ALBERT

Description: Bioguided fractionation of Agelas cerebrum crude extract resulted in isolation of four bromopyrrole and four bromopyrrole aminoimidazole alkaloids, identified as 5-bromopyrrole-2-carboxylic acid (1), 4-bromopyrrole-2-carboxylic acid (2), 3,4-bromopyrrole-2-carboxylic acid (3), 4,5-bromopyrrole-2-carboxylic acid (4), oroidin (5), bromoageliferin (6), dibromoageliferin (7) and dibromosceptrin (8) on the basis of spectroscopic data analyses (UV, IR, HRMS, 1D and 2D NMR) and comparison with literature data. This is the first report of compounds 2 and 3 in a marine sponge belonging to the Agelas genus and the first evidence of the presence of 1 from a natural source.

Description: Published

Description: Agelas cerebrum, bromopyrrole alkaloids, antitumoral, antiprotozoal activity

Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution August 1984

Description: This thesis addresses several aspects of the problem of determining the effect of the low-frequency eddy variability on the mean circulation of the Western North Atlantic. A framework for this study is first established by scale analysis of the eddy and mean terms in the mean momentum, vorticity, and heat balances in three regions of the Western North Atlantic -- the northern recirculation, the southern recirculation, and the mid-ocean. The data from the last decade of field experiments suggest somewhat different conclusions from the earlier analysis of Harrison (1980). In the momentum balance we confirm that the eddy terms are negligible compared to the lowest order mean geostrophic balance. The eddy term may be an 0(1) term in the vorticity balance only in the northern recirculation region where the mean flow is anisotropic. In the mean heat balance, if the mean temperature advection is scaled using the thermal wind relation, then the eddy heat flux is negligible in the mid-ocean, but it may be important in the recirculation areas. For all the balances the eddy terms are comparable to or an order of magnitude larger than the mean advective terms. We conclude from the scale analysis that the eddy field is most likely to be important in the Gulf Stream recirculation region. These balances are subsequently examined in more detail using data from the Local Dynamics Experiment (LDE). Several inconsistencies are first shown in McWilliams' (1983) model for the mean dynamical balances in the LDE. The sampling uncertainties do not allow us to draw conclusions about the long-term dynamical balances. However, it is shown that if we assume that the linear vorticity balance holds between the surface and the thermocline for a finite record, then the vertical velocity induced by the eddy heat flux divergence is non-zero. The local effect of the mesoscale eddy field on the mean potential vorticity distribution of the Gulf Stream recirculation region is determined from the quasigeostrophic eddy potential vorticity flux. This flux is calculated by finite difference of current and temperature time series from the Local Dynamics Experiment. This long-term array of moorings is the only experimental data from which the complete eddy flux can be calculated. The total eddy flux is dominated by the term due to the time variation in the thickness of isopycnal layers. This thickness flux is an order of magnitude larger than the relative vorticity flux. The total flux is statistically significant and directed 217° T to the southwest with a magnitude of 1.57 x 10 -5 cm/2s. The direction of the eddy flux with respect to the mean large scale potential vorticity gradient from hydrographic data indicates that eddies in this region tend to reduce the mean potential vorticity gradient. The results are qualitatively consistent with numerical model results and with other data from the Gulf Stream recirculation region. We find that the strength of the eddy transfer in the enstrophy cascade is comparable to the source terms in the mean enstrophy balance. The Austauch coefficient for potential vorticity mixing is estimated to be 0(107cm2/sec). An order of magnitude estimate of the enstrophy dissipation due only to the internal wave field shows that other processes must be important in enstrophy dissipation. The measured eddy potential vorticity fluxes are compared to the linear stability model of Gill, Green, and Simmons (1974). An earlier study (Hogg, 1984) has shown agreement between the empirical orthogonal modes of the data and the predicted wavenumbers, growth rates, and phase speeds of the most unstable waves. However, we show substantial disagreement in a comparison of the higher moments the eddy heat and potential vorticity fluxes. Because the critical layer of the model is located near the surface, the model predicts that most of the eddy potential vorticity and eddy heat flux should occur within about 300 meters of the surface. The data show much greater deep eddy heat flux than predicted by the model. It is suggested that the unstable modes in the ocean have a longer vertical scale because of the reduction in the buoyancy frequency near the surface. The evidence for in situ instability is also examined in the decay region of the Gulf Stream from an array of current and temperature recorders. Although there is vertical phase propagation in the empirical orthogonal modes for some of the variables at some of the moorings, there is not much evidence for a strong ongoing process of wave generation.

Description: This research has been conducted under NSF contract numbers OCE 77-19403, ATM 79-21431, and OCE 82-00154.

Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 1996

Description: This thesis addresses the question of how a highly energetic eddy field could be generated in the interior of the ocean away from the swift boundary currents. The energy radiation due to the temporal growth of non-trapped (radiating) disturbances in such a boundary current is thought to be one of the main sources for the described variability. The problem of stability of an energetic current, such as the Gulf Stream, is formulated. The study then focuses on the ability of the current to support radiating instabilities capable of significant penetration into the far-field and their development with time. The conventional model of the Gulf Stream as a zonal current is extended to allow the jet axis to make an angle to a latitude circle. The linear stability of such a nonzonal flow, uniform in the along-jet direction on a beta-plane, is first studied. The stability computations are performed for piece-wise constant and continuous velocity profiles. New stability properties of nonzonal jets are discussed. In particular, the destabilizing effect of the meridional tilt of the jet axis is demonstrated. The radiating properties of nonzonal currents are found to be very different from those of zonal currents. In particular, purely zonal flows do not support radiating instabilities, whereas flows with a meridional component are capable of radiating long and slowly growing waves. The nonlinear terms are then included in the consideration and the effects of the nonlinear interactions on the radiating properties of the solution are studied in detail. For these purposes, the efficient numerical code for solving equation for the QG potential vorticity with open boundary conditions of Orlanski's type is constructed. The results show that even fast growing linear solutions, which are trapped during the linear stage of developement, can radiate energy in the nonlinear regime if the basic current is nonzonal. The radiation starts as soon as the initial fast exponential growth significantly slows. The initial trapping of those solutions is caused by their fast temporal growth. The new mechanism for radiation is related to the nonzonality of a current.

Description: This work was supported by NSF Grant OCE 9301845.

Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution December 1996

Description: Two-thirds of the surface of the Earth is created at mid-ocean ridges where magmas rise from the mantle and cool to form the oceanic crust. The objective of this Thesis is to examine the influence of magma supply and eruptive processes on axial morphology, crustal construction, and the properties of crustal magma chambers at intermediate and fast spreading ridges. Variations in magma supply on time scales of ~100 Kyr generate along-axis changes in crustal thickness and temperature. Magma sill properties and hydrothermal activity are closely linked to spreading events which occur on much shorter time scales (ca. 10-100 yr) than the longer-term variations in magma supply reflected in along-axis changes in ridge morphology. The seismically constrained depths of ridge crest magma sills (〉1-2 km) are considerably deeper than the level of neutral buoyancy (100-400 m). The apparent inverse relationship between magma sill depth and spreading rate suggests that a thermally controlled permeability boundary, such as the solidus horizon, controls the depth at which magma ponds beneath mid-ocean ridges. Recent thermo-mechanical models predict that, at intermediate spreading rates, rift valley and magma sill formation are sensitive to small changes in crustal thickness and mantle temperature. Analysis of gravity at an intermediate spreading ridge shows that small differences in crustal thickness (300-700 m) and mantle temperature (10-15°C) are indeed sufficient to produce major changes in lithospheric strength and axial morphology. A stochastic model for the emplacement of dikes and lava flows with a bimodal distribution of lava flows is required to satisfy geological and geophysical constraints on the construction of the extrusive section. Most dikes are intruded within a narrow zone at the ridge axis. Short flows build up approximately half the extrusive volume. Occasional flows that pond at a considerable distance off-axis build up the remainder of the extrusive section. This Thesis underlines the importance of eruption dynamics in the emplacement of the uppermost volcanic layer of the crust and of the crustal thermal structure in controlling local variations in magma sill depth and ridge morphology.

Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February 2013

Description: Studying oceanic eddies is important for understanding and predicting ocean circulation and climate variability. The central focus of this dissertation is the energy exchange between eddies and mean flow and banded structures in the low-frequency component of the eddy field. A combination of a realistic eddy-permitting ocean state estimate and simplified theoretical models is used to address the following specific questions. (1) What are the major spatial characteristics of eddy-mean flow interaction from an energy perspective? Is eddy-mean flow interaction a local process in most ocean regions? (2) The banded structures in the low-frequency eddy field are termed striations. How much oceanic variability is associated with striations? How does the time-mean circulation, for example a subtropical gyre or constant mean flow, influence the origin and characteristics of striations? How much do striations contribute to the energy budget and tracer mixing?

Description: This research was supported by the National Aeronautics and Space Administration contracts NNX09AI87G and NNX08AR33G.

Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February 1999

Description: This thesis addresses the parameterization of the heat and momentum transporting properties of eddy motions for use in three-dimensional, primitive equation, z-coordinate atmosphere and ocean models. Determining the transport characteristics of these eddies is fundamental to understanding their effect on the large-scale ocean circulation and global climate. The approach is to transform the primitive equations to yield the altered 'transformed Eulerian mean' (TEM) equations. The assumption is made that the eddy motions obey quasigeostrophic dynamics while the mean flow obeys the primitive equations. With this assumption, the TEM framework leads to the eddies appearing as one term, which acts as a body force in the momentum equations. This force manifests itself as a flux of potential vorticity (PV) - a quantity that incorporates both eddy momentum and heat transporting properties. Moreover, the dynamic velocities are those of the residual mean circulation, a much more relevant velocity for understanding heat and tracer transport. Closure for the eddy PV flux is achieved through a flux-gradient relationship, which directs the flux down the large scale PV gradient. For zonal flows, care is taken to ensure that the resulting force does not generate any net momentum, acting only to redistribute it. Neglect of relative vorticity fluxes in the PV flux yields the parameterization scheme of Gent and McWilliams. The approach is investigated by comparing a zonally-averaged parameterized model with a three dimensional eddy-resolving calculation of flow in a stress-driven channel. The stress at the upper surface is communicated down the water column to the bottom by eddy form drag. Moreover, lateral eddy momentum fluxes act to strengthen and sharpen the mean flow, transporting eastward momentum up its large scale gradient. Both the vertical momentum transfer and lateral, upgradient momentum transfer by eddies, are captured in the parameterized model. The advantages of this approach are demonstrated in two further zonal cases: 1) the spin-down of a baroclinic zone, and 2) the atmospheric jet stream. The time mean TEM approach and the eddy PV flux closure are explored in the context of an eddy-resolving closed basin flow which breaks the zonal symmetry. Decomposition of eddy PV fluxes into components associated with advective and dissipative effects suggest that the component associated with eddy flux divergence, and therefore forcing of the mean flow, is mainly directed down the large scale gradient and can be parameterized as before. Thus, the approach can be used to capture eddy transport properties for both zonal mean and time mean flows. The PV flux embodies both the eddy heat and momentum fluxes and so presents a more unified picture of their transferring properties. It therefore provides a powerful conceptual and practical framework for representing eddies in numerical models of the atmsophere and ocean.

Description: The work in this thesis was funded by grants from NSF, (OCE-9634331, OCE- 9503895), ONR (NOOOI4-95-1-0967), and by a fellowship from the Joint Program on the Science and Policy of Global Change at MIT.

Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution May 1997

Description: Many of the most important processes that create and modify continental crust occur at continental margins, but recently has the scientific community acquired the necessary intrumentation to image crustal structure across margins in detail. In this thesis we investigate the crustal structure across the U.S. East Coast rifted margin and the convergent margin of southwestern Alaska using modern, deep-penetrating marine seismic reflection/refraction data. We consider U.S. East Coast margin transects along the shelf offshore Georgia and across the mid-Atlantic margin near Chesapeak bay. Results by other workers, based on data from these transects, have shown that voluminous volcanism accompanied formation of the rifted margin during continental breakup. Results presented in this thesis constrain the landward extent of rift-related magmatic emplacement. We find that magmatic intrusion and underplating of pre-existing continental crust occurs primarily in extended crust and that crustal extension is focused in a 75-km-wide region beneath the shelf and slope. The crust thinned by 50 to 80% within this interval and then seafloor spreading began with an unusually large volume of igneous crust production. The initial volcanic extrusives were emplaced subaerially and are now present beneath the sediments in a thick seaward-dipping wedge. We use post-stack depth migration to image this wedge and use the resulting image to consider the early subsidence of the margin. The geometry of the subaerially extruded rift volcanics suggest that the margin subsided rapidly once volncanism began. We infer from the subsidence, the along-margin distribution of magmatic material, and the across-margin localization of magmatic emplacement and deformation that the U.S. East Coast rift volcanics had an anomalously-hot mantle source whose distribution beneath the lithosphere prior to rifting was long (the length of the margin) but not deep. We speculate that the distribution of this material was controlled by topography at the base of the lithosphere inherited from the Paleozoic collision of North America and Africa. Our analysis of the southwestern Alaska convergent margin is based on data from the 1994 Aleutian seismic experiment. The crust of most of Alaska has been built through terrane accretion and arc magmatism, and this experiment was conducted to study the evolution of continental crust through these processes. We consider transects across the westernmost Alaska Peninsula margin, where subduction is occurring beneath protocontinental crust composed of oceanic-arc terranes accreted in the Cretaceous, and across Bristol Bay in the back arc region where the crust has undergone a number of geologic events since accretion. Across the Peninsula, we find that the velocity structure of the accreted terranes differs little from that of the Cenozoic Aleutian oceanic-arc crust west of the Peninsula determined along another transect of this experiment. The accreted oceanicarc terranes are considerably more mafic than continental crust and the process of accretion has apparently not modified the bulk composition of these terranes toward that of average continental crust. It is possible that Cenozoic arc magmatism has been more felsic in composition than that which formed the accreted terranes and the Aleutian oceanic arc to the west, and that these magmas have been emplaced primarily within the crust inboard of the accreted terranes which lie south of the currently active arc. The geology of the Bristol Bay region suggests that the crustal components here had an origin similar to that of the Alaska Peninsula margin- that is, accreted terranes. We find, however, that the crust beneath Bristol Bay has a typically continental velocity structure. If this crust originally had a structure similar to the Alaska Peninsula margin, then at least two processes must have occured to affect the transformation to its current structure: crustal thickening and removal of the mafic lower crust. The geologic events that have affected this region since accretion are consistent with such and evolution.

Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution June 2010

Description: This thesis presents the results of four discrete investigations into processes governing the organic and inorganic chemical composition of seafloor hydrothermal fluids in a variety of geologic settings. Though Chapters 2 through 5 of this thesis are disparate in focus, each represents a novel investigation aimed at furthering our understanding of subsurface geochemical processes affecting hydrothermal fluid compositions. Chapters 2 and 3 concern the abiotic (nonbiological) formation of organic compounds in high temperature vent fluids, a process which has direct implications for the emergence of life in early Earth settings and sustainment of present day microbial populations in hydrothermal environments. Chapter 2 represents an experimental investigation of methane (CH4) formation under hydrothermal conditions. The overall reduction of carbon dioxide (CO2) to CH4, previously assumed to be kinetically inhibited in the absence of mineral catalysts, is shown to proceed on timescales pertinent to crustal residence times of hydrothermal fluids. In Chapter 3, the abundance of methanethiol (CH3SH), considered to be a crucial precursor for the emergence of primitive chemoautotrophic life, is characterized in vent fluids from ultramafic-, basalt- and sediment-hosted hydrothermal systems. Previous assumptions that CH3SH forms by reduction of CO2 are not supported by the observed distribution in natural systems. Chapter 4 investigates factors regulating the hydrogen isotope composition of hydrocarbons under hydrothermal conditions. Isotopic exchange between low molecular weight n-alkanes and water is shown to be facilitated by metastable equilibrium reactions between alkanes and their corresponding alkenes, which are feasible in natural systems. In Chapter 5, the controls on vent fluid composition in a backarc hydrothermal system are investigated. A comprehensive survey of the inorganic geochemistry of fluids from sites of hydrothermal activity in the eastern Manus Basin indicates that fluids there are influenced by input of acidic magmatic solutions at depth, and subsequently modified by variable extents of seawater entrainment and mixing-related secondary acidity production.

Description: The thesis research presented here was funded by the National Science Foundation through grants OCE-0327448, OCE-0136954, MCB-0702677, OCE-0549829, and by the Department of Energy grant DE-FG02-97ER14746.

Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution August 2000

Description: The plausibility of local baroclinic instability as a generation mechanism for midocean mesoscale eddies is examined with a two-layer, quasi-geostrophic (QG) model forced by an imposed, horizontally homogeneous, vertically sheared mean flow and dissipated through bottom Ekman friction, Explanations are sought for two observed features of mid-ocean eddies: 1) substantial energy is retained in the baroclinic mode and in the associated deformation radius (Rd) scale, and 2) the ratio of eddy to mean kinetic energy is much larger than one, The tendency of QG to cascade energy into the barotropic mode and into scales larger than Rd can be counteracted when stratification is surface-trapped, for then the baroclinic mode is weakly damped, and hence enhanced, Numerical experiments are performed with both surface-trapped and uniform stratification to quantify this, Experiments with equal Ekman frictions in the two layers are also performed for purposes of contrast, Interpretation is aided with an inequality derived from the energy and enstrophy equations, The inequality forbids the simultaneous retention of substantial energy in the baroclinic mode and in scales near Rd when Ekman friction is symmetric, but points towards surface-trapped stratification and bottomtrapped friction as an environment in which both of these can be achieved, The dissertation also contains a systematic study of geostrophic turbulence forced by nonzonal flows, Narrow zonal jets emerge when shear-induced mean potential vorticity (PV) gradients are small compared to the planetary gradient (β), and energy is a strong function of the angle shear presents to the east-west direction, When shear-induced PV gradients are comparable to β, and the mean shear has a westward component, fields of monopolar vortices form and persist, Energy is asymmetric between fields of cyclones and anticyclones, Such asymmetry was commonly thought not to occur in QG, but is shown here to be introduced by the nonzonal basic state, In both jet and vortex regimes, eddy energy can be much larger than mean kinetic energy, contrary to the expectation that β stabilizes weak shear flows,

Description: My first three years here were funded by an Office of Naval Research/National Defense Science and Engineering Graduate Fellowship administered by Jeff Jarocz at the American Society for Engineering Education. During the last three years, most of my support has come the National Science Foundation via grant OCE-9617848, with some additional support coming from the Office of Naval Research via grant N00014-95-1-0824.

Description: Submitted in partial fulfillment of the requirements for the degree of Master of Science at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February 1998

Description: Stable sulfur isotopes (δ34S) and trace Co are analyzed in sulfide and sulfate minerals from six sample types collected from the TAG active mound, 26°N Mid-Atlantic Ridge. δ34S values range from 2.7 to 2O.9%, with sulfate minerals isotopically indistinguishable from seawater (21%), and sulfide minerals reflecting input of 1/3 seawater and 2/3 basaltic sulfur (~0%). Co concentrations in pyrite analyzed by ion microprobe primarily reflect depositional temperatures. The δ34S and Co data are combined to provide information regarding the sources and temperatures of parent fluids, the genetic relationships among sample types, and the circulation of hydrothermal fluids and seawater in the mound. δ34S values and Co concentrations vary by sample type. Chalcopyrite from black smoker samples exhibits invariant δ34S values, indicating direct precipitation from black smoker fluids. Crust samples contain chalcopyrite with a mean δ34S indistinguishable from that of black smoker samples, and pyrite with some light δ34S and moderately high Co values, consistent with crust samples precipitating from cooled black smoker fluids. Massive anhydrite samples are a mixture of anhydrite with high δ34S, and pyrite with variable δ34S and Co values, indicative of deposition from disequilibrium mixing between black smoker fluids and seawater. White smoker samples contain chalcopyrite and sphalerite with high δ34S, and pyrite with low Co values, reflecting deposition from cooler fluids formed from mixtures of seawater and black smoker fluid, with some reduction of sulfate. Mound samples contain chalcopyrite with a mean δ34S indistinguishable from that of black smoker and crust samples, and pyrite with low Co values, suggesting deposition from a fluid isotopically similar to black smoker fluid at temperatures similar to those of white smoker fluid. Massive sulfide samples exhibit pyrite with high δ34S values and very high Co, indicating deposition from and recrystallization with very hot fluids contaminated with seawater-derived sulfate. The data demonstrate that direct precipitation from black smoker fluids, conductive cooling, disequilibrium mixing with entrained seawater, sulfate reduction, and recrystallization all contribute to the formation of the TAG mound deposit. The successful preliminary Co analyses demonstrate that ion microprobe analyses are a viable technique for measuring trace elements in sulfides.

Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution May 1998

Description: Planktonic protozoan grazers have the potential to significantly affect the chemistry of particle-associated trace metals. This is due both to the importance of protists as consumers of bacterial-sized particles, and to the unique low-pH, enzyme-rich microenvironment of the grazer food vacuole. This thesis examines the role of protozoan grazers in the marine geochemistry of strongly hydrolyzed, particle-reactive trace metals, in particular Th and Fe. A series of tracer experiments was carried out in model systems in order to determine the effect of grazer-mediated transformations on the chemical speciation and partitioning of radioisotopes C9Fe, 234Th, 51Cr) associated with prey cells. Results indicate that protozoan grazers are equally able to mobilize intracellular and extracellular trace metals. In some cases, protozoan regeneration of trace metals appears to lead to the formation of metal-organic complexes. Protozoan grazing may generate colloidal material that can scavenge trace metals and, via aggregation, lead to an increase in the metal/organic carbon ratio of aggregated particles. Model system experiments were also conducted in order to determine the effect of grazers on mineral phases, specifically colloidal iron oxide (ferrihydrite). Several independent techniques were employed, including size fractionation ors9Fe-labeled colloids, competitive ligand exchange, and iron-limited diatoms as "probes" for bioavailable Fe. Experimental evidence strongly suggests that protozoan grazing can affect the surface chemistry and increase the dissolution rate of iron oxide phases through phagotrophic ingestion. In further work on protozoan-mediated dissolution of colloidal Fe oxides, a novel tracer technique was developed based on the synthesis of colloidal ferrihydrite impregnated with 133Ba as an inert tracer. This technique was shown to be a sensitive, quantitative indicator for the extent of ferrihydrite dissolution/alteration by a variety of mechanisms, including photochemical reduction and ligand-mediated dissolution. In field experiments using this technique, grazing by naturally occuring protistan assemblages was shown to significantly enhance the dissolution rate of colloidal ferrihydrite over that in non-grazing controls. Laboratory and field results indicate that, when integrated temporally over the entire euphotic zone, protozoan grazing may equal or exceed photoreduction as a pathway for the dissolution of iron oxides.

Description: This work was financially supported by a Department of Defense ONR-NDSEG Graduate Fellowship, Office ofNaval Research AASERT Award (N00014-94-1-0711), and the National Science Foundation EGB Program (OCE-9523910).

Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution June 1993

Description: This dissertation studies several aspects of the formation of the Earth's oceanic mantle and crust, using a variety of geologic techniques, principally major elements, radiogenic isotopes and trace elements, but including petrography, mineral chemistry, x-ray diffraction, seafloor geomorphology, and analysis of the tectonics of fracture zones. The first chapter is an introduction to the problems to be addressed in this work. The second chapter examines the composition of basalts erupted near the Atlantis II Fracture Zone on the Southwest Indian Ridge. Trends in major element compositions of those basalts can be related directly to the nearby presence of the fracture zone. The effects of mantle composition and crustal level lateral transport of magma in the rift system can be ruled out by the analysis of isotopes and the geomorphology of the fracture zone floor. This is the best demonstration to date of a transform fault effect on basalt compositions. In trying to quantify putative transform fault effects documented at other fracture zones, no systematic correlation of transform offset age with mantle temperature change can be found, suggesting that mantle composition and lateral transport phenomena play a larger than expected role in the evolution of those areas. The third chapter relates to oceanic mantle rocks as they are altered at or near the Earth's surface. The major elements which make up abyssal peridotites are extensively redistributed by the alteration they have undergone. Mg is shown to be extracted from the peridotites, and a variety of trace elements added. This elemental redistribution is taken as evidence for extensive Mg transport by circulating waters. Since the solubility of Mg-bearing minerals in hydrothermal solutions is quite limited, much lower temperatures and much higher water /rock ratios are required to explain the major element compositions of the peridotites than had previously been assumed. The behavior of the Nd, Sr and Os isotopic systems during seafloor alteration was also studied. The isotope systematics of these rocks strongly support the hypothesis of high water /rock ratios in the formation of serpentinized abyssal peridotites. Nonetheless, Nd and Sr reside in a phase which is resistant to alteration (clinopyroxene) and the concentration of Os is high relative to that of seawater, so that it too appears resistant to alteration. Primary mantle isotopic signatures may be obtained from abyssal peridotites by careful analysis, even of extremely weathered rocks. Radiogenic strontium in excess of what could be introduced by seawater contamination or in situ radiogenic growth in a reasonable period of time was also found. These observations confirm earlier work which had been discredited for many years. The only plausible mechanism for the formation of this "orphan" S7Sr is that it is introduced as part of a sedimentary component which infiltrates the rock during metamorphism and/ or weathering. The 87Sr may be contained by or sorbed onto extremely fine clay particulates, or colloidal suspensions, as opposed to the dissolved ionic Sr which is normally thought of as characterizing the Sr isotopic composition of seawater. The high water/rock ratios required by the bulk isotopic analysis, as well as the pervasive elemental redistribution arguing for extensive near-surface weathering at high water /rock ra.tios strongly support this hypothesis. Given pervasive percolation of water throughout the samples, sufficient radiogenic, sediment-derived strontium may be drawn deep into the crust in the course of its weathering to cause such high B7SrfB6Sr ratios. The fourth chapter deals exclusively with primary mantle isotopic information from abyssal peridotites. This is the first study which has attempted to relate the Os isotopic system in the oceanic mantle to other isotopic systems and to trace elements. It is possible, with some extreme assumptions, to model the range of Os isotopes in the oceanic mantle alone in a standard model of formation of the depleted mantle by extraction of the crust. The additional constraints provided by the study of Nd isotopes in depleted mantle rocks from the oceans show that partial melt extraction and the formation of a depleted reservoir alone are not sufficient to account for the range of both N d and Os isotopes in the Earth's mantle. Possible mechanisms for the decoupling of the Os and Nd isotopic systems include elemental fractionation via the porous flow of basalt through the mantle, mantle metasomatism, recycling of a subducted component in the mantle and core formation. The core extraction model is pursued in some detail. Such core extraction models can account for the distributions and isotopic compositions of compatible and incompatible trace elements in the Earth's mantle, but they are highly non-unique, and thus difficult to test.

Description: This thesis was supported by an NSF Graduate Fellowship, and by a grant from the WHOI Ocean Ventures Fund.

Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 1996

Description: We analyze bathymetric and gravity anomalies at five plume-ridge systems to constrain crustal and mantle density structure at these prominent oceanic features. Numerical models are then used to explore the physical mechanisms controlling plume-ridge interaction and to place theoretical constraints on the temperature anomalies, dimensions, and fluxes of the Icelandic and Galapagos plumes. In Chapter 1 we analyze bathymetric and gravity anomalies along the hotspot-influenced Galapagos Spreading Center. We find that the Galapagos plume generates along-axis bathymetric and mantle-Bouguer gravity anomalies (MBA) that extend 〉500 km east and west of the Galapagos Islands. The along-axis MBA becomes increasingly negative towards the plume center, reaching a minimum of ~-90 mGal near 91°W, and axial topography shallows by ~1.1 km toward the plume. These variations in MBA and bathymetry are attributed to the combined effects of crustal thickening and anomalously low mantle densities, both of which are due to a mantle temperature anomaly imposed beneath the ridge by the Galapagos plume. Passive mantle flow models predict a temperature anomaly of 50±25°C is sufficient to produce the 2-4 km excess crust required to explain the along-axis anomalies. 70-75% of the along-axis bathymetric and MBA variations are estimated to arise from the crust with the remaining 25-30% generated by the anomalously hot, thus low-density mantle. Along Cocos-plate isochrons, bathymetric and MBA variations increase with increasing isochron age, suggesting the subaxial mantle temperature anomaly was greater in the past when the plume was closer, to the ridge axis. In addition to the Galapagos plume-ridge system, in Chapter 2 we examine alongisochron bathymetric and MBA variations at four other plume-ridge systems associated with the Iceland, Azores, Easter and Tristan hotspots. We show that residual bathymetry (up to 4.7 km) and mantle-Bouguer gravity anomalies (up to -340 mGal) are greatest at on-axis plumes and decreases with increasing ridge-hotspot separation distance, until becoming insignificant at a plume-ridge separation of ~500 km. Along-isochron widths of bathymetric anomalies (up to 2700 km) decrease with increasing paleo-spreading rate, reflecting the extent to which plume material flows along-axis before being swept away by the spreading lithosphere. Scaling arguments suggest an average ridgeward plume flux of -2.2x106 km/my. Assuming that the amplitudes of the MBA and bathymetric anomalies reflect crustal thickness and mantle density variations, passive mantle flow models predict maximum subaxial mantle temperature anomalies to be 150-225°C for ridge-center plumes, which decrease as the ridges migrate away from the plumes. The dynamics of mantle flow and melting at ridge-centered plumes are investigated in Chapters 3 using three-dimensional, variable-viscosity, numerical models. Three buoyancy sources are examined: temperature, melt depletion, and melt retention. The width W to which a plume spreads along a ridge axis depends on plume volume flux Q, full spreading rate U, buoyancy number B = (QΔρg)/(48η0U2), and ambient/plume viscosity contrast ϒ according to W=2.37(Q/U)l/2(Bϒ)0.04. Thermal buoyancy is first order in controlling along-axis plume spreading while latent heat loss due to melting, and depletion and retention buoyancy forces contribute second order effects. Two end-member models of the Iceland-Mid-Atlantic Ridge (MAR) system are examined. The first endmember model has a broad plume source of radius 300 km, temperature anomaly of 75°C, and volume flux of 1.2xl07 km3/my. The second model has a narrower plume source of radius 60 km, temperature anomaly of l70°C, and flux of 2.1 x106 km3/my. The first model predicts successfully the observed crustal thickness, topographic, and MBA variations along the MAR, but the second model requires substantial along-axis melt transport in order to explain the observed along-axis variations in crustal thickness, bathymetry, and gravity. We favor this second model because it predicts a mantle P-wave velocity reduction in the plume of ~2% as consistent with recent seismic observations beneath Iceland. Finally in Chapter 4 we use three-dimensional numerical models to investigate the interaction of plumes and migrating midocean ridges. Scaling laws of axial plume spreading width Ware derived first for stationary ridges and off-axis plumes, which yield results consistent with those obtained from independent studies of Ribe [1996]. Wand the maximum plume-ridge interaction distance Xmax again scale with (Q/U)l/2 as in the case of ridge-centered plumes and increase with ϒ and buoyancy number. In the case of a migrating ridge, Xmax is reduced when a ridge migrates toward the plume due to excess drag of the faster-moving leading plate, and enhanced when a ridge migrates away from the plume due to reduced drag of the slower-moving trailing plate. Thermal erosion of the lithospheric boundary layer by the previously ridge-centered plume further enhances Wand Xmax but to a degree that is secondary to the differential migration rates of the two plates. Model predictions are compared with observed along-isochron bathymetric and MBA variations at the Galapagos plume-ridge system. The anomaly amplitudes and widths, as well as the increase in anomaly amplitude with age are predicted with a plume source temperature anomaly of 80-120°C, radius of 80-100 km, and volume flux of 4.5x106 km3/m.y. Our numerical models also predict crustal production rates of the Galapagos Islands consistent with those estimated independently using the observed island topography. Predictions of the geochemical signature of the plume along the present-day ridge suggest that mixing between the plume and ambient mantle sources is unlikely to occur in the asthenosphere or shallow crust, but most likely deeper in the mantle possibly by entrainment of ambient mantle as the plume ascends through the depleted portion of the mantle from its deep source reservoir.

Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution March 1997

Description: The formation of new oceanic crust is the result of a complex geodynamic system in which mantle rises beneath spreading centers and undergoes decompression melting. The melt segregates from the matrix and is focused to the rise axis, where it is eventually intruded and/or erupted to form the oceanic crust. This thesis combines surface observations with laboratory studies and geodynamic modeling to study this crustal-production system. Quantitative modeling of the crustal and mantle contributions to the axial gravity and topography observed at the East Pacific Rise shows that the retained melt fraction in the mantle is small (〈3%) and is focused into a narrow column extending up to 70 km beneath the ridge axis. Consistent with geochemical constraints, the extraction of melt from the mantle therefore appears to be efficiently focus melt toward the ridge axis. A combination of laboratory and numerical studies are used to constrain the pattern of mantle flow beneath highly-segmented ridges. Even when the buoyant component of mantle flow is constrained to be two-dimensional, laboratory studies show that a segmented ridge will drive three-dimensional mantle upwelling. However, using reasonable mantle parameters in numerical models, it is difficult to induce large-amplitude three-dimensional mantle upwelling at the relatively short wavelengths of individual segments (~50 km). Instead, a simple model of three-dimensional melt migration shows that the observed segment-scale variations in crustal thickness can be explained by focusing of melt as it upwells through a more two-dimensional mantle flow field. At the Reykjanes Ridge, the melt appears to accumulate in small crustal magma chambers, before erupting in small batches to form numerous overlapping hummocky lava flows and small volcanoes. This suggests that crustal accretion, particularly at slow-spreading centers, may be a highly discontinuous process. Long-wavelength variations in crustal accretion may be dominated by variations in mantle upwelling while short-wavelength, segment-scale variations are more likely controlled by a complex three-dimensional processes of melt extraction and magma eruption.

Description: During my first three years in the Joint Program, I was supported by an National Science Foundation Graduate Student Fellowship. Other support has been derived from National Science Foundation grants OCE-9296017, OCE-9224738, OCE-9215544, and EAR grant 93-07400.

Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution June 2010

Description: Volcanic accretion at the fast-spreading East Pacific Rise (EPR) occurs over a ~2-4 km wide neo-volcanic zone on either side of the axial summit trough (AST). Eruption ages are critical for understanding the distribution and timing of volcanic and magmatic activity. Uranium series nuclides are susceptible to fractionation by magmatic processes that occur beneath mid-ocean ridges, and the half-lives of 226Ra (1.6 kyrs) and 230Th (75 kyrs) make them ideally suited for determining eruption ages and placing constraints on eruption frequency and temporal changes in magma chemistry. Accordingly, major and trace element, and long-lived radiogenic and 238U-230Th-226Ra isotope compositions were measured in basalts from 9º-10ºN EPR to determine eruption ages and to place temporal constraints on volcanic and magmatic processes. At 9º30’N EPR, 238U-230Th-226Ra compositions indicate that trace elementally and isotopically enriched mid-ocean ridge basalt (MORB) collected off-axis erupted 〉8 ka and that E-MORB magmatism is interspersed with normal, depleted MORB magmatism. Lava ages are consistent with eruption from the AST and flow down the ridge flanks, which is in contrast to previous studies that suggested E-MORB erupted from off-axis vents. At 9º50’N EPR, discrete eruptive units are distinguished by high precision 238U, 232Th, and 226Ra sample concentrations, but because the resolution of the 230Th-226Ra model age dating technique is ~±1 kyrs, the surprisingly young ages of these lavas prohibit the construction of an explicit, time-constrained lava stratigraphy. Nonetheless, seven different flows identified within 0.8-2.0 km west of the AST imply greater frequency of flows to these distances than previously recognized. Model age dating of ferrobasalts, basaltic andesites, andesites, and dacites sampled from the east limb of the overlapping spreading center at 9º03’N EPR is difficult due to uncertainties in magma residence times. However, (226Ra/230Th) disequilibria indicate recent basaltic volcanism (〈〈8 ka) up to ~4 km off-axis. The axial graben at the rise crest sources the most recent volcanic activity and is the dominant location for eruption of high-silica magmas. Major element, trace element, 87Sr/86Sr, and (234U/238U) isotope compositions are consistent with the formation of dacite magmas by extensive crystallization, and 238U-230Th-226Ra systematics imply crustal residence times of ~8 kyrs.

Description: This research was made possible by funding from the Academic Programs Office, from the WHOI travel assistance funds, a Goldschmidt student travel grant, and National Science Foundation grants OCE-0623838, OCE-0527053, and OCE-0137325 to K.W.W.S.

Description: Submitted in partial fulfillment of the requirements for the degree of Master of Science at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution August 2000

Description: With Lagrangian and hydrographic data taken in the deep Brazil Basin, we identify several submesoscale coherent vortices (SCVs). These features contrast with SCV paradigms in that float data indicate approximately equal populations of cyclonic and anticyclonic vortices, and hydrographic data suggest that roughly half exhibit the convex lens shape generally associated with SCVs, while half are instead shaped like a concave lens, with isopycnal surfaces pinched together. There is some evidence that the vortex cores may be enriched in warm, salty North Atlantic Deep Water, suggesting formation in the north or northwest regions of the basin. Data is available from 153 floats which were ballasted for 2500 and 4000 db pressures. They tracked 34 eddies, which are believed to be roughly 30 km in diameter, and rotate with apparent periods of about 30 days. Many floats experienced formation or entrainment events, and destruction or detrainment events, near seamounts.

Description: This work was supported by the National Science Foundation, grants OCE 99-11148 and OCE 94-15509.

Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and Woods Hole Oceanographic Institution February 1994

Description: In this work we study motion of a baroclinic upper-ocean eddy over a large-scale topography which simulates a continental slope. We use a quasigeostrophic f-plane approximation with continuous stratification. To study this problem we develop a new numerical technique which we call "semi-lagrangian contour dynamics". This technique resembles the traditional 2-D contour dynamics method but differs significantly from it in the numerical algorithm. In addition to "Lagrangian" moving contours it includes an underlying "Eulerian" regular grid to which vorticity or density fields are interpolated. To study topographic interactions in a continuously stratified model we use density contours at the bottom in a similar manner as vorticity contours are used in the standard contour dynamics. For the case of a localized upper-ocean vortex moving over a sloping bottom the problem becomes computationally 2-dimensional (we need to follow only bottom density contours and the position of the vortex itself) although the physical domain is still 3-dimensional. Results of the numerical model lndicate importance of baroclinic effects in the vortex-topography interaction. After the initial surge of topographic Rossby waves a vortex moves almost steadily due to the interaction with a bottom density anomaly which is created and supported by a vortex itself. This anomaly is equivalent to a region of opposite-signed vorticity with a total circulation exactly compensating that of a vortex. This results in a vertically aligned dipolar structure with the total barotropic component equal to zero. Analytical considerations explaining this effect are presented and formulated in a more general statement which resembles but does not coincide with the "zero angular momentum theorem" of Flierl, Stern and Whitehead, 1983. In such steady translation the centroid of a bottom density anomaly is displaced horizon tally from the center of an upper-ocean vortex so the whole system moves due to this misalignment, which is known as a "he tonic mechanism". Cyclonic vortices go generally upslope, and anticyclones - in a downslope direction. The along-slope component of their motion depends upon the strength of a vortex, curvature of the bottom slope and background flows. When surrounded by a bowl-shaped topography anticyclonic vortices tend to stay near the deepest center of a basin, even resisting ambient flows which advect them outward. Application of this results to various oceanic examples (particularly to the "Shikmona eddy" in the Eastern Meditenanian) is discussed. Our results show that the behavior of a vortex over a sloping bottom differs significantly from its motion on the planetary beta-plane (but with a flat bottom). To explain this difference we introduce the concept of a "wave-breaking regime" relevant for the case of a planetary beta-effect, and a "wave-gliding regime" which characterizes the interaction of an eddy with a topographic slope.

Description: This work was supported by the NSF grant #OCE 90-12821.

Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution March 1992

Description: Rotating baroclinic and barotropic boundary currents flowing around a corner in the laboratory were studied in order to discover the circumstances under which eddies were produced at the corner. Such flows are reminiscent of oceanic coastal flows around capes. When the baroclinic currents, which consisted of surface flows bounded by a density front, encountered a sharp corner, immediately downstream of the corner an anticyclone grew in the surface layer for an angle of greater than 40 degrees. Varying the initial condition of the flow or the depth of the lower layer did not noticeably affect the gyre's properties except for its growth speed, which was greater when the lower layer was shallower. The barotropic currents were pumped along a sloping bottom, and also formed anticyclonic gyres which quickly attained an approximately steady state. For a given topography, the size of the gyre was proportional to the inertial radius u/f. Volume flux calculations based on the surface velocity revealed vertical shear which increased with gyre size. Hydraulic models were also applied to flow around gently curving topography to determine the critical separation curvature as a function of upstream parameters.

Description: This work was supported by the National Science Foundation grant OCE 89-15408.

Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution April 1992

Description: A pair of simple models representing the interaction of a continuously stratified f-plane quasigeostrophic lens with a uniform external shear flow is examined. The study is motivated by the desire to understand the processes that affect Mediterranean Salt Lenses and other mesoscale lenses in the ocean. The first model represents the eddy as a pair of quasigeostrophic 'point potential vortices' in uniform external shear, where the two point vortices are imagined to represent the top and bottom of a baroclinic eddy. While highly idealized, the model succeeds in qualitatively reproducing many aspects of the behavior of more complex models. In the second model the eddy is represented by an isolated three dimensional patch characterized by quasigeostrophic potential vorticity linear in z, in a background flow with constant potential vorticity. The boundary of the lens may be deformed by interactions with a uniform background shear. A family of linearized analytical solutions representing such a vortex is discussed in Chapter 3. These solutions represent lens-like eddies with trapped fluid cores, which may propagate through the surrounding water when there is external vertical shear. The analysis predicts the possible forms of the boundary deformation in a specified external flow, and the precession rate of normal mode boundary perturbations in the absence of external flow. The translation speed of the lens with respect to the surrounding fluid is found to be a simple function of the external vertical shear and the core baroclinicity. A numerical algorithm which is a generalization of the contour dynamics technique to stratified quasigeostrophic flow is used to extend the linear results into the nonlinear regime. This numerical analysis allows a determination of the range of environmental conditions (e.g., the maximum shear and/ or core baroclinicity) in which coherent vortex solutions can be found, and allows the stability of the steadily translating solutions to be examined directly. It is found that the solutions are stable if neither the external shear nor the core baroclinicity is too large, and that the breakdown of the unstable solutions is characterized by the loss of an extrusion of core fluid to the surrounding waters. The translation speeds of the large amplitude numerical solutions are found to have the same functional dependence on the external vertical shear and the core baroclinicity that was found in the linear analysis, and it is demonstrated that the solutions translate at a rate which is equal to the background flow speed at the center of potential vorticity of the lens. As a test of the model results, new data from a recent SOFAR float experiment are presented and compared with the model predictions. The data show that the cores of two different Mediterranean Salt Lenses are tilted, presumably as a result of interactions with external flows. Both the sense of the tilt and its relation to the translation of the lens are in qualitative agreement with the model solutions.

Description: I am happy to acknowledge the support of the Office of Naval Research (grant N00014-89-J-1182) and the National Science Foundation (grants OCE 8916446 and OCE 87-00601).

Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 1992

Description: This study concerns the barotropic interactions between a mesoscale eddy and a straight monotonic bottom topography. Through simple to relatively complicated modeling effort, some of the fundamental properties of the interaction are investigated. In chapter two, the fundamental aspects of the interaction are examined using a simple contour dynamics model. With the simplest model configuration of an ideal vortex and a step topography, the basic dynamical features of the observed oceanic eddy-topography interaction are qualitatively reproduced. The results consist of eddy-induced cross-topography exchange, formation of topographic eddies, eddy propagation and generation of topographic waves. In chapter three, a more complicated primitive equation model is used to investigate a mesoscale eddy interacting with an exponential continental shelf/slope topography on both f and β-planes. The f-plane model recasts the important features of chapter two. The roles of the eddy size and strength and the geometry of topography are studied. It is seen that the multiple anticyclonic eddy-slope interactions strongly affect the total cross-slope volume transport and the evolution of both the original anticyclone and the topographic eddy. Since a cyclone is trapped at the slope and eventually moves on to the slope, it is most effective in causing perturbation on the shelf and slope. The responses on the shelf and slope are mainly wavelike with dispersion relation obeying that of the free shelf-trapped wave modes. On the β-plane, the problem of an eddy colliding onto a continental shelf/slope from a distance with straight or oblique incident angles is investigated. It is found that the straight eddy incident is more effective in achieving large onslope eddy penetration distance than the oblique eddy incident. The formation of a dipole-like eddy pair consisting of the original anticyclone and the topographic cyclone acts to suppress the eddy decay due to long Rossby wave radiation. A weak along-slope current near the edge of the slope is found, which is part of a outer slope circulation cell originated from the Rossby wave wake trailing the propagating eddy. Model-observation comparisons in_chapter four show favorable qualitative agreement of the model results with some of the observed events in the eastern U.S. continental margins and in the Gulf of Mexico. The model results give dynamical interpretations to some observed features of the oceanic eddy-topography interactions and provide enlightening insight into the problem.

Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution November 1990

Description: One and two layer models are used to study flow over axisymmetric isolated topography. Inviscid or nearly inviscid flow in which non-linear effects have order one importance is considered, and both the effects of β and finite topography are included. A one-layer quasi-geostrophic model is used to find the shape of Taylor columns on both the f-plane and the β-plane in the inviscid limit of the frictional problem. In this limit, the boundary of the Taylor column is a streamline, and the velocity in both directions vanishes on the boundary. The fluid within the Taylor column is stagnant, corresponding to the solution that Ingersoll (1969) found for flow over a right circular cylinder on the f-plane. In this case, the Taylor column is circular. An iterative boundary integral technique is used to find the solutions for flow over a cone on the f-plane. In this case the Taylor column has a tear drop shape. Solutions are also found for flow on the β-plane over a cylinder, and the Taylor column is approximately elliptical for westward flow with the major axis in the x direction, while it is slightly elongated in the y direction for eastward flow. The stagnation point of the Taylor column is located on the edge of the topography for all the solutions found. It was not possible to find solutions for smooth topographic shapes. Steady solutions for flow over a right circular cylinder of finite height are studied when the quasi-geostrophic approximation no longer applies. The solution consists of two parts, one which is similar to the quasi-geostrophic solution and is driven by the potential vorticity anomaly over the topography and the other which is similar to the solution of potential flow around an cylinder and is driven by the matching conditions on the edge of the topography. When the effect of β is large, the transport over the topography is enhanced as the streamlines follow lines of constant background potential vorticity. For eastward flow, the Rossby wave drag can be much larger than predicted from quasi-geostrophic theory. A two-layer model over finite topography using the quasi-geostrophic approximation is developed. The topography is a right circular cylinder which goes all of the way through the lower layer and an order Rossby number amount into the upper layer, so that the quasi-geostrophic approximation can be applied consistently. This geometry allows description of flow in which an isopycnal intersects the topography. The model is valid for a different regime than existing models of steady flow over finite topography in a continuously stratified fluid in which the bottom boundary is an isopycnal surface. The solutions contain the two components that are found in the the barotropic model of flow over finite topography. The model breaks down when the interface goes above the topography which occurs more easily when the stratification is weak. Closed streamlines occur more readily over the topography when the stratification is weak, whereas in traditional quasi-geostrophic theory they occur more readily when the stratification is strong. Near the topography, the interface is depressed to the right and raised to the left (looking downstream). A hierarchy of time-dependent models is used to examine the initial value problem of flow initiation over topography on the f-plane. A modified contour dynamics method is developed that extends the range of problems to which contour dynamics can be applied. The method allows boundary and matching conditions to be applied on a circular boundary. A one-layer quasi-geostrophic model is used to show that more fluid that originates over the topography remains there when the flow is turned on slowly than when it is turned on quickly. Flow over finite topography in a one-layer model shows a variety of different behaviors depending on the topographic height. When the topography has moderate height, two cyclonic eddies are created; when the topography fills up most of the water column, the fluid oscillates on and off the topography as it moves around the topography in a clockwise direction, and none of the fluid is shed downstream. Two quasi-geostrophic stratified models are considered, one in which the topography is small, and the other in which it is finite. In the small topography model, an eddy is shed which is cyclonic, warm-core, and bottom-trapped. In contrast, the shed eddy is cyclonic, cold-core, and surfaceintensified in the finite depth model using the geometry described above.

Description: This study was supported by the Office of Naval Research Program N00014- 90-J-1839.

Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 1999

Description: Climate simulation with numerical oceanic models requires a proper parameterization scheme in order to represent the effects of unresolved mesoscale eddies. Even though a munber of schemes have been proposed and some have led to improvements in the simulation of the bulk climatological properties, the success of the parameterizations in representing the mesoscale eddies has not been investigated in detail. This thesis examines the role of eddies in a 105-years long basin scale eddy resolving simulation with the MIT General Circulation Model (GCM) forced by idealized wind stress and relaxation to prescribed meridional temperature; this thesis also evaluates the Fickian diffusive, the diabatic Green-Stone (GS) and the quasi-adiabatic Gent-McWilliams (GM) parameterizations in a diagnostic study and a series of coarse resolution experiments with the same model in the same configuration. The mesoscale eddies in the reference experiment provide a significant contribution to the thermal balance in limited areas of the domain associated with the upper 1000M of the boundary regions. Specifically designed diagnostic tests of the schemes show that the horizontal and vertical components of the parameterized flux are not simultaneously downgradient to the eddy heat flux. The transfer vectors are more closely aligned with the isopycnal surfaces for deeper layers, thus demonstrating the adiabatic nature of the eddy heat flux for deeper layers. The magnitude of the coefficients is estimated to be consistent with traditionally used values. However, the transfer of heat associated with timedependent motions is identified as a complicated process that cannot be fully explained with any of the local parameterization schemes considered. The eddy parameterization schemes are implemented in the coarse resolution configuration with the same model. A series of experiments exploring the schemes' parameter space demonstrate that Fickian diffusion has the least skill in the climatological simulations because it overestimates the temperature of the deep ocean and underestimates the total heat transport. The GS and GM schemes perform better in the simulation of the bulk climatological properties of the reference solution, although the GM scheme in particular produces an ocean that is consistently colder than the reference state. Comparison of the eddy heat flux divergence with the parameterized divergences for typical parameter values demonstrates that the success of the schemes in the climatological simulation is not related to the representation of the eddy heat flux but to the representation of the overall internal mixing processes.

Description: The financial support for this research was provided by ONR grant number NOOOl4- 98-1-0881, Alliance for Global Sustainability and American Automobile Manufactures Association.