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  • 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks  (28)
  • 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases  (15)
  • Elsevier  (42)
  • American Meteorological Society
  • 2005-2009  (42)
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  • 1
    Publication Date: 2020-10-29
    Description: Two sets of cooling experiments were run at atmospheric conditions for two anhydrous starting latitic and trachytic melts: 1) five cooling rates (25, 12.5, 3, 0.5, and 0.125 °C/min) between 1300° and 800 °C, and 2) a 11 0.5 °C/min cooling rate from 1300 °C with quench temperatures at 1200°, 1100°, 1000° and 900 °C. Trachytic run-products are invariably glassy. Nucleation is also suppressed in the latitic run-products at the three highest 13 cooling rates. Conversely, in the 0.5 and 0.125 °C/min runs, latites have a crystal content of 90 vol.%. The 14 phases are: plagioclase, clinopyroxene, glass and iron-bearing oxide (in order of abundance). The variable 15 quench temperatures, investigated by coupling experiments with Pt-wire and Pt- capsule sample containers inset 2,again did not produce crystallization of trachyte, whereas latitic samples are characterized by 10 vol.% of oxides, pyroxenes and plagioclase (in order of appearance), at temperature b1000 °C. Effects of (preferential) heterogeneous nucleation on sample holders, of superheating degree, and chemical species loss during cooling are absent for both melt compositions. The difference of solidification paths between these two silicate melts can be ascribed only to their small chemical differences. In comparison with calculated equilibrium conditions all the experimental latitic and trachytic run-products revealed strong kinetic effects, interpretable in the light of the nucleation theory. The glass- forming ability (GFA) of trachyte is higher, whereas their critical cooling rate (Rc) is lower (b0.125 °C/min), in comparison to latitic melts (RcN0.5 °C/min). The experimental results carried out in this study can be applied to lava flows and domes; trachytic lavas are able to flow for longer period with respect to latitic ones in a metastable condition. Glass-rich terrestrial lavas, i.e. obsidians, can be the result of sluggish nucleation kinetics due to the relative high polymerisation of evolved silicate melts.
    Description: Published
    Description: 91-101
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: crystallization ; lava flows ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.02. Seismological data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 2
    Publication Date: 2020-11-26
    Description: During the July^August 2001 eruption of Mt. Etna development of extensional fractures/faults and grabens accompanied magma intrusion and subsequent volcanic activity. During the first days of the eruption, we performed an analysis of attitude, displacement and propagation of fractures and faults exposed on the ground surface in two sites, Torre del Filosofo and Valle del Leone, located along the same fracture system in the region surrounding the Valle del Bove depression on the eastern flank of Mt. Etna. Fractures and faults formed as the consequence of a shallow intruding dyke system that fed the several volcanic centres developed along the fracture system. The investigated sites differ in slope attitude and in geometrical relationships between fractures and slopes. In particular, the fracture system propagated parallel to the gentle slope (67‡ dip) in the Torre del Filosofo area, and perpendicular to the steep slope (V25‡ dip) in the Valle del Leone area. In the Torre del Filosofo area, slight graben subsidence and horizontal extension of the ground surface by about 3 m were recorded. In the Valle del Leone area, extensional faulting forming a larger and deeper graben with horizontal extension of the ground surface by about 10 m was recorded. For the Valle del Leone area, we assessed a downhill dip of 14‡ for the graben master fault at the structural level beneath the graben where the fault dip shallows. These results suggest that dyke intrusion at Mount Etna, and particularly in the region surrounding the Valle del Bove depression, may be at the origin of slope failure and subsequent slumps where boundary conditions, i.e. geometry of dyke, slope dip and initial shear stress, amongst others, favour incipient failures.
    Description: Published
    Description: 281-294
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: dykes ; extensional fractures ; grabens ; slope failures ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 3
    Publication Date: 2020-12-03
    Description: A study of the He isotopic ratios of fluid inclusions in olivine and pyroxene from the Roman Comagmatic Province (RCP),Italy, is presented together with 87Sr/86Sr isotope compositions of the whole rock or pyroxene phenocrysts. A clear covariation in He and Sr isotopes is apparent, with a strong northward increase in radiogenic He and Sr being evident. He and Sr isotopes ratios range from 3He/4He = 5.2 Ra and 87Sr/86Sr = 0.7056 in south Campania, to 3He/4He = 0.44 Ra and 87Sr/86Sr = 0.715905 in the northernmost Latium. Helium isotope ratios are significantly lower than MORB values and are among the lowest yet measured in subduction zone volcanism. The 3He/4He of olivine and pyroxene phenocryst-hosted volatiles appear to be little influenced by posteruptive processes and magma–crust interaction. The 3He/4He–87Sr/86Sr covariation is consistent with binary mixing between an asthenospheric mantle similar to HIMU ocean island basalts, and an enriched (radiogenic) mantle end member generated from subduction of the Ionian/Adriatic plate. The contribution of radiogenic He from metasomatic fluids and postmetasomatism radiogenic ingrowth in the wedge is strongly dependent on the initial He concentration of the mantle. Only when asthenosphere He concentrations are substantially lower than the MORB source mantle, and metasomatism occurred at the beginning of the subduction (f30 Ma), can ingrowth in the mantle wedge account for the 3He/4He of the most radiogenic basalts.
    Description: - European Social Fund - Scottish Universities - Carnegie Trust for the Universities of Scotland.
    Description: Published
    Description: 295–308
    Description: partially_open
    Keywords: Roman Comagmatic Province ; fluid inclusions ; helium ; strontium ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes ; 04. Solid Earth::04.07. Tectonophysics::04.07.08. Volcanic arcs ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 4
    Publication Date: 2021-06-15
    Description: Public works in progress in the Campanian plain north of Somma-Vesuvius recently encountered the remains of a prehistoric settlement close to the town of Afragola. Rescue excavations brought to light a Bronze Age village partially destroyed and buried by pyroclastic density currents (PDCs) of the Vesuvian Pomici di Avellino eruption (3.8 14C ka BP) and subsequently sealed by alluvial deposits. Volcanological and rockmagnetic investigations supplemented the excavations. Careful comparison between volcanological and archaeological stratigraphies led to an understanding of the timing of the damage the buildings suffered when they were struck by a series of PDCs. The first engulfed the village, located some 14 km to the north of the inferred vent, and penetrated into the dwellings without causing major damage. The buildings were able to withstand the weak dynamic pressure of the currents and deviate their path, as shown by the magnetic fabric analyses. Some later collapsed under the load of the deposits piled up by successive currents. Stepwise demagnetization of the thermal remanent magnetization (TRM) carried by potsherds embedded in the deposits yields deposition temperatures in the order of 260– 320 °C, fully consistent with those derived from pottery and lithic fragments from other distal and proximal sites. The fairly uniform temperature of the deposits is here ascribed to the lack of pervasive air entrainment into the currents. This, in turn, resulted from the lack of major topographical obstacles along the flat plain. The coupling of structural damage and sedimentological analyses indicates that the currents were not destructive in the Afragola area, but TRM data indicate they were still hot enough to cause death or severe injury to humans and animals. The successful escape of the entire population is apparent from the lack of human remains and from thousands of human footprints on the surface of the deposits left by the first PDCs. People were thus able to walk barefoot across the already emplaced deposits and escape the subsequent PDCs. The rapid cooling of the deposits was probably due to both their thinness and heat dissipation due to condensation of water vapour released in the mixture by magma–water interaction.
    Description: Published
    Description: 408–421
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: pyroclastic density current ; Bronze Age ; magnetic fabric ; deposition temperature ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.07. Rock magnetism ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 5
    Publication Date: 2020-12-17
    Description: The Neapolitan Yellow Tuff (NYT) is the product of the largest known trachytic phreatoplinian eruption. It covered an area larger than 1000 km2 with an estimated volume of about 40 km3 of erupted magma. During the course of the eruption a caldera collapsed within the previously formed Campanian Ignimbrite caldera. The resulting nested structure strongly influenced the following volcanic activity in the Campi Flegrei caldera. As previous dating of the NYT does not converge toward a unique result, a new set of 40Ar/39Ar age determinations has been carried out to better constrain the age of the eruption. Two variants of the 40Ar/39Ar dating method were applied to determine the age of the NYT eruption: (1) single-crystal total fusion (SCTF), on an individual phenocryst of feldspar, and (2) laser incremental heating (LIH), on bulk aliquots of feldspar phenocrysts. The results of the SCTF analyses show that the overall sample weighted mean age, derived from the conventional age calculation, is 15.6 ;0.8 ka. A weighted mean of the isochron age is 15.3 ;1.2 ka (2c), and has been assumed as the best indicator of age to be derived from the SCTF analyses. The LIH analyses results show that plateau ages vary from 15.4; 0.5 to 14.5; 0.5 ka. The overall weighted mean age of the isochron results is 14.9;0.4 ka (2c). This result has been assumed as the reference age for the NYT eruption, and agrees with the SCTF age. The new age obtained for the NYT deposits is of great relevance for the understanding of the evolution and the present state of the Campi Flegrei caldera and collocates the NYT in a crucial stratigraphical position to date the climatic oscillations that occurred between the Late Glacial and the Holocene.
    Description: Published
    Description: 157-170
    Description: partially_open
    Keywords: Neapolitan Yellow Tuff ; Campi Flegrei caldera ; 40Ar/39Ar dating method ; Geochronology ; Late Glacial ; Holocene ; 04. Solid Earth::04.04. Geology::04.04.02. Geochronology ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 6
    Publication Date: 2021-05-17
    Description: Papandayan is a stratovolcano situated in West Java, Indonesia. Since the last magmatic eruption in 1772,only few hydrothermal explosions have occurred. An explosive eruption occurred in November 2002 and ejected ash and altered rocks. The altered rocks show that an advanced argillic alteration took place in the hydrothermal system by interaction between acid fluids and rocks. Four zones of alteration have been defined and are limited in extension and shape along faults or across permeable structures at different levels beneath the active crater of the volcano. At the present time, the activity is centered in the northeast crater with discharge of low temperature fumaroles and acid hot springs. Two types of acid fluids are emitted in the crater of Papandayan volcano: (1) acid sulfate-chloride waters with pH between 1.6 and 4.6 and (2) acid sulfate waters with pH between 1.2 and 2.5. The water samples collected after the eruption on January 2003 reveal an increase in the SO4/Cl and Mg/Cl ratios. This evolution is likely explained by an increase in the neutralization of acid fluids and tends to show that water–rock interactions were more significant after the eruption. The evolution in the chemistry observed since 2003 is the consequence of the opening of new fractures at depth where unaltered (or less altered) volcanic rocks were in contact with the ascending acid waters. The high δ34S values (9–17‰) observed in acid sulfatechloride waters before the November 2002 eruption suggest that a significant fraction of dissolved sulfates was formed by the disproportionation of magmatic SO2. On the other hand, the low δ34S (−0.3–7‰) observed in hot spring waters sampled after the eruption suggest that the hydrothermal contribution (i.e. the surficial oxidation of hydrogen sulfide) has increased.
    Description: Published
    Description: 276-286
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: Papandayan volcano ; Indonesia ; phreatic eruption ; hydrothermal system ; fluid geochemistry ; advanced argillic alteration ; gas geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 7
    Publication Date: 2021-06-25
    Description: We report in this paper a systematic investigation of the chemical and isotopic composition of groundwaters flowing in the volcanic aquifer of Mt. Vesuvius during its current phase of dormancy, including the first data on dissolved helium isotope composition and tritium content. The relevant results on dissolved He and C presented in this paper reveal that an extensive interaction between rising magmatic volatiles and groundwaters currently takes place at Vesuvius. Vesuvius groundwaters are dilute (mean TDS 2800 mg/L) hypothermal fluids (mean T 17.7°C) with a prevalent alkaline-bicarbonate composition. Calcium-bicarbonate groundwaters normally occur on the surrounding Campanian Plain, likely recharged from the Apennines. D and 18O data evidence an essentially meteoric origin of Vesuvius groundwaters, the contribution from either Tyrrhenian seawater or 18O-enriched thermal water appearing to be small or negligible. However, the dissolution of CO2-rich gases at depth promotes acid alteration and isochemical leaching of the permeable volcanic rocks, which explains the generally low pH and high total carbon content of waters. Attainment of chemical equilibrium between the rock and the weathering solutions is prevented by commonly low temperature (10 to 28°C) and acid-reducing conditions. The chemical and isotope (C and He) composition of dissolved gases highlights the magmatic origin of the gas phase feeding the aquifer. We show that although the pristine magmatic composition may vary upon gas ascent because of either dilution by a soil-atmospheric component or fractionation processes during interaction with the aquifer, both 13C/12C and 3He/4He measurements indicate the contribution of a magmatic component with a 13C 0‰ and R/Ra of 2.7, which is consistent with data from Vesuvius fumaroles and phenocryst melt inclusions in olivine phenocrysts. A main control of tectonics on gas ascent is revealed by data presented in this paper. For example, two areas of high CO2 release and enhanced rock leaching are recognized on the western (Torre del Greco) and southwestern (Torre Annunziata–Pompeii) flanks of Vesuvius, where important NE-SW and NW-SE tectonic structures are recognized. In contrast, waters flowing through the northern sector of the volcano are generally colder, less saline, and CO2 depleted, despite in some cases containing significant concentrations of magmaderived helium. The remarkable differences among the various sectors of the volcano are reconciled in a geochemical interpretative model, which is consistent with recent structural and geophysical evidences on the structure of Somma-Vesuvius volcanic complex.
    Description: -European Union, -Ministero dell’Universita’ e della Ricerca Scientifica e Tecnologica; -CNR–Gruppo Nazionale per la Vulcanologia.
    Description: Published
    Description: 963–981
    Description: partially_open
    Keywords: isotopes ; water chemistry ; dissolved gases ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 8
    Publication Date: 2020-11-17
    Description: Recent seismic swarms and hydrothermal activity suggest that the Quaternary volcanic complex of the Alban Hills may pose a threat to the city of Rome. A 350m scientific borehole was therefore drilled into this volcanic area to elucidate its inner structure for the first time. Wire-line logs were run in the borehole in order to characterize the physical properties of the rocks and their variations with depth. In particular, a detailed sonic log was run to measure the P-wave velocity from the well-head down to 110 m. To further investigate velocity changes, we carried out laboratory measurements of P and S elastic wave velocities and fluid permeability at effective pressures up to 70 MPa during both increasing and decreasing pressure cycles on selected core samples representative of the main volcanic units. Specifically, we studied samples from two pyroclastic units representative of two classes of volcanic deposits that are representative of the whole succession: (i) a coarse-grained, well-lithified facies (Pozzolane Rosse unit), containing abundant mm-to-cm lava clasts and crystals; and (ii) a fine-grained, matrix-supported pyroclastic deposit (Tufo Pisolitico di Trigoria unit), with rare lithic lava clasts and sparse pumice. Elastic wave velocities reveal significant differences between units and indicate how, within the same lithology, the different degree of lithification and presence of clasts can affect significantly physical property values. The mean laboratory value of the Pwave velocity for Pozzolane Rosse and Tufo Pisolitico di Trigoria units is respectively of 3.75 and 3.2 km/s at an effective pressure equivalent to that at the depth at which the sonic velocity was measured. Under increasing effective pressure a profound influence on the transport properties is observed. Permeability ranges from the order of 10−18 m2 for the Pozzolane Rosse unit to the order of 10−15 m2 for the Tufo Pisolitico di Trigoria unit, in good agreement with the shallow aquifer circulating in the shallower units.
    Description: Published
    Description: 161-169
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: Scientific borehole ; Volcanic rocks ; Physical properties ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 9
    Publication Date: 2020-11-16
    Description: Volcanic edifices, such as Mt. Etna (Italy), are commonly subject to repeated cycles of stress over time due to the combination of magma emplacement from deep reservoirs to shallow depths and superimposed tectonic stresses. Such repeated stress cycles lead to anisotropic deformation and an increase in the level of crack damage within the rocks of the edifice and hence changes to their elastic moduli, which are a key parameter for reliable modelling of deformation sources. We therefore report results of changes in elastic moduli measured during increasing amplitude cyclic stressing experiments on dry and water-saturated samples of Etna basalt. In all experiments, the Young’s modulus decreased by approximately 30% over the total sequence of loading cycles, and the Poisson’s ratio increased by a factor of approximately 3 ± 0.5. Microseismicity, in terms of acoustic emission (AE) output, was also recorded throughout each experiment. Our results demonstrate that AE output only re-commences during any loading cycle when the level of stress where AE ceased during the unloading portion of the previous cycle is exceeded; a manifestation of the Kaiser stress-memory effect. In cycles where no AE output is generated, we also observe no change in elastic moduli. This result is observed for both mechanical and thermal stressing. Our results are interpreted in relation to measurements of volcano-tectonic seismicity and deformation at Mt. Etna volcano.
    Description: Published
    Description: 153-160
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: rock mechanics, elastic moduli, Etna basalt ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 10
    Publication Date: 2017-04-04
    Description: This work presents the results of hydrogeochemical studies carried out at Vesuvius during the period May 1998 - December 2001, mostly focusing on compositional time variations observed during this time. Based on their chemistry, groundwater samples are distinguished into two groups, 1 and 2, representative of water circulation in the southern and northern sectors of the volcano, respectively. Waters from group 1 are typically more acidic, warmer,and more saline than those of group 2. They also have higher CO2 and CH4 contents, attributed to enhanced input of deep-rising volatiles and prolonged water-rock interactions. Time-series highlight the fairly constant chemical composition of the entire aquifer. Groundwater temperature, pH, bicarbonate content and dissolved CO2 display quite stable values in the study period, particularly in deep wells (piezometric level more than 100 m deep). Shallower water bodies present more evident temporal variations, related to seasonal and anthropogenic effects. This paper also describes some important variations in water chemistry which had occurred by the time of the seismic event in early October 1999, particularly in the Olivella spring located on the northern flank of the volcano. At this site, a great decrease in water pH and redox potential, and increased dissolved CO2 contents and 3He/4He ratios were observed. These changes in chemical and isotope composition support the hypothesis of an input of magma-derived helium and carbon dioxide into the aquifer feeding the Olivella spring by the time of the earthquake.
    Description: Published
    Description: 81-104
    Description: partially_open
    Keywords: Vesuvius ; volcanic surveillance ; groundwater ; hydro-geochemistry ; oxygen-18 ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 11
    Publication Date: 2017-04-04
    Description: In order to improve the microscopic understanding of the water-magma interaction process during explosive volcanism,volcanic glasses representative of deposits with sedimentological characteristics suggesting different water/melt ratios were studied by a combination of the nuclear magnetic resonance (NMR) and TIMS methods. The glasses were separated from pumices of two surge layers and one fallout bed of the Cretaio Tephra (Ischia Island,Italy), which is the product of an explosive eruption that occurred at Ischia in the second century BC. The 29Si CP^MAS NMR experiments indicate the occurrence of 1H^29Si dipolar couplings in glasses from the phreatomagmatic activity, suggesting the presence of hydrogen atoms in proximity of silicon atoms. This feature is not detected in the glass from the deposit of the magmatic explosion. 1H MAS NMR spectra reveal different peaks attributed to different hydrous species characterized by different motional properties. These include ‘rigid’ H2O groups isolated in the glass structure, more mobile water species and possibly structural hydroxyl groups. 1H MAS NMR spectra recorded after deuteration experiments of the glass at a temperature up to 300‡C revealed that the exchange reactions of the D2O vapor with hydrogen were limited to the most mobile water species,possibly on vesicle surfaces or in channels. The hydrogen concentration linearly correlates with the 87Sr/86Sr isotope ratio in glasses,suggesting isotopic tracer exchanges between the Sr dissolved in the water vapor and the Sr in the silicon-oxygen network during hydration. It is proposed that the uprising melt interacted with a hydrothermal system of seawater-derived fluids,characterized by relatively high Sr isotopic composition.
    Description: Published
    Description: 311-320
    Description: partially_open
    Keywords: Ischia ; Cretaio Tephra ; Water-melt interaction ; Nuclear magnetic resonance ; Sr isotopes ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 12
    Publication Date: 2017-04-04
    Description: New major and trace element analyses and Sr-isotope determinations of rocks from Mt. Somma–Vesuvius volcano produced from 25 ky BP to 1944 AD are part of an extensive database documenting the geochemical evolution of this classic region. Volcanic rocks include silica undersaturated, potassic and ultrapotassic lavas and tephras characterized by variable mineralogy and different crystal abundance, as well as by wide ranges of trace element contents and a wide span of initial Sr-isotopic compositions. Both the degree of undersaturation in silica and the crystal content increase through time, being higher in rocks produced after the eruption at 472 AD (Pollena eruption). Compositional variations have been generally thought to reflect contributions from diverse types of mantle and crust. Magma mixing is commonly invoked as a fundamental process affecting the magmas, in addition to crystal fractionation. Our assessment of geochemical and Srisotopic data indicates that compositional variability also reflects the influence of crustal contamination during magma evolution during upward migration to shallow crustal levels and/or by entrapment of crystal mush generated during previous magma storage in the crust. Using a variant of the assimilation fractional crystallization model (Energy Conservation– Assimilation Fractional Crystallization; [Spera and Bohrson, 2001. Energy-constrained open-system magmatic processes I: General model and energy-constrained assimilation and fractional crystallization (EC–AFC) formulation. J. Petrol. 999– 1018]; [Bohrson, W.A. and Spera, F.J., 2001. Energy-constrained open-system magmatic process II: application of energyconstrained assimilation–fractional crystallization (EC–AFC) model to magmatic systems. J. Petrol. 1019–1041]) we estimated the contributions from the crust and suggest that contamination by carbonate rocks that underlie the volcano (2 km down to 9–10 km) is a fundamental process controlling magma compositions at Mt. Somma–Vesuvius in the last 8 ky BP. Contamination in the mid- to upper crust occurred repeatedly, after the magma chamber waxed with influx of new mantle- and crustal-derived magmas and fluids, and waned as a result of magma withdrawal and production of large and energetic plinian and subplinian eruptions.
    Description: Published
    Description: 303– 329
    Description: reserved
    Keywords: Mt. Somma–Vesuvius volcano ; Sr isotopes ; Geochemistry ; Crustal contamination ; Mantle source ; Phenocryst entrapment ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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    Type: article
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  • 13
    Publication Date: 2017-04-04
    Description: This paper presents and discusses the measurement of permeability of Neapolitan Yellow Tuff (NYT) samples obtained in the framework of a study concerning the phenomenon of bradyseism, i.e. the slow vertical movement of soil, in the Campi Flegrei caldera (Campania—Italy). Measurements have been performed under isothermal, non-isothermal and transient non-isothermal conditions using a specifically designed apparatus. Results of measurements of porosity of different samples are also reported. Experimental results in isothermal conditions show that the volume flux through the samples changes linearly with applied pressure. The values of permeability obtained turn out to be independent of the temperature and pressure gradients applied to the samples. This result is consistent with the fact that the permeability is a characteristic of the porous medium, and as such is not affected by temperature and pressure variation, at least in the range examined. The permeability values measured in our laboratories agree quite well with the ones measured in situ by the Agenzia Generale Italiana Petroli (AGIP) during a geothermal exploration of the Campi Flegrei area in 1980. An interesting, still unexplained phenomenon has been detected during transient phases when both pressure and temperature gradients were applied to the samples. The phenomenon consists in an enhancement of volume flux due to heat flux in the transient phase. The extra volume-flux disappears once the steady temperature gradient is reached.
    Description: Published
    Description: 125-136
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: Campi Flegrei ; hydrothermal systems; ; resurgent calderas ; porous media ; hydraulic permeability ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 14
    Publication Date: 2017-04-04
    Description: The October 17 to November 5, 1999, eruption of Mount Etna’s Bocca Nuova crater emplaced a V15U106 m3 flow field. The eruption was characterized by 11 paroxysmal events during which intense Strombolian and lava fountain activity fed vigorous channelized PaPa flows at eruption rates of up to 120 m3 s31. Each paroxysm lasted between 75 and 450 min, and was separated by periods of less intense Strombolian activity and less vigorous (610 m3 s31) effusion. Ground-based, satellite- and model-derived volumetric data show that the eruption was characterized by two periods during which eruption rates and cumulative volume showed exponential decay. This is consistent with a scenario whereby the system was depressurized during the first eruptive period (October 17^23), repressurized during an October 24 pause, and then depressurized again during the second period (October 25^28). The imbalance between the erupted and supplied volumes mean that the two periods involved the collection of 1.5^5.7U106 m3 and 1.2^ 3.6U106 m3, respectively, or an increase in the time-averaged supply to 11.6^13.6 m3 s31 and 12.5^14.9 m3 s31. Two models are consistent with the observed episodic fountaining, derived volumetric trends and calculated volume imbalance: a magma collection model and a pulsed supply model. In the former case, depressurization of a shallow reservoir cause the observed volumetric trends and foam collapse at the reservoir roof powers fountaining. In the pulsing case, variations in magma flux account for pressurization^depressurization and supply the excess volume. Increases in rise rate and volatile flux, coupled with rapid exsolution during ascent, trigger fountaining. Limiting equations that define critical foam layer volumes and magma rise rates necessary for Hawaiian-style fountaining favor the latter model.
    Description: Published
    Description: 79-95
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Etna ; lava fountaining ; eruption rates ; lava channel ; foam layers ; rise rates ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.02. Exploration geophysics::04.02.05. Downhole, radioactivity, remote sensing, and other methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.07. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 15
    Publication Date: 2017-04-04
    Description: The Albano Lake is the deepest volcanic lake in Italy (−167 m) and fills the youngest maar of the quiescent Colli Albani volcano. The lake has undergone significant level changes and lahar generating overflows occurred about 5800 yrs B.P. and likely in 398 b.C., when Romans excavated a tunnel drain through the maar wall. Hazardous lake rollovers and CO2 release are still possible because the Albano volcano shows active ground deformation, gas emission and periodic seismic swarms. On November 2005, the first high resolution bathymetric survey of the Albano Lake was performed. Here we present the results provided by a Digital Elevation Model and 2-D and 3-D images of the crater lake floor, which is made by coalescent and partly overlapping craters and wide flat surfaces separated by some evident scarps. Submerged shorelines are identified at depths between −20 m and −41 m and indicate the occurrence of significant lake level changes, likely between 7.1 and 4.1 ka. The current lake volume is ~447.5×106 m3 and the total quantity of dissolved CO2 is 6850 t estimated by chemical analyses of samples collected on May 2006. A decrease of nearly one order of magnitude of the CO2 dissolved in the lake water below −120 m, observed from December 1997 to May 2006 (from 4190 to 465 t respectively), has been attributed to lake water overturn. The observed oscillations of the dissolved CO2 concentrations justify the efforts of monitoring the chemical and physical characteristics of the lake. At present the quantity of dissolved CO2 is very far from saturation and Nyostype events cannot presently occur.
    Description: DPC-INGV Project V3_1
    Description: Published
    Description: 258–268
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Albano maar ; lake bathymetry ; geochemistry ; crater lake hazard ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 16
    Publication Date: 2017-04-04
    Description: On 27 February 2007, at 12.49 GMT, a new eruption of Stromboli took place with the effusion of a lava flow from a fracture cutting the flank of the NE cone, which rapidly reached the sea. The eruption had been heralded by an increase in the amplitude of tremor and flank movement since at least the 14th of February. Short-term precursors were an increase in the rate of occurrence of small landslides within the “Sciara del Fuoco” scar on the North-western flank of the volcano. A new effusive vent opened at 18.30 GMT on the Sciara del Fuoco at an height of 400 m asl. The new lava emission caused the sudden termination of the summit flow and initiated a period of non-stationary lava outpouring which ended on 2 April, 2007. The eruption has been characterized by a rapid decrease in the eruption rate after the first days and subsequently by episodic pulse increases. On the 15th of March, the increase in lava outpouring, monitored by a thermal camera, heralded by 9 min the occurrence of a violent paroxysmal explosion with the formation of an impulsive eruption column and the emission of small pumices mingled with black scoriae. The pumice had a bulk composition similar to that of the lava and of the black scoriae, but with a distinct lower content of phenocrysts. A similar feature has been repeatedly observed during the major explosive paroxysms of Stromboli. Short term precursors of the paroxysm were recorded by strainmeter and tiltmeter stations. The volcano monitoring activity has been made by a joint team of researchers from the INGV sections of Catania, Napoli, Palermo and Rome, along with researchers from the Universities of Florence, Pisa, Roma Tre, and Palermo. The scientific activity was coordinated by a Synthesis Group made up by scientists responsible for the different monitoring techniques of INGV and Universities and by the volcanic experts of Commissione Nazionale Grandi Rischi of the Prime Minister Office (Civil Protection Department). The group made a daily evaluation of the state of the volcano and transmitted its recommendations to the Civil Protection Department (DPC). Several prevention measures were adopted by DPC, the main of which were the evacuation of the coast zone when strong acceleration of the Sciara del Fuoco slope motion (occurred twice) could led to a dangerous tsunami by flank collapse (as last occurred on 30 December 2002) and four days before the 15 March paroxysm when access was prohibited to the part of the volcano above 290 m asl.
    Description: Published
    Description: 123–130
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: reserved
    Keywords: Stromboli volcano ; 2007 eruption ; scientific emergency management ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 17
    Publication Date: 2017-04-04
    Description: The cataclysmic 18 May 1980 eruption at Mount St. Helens was preceded by intense seismic activity marking the mechanical response of the volcanic edifice to interior pressurisation. This seismicity is analysed to yield the temporal change in the seismic scaling exponent, D, inferred from the seismic b-value, that in-turn is related to the seismic moment of an earthquake. Time evolution of D preceding the eruption onset reveals: (1) a major decrease in D occurring over only a few days at the end of March; (2) a steady but stepped decrease in D (steps ~5–10 days) occurring from the end of March to early May; (3) a sharp decrease in D in early May; and (4) steady low values of D occurring 2–3 days before the eruption onset. This response is interpreted as major ruptures, formed at the end of March, arresting and participating in, but not triggering the ultimate failure of the flank. Rather, the rate of interior fracturing slowed in the 2 months preceding the 18 May 1980 major blast, and the triggering of failure is consistent with interior gas overpressurisation. The occurrence of two swarms of low frequency seismic events and the high values of the harmonic tremor indicate the action of interior pressurisation on a cycle of 20–25 days. Solutions are applied to represent the harmonic interior pressurisation of the edifice by gas exsolving from the volcano core. The transient radial migration of overpressured gas may reduce the apparent strength of the edifice, and ultimately trigger failure of the flank. Importantly, this mechanism is capable of triggering flank failure both after multiple core pressurisation cycles have been sustained, and as core pressures are low and diminishing—and may be a minimum. These twin attributes are both apparent in the seismic record for Mount St. Helens, used as a proxy for the unrecorded timing and magnitude of gas pressurisation at the volcano core.
    Description: Published
    Description: 155-168
    Description: partially_open
    Keywords: seismicity ; scaling exponents ; haronic inflation ; pressurisation mechanics ; 04. Solid Earth::04.01. Earth Interior::04.01.04. Mineral physics and properties of rocks ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 18
    Publication Date: 2017-04-04
    Description: The “methane-led hypotheses” assume that gas hydrates and marine seeps are the sole geologic factors controlling Quaternary atmospheric and climate changes. Nevertheless, a wider class of geologic sources of methane exist which could have played a role in past climate changes. Beyond offshore seepage, relevant geologic emissions of methane (GEM) are from onshore seepage, including mud volcanism, microseepage and geothermal flux; altogether GEM are the second most important natural source of atmospheric methane at present. The amount of methane entering the atmosphere from onshore GEM seems to prevail on that from offshore seepage. Onshore sources inject a predominantly isotopically heavy (13C-enriched) methane into the atmosphere. They are controlled mainly by endogenic (geodynamic) processes, which induce large-scale gas flow variations over geologic and millennial time scales, and only partially by exogenic (surface) conditions, so that they are not affected by negative feedbacks. The eventual influence on atmospheric methane concentration does not necessarily require catastrophic or abrupt releases, as proposed for the “clathrate gun hypothesis”. Enhanced degassing from these sources could have contributed to the methane trends observed in the ice core records, and could explain the late Quaternary peaks of increased methane concentrations accompanied by the enrichment of isotopically heavy methane, as recently observed. This hypothesis shall be tested by means of robust multidisciplinary studies, mainly based on a series of atmospheric, biologic and geologic proxies.
    Description: Published
    Description: On line First
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Methane ; climate change ; seepage ; Quaternary ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
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  • 19
    Publication Date: 2017-04-03
    Description: Central to any study of climate change is the development of an inventory that identifies and quantifies natural and anthropogenic sources and sinks of greenhouse gases (GHG). Recent studies have demonstrated that geologic emissions of methane (GEM), although not considered in the inventories of the IntergovernmentalPanel on Climate Change (IPCC), are an important GHG source. Etiope and Klusman (2002, Chemosphere 49, 777–789) documented that significant amounts of methane, produced within the Earth crust, are released naturally into the atmosphere through faults and fractured rocks. Major GEMs are related to hydrocarbon production in sedimentary basins (biogenic and thermogenic methane), through continuous exhalation and eruptions from more than 1200 onshore and offshore mud volcanoes (MVs), through diffuse soil microseepage, and shallow marine seeps; secondarily, methane is released from geothermal and volcano-magmatic systems. Minor geologic sources are those related to natural exhalation from coal-bearing rocks (influenced by mining activities), degassing from crystalline basement and mantle. While marine seeps have been studied for decades, methane flux from MVs has been the object of detailed measurements only since 2001, when hundreds of gas flux measurements were performed from vents and soilin the main terrestrial MVs of Europe, in Romania and Italy (Etiope et al.,2003, Geophysical Research Letters 30, 1094, doi:10.1029/2002GL016287; and references therein). In 2003 gas flux was measured in Azerbaijan, which hosts the world’s biggest MVs and densest MV population (Etiope et al., 2004, Geology, in press). In all areas investigated around 102–103 tons of methane per km2 are annually injected into the atmosphere. The global estimates of GEM from MVs range from 5 to 13Tg yr-1 (Etiope and Milkov, 2004, Environmental Geology, in press).
    Description: Published
    Description: 3099-3100
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Methane ; atmospheric gas budget ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
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  • 20
    Publication Date: 2017-04-04
    Description: In this paper we will discuss a simplified thermodynamic description for the saturation of FeS, either liquid or solid, in magmatic melts. The Conjugated-Toop–Samis–Flood–Grjotheim model [Moretti R. and Ottonello G., 2005. Solubility and speciation of sulfur in silicate melts, the Conjugated-Toop–Samis–Flood–Grjotheim (CTSFG) model. Geochimica et Cosmochimica Acta, 69, 801–823] has furnished the theoretical reference frame, since it already accounts for the solubility of gaseous sulfur and the speciation and oxidation state of sulfur in silicate melts. We provide a new model to predict the saturation of magmatic silicate melts with an FeS phase that is internally consistent with these previous parameterizations. The derived model provides an effective sulfogeobarometer, which is superior with respect to previous models. For magmas rising from depth to surface, our appraisal of molar volumes of sulfur-bearing species in silicate melts allows us to model oxidation–reduction processes at different pressures, and sulfur concentrations for saturationwith either liquid or solid phases. In this respect, the nature of the oxygen fugacity buffer is critical. On the basis of model results on some typical compositions of volcanological interest, the sulfur contents at sulfide saturation (SCSS) have been calculated and the results duplicate the experimental observations that the SCSS is positively correlatedwith pressure forwatersaturated acidic melts and negatively correlated with pressure for water-poor basaltic melts. This new model provides fO2–fS2 pairs of FeS saturation of natural silicatemelts. In caseswhere the redox constraint is lacking, the model can be used to investigate whether the dissolved sulfur content approaches SCSS or not, and if so, to estimate at which fO2 value the silicate melt is saturated with a sulfide phase
    Description: Published
    Description: 286–298
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Sulfur ; Silicate melt ; Iron sulfide ; Chemical thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 21
    Publication Date: 2017-04-04
    Description: Major results of post-intrusive GPS monitoring of the five months encompassing and following the onset of 2002-03 Mt. Etna eruption are presented and discussed here. The overall ground deformation pattern is characterized by a time-dependent relaxation function. We evaluated two different parameterizations of relaxation functions, each one linked to a different relaxation process: i) viscoelastic relaxation and ii) after-slip mechanism. The former indicated that the process occurred within a weak layer characterized by viscosity values ranging between 7.1 • 1014 Pa s and 1.3 • 1015 Pa s. The latter evidenced that frictional processes occurred beneath a layer of velocity-strengthening having a thickness with values ranging between 0.4 km and 1.7 km. Either model may explain the observed time-dependent deformation, both from the statistical point of view and the comparison with geologic and seismic information. Although we are unable to favour one model rather than the other, these results indicate that the mechanism, responsible for the observed post-intrusive deformation, occurs within a sliding “zone” located inside the clayey sedimentary basement.
    Description: This study was undertaken with financial support from the FLANK project (DPC-INGV 2008 - 2010 contract)
    Description: Published
    Description: 300-311
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: 2002-03 Mt. Etna eruption ; Post-intrusive relaxation ; Viscoelastic ; After-slip ; Rheology ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 22
    Publication Date: 2017-04-04
    Description: Correlation of distal ash deposits with their proximal counterparts mainly relies on chemical and mineralogical characterization of bulk rock and matrix glasses. However, the study of juvenile fragments often reveals the heterogeneity in terms of clast shape, external surface, groundmass texture and composition. This is particularly evident in small scale eruptions, characterized by a strong variability in texture and relative abundance of juvenile fragments. This heterogeneity introduces an inherent uncertainty, that makes the compositional data alone inadequate to unequivocally characterize the tephra bed. Pyroclast characteristics, if described and quantified, can represent an additional clue for the correct identification of the tephra. The paper presents morphological, textural and compositional data on the products of an ash eruption from Middle Age activity of Vesuvius, to demonstrate the information that can be extracted from the proposed type of analysis. Juvenile fragments from five ash layers throughout the studied products were randomly hand-picked and fully characterized in terms of external morphology, particle outline parameterization, groundmass texture and glass composition. Statistical analysis of shape parameters characterized groups of fragments that can be compared with the other textural and physical parameters. The main result is that the data do not show important cross-correlation so suggesting that all of these parameters, together with accurate field data are needed for the complete fingerprinting of a tephra bed. We suggest that this approach is especially important for characterizing the products of small scale, compositionally undistinguishable, eruptions and represents the necessary step to deal with before going into more detailed compositional analyses.
    Description: Published
    Description: 277-287
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: tephrostratigraphic methods ; shape parameters ; groundmass texture ; mid-intensity eruptions ; ash deposits ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 23
    Publication Date: 2017-04-04
    Description: A 4.8 m long gravity core was recovered on a relative topographic high in the northern part of the Marsili Basin (southern Tyrrhenian Sea) at a water depth of 3200 m. The core was taken in order to decipher the sedimentary record of the past volcanic events of the nearby Aeolian arc. A succession of thin (2 cm to 5 cm thick) fine-grained turbidites, mainly of volcaniclastic origin, topped by hemipelagic mud layers and a number of primary tephra layers were recovered by the core. The most prominent turbidite occurs in the lower part of the core at 385 cm. It consists of a 20 cm-thick, thinning-upward, pebble to sand-sized bed. Grain-size analysis and component compositions in the 0.063–0.250 mm size fractions were determined on thirty samples taken from primary tephra beds and the silty–sandy basal part of the volcaniclastic turbidite units. SEM scans and glass fraction chemical analyses were successively carried out on a selection of 17 samples. To aid source correlation and comparison, sub-aerial tephras of the Lower Pollara (Salina, 24 ± 3.6 ka), Gabellotto-Fiumebianco (Lipari, 8.5 or 11.5 ka), Monte Pilato (Lipari, 749 or 580 AD) and Secche di Lazzaro (Stromboli, ~ 5 ka) eruptions were also analyzed with the same procedure. Primary tephra respectively belonging to the eruptions of Lower Pollara, Gabellotto-Fiumebianco and Vesuvius (AP eruptions 3.5 ka–79 AD) were identified in the core at the expected relative stratigraphic depths. Two turbidite beds composed of monogenic glass shards were also identified and interpreted as the remobilisation of primary tephras of Secche di Lazzaro (Stromboli, 5 ka) and Pilato (Lipari, 580 or 749 AD). Tephrochronology results indicate that the cored sequence formed in the last 30 ka suggesting an average sedimentation rate of 0.15–0.17 mm/y. The thick pebbly sandy turbidite unit in the lower part of the core has component and glass composition compatible with the Lower Pollara volcanic sequence of Salina Island. In view of the grain-size and thickness of the turbidite unit, we suggest that it represents the deposit of a large failure event. The tephra corresponding to the Lower Pollara event lies below the turbidite unit, separated by 16 cm of hemipelagic mud, indicating that the collapse took place sometime after the eruption.
    Description: Published
    Description: 133-144
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: tephrochronology ; turbidity current ; flank collapse ; Marsili Basin ; gravity core ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 24
    Publication Date: 2017-04-04
    Description: This survey proposes a new approach to identify buried caldera boundaries of a volcanic cone, combining (1) a systematic elliptic Fourier functions (EFF) analysis on the contour lines based on the external shape of the edifice with (2) self-potential (SP) measurements on volcano flanks. The methodology of this approach is to investigate the relationships between (1) vertical morphological changes inferred from EFF analysis and (2) lateral lithological transition inside the edifice inferred from SP/elevation gradients. The application of these methods on Misti volcano in southern Peru displays a very good correlation. The three main boundaries evidenced by hierarchical cluster analysis on the contour lines coincide with the two main boundaries characterised by SP signal and with a secondary SP signature related with a summit caldera. In order to explain these results showing a very good correlation between morphologic and lithologic changes as function of elevation, caldera boundaries have been suggested. The latter would be located at an average elevation of (1) 4350–4400 m, (2) 4950–5000 m, and (3) 5500– 5550 m. For the lowest boundary in elevation, the coincidence with the lateral extension of the hydrothermal system inferred from SP measurements suggests that caldera walls act as a barrier for lateral extension of hydrothermal systems. In the summit area, the highest boundary has been related with the summit caldera, inferred by a secondary SP minimum and geological evidence.
    Description: - Institut de Recherche pour le Développement (IRD) - Instituto Geofisico del Peru´ (IGP).
    Description: Published
    Description: 283– 297
    Description: partially_open
    Keywords: caldera ; elliptic Fourier functions ; geomorphology ; self-potential ; Misti volcano ; Peru ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data ; 05. General::05.05. Mathematical geophysics::05.05.99. General or miscellaneous ; 05. General::05.08. Risk::05.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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    Type: article
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  • 25
    Publication Date: 2017-04-04
    Description: Volcanism at Mount Etna (Italy) has been observed for millennia and inspired ancient mythologies as well as scientific thought through countless generations.Yetmuch of our understanding of the way this volcano works stems fromstudies of the past 20 years, and in particular from strengthened monitoring since the late 1980s. In addition, the eruptive activity of Etna has undergone significant changes during the past 13 years, and these have led to an improved understanding of the relationship between the plumbing system of the volcano and instability of its eastern to southern f lanks. Following the end of the 1991–1993 eruption, a new eruptive cycle began, which so far has produced about 0.23 km3 of lavas and pyroclastics (dense-rock equivalent). The cycle evolved frominitial recharging of the plumbing system and inf lation, followed by powerful summit eruptions and slow spreading of the eastern to southern f lanks, to a sequence of f lank eruptions accompanied by accelerated f lank displacement. Structurally, the volcanic system has become increasingly unstable during this period. Volcanological, geophysical and geochemical data allow the cause–effect and feedback relationships between magma accumulation below the volcano, f lank instability, and the shift from continuous summit activity to episodic f lank eruptions to be investigated. In this scenario, the growth of magma storage areas at a depth of 3–5 km below sea level exerts pressure against those f lank sectors prone to displacement, causing them to detach from the stable portions of the volcanic edifice. Geochemical data indicate that magma remains stored belowthe volcano, even during phases of intense eruptive activity, thus causing a net volumetric increase that is accommodated by f lank displacement. Instability can be enhanced by the forceful uprise ofmagma through the f lanks, as in 2001, when the f irst f lank eruption of the current eruptive cycle took place. Subsequent f lank eruptions in 2002–2003 and 2004– 2004, on the other hand, were, at least in part, facilitated by the opening of fractures at the head of moving f lank sector, although the eruptions were significantly dissimilar from one another. Renewed inflation of the volcano after the 2004–2005 eruption, continued displacement of the unstable f lank sector, and gradual resumption of summit activity in late-2005, demonstrate that the same feedback mechanisms continue to be active, and the Etna system remains highly unstable. The evolution of earlier eruptive cycles shows that a return to a state of relative stability is only possible once a voluminous f lank eruption effectively drains the magmatic plumbing system.
    Description: Published
    Description: 85–114
    Description: reserved
    Keywords: Mount Etna ; eruptive cycle ; volcano monitoring ; seismicity ; deformation ; geochemistry ; structural geology ; magma storage ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring
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  • 26
    Publication Date: 2017-04-04
    Description: A large database of major, trace and isotope (Sr, Nd, Pb, O) data exists for rocks produced by the volcanic activity of Somma-Vesuvius volcano. Variation diagrams strongly suggest a major role for evolutionary processes such as fractional crystallization, contamination, crystal trapping and magma mixing, occurring after magma genesis in the mantle. Most mafic magmas are enriched in LILE (K, Rb, Ba), REE (Ce, Sm) and Y, show small Nb–Ta negative anomalies, and have values of Nb/Zr at about 0.15. Enrichments in LILE, REE, Nb and Ta do not correlate with Sr isotope values or degree of both K enrichment and silica undersaturation. The results indicate mantle source heterogeneity produced by slab-derived components beneath the volcano. However, the Sr isotope values of Somma-Vesuvius increase from 0.7071 up to 0.7081 with transport through the uppermost 11–12 km of the crust. The Sr isotope variation suggests that the crustal component affected the magmas during ascent through the lithosphere to the surface. Our new geochemical assessment based on chemical, isotopic and fluid inclusion data points to the existence of three main levels of magma storage. Two of the levels are deep and may represent long-lived reservoirs, and an uppermost crustal level that probably coincides with the volcanic conduit. The deeper level of magma storage is deeper than 12 km and fed the 1944 AD eruption. The intermediate level coincides with the seismic discontinuity detected by Zollo et al. (1996) at about 8 km. This intermediate level supplies magmas with 87Sr/86Sr values between 0.7071 and 0.7074, and δO18 8‰ that typically erupted both during interplinian (i.e. 1906 AD) and sub-plinian (472 AD, 1631 AD) events. The shallowest level of magma storage at about 5 km was the site of magma chambers for the Pompei and Avellino eruptions. New investigations are necessary to verify the proposed magma feeding system.
    Description: Published
    Description: 183-204
    Description: open
    Keywords: NONE ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 27
    Publication Date: 2017-04-04
    Description: During 2001–2005, Mount Etna was characterized by intense eruptive activity involving the emission of petrologically different products from several vents, which involved at least two types of magma with different degrees of evolution. We investigated the ratios and abundances for noble-gas isotopes in fluid inclusions trapped in olivines and pyroxenes in the erupted products. We confirm that olivine has the most efficient crystalline structure for preserving the pristine composition of entrapped gases, while pyroxene can suffer diffusive He loss. Both the minerals also experience noble gas air contamination after eruption. Helium isotopes of the products genetically linked to the two different magmas fall in the isotopic range typical of the Etnean volcanism. This result is compatible with the metasomatic process that the Etnean mantle is undergoing by fluids from the Ionian slab during the last ten kyr, as previously inferred by isotope and trace element geochemistry. Significant differences were also observed among olivines of the same parental magma that erupted throughout 2001–2005, with 3He/4He ratios moving from about 7.0 Ra in 2001 volcanites, to 6.6 Ra in 2004–2005 products. Changes in He abundances and isotope ratios were attributed to variations in protracted degassing of the same magma bodies from the 2001 to the 2004–2005 events, with the latter lacking any contribution of undegassed magma. The decrease in 3He/4He is similar to that found from measurements carried out every fifteen days during the same period in gases discharged at the periphery of the volcano. To our knowledge this is the first time that such a comparison has been performed so in detail, and provides strong evidence of the real-time feeding of peripheral emissions by magmatic degassing.
    Description: Published
    Description: 683-690
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: open
    Keywords: fluid inclusions ; noble gases ; helium isotopes ; magma degassing ; olivine ; pyroxene ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 28
    Publication Date: 2017-04-04
    Description: An extensive geochemical survey of the fluids released by the volcanic/geothermal system of Methana was undertaken. Gases were characterized based on the chemical and isotopic [helium (He) and carbon (C)] analysis of 27 samples. Carbon dioxide soil gas concentration and fluxes were measured at 179 sampling sites throughout the peninsula. Forty samples of thermal and cold groundwaters were also sampled and analysed to characterize the geochemistry of the aquifers. Gases of hydrothermal origin gave a preliminary geothermometric estimate of about 210 °C. The He-isotope composition indicated mantle contributions of up to 40%, and the C-isotope composition of CO2 indicated that it predominantly (〉90%) originated from limestone decomposition. The groundwater composition was suggestive of mixing between meteoric and hydrothermally modified sea-water endmembers and water–rock interaction processes limited to simple rock dissolution driven by an increased endogenous CO2 content. All of the thermal manifestations and anomalous degassing areas, although of limited extent, were spatially correlated with the main active tectonic system of the area. The total CO2 output of the volcanic system has been preliminary estimated to be less than 0.05 kg s–1. Although this value is very low compared to those of other volcanic systems, anomalous CO2 degassing at Methana – which is currently restricted to limited areas and at present is the only volcanic risk of the peninsula – is a potential gas hazard that warrants further assessment in future studies.
    Description: Published
    Description: 818-828
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Methana ; south Aegean volcanic arc ; fluids geochemistry ; soil gases ; groundwaters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 29
    Publication Date: 2017-04-04
    Description: On February 27, 2007 a new eruption started at Stromboli that lasted until April 2 and included a paroxysmal explosion on March 15. Geochemical monitoring carried out over several years revealed some appreciable variations that preceded both the eruption onset and the explosion. The carbon dioxide (CO2) flux from the soil at Pizzo Sopra La Fossa markedly increased a few days before the eruption onset, and continued during lava effusion to reach its maximum value (at 90,000 g m−2 d−1) a few days before the paroxysm. Almost contemporarily, the δ13CCO2 of the SC5 fumarole located in the summit area increased markedly, peaking just before the explosion (δ13CCO2~−1.8‰). Following the paroxysm, helium (He) isotopes measured in the gases dissolved in the basal thermal aquifer sharply increased. Almost contemporarily, the automatic station of CO2 flux recorded an anomalous degassing rate. Also temperatures and the vertical thermal gradient, which had been measured since November 2006 in the soil at Pizzo Sopra La Fossa, showed appreciable variabilities that lasted until the end of the eruption. The geochemical variations indicated the degassing of a new batch of volatile-rich magma that preceded and probably fed the paroxysm. The anomalous 3He/4He ratio suggested that the ascent of a second batch of volatile-rich magma toward the surface was probably responsible of the resumption of the ordinary activity. A comparison with the geochemical variations observed during the 2002–2003 eruption indicated that the 2007 eruption was less energetic.
    Description: Published
    Description: 246-254
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: geochemistry ; eruption ; dissolved gases ; Stromboli ; volcanic activity ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 30
    Publication Date: 2017-04-04
    Description: The Campi Flegrei caldera is an active and restless volcano in the densely inhabited Neapolitan area of southern Italy. Because of the very high value (lives, properties, infrastructures, etc.) exposed to potential volcanic hazards, it is one of the areas at highest volcanic risk on Earth. In such a situation we have made an attempt to contribute to assessment of its volcanic hazards by providing a quantitative probabilistic longterm forecast of style and size of the next eruption. We have evaluated the most relevant physical parameters of the 22 explosive eruptions of the Campi Flegrei caldera over the past 5 ka. This time span has been taken as the reference period for volcanic hazards assessment on the basis of the volcanic and deformation history of the caldera. The evaluated parameters include dispersal, volume and density of the pyroclastic deposits, volume of erupted magma, total erupted mass, and eruption magnitude. The obtained results permit a size classification of the explosive eruptions, which are grouped into three sizes: small, medium, and large. On the basis of the reconstructed eruption dynamics, we have considered a type event(s) representative of each size class and hypothesized the style of the next event. An effusive eruption will likely generate a dome or very small lava flows, while an explosive event of any size very probably will produce particles fallout and flowage of pyroclastic density currents. Using a Bayesian inference procedure, we have assigned a conditional probability of occurrence to each of the eruption size classes. A small-size explosive eruption is the most likely event with a probability of about 60%; a large-size explosive eruption is the least likely event with a probability of about 4%; a medium-size explosive eruption has a probability of occurrence of about 25%; an effusive eruption has about 11% probability of occurrence.
    Description: Published
    Description: 265–276
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: volcanic hazards assessment ; eruption size ; eruption style ; Campi Flegrei caldera ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 31
    Publication Date: 2017-04-04
    Description: Geochemical research was carried out on cold and hot springs at Popocatepetl (Popo) volcano (Mexico) in 1999 to identify a possible relationship with magmatic activity. The chemical and isotopic composition of the fluids is compatible with strong gas–water interaction between deep and shallow fluids. In fact, the isotopic composition of He and dissolved carbon species is consistent with a magmatic origin. The presence of a geothermal system having a temperature of 80–1008 C was estimated on the basis of liquid geothermometers. A large amount of dissolved CO2 in the springs was also detected and associated with high CO2 degassing.
    Description: Published
    Description: 91– 108
    Description: partially_open
    Keywords: Popocatepetl volcano ; helium isotope composition ; carbon isotope composition ; dissolved gases ; gas–water interaction ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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    Type: article
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  • 32
    Publication Date: 2017-04-04
    Description: We describe the reactivation and the successive evolution of the shallow plumbing system of Mt. Etna between the end of the largest flank eruption of the last three centuries (1991–1993) and the subterminal eruption from South-East Crater (SEC), which occurred between February and mid-November 1999. Our analysis is based on observations of the volcanic activity and petrological studies of the erupted volcanics. Bulk rock, mineral and glass compositions have been determined for more than 80 samples erupted from the four summit craters between October 1995 and February 1999. These data allow us to recognise significant compositional variations among the products of different craters. In particular, volcanics produced between 1995 and 1999 by Bocca Nuova (BN), Voragine (VOR) and North-East Crater (NEC) show limited compositional variations and are similar to those observed during recent eruptions (e.g., 1991–93). More primitive magmas have been produced during the more vigorous fire fountains episodes. On the contrary, the South-East Crater produced slightly more differentiated volcanics than those of the other summit craters following its reactivation (November 1996) until the end of 1998. Whole rock compositions of products from this crater show low CaO/Al2O3, whereas interstitial glasses have lower MgO and higher alkali contents than those from the other craters. However, since the beginning of 1999, and just before the start of the subterminal eruption from SEC, the volcanics erupted from this crater progressively changed in composition, becoming similar to those of the other craters. This trend indicates that within the conduits of the summit craters, distinct thermal and fluid-dynamical regimes can evolve, controlling the cooling and crystallisation of Etna magmas.
    Description: Published
    Description: 55-71
    Description: partially_open
    Keywords: Mount Etna ; crystal fractionation ; petrologic monitoring and magmatic process ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 33
    Publication Date: 2017-04-04
    Description: The first measurements of volcanic/hydrothermal water vapor and heat flux using eddy covariance (EC) were made at Solfatara crater, Italy, June 8–25, 2001. Deployment at six different locations within the crater allowed areas of focused gas venting to be variably included in the measured flux. Turbulent (EC) fluxes of water vapor varied between 680 and 11200g H2O m−2 d−1. Heat fluxes varied diurnally with the solar input, and the volcanic component of sensible heat ranged from ∼25 to 238W m−2. The highest measurements of both sensible and latent heat flux were made downwind of hot soil regions and degassing pools and during mid-day. The ratio of average volcanic heat (both latent and sensible) to CO2 flux resulted in an equivalent H2O/CO2 flux ratio of 2.2 by weight, which reflects the deep source H2O/CO2 gas ratio. The amount latent heat flux/evaporation was determined to be consistent both with what would be expected from the magnitude of CO2 fluxes and the fumarolic H2O/CO2 ratio, as well as with observed surface temperatures and wind speeds given a moist soil. This suggests that the water vapor that condenses in the shallow subsurface is remobilized at the soil–atmosphere interface through variable evaporation dependent on the deep heat flux and surface temperature. The results suggest that EC provides a quick and easy method to monitor average H2O/CO2 ratios continuously in volcanic regions, providing another important tool for volcanic hazards monitoring.
    Description: Published
    Description: 72–82
    Description: reserved
    Keywords: eddy covariance ; volcanic ; heat flux ; water vapor ; hydrothermal ; degassing ; flux ; emissions ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.08. Instruments and techniques
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  • 34
    Publication Date: 2017-04-04
    Description: The tectonic escarpments locally known as ‘Timpe’ cut a large sector of the eastern flank of Etna, and allow an ancient volcanic succession dating back to 225 ka to be exposed. Geological and volcanological investigations carried out on this succession have allowed us to recognize relevant angular unconformities and volcanic features which are the remnants of eruptive fissures, as well as important changes in the nature, composition and magmatic affinity of the exposed volcanics. In particular, the recognition in the lower part of the succession of important and unequivocal evidence of ancient eruptive fissures led us to propose a local origin for these volcanics and to revise previous interpretations which attributed their westward-dipping to the progressive tectonic tilting of strata. These elements led us to reinterpret the main features of the volcanic activity occurring since 250 ka BP and their relationship with tectonic structures active in the eastern flank of Etna. We propose a complex paleo-environmental and volcanotectonic evolution of the southeastern flank of Mt. Etna, in which the Timpe fault system played the role of the crustal structure that allowed the rise and eruption of magmas in the above considered time span.
    Description: Published
    Description: 289-306
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Mount Etna ; tectonics ; fisssure eruptions ; columnar basalt ; fault escarpment ; xenoliths ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 35
    Publication Date: 2017-04-04
    Description: A new method combining measurements of soil CO2 flux and determinations of the carbon isotopic composition of soil CO2 efflux was developed in order to qualitatively and quantitatively characterise the CO2 source feeding the soil CO2 diffuse degassing. The method was tested in March 2007 at the Solfatara of Pozzuoli volcano degassing area (Naples, Italy) where more than 300 measurements of soil CO2 flux and determinations of the carbon isotopic composition of soil CO2 efflux were performed, surveying Solfatara crater and its surroundings. The wide range of CO2 flux and CO2 isotopic composition values (from 8.4 g m−2 d−1 to 28,834 g m−2 d−1, and from 0.73‰ to −33.54‰, respectively), together with their statistical distributions suggests the occurrence of multiple CO2 sources feeding soil degassing. The combined interpretation of flux and isotopic data allows us to identify and characterise two distinct gas sources: a hydrothermal and a biogenic source. The soil CO2 from the hydrothermal source is characterised by a mean δ13CCO2 of −2.3‰±0.9‰, hence close to the isotopic composition of the fumarolic CO2 (δ13CCO2=−1.48‰± 0.22‰) and by a mean CO2 flux of 2875 g m−2 d−1. The CO2 from the biogenic source is characterised by a mean δ13CCO2 of −19.4‰±2.1‰, and by a mean CO2 flux of 26 g m−2 d−1, which are both in the range of the typical values for biologic CO2 soil degassing. This reliable characterisation of the biogenic CO2 flux would not have been possible by solely applying a statistical analysis of the CO2 flux values, which is commonly applied in volcanological studies for the partitioning between background fluxes and anomalous CO2 fluxes. A map of the Solfatara diffuse degassing structure was derived from the estimated threshold for the biogenic CO2 flux, highlighting that soil degassing of hydrothermal CO2 mixed in different proportion with biogenic CO2 occurs over a large area (~0.8 km2), which extends over the inner part of the Solfatara crater as well as the eastern periphery, corresponding with a NW–SE fault system. The presented method and data analysis are important means of surveillance of the volcanic activity.
    Description: Published
    Description: 372–379
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: CO2 soil degassing ; CO2 flux ; carbon dioxide ; carbon isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 36
    Publication Date: 2017-04-04
    Description: Lake Averno is situated in the homonymous crater in the northwestern sector of the Campi Flegrei active volcanic system in Campania region, Italy. In February 2005 a fish kill event was observed in the lake, prompting a geochemical survey to ascertain the possible cause. In February 2005 a geochemical survey revealed that the lake water was unstratified chemically and isotopically, presumably, as a result of lake overturn. This fish kill phenomenon was recorded at least two other times in the past. In contrast to the February 2005 results, data collected in October 2005, shows the Lake Averno to be stratified, with an oxic epilimnion (surface to 6 m) and an anoxic hypolimnion (6 m to lake bottom at about 33 m). Chemical and isotopic compositions of Lake Averno waters suggest an origin by mixing of shallow waters with a Na–Cl hydrothermal component coupled with an active evaporation process. The isotopic composition of Dissolved Inorganic Carbon, as well as the composition of the non-reactive dissolved gas species again supports the occurrence of this mixing process. Decreasing levels of SO4 and increasing levels of H2S and CH4 contents in lake water with depth, strongly suggests anaerobic bacterial processes are occurring through decomposition of organic matter under anoxic conditions in the sediment and in the water column. Sulfate reduction and methanogenesis processes coexist and play a pivotal role in the anaerobic environment of the Lake Averno. The sulfate reducing bacterial activity has been estimated in the range of 14–22 μmol m−2 day−1. Total gas pressure of dissolved gases ranges between 800 and 1400 mbar, well below the hydrostatic pressure throughout the water column, excluding the possibility, at least at the survey time, of a limnic eruption. Vertical changes in the density of lake waters indicate that overturn may be triggered by cooling of epilimnetic waters below 7 °C. This is a possible phenomenon in winter periods if atmospheric temperatures remain frosty for enough time, as occurred in February 2005. The bulk of these results strongly support the hypothesis that fish kill was caused by a series of events that began with the cooling of the epilimnetic waters with breaking of the thermal stratification, followed by lake overturn and the rise of toxic levels of H2S from the reduced waters near the lake bottom.
    Description: Published
    Description: 305–316
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: lake Averno ; dissolved gases ; stable isotopes ; stable isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 37
    Publication Date: 2017-04-04
    Description: A new proposal for the classification of Somma-Vesuvius (SV) explosive activity is presented, based on a critical revision of a large set of published and unpublished stratigraphic, compositional, and physical volcanology data on the products of the past 20,000 years of activity. The new database is used to discuss the general behaviour of the volcano in terms of frequency, magnitude and intensity of the events, as well as of the length of the repose time which preceded each eruption. Several different types of eruption are recognized, each characterised by specific physical eruptive parameters: plinian, subplinian (further subdivided in subplinian I and subplinian II), violent strombolian, ash emission events. For each eruption type, a complex scenario is described, with phases of different style, duration, magnitude and intensity occurring during the course of the eruption itself. The name given to each eruption type is derived from the style of the most representative part of the eruption (in terms of duration or volume). On the whole, the magnitude (expressed as the volume of erupted magma) of the past SV eruptions has been roughly decreasing with time while, starting from 3900 years BP, their frequency has been increasing. The eruption intensity, expressed as the estimated magma discharge rate (MDR) continuously increases with increasing magnitude from strombolian to plinian eruptions, the most voluminous plinian events being, however, characterised by a lower MDR than the smaller ones. The length of the “apparent” repose preceding an eruption (the difference in age between one deposit and that immediately on top of it) appears clearly correlated with magnitude for the most intense eruptions (plinian and subplinian I), while this correlation is poorer for eruptions of intermediate size (from violent strombolian to subplinian II). These exhibit a large variability in magnitude, intensity and eruption style for a range of repose time varying from dozens to hundreds of years, then including the current duration of Vesuvius quiescence. By reckoning with the whole range of possibilities that a next unrest at Vesuvius implies, the set of presented eruption scenarios can be useful both for developing a probabilistic approach to hazard assessment and depicting a range of impact scenarios. The scenario for high-intensity events had been already well defined since 1995, in order to redact the emergency plan of the National Department of Civil Defence. Conversely, it is now clear that the impact on the territory of long-lasting, although low-intensity, eruptions (subplinian II, violent strombolian, ash emission activity) can be relevant especially in terms of economic costs. A larger consideration of this type of activity at Vesuvius can be important especially for the aspects of emergency planning and risk reduction.
    Description: Published
    Description: 331-346
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Explosive eruption ; Eruption scenario ; Volcanic history ; Somma-Vesuvius ; Volcanic hazard ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 38
    Publication Date: 2017-04-04
    Description: The Astroni volcano was built through seven eruptions that generated pyroclastic deposits and lava domes within the Campi Flegrei caldera (southern Italy) 4.1–3.8 ka BP. Whole-rock geochemical and B–Sr–Nd isotopic investigations were carried out on representative samples of all seven eruptions. The products vary from tephriphonolites to phonolites, and from latites to trachytes. They show textural, mineralogical and isotopic evidence of disequilibrium, including distinct clinopyroxene populations, rounded and/or resorbed plagioclase and alkali-feldspar, and reverse-zoned phenocrysts of all these mineral phases. The Sr, Nd and B isotopic composition of whole rocks is variable and correlated with the degree of chemical evolution, suggesting open-system processes in addition to fractional crystallisation. Moreover, significant Sr-isotopic disequilibrium between the phenocrysts and glass has been documented for one sample. The chemostratigraphy of the products indicates that Astroni eruptions 1 through 5 were fed by magmas of trachytic to phonolitic composition that were less enriched in radiogenic Sr and 11B up-section. This variability has been interpreted as the result of mingling between at least two distinct magmatic endmembers, one more evolved and the other less evolved. Another heterogeneous batch of magma, resulting from almost complete mixing between the same two end-members, was drained during eruptions 6 and 7. The more evolved end-member, characterised by 87Sr/86Sr≥0.7075, 143Nd/144Nd≤0.51247 and δ11B≥−8‰, was very similar to the magma that fed the final phases of the Agnano–Monte Spina eruption, which occurred a few centuries earlier in the Astroni vent area. The less evolved end-member had 87Sr/ 86Sr≤0.70726, 143Nd/144Nd≥0.51251 and δ11B≤10‰, and was likely derived by fractional crystallisation of a mantle-derived magma. An abrupt decrease in both the Sr isotope ratio and the Th content, detected at the transition between Unit 4 and 5, suggests that another magma with a 87Sr/86Sr ratio intermediate between those of the two identified end-members may have been involved in Astroni activity. The more evolved endmember is interpreted as a residue of the Agnano–Monte Spina eruption that was invaded by either the intermediate or the less evolved magmatic end-member, promoting mingling and triggering Astroni activity. This study of Astroni provides insights for both short- and long-term volcanic hazard assessment, as the Astroni volcano is the best example of a very close sequence of eruptions from the same vent area in the Campi Flegrei caldera.
    Description: Published
    Description: 135–151
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Campi Flegrei caldera ; B–Sr–Nd isotope geochemistry ; Magma mingling/mixing ; Chemostratigraphy ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 39
    Publication Date: 2020-02-24
    Description: Tephra layers from archaeological sites in southern Italy and eastern Europe stratigraphically associated with cultural levels containing Early Upper Palaeolithic industry were analysed. The results confirm the occurrence of the Campanian Ignimbrite tephra (CI; ca. 40 cal ka BP) at Castelcivita Cave (southern Italy), Temnata Cave (Bulgaria) and in the Kostenki–Borshchevo area of the Russian Plain. This tephra, originated from the largest eruption of the Phlegrean Field caldera, represents the widest volcanic deposit and one of the most important temporal/stratigraphic markers of western Eurasia. At Paglicci Cave and lesser sites in the Apulia region we recognise a chemically and texturally different tephra, which lithologically, chronologically and chemically matches the physical and chemical characteristics of the Plinian eruption of Codola; a poorly known Late Pleistocene explosive event from the Neapolitan volcanoes, likely Somma–Vesuvius. For this latter, we propose a preliminary age estimate of ca. 33 cal ka BP and a correlation to the widespread C-10 marine tephra of the central Mediterranean. The stratigraphic position of both CI and Codola tephra layers at Castelcivita and Paglicci help date the first and the last documented appearance of Early Upper Palaeolithic industries of southern Italy to ca. 41–40 and 33 cal ka BP, respectively, or between two interstadial oscillations of the Monticchio pollen record – to which the CI and Codola tephras are physically correlated – corresponding to the Greenland interstadials 10–9 and 5. In eastern Europe, the stratigraphic and chronometric data seem to indicate an earlier appearance of the Early Upper Palaeolithic industries, which would predate of two millennia at least the overlying CI tephra. The tephrostratigraphic correlation indicates that in both regions the innovations connected with the so-called Early Upper Palaeolithic – encompassing subsistence strategy and stone tool technology – appeared and evolved during one of the most unstable climatic phases of the Last Glacial period. On this basis, the marked environmental unpredictability characterising this time-span is seen as a potential ecological factor involved in the cultural changes observed.
    Description: Published
    Description: 208–226
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Campanian Ignimbrite ; Early Upper Palaeolithic ; Codola Plinian eruption ; south-eastern Europe ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 40
    Publication Date: 2022-02-16
    Description: The “methane-led hypotheses” assume that gas hydrates and marine seeps are the sole geologic factors controlling Quaternary atmospheric and climate changes. Nevertheless, a wider class of geologic sources of methane exist which could have played a role in past climate changes. Beyond offshore seepage, relevant geologic emissions of methane (GEM) are from onshore seepage, including mud volcanism, microseepage and geothermal flux; altogether GEM are the second most important natural source of atmospheric methane at present. The amount of methane entering the atmosphere from onshore GEM seems to prevail on that from offshore seepage. Onshore sources inject a predominantly isotopically heavy (13C-enriched) methane into the atmosphere. They are controlled mainly by endogenic (geodynamic) processes, which induce large-scale gas flow variations over geologic and millennial time scales, and only partially by exogenic (surface) conditions, so that they are not affected by negative feedbacks. The eventual influence on atmospheric methane concentration does not necessarily require catastrophic or abrupt releases, as proposed for the “clathrate gun hypothesis”. Enhanced degassing from these sources could have contributed to the methane trends observed in the ice core records, and could explain the late Quaternary peaks of increased methane concentrations accompanied by the enrichment of isotopically heavy methane, as recently observed. This hypothesis shall be tested by means of robust multidisciplinary studies, mainly based on a series of atmospheric, biologic and geologic proxies.
    Description: Published
    Description: 79-88
    Description: 3.8. Geofisica per l'ambiente
    Description: JCR Journal
    Description: reserved
    Keywords: climate change ; methane ; greenhouse gas emissions ; Quaternary ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 41
    Publication Date: 2023-01-16
    Description: On April 5, 2003, Stromboli volcano (Italy) produced the most violent explosion of the past 50 years. The event was exceptionally well documented thanks to the presence on the island of several scientists and a large number of instruments deployed over the preceding months to monitor the effusive eruption that began in December 2002. Integration of visual documentation, deposit features and geophysical data allowed an accurate reconstruction of the explosive event and its dynamics. The eruption consisted of a 8-min long explosive event which evolved through four phases whose timing was precisely recorded by an infrared thermometer located about 450 m from the summit crater. Phases 2 and 3 lasted 39 and 42 s, respectively. Both had an impulsive character, were responsible for ejecting almost the entire mass of the pyroclastic products. Phases 1 and 4 represented, respectively, a short-lived precursory event and a waning tale. During Phase 2, meter-sized ballistic blocks were launched with velocities of 170 m/s to altitudes of up to 1400 m above the craters. These fell on the volcano flanks and on the village of Ginostra, about 2 km distant from the vent. A vertical jet rose above the craters which developed to feed a convective plume that reached a height of up to 4 km. The calculated mass of the Phase 2 fallout deposit and mass discharge rate were 1.1–1.4×108 kg and 2.8– 3.6×106 kg/s, respectively. During Phase 3 a scoria flow deposit, with an estimated volume of 0.9–1.1×104 m3, was erupted from the same vent that fed the ongoing sustained lava flow. The average mass discharge rate for this phase was 2.5–3.1×105 kg/s. Products emitted during Phases 2 and 3 consisted of lithic and fresh magmatic material in similar proportions. The juvenile fraction consisted of a deep-originated, almost aphyric, highly vesicular pumice mingled with a shallow-derived, crystal-rich, moderately vesicular scoria. Similarities with the eruption dynamics of other historical paroxysms at Stromboli makes the April 5, 2003 explosion representative of these highly energetic events that constitute the most hazardous volcanic phenomena at Stromboli volcano.
    Description: Published
    Description: 594-606
    Description: JCR Journal
    Description: reserved
    Keywords: stromboli ; Thermal monitoring; paroxysm ; explosive dynamics ; ballistic ejecta ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 42
    Publication Date: 2022-05-24
    Description: Many studies have assessed the strong influence of volcanic activity on the surrounding environment. This is particularly true for strong gas emitters such as Mt. Etna and Stromboli volcanoes. Among volcanic gases, fluorine compounds are potentially very harmful. Fluorine cycling through rainwater in the above volcanic areas was studied analysing more than 400 monthly bulk samples. Data indicate that only approximately 1% of fluorine emission through the plume is deposited on the two volcanic areas by meteoric precipitations. Although measured bulk rainwater fluorine fluxes are comparable to and sometimes higher than in heavily polluted areas, their influence on the surrounding vegetation is limited. Only annual crops, in fact, show some damage that could be an effect of fluorine deposition, indicating that long-living endemic plant species or varieties have developed some kind of resistance.
    Description: Published
    Description: 175–185
    Description: partially_open
    Keywords: Fluorine ; Rainwater chemistry ; Volcanic activity ; Mt. Etna ; Stromboli Island ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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