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  • Articles  (35)
  • 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry  (21)
  • Etna  (15)
  • Elsevier  (35)
  • American Chemical Society
  • American Chemical Society (ACS)
  • 2010-2014  (35)
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  • Articles  (35)
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  • 1
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    Carbon dioxide degassing and thermal energy release in the Monte Amiata volcanic-geothermal area (Italy) (2010)
    Elsevier
    Details
    Publication Date: 2021-01-07
    Description: The quaternary volcanic complex of Mount Amiata is located in southern Tuscany (Italy) and represents the most recent manifestation of the Tuscan Magmatic Province. The region is characterised by a large thermal anomaly and by the presence of numerous CO2-rich gas emissions and geothermal features, mainly located at the periphery of the volcanic complex. Two geothermal systems are located, at increasing depths, in the carbonate and metamorphic formations beneath the volcanic complex. The shallow volcanic aquifer is separated from the deep geothermal systems by a low permeability unit (Ligurian Unit). A measured CO2 discharge through soils of 1.8 109 mol a 1 shows that large amounts of CO2 move from the deep reservoir to the surface. A large range in d13CTDIC ( 21.07 to +3.65) characterises the waters circulating in the aquifers of the region and the mass and isotopic balance of TDIC allows distinguishing a discharge of 0.3 109 mol a 1 of deeply sourced CO2 in spring waters. The total natural CO2 discharge (2.1 109 mol a 1) is slightly less than minimum CO2 output estimated by an indirect method (2.8 109 mol a 1), but present-day release of 5.8 109 mol a 1 CO2 from deep geothermal wells may have reduced natural CO2 discharge. The heat transported by groundwater, computed considering the increase in temperature from the infiltration area to the discharge from springs, is of the same order of magnitude, or higher, than the regional conductive heat flow (〉200 mWm 2) and reaches extremely high values (up to 2700mWm 2) in the north-eastern part of the study area. Heat transfer occurs mainly by conductive heating in the volcanic aquifer and by uprising gas and vapor along fault zones and in those areas where low permeability cover is lacking. The comparison of CO2 flux, heat flow and geological setting shows that near surface geology and hydrogeological setting play a central role in determining CO2 degassing and heat transfer patterns.
    Description: Published
    Description: 860–875
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Carbon dioxide degassing ; Monte Amiata ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 2
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    Fluid circulation in the upper brittle crust: Thickness distribution, hydraulic transmissivity fluid inclusion and isotopic data of veins hosted in the Oligocene sandstones of the Macigno Formation in southern Tuscany, Italy (2011)
    Elsevier
    Details
    Publication Date: 2020-11-30
    Description: We present structural analysis, fluid inclusion data on calcite and quartz, and isotopic composition of calcite forming veins occurring in the upper crustal level and hosted in Oligocene sandstone in southern Tuscany (Italy). The veins have been analysed in two sites few kilometres apart, along well-exposed coastal cliffs and in an abandoned quarry. These two sites were at a different depths at the time of the vein formation with a Δh ~ 100 m. Structural analysis of veins provided estimations of stress ratio (Φ = (σ2 − σ3)/(σ1 − σ3)), driving stress ratio (R′ = (Pf − σ3)/(σ1 − σ3)) and fluid overpressure (ΔPo = Pf − σ3) at the time of vein formation. The estimated ΔPo is in the range of 42–103 MPa, Φ = 0.24 and R′ = 0.45, indicating that fluid pressure was higher than the intermediate principal stress at the time of veins formation. The veins' thickness (t) shows a clear power-law distribution (D = 1.8835 and R2 = 0.9762) in the lowermost site (coast) and a negative exponential distribution (a = 0.6943 and R2 = 0.9921) in the uppermost site (abandoned quarry). The vein thickness distributions have been used to compute the average transmissivity of the veins in the two sites. The computed transmissivity for the vein formation is ~ 10−4 m2 s−1, with higher values attained by the veins having negative exponential thickness distribution. Fluid inclusions studies highlighted that in both calcite and quartz, water-rich inclusions, with salinities of 2.2–4.3 wt.% NaCl equiv., and methane-rich inclusions were coevally trapped during fluid un-mixing processes. Thermogenic origin, from thermal maturation of organic matter present in the Macigno Formation, is proposed for methane. Whereas, the similarity between the δ18O (from 14.9 to 17.4‰) and δ13C (from −0.4 to −2.4‰) data of representative calcite veins and the isotopic composition (δ18O: 16.1‰, δ13C: −1.0‰) of host-rock carbonate component, indicates that the fluid which formed calcite was in isotopic equilibrium with the carbonates present in the Oligocene sandstones. The calculated pressure–temperature conditions during the formation of these inclusions are prevalently within the 40–145 MPa and 160–260 °C ranges. The highest pressure values approximate the lithostatic pressure (~ 120 MPa) computed from geological data and are coherent with a geothermal gradient ranges of 35–45 °C/km. Whereas, the lower pressure values are comparable with hydrostatic pressure conditions. The pressure range indicated by fluid inclusion data is also comparable with the fluid pressure estimated from structural analysis. The considerable pressure range can be related to pressure cycling between lithostatic and hydrostatic conditions as a consequence of fault-valve actions and rock fracturing with subsequent pressure recover due to self-sealing process.
    Description: Published
    Description: 118-138
    Description: 3.2. Tettonica attiva
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: Vein systems ; Fluid type ; Fluid pressure ; Fluid inclusions ; Upper crust ; Tuscany ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
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    Shifting styles of basaltic explosive activity during the 2002-03 eruption of Mt. Etna, Italy (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The 2002–03 flank eruption of Etna was characterized by two months of explosive activity that produced copious ash fallout, constituting a major source of hazard and damage over all eastern Sicily. Most of the tephra were erupted from vents at 2750 and 2800 m elevation on the S flank of the volcano, where different eruptive styles alternated. The dominant style of explosive activity consisted of discrete to pulsing magma jets mounted by wide ash plumes, which we refer to as ash-rich jets and plumes. Similarly, ash-rich explosive activity was also briefly observed during the 2001 flank eruption of Etna, but is otherwise fairly uncommon in the recent history of Etna. Here, we describe the features of the 2002–03 explosive activity and compare it with the 2001 eruption in order to characterize ash-rich jets and plumes and their transition with other eruptive styles, including Strombolian and ash explosions, mainly through chemical, componentry and morphology investigations of erupted ash. Past models explain the transition between different styles of basaltic explosive activity only in terms of flow conditions of gas and liquid. Our findings suggest that the abundant presence of a solid phase (microlites) may also control vent degassing and consequent magma fragmentation and eruptive style. In fact, in contrast with the Strombolian or Hawaiian microlite-poor, fluidal, sideromelane clasts, ash-rich jets and plumes produce crystal-rich tachylite clasts with evidence of brittle fragmentation, suggesting that high groundmass crystallinity of the very top part of the magma column may reduce bubble movement while increasing fragmentation efficiency.
    Description: Published
    Description: 110-122
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Etna ; basaltic explosive activity ; ash-rich jet and plume ; tachylite ; sideromelane ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
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    Morphometry of scoria cones located on a volcano flank: A case study from Mt. Etna (Italy), based on high-resolution LiDAR data (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: By using new high-resolution (2 m) digital elevation model derived from the 2005 LiDAR survey of Mt. Etna volcano (Italy), our study measured the classical morphometrical parameters for scoria cones, i.e. Wco (cone width), Wcr (crater diameter), H (cone height) as well as volume, inclination of cone slope and substrate, and a number of other parameters for 135 scoria cones of Mt. Etna. Volume and age distribution of cones shows that there is no direct structural control on their emplacement in terms of Etna's rift zones. The cones are progressively smaller in size toward summit, which can be explained by the large volcano's feeding system and progressively frequent lava burial toward top. A careful analysis of H/Wco ratio (determined as 0.18 for other volcanic fields worldwide) shows that this ratio strongly depends on (1) the calculation method of H and (2) lava burial of cone. For Etnean cones, applying an improved method for calculating H relative to the dipping substrate results in a significantly lowered standard H/Wco ratio (0.137), which in turn questions the validity of the classical value of 0.18 in the case of large central volcanoes. The reduction of the ratio is not only due to methodology but also to the common lava burial. This can be expressed even better if Hmean is used instead of Hmax (Hmean/Wco = 0.098). Using this measure, at Etna, well formed cones have higher ratios than structurally deformed (e. g. double or rifted) cones. Furthermore, although the sampled scoria cones at Etna have formed in a relatively narrow time interval (〈 6500 yrs BP), there is a slight decrease in H/Wco corresponding to erosional changes detected globally (H/Wco = 0.143, 0.135 and 0.115 for three age classes of Etna's scoria cones, corresponding to average slopes of 26.6, 23.9 and 23.7°). Because the morphometrical effect of position on a dipping substrate as well as lava burial exceeds the effect of erosion, we call attention to use caution in simply using the H/Wco ratio of scoria cones for detecting age, especially on large active volcanoes.
    Description: Published
    Description: 320-330
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: scoria cone ; morphometry ; Etna ; H/Wco ratio ; DEM analysis ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.06. Methods::05.06.99. General or miscellaneous
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  • 5
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    Lava flow superposition: The reactivation of flow units in compound ’a’a flows (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Basaltic 'a'ā lava flows often demonstrate compound morphology, consisting of many juxtaposed and superposed flow units. Following observations made during the 2001 eruption of Mt. Etna, Sicily, we examine the processes that can result from the superposition of flow units, when the underlying units are sufficiently young to have immature crusts and deformable cores. During this eruption, we observed that the emplacement of new surface flow units may reactivate older, underlying units by squeezing the still-hot flow core away from the site of loading. Here, we illustrate three different styles of reactivation that depend on the time elapsed between the emplacement of the two flow units, hence the rheological contrast between them. For relatively long time intervals (2 to 15 days), and consequently significant rheological contrasts, superposition can pressurise the underlying flow unit, leading to crustal rupture and the subsequent extrusion of a small volume of high yield strength lava. Following shorter intervals (1 to 2 days), the increased pressure caused by superposition can result in renewed, slow advance of the underlying immature flow unit front. On timescales of 〈 1 day, where there is little rheological contrast between the two units, the thin intervening crust can be disrupted during superposition, allowing mixing of the flow cores, large-scale reactivation of both units, and widespread channel drainage. This mechanism may explain the presence of drained channels in flows that are known to have been cooling-limited, contrary to the usual interpretation of drainage as an indicator of volume-limited behaviour. Because the remobilisation of previously stagnant lava can occur swiftly and unexpectedly, it may pose a significant hazard during the emplacement of compound flows. Constant monitoring of flow development to identify areas where superposition is occurring is therefore recommended, as this may allow potentially hazardous rapid drainage events to be forecast. Reactivation processes should also be borne in mind when reconstructing the emplacement of old lava flow fields, as failure to recognise their effects may result in the misinterpretation of features such as drained channels.
    Description: The work was funded by NERC studentship NER/S/A2005/13681 and grant NE/F018010/1.
    Description: Published
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: open
    Keywords: Etna ; flow unit ; compound flow ; superposition ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
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    LIDAR strip adjustment: Application to volcanic areas (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: DEMs derived from LIDAR data are nowadays largely used for quantitative analyses and modelling in geology and geomorphology. High-quality DEMs are required for the accurate morphometric and volumetric measurement of land features. We propose a rigorous automatic algorithm for correcting systematic errors in LIDAR data in order to assess sub-metric variations in surface morphology over wide areas, such as those associated with landslide, slump, and volcanic deposits. Our procedure does not require a priori knowledge of the surface, such as the presence of known ground control points. Systematic errors are detected on the basis of distortions in the areas of overlap among different strips. Discrepancies between overlapping strips are assessed at a number of chosen computational tie points. At each tie point a local surface is constructed for each strip containing the point. Displacements between different strips are then calculated at each tie point, and minimization of these discrepancies allows the identification of major systematic errors. These errors are identified as a function of the variables that describe the data acquisition system. Significant errors mainly caused by a non-constant misestimation of the roll angle are highlighted and corrected. Comparison of DEMs constructed using first uncorrected and then corrected LIDAR data from different Mt. Etna surveys shows a meaningful improvement in quality: most of the systematic errors are removed and the accuracy of morphometric and volumetric measurements of volcanic features increases. These corrections are particularly important for the following studies of Mt. Etna: calculation of lava flow volume; calculation of erosion and deposition volume of pyroclastic cones; mapping of areas newly covered by volcanic ash; and morphological evolution of a portion of an active lava field over a short time span.
    Description: Published
    Description: 123-135
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: LIDAR ; Calibration ; DEM ; Etna ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.06. Methods::05.06.99. General or miscellaneous
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  • 7
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    The role of syn-eruptive vesiculation on explosive basaltic activity at Mt. Etna, Italy (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: We investigated the dynamics of explosive activity at Mt. Etna between 31 August and 15 December 2006 by combining vesicle studies in the erupted products with measurements of the gas composition at the active, summit crater. The analysed scoria clasts present large, connected vesicles with complex shapes and smaller, isolated, spherical vesicles, the content of which increases in scoriae from the most explosive events. Gas geochemistry reports CO2/SO2 and SO2/HCl ratios supporting a deep-derived gas phase for fire-fountain activity. By integrating results from scoria vesiculation and gas analysis we find that the highest energy episodes of Mt. Etna activity in 2006 were driven by a previously accumulated CO2-rich gas phase but we highlight the lesser role of syn-eruptive vesicle nucleation driven by water exsolution during ascent. We conclude that syn-eruptive vesiculation is a common process in Etnean magmas that may promote a deeper conduit magma fragmentation and increase ash formation.
    Description: Published
    Description: 265-269
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: Etna ; fire-fountains ; vesicle textures ; volcanic degassing ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
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    Fluids-Faults relationships over the seismic area of Southern Apennine (Calabria region, Southern Italy): geochemical information from thermal and sulphurous water discharges. (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The first comprehensive geochemical data-set of the fluids circulating over a 14,000 km2-wide seismic-prone area of the Southern Apennines, Calabria Region (Italy), is presented here. The geochemical investigations were carried out with the two-fold aim of constraining the origin and interactions of the circulating fluids and to investigate possible relationships with local faults. We collected 60 samples of both thermal and cold waters, from which we extracted the dissolved gases . The geochemical features of the water samples display different types and degrees of water-rock interactions, irrespective of the outlet temperature. The calculated equilibrium temperatures of the thermal waters (60-160°C) and the low heat flow of the whole study area, are consistent with a heating process due to deep water circulation and rapid upflow through lithospheric structures. The composition of the dissolved gases reveals that crustal-originating gases (N2 and CO2-dominated ) feed all the groundwaters. The 3He/4He ratios of the dissolved helium, in the range of 0.03 to 0.22Rac for the thermal waters and 0.05-0.63Rac for the cold waters (Rac = helium isotope ratio corrected for atmospheric contamination), are mainly the result of a two-component (radiogenic and atmospheric) mixing, although indications of mantle-derived helium are found in some cold waters. As the study area had been hit by 18 of the most destructive earthquakes (magnitude ranging from 5.9 to 7.2) occurring over a 280-year time span (1626-1908) in Southern Apennines, the reported results on the circulating fluids may represent the reference for a better inside knowledge of the fault-fluid relationships and for the development oflong-term geochemical monitoring strategies for the area.
    Description: In press
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: Fluids/Fault interactions ; isotope geochemistry ; thermal waters ; dissolved gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
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    Anomalous fluid emission of a deep borehole in a seismically active area of Northern Apennines (Italy) (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The Miano borehole of 1047 m depth is located close to the river Parma in the Northern Apennines, Italy. A measuring station is installed to observe the discharge of fluids continuously since November 2004. The upwelling fluid of this artesian well is a mixture of thermal water and methane as main components. In non-seismogenic areas, we would expect a relative constant fluid emission perhaps overlaid with long term variations from that kind of deep reservoirs during the time. However, the continuously record of the fluid emission, in particular the water discharge, the gas flow rate and the water temperature, show periods of stable values interrupted by anomalous periods of fluctuations in the recorded parameters. The anomalous variations of these parameters are of low amplitude in comparison to the total values but significant in their long-term trend. Meteorological influences of rain and barometric pressure were not detected in recorded data probably due to reservoir depth and relatively high reservoir overpressure. Influences due to the ambient temperature after the discharge were evaluated by statistical analysis. We consider that recorded changes in fluid emission parameters can be interpreted as a mixing process of different fluid components in depth by variations in pore pressure as result of seismogenic stress variation. Local seismicity was analyzed in comparison to fluid’s physico-chemical data. The analysis supports the idea of an influence to fluid transport conditions due to geodynamic processes exist. Water temperature data show frequent anomalies probably connected with possible precursory phenomena of local seismic events.
    Description: In press
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: Fluids ; Earthquakes ; Continous monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
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    Mercury content and speciation in the Phlegrean Fields volcanic complex: Evidence from hydrothermal system and fumaroles (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Mercury is outstanding among the global environmental pollutants of continuing concern. Although degassing of active volcanic areas represents an important natural source of mercury into the atmosphere, still little is known about the amount and behaviour of Hg in volcanic aquifers, especially regarding its chemical speciation. In order to assess the importance of mercury emissions from active volcanoes, thermal waters were sampled in the area surrounding La Solfatara, Pozzuoli bay. This is the most active zone of the Phlegrean Fields complex (coastal area north–west of Naples), with intense hydrothermal activity at present day. Studied groundwaters show total Hg (THg) concentrations range from 56 to 171 ng/l and are lower than the 1000 ng/l threshold value for human health protection fixed by the World Health Organization (WHO, 1993). We also carefully discriminated the different aqueous species of Hg in the collected water samples. Besides, original data on Hg determination in gaseous manifestations at La Solfatara crater are also reported. We measured volcanogenic mercury concentration and Hg/Stot ratio both in the volcanic plume and in fumarolic condensates in order to better constrain Hg reactivity once emitted into the atmosphere. Data on Hg/Stot reveal that there is no significant difference between Hg volcanic composition at the venting source (fumaroles) and in near-vent diluted volcanic plumes (1.6×10−5 and 1.9×10−5, respectively), suggesting that there is limited Hg chemical processing in volcanic fumarole plumes, at least on the timescales of a few seconds investigated here. Combining the mean fumaroles Hg/CO2 mass ratio of about 1.3×10−8 (molar ratio: 2.1×10−9) with the hydrothermal soil diffuse CO2 degassing of the area, the annual Hg flux from La Solfatara is estimated as 7 kg y−1 (0.007 t y−1). Current mercury emission from La Solfatara volcano represents a very small contribution to the estimated global volcanic budget for this element, and the estimated Hg flux is considerably lower than that estimated from open-conduit active basaltic volcanoes.
    Description: Published
    Description: 250–260
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: hydrothermal waters ; total mercury ; mercury speciation ; fumaroles ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 11
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    Extreme methane deuterium, nitrogen and helium enrichment in natural gas from the Homorod seep (Romania) (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Methane (CH4) in terrestrial environments, whether microbial, thermogenic, or abiogenic, exhibits a large variance in C and H stable isotope ratios due to primary processes of formation. Isotopic variability can be broadened through secondary, post-genetic processes, such as mixing and isotopic fractionation by oxidation. The highest and lowest 13C and 2H (or D, deuterium) concentrations in CH4 found in various geologic environments to date, are defined as “natural” terrestrial extremes. We have discovered a new extreme in a natural gas seep with values of deuterium concentrations, δDCH4, up to+124‰that far exceed those reported for any terrestrial gas. The gas, seeping from the small Homorod mud volcano in Transylvania (Romania), also has extremely high concentrations of nitrogen (N92 vol.%) and helium (up to 1.4 vol.%). Carbon isotopes in CH4, C2H6 and CO2, and nitrogen isotopes in N2 indicate a primary organic sedimentary origin for the gas (a minor mantle component is suggested by the 3He/4He ratio, R/Ra~0.39). Both thermogenic gas formation modeling and Rayleigh fractionation modeling suggest that the extreme deuterium enrichment could be explained by an oxidation process characterised by a δDCH4 and δ13CCH4 enrichment ratio (ΔH/ΔC) of about 20, and may be accounted for by abiogenic oxidation mediated by metal oxides. All favourable conditions for such a process exist in the Homorod area, where increased heat flow during Pliocene–Quaternary volcanism may have played a key role. Finally we observed rapid variations (within 1 h) in C and H isotope ratios of CH4, and in the H2S concentrations which are likely caused by mixing of the deep oxidized CH4–N2–H2S–He rich gas with a microbial methane generated in the mud pool of one of the seeps. We hypothesize that the unusual features of Homorod gas can be the result of a rare combination of factors induced by the proximity of sedimentary organic matter, mafic, metal-rich volcanic rocks and salt diapirs,leading to the following processes: a) primary thermogenic generation of gas at temperatures between 130 and 175 °C; b) secondary alteration through abiogenic oxidation, likely triggered by the Neogene–Quaternary volcanism of the eastern Transylvanian margin; and c) mixing at the surface with microbial methane that formed through fermentation in the mud volcano water pool. The Homorod gas seep is a rare example that demonstrates how post-genetic processes can produce extreme gas isotope signatures (thus far only theorized), and that extremely positive δDCH4 values cannot be used to unambiguously distinguish between biotic and abiotic origin.
    Description: Published
    Description: 89-96
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Methane ; Deuterium ; Nitrogen ; Helium ; Seep ; Mud volcano ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 12
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    Abiotic methane flux from the Chimaera seep and Tekirova ophiolites (Turkey): Understanding gas exhalation from low temperature serpentinization and implications for Mars (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The emission of abiotic methane (CH4) into the atmosphere from low temperature serpentinization in ophiolitic rocks is documented to date only in four countries, the Philippines, Oman, New Zealand, and Turkey. Serpentinization produces large amounts of hydrogen (H2) which in theory may react with CO2 or CO to form hydrocarbons (Fischer–Tropsch Type synthesis, FTT). Similar mechanisms have been invoked to explain the CH4 detected on Mars, so that understanding flux and exhalation modality of ophiolitic gas on Earth may contribute to decipher the potential degassing on Mars. This work reports the first direct measurements of gas (CH4, CO2) flux ever done on onshore ophiolites with present-day serpentinization. We investigated the Tekirova ophiolites at Çirali, in Turkey, hosting the Chimaera seep, a system of gas vents issuing from fractures in a 5000 m2 wide ophiolite outcrop. At this site at least 150–190 t of CH4 is annually released into the atmosphere. The molecular and isotopic compositions of C1–C5 alkanes, CO2, and N2 combined with source rock maturity data and thermogenic gas formation modelling suggested a dominant abiotic component (~80– 90%) mixed with thermogenic gas. Abiotic H2-rich gas is likely formed at temperatures below 50 °C, suggested by the low deuterium/hydrogen isotopic ratio of H2 (δDH2: −720‰), consistent with the low geothermal gradient of the area. Abiotic gas synthesis must be very fast and effective in continuously producing an amount of gas equivalent to the long-lasting (N2 millennia) emission of N100 t CH4 yr−1, otherwise pressurised gas accumulation must exist. Over the same ophiolitic formation, 3 km away from Chimaera, we detected an invisible microseepage of abiotic CH4 with fluxes from 0.07 to 1 g m−2 d−1. On Mars similar fluxes could be able to sustain the CH4 plume apparently recognised in the Northern Summer 2003 (104 or 105 t yr−1) over the wide olivine bedrock and outcrops of hydrated silicates in the Syrtis Major and Nili Fossae; just one seep like Chimaera or, more realistically, a weak, spatially sporadic microseepage, would be sufficient to maintain the atmospheric CH4 level on Mars.
    Description: Published
    Description: 96-104
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: abiotic methane ; seepage ; serpentinization ; ophiolites ; Mars ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 13
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    Fluid origin, gas fluxes and plumbing system in the sediment-hosted Salton Sea Geothermal System (California, USA) (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The Salton Sea Geothermal System (California) is an easily accessible setting for investigating the interactions of biotic and abiogenic geochemical processes in sediment-hosted hydrothermal systems. We present new temperature data and the molecular and isotopic composition of fluids seeping at the Davis-Schrimpf seep field during 2003–2008. Additionally, we show the first flux data for CO2 and CH4 released throughout the field from focused vents and diffuse soil degassing. The emitted gases are dominated by CO2 (~98%) and CH4 (~1.5%). By combining δ13CCO2 (as low as −5.4‰) and δ13CCH4 (−32‰to−17.6‰) with 3He/4He (R/RaN6) and δDCH4 values (−216‰to−150‰), we suggest, in contrast to previous studies, that CO2 may have a significant Sub-Continental Mantle source, with minimal crustal contamination, and CH4 seems to be a mixture of high temperature pyrolitic (thermogenic) and abiogenic gas. Water seeps show that δD and δ18O increase proportionally with salinity (Total Dissolved Solids in g/L) ranging from 1–3 g/L (gryphons) to 145 g/L (hypersaline pools). In agreement with elemental analyses, the isotopic composition of the waters indicate a meteoric origin, modified by surface evaporation, with little or no evidence of deep fossil or magmatic components. Very high Cl/Br (N3,000) measured at many seeping waters suggests that increased salinities result from dissolution of halite crusts near the seep sites. Gas flux measurements from 91 vents (pools and gryphons) give a conservative estimate of ~2,100 kg of CO2 and 11.5 kg of CH4 emitted per day. In addition soil degassing measured at 81 stations (20x20 m grid over 51,000 m2) revealed that 7,310 kg/d CO2 and 33 kg/d CH4 are pervasively released to the atmosphere. These results emphasise that diffuse gas emission from soil can be dominant (~75%) even in hydrothermal systems with large and vigorous gas venting. Sediment-hosted hydrothermal systems may represent an intermediate class of geologic methane sources for the atmosphere, with emission factors lower than those of sedimentary seepage in petroleum basins but higher than those of traditional geothermal-volcanic systems; on a global scale they may significantly contribute to the atmospheric methane budget.
    Description: Published
    Description: 67-83
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Salton Sea Geothermal System ; hydrothermal seeps ; gas and water geochemistry ; flux measurements ; mantle ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 14
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    Coupled Use of COSPEC and Satellite Measurements to define the Volumetric Balance During Effusive Eruptions at Mt. Etna, Italy (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Mt. Etna is one of the most studied and extensively monitored volcanoes on earth (Bonaccorso et al., 2004). One of the most frequent hazards are due to the eruption of lava flows, more specifically those flows produced during flank eruptions. These eruptions potentially can produce extensive flows that can inundate densely populated communities of the lower slopes (Guest and Murray, 1979; Behncke et al., 2005). Satellite remote sensing can be used during effusive eruptions to help monitoring the volcano, by determining effusion rates of the flows, aiding in hazard management. The degassing that takes place when magma is rising to the surface can be regularly monitored using ultraviolet spectroscopic methods (e.g. Andres et al., 2001, Sutton et al., 2001). Sulfur Dioxide (SO2) fluxes have been derived from correlation spectrometer (COSPEC) measurements at Mt. Etna (Italy) on a regular basis since 1987 (e.g. Caltabiano et al., 1994; Allard, 1997; Andronico et al., 2005; Burton et al., 2005; Burton et al., in press). Previous studies have compared field-based effusion rates with the measured SO2 fluxes to determine how much of the degassed magma is erupted onto Etna’s flanks in the form of lava flows (Allard, 1997; Harris et al., 2000). However, most of these studies examine bulk volumes erupted over an eruption rather than examining the short-term variations during eruptions. Determining the amount of lava erupted and/or the balance between the amount supplied and the amount erupted remains an unresolved issue. The main objectives of this paper are to examine such short-term variations using satellite-based effusion rates along with regularly measured SO2 fluxes. Using these measurements we determine how and when the volume of supplied magma is balanced by the volume of erupted lava during individual effusive eruptions.
    Description: In press
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: restricted
    Keywords: Etna ; Thermal Remote Sensing ; SO2 ; Mass Balance ; Effusive Eruptions ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 15
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    Societal need for improved understanding of climate change, anthropogenic impacts, and geo-hazard warning drive development of ocean observatories in European Seas (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Society’s needs for a network of in situ ocean observing systems cross many areas of earth and marine science. Here we review the science themes that benefit from data supplied from ocean observatories. Understanding from existing studies is fragmented to the extent that it lacks the coherent long-term monitoring needed to address questions at the scales essential to understand climate change and improve geo-hazard early warning. Data sets from the deep sea are particularly rare with long-term data available from only a few locations worldwide. These science areas have impacts on societal health and well-being and our awareness of ocean function in a shifting climate. Substantial efforts are underway to realise a network of open-ocean observatories around European Seas that will operate over multiple decades. Some systems are already collecting high-resolution data from surface, water column, seafloor, and sub-seafloor sensors linked to shore by satellite or cable connection in real or near-real time, along with samples and other data collected in a delayed mode. We expect that such observatories will contribute to answering major ocean science questions including: How can monitoring of factors such as seismic activity, pore fluid chemistry and pressure, and gas hydrate stability improve seismic, slope failure, and tsunami warning? What aspects of physical oceanography, biogeochemical cycling, and ecosystems will be most sensitive to climatic and anthropogenic change? What are natural versus anthropogenic changes? Most fundamentally, how are marine processes that occur at differing scales related? The development of ocean observatories provides a substantial opportunity for ocean science to evolve in Europe. Here we also describe some basic attributes of network design. Observatory networks provide the means to coordinate and integrate the collection of standardised data capable of bridging measurement scales across a dispersed area in European Seas adding needed certainty to estimates of future oceanic conditions. Observatory data can be analysed along with other data such as those from satellites, drifting floats, autonomous underwater vehicles, model analysis, and the known distribution and abundances of marine fauna in order to address some of the questions posed above. Standardised methods for information management are also becoming established to ensure better accessibility and traceability of these data sets and ultimately to increase their use for societal benefit. The connection of ocean observatory effort into larger frameworks including the Global Earth Observation System of Systems (GEOSS) and the Global Monitoring of Environment and Security (GMES) is integral to its success. It is in a greater integrated framework that the full potential of the component systems will be realised.
    Description: Published
    Description: 1-33
    Description: 3.7. Dinamica del clima e dell'oceano
    Description: JCR Journal
    Description: reserved
    Keywords: Seafloor and water columnobservatories ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate ; 01. Atmosphere::01.01. Atmosphere::01.01.04. Processes and Dynamics ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques ; 03. Hydrosphere::03.01. General::03.01.03. Global climate models ; 03. Hydrosphere::03.01. General::03.01.07. Physical and biogeochemical interactions ; 03. Hydrosphere::03.01. General::03.01.08. Instruments and techniques ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.03. Physical::03.03.02. General circulation ; 03. Hydrosphere::03.03. Physical::03.03.03. Interannual-to-decadal ocean variability ; 03. Hydrosphere::03.03. Physical::03.03.05. Instruments and techniques ; 03. Hydrosphere::03.04. Chemical and biological::03.04.01. Biogeochemical cycles ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.08. Instruments and techniques ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.05. Geomagnetism::04.05.05. Main geomagnetic field ; 04. Solid Earth::04.05. Geomagnetism::04.05.08. Instruments and techniques ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.03. Heat generation and transport ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.01. Computational geophysics::05.01.01. Data processing ; 05. General::05.02. Data dissemination::05.02.99. General or miscellaneous ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.02. Seismological data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data ; 05. General::05.08. Risk::05.08.01. Environmental risk ; 05. General::05.08. Risk::05.08.02. Hydrogeological risk
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  • 16
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    New evidence of mantle heterogeneity beneath the Hyblean Plateau (southeast Sicily, Italy) as inferred from noble gases and geochemistry of ultramafic xenoliths (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: We analyzed major and trace elements, Sr and Nd isotopes in ultramafic xenoliths in Miocenic age Hyblean diatremes, along with noble gases of CO2-rich fluid inclusions hosted in the same products. The xenoliths consist of peridotites and pyroxenites, which are considered to be derived from the upper mantle. Although the mineral assemblage of peridotites and their whole-rock abundance of major elements (e.g., Al2O3 = 0.8–1.5 wt.%, TiO2 = 0.03–0.08 wt.%) suggest a residual character of the mantle, a moderate enrichment in some incompatible elements (e.g., LaN/YbN = 9–14) highlights the presence of cryptic metasomatic events. In this context a deep silicate liquid is considered the metasomatizing agent, which is consistent with the occurrence of pyroxenites as veins in peridotites. Both the Zr/Nb and 143Nd/144Nd ratios of the investigated samples reveal two distinct compositional groups: (1) peridotites with Zr/Nb ≈ 4 and 143Nd/144Nd ≈ 0.5129, and (2) pyroxenites with Zr/Nb ≈ 20 and 143Nd/144Nd ≈ 0.5130. The results of noble-gas analyses also highlight the difference between the peridotite and pyroxenite domains. Indeed, the 3He/4He and 4He/40Ar* ratios measured in the fluid inclusions of peridotites (respectively 7.0–7.4 ± 0.1 Ra and 0.5–8.2, where Ra is the atmospheric 3He/4He ratio of 1.38 × 10− 6) were on average lower than those for the pyroxenites (respectively 7.2–7.6 Ra and 0.62–15). This mantle heterogeneity is interpreted as resulting from a mixing between two end-members: (1) a peridotitic layer with 3He/4He ≈ 7 Ra and 4He/40Ar* ≈ 0.4, which is lower than the typical mantle ratio (~ 1–4) probably due to melt extraction events, and (2) metasomatizing mafic silicate melts that gave rise to pyroxenites characterized by 3He/4He ≈ 7.6 Ra, with a variable 4He/40Ar* due to degassing processes connected with the ascent of magma at different levels in the peridotite wall rock. The complete geochemical data set also suggests two distinct mantle sources for the xenolithic groups highlighted above: (1) a HIMU (high-μ)-type source for the peridotites and (2) a DM (depleted mantle)-type source for the pyroxenites.
    Description: Published
    Description: 70-81
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: restricted
    Keywords: noble gases ; mantle ; xenoliths ; fluid inclusions ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 17
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    Comment on ‘Conduit convection, magma mixing, and melt inclusion trends at persistent degassing volcanoes’ by Fred Witham, published in Earth Planetary Science Letters (2011) 301, 345–352 (2012)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: No abstract
    Description: Published
    Description: 306-308
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Etna ; Stromboli ; volatiles ; melt inclusions ; magma mixing ; magma degassing ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
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  • 18
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    Interaction of volcano-tectonic fault with magma storage, intrusion and flank instability: a thirty years study at Mt. Etna volcano (2012)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: We investigated the relationship between the occurrence of earthquakes along the main volcano-tectonic structures and periods of volcanic unrest at Mt Etna. We focused our study on the Pernicana Fault System (PFS), one of the most outstanding tectonic structures delineating the northern border of the sliding eastern flank of Etna volcano. During recent decades several flank eruptions have occurred at Mt Etna and sometimes PFS released seismicity before the eruptive events, while in other cases there have been earthquakes that did not precede any eruption. To highlight a possible relation between PFS ruptures and volcanic unrest, we took into account the most energetic earthquakes (M ≥ 3.5) occurring in the last three decades (1980-2010), and considered the volcano deformation sources previously inferred by inverting geodetic data recorded during the several flank eruptions in this time interval. The estimates of stress redistribution on the PFS due to different volcano sources, such as the magma storage, the dike intrusions and the sliding eastern flank, were studied by implementing 3D numerical models that also consider the presence of topography and medium heterogeneity. Our results show that the pressurization of an intermediate storage and the traction exerted by the eastern flank sliding contribute to the seismicity along the PFS even without preceding an immediate eruption. Instead, the seismicity along the PFS related to the intrusions inside the northern sector of the volcano would represent a potential early-warning for an impending eruption at Mt Etna.
    Description: Published
    Description: 127-136
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: restricted
    Keywords: Etna ; volcano-tectonic faults ; volcano sources and stress ; stress field change ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 19
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    Relations between deformation and upper crustal magma emplacement in laboratory physical models (2011)
    Elsevier
    Details
    Publication Date: 2020-05-28
    Description: This paper presents analogue models for the emplacement of granitic magmas in upper crustal levels with different mechanical layering during shortening, extension and strike–slip deformation. In particular, we investigated how a weak layer embedded in the upper brittle crust can control the level of magma emplacement. The adopted experimental setup was used to examine the control of soft rocks on the movement of magma through a deforming brittle crust. Model results indicate that the occurrence of a weak (soft) layer embedded in brittle (stiff) material has an impact on the level of magma emplacement. The level of emplacement during both extension and shortening was systematically deeper for models with a soft layer than for purely brittle models. During strike–slip deformation the magma pierced the surface in both purely brittle and brittle–ductile models.
    Description: Published
    Description: 139-146
    Description: 3.2. Tettonica attiva
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: Mechanical layering of upper crust ; Magma emplacement ; Analogue modelling ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 20
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    Microseepage in drylands: Flux and implications in the global atmospheric source/sink budget of methane (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Drylands are considered a net sink for atmospheric methane and a main item of the global inventories of the greenhouse gas budget. It is outlined here, however, that a significant portion of drylands occur over sedimentary basins hosting natural gas and oil reservoirs, where gas migration to the surface takes place, producing positive fluxes of methane into the atmosphere. New field surveys, in different hydrocarbonprone basins, confirm that microseepage, enhanced by faults and fractures in the rocks, overcomes the methanotrophic consumption occurring in dry soil throughout large areas, especially in the winter season. Fluxes of a few units to some tens of mg m−2 day−1 are frequent over oil–gas fields, whose global extent is estimated at 3.5–4.2 million km2; higher fluxes (〉50 mg m−2 day−1) are primarily, but not exclusively, found in basins characterized by macro-seeps. Microseepage may however potentially exist over a wider area (∼8 million km2, i.e. 15% of global drylands), including the Total Petroleum Systems, coal measures and portions of sedimentary basins that have experienced thermogenesis. Based on a relatively large and geographically dispersed data-set (563 measurements) from different hydrocarbon-prone basins in USA and Europe, upscaling suggests that global microseepage emission exceeding 10 Tg year−1 is very likely. Microseepage is then only one component of a wider class of geological sources, including mud volcanoes, seeps, geothermal and marine seepage, which cannot be ignored in the atmospheric methane budget.
    Description: Published
    Description: 265-274
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: microseepage ; methane flux ; soil sink ; drylands ; petroleum ; greenhouse gas ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 21
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    Benthic habitat characterization and distribution from two representative sites of the deep-water SML Coral Province (Mediterranean) (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Two sites (MS04 and MS06) from the Santa Maria di Leuca (SML) Coral Province were analyzed by a video and acoustic survey during the National Italian Project Apulian Plateau Bank Ecosystem Study (APLABES). Site MS04 (Atlantis Mound) is characterized by a sub-conical mound, 500 m wide and 25 m high, located at a water depth of about 650 m. Site MS06 (Yellow Chain) comprises several elongated reliefs (NNW–SSE-oriented), up to 25 m high and 500 m in maximum lateral extent, located at a depth of between 490 and 540 m. At both sites, two main mesohabitats (mound and intermound) containing several coral-bearing and -barren macrohabitats were observed in recorded videos and detected in side-scan sonographs. The coral-rich macrohabitats, characterized by densely packed colonies of the scleractinians Madrepora oculata and, secondarily, Lophelia pertusa (M/L), are typically restricted to the mound areas. The mud-dominated ones, almost devoid of M/L colonies, are more common within the intermound mesohabitat. However, on the most extensive mounds, both macrohabitat typologies exist. They are heterogeneously distributed on the mound surface, often showing a clear differentiation along two opposite flanks of the same topographic feature. M/L-rich macrohabitats are preferentially located on top and along the mound northeastern flank, showing a typical step-like distribution, probably reflecting the arrangement of hard substrate outcrops. Along this flank, fan-shaped Madrepora colonies and sponges are often oriented NNW–SSE, implying, together with other evidence, a primary southwestern current flow. The hard-bottom macrohabitats of the southwestern mound flank are generally restricted to sparse exposed, subvertical to overhanging scarps as well as to heterometric boulders located at the scarp base. Their fauna is mainly characterized by small-sized organisms (such as sponges and solitary scleractinians) although m-sized boulders may locally host very large antipatharian colonies (Leiopathes glaberrima). The heterogeneous distribution of the observed benthic macrohabitats seems to be strictly related to the local topography, the main current flow (and consequently larvae/food supply per unit of time), and the substrate typology (hard- vs. soft-bottom).
    Description: Published
    Description: 380-396
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Deep-watercoralmound ; Habitat ; Mediterranean ; Madrepora ; Lophelia ; Visual survey ; Acoustic survey ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 22
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    Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: GEMS (Gamma Energy Marine Spectrometer) is a prototype of an autonomous radioactivity sensor for underwater measurements, developed in the framework for a development of a submarine telescope for neutrino detection (KM3NeT Design Study Project). The spectrometer is highly sensitive to gamma rays produced by 40K decays but it can detect other natural (e.g., 238U,232Th) and anthropogenic radio-nuclides (e.g., 137Cs). GEMS was firstly tested and calibrated in the laboratory using known sources and it was successfully deployed for a long-term (6 months) monitoring at a depth of 3200 m in the Ionian Sea (Capo Passero, offshore Eastern Sicily). The instrument recorded data for the whole deployment period within the expected specifications. This monitoring provided, for the first time, a continuous time-series of radioactivity in deep-sea.
    Description: In press
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: open
    Keywords: NaI(Tl) sensor ; underwater spectrometer ; marine radioactivity ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 23
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    Helium and argon isotopic compositions of mantle xenoliths from Tallante and Calatrava, Spain. (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: We have analyzed by single-step crushing helium and argon isotopes in olivine and orthopyroxene from mantle xenoliths of Calatrava (CLV) in central Spain and Tallante (TL) in southeast Spain. The investigation focused on carefully selected samples previously characterized in terms of major and trace elements on both bulk rock and constituent minerals, and Sr and Nd isotopes on clinopyroxene separates. Six analyses were performed on protogranular spinel lherzolites from CLV, and 17 were performed on spinel harzburgites, lherzolites, and orthopyroxenites from TL. The 40Ar/36Ar ratio was between 296 and 622, indicating atmospheric contamination, which probably occurred during exposure to the surface. The helium-isotope ratio (3He/4He) ranged between 3.6 and 6.5 Ra in CLV samples and between 1.4 and 5.7 Ra in TL samples. There was a positive correlation between the 3He/4He and 4He/40Ar* ratios, possibly reflecting diffusive fractionation between 3He, 4He, and 40Ar within mantle sections interacting with ascending melts. However, the difference between the maximum 3He/4He ratios measured in CLV and TL appears to be related to significant differences in the metasomatic melts that affected the two sectors of the lithospheric mantle. In agreement with the findings of previous studies, the helium isotopes at CLV are compatible with metasomatism due to ascending HIMU-type asthenospheric melts. In contrast, the lower 3He/4He values recorded at TL suggest subduction-related metasomatic components that are possibly related to the Cenozoic subduction of the Betic system. Such event plausibly introduced crust-derived fluids that metasomatized the mantle wedge, slightly decreasing its 3He/4He value. Noble gases appear decoupled from other elements during these mantle processes, since comparatively low 3He/4He values have been recorded also in samples that are relatively unmetasomatized in terms of incompatible lithophile elements. We hypothesize a role for volatile-dominated, CO2-rich fluids progressively decoupling from the ascending metasomatic melts and migrating in the surrounding peridotite matrix to form a diffuse aureola enriched in noble gases.
    Description: Published
    Description: 18-26
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: noble gas ; xenoliths ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 24
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    Gas seepage from Tokamachi mud volcanoes, onshore Niigata Basin (Japan): Origin, post-genetic alterations and CH4–CO2 fluxes (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Methane and CO2 emissions from the two most active mud volcanoes in central Japan, Murono and Kamou (Tokamachi City, Niigata Basin), were measured in from both craters or vents (macro-seepage) and invisible exhalation from the soil (mini- and microseepage). Molecular and isotopic compositions of the released gases were also determined. Gas is thermogenic (d13CCH4 from 32.9‰ to 36.2‰), likely associated with oil, and enrichments of 13C in CO2 (d13CCO2 up to +28.3‰) and propane (d13CC3H8 up to 8.6‰) suggest subsurface petroleum biodegradation. Gas source and post-genetic alteration processes did not change from 2004 to 2010. Methane flux ranged within the orders of magnitude of 101–104 gmˉ2 dˉ1 in macro-seeps, and up to 446 g mˉ2 dˉ1 from diffuse seepage. Positive CH4 fluxes from dry soil were widespread throughout the investigated areas. Total CH4 emission from Murono and Kamou were estimated to be at least 20 and 3.7 ton aˉ1, respectively, of which more than half was from invisible seepage surrounding the mud volcano vents. At the macro-seeps, CO2 fluxes were directly proportional to CH4 fluxes, and the volumetric ratios between CH4 flux and CO2 flux were similar to the compositional CH4/CO2 volume ratio. Macro-seep flux data, in addition to those of other 13 mud volcanoes, supported the hypothesis that molecular fractionation (increase of the ‘‘Bernard ratio’’ C1/(C2 + C3)) is inversely proportional to gas migration fluxes. The CH4 ‘‘emission factor’’ (total measured output divided by investigated seepage area) was similar to that derived in other mud volcanoes of the same size and activity. The updated global ‘‘emission-factor’’ data-set, now including 27 mud volcanoes from different countries, suggests that previous estimates of global CH4 emission from mud volcanoes may be significantly underestimated.
    Description: Published
    Description: 348-359
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Methane ; natural gas ; mud volcanoes ; seepage ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 25
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    Geochemical evidence for and characterization of CO2 rich gas sources in the epicentral area of the Abruzzo 2009 earthquakes (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: We describe the results of a detailed hydrogeochemical campaign on the groundwater circulating in two regional aquifers located in the area of the Abruzzo 2009 earthquakes. The influx of deeply derived CO2 rich gases into the two aquifers is highlighted by the 13C isotopic composition of dissolved carbon species. The source of the gas is roughly localised beneath the epicentral area of the earthquakes where the presence of sources of fluids under high pressure is suggested by seismological investigations. The carbon isotopic-mass balance of the aquifers indicates that the amount of the deep CO2 dissolved and transported by the groundwaters is ~530 t/day. The chemical and isotopic composition of the gas entering the aquifers, named Abruzzo gas, has been derived by comparing the data measured in the springs with the results of a gas–water– rock reaction model, that simulates the evolution of the chemical and isotopic composition of groundwater affected by the input of a deeply-derived CO2 rich gas phase. The composition of Abruzzo gas is compared to that of 40 large gas emissions located in central Italy. The gas becomes progressively richer in radiogenic elements (4He and 40Ar) and in N2, from the volcanic complexes in the west to the Apennines in the east. The Abruzzo gas, in agreement with its location, well matches the composition of the gases emitted in the pre- Apennine region. These geochemical features, consistent with the structural setting of the region, indicate increasing residence times of the gas in the crust moving from west to east. In particular we suggest that the strong increase in radiogenic crustal gases reflects the occurrence of deep traps where the gas is stored at high pressures for a long time and that such high pressure gas pockets play a major role in the generation of Apennine earthquakes.
    Description: Published
    Description: 389–398
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: carbon dioxide ; Abruzzo earthquakes ; carbon isotopes ; helium isotopes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques
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  • 26
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    Insights into explosive activity at closely-spaced eruptive vents using infrasound signals: Example of Mt. Etna 2008 eruption (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: On 13 May 2008 an eruptive fissure opened on Mount Etna's eastern flank feeding both explosive activity and lava effusion from multiple vents for about 14 months. During the investigated May-September 2008 eruptive period, infrasound recordings from a 4 station-sparse network allowed tracking of the explosive activity in terms of location and dynamics. In order to focus on activity from the eruptive fissure, the infrasonic events generated by the summit craters were selected by using both spectral features and time delays between pairs of stations and excluded from our analysis. Then, to accurately locate events from the fissure, we used a composite method, based on the semblance and brightness functions. This enabled the study of the co-existence of more than one infrasound source and/or its migration along the eruptive fissure. Hence, results permitted us to discriminate the number of active vents and their location along the fissure even when, due to poor weather conditions, it was not possible to access the vents or carry out direct observations. The eruptive activity was characterised by variations in the number of active vents according to the overall intensity of the eruptive event. Variability of the infrasound waveforms highlighted either that distinct vents produced signals with different waveforms, or that single vents generated different events during distinct periods of time, or finally both the previous phenomena. We applied the strombolian bubble vibration model to model waveform differences and attributed the signal variations to bubble radius changes.
    Description: Published
    Description: 1-11
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Etna ; Infrasound ; Infrasonic source location ; explosive activity ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
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  • 27
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    Coupled use of COSPEC and satellite measurements to define the volumetric balance during effusive eruptions at Mt. Etna, Italy (2012)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Using Etna as a case study location, we examine the balance between the volume of magma supplied to the shallow volcanic system (using ground-based SO2 data) and the volume erupted (using satellite thermal data). We do this for three eruptions of Mt. Etna (Italy) during 2002 to 2006. We find that, during the three eruptions, 2.3×107 m3 or 24% of the degassed volume remained unerupted. However, variations in the degree of partitioning between supplied (Vsupply) and erupted (Verupt) magma occur within individual eruptions over the time scales of days. Consequently, we define and quantify three types of partitioning. In the first case, VsupplybVerupt, i.e. more lava is erupted than is supplied. In such a case previously degassed magma is erupted or magma can rise faster than it is able to degas, as occurred during the open phases of the 2002–2003 and 2004–2005 eruptions, respectively. In the second case, VsupplyNVerupt, i.e. less lava is erupted than is supplied. In such a case, magma can erupt in an explosive manner, as occurred during Phase II of the 2002–2003 eruption, or remain within or below the edifice. In the third case, Vsupply=Verupt, i.e. all supplied magma is erupted. During 2002–2006, over a total of 280 days of eruptive activity, this balancing case applied to 50% of the time.
    Description: Published
    Description: 47-53
    Description: JCR Journal
    Description: reserved
    Keywords: Etna ; thermal remote sensing ; SO2 flux ; Effusive eruption ; mass balance ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 28
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    Repeating volcano-tectonic earthquakes at Mt. Etna volcano (Sicily, Italy) during 1999–2009 (2013)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Repeating volcano-tectonic (VT) earthquakes, taking place at Mt. Etna during 1999–2009,were detected and analyzed to investigate their behavior. We found 735 families amounting to 2479 VT earthquakes, representing ~38% of all the analyzed VT earthquakes. The number of VT earthquakes making up the families ranges from 2 to 23. Over 70% of the families comprise 2 or 3 VT earthquakes and only 20 families by more than 10 events. The occurrence lifetime is also highly variable ranging from some minutes to ten years. In particular, more than half of the families have a lifetime shorter than 0.5 day and only ~10% longer than 1 year. On the basis of these results, most of the detected families were considered “burst-type”, i.e., show swarm-like occurrence, and hence their origin cannot be explained by a temporally constant tectonic loading. Indeed, since the analyzed earthquakes take place in a volcanic area, the rocks are affected not only by tectonic stresses related to the fairly steady regional stress field but also by local stresses, caused by the volcano, such as magma batch intrusions/ movements and gravitational loading.We focused on the five groups of families characterized by the longest repeatability over time, namely high number of events and long lifetime, located in the north-eastern, eastern and southern flanks of the volcano. Unlike the first four groups, which similarly to most of the detected families show swarm-like VT occurrences, group “v”, located in the north-eastern sector, exhibits a more “tectonic” behavior with the events making up such a group spread over almost the entire analyzed period. It is clear how both occurrence and slip rates do not remain constant but vary over time, and such changes are time-related to the occurrence of the 2002–2003 eruption. Finally, by FPFIT algorithm a good agreement between directions identified by nodal planes and the earthquake epicentral distribution was generally found.
    Description: Published
    Description: 1223 – 1236
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: repeating earthquakes ; Etna ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
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  • 29
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    Atmospheric sources and sinks of volcanogenic elements in a basaltic volcano (Etna, Italy) (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: This study reports on the first quantitative assessment of the geochemical cycling of volcanogenic elements, from their atmospheric release to their deposition back to the ground. Etna’s emissions and atmospheric depositions were characterised for more than 2 years, providing data on major and trace element abundance in both volcanic aerosols and bulk depositions. Volcanic aerosols were collected from 2004 to 2007, at the summit vents by conventional filtration techniques. Precipitation was collected, from 2006 to 2007, in five rain gauges, at various altitudes around the summit craters. Analytical results for volcanic aerosols showed that the dominant anions were S, Cl, and F, and that the most abundant metals were K, Ca, Mg, Al, Fe, and Ti (1.5–50 lg m 3). Minor and trace element concentrations ranged from about 0.001 to 1 lg m 3. From such analysis, we derived an aerosol mass flux ranging from 3000 to 8000 t a 1. Most analysed elements had higher concentrations close to the emission vent, confirming the prevailing volcanic contribution to bulk deposition. Calculated deposition rates were integrated over the whole Etna area, to provide a first estimate of the total deposition fluxes for several major and trace elements. These calculated deposition fluxes ranged from 20 to 80 t a 1 (Al, Fe, Si) to 0.01–0.1 t a 1 (Bi, Cs, Sc, Th, Tl, and U). Comparison between volcanic emissions and atmospheric deposition showed that the amount of trace elements scavenged from the plume in the surrounding of the volcano ranged from 0.1% to 1% for volatile elements such as As, Bi, Cd, Cs, Cu, Tl, and from 1% to 5% for refractory elements such as Al, Ba, Co, Fe, Ti, Th, U, and V. Consequently, more than 90% of volcanogenic trace elements were dispersed further away, and may cause a regional scale impact. Such a large difference between deposition and emission fluxes at Mt. Etna pointed to relatively high stability and long residence time of aerosols in the plume.
    Description: Published
    Description: 7401-7425
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: trace elements ; volcanic plume chemistry ; bulk deposition ; Etna ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 30
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    Reconstruction of SO2 flux emission chronology from space-based measurements (2012)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Infrared satellite images measured with the MODIS instrument of the volcanic plume produced during the 2006 eruption of Mt. Etna were analysed to produce maps of SO2 amount. We used these maps to reconstruct time series of SO2 fluxes by integrating profiles of SO2 orthogonal to the plume advection direction and multiplying with wind speeds from a meteorological model. These data were then compared with a reconstructed time series of SO2 fluxes measured with the FLAME ground-based network of ultraviolet DOAS systems surrounding the volcano. We found weak agreement on 3rd December when little ash was emitted, but this agreement improved when a 0.3 m s−1 wind speed correction factor was used. FLAME and MODIS results were in good agreement on the 6th December, and improved when a –0.3 m s−1 offset was applied. The corrected data revealed that the only period of time when FLAME and MODIS did not track together was coincident with the presence of ash, which interferes with the IR imagery and retrieval of SO2. We highlight that combining two independent time series of SO2 flux allows a precise determination of wind speed, if there is sufficient time-dependent structure in the SO2 signal. The observed increase in SO2 flux prior to the ash emission is interpreted as a quiescent release of an accumulated gas phase that drive eruptive activity, as previously suggested for the southeast crater system of Etna. In this case the SO2 flux signal therefore acted as a precursor to the eruptive ash events. This work demonstrates that quantitative reconstruction of SO2 flux time series is feasible using MODIS data, opening a new frontier in the use of satellite data to interpret volcanic processes, in particular in poorly monitored remote locations.
    Description: European Space Agency's Earth Observation Envelope Programme (EOEP) – Data User Element (project SAVAA).
    Description: Published
    Description: 80-87
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: SO2 flux ; Modis ; Etna ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 31
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    Deep-sea survey for the detection of methane at the “Santa Maria di Leuca” cold-water coral mounds (Ionian Sea, South Italy) (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The “Santa Maria di Leuca” Cold-Water Coral (CWC) province (northern Ionian Sea) was investigated for the first time to detect eventual occurrence of methane anomalies as a possible indication of hydrocarbon seepage stimulating the coral growth. Most coral mounds have developed in correspondence with tectonic scarps and faults, orthogonal to the southern margin and trending NW-SE, which could be potential sites of gas escape. A visual and instrumental inspection was performed by using a new deep-sea probe equipped with video-cameras, sonar, CTD, methane sensors, and a water sampler. Eight areas were explored by 10 surveys, depths ranging from 380 to 1100 m, for a total of more than 26 h of continuous video and instrumental recording. Sediments were also sampled by gravity corers and analysed in laboratory. The images allowed to assess distribution, abundance and geometry of the colonies, most of which are developed on morphological highs often characterised by tectonic scarps. All data indicate however the lack of a significant occurrence of methane, both in seawater and sediments. No direct or indirect expressions of gas seepage were recognised on the seabed. Weak methane anomalies were detected only in seawater at the base of some fault-linked scarps, where more reducing conditions and bacterial methanogenesis are possibly enhanced by less water circulation. The faults are not fluid-bearing as previously suggested by high-resolution geophysical signatures. The development of the coral colonies thus cannot be attributed to seeping fluids, but to a favourable physiographic position with exposure to nutrient-rich currents.
    Description: Published
    Description: 431-440
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Methane ; Corals ; Seepage ; Marine geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 32
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    Methane emissions from Earth’s degassing: Implications for Mars (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The presence of methane on Mars is of great interest, since one possibility for its origin is that it derives from living microbes. However, CH4 in the martian atmosphere also could be attributable to geologic emissions released through pathways similar to those occurring on Earth. Using recent data on methane degassing of the Earth, we have estimated the relative terrestrial contributions of fossil geologic methane vs. modern methane from living methanogens, and have examined the significance that various geologic sources might have for Mars. Geologic degassing includes microbial methane (produced by ancient methanogens), thermogenic methane (from maturation of sedimentary organic matter), and subordinately geothermal and volcanic methane (mainly produced abiogenically). Our analysis suggests that not, vert, similar80% of the “natural” emission to the terrestrial atmosphere originates from modern microbial activity and not, vert, similar20% originates from geologic degassing, for a total CH4 emission of not, vert, similar28.0×107 tonnes year−1. Estimates of methane emission on Mars range from 12.6×101 to 57.0×104 tonnes year−1 and are 3–6 orders of magnitude lower than that estimated for Earth. Nevertheless, the recently detected martian, Northern-Summer-2003 CH4 plume could be compared with methane expulsion from large mud volcanoes or from the integrated emission of a few hundred gas seeps, such as many of those located in Europe, USA, Mid-East or Asia. Methane could also be released by diffuse microseepage from martian soil, even if macro-seeps or mud volcanoes were lacking or inactive. We calculated that a weak microseepage spread over a few tens of km2, as frequently occurs on Earth, may be sufficient to generate the lower estimate of methane emission in the martian atmosphere. At least 65% of Earth’s degassing is provided by kerogen thermogenesis. A similar process may exist on Mars, where kerogen might include abiogenic organics (delivered by meteorites and comets) and remnants of possible, past martian life. The remainder of terrestrial degassed methane is attributed to fossil microbial gas (not, vert, similar25%) and geothermal-volcanic emissions (not, vert, similar10%). Global abiogenic emissions from serpentinization are negligible on Earth, but, on Mars, individual seeps from serpentinization could be significant. Gas discharge from clathrate-permafrost destabilization should also be considered. Finally, we have shown examples of potential degassing pathways on Mars, including mud volcano-like structures, fault and fracture systems, and major volcanic edifices. All these types of structures could provide avenues for extensive gas expulsion, as on Earth. Future investigations of martian methane should be focused on such potential pathways.
    Description: In press
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Mars ; Methane ; Earth’s degassing ; Seepage ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 33
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    Dike deflection modelling for inferring magma pressure and withdrawal, with application to Etna 2001 case (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: We studied the stress effects of the topography load on dike propagation by considering the results from analogue experiments; in addition, we refined the results by applying numerical simulations using the finite element method (FEM) in order to also consider the medium rheology and real topography. We investigated the dike deflection observed during the final dike emplacement accompanying Etna’s 2001 eruption. We cross-related the information on the position of the dike from ground deformation modelling with the numerical simulation results with the aim of estimating the final excess pressure of the dike when it started to deflect, which proved to be about 4-8 MPa. Assuming that the pressure decreases linearly with the volume of magma moving from the chamber into the dike, we estimated 7-15 MPa as the initial overpressure accumulated at the intermediate magma chamber before its breakout. Although the previous modelling overestimated the stress, the approach presented here leads to infer a compatible stress with the strength of the rocks.
    Description: Published
    Description: 121-129
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Etna ; dike mechanisms ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 34
    facet.materialart.
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    Methane emissions from Earth’s degassing: Implications for Mars (2011)
    Elsevier
    Details
    Publication Date: 2022-02-16
    Description: The presence of methane on Mars is of great interest, since one possibility for its origin is that it derives from living microbes. However, CH4 in the martian atmosphere also could be attributable to geologic emissions released through pathways similar to those occurring on Earth. Using recent data on methane degassing of the Earth, we have estimated the relative terrestrial contributions of fossil geologic methane vs. modern methane from living methanogens, and have examined the significance that various geologic sources might have for Mars. Geologic degassing includes microbial methane (produced by ancient methanogens), thermogenic methane (from maturation of sedimentary organic matter), and subordinately geothermal and volcanic methane (mainly produced abiogenically). Our analysis suggests that not, vert, similar80% of the “natural” emission to the terrestrial atmosphere originates from modern microbial activity and not, vert, similar20% originates from geologic degassing, for a total CH4 emission of not, vert, similar28.0×107 tonnes year−1. Estimates of methane emission on Mars range from 12.6×101 to 57.0×104 tonnes year−1 and are 3–6 orders of magnitude lower than that estimated for Earth. Nevertheless, the recently detected martian, Northern-Summer-2003 CH4 plume could be compared with methane expulsion from large mud volcanoes or from the integrated emission of a few hundred gas seeps, such as many of those located in Europe, USA, Mid-East or Asia. Methane could also be released by diffuse microseepage from martian soil, even if macro-seeps or mud volcanoes were lacking or inactive. We calculated that a weak microseepage spread over a few tens of km2, as frequently occurs on Earth, may be sufficient to generate the lower estimate of methane emission in the martian atmosphere. At least 65% of Earth’s degassing is provided by kerogen thermogenesis. A similar process may exist on Mars, where kerogen might include abiogenic organics (delivered by meteorites and comets) and remnants of possible, past martian life. The remainder of terrestrial degassed methane is attributed to fossil microbial gas (not, vert, similar25%) and geothermal-volcanic emissions (not, vert, similar10%). Global abiogenic emissions from serpentinization are negligible on Earth, but, on Mars, individual seeps from serpentinization could be significant. Gas discharge from clathrate-permafrost destabilization should also be considered. Finally, we have shown examples of potential degassing pathways on Mars, including mud volcano-like structures, fault and fracture systems, and major volcanic edifices. All these types of structures could provide avenues for extensive gas expulsion, as on Earth. Future investigations of martian methane should be focused on such potential pathways.
    Description: Published
    Description: 182-195
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Mars ; Methane ; Earth’s degassing ; Seepage ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 35
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    Dynamic plumbing system beneath volcanoes revealed by kinetic modeling, and the connection to monitoring data: An example from Mt. Etna (2012)
    Elsevier
    Details
    Publication Date: 2023-01-27
    Description: Our ability to monitor volcanoes (using seismic signals, ground deformation, gas fluxes, or other ground and satellite based observations) as well as our understanding of melt reservoirs that feed eruptions have evolved tremendously in recent years. The complex plumbing systems that are thought to feed eruptions are, however, difficult to relate to the monitoring signals. Here we show that the record preserved in compositional zoning of erupted minerals may be used to reconstruct sections of the plumbing system. Kinetic modeling of such zoning can yield information on the residence time of magma in different segments of the plumbing systems. This allows a more nuanced evaluation of the link between observed monitoring signals or eruption styles and the magmatic processes and movement of batches of melts at depth. The approach is illustrated through a study of the compositional zoning recorded in olivine crystals from the 1991–1993 SE-flank eruption products of Mt. Etna (Sicily). The zoning patterns in crystals reveal that the plumbing system of the volcano consisted of at least three different magmatic environments between which magma was transported and mixed in the year or two preceding the start of eruption. Quantification of this history indicates that two main pathways of melt migration and three timescales dominated the dynamics of the system. Combination of this information with the timing of observation of various monitoring signals allows a reconstruction of the dynamic evolution of this section of the plumbing system during the early stages of the 1991–1993 eruption. It is seen, for example, how the migration of melt through the same sections of the plumbing system can cause pre-eruptive triggering, enhance Strombolian activity, and through the ensuing eruption cleanse and flush the plumbing system. Different kinds of mixing occur simultaneously at different sections of the plumbing system on different timescales (a few days up to two years).
    Description: Published
    Description: 11-22
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Etna ; plumbing system ; olivine ; zoning ; timescales ; monitoring ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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