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  • Chemistry  (9,463)
  • Inorganic Chemistry  (1,632)
  • 42.75
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  • 201
    Publication Date: 2017-12-01
    Description: Deuterium- and tritium-labeled pharmaceutical compounds are pivotal diagnostic tools in drug discovery research, providing vital information about the biological fate of drugs and drug metabolites. Herein we demonstrate that a photoredox-mediated hydrogen atom transfer protocol can efficiently and selectively install deuterium (D) and tritium (T) at α-amino sp 3 carbon-hydrogen bonds in a single step, using isotopically labeled water (D 2 O or T 2 O) as the source of hydrogen isotope. In this context, we also report a convenient synthesis of T 2 O from T 2 , providing access to high-specific-activity T 2 O. This protocol has been successfully applied to the high incorporation of deuterium and tritium in 18 drug molecules, which meet the requirements for use in ligand-binding assays and absorption, distribution, metabolism, and excretion studies.
    Keywords: Chemistry
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  • 202
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-10-27
    Keywords: Chemistry
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  • 203
    Publication Date: 2017-11-03
    Description: The irradiation of gold nanorod colloids with a femtosecond laser can be tuned to induce controlled nanorod reshaping, yielding colloids with exceptionally narrow localized surface plasmon resonance bands. The process relies on a regime characterized by a gentle multishot reduction of the aspect ratio, whereas the rod shape and volume are barely affected. Successful reshaping can only occur within a narrow window of the heat dissipation rate: Low cooling rates lead to drastic morphological changes, and fast cooling has nearly no effect. Hence, a delicate balance must be achieved between irradiation fluence and surface density of the surfactant on the nanorods. This perfection process is appealing because it provides a simple, fast, reproducible, and scalable route toward gold nanorods with an optical response of exceptional quality, near the theoretical limit.
    Keywords: Chemistry
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  • 204
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-11-03
    Keywords: Chemistry
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  • 205
    Publication Date: 2017-10-27
    Description: Whereas standard transmission electron microscopy studies are unable to preserve the native state of chemically reactive and beam-sensitive battery materials after operation, such materials remain pristine at cryogenic conditions. It is then possible to atomically resolve individual lithium metal atoms and their interface with the solid electrolyte interphase (SEI). We observe that dendrites in carbonate-based electrolytes grow along the 〈111〉 (preferred), 〈110〉, or 〈211〉 directions as faceted, single-crystalline nanowires. These growth directions can change at kinks with no observable crystallographic defect. Furthermore, we reveal distinct SEI nanostructures formed in different electrolytes.
    Keywords: Chemistry
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  • 206
    Publication Date: 2017-05-12
    Description: Nanostructured materials have shown extraordinary promise for electrochemical energy storage but are usually limited to electrodes with rather low mass loading (~1 milligram per square centimeter) because of the increasing ion diffusion limitations in thicker electrodes. We report the design of a three-dimensional (3D) holey-graphene/niobia (Nb 2 O 5 ) composite for ultrahigh-rate energy storage at practical levels of mass loading (〉10 milligrams per square centimeter). The highly interconnected graphene network in the 3D architecture provides excellent electron transport properties, and its hierarchical porous structure facilitates rapid ion transport. By systematically tailoring the porosity in the holey graphene backbone, charge transport in the composite architecture is optimized to deliver high areal capacity and high-rate capability at high mass loading, which represents a critical step forward toward practical applications.
    Keywords: Chemistry
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  • 207
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-05-12
    Keywords: Chemistry
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  • 208
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-05-12
    Keywords: Chemistry
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  • 209
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-04-21
    Keywords: Chemistry
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  • 210
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-04-28
    Keywords: Chemistry
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  • 211
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-04-28
    Keywords: Chemistry
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  • 212
    Publication Date: 2017-04-28
    Description: The next generation of high-performance batteries should include alternative chemistries that are inherently safer to operate than nonaqueous lithium-based batteries. Aqueous zinc-based batteries can answer that challenge because monolithic zinc sponge anodes can be cycled in nickel–zinc alkaline cells hundreds to thousands of times without undergoing passivation or macroscale dendrite formation. We demonstrate that the three-dimensional (3D) zinc form-factor elevates the performance of nickel–zinc alkaline cells in three fields of use: (i) 〉90% theoretical depth of discharge (DOD Zn ) in primary (single-use) cells, (ii) 〉100 high-rate cycles at 40% DOD Zn at lithium-ion–commensurate specific energy, and (iii) the tens of thousands of power-demanding duty cycles required for start-stop microhybrid vehicles.
    Keywords: Chemistry
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  • 213
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-04-21
    Keywords: Chemistry
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  • 214
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-04-21
    Keywords: Chemistry
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  • 215
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-04-21
    Description: Methane undergoes highly facile C–H bond cleavage on the stoichiometric IrO 2 (110) surface. From temperature-programmed reaction spectroscopy experiments, we found that methane molecularly adsorbed as a strongly bound complex on IrO 2 (110) and that a large fraction of the adsorbed complexes underwent C–H bond cleavage at temperatures as low as 150 kelvin (K). The initial dissociation probability of methane on IrO 2 (110) decreased from 80 to 20% with increasing surface temperature from 175 to 300 K. We estimate that the activation energy for methane C–H bond cleavage is 9.5 kilojoule per mole (kJ/mol) lower than the binding energy of the adsorbed precursor on IrO 2 (110), and equal to a value of ~28.5 kJ/mol. Low-temperature activation may avoid unwanted side reactions in the development of catalytic processes to selectively convert methane to value-added products.
    Keywords: Chemistry
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  • 216
    Publication Date: 2017-04-21
    Description: Real-time tracking of the three-dimensional (3D) evolution of colloidal nanoparticles in solution is essential for understanding complex mechanisms involved in nanoparticle growth and transformation. We used time-resolved small-angle and wide-angle x-ray scattering simultaneously to monitor oxidation of highly uniform colloidal iron nanoparticles, enabling the reconstruction of intermediate 3D morphologies of the nanoparticles with a spatial resolution of ~ 5 angstroms. The in situ observations, combined with large-scale reactive molecular dynamics simulations, reveal the details of the transformation from solid metal nanoparticles to hollow metal oxide nanoshells via a nanoscale Kirkendall process—for example, coalescence of voids as they grow and reversal of mass diffusion direction depending on crystallinity. Our results highlight the complex interplay between defect chemistry and defect dynamics in determining nanoparticle transformation and formation.
    Keywords: Chemistry
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  • 217
    Publication Date: 2017-04-28
    Description: The catalytic stereoselective synthesis of compounds with chiral phosphorus centers remains an unsolved problem. State-of-the-art methods rely on resolution or stoichiometric chiral auxiliaries. Phosphoramidate prodrugs are a critical component of pronucleotide (ProTide) therapies used in the treatment of viral disease and cancer. Here we describe the development of a catalytic stereoselective method for the installation of phosphorus-stereogenic phosphoramidates to nucleosides through a dynamic stereoselective process. Detailed mechanistic studies and computational modeling led to the rational design of a multifunctional catalyst that enables stereoselectivity as high as 99:1.
    Keywords: Chemistry
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  • 218
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-05-05
    Description: Medvedev et al . (Reports, 6 January 2017, p. 49) argue that recent density functionals stray from the path toward exactness. This conclusion rests on very compact 1s 2 and 1s 2 2s 2 systems favored by the Hartree-Fock picture. Comparison to actual energies for the same systems indicates that the "straying" is not chemically relevant and is at best specific to the studied dense systems.
    Keywords: Chemistry
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  • 219
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-05-05
    Keywords: Chemistry
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  • 220
    Publication Date: 2017-05-05
    Description: Direct functionalization of methane in natural gas remains a key challenge. We present a direct stepwise method for converting methane into methanol with high selectivity (~97%) over a copper-containing zeolite, based on partial oxidation with water. The activation in helium at 673 kelvin (K), followed by consecutive catalyst exposures to 7 bars of methane and then water at 473 K, consistently produced 0.204 mole of CH 3 OH per mole of copper in zeolite. Isotopic labeling confirmed water as the source of oxygen to regenerate the zeolite active centers and renders methanol desorption energetically favorable. On the basis of in situ x-ray absorption spectroscopy, infrared spectroscopy, and density functional theory calculations, we propose a mechanism involving methane oxidation at Cu II oxide active centers, followed by Cu I reoxidation by water with concurrent formation of hydrogen.
    Keywords: Chemistry
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  • 221
    Publication Date: 2017-05-05
    Description: Kepp argues in his Comment, among other concerns, that the atomic densities we have considered are not relevant to molecular bonding. However, this does not change the main conclusion of our study, that unconstrained fitting of flexible functional forms can make a density functional more interpolative but less widely predictive.
    Keywords: Chemistry
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  • 222
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-02-10
    Description: Author: Jake Yeston
    Keywords: Inorganic Chemistry
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  • 223
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-04-15
    Keywords: Chemistry
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  • 224
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-04-15
    Keywords: Chemistry
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  • 225
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-04-15
    Keywords: Chemistry
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  • 226
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-04-15
    Description: The synthesis of a carbon nanobelt, comprising a closed loop of fully fused edge-sharing benzene rings, has been an elusive goal in organic chemistry for more than 60 years. Here we report the synthesis of one such compound through iterative Wittig reactions followed by a nickel-mediated aryl-aryl coupling reaction. The cylindrical shape of its belt structure was confirmed by x-ray crystallography, and its fundamental optoelectronic properties were elucidated by ultraviolet-visible absorption, fluorescence, and Raman spectroscopic studies, as well as theoretical calculations. This molecule could potentially serve as a seed for the preparation of structurally well-defined carbon nanotubes.
    Keywords: Chemistry
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  • 227
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-01-06
    Description: Computational modeling of molecules and materials is now an essential part of the scientific endeavor in chemistry, physics, and biology. A widely used methods is density functional theory (DFT), which provides energies and electron densities of molecular systems in a computationally tractable manner. However, as Medvedev et al. show on page 49 of this issue (1), recent developments in DFT have improved the energies while not always concurrently improving the electron densities, suggesting a departure from the theoretical principles underlying DFT. Author: Sharon Hammes-Schiffer
    Keywords: Chemistry
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  • 228
    Publication Date: 2017-01-07
    Description: We investigated post-seismic velocity changes within the fault zone of the 2008 M 7.9 Wenchuan earthquake using coda wave data of repeating small earthquakes. We employed template matching and grid search methods to identify well-defined repeating earthquakes in order to minimize artefacts induced by variations in source location. We identified a total of 12 isolated patches in the fault zone that ruptured more than twice in a 1 yr period after the M 7.9 earthquake. We applied the coda wave interferometry technique to the waveform data of the 34 identified repeating earthquakes to estimate velocity changes between the first and subsequent events in each cluster. We found that major post-seismic velocity changes occurred in the southwestern part of the rupture area, where the main rupture was initiated and characterized by thrust motion, while the Beichuan area in the northeastern part of the rupture zone appears to experience very little post-seismic velocity changes.
    Keywords: Seismology
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 229
    Publication Date: 2017-01-07
    Description: In this study, we demonstrate the feasibility of imaging broad-band (10–150 s) Rayleigh wave phase velocity maps on a continental scale using ambient noise tomography (ANT). We obtain broad-band Rayleigh waves from cross-correlations of ambient noise data between all station pairs of USArray and measure the dispersion curves from these cross-correlations at a period band of 10–150 s. The large-scale dense USArray enables us to obtain over 500 000 surface wave paths which cover the contiguous United States densely. Using these paths, we generate Rayleigh wave phase velocity maps at 10–150 s periods. Our phase velocity maps are similar to other reported phase velocity maps based on ambient noise data at short periods (〈50 s) and based on earthquake data at intermediate/long periods (50–90 s). This study extends ANT from short/intermediate periods (〈50 s) to long periods up to 150 s in a continental scale of the USA. These broad-band phase velocity maps from ANT can be used to construct 3-D lithospheric and asthenospheric velocity structures.
    Keywords: Seismology
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 230
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-01-27
    Description: Author: Jake Yeston
    Keywords: Inorganic Chemistry
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  • 231
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-03-03
    Description: Although methane is a volatile gas, it can be efficiently trapped in ice, which can then be readily set on fire. Beyond the curiosity of this “burning ice,” caged methane is of great importance as one of the world's largest natural gas resources (1). In these materials, known as clathrates, methane molecules are tightly bound in nanometer-sized, regularly interspaced cages. Other inorganic materials, such as the silica mineral chibaite, can similarly encapsulate methane and higher hydrocarbons (2). Simple organic compounds have also been found to trap various organic molecules upon crystallization (3). On page 931 of this issue, Lin et al. (4) show that bipyramidal gold nanocrystals can be programmed to assemble into colloidal crystals with structures that resemble those of molecular clathrates, but on a much higher length scale. Authors: Dipak Samanta, Rafal Klajn
    Keywords: Chemistry
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  • 232
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-10-20
    Keywords: Chemistry
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  • 233
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-10-20
    Keywords: Chemistry
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  • 234
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-10-20
    Keywords: Chemistry
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  • 235
    Publication Date: 2017-10-20
    Description: The development of base metal catalysts for the synthesis of pharmaceutically relevant compounds remains an important goal of chemical research. Here, we report that cobalt nanoparticles encapsulated by a graphitic shell are broadly effective reductive amination catalysts. Their convenient and practical preparation entailed template assembly of cobalt-diamine-dicarboxylic acid metal organic frameworks on carbon and subsequent pyrolysis under inert atmosphere. The resulting stable and reusable catalysts were active for synthesis of primary, secondary, tertiary, and N -methylamines (more than 140 examples). The reaction couples easily accessible carbonyl compounds (aldehydes and ketones) with ammonia, amines, or nitro compounds, and molecular hydrogen under industrially viable and scalable conditions, offering cost-effective access to numerous amines, amino acid derivatives, and more complex drug targets.
    Keywords: Chemistry
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  • 236
    Publication Date: 2017-10-20
    Description: Many biomolecular motors catalyze the hydrolysis of chemical fuels, such as adenosine triphosphate, and use the energy released to direct motion through information ratchet mechanisms. Here we describe chemically-driven artificial rotary and linear molecular motors that operate through a fundamentally different type of mechanism. The directional rotation of [2]- and [3]catenane rotary molecular motors and the transport of substrates away from equilibrium by a linear molecular pump are induced by acid-base oscillations. The changes simultaneously switch the binding site affinities and the labilities of barriers on the track, creating an energy ratchet. The linear and rotary molecular motors are driven by aliquots of a chemical fuel, trichloroacetic acid. A single fuel pulse generates 360° unidirectional rotation of up to 87% of crown ethers in a [2]catenane rotary motor.
    Keywords: Chemistry
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  • 237
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-10-20
    Description: In chain-growth polymerization, a chain grows continually to reach thousands of subunits. However, the real-time dynamics of chain growth remains unknown. Using magnetic tweezers, we visualized real-time polymer growth at the single-polymer level. Focusing on ring-opening metathesis polymerization, we found that the extension of a growing polymer under a pulling force does not increase continuously but exhibits wait-and-jump steps. These steps are attributable to the formation and unraveling of conformational entanglements from newly incorporated monomers, whose key features can be recapitulated with molecular dynamics simulations. The configurations of these entanglements appear to play a key role in determining the polymerization rates and the dispersion among individual polymers.
    Keywords: Chemistry
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  • 238
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-10-20
    Description: Measurement of vector correlations in molecular scattering is an indispensable tool for mapping out interaction potentials. In a coexpanded supersonic beam, we have studied the rotationally inelastic process wherein deuterium hydride (HD) ( v = 1, j = 2) collides with molecular deuterium (D 2 ) to form HD ( v = 1, j = 1), where v and j are the vibrational and rotational quantum numbers, respectively. HD ( v = 1, j = 2) was prepared by Stark-induced adiabatic Raman passage, with its bond axis aligned preferentially parallel or perpendicular to the lab-fixed relative velocity. The coexpansion brought the collision temperature down to 1 kelvin, restricting scattering to s and p partial waves. Scattering angular distributions showed a dramatic stereodynamic preference (~3:1) for perpendicular versus parallel alignment. The four-vector correlation measured between the initial and final velocities and the initial and final rotational angular momentum vectors of HD provides insight into the strong anisotropic forces present in the collision process.
    Keywords: Chemistry
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  • 239
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-06-30
    Keywords: Chemistry
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  • 240
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-07-14
    Keywords: Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 241
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-07-14
    Description: We present an approach to multidimensional high-throughput discovery of catalytic coupling reactions that integrates molecular design with automated analysis and interpretation of mass spectral data. We simultaneously assessed the reactivity of three pools of compounds that shared the same functional groups (halides, boronic acids, alkenes, and alkynes, among other groups) but carried inactive substituents having specifically designed differences in masses. The substituents were chosen such that the products from any class of reaction in multiple reaction sets would have unique differences in masses, thus allowing simultaneous identification of the products of all transformations in a set of reactants. In this way, we easily distinguished the products of new reactions from noise and known couplings. Using this method, we discovered an alkyne hydroallylation and a nickel-catalyzed variant of alkyne diarylation.
    Keywords: Chemistry
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  • 242
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-07-21
    Keywords: Chemistry
    Print ISSN: 0036-8075
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 243
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-07-21
    Keywords: Chemistry
    Print ISSN: 0036-8075
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 244
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-07-21
    Keywords: Chemistry
    Print ISSN: 0036-8075
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 245
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-03-25
    Description: A reassuring rule of thumb about earthquakes is breaking down. For decades, seismologists had assumed that individual faults—as well as isolated segments of longer faults—rupture independently of one another. That limits the maximum size of the potential earthquake that a fault zone can generate. But the magnitude-7.8 earthquake that struck New Zealand just after midnight on 14 November 2016—among the largest in the islands' modern history—has reduced that thinking to rubble. According to a new study, published online this week in Science, the heavy shaking in the Kaikoura quake was amassed by ruptures on at least 12 different faults, in some cases so far apart that they were thought to be immune to each other's influence. Author: Betsy Mason
    Keywords: Seismology
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  • 246
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-10-20
    Keywords: Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 247
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-10-20
    Keywords: Chemistry
    Print ISSN: 0036-8075
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 248
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-10-20
    Keywords: Chemistry
    Print ISSN: 0036-8075
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 249
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-10-20
    Keywords: Chemistry
    Print ISSN: 0036-8075
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 250
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-11-10
    Keywords: Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 251
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-11-10
    Keywords: Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 252
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-11-10
    Description: Small-molecule dual hydrogen-bond (H-bond) donors such as ureas, thioureas, squaramides, and guanidinium ions enjoy widespread use as effective catalysts for promoting a variety of enantioselective reactions. However, these catalysts are only weakly acidic and therefore require highly reactive electrophilic substrates to be effective. We introduce here a mode of catalytic activity with chiral H-bond donors that enables enantioselective reactions of relatively unreactive electrophiles. Squaramides are shown to interact with silyl triflates by binding the triflate counterion to form a stable, yet highly Lewis acidic, complex. The silyl triflate-chiral squaramide combination promotes the generation of oxocarbenium intermediates from acetal substrates at low temperatures. Enantioselectivity in nucleophile additions to the cationic intermediates is then controlled through a network of noncovalent interactions between the squaramide catalyst and the oxocarbenium triflate.
    Keywords: Chemistry
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  • 253
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-10-20
    Keywords: Chemistry
    Print ISSN: 0036-8075
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 254
    Publication Date: 2017-10-20
    Description: Vinylidene-acetylene isomerization is the prototypical example of a 1,2-hydrogen shift, one of the most important classes of isomerization reactions in organic chemistry. This reaction was investigated with quantum state specificity by high-resolution photoelectron spectroscopy of the vinylidene anions H 2 CC and D 2 CC and quantum dynamics calculations. Peaks in the photoelectron spectra are considerably narrower than in previous work and reveal subtleties in the isomerization dynamics of neutral vinylidene, as well as vibronic coupling with an excited state of vinylidene. Comparison with theory permits assignment of most spectral features to eigenstates dominated by vinylidene character. However, excitation of the 6 in-plane rocking mode in H 2 CC results in appreciable tunneling-facilitated mixing with highly vibrationally excited states of acetylene, leading to broadening and/or spectral fine structure that is largely suppressed for analogous vibrational levels of D 2 CC.
    Keywords: Chemistry
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  • 255
    Publication Date: 2017-10-20
    Description: Gas transport through metal-organic framework membranes (MOFs) was switched in situ by applying an external electric field (E-field). The switching of gas permeation upon E-field polarization could be explained by the structural transformation of the zeolitic imidazolate framework ZIF-8 into polymorphs with more rigid lattices. Permeation measurements under a direct-current E-field poling of 500 volts per millimeter showed reversibly controlled switching of the ZIF-8 into polar polymorphs, which was confirmed by x-ray diffraction and ab initio calculations. The stiffening of the lattice causes a reduction in gas transport through the membrane and sharpens the molecular sieving capability. Dielectric spectroscopy, polarization, and deuterium nuclear magnetic resonance studies revealed low-frequency resonances of ZIF-8 that we attribute to lattice flexibility and linker movement. Upon E-field polarization, we observed a defibrillation of the different lattice motions.
    Keywords: Chemistry
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  • 256
    Publication Date: 2017-01-07
    Description: In finite-difference (FD) method, numerical dispersion is the dominant factor influencing the accuracy of seismic modelling. Various optimized FD schemes for scalar wave modelling have been proposed to reduce grid dispersion, while the optimized time–space domain FD schemes for elastic wave modelling have not been fully investigated yet. In this paper, an optimized FD scheme with Equivalent Staggered Grid (ESG) for elastic modelling has been developed. We start from the constant P - and S -wave speed elastic wave equations and then deduce analytical plane wave solutions in the wavenumber domain with eigenvalue decomposition method. Based on the elastic plane wave solutions, three new time–space domain dispersion relations of ESG elastic modelling are obtained, which are represented by three equations corresponding to P -, S - and converted-wave terms in the elastic equations, respectively. By using these new relations, we can study the dispersion errors of different spatial FD terms independently. The dispersion analysis showed that different spatial FD terms have different errors. It is therefore suggested that different FD coefficients to be used to approximate the three spatial derivative terms. In addition, the relative dispersion error in L2-norm is minimized through optimizing FD coefficients using Newton's method. Synthetic examples have demonstrated that this new optimal FD schemes have superior accuracy for elastic wave modelling compared to Taylor-series expansion and optimized space domain FD schemes.
    Keywords: Seismology
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 257
    Publication Date: 2017-01-07
    Description: Markov chain Monte-Carlo (McMC) sampling generates correlated random samples such that their distribution would converge to the true distribution only as the number of samples tends to infinity. In practice, McMC is found to be slow to converge, convergence is not guaranteed to be achieved in finite time, and detection of convergence requires the use of subjective criteria. Although McMC has been used for decades as the algorithm of choice for inference in complex probability distributions, there is a need to seek alternative approaches, particularly in high dimensional problems. Walker & Curtis ( 2014 ) developed a method for Bayesian inversion of 2-D spatial data using an exact sampling alternative to McMC which always draws independent samples of the target distribution. Their method thus obviates the need for convergence and removes the concomitant bias exhibited by finite sample sets. Their algorithm is nevertheless computationally intensive and requires large memory. We propose a more efficient method for Bayesian inversion of categorical variables, such as geological facies that requires no sampling at all. The method is based on a 2-D Hidden Markov Model (2D-HMM) over a grid of cells where observations represent localized data constraining each cell. The data in our example application are seismic attributes such as P - and S -wave impedances and rock density; our categorical variables are the hidden states and represent the geological rock types in each cell—facies of distinct subsets of lithology and fluid combinations such as shale, brine-sand and gas-sand. The observations at each location are assumed to be generated from a random function of the hidden state (facies) at that location, and to be distributed according to a certain probability distribution that is independent of hidden states at other locations – an assumption referred to as ‘localized likelihoods’. The hidden state (facies) at a location cannot be determined solely by the observation at that location as it also depends on prior information concerning the spatial distribution of other hidden states elsewhere. The prior information is included in the inversion in the form of a training image which represents a conceptual depiction of local geologies that might be expected, but other forms of prior information can be used in the method as desired. The method provides direct estimates of posterior marginal probability distributions over each variable, so these do not need to be estimated from samples such as in McMC. Nevertheless, in the case that samples are desired, these can be generated. On a 2-D test example the method is shown to outperform previous methods significantly, at a fraction of the computational cost. In many foreseeable applications there are therefore no serious impediments to extending the method to 3-D cases.
    Keywords: Seismology
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 258
    Publication Date: 2017-01-07
    Description: A double-correlation method is introduced to locate tremor sources based on stacks of complex, doubly-correlated tremor records of multiple triplets of seismographs back projected to hypothetical source locations in a geographic grid. Peaks in the resulting stack of moduli are inferred source locations. The stack of the moduli is a robust measure of energy radiated from a point source or point sources even when the velocity information is imprecise. Application to real data shows how double correlation focuses the source mapping compared to the common single correlation approach. Synthetic tests demonstrate the robustness of the method and its resolution limitations which are controlled by the station geometry, the finite frequency of the signal, the quality of the used velocity information and noise level. Both random noise and signal or noise correlated at time shifts that are inconsistent with the assumed velocity structure can be effectively suppressed. Assuming a surface wave velocity, we can constrain the source location even if the surface wave component does not dominate. The method can also in principle be used with body waves in 3-D, although this requires more data and seismographs placed near the source for depth resolution.
    Keywords: Seismology
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 259
    Publication Date: 2017-01-07
    Description: The possibility of applying one explicit finite-difference (FD) scheme to all interior grid points (points not lying on a grid border) no matter what their positions are with respect to the material interface is one of the key factors of the computational efficiency of the FD modelling. Smooth or discontinuous heterogeneity of the medium is accounted for only by values of the effective grid moduli and densities. Accuracy of modelling thus very much depends on how these effective grid parameters are evaluated. We present an orthorhombic representation of a heterogeneous medium for the FD modelling. We numerically demonstrate its superior accuracy. Compared to the harmonic-averaging representation the orthorhombic representation is more accurate mainly in the case of strong surface waves that are especially important in local surface sedimentary basins. The orthorhombic representation is applicable to modelling seismic wave propagation and earthquake motion in isotropic models with material interfaces and smooth heterogeneities using velocity–stress, displacement–stress and displacement FD schemes on staggered, partly staggered, Lebedev and collocated grids.
    Keywords: Seismology
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 260
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2017-01-27
    Description: Polynitrogens have the potential for ultrahigh-performing explosives or propellants because singly or doubly bonded polynitrogens can decompose to triply bonded dinitrogen (N2) with an extraordinarily large energy release. The large energy content and relatively low activation energy toward decomposition makes the synthesis of a stable polynitrogen allotrope an extraordinary challenge. Many elements exist in different forms (allotropes)—for example, carbon can exist as graphite, diamond, buckyballs, or graphene. However, no stable neutral allotropes are known for nitrogen, and only two stable homonuclear polynitrogen ions had been isolated until now—namely, the N3− anion (1) and the N5+ cation (2). On page 374 of this issue, Zhang et al. (3) report the synthesis and characterization of the first stable salt of the cyclo-N5− anion, only the third stable homonuclear polynitrogen ion ever isolated. Author: Karl O. Christe
    Keywords: Inorganic Chemistry
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  • 261
    Publication Date: 2017-01-12
    Description: We present two independent, automated methods for estimating the absolute horizontal misorientation of seismic sensors. We apply both methods to 44 free-fall ocean-bottom seismometers (OBSs) of the RHUM-RUM experiment ( http://www.rhum-rum.net/ ). The techniques measure the 3-D directions of particle motion of (1) P -waves and (2) Rayleigh waves of earthquake recordings. For P -waves, we used a principal component analysis to determine the directions of particle motions (polarizations) in multiple frequency passbands. We correct for polarization deviations due to seismic anisotropy and dipping discontinuities using a simple fit equation, which yields significantly more accurate OBS orientations. For Rayleigh waves, we evaluated the degree of elliptical polarization in the vertical plane in the time and frequency domain. The results obtained for the RHUM-RUM OBS stations differed, on average, by 3.1° and 3.7° between the methods, using circular mean and median statistics, which is within the methods’ estimate uncertainties. Using P -waves, we obtained orientation estimates for 31 ocean-bottom seismometers with an average uncertainty (95 per cent confidence interval) of 11° per station. For 7 of these OBS, data coverage was sufficient to correct polarization measurements for underlying seismic anisotropy and dipping discontinuities, improving their average orientation uncertainty from 11° to 6° per station. Using Rayleigh waves, we obtained misorientation estimates for 40 OBS, with an average uncertainty of 16° per station. The good agreement of results obtained using the two methods indicates that they should also be useful for detecting misorientations of terrestrial seismic stations.
    Keywords: Seismology
    Print ISSN: 0956-540X
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    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 262
    Publication Date: 2017-01-12
    Description: We investigate the elastic and anelastic structure of the lowermost mantle at the western edge of the Pacific large low shear velocity province (LLSVP) by inverting a collection of S and ScS waveforms. The transverse component data were obtained from F-net for 31 deep earthquakes beneath Tonga and Fiji, filtered between 12.5 and 200 s. We observe a regional variation of S and ScS arrival times and amplitude ratios, according to which we divide our region of interest into three subregions. For each of these subregions, we then perform 1-D (depth-dependent) waveform inversions simultaneously for radial profiles of shear wave velocity ( V S ) and seismic quality factor ( Q ). Models for all three subregions show low V S and low Q structures from 2000 km depth down to the core–mantle boundary. We further find that V S and Q in the central subregion, sampling the Caroline plume, are substantially lower than in the surrounding regions, whatever the depth. In the central subregion, V S -anomalies with respect to PREM (d V S ) and Q are about –2.5 per cent and 216 at a depth of 2850 km, and –0.6 per cent and 263 at a depth of 2000 km. By contrast, in the two other regions, d V S and Q are –2.2 per cent and 261 at a depth of 2850 km, and –0.3 per cent and 291 at a depth of 2000 km. At depths greater than ~2500 km, these differences may indicate lateral variations in temperature of ~100 K within the Pacific LLSVP. At shallower depths, they may be due to the temperature difference between the Caroline plume and its surroundings, and possibly to a small fraction of iron-rich material entrained by the plume.
    Keywords: Seismology
    Print ISSN: 0956-540X
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    Topics: Geosciences
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  • 263
    Publication Date: 2022-05-13
    Description: Abstract
    Description: Raw-, SEG-Y and other supplementary data of the landside deployment from the amphibious wide-angle seismic experiment ALPHA are presented. The aim of this project was to reveal the crustal and lithospheric structure of the subducting Adriatic plate and the external accretionary wedge in the southern Dinarides. Airgun shots from the RV Meteor were recorded along two profiles across Montenegro and northern Albania.
    Keywords: Seismology ; Adriatic Plate ; Montenegro ; Albania
    Language: English
    Type: Dataset , controlled source data
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  • 264
    Publication Date: 2022-11-29
    Description: Abstract
    Description: This dataset contains supplementary data concerning the SELASOMA project (GIPP-Project: Madagaskar; ID: 201204; FDSN-network code: ZE): (1) For stations with Cube data loggers, the raw data files are included. (2) For stations with EDL data loggers the log and auxiliary files are included. The main purpose of this dataset is to archive raw information on the timing quality, and to allow future use of alternative Cube-to-miniseed converters. Do not use this dataset if you are interested in continuous or event-based waveform data. Instead, refer to related dataset containing continuous waveforms . The dataset contains 1) log files for the stations with EDL data loggers (organized in sub-directories according to time range and station code); 2) separated MSEED-formatted data affected by some problems (organized in sub-directories according to time range and station code) and 3) raw CUBE-formatted data (organized in sub-directories according to time range and station name).
    Keywords: Seismology
    Language: English
    Type: Dataset , Dataset
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  • 265
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    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.46 (2016) p.115
    Publication Date: 2018-12-13
    Description: Oligochaete wormen komen vooral in zoet water voor. Maar in brak water en zelfs in de volle zee komen enkele soorten voor. Bij onderzoek naar marien benthos werden deze dieren traditioneel niet tot op soort gedetermineerd, omdat ze klein en lastig te determineren zijn. Ze zijn echter niet veel lastiger dan de nauw verwante Polychaeta, die ook hele kleine vertegenwoordigers kennen. In dit artikel wordt een overzicht gegeven van de 32 soorten die nu uit het zoute water in ons land bekend zijn, waarvan er hier zes als nieuw voor de Nederlandse fauna gepresenteerd worden. De vondst van Heterodrilus subtilis in de Noordzee is zeer bijzonder, omdat deze soort verder alleen bekend is van het typemateriaal, dat ongeveer honderd jaar geleden in de Golf van Napels werd verzameld.
    Keywords: Oligochaeta ; Nederland ; verspreiding ; herkenning ; biologie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 266
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    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.46 (2016) p.87
    Publication Date: 2018-12-13
    Description: Het laatste overzicht van de wantsen van de Nederlandse waddeneilanden dateert van 2012. Een opsomming wordt gegeven van 43 nieuwe eilandrecords, waaronder vijf soorten die voor het eerst op de waddeneilanden zijn waargenomen. In totaal zijn er nu 380 soorten wantsen van de Nederlandse waddeneilanden bekend.
    Keywords: Heteroptera ; Nederland ; Waddeneilanden ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 267
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    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.46 (2016) p.57
    Publication Date: 2018-12-13
    Description: Een overzicht wordt gegeven van waarnemingen van 33 soorten nieuwe of anderszins interessante soorten wantsen. Psallus aethiops (Miridae), Empicoris rubromaculatus (Reduviidae), Arocatus melanocephalus, Lygaeus simulans, Eremocoris fenestratus (Lygaeidae) en Nezara viridula (Pentatomidae) zijn nieuw voor de Nederlandse lijst, die daarmee nu 640 soorten telt. Naast nieuwe waarnemingen van zeldzame soorten wordt de recente uitbreiding van Cymatia rogenhoferi (Corixidae), Cardiastethus fasciiventris (Anthocoridae), Arocatus longiceps en Rhyparochromus vulgaris (Lygaeidae), Leptoglossus occidentalis (Coreidae), en Peribalus strictus en Rhaphigaster nebulosa (Pentatomidae) in kaart gebracht.
    Keywords: Heteroptera ; Nederland ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 268
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    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.46 (2016) p.101
    Publication Date: 2018-12-13
    Description: In Nederland komen tien soorten ruighaarkevers (genera Dryops en Pomatinus) voor. Ze leven langs oevers van stilstaande en stromende wateren. Het was een verrassing toen in 2014 een vrouwtje van de zeer zeldzame Dryops striatellus gevonden werd bij Bakkeveen (provincie Friesland). De soort was sinds 1960 niet meer in Nederland gevonden. In 2016 werd D. striatellus op een tweede locatie nabij Bakkeveen gevonden. In dit artikel geven wij informatie over de soort en presenteren bijzonderheden over de Friese populatie en haar habitat.
    Keywords: Coleoptera ; Dryopidae ; Dryops striatellus ; Nederland ; verspreiding ; herkenning ; biologie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 269
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    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.46 (2016) p.11
    Publication Date: 2018-12-13
    Description: Op 14 oktober 2015 werd een halmvlieg met fraaie zwarte vlekken op de vleugels gefotografeerd in Hoogerheide (Noord-Brabant). Na vergelijking van foto’s werd geconcludeerd dat het moest gaan om Gampsocera numerata, welke determinatie later werd bevestigd. Reeds in 2009 bleek in België een mannetje van de soort gefotografeerd te zijn in een tuin in Evere. Ook in 2010 en 2015 is de soort in België gevonden. Dit zijn de eerste meldingen van G. numerata voor Nederland en België.
    Keywords: Diptera ; Chloropidae ; Gampsocera numerata ; Nederland ; België ; verspreiding ; herkenning ; biologie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
    Format: application/pdf
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  • 270
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    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.46 (2016) p.49
    Publication Date: 2018-12-13
    Description: Recently two exotic tubeworms new to the fauna of the Netherlands have been recorded in inshore waters in the delta area: Desdemona ornata and Pseudopolydora paucibranchiata. Within the Polychaeta these worms belong to the group of the Sedentaria. These construct a tube, in which the body of the worm is hidden. The head and feeding appendages protrude from the opening. Most probably these tubes are a major factor in the transport of these animals around the world, as they provide excellent shelters when they are attached to the hull of a ship or commercially traded shellfish.
    Keywords: Polychaeta ; Pseudopolydora paucibranchiata ; Desdemona ornata ; Nederland ; verspreiding ; exoot ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 271
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    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.47 (2016) p.31
    Publication Date: 2018-12-13
    Description: De boszandbij Andrena coitana leek verdwenen uit Nederland. Veertig jaar na de laatste waarneming in 1975 is weer een populatie van deze soort gevonden, bij Epe in Gelderland. De boszandbij is een kleine soort, die mogelijk nog op sommige plaatsen over het hoofd gezien is. In dit artikel wordt de kennis over deze bijzondere bij samengevat en gespeculeerd over de oorzaken van de achteruitgang in Nederland.
    Keywords: Hymenoptera ; Apidae ; Andrena coitana ; Nederland ; verspreiding ; herkenning ; biologie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 272
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    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.46 (2016) p.1
    Publication Date: 2018-12-13
    Description: In 2015 werd Kelisia monoceros voor het eerst in ons land verzameld bij Kamperland in Zeeland. Deze spoorcicade leeft op de algemeen voorkomende valse voszegge. De vondst wijst op een recente areaaluitbreiding. Een andere spoorcicade, Ditropsis flavipes, werd al eerder uit ons land gemeld, maar verspreidingsgegevens worden nu voor de eerste maal gepubliceerd. Ditropsis flavipes leeft monofaag op bergdravik, een in Nederland zeldzaam gras.
    Keywords: Homoptera ; Delphacidae ; Nederland ; verspreiding ; biologie ; Kelisia monoceros ; Ditropsis flavipes ; herkenning ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 273
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    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.47 (2016) p.17
    Publication Date: 2018-12-13
    Description: Alle spinnen hebben gif in hun kaken om hun prooien te doden. Verreweg de meeste soorten kunnen de menselijke huid niet doorboren met hun kaken en zijn dus volkomen ongevaarlijk. Kogelspinnen uit het genus Latrodectus, oftewel weduwen, vormen een uitzondering. Deze exotische spinnen worden af en toe geïmporteerd in Nederland. In 2013 is het aantal vondsten van geïmporteerde Latrodectus-spinnen op een rij gezet in een risicobeoordeling, met als resultaat een lijst van tien records met bewijsmateriaal. Hier kunnen nu vier records aan toegevoegd worden. Hieronder bevindt zich een vondst van de bruine weduwe L. geometricus, die recent voor het eerst in ons land werd vastgesteld, en een eerste geval van uitgekomen eitjes van een Latrodectus in ons land, van de roodrugspin L. hasselti.
    Keywords: Araneae ; Theridiidae ; Latrodectus ; Nederland ; exoot ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 274
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    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.47 (2016) p.27
    Publication Date: 2018-12-13
    Description: In 2015 werd tijdens een monitoringsproject van mariene bodemfauna op het Friese front de vulkaanworm Maxmuelleria lankesteri aangetroffen. Dit is de eerste vondst in Nederlandse wateren. De vulkaanworm dankt zijn naam aan de vorm van de opening van zijn leefgang, een vulkaanachtige slibheuvel. Het is opmerkelijk dat deze grote, opvallende worm (12-18 cm lang) niet eerder is aangetroffen. Mogelijk ligt dit aan de ongebruikelijke bemonsteringsmethode. Anderzijds kan de vulkaanworm daadwerkelijk zeldzaam zijn.
    Keywords: Echiura ; Maxmuelleria lankesteri ; Nederland ; verspreiding ; herkenning ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 275
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    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.46 (2016) p.95
    Publication Date: 2018-12-13
    Description: De kleine bleekvlekwespbij Nomada baccata behoort tot een complex van taxa rond de bleekvlekwespbij Nomada alboguttata. De kleine bleekvlekwespbij is vroeger verspreid over het land aangetroffen, maar de laatste waarneming dateerde alweer van 1992. In de afgelopen jaren werd de soort op twee plekken in ons land teruggevonden, in de Schoorlse duinen in Noord-Holland in 2012 en op de Tongerense hei bij Epe in Gelderland in 2015.
    Keywords: Hymenoptera ; Apidae ; Nomada baccata ; taxonomie ; verspreiding ; herkenning ; biologie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 276
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    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.46 (2016) p.37
    Publication Date: 2018-12-13
    Description: De familie der sluipvliegen is één van de soortenrijkste vliegenfamilies in ons land. De larven ontwikkelen zich inwendig in ongewervelden, veelal vlinderrupsen. De groep is in ons land relatief goed bestudeerd en de afgelopen jaren zijn diverse aanvullingen op de checklist uit 2002 gepubliceerd. In dit artikel worden wederom twee soorten voor het eerst uit ons land vermeld. Hiermee komt het totaal aantal soorten dat in Nederland is vastgesteld op 336. Daarnaast wordt de herontdekking van een soort beschreven die al meer dan een eeuw niet meer waargenomen was.
    Keywords: Diptera ; Tachinidae ; Nederland ; verspreiding ; herkenning ; biologie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 277
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    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.46 (2016) p.15
    Publication Date: 2018-12-13
    Description: Canacidae zijn gebonden aan de kust en zou je daarmee typisch Nederlandse vliegjes kunnen noemen. In dit artikel melden wij een nieuwe soort van deze familie: Canace nasica en presenteren we een nieuwe Nederlandse checklist voor de familie. Naar de nieuwste taxonomische inzichten wordt daarbij de familie Tethinidae als subfamilie onder de Canacidae toegevoegd. Hiermee is de Nederlandse fauna een vliegenfamilie armer.
    Keywords: Diptera ; Canacidae ; Canace nasica ; Nederland ; herkenning ; verspreiding ; biologie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 278
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    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.47 (2016) p.11
    Publication Date: 2018-12-13
    Description: De kassprinkhaan is een buitenbeentje onder de Nederlandse sprinkhanen en krekels. Ze komt van oorsprong waarschijnlijk voor in grotten in Oost-Azië en is door transport van eieren met plantenmateriaal over de hele wereld verspreid geraakt. Ze kan tijdelijk overleven in het kunstmatig grotmilieu van bijvoorbeeld kruipruimtes van woonhuizen, in kassen en tuincentra. Recentelijk werd een opmerkelijk grote populatie van de kassprinkhaan gevonden in het uitgebreide stelsel aan kruipruimtes onder een verpleeghuis in Friesland. De kassprinkhaan blijkt hier al ruim 40 jaar voor te komen. Het is waarschijnlijk de grootste Europese populatie van deze soort.
    Keywords: Orthoptera ; Diestrammena asynamora ; verspreiding ; exoot ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 279
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    In:  Nederlandse Faunistische Mededelingen (0196-2453) vol.46 (2016) p.43
    Publication Date: 2018-12-13
    Description: In het kader van het project ‘Duik de Noordzee Schoon’ worden scheepswrakken onderzocht, beschreven en van afval ontdaan. Scheepswrakken vormen een bijzonder leefgebied in het mariene milieu, met een hoge biodiversiteit. Dit bleek weer tijdens onderzoek van visnetten die van ver weg gelegen wrakken waren verwijderd. Hierbij werden maar liefst vier nieuwe mosdiertjes voor de Nederlandse fauna aangetroffen.
    Keywords: Bryozoa ; Nederland ; verspreiding ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 280
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    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.47 (2016) p.43
    Publication Date: 2018-12-13
    Description: Pauropoda of weinigpoten zijn nauw verwant aan de miljoenpoten en duizendpoten. Het is een weinig bestudeerde diergroep, die bestaat uit kleine, witte en blinde bodemdieren die nauwelijks opvallen. Het meest kenmerkende zijn de gevorkte antennen, die wat bouw betreft uniek zijn ten opzichte van andere ongewervelden. Er zijn slechts acht soorten gemeld uit Nederland, alle behorend tot het genus Allopauropus. Recentelijk is een nieuwe soort, uit het genus Pauropus, in het westen van het land aangetroffen. Het betreft dus ook een nieuw genus voor de Nederlandse fauna. In dit artikel wordt de nieuwe soort voorgesteld, beschrijven we de habitat en geven we informatie over de verspreiding.
    Keywords: Myriapoda ; Pauropoda ; Pauropus lanceolatus ; Nederland ; verspreiding ; herkenning ; biologie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 281
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    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.46 (2016) p.19
    Publication Date: 2018-12-13
    Description: Slakkendodende vliegen (familie Sciomyzidae) zijn al niet zo opvallend in het veld, maar de soorten uit de genera Pherbellia en Ditaeniella worden nog minder gevonden, mede doordat ze vrij klein zijn. De 14 Nederlandse soorten lijken sterk op elkaar. Dit artikel biedt een tabel om ze te kunnen herkennen en geeft informatie over ecologie en verspreiding.
    Keywords: Diptera ; Sciomyzidae ; Pherbellia ; Ditaeniella ; Nederland ; verspreiding ; herkenning ; biologie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 282
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    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.47 (2016) p.1
    Publication Date: 2018-12-13
    Description: Platwormen komen in Nederland vooral voor in zoet water, maar er zijn twee soorten van landbiotoop bekend. De laatste jaren duiken steeds vaker exotische landplatwormen op in Europa, vooral in kassen en tuincentra, maar sommige kunnen ook buitenshuis overleven. Uit Nederland zijn Bipalium kewense, Caenoplana bicolor en Marionfyfea adventor gemeld. Omdat ze regenwormen en slakken eten, kunnen ze een grote invloed hebben op het bodemleven, met gevolgen voor natuurlijke ecosystemen en landbouwgebieden. In het buitenland is de aandacht voor exotische landplatwormen al groeiende. Zo wordt de Nieuw-Guineese landplatworm Platydemus manokwari door de IUCN tot de 100 ergste invasieve soorten aangemerkt. In Nederland is er nog nauwelijks aandacht voor landplatwormen. Daarom wordt in dit artikel de kennis over deze groep samengevat.
    Keywords: Platyhelminthes ; Tricladida ; Nederland ; verspreiding ; biologie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 283
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    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.47 (2016) p.39
    Publication Date: 2018-12-13
    Description: Blaaskopvliegen zijn een van de groepen uit het atlasproject Leuke vliegen, dat in 2015 werd afgesloten. Het zijn over het algemeen opvallend gekleurde vliegen, die parasiteren bij bijen en wespen. In een overzichtsartikel uit 2014 werd de komst van Leopoldius calceatus al voorspeld en in 2015 werd soort inderdaad aangetroffen in Groeve Craubeek in de provincie Limburg en een jaar later op de Stratumse heide bij Eindhoven.
    Keywords: Diptera ; Conopidae ; Nederland ; Leopoldius calceatus ; verspreiding ; herkenning ; biologie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
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  • 284
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    In:  Nederlandse Faunistische Mededelingen (0169-2453) vol.47 (2016) p.49
    Publication Date: 2018-12-13
    Description: Astigmatic mites probably form the most diverse cohort of mites. At present the former order of Astigmatina is ranked within the suborder Oribatida or moss mites. However astigmatic mites occupy a much wider range of habitats than other oribatid mites: from marine coasts to stored food, plant bulbs and houses. The vast majority live as commensals or parasites on a variety of hosts, ranging from insects to birds and mammals, inhabiting the fur, feathers, skin and even lungs and stomach. This first checklist for the Netherlands contains 262 species, but many more are to be expected. Brief data on occurrence and nomenclature are provided for each species.
    Keywords: Acari ; Oribatida ; Astigmatina ; verspreiding ; taxonomie ; 42.75
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
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  • 285
    Publication Date: 2016-02-09
    Description: Wing shape variation was investigated between the sexes and among four populations of the scorpionfly Dicerapanorpa magna (Chou, 1981) endemic to the Qin-Ba Mountains area, China through the landmark-based geometric morphometric approach. The results show that sexual dimorphism exists both in wing size and shape in D. magna. Significant differences exist in female wing size and shape among D. magna populations. The possible reasons of the wing variation are discussed based on the divergence time of D. magna in combination with the tectonic and climatic events in the Qin-Ba Mountains during the late Miocene-Pleistocene period. Whether reproductive isolation exists between different populations needs further research.
    Keywords: canonical variates analysis ; individual variation ; sexual dimorphism ; 42.75 ; 42.62
    Repository Name: National Museum of Natural History, Netherlands
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  • 286
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    Station Océanographique de Salammbô | Paris, France
    Publication Date: 2021-05-19
    Description: La détermination de la chloruration des eaux de mer est effectuée depuis de nombreuses années par la méthode volémetrisque de Moher.
    Description: Published
    Keywords: Volumetric analysis ; Sea water ; Chemistry ; Density ; Water density ; Chlorination ; Methodology ; Marine
    Repository Name: AquaDocs
    Type: Book/Monograph/Conference Proceedings , Refereed
    Format: 28pp.
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  • 287
    Publication Date: 2022-05-25
    Description: Seismic data obtained using borehole seismometers during the LFASE experiment (Stephen et al, 1989; Koelsch et al, 1990) are retrieved from the seafloor instrument package and converted to a data format more suitable for analysis with existing computer systems. This report describes the computer program CGG2ROSE2 for converting LFASE optical disk files recorded in CGG format by the data acquisition computer into standard ROSE format data files on a VAX/VMS computer. CGG2ROSE2 provides features for rearranging LFASE data into smaller segments, making corrections to timing information, and replacing file header information.
    Keywords: Seismic arrays ; Seismology
    Repository Name: Woods Hole Open Access Server
    Type: Working Paper
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  • 288
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    Woods Hole Oceanographic Institution
    Publication Date: 2022-05-25
    Description: This technical report provides an overview of the LFASE data processing system. This software system is made up of over twenty-five programs which are used to acquire, reduce, and analyze acoustic seismic data collected during the Low Frequency Acoustic Seismic Experiment (LFASE) (Stephen et al, 1989; Koelsch et al, 1990). This report is directed at scientific and engineering personnel who wish to understand the overall LFASE data processing system as well as the individual processing procedures which are utilized during each stage of data reduction and interpretation. The report is also directed at programmers, data processors, technicians, and other individuals who plan to work with LFASE programs and data.
    Keywords: Seismic arrays ; Seismology
    Repository Name: Woods Hole Open Access Server
    Type: Working Paper
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  • 289
    Publication Date: 2022-05-25
    Description: The Low Frequency Acoustic Seismic Experiment (LFASE) was conducted to measure sound propagation and ambient noise above, at and below the sea floor. To this end an array consisting of four geophone nodes was introduced into a DSDP borehole. These seismic sensors were clamped inside the borehole at various depths below the ocean floor. The geophone array was connected by an electromechanical cable to a bottom reentry structure (BCU frame) housing the Data Recording Unit (DRU), the Data Telemetry Unit (DTU), the Bottom Control Unit (BCU) and the power supply.
    Description: Report prepared under Office of Naval Research Contracts #N00014-89-C-0018, N00014-89-J-1012 and Office of Naval Technology Contract #00014-90-C-0098, WHOI Project #13/1012
    Keywords: Seismic arrays ; Seismology ; Melville (Ship) Cruise HYDR01MV ; Melville (Ship) Cruise HYDR05MV ; Melville (Ship) Cruise HYDR09MV ; Melville (Ship) Cruise HYDR10MV
    Repository Name: Woods Hole Open Access Server
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  • 290
    Publication Date: 2022-05-25
    Description: The Seafloor Borehole Array Seismic System (SEABASS) was originally developed to record autonomously on the seafloor the signals received on a four-sonde three-component borehole geophone array in the VLF band (2-50Hz)(Stephen eta!., 1994). The system is designed to use the wireline re-entry capability (Spiess, 1993; Spiess eta!., 1992) to install and retrieve the seafloor instrumentation (Figures 1 and 2). Following the successful demonstration of this technology on the LFASE (Low Frequency Acoustic-Seismic Experiment) project in September 1989, it was decided to extend the capability to broadband (1000sec-5Hz) borehole seismometers which could be used for permanent seafloor seismic observatories in the Ocean Seismic Network (Orcutt and Stephen, 1993; Purdy and Dziewonski, 1988; Purdy and Orcutt, 1995; Stephen, 1995; Sutton and Barstow, 1990; Sutton eta!., 1988; Sutton eta!., 1965). The Broadband Borehole Seismic System (B3S2) is the prototype system for permanent broadband borehole seismic observatories on the seafloor. It has three major components: i) a broadband borehole seismometer, the Teledyne 54000, modified for seafloor operations by Scripps-IGPP; ii) the re-entry system provided by Scripps-MPL; and iii) the seafloor recording system developed by WHO I. Because of the similarity of the seafloor recording system to SEABASS we have named this new system SEABASS-ll. This report discusses the development of SEABASS-Il at WHOI in the period from July 14, 1992 to January 31, 1996. The motivation for the project and a work statement are contained in WHOI proposals 7016 and 7016.1. This report is a collection of documentation prepared while the work was being carried out. Some of the issues discussed in early memos were subsequently changed. Modifications and further testing of SEABASS-ll, as well as final system integration tests with the borehole andreentry systems (both of which are also still being modified and tested) have still to be carried out in preparation for the OSN Pilot Experiment Cruise in Spring 1997. This is a preliminary report only and presents work in progress. It will be useful to the engineering team as a historical reference of the sequence of events in the development of SEABASS-ll but it should not be considered as a technical manual for the instrumentation.
    Keywords: Seismology ; Borehole gravimetry ; Ocean bottom ; Oceanographic instruments
    Repository Name: Woods Hole Open Access Server
    Type: Working Paper
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  • 291
    Publication Date: 2022-05-26
    Description: The broadband borehole seismic system (B3S2) is being developed as one component of the Ocean Seismic Network (OSN) Pilot Experiment which will be carried out at the OSN-1 Site off Hawaii in Winter 1998. The other major instruments being developed for the experiment are a Broadband Ocean Bottom Seismometer and a Shallow Buried Broadband Ocean Bottom Seismometer. B3S2 consists of four major components: 1) a borehole sonde with a re-entry guide, Teledyne 54000 broadband seismometer, and REFTEK digitizing system, 2) a seafloor acquisition and recording system (SEABASS), 3) a control vehicle for deploying the sonde in a borehole, and 4) shipboard command and control electronics. The deployment system is very similar to the SEABASS configuration used on LFASE (Stephen eta!, 1994). The purposes of the tests at Pinon Flat were: 1) to integrate the borehole sonde and seafloor and shipboard electronics which had been constructed by different groups: WHOI and SIO/IGPP; 2) test the combined subsystem in a wet borehole environment using actual cables and simulating seafloor conditions; and 3) acquire seismic ambient noise and earthquake data over approximately a three month period for comparison with known stations at the Pinon Flat Observatory.
    Description: This work was carried out under NSF Grants No. OCE-91-18943 and OCE No. OCE-95-05730: "A Broadband Borehole Seismometer for the Deep Ocean - Development and Land Testing"
    Keywords: Seismology ; Borehole gravity meters ; Ocean bottom ; Oceanographic instruments
    Repository Name: Woods Hole Open Access Server
    Type: Working Paper
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  • 292
    Publication Date: 2022-05-26
    Description: On the Low Frequency Acoustic - Seismic Experiment (LFASE), carried out at DSDP hole 534A in August, 1989, WHOI was responsible for acquiring data from a twelve channel borehole seismic array. Data were acquired both on-board while tethered to the array and autonomously in a seafloor package. Seismic source data (explosives and airguns) and ambient noise data were recorded. This report describes the nature of data acquired, reviews the data reduction procedure from field format to ROSE data format, and includes examples of the data. A total of918.6 Mbytes of data were acquired (769 Mbytes in the shipboard recording mode and 149.6 Mbytes in the seafloor recording mode). Approximately 85 explosive shots, 2000 airgun shots, and 10 hours of ambient noise data were recorded.
    Keywords: Seismic arrays ; Seismology
    Repository Name: Woods Hole Open Access Server
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  • 293
    Publication Date: 2016-07-13
    Description: Earth's free oscillations excited by a mega-thrust earthquake were observed by a continent-scale array of groundwater monitoring sites for the first time. After the occurrence of the 2011 Tohoku M w 9.0 earthquake, water level records at 43 out of 216 wells in the China mainland revealed long-period free oscillation signals. In the time domain, these free oscillations exhibit globe circling Rayleigh surface waves. In some single wells, even the globe-circling Rayleigh wave R7 was visible, which travels three times around the Earth after the first arrival and appears about 10 hr after the earthquake occurrence in the present case. The spectral analysis shows that the principal oscillatory fluctuations seen in the water level records correspond to the spheroidal modes 0 S l ( l  = 2–31 for frequencies between 0.3 and 5.0 mHz) of the Earth's free oscillation. Especially at quiet sites, the spheroidal modes at very low frequencies (〈1.5 mHz) can be identified with high signal-to-noise ratios. Using signal enhancement methods (product spectrum over 43 wells), even the gravest modes of these oscillations can be detected. The results suggest that groundwater level arrays can be considered as a low-cost complementary tool to study the Earth's free oscillations excited by great earthquakes. Additionally, the site-specific aquifer response may provide further insight into local hydrogeological conditions.
    Keywords: Seismology
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 294
    Publication Date: 2016-07-13
    Description: We performed numerical simulations of the 2011 deep-seated Akatani landslide in central Japan to understand the dynamic evolution of friction of the landslide. By comparing the forces obtained from numerical simulation to those resolved from seismic waveform inversion, the coefficient of the friction during sliding was investigated in the range of 0.1–0.4. The simulation assuming standard Coulomb friction shows that the forces obtained by the seismic waveform inversion are well explained using a constant friction of μ = 0.3. A small difference between the residuals of Coulomb simulation and a velocity-dependent simulation suggests that the coefficient of friction over the volume is well constrained as 0.3 most of time during sliding. It suggests the sudden loss of shearing resistance at the onset of sliding, that is, sudden drop of the initial coefficient of friction in our model, which accelerates the deep-seated landslide. Our numerical simulation calibrated by seismic data provides the evolution of dynamic friction with a reasonable resolution in time, which is difficult to obtain from a conventional runout simulation, or seismic waveform inversion alone.
    Keywords: Seismology
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 295
    Publication Date: 2016-07-13
    Description: We introduce a technique to compute exact anelastic sensitivity kernels in the time domain using parsimonious disk storage. The method is based on a reordering of the time loop of time-domain forward/adjoint wave propagation solvers combined with the use of a memory buffer. It avoids instabilities that occur when time-reversing dissipative wave propagation simulations. The total number of required time steps is unchanged compared to usual acoustic or elastic approaches. The cost is reduced by a factor of 4/3 compared to the case in which anelasticity is partially accounted for by accommodating the effects of physical dispersion. We validate our technique by performing a test in which we compare the K α sensitivity kernel to the exact kernel obtained by saving the entire forward calculation. This benchmark confirms that our approach is also exact. We illustrate the importance of including full attenuation in the calculation of sensitivity kernels by showing significant differences with physical-dispersion-only kernels.
    Keywords: Seismology
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 296
    Publication Date: 2016-07-13
    Description: Real Earth media are not perfectly elastic. Instead, they attenuate propagating mechanical waves. This anelastic phenomenon in wave propagation can be modeled by a viscoelastic mechanical model consisting of several standard linear solids. Using this viscoelastic model, we approximate a constant Q over a frequency band of interest. We use a four-element viscoelastic model with a trade-off between accuracy and computational costs to incorporate Q into 2-D time-domain first-order velocity–stress wave equations. To improve the computational efficiency, we limit the Q in the model to a list of discrete values between 2 and 1000. The related stress and strain relaxation times that characterize the viscoelastic model are pre-calculated and stored in a database for use by the finite-difference calculation. A viscoelastic finite-difference scheme that is second order in time and fourth order in space is developed based on the MacCormack algorithm. The new method is validated by comparing the numerical result with analytical solutions that are calculated using the generalized reflection/transmission coefficient method. The synthetic seismograms exhibit greater than 95 per cent consistency in a two-layer viscoelastic model. The dispersion generated from the simulation is consistent with the Kolsky–Futterman dispersion relationship.
    Keywords: Seismology
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 297
    Publication Date: 2016-07-13
    Description: After 83 yr, the great normal-faulting earthquake of 1933 March 2, which took place off the Japan Trench and produced a devastating tsunami on the Sanriku coast and damaging waves in Hawaii, remains the largest recorded normal-faulting earthquake. This study uses advanced methods to investigate this event using far-field seismological and tsunami data and complements a sister study by Uchida et al. which used exclusively arrival times at Japanese stations. Our relocation of the main shock (39.22°N, 144.45°E, with a poorly constrained depth of less than 40 km) places it in the outer trench slope, below a seafloor depth of ~6500 m, in a region of horst-and-graben structure, with fault scarps approximately parallel to the axis of the Japan Trench. Relocated aftershocks show a band of genuine shallow aftershocks parallel to the Japan Trench under the outer trench slope and a region of post-mainshock events landward of the trench axis that occur over roughly the same latitude range and are thought to be the result of stress transfer to the interplate thrust boundary following the normal-faulting rupture. Based on a combination of P -wave first motions and inversion of surface wave spectral amplitudes, we propose a normal-faulting focal mechanism ( = 200°, = 61° and = 271°) and a seismic moment M 0 = (7 ± 1) x 10 28 dyn cm ( M w = 8.5). A wide variety of data, including the distribution of isoseismals, the large magnitudes (up to 8.9) proposed by early investigators before the standardization of magnitude scales, estimates of energy-to-moment ratios and the tentative identification of a T wave at Pasadena (and possibly Riverside), clearly indicate that this seismic source was exceptionally rich in high-frequency wave energy, suggesting a large apparent stress and a sharp rise time, and consistent with the behaviour of many smaller shallow normal-faulting earthquakes. Hydrodynamic simulations based on a range of possible sources consistent with the above findings, including a compound rupture on two opposite-facing normal-faulting segments, are in satisfactory agreement with tsunami observations in Hawaii, where run-up reached 3 m, causing significant damage. This study emphasizes the need to include off-trench normal-faulting earthquake sources in global assessments of tsunami hazards emanating from the subduction of old and cold plates, whose total length of trenches exceed 20 000 km, even though only a handful of great such events are known with confidence in the instrumental record.
    Keywords: Seismology
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 298
    Publication Date: 2016-07-15
    Description: To refine the 3-D seismic velocity model in the greater Parkfield, California region, a new data set including regular earthquakes, shots, quarry blasts and low-frequency earthquakes (LFEs) was assembled. Hundreds of traces of each LFE family at two temporary arrays were stacked with time–frequency domain phase weighted stacking method to improve signal-to-noise ratio. We extend our model resolution to lower crustal depth with LFE data. Our result images not only previously identified features but also low velocity zones (LVZs) in the area around the LFEs and the lower crust beneath the southern Rinconada Fault. The former LVZ is consistent with high fluid pressure that can account for several aspects of LFE behaviour. The latter LVZ is consistent with a high conductivity zone in magnetotelluric studies. A new Vs model was developed with S picks that were obtained with a new autopicker. At shallow depth, the low Vs areas underlie the strongest shaking areas in the 2004 Parkfield earthquake. We relocate LFE families and analyse the location uncertainties with the NonLinLoc and tomoDD codes. The two methods yield similar results.
    Keywords: Seismology
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 299
    Publication Date: 2016-07-20
    Description: The Cadzow rank-reduction method can be effectively utilized in simultaneously denoising and reconstructing 5-D seismic data that depend on four spatial dimensions. The classic version of Cadzow rank-reduction method arranges the 4-D spatial data into a level-four block Hankel/Toeplitz matrix and then applies truncated singular value decomposition (TSVD) for rank reduction. When the observed data are extremely noisy, which is often the feature of real seismic data, traditional TSVD cannot be adequate for attenuating the noise and reconstructing the signals. The reconstructed data tend to contain a significant amount of residual noise using the traditional TSVD method, which can be explained by the fact that the reconstructed data space is a mixture of both signal subspace and noise subspace. In order to better decompose the block Hankel matrix into signal and noise components, we introduced a damping operator into the traditional TSVD formula, which we call the damped rank-reduction method. The damped rank-reduction method can obtain a perfect reconstruction performance even when the observed data have extremely low signal-to-noise ratio. The feasibility of the improved 5-D seismic data reconstruction method was validated via both 5-D synthetic and field data examples. We presented comprehensive analysis of the data examples and obtained valuable experience and guidelines in better utilizing the proposed method in practice. Since the proposed method is convenient to implement and can achieve immediate improvement, we suggest its wide application in the industry.
    Keywords: Seismology
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 300
    Publication Date: 2016-07-21
    Description: An exact analytical solution is presented for the effective dynamic transverse shear modulus in a heterogeneous fluid-filled porous solid containing cylindrical inclusions. The complex and frequency-dependent properties of the dynamic shear modulus are caused by the physical mechanism of mesoscopic-scale wave-induced fluid flow whose scale is smaller than wavelength but larger than the size of pores. Our model consists of three phases: a long cylindrical inclusion, a cylindrical shell of poroelastic matrix material with different mechanical and/or hydraulic properties than the inclusion and an outer region of effective homogeneous medium of laterally infinite extent. The behavior of both the inclusion and the matrix is described by Biot's consolidation equations, whereas the surrounding effective medium which is used to describe the effective transverse shear properties of the inner poroelastic composite is assumed to be a viscoelastic solid whose complex transverse shear modulus needs to be determined. The determined effective transverse shear modulus is used to quantify the S -wave attenuation and velocity dispersion in heterogeneous fluid-filled poroelastic rocks. The calculation shows the relaxation frequency and relative position of various fluid saturation dispersion curves predicted by this study exhibit very good agreement with those of a previous 2-D finite-element simulation. For the double-porosity model (inclusions having a different solid frame than the matrix but the same pore fluid as the matrix) the effective shear modulus also exhibits a size-dependent characteristic that the relaxation frequency moves to lower frequencies by two orders of magnitude if the radius of the cylindrical poroelastic composite increases by one order of magnitude. For the patchy-saturation model (inclusions having the same solid frame as the matrix but with a different pore fluid from the matrix), the heterogeneity in pore fluid cannot cause any attenuation in the transverse shear modulus at all. A comparison with the case of spherical inclusions illustrates that the transverse shear modulus for the cylindrical inclusion exhibits more S -wave attenuation than spherical inclusions.
    Keywords: Seismology
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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