oxygen index test. Also, the rate of heat release and toxicities of fumes evolved during the combustion process for hybrid fibre with 33% SiO2 loading was obtained using the cone calorimeter and FT-IR techniques. The low flammability and toxicity indices indicate that this hybrid fibre can be used as a flame-retardant fibre.
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    Fire and Materials 17 (1993), S. 25-32 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Three timber-based materials were investigated by subjecting them to a constant uniform heat flux in the range 20-70 kW m-2 using a Cone Calorimeter and the ISO Ignitability Apparatus. The specimens were examined in the vertical and horizontal orientations in the Cone Calorimeter using gas flame pilot, spark pilot and spontaneous methods of ignition. They were also studied using the ISO Ignitability Apparatus in the normal and inverted horizontal orientations using gas flame pilot and spontaneous methods of ignition. The results obtained are compared by specimen, orientation and mode of ignition.
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    Fire and Materials 17 (1993), S. 103-110 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The rate of heat release from a thermally thin material burning on both sides will be more than twice the value seen when only one side is burning. Two simplified models demonstrate that this is a consequence of the Arrhenius temperature dependence of the gasification rate of the solid. Experiments carried out on three composite materials over a range of incident heat fluxes confirm this effect. It is inferred that a further consequence of this heat release enhancement is an increased tendency for concurrent flame spread in the two-sided burning case. Materials whose application could lead to two-sided burning should thus be assessed in this mode to obtain a true picture of their flammability potential.
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  • 87
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    Fire and Materials 17 (1993), S. 91-102 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Several -i-isocyanates have become commercially important materials, used as intermediates in the manufacture of a wide variety of polyurethane products, yet little is recorded on their behaviour if involved in fire. This paper describes a series of programmes carried out under the auspices of the International Isocyanate Institute Inc. First, a small-scale laboratory investigation of the ignition, heat release, smoke and toxic gas production characteristics of di-isocyanates was carried out. Second, their behaviour in drumstock and pool fires, respectively, was examined, using full-sized samples and selected real-fire scenarios. Part 1 records the results for toluene di- isocyanate (TDI) showing the need for a modest energy input to ignite it from a pilot flame. It then burns in a steady rather than vigorous manner, leaving no residues. Toxic gases evolved are mainly carbon monoxide, while free isocyanate is likely in the early stages of the fire, and hydrogen cyanide may be important in well-developed fires. Drumstock material behaviour in a fire is dictated mainly by the rupture characteristics of the containers, which can be violent. A series of simple guidelines is suggested, which includes the need for firefighters to wear full protective clothing and fresh-air breathing equipment. It is also recommended that drumstock TDI should be stored away from easily ignitable materials.
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  • 88
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    Fire and Materials 17 (1993), S. 111-117 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The flame height behavior of merged or inclined flames from two rectangular fire sources in a parallel configuration and from three and four circular pools of 120 mm diameter in a symmetrical configuration were studied experimentally. A rectangular gas diffusion burner, 20 mm × 400 mm or 20 mm × 800 mm was used as line fire sources. Propane gas gave 9.5-57 kW per meter for each burner. Hexane was utilized for the flame merging test using circular pool fires. The height of the flame tip when merged or inclined due to interaction of the flames and|or convective flow was estimated from picture analysis of 300 successive frames of video-recorded data. The flame extension behavior was expressed in dimensionless form as L/Lm = (fs)2/5 for square pool fires and L/Lm = (f1)2/3 for rectangular fires. The correction factors of fs and f1 are fs = (nD2 + S2) / n(D2 + S2) and f1 = (2DW + S2) / 2(DW + S2), respectively. When a rectangular or a circular fire source approaches the wall, the same correlation on flame extension behavior was obtained and simulated successfully considering an imaginary fire source inside a wall.
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  • 89
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    Fire and Materials 17 (1993), S. 119-123 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Wall-fire spread models require heat of gasification or non-dimensional heat of gasification to calculate mass loss rate or rate of heat release from the wall material. An intermediate scale rate of heat release apparatus was used to measure all the parameters needed to calculate non-dimensional heat of gasification for wood materials. An infra-red pyrometer was used to measure surface temperature. The results of measurements on six wood materials indicate that non-dimensional heat of gasification, if plotted against mass remaining, does not change significantly with external heat flux, but is material dependent.
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    Fire and Materials 17 (1993), S. 125-129 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The temperature distribution in the condensed and gas phase during combustion of polymer materials in fire tests was measured by means of thermography. It is shown that these data are very useful for mechanistic rationalization of the diagnostically poor, fail-pass rating of most of these tests. Preliminary data were obtained for polymer materials, fire retarded or not, burning in the widely used Glow Wire and UL 94 tests. It is shown that the relative fire hazard and test rating may depend strongly on the combustion parameter on which the rating is based. Furthermore, detailed data on temperature distribution are helpful in eliminating intrinsic ambiguity of the UL 94 classification in the case of fire-retarded materials burning with dripping.
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    Fire and Materials 17 (1993), S. 131-138 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The fast and precise transient hot-strip (THS) method is well suited for thermal conductivity measurements on solid materials. The THS method may, however, give large experimental errors when applied to thermally insulating materials of low heat capacity per unit volume. Models to deal with those potential error sources and some indications about the precautions to be taken in order to minimize them are described in the present work. Measurements of thermal conductivity of a styrofoam insulating material (thermal conductivity 0.036 W m-1K-1, density 25.4 kg m-3) was performed to verify the models. The result obtained is in good agreement with the standard hot plate method, indicating that the THS method is also well suited for thermal conductivity measurements of thermal insulators.
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  • 92
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    Fire and Materials 17 (1993), S. 145-145 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 93
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    Fire and Materials 17 (1993), S. 265-270 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper outlines the flammability test methods and requirements for electric cables specified in some Japanese standards. Only two different methods of a small-scale flame test as specified in Clause 28 of JIS C 3005 are applied to electric cables for general use, and whether or not the flammability test should be conducted and which method should be adopted depends on the type of cables, both of which are specified in each separate standard. Cables for electrical equipment of ships have to pass another small-scale flame test as prescribed in Section 6.7 of JIS C 3410. A flame test method for flame-retardant telecommunication cables has been introduced in JIS C 3521. This specifies a vertical open tray flame test on grouped cables, almost in accordance with IEEE Standard 383. In addition to the method for a vertical open tray flame test, one for a vertical closed duct flame test on grouped cables is also specified in a Japanese Cable Makers' Association Standard, i.e. JCS 366. Some flame-retardance requirements for electric cables in Japan are listed and discussed.
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    Fire and Materials 17 (1993), S. 279-292 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper reports an experimental study on the physical properties of a sprinkler water spray. The mass flux density, shape of spray pattern, size distribution and velocity of water droplets discharged from two types of 15 mm orifice sprinkler heads were measured. Three operating flow conditions of the sprinkler system, including one specified for the Ordinary Hazard class under the LPC rules for sprinkler design, were set. The sprinkler head was installed above finished floor levels of either 2 m or 2.2 m. The median droplet size was found to be related to the water pressure and the orifice diameter of the sprinkler head as proposed by Dundas. The droplet size distribution function can be fitted by a Rosin-Rammler function.
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  • 95
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    Fire and Materials 18 (1994) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Fire and Materials 17 (1993), S. 293-303 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A small-scale enclosure was constructed for characterizing the contribution of interior finish wall-lining materials to fire growth in compartments. The enclosure was based upon refinements to a design devised by scientists at the National Institute for Standards and Technology for quarter-scale modelling of room fire tests on interior-finish materials. A large volume of evidence is presented demonstrating how this small-scale enclosure could provide the information about surface flammability, heat release, smoke generation and contribution to fire growth that is required for a reasonable assessment of the fire performance of interior wall-finish materials.
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  • 97
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    Fire and Materials 18 (1994), S. 1-7 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Phospham is an iminophosphazene polymer of unusually high thermal stability. We have found that phospham imparts a substantial level of flame retardancy to nylon-4,6, a high-melting crystalline engineering thermoplastic. It did not appear to produce degradation of the polyamide in the processing temperature range. The flame retardant efficacy of phospham in nylon-4,6 was similar to that of stabilized red phosphorus, when compared on an equal phosphorus basis. In nylon-4,6, it did not display nitrogen-phosphorus synergism. Limited evidence from TGA suggested a condensed phase mode of action in nylon-4,6. Phospham showed orders-of-magnitude better hydrolytic stability than did ammonium polyphosphate, and did not produce detectable phosphine on processing as did red phosphorus.
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    Fire and Materials 18 (1994), S. 17-30 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The behaviour of polymeric diphenyl methane-4,4′-diisocyanate (PMDI) is described when examined in a laboratory small-scale test for its reaction to fire (ease of ignition; heat release and toxic gas production). Full-scale real fire scenarios have also been staged to predict events if (1) drumstock PMDI and (2) sizeable pools of liquid PMDI become enveloped in a fire. PMDI requires a stimulus (e.g. heat) before it will ignite from an applied flame. It then burns in a self-sustaining manner for a few minutes, during which main emissions take place. Then a polymerization reaction begins, producing a low density non-burning residue, which progressively dampens down the burning events by blanket action. Residues of 30-80% sample weight were recorded. The major toxic gas produced is carbon monoxide, though free isocyanate is to be expected in the early stages of the fire, and hydrogen cyanide could be important, especially in well-developed fire conditions. Firefighters should therefore wear full protective clothing and fresh-air breathing equipment. Events when drums of PMDI are exposed to fire depend heavily on the characteristics of the containers, with some rupture steps proceeding with considerable violence. Drumstock PMDI should be stored separately from easily ignitable materials.
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    Fire and Materials 18 (1994), S. 45-50 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A small-scale test series was carried out using the heating system (radiant exposure) of a cone calorimeter to detect any differences in the way different fibres affect the thermal properties of a standard mortar. The fibres were different polypropylene, polyacrylonitrile, aramide, carbon or steel. Fibres affect the release of moisture from the fibre mortar material. Local pressures caused by water vaporization due to rapid heating can be decreased by incorporating fibres. Fibres have a weak insulating effect. However, use of polyacrylonitrile fibres in mortar may increase the risk to spalling under rapid thermal exposure such as fire. The moisture level in specimens is highly significant for their thermal properties and hence their fire behavior.
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    Fire and Materials 18 (1994), S. 51-55 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Experimental investigations were made to assess the fire behaviour of rice husk particleboard, a potential substitute for wood particleboards. Releveant fire properties, namely non-combustibility, ignitability, fire propagation index, surface spread of flame classification, specific optical density of smoke generated, flammability and flame penetration were determined in accordance with existing standard methods. In this paper the salient results obtained are discussed.
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