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  • 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas  (21)
  • Elsevier  (13)
  • American Geophysical Union  (8)
  • 2010-2014  (21)
  • 1985-1989
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Keywords
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Year
  • 1
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    The effect of particle size on the rheology of liquid-solid mixtures with application to lava flows: Results from analogue experiments (2013)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: We investigate the effect of crystal size on the rheology of basaltic magmas by means of a rheometer and suspensions of silicon oil with natural magmatic crystals of variable size (from 63 to 0.5 mm) and volume fraction fi (from 0.03 to 0.6). At constant fi, finer suspensions display higher viscosities than coarser ones. Shear thinning (flow index n 〈 1) occurs at fi 〉 0.1–0.2 and is more pronounced (stronger departure from the Newtonian behavior) in finer suspensions. Maximum packing and average crystal size displays a nonlinear, positive correlation, while yield stress develops at fi 〉 0.2–0.3 irrespective of the crystal size. We incorporate our results into physical models for flow of lava and show that, with respect to lava flows containing coarser crystals, those with smaller crystals are expected to: 1) flow at lower velocity, 2) have a lower velocity gradient, and 3) be more prone to develop a region of plug flow. Our experimental results explain the observation that phenocryst-bearing and microlite-bearing lavas at Etna volcano (Italy) show smooth pahoehoe and rough aa’ surfaces, respectively.
    Description: FIRB-MIUR ‘‘Research and Development of New Technologies for Protection and Defense of Territory from Natural Risks’’
    Description: Published
    Description: 2661-2669
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: restricted
    Keywords: rheology ; magmatic suspensions ; analogue model ; lava flo ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 2
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    Enhanced crystal fabric analysis of a lava flow sample by neutron texture diffraction: A case study from the Castello d’Ischia dome (2013)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: The crystal fabric of a lava has been analyzed for the first time by neutron texture diffraction. In this study we quantitatively investigate the crystallographic preferred orientation of feldspars in the Castello d’Ischia (Ischia Island, Italy) trachytic exogenous dome. The crystallographic preferred orientation was measured with the monochromatic neutron texture diffractometer SV7 at the Forschungszentrum Jülich in Germany and a Rietveld refinement was applied to the sum diffraction pattern. The complementary thin section analysis showed that the three-dimensional crystal shape and the corresponding shape preferred orientation are in agreement with the quantitative orientation distributions of the neutron texture data. The (0k0) crystallographic planes of the feldspars are roughly parallel to the local flow bands, whereas the other corresponding pole figures show that a pivotal rotation of the anorthoclase and sanidine crystals was active during the emplacement of this lava dome. In combination with scanning electron microscopy investigations, electron probe microanalysis, XRF, and X-ray diffraction, the Rietveld refinement of the neutron diffraction data indicates a slow cooling dynamic on the order of several months during their crystallization under subaerial conditions. Results attained here demonstrate that neutron texture diffraction is a powerful tool that can be applied to lava flows.
    Description: Published
    Description: 179-196
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: restricted
    Keywords: neutron diffraction ; crystal fabric ; 04. Solid Earth::04.01. Earth Interior::04.01.04. Mineral physics and properties of rocks ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
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    Carbonate-derived CO2 purging magma at depth: Influence on the eruptive activity of Somma-Vesuvius, Italy (2012)
    Elsevier
    Details
    Publication Date: 2020-11-30
    Description: Mafic phenocrysts from selected products of the last 4 ka volcanic activity at Mt. Vesuvius were investigated for their chemical and O-isotope composition, as a proxy for primary magmas feeding the system. 18O/16O ratios of studied Mg-rich olivines suggest that near-primary shoshonitic to tephritic melts experienced a flux of sedimentary carbonate-derived CO2, representing the early process of magma contamination in the roots of the volcanic structure. Bulk carbonate assimilation (physical digestion) mainly occurred in the shallow crust, strongly influencing magma chamber evolution. On a petrological and geochemical basis the effects of bulk sedimentary carbonate digestion on the chemical composition of the near-primary melts are resolved from those of carbonate-released CO2 fluxed into magma. An important outcome of this process lies in the effect of external CO2 in changing the overall volatile solubility of the magma, enhancing the ability of Vesuvius mafic magmas to rapidly rise and explosively erupt at the surface.
    Description: Published
    Description: 84-95
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: stable-isotope ; magma geochemistry ; CO2-degassing ; Vesuvius ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
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    Comment on ‘Conduit convection, magma mixing, and melt inclusion trends at persistent degassing volcanoes’ by Fred Witham, published in Earth Planetary Science Letters (2011) 301, 345–352 (2012)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: No abstract
    Description: Published
    Description: 306-308
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Etna ; Stromboli ; volatiles ; melt inclusions ; magma mixing ; magma degassing ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
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  • 5
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    Integrated petrochemical and geophysical data reveals thermal distribution of the feeding conduits at Stromboli volcano, Italy (2012)
    American Geophysical Union
    Details
    Publication Date: 2020-02-24
    Description: Samples of scoriae erupted at Stromboli volcano during its persistent strombolian activity were collected between 2005 and 2008. Chemical and mineralogical compositions were obtained on products erupted from the three main crater sectors (SW, Central and NE). Small chemical variations indicate a different degree of evolution coupled with small difference of magma temperature 〈10°C. Analysis of the acoustic data for the same time period as the scoria sampling, indicates that puffing (a persistent overpressurized bubble degassing) was, on average, mainly observed at the central craters and at times moved to the NE sector. The cross-check of the two independent data sets allowed us to assess correlation between composition of products and puffing activity at vents. The hotter products are always erupted from the vents where puffing occurs indicating that slightly higher temperature can be the expression of an enhanced two-phase bubble flow dynamics.
    Description: Published
    Description: L08305
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Stromboli ; glass chemistry ; infrasound ; conduit dynamics ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
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    An analytical model for gas overpressure in slug-driven explosions: Insights into Strombolian volcanic eruptions (2012)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Strombolian eruptions, common at basaltic volcanoes, are mildly explosive events that are driven by a large bubble of magmatic gas (a slug) rising up the conduit and bursting at the surface. Gas overpressure within the bursting slug governs explosion dynamics and vigor and is the main factor controlling associated acoustic and seismic signals. We present a theoretical investigation of slug overpressure based on magma-static and geometric considerations and develop a set of equations that can be used to calculate the overpressure in a slug when it bursts, slug length at burst, and the depth at which the burst process begins. We find that burst overpressure is controlled by two dimensionless parameters: V′, which represents the amount of gas in the slug, and A′, which represents the thickness of the film of magma that falls around the rising slug. Burst overpressure increases nonlinearly as V′ and A′ increase. We consider two eruptive scenarios: (1) the “standard model,” in which magma remains confined to the vent during slug expansion, and (2) the “overflow model,” in which slug expansion is associated with lava effusion, as occasionally observed in the field. We find that slug overpressure is higher for the overflow model by a factor of 1.2–2.4. Applying our model to typical Strombolian eruptions at Stromboli, we find that the transition from passive degassing to explosive bursting occurs for slugs with volume 〉24–230 m3, depending on magma viscosity and conduit diameter, and that at burst, a typical Strombolian slug (with a volume of 100–1000 m3) has an internal gas pressure of 1–5 bars and a length of 13–120 m. We compare model predictions with field data from Stromboli for low-energy “puffers,” mildly explosive Strombolian eruptions, and the violently explosive 5 April 2003 paroxysm. We find that model predictions are consistent with field observations across this broad spectrum of eruptive styles, suggesting a common slug-driven mechanism; we propose that paroxysms are driven by unusually large slugs (large V′).
    Description: Published
    Description: B02206
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: restricted
    Keywords: Stromboli ; Taylor bubble ; basaltic volcanoes ; falling film ; gas slug ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
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  • 7
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    Xenopumices from the 2011–2012 submarine eruption of El Hierro (Canary Islands, Spain): Constraints on the plumbing system and magma ascent (2012)
    American Geophysical Union
    Details
    Publication Date: 2021-12-16
    Description: Textures, petrography and geochemical compositions of products emitted during the onset of the 2011–2012 submarine eruption (15 October, 2011) off the coast of El Hierro have been investigated to get information on interaction mechanism between the first rising magma and the crust during the onset of the eruption as well as to get information on magma storage and plumbing systems beneath El Hierro volcano. Studied products consist of 5–50 cm bombs with an outer black to greenish, vesicular crust with bulk basanite composition containing pumiceous xenoliths (xenopumices). Our results show that xenopumices are much more heterogeneous that previously observed, since consist of a macro-scale mingling of a gray trachyte and white rhyolite. We interpreted xenopumices as resulting from the interaction (heating) between the basanitic magma feeding the eruption, a stagnant trachytic magma pocket/s and an associated hydrothermally altered halo with rhyolitic composition. Our findings confirm the importance of the study of the early products of an eruption since they can contain crucial information on the plumbing system geometry and the mechanism of magma ascent.
    Description: Published
    Description: L17302
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: restricted
    Keywords: El Hierro ; submarine eruption ; xenopumice ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 8
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    Dynamic plumbing system beneath volcanoes revealed by kinetic modeling, and the connection to monitoring data: An example from Mt. Etna (2012)
    Elsevier
    Details
    Publication Date: 2023-01-27
    Description: Our ability to monitor volcanoes (using seismic signals, ground deformation, gas fluxes, or other ground and satellite based observations) as well as our understanding of melt reservoirs that feed eruptions have evolved tremendously in recent years. The complex plumbing systems that are thought to feed eruptions are, however, difficult to relate to the monitoring signals. Here we show that the record preserved in compositional zoning of erupted minerals may be used to reconstruct sections of the plumbing system. Kinetic modeling of such zoning can yield information on the residence time of magma in different segments of the plumbing systems. This allows a more nuanced evaluation of the link between observed monitoring signals or eruption styles and the magmatic processes and movement of batches of melts at depth. The approach is illustrated through a study of the compositional zoning recorded in olivine crystals from the 1991–1993 SE-flank eruption products of Mt. Etna (Sicily). The zoning patterns in crystals reveal that the plumbing system of the volcano consisted of at least three different magmatic environments between which magma was transported and mixed in the year or two preceding the start of eruption. Quantification of this history indicates that two main pathways of melt migration and three timescales dominated the dynamics of the system. Combination of this information with the timing of observation of various monitoring signals allows a reconstruction of the dynamic evolution of this section of the plumbing system during the early stages of the 1991–1993 eruption. It is seen, for example, how the migration of melt through the same sections of the plumbing system can cause pre-eruptive triggering, enhance Strombolian activity, and through the ensuing eruption cleanse and flush the plumbing system. Different kinds of mixing occur simultaneously at different sections of the plumbing system on different timescales (a few days up to two years).
    Description: Published
    Description: 11-22
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Etna ; plumbing system ; olivine ; zoning ; timescales ; monitoring ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 9
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    Magma vesiculation and infrasonic activity at Stromboli open conduit volcano (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Explosive activity at Stromboli is explained in terms of dynamics of large gas bubbles that ascend in the magma conduit and burst at the free surface generating acoustic pressure that propagates as infrasonic signals in the atmosphere. The rate and the amplitude of the infrasonic activity is directly linked to the rate and the overpressure of the bursting gas bubbles and thus reflects the rate at which magma column degasses under non-equilibrium pressure conditions. We investigate the link between explosive degassing and magma vesiculation by comparing the rate of infrasonic activity with the bubble size distributions (BSDs) of scoria clasts collected during several days of explosive activity at Stromboli. BSDs of scoria show a characteristic power law distribution, which reflect a gas bubble concentration mainly controlled by a combined process of bubble nucleation and coalescence. The cumulative distribution of the infrasonic pressure follows two power laws, indicating a clear separation between the frequent, but weak, bursting of small gas bubbles (puffing) and the more energetic explosions of large gas slugs. The exponents of power laws derived for puffing and explosive infrasonic activity show strongly correlated (0.96) changes with time indicating that when the puffing rate is high, the number of energetic explosions is also elevated. This correlation suggests that both puffing and explosive activity are driven by the same magma degassing dynamics. In addition, changes of both infrasonic power law exponents are very well correlated (0.92 with puffing and 0.87 with explosions) with variations of the BSD exponents of the scoria clasts, providing evidence of the strong interplay between scoria vesiculation and magma explosivity. Our analysis indicates that variable magma vesiculation regimes recorded in the scoria correlate with the event number and energy of the explosive activity. We propose that monitoring infrasound on active volcanoes may be an alternative way to look at the vesiculation process in open conduit systems.
    Description: Published
    Description: 274-280
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: Strombolian activity ; magma vesiculation ; infrasound ; conduit dynamics ; explosive volcanism ; bubble size distribution ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 10
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    Thirty years of satellite‐derived lava discharge rates at Etna: Implications for steady volumetric output (2011)
    American Geophysical Union
    Details
    Publication Date: 2020-02-24
    Description: We present a 30 year long data set of satellite‐derived time‐averaged lava discharge rates (TADR) for Mount Etna volcano (Sicily, Italy), spanning 1980–2010 and comprising 1792 measurements during 23 eruptions. We use this to classify eruptions on the basis of magnitude and intensity, as well as the shape of the TADR time series which characterizes each effusive event. We find that while 1983–1993 was characterized by less frequent but longer‐duration effusive eruptions at lower TADRs, 2000–2010 was characterized by more frequent eruptions of shorter duration and higher TADRs. However, roughly the same lava volume was erupted during both of these 11 year long periods, so that the volumetric output was linear over the entire 30 year period, increasing at a rate of 0.8 m3 s−1 between 1980 and 2010. The cumulative volume record can be extended back in time using data available in the literature. This allows us to assess Etna’s output history over 5 centuries and to place the current trend in historical context. We find that output has been stable at this rate since 1971. At this time, the output rate changed from a low discharge rate phase, which had characterized the period 1759 to 1970, to a high discharge rate phase. This new phase had the same output rate as the high discharge rate phase that characterized the period 1610–1669. The 1610–1669 phase ended with the most voluminous eruption of historic times.
    Description: This contribution is in support of the LMV‐based (PI: Franck Donnadieu) TerMex‐MYSTRALS project “Contribution à l’évaluation des risques associés aux activités éruptives majeures de l’Etna: approche multidisciplinaire des processus et précurseurs.”
    Description: Published
    Description: B08204
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: partially_open
    Keywords: Etna ; time averaged effusion rate ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 11
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    Transient effects of magma ascent dynamics along a geometrically variable dome-feeding conduit (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The transient dynamics of magma ascent during dome-forming eruptions were investigated and the effects of magma chamber pressure perturbations on eruption rate are illustrated. The numerical model DOMEFLOW, developed by the authors for this work, is applied to the problem. DOMEFLOW is a transient 1.5D isothermal two-phase flow model of magma ascent through an axisymmetric conduit of variable radius, which accounts for gas exsolution, bubble growth, crystallization induced by degassing, permeable gas loss through overlying magma and through conduit walls, as well as viscosity changes due to crystallization and degassing. For runs in which chamber pressure increases, the time required to reach the new steady state (transition time) is a complex function of the pressure perturbation, while for decreasing chamber pressure, transition time is a monotonic function of the magnitude of the pressure perturbation. The transition to the new steady state is mainly controlled by magma compressibility, travel time (time required for one parcel of magma to travel from chamber to surface), and the time over which the pressure perturbation occurs. Results of many runs (〉 300) were analyzed using dimensional analysis to reveal a general relationship which predicts the temporal evolution of magma effusion rate for a given sudden increase in chamber pressure; the product of the change in steady-state extrusion rate and the time required to reach the new steady state is linearly proportional to the normalized change in chamber pressure, the volume of the conduit, and the ratio of top and bottom conduit radii, and inversely proportional to the cubic root of volatile fraction. This relationship is used to interpret observed variations in two ongoing dome-building eruptions, the Soufrière Hills volcano, Montserrat, and Merapi volcano, Indonesia.
    Description: Published
    Description: 541-553
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: conduit dynamics ; conduit geometry ; magma ascent ; effusion rate ; computational model ; dome-building ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 05. General::05.01. Computational geophysics::05.01.05. Algorithms and implementation
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  • 12
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    The pre-eruptive volatile contents of recent basaltic and pantelleritic magmas at Pantelleria (Italy) (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Pantelleria Island, located in the Sicily Channel Rift Zone (Italy), is the type locality for the peralkaline rhyolitic rocks called pantellerites. In the last 50 ka, after the large Green Tuff caldera-forming eruption, volcanic activity at Pantelleria has consisted of effusive and explosive eruptions mostly vented inside and along the rim of the caldera and producing silicic lava flows, lava domes and poorly dispersed pantelleritic pumice fall deposits. Basaltic cinder cones and lava flows are only present outside the caldera in the NW sector of the island. The most recent basaltic (Cuddie Rosse, 20 ka) and pantelleritic (Cuddia Randazzo and Cuddia del Gallo, 6 ka) pyroclastic products were sampled to investigate magmatic volatile contents through the study of melt inclusions. The melt inclusions in pyroxene and olivine phenocrysts of Cuddie Rosse scoriae have an alkali basalt composition. The dissolved volatiles comprise 0.9–1.6 wt.% H2O, several hundred ppm of CO2, 1600–2000 ppm of sulphur and 500–900 ppm of chlorine. The water–carbon dioxide couple gives a confining pressure 2 kbar prior to the eruption. This result indicates that episodes of magma ponding and crystallization occurred in the upper crust prior to eruption. The melt inclusions in feldspar, fayalite and aenigmatite phenocrysts of Cuddia del Gallo and Cuddia Randazzo pumice have a pantelleritic composition (Agpaitic Indices 1.3–2.1), up to 4.4 wt.% H2O, 8700 ppm Cl, 6000 ppm F, and CO2 below the detection limit. Sulphur averaging 420 ppm has been measured in Cuddia Randazzo melt inclusions. These data indicate relatively high volatile contents for these low-energy Strombolian-type eruptions. Melt inclusions in Cuddia del Gallo pumice show the most evolved composition (Agpaitic Indices 2–2.1) and the highest volatile content, in agreement with fluid saturation conditions in the magma chamber prior to the eruption. This implies a confining pressure of 1 kbar for the top of the pantelleritic reservoir. The composition of melt inclusions and mineralogical assemblage of Cuddia Randazzo pumice indicate that it has a lower evolutionary degree (Agpaitic Indices 1.3–1.8) and lower pre-eruptive Cl and H2O contents than Cuddia del Gallo pumice. An increase in pressure due to the exsolution of volatiles in the upper part of the pantelleritic reservoir may have triggered the Cuddia del Gallo explosive eruption. Evidence of widespread pre-eruptive mingling between trachytes and pantellerites suggests that the intrusion of trachytic magma into the pantelleritic reservoir likely played a major role in destabilizing the magma system just prior to the Cuddia Randazzo event.
    Description: Published
    Description: 191-201
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Pantelleria ; peralkaline ; volatiles ; melt inclusions ; eruptive style ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 13
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    The feeding system of Agnano–Monte Spina eruption (Campi Flegrei, Italy): Dragging the past into present activity and future scenarios (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Magmatic processes triggering eruptions at Campi Flegrei caldera (southern Italy) and their relationships with the widespread emissions of fluids and caldera unrest episodes, are poorly constrained. The 4.1 ka B.P. Agnano–Monte Spina eruption, the reference event for a future large-size explosive eruption at Campi Flegrei, was investigated to shed light, through melt inclusion and isotope analyses, on the geochemical processes operating in the plumbing system. Chemical and isotopic data on whole rocks and glasses suggest that at least two magma batches mixed during the course of the eruption. Melt inclusion data highlight the pre-eruption storage conditions of two magmatic end-members. One end-member is like the less differentiated (shoshonitic) Campi Flegrei erupted magma, while the other could be a residual of the Neapolitan Yellow Tuff magma. Mixing between these two components was driven by a large gas phase which sustained the ascent of magmas of deep provenance. The H2O and CO2 contents in pyroxene-hosted melt inclusions yield entrapment pressures between 107 and 211 MPa, corresponding to depths between 4 and 8 km. The degassing trends reveal two extreme patterns. One pattern, already documented in the literature, is the volatile signature of poorly differentiated magmas ascending from more than 8 km depth, while the other is related to a gas-dominated magma, flushed by a CO2-rich gas phase partly released from the deep reservoir. This study provides a conceptual frame for unrest phases at Campi Flegrei, such as the 1982–84 event. Uplift phases can be related to closed-system ascent of magmas and fluids from more than 8 km depth, and their emplacement at shallow levels. This leads the shallow system to store, and then progressively release, the accumulated gas. In this view, both unrest episodes and eruptions could be strongly influenced by both the achievement of a critical upper limit of gas storage in the shallow magmatic reservoir and the stress and fracturing state of the roof rocks. The present results help to constrain the preeruptive conditions expected at Campi Flegrei caldera in case of a future large-size eruptive event.
    Description: Published
    Description: 135–147
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Sr and Nd isotopes ; Melt inclusions ; Gas flushing ; Magma mixing ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 14
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    A CO2-rich gas trigger of explosive paroxysms at Stromboli basaltic volcano, Italy (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: In addition to rhythmic slug-driven Strombolian activity, Stromboli volcano occasionally produces discrete explosive paroxysms (2 per year on average for the most frequent ones) that constitute a major hazard and whose origin remains poorly elucidated. Partial extrusion of the volatile-rich feeding basalt as aphyric pumice during these events has led to consider their triggering by the fast ascent of primitive magma blobs from possibly great depth. Here I examine and discuss the alternative hypothesis that most of the paroxysms could be triggered and driven by the fast upraise of CO2-rich gas pockets generated by bubble foam growth and collapse in the sub-volcano plumbing system. Data for the SO2 and CO2 crater plume emissions are used to show that Stromboli's feeding magma may originally contain as much as 2 wt.% of carbon dioxide and early coexists with an abundant CO2-rich gas phase with high CO2/SO2 molar ratio (≥60 at 10 km depth below the vents, compared to ∼7 in time-averaged crater emissions). Pressure-related modelling indicates that the time-averaged crater gas composition and output are well accounted for by closed system decompression of the basalt–gas mixture until the volcano–crust interface (∼3 km depth), followed by open degassing and crystallization in the volcano conduits. However, both the low viscosity and high vesicularity of the basaltic magma permit bubble segregation and bubble foam growth at deep sill-like feeder discontinuities and at shallower physical boundaries (such as the volcano–crust interface) where the gasrich aphyric basalt interacts with the unerupted crystal-rich and viscous magma drained back from the volcano conduits. Gas pressure build-up and bubble foam collapse at these boundaries will intermittently trigger the sudden upraise of CO2-rich gas blobs that constitute the main driving force of the paroxysms. Deeper-sourced gas blobs, driving the most powerful explosions, will be the richest in CO2 and have highest CO2/SO2 ratios. This mechanism is shown to account well for the dynamic, seismic and petrologic features of Stromboli's paroxysms and, hence, to provide a potential alternative interpretation for their genesis and their forecasting. Enhanced bubble foam leakage prior to a paroxysm, or foam emptying in several steps, should lead indeed to precursory upstream of CO2-rich gas and increasing CO2/SO2 ratio in crater plume emissions. The recent detection of such signals prior to two explosions in December 2006 and March 2007 strongly supports this expectation and the model proposed in this study.
    Description: Published
    Description: 363–374
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: basaltic volcanoes ; magma degassing ; explosive paroxysms ; CO2 ; gas bubbles ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 15
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    Carbonate assimilation in magmas: a reappraisal based on experimental petrology (2010)
    Elsevier
    Details
    Publication Date: 2020-11-13
    Description: The main effect of magma-carbonate interaction on magma differentiation is the formation of a silica-undersaturated, alkali-rich residual melt. Such a desilication process was explained as the progressive dissolution of CaCO3 in melt by consumption of SiO2 and MgO to form diopside sensu stricto. Magma chambers emplaced in carbonate substrata, however, are generally associated with magmatic skarns containing clinopyroxene with a high Ca-Tschermak activity in their paragenesis. Data are presented from magma-carbonate interaction experiments, demonstrating that carbonate assimilation is a complex process involving more components than so far assumed. Experimental results show that, during carbonate assimilation, a diopside-hedenbergite-Ca-Tschermak clinopyroxene solid solution is formed and that Ca-Tschermak/diopside and hedenbergite/diopside ratios increase as a function of the progressive carbonate assimilation. Accordingly, carbonate assimilation reaction should be written as follows, taking into account all the involved magmatic components: CaCO3solid+SiO2melt+MgOmelt+FeOmelt+Al2O3melt → (Di-Hd-CaTs)sssolid+CO2fluid The texture of experimental products demonstrates that carbonate assimilation produces three-phases (solid, melt, and fluid) whose main products are: i) diopside-hedenbergite-Ca-Tschermak clinopyroxene solid solution; ii) silica-undersaturated CaO-rich melt; and iii) C-O-H fluid phase. The silica undersaturation of the melt and, more importantly, the occurrence of a CO2-rich fluid phase, must be taken into account as they significantly affect partition coefficients and the redox state of carbonated systems, respectively.
    Description: TRIGS Project “Sixth Framework Programme of the European Commission and to the New and Emerging Science and Technology Pathfinder". Project FIRB MIUR “Development of innovative technologies for the environmental protection from natural events”.
    Description: Published
    Description: 503-514
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Description: open
    Keywords: carbonate assimilation ; skarns ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
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  • 16
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    Shifting styles of basaltic explosive activity during the 2002-03 eruption of Mt. Etna, Italy (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The 2002–03 flank eruption of Etna was characterized by two months of explosive activity that produced copious ash fallout, constituting a major source of hazard and damage over all eastern Sicily. Most of the tephra were erupted from vents at 2750 and 2800 m elevation on the S flank of the volcano, where different eruptive styles alternated. The dominant style of explosive activity consisted of discrete to pulsing magma jets mounted by wide ash plumes, which we refer to as ash-rich jets and plumes. Similarly, ash-rich explosive activity was also briefly observed during the 2001 flank eruption of Etna, but is otherwise fairly uncommon in the recent history of Etna. Here, we describe the features of the 2002–03 explosive activity and compare it with the 2001 eruption in order to characterize ash-rich jets and plumes and their transition with other eruptive styles, including Strombolian and ash explosions, mainly through chemical, componentry and morphology investigations of erupted ash. Past models explain the transition between different styles of basaltic explosive activity only in terms of flow conditions of gas and liquid. Our findings suggest that the abundant presence of a solid phase (microlites) may also control vent degassing and consequent magma fragmentation and eruptive style. In fact, in contrast with the Strombolian or Hawaiian microlite-poor, fluidal, sideromelane clasts, ash-rich jets and plumes produce crystal-rich tachylite clasts with evidence of brittle fragmentation, suggesting that high groundmass crystallinity of the very top part of the magma column may reduce bubble movement while increasing fragmentation efficiency.
    Description: Published
    Description: 110-122
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Etna ; basaltic explosive activity ; ash-rich jet and plume ; tachylite ; sideromelane ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 17
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    Anatomy of an unstable volcano from InSAR: Multiple processes affecting flank instability at Mt. Etna, 1994–2008 (2010)
    American Geophysical Union
    Details
    Publication Date: 2012-02-03
    Description: An edited version of this paper was published by AGU. Copyright (2010) American Geophysical Union.
    Description: Volcano deformation may occur under different conditions. To understand how a volcano deforms, as well as relations with magmatic activity, we studied Mt. Etna in detail using interferometric synthetic aperture radar (InSAR) data from 1994 to 2008. From 1994 to 2000, the volcano inflated with a linear behavior. The inflation was accompanied by eastward and westward slip on the eastern and western flanks, respectively. The portions proximal to the summit showed higher inflation rates, whereas the distal portions showed several sectors bounded by faults, in some cases behaving as rigid blocks. From 2000 to 2003, the deformation became nonlinear, especially on the proximal eastern and western flanks, showing marked eastward and westward displacements, respectively. This behavior resulted from the deformation induced by the emplacement of feeder dikes during the 2001 and 2002–2003 eruptions. From 2003 to 2008, the deformation approached linearity again, even though the overall pattern continued to be influenced by the emplacement of the dikes from 2001 to 2002. The eastward velocity on the eastern flank showed a marked asymmetry between the faster sectors to the north and those (largely inactive) to the south. In addition, from 1994 to 2008 part of the volcano base (south, west, and north lower slopes) experienced a consistent trend of uplift on the order of ∼0.5 cm/yr. This study reveals that the flanks of Etna have undergone a complex instability resulting from three main processes. In the long term (103–104 years), the load of the volcano is responsible for the development of a peripheral bulge. In the intermediate term (≤101 years, observed from 1994 to 2000), inflation due to the accumulation of magma induces a moderate and linear uplift and outward slip of the flanks. In the short term (≤1 year, observed from 2001 to 2002), the emplacement of feeder dikes along the NE and south rifts results in a nonlinear, focused, and asymmetric deformation on the eastern and western flanks. Deformation due to flank instability is widespread at Mt. Etna, regardless of volcanic activity, and remains by far the predominant type of deformation on the volcano.
    Description: ESA provided the SAR data (Cat‐1 no. 4532 and GEO Supersite initiative). The DEM was obtained from the SRTM archive, while the ERS‐1/2 orbits are courtesy of the TU‐Delft, The Netherlands. This work was partially funded by INGV and the Italian DPC (DPCINGV project V4 “Flank”), the Italian DPC (under special agreement with IREA‐CNR), and the Italian Space Agency under contract “sistema rischio vulcanico (SRV).” The authors thank Francesco Casu, Paolo Berardino, and Riccardo Lanari for their support and Geoff Wadge and Michael Poland for their helpful and constructive review of the manuscript.
    Description: Published
    Description: B10405
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 1.10. TTC - Telerilevamento
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Flank instability ; InSAR ; volcanoes ; Etna ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 05. General::05.04. Instrumentation and techniques of general interest::05.04.99. General or miscellaneous ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
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  • 18
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    The feeding system of Agnano–Monte Spina eruption (Campi Flegrei, Italy): Dragging the past into present activity and future scenarios (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Magmatic processes triggering eruptions at Campi Flegrei caldera (southern Italy) and their relationships with the widespread emissions of fluids and caldera unrest episodes, are poorly constrained. The 4.1 ka B.P. Agnano–Monte Spina eruption, the reference event for a future large-size explosive eruption at Campi Flegrei, was investigated to shed light, through melt inclusion and isotope analyses, on the geochemical processes operating in the plumbing system. Chemical and isotopic data on whole rocks and glasses suggest that at least two magma batches mixed during the course of the eruption. Melt inclusion data highlight the pre-eruption storage conditions of two magmatic end-members. One end-member is like the less differentiated (shoshonitic) Campi Flegrei erupted magma, while the other could be a residual of the Neapolitan Yellow Tuff magma. Mixing between these two components was driven by a large gas phase which sustained the ascent of magmas of deep provenance. The H2O and CO2 contents in pyroxene-hosted melt inclusions yield entrapment pressures between 107 and 211 MPa, corresponding to depths between 4 and 8 km. The degassing trends reveal two extreme patterns. One pattern, already documented in the literature, is the volatile signature of poorly differentiated magmas ascending from more than 8 km depth, while the other is related to a gas-dominated magma, flushed by a CO2-rich gas phase partly released from the deep reservoir. This study provides a conceptual frame for unrest phases at Campi Flegrei, such as the 1982–84 event. Uplift phases can be related to closed-system ascent of magmas and fluids from more than 8 km depth, and their emplacement at shallow levels. This leads the shallow system to store, and then progressively release, the accumulated gas. In this view, both unrest episodes and eruptions could be strongly influenced by both the achievement of a critical upper limit of gas storage in the shallow magmatic reservoir and the stress and fracturing state of the roof rocks. The present results help to constrain the pre-eruptive conditions expected at Campi Flegrei caldera in case of a future large-size eruptive event.
    Description: In press
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Sr and Nd isotopes ; Melt inclusions ; Gas flushing ; Magma mixing ; Bradyseismic crises ; Explosive eruptions ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 19
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    Heterogeneous large total CO2 abundance in the shallow magmatic system of Kilauea volcano, Hawaii (2010)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Due to its very low solubility in silicate melts, CO2 concentrations in melt inclusions (MIs) within crystals are commonly orders of magnitude less than the total concentration in the multiphase magma, strongly limiting the possibility to constrain CO2 abundance based on the dissolved quantities. Here we develop a statistical method to process MI data, which allows analytical uncertainties to be taken into account together with the peculiar features of the local saturation surface. The method developed leads to retrieve total H2O and CO2 concentrations in magma as well as the gas phase abundance at the time of magma crystallization. Application to a set of 29 high-resolution secondary ion mass spectrometry (SIMS) MI data from a single specimen of the 1842–1844 eruption of Kilauea, Hawaii, reveals the existence of heterogeneous total CO2 abundance, and of at least 2–6 wt % total CO2 in some magma batches, two orders of magnitude higher than the dissolved amounts and 30–50 times more abundant than the corresponding total H2O content. Heterogeneous total volatile concentrations are interpreted as due to a combination of degassing and gas flushing in magma subject to convective motion at shallow depth where P 〈 100 MPa. In such a view, the magma rising to shallow depth in the volcanic system carries initially a total volatile content ≤1 wt %, corresponding to the determined low total CO2 population, and consistent with previous global estimates. The high CO2 populations correspond to progressive CO2 enrichment due to degassing at low P and flushing from a deep CO2-rich gas. A total CO2 content 〉1 wt % is likely to characterize the 〉30 km deep magma, not represented in the analyzed inclusions, from which a CO2-rich gas phase exsolves and decouples from the liquid.
    Description: Published
    Description: B12201
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: carbon dioxide ; Kilauea volcano ; conduit dynamics ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
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  • 20
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    The pre-eruptive volatile contents of recent basaltic and pantelleritic magmas at Pantelleria (Italy) (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Pantelleria Island, located in the Sicily Channel Rift Zone (Italy), is the type locality for the peralkaline rhyolitic rocks called pantellerites. In the last 50 ka, after the large Green Tuff caldera-forming eruption, volcanic activity at Pantelleria has consisted of effusive and explosive eruptions mostly vented inside and along the rim of the caldera and producing silicic lava flows, lava domes and poorly dispersed pantelleritic pumice fall deposits. Basaltic cinder cones and lava flows are only present outside the caldera in the NW sector of the island. The most recent basaltic (Cuddie Rosse, 20 ka) and pantelleritic (Cuddia Randazzo and Cuddia del Gallo, 6 ka) pyroclastic products were sampled to investigate magmatic volatile contents through the study of melt inclusions. The melt inclusions in pyroxene and olivine phenocrysts of Cuddie Rosse scoriae have an alkali basalt composition. The dissolved volatiles comprise 0.9–1.6 wt.% H2O, several hundred ppm of CO2, 1600–2000 ppm of sulphur and 500–900 ppm of chlorine. The water–carbon dioxide couple gives a confining pressure 2 kbar prior to the eruption. This result indicates that episodes of magma ponding and crystallization occurred in the upper crust prior to eruption. The melt inclusions in feldspar, fayalite and aenigmatite phenocrysts of Cuddia del Gallo and Cuddia Randazzo pumice have a pantelleritic composition (Agpaitic Indices 1.3–2.1), up to 4.4 wt.% H2O, 8700 ppm Cl, 6000 ppm F, and CO2 below the detection limit. Sulphur averaging 420 ppm has been measured in Cuddia Randazzo melt inclusions. These data indicate relatively high volatile contents for these low-energy Strombolian-type eruptions. Melt inclusions in Cuddia del Gallo pumice show the most evolved composition (Agpaitic Indices 2–2.1) and the highest volatile content, in agreement with fluid saturation conditions in the magma chamber prior to the eruption. This implies a confining pressure of 1 kbar for the top of the pantelleritic reservoir. The composition of melt inclusions and mineralogical assemblage of Cuddia Randazzo pumice indicate that it has a lower evolutionary degree (Agpaitic Indices 1.3–1.8) and lower pre-eruptive Cl and H2O contents than Cuddia del Gallo pumice. An increase in pressure due to the exsolution of volatiles in the upper part of the pantelleritic reservoir may have triggered the Cuddia del Gallo explosive eruption. Evidence of widespread pre-eruptive mingling between trachytes and pantellerites suggests that the intrusion of trachytic magma into the pantelleritic reservoir likely played a major role in destabilizing the magma system just prior to the Cuddia Randazzo event.
    Description: In press
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Pantelleria ; peralkaline ; volatiles ; melt inclusions ; eruptive style ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
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  • 21
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    Dependence of clinopyroxene composition on cooling rate in basaltic magmas: Implications for thermobarometry (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The compositional variation of clinopyroxene and the partitioning ofmajor elements between clinopyroxene and melt are estimated as a function of the cooling rate. Clinopyroxenes were crystallized under variable cooling regimes (15, 9.4, 3, 2.1, and 0.5 °C/min from1250 down to 1000 °C) and at isothermal conditions of 1000 °C from a basaltic composition at a pressure of 500 MPa under anhydrous and hydrous (H2O=1.3 wt.%) conditions. The clinopyroxene chemistry shows that, as the cooling rate increases, crystals are progressively depleted in Ca,Mg, Fe2+ and Si and enriched inNa, Fe3+, Al (mainlyAlIV), and Ti. Di andHd versus CaTs and CaFeTs forma continuous binary solid solution characterized by higher amounts of tschermakitic componentswith increasing cooling rate. Two parameters (DH=Di+Hd and TE=CaTs+CaFeTs+En) are calculated to describe the effect of cooling rate on the clinopyroxene composition. The variation of DH/TE with increasing cooling rate evidences the kinetic process induced by rapid cooling in basic rocks under hydrous and anhydrous conditions. Dynamic crystallization conditions affect the partitioning of major elements between clinopyroxene and melt; with increasing cooling rate, the value of crystal–melt partition coefficient departs from that obtained at the isothermal condition. However, in spite of these variations, the values of cpx–meltKdFe–Mg remain almost constant. Therefore, the Fe2–Mg exchange between clinopyroxene and melt is not suitable to prove the (dis)equilibrium conditions in basaltic coolingmagmas, giving rise to possiblemismatches in the application of thermobarometers. The results of our study are consistentwith that observed at themargin of dikes or inthe exterior portions of lavas, where the cooling rate is maximized and disequilibrium compositions of clinopyroxene have been found.
    Description: Published
    Description: 302-312
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: reserved
    Keywords: cooling rate ; clinopyroxene ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
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