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  • 04. Solid Earth::04.08. Volcanology::04.08.01. Gases  (21)
  • 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous  (7)
  • American Geophysical Union  (27)
  • Annual Reviews
  • 2005-2009  (27)
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  • 1
    Publication Date: 2021-01-27
    Description: We report the first combined measurements of the composition and flux of gas emitted from Nyiragongo volcano by ground-based remote-sensing techniques. Ultraviolet spectroscopic measurements made in May/June 2005 and January 2006 indicate average SO2 emission rates of 38 kg s−1 and 23 kg s−1, respectively. Open-path Fourier transform infrared spectroscopic measurements obtained in May/June 2005, January 2006, and June 2007 indicate average molar proportions of 70, 24, 4.6, 0.87, 0.26, 0.11, and 0.0016% for H2O, CO2, SO2, CO, HCl, HF, and OCS, respectively. The composition of the plume was remarkably similar in 2005, 2006, and 2007, with little temporal variation in proportions of CO2, SO2, and CO, in particular, on the scale of seconds or days or even between the three field campaigns that span a period of 24 months. This stability persisted despite a wide range of degassing behaviors on the surface of the summit crater's lava lake (including discrete strombolian bursts and lava fountains) and variations in the SO2 emission rate. We explain these observations by a regime of steady state degassing in which bubbles nucleate and ascend in chemical equilibrium with the convecting magma. Short-term (seconds to minutes) temporal fluctuations in the SO2–HCl–HF composition were observed, and these are attributed to shallow degassing processes.
    Description: Published
    Description: Q02017
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Nyiragongo ; volcanic gas emissions ; FTIR ; DOAS ; remote sensing ; spectroscopy ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 2
    Publication Date: 2017-04-04
    Description: The recent eruption of Mount Etna (July 2001) offered the opportunity to analyze magma-derived volatiles emitted during preand syn-eruptive phases, and to verify whether their composition is affected by changes in volcanic dynamics. This paper presents the results of analyses of F, Cl and S in the volcanic plume collected by filter-packs, and interprets variations in the composition based on contrasting solubility in magmas. A Rayleigh-type degassing mechanism was used to fit the acquired data and to estimate Henryâ s solubility constant ratios in Etnean basalt. This model provided insights into the dynamics of the volcano. Abundances of sulfur and halogens in eruptive plumes may help predict the temporal evolution of an ongoing effusive eruption.
    Description: -Gruppo Nazionale per la Vulcanologia.
    Description: Published
    Description: 1559
    Description: partially_open
    Keywords: magmatic degassing ; acidic gases ; plume chemistry ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 3
    Publication Date: 2017-04-04
    Description: Sulphur speciation in volcanic gases acts as a major redox buffer, and H2S/SO2 ratios represent a valuable indicator of magmatic conditions and interactions between magmatic and hydrothermal fluids. However, measurement of H2S/SO2 even by direct sampling techniques, is not straightforward. We report here on application of a small ultraviolet spectrometer for real-time field measurement of H2S and SO2 concentrations, using open-path and extractive configurations. The device was tested at fumaroles on Solfatara and Vulcano, Italy, in November 2002. H2S concentrations of up to 220ppmm(400 ppmv) were measured directly above the Bocca Grande fumarole at Solfatara, and H2S/SO2 molar ratios of 2 and 2.4, respectively, were determined for the ‘F11’ and ‘F0’ fumaroles at Vulcano. In comparison with other optical techniques capable of multiple volcanic gas measurements, such as laser and FTIR spectroscopy, this approach is considerably simpler and cheaper, with the potential for autonomous, sustained hightime resolution operation.
    Description: Published
    Description: 1652
    Description: partially_open
    Keywords: Remote monitoring ; Plume chemistry ; sulphur species ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 4
    Publication Date: 2017-04-04
    Description: Morphostructural data derived from Lidar (Light detection and ranging) surveys carried out on Mount Etna in 2005 and 2007 are compared with earlier aerophotogrammetric surveys in 1986 and 1998. These data render an unprecedentedly clear and quantitative image of morphostructural and volumetric changes that have affected the summit area of the volcano in the past two decades and permit the production of a new topographic map. The computed volume gain during the 1986–2007 period amounts to 112 ± 12 106 m3, at a mean annual rate of 5.3 106 m3. The comparison of the various surveys furthermore emphasizes the levels of accuracy and resolution of the different techniques applied. The Lidar technology used in 2007 allows production of high-precision maps in near-real-time, facilitating work concerning environmental hazards such as numerical simulations of, e.g., lava flows.
    Description: Published
    Description: L09305
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 1.10. TTC - Telerilevamento
    Description: JCR Journal
    Description: partially_open
    Keywords: Lidar ; Etna ; morphostructural changes ; lava flows ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
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  • 5
    Publication Date: 2017-04-04
    Description: The soil CO2 flux on Mt. Etna as recorded by the ETNAGAS network (an automatic system for measuring soil CO2 flux and meteorological parameters) started to increase strongly about 5 months prior to the onset of the 2004–2005 eruption and decreased a few months before the end of the eruption. Time delays in the occurrences of anomalies in soil CO2 flux at different sites in the geochemical network constrain the relationship between soil CO2 flux distributions and the tectonic framework of Etna volcano. The anomalies observed before the 2004–2005 eruption support the intrusion of new undegassed magma into the upper feeding system of the volcano (〈20 km below sea level). Magma subsequently rose slowly in the volcano conduits, thereby triggering the onset of the 2004–2005 eruption. The time delays in the occurrences of anomalies in combination with spectral analysis indicate the importance of tectonic and volcanotectonic structures in driving the ascent of deep gases within the crust. Moreover, greatest amplitude pulsations of the low-frequency components of the CO2 flux signals were correlated with the paroxystic activities of the 2004–2005 eruption. This study confirms that CO2 flux variation is a useful indicator for volcanic activity in the surveillance of the Mt. Etna and similar basaltic volcanoes.
    Description: Dipartimento Protezione Civile Ministero degli Interni
    Description: Published
    Description: B09206
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: CO2 flux ; Continuous monitoring of soil CO2 flux ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 6
    Publication Date: 2017-04-04
    Description: Volcanic gas emissions from fumaroles on the rim of La Fossa crater, Vulcano Island, Italy, were measured simultaneously using direct sampling (for H2O, CO2, total sulfur, HCl and HF), filter packs (for SO2, HCl, HF) and short-path active-mode FTIR measurements (for H2O, CO2,SO2, HCl and HF) in an intercomparison study in May 2002. The results show that Cl/F ratios were in good agreement between all three methods, and that FTIR and direct sampling determined comparable proportions of CO2 and H2O. Amounts of total S observed in direct sampling data were approximately double the amounts of SO2 measured with filter packs and FTIR. This difference could be attributed either to the fact FTIR and filter packs do not measure reduced sulfur species (e.g., H2S) or to sublimation of elemental S upon exit from the fumarole, after collection by direct sampling but before detection with FTIR and filter packs.
    Description: Published
    Description: L02610
    Description: partially_open
    Keywords: volcanic gas techniques ; gas geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 7
    Publication Date: 2017-04-04
    Description: Chemical and isotopic data have been used as geochemical tracers for a genetic characterization of hydrocarbon gases from a total of eleven manifestations located in Eastern and Central-Southern Sicily (Italy). The molecular analysis shows that almost all the samples are enriched in methane (up to 93.2% Vol.), with the exception of four gas samples collected around Mt. Etna showing high mantle-derived CO2 content. Methane isotope signatures suggest that these are thermogenic gases or a mixture between thermogenic gases and microbial gases. Although samples from some mud volcanoes in Southern Sicily (Macalube di Aragona) show isotope signatures consistent with a mixing model between thermogenic and microbial, by combining the molecular compositions (C1/(C2 + C3))and the methane isotope ratios (d13C1), such a process seems to be excluded. Therefore, the occurrence of secondary post-genetic processes should be invoked. Two main hypotheses have been considered: the first hypothesis includes that the gas is produced by microbial activity and altered post-genetically by microbial oxidation of methane, while according to the second hypothesis thermogenic gas have modified their molecular ratios due to vertical migration.
    Description: Published
    Description: L06607
    Description: partially_open
    Keywords: Isotopic composition/chemistry ; Organic geochemistry ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 8
    Publication Date: 2017-04-04
    Description: Constraining fluxes of volcanic bromine and iodine to the atmosphere is important given the significant role these species play in ozone depletion. However, very few such measurements have been made hitherto, such that global volcanic fluxes are poorly constrained. Here we extend the data set of volcanic Br and I degassing by reporting the first measurements of bromine and iodine emissions from Mount Etna. These data were obtained using filter packs and contemporaneous ultraviolet spectroscopic SO2 flux measurements, resulting in time-averaged emission rates of 0.7 kt yr 1 and 0.01 kt yr 1 for Br and I, respectively, from April to October 2004, from which we estimate global Br and I fluxes of order 13 (range, 3â 40) and 0.11 (range, 0.04â 6.6) kt yr 1. Observed changes in plume composition highlight the coherent geochemical behavior of HCl, HF, HBr, and HI during magmatic degassing, and strong fractionation of these species with respect to SO2.
    Description: Published
    Description: Q08008
    Description: partially_open
    Keywords: bromine and iodine in volcanic gases ; halogen atmospheric chemistry ; volcanic degassing ; volcanic plumes ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 9
    Publication Date: 2017-04-04
    Description: Ground-based measurements of volcanic sulfur dioxide fluxes are important indicators of volcanic activity, with application in hazard assessment, and understanding the impacts of volcanic emissions upon the environment and climate. These data are obtained by making traverses underneath the volcanic plume a few kilometers from source with an ultraviolet spectrometer, measuring integrated SO2 concentrations across the plume’s cross section, and multiplying by the plume’s transport speed. However, plume velocities are usually derived from ground-based anemometers, located many kilometers from the traverse route and hundreds of meters below plume altitude, complicating the experimental design and introducing large flux (can be 〉100%) errors. Here we present the first report of a single instrument capable of (accurate) volcanic SO2 flux measurements. This device records integrated SO2 concentrations and plume heights during traverses. Between traverses, two in-plume SO2 time series are measured from underneath the plume with the instrument, corresponding to zenith and inclined (user-specified angle from vertical in the direction of the volcano) fields of view, respectively. The distance between the points of intersection of the two views with the plume is found on the basis of the determined plume height, and the two signals are cross-correlated to determine the lag between them, enabling accurate derivation of the wind speed. We present flux data (with errors ±12%) obtained in this way at Mt. Etna during July 2004.
    Description: Published
    Description: Q02003
    Description: partially_open
    Keywords: DOAS ; volcanic SO2 emissions. ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 10
    Publication Date: 2017-04-04
    Description: The FLOWGO thermo-rheological model links heat loss, core cooling, crystallization, rheology and flow dynamics for lava flowing in a channel. We fit this model to laser altimeter (LIDAR) derived channel width data, as well as effusion rate and flow velocity measurements, to produce a best-fit prediction of thermal and rheological conditions for lava flowing in a ~1.6 km long channel active on Mt. Etna (Italy) on 16th September 2004. Using, as a starting condition for the model, the mean channel width over the first 100 m (6 m) and a depth of 1 m we obtain an initial velocity and instantaneous effusion rate of 0.3–0.6 m/s and ~3 m3/s, respectively. This compares with field- and LIDAR-derived values of 0.4 m/s and 1–4 m3/s. The best fit between model-output and LIDAR-measured channel widths comes from a hybrid run in which the proximal section of the channel is characterised by poorly insulated flow and the medial-distal section by well-insulated flow. This best-fit model implies that flow conditions evolve down-channel, where hot crusts on a free flowing channel maximise heat losses across the proximal section, whereas thick, stable, mature crusts of ′a′a clinker reduce heat losses across the medial-distal section. This results in core cooling per unit distance that decreases from ~0.02–0.015°C m−1 across the proximal section, to ~0.005°C m−1 across the medial-distal section. This produces an increase in core viscosity from ~3800 Pa s at the vent to ~8000 Pa s across the distal section.
    Description: Published
    Description: L01301
    Description: 3.6. Fisica del vulcanismo
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: Kava Channel ; LIDAR ; thermal modeling ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
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  • 11
    Publication Date: 2017-04-04
    Description: Volcanoes deform as a consequence of the rise and storage of magma; once magma reaches a critical pressure, an eruption occurs. However, how the edifice deformation relates to its eruptive behavior is poorly known. Here, we produce a joint interpretation of spaceborne InSAR deformation measurements and volcanic activity at Mt. Etna (Italy), between 1992 and 2006. We distinguish two volcano-tectonic behaviors. Between 1993 and 2000, Etna inflated with a starting deformation rate of 1 cm yr 1 that progressively reduced with time, nearly vanishing between 1998 and 2000; moreover, low-eruptive rate summit eruptions occurred, punctuated by lava fountains. Between 2001 and 2005, Etna deflated, feeding higher-eruptive rate flank eruptions, along with large displacements of the entire East-flank. These two behaviors, we suggest, result from the higher rate of magma stored between 1993 and June 2001, which triggered the emplacement of the dike responsible for the 2001 and 2002–2003 eruptions. Our results clearly show that the joint interpretation of volcano deformation and stored magma rates may be crucial in identifying impending volcanic eruptions.
    Description: This work was partly funded by INGV and the Italian DPC and was supported by ASI, the Preview Project and CRdC-AMRA. DPC-INGV Flank project providing the funds for the publication fees.
    Description: Published
    Description: L02309
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 1.10. TTC - Telerilevamento
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: partially_open
    Keywords: deformation ; eruptions ; Mt. Etna ; eruptive cycle ; InSAR ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 12
    Publication Date: 2017-04-04
    Description: The 2002–2003 effusive eruption of Stromboli volcano represents an excellent opportunity to investigate the transition from effusive to explosive activity at an open-conduit basaltic system, when activity migrated from effusive vents, at the base of the craters, to summit explosions. The transition is investigated here through the analysis of very long period seismicity, delay times between infrasonic and thermal onsets of explosions, and SO2 flux recorded during a 1-year period. The synergy of the multiple geophysical observations points to a magma-driven migration of the magma column. Here the increased magma supply at the eruption onset lead to opening of effusive fissures, which draining the magma in the shallow conduit caused the decrease of the magma level. The decrease of the magma supply at the end of the effusion lead to sealing of effusive fissures, upraise of the magma level within the conduit, and reestablishment of explosive activity from the summit vents.
    Description: Unpublished
    Description: 11
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.10. TTC - Telerilevamento
    Description: 3.6. Fisica del vulcanismo
    Description: reserved
    Keywords: Stromboli ; SO2 Flux ; Magma column ; Infrasound ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 13
    Publication Date: 2017-04-04
    Description: This paper reports the use of diffusive tubes in determining HF, HCl, and SO2 in the volcanic plume of Mount Etna in an attempt to highlight the potential of this method in studying volcanoes. In a first application a network of 18 diffusive tubes was installed on Etna flanks, aimed at evaluating the atmospheric dispersion of the volcanic plume on a local scale. Results showed a monotonic decrease in volatile air concentrations with distance from the craters (HF from 0.15 to 〈0.003 mmol m3, HCl from 2 to 〈0.01 mmol m3, and SO2 from 11 to 0.04 mmol m3), revealing the prevalently volcanic contribution. Matching of SO2/HCl and HCl/HF volatile ratios with contemporaneous measurements at the summit craters validated the use of diffusive tubes in tracing the chemical features of a volcanic plume from remote locations. A first tentative assessment of dry deposition rates of volcanogenic acidic gases was also made, yielding 2.5 74 t d1 (SO2), 0.6 17 t d1 (HCl), and 0.02 0.6 t d1 (HF) and revealing the potential environmental impact of gas emissions. In a second experiment, carried out during the recent October 2002 to February 2003 eruption of Etna, diffusive tubes provided a continuous record of the chemical composition of the eruptive plume from a safe distance of 1 km from the vents, thus considerably decreasing the risks involved in sampling. This highlighted a clear time decrease in SO2 concentrations and SO2/HCl ratios, which was interpreted as due to progressive exhaustion of volatile degassing and eruption energy.
    Description: Published
    Description: D21308
    Description: partially_open
    Keywords: volcanic plumes ; impact of volcanic emissions ; sulfur and halogens chemistry ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 14
    Publication Date: 2017-04-04
    Description: In the last 13 years gas emissions from both the summit and the flanks of Mount Etna volcano have been monitored using remote sensing techniques (COSPEC, and FTIR since 2000) and on-site monitoring devices. The SO2 flux variations (600 to 25,000 Mg/day) indicated: (i) low values coinciding with deep seismicity prior to eruptions or/and preceding increases in summit volcanic activity; (ii) increasing trends tracking the ascent of fresh magma within the shallow feeding system and whose rate seems proportional to the speed of magma rise; (iii) decreasing trends related to progressive degassing of magma batches; (iv) an imbalance between the amount of magma erupted and that which contributed the SO2 emission (~ 13 % of the degassing magma having been erupted during the studied period), implying that magma degassing is dominantly intrusive; (v) a seasonal component, probably due to variations in solar zenith angle, meteorological parameters and, possibly, tidal forces.FTIR monitoring allowed to recognize significant variations of SO2/HCl and SO2/HF ratios in the volcanic plume which, combined with COSPEC data, provided new insight into the dynamics of ascent and degassing of discrete magma bodies. Strong variations in CO2-rich soil degassing are interpreted as markers of gradual magma ascent from great depth (〉10 km) to the upper (〈5 km) feeding system of Mt. Etna. These changes appear to precede increases in SO2 plume flux at the craters and, so, provide additional constraints upon the interpretation of COSPEC data and the modeling of magma rise at that volcano.
    Description: Published
    Description: 111-128
    Description: partially_open
    Keywords: Gas emissions ; Mt. Etna ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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    Type: book chapter
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  • 15
    Publication Date: 2017-04-04
    Description: The Jalisco Block (JB) is a geologically and tectonically complex part of northwestern Mexico characterized by active subduction-type volcanism, rifting, and old stable structures. Thermal springs and groups of springs are widely distributed over JB. Bubbling gas from seven thermal springs located within different tectonic environments of the JB was analyzed for He, 20Ne, and N2 concentrations and d15N ratios. All gases are N2-dominant (〉84%) with the exception of one sample (Rio´ Purificacio´n), which has a significant CH4 content (about 50%). All collected gas samples are relatively high in He, up to 1500 ppm vol and with 3He/4He values ranging from 0.6 to 4.5 Ra. All measured nitrogen isotope ratios are heavier than air with d15N values ranging from 0.5 to 5.0%. The relative N2 excess with respect to air-saturated water computed on the basis of N2 and 20Ne contents indicates the contribution of a nonatmospheric N2 source. All the samples show a good correlation between d15N and the relative excess of N2 with d15N +5.3% for the maximum N2 excess of 100%. Due to a presumed lack of seafloor sediment involved in the subduction process, such a d15N positive value seems to reflect the addition to the fluids of a heavy nitrogen originating from metamorphism processes of rocks occurring within the overlying continental crust.
    Description: Published
    Description: 1-9
    Description: partially_open
    Keywords: bubbling gases ; forearc region ; Jalisco Block-Mexico ; nitrogen isotopes ; subduction-related volcanism ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 16
    Publication Date: 2017-04-04
    Description: The performance of a newly-developed portable gas analyzer, capable of real-time measurement of CO2, SO2 and H2S concentrations in volcanic gases, was tested at La Fossa Crater, Vulcano Island. The gas analyzer was used to acquire about 3000 determinations over the fumarolic field, allowing the definition of its chemical structure and heterogeneity. Our high-resolution analysis reveals that, in December 2004, the La Fossa fumarolic field was characterized by an oxidized inner core (SO2/H2S ratios of 3), and by more reducing conditions on its northern edge (SO2/H2S ratios of 1; range: 0.2–3.3). CO2/(SO2+H2S) molar ratios averaged 35 ± 21, with overlapping compositions for rim and inner crater fumaroles. S-poor compositions (CO2/(SO2+H2S) 50) characterized the field margins, probably due to deposition of native sulfur. Based on the above data and an SO2 flux of 18 ± 3 t.d-1, we estimate CO2 and H2S output rates from the volcano of 420 ± 250 and 4 ± 2 t.d-1, respectively.
    Description: Published
    Description: L13309
    Description: partially_open
    Keywords: electrochemical sensors ; fumarolic gases ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 17
    Publication Date: 2017-04-04
    Description: Repeated phenomena of flank instability accompanied the 28 December 2002 to 21 July 2003 eruption of Stromboli volcano. The major episodes were two tsunamigenic landslides on 30 December 2002, 2 d after the volcano unrest. After 30 December, sliding processes remodeled the area affected by slope instability.We propose analyses of 565 sliding episodes taking place from December 2002 to February 2003.We try to shed light on their main seismic features and links with the ongoing seismic and volcanic activity using variogram analysis as well. A characterization of the seismic signals in the time and frequency domains is presented for 185 sliding episodes. Their frequency content is between 1 Hz and 7 Hz. On the basis of the dominant peaks and shape of the spectrum, we identify three subclasses of signals, one of which has significant energy below 2 Hz. Low-frequency signatures were also found in the seismic records of the landslides of 30 December, which affected the aerial and submarine northwestern flank of the volcano. Accordingly, we surmise that spectral analysis might provide evidence of sliding phenomena with submarine runouts.We find no evidence of sliding processes induced by earthquakes. Additionally, a negative statistical correlation between sliding episodes and explosion quakes is highlighted by variogram analysis. Variograms indicate a persistent behavior, memory, of the flank instability from 5 to 10 d.We interpret the climax in the occurrence rate of the sliding processes between 24 and 29 January 2003 as the result of favorable conditions to slope instability due to the emplacement of NW-SE aligned, dike-fed vents located near the scarp of the landslide area. Afterward, the stabilizing effect of the lava flows over the northwestern flank of the volcano limited erosive phenomena to the unstable, loose slope not covered by lava.
    Description: This work was supported financially by Istituto Nazionale di Geofisica e Vulcanologia and Dipartimento per la Protezione Civile, project INGV-DPC V4/02.
    Description: Published
    Description: Q04022
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: rockfalls ; seismicity ; volcanoes ; volcano collapses ; Stromboli ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 18
    Publication Date: 2017-04-04
    Description: We applied the Multi-GAS technique to measure compositions of the volcanic plumes continuously discharged from summit craters of Voragine, Northeast and Bocca Nuova at Mount Etna, in an attempt to estimate compositions of the source volcanic gases. The estimated CO2/SO2 and H2O/CO2 ratios of the volcanic gases show a large variation ranging from 0.6 to 30 and from 1 to 18, respectively. This variability overlaps with the compositional range of dissolved volatiles in melt inclusions and their coexisting bubbles in a magma chamber and can be caused by the low-pressure degassing of a magma with variable bubble content ranging from 0.3 to 15 wt.%. The variable bubble content in the magma is likely a result of supply of deep-derived CO2-rich gas phase to the chamber and subsequent bubble-magma differentiation by bubble ascent in the magma chamber. In contrast, the variation of volcanic gas composition can also be caused by changes of degassing pressure (gas–magma separation pressure), ranging from 0 to 100 MPa, as a result of changes in the depth of the top of the convecting magma in volcanic conduits. Both mechanisms can cause similar compositional variations. However, the two mechanisms will result in contrasting correlations between the SO2 emission rates and the gas compositions that can be examined by parallel observations of the emission rates and compositions in the future.
    Description: Published
    Description: B09203
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Plume ; gas ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 19
    Publication Date: 2017-04-04
    Description: We report the first measurements of volcanic gases with an unmanned aerial vehicle (UAV). The data were collected at La Fossa crater, Vulcano, Italy, during April 2007, with a helicopter UAV of 3 kg payload, carrying an ultraviolet spectrometer for remotely sensing the SO2 flux (8.5 Mg d 1), and an infrared spectrometer, and electrochemical sensor assembly for measuring the plume CO2/SO2 ratio; by multiplying these data we compute a CO2 flux of 170 Mg d 1. Given the deeper exsolution of carbon dioxide from magma, and its lower solubility in hydro-thermal systems, relative to SO2, the ability to remotely measure CO2 fluxes is significant, with promise to provide more profound geochemical insights, and earlier eruption forecasts, than possible with SO2 fluxes alone: the most ubiquitous current source of remotely sensed volcanic gas data.
    Description: Published
    Description: L06303
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Plume measurements ; carbon dioxide fluxes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 20
    Publication Date: 2017-04-04
    Description: A major explosion occurred at Stromboli on April 5 2003, being the most powerful event over a period of exceptional eruptive activity lasting from December to July. Here, we describe results from a network of diffusive tubes set up on the Stromboli’s summit area, aimed at a characterisation of plume composition (SO2, HCl, HF) prior to and after April 5. Data analysis revealed anomalous sulphur degassing 2–3 days before the event, when SO2/HCl ratios (9) significantly higher than those typical of quiescent degassing (1) were recorded. We interpret this exceptional plume signature as an evidence of S-rich magmas ascending in the shallow plumbing system, and propose high SO2/HCl as a potential precursor of major explosions on the volcano. The post-April 5 phase was characterised by time-decreasing SO2/HCl and SO2/HF plume ratios, ascribed to declining magma feeding as a prelude to restoration of ‘‘normal’’ Strombolian activity.
    Description: Published
    Description: L14607
    Description: partially_open
    Keywords: magmatic degassing ; paroxysm ; Stromboli ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 21
    Publication Date: 2017-04-04
    Description: On 2nd/3rd November 2002, a huge amount of gas, mainly composed of CO2, was suddenly released from the sea bottom off the coast of Panarea, producing a ‘‘crater’’20 by 10 meters wide and 7 meters deep. The gas output was estimated to be 109 l/d, two orders of magnitude higher than that measured in the 1980s. The anomalous degassing rate lasted for some weeks, slowly decreasing to an almost constant rate of about 4 x 107 l/d after two months. The geothermo- barometric estimations revealed an increase of both the temperature and pressure in the geothermal system feeding the sampled vents. The 3He/4He ratios were similar to those measured in nearby Stromboli. We have monitored the area for the last two decades, and based on our intensive and extensive geochemical measurements, have ascertained that the geothermal reservoir has lost its steady state. We maintain that a new magmatic input caused these phenomena.
    Description: - Istituto Nazionale di Geofisica e Vulcanologia, Osservatorio Vesuviano, Naples, Italy. - Istituto Nazionale di Geofisica e Vulcanologia, Sezione di Palermo, Palermo, Italy. - Dipartimento Chimica e Fisica della Terra ed Applicazioni, Palermo, Italy.
    Description: Published
    Description: L07619
    Description: partially_open
    Keywords: Submarine degassing ; magmatic fluids ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 22
    Publication Date: 2017-04-04
    Description: Five gas discharges in the area of Mount Etna volcano (Italy) and in the near Hyblean plateau have been monitored since 1996. All the emissions displayed low contributions from crustal fluids, whereas magmatic gases were the main component. Selective dissolution of these gases into hydrothermal aquifers has been recognized and modeled, allowing us to calculate the original composition of the magma-released gases. The inferred composition of the magmatic gases exhibits synchronous variations of He/Ne and He/CO2 ratios, which are coherent with the magma degassing process. On the basis of numerical simulations of volatile degassing from Etnean basalts we have computed the initial and final pressures of the magma batches feeding the emissions. We thus can define the levels of the Etna plumbing system where magmas are stored. Pressure values were around 360 and 160 MPa for initial and final stages, respectively, meaning related depths of about 10 and 3 km below sea level, matching those obtained by geophysical investigations for the deep and shallow magma reservoirs. In addition, we have been able to recognize episodes of magma migration from the deeper reservoir toward the shallow one. An important magma injection into the shallow storage volume was detected during the onset of the 2001 eruption (17 July). No further injection had taken place during this period until September 2001, providing a possible reason for the quick exhaustion of the eruption. In view of this we suggest that the sampled emissions are a powerful geochemical tool to investigate the Etna’s plumbing system and its magma dynamics, as well as the development of eruptive events.
    Description: Published
    Description: 2463
    Description: partially_open
    Keywords: gas geochemistry ; magma degassing ; modeling ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 23
    Publication Date: 2017-04-04
    Description: Five years of gas monitoring from selected sites suggest that Mt Etna’s plumbing system is much more extensive than previously reported. It extends at least 40 km SW from the volcano’s boundary along the NE-SW regional fault, where it discharges about 200 tons/day of gas, containing helium with mantle-type isotopic composition. Synchronous variations of 3He/4He isotopic ratios in gas sampled at sites located 60 kilometers apart have allowed us to detect pulses of ascending magma in the plumbing system, thus providing a powerful tool for eruption forecasting. Following summer 2001 eruption, the still increasing trend of the 3He/4He ratios indicates that magma storage is even now occurring at a shallow depth. Hence, the volcano maintains a high capacity to re-erupt within the next few months.
    Description: Published
    Description: 1057
    Description: partially_open
    Keywords: helium isotopes ; geochemical monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 24
    Publication Date: 2017-04-04
    Description: The 2002–2003 Etna eruption is studied through earthquake distributions and surface fracturing. In September 2002, earthquake-induced surface rupture (sinistral offset 0.48 m) occurred along the E-W striking Pernicana Fault (PF), on the NE flank. In late October, a flank eruption accompanied further ( 0.77 m) surface rupturing, reaching a total sinistral offset of 1.25 m; the deformation then propagated for 18 km eastwards to the coastline (sinistral offset 0.03 m) and southwards, along the NW-SE striking Timpe (dextral offset 0.04 m) and, later, Trecastagni faults (dextral offset 0.035 m). Seismicity (〈4 km bsl) on the E flank accompanied surface fracturing: fault plane solutions indicate an overall ESEWNWextension direction, consistent with ESE slip of the E flank also revealed by ground fractures. A three-stage model of flank slip is proposed: inception (September earthquake), climax (accelerated slip and eruption) and propagation (E and S migration of the deformation).
    Description: Published
    Description: 2286
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: volcano seismology ; surface fracturing ; flank slip ; eruption ; Etna ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 25
    Publication Date: 2017-04-04
    Description: Two-dimensional cross sections of the sulphur dioxide (SO2) distribution in the volcanic gas plume of Mt. Etna were reconstructed using tomographic techniques. The data for these projections were generated by a network of five automated scanning spectrometers, positioned on the flanks of the volcano. These measure slant-column amounts of SO2 at 105 different angles, every four minutes. Stable wind conditions allow the plume to be monitored on 82% of days. A time-series of plume cross sections was computed, revealing the potential of this method to track variations in plume position and structure on timescales of minutes to hours, a result of potential importance for air traffic and civil defence in case of eruption, when copious amounts of fine ash can be transported.
    Description: Published
    Description: L17811
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: tomography ; SO2 ; DOAS ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 26
    Publication Date: 2020-02-24
    Description: Measurements of 220Rn and 222Rn activity and of CO2 flux in soil and fumaroles were carried out on Mount Etna volcano in 2005–2006, both in its summit area and along active faults on its flanks. We observe an empirical relationship between (220Rn/222Rn) and CO2 efflux. The higher the flux of CO2, the lower the ratio between 220Rn and 222Rn. Deep sources of gas are characterized by high 222Rn activity and high CO2 efflux, whereas shallow sources are indicated by high 220Rn activity and relatively low CO2 efflux. Excess 220Rn highlights sites of ongoing shallow rock fracturing that could be affected by collapse, as in the case of the rim of an active vent. Depletion both in 220Rn and in CO2 seems to be representative of residual degassing along recently active eruptive vents.
    Description: This work was funded by the Istituto Nazionale di Geofisica e Vulcanologia (S.G., M.N.) and by the Dipartimento per la Protezione Civile (Italy), projects V3_6/28-Etna (M.N.) and V5/08-Diffuse degassing in Italy (S.G.), and NSF EAR 063824101 (K.W.W.S.).
    Description: Published
    Description: Q10001
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: radon ; thoron ; carbon dioxide ; rock stress ; gas transport ; Mount Etna ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 27
    Publication Date: 2020-05-29
    Description: In January 2002 Mount Nyiragongo erupted foiditic lavas that covered the Southern volcano flank devastating vast urban areas. Lava flows originated from vents at different heights on the eruptive fissure displayed different velocities, from tens of km/h at the highest vents to slow-advance (0.1–1 km/h) in Goma town several km away from the volcano. To understand the different behavior of lava flows and their threat to the local population, we undertook a multidisciplinary study involving textural and rheological measurements and numerical simulations of heat transfer during magma ascent. We demonstrate that pre-eruptive cooling and syn-eruptive undercooling of magma determined the different rheological behavior of lava flows erupted from vents at diverse heights. Venting at lower altitudes is expected to produce viscous, slowly advancing lavas, although development of fluid, faster flows should be included among possible future eruptive scenarios.
    Description: Published
    Description: L06301
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Nyiragongo volcano ; textural and rheological measurements ; numerical simulations ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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