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  • Articles  (499)
  • Chemical Engineering  (389)
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  • 1995-1999  (499)
  • Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics  (492)
  • Electrical Engineering, Measurement and Control Technology  (5)
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  • Articles  (499)
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  • 1
    ISSN: 1572-8838
    Keywords: adsorption ; dye photooxidation ; titanium dioxide
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract A two-part study was undertaken to examine the feasibility of combining a batch-recirculated photoreactor with a hollow-fibre membrane based ultrafiltration unit for heterogeneous photocatalysis applications. Methylene Blue (MB) and titanium dioxide (Degussa, P-25) were used as the test substrate and photocatalyst respectively for this study. This paper, which forms Part I of this study, describes the influence of MB concentration, recirculation flow rate, TiO2 dose, solution volume in the reservoir and solution pH on the photocatalytic reaction rate. The dark adsorption of MB on the TiO2 particle surface was also analysed. The combination of the reservoir and the annular reaction vessel could be modelled as a continuous flow stirred tank in series with a plug-flow reactor. This model predicts that the reaction rate should increase with a decrease of solution volume in the reservoir, both in the low and high substrate concentration regimes of the Langmuir–Hinshelwood kinetics formalism. This prediction was borne out by the experimental data for the low concentration regime. Part II of this series will describe experiments and modelling of the UF unit, and the operation of the combined system, respectively.
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  • 2
    ISSN: 1572-8838
    Keywords: acidic media ; adsorption ; corrosion inhibitors ; electrochemical impedance spectroscopy ; mild steel ; triazoles
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract A new class of corrosion inhibitors, namely, 3,5-bis(n-hydroxyphenyl)-4-amino-1,2,4-triazoles and 3,5-bis(n-aminophenyl)-4-amino-1,2,4-triazoles which have been labelled n-HPAT and n-APAT has been synthesized. The influence of aminotriazoles on the corrosion of mild steel in 1m HCl has been studied using weight loss and electrochemical impedance spectroscopy. Results obtained show that these compounds are very good anodic inhibitors. The adsorption of these aminotriazoles is found to obey Langmuir adsorption isotherm.
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  • 3
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    Annals of combinatorics 3 (1999), S. 451-473 
    ISSN: 0219-3094
    Keywords: 05A15 ; 82B20 ; 82B23 ; 82B41 ; staircase walks ; dyck paths ; adsorption ; staircase polygons
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract The adsorption of staircase walks and staircase polygons on the main diagonal in the square lattice is reviewed. We draw attention to the connection between adsorbing random walks in subsets of the integers and the square lattice, and this problem. The generating functions of adsorbing staircase walks and polygons are determined using several techniques, and information about the adsorption transition is found by the calculation of a critical exponent associated with it.
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  • 4
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    Journal of computer-aided materials design 6 (1999), S. 69-80 
    ISSN: 1573-4900
    Keywords: adsorption ; friction ; lubrication ; tribological system
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A molecular dynamics simulation study of friction in boundary lubrication was conducted in order to investigate the atomic-scale behavior of lubricant molecules during sliding motion. The simulated system consisted of two silicon (001) semi-infinite substrates lubricated by a three-layer film of dodecane. Silicon was modeled using the Stillinger–Weber potential, and the dodecane with the Consistent Force Field function; a novel scheme was used to generate the silicon–dodecane interaction potentials. The simulations show that dodecane molecules strongly prefer to adsorb into the ledges on the silicon surface. The orientation of the adsorbed molecules depends, however, on the concentration of the lubricant at the surface, showing a tendency to stand up at high lubricant concentrations. In sliding, the dodecane layers adsorbed on the surfaces behave as a solid, whereas the middle layer exhibits liquid-like characteristics. The friction coefficient of this well-lubricated case was calculated to be 0.08.
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  • 5
    ISSN: 1573-2746
    Keywords: contact angle transition ; wetting ; interfacial energy ; solid pb-Ni/graphite system ; adsorption
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The wetting of Pb-Ni crystals on graphite has been observed at 558 K in a Scanning Auger Microprobe. Samples were prepared so as to produce 10 μm crystals of Pb with Ni contents increasing from 0 to 0.3 wt% along one axis of the graphite substrate. In the low Ni region, the contact angle was found to decrease slowly from 119° to 98° with increasing Ni content. In the region of high Ni content, a constant contact angle of 83° was measured. In between, crystals with contact angles of 98° and 83° were observed to coexist, near the limit of solubility of Ni in Pb, indicating the presence of a first order transition in contact angle. The continuous decrease in contact angle, in the low Ni region, is due to Ni adsorption at the Pb-graphite interface, which leads to a decrease in interfacial energy. The constant contact angle in the high Ni region is associated with the precipitation of a Ni-rich phase. Various hypotheses are advanced to account for the first order transition in contact angle as a function of Ni concentration.
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  • 6
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    Journal of applied electrochemistry 28 (1998), S. 993-998 
    ISSN: 1572-8838
    Keywords: thiosulfate ; silver ; adsorption ; differential capacitance
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The differential capacitance of a polycrystalline Ag electrode was measured in a NaClO4 electrolyte containing Na2S2O3 at concentrations ranging from 0.1 to 20mm and at electrode potentials ranging from −0.9 to −0.3V vs SCE. The differential capacitance measurements were analysed to obtain the surface coverage of specifically adsorbed thiosulfate (S2O32−) as a function of both electrode potential and bulk concentration. The various forms for the adsorption isotherm at an electrochemical interface which are commonly employed are reviewed and discussed. The adsorption behaviour is best explained by the formation of image dipoles by the specifically adsorbed ions, whose energetic interactions are then dominated by repulsion of like dipoles. The adsorption data is quantitatively fit to an adsorption isotherm for interacting dipoles, yielding an effective dipole moment of 0.72D for the system S2O32−/Ag.
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  • 7
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    Journal of applied electrochemistry 28 (1998), S. 819-825 
    ISSN: 1572-8838
    Keywords: adsorption ; experimental design ; metal electrodeposition ; modelling ; voltammetry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Chromium deposition on an inert electrode is a complex process. To gain a better understanding of phenomena involved in multistep reactions we have studied such a mechanism and developed Voltasim, a new software that simulates cyclic voltammograms for a two-step metal deposition with adsorption. In addition, Voltasim is suitable for either reversible or quasi-reversible or irreversible reactions. The software was validated with experimental results obtained for the chromium deposition case. Data fitting was achieved using a screening design of experiments involving 12␣parameters.
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  • 8
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    Journal of porous materials 5 (1998), S. 275-287 
    ISSN: 1573-4854
    Keywords: activated carbons ; adsorption ; characterization ; Dubinin-Radushkevich ; carbon dioxide
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract In this paper we present adsorption isotherms of carbon dioxide on five different activated carbons from CHEMVIRON CARBON Belgium (Centaur HSV, BPL 410, F30-470, WS 42, Reactivated) and on a carbon molecular sieve from BERGBAU FORSCHUNG Gmbh (CMS II). The temperature is 303 K and the pressure ranges from 100 kPa up to 4000 kPa. Such conditions correspond to relative pressures ranging from 0.01 to 0.5. We also provide, for the same six sorbents, the nitrogen isotherms at 77 K (pressure: 0.001 to 100 kPa, relative pressure: 10-5 to 1). A theoretical treatment based on the Dubinin-Radushkevich and Stoeckli concept is presented and applied to the experimental results in order to obtain the micropore size distribution function (considered as Gaussian) of each sorbent. Using the CO2 data, it is possible to point out important structural differences between the six carbons. The theoretical treatment provides micropore size distribution functions in agreement with what is physically expected. Using N2 data, the structural differences are not so well marked. As a consequence, the structural parameters provided by the theoretical treatment are not reliable: except for the total micropore volume, they fluctuate strongly when changing the relative pressure domain of the used data.
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  • 9
    ISSN: 1435-1536
    Keywords: Key words poly(ethylene oxide) ; silica-tethered poly(methyl methacrylate) ; adsorption ; spin-label ; molecular motion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract  The spin-label method was used to study the structure and molecular motion of poly(ethylene oxide) (PEO) chains adsorbed on a silica-tethered poly(methyl methacrylate) (PMMA). Spin-labelled PEO with a narrow molecular weight distribution, having number averaged molecular weight (M N)=6.0×103, was adsorbed on the surface of the silica-tethered PMMA with various grafting ratios in carbon tetrachloride solution at 35 °C. ESR spectra were measured at various temperatures after the samples were completely dried. The ESR spectra are composed of two spectra arising from spin-labels attached to “train” and “tail” segments, which are strongly and weakly interacted with the silica surface, respectively. The fractional amount of the “tail” segments increases extremely with the grafting ratio of PMMA. Molecular mobility of the PEO chains estimated from the temperature dependence of the ESR spectra also decreases significantly with the grafting ratio of PMMA. Structure and molecular motion of the PMMA chains tethered on the silica were also studied using the spin-labelled PMMA. Consequently, parts of the PEO segments penetrate into the PMMA chains and is adsorbed on the silica surface (“train” segments), whereas parts of the PMMA segments protrude from the surface. The other PEO segments are entangled with the tethered PMMA chains (“tail” segments).
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  • 10
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    Colloid & polymer science 276 (1998), S. 52-58 
    ISSN: 1435-1536
    Keywords: Key words Dodecanephosphonic acid ; soluble monolayer ; air/water interface ; evaporation ; adsorption ; ion-selective electrodes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract  The air/water interface of the system n-dodecanephosphonic acid (H2DP)–water was studied by surface tension, ion-selective electrodes and evaporation in an electrobalance. The combination of surface tension and ion-selective electrodes measurements enables to study the adsorption of soluble surfactants above the cmc using the Gibbs’ equation. H2DP formed a nonideal monolayer at the air/water interface with A molec=0.995 nm2 below the cmc. Above the cmc there was a reduction in adsorption giving A molec=6.32 nm2, which remained almost constant in the explored concentration range. This adsorption reduction may be due to a change composition on micellization, or to a thermodynamic advantage of micellization on adsorption. The reduction in the evaporation rate of water was mainly due to the reduction of the water activity, caused by the presence of solutes in bulk. This is because the strong changes in the surface coverage did not have significant influence on the evaporation rate.
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  • 11
    ISSN: 1435-1536
    Keywords: Key words Composite particle ; temperature-sensitive ; biomolecules ; specific activity ; adsorption
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract  Temperature-sensitive micron-sized monodispersed composite polymer particles were prepared by seeded copolymerization of dimethylaminoethyl methacrylate and ethylene glycol dimethacrylate with 1.77 μm-sized monodispersed polystyrene seed particles. The change in surface property at temperature above and below 35 °C was examined by differential scanning calorimetry, trypsin activity and the adsorption/ desorption behaviors of low molecular weight cationic emulsifier as well as biomolecules.
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  • 12
    ISSN: 1435-1536
    Keywords: Key words Surface tension ; adsorption ; micelle ; entropy ; energy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The surface tension of aqueous solutions of tetradecyl-trimethylammonium chloride (TTAC) and decyltrimethylammonium chloride (DeTAC) were measured as a function of temperature at concentrations below and above the critical micelle concentration under atmospheric pressure. The entropy and energy of adsorption from the monomeric state and from the micellar state and also the entropy and energy of micelle formation for TTAC were evaluated and compared with those of dodecyltrimethyl-ammonium chloride (DTAC). The values of ΔM W s and ΔM W u for TTAC and DTAC systems show that the micelle formation is driven by the entropy at low temperatures and by the energy at high temperatures.
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  • 13
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    Journal of porous materials 5 (1998), S. 227-239 
    ISSN: 1573-4854
    Keywords: pillared clays ; cation doping ; pore structure tailoring ; adsorption
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Techniques and mechanism of doping controlled amounts of various cations into pillared clays without causing precipitation or damages to the pillared layered structures are reviewed and discussed. Transition metals of great interest in catalysis can be doped in the micropores of pillared clay in ionic forms by a two-step process. The micropore structures and surface nature of pillared clays are altered by the introduced cations, and this results in a significant improvement in adsorption properties of the clays. Adsorption of water, air components and organic vapors on cation-doped pillared clays were studied. The effects of the amount and species of cations on the pore structure and adsorption behavior are discussed. It is demonstrated that the presence of doped Ca2+ ions can effectively aides the control of modification of the pillared clays of large pore openings. Controlled cation doping is a simple and powerful tool for improving the adsorption properties of pillared clay.
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  • 14
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    Journal of porous materials 5 (1998), S. 289-303 
    ISSN: 1573-4854
    Keywords: zeolites ; design ; catalysis ; shape selectivity ; adsorption ; properties ; application
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Zeolites and molecular sieves are microporous materials with an increasing number of applications. Established applications of molecular sieves are in the field of oil refining processes, selective adsorption and ion exchange. Nowadays, zeolites come to the fore as clean, selective and recyclable catalysts in petrochemistry, e.g., in aromatic alkylation. Zeolites are considered to have a high potential for the synthesis of commodities and fine chemicals due to their molecular sized pores. Nevertheless, only a few commercial applications in fine chemical synthesis are known. Based on the essential criteria, extracted from the organic reaction under consideration, some of the potential pitfalls in selecting and screening zeolites as potential catalysts are discussed.
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  • 15
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    Tribology letters 4 (1998), S. 59-66 
    ISSN: 1573-2711
    Keywords: scuffing ; oil oxidation ; base oils ; adsorption ; Fourier transform infrared spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract In this work, the effect of base oil oxidation on scuffing was investigated. It was found that under mixed lubrication conditions there is a direct relationship between the level of base oil oxidation and the onset of scuffing, i.e., the greater the oxidation the lower the likelihood of scuffing. An oxidised base oil forms, among other products, carboxylic acids, which reduce scuffing failure in comparison with the parent oil. This was confirmed by the addition of a carboxylic acid directly to the base oil operating under the same mixed lubrication conditions. The removal of the carboxylic acids from the oxidised oil via column chromatography resulted in a scuffing failure performance equivalent to the parent oil.
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  • 16
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    Mechanics of Cohesive-frictional Materials 3 (1998), S. 1-26 
    ISSN: 1082-5010
    Keywords: anisotropy ; failure criterion ; schist ; sedimentary rock ; rock joints ; laboratory testing ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper is devoted to the assessment of some representative failure criteria in the framework of modelling the failure behaviour of strongly anisotropic geomaterials. Experimental data concerning the failure behaviour of a typical strongly anisotropic rock; the schist of Angers are first presented. Nine widely used failure criteria are then selected and classified into three groups, the mathematical continuous models, the empirical continuous models and the discontinuous weakness planes based models. This classification is made up according to the main assumptions and techniques used in each criterion to describe the strength anisotropy. The calibration of each one is carried out with respect to the laboratory data of Angers schist. Qualitative and quantitative comparisons between the selected criteria and with the experimental data are provided. © 1998 John Wiley & Sons, Ltd.
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  • 17
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    Mechanics of Cohesive-frictional Materials 3 (1998), S. 89-103 
    ISSN: 1082-5010
    Keywords: transversely isotropic material ; elliptic paraboloid failure surface ; strength differential effect ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A coordinate-free formulation of a failure criterion for transversely isotropic solids is proposed. In the three-dimensional stress space the criterion is represented by an elliptic paraboloid. The anisotropic form of the proposed criterion is based on generalization of the second invariant of the deviatoric stress and of the mean stress obtained through the introduction of a unique fourth-order tensor. For isotropic conditions, the criterion reduces to the Mises-Schleicher failure condition. It is shown that the criterion satisfactorily predicts the strength anisotropy of transversely isotropic rocks subjected to an axisymmetric stress state. The procedure for the identification of the parameters of the criterion from a few simple laboratory tests is outlined. © 1998 John Wiley & Sons, Ltd.
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  • 18
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    Mechanics of Cohesive-frictional Materials 3 (1998), S. 27-39 
    ISSN: 1082-5010
    Keywords: creep ; effective spring concept ; Kelvin chain model ; load bearing volume ; micromechanical model ; relaxation ; softening spring ; solidification ; tension softening ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An analytical constitutive model similar to the Kelvin chain rheological model associated with solidification theory, is developed for time-dependent tension softening of ageing materials like concrete. The stiffness of spring elements is allowed to vary with time via a function of load bearing volume fraction as in the solidification theory. The development of cracks reduces the load bearing volume fraction with time, so that the overall behaviour of springs is a softening type. A reduction in the load bearing volume with time ensures a gradual reduction in the spring stiffness without violating prescribed retardation times. In some circumstances, depending on the boundary conditions, the stress in a structure can remain unchanged over a period of time. During this period, any cracks in the structure will continue to experience an increased opening due to creep. In other parts of the structure, again depending on the boundary conditions, the crack opening displacements may remain unchanged over a period of time, so that the stress will relax over these parts of the structure. In a large concrete structure, creep and relaxation may be taking place simultaneously in different parts or in the same part but at different times. There is thus a need for a visco-elastic tension softening model for ageing concrete that will cater for both creep and relaxation. © 1998 John Wiley & Sons, Ltd.
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  • 19
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    Mechanics of Cohesive-frictional Materials 3 (1998), S. 41-63 
    ISSN: 1082-5010
    Keywords: elastoplasticity ; damage ; bonded geomaterials ; triaxial testing ; intact and remoulded specimen ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In order to model the various phenomena which govern the mechanical response of bonded geomaterials under monotonic loadings, an elastoplastic model coupled with an elastic model with damage was developed, taking into account both the frictional and cohesive aspects of these materials. First, the principles at the base of the model are presented, as well as the physical meaning of the parameters which were used in the elastic model with damage. In order to illustrate the capabilities of the model to reproduce the mechanical behaviour of bonded geomaterials, we simulated triaxial tests on various materials: a deep cemented clay, whose heterogeneity from one specimen to another appeared mainly due to the calcium carbonate content; an assembly of sintered glass balls; and an artificially cemented sand. In this last example, various initial mean stresses allowed us to enlighten the brittle-ductile transition which was modelled by introducing the mean confining pressure in the damage evolution law. We demonstrated that the parameters of each part of the model could be adapted to reproduce the observed general trends. For weak bonds, the elastoplastic part played the predominant role, whereas for strong bonds, the elastic part with damage governed the mechanical behaviour. © 1998 John Wiley & Sons, Ltd.
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  • 20
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    Mechanics of Cohesive-frictional Materials 3 (1998), S. 65-87 
    ISSN: 1082-5010
    Keywords: elastoplasticity ; sand ; constitutive modelling ; controllability ; instability ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The paper investigates the possibility of the occurrence of a multiplicity of homogeneous responses of soil specimens under the same incremental loading, and the associated non-controllability of the imposed loading path.It is shown that for non-associated elastoplastic strain-hardening constitutive laws, such a possibility exists even in the hardening regime. Only when the stiffness matrix is positive-definite is the incremental solution unique for any loading programme.A particular constitutive model is chosen and the shape of the loci of non-uniqueness is calculated for various loading programmes. It is shown that the conditions for the occurrence of a shear band and of a peak of the deviator stress in a triaxial undrained test can be seen as special cases of the theory presented. Accordingly, the so-called ‘instability line’ concept in undrained conditions is generalized. © 1998 by John Wiley & Sons, Ltd.
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  • 21
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    Mechanics of Cohesive-frictional Materials 3 (1998), S. 105-125 
    ISSN: 1082-5010
    Keywords: localization ; non-local damage ; Perzyna viscoplasticity ; mesh adaptivity ; Arbitrary Lagrangian-Eulerian technique ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The computational modelling of localization of deformation in cohesive-frictional materials must be carried out in a proper, accurate and efficient manner. A proper solution can be obtained by using an enriched material description such as a non-local damage model or Perzyna's viscoplasticity model. However, still a large number of finite elements is needed for an accurate description of the localization zone. To improve efficiency, mesh adaption is applied here by means of the Arbitrary Lagrangian-Eulerian (ALE) technique. The ALE technique must typically be applied in combination with an enriched material model. Otherwise, the use of a standard model gives a zero-width solution of the localization zone and therefore remeshing results in a continuing decrease of finite element size. Implementation of this method requires the addition of convective forces in the equations of motion, transport of the state variables and the formulation of a remeshing strategy. The remeshing strategy heavily determines the success of the ALE method. Three examples of wave propagation have been treated and it is shown that a suitable remeshing strategy in combination with an enriched material model leads to proper, accurate and efficient analyses of the localization process. © 1998 John Wiley & Sons. Ltd.
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  • 22
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    Mechanics of Cohesive-frictional Materials 3 (1998), S. 127-153 
    ISSN: 1082-5010
    Keywords: constitutive equations ; post-localization behaviour ; large strain ; interface model ; bifurcation ; shear band ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper addresses developments on a constitutive model able to describe the post-localized behaviour of structures composed by geomaterials. The behaviour of the shear band is defined by means of a specific non-linear constitutive equation in the framework of large strain. Concept of ‘consistency’ of this model with the CLoE model from which it is derived at the onset of localization is discussed. During the post-localization regime this model evolves in a specific way by introducing the concept of critical void ratio. After some recalls about the CLoE framework and about a Rice bifurcation analysis involving CLoE models, the basic concepts of the Daphnis model are introduced. The last part of this paper is devoted to numerical results on an initially homogeneous frictionless biaxial test. The behaviour of the sample is modelled by means of a plane Mohr Coulomb model defined in the CLoE framework and its associated Daphnis model is used to characterize the specific behaviour of the shear band in the post-localization regime. © 1998 John Wiley & Sons, Ltd.
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  • 23
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    Mechanics of Cohesive-frictional Materials 3 (1998), S. 155-180 
    ISSN: 1082-5010
    Keywords: reinforced concrete ; bond model ; plasticity ; interface ; yield surface ; modelling ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The development of an interface, non-associative, plasticity model for bond between ribbed, steel bars and concrete is discussed. The model relates average local slip and radial dilation to average bond shear stress and radial confinement stress. The model partially accounts for the response of the damaged, finite-thickness region around the bar - the bond zone. The model is developed for standard steel bars that are initially unstrained. With simplifying assumptions, data for the components of a plasticity law are extracted from a key set of experimental results. In this paper, we emphasize the development of an expression for the yield surface for monotonic loading. While the forms of the model's components are empirically derived, they qualitatively reflect the mechanics of the mechanical interaction of ribbed bars with the adjacent concrete. A characteristic length, related to the rib pattern, helps quantify this interaction. The mechanics of the bond are difficult to characterize in a simple form, but the calibrated model only requires four physical properties and reproduces with acceptable accuracy experimental results with various levels of radial confinement stress. Model refinements are suggested for future work. © 1998 John Wiley & Sons, Ltd.
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  • 24
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    Mechanics of Cohesive-frictional Materials 3 (1998), S. 181-205 
    ISSN: 1082-5010
    Keywords: cemented ; carbide ; finite ; element ; compaction ; sintering ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: We have developed a tool for simulating the press cycle and the sintering cycle of cemented carbides. A constitutive model for compaction and tensile fracture has been implemented in the explicit FE programme LS-DYNA2D, and it has been tuned to experiments of hydrostatic compression, uniaxial strain and conventional triaxial compression. The programme simulates the complete compaction cycle in a robust manner. Friction against the tooling is properly taken into account. We have further developed a constitutive model for the stress-free solid-state sintering to also account for a mechanical stress field. The sintering model is based on physical concepts, diffusion parameters, free surface energy, dimensions of carbide grains, etc. of the constituents, and was tuned to successfully simulate the unloaded and loaded sintering of simple specimens. The models of compaction and sintering have a common set of state variables, such that after the compaction cycle, and at raising the temperature the sintering starts out with proper account of the residual stress field. Finally, the potential of the model is demonstrated by simulating the production cycle of a simple WC-Co tool piece until sintering to 75% of full density. The final geometrical shape of the specimen is compared to experimental data. © 1998 John Wiley & Sons, Ltd.
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  • 25
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    Mechanics of Cohesive-frictional Materials 3 (1998), S. 229-256 
    ISSN: 1082-5010
    Keywords: finite element method ; viscous constitutive equations ; time-discrete scheme ; stability ; superstability ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The general framework of the paper deals with the finite element modelling of mechanical problems involving viscous materials such as bitumen or bituminous concrete. Its aim is to present a second-order-accurate discrete scheme which remains unconditionally superstable when used for the time discretization of the linear and non-linear viscoelastic constitutive equations considered. After stating the space- and time-continuous mechanical problem we focus on the time discretization of these equations, considering three different schemes. For both of them sufficiently small values of the time step are required in order to ensure the superstability, whereas the third remains unconditionally superstable. Eventually, some numerical results are presented. © 1998 John Wiley & Sons, Ltd.
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  • 26
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    Mechanics of Cohesive-frictional Materials 3 (1998), S. 257-276 
    ISSN: 1082-5010
    Keywords: impacts ; structural damage ; discrete element method ; dynamic loading ; scabbing ; perforation ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Impacts of rigid spherical nose shaped missiles on concrete beams are simulated with a discrete element method. The history of the structural damage of the beam is followed from the very first crushing and fracturing processes to the ultimate fragmentation step. Spalling, scabbing, penetration and perforation events are characterized and compared with real test cases of the civil engineering industry. It is found that these phenomena depend not only on the kinetic energy of the missile as predicted by some recent empirical laws but also on its momentum. This means that the dynamic impact loading time is determinant in the scabbing and perforation thicknesses. When the numerical data is plotted against the empirical rules determined from experimental data, the fit is good although the model is two dimensional. © 1998 John Wiley & Sons, Ltd.
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  • 27
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    Mechanics of Cohesive-frictional Materials 3 (1998), S. 207-228 
    ISSN: 1082-5010
    Keywords: jointed rock masses ; stability ; failure ; yield design ; homogenization ; strength anisotropy ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Conceived as a potential alternative to the methods usually employed for evaluating the stability of jointed rock masses, the homogenization approach developed in this paper stems from the intuitive idea that, from a macroscopic point of view, a rock mass intersected by a regular network of joint surfaces may be perceived as a homogeneous continuum. The failure criterion of such an equivalent medium is theoretically determined from the knowledge of the failure conditions of the individual constituents, namely the intact rock matrix and joint interfaces. Owing to the existence of privileged material directions associated with the joint orientation distribution, this criterion turns out to be of the anisotropic frictional type, as shown by the closed-form expression obtained in the particular case of two mutually orthogonal joint sets. This criterion is then applied to the investigation of two illustrative engineering problems: the calculation of the load-bearing capacity of a shallow foundation on a jointed rock half-space and the stability analysis of an excavation. Both problems are handled by means of the kinematic method of yield design, making use of the previously determined macroscopic failure condition. The upper bound estimates thus derived appear to be significantly better than those obtained from a direct analysis in which the intact rock matrix and joints are considered separately. In spite of some limitations regarding its range of applicability, which are underlined throughout the paper, the homogenization approach may constitute an appropriate general framework for the design of densely jointed rock structures. © 1998 John Wiley & Sons, Ltd.
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    Mechanics of Cohesive-frictional Materials 3 (1998), S. 277-290 
    ISSN: 1082-5010
    Keywords: experimental analysis ; slabs on soil ; reinforced concrete ; steel fibres ; fracture energy ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The cracking control of plain concrete slabs on soil foundation requires the execution of joints with mechanisms of load transfer between adjacent panels. These joints increase the construction costs and, often, are the source of local damage and loss of service performance. Slabs reinforced with steel wire mesh have been used in order to increase the load-carrying capacity and to enhance the cracking control. However, the use of this conventional reinforcement increases the costs, mainly due to labour time spent on the arrangement and positioning of the reinforcement.Fibre-reinforced concrete is a recent material well fitted for applications in industrial floors on soil foundation. The cost of fibres is compensated by a faster construction process and a reduction in the number of expansion joints. The fatigue, impact and flexural strength are significantly improved when steel fibres are added to the concrete mix.The work developed aims to contribute to the on going research effort to clarify the behaviour of fibre-reinforced concrete slabs on soil foundation. For this purpose, an experimental and numerical investigation were carried out. The present article deals basically with the experimental work developed, describing the tests performed and discussing the main results obtained. © 1998 John Wiley & Sons, Ltd.
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  • 29
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    Mechanics of Cohesive-frictional Materials 3 (1998), S. 291-303 
    ISSN: 1082-5010
    Keywords: poroelasticity ; isotropic damage ; brittle geomaterials ; enhanced consolidation ; saturated geomaterials ; computational modelling ; indentation of geomaterials ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper examines consolidation behaviour of saturated geomaterials with a matrix component which is susceptible to damage. Finite-element-based computational model accounts for the alteration in both the deformability and permeability characteristics of the porous material due to damage evolution. The isotropic damage criteria governing the evolution of elastic stiffness and hydraulic conductivity parameters are characterized by the dependency of the damage variable on the distortional strain invariant. The computational procedure is utilized to evaluate the extent to which the time-dependent axisymmetric indentation behaviour of a rigid circular punch on a poroelastic half-space can be influenced by the damage evolution in the porous skeleton. © 1998 John Wiley & Sons, Ltd.
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  • 30
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    Mechanics of Cohesive-frictional Materials 3 (1998), S. 305-322 
    ISSN: 1082-5010
    Keywords: strain localization ; finite element ; mesh sensitivity ; regularization ; gradient plasticity ; multilayered concrete beams ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A gradient-dependent plasticity theory is applied to finite element solutions of static strain localization problems. Assuming weak satisfaction of constitutive equations, a multilayered beam finite element with a mixed character is developed. The plastic strain field is discretized in addition of the displacement field. A consistent Newton-Raphson algorithm for this approach is presented. Some examples are carried out in order to illustrate the approach and verify the performances of the element. © 1998 John Wiley & Sons, Ltd.
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    Mechanics of Cohesive-frictional Materials 3 (1998), S. 365-365 
    ISSN: 1082-5010
    Keywords: Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 32
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    Mechanics of Cohesive-frictional Materials 3 (1998), S. 323-342 
    ISSN: 1082-5010
    Keywords: concrete fracture ; computational modelling ; continuum damage mechanics ; localization ; regularization ; gradient enhancement ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Classical continuum damage theory for quasi-brittle fracture exhibits an extreme sensitivity to the fineness and orientation of the spatial discretization in finite element simulations. This sensitivity is caused by the fact that the mathematical description becomes ill-posed at a certain level of accumulated damage. The ill-posedness can be removed by the use of a gradient-enhanced damage model. In this model, higher-order deformation gradients give rise to a non-local effect, which regularizes the localization of deformation and thus renders numerical analyses mesh-objective.The mesh objectivity of the gradient-enhanced damage approach is demonstrated by the application to two concrete fracture experiments: a double-edge notched bar subjected to a uniaxial, tensile load and a single-edge notched beam under anti-symmetric four-point loading. Both the initiation and the propagation of damage can be simulated. Particularly the latter aspect calls for an appropriate definition of the strain measure which governs the evolution of damage. © 1998 John Wiley & Sons, Ltd.
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    Mechanics of Cohesive-frictional Materials 3 (1998), S. 343-364 
    ISSN: 1082-5010
    Keywords: concrete modelling ; microplane model ; anisotropic damage ; consistent linearization ; localization analysis ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The paper addresses the microplane model in the context of localization analysis. Capable of reproducing experimental results of concrete specimens, the microplane model includes anisotropic damage in a natural and conceptually simple and explicit way. However, the efficiency of former microplane implementations suffers from the expense of the solution procedure being based on the secant stiffness method. Within this paper, the macroscopic constitutive equation derived by kinematically constraining the microplane strains to the macroscopic strain tensor is consistently linearized resulting in quadratic convergence of the Newton-Raphson iteration for the equilibrium equations. A fully three-dimensional model will be presented and linearized incorporating the two-dimensional case in a natural fashion. Furthermore, the localization criterion is analysed, indicating locally the onset of localization in terms of the acoustic tensor. Several examples demonstrate the features of the microplane model in predicting the material behaviour of concrete in tension and compression as well as in shear. © 1998 John Wiley & Sons, Ltd.
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    Colloid & polymer science 105 (1997), S. 6-10 
    ISSN: 1435-1536
    Keywords: Colloidal aqueous suspensions ; adsorption ; rheology ; polyethylene oxide ; phosphonate ; calcium carbonate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract New polymeric dispersing agents designed to stabilize and lower the viscosity of aqueous mineral suspensions have been synthesized and studied. These dispersants are made of a non-ionic hydrosoluble polymer (polyethylene oxide) with a functional group (diphosphonate) having a strong affinity for the mineral surfaces attached at one end of the macromolecular chains. This molecular architecture allows a brush-like adsorption at the solid surface which differs from conventional homopolymer dispersants such as polyacrylates. The adsorption of these dispersants onto calcium carbonate as a model mineral and the rheological behavior of concentrated aqueous colloidal dispersions of CaCO3 particles were studied. Strong adsorption by the polymer chain-end provides an enhanced colloidal stability of the suspensions of CaCO3 particles. The addition of the dispersing polymer causes a deaggregation of the initially flocculated CaCO3 particles, which results in a drastic reduction of the viscosity of the concentrated suspensions. Thus, the viscosity of a 20 wt% CaCO3 suspension in water at pH=11 is lowered to 2 mPa s upon the addition of a low concentration of polymer. Comparison with polyacrylate dispersants shows the advantages of such a diblock macromolecular structure with a non-ionic polymeric part at high solid contents and high ionic strengths.
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  • 35
    ISSN: 1572-8838
    Keywords: photovoltaic cells ; photoelectrochemical cells ; vapour-deposited electrodes ; PcZn thin films ; MePTCDI thin films ; electrode kinetics ; adsorption
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract As a direct comparison to all-solid state photovoltaic cells, photoelectrochemical cells consisting of n-type N,N′-dimethyl-3,4,9,10-perylenetetracarboxylic acid diimide (MePTCDI) and p-type phthalocyaninatozinc(ii) (PcZn) thin film electrodes vapour-deposited onto ITO have been investigated in aqueous ferri/ferrocyanide, p-benzoquinone/hydroquinone or I3−/I− electrolytes. The ferri/ferrocyanide cell has been studied in more detail, and the results are discussed with regard to the HOMO-, LUMO- and Fermi-energies of the materials used. A setup of the electrodes in a tandem cell could increase the efficiency of the cell due to improved light harvesting. Saturation of the photocurrent with increasing ferri/ferrocyanide electrolyte concentration at single PcZn or MePTCDI electrodes is discussed using a model of reactant adsorption prior to the charge transfer step. In addition, a decrease observed for the open-circuit voltage of the entire cell with increasing ferri/ferrocyanide concentration leads to an optimum concentration of 10−3 moldm−3.
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    Oxidation of metals 47 (1997), S. 495-506 
    ISSN: 1573-4889
    Keywords: chromia-forming alloys ; nonmetallic-element effects ; segregation ; adsorption ; surface compounds ; nucleation ; oxide grain boundaries
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The effect of S, N, and C on the oxidation of Ni 20%Cr and Fe-20%Cr was investigated by two approaches (i) using AES and LEED following oxide nucleation and growth under UHV conditions and (ii) by thermogravimetry and subsequent SEM analysis, under conditions where only adsorption/segregation of these elements and congregation of Cr occurred. Sulfur retards nucleation, inhibits lateral growth, and leads to a coarse-grained oxide with a wide network of ridges at the grain boundaries—the growth rate decreases with increasing sulfur activity. Nitrogen and carbon or rather the cosegregated Cr promote the nucleation of C2O3, which leads to many grains and grain boundaries in the oxide layer, accelerated growth and a sponge-like morphology.
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    Journal of porous materials 4 (1997), S. 5-15 
    ISSN: 1573-4854
    Keywords: pillared clay ; pore size modification ; adsorption ; cracking ; carbon
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract To enhance the adsorption selectivity of pillared clays an attempt is made to modify the initial pore size by a controlled deposition of carbon. Cracking of hydrocarbons in the pores of the pillared clay results in coke deposits which can alter the pore size. Based on the evaluation of the amount of coke, the coke density, the decrease in micropore volume, changes in the micropore size distribution and the acidity it was possible to distinguish between pore-blocking, pore-filling and pore-narrowing effects. The modification mechanisms strongly depend on the initial porous structure, the acidity (Brönsted/Lewis), the cracking conditions (static or flow) and the hydrocarbons used. The carbon deposition results in a decrease in pore volume due to pore-filling (Ti-PILC) and pore-blocking (Al-PILC) without achieving a controlled pore-narrowing but some indications for pore-entrance narrowing were found.
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  • 38
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    Journal of porous materials 4 (1997), S. 277-280 
    ISSN: 1573-4854
    Keywords: woodceramics ; porous carbon ; adsorption ; humidity sensor
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The humidity sensor characteristics of Woodceramics were investigated. The Woodceramics used in this experiment were prepared at 650–900°C. The size of specimens selected was 1 × 1 × 10 mm . One was used as-cut and the other was polished. Above 700°C, the resistance of the specimen was below 50 Ω and the decrease of resistance with increasing relative humidity was small. The specimen prepared at 650°C had a resistance of about 1 kΩ. The resistance of as-cut specimens decreased with increase in relative humidity, but that of the polished specimen did not change significantly. The difference between as-cut and polished samples was explained by the differences in surface micro-structure.
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  • 39
    ISSN: 1435-1536
    Keywords: Key words Polyelectrolyte ; adsorption ; latex ; surface charge
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract  Adsorption of a well-characterized cationic polyacrylamide (CPAM) onto the surface of a model colloid (monodisperse polystyrene latex with carboxylic functional groups) was studied over a wide range of pH (4–9) and KCl concentration (c s =10-3–0.3 M). The surface charge density of the latex particles with and without adsorbed CPAM was also measured over the same range of electrolyte compositions. The adsorbed amount of CPAM increases with increase in c s and pH. The polyelectrolyte adsorption alters substantially the surface charge density of the latex particles as compared to the polymer-free case. A large overcompensation of the surface charge by the adsorbed polyelectrolyte is established at high c s and low pH. A qualitative explanation of the observed features is put forward.
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  • 40
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    Colloid & polymer science 105 (1997), S. 72-74 
    ISSN: 1435-1536
    Keywords: Zeta potential ; static electricity ; surfactants ; viscose fibres ; adsorption
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Viscose fibres were finished with a blend of a nonionic fatty acid ethoxylate and a quarternary ammonium derivative. Zeta potential and static charging were investigated as a function of a cationic compound. There is strong evidence that the charging of the viscose fibres depends on the chemical nature of the surfactants side-groups.
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  • 41
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    Colloid & polymer science 105 (1997), S. 91-95 
    ISSN: 1435-1536
    Keywords: Surfactant ; adsorption ; pore ; curvature ; mean field ; lattice
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A mean field lattice (MFL) theory has been used to study the adsorption behaviour of nonionic surfactants in hydrophilic cylindrical pores. The theory predicts that with decreasing pore radius the absorbed amount decreases. Moreover, the step in the adsorption isotherm, which is a first-order phase transition in the mean field approximation, shifts to lower concentrations. Both effects have been observed in experiments. When an adsorbed layer is curved from convex (rod) to concave (pore) at constant area, the volume of the layer decreases. As a consequence, the stability of the layer increases and the adsorbed amount decreases.
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    Colloid & polymer science 105 (1997), S. 118-125 
    ISSN: 1435-1536
    Keywords: Langmuir monolayer ; adsorption ; X-ray reflectivity ; surface potential
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract We have investigated the interaction between a Langmuir monolayer of C20H41NH2, a long-chain fatty amine and large, multivalent, heteropolyanions (phosphotungstic acid, PTA for short) dissolved in the aqueous subphase. By using X-ray reflectivity, surface pressure and surface potential measurements, we show that the adsorption is controlled by the electrostatic interaction between the PTA molecules and the amine film. At basic pH, the amine groups are not charged and no adsorption occurs. On the contrary, at acidic pH, the amines are positively charged. The surface pressure isotherms are markedly different in presence of PTA and the surface potential measurements reveal a reversal of the surface polarity. X-ray reflectivity gives a microscopic picture of the interfacial layer. The PTA anions are adsorbed onto the charged amine head groups as a monolayer or at most a bilayer. Changing the surface density of amines allows to control the total amount of PTA adsorbed and to vary the inorganic layer thickness.
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  • 43
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    Colloid & polymer science 105 (1997), S. 130-137 
    ISSN: 1435-1536
    Keywords: Phase transition ; adsorption ; isotherm ; Brewster angle microscopy ; Gibbs monolayer ; Langmuir monolayer
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The adsorption layers of aqueous solutions of N-dodecyl-γ-hydroxy-butyric acid amide show a first-order phase transition between a fluid-like low-density phase and a condensed phase. Two-dimensional domains are formed which were visualized by Brewster angle microscopy. Theπ- A isotherms of the Langmuir monolayers show the wellknown plateau region with the critical surface pressure as the starting point for the first-order phase transition in the Langmuir monolayer. The measurements ofπ-t adsorption kinetics revealed a conspicuous inflection point at the same critical surface pressure. This inflection point is also related to the start of a first-order phase transition in the Gibbs monolayer. The results of theσ-logc isotherms are interpreted by the Frumkin's equation of state. Based on the calculated interaction parameters, the formation of a condensed phase in Gibbs monolayers is concluded. Thermodynamic behavior and morphological features of the Langmuir and Gibbs monolayers were compared and the similarities in morphology and thermodynamically properties of spread and of adsorbed molecules at the air-water interface demonstrated.
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  • 44
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    Colloid & polymer science 106 (1997), S. 24-33 
    ISSN: 1435-1536
    Keywords: Polyelectrolyte-surfactant association ; surface forces ; steric forces ; critical association concentration ; adsorption
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Interactions between negatively charged surfaces coated with cationic polyelectrolytes across solutions containing an anionic surfactant, sodium dodecyl sulphate (SDS) have been studied. Polyelectrolytes with charge densities between 100% and 10%, counted per monomer unit, were used. At low ionic strength the polyelectrolytes adsorb in a flat conformation to neutralize the negative mica surface charge. The higher the linear charge density of the polyelectrolyte, the thinner adsorbed layers are obtained. In no case could any desorption be detected when the polyelectrolyte containing solution was replaced with an aqueous polyelectrolyte-free solution. The presence of SDS at concentrations considerably below the critical micellar concentration (cmc) does in all cases result in a recharging and a considerable swelling of the adsorbed layer. This is due to a cooperative association of surfactants in the preadsorbed polyelectrolyte layer. In case of the 100% charged PCMA, the force versus distance profile displays clear oscillations. We interpret these oscillations as being caused by the spatial arrangement of SDS micelles induced by the polyelectrolyte. The oscillations in the force curve remain as the SDS concentration is increased to twice the cmc. No similar oscillations in the force distance curve are observed when the surfaces are precoated with less charged polyelectrolytes. In these cases a strong swelling of the polyelectrolyte layer is observed once the surfactant concentration reaches a critical value (well below the cmc).
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  • 45
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    Colloid & polymer science 106 (1997), S. 180-182 
    ISSN: 1435-1536
    Keywords: Rheology ; suspension ; adsorption ; polystyrene ; depletion flocculation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Storage moduli (G′) of hydrophilic and hydrophobic silica suspensions in trans-decalin and in trans-decalin solutions of polystyrene (PS) have been measured by taking account of PS adsorption. PS were adsorbed on the hydrophilic silica. TheG′ values of the hydrophilic suspensions in the presence of low molecular weight PS are similar to those without PS and they are larger than those in the presence of higher molecular weight PS. On the other hand, any PS chains cannot adsorb on the hydrophobic silica particles. TheG′ values of all hydrophobic suspensions are higher than that in trans-decalin due to depletion flocculation and they are two orders of magnitude larger than those for the hydrophilic silica suspensions.
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  • 46
    ISSN: 1573-2746
    Keywords: catalysis ; adsorption ; transition metal complexes ; designed dispersions ; metal oxide coatings ; infrared spectroscopy ; thermogravimetric analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract In many catalytic reactions, the configuration, dispersion andensemble size of the supported catalytic species have a significant impacton the activity, selectivity and product distribution of the catalyst. Byusing the method of molecular design, it becomes possible to fundamentallyoptimize these catalytic reactions, eliminating side reactions and improvingthe activity or selectivity of the catalyst, provided that the detailedreaction mechanisms and the structural dependencies are known. In thismanuscript, several examples are presented that illustrate the dramaticeffect of the ensemble size of the supported catalytic species on thecatalytic behavior. It is evidenced how supported metal oxides may beprepared to have quite different catalytic properties.
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  • 47
    ISSN: 1573-2746
    Keywords: catalysis ; adsorption ; transition metal complexes ; designed dispersions ; metal oxide coatings ; infrared spectroscopy ; thermogravimetric analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract One way to design a catalyst begins with a consideration of thereaction mechanism to the desired product so that only the chemistryrequired of that mechanism will be present on the surface. The reactionmechanism will suggest the structure(s) to be developed on the surface whichshould be stabilized against changes during operation. We believe that thisideal may be approached by decorating surfaces or porous powders with amonolayer of metal complexes having the desired structures. These complexesmay be partially decomposed to develop a high dispersion of the supportedmetal oxide.
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  • 48
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    Interface science 5 (1997), S. 159-167 
    ISSN: 1573-2746
    Keywords: adsorption ; ellipsometry ; opsonins ; PEG ; phospholipids ; polymers ; proteins ; TIRF
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Ellipsometry and total internal reflection fluorescence spectroscopy(TIRF) were used for investigating adsorption processes of relevance forparenteral administration of colloidal drug carriers. Emphasis is put ondiscussing the effects of both protein and surface properties on theadsorption of serum proteins at phospholipid and other surfaces.Furthermore, the adsorption from multicomponent protein systems, such asblood, is addressed, and both competitive and associative adsorptionphenomena discussed. The correlation between effects of the drug carriersurface properties on the serum protein adsorption and the circulation timeand tissue distribution of colloidal drug carriers is also addressed.Finally, the potential of ellipsometry in another adsorption process ofmajor importance for phagocytosis, i.e., the adsorption of colloidalparticles to macroscopic or mesoscopic surfaces, is indicated byinvestigations of the adsorption of oil-in-water emulsion droplets atsilica.
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 357-357 
    ISSN: 1082-5010
    Keywords: Engineering ; Civil and Mechanical Engineering
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 301-320 
    ISSN: 1082-5010
    Keywords: theory of porous media ; micropolar grain rotations ; liquid-saturated cohesive-frictional granular elastoplastic skeleton materials ; single-surface yield function ; non-associated flow ; shear band localization ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Elastoplastic deformations of cohesive-frictional liquid-saturated granular solid materials can be described by use of a macroscopic continuum mechanical approach within the well-founded framework of the theory of porous media (TPM). In the present contribution, the TPM formulation of the skeleton material is extended by micropolar degrees of freedom in the sense of the Cosserat brothers. Proceeding from two basic assumptions, material incompressibility of both constituents (skeleton material and pore liquid) and geometrically linear solid deformations, the non-symmetric effective skeleton stress and the couple stress tensor are determined by linear elasticity laws. In the framework of the ideal plasticity concept, the plastic yield limit is governed by a smooth and closed single-surface yield function together with non-associated flow rules for both the plastic strain rate and the plastic rate of curvature tensor. Fluid viscosity is taken into account by the drag force.The inclusion of micropolar degrees of freedom, in contrast to the usual continuum mechanical approach to the TPM, allows, on the one hand, for the determination of the local average grain rotations and, on the other hand, additionally yields a regularization effect on the solution of the strongly coupled system of governing equations when shear banding occurs. However, in the framework of the original TPM formulation of fluid-saturated porous materials, the inclusion of the fluid viscosity alone also yields a certain regularization on shear band computations. The numerical examples are solved by use of finite element discretization techniques, where, in particular, the computation of shear band localization phenomena is carried out by the example of the well-known base failure problem of geotechnical engineering. © 1997 John Wiley & Sons, Ltd.
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 321-337 
    ISSN: 1082-5010
    Keywords: thermal-softening behaviour ; transient evolution ; corner flow ; analytical solution ; convergence-confinement concept ; thermomechanical interaction ; Engineering ; Civil and Mechanical Engineering
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    Notes: A closed-form solution of deep tunnel subject to an internal pressure and to an axisymmetrical time-dependent temperature field is presented. The material is supposed to have a thermal-softening behaviour, the cohesion decreasing with the temperature. The thermal expansion generates plastic zones with face flow and corner flow, which can coexist and interact. The explicit character of the solution allows rigorous demonstrations of the evolution of such plastic zones, as well as other interesting and fundamental properties of the thermoplastic behaviour of deep tunnels. On the other hand, the causal relationship between the thermomechanical loading and the structural response (convergence, extension of rupture zones) is rendered transparent, thanks to the simplicity of the analytical solution. The consequence of thermal-softening is clearly shown by comparison with the analytical solution for a constant cohesion previously established. Quantitatively, its importance is illustrated by a restricted parametric study, to which the analytical solution is ideally suited. © 1997 John Wiley & Sons, Ltd.
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 339-356 
    ISSN: 1082-5010
    Keywords: biaxial tests ; combined stresses ; compressive strength ; engineering materials ; failure ; failure surfaces ; mathematical models ; tensile strength ; triaxial tests ; Engineering ; Civil and Mechanical Engineering
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    Notes: A general, three-dimensional failure criterion is presented. This criterion is formulated in terms of the first and third stress invariants of the stress tensor, and it involves only three independent material parameters. Although these parameters interact with one another, each parameter corresponds to one of three failure characteristics of material behaviour. These material parameters may be determined from any type of strength test, including the simplest possible, such as uniaxial compression and tension tests or biaxial tests for materials with cohesion and tensile strength, and by triaxial compression tests for materials without tensile strength. The procedure for determination of the three material parameters is demonstrated and comparisons between the failure criterion and experimental results are presented for different types of engineering materials. © 1997 John Wiley & Sons, Ltd.
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 31-46 
    ISSN: 1082-5010
    Keywords: block structure ; elasticity ; homogenization ; Cosserat continuum ; dynamics ; large deformation ; Engineering ; Civil and Mechanical Engineering
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    Notes: A continuum model for regular block structures is derived by replacing the difference quotients of the discrete equations by corresponding differential quotients. The homogenization procedure leads to an anisotropic Cosserat Continuum. For elastic block interactions the dispersion relations of the discrete and the continuous models are derived and compared. Yield criteria for block tilting and sliding are formulated. An extension of the theory for large deformation is proposed. © 1997 by John Wiley & Sons, Ltd.
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 1-29 
    ISSN: 1082-5010
    Keywords: numerical integration ; constitutive modelling ; frictional materials ; highly non-linear hardening functions ; Engineering ; Civil and Mechanical Engineering
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    Notes: Constitutive relations in elastoplasticity may be formulated in a variety of ways, and different update algorithms may be employed to solve the resulting equations. Several implicit integration schemes, although some not widely used, have been suggested in the last years. Among them, the closest point projection method (CPPM) has proven to be an effective and robust integration scheme. In order to gain maximum control of the stress projection, a two-level CPPM iteration scheme is proposed. The hardening variables are fixed during the stress projection onto consequently fixed yield surfaces, and after the stress projection, new values of the hardening variables are calculated defining new yield surfaces. The update of the hardening parameters which, in general, may be highly nonlinear functions, may be determined by a combination of a Picard Iteration (PI) on the hardening variables and an adaptative order inverse interpolation (AOII) on the difference of subsequent iterations of the hardening variables.The integration scheme has been implemented in a general constitutive driver which has been formulated independent of the selected constitutive model and easily linked to finite element codes. A third stress invariant dependent, cone-cap elastoplastic constitutive model, referred to as the MRS-Lade, with a highly non-linear hardening function has been used to show the applicability of the proposed iteration scheme. Error analyses and accuracy assessment are presented along with some representative test results. © 1997 by John Wiley & Sons, Ltd
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 71-92 
    ISSN: 1082-5010
    Keywords: undrained instability ; static liquefaction ; non-associated plasticity ; loss of uniqueness ; model validations ; very loose sand ; Engineering ; Civil and Mechanical Engineering
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    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The characteristics of the loss of stability associated with the initiation of the static liquefaction phenomenon is obtained using the CJS model within the elastoplasticity framework. This model is based on the characteristic line concept. The determining factors involved in the prediction of this phenomenon and in the modelling process are identified. The importance of the elastic components is highlighted, in particular its non-linearity. The possibilities and the limits of the proposed model to describe the undrained behaviour of very loose sand are examined, taking into consideration the effects of the more or less complex stress history. Finally, the conditions leading to the appearance of the uniqueness domain are indicated. The findings of this theoretical study rely entirely on the experimental data presented in a companion paper, with emphasis on the triaxial tests on anisotropically consolidated samples. © 1997 by John Wiley & Sons, Ltd.
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 93-120 
    ISSN: 1082-5010
    Keywords: loose sands ; load-controlled triaxial tests ; creep tests ; instability ; theoretical interpretation ; strain-rate sensitivity ; Engineering ; Civil and Mechanical Engineering
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    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A series of triaxial load-controlled tests is performed.Finite load increments are imposed. The single load-steps are followed by a time period during which the axial load is kept constant.At low stress levels the mechanical response is stable and characterized by a continuous decrease in strain rate with time. At higher stress levels, the mechanical response changes and, subsequently, the collapse takes place.The collapse is unexpected and occurs at a stress level less than that associated with the steady state, experimentally observed by performing strain triaxial controlled tests.In order to interpret such a behaviour, a theoretical discussion is introduced. This is based on a dynamical reinterpretation of the micromechani cal fabric rearrangement of granular assembly.In particular, the role played by the kinetic energy of the system, as well as that played by the anisotropy of the microstructure, have been analysed. © 1997 by John Wiley & Sons, Ltd. Mech. cohesive-frictional mater. 2, 93-120 (1997)
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 47-70 
    ISSN: 1082-5010
    Keywords: instability ; liquefaction ; laboratory tests ; undrained ; triaxial ; loose sand ; Engineering ; Civil and Mechanical Engineering
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    Notes: The undrained behavior of very loose Hostun RF sand in triaxial compression and extension tests is described. The samples are consolidated isotropically or anisotropically along constant effective stress ratio paths. Very loose sand exhibits partial liquefaction, deviator peak stress at relatively low to very low axial strain, gradual post-peak stress reduction to a small residual value at large strains, sharp loss of effective mean pressure due to generation of large pore pressure and overall volume reduction. The instability line of Lade is examined in the case of extension tests and extended for anisotropic samples. It is shown that monotonic and anisotropic consolidation strongly influences the instability concept. A higher positive anisotropic consolidation level produces a greater slope of the instability line in compression and a reverse trend can occur in extension. Complex stress history can develop a fossilized instability line depending on the amount of axial strain attained. Effective strain ratio increment at peak has an asymptotic stabilization effect. © 1997 by John Wiley & Sons, Ltd.
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 121-163 
    ISSN: 1082-5010
    Keywords: granular materials ; micromechanics ; biaxial tests ; complex loading paths ; micro-macro relations ; fabric anisotropy ; Engineering ; Civil and Mechanical Engineering
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    Notes: This paper is concerned with micromechanics of Schneebeli material specimens composed of wooden roller stacks. Several laboratory tests are carried out to analyse the material behaviour under complex loading conditions, involving loading-unloading cycles and principal axes rotations. In order to characterize micromechanical deformation features and structure evolution, a series of pictures is taken during loading. Pictures are then digitized using a stereo device, obtaining the position of each roller. Starting from these data a number of computer programs, conceived for the purpose, allow us to measure micromechanical variables and to analyse their evolution.In the following, after the description of the devices employed in this research, macromechanical results are analysed to evaluate the reliability of the laboratory model. Then, local variables are introduced and the use of continuum mechanics to describe granular materials behaviour is discussed. Finally, the evolution of local kinematic variables is described, focusing interest on the evolution of specimen anisotropy. © 1997 by John Wiley & Sons, Ltd. Mech. cohesive-frictional mater. 2, 121-163 (1997)
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 165-183 
    ISSN: 1082-5010
    Keywords: elastoplasticity ; pressure sensitive materials ; constitutive modelling ; dilatancy ; implicit integrations ; Engineering ; Civil and Mechanical Engineering
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    Notes: The paper presents the derivation of a fully implicit Newton algorithm for direct integration of constitutive equations, in extended stress-internal variable space, involving hardening or softening of a general dilatant isotropic elastoplastic geomaterial. All relevant derivatives are provided in tensor notation, thus facilitating implementation. The consistent, algorithmic tangent stiffness tensor is derived. The relative accuracy of a template algorithm is assessed on a number of examples by means of iso-error maps. We present a rather simple, one-increment example concerning convergence properties of the Newton iterative scheme at the global, finite element level, associated with the consistent tangent stiffness tensor for integrating the weak form of the equilibrium equations. © 1997 by John Wiley & Sons, Ltd. Mech. Cohesive-frictional mater. 2, 165-183 (1977)
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 185-203 
    ISSN: 1082-5010
    Keywords: fluid-saturated porous media ; enhanced element technology ; Engineering ; Civil and Mechanical Engineering
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    Notes: This contribution is concerned with a new mixed finite element formulation for geometrically linear Terzaghi-Biot type fluid-saturated porous media. To this end, an extended Hu-Washizu type mixed variational principle is presented for fluid-saturated porous continua. Then, a suitable discretization and its implementation are discussed, resulting in an improved element behaviour especially in numerical localization analyses. The intriguing element performance is firstly demonstrated for the case of localization within an elastoplastic compression problem. Finally, an elastoplastic slope stability problem is examined, whereby the new element formulation proves to render more pronounced failure modes as compared with a standard element expansion. © 1997 John Wiley & Sons, Ltd.
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 205-221 
    ISSN: 1082-5010
    Keywords: pollutant diffusion ; advection ; porous media ; surface transfer resistance ; physical modelling ; homogenization ; model classification ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: In the paper, an attempt to model local equilibrium and local non-equilibrium in pollutant migration in porous media is presented. Diffusion is assumed to occur in the pores as well as in the solid porous matrix. The macroscopic models are developed using the homogenization method (asymptotic expansion technique). The resulting macroscopic equations show either a one-concentration field or two-concentration fields or memory effects. The domains of validity of all the presented models are also determined. Local cell problems are provided to compute the effective diffusion tensors. The conditions for the local mass equilibrium assumption to be valid are derived in terms of the dimensionless characteristic parameters. The effect of pollutant source distributions is also investigated. © 1997 John Wiley & Son, Ltd.
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 223-236 
    ISSN: 1082-5010
    Keywords: granular materials ; vortices ; discrete element method ; coherent structures ; proper orthogonal decomposition ; Engineering ; Civil and Mechanical Engineering
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    Notes: Discrete element models are used to investigate the formation of coherent structures within a deforming granular material. The numerical models predict the formation of coherent vortex-like structures, even when the boundary deformations introduce zero vorticity. We name these structures circulation cells because the particles instantaneously translate and rotate as a rigid body about a common centre. They occur for all the particle shapes and material properties tested. The size of these coherent structures range from approximately 20 to 600 particles, with the largest structures being limited by the test boundaries. Circulation cells are seen to play an important role in granular deformations including the formation of shear bands. © 1997 John Wiley & Sons, Ltd.
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 237-249 
    ISSN: 1082-5010
    Keywords: concrete ; confinement ; dilation ; fibres ; plastics ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Confinement of concrete enhances it strength and ductility by restraining lateral dilation. The accuracy of a confinement model depends on how well it captures the dilation tendency of concrete. In recent years, external confinement of concrete by fibre composites has become increasingly popular for civil infrastructure applications. This includes fibre-wrapping of existing columns or encasement of concrete in a fibre reinforced plastics (FRP) shell. A total of 54-concrete-filled FRP tubes were tested in uniaxial compression under displacement control mode. Full instrumentation of the specimens has allowed the variation of tangent Poisson's ratio for concrete to be captured. The dilation trend of confined concrete is shown to be a function of jacket stiffness. In steel-encased members, once steel yields, confining pressure becomes constant and the jacket renders itself ineffective in containing the dilation of concrete. On the other hand, for linear-elastic materials such as fibre composites, a strain reversal occurs that results in containment of dilation. A method for predicting the dilation is developed that can be easily adopted in any active confinement model. Moreover, a new confinement model for FRP-encased concrete is discussed. © 1997 John Wiley & Sons, Ltd.
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 279-299 
    ISSN: 1082-5010
    Keywords: constitutive model ; hypoplasticity ; plasticity ; grain contacts ; intergranular strain ; strain-space plasticity ; recent history ; small strain ; ratcheting ; Engineering ; Civil and Mechanical Engineering
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    Notes: In order to eliminate ratcheting a so-called intergranular strain has been added to a hypoplastic constitutive model. This additional state variable represents the deformation of the interface layer between the grains. The new concept is outlined and comparisons with and without intergranular strain are presented. Some comments on numerical implementation and determination of material constants are made. A discussion on the uniqueness of the solution and objectivity of the rate of intergranular strain is added. © 1997 John Wiley & Sons, Ltd.
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    Mechanics of Cohesive-frictional Materials 2 (1997), S. 251-278 
    ISSN: 1082-5010
    Keywords: Pietra Leccesse chalk ; laboratory tests ; constitutive modelling ; capillary forces ; partial saturation ; collapsible rocks ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Experiments on Pietra Leccese chalk revealed that many of the material parameters describing its mechanical behaviour, such as the Young's modulus, the uniaxial compressive strength and the plastic yield stress, depend strongly on the water saturation and the ensuing capillary suction. The experimental results show that Bishop's generalized effective stress is not by itself adequate to explain the observed behaviour and in particular the spontaneous collapse which may occur upon water injection under stress. An elastoplastic constitutive model for partially-saturated collapsible rocks is proposed where the capillary suction is assumed to affect primarily the material properties related to the intergranular cohesion, such as the elastic stiffness, the plastic tension cut-off and pressure cap parameters. The model builds upon the well- established Mohr-Coulomb theory of elastoplasticity by including a pressure cap and considering the water saturation as an internal variable. In low levels of water saturation, as is often the case in oil reservoir formations, the experimental and theoretical results demonstrate the potential significance of capillary effects on the response of reservoir rocks, a mechanism that has been largely underestimated in the petroleum industry. © 1997 John Wiley & Sons, Ltd.
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    Journal of porous materials 3 (1996), S. 5-16 
    ISSN: 1573-4854
    Keywords: carbon molecular sieve ; adsorption ; adsorption kinetics
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    Notes: Abstract Equilibrium and kinetics of oxygen and nitrogen sorption in two different carbon molecular sieves (CMS) have been modeled. In both CMS materials, equilibrium characteristics are adequately described by the Langmuir model. However, for kinetics of sorption, one CMS followed classic Fickian diffusion, while the other sample did not. A mathematical model was developed which accurately describes both pure component as well as binary uptakes in both materials. Simple manipulation of the boundary condition of the diffusion process allows the model to accurately predict both Fickian and surface barrier diffusion. All parameters needed to estimate binary uptake rates are obtained from pure component uptakes and isotherms. In addition, the model predicts both pure component and binary diffusion rates with diffusion coefficients which are not concentration dependent.
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    Journal of porous materials 3 (1996), S. 257-266 
    ISSN: 1573-4854
    Keywords: pillared clay ; pore size modification ; adsorption ; polymers ; carbon
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract In order to use pillared clays (PILC) for selective adsorption, further modifications of the porous structure are necessary. The deposition of carbon residues onto the porous structure of pillared clays by the carbonization of polymers (polyvinylalcohol) was proposed to achieve a controlled modification of the pore size. Ti and Al-pillared clays (calcined and non-calcined) were impregnated with PVA (different grades and different concentrations and subsequently carbonized to form carbon phases. The effect of the carbon deposits on the porosity of Ti- and Al-PILC is discussed in terms of pore-blocking, pore-filling and pore-narrowing. The deposition of carbon using PVA resulted in a complete pore-blocking for Al-PILC and in a narrowing of the pore size distribution for Ti-PILC, without achieving a controlled pore-narrowing.
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  • 68
    ISSN: 1573-8868
    Keywords: mass transport ; 2-D advection-dispersion ; adsorption ; particle tracking
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    Topics: Geosciences , Mathematics
    Notes: Abstract A new method for solving the transport equation based on the management of a large numbe of particles in a discretized 2-D domain is presented. The method uses numerical variables to represent the number of particles in a given mesh and is more complex than the 1-D problem. The first part of the paper focuses on the specific management of particles in a 2-D problem. The method also would be valid for three dimensions as long as the medium can be modeled similar to a layered system. As the particles are no longer tracked individually, the algorithm is fast and does not depend on the number of particles present. The numerical tests show that the method is nearly numerical dispersion free and permits accurate calculations even for simulations of low-concentration transport. Because each mesh is considered as a closed system between two successive time steps, it is easy to add adsorption phenomenon without any problem of numerical stability. The model is tested under conditions that are extremely demanding for its operating mode and gives a good fit to analytical solutions. The conditions in which it can be used to best advantage are discussed.
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    Colloid & polymer science 274 (1996), S. 548-554 
    ISSN: 1435-1536
    Keywords: Polyacrylic acid ; γ-Al2O3 ; mercury surface ; adsorption ; voltammetry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract In this paper the adsorption of polyacrylic acid (MW=5000) on the hydrophobic mercury surface and on the hydrophilic γ-Al2O3 surface at pH=3–4 in 0.55 M sodium chloride solution was investigated. Measurements of change of the double layer capacitance by phase selective a.c. voltammetry were used for determination of the adsorption of polyacrylic acid on the mercury electrode. The same method was used for the determination of the polyacrylic acid remaining in the solution after the adsorption on hydrophilic particles (γ-Al2O3 particles). The results obtained for adsorption of polyacrylic acid were compared to the results of the adsorption of humic substance of similar molecular weight under similar experimental conditions. The study has shown that polyacrylic acid in acidic solution is strongly adsorbed on the mercury surface, which is comparable to the adsorption of humic substance on the mercury surface. At the same time, the adsorption/deposition of polyacrylic acid on the γ-Al2O3 surface is weaker compared to humic acid, indicating at a smaller degree of interaction of polyacrylic acid with aluminium ions and with hydrophilic surface.
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    Colloid & polymer science 274 (1996), S. 779-787 
    ISSN: 1435-1536
    Keywords: Silica particles ; colloid stability ; Hamaker constant ; van der Waals potential ; adsorption ; rheology ; SAXS
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Hydrophilic Stöber silica particles are stable in ethanol, but flocculation may be induced by the addition of sufficient cyclohexane. Low-shear rheological measurements indicated non-Newtonian behaviour beyond the critical cyclohexane concentration. The thickness and composition of the solvation layer around the particles were calculated from the adsorption excess isotherm on the basis of a multilayer adsorption model. The composition dependences of the Hamaker constants of the dispersion medium and the adsorption layer were obtained from optical dispersion measurements. A single-sheet, hard-sphere model predicted a weak van der Waals attraction in the ethanolic regime, but a strong attraction in the cyclohexane-rich region, in good accordance with the rheological properties of the dispersions and visual observations.
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  • 71
    ISSN: 1435-1536
    Keywords: Sodium dodecylsulfate ; adsorption ; precipitation ; montmorillonite
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The interaction of dodecylsulfate anions (DS−) with homoionic Ca-, Mg-, Ni-, Cu-, Cd-, Pb- and Fe-montmorillonites were investigated. Mg- and Cd-montmorillonite do not adsorb DS−, and an anion exchange at the edges of the clay mineral does not take place. Three different adsorption processes are identified on the other montmorillonites: i) Fe-montmorillonite is covered with amorphous iron hydroxide, and DS−-anions are bound at positively charged sites. ii) On Ca- and Pb-montmorillonite DS− is precipitated as Me(DS)2. iii) On Ni- and Cu-montmorillonite DS− forms ion pairs with the cations on the surface. In all cases DS− is not bound above the CMC but the metal ions are mobilized from the surface either by solubilization of the precipitates or by formation of mixed micelles.
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  • 72
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    Colloid & polymer science 274 (1996), S. 112-116 
    ISSN: 1435-1536
    Keywords: Temperature-sensitive ; emulsifier ; biomolecules ; adsorption ; surface
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Adsorption and desorption behaviours of emulsifiers and biomolecules on the two kinds of temperature-sensitive composite polymer particles were compared. One (I) was produced by seeded emulsion copolymerization of dimethylaminoethyl methacrylate and ethylene glycol dimethacrylate with 0.17 μm-sized polystyrene seed particles. The other (II) was produced by seeded emulsion copolymerization of N-isopropylacrylamide (NIPAM) and N,N′-methylenebisacrylamide with 0.36 μm-sized styrene-NIPAM copolymer particles. The amount of adsorption at temperatures above each lower critical solution temperature (LCST) was found to be much higher for I than II. In both cases, at temperatures below the LCST, almost all lactalbumin hydrolysate molecules adsorbed above the LCST were desorbed but the desorptions of adsorbed egg albumin and lysozyme molecules were not so high. The adsorption and desorption were reversible for both particles and the efficiency was better for I than II. From these results, it is concluded that the adsorption/desorption of protein onto the temperature-sensitive polymer particles is controllable by changing the temperature below and above the LCST of the shell layer and the sensitivity is based on the surface property of the composite polymer particles.
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  • 73
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    Journal of porous materials 3 (1996), S. 247-255 
    ISSN: 1573-4854
    Keywords: adsorption ; micropore characterization ; activated carbon ; Dubinin-Astakhov equation ; Dubinin-Radushkevich equation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The characterization of the pore structure of microporous materials is of interest because of the usefulness of these materials in many applications. Of these, the characterization of carbon adsorbents is particularly problematic because of the presence of small pores with size on the order of small molecules (micropores) along with a wide distribution of pore sizes, and their non-crystalline structure. In this paper, we present results obtained using the Dubinin-Astakhov equation to analyze data from high pressure CO2 adsorption at 273 K to characterize two sets of microporous carbons. Our results support the conclusions of previous workers that the Dubinin-Astakhov (DA) equation is able to linearize adsorption data that gives rise to curved Dubinin-Radushkevich plots. However, when applied over different ranges of relative pressure on the adsorption isotherm, the Dubinin-Astakhov plots result in different values of micropore volume and characteristic adsorption potential. Furthermore, DA analysis of CO2 (273 K) adsorption data over a wide range of pressures (10−3–22000 Tort), gives results different from DA analysis of CO2 (273 K) isotherms measured at low pressures only (10−3–830 Tort). It would appear desirable to apply the DA equation to data that reflects the entire range of micropore filling on the adsorption isotherm, as opposed to data over a limited relative pressure range. For CO2 adsorption at 273 K, this would necessitate adsorption studies at high pressures, to about 28 atm. Micropore volumes obtained in this manner, agreed with the total pore volumes determined by nitrogen (77 K) adsorption for all the activated carbons studied.
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  • 74
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    Mechanics of Cohesive-frictional Materials 1 (1996), S. 1-24 
    ISSN: 1082-5010
    Keywords: jointed rocks ; strength criterion ; homogenization method ; yield design ; anisotropy ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A comprehensive three-dimensional formulation for the strength criterion of regular jointed rocks is derived in this paper. The approach is based upon the implementation of the homogenization method of periodic media within the framework of the yield design theory. A rigorous explicit expression of the macroscopic criterion is given as a function of the strength properties of the intact rock and of the joints modelled as interfaces. Attention is focused on the particular case of an infinitely resistance intact rock. It is shown in particular how the relevant velocity jumps for the homogenized medium can be characterized from the introduction of the set of admissible stress vectors acting upon an elementary surface. The results make it possible to perform the static and kinematic approaches in order to address the stability analysis of rock masses cut by sets of regular joints, even for the three-dimensional geometries.
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  • 75
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    Mechanics of Cohesive-frictional Materials 1 (1996), S. 45-73 
    ISSN: 1082-5010
    Keywords: loose sand ; load controlled triaxial tests ; creep tests ; time dependency delayed mechanical response ; elasto viscoplasticity ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The time dependency of loose sands mechanical behaviour has been experimentally analysed and theoretically interpreted. A series of load controlled triaxial tests, by imposing finite load increments, has been performed. The single load increments are followed by variable time periods, in order to carry out many classical creep tests.According to the authors, the considered time dependency is due to the internal fabric rearrangement of the granular assembly, i.e. to the plastic strain development with time.This mechanical peculiarity is theoretically interpreted by means of an elastoviscoplastic constitutive model. This is a very simple extension of a previous incremental elastoplastic constitutive model and appears to be capable to reproduce experimental data quite well.Finally, the importance of the considered time dependency is underlined, both by considering numerical solutions and in analysing unstable natural and experimental phenomena.
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  • 76
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    Mechanics of Cohesive-frictional Materials 1 (1996), S. 25-44 
    ISSN: 1082-5010
    Keywords: shear waves ; spontaneous liquefaction ; stability ; hypoplasticity ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A theoretical study of plane shear waves in a fully saturated granular medium is presented using a hypoplastic constitutive relation for the solid constituent. Dynamic equations for small disturbances about an initial state are derived and analysed with constitutive parameters for Karlsruhe sand. Permanent changes in stresses during the propagation of waves are shown to result in the liquefaction of the material. As follows from the equations, in the general case the propagation is characterized by two different wave speeds, corresponding to the plus or minus sign of the velocity gradient, i.e. to different directions of an instantaneous shear. The values of the wave speeds depend on the initial state (stresses and void ratio) as well as on the orientation of the wave with respect to the principal stresses of the initial stress tensor. If the granular material is loose enough and the initial stress state differs from the hydrostatic one, it is possible that one of the wave speeds becomes imaginary, i.e. physically does not exist. This case means a loss of stability of the body in the sense that a small boundary disturbance results in a flow of the whole mass which cannot be prevented by a boundary control. Such a solution can be viewed as a model of spontaneous liquefaction. The condition obtained for stability is compared with the one derived from the analysis of the second-order work.
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    Mechanics of Cohesive-frictional Materials 1 (1996), S. 75-94 
    ISSN: 1082-5010
    Keywords: concrete modelling ; softening plasticity ; fracture energy models ; stress return ; five parameter model ; improved predictors ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Several computational aspects of the fracture energy based softening plasticity model for plain concrete are considered. A need for a more robust stress return strategy is identified, as the basic closest point projection algorithm leads to regions of nonconvergence, associated with zones of high curvature near the compressive meridian close to the apex. The use of an intermediate stress return to an auxiliary surface to establish an improved predictor is proposed, in conjunction with a controlled scaling of stress return increments, ensuring convergence and providing an efficient and robust stress return strategy.
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  • 78
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    Mechanics of Cohesive-frictional Materials 1 (1996), S. iii 
    ISSN: 1082-5010
    Keywords: Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 79
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    Mechanics of Cohesive-frictional Materials 1 (1996), S. 95-114 
    ISSN: 1082-5010
    Keywords: multiphase material ; strain localisation ; averaging theories ; pore pressure ; cavitation ; finite element method ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: It is recalled that negative water pressures are of importance in localisation phenomena of fully saturated, undrained samples of dilatant geomaterials. A model to simulate cavitation phenomena connected with such pore water tractions is developed and implemented in a simplified form in a dynamics code for partially saturated porous media. A case of localisation is studied from the onset of the instability up to the full developed shear band. The weak mesh dependence of the maximum effective plastic strain, due to the employed physical model, is also shown.
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    Mechanics of Cohesive-frictional Materials 1 (1996), S. 115-127 
    ISSN: 1082-5010
    Keywords: concrete ; fracture ; uniaxial compression tests ; boundary restraint ; slenderness ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Localization of deformations has been investigated in a series of displacement controlled uniaxial compression experiments. Of main interest are the effects of specimen slenderness and friction between loading platen and specimen. Both effects have a direct influence on the development of localized fracture zones in the specimen. The results indicate that the use of a double layer of teflon with an intermediate layer of grease yields size-independent results as far as the pre-peak stress-strain behaviour and the peak strength are concerned. However, in terms of stress and strain, a significant influence of both the specimen slenderness and the amount of boundary restraint has been observed in the post-peak regime. It is found that the post-peak curves become almost completely identical when they are plotted in terms of nominal stress and post-peak displacement. For any type of loading platen used, the post-peak relative stress-displacement curves are found to be independent of the specimen height. Furthermore, since during post-peak localization relative sliding and movements of larger parts of the specimen are observed, the definition of a unique Poisson's ratio is virtually impossible.
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    Mechanics of Cohesive-frictional Materials 1 (1996), S. 129-144 
    ISSN: 1082-5010
    Keywords: damage ; void growth ; softening ; localisation ; bifurcation ; rupture ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An extension of the theory of elastic material with voids to the case where the material undergoes an irreversible void growth is presented. The particularity of this theory is that the continuum is described by two kinematic variables: the displacements and the variation of the volume fraction of material in the porous continuum. Motion is controlled by two governing equations, the classical one involving the displacement or stresses and another one that involves the other kinematic variable, similar to the governing equation in heat conduction problems. The degradation of the elastic moduli is described in the model by a damage scalar variable. A simplified model where the damage variable is proportional to the irreversible variation of volume fraction of material is discussed. From the governing equations, it is deduced that the equation which governs the growth of damage involves the second gradient of damage and a material parameter which plays the role of an internal length according to the analysis of strain localisation. The finite element implementation of the theory is briefly presented. The two variables are discretised separately and the form of the equations to be solved is similar to those obtained in coupled thermoelasticity. One dimensional finite element results of strain localisation show that a proper convergence upon mesh refinement is obtained. The equation which governs the irreversible variation of volume fraction (or the damage growth) acts as a localisation limiter.
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  • 82
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    Mechanics of Cohesive-frictional Materials 1 (1996), S. 145-163 
    ISSN: 1082-5010
    Keywords: constitutive model ; hypoplasticity ; failure criterion ; flow rule ; dissipation function ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Failure criterion, flow rule and dissipation function derived from a class of incrementally non-linear, so-called hypoplastic, constitutive equations are presented. Although the hypoplastic model is developed without recourse to some concepts pertinent to pasticity theory, such as failure surface, plastic potential, flow rule and decomposition of deformation into elastic and plastic parts, it is shown how these concepts may be obtained as natural outcomes of the constitutive model. A connection of the hypoplastic model to Truesdell's hypoelasticity theory and of the derived failure criterion and flow rule to their hypoelastic counterparts is made. By defining the plastic strain rate properly, the dissipation surface is obtained based on the principle of maximum entropy production. Furthermore, the plastic potential is constructed with reference to the direction of plastic strain rate. Finally, the failure surface, flow rule and dissipation surface obtained with a specific hypoplastic constitutive equation are presented and compared with experimental results in the literature.
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    Mechanics of Cohesive-frictional Materials 1 (1996), S. 199-218 
    ISSN: 1082-5010
    Keywords: homogenization ; granular material ; yield surface ; elasticity ; plasticity ; modelling ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Using a homogenization framework, this paper proposes a description of the non-reversible behaviour of granular materials. First the basic equations are reviewed and some general elasticity results are presented with a comparison to DEM simulations. The global non-reversible behaviour is introduced by the definition of local conditions of contact stability: loss of contact and sliding. The first consequence is the possible definition of global yield surfaces and thus failure surfaces. These surfaces are compared to the usual plastic criteria. The influence of the different homogenization parameters introduced by the definition of localization and averaging operators is also studied. In the last section, a simulation of non-reversible behaviour is presented. Comparisons to experimental data are made in the case of simple loading paths (isotropic compression, triaxial test) as well as in complex loading histories.
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    Mechanics of Cohesive-frictional Materials 1 (1996) 
    ISSN: 1082-5010
    Keywords: Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Mechanics of Cohesive-frictional Materials 1 (1996), S. 219-234 
    ISSN: 1082-5010
    Keywords: effective stress ; theory of mixture ; compressibility ; pore-water pressure ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The effective stress concept in geomechanics advocated by Terzaghi is historically reviewed and the mechanical interpretation of this concept is clarified based on the theory of mixtures. In the interpretation of the effective stress concept, both the compressibility of the constituents and the balance of force are taken into consideration. The effectiveness of the effective stress comes from the fact that the descriptions of the effective stress in undrained and unjacketed conditions are approximately equal, although the role of the pore-water pressure under different test conditions is not the same. It is shown that the effective stress concept is also applicable to soft rock. Finally, classical interpretations and various definitions of the effective stresses are critically examined.
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    Mechanics of Cohesive-frictional Materials 1 (1996), S. 165-197 
    ISSN: 1082-5010
    Keywords: creep ; dilatancy ; damage ; stability ; failure ; galleries ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An analysis of stability of rectangular-like galleries or caverns is developed from the point of view of creep, creep failure and short-time failure. The initial stress distribution around the cavern just after excavation is obtained with an exact elastic solution. Further this solution is used in conjunction with an elastic/viscoplastic non-associated constitutive equation to determine first the domains around the excavation where the rock becomes dilatant, where compressible, and where a short-time failure is expected. This constitutive equation is further used to determine the creep of the rock around the opening, and where and when a creep failure is to be expected due to excessive dilatancy. It is shown that the location of the incipient creep failure depends on the stress concentration due to the presence of the ‘corners’, on the possible elongated shape of the cavern, and also to the stress concentration induced by the far field stresses. This location also depends on the internal pressure and on depth, and it can be determined quite accurately. Thus the location of incipient creep damage depends on a variety of parameters and the determination of this exact location is very important, and is described in this paper. It is shown that the evolutive damage is spreading mainly in the direction of minimum far field stresses or in the direction of greater elongation of the cross-section. The same constitutive equation allows us to determine the creep convergence (or divergence) of the walls, where this creep is quite fast and when for the first time the incipient creep failure due to dilatancy is to be expected. This timing depends primarily on the magnitude of octahedral shear stress. The time up to creep failure is shorter if this stress is larger (close to the short-term failure value), but tends towards infinity if the stress is relatively small (close but still above the compressibility/dilatancy boundary). Once the various failure modes are well understood the orientation and magnitude of far field stresses can be determined by this analysis if not known a priori. Also, once the location of losing the stability and that of the volume of rock involved in fast creep and creep failure are determined, one can suggest the optimal design of a support. The way in which the stress variation is influencing the above mentioned problem will be discussed in forthcoming papers. While the authors recognize the importance of the pre-existing rock discontinuities in the overall cavern stability, it was thought that a better understanding of this stability starts from analyzing a rock without such pre-existing discontinuities. The examples are given for rock salt.
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    Mechanics of Cohesive-frictional Materials 1 (1996), S. i 
    ISSN: 1082-5010
    Keywords: Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Mechanics of Cohesive-frictional Materials 1 (1996), S. 235-249 
    ISSN: 1082-5010
    Keywords: boundary element method ; concrete ; fracture mechanics ; fictitious crack model ; crack growth ; contact mechanics ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A boundary element formulation for the analysis of pullout behaviour of an anchor bolt embedded in concrete is presented. The pullout analysis involves modelling two different bodies (i.e. anchor head and concrete) which are in contact over a certain region. The fracture of concrete is represented by the fictitious crack model (FCM) in which the fracture zone is replaced by applying closing forces on both crack surface. The FCM in conjunction with the boundary element method (BEM) allows the simulation of crack growth in concrete in a straight forward manner without remeshing. The crack path need not be known in advance as it is calculated during the iteration process. The numerical results obtained are compared with the round-robin analysis of pullout test proposed by RILEM TC 90-FMA.
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    Mechanics of Cohesive-frictional Materials 1 (1996), S. 251-271 
    ISSN: 1082-5010
    Keywords: constitutive law ; plasticity ; hypoplasticity ; asymptotic state ; limit surface ; sand ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A hypoplastic theory for granular materials developed by Gudehus and Bauer is discussed. The description of asymptotic states is of particular interest. Three forms of asymptotic states are defined. Useful criteria to describe the tensorial part of the constitutive relation is developed for one of them, namely for the critical states. The terms proposed by Wu are correlated to the well-known formulations of elastic plastic theory: the Drucker/Prager model and the yield condition by Matsuoka/Nakai. The suitability of the Matsuoka/Nakai criterion for critical states is discussed.Specification of tensorial functions follows in two steps. First the hypoplastic Drucker/Prager model is developed, and then the limit condition by Matsuoka/Nakai is implemented. The resulting tensorial functions require the critical friction angle as the only material constant. The limit condition in critical states obtained from the hypoplastic law coincide with the one by Matsuoka/Nakai. A more comprehensive hypoplastic constitutive relation based on these new tensorial functions is discussed and applied to simulations of element tests. These numerical results are compared with experimental results for sand.
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    Mechanics of Cohesive-frictional Materials 1 (1996) 
    ISSN: 1082-5010
    Keywords: Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Mechanics of Cohesive-frictional Materials 1 (1996), S. 273-294 
    ISSN: 1082-5010
    Keywords: homogenisation ; layered media ; non-linear analysis ; plasticity ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: In this article attention is given to the homogenisation of periodic layered materials. Based on the assumption of a homogeneous state of stress and strain in each layer, a novel matrix formulation capable of representing the elastic behaviour of the composite material is established. The matrix formulation yields a much clearer implementation of linear elastic homogenisation algorithms and a relatively straightforward extension to inelastic behaviour. The theory of plasticity, which is adopted to describe the inelastic behaviour, follows modern concepts, including a unconditionally stable implicit Euler backward return mapping, a local Newton-Raphson method and a consistent tangent stiffness matrix. A comparison between the homogenised continuum and the standard continuum with an exact discretisa tion of the geometry of the composite shows excellent agreement, both in the presence of elastic and inelastic material behaviour.
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    Mechanics of Cohesive-frictional Materials 1 (1996), S. 295-304 
    ISSN: 1082-5010
    Keywords: creep ; effective spring concept ; micromechanical model ; relaxation ; rheological model ; softening-type spring ; tension softening ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A methodology that combines a rheological model for viscoelastic behaviour with a micromechanical model for tension softening through the effective spring concept is developed for materials exhibiting both tension softening and time-dependent behaviour. Spring elements with softening characteristics and dashpot with varying viscosity are used for this purpose. The characteristics of the spring elements and dashpot are obtained from a micromechanical model which relates the microstructure of the material to its tension softening response. The softening-type springs ensure gradual reduction in stiffness, whereas the dashpot with varying viscosity ensures that the retardation and relaxation times equal prescribed values. In this way, both the stress and crack opening are allowed to vary with time to reflect the real behaviour of a time-dependent tension softening material. The methodology is illustrated on the simple Poynting- Thompson rheological model, without restricting its application to more sophisticated models.
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    Mechanics of Cohesive-frictional Materials 1 (1996), S. 305-319 
    ISSN: 1082-5010
    Keywords: concrete structures ; alkali-aggregate reaction ; plasticity ; finite elements ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In this paper a simple continuum theory, as recently proposed by Pietruszczak (Int. J. Computers Struct., 58, 1093-1099 (1996)), is applied to describe the mechanical effects of the alkali-aggregate reaction in concrete structures. The formation of alkali- silica gel leads to a progressive expansion of the material. The progress in the reaction is assumed to be coupled with the degradation of mechanical properties, the latter described within the framework of elastoplasticity. The paper discusses the details of the numerical implementation of the constitutive model, including an implicit integration scheme and the computation of an updated tangent operator. Numerical examples are provided to assess the performance of the proposed algorithm. The formulation is then used to analyse the junction between the right-wing dam and the water intake structure of the Beauharnois powerhouse situated in Quebec (Canada). A non-linear 3D finite element analysis is performed simulating the time history of the deformation due to continuing reaction.
    Additional Material: 9 Ill.
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  • 94
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    New York, NY [u.a.] : Wiley-Blackwell
    Mechanics of Cohesive-frictional Materials 1 (1996), S. 349-366 
    ISSN: 1082-5010
    Keywords: damage ; fracture energy ; homogenisation ; masonry ; mesh dependence ; unilateral effect ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: By considering masonry as a composite material, its mechanical properties are obtained by taking into account the properties of the components (bricks and mortar) through a homogenisation technique. To describe the behaviour of the material components a unilateral damage model is proposed. This model, based on the introduction of three damage variables, describes the behaviour of brittle materials subjected to alternating tensile-compressive cyclic loads. The model is applied to the simulation of tests on masonry panels and miniaturised walls; numerical results are discussed and successfully compared with experimental data.
    Additional Material: 14 Ill.
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  • 95
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Mechanics of Cohesive-frictional Materials 1 (1996), S. 321-347 
    ISSN: 1082-5010
    Keywords: damage ; dilatancy ; failure-modes ; fractures ; localization ; shear ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A model is presented based on the non-local damage theory. It sets out to describe the behavior of concrete under free-variable loads, which are constant in sign. Its purpose is to analyze shear behavior and high strain-gradient localized problems, and it takes Mazar's model as a starting point with reference to the basic idea of a scalar isotropic non-local damage controlled by principal tensile strains. In addition, the other two main features are an internal variable denoted to the control or reversible volumetric expansion in compression, and irreversible strains aimed at modelling crushing in compression and cracks both in tension and compression. As a consequence, induced-anisotropy, dilatancy and path-dep endency can be reproduced. In particular, the modelling of micro- and macrocracks makes it possible to capture mixed-mode cracking as well as aggregate interlock, which requires a residual stiffness to guarantee the transmission of transversal and normal stresses for assigned slips. The model requires the knowledge of the material response in uniaxial tension and compression, and biaxial compression tests which can be introduced directly by adopting experimental curves, or by means of a reduced number of parameters. The effectiveness of the model is shown through comparisons with several sets of experimental tests on both small specimens, assumed to be homogeneous, and boundary value problems.
    Additional Material: 18 Ill.
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  • 96
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Mechanics of Cohesive-frictional Materials 1 (1996), S. 367-383 
    ISSN: 1082-5010
    Keywords: plasticitity ; isotropy ; Mohr-Coulomb ; consistent linearization ; algorithmic tangent stiffness ; multisurface plasticity ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In this paper, we discuss the efficient treatment of yield criteria that are of the Mohr-Coulomb type for elastic and plastic isotropy. On the basis of the fully implicit method, we derive the explicit expression for the integrated stress along with a flow rule that represents volumetric non-associativity. The integration algorithm covers all the possible cases of regular, corner and apex solutions including the suitable indicator for each case. We also establish the consequent consistently linearized tangent stiffness modulus tensor, which is shown to appear in the form of an additive modification of the continuum tangent stiffness tensor. The convergence properties of the consistent tangent stiffness tensor are compared with its feasible approximations. The results indicate the strongly sensitivity to the proper treatment of the corner conditions at the establishment of the ATS-tensor.
    Additional Material: 5 Ill.
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  • 97
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Mechanics of Cohesive-frictional Materials 1 (1996) 
    ISSN: 1082-5010
    Keywords: Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 98
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    New York, NY [u.a.] : Wiley-Blackwell
    Mechanics of Cohesive-frictional Materials 1 (1996), S. 385-403 
    ISSN: 1082-5010
    Keywords: granular flow ; constitutive equation ; simple fluid ; friction ; collision ; microstructural model ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The aim of this paper is to examine the possibility of a simple fluid-mechanics treatment of rapid dense granular flows. In other words, we examine whether the constitutive equation can be sought in a simple relationship between the strain-rate and stress tensors. With this aim, we first show that an inclined channel is an appropriate device for providing rheological data. Here we provide a complete rheometrical treatment, which allows to infer the shear-stress/shear-rate curve (for simple shear flows) from the flow-depth/mass-flow-rate curve. Experi-ments performed with glass beads and sand grains revealed an apparent decrease in the shear stress with increasing shear rate. We then demonstrate that this result, although paradoxical, is not unphysical. Moreover, more detailed theoretical analysis shows that the main issues raised by our experiments may be overcome by ‘microstructural’ models. We finally give two examples of models including a single microstructural parameter, which are able to qualitatively account for the main features of our experiments.
    Additional Material: 6 Ill.
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  • 99
    ISSN: 1573-4854
    Keywords: relative permeability ; pore structure characterisation ; adsorption
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A novel design for the application of a simplified experimental procedure, capable of providing satisfactory relative permeability data for porous media at low relative pressures, is presented. The technique avoids the two-component mixing complications as well as the problems arising from the sample macroscopic inhomogeneity. The latter has been reduced with the aid of a variable pressure compaction procedure. Thus, it becomes easier to utilise the powerful relative permeability technique for the characterisation of the structure of porous solids. Emphasis is given to the combination of the relative permeability data obtained with an analytical approach based on Effective Medium Theory for the calculation of pore connectivity.
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  • 100
    Electronic Resource
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    Springer
    Journal of porous materials 2 (1995), S. 191-199 
    ISSN: 1573-4854
    Keywords: adsorption ; analysis of pore structure ; estimation from sorption pore shape ; from ad-de-sorption surface area ; calculations from sorption
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The interpretation of pore dimensions based on physical ad-desorption analyses is central to the characterization of pore network structure. Several approaches have been proposed and are commonly employed in the analysis of physical adsorption and/or desorption to deduce the dimensions of the porous network. These approaches assume either theoretical (e.g., BET, the Halsey equation as interpreted by Pierce et al., or the more recent analyses of microporosity) or “standard” isotherms as model(s) for the sequential calculations required in estimating the pore network dimensions. Subsequent representation of the pore dimensions and the relationship between these distributions in dimension and other experimental parameters (such as catalytic activity, adsorptivity or transport); thus, depend explicitly on the model employed in the analyses. Each instrument currently available for the measurement of porous solid structure by sorption employs the same specific models for the relationship between the volume ad-desorbed and the dimensions of the porous network that is being characterized. This paper analyzes the interpretation of porous dimensions based on the sequential calculations required in the analyses. A new approach is proposed which is based on a modification to current practices reflecting Halsey's original theory for the thickness of the adsorbed layer (as a function of P/P 0). Further, the calculations of the incremental changes in the exposed surface area are discussed as they relate to pore network structure. A method is proposed to infer the differences in pore shape. Sorption data are analyzed by these new approaches, and these analyses will be compared with those approaches currently employed. Analyses based on these modified approaches provide a dramatically more consistent interpretation of the sorption data and the corresponding pore network structures.
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