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  • 04. Solid Earth::04.08. Volcanology::04.08.01. Gases  (11)
  • Electronics and Electrical Engineering
  • Fisheries
  • Industrial Chemistry
  • Inorganic Chemistry
  • Seismology
  • AGU  (13)
  • 2005-2009  (13)
  • 1950-1954
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  • 1
    Publication Date: 2021-06-07
    Description: Stromboli made in July 2002 from fixed positions, using an automated plume scanning technique. Spectral data were collected using a miniature ultraviolet spectrometer, and SO2 column amounts were derived with a differential optical absorption spectroscopy evaluation routine. Scanning through the plume was enabled by a 45 turning mirror affixed to the shaft of a computer controlled stepper motor, so that scattered skylight from incremental angles within the horizon-to-horizon scans was reflected into the field of view of the spectrometer. Each scan lasted _5 min and, by combining these data with wind speeds, average fluxes of 940, 14, and 280 Mg d_1 were obtained for Etna, Vulcano, and Stromboli, respectively. For comparative purposes, conventional road and airborne traverses were also made using this spectrometer, yielding fluxes of 850, 17, and 210 Mg d_1. The automated scanning technique has the advantage of obviating the need for time-consuming traverses underneath the plume and is well suited for longer-term telemetered deployments to provide sustained high time resolution flux data.
    Description: Gruppo Nazionale per Vulcanolgia (GNV), the EC 5th Framework project ‘‘MULTIMO’’, and NERC grant GR9/04655
    Description: Published
    Description: 2455
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: volcanic gas monitoring, remote sensing, SO2 emissions, DOAS,ultraviolet spectroscopy ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: Helium isotope ratios of olivine and pyroxene phenocrysts from Plio-Quaternary volcanic rocks from southern Italy (seven Aeolian Islands, Mt. Vulture, Etna, Ustica, and Pantelleria) range from 2.3 to 7.1 Ra. Importantly, the phenocryst 3He/4He correlate well with whole rock Sr isotopic composition (0.70309– 0.70711), reflecting the mixing of two sources. A significant contribution of He from crustal contamination is recorded only occasionally (e.g., pyroxenes from Vulcano). When merged with data from the Roman Comagmatic Province, a remarkably strong near-linear He-Sr isotope correlation is apparent. The general northward decrease in 3He/4He corresponds to an increase in 87Sr/86Sr (and a decrease in 143Nd/144Nd and 206Pb/204Pb) that is due to increasing metasomatic enrichment of the mantle wedge via subduction of the Ionian-Adriatic plate. Calculations based on the ingrowth of 4He in the wedge and on the 4He content of the subducting crust show that mechanisms of enrichment in radiogenic He are effective only if the wedge is strongly depleted in He relative to best estimates of the depleted mantle. This can be accommodated if the process of metasomatism by the subduction fluids depletes the mantle wedge. The 3He/4He of Pantelleria, Etna, Iblei, Ustica, Alicudi, and Filicudi basalts (7.0 ± 0.6 Ra) define the mantle composition least affected by subduction-related metasomatism. Although these volcanoes are from a variety of tectonic regimes (subduction-related, intraplate, rifting), their similarities suggest a common origin of geochemical features. Their characteristics are consistent with a HIMU-type mantle that either is younger than the Cook- Austral island end-member or has a lower 238U/204Pb.
    Description: Published
    Description: Q02001
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: helium ; strontium ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2017-04-04
    Description: Geochemical surveillance has been carried out at Stromboli since 1999 using discrete and continuous monitoring of thermal waters and soil degassing. On 27 February 2007 a new eruption began which lasted until 2 April; it was characterized by effusive activity on the Sciara del Fuoco and also by a paroxistic event (15 March). This crisis represented an opportunity to refine the model developed previously and to improve our understanding of the relationship between the magmatic dynamics of the volcano and geochemical variations. The main aim of this research was to evaluate the level of criticality of the volcanic activity. The SO2 fluxes of the degassing plume and the CO2 fluxes emitted from the soil at Pizzo Sopra la Fossa are herein presented. Furthermore, we propose a refined geochemical model of fluids circulation, including plume and summit fumarolic soil degassing. Noteworthy geochemical signals of volcanic unrest were also clearly identified (before, during and after the effusive activity) in the degassing plume as well as in the degassing from the soil at the summit.
    Description: Published
    Description: San Francisco, CA,USA
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: open
    Keywords: CO2 flux ; Stromboli volcano ; SO2 Flux ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 4
    Publication Date: 2017-04-04
    Description: The Total Volatile (TV) flux from Mount Etna volcano has been characterised for the first time, by summing the simultaneously-evaluated fluxes of the three main volcanogenic volatiles: H2O, CO2 and SO2.SO2 flux was determined by routine DOAS traverse measurements, while H2O and CO2 were evaluated by scaling MultiGAS-sensed H2O/SO2 and CO2/SO2 plume ratios to the UV-sensed SO2 flux. The time-averaged TV flux from Etna is evaluated at ~21,000 t∙day-1, with a large fraction accounted for by H2O(~13,000 t∙day-1). H2O dominates (≥70%) the volatile budget during syn-eruptive degassing, while CO2 and H2O contribute equally to the TV flux during passive degassing. The CO2 flux was observed to be particularly high prior to the 2006 eruption, suggesting that this parameter is a good candidate for eruption prediction at basaltic volcanoes.
    Description: Published
    Description: L24302
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: Active volcanoes ; Volcanic monitoring ; Gas ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2017-04-04
    Description: We investigated the gas geochemistry of fumaroles close to the Voragine crater of Mt Etna that have a temperature of 90–95 C, are CO2-dominated, and have an air content as low as 〈1%. This is the first report of the monitoring of such air-free fumaroles at the Etnean crater area—previous studies indicated an air contribution of 70% or more. The helium and carbon isotopes (Rc/Ra = 6.5 ± 0.4, d13CCO2 = 1.7 ± 0.5%) suggest that the released gas is directly related to the magmatic degassing. The fumaroles were sampled 12 times between June 2007 and June 2008, which revealed an increase in Rc/Ra from 6.1 to 6.9 that can be related to the increasing volcanic activity at the summit area of Mt Etna. These fumaroles offer a new tool for detecting magmatic processes (magma ascent, refilling, degassing, etc.), and will be useful for volcano surveillance.
    Description: Published
    Description: L21302
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: helium ; isotope ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2017-04-04
    Description: We report measurements of Hg, SO2, and halogens (HCl, HBr, HI) in volcanic gases from Masaya volcano, Nicaragua, and gaseous SO2 and halogens from Telica volcano, Nicaragua. Mercury measurements were made with a Lumex 915+ portable mercury vapor analyzer and gold traps, while halogens, CO2 and S species were monitored with a portable multi gas sensor and filter packs. Lumex Hg concentrations in the plume were consistently above background and ranged up to 350 ng/m3. Hg/SO2 mass ratios measured with the real-time instruments ranged from 1.1*10-7 to 3.5*10-5 (mean 2*10-5). Total gaseous mercury TGM)concentrations measured by gold trap ranged from 100 to 225 ng/m3. Reactive gaseous mercury accounted for 1% of TGM, while particulate mercury was 5% of the TGM. Field measurements of Masaya’s SO2 flux, combined with the Hg/SO2 ratio, indicate a Hg flux from Masaya of 7.2 Mg/a-1. At Masaya’s low temperature fumaroles, Hg/CO2 mass ratios were consistently around 2*10-8, lower than observed in the main vent (Hg/CO2 10-7). Low-temperature fumarole Hg fluxes from Masaya are insignificant (150 g a-1). Ratios of S, C and halogen species were also measured at Masaya and Telica volcanoes. CO2/SO2 ratios at Masaya ranged from 2.8 to 3.9, comparable to previously published values. At Masaya molar Br/SO2 was 3*10-4 and I/SO2 was 2*10-5, suggesting fluxes of 0.2–0.5 Mg HBr d-1 and 0.02–0.05 Mg HI d-1. At Telica the Br/SO2 ratio was also 3*10-4 and the I/SO2 ratio was 5.8*10-5, with corresponding fluxes of 0.2 Mg HBr d-1 and 0.06 Mg HI d-1. Gases at both volcanoes are enriched in I relative to Br and Cl, compared to gases from volcanoes elsewhere.
    Description: This work was funded by NERC grant NE/ C511180/1/.
    Description: Published
    Description: B06203
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Mercury ; Halogen ; Volcanic emissions ; Masaya volcano ; Telica volcano ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
    Publication Date: 2017-04-04
    Description: Ground-based thermal imaging is becoming an increasingly important tool for volcano surveillance, however the impact of volcanic plumes on quantitative measurements of surface temperature has not been previously evaluated. Here we use a radiative transfer model to simulate gas (primarily H2O and SO2) and aerosol absorptions over the path between a thermal camera and a heat source on Stromboli volcano, Italy. A FTIR spectrometer was used to quantify path amounts of gases likely to be encountered when making thermal measurements of the active craters. We find that when using a camera sensitive from 7.5 to 13 mm, underestimates of 400 K may be produced when viewing a source with an actual temperature of 1200 K. Cameras that operate between 3 and 5 mm are somewhat less susceptible to these errors.
    Description: Published
    Description: L14311
    Description: reserved
    Keywords: NONE ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
    Publication Date: 2017-04-04
    Description: Continuous soil radon monitoring was carried out near the Southeast Crater (SEC) of Mt. Etna during the 10-day July 2006 Strombolian-effusive eruption. This signal was compared with simultaneously acquired volcanic tremor and thermal radiance data. The onset of explosive activity and a lava fountaining episode were preceded by some hours with increases in radon soil emission by 4–5 orders of magnitude, which we interpret as precursors. Minor changes in eruptive behavior did not produce significant variations in the monitored parameters. The remarkably high radon concentrations we observed are unprecedented in the literature. We interpret peaks in radon activity as due primarily to microfracturing of uranium-bearing rock. These observations suggest that radon measurements in the summit area of Etna are strongly controlled by the state of stress within the volcano and demonstrate the usefulness of radon data acquisition before and during eruptions.
    Description: Published
    Description: L24316
    Description: reserved
    Keywords: NONE ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 9
    Publication Date: 2017-04-04
    Description: SO2 flux is widely monitored on active volcanoes as it gives a window into the hidden, subsurface magma dynamics. We present here a new approach to SO2 flux monitoring using ultraviolet imaging of the volcanic plume through carefully chosen filters to produce images of SO2 column amount. The SO2 camera heralds a breakthrough in both our ability to measure SO2 flux at unprecedented frequencies (2 Hz) and at unprecedented accuracy, thanks to the application of correlation techniques to determine wind speed directly from the images and the ability to measure the whole profile simultaneously. In this paper we detail the commercially available pieces required to construct the SO2 camera, introduce a retrieval scheme to determine SO2 amounts from the images and present results from a field campaign in November 2005 on Sakurajima volcano, Japan.
    Description: Published
    Description: L24804
    Description: reserved
    Keywords: NONE ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 10
    Publication Date: 2017-04-04
    Description: Measurements of 220Rn and 222Rn activity and of CO2 flux in soil and fumaroles were carried out on Mount Etna volcano in 2005–2006, both in its summit area and along active faults on its flanks. We observe an empirical relationship between (220Rn/222Rn) and CO2 efflux. The higher the flux of CO2, the lower the ratio between 220Rn and 222Rn. Deep sources of gas are characterized by high 222Rn activity and high CO2 efflux, whereas shallow sources are indicated by high 220Rn activity and relatively low CO2 efflux. Excess 220Rn highlights sites of ongoing shallow rock fracturing that could be affected by collapse, as in the case of the rim of an active vent. Depletion both in 220Rn and in CO2 seems to be representative of residual degassing along recently active eruptive vents.
    Description: Published
    Description: Q10001
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: radon ; thoron ; carbon dioxide ; rock stress ; gas transport ; Mount Etna ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 11
    Publication Date: 2023-01-19
    Description: Bromine monoxide (BrO) and sulphur dioxide (SO2) abundances as a function of the distance from the source were measured by ground-based scattered-light Multi AXis Differential Optical Absorption Spectroscopy (MAX-DOAS) in the volcanic plumes of Mt. Etna on Sicily, Italy in August-October 2004 and May 2005 and Villarica in Chile in November 2004. BrO and SO2 spatial distributions in a cross section of Mt. Etna’s plume were also determined by Imaging DOAS. We observed an increase in the BrO/SO2 ratio in the plume from below the detection limit near the vent to about 4.5 x 10-4 at 19 km (Mt. Etna) and to about 1.3 x 10-4 at 3 km (Villarica) distance, respectively. Additional attempts were undertaken to evaluate the compositions of individual vents on Mt. Etna. Furthermore, we detected the halogen species ClO and OClO. This is the first time that OClO could be detected in a volcanic plume. Using calculated thermodynamic equilibrium compositions as input data for a one–dimensional photochemical model, we could reproduce the observed BrO and SO2 vertical columns in the plume and their ratio as function of distance from the volcano as well as vertical BrO and SO2 profiles across the plume with current knowledge of multiphase halogen chemistry, but only when we assumed the existence of an ”effective source region”, where volcanic volatiles and ambient air are mixed at about 600°C (in the proportions of 60% and 40%, respectively)
    Description: Published
    Description: D06311
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Description: open
    Keywords: Chemistry ; Volcanic Plumes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 12
    Publication Date: 2017-04-04
    Description: A correlation has been recently found between large earthquakes and the succeeding largest 9 explosive eruptions of the last century, which has been interpreted as a product of co- and post-seismic stress diffusion. Here, we check the statistical significance of the proposed coupling by using a larger dataset, and investigate the reliability of the causality hypothesis. We find that the volcanoes with VEI ≥ 4 eruptions underwent, in the few decades before the volcanic event, higher seismic stress perturbations due to large earthquakes compared to other volcanic areas. The correlation is statistically significant and it is not explained by a spatio-temporal clustering of eruptions and earthquakes due to tectonic pulses. This implies that the large earthquakes indeed triggered the eruptions.
    Description: Gruppo Nazionale di Vulcanologia and e-Ruption projects
    Description: Published
    Description: reserved
    Keywords: Volcanology ; Eruption mechanisms ; Seismology ; Volcano seismology ; Tectonophysics ; Stresses - general ; 05. General::05.01. Computational geophysics::05.01.04. Statistical analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 13
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    AGU
    In:  Washington, D.C., 280 pages, AGU, vol. 81A and 81B, no. 22, pp. 65-70, (ISBN 0-87590-422-X)
    Publication Date: 2005
    Keywords: Seismology ; Seismic arrays ; Data analysis / ~ processing ; Ray seismics ; Synthetic seismograms ; Modelling ; Wave propagation ; Waves ; Earth model, also for more shallow analyses ! ; Physical properties of rocks ; Broad-band
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