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  • Articles  (7)
  • 04.08. Volcanology  (7)
  • Elsevier  (7)
  • Hindawi
  • 2015-2019  (7)
  • 1975-1979
  • 1
    Publication Date: 2021-06-30
    Description: Soil CO2 flux and 222Rn activity measurements may positively contribute to the geochemicalmonitoring of active volcanoes. The influence of several environmental parameters on the gas signals has been substantially demonstrated. Therefore, the implementation of tools capable of removing (or minimising) the contribution of the atmospheric effects from the acquired time series is a challenge in volcano surveillance. Here, we present 4 years-long continuousmonitoring (fromApril 2007 to September 2011) of radon activity and soil CO2 flux collected on the NE flank of Stromboli volcano. Both gases record higher emissions during fall–winter (up to 2700 Bq * m−3 for radon and 750 g m−2 day−1 for CO2) than during spring–summer seasons. Short-time variations on 222Rn activity aremodulated by changes in soil humidity (rainfall), and changes in soil CO2 flux that may be ascribed to variations in wind speed and direction. The spectral analyses reveal diurnal and semi-diurnal cycles on both gases, outlining that atmospheric variations are capable to modify the gas release rate fromthe soil. The long-termsoil CO2 flux shows a slow decreasing trend, not visible in 222Rn activity, suggesting a possible difference in the source depth of the of the gases, CO2 being deeper and likely related to degassing at depth of the magma batch involved in the February–April 2007 effusive eruption. To minimise the effect of the environmental parameters on the 222Rn concentrations and soil CO2 fluxes, two different statistical treatments were applied: the Multiple Linear Regression (MLR) and the Principal Component Regression (PCR). These approaches allow to quantify theweight of each environmental factor on the two gas species and showa strong influence of some parameters on the gas transfer processes through soils. The residual values of radon and CO2 flux, i.e. the values obtained after correction for the environmental influence, were then compared with the eruptive episodes that occurred at Stromboli during the analysed time span (2007–2011) but no clear correlations emerge between soil gas release and volcanic activity. This is probably due to i) the distal location of the monitoring stations with respect to the active craters and to ii) the fact that during the investigated period no major eruptive phenomena (paroxysmal explosion, flank eruption) occurred. Comparison of MLR and PCR methods in time-series analysis indicates thatMLR can bemore easily applied to real time data processing in monitoring of open conduit active volcanoes (like Stromboli) where the transition to an eruptive phase may occur in relatively short times.
    Description: This researchwas partly funded by ItalianMinistry of University and Research (MIUR) and by University of Torino-Fondazione Compagnia di San Paolo. Additional fundswere provided by the Italian “Presidenza del Consiglio dei Ministri–Dipartimento della Protezione Civile (DPC)” through the DEVnet Project (a cooperative program between the Departments of Earth Sciences of the University of Torino and the University of Florence) and through the “Potenziamento Monitoraggio Stromboli” project. Additional funds for improving our computing hardware were provided by Fondazione Cassa di Risparmio di Torino.
    Description: Published
    Description: 65-78
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Stromboli volcano ; Continuous geochemical monitoring ; Soil CO2 flux ; Radon activity ; Environmental parameters ; Time series analyses ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2021-03-16
    Description: The Nevado del Ruiz volcano is considered one of the most active volcanoes in Colombia, which can potentially threaten approximately 600,000 inhabitants. The existence of a glacier and several streams channelling in some main rivers, flowing downslope, increases the risk for the population living on the flank of the volcano in case of unrest, because of the generation of lahars and mudflows. Indeed, during the November 1985 subplinian eruption, a lahar generated by the sudden melting of the glacier killed twenty thousand people in the town of Armero. Moreover, the involvement of the local hydrothermal system has produced in the past phreatic and phreatomagmatic activity, as occurred in 1989. Therefore, the physico-chemical conditions of the hydrothermal system as well as its contribution to the shallow thermal groundwater and freshwater in terms of enthalpy and chemicals require a close monitoring. The phase of unrest occurred since 2010 and culminated with an eruption in 2012, after several years of relative stability, stillmaintains amoderate alert, as required by the high seismicity and SO2 degassing. In October 2013, a sampling campaign has been performed on thermal springs and stream water, located at 2600–5000 m of elevation on the slope of Nevado del Ruiz, analyzed for water chemistry and stable isotopes. Some of these waters are typically steam-heated (low pH and high sulfate content) by the vapour probably separating from a zoned hydrothermal system. By applying a model of steam-heating, based on mass and enthalpy balances, we have estimated themass rate of hydrothermal steam discharging in the different springs. The composition of the hottest thermal spring (Botero Londono) is probably representative of a marginal part of the hydrothermal system, having a temperature of 250 °C and low salinity (Cl ~1500 mg/l), which suggest, along with the retrieved isotope composition, a chiefly meteoric origin. The vapour discharged at the steam vent “Nereidas” (3600 m asl) is hypothesized to be separated from a high temperature hydrothermal system. Based on its composition and on literature data on fluid inclusions, we have retrieved the P-T-X conditions of the deep hydrothermal system, aswell as its pH and fO2. The vapour feeding Nereidas would separate from a biphasic hydrothermal system characterized by the following parameters: t= 315 °C, P= 15 MPa, NaCl = 10 wt%, CO2=5 wt%, and similar proportion between liquid and vapour. Considering also the equilibria involving S-bearing gases and HCl, pH would approach the value of 1.5 while fO2 would correspond to the FeO-Fe2O3 buffer. Chlorine content is estimated at 10,300mg/l. Changes in the magmatic input into the hydrothermal system couldmodify its degree of vapourization and/or P-T-X conditions, thus inducing corresponding variations in vapour discharges and thermal waters. These findings, paralleled by contemporary measurements of water flow rates, could give significant clues on risk evaluation.
    Description: Published
    Description: 40-53
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: Nevado del Ruiz ; Water isotopes ; Geothermal system ; Equilibrium modelling ; Water chemistry ; 04.08. Volcanology ; 03.02. Hydrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2021-03-19
    Description: Syneruptive gas flux time series can, in principle, be retrieved from satellite maps of SO2 collected during and immediately after volcanic eruptions, and used to gain insights into the volcanic processes which drive the volcanic activity. Determination of the age and height of volcanic plumes are key prerequisites for such calculations. However, these parameters are challenging to constrain using satellite-based techniques. Here, we use imagery from OMI and GOME-2 satellite sensors and a novel numerical procedure based on back-trajectory analysis to calculate plume height as a function of position at the satellite measurement time together with plume injection height and time at a volcanic vent location. We applied this new procedure to three Etna eruptions (12 August 2011, 18 March 2012 and 12 April 2013) and compared our results with independent satellite and ground-based estimations. We also compare our injection height time-series with measurements of volcanic tremor, which reflects the eruption intensity, showing a good match between these two datasets. Our results are a milestone in progressing towards reliable determination of gas flux data from satellite-derived SO2 maps during volcanic eruptions, which would be of great value for operational management of explosive eruptions.
    Description: 1) European Research Council under the European Union's Seventh Framework Programme (FP/2.007-2013)/ERC Grant Agreement no. 279802, project 283 CO2Volc. 2) MEDiterranean SUpersite Volcanoes 280 (MED-SUV) WP 3.3.3
    Description: Published
    Description: 79-91
    Description: 5V. Dinamica dei processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Volcanic SO2 ; Trajectory modelling ; Remote sensing ; Volcanic tremor ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2021-06-30
    Description: Volcanic activity exhibits a wide range of eruption styles, from relatively slow effusive eruptions that produce lava flows and lava domes, to explosive eruptions that can inject large volumes of fragmented magma and volcanic gases high into the atmosphere. Although controls on eruption style and scale are not fully understood, previous research suggests that the dynamics of magma ascent in the shallow subsurface (〈 10 km depth) may in part control the transition from effusive to explosive eruption and variations in eruption style and scale. Here we investigate the initial stages of explosive eruptions using a 1D transient model for magma ascent through a conduit based on the theory of the thermodynamically compatible systems. The model is novel in that it implements finite rates of volatile exsolution and velocity and pressure relaxation between the phases. We validate the model against a simple two-phase Riemann problem, the Air-Water Shock Tube problem, which contains strong shock and rarefaction waves. We then use the model to explore the role of the aforementioned finite rates in controlling eruption style and duration, within the context of two types of eruptions at the Soufrière Hills Volcano, Montserrat: Vulcanian and sub-Plinian eruptions. Exsolution, pressure, and velocity relaxation rates all appear to exert important controls on eruption duration. More significantly, however, a single finite exsolution rate characteristic of the Soufrière Hills magma composition is able to produce both end-member eruption durations observed in nature. The duration therefore appears to be largely controlled by the timescales available for exsolution, which depend on dynamic processes such as ascent rate and fragmentation wave speed.
    Description: Published
    Description: 110-139
    Description: 5V. Dinamica dei processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Magma ascent ; Conduit dynamics ; Soufrière Hills Volcano ; Finite-rate exsolution ; Pressure relaxation ; Velocity relaxation ; 04.08. Volcanology ; Numerical modeling
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2017-09-11
    Description: Telica volcano, in north-west Nicaragua, is a young stratovolcano of intermediate magma composition producing frequent Vulcanian to phreatic explosive eruptions. The Telica stratigraphic record also includes examples of (pre)historic sub-Plinian activity. To refine our knowledge of this very active volcano, weanalyzedmajor element composition and volatile content of melt inclusions fromsomestratigraphically significant Telica tephra deposits. These include: (1) the Scoria Telica Superior (STS) deposit (2000 to 200 years Before Present; Volcanic Explosive Index, VEI, of 2–3) and (2) pyroclasts from the post-1970s eruptive cycle (1982; 2011). Based on measurements with nanoscale secondary ion mass spectrometry, olivine-hosted (forsterite [Fo] N 80) glass inclusions fall into 2 distinct clusters: a group of H2O-rich (1.8–5.2 wt%) inclusions, similar to those of nearby Cerro Negro volcano, and a second group of CO2-rich (360–1700 μg/g CO2) inclusions (Nejapa, Granada). Model calculations show that CO2 dominates the equilibrium magmatic vapor phase in the majority of the primitive inclusions (XCO2 N 0.62–0.95). CO2, sulfur (generally b2000 μg/g) and H2O are lost to the vapor phase during deep decompression (P N 400 MPa) and early crystallization of magmas. Chlorine exhibits a wide concentration range (400–2300 μg/g) in primitive olivine-entrapped melts (likely suggesting variable source heterogeneity) and is typically enriched in the most differentiated melts (1000–3000 μg/g). Primitive, volatile-rich olivine-hosted melt inclusions (entrapment pressures, 5–15 km depth) are exclusively found in the largest-scale Telica eruptions (exemplified by STS in our study). These eruptions are thus tentatively explained as due to injection of deep CO2-rich mafic magma into the shallow crustal plumbing system. More recent (post-1970), milder (VEI 1–2) eruptions, instead, do only exhibit evidence for low-pressure (P b 50–60 MPa), volatile-poor (H2O b 0.3–1.7 wt%; CO2 b 23–308 μg/g) magmatic conditions. These are manifested as andesitic magmas, recording multiple magma mixing events, in pyroxene inclusions.Wepropose that post-1970s eruptions are possibly related to the high viscosity of resident magma in shallow plumbing system (b2.4 km), due to crystallization and degassing
    Description: Published
    Description: 131-148
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Keywords: Telica, Nicaragua ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2017-12-13
    Description: This study focuses on the interaction among deep volcanic/hydrothermal gases, groundwater and soil gases at Vulcano Island (Aeolian Archipelago, Italy). The chemical-physical parameters of the groundwater, the total dissolved inorganic carbon (TDIC) and the isotopic composition of the CO2 dissolved in groundwater are reported and discussed. Furthermore, a comparison between soil gases and groundwater indicates that groundwater and soil gases show the same qualitative information, giving a good overall picture of the main degassing zones of a volcanic system, whereas the soil gas discharge provides an evaluation of the mass released by the deep feeding system. This approach can be a useful tool both to characterize mixing and/or interaction processes among different sources and for a monitoring of degassing activity of a volcanic system.
    Description: Published
    Description: 116-119
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 4V. Dinamica dei processi pre-eruttivi
    Description: N/A or not JCR
    Keywords: Soil CO2 flux ; Dissolved gases ; Isotope composition of CO2 ; Groundwaters ; Vulcano Island ; 03.02. Hydrology ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
    Publication Date: 2024-05-09
    Description: The carbon isotopic composition of dissolved C-bearing species is a powerful tool to discriminate the origin of carbon in thermal waters from volcanic and hydrothermal systems. However, the δ13C values of dissolved CO2 and TDIC (Total Dissolved Inorganic Carbon) are often different with respect to the isotopic signature that characterizes the potential carbon primary sources, i.e. deep hydrothermal reservoirs, magmatic gases and organic activity. The most commonly invoked explanation for such isotopic values is related to mixing processes between deep and shallow end-members. Nevertheless, experimental and empirical investigations demonstrated that isotopic fractionation due to secondary processes acting on the uprising fluids from the hydrothermal reservoirs is able to reproduce the measured isotopic values. In this paper,we investigated the chemistry of thermalwaters, collected at Campi Flegrei and Vulcano Island (southern Italy),whose origin is related to interaction processesamongmagmatic gases, meteoric water, seawater and hosting rocks. A special focus was dedicated to the δ13C values of dissolved CO2 (δ13CCO2(aq)) and total dissolved inorganic carbon (δ13CTDIC). The δ13CCO2(aq) and δ13CTDIC values in the water samples fromboth these systems ranged from(i) those measured in fumarolic gases, likely directly related to the deep hydrothermal-magmatic reservoir, and (ii) those typically characterizing biogenic CO2, i.e. produced by microbially-driven degradation of organic matter. A simple mixingmodel of the two end-members, apparently explaining these intermediate carbon isotopic values, contrastswith the chemical composition of the dissolved gases. On the contrary, isotopic fractionation due to secondary processes, such as calcite precipitation, affecting hydrothermal fluids during their underground circulation, seems to exhaustively justify both the chemical and isotopic data. If not recognized, these processes, which frequently occur in volcanic and hydrothermal systems, may lead to an erroneous interpretation of the carbon source, causing an underestimation of the contribution of the hydrothermal/magmatic fluids to the dissolved carbon species. These results pose extreme caution in the interpretation of intermediate δ13CCO2(aq) and δ13CTDIC values for the assessment of the carbon budget of hydrothermal- volcanic systems.
    Description: Published
    Description: 46–57
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 4V. Dinamica dei processi pre-eruttivi
    Description: JCR Journal
    Keywords: Thermal waters ; Carbon isotopes ; Dissolved CO2 ; TDIC ; Volcanic-hydrothermal systems ; Secondary fractionation processes ; 04.08. Volcanology ; 03.02. Hydrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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