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  • Articles  (317,865)
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  • 1
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    GPS solutions 3 (2000), S. 44-48 
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: The global positioning system (GPS) is used increasingly to control horizontal and vertical displacement of large civil constructions. The displacements can occur over varius time scales. For example, in case of the loading test of a bridge, the time span between measurements is on the order of 30 min. The achievable precision in the vertical component and its relation to residual multiplath effects become critically important in such aaplications. A multipath-to-noise ratio (MNR) on individual satellites is introduced to quantify the multipath effects. © 2000 John Wiley & Sons, Inc.
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  • 2
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    GPS solutions 3 (2000), S. 65-68 
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
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  • 3
    ISSN: 1521-1886
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    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: In this article, initial results are presented of a method to improve fast carrier phase ambiguity resolution over longer baselines (with lengths up to about 200 km). The ionospheric delays in the global positioning system (GPS) data of these long baselines mainly hamper successful integer ambiguity resolution, a prerequisite to obtain precise positions within very short observation time spans. A way to correct the data for significant ionospheric effects is to have a GPS user operate within an active or permanently operating network use ionospheric estimates from this network. A simple way to do so is to interpolate these ionospheric estimates based on the expected spatial behaviour of the ionospheric delays. In this article such a technique is demonstrated for the Dutch Active Control Network (AGRS.NL). One hour of data is used from 4 of the 5 reference stations to obtain very precise ionospheric corrections after fixing of the integer ambiguities within this network. This is no problem because of the relatively long observation time span and known positions of the stations of the AGRS.NL. Next these interpolated corrections are used to correct the GPS data from the fifth station for its ionospheric effects. Initial conclusions about the performance of this technique are drawn in terms of improvement of integer ambiguity resolution for this baseline. © 1999 John Wiley & Sons, Inc.
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  • 4
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    GPS solutions 3 (2000), S. 69-69 
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
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  • 5
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    GPS solutions 3 (2000), S. 58-64 
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: Since global positioning system (GPS) measurements are ranges (code) and biased ranges (carrier), it seems natural to model them as ranges and determine the biases. This is particularly compelling since the double-difference range biases turn out to be integers. At some level there is also an elegance, perhaps therefore a naturalness, to modeling the carrier measurements as time differences of double differences. While something is lost something else is gained. Here we apply the proven delayed-state Kalman filter to processing carrier phase measurements as triple differences. In practice we process these triple differences along with double-difference code measurements. We also treat the measurement error as, mostly, Gauss-Markov states to be determined. Many of the details are discussed and experimental results are included. These demonstrate that excellent performance can be obtained if the Kalman filter modeling is done carefully. © 2000 John Wiley & Sons, Inc.
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  • 6
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    GPS solutions 3 (2000), S. 75-77 
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
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  • 7
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    GPS solutions 3 (2000), S. 1-9 
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: A third civil frequency at 1176.45 MHz will be added to the Global Positioning System (GPS). This new frequency will bring a number of benefits. The aviation user will be one of the prime beneficiaries because the new frequency is in a protected aviation band. Thus, the system will be more robust against interference and jamming. The carrier-phase differential user will also be a prime beneficiary as long as his application has a reasonably short baseline. It is this high accuracy use that is explored in some depth. The process of forming linear combinations of both the code and carrier-phase measurements is studied, and the benefits and problems are explained. © 2000 John Wiley & Sons, Inc.
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  • 8
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    GPS solutions 3 (2000), S. 70-74 
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: The ionospheric range delay is highly variable both in space and in time. The ionospheric correlation distance is defined as the distance over which a measurement of the difference from monthly mean ionospheric range delay at one location can be used to determine the difference from mean conditions at a second location. The percentage improvement required is dependent upon the actual correlation coefficient, which must be relatively large to produce a significant improvement over differences from average conditions at two stations. Results of studies of the correlation distance show that, in order to obtain even a 28% improvement over monthly median conditions, the measurement location must be within approximately 3,000 km in longitude or 1,800 km in latitude from the location where the update from monthly mean conditions is required, at least in the mid-latitude region. Another study showed that, in order to be able to determine an improvement of 1 m in ionospheric range delay from average ionospheric conditions at a location remote from where the actual measurement of range delay is made, the measurement must be within approximately 500 km of that location. © 2000 John Wiley & Sons, Inc.
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  • 9
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    GPS solutions 3 (2000), S. 24-34 
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: At the Delft University of Technology (DUT), the data of six stations participating in the first international GLONASS (Global Navigation Satellite System, the Russian counterpart of GPS) tracking campaign, IGEX-98, were analyzed with integrity monitoring software. The software was developed at the Department of Mathematical Geodesy and Positioning of DUT. The main function of this software is to detect slips and outliers in phase and code observations in real time. In addition, the software also allowe the validation of the information contained in the broadcast navigation messages. The results of the IGEX-98 data analyses will be presented in a three-part series. In this second part of the series, GLONASS outlier and slip statistics will be discussed in detail. The first part was concerned with the availability of GLONASS observations, while in the third one the broadcast navigation message validation results will be considered. © 2000 John Wiley & Sons, Inc.
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  • 10
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    GPS solutions 3 (2000), S. 35-38 
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: The forthcoming World Radiocommunication Conference (WRC) will deal with frequency allocation and protection issues that are of fundamental importance to GNSS (Global Navigation Satellite System) and GPS (Global Positioning System), which is a component of GNSS. In many countries, GPS L1 and L2 are not protected, and much needs to be done to obtain a frequency allocation for GPS L5. A brief explanation of the International Telecommunication Union (ITU) and how it can impact satellite navigation at its World Radiocommunication Conference in 2000 (WRC-2000) is provided. © 2000 John Wiley & Sons, Inc.
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  • 11
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    GPS solutions 3 (2000), S. 39-47 
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: Positioning and navigation – as are presently possible with the American Global Positioning System (GPS) and the Russian GLONASS system – is briefly reviewed. Deficiencies, which have led to augmentations like the European Geostationary Navigation Overlay System (EGNOS), are outlined. Europe's decision to get involved in the definition and possible set-up of a Global Navigation Satellite System (GNSS) of the second generation (GNSS-2), called Galileo, is discussed in detail as well as the GPS modernization program that might take place during the sample phase. Finally, some brief thoughts on the benefit of GNSS-2 for geodesy and surveying are given. © 2000 John Wiley & Sons, Inc.
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  • 12
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    GPS solutions 3 (2000), S. 10-23 
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: The International GLONASS Experiment 1998 (IGEX-98) was the first international tracking campaign of the Russian counterpart to the Global Positioning System (GPS), GLONASS. Started in October 1998, the campaign was originally scheduled to last for three months. However, the launch of additional GLONASS satellites and a widespread enthusiasm among the participants led to an indefinite continuation of the campaign on a “best effort” basis. At the Delft University of Technology, the data of six IGEX-98 stations have been analyzed in detail with integrity monitoring software, developed at the Department of Mathematical Geodesy and Positioning of the University. The software aims to detect outliers and slips in code and phase observations in real time. In addition, the software also allows the validation of the information contained in the broadcast navigation messages. The results of the IGEX-98 data analyses will be presented in a three-part series. In the second part, GLONASS outlier and slips statistics will be discussed, while in the third part the anomaly detection results of the GLONASS and GPS messages will be shown. In this first part of the series, however, the most basic of all statistics will be considered: a simple day-to-day count of the number of GLONASS and GPS observations. Although simple, this statistic yields a surprising amount of information both on the availability of the GLONASS satellites and on the peculiarities of some of the receiver makes participating in the IGEX-98 campaign. © 2000 John Wiley & Sons, Inc.
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  • 13
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    GPS solutions 3 (2000), S. 48-57 
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: The Federal Aviation Administration (FAA) is developing the wide-area augmentation system (WAAS) to supplement the Global Positioning System (GPS) and serve as a single en-route navigation aid. The program traveled a rocky road so far. We compare the original concept of WAAS with its current scaled down version, analyze the changed perspectives with respect to the utility of GPS for air navigation and the concomitant role of WAAS, and explore the future of GPS/WAAS. © 2000 John Wiley & Sons, Inc.
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  • 14
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    GPS solutions 3 (2000), S. 70-70 
    ISSN: 1521-1886
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  • 15
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    GPS solutions 3 (2000), S. 58-64 
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: There are various applications in which a Global Positioning System (GPS) sensor only down-converts and digitizes the received GPS signal and sends the digitized data to a processor, where the processor software performs all the correlation, search/track operations, navigation solution, and so on. Among the applications are military and commercial ones (e. g., GPS(Communication handheld sets, people tracking systems). A major problem with the Software GPS Receiver is the large computing resources required for correlation or acquisition of the GPS signal. In this article, several possible approaches for reducing computing resources will be introduced and analyzed. It will be shown that the performance of the GPS software design strongly depends on the features of the computer hardware. Implementations will be described on the TMS320C6201 processor and the Pentium II. Experimental results will be demonstrated by processing of real GPS signals. A complete 16-channel GPS receiver was implemented on the single TMS320C6201 processor in real-time mode and on the Pentium II processor with a duty cycle of about 50%. © 2000 John Wiley & Sons, Inc.
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  • 16
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    GPS solutions 3 (2000), S. 65-69 
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: The law affects the Global Positioning System (GPS) industry both on a macro and on a micro level. On a macro level, issues such as future regulation of telematics, frequency spectrum allocation, and international agreements will shape the future of the industry. On a micro level, GPS companies can benefit from knowledge of legal pitfalls common in the high technology arena. Many thanks to Ingrid Lagarrigue, a French aviation and space lawyer specializing in Global Navigation Satellite legal issues, for her assistance and comments. © 2000 John Wiley & Sons, Inc.
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  • 17
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    GPS solutions 3 (2000), S. 71-74 
    ISSN: 1521-1886
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  • 18
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    GPS solutions 3 (2000), S. 80-82 
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
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  • 19
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    GPS solutions 4 (2000), S. 1-1 
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
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  • 20
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: A number of statistic Global Positioning System (GPS) measurement campaigns have been made on a floating Antarctic ice shelf, the Amery Ice Shelf, as part of ongoing glaciological studies designed to investigate the ice shelf dynamics, grounding zone definition, and ice shelf strain. Such studies ar fundamental to improving out knowledge of the Antarctic ice-sheet mass balance and dynamical models of ice sheet/ocean interaction. This article describes two techniques used to process the statistic GPS data. One approach uses a segmented version of the classical static methodology, and the other approach adopts a new sequential processing technique. Both approaches yield similar results for the station coordinates and demonstrate the potential of GPS for extracting the tidal signal on the ice shelves and giving information on the dynamical motion of the ice sheet. To verify our results for the vertical component, we compare the ice shelf GPS tidal signal with a tidal model derived from tide gauge measurements at nearby Beaver Lake. Comparison of the GPS results with the tide model give good agreement in amplitude at the few cm level (GPS results always larger) but clearly shows evidence of phase propagation of the ocean tidal wave under the ice shelf. Improving the resolution of the tides over the ice shelves will be of tremendous benefit for future satellite missions, such as Ice, Cloud and Land Elevation Satellite (ICESAT), and the integrated use of GPS and satellite data will be fundamental for any on-going Antarctic ice sheet mass balance studies. © 2000 John Wiley & Sons, Inc.
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  • 21
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    GPS solutions 4 (2000), S. 13-20 
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: A new computer-aided design (CAD) program called Falcon 3.0 has been created to simulate and evaluate receiver designs. This CAD tool aims to solve tasks at the design stage of navigation receivers that operate with signals from Navigational Satellite Time and Ranging (NAVSTAR) and Global Navigational Satellite System (GLONASS). Specific tasks include: · Defining the receiver frequency plan (frequencies of oscillators and filters that guarantee accuracy of the receiver) · Specifying parameters for the digital processing of received signal · Computing interpath and interchannel biases · Computing statistical characteristics of correlation signals I, Q, dl, and dQ · Calculating noise and multipath errors of measurements · Determeining energy losses This CAD tool has been used in the design of receivers such as Javad Positioning Systems (JPS) Legacy, Regency, Odyssey, and Eurocard and in the prediction of their accuracy. It has been shown that experimental and predicted data agree well. © 2000 John Wiley & Sons, Inc.
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  • 22
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    GPS solutions 4 (2000), S. 21-33 
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: The recent development of low-cost, high-precision oscillators has allowed many applications in various fields to become financially feasible. The stability of an oscillator is ultimatively what determines its usefulness for a certain application, and is therefore desirable to quantify. Current methods of evaluating stability require a direct comparison of the oscillator under test (OUT) with amore stable reference oscillator, the cost of which often offsets the initial benefit of a low-cost device. However, a relatively inexpensive Global Positioning System (GPS) receiver is capable of exploiting the highly stable GPS time scale, thus obviating the need for an expensive reference oscillator. By allowing the OUT to drive a GPS receiver, and processing the data with precise GPS orbits and clock corrections to eliminate the effects of selective availability (SA), the time series of computed clock offsets provides a measure of the oscillator's stability relative to GPS time. The use of GPS for assessing clock stability in the time domain is evaluated herein via the computation of Allan variance values. Performance of one rubidium and three ovenized crystal oscillator are investigated. Results show the method is limited to time intervals less than about two seconds or longer than about 300 seconds, where the effects of measurement noise and residual SA is less pronounced. © 2000 John Wiley & Sons, Inc.
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  • 23
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: Patricia Doherty joins the regular contributors of this column to discuss the correlation between measurements of solar 10.7 cm radio flux and ionospheric range delay effects on GPS. Mrs. Doherty has extensive experience in the analysis of ionospheric range delays from worldwide systems and in the utilization and development of analytical and theoretical models of the Earth's ionosphere. Ionospheric range delay effects on GPS and other satellite ranging systems are directly proportional to the Total Electron Content (TEC) encountered along slant paths from a satellite to a ground location. TEC is a highly variable and complex parameer that is a function of geographic location, local time, season, geomagnetic activity, and solar activity. When insufficiently accounted for, ionospheric TEC can seriously limit the performance of satellite ranging applications. Since the ionosphere is a dispersive medium, dual-frequency Global Positoning System (GPS) users can make automatic corrections for ionospheric range delay by computing the apparent difference in the time delays between the two signals. Single-frequency GPS users must depend on alternate methods to account for the ionospheric range delay. Various models of the ionosphere have been used to provide estimates of ionospheric range delay. These models range from the GPS system's simple eight-coefficient algorithm designed to correct for approximately 50% rms of the TEC, to state-of-the-art models derived from physical first principles, which can correct for up to 70 to 80% rms of the TEC but at a much greater computational cost. In an effort to improve corrections for the day-to-day variability of the ionosphere, some attempts have been made to predict the TEC by using the daily values of solar 10.7 cm radio flux (F10,7). The purpose of this article is to show that this type of prediction is not useful due to irregular, and sometimes very poor, correlation between daily values of TEC and F10.7. Long-term measurements of solar radio flux, however, have been shown to be well correlated with monthly mean TEC, as well as with the critical frequency of the inonospheric F2 region (foF2), which is proportional to the electron density at the peak of the ionospheric F2 region. © 2000 John Wiley & Sons, Inc.
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    GPS solutions 4 (2000), S. 14-18 
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
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    Notes: Neural networks have been proposed as nonlinear filters in a variety of applications that involve nonlinear processing of input signals; examples include blind signal separation, image registration, and blind deconvolution. The Global Positioning System (GPS) navigation equations are nonlinear (quadratic) in nature, and a direct closed form solution of the GPS navigation equations does not exist. This article presents a new approach to solving the GPS pseudorange equations using three-layer neural networks. A three-layer radial basis function (RBF) neural network is designed, which solves the non-linear GPS pseudorange equations directly as opposed to the linear least squares or extended Kalman filter approaches in traditional GPS receivers. For training the neural network, a carefully selected cost function is minimized using a variation of the classical conjugate gradient algorithm such that training time for the neural network is reasonable. Simulations have been performed at SiRF Technology Inc. that show stable behavior even under bad geometry conditions where the traditional recursive least squares and extended Kalman filter approaches show high sensitivity to measurement errors. Under good geometry conditions the neural network solution shows slightly improved noise performance compared to the expected performance of traditional leas squares solution. Simulations have been performed with additive white Gaussian noise and correlated noise models to evaluate the performance of the trained neural network. © 2000 John Wiley & Sons, Inc.
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  • 25
    ISSN: 1521-1886
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    Notes: In order to achieve to GPS solutions of first-order accuracy and integrity, carrier phase observations as well as pseudorange observations have to be adjusted with respect to a linear/linearized model. Here the problem of mixed integer-real valued parameter adjustment (IRA) is met. Indeed, integer cycle ambiguity unknowns have to be estimated and tested. At first we review the three concepts to deal with IRA: (i) DDD or triple difference observations are produced by a properly chosen difference operator and choice of basis, namely being free of integer-valued unknowns (ii) The real-valued unknown parameters are eliminated by a Gauss elimination step while the remaining integer-valued unknown parameters (initial cycle ambiguities) are determined by Quadratic Programming and (iii) a RA substitute model is firstly implemented (real-valued estimates of initial cycle ambiguities) and secondly a minimum distance map is designed which operates on the real-valued approximation of integers with respect to the integer data in a lattice. This is the place where the integer Gram-Schmidt orthogonalization by means of the LLL algorithm (modified LLL algorithm) is applied being illustrated by four examples. In particular, we prove that in general it is impossible to transform an oblique base of a lattice to an orthogonal base by Gram-Schmidt orthogonalization where its matrix enties are integer. The volume preserving Gram-Schmidt orthogonalization operator constraint to integer entries produces “almost orthogonal” bases which, in turn, can be used to produce the integer-valued unknown parameters (initial cycle ambiguities) from the LLL algorithm (modified LLL algorithm). Systematic errors generated by “almost orthogonal” lattice bases are quantified by A. K. Lenstra et al. (1982) as well as M. Pohst (1987). The solution point ${\hat z}$ of Integer Least Squares generated by the LLL algorithm is ${\hat z}$ = (L')−1[L'◯] ∈ ℤ m where L is the lower triangular Gram-Schmidt matrix rounded to nearest integers, [L], and ${\hat z}$ = [L'◯] are the nearest integers of L'◯, ◯ being the real valued approximation of z ∈ ℤ m , the m-dimensional lattice space Λ. Indeed due to “almost orthogonality” of the integer Gram-Schmidt procedure, the solution point ${\hat z}$ is only suboptimal, only close to “least squares.” © 2000 John Wiley & Sons, Inc.
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    GPS solutions 4 (2000), S. 45-53 
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    Notes: At the Delft University of Technology (DUT), data of six stations participating in the first international GLONASS tracking campaign, IGEX-98, were analyzed with integrity monitoring software. The software was developed at the Department of Mathematical Geodesy and Positioning of DUT. The main function of the software is to detect slips and outliers in phase and code observations in real time. In addition, the software also allows the validation of the information contained in the broadcast navigation messages. The results of the IGEX-98 data analyses are presented in a three part series. In this third and final part of the series, GLONASS and GPS navigation message validation results will be discussed in detail. The first part was concerned with the availability of GLONASS observations (Jonkman & de Jong, 2000a), while in the second part, GLONASS slip and outlier statistics were considered (Jonkman & de Jong, 2000b). The discussion of the navigation message validation results concentrates on anomalies detected in the data of an IGEX-98 station in Switzerland. Data collected at this station from September 1998 to December 1999 was analyized. In all, 19 anomalies were detected by the integrity monitoring software, 8 in GLONASS messages and 11 in GPS messages. The cause of the anomalies was established by evaluating the original data files, studying official bulletins of the GLONASS and GPS ground segments, and in some cases tracing the anomaly through the complete IGEX-98 network. © 2000 John Wiley & Sons, Inc.
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    GPS solutions 3 (2000), S. 1-3 
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: The NMEA GGA standard for global positioning system (GPS) and GLONASS receiver interfaces provides smooth data transfer from receiver to computer for postprocessing. Specifically, the NMEA GGA specifies that the orthometric height and the undulation be listed in addition to other quantities. The Ashtech manual (Ashtech, 1997; p. 104), however, specifies that the respective field in the NMEA GGA message contains the ellipsoidal height when outputting from Ashtech's GG24 receiver. Because such an inconsistency between the official NMEA GGA specifications and the implementation by a manufacturer can potentially confuse the user, we carried out a numerical test to confirm Ashtech's implentation. The result indicates that Ashtech indeed gives the ellipsoidal height in the fielt that should actually contain the orthometric height according to the NMEA GGA specifications. Firmware version after and including GF02 have corrected this situation. © 2000 John Wiley & Sons, Inc.
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    GPS solutions 3 (2000), S. 12-18 
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    Notes: In this article, analytic expressions are given for the minimal detectable biases (MDBs) of dual-frequency cross-correlated global positioning system (GPS) single difference code and carrier observations. They are given for three different short baseline models. (Short here implies that orbital and atmospheric uncertainties are assumed absent.) A comparison is made with the expressions for the MDBs of non-cross-correlating receivers. Finally, in order to get a better understanding of them, MDBs are visualized as a function of the parameters on which they depend, such as the number ob tracked satellites and the number of observation epochs. © 2000 John Wiley & Sons, Inc.
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    Notes: As technology matures, Real Time Kinematic (RTK) global positioning system (GPS) receivers are providing increased performance in accuracy, on-the-fly (OTF) initialization times, measurement speed, and latency. Leica's Dozer 2000 machine guidance system combines an MC1000 GPS sensor, graphic intensive guidance software, a digital terrain model, and a digital site plan. Figure 1 shows the operator's view of the system. The end results is a highly accurate, extremely responsive local navigation system. Engineers can easily upload design information onto a touch-screen machine guidance personal computer (PC) and greatly reduce earthmoving costs while simultaneously recording “as-built” inspection data. The Leica MC1000 machine control sensor is a true 10-Hz, centimeter-level-accuracy, open-architecture GPS sensor specifically designed for machine guidance and control. At the heart of the MC1000's performance are a very stable oven-controlled oscillator (3 × 10−11/s short-term stability), a low-power Intel 486-DX4-80 processor, and four user-configurable input/output (I7O) ports. Special algorithms mitigate the effects of multipath and Selective Availability (SA) while providing centimeter accuracy up to 10 times per second with only 30 milliseconds' latency. The high update rate and low latency are essential for machine guidance and control. The MC1000 GPS reference station is capable of outputting RTK and Differential GPS (DGPS) data simultaneously, providing and entire site with GPS information for machine guidance and control, tracking and dispatching of vehicles, and support of survey crews. This article describes how recent advances in technology have combined to produce the Leica Dozer 2000 – a machine guidance system that is ideal for a wide range of earthmoving and inspection applications. © 2000 John Wiley & Sons, Inc.
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    GPS solutions 3 (2000), S. 37-43 
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    GPS solutions 3 (2000), S. 19-25 
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    Notes: A global positioning system (GPS)-based online control and alarm system (GOCA) for monitoring of three-dimensional movements has been developed at the Karlsruhe University of Technology. The GOCA hardware consists of an array of GPS sensors and communication units to be placed in the monitoring area. The hardware-dependent control software communicates with the GPS sensors and provides the GPS baseline data and covariance information to the GOCA deformation analysis software. The GOCA center, which comprises both the control software and the GOCA software, may be linked – for example, over a long distance – to another personal computer (PC) that serves as a remote control station. GOCA is able to provide the full capabilities of classical deformation analysis online (with stations grouped into stable points and moving object points). Both types of points may be occupied either continuously or over short periods at different times. The object points are determined with respect to the stable points. A network adjustment is performed for each interval of data collection, and the coordinate and covariance information may optionally be transformed into a specific reference system (e. g., the building system). Unstable reference points are to be detected by statistical tests. The estimated object point time series are filtered with respect to gross errors using robust estimation techniques. Online filters are used to smooth the time series data of critical displacements and to predict other deformation functions. The time series data, as well as prediction results, are displayed graphically for each object point. An example concerning the online monitoring of a slag heap in a coal-mining area is included. © 2000 John Wiley & Sons, Inc.
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    GPS solutions 3 (2000), S. 26-36 
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    Notes: This article describes a single difference approach to estimate heading and pitch with a twin global positoning system (GPS)/GLONASS (GG) receiver system. Augmentation of GPS with GLONASS is not straightforward, however, because the latter system employs the frequency division multiple access technique to distinguish the signals form different satellites, rather than the code division multiple access technique used by GPS. The fact that each GLONASS signal has its own slightly different frequency makes the double difference (DD) of carrier phase observables no longer possible without modification. To get around this problem, the use of the between-receiver single difference (SD) of the carrier phase observables is proposed. In this case, however, receiver clock and other errors do not cancel out. The possibility of using a common external oscillator for the two receivers is explored. Remaining time and other biases are estimated using a low-pass averaging filter. The single difference integer ambiguities can then be resolved and the heading and pitch can be determined with a relatively good level of accuracy. Static and kinematic tests conducted with a pair of GPS/GLONASS receivers are used to validate the approach. Under reduced visibility, the combined GPS/GLONASS approach is shown to yield superior availability. © 2000 John Wiley & Sons, Inc.
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    GPS solutions 4 (2000), S. 45-47 
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    Notes: In June 1999, United States Space Command took formal steps to set up a support center for military and government Global Positioning System (GPS) users worldwide. The center was created to meet three main objectives: · Detect, analyze, report, and facilitate the resolution of GPS anomalies · Monitor and report GPS performance · Provide GPS status, constellation status, and tactical support This article is intended to provide a brief overview of the GPS Support Center (GSC), outlining its creation and products and services, and providing a more detailed discussion of its objectives. © 2000 John Wiley & Sons, Inc.
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    Notes: The Internet as a basis for Real-Time Kinematic (RTK) and differential Global Positioning System (DGPS) service provides many advantages for worldwide GPS users. Among these advantages are service unification, open architecture, bidirectional communication, and scalability. The current development of this service allows users to use RTK and DGPS through the Internet with conventional accuracy over the short and medium baselines. The perspective for this service lies in the field of wide-area augmentation systems (WASS). At this stage of the Internet-based RTK and DGPS service project, the general concept, system components, draft standards, and software are developed. © 2000 John Wiley & Sons, Inc.
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    GPS solutions 4 (2000), S. 56-66 
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    Notes: In this article, the architecture of a software Global Positioning System (GPS) receiver is described and an analysis is included of the performance of a software GPS receiver when tracking the GPS signals in challenging environments. Results are included that demonstrate the advantage of the software GPS receiver in tracking the GPS signals in low signal-to-noise or jamming scenarios. Various current and previous applications of the software GPS receiver are also described. © 2000 John Wiley & Sons, Inc.
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    GPS solutions 4 (2000), S. 67-71 
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    Notes: Unlike the conventional hardware approaches to GPS base band signal processing, a software GPS receiver is extremely flexible as it comes with all the associated advantages of a software solution. With a software solution, the improvements of silicon technology can be easily translated into better performance at smaller form factors and lower power consumption, without a redesign and/or change to the ASIC. A general purpose Digital Signal Processor (DSP) can be used effectively for GPS signal processing. The memory and speed resources available determine the algorithms and applications that can be effectively implemented in the receiver. The performance of software GPS receivers will soon be difficult to be surpassed by the hardware counterparts, as high-performance processors become available at low cost. © 2000 John Wiley & Sons, Inc.
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    GPS solutions 4 (2000), S. 63-67 
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    Notes: This paper presents the current progress of the River Level Monitoring using GPS Heighting (RiGHt) project. The aim of the project is to develop an integrated system to allow the continuous monitoring of river heights using a buoy equipped with Global Positioning System (GPS) and satellite communications and using Geographical Information System (GIS) techniques. © 2000 John Wiley & Sons, Inc.
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    GPS solutions 4 (2000), S. 54-62 
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    Notes: Kinematic differential Global Positioning System (DGPS) positioning is routinely used in industry for directly observing an aircraft's position at each instant of photographic exposure during a photogammetric survey. A critical aspect of the subsequent data processing is estimation of the aircraft position at the exact time of exposure. GPS measurements are acquired at a uniform sampling rate, typically 1 Hz. The exposure times, however, do not generally coincide with these times. As a result, the exposure station positions must be interpolated from the adjacent GPS positions. This is typically done using a low-order polynomial, expressed as a function of time, for each coordinate dimension. However, trajectory perturbations induced by atmospheric turbulence can render such interpolation methods ineffective. This article will convey the results of an investigation into the use of several different interpolation models with airborne GPS data during straight, level flight. The fundamental task of time series reconstruction will first be addressed, in which several possible interpolation models are described. Two 10-Hz, airborne GPS data sets were collected to test the accuracy of each model. The error properties resulting from the application of each model to these data will be presented and analyzed in terms of time-domain statistics and frequency-domain characteristids. It will be demonstrated that interpolation error can be significantly reduced, especially in the height dimension, through judicious choice of an interpolator. © 2000 John Wiley & Sons, Inc.
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    GPS solutions 4 (2000), S. 76-77 
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    GPS solutions 4 (2000), S. 68-75 
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    Notes: In recent years the importance of real-time positioning and navigation with the Global Positioning System (GPS) has grown rapidly. Starting from the establishment of differential GPS (DGPS) reference stations for marine and land navigation, new users and applications have emerged that resulted in a high demand for the establishment of a high-density network of reference stations around the world. Many countries have established their own DGPS service, which is either governmentally or commercially owned. These services are referred to as Local Area DGPS Systems (LADGPS). However, the costs for the establishment and maintenance of a dense network of reference stations are very high. Therefore Wide Area DGPS Systems (WADGPS) are being developed to overcome the main drawbacks of LADGPS. In this case, only a few reference stations are used to cover a large area, such s a continent like Europe. To achieve high positioning accuracies, real-time modeling of the main error sources for long-range baselines is required as errors in the satellite orbit and ionospheric refraction do not cancel entirely in double differencing. In this article, a real-time correction model based on the Kalman filter for WADGPS and networked LADGPS services is discussed and results of field tests in a WADGPS network in Europe are presented. © 2000 John Wiley & Sons, Inc.
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    GPS solutions 4 (2000), S. 83-83 
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    GPS solutions 4 (2000), S. 84-86 
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    Stochastic environmental research and risk assessment 14 (2000), S. 109-122 
    ISSN: 1436-3259
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    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering , Geography , Geosciences
    Notes: Abstract. We consider the problem of upscaling transient real gas flow through heterogeneous bounded reservoirs. One of the commonly used methods for deriving effective permeabilities is based on stochastic averaging of nonlinear flow equations. Such an approach, however, would require rather restrictive assumptions about pressure-dependent coefficients. Instead, we use Kirchhoff transformation to linearize the governing stochastic equations prior to their averaging. The linearized problem is similar to that used in stochastic analysis of groundwater flow. We discuss the effects of temporal localization of the nonlocal averaged Darcy's law, as well as boundary effects, on the upscaled gas permeability. Extension of the results obtained by means of small perturbation analysis to highly heterogeneous porous formations is also discussed.
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    Stochastic environmental research and risk assessment 14 (2000), S. 139-158 
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    Keywords: Key words: Confluent hypergeometric, generalised inverse Gaussian, Halphen system of distributions, modified Bessel, randomisation, simulation, sufficient statistics.
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    Notes: Abstract. Some of the considerable statistical content of modified Bessel functions of the second kind and of Tricomi's confluent hypergeometric function is illustrated. Moment solutions for the parameters of exponential class distribution functions based on both are derived. Unlike the generalised inverse Gaussian, the Tricomi exponential distribution is little known but it emerges that it is of wide applicability, highly flexible and has the gamma distribution as a special case.
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    Stochastic environmental research and risk assessment 14 (2000), S. 159-160 
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    Stochastic environmental research and risk assessment 14 (2000), S. 173-179 
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    Notes: Abstract.  The use of complicated models of the cancer process has been limited by the need to have a mathematical framework allowing for a general expansion of the theory of carcinogenesis while maintaining numerically tractable results. A system of ordinary differential equations is derived for calculating tumor incidence in multistage models of carcinogenesis. The resulting system of equations is applicable to nonhomogenous processes (i.e. ones in which the rates change with time, age, etc.). In addition, a solution is given for the case of instantaneous initiation. These formulae can easily be coupled with physiologically-based pharmacokinetic models to link biomarkers of exposure to cancer risks. An example is presented.
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    Polymer bulletin 45 (2000), S. 45-52 
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Redox behaviour of 2-allylphenol (2APhOH) was studied by using cyclic voltammetry (CV) and electroinitiated polymerization was conducted at the measured peak potentials. Constant potential electrolysis (CPE) of the monomer was carried out in acetonitrile-sodium perchlorate, solvent-electrolyte couple, at room temperature. Polymerization of the monomer yielded insoluble polymer films on the surface of the electrode together with the low molecular weight polymers in the bulk of the solution. The structural analysis of the polymers were carried by 1H-NMR and FTIR spectroscopy. Molecular weight of the soluble polymer was determined by GPC. Thermal properties of the polymer film and soluble polymer were studied by DSC. The course of electroinitiated polymerization was monitored by in-situ UV-VIS spectroscopy.
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    Polymer bulletin 45 (2000), S. 61-68 
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    Notes: Summary The synthesis and solution-state NMR investigation of the structure of a novel type of water-soluble polyaniline (PANI) derivative in leucoemeraldine and emeraldine oxidation states is presented. Copolymers of 3-aminobenzenesulfonic acid and 2-methoxyaniline (PMAOMA) with various monomer molar ratios were synthesized by chemical polymerization in a hydrochloric acid medium. Due to a large difference in the reactivities of 2-methoxyaniline (OMA) and 3-aminobenzenesulfonic acid (MA), the content of OMA in the copolymers was much higher (over 0.65 of the mole fraction) than in the reaction mixture. Structural characterization of the reaction products was performed using one- (1H, 13C) and two-dimensional (GHSQC and GCOSY) NMR spectroscopy. The NMR data indicated an almost block structure of OMA sequences of variable length separated by shorter sequences of MA units. It was also shown that the incorporation of MA units in the copolymer chains favors the formation of a less oxidized material.
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    Notes: Summary An attempt was made in this study to relate the releases of water soluble herbicide (sodium 2,2 dichloropropionate (Dowpon)) and model fertilizers (ammonium nitrate, potassium nitrate and ammonium sulfate) from the cylindrical devices of radiation crosslinked poly(acrylamide/itaconic acid) (AAm/IA) copolymers with the swelling that may effect the release behaviour. AAm/IA copolymers containing agrochemicals are prepared by two different composition of itaconic acid and two different γ-rays doses. The agrochemicals were trapped in the gels by including it in the feed mixture of radiation polymerization. The equilibrium swelling, diffusional exponent, and diffusion and intrinsic diffusion coefficients of the process were obtained. The agrochemical dissolution was determined by conductimetric method. The maximum concentrations of releasing agrochemicals and initial releasing rates were calculated by using of second order kinetics equation. The agrochemical releases appeared to be controlled by swelling. As a result, if AAm/IA hydrogels containing agrochemicals were swelled in water, release of agrochemicals was decreased with the raising of γ-rays doses and itaconic acid quantities in the hydrogel.
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    Polymer bulletin 45 (2000), S. 303-310 
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    Notes: Summary Constitutive equations are developed for the kinetics of enthalpy relaxation in polymeric glasses. An amorphous polymer is treated as an ensemble of cooperatively rearranged regions (CRR). Rearrangement of a CRR is modeled as a hop from one potential well on the energy landscape to another. The probability for changing traps in a hop is determined by the difference between the current and equilibrium concentrations of CRRs. A nonlinear parabolic equation is derived for the distribution function of CRRs. It is applied to predict entropy recovery after a thermal jump. Fair agreement is demonstrated between results of numerical simulation and experimental data for poly(vinyl acetate) and poly(methyl methacrylate) in the vicinity of the glass transition temperature.
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    Notes: Summary We describe here the synthesis of a new tin chelate Sn(C6H5O3)2.2H2O. The catalytic performance of this chelate is shown for polyesterification reactions involving terephthalic acid and poliols, such as neopentylglygol and trimetilolpropane. The complex is highly active for low molecular weight (Mn= 1700 and Mw= 4500) polymer formation. IR spectra also show free OH in the polymer chain.
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    Notes: Summary New dianhydrides having alkyloxy side chains were synthesized and polymerized with 4,4'-oxydianiline in NMP. Chemically cyclized polyimides were obtained with inherent viscosities of 0.30∼0.84 dL/g range. All the polymers were highly soluble in polar solvent such as NMP at room temperature. TGA pyrograms showed two-step degradation and in DSC thermograms the polymers exhibited Tgs between 124°C and 259°C. Wide-angle X-ray diffractograms revealed very low crystallinity and layered structure, which was better developed in the polymers with longer side chains
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    Polymer bulletin 45 (2000), S. 319-326 
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    Notes: Summary New AB2 and A2B monomers, bis(4-fluorophenyl)-4'-hydroxyphenylphosphine oxide and bis(4-hydroxyphenyl)-4'-fluorophenyl-phosphine oxide were prepared and converted to corresponding hyperbranched poly(arylene ether phosphineoxide)s with hydroxyphenyl and fluorophenyl end functional groups. While the dihydroxy monomer gave a low molecular weight polymer, the difluoro monomer produced a high molecular weight hyperbranched polymer. The glass transition temperature of the obtained polymers was 266°C and 230°C, and 5% weight loss temperature was 491 °C and 391 °C, respectively. The fluorophenyl-terminated hyperbranched polymer was soluble in CHCl3, but the hydroxyphenyl-terminated polymer was not soluble in CHCl3 even though it has lower molecular weight than the fluorophenyl-terminated polymer, indicating that properties of the hyperbranched polymers markedly depend on end functional groups as well as their molecular weight.
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    Notes: Summary Enantiomeric diblock and triblock copolymers from caprolactone and lactide with various compositions were synthesized using alcohol/tin octoate as initiator system. Stereocomplexes were formed between pairs of enantiomeric block copolymers and their thermal properties examined. The melting temperatures of the crystalline PCL and PLA phases are depending on the composition of block copolymers. A raise of approximately 55°C of the temperature of PLA phase is observed in the blends as a consequence of stereocomplex formation as well in diblock as in triblock copolymers.
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    Notes: Summary A new alcoholate of cyclopentadienyl metallocene with voluminous group as ligand substituting chlorine atoms and formula Cp2Hf(OMAd)2 (where Cp = cyclopentadienyl and OMAd = derived of 2-methyl-2-adamantol) was synthesized and employed as catalyst for olefin polymerization. The compound was evaluated in ethylene polymerization activated by methylaluminoxane (MAO) using several experimental conditions. These conditions were determined by a statistic method, and a model for dependent variables like catalyst activity and average molecular weight of polymers were developed. The hafnocene alcoholate produced polyethylenes with molecular weights in the same range of the corresponding metallocene dichloride. The new catalyst system showed high stability under temperature of 100°C. In the presence of H2 as molecular weight controlling agent, the catalyst showed a maximum of activity in the concentration range used.
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    Notes: Summary The time dependent order parameter concept of the glass transition is used in a description of the relaxation behaviour of the glassforming material. The connection between the macroscopic theory and the measured glass transition temperature has been determined. It has been found that in a case when the Prigogine-Defay ratio is greater than unity, different values of the relaxation functions of entropy and volume obtained by different experiments (e.g., isobaric dilatometry and isothermal compression) should be used in order to obtain the identical Tg. The Prigogine-Defay ratio is found to be a decreasing function of the observation time reaching values between unity in the limit of infinite time and a limit which corresponds to extremely short experiments.
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    Notes: Summary An instrument for High Performance Liquid Chromatography (HPLC) was modified by relatively simple means for working in the field of Supercritical Fluid Chromatography (SFC). By use of this modified apparatus three different gradient methods were tried with respect to their applicability for the analytical separation of oligomers. Especially by using a gradient in eluent composition or by a pressure gradient good resolution could be obtained.
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    Polymer bulletin 5 (1981), S. 643-649 
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    Notes: Summary α,ω-p-Toluensulphonic acid ester of poly(ethyleneglycoladipate) was synthesized and used to initiate the cationic isomerization polymerization of 2-phenyl-2-oxazoline, 2-(β-N-Carbazolylethyl)-2-oxazoline and 2-(3,5-dinitrophenyl)-2-oxazoline. ABA triblock copolymers containing poly(N-benzoylethylenimine), poly [N-β(N-carbazolyl)propionyl ethyleneimine] or poly(3,5-dinitrobenzoylethylenimine) blocks (A block) and poly (ethyleneglycoladipate) blocks (B block) have been synthesized.
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    Polymer bulletin 5 (1981), S. 635-641 
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    Notes: Summary The influence of various nucleating agents on the crystallization parameters of polybutene-1 is reported. Isothermal crystallization is investigated by differential scanning calorimetry. The morphology induced by the differents nucleating agents has been observed by hot stage polarizing microscopy. It has been stated that the addition of nucleating agent affects the crystallization rate, dimension and homogeneity of spherulitic sizes. The induction time ti, the semicrystallization time t1/2, the crystallization rate constant K, and the Avrami coefficient n were measured and related to the different characteristics of the specimens. Because of the fractional values of n obtained in this study, it is not possible to propose well determined mechanisms of crystallization.
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    Polymer bulletin 5 (1981), S. 667-672 
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    Notes: Summary Broad line NMR spectra have been measured at room temperature of the binary system Arkopal (C9H19C6H4O(CH2CH2O)15H) -heavy water (40 % to 60 % by weight) and of the ternary systems Arkopal — heavy water — paraffin at different paraffin concentrations at constant Arkopal — heavy water ratio. It has been established how the additives change the lyotropic phases.
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    Polymer bulletin 5 (1981), S. 61-66 
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    Notes: Summary Investigations carried out in plasma-induced polymerization (copolymerization) led to the idea of the existence of “living” macroradicals. Their presence in both homogeneous and heterogeneous media was experimentally proved and theoretically explained and their use as macromolecular initiators in polymerization processes is exemplified.
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  • 63
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    Notes: Summary Critical interpretation of the various conceptions concerning the problems in characterization of linear polyelectrolyte type polymers containing maleic acid as a comonomer is given. Proper conditions to avoid the fundamental experimental difficulties are proposed. Our conception is supported by molecular light scattering measurements of hydrolysed, fractionated poly (N-vinylpyrrolidone-co-maleic anhydride) samples. It was found that the problems were eliminated by the reduction of the degree of dissociation of carboxyl groups to a minimum value.
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    Polymer bulletin 5 (1981), S. 67-74 
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    Notes: Summary The relation proposed between the preferential adsorption coefficient, λ, and the intrinsic viscosity, ¦η¦ λ¦η¦=λ∞¦η¦+AKθ has been applied in this paper to previously published data. This equation is found to be valid in theta condi tions and far away from them. The obtained results are compared to the ones calculated with the Dondos-Benoit equation.
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    Polymer bulletin 5 (1981), S. 81-86 
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    Notes: Summary This paper describes the acid and enzymic hydrolysis of Kappa carrageenan and the gel permeation chromatography of the charged oligosaccharides.
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  • 66
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    Polymer bulletin 5 (1981), S. 75-80 
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    Notes: Summary On the basis of experimental data for blends of polyethylene with different polymers an empirical equation is proposed to describe the dependence of melt viscosity of blends on component viscosities and composition. The model ensures the continuity of viscosity vs. composition curves throughout the whole composition range, the possibility of obtaining extremum values higher or lower than the viscosities of components, allows the calculation of flow curves of blends from the flow curves of components and their volume fractions.
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  • 67
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    Notes: Summary Starch copolymers with polyacrylonitrile grafts were prepared using the Mn3+ initiation method and different amounts of acrylonitrile. The product was hydrolyzed in aqueous alkali (nitrile groups to amide and carboxyl groups) to enhance the hydrophilic character of the copolymer and achieve “superabsorbent properties”. At relative humidities (RH) up to 95–97 % the modified starch shows “normal” water vapor absorption like cellulose and other polysaccharides. When in contact with liquid distilled water, the modified starch forms a “superabsorbent” gel which retains very large amounts of water (up to 800 g/g). At low and high pH and in aqueous salt solutions (NaCl, CaCl2 and synthetic urine) the water retention is strongly reduced. This is interpreted as due to the ionic strength (salt effect) and for Ca2+ ions probably also crosslinking by salt formation with carboxyl groups on adjacent chains or chain segments.
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  • 68
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    Polymer bulletin 5 (1981), S. 95-101 
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    Notes: Summary It is shown that the inverse velocity of a fallingball in, or ηm the apparent minimum viscosity of, anisotropic solutions of poly(n-hexylisocyanate) in toluene, are molecular weight dependent. The molecular weight dependence follows two linear branches. Below Mw=42600 the apparent minimum viscosity is very weakly dependent on Mw. Above Mw=42600 the apparent minimum viscosity of the anisotropic solution is strongly dependent on the molecular weight.
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  • 69
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    Polymer bulletin 5 (1981), S. 111-116 
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    Notes: Summary Sulfinate functional groups have been introduced on selected positions of the aromatic rings of soluble or crosslinked polystyrene via lithiation reactions followed by quenching with sulfur dioxide. The sulfinate polymers have good stability, can be stored at room temperature, and can be used for ion-exchange or as nucleophiles to produce polymer-bound sulfones. Good functional yields of polystyrene resins with sulfone pendant groups can be obtained by reaction of the polymeric sulfinates with various alkyl halides under phase transfer or classical conditions.
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    Polymer bulletin 5 (1981), S. 103-110 
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    Notes: Summary Kinetic studies of crosslinking vinyl polymerizations are usually only applicable to the initial stages of the reaction, prior to the gel point, due to the subsequent insolubility of the polymer and the great increase in viscosity. We have demonstrated the suitability of laser Raman spectroscopy for quantitative analysis over the entire conversion range in an investigation of the polymerization of diethylene glycol bis (allyl carbonate) in bulk, with benzoyl peroxide initiation, between 70 and 85°C. The rate of consumption of vinyl bonds could be approximated by first-order kinetics up to ca. 80% depletion. Lower rates were observed at higher conversions.
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    Polymer bulletin 5 (1981), S. 117-117 
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    Polymer bulletin 5 (1981), S. 151-157 
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    Notes: Summary Based on a reconsideration of the packing conditions in amorphous polymers, a modification of the statistical theory of rubber elasticity is derived. The main assumption is, that the mean square end-to-end distance of a free chain in the bulk state depends on the dimensions of the surrounding chains. The theory describes quite well the deformation behaviour of real elastomeric networks.
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    Polymer bulletin 5 (1981), S. 131-135 
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    Notes: Summary Cyclotetracosane exhibits complex phase behaviour in the solid state as well as in the melt as evidenced by complementary methods, DSC, BRILLOUIN scattering, dielectric constant and PE-MAS 13c-NMR. Three solid phases have been verified, one of them — within the range from 299.5 to 312 K — exhibits extremely high molecular mobility. Between the start of melting, 312 K, and the first order transition at ∼ 321 K a mesomorphic type region develops. Two additional transitions have been detected in the melt. That occuring at 361 K (DSC), 356 K (BRILLOUIN data) resembles the Tu as observed in n-alkanes.
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    Polymer bulletin 5 (1981), S. 159-166 
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    Notes: Summary Monomeric Bis-(4-hydroxybutyl) terephthalate has been synthesized and characterized. Titanium iso-propoxide has been found to be a superior catalyst for transesterification compared to metal acetates. Further polycondensation of Bis (HBT) yields poly (1,4-butylene terephthalate). The effect of various titanium derived catalysts on the polycondensation of Bis (HBT) has been studied. The catalytic efficiency of these derivatives is ascribed to their relative hydrolytic stability and the degree of interaction between the carbonyl oxygen and the metal.
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    Polymer bulletin 5 (1981), S. 167-174 
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    Notes: Summary A radiochemical method was used to study PVC chlorination. A reaction mechanism was proposed based on the results obtained from chlorination of 36chlorine labeled PVC. A mechanism was proposed also for chain transfer reaction to polymer in vinyl chloride polymerization.
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    Polymer bulletin 5 (1981), S. 175-177 
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    Notes: Summary The longitudinal acoustic modes (LAM) of several cycloalkanes ((CH2)14 to (CH2)96) measured by Raman spectroscopy are described. The frequency differences between the LAMs of the cycloalkanes and the corresponding n-alkanes are explained by a simple linear chain model. It is shown that the LAM-modes are practically not affected by the gauche conformations of the two folds in the cyclic molecule.
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  • 77
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    Notes: Summary An analysis is made of a system of many interacting chains confined between a pair of surfaces which exert a short range attraction on the chains. The free energy of the system is determined from the partition functions of the confined chains which are, in turn, determined by solutions to the self consistent field form of the diffusion equation with mixed boundary conditions. The incorporation of the analysis into the ‘sandwich’ model of bulk polymers is discussed.
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    Polymer bulletin 5 (1981), S. 195-200 
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    Notes: Summary The permeation and separation characteristics of methanol/n-pentanol systems and n-propanol/n-heptane systems through nylon 12 membranes were studied by changing the feed composition of the binary organic mixtures. These characteristics were discussed from the viewpoints of physical and chemical nature of the permeating molecules and the membrane.
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    Polymer bulletin 5 (1981), S. 187-194 
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    Notes: Summary Random terephthalate copolyesters of ethylene glycol and butane-1,4-diol of various compositions were prepared by trans-esterification of poly(ethylene terephthalate) (PET) with butane-1,4-diol (BD). Proton nuclear magnetic resonance spectroscopy (NMR) was used to elucidate the structure and compositions of copolyesters. The thermal behaviour of the copolyesters were investigated by differential thermal analysis (DTA). Intrinsic viscosities were measured in orthochlorophenol at 30°C.
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    Polymer bulletin 5 (1981), S. 201-207 
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    Notes: Abstract This paper concerns the cationic modification of polystyrene by the electophilic substitution of polystyrene with S-methylthiocarbcxonium.The substitution is quantitative and gives poly p-(methylthio) carbonylstyrene. After hydrolysis and purification poly (p-carboxystyrene is obtained. The polymers are formed without degradation after this cationic modification.
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    Polymer bulletin 5 (1981), S. 255-261 
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    Notes: Summary 13C spin-lattice relaxation rates R1 in samples of solid PMMA have been measured with CP MAS NMR. Isotactic, atactic, syndiotactic, and the 1∶2 i-s PMMA complex were measured, along with atactic samples containing bisdioxan or the monomer as a plasticizer. The reorientation of the α-methyl protons is the dominant relaxation source for the methylene, α-methyl and quarternary carbon nuclei. Increased mobility of the polymer in the presence of a plasticizer is not reflected in significant changes in R1.
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  • 82
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    Notes: Summary Magnetic resonance techniques yield important information on different coordination behaviour of Mn(II) in the presence of biomacromolecules. A preliminary study on model systems is necessary to have a deeper insight on dynamics and structural aspects. The EPR technique is not able to identify a binding interaction between Trp and manganous ion when the metal is bonded to the Imidazole. Proton shift NMR studies on the Mn(II)-5′ATP-Imid complex evidenziate a ternary system formation and a stacking interaction between the imidazole-ring and the nucleotide purine-moiety. An EPR and NMR combined analysis on the Mn(II)-5′ATP-Trp system points out a stacking interaction and the simultaneous presence of a covalent binding between the metal ion and the biomolecules. The role of the metal ion to favour this coordination is suggested.
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    Polymer bulletin 5 (1981), S. 277-284 
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    Notes: Summary It is shown that the transverse magnetic component of protons bound to polystyrene chains in solutions is sensitive to the slow chain diffusion through entanglements. A theoretical interpretation of the dynamical polymer coil overlap observed by NMR is proposed.
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    Polymer bulletin 5 (1981), S. 271-275 
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    Notes: Summary Proton second moment and spin-lattice relaxation times T1, T1e and T1D for helical poly (ethylene oxide) 5000 over a wide temperature range are measured. The results of CW and pulse experiments corroborate the existence of a motional process in the crystalline region of the polymer interpreted as oscillation or rotation of molecules around their helical axes. The activation energy for this type of motion is found to be 12 kcal/mole.
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    Polymer bulletin 5 (1981), S. 285-289 
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    Notes: Summary Measurements of proton spin-lattice relaxation time T1 for thylakoid membranes of wheat chloroplast suspensions as a function of proton concentration in solvent are performed. The solvent was a mixture of H2O and D2O. Different contributions to the proton relaxation process due to dipolar interactions are considered. The dipolar interactions p-p′ and p-i between exchangeable protons /p/ of membrane of solvent and non-exchangeable ones of membrane /p′/ and paramagnetic ions /i/ give predominant contribution to the relaxation process.
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  • 86
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    Notes: Summary A cyclic phosphonite(1) was copolymerized with 4, 4′-diphenoquinones (2a–2c) to give 1∶1 alternating copolymers (3a–3c) consisting of a carboxylic acid ester and a triaryl phosphonate ester. Copolymerization took place without added initiator. During the reaction 1 was oxidized whereas 2 was reduced (“redox copolymerization”). A mechanism involving a genetic zwitterion intermediate (4) is proposed for the copolymerization.
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  • 87
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    Notes: Summary This paper reports new cationic ring-opening polymerization of a spirophosphorane, 5-phenyl-1, 4, 6, 9-tetraoxa-5-phosphaspiro (4, 4) nonane, 1. The polymerization of 1. was induced by cationic initiators such as methyl trifluoromethanesulfonate (MeOTf), BF3·OEt2, and Et3O+-BF4 − to give polymer 2 consisting of two different units, 2a and 2b. During the reaction cyclic phosphonate 3 and 1,4-dioxane were simultaneously produced. The formation of unit 2b is considered to be due mainly to the cationic ring-opening polymerization of 3.
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    Notes: Summary Well-defined graftcopolymers were prepared by radical copolymerization of methyl methacrylate macromonomer with perfluoroalkyl acrylate. Contact angle of the solvent cast films of poly(methyl methacrylate) containing various amount of the graftcopolymer was measured against water droplet. Addition of 0.2 wt% of the graftcopolymer was sufficient to improve the polymer films to water repellent surfaces, while 10 wt% was necessary to modify the polymer surfaces to the same level of water repellency.
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    Polymer bulletin 5 (1981), S. 347-354 
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    Notes: Summary We present the results of a calculation of the spin-lattice and spin-spin relaxation for dipolar solid when it is irradiated by the WAHUHA and MREV-8 pulse sequences. The spin-spin relaxation rate which is determined by the second-order dipolar interaction term of the average Hamiltonian depends on thermal motion of four atoms. It has been shown that from the temperature dependence of this relaxation rate the degree of correlated atomic motion can be estimated.
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    Polymer bulletin 5 (1981), S. 355-360 
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    Notes: Summary The decomposition of the solid-echo curves of crystalline polymers into the crystalline and the amorphous component is discussed. The crystalline component is experimentally determined by using a special method of measurement. The amorphous component is assumed to correspond to a distribution of correlation times.
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    Polymer bulletin 5 (1981), S. 341-346 
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    Notes: Summary Proton relaxation time measurements of chemical crosslinked polystyrenes swollen in protonated and deuterated benzene have been done in order to get informations on the microdynamic behaviour of polystyrene as well as of benzene molecules under the influence of the polymeric network. By means of additional T1d-measurements further evidences for a slow anisotropic motion could be obtained, which cause a T2-“plateau” in the high temperature region. The results are compared with those of MAR-experiments.
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  • 92
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    Notes: Summary Dicarboxyl-terminated macromolecular monomers (macromonomers) were synthesized by radical polymerization of methyl methacrylate in the presence of thiomalic acid as a chain transfer agent. This macromonomer and sebacic acid were condensed with diamines (p,p′-diaminodiphenyl ether, p,p′-diaminodiphenylmethane and m-phenylenediamine) by triphenylphosphitepyridine system. Thus, graft copolyamides of well-defined structure and composition were readily prepared. This is the first example of the polycondensation reactions of macromonomers.
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    Polymer bulletin 5 (1981), S. 367-372 
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    Notes: Summary The 1H-NMR-spectra of raw poly (vinyl chloride) obtained at atmospheric pressure (U-PVC) have revealed the presence of high concentrations of branches. The content of labile chlorine was determined by reaction with phenole in order to estimate the branch points with tertiary chlorine. The branch length of reductively dehalogenated U-PVC by13C-NMR analysis have provided evidence for both short chain branches including chloromethyl groups and 2.4-dichloro-n-butyl groups and long chain branching. For a number of U-polymers the total amount of branching ranges from 7.5 to 13.5/1000 C. The 13C-NMR measurements point to a ratio of methyl/butyl branches of 1 ∶ 1 and short chains/long chains of 6 ∶ 1 .
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    Polymer bulletin 5 (1981), S. 373-377 
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    Notes: Summary The membrane composed of gluconolactone-containing polymer was prepared by the following three steps, (1) the copolymerization between acrylonitrile and a styrene derivative carrying a protected glucose substituent, (2) casting a membrane from the DMF solution of the copolymer, and (3) a sequence of reactions for the membrane. It exhibited active transport of Na+ ion against the concentration gradient.
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    Polymer bulletin 5 (1981), S. 379-384 
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    Notes: Summary This paper concerns the synthesis and characterization of new Si-Cl and Si-H end-groups containing polyisobutylenes. The syntheses involved 1) The preparation of polyisobutylenes carrying one or two -CH2C-(CH3)=CH2 termini, ii) Hydrosilylation with H(CH3)2-SiCl, H(CH3)SiCl2, and HSiCl3, and iii) Reduction of the Si-Cl groups to yield the corresponding -Si-H termini. A series of model compounds mimicking the end-groups have been synthesized and employed for end-group characterization. These Si-Cl and Si-H containing mono- and difunctional polyisobutylenes may be useful intermediates for the preparation of block and graft copolymers or for the synthesis of various terminal functional groups.
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    Polymer bulletin 4 (1981), S. 83-87 
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    Notes: Summary The monomer, N-4'-fluorophenylmethacrylamide (FPMA) was polymerized for the first time using benzoyl peroxide as the initiator. The IR and NMR spectra of FPMA and the polymer, poly(N-4'-fluorophenylmethacrylamide) (PFPMA) are discussed. Viscosity measurements of PFPMA was carried out in dimethylformamide medium at 25°C. The number average molecular weight of PFPMA was determined to be 690 using vapour pressure osmometer. The formation of low molecular weight of PFPMA is explained on the basis of intermolecular hydrogen bonding in the monomer.
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    Polymer bulletin 4 (1981), S. 105-110 
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    Notes: Summary Constitutional and configurational structure of oligomers from poly (styrene) have been determined by joint liquid chromatography and C-13 nmr spectroscopy.
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    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary An increase in light scattering intensity was observed throughout the curing of diepoxides with amines. The value of such an increase depends on the chemical structure of the reagents and on the curing temperature. This phenomenon was explained by polycondensation reaction peculiarities and the glass state transition nature.
    Type of Medium: Electronic Resource
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  • 99
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 4 (1981), S. 133-139 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract For application as components in an adhesive layer in photographic movie-films, five copolymers of methylmethacrylate and butylacrylate each with a different multifunctional comonomer, have been synthetized. Depending on the copolymerizability of the multifunctional comonomers, adhesive layers with different mechanical properties were obtained. An approach towards an explanation for the diverging results from swelling and modulus measurements was worked out.
    Type of Medium: Electronic Resource
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  • 100
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary If styrene-divinylbenzene copolymerization is performed at certain conditions of network formation, regions of relative high segmental density may occur. The segmental density can be monitored directly by the microstructure sensitive fluorescence polarization method. Measurements were made in the pre- and post-gel state at various degrees of conversion depending on the initial composition of the reaction mixture. The results, particularly in situations of high crosslinker content support the currently used models of network formation mechanisms during crosslinking copolymerization.
    Type of Medium: Electronic Resource
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