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  • 36.40.+d  (210)
  • 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology
  • 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
  • Mt. Etna
  • Springer  (223)
  • EGU  (2)
  • Essen : Verl. Glückauf
  • Institute of Physics
  • Krefeld : Geologischer Dienst Nordhein-Westfalen
  • 2010-2014  (14)
  • 1990-1994  (211)
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  • 1
    Publikationsdatum: 2017-04-04
    Beschreibung: Here, we report the first continuous data of geochemical parameters acquired directly from the active summit crater of Vulcano. This approach provides a means to better investigate deep geochemical processes associated with the degassing system of Vulcano Island. In particular, we report on soil CO2 fluxes from the upper part of Vulcano, a closed-conduit volcano, from September 2007 to October 2010. Large variations in the soil CO2 and plume SO2 fluxes (order of magnitude), coinciding with other discontinuous geochemical parameters (CO2 concentrations in fumarole gas) and physical parameters (increase of shallow seismic activity and fumarole temperatures) have been recorded. The results from this work suggest new prospects for strengthening geochemical monitoring of volcanic activity and for improving the constraints in the construction of a “geochemical model”, this being a necessary condition to better understand the functioning of volcanic systems.
    Beschreibung: Published
    Beschreibung: 1859-1863
    Beschreibung: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Beschreibung: 4V. Vulcani e ambiente
    Beschreibung: 5V. Sorveglianza vulcanica ed emergenze
    Beschreibung: 1R. Reti di monitoraggio e Osservazioni
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): Vulcano Island ; Geochemical monitoring ; CO2 flux ; CO2 fumaroles ; SO2 flux ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Publikationsdatum: 2017-04-04
    Beschreibung: Using a lava flow emplacement model and a satellite-based land cover classification, we produce a map to allow assessment of the type and quantity of natural, agricultural and urban land cover at risk from lava flow invasion. The first step is to produce lava effusion rate contours, i.e., lines linking distances down a volcano’s flank that a lava flow will likely extend if fed at a given effusion rate from a predetermined vent zone. This involves first identifying a vent mask and then running a downhill flow path model from the edge of every pixel around the vent mask perimeter to the edge of the DEM. To do this, we run a stochastic model whereby the flow path is projected 1,000 times from every pixel around the vent mask perimeter with random noise being added to the DEM with each run so that a slightly different flow path is generated with each run. The FLOWGO lava flow model is then run down each path, at a series of effusion rates, to determine likely run-out distance for channel-fed flow extending down each path. These results are used to plot effusion rate contours. Finally, effusion rate contours are projected onto a land classification map (produced from an ASTER image of Etna) to assess the type and amount of each land cover class falling within each contour. The resulting maps are designed to provide a quick look-up capability to assess the type of land at risk from lava extending from any location at a range of likely effusion rates. For our first (2,000 m) vent zone case used for Etna, we find a total of area of ~680 km2 is at risk from flows fed at 40 m3 s−1, of which ~6 km2 is urban, ~150 km2 is agriculture and ~270 km2 is grass/woodland. The model can also be run for specific cases, where we find that Etna’s 1669 vent location, if active today, would likely inundate almost 11 km2 of urban land, as well as 15.6 km2 of agricultural land, including 9.5 km2 of olive groves and 5.2 km2 of vineyards and fruit/nut orchards.
    Beschreibung: Published
    Beschreibung: 1001-1027
    Beschreibung: 3.6. Fisica del vulcanismo
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Lava flow ; Risk ; FLOWGO ; ASTER image ; Land classification ; Mt. Etna ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Publikationsdatum: 2017-04-04
    Beschreibung: Destructive volcaniclastic flows are among the most recurrent and dangerous natural phenomena in volcanic areas. They can originate not only during or shortly after an eruption (syn-eruptive) but also during a period of volcanic quiescence (inter-eruptive), when heavy and/or persistent rains remobilize loose pyroclastic deposits. The area in Italy most prone to such flows is that of the Apennine Mountains bordering the southern Campania Plain. These steep slopes are covered by pyroclastic material of variable thickness (a few cm to several m) derived from the explosive activity of the Somma-Vesuvius and Campi Flegrei volcanoes a few tens of kilometers to the west. The largest and most recent devastating event occurred on May 5, 1998, causing the death of more than 150 people and considerable damage to villages at the foot of the Apennine Mountains. This tragic event was only the most recent of a number of volcaniclastic flows affecting the area in both historical and prehistoric times. Historical accounts report that more than 500 events have occurred in the last five centuries and that more than half of these occurred in the last 100 years, causing hundreds of deaths. In order to improve volcaniclastic flow hazard zonation and risk mitigation in the study area, we produced a zonation map that identifies the drainage basins potentially prone to disruption. This map was obtained by combining morphological characteristics (concavity and basin shape factor) and the mean slope distribution of drainage basins derived from a digital elevation model with a 10-m resolution. These parameters allowed for the classification of 1,069 drainage basins, which have been grouped into four different classes of proneness to disruption: low, moderate, high and very high. The map compiled in a GIS environment, as well as the linked database, can be rapidly queried.
    Beschreibung: Published
    Beschreibung: 371-387
    Beschreibung: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Volcaniclastic flow hazard ; GIS ; Vesuvian area ; Southern Campania Plain ; Slope instability ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Publikationsdatum: 2017-04-04
    Beschreibung: The Mw 5.7 earthquake that occurred on 12 May 1802 is the only one with Mw ≥ 5.5 located west of Lake Garda in the central-northern part of the Po Plain, Northern Italy, and the strongest event located in the seismic zone 907 of the ZS9 seismogenic zonation of Italy. Current parametric earthquake catalogs locate the event not far from important cities (e.g., Milan) and to sites where nuclear power plants were to be built in the 1980s or could be built in a near future. Although the earthquake parameters seemed sufficiently well constrained, a detailed investigation of documentary sources was performed, in repositories storing the documents of the Napoleonic departments to which the area affected by the earthquake belonged at that time. In the surviving archival series, we found the officers’ correspondence on all the administrative aspects raised by the earthquake. The newly collected records allowed the authors to significantly increase the number of macroseismic intensity data, including new observations in the most damaged area. The results have been then interpreted in terms of both Mercalli–Cancani–Sieberg and EMS98 macroseismic scales. The earthquake parameters were derived applying two different methods in order to get two independent estimates. Earthquake location is confirmed, although the still scarce data available in the area to the east of the epicenter do not permit to reduce the uncertainty to a minimum. According to the Boxer method, the magnitude is now slightly higher, and the source model shows a good agreement with the tectonic setting of the area.
    Beschreibung: Published
    Beschreibung: 629-651
    Beschreibung: 3.10. Storia ed archeologia applicate alle Scienze della Terra
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): 1802 earthquake ; Northern Italy ; Historical seismology ; Macroseismic intensity ; Earthquake parameters ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Publikationsdatum: 2017-04-04
    Beschreibung: On 30 December 2002, a 25-30 × 106 m3 landslide on the NW flank of Stromboli volcano produced a tsunami that caused relevant damage to the Stromboli village and to the neighboring islands of the Aeolian archipelago. The NW flank of Stromboli has been the site of several, cubic kilometer-scale, landslides during the past 13 ka. In this paper we present sedimentological and compositional data of deep-sea cores recovered from a site located about 24 km north of the island. Our preliminary results indicate that: (i) turbidity currents were effectively generated by the large-scale failures and (ii) volcanogenic turbidity current deposits retain clues of the landslide source and slope failure dynamics. By analogy with Hawaii and the Canary islands we confirm that deep-sea sediments can be effectively used to assess the age and scale of past landslide events giving an important contribution to the tsunami hazard assessment of this region.
    Beschreibung: Published
    Beschreibung: 719-731
    Beschreibung: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: reserved
    Schlagwort(e): Landslide ; turbidite ; tsunami ; Stromboli ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: book chapter
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Publikationsdatum: 2017-04-04
    Beschreibung: Recent stratigraphic studies at Vesuvius have revealed that, during the past 4,000 years, long lasting,moderate to low-intensity eruptions, associated with continuous or pulsating ash emission, have repeatedly occurred. The present work focuses on the AS1a eruption, the first of a series of ash-dominated explosive episodes which characterized the period between the two Subplinian eruptions of 472 AD and 1631 AD. The deposits of this eruption consist of an alternation of massive and thinly laminated ash layers and minor well sorted lapilli beds, reflecting the pulsatory injection into the atmosphere of variably concentrated ash-plumes alternating with Violent Strombolian stages. Despite its nearly constant chemical composition, the juvenile material shows variable external clast morphologies and groundmass textures, reflecting the fragmentation of a magma body with lateral and/or vertical gradients in both vesicularity and crystal content. Glass compositions and mineralogical assemblages indicate that the eruption was fed by rather homogeneous phonotephritic magma batches rising from a reservoir located at ~ 4 km (100 MPa) depth, with fluctuations between magma delivery and magma discharge. Using crystal size distribution (CSD) analyses of plagioclase and leucite microlites, we estimate that the transit time of the magma in the conduit was on the order of ~ 2 days, corresponding to an ascent rate of around 2× 10−2 ms−1. Accordingly, assuming a typical conduit diameter for this type of eruption, the minimum duration of the AS1a event is between about 1.5 and 6 years. Magma fragmentation occurred in an inertially driven regime that, in a magma with low viscosity and surface tension, can act also under conditions of slow ascent.
    Beschreibung: In press
    Beschreibung: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Ash emission activity ; Tephrite ; Vesuvius ; Stratigraphy ; Textural analyses ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Publikationsdatum: 2017-04-04
    Beschreibung: Etna’s 2001 basaltic lava flow provided a good example of the distal flow segment between the flow front and stable channel, across which the flow evolves from channel-contained to dispersed. This zone was mapped with meter precision using LIDAR data collected during 2004 and 2005. These data, supported by field mapping, show that the flow front comprised eight lobes each 10 to 20 m high. The flow front appears to have advanced not as a single unit, but as a series of lobes moving forward one lobe at a time. Primary lobes were centered on the channel axis and marginal lobes were off-axis. The lobes advanced as breakouts of low-yield-strength lava from the flow core of the stalled flow front. Marginal lobes were abandoned and contributed to marginal levees flanking the transitional channel. For Etna’s 2001 flow, the transitional channel is 140 m wide, 700 m long and fed a 240-m-long zone of dispersed flow; the change from stable to transitional channel occurred at a major reduction in slope. Above this, the stable channel is 5.2 km long, 55 to 105 m wide and bounded by 15- to 25-m-high levees, and the stable channel is located over a previous channel. In a final stage of activity, lava ponding at the break-in-slope that marks the terminus of the stable channel put pressure on the eastern levee, causing it to fail. Liberated lava then fed a final break-out to the east. Similar flow front-features occur at other volcanoes, indicating that similar processes are characteristic of dispersed flow zones.
    Beschreibung: Published
    Beschreibung: 119-127
    Beschreibung: 1.10. TTC - Telerilevamento
    Beschreibung: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Beschreibung: 3.6. Fisica del vulcanismo
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Basalt lava ; Channelised lava flow ; Flow front ; Zone of dispersed flow ; Flow dynamics ; LIDAR ; Etna ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Publikationsdatum: 2017-04-04
    Beschreibung: Changes of the susceptibility to lava flow invasion at Mount Etna are quantified by using lava flow simulations on four Digital Elevation Models documenting the morphostructural modifications of the volcano in the time interval 1986–2007. The probabilistic code DOWNFLOW is used to derive the areas invaded by several thousands of lava flows obtaining, for each DEM, maps of the susceptibility to lava flow invasion and of the lava flow hazard. These maps show, for the first time, the evolution of these surficial properties with time, and render a quantitative image of the effects of topographic changes on the preferential lava flow drainage paths. The results illustrate how the emplacement of new lava flows and the growth of scoria cones affect the probability of inundation by lava flows. We conclude that the persistent activity of this volcano requires a frequent updating of the topography for a reliable lava flow hazard assessment.
    Beschreibung: Published
    Beschreibung: 537-546
    Beschreibung: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Lava flow simulation ; Digital Elevation Model ; Lidar ; Time series ; Lava flow hazard maps ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Publikationsdatum: 2020-11-16
    Beschreibung: Active volcanoes characterized by open conduit conditions generate sonic and infrasonic signals, whose investigation provides useful information for both monitoring purposes and studying the dynamics of explosive processes. In this work, we discuss the automatic procedures implemented for a real-time application to the data acquired by a permanent network of five infrasound stations running at Mt. Etna volcano. The infrasound signals at Mt. Etna consist in amplitude transients, called infrasound events. The adopted procedure uses a multi-algorithm approach for event detection, counting, characterization and location. It is designed for an efficient and accurate processing of infrasound records provided by single-site and array stations. Moreover, the source mechanism of these events can be investigated off-line or in near real-time by using three different models: i) Strombolian bubble; ii) resonating conduit and iii) Helmholtz resonator. The infrasound waveforms allow us to choose the most suitable model, to get quantitative information about the source and to follow the time evolution of the source parameters.
    Beschreibung: Published
    Beschreibung: 1215–1231
    Beschreibung: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Beschreibung: JCR Journal
    Beschreibung: open
    Schlagwort(e): infrasound ; monitoring system ; Mt. Etna ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Publikationsdatum: 2020-11-16
    Beschreibung: Earthquake catalogues for Romania supply for 11th–15th century earthquakes located in the region of Vrancea records that consist of a complete set of parameters, including magnitude and depth. Scope of this paper is to verify the reliability and consistency of these parameters with the informative background as explicitly referenced by the catalogues. After retrieving the original sources they mention, the set of data appeared to be related almost exclusively to the Russian plain and too poor to be at the very origin of the parameter assessment. Data for 19th–20th century earthquakes, such as instrumental locations and CMT solutions, added to the understanding of the macroseismic response of the Russian plain to Vrancea earthquakes. On the one hand, the investigation and analysis of historical earthquake records for the fourteen events listed by the catalogues in the 11th–15th centuries has shown that for three earthquakes (1022, 1038, 1258) no primary sources could be traced, and three more earthquakes (1091, 1170 and 1328) are attested only by scarcely reliable records and had to be classified as doubtful, and one (1473) is simply a duplication of the 1471 event. On the other hand, the availability of data on recent earthquakes that may be compared to historical ones in terms of macroseismic effects allowed the authors to agree with the previous catalogue compilers’ solution with regard to both magnitude and depth of the past earthquakes for which do exist reliable primary historical records.
    Beschreibung: Published
    Beschreibung: 575–604
    Beschreibung: 4IT. Banche dati
    Beschreibung: JCR Journal
    Beschreibung: open
    Schlagwort(e): Vrancea earthquakes ; 11th-15th earthquakes ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 11
    Publikationsdatum: 2017-04-04
    Beschreibung: Studies on volcanic degassing have recently shown the important role of volatile release from active volcanoes in understanding magmatic processes prior to eruptions. Here we present and discuss the evolution of magmatic degassing that preceded and accompanied the 2008 Mt. Etna eruption. We tracked the ascent of magma bodies by high-temporal resolution measurements of SO2 emission rates and discrete sampling of SO2/HCl and SO2/HF molar ratios in the crater plume, as well as by periodic measurement of soil CO2 emission rates. Our data suggest that the first signs of upward migration of gas-rich magma before the 2008 eruption were observed in June 2007, indicated by a strong increase in soil CO2 efflux followed by a slow declining trend in SO2 flux and halogens. This degassing behavior preceded the mid-August 2007 summit activity culminated with the September 4th paroxysmal event. Five months later, a new increase in both soil CO2 and SO2 emission rates occurred before the November 23rd paroxysm, to drop down in late December. In the following months, geochemical parameters showed high variability, characterized by isolated sudden increases occurred in early December 2007 and late March 2008. In early May soil CO2, SO2 emission rates and S/Cl molar ratio gradually increased. Crater degassing peaked on May 13th marking the onset of the eruption. Eruptive activity was accompanied by a general steady-state of SO2 flux characterized by two main degassing cycles. These cycles preceded explosive activity at the eruptive vents, indicating terminal new-arrival of deep gas-rich magma bodies in the shallow plumbing system of Mt Etna. Conversely, halogens described a slight increasing trend till the end of 2008. These observations suggest an impulsive syn-eruptive dynamics of magma transfer from depth to the surface. Differently from the SO2 emission rates, the S/Cl ratio and the soil CO2 efflux values showed an increasing trend from mid-April to mid-July 2008, indicating steady-increasing input of deeper, gas-rich magma. Since August, geochemical parameters decreased, suggesting that new magma has not arrived from depth. According to our interpretation, both the CO2 efflux and the S/Cl ratio increases observed in early November may indicate a new input of fresh magma form depth. Finally, the estimated volume of degassing magma showed substantial equilibrium between degassed and erupted magma suggesting an “eruptive” steady-state of the volcano.
    Beschreibung: INGV, Sezione di Catania; INGV, Sezione di Pisa; University of Cambridge, Cambridge, UK
    Beschreibung: Published
    Beschreibung: Vienna, Austria
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: open
    Schlagwort(e): Mt. Etna ; plume gases ; soil CO2 ; eruption ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: Abstract
    Standort Signatur Erwartet Verfügbarkeit
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  • 12
    Publikationsdatum: 2017-04-04
    Beschreibung: Concurrent measurement of soil radon, soil thoron and soil CO2 efflux is based on the method developed by Giammanco et al. (Geochem. Geophys. Geosys., 8(10), Q 10001, doi:10.1029/2007GC001644, 2007). An empirical relationship links the 222Rn/220Rn ratio to the CO2 efflux: deep sources of gas are characterized by high 222Rn activity and high CO2 efflux, whereas shallow sources are indicated by high 220Rn activity and relatively low CO2 efflux. This relationship is more constraining on the type and depth of the gas source than using the 222Rn/220Rn ratio alone.We studied the temporal variation of the ratio between CO2 efflux and (222Rn/220Rn), that we define as a Soil Gas Disequilibrium Index (SGDI). Since June 2006, periodical measurements of the SGDI were carried out in ten sites located on the flanks of Mt. Etna, with sampling frequency of about ten days. Remarkable variations in this parameter were recorded during the period 2006-2008 likely associated with changes in the activity level of Mt. Etna. In particular, one of the sites located in the area called Primoti (on the lower east flank of the volcano) has shown significant anomalous changes of the SGDI in time, possibly correlated with the eruptive/tectonic activity. For this reason, in this site we set up an automatic monitoring station made of a Radon/Thoron monitor (model RTM 2100, SARAD GmbH, Germany) coupled with a soil CO2 efflux station (model ACE, ADC BioScientific Ltd., UK). The sampling frequency was set at 30 minutes, in order to allow for a sufficient decay equilibration in the radon isotopes. Air temperature and barometric pressure were recorded as well, with the same sampling rate as for the soil gases. The site chosen for testing the monitoring station is located on the east flank of Mt. Etna at an altitude of about 520 a.s.l., in an area known for widespread diffuse emissions of CO2 and other gases of magmatic origin. The preliminary data acquired so far showed an average soil CO2 efflux of 10 g m􀀀2 d􀀀1 (std dev of about 7 g m􀀀2 d􀀀1) and average 222Rn and 220Rn activities of about 3.3 103 Bq/m3 (std dev of about 1140 Bq/m3) and about 2.0 103 Bq/m3 (std dev of about 620 Bq/m3), respectively. The corresponding values of the SGDI thus obtained varied in the range from about -1.5 to about 70.1, with an average of about 7 and standard deviation of about 6.3. The apparent baseline of the parameter is around the value of 3, and daily variations are clearly detected due to the combined influence of air temperature and barometric pressure. No clear influence from rainfall was observed. Some spikes were also detected, whose origin has to be studied by correlating the SGDI with other environmental parameters as well as with changes in the volcanic/tectonic activity of Mt. Etna.
    Beschreibung: INGV, Sezione di Catania
    Beschreibung: Published
    Beschreibung: Vienna, Austria
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: open
    Schlagwort(e): Mt. Etna ; soil radon ; CO2 ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: Abstract
    Standort Signatur Erwartet Verfügbarkeit
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  • 13
    Publikationsdatum: 2017-04-04
    Beschreibung: On 30 December 2002, a 25-30 × 106 m3 landslide on the NW flank of Stromboli volcano produced a tsunami that caused relevant damage to the Stromboli village and to the neighboring islands of the Aeolian archipelago. The NW flank of Stromboli has been the site of several, cubic kilometer-scale, landslides during the past 13 ka. In this paper we present sedimentological and compositional data of deep-sea cores recovered from a site located about 24 km north of the island. Our preliminary results indicate that: (i) turbidity currents were effectively generated by the large-scale failures and (ii) volcanogenic turbidity current deposits retain clues of the landslide source and slope failure dynamics. By analogy with Hawaii and the Canary islands we confirm that deep-sea sediments can be effectively used to assess the age and scale of past landslide events giving an important contribution to the tsunami hazard assessment of this region.
    Beschreibung: Unpublished
    Beschreibung: -
    Beschreibung: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Beschreibung: 4.3. TTC - Scenari di pericolosità vulcanica
    Beschreibung: reserved
    Schlagwort(e): Landslide ; turbidite ; tsunami ; Stromboli ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: book chapter
    Standort Signatur Erwartet Verfügbarkeit
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  • 14
    Publikationsdatum: 2020-02-24
    Beschreibung: A multidisciplinary geological and compositional investigation allowed us to reconstruct the occurrence of flank eruptions on the lower NE flank of Stromboli volcano since 15 ka. The oldest flank eruption recognised is Roisa, which occurred at ~15 ka during the Vancori period, and has transitional compositional characteristics between the Vancori and Neostromboli phases. Roisa was followed by the San Vincenzo eruption that took place at ~12 ka during the early stage of Neostromboli period. The eruptive fissure of San Vincenzo gave rise to a large scoria cone located below the village of Stromboli, and generated a lava flow, most of which lies below sea level. Most of the flank eruptions outside the barren Sciara del Fuoco occurred in a short time, between ~9 and 7 ka during the Neostromboli period, when six eruptive events produced scoria cones, spatter ramparts and lava flows. The Neostromboli products belong to a potassic series (KS), and cluster in two differently evolved groups. After an eruptive pause of ~5,000 years, the most recent flank eruption involving the NE sector of the island occurred during the Recent Stromboli period with the formation of the large, highly K calc-alkaline lava flow field, named San Bartolo. The trend of eruptive fissures since 15 ka ranges from N30°E to N55°E, and corresponds to the magma intrusions radiating from the main feeding system of the volcano.
    Beschreibung: The mapping of Stromboli was supported by a grant to S. Calvari (Project V2/01, 2005–2007, funded by the Istituto Nazionale di Geofisica e Vulcanologia and by the Italian Civil Protection). This work was partly supported by INGV through a research grant financed by MIUR-FIRB to G. Norini. We wish to thank the former Director of INGV-Sezione di Catania, A. Bonaccorso, for making additional funds available for field trip and datings.
    Beschreibung: In press
    Beschreibung: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Beschreibung: JCR Journal
    Beschreibung: restricted
    Schlagwort(e): Stromboli ; flank fissures ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 15
    Digitale Medien
    Digitale Medien
    Springer
    Applied physics 58 (1994), S. 57-62 
    ISSN: 1432-0649
    Schlagwort(e): 32.80.Pj ; 42.50.Vk ; 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The mechanism responsible for transitions of laser-cooled trapped ions from an ordered “crystal” state to an irregular “cloud” state has been discussed controversially. A numeric and analytic study of the relative motion of two trapped ions without laser cooling is performed and compared with the results of previous simulations involving the laser. It turns out that the system without laser, in spite of its simplicity, already exhibits a non-monotonic dependence of crystal stability on trap parameters, which is linked to the presence of low-order nonlinear resonances.
    Materialart: Digitale Medien
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  • 16
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 349 (1994), S. 219-222 
    ISSN: 1434-601X
    Schlagwort(e): 21.60.Jz ; 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We discuss and compare the gross features of resonance excitations in nuclei and metal clusters. We point out the phenomenon of ”jellium scaling” which means that different materials for metal clusters all give similar resonance spectra and we discuss the various effects which determine the exact position of the resonance.
    Materialart: Digitale Medien
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  • 17
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 29 (1994), S. 45-48 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 34.90.+q
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A direct measurement of collisionally induced fission of C 60 2+ has been performed. We have measured coincidences between various charged fragments resulting from collisions between C 60 2+ and He atoms. The measurements show that C 60 2+ not only emits C2 units but also breaks up into larger, singly charged parts. In this paper, we report on coincidences between C n + (2≦n≦9) and C m + (42≦m≦48) fragment ions.
    Materialart: Digitale Medien
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  • 18
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 29 (1994), S. 53-59 
    ISSN: 1434-6079
    Schlagwort(e): 34.90.+q ; 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Various fullerene ions are generated in a standard plasma ion source from a vaporized mixture of C60/C70. Except C 60 + and C 70 + , the fullerene ions are formed by fragmentation of C60 or C70 excited by electron impact. Information on the structure and stability of the fullerene ions is obtained by studying unimolecular dissociation and collision-induced fragmentation of C 60 + , C 58 + and C 56 + in H2 and Ar target gases.
    Materialart: Digitale Medien
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  • 19
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 30 (1994), S. 327-340 
    ISSN: 1434-6079
    Schlagwort(e): 34.20.−b ; 36.40.+d ; 31.20.Ej
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A detailed study of the intrinsic consistency of the semiempirical method of P. Claverie namely, the effects of the basis set and intramolecular correlation on the multipole distributions of molecular subunits and the influence of the electronic population of each atom in the molecular subunit on its van der Waals radius, is performed on some van der Waals dimers. The validity, limits of this model and the appropriate way to use it is established. In particular, the dependence of the geometry and the interaction energy on the basis set chosen and the intramolecular correlation shows that the multipole distribution involved in the calculation of the electrostatic and polarization terms must be derived from a correlated wave function within an extended basis set. Associated to non local methods for finding stationary points, the method of P. Claverie reproduce reliably the intermolecular geometrical parameters observed for the equilibrium structures and the transition states of the dimer and trimer of acetylene. In addition, a study of the equilibrium structures of the ethylene dimer is presented, the aim of being to clarify the considerable uncertainty in their number and their geometry.
    Materialart: Digitale Medien
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  • 20
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 30 (1994), S. 349-356 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 61.55.Hg ; 68.35.Dv
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Density functional theory is used to study the atomic and electronic structures of Na10K10Cs n clusters with up to sixty atoms. The simplifying approximation has been made of replacing the external potential of the ionic background by its spherical average about the cluster centre in the iterative process of solving the Kohn-Sham equations for each geometry tested. The search for the equilibrium geometry is performed by employing the technique of simulated annealing. We have always found segregation of Cs atoms to the surface as well as a rather neat separation of different species in different (radial) regions of the cluster. This layering effect appears to be consistent with a tendency to maximize electronegativity differences. When the cluster is big enough, Cs atoms begin to appear also inside the cluster. Those geometrical effects do not perturb the electronic magic numbers well known for pure alkali metal clusters.
    Materialart: Digitale Medien
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  • 21
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 31 (1994), S. 85-93 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 07.75.+h ; 07.77.+p
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The cluster source we use, a low pressure, rare gas condensation cell, is capable of producing clusters containing more than 45 000 atoms or having masses exceeding 2 500 000 amu. Details of this source and the dependence of the cluster size distribution on adjustable working parameters (oven temperature, inert gas pressure, inert gas type) are discussed in this report. Measurements of the mass-dependent velocity distributions of the clusters emitted by the source are presented and compared to a simple model calculation. The clusters are mass-analyzed with a time-of-flight mass spectrometer and detected by a multi-channel plate. The dependence of the detectability of large clusters on the acceleration voltage is investigated.
    Materialart: Digitale Medien
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  • 22
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 31 (1994), S. 187-189 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Collision of Ar cluster ions, Ar n + (n=3−16), with He and Ne atoms was investigated by use of mass spectroscopic techniques. The cross sections for the production of Ar n′ + (n′〈n) were measured as functions of the size of the parent cluster ion and the collision energy (0.1–10 eV in the center-of-mass frame). These results were analyzed in the scheme of hard-sphere spectator collision with RRK theory. It was concluded that the reaction proceeds via collisional excitation of the parent cluster ion and following sequential loss of the constituent Ar atoms.
    Materialart: Digitale Medien
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  • 23
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 32 (1994), S. 125-136 
    ISSN: 1434-6079
    Schlagwort(e): 31.20.Sy ; 31.20.Rx ; 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We present an extension of the jellium model for alkali clusters which allows a selfconsistent determination of the jellium background in addition to the Kohn-Sham solution of the electron dynamics. It includes the volume and the surface energy of the ionic distribution. We discuss applications to the shape of clusters and to the position and width of the plasmon resonances.
    Materialart: Digitale Medien
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  • 24
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 29 (1994), S. 67-72 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 75.60.Jp ; 76.50.+g
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The deflection of free magnetic metal clusters in a Stern-Gerlach magnetic field is studied. In particular we investigate magnetic resonance effects resulting from lattice anisotropy and cluster rotation. In analogy to small suspended particles in an oscillating magnetic field the anisotropy field fixed to the rotating atomic lattice of the cluster acts on the cluster magnetization like an rf field in NMR experiments. In our calculation we have used the Bloch equations and assumed different anisotropy field symmetries (uniaxial, cubic). A minimum in the magnetization as a function of the Stern-Gerlach field and also of the cluster size, as observed recently, is obtained under certain conditions. However, such a resonance behavior occurs only if the distribution of the rotation frequency ωrot is relatively narrow, while a broad distribution of ωrot yields an almost superparamagnetic behavior. In addition, the strength of the anisotropy field and the relaxation time are important variables which determine the magnetic behavior of the clusters.
    Materialart: Digitale Medien
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  • 25
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 29 (1994), S. 81-83 
    ISSN: 1434-6079
    Schlagwort(e): 33.80.Eh ; 36.40.+d ; 36.90.+f
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Ionization dynamics of free C60 is investigated after single photon excitation with synchrotron radiation in the energy range between 8.9 eV and 27.6 eV. Upper limits for the time constants describing possible delayed ionization are obtained from peak shape asymmetries in time of flight spectra as a function of excitation energy. The results clearly indicate that delayed ionization is not observed after single photon excitation in contrast to the results obtained in ns-laser MPI experiments.
    Materialart: Digitale Medien
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  • 26
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 29 (1994), S. 147-150 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 34.20.−b
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The limits of stability of small atomic clusters with angular momentum are investigated as a function of the size and charge of the aggregates. Critical angular momenta are obtained in a di-cluster picture from the balance of a cohesive surface-surface interaction and the disruptive centrifugal and electric interactions. The calculation scheme incorporates the mass and charge asymmetry degrees of freedom and it is thus particularly suited to explore cluster-cluster reaction processes. Deformation of the fragments is taken into account.
    Materialart: Digitale Medien
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  • 27
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 29 (1994), S. 241-243 
    ISSN: 1434-6079
    Schlagwort(e): 21.60.Jz ; 36.40.+d ; 71.10.+x
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Numerical Hartree-Fock calculations on the2S+1 L states arising from 1s 2 1 pv and 1s 2 1p 6 1 pμ open-shell configurations of Nan-type (n≦20) jellium spheres are reported for the first time. TheL, S multiplet energy spread is substancially larger than that expected from earlier estimates of exchange interaction energies. A new way of considering cluster abundance structures in mass spectra emerges from the results.
    Materialart: Digitale Medien
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  • 28
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The effects of adding molecules on the LIF at 540 nm of a barium atom at the surface of an argon cluster (average size 420) has been investigated. We showed that molecules like ethanol,n-hexane and O2 from stable complexes with ground state barium. In the case of molecules like N2, CH4 and SF6, the collisional quenching of solvated Ba(1 P) is observed. The large quenching rates obtained are interpreted by a surface mobility of the collisional partners. Moreover, we showed that this collisional quenching leads to the ejection of free Ba(3 P 1).
    Materialart: Digitale Medien
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  • 29
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 30 (1994), S. 69-75 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 33.80.Eh ; 82.30.Nr ; 82.40.Dm
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Geometric structures and the energies for the ground and several excited electronic states of a sodium atom bound with one or two ammonia molecules are presented. All self consistent field (SCF) calculations are performed with extended basis sets. Geometry optimization and one electron properties have been performed within the SCF approximation. Excited states have been calculated with the multi-configuration SCF (MCSCF) technique. This system may be viewed as a precursor to solvation in a macroscopic system. The excited state calculations provide important information for spectroscopic studies of these complexes.
    Materialart: Digitale Medien
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  • 30
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 32 (1994), S. 257-260 
    ISSN: 1434-6079
    Schlagwort(e): 34.20.cf ; 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A new empirical potential energy function (PEF) is proposed, which is formed from pair-interactions only, and containes the many-body contributions. The PEF satisfies bulk cohesive energy and bulk stability condition. The PEF is parameterized for copper, silver, and gold elements in fcc crystal structure. The elastic constantsC 11 andC 12 and the bulk modulus of the elements are calculated, and the structural stability and energetics of microclusters containing 3 to 7 atoms of the same elements are investigated.
    Materialart: Digitale Medien
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  • 31
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 29 (1994), S. 73-80 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 78.40
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We have computed the electronic structure and the imaginary part of the dielectric function of the Au55 cluster using a tight-binding model which takes into account size and boundary effects. Besides the Drude behavior, we obtain anomalous absorption peaks in the infrared region due to the breakdown of the selection rule Δk=0. Taking into account surface coating effects, the onset of the interband absorption above 2.5 eV results to be red shifted, in agreement with the experimental data. As a consequence, we obtain a dramatic increase of the width of the plasmonic absorption peak, which accounts for the experimental optical spectra observed by Kreibig.
    Materialart: Digitale Medien
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  • 32
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 31 (1994), S. 125-129 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 73.20.Mf ; 21.60.Cs
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The origin of the plasmon excitation in small metal clusters is studied within the jellium model through ab initio electronic-structure calculations based on the nuclear shell model. In the limit of infinite size, the plasmon classically represents pure harmonic motion of the center of mass of the valence electrons. It is shown that this limit is already well approximated by clusters of only eight electrons.
    Materialart: Digitale Medien
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  • 33
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 29 (1994), S. 139-145 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 34.10.+x ; 82.20.Rp
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract In this article, the dynamics of fragmentation of highly excited van der Waals clusters are analyzed. An approach to the characterization of complex cluster fragmentation is described, based on a combination of structural and dynamical analysis of classical trajectories. In this method, the final fragmentation pattern is analyzed by a depth-first search algorithm based on graph theory, which provides a partitioning of the system into intact fragments of various sizes: monomers, dimers, trimers, and higher multimers. With knowledge of the final products, a dynamical analysis is accomplished by tracing back the time dependence of the relevant fragment energies. A transition from oscillatory to constant behavior of these energies indicates that the fragment has become energetically isolated from the parent cluster. This allows an unambiguous definition of the dissociation time of the fragment. The method is applied to the characterization of cluster fragmentation of chemically activated I2Ar 12 * formed in the association reaction I+I(Ar)12→I2+12 Ar. It is found that cluster decomposition channels, leading to the formation of at least one multi-atom fragment, play an important role in the evaporative cooling of I2, in addition to monoatomic sequential evaporation.
    Materialart: Digitale Medien
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  • 34
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 30 (1994), S. 57-68 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 64.70.-p
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Using a distance-dependent tight-binding hamiltonian, we have studied the influence of the temperature on the geometries of small alkali clusters (Na4, Na8, and Na20). We have applied a Monte-Carlo thermodynamical method which consists in performing canonical samplings for various temperatures, these samplings being reexpressed in the microcanonical ensemble. This method provides thermodynamical values such as the entropy and the specific heat. Their behaviour shows one phase transition in the case of Na4 and Na8, and two phase transitions for Na20. As concerns Na4 and Na8, the transition occurs at ≈200 K, between a solid-like phase and a phase for which the geometry of these clusters oscillates between numerous shapes. In the case of Na20, the two observed phase transitions can be described as a melting of the surface atoms (at ≈200 K) preliminarily to the fluctuation of an inner icosahedron seed (at ≈300 K).
    Materialart: Digitale Medien
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  • 35
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 30 (1994), S. 323-326 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 34.90.+q
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Electron capture in collisions of C 60 2+ and C 60 3+ molecular ions with atomic and molecular gases has been studied at impact energies around 100 keV. The cross-section dependence on the target-ionization potentials is discussed, and a simple over-barrier model is evoked to explain the energy dependences. The cross sections for endothermic processes are discussed in the light of a simple two-state model, and a general understanding of their behaviour is obtained.
    Materialart: Digitale Medien
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  • 36
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 34.50.−s ; 35.20.Gs
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The stability of gold cluster ions Au n + (2≦n≦23) has been investigated via collision induced dissociation in a Penning trap. Threshold energies and dissociation channels have been determined. The cluster stability exhibits a pronounced odd — even alternation: Clusters with an odd number of atoms,n, are more stable than the even-numbered ones. Enhanced stabilities are found for Au 3 + , Au 9 + , and Au 19 + in accordance with the Clemenger-Nilsson and the deformed jellium model of delocalized valence electrons. Excited odd cluster ions withn≦15 predominantly decay by evaporation of dimers; all others decay by monomer evaporation. From the dissociation channels estimates of the binding energies are deduced.
    Materialart: Digitale Medien
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  • 37
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 31 (1994), S. 95-104 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 33.10.Gx
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A second order perturbation approach for the evaluation of the splitting and shifting of the infrared vibrational bands of molecular clusters, based on early publications of Buckingham, is presented. The Hamiltonian of the system comprises harmonic- and anharmonic intramolecular vibration terms, as well as the intermolecular potential. The anharmonic contributions of the intramolecular force field and the intermolecular potential are treated as a perturbation. In order to extend the applicability of the approach to homogeneous molecular clusters, the formalism of degenerate perturbation theory is employed. The new approach is applied to methanol clusters from dimer to hexamer for calculating the frequency shifts of the OH stretching mode (ω1=3681.5 cm−1), the CH3 rocking mode (ω7=1074.5 cm−1), and the CO stretching mode (ω8=1033.5 cm−1). The numerical results compare favourably with experimental and previous theoretical data (except for ω1), but with a tendency to overestimate the shifts.
    Materialart: Digitale Medien
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  • 38
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 31 (1994), S. 131-134 
    ISSN: 1434-6079
    Schlagwort(e): 61.16.Di ; 36.40.+d ; 66.30.−h
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Cluster-size dependence of alloying behavior in nm-sized atom clusters has been studied by transmission electron microscopy, using clusters in the Au-Cu system. It was revealed that occurrence of rapid spontaneous alloying becomes more difficult with increasing cluster size. In gold clusters of approximately 4 nm in the mean size, a rapid dissolution of copper atoms took place and homogeneously mixed Au-Cu alloy clusters were formed. In gold clusters of approximately 10 nm in the mean size, rapid alloying of copper took place only at a shell-shaped region beneath the free surface of individual clusters and pure gold was retained at the central region of clusters. In gold clusters of approximately 30 nm in the mean size, no rapid alloying of copper was induced. The ease with which spontaneous alloying takes place is discussed in terms of the lattice softening in atom clusters.
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  • 39
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 31 (1994), S. 191-197 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Highly charged metal clusters can be easily produced using the technique of multi-step photoionization. The critical sizes at which fission occurs are reported here for alkali metal clusters having charges as high as +7. An interpretation within the framework of the liquid droplet model reveals that the fission process is strongly asymmetric and thermally activated.
    Materialart: Digitale Medien
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  • 40
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 32 (1994), S. 249-255 
    ISSN: 1434-6079
    Schlagwort(e): 31.20.Ej ; 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Alkali halide clusters Na n F n have most frequently cuboid structures and Na n F n−1 clusters are derived from Na n F n by removing a F− centre. An excess electron localises on the site of the removed F− ion. In this paper, other kind of clusters are studied at the SCF level: i) The non-cubic structures. ii) The cubic Na n F n−1 for which the excess electron has no defined site. Due to very large size of these species (at least 27 atoms!) some equivalent fictive linear and planar geometries are studied.
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  • 41
    ISSN: 1432-0819
    Schlagwort(e): Mt. Etna ; seismic network ; eruption ; migration ; hypocenter ; S-wave ; forerunner
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie
    Notizen: Abstract Data from a portable array of three-component digital stations, run at Mt Etna from 1988 to early 1990, highlight the seismic behaviour of the volcano before the 1989 eruption, one of the most significant in terms of energy of the last two decades. After a two-year period of weak and discotinuous seismicity, the depth of the seismically active volumes was observed to become shallower a few months before the volcanic event. The overall migration of the events, inferred by hypocentral locations and decreases of S-P time differences at two stations, agrees with other geophysical forerunners and allows further insights into the changes in the stress field leading to the eruption.
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  • 42
    Digitale Medien
    Digitale Medien
    Springer
    Applied physics 56 (1993), S. 215-217 
    ISSN: 1432-0630
    Schlagwort(e): 71.25.Mg ; 71.25.Rk ; 71.20.−b ; 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau , Physik
    Notizen: Abstract A tight-binding method which has been previously applied to study the effect of uncorrelated orientational disorder on conduction-band properties is extended here to the case of systems with long-range order and/or short-range correlations. The density of states and conductivity are not highly sensitive to the specific short-range correlations, so long as the system is not too close to being fully ordered. Hence the strong effects of disorder found previously appear to be robust and should play an important role in the interpretation of normal-state properties of A3C60.
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  • 43
    Digitale Medien
    Digitale Medien
    Springer
    Applied physics 57 (1993), S. 101-104 
    ISSN: 1432-0630
    Schlagwort(e): 73.20.Mf ; 82.65.Pa ; 82.50.−m ; 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau , Physik
    Notizen: Abstract Laser-induced desorption of metal atoms from the surface of small metal particles has been investigated as a function of the shape of the particles and the polarization of the incident laser light. The particles were supported on LiF, quartz or sapphire substrates. In a first set of experiments, the shape of the particles was determined by recording optical transmission spectra with s- and p-polarized light incident under an angle of typically 40° with respect to the surface normal. The metal particles turn out to be oblate, the ratio of the axes perpendicular and parallel to the substrate surface being on the order of 0.5. This ratio decreases with increasing particle size. Also, the particles change shape if the temperature is raised. In further experiments, s- and p-polarized light has been used to stimulate desorption of atoms via surface plasmon excitation. It is found that the desorption rate markedly depends on the polarization of the light. This is explained by excitation of the collective electron oscillation along different axes of the non-spherical particles.
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  • 44
    ISSN: 1434-6036
    Schlagwort(e): 36.40.+d ; 74.75.+t ; 79.60.−i
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The electronic structure of K-doped C60 was investigated by photoemission (PE) and X-ray absorption near-edge structure (XANES) studies at the C-1s and K-2p thresholds. In addition, information on the local K-derived partial density of states in superconducting K3C60 was obtained by resonant PE at the K-2p 1/2 threshold. The experimental observations support a complete charge transfer from K to C60 and we clearly observe a finite density of states atE F . From resonant PE, occupied states with K-p, d character could be identified in the binding-energy region from 1.5 to 8 eV below, but not directly at the Fermi level. This partial-density-of-states structure agrees well with the results of our band-structure calculations based on the local-density approximation.
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  • 45
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 141-143 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 61.50.Lt
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Size selected silicon clusters have been isolated in rare gas matrices and studied by optical absorption spectroscopy. The clusters were produced in a pulsed laser vaporization source, size selected with a quadrupole mass spectrometer and deposited at low energies into a cocondensed krypton matrix held at T〈20 K. A comparison of the optical spectra of ten atom wide bands (Si25-Si35, Si35-Si45 and Si45-Si55) shows the general size evolution of the optical properties. Single cluster sizes have also been isolated and show somewhat sharper spectra than the bands. The measured spectra show similarities to spectra calculated using Mie theory and bulk optical constants. Cluster-cluster agglomeration was studied by evaporating the inert gas matrix. The results suggest that the clusters agglomerate into larger particles even under the mildest "soft landing" conditions.
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  • 46
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 159-161 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 82.30.N ; 82.60
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A new class of molecular clusters with the composition M8C12 (M=Ti, V, Hf and Zr) has been discovered. The cation, anion and neutral species are unusually abundant and stable. In the case of the Zr-C system, evidence has also been obtained for growth through the development of multicage structures.
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  • 47
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 195-197 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 05.45.+b
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The structure and long-time dynamics of (LiBr) n n=4,5,8 were studied by optimization and molecular dynamics. The ring structure, double ring stack for (LiBr)8, was found to be the energy minimum. They are dynamically flexible and, particularly for (LiBr)4 and (LiBr)5, hardly isomerise into other isomers determined by optimization. (LiBr)8 is probably a promising candidate to exhibit dynamic coexistence among a number of isomers.
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  • 48
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 207-209 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 33.20. Ea ; 33.80 Gj
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We report the vibrational spectra of the cluster ions Cs+(CH3NH2)N, N=3–22. Bands in the 1015–1050 cm−1 region of the infrared are due to the v8 mode (CN stretch) of methylamine molecules displaying different degrees of interaction with the central ion. Monte Carlo simulations of the solvated Cs+ ion indicate that nine methylamine molecules fill the first solvation shell of Cs+ and that possible rearrangements in cluster structure occur at N=14−15. No absorptions due to bulklike methylamine molecules are observed through N=22.
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  • 49
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 217-219 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 33.70.Jg ; 34.10.+x
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We present results of semiclassical simulations of the electronic spectra and dynamics of aniline-Arn (1≤n≤3) clusters. The spectral density formalism of Mukamel [3] is used to generate the spectra from the time dependent energy difference of the S0 and S1 states of aniline solvated by the argon atoms. A repulsive Ar-N interaction is incorporated in the Hamiltonian of the S1 state; this term permits a quantitative prediction of the origin shifts of the S1〈--S0 transition (both red and blue shifts) for all the clusters studied. The temperature dependence of the spectrum of aniline-Ar2 is correlated with the underlying dynamics of this cluster.
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  • 50
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 33-35 
    ISSN: 1434-6079
    Schlagwort(e): 33.80.-b ; 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Using picosecond pump&probe technique followed by mass-selective detection, the dynamics of excited states of cold Nan=3...8-clusters in a supersonic beam — excited at λ=422nm — have been studied in time-resolved two-photon-ionization (TPI)-experiments. With growing cluster size a monotonous decrease of the decay times is observed except in the case of Na7 known to be a very symmetric cluster.
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  • 51
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 166-168 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 61.22.Pg
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We describe here molecular dynamics computer simulations performed to study the solvation of ions (Cl− and Na+) in water clusters. Our simulations show that the calculated structure and dynamics of the clusters is very sensitive to the potential model which is used to describe the interactions. From the comparison with thermodynamic data and data from the photoelectron spectra we conclude that in Cl−(H2O)n (n≤20) clusters the ion is located on the surface of the cluster.
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  • 52
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 162-165 
    ISSN: 1434-6079
    Schlagwort(e): 31.10.+z ; 36.40.+d ; 33.45.+x ; 33.60.-q
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We discuss the electronic structure, bonding and physical properties of the gold cluster compound Au55(PPh3)12Cl6. Results from our experimental measurements, including EXAFS, specific heat, Mössbauer, UV-visible and photoelectron spectroscopy, are combined with those of other work to form a consistent physical picture of the system. The bonding in Au55(PPh3)12Cl6 is much more delocalised and non-directional than in smaller gold cluster molecules. The Au55 cluster exhibits a substantial degree of metallic bonding, while displaying some of the characteristics of a discrete energy level spectrum.
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  • 53
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 178-180 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The (KCl)32 cluster is used as a model system to study the possibilities for clusters to exhibit amorphous or glassy solid forms. The problem has two aspects: first, whether the potential surface of the cluster supports a myriad of locally stable, disordered structures, the ensemble of which would constitute the glassy state, and second, whether an ensemble of amorphous clusters can be prepared under laboratory conditions. Molecular dynamics studies give an emphaticyes to the first issue, and an equally emphaticno to the second, for cooling rates up to 1012 K/s, a thousand-fold faster than the fastest rates yet reported. However, if the long-range Coulomb interaction of the ions is replaced by a shielded Coulomb (Debye or Yukawa) potential, the secondary minima are sufficiently stabilized and the saddles, sufficiently high, that disordered equilibrium structures can be reached by cooling at fast, but still conceivably attainable rates. The implication is that while alkali halide clusters probably cannot form glasses, binary clusters with shorter-range forces, such as those of II–VI and III–V compounds, probably can form glasses. The highly disordered structures of (KCl)32 are perhaps the most disordered forms yet seen for solid matter.
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  • 54
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 192-194 
    ISSN: 1434-6079
    Schlagwort(e): 31.20.Tz ; 31.50.+w ; 33.10.-u ; 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Stable ground state structures for neutral and charged Li n H, Li n H2 and Na n F m (n↛m) have been determined usingab —initio methods accounting for electronic correlation effects. The consequences of replacing alkali-atom by foreign-atom or -atoms have been studied. The similarities and differences with respect to topologies of the most stable Li n and Na n clusters will be pointed out. The ionization potentials and spectroscopic patterns are compared with available experimental data. This allows for the geometrical and spectroscopic assignments as well as for a study of the influence of localized versus non localized bonding on the ground and excited state properties of mixed clusters.
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  • 55
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 270-272 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 33.20.Kf ; 35.20.Pa
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The B state of Na3 is often cited as an example of fractional quantization of the pseudorotational motion on the lower adiabatic surface of theE×e Jahn-Teller system. Recently, an alternative interpretation of the experimental results was given which is based on a pseudo-Jahn-Teller treatment and implies integer quantization. We present rotationally resolved spectra of a number of vibronic bands of the Na3 B-X system and believe that they can only be explained in terms of integer quantum numbersj of the vibronic angular momentum.
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  • 56
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 301-303 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 75.50.Cc
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We use a variation of the Stern-Gerlach experiment to study the magnetic behavior of transition metal clusters. We report measurements of the magnetic properties of nickel clusters as a function of cluster size, vibrational temperature, and applied magnetic field. Results for these nickel clusters resemble those previously published for cobalt clusters in that superparamagnetic behavior is observed. As is the case for cobalt clusters, nickel clusters are observed to have magnetic moments per atom that are greater than the bulk value.
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  • 57
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 325-327 
    ISSN: 1434-6079
    Schlagwort(e): numbers 75.50Bb ; 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Magnetic properties of small iron clusters in a supersonic molecular beam are investigated. The magnetization is probed as function of magnetic field, temperature and cluster size. Temperatures are controlled by changing the source temperature (100 K to 500 K) and the expansion conditions. The clusters also may be heated in flight with light from a pulsed laser. Hot clusters are found to be superparamagnetic however cold clusters are not but show strongly reduced magnetization which furthermore is non-linear with the applied field. Experimentally it is found that the anomalies are related to the cluster rotations. We also address a controversy between our earlier findings [1] and those by Bucher et al. [2], and demonstrate that their temperature determinations and consequent conclusions are incorrect.
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  • 58
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 352-354 
    ISSN: 1434-6079
    Schlagwort(e): .64.70.Fx ; 36.40.+d ; 35.20.Vf
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract In this paper, we report properties of selenium clusters produced by vapor condensation technique. Impact electronic ionization is performed on clusters in the size range from 2 to 36 atoms. The measured ionization potentials exhibit small oscillation corresponding to the wiggles observed on the mass distribution. An attempt to connect these experimental observations with the geometrical structure of the molecules is made in the discussion.
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  • 59
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 394-396 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Noble gas atoms trapped in the intracrystalline cavities of zeolites may form clusters. A classical-mechanical isoenergetic molecular dynamics simulation is performed to simulate the dynamical behavior of noble gas clusters in zeolite cavities. To implement the simulation, a model is adopted of a homogeneous spherical cavity with Morse interaction between the noble gas atoms and cavity walls. The results for Ar6 clusters indicate that the noble gas clusters in the cavity undergo the same solid/liquid phase changes as in free space, and, at high enough energies, a rapid exchange between atoms adsorbed on the inner surface and thosein the interior of the cavity. Mathematical quenching is used to investigated the multidimensional potential surface of Ar clusters in the cavity.
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  • 60
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 391-393 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 05.45.+b
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We have computed the local Kolmogorov entropy of molecular dynamics trajectory segments near the potential energy saddles of model Ar3 and Ar5 clusters. In the case of Ar3 clusters bound with a Lennard-Jones potential, the local Kolmogorov entropy of the cluster is significantly smaller in the saddle region than in other areas of the potential surface. This behavior indicates an increase in the degree of nearly quasiperiodic motion near the Ar3 saddle due to the partial decoupling of the cluster's vibrational modes there. Lennard-Jones Ar5 clusters do not exhibit similar behavior, but Ar5 clusters bound with a short-range Morse potential do. This suggests that the “regularizing” effect of saddle regions is strongly dependent on the shape of the energy surface near the saddle. From these observations, we can determine which features of the saddle are most important in this respect; the flatness of the saddle region seems to be one such feature.
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  • 61
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 95-97 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 33.20.Kf
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The dipole surface plasmon forK N + clusters is analyzed using the RPA sum-rule technique within a semiclassical Density Functional Theory and the spherical jellium model. The theoretical frequencies are blue shifted as compared to the experimental ones. The discrepancies between theory and experiment are reduced when considering non-local energy contributions in the density functional and phenomenologically including atomic lattice effects by means of an electron effective mass and a static dielectric constant.
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  • 62
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 73-75 
    ISSN: 1434-6079
    Schlagwort(e): 61.14.−x ; 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Calculations of the dynamical Debye-Scherrer electron diffraction pattern for ultrafine gold and silver particles have been performed using the multislice method. Two cluster sizes, 31 and 55 Å in diameter (923 and 5083 atoms, respectively), of both f.c.c. and icosahedral structures were used, at incident voltages of 40 kV and 100 kV.
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  • 63
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 92-94 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 03.65.Sq ; 33.80.Eh ; 35.20.Vf
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Neutral aluminum clusters have been produced by laser vaporization technique, ionized by a low-power near-threshold laser light and detected using standard TOF spectrometric methods. Ionization potentials have been deduced in the low size range. In the large size range 250〈N〈1400 the patterns of the mass spectra exhibit a regular and continuous oscillation, originating from size-dependent ionization threshold effects. The period, constant on a Ne 1/3 scale (Ne=3N is the number of valence electrons), is approximately two times shorter than the one observed in alkali experiments. This feature is analyzed in terms of shell structure.
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  • 64
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 110-112 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 21.60.Cs
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Under experimental conditions which do not favor delocalization of valence electrons alkali atoms remain neutral and are taken as atomic fermions. Thus, two neutral alkali component microclusters are treated by a two-fermion shell model producing two sets of magic numbers containing many common numbers.
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  • 65
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 113-114 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 82.80.Ms
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The present paper supports coexistence of electronic shells and shells of ion cores for large alkali clusters.
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  • 66
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 146-149 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 33.60.Cv ; 07.77.+p
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Bismuth cluster anions are produced in a new type of source (PACIS). For Bismuth the intensity is estimated to be 10 times higher than that of a laser vaporization source. UV-photoelectron spectroscopy serves to study the electronic level structure of the cluster anions. In the photoelectron spectra of Bi 2 − , Bi 3 − and Bi 4 − the main transitions agree with earlier results of LIF investigations on the neutral species as well as with recent theoretical and experimental data. Here we present a first extension to higher photon energies.
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  • 67
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 15-17 
    ISSN: 1434-6079
    Schlagwort(e): 68.35.Bs ; 36.40.+d ; 35.20.Bm
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Rigorous analytical formulae for mean nearest-neighbour coordination numbers in clusters as a function of cluster size have been derived for a range of geometries: the tetrahedron, octahedron, cuboctahedron, icosahedron and bcc rhombic dodecahedron. Formulae for outer-neighbour coordination numbers are also reported, including a complete analysis of interatomic distances and mean coordination numbers in icosahedra. The formulae will find application in studies of electronic structure and interpretation of EXAFS data.
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  • 68
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 180-182 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 33.80.Eh
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Electronically excited states of magnesium-water cluster ions, Mg+(H2O) n ,n=1–5, are studied by photodissociation after mass selection. The observed photodissociation spectra are assigned to the2P–2S type transitions localized on the Mg+ ion with the aid of ab initio CI calculations. In addition to evaporation of water molecules, photoinduced intracluster reaction to produce MgOH+(H2O) n is found to occur efficiently, with pronounced size dependence. The intriguing features observed in the mass spectrum of nascent cluster ions are discussed in relation to the stepwise solvation of this reaction.
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  • 69
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 213-215 
    ISSN: 1434-6079
    Schlagwort(e): 31.20.Di ; 31.20.Gm ; 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract In this paper we present the theoretical results obtained for (NaCl) n clusters withn≤19. The calculations were performed using the ab-initio Perturbed-Ion (PI) model. That model was first developed for the study of ionic crystals and we have adapted it to study clusters. Within the PI method we can determine the total energy of the cluster as a function of the position of the atoms in the cluster and minimizing the total energy with respect to the positions of the atoms we can obtain the ground state geometry and other related properties. The results obtained for the equilibrium geometries are in good agreement with theoretical calculations using pair potentials. The study of the relative stabilities of clusters with different numbers of molecules show that the clusters are specially stable for n=4, 6, 9, 12, 15, 16 and 18 molecules, in good agreement with experimetal results.
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  • 70
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 237-239 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 31.20.Ej ; 31.20.Tz
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract In this paper, we report the results ofab initio molecular orbital calculations on cube-like (MgO)n clusters (n=1−13). We determine the relative stability of the clusters by analyzing binding energies and dissociation energies involved in the evaporation of a neutral MgO monomer. The calculated magic numbers are in very good agreement with the abundance maxima observed in the mass spectra. We also explore the size-dependence of structural, energetic and electronic properties of the clusters, finding different rates to reach the corresponding bulk limit.
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  • 71
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 255-257 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 31.90.+s ; 71.45.Nt
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A local-density approximation calculation is performed on various M8C12 structures, including Ti8C12, V8C12, VTi7C12 and ScTi7C12. It is found that the magic numbers observed during the experimental discovery of these species does not depend on the details of the electronic structure, but rather can be described as a chemical system derived from ethylene.
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  • 72
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 282-284 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 71.45.−d ; 78.65.−s
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We discuss the collective dipolar resonances of theC 60 molecule described by a spherically symmetric shell. The shell is modeled by a step in the radial direction. We present results for π and π+σ plasmons in good quantitative agreement with recent experiments. New features, like a monopole mode of oscillation, are predicted for theC 60 molecule.
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  • 73
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 26 (1993), S. 300-304 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 34.50.-s
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract This article reviews recent work in Los Angeles on elementary processes in fullerene vapors. The production of fullerene molecules typically involves extreme high-temperature conditions and processes which are poorly understood at date [1–3]. Once generated, these molecules may represent the most stable molecules known [4,5]. In a recent work [C. Yeretzian et al., Nature 359, 44 (1992)] we presented clear evidence for coalescence reactions between fullerene molecules. Mass spectrometric measurements on hot, dense vapors of small fullerenes (C60 and C70) reveal the formation of stable higher fullerenes which are multiples of the initial masses. These processes are shown to occur in the gas-phase rather than in the solid film and their dependences on laser fluence and He-gas pressure are investigated. Three distinct reactions are proposed—coalescence, emission and capture—to account for the observed distributions at higher fullerene sizes. Specifically, the heat of coalescence is released through emission of small, even-numbered fragments which, in a very dense vapor, are efficiently captured by other coalesced fullerenes. These findings have implications for the long-time stability of the fullerene vapor, and for the mechanism of fullerene formation and growth, and may open new ways to the synthesis of selected higher fullerenes and encapsulation compounds.
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  • 74
    ISSN: 1434-6079
    Schlagwort(e): 07.77.+p ; 34 ; 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The hydrogen cluster accelerator existing at Institut de Physique Nucléaire de Lyon (IPN Lyon) has been upgraded by adding a Variable Energy Post-accelerator of RFQ type (VE-RFQ). This operation has been performed in the frame of a collaboration between KfK Karlsruhe, IAP Frankfurt and IPN Lyon. The facility has been designed to deliver beams of mass selected Hn+ clusters, n chosen between 3 and 49, in the energy range 65–100 keV/u. For the first time, hydrogen clusters have been accelerated at energies as high as 2 MeV. This facility opens new fields for experiments which will greatly benefit from a velocity range never available until now for such exotic projectiles.
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  • 75
    Digitale Medien
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    The European physical journal 28 (1993), S. 67-72 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 71.28.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Rare earth clusters of europium, thullium and ytterbium were generated by gas aggregation technique and probed by photoionization mass spectrometry. Their relative intensities in mass spectra have shown that their stabilities are governed by compact geometrical structures. The addition of oxygen gas in the nucleation region was used to produce the reactive nucleation. Several stages of oxidation were observed as a function of oxygen pressure up to saturation. For the maximal degree of oxidation the observed oxide ion compositions enable one to follow the valence of metal atom in its oxide as cluster size increases. This exhibits a divalent to trivalent valence change with cluster size. Moreover it emerges from the data that the divalent to trivalent transition for Tm, Yb, and Eu occurs at different size values.
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  • 76
    Digitale Medien
    Digitale Medien
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    The European physical journal 25 (1993), S. 261-265 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 79.20.Kz
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Gold clusters with diameters from 2 to 10 nm are prepared by evaporation on mica substrates. They are investigated with low energy electron loss spectroscopy in the reflected beam and characterised in a transmission electron microscope. The energy loss spectra show a broadening of the plasma peak with decreasing particle size. The plasma frequency shifts to higher energies. The size dependence of the half width and of the plasma frequency is compared to known models. The results support the quantum box model of Genzel et al.
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  • 77
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The optical absorption spectra of small niobium clusters have been determined over the wavelength range 260 – 740 nm by photodetaching Krypton atoms from the corresponding neutral van der Waals, vdW, complexes, NbnKrm, n=5–15, m=1–3. Cross sections for small gold clusters were determined by photodetachment experiments oncharged vdW complexes [AunXem]+, m=1, 2. The absorption cross sections are observed to increase monotonically with decreasing wavelength. At the long wavelength end of the range, the cross section is practically independent of the cluster nuclearity, n; whereas, at the short wavelength end of the range, the cross section increases monotonically with n.
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  • 78
    Digitale Medien
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    The European physical journal 26 (1993), S. 56-58 
    ISSN: 1434-6079
    Schlagwort(e): 68.35.Md ; 36.40.+d ; 64.60.-i ; 62.50.+p
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract High pressure optical absorption spectra are presented for CdSe nanocrystals as a function of size. The spectra show a transition to a high pressure Rock Salt type phase at pressure greatly elevated from the bulk. The size dependence of the transition pressure can be explained in part by an increased surface tension in the Rock Salt phase relative to the low pressure tetrahedral phase.
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  • 79
    Digitale Medien
    Digitale Medien
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    The European physical journal 26 (1993), S. 51-55 
    ISSN: 1434-6079
    Schlagwort(e): 71.10.+x ; 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We present a simulation method to determine from first principles the structure of low symmetry atomic systems. Our method is based on Langevin molecular dynamics and quantum mechanical interactions derived fromab initio pseudopotential calculations. The molecular dynamics time step with this approach can be one to two orders of magnitude larger than in the Car-Parrinello method, compensating for the time required for self-consistency at each step. Moreover, because the simulation is constrained to reside on the Born-Oppenheimer surface, this method can be used for insulating as well as metallic and charged systems. Application will be made to small silicon clusters.
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  • 80
    Digitale Medien
    Digitale Medien
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    The European physical journal 26 (1993), S. 105-109 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract This invited review attempts to draw together recent advances in the structural characterisation of clusters and our theoretical understanding of dynamics, especially coexistence phenomena. It is now possible to characterise the potential energy surface of a small cluster in great detail, both in terms of local minima and transition states. A selection of results is collected includingab initio calculations on main group ligated clusters and a wide variety of systems bound by model analytic potentials. Useful comparisons may be made between the rearrangement mechanisms supported by the various potential energy surfaces. Furthermore, knowledge of transition states enables us to explain the results of dynamical simulations in great detail, and make comparisons with thermodynamic models. For larger systems, however, the number of stationary points is daunting, yet progress is still possible in terms of the underlying potential energy surface using the harmonic superposition approximation.
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  • 81
    Digitale Medien
    Digitale Medien
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    The European physical journal 26 (1993), S. 131-134 
    ISSN: 1434-6079
    Schlagwort(e): 33.80.-b ; 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The real-time dynamics of Nan (n=3–21) cluster multiphoton ionization and fragmentation has been studied in beam experiments applying femtosecond pump-probe techniques in combination with ion and electron spectroscopy. Three dimensional wave packet motions in the trimer Na3 ground state X and excited state B have been observed. We report the first study of cluster properties (energy, bandwidth and lifetime of intermediate resonancesNa n * ) with femtosecond laser pulses. The observation of four absorption resonances for the cluster Na8 with different energy widths and different decay patterns is more difficult to interpret by surface plasmon like resonances than by molecular structure and dynamics. Time-resolved fragmentation of cluster ions Na n + indicates that direct photo-induced fragmentation processes are more important at short times than the statistical unimolecular decay.
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  • 82
    Digitale Medien
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    The European physical journal 26 (1993), S. 204-206 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 81.10.Bk ; 35.20.Wg
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Using a CO2 laser we have desorbed LiOH and NaOH from a solid target into an expanding inert gas jet pulse. Subsequently the beam was ionized by photons from a UV laser. Surprisingly, we observed in mass spectra metal water clusters and metal-hydride water clusters. For the metals M=Li, Na we find that the [M(H2O)n]+ peaks are dominant for small clusters, while for large clusters (n〉20) the [MH(H2O)n]+ peaks are dominant. This indicates that the clathrate (H2O)20 may play an important role in the formation of metallo-water clusters.
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  • 83
    Digitale Medien
    Digitale Medien
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    The European physical journal 26 (1993), S. 226-228 
    ISSN: 1434-6079
    Schlagwort(e): 79.20.Rf ; 34.50.Lf ; 79.20.Nc ; 81.60.Cp ; 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We review the processes which have been observed from collisions between alkali-halide clusters and solid surfaces. Soft impact of nanocrystalline NanF n−1 + clusters against solid surfaces causes them to cleave along the lowest energy (100) plane. At higher collision energies (Ei〉1 eV/atom), an evaporative cascade occurs which is characteristic of a transformation of the nanocrystal to a molten state. Efficient F− transfer from the cluster to the surface can occur for the larger clusters (〉60 atoms) scattering from Si(111), in direct competition with the cleaving channel at low energies. In this regime, strong bonds can form between the F− and silicon surface. The reaction probability increases with cluster size indicating that an impact-initiated shock wave is needed to enhance the reactive process.
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  • 84
    Digitale Medien
    Digitale Medien
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    The European physical journal 26 (1993), S. 264-266 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 31.90.+s
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We have investigated symmetrical and asymmetrical fissions of positively charged silver clusters by a shell correction method. Contour plots of the total electronic energy as a function of deformation parameters have been obtained. They show complicated topographies arising from the shell correction.
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  • 85
    ISSN: 1434-6079
    Schlagwort(e): 32.80.Fb ; 36.40.+d ; 33.20.Kf
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Photo-absorption cross-sections for charged sodium clusters (14 to 48 atoms) have been measured for photon energies from 2.0 eV to 3.5 eV. The spectra are dominated by surface plasma oscillations of the valence electrons exhausting 70–100% of the dipole sum rule. The mean resonance energy of ≃2.75 eV is nearly independent of cluster size. A splitting of the resonance peaks is observed for non-“magic” clusters and discussed in terms of a deformation picture involving prolate and oblate shapes.
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  • 86
    Digitale Medien
    Digitale Medien
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    The European physical journal 26 (1993), S. 284-286 
    ISSN: 1434-6079
    Schlagwort(e): 73.20.Mf ; 36.40.+d ; 31.20.Sy
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We study the origin of the discrepancy between the photoabsorption cross sections of small jellium spheres calculated by the time dependent local density approximation (TDLDA) and experiments for small metallic clusters. We have specifically studied Na 21 + . We conclude that both non-local exchange-correlation effects beyond the LDA and geometrical effects beyond the jellium approximation should be taken in the same calculation. We also present local and non-local calculations for Na n − (n=19, 91 and 197) within the framework of the jellium model. The large anions show a fragmentation of the plasmon due to its interference with the ionization threshold. This feature is absent in the TDLDA results.
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  • 87
    Digitale Medien
    Digitale Medien
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    The European physical journal 26 (1993), S. 296-300 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 71.10.+x
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Energetics and structures of small aluminum-lithium clusters were investigated using structure-minimization and dynamic simulated annealing on the Born-Oppenheimer surface, calculated via local-spin-density functional method. A transition from atomic-based characteristics forn≤5 to a perturbed delocalized electronic cluster-shell behavior forn≥6, containing an AiLi5 “core”, is suggested.
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  • 88
    ISSN: 1434-6079
    Schlagwort(e): 31.20.Tz ; 31.50.+w ; 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The ground state geometries of small neutral Ag n (n=2–9) and charged Ag n ± (n=2–9) clusters have been determined in the framework of the SCF procedure employing a relativistic pseudopotential accounting for core-valence correlation effects (RECP-CVC). Similarities and differences between neutral and charged clusters have been found. Large scale CI for 5s electrons only has been carried out for determining stabilities, ionization potentials (IP) and vertical detachment energies (VDE) of anions. A comparison between predicted and measured observables allows for the tentative structural assignments. In addition, the low lying energies of excited states for the neutral species at the anionic geometries have been calculated to account fully for geometrical and spectroscopic assignment to the photodetachment measurements.
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  • 89
    Digitale Medien
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    The European physical journal 26 (1993), S. 8-12 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The change of the cohesive energy and the optical absorption spectra of small singly sized Hg clusters is discussed. The cohesive energy allows one to determine the different regimes of chemical bonding. The optical spectra show an abrupt transition to a collective, plasmon-like absorption as a function of increasing cluster size. The position of the one plasmon peak is: 1) independent of the charge state, 2) nearly independent of cluster size, and 3) agrees with that of the classical Mie plasmon calculated from the experimental dielectric constants. The width of the plasmon peaks is discussed. A strong influence of electronic correlations on the cluster size dependence of the oscillator strength is observed.
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  • 90
    Digitale Medien
    Digitale Medien
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    The European physical journal 26 (1993), S. 17-22 
    ISSN: 1434-6079
    Schlagwort(e): 31.20.Tz ; 31.50.+w ; 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The contribution of quantum chemicalab — initio studies of optical response in small metal clusters towards understanding of their specific electronic and structural properties has been presented. The role of cluster size, geometry, number of valence electrons and chemical composition has been pointed out. It has been shown that an appropriate many-electron description of excited states for stable cluster structures allows for the quantum molecular interpretation of the absorption spectra and other optical probles. The nature of excitations responsible for characteristic spectroscopic patterns has been discussed.
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  • 91
    Digitale Medien
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    The European physical journal 26 (1993), S. 373-376 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The paper presents an analytic model which is based on approximation of the catchment basins in cluster potential energy surface by structures of ash-tray type. In order to see how the quantities to be specified relate to those obtained by means of numerical computation, predictions for the Ar13 caloric curve are made and they are compared with computer simulation data.
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  • 92
    Digitale Medien
    Digitale Medien
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    The European physical journal 26 (1993), S. 27-29 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 65.40.−f ; 76.80.+y
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract There are 5 different Au-sites in the Au55 core of Au55(PPh3)12Cl6. The 13 inner atoms are almost identical to that of bulk gold. At the surface the attachment of the ligands is responsible for further differentiation. We have calculated the low temperature specific heat using the Mössbauer determined electrical quadrupolar splitting of the surface atoms. Due to too long a quadrupolar relaxation time, no such contribution is seen in the zero field results (down to 0.06 K) of Goll et al., Z. Phys. D 20, 329 (1991). The latter zero and in-field data are interpreted as the contribution of an electronic spin, hyperfine coupled to a nuclear spin 3/2. The effective abundance is about one spin per ten clusters.
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  • 93
    Digitale Medien
    Digitale Medien
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    The European physical journal 26 (1993), S. 131-133 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 31.20.Sy ; 03.65.Sq
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Starting from the Hartree-Fock exchange energy density of a spin saturated system and using the Density Matrix Expansion we have built a non local Energy Density Functional without problems of divergence in the large gradient limit. We have applied this functional to the study of ground state properties and the dipole excitation energies of some metallic clusters in the quantal and semiclassical approaches.
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  • 94
    Digitale Medien
    Digitale Medien
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    The European physical journal 26 (1993), S. 143-145 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 31.20.Sy ; 71.30.+h
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Electronic structures of mercury clusters are studied by the self-consistent calculations. It is found that an icosahedral Hg13 cluster is characterized by the atomic nature with closed electronic shell configuration while a significant amount of thespd-hybridization is observed for a Hg19 cluster with a double-icosahedral shape. The electronic structure of a Hg12Ag cluster is also studied with a special focus on the electronic shell structure.
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  • 95
    Digitale Medien
    Digitale Medien
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    The European physical journal 26 (1993), S. 137-139 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 35.20.Vf ; 33.80.Eh
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Laser photoionization experiments have been performed on a large size range of indium and thallium clusters. The metal clusters were produced by laser vaporization technique and analyzed after laser ionization by standard time-of-flight mass spectrometry. For the indium clusters, individual ionization potentials (IP) are deduced for N≤132. Abrupt decreases in the IP values are observed, which correspond to the openings of new electronic shell as predicted by the spherical jellium model. For larger indium clusters, the unresolved mass spectra present small but reproducible oscillations. Interpretations in terms of either electronic shell structure or cluster geometry remain undecided for the moment. Our results on thallium clusters are less abundant and only qualitative. Nevertheless, they show that thallium behaves more like a monovalent element than like a trivalent one.
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  • 96
    Digitale Medien
    Digitale Medien
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    The European physical journal 26 (1993), S. 288-290 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 33.80.Eh ; 35.20.Wg
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We investigate the time dependence of carbon cluster ions, formed via thermionic emission from photoexcited fullerenes (C60 and C70). By pulsing the extraction field, we are able to observe delayed ions formed as late as 100 µs after excitation at 532 nm, 355 nm, or 266 nm. All even-sized clusters in the range 36 ≤ n ≤ 70 undergo thermionic emission.
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  • 97
    Digitale Medien
    Digitale Medien
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    The European physical journal 26 (1993), S. 297-299 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 33.60.Cv
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The electronic structure of an isolated Ca@C60 molecule was probed by photoelectron spectroscopy (PES) of Ca@C 60 − , generated by laser desorption of a preformed Ca@C60/fullerene thin film. The PES spectrum of Ca@C60 was found to be similar to that of C 60 − , except that Ca@C60 has an electron affinity of 3.0 eV, about 0.3 eV higher than that of C60. The spectrum suggests that Ca atom donates its two 4s electrons to the C60 t lu lowest unoccupied molecular orbital. Thus, the interaction between the central Ca atom and C60 is quite ionic, and Ca@C60 can essentially be expressed as Ca2+@C 60 2− .
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  • 98
    Digitale Medien
    Digitale Medien
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    The European physical journal 26 (1993), S. 311-313 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 35.20.Wg
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Using a pulsed CO2 laser we have desorbed C60 clusters from a solid target into an expanding He jet, coupled to a time-of-flight mass spectrometer. We observed self ionization of the excited clusters with a time delay of 120 ±20 µs. This is large compared to previously reported delays of up to 15 µs after laser excitation with visible or ultraviolet light. We suggest that the delayed ionization is caused by structural isomers of hot C60 clusters differing from the truncated-icosahedron structure.
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  • 99
    Digitale Medien
    Digitale Medien
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    The European physical journal 26 (1993), S. 174-176 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Cluster beams of high intensity as resulting from condensation in adiabatic nozzle expansions of pure gases or vapors can be used either for thin film deposition or for substrate erosion, depending on the cluster impact energy. For deposition, high-intensity cluster beams of zinc and of silver have been obtained for the first time from pure metal vapor nozzle expansions. The clusters contain several thousand atoms of zinc, or several hundred atoms of silver, respectively. Reflecting thin films have been deposited without ionizing and accelerating the cluster beams. For purposes of erosion, ionized clusters have to be accelerated to impact speeds larger than about 10 km/s in order to get surface erosion via shock wave induced crater formation. Crater dimensions of some nanometers are estimated, providing a limit for the spatial resolution of cluster impact lithography (CIL).
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  • 100
    Digitale Medien
    Digitale Medien
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    The European physical journal 26 (1993), S. 177-179 
    ISSN: 1434-6079
    Schlagwort(e): 36.40.+d ; 33.80.Eh ; 33.20.Lg
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Clusters of aluminum atoms solvated with water molecules, Al(H2O) n , have been studied by one-photon ionization and time-of-flight mass spectroscopy. Characteristic feature is observed in the photoionization mass spectrum: The intensities of the product Al+(H2O) n ions are about one order of magnitude larger forn≤4 than forn≥5. The ionization potentials are determined forn up to 4. The obtained results are discussed in connection with the recent theoretical works. The photodissociation spectroscopy has also been applied to the Al+(H2O) n ions withn=1−10. The observed spectra are ascribed to the transition localized on the Al+ ion on the analogy of the results of Mg+(H2O) n photodissociation. The dissociation dynamics is also discussed from the fragmentation pattern with the aid of the recent theoretical work on the structure and stability of these ions.
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