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  • American Institute of Physics  (102,839)
  • Copernicus
  • International Union of Crystallography (IUCr)
  • 2020-2024  (112)
  • 1990-1994  (56,840)
  • 1975-1979  (33,333)
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  • 1
    Publication Date: 2023-06-21
    Description: Abstract. Clouds are assumed to play an important role in the Arctic amplification process. This motivated a detailed investigation of cloud processes, including radiative and turbulent fluxes. Data from the aircraft campaign ACLOUD were analyzed with a focus on the mean and turbulent structure of the cloudy boundary layer over the Fram Strait marginal sea ice zone in late spring and early summer 2017. Vertical profiles of turbulence moments are presented from contrasting atmospheric boundary layers (ABLs) from 4 d. They differ by the magnitude of wind speed, boundary-layer height, stability, the strength of the cloud-top radiative cooling and the number of cloud layers. Turbulence statistics up to third-order moments are presented, which were obtained from horizontal-level flights and from slanted profiles. It is shown that both of these flight patterns complement each other and form a data set that resolves the vertical structure of the ABL turbulence well. The comparison of the 4 d shows that especially during weak wind, even in shallow Arctic ABLs with mixing ratios below 3 g kg-1, cloud-top cooling can serve as a main source of turbulent kinetic energy (TKE).Well-mixed ABLs are generated where TKE is increased and vertical velocity variance shows pronounced maxima in the cloud layer. Negative vertical velocity skewness points then to upside-down convection. Turbulent heat fluxes are directed upward in the cloud layer as a result of cold downdrafts. In two cases with single-layer stratocumulus, turbulent transport of heat flux and of temperature variance are both negative in the cloud layer, suggesting an important role of large eddies. In contrast, in a case with weak cloud-top cooling, these quantities are positive in the ABL due to the heating from the surface. Based on observations and results of a mixed-layer model it is shown that the maxima of turbulent fluxes are, however, smaller than the jump of the net terrestrial radiation flux across the upper part of a cloud due to the (i) shallowness of the mixed layer and (ii) the presence of a downward entrainment heat flux. The mixed-layer model also shows that the buoyancy production of TKE is substantially smaller in stratocumulus over the Arctic sea ice compared to subtropics due to a smaller surface moisture flux and smaller decrease in specific humidity (or even humidity inversions) right above the cloud top. In a case of strong wind, wind shear shapes the ABL turbulent structure, especially over rough sea ice, despite the presence of a strong cloud-top cooling. In the presence of mid-level clouds, cloud-top radiative cooling and thus also TKE in the lowermost cloud layer are strongly reduced, and the ABL turbulent structure becomes governed by stability, i.e., by the surface–air temperature difference and wind speed. A comparison of slightly unstable and weakly stable cases shows a strong reduction of TKE due to increased stability even though the absolute value of wind speed was similar. In summary, the presented study documents vertical profiles of the ABL turbulence with a high resolution in a wide range of conditions. It can serve as a basis for turbulence closure evaluation and process studies in Arctic clouds.
    Repository Name: EPIC Alfred Wegener Institut
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  • 2
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    Copernicus
    In:  EPIC3Atmospheric Chemistry and Physics, Copernicus, 23(5), pp. 3207-3232, ISSN: 1680-7316
    Publication Date: 2023-10-19
    Description: The presence of reactive bromine in polar regions is a widespread phenomenon that plays an important role in the photochemistry of the Arctic and Antarctic lower troposphere, including the destruction of ozone, the disturbance of radical cycles, and the oxidation of gaseous elemental mercury. The chemical mechanisms leading to the heterogeneous release of gaseous bromine compounds from saline surfaces are in principle well understood. There are, however, substantial uncertainties about the contribution of different potential sources to the release of reactive bromine, such as sea ice, brine, aerosols, and the snow surface, as well as about the seasonal and diurnal variation and the vertical distribution of reactive bromine. Here we use continuous long-term measurements of the vertical distribution of bromine monoxide (BrO) and aerosols at the two Antarctic sites Neumayer (NM) and Arrival Heights (AH), covering the periods of 2003–2021 and 2012–2021, respectively, to investigate how chemical and physical parameters affect the abundance of BrO. We find the strongest correlation between BrO and aerosol extinction (R=0.56 for NM and R=0.28 for AH during spring), suggesting that the heterogeneous release of Br2 from saline airborne particles (blowing snow and aerosols) is a dominant source for reactive bromine. Positive correlations between BrO and contact time of air masses, both with sea ice and the Antarctic ice sheet, suggest that reactive bromine is not only emitted by the sea ice surface but by the snowpack on the ice shelf and in the coastal regions of Antarctica. In addition, the open ocean appears to represent a source for reactive bromine during late summer and autumn when the sea ice extent is at its minimum. A source–receptor analysis based on back trajectories and sea ice maps shows that main source regions for BrO at NM are the Weddell Sea and the Filchner–Ronne Ice Shelf, as well as coastal polynyas where sea ice is newly formed. A strong morning peak in BrO frequently occurring during summer and that is particularly strong during autumn suggests a night-time build-up of Br2 by heterogeneous reaction of ozone on the saline snowpack in the vicinity of the measurement sites. We furthermore show that BrO can be sustained for at least 3 d while travelling across the Antarctic continent in the absence of any saline surfaces that could serve as a source for reactive bromine.
    Repository Name: EPIC Alfred Wegener Institut
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  • 3
    Publication Date: 2023-06-21
    Description: Springtime Arctic mixed-phase convection over open water in the Fram Strait as observed during the recent ACLOUD (Arctic CLoud Observations Using airborne measurements during polar Day) field campaign is simulated at turbulence-resolving resolutions. The first objective is to assess the skill of large-eddy simulation (LES) in reproducing the observed mixed-phase convection. The second goal is to then use the model to investigate how aerosol modulates the way in which turbulent mixing and clouds transform the low-level air mass. The focus lies on the low-level thermal structure and lapse rate, the heating efficiency of turbulent entrainment, and the low-level energy budget. A composite case is constructed based on data collected by two research aircraft on 18 June 2017. Simulations are evaluated against independent datasets, showing that the observed thermodynamic, cloudy, and turbulent states are well reproduced. Sensitivity tests on cloud condensation nuclei (CCN) concentration are then performed, covering a broad range between pristine polar and polluted continental values. We find a significant response in the resolved mixed-phase convection, which is in line with previous LES studies. An increased CCN substantially enhances the depth of convection and liquid cloud amount, accompanied by reduced surface precipitation. Initializing with the in situ CCN data yields the best agreement with the cloud and turbulence observations, a result that prioritizes its measurement during field campaigns for supporting high-resolution modeling efforts. A deeper analysis reveals that CCN significantly increases the efficiency of radiatively driven entrainment in warming the boundary layer. The marked strengthening of the thermal inversion plays a key role in this effect. The low-level heat budget shifts from surface driven to radiatively driven. This response is accompanied by a substantial reduction in the surface energy budget, featuring a weakened flow of solar radiation into the ocean. Results are interpreted in the context of air–sea interactions, air mass transformations, and climate feedbacks at high latitudes.
    Repository Name: EPIC Alfred Wegener Institut
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  • 4
    Publication Date: 2024-04-19
    Description: We combine satellite data products to provide a first and general overview of the physical sea ice conditions along the drift of the international Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition and a comparison with previous years (2005–2006 to 2018–2019). We find that the MOSAiC drift was around 20 % faster than the climatological mean drift, as a consequence of large-scale low-pressure anomalies prevailing around the Barents–Kara–Laptev sea region between January and March. In winter (October–April), satellite observations show that the sea ice in the vicinity of the Central Observatory (CO; 50 km radius) was rather thin compared to the previous years along the same trajectory. Unlike ice thickness, satellite-derived sea ice concentration, lead frequency and snow thickness during winter months were close to the long-term mean with little variability. With the onset of spring and decreasing distance to the Fram Strait, variability in ice concentration and lead activity increased. In addition, the frequency and strength of deformation events (divergence, convergence and shear) were higher during summer than during winter. Overall, we find that sea ice conditions observed within 5 km distance of the CO are representative for the wider (50 and 100 km) surroundings. An exception is the ice thickness; here we find that sea ice within 50 km radius of the CO was thinner than sea ice within a 100 km radius by a small but consistent factor (4 %) for successive monthly averages. Moreover, satellite acquisitions indicate that the formation of large melt ponds began earlier on the MOSAiC floe than on neighbouring floes.
    Repository Name: EPIC Alfred Wegener Institut
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  • 5
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    Copernicus
    In:  EPIC3Natural Hazards and Earth System Sciences, Copernicus, 2021, pp. 1-34, ISSN: 1561-8633
    Publication Date: 2024-04-22
    Description: 〈jats:p〉Abstract. The combined effect of hot and dry extremes can have disastrous consequences for the society, economy, and the environment. While a significant number of studies have been conducted regarding the variability of the individual hot or dry extremes in Romania, the evaluation of the combined effect of these extremes (e.g. compound effect) is still lacking for this region. Thus, in this study we have assessed the spatio-temporal variability and trends of hot and dry summers in the eastern part of Europe, focusing on Romania, between 1950 and 2020 and we have analyzed the relationship between the frequency of hot summers and the prevailing large-scale atmospheric circulation. The length, spatial extent and frequency of HWs in Romania has increased significantly over the last 70 years, while for the drought conditions no significant changes have been observed. The rate of increase in the frequency and spatial extent of HWs has accelerated significantly after the 1990’s, while the smallest number of HWs was observed between 1970 and 1985. The hottest years, in terms of heatwave duration and frequency, were 2007, 2012, 2015, and 2019. One of the key drivers of hot summers, over our analyzed region, is the prevailing large-scale circulation, featuring an anticyclonic circulation over the central and eastern parts of Europe and enhanced atmospheric blocking activity associated with positive temperature anomalies underneath. We conclude that our study can help improve our understanding of the spatio-temporal variability of hot and dry summers, especially at the regional scale, as well as their driving mechanisms which might lead to a better predictability of these extreme events. 〈/jats:p〉
    Repository Name: EPIC Alfred Wegener Institut
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  • 6
    Publication Date: 2024-01-30
    Description: Methane emissions from boreal and arctic wetlands, lakes, and rivers are expected to increase in response to warming and associated permafrost thaw. However, the lack of appropriate land cover datasets for scaling field-measured methane emissions to circumpolar scales has contributed to a large uncertainty for our understanding of present-day and future methane emissions. Here we present the Boreal–Arctic Wetland and Lake Dataset (BAWLD), a land cover dataset based on an expert assessment, extrapolated using random forest modelling from available spatial datasets of climate, topography, soils, permafrost conditions, vegetation, wetlands, and surface water extents and dynamics. In BAWLD, we estimate the fractional coverage of five wetland, seven lake, and three river classes within 0.5 × 0.5∘ grid cells that cover the northern boreal and tundra biomes (17 % of the global land surface). Land cover classes were defined using criteria that ensured distinct methane emissions among classes, as indicated by a co-developed comprehensive dataset of methane flux observations. In BAWLD, wetlands occupied 3.2 × 106 km2 (14 % of domain) with a 95 % confidence interval between 2.8 and 3.8 × 106 km2. Bog, fen, and permafrost bog were the most abundant wetland classes, covering ∼ 28 % each of the total wetland area, while the highest-methane-emitting marsh and tundra wetland classes occupied 5 % and 12 %, respectively. Lakes, defined to include all lentic open-water ecosystems regardless of size, covered 1.4 × 106 km2 (6 % of domain). Low-methane-emitting large lakes (〉10 km2) and glacial lakes jointly represented 78 % of the total lake area, while high-emitting peatland and yedoma lakes covered 18 % and 4 %, respectively. Small (〈0.1 km2) glacial, peatland, and yedoma lakes combined covered 17 % of the total lake area but contributed disproportionally to the overall spatial uncertainty in lake area with a 95 % confidence interval between 0.15 and 0.38 × 106 km2. Rivers and streams were estimated to cover 0.12  × 106 km2 (0.5 % of domain), of which 8 % was associated with high-methane-emitting headwaters that drain organic-rich landscapes. Distinct combinations of spatially co-occurring wetland and lake classes were identified across the BAWLD domain, allowing for the mapping of “wetscapes” that have characteristic methane emission magnitudes and sensitivities to climate change at regional scales. With BAWLD, we provide a dataset which avoids double-accounting of wetland, lake, and river extents and which includes confidence intervals for each land cover class. As such, BAWLD will be suitable for many hydrological and biogeochemical modelling and upscaling efforts for the northern boreal and arctic region, in particular those aimed at improving assessments of current and future methane emissions. Data are freely available at https://doi.org/10.18739/A2C824F9X (Olefeldt et al., 2021).
    Repository Name: EPIC Alfred Wegener Institut
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  • 7
    Publication Date: 2024-01-31
    Description: Lakes in permafrost regions are dynamiclandscape components and play an important role for climatechange feedbacks. Lake processes such as mineralizationand flocculation of dissolved organic carbon (DOC), oneof the main carbon fractions in lakes, contribute to thegreenhouse effect and are part of the global carbon cycle.These processes are in the focus of climate research, butstudies so far are limited to specific study regions. Inour synthesis, we analyzed 2167 water samples from 1833lakes across the Arctic in permafrost regions of Alaska,Canada, Greenland, and Siberia to provide first pan-Arcticinsights for linkages between DOC concentrations andthe environment. Using published data and unpublisheddatasets from the author team, we report regional DOCdifferences linked to latitude, permafrost zones, ecoregions,geology, near-surface soil organic carbon contents, andground ice classification of each lake region. The lakeDOC concentrations in our dataset range from 0 to1130 mg L−1(10.8 mg L−1median DOC concentration).Regarding the permafrost regions of our synthesis, wefound median lake DOC concentrations of 12.4 mg L−1(Siberia), 12.3 mg L−1(Alaska), 10.3 mg L−1(Greenland),and 4.5 mg L−1(Canada). Our synthesis shows a significantrelationship between lake DOC concentration and lakeecoregion. We found higher lake DOC concentrationsat boreal permafrost sites compared to tundra sites. Wefound significantly higher DOC concentrations in lakesin regions with ice-rich syngenetic permafrost deposits(yedoma) compared to non-yedoma lakes and a weak butsignificant relationship between soil organic carbon contentand lake DOC concentration as well as between ground icecontent and lake DOC. Our pan-Arctic dataset shows that theDOC concentration of a lake depends on its environmentalproperties, especially on permafrost extent and ecoregion, aswell as vegetation, which is the most important driver of lakeDOC in this study. This new dataset will be fundamental toquantify a pan-Arctic lake DOC pool for estimations of theimpact of lake DOC on the global carbon cycle and climatechange.
    Repository Name: EPIC Alfred Wegener Institut
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  • 8
    Publication Date: 2024-01-31
    Description: Arctic river deltas and deltaic near-shore zones represent important land–ocean transition zones influencing sediment dynamics and nutrient fluxes from permafrost-affected terrestrial ecosystems into the coastal Arctic Ocean. To accurately model fluvial carbon and freshwater export from rapidly changing river catchments as well as assess impacts of future change on the Arctic shelf and coastal ecosystems, we need to understand the sea floor characteristics and topographic variety of the coastal zones. To date, digital bathymetrical data from the poorly accessible, shallow, and large areas of the eastern Siberian Arctic shelves are sparse. We have digitized bathymetrical information for nearly 75 000 locations from large-scale (1:25 000–1:500 000) current and historical nautical maps of the Lena Delta and the Kolyma Gulf region in northeastern Siberia. We present the first detailed and seamless digital models of coastal zone bathymetry for both delta and gulf regions in 50 and 200 m spatial resolution. We validated the resulting bathymetry layers using a combination of our own water depth measurements and a collection of available depth measurements, which showed a strong correlation (r〉0.9). Our bathymetrical models will serve as an input for a high-resolution coupled hydrodynamic–ecosystem model to better quantify fluvial and coastal carbon fluxes to the Arctic Ocean, but they may be useful for a range of other studies related to Arctic delta and near-shore dynamics such as modeling of submarine permafrost, near-shore sea ice, or shelf sediment transport. The new digital high-resolution bathymetry products are available on the PANGAEA data set repository for the Lena Delta (https://doi.org/10.1594/PANGAEA.934045; Fuchs et al., 2021a) and Kolyma Gulf region (https://doi.org/10.1594/PANGAEA.934049; Fuchs et al., 2021b), respectively. Likewise, the depth validation data are available on PANGAEA as well (https://doi.org/10.1594/PANGAEA.933187; Fuchs et al., 2021c).
    Repository Name: EPIC Alfred Wegener Institut
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  • 9
    Publication Date: 2024-01-19
    Repository Name: EPIC Alfred Wegener Institut
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  • 10
    Publication Date: 2024-04-19
    Repository Name: EPIC Alfred Wegener Institut
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  • 11
    Publication Date: 2024-04-17
    Description: TR17-08, a marine sedimentary core (14.6 m), was collected during 2017 from the Edisto Inlet (Ross Sea, Antarctica), a small fjord near Cape Hallett. The core is characterized by expanded laminated sedimentary sequences making it suitable for studying submillennial processes during the Early Holocene. By studying different well-known foraminifera species (Globocassidulina biora, G. subglobosa, Trifarina angulosa, Nonionella iridea, Epistominella exigua, Stainforthia feylingi, Miliammina arenacea, Paratrochammina bartrami and Portatrochammina antarctica), we were able to identify five different foraminiferal assemblages over the last ∼ 2000 years BP. Comparison with diatom assemblages and other geochemical proxies retrieved from nearby sediment cores in the Edisto Inlet (BAY05-20 and HLF17-1) made it possible to distinguish three different phases characterized by different environmental settings: (1) a seasonal phase (from 2012 to 1486 years BP) characterized by the dominance of calcareous species, indicating a seasonal opening of the inlet by more frequent events of melting of the sea-ice cover during the austral summer and, in general, a higher-productivity, more open and energetic environment; (2) a transitional phase (from 1486 to 696 years BP) during which the fjord experienced less extensive sea-ice melting, enhanced oxygen-poor conditions and carbonate dissolution conditions, indicated by the shifts from calcareous-dominated association to agglutinated-dominated association probably due to a freshwater input from the retreat of three local glaciers at the start of this period; and (3) a cooler phase (from 696 years BP to present) during which the sedimentation rate decreased and few to no foraminiferal specimens were present, indicating ephemeral openings or a more prolonged cover of the sea ice during the austral summer, affecting the nutrient supply and the sedimentation regime.
    Description: Published
    Description: 95–115
    Description: OSA2: Evoluzione climatica: effetti e loro mitigazione
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 12
    Publication Date: 2024-04-11
    Description: 〈jats:p〉Abstract. The risk of carbon emissions from permafrost ground is linked to ground temperature and thus in particular to thermal insulation by vegetation and organic soil layers in summer and snow cover in winter. This ground insulation is strongly influenced by the presence of large herbivorous animals browsing for food. In this study, we examine the potential impact of large herbivore presence on the ground carbon storage in thermokarst landscapes of northeastern Siberia. Our aim is to understand how intensive animal grazing may affect permafrost thaw and hence organic matter decomposition, leading to different ground carbon storage, which is significant in the active layer. Therefore, we analysed sites with differing large herbivore grazing intensity in the Pleistocene Park near Chersky and measured maximum thaw depth, total organic carbon content and decomposition state by δ13C isotope analysis. In addition, we determined sediment grain size composition as well as ice and water content. We found the thaw depth to be shallower and carbon storage to be higher in intensively grazed areas compared to extensively and non-grazed sites in the same thermokarst basin. The intensive grazing presumably leads to a more stable thermal ground regime and thus to increased carbon storage in the thermokarst deposits and active layer. However, the high carbon content found within the upper 20 cm on intensively grazed sites could also indicate higher carbon input rather than reduced decomposition, which requires further studies. We connect our findings to more animal trampling in winter, which causes snow disturbance and cooler winter ground temperatures during the average annual 225 days below freezing. This winter cooling overcompensates ground warming due to the lower insulation associated with shorter heavily grazed vegetation during the average annual 140 thaw days. We conclude that intensive grazing influences the carbon storage capacities of permafrost areas and hence might be an actively manageable instrument to reduce net carbon emission from these sites. 〈/jats:p〉
    Repository Name: EPIC Alfred Wegener Institut
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  • 13
    Publication Date: 2024-05-17
    Description: In this study, the first fully continuous monitoring of water vapour isotopic composition at Neumayer Station III, Antarctica, during the 2-year period from February 2017 to January 2019 is presented. Seasonal and synoptic-scale variations in both stable water isotopes H182O and HDO are reported, and their links to variations in key meteorological variables are analysed. In addition, the diurnal cycle of isotope variations during the summer months (December and January 2017/18 and 2018/19) has been examined. Changes in local temperature and specific humidity are the main drivers for the variability in δ18O and δD in vapour at Neumayer Station III, on both seasonal and shorter timescales. In contrast to the measured δ18O and δD variations, no seasonal cycle in the Deuterium excess signal (d) in vapour is detected. However, a rather high uncertainty in measured d values especially in austral winter limits the confidence of this finding. Overall, the d signal shows a stronger inverse correlation with specific humidity than with temperature, and this inverse correlation between d and specific humidity is stronger for the cloudy-sky conditions than for clear-sky conditions during summertime. Back-trajectory simulations performed with the FLEXPART model show that seasonal and synoptic variations in δ18O and δD in vapour coincide with changes in the main sources of water vapour transported to Neumayer Station III. In general, moisture transport pathways from the east lead to higher temperatures and more enriched δ18O values in vapour, while weather situations with southerly winds lead to lower temperatures and more depleted δ18O values. However, on several occasions, δ18O variations linked to wind direction changes were observed, which were not accompanied by a corresponding temperature change. Comparing isotopic compositions of water vapour at Neumayer Station III and snow samples taken in the vicinity of the station reveals almost identical slopes, both for the δ18O–δD relation and for the temperature–δ18O relation.
    Repository Name: EPIC Alfred Wegener Institut
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  • 14
    Publication Date: 2024-05-14
    Description: The thermokarst lakes of permafrost regions play a major role in the global carbon cycle. These lakes are sources of methane to the atmosphere although the methane flux is restricted by an ice cover for most of the year. How methane concentrations and fluxes in these waters are affected by the presence of an ice cover is poorly understood. To relate water body morphology, ice formation and methane to each other, we studied the ice of three different water bodies in locations typical of the transition of permafrost from land to ocean in a continuous permafrost coastal region in Siberia. In total, 11 ice cores were analyzed as records of the freezing process and methane composition during the winter season. The three water bodies differed in terms of connectivity to the sea, which affected fall freezing. The first was a bay underlain by submarine permafrost (Tiksi Bay, BY), the second a shallow thermokarst lagoon cut off from the sea in winter (Polar Fox Lagoon, LG) and the third a land-locked freshwater thermokarst lake (Goltsovoye Lake, LK). Ice on all water bodies was mostly methane-supersaturated with respect to atmospheric equilibrium concentration, except for three cores from the isolated lake. In the isolated thermokarst lake, ebullition from actively thawing basin slopes resulted in the localized integration of methane into winter ice. Stable δ13C-CH4 isotope signatures indicated that methane in the lagoon ice was oxidized to concentrations close to or below the calculated atmospheric equilibrium concentration. Increasing salinity during winter freezing led to a micro-environment on the lower ice surface where methane oxidation occurred and the lagoon ice functioned as a methane sink. In contrast, the ice of the coastal marine environment was slightly supersaturated with methane, consistent with the brackish water below. Our interdisciplinary process study shows how water body morphology affects ice formation which mitigates methane fluxes to the atmosphere.
    Repository Name: EPIC Alfred Wegener Institut
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  • 15
    Publication Date: 2024-05-29
    Description: Data from the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition allowed us to investigate the temporal dynamics of snowfall, snow accumulation and erosion in great detail for almost the whole accumulation season (November 2019 to May 2020). We computed cumulative snow water equivalent (SWE) over the sea ice based on snow depth and density retrievals from a SnowMicroPen and approximately weekly measured snow depths along fixed transect paths. We used the derived SWE from the snow cover to compare with precipitation sensors installed during MOSAiC. The data were also compared with ERA5 reanalysis snowfall rates for the drift track. We found an accumulated snow mass of 38 m SWE between the end of October 2019 and end of April 2020. The initial SWE over first-year ice relative to second-year ice increased from 50 % to 90 % by end of the investigation period. Further, we found that the Vaisala Present Weather Detector 22, an optical precipitation sensor, and installed on a railing on the top deck of research vessel Polarstern, was least affected by blowing snow and showed good agreements with SWE retrievals along the transect. On the contrary, the OTT Pluvio2 pluviometer and the OTT Parsivel2 laser disdrometer were largely affected by wind and blowing snow, leading to too high measured precipitation rates. These are largely reduced when eliminating drifting snow periods in the comparison. ERA5 reveals good timing of the snowfall events and good agreement with ground measurements with an overestimation tendency. Retrieved snowfall from the ship-based Ka-band ARM zenith radar shows good agreements with SWE of the snow cover and differences comparable to those of ERA5. Based on the results, we suggest the Ka-band radar-derived snowfall as an upper limit and the present weather detector on RV Polarstern as a lower limit of a cumulative snowfall range. Based on these findings, we suggest a cumulative snowfall of 72 to 107 m and a precipitation mass loss of the snow cover due to erosion and sublimation as between 47 % and 68 %, for the time period between 31 October 2019 and 26 April 2020. Extending this period beyond available snow cover measurements, we suggest a cumulative snowfall of 98-114 m.
    Repository Name: EPIC Alfred Wegener Institut
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  • 16
    Publication Date: 2024-06-21
    Description: Stable water isotopologues of snow, firn and ice cores provide valuable information on past climate variations. Yet single profiles are generally not suitable for robust climate reconstructions. Stratigraphic noise, introduced by the irregular deposition, wind-driven erosion and redistribution of snow, impacts the utility of high-resolution isotope records, especially in low-Accumulation areas. However, it is currently unknown how stratigraphic noise differs across the East Antarctic Plateau and how it is affected by local environmental conditions. Here, we assess the amount and structure of stratigraphic noise at seven sites along a 120 km transect on the plateau of Dronning Maud Land, East Antarctica. Replicated oxygen isotope records of 1 m length were used to estimate signal-To-noise ratios as a measure of stratigraphic noise at sites characterised by different accumulation rates (43-64 mm w.e. a-1), snow surface roughnesses and slope inclinations. While we found a high level of stratigraphic noise at all sites, there was also considerable variation between sites. At sastrugi-dominated sites, greater stratigraphic noise coincided with stronger surface roughnesses, steeper slopes and lower accumulation rates, probably related to increased wind speeds. These results provide a first step to modelling stratigraphic noise and might guide site selection and sampling strategies for future expeditions to improve high-resolution climate reconstructions from low-Accumulation regions.
    Repository Name: EPIC Alfred Wegener Institut
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  • 17
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics
    ISSN: 1089-7682
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A quarterly journal devoted to increasing the understanding of nonlinear phenomena and describing the manifestations in a manner comprehensible to researchers from a broad spectrum of disciplines
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  • 18
    ISSN: 1089-7674
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: The journal features concise, up-to-date reports on significant new findings in applied physics. Emphasizing rapid dissemination for key data and new physical insights, Physics of Plasmas offers prompt publication of new experimental and theoretical papers bearing on applications of physics phenomena to all branches of science, engineering, and modern technology. The journal emphasizes coverage of significant new topics, such as in recent years, high-Tc superconductors, diamond films, porous silicon, and fullerenes. It prints papers which report results of research in nuclear physics and related fields such as nuclear astrophysics.
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  • 19
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 1 (1968), S. 1-19 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
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    Notes: The desirability and requirements for a specimen capable of testing the resolving power and other image characteristics of an electron microscope are discussed in detail. In this discussion, the underlying diffraction phenomena are particularly utilized. A partially graphitized carbon black is shown to satisfy the requirements extremely well and constitutes an easily prepared specimen for conducting tests of image quality in the molecular size range. The structure of the test object is known in detail with the result that readily interpretable phase contrast images are obtained. Micrographs illustrating the use of the 3.4 Å (002) spacing for magnification calibration, astigmatism and asymmetry check as well as resolving power are exhibited. The second order c-spacing of 1.7 Å is occasionally found in an image. The micrographs shown herein were taken with two different electron microscopes by different operators obtaining the same structural detail in the images. It is concluded that the carbon black test object offers the best possibilities for evaluating image performance of any specimen yet suggested.
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    Applied crystallography online 1 (1968), S. 84-90 
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    Topics: Geosciences , Physics
    Notes: Bent-glass mirrors can be used to produce a narrow, highly collimated X-ray beam, particularly suitable for photographing diffraction patterns from crystals with very large unit cells (i.e., several hundred Å to a side). A camera is described that employs double-mirror focusing optics with a precession apparatus. A comparison of optical reflection and simple collimation shows that for high resolving power, focusing devices are very much superior to pinhole collimators. The reduction of background is especially noteworthy. Use of this camera has permitted the collection of accurate three-dimensional data from crystals of tomato bushy stunt virus.
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  • 21
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    Applied crystallography online 1 (1968), S. 121-122 
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    Notes: A new method for determination of the polarization factor of a crystal monochromator is presented. This method is based on the use of polarized X-rays produced by anomalous transmission or the Borrmann effect. The polarization factors of two quartz (10\overline 11) monochromators of Johansson type have been measured with Cu Kα radiation, and the resulting values are in close agreement with the expression derived from the kinematic diffraction theory.
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  • 22
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    Applied crystallography online 1 (1968), S. 126-128 
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    Topics: Geosciences , Physics
    Notes: An adapter which supports a Polaroid flat-plate film holder has been designed for a standard Weissenberg goniometer. A number of applications, including a method for rapidly aligning single crystals, are described.
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  • 23
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    Applied crystallography online 1 (1968), S. 145-153 
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    Topics: Geosciences , Physics
    Notes: The use of X-ray diffraction topography to identify domains of different polytype in crystals of silicon carbide has been described in a previous paper. Further methods have been developed and applied to the analysis of thin films deposited epitaxically from the vapour phase onto basal surfaces of crystals of hexagonal α-SiC. The epitaxic films consist either of α-SiC, or of the cubic form β-SiC, with multiple twinning about the axis normal to the surface. The fine scale texture of interlocking twin domains is readily demonstrated in X-ray diffraction topographs.
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  • 24
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    Applied crystallography online 1 (1968), S. 165-171 
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    Notes: Inversion twin boundaries in BeO crystals (wurtzite structure) can be studied by X-ray topography. They can be regarded as a special kind of stacking fault. The section topograph images of a twin boundary, lying parallel to the c axis, agree well with the theory for a single stacking fault. From the contrast variation of the images for various reflections, it is concluded that the oxygen sublattice on one side of the twin boundary is displaced from that on the other side by \mid(1/16)[001]\mid so that the oxygen layer parallel to the basal plane on one side is located at the center of the oxygen and beryllium layers on the other side. The image contrast in section topographs is very sensitive to the phase shift due to a fault. The phase shift of a few degrees can be detected easily. This sensitivity leads to an accurate structure determination of the inversion twin boundary.
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  • 25
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    Applied crystallography online 1 (1968), S. 181-184 
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    Notes: The refractive index, n, for X-rays is measured by interposing a prism in the path of X-rays falling on a perfect silicon crystal at the Bragg incidence angle. Owing to the deviation angle of the prism, the separation of the two wave fields excited in the silicon crystal is modified, from which the value of n − 1 can be deduced with a 1% accuracy. The method has been applied to the measurement of the anomalous dispersion correction for the refractive index of zirconium for Mo Kα.
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  • 26
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    Applied crystallography online 1 (1968), S. 187-189 
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    Notes: A method based on the variation of the lattice parameter with Li content, for the quantitative determination of lithium in the system Lix+Ni1−2x2+Nix3+O2−, is proposed. A precision between 1 and 5% relative, depending upon the concentration range, has been obtained. The results are compared with those obtained by flame emission spectroscopy. For values of x 〉 0.12 the original rhombohedral lattice transforms into a face centred cubic lattice.
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  • 27
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    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 1 (1968), S. 198-198 
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  • 28
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    Applied crystallography online 1 (1968), S. 139-145 
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    Notes: A study of strain inhomogeneities in a zone-refined tungsten crystal oriented for (123) slip was carried out before and after a slight compression. The study was based on changes of interplanar spacings measured along different crystallographic directions and samples from different areas of the crystal by means of the X-ray back-reflection divergent beam method. Upon compression a redistribution of the locked-in elastic strains took place and the induced strains assumed a more homogeneous distribution for one of the sets of (123) planes considered. This homogeneity in the strain distribution along definite crystallographic directions is believed to result from the interaction of the primary slip dislocations with the pre-existing dislocation configuration and appears to be characteristic of the initial stage of work-hardening. The dislocation interaction induced by a small strain found practical application in the elimination of a troublesome substructure in highly zone-refined tungsten crystals and appears to form the scientific basis of certain stress-relief treatments long practised in metallurgical technology.
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  • 29
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    Applied crystallography online 1 (1968), S. 218-226 
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    Notes: All the hard carbons are composed of three phases when they are heated above 2000°C: non-graphitizable carbon, graphitizable carbon, and graphite (the latter two appearing only in very small amounts). When the heat treatment temperature is increased to 3000°C, these phases change in various ways. At low temperatures, the non-graphitizable phase is formed by small turbostratic stacks of carbon layers which are oriented completely at random inside the carbon grains. Above 2000°, these stacks begin to undergo mutual rearrangement to produce small fibers by ordering roughly parallel to each other. The graphitizable phase is formed of spheres made up of conical rolled spirals, which are themselves made up by turbostratic stacking of the carbon layers. When heat treated, each sphere transforms to graphite very suddenly. The third phase is well crystallized graphite with stacking faults and twist defects.
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  • 30
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    Applied crystallography online 1 (1968), S. 241-246 
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    Notes: Samples in the Bi–Te system containing 59.0, 58.0, 57.0, 55.0, 51.0, and 50.0 at.% Te, in addition to 5 samples within the Bi2Te3 homogeneity range, have been equilibrated near 525 or 450°C and room temperature powder diffraction patterns taken. There are now 4 known phases in the 50–60 at.% Te region. The 59.0 and 58.0 at.% samples are two phase at 525°C. The 57.0 and 55.0 at.% samples are new phases with hexagonal parameters, a = 4.4106±0.0002 Å, c = 54.330±0.003 Å and a = 4.4214±0.0004 Å, c = 78.195±0.012 Å, respectively. The 51.0 and 50.0 at.% samples are two-phase at 525 C. At 450°C the 51.0 at.% sample is single phase while the 50.0 at.% sample probably is not. The common indexing scheme for the 50.0 and 51.0 at.% samples is different from those for the 55–0 and 57.0 at.% samples. For the 51.0 at.% sample a = 4.4296±0.0002 Å and c = 24.017±0.001 Å. The 00l lines for all these phases vary strongly with composition and those near d = 9 and 5 Å are isolated enough to provide a convenient way of distinguishing among the various phases. The results are discussed in terms of other phase-diagram information. They are inconsistent with Stasova's correlation between composition and powder-pattern indices for the Bi–Te, Bi–Se, and Sb–Te systems.
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    Applied crystallography online 1 (1968), S. 262-262 
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  • 32
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    Applied crystallography online 1 (1968), S. 263-271 
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    Notes: The study of the scattering outside the Bragg reflexions shows no local order in the ordered phase I of alloys such as Au (50 at. %) Cu (46 at. %) Ni (4 at. %) even for the smallest degree of long range order. The modulation of the scattering appears only with the presence of short range order in the disordered α phase. There is evidence of a two-phase region on the equilibrium diagram at the AuCu3 stoichiometric composition.
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    Applied crystallography online 1 (1968), S. 290-292 
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    Notes: Accurate lattice parameters (at 25 and 48°C), density, thermal expansion coefficients, the indexed powder pattern, and optical data are given for Ba(4+x)Na(2−2x)Nb10O30, where x = 0.13±0.013, grown by pulling from a nominally stoichiometric melt.
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    Applied crystallography online 1 (1968), S. 313-317 
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    Notes: In an earlier communication by the authors it was shown that the stack height distribution in a raw carbon black followed an exponential law. Extension of these studies to a heat-treated (2000°C) black showed that the exponential law is still valid when stacking is extensive. The exponential law and the effect of heat-treatment are explained by the existence in blacks of extensive stratification rather than the presence of short stacks of small layers. Evidently heat-treatment results in annealing of the strata to yield uniform layer domains and more ordered stacking. Simple expressions are derived for calculating the profiles of the 00l reflections and the coefficient of the exponent.
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    Applied crystallography online 1 (1968), S. 324-325 
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    Applied crystallography online 1 (1968), S. 323-323 
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    Notes: Long chain secondary ammonium chlorides, bromides and iodides crystallize in a preferred orientation. Values of the basal spacings of the salts indicate hydrocarbon chains oriented towards each other between planes of the ionic heads. The inclination angle of the chains was found to be 40°.
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  • 37
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    Applied crystallography online 2 (1969), S. 72-76 
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    Notes: The paper describes a method for obtaining consistent estimates of domain size from an evaluation of coefficients derived from curves fitted to the tails of diffraction profiles. An estimate of the mean domain size is computed directly from the intensity data and this is equivalent to the value derived from the slope of the variance-range function. For many applications this provides a convenient alternative to the method described by Langford & Wilson (Crystallography and Crystal Perfection. London: Academic Press, 1963) but does not replace it. An advantage of the present method is its simplicity and consequent reduction in computing time. It is easier to apply if a computer is not available and is applicable in cases where one or other of the profile tails overlaps that of a neighbouring line. The results obtained by this method are comparable in accuracy to those given by existing techniques.
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    Applied crystallography online 2 (1969), S. 18-24 
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    Notes: The usual method of specimen preparation for electron-probe microanalysis can introduce errors of up to about ±3% in the estimates of the amount of an element present. It is believed that these errors are caused by the formation of `flowed' layers on the surfaces of polished samples. Two methods of reducing the errors are described.
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  • 39
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    Applied crystallography online 2 (1969), S. 30-36 
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    Notes: The lattice constants and the atomic position parameter, z, of a high purity, low strain, single-crystal of arsenic have been determined. Low extinction reflections of filtered Mo Kα and Ag Kα radiation were used for the determination of z. The Bond precision technique with Mo Kα radiation was used for the determination of the unit-cell dimensions a and c. Average values for a and c in Å, and for z are: 4.2°K z = 0.22764 a = 3.7597 c = 10.4412; 78°K z = 0.22754 a = 3.7595 c = 10.4573; 299±3°K z = 0.22707 a = 3.7598 c = 10.5475. The estimated standard deviation of z is ±0.00004 at 4.2°K, ±0.00002 at 78°K and ±0.00005 at 299°K. The precision of a is estimated to be ±0–0001 Å and that for c to be ±0.0002 Å. The results for As are compared with those reported earlier for Sb and Bi.
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    Applied crystallography online 2 (1969), S. 146-147 
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    Applied crystallography online 2 (1969), S. 156-164 
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    Notes: The strain induced phase transformations produced in lead monoxide powders by ball milling at temperatures ranging from −196 to 200°C have been studied by X-ray diffraction methods. It has been found that either of the two polymorphs, litharge and massicot, was partially converted to the other at all the temperatures investigated, and that, whichever polymorph was the starting material, the end product, after a sufficiently long time, was a mixture of the two polymorphs, both highly strained. The percentage of each phase present was found to be dependent on the temperature of deformation. The results have been interpreted by consideration of the production of the microstrain energy required to overcome the energy barrier to the transformation, and of the shear generated in the mill on the pressure-temperature phase diagram. It is considered that shear stresses can affect the nature of the pressure-temperature phase diagram, in a manner theoretically postulated by Kumazawa. The commercial importance of the results has been briefly outlined.
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    Applied crystallography online 2 (1969), S. 176-180 
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    Notes: The theory of the direct comparison X-ray method of phase analysis is extended to correct for preferred orientation effects. Texture parameters are defined to assess the type and intensity of preferred orientation using data from diffractometer patterns. The analysis is illustrated with results obtained on three austenitic stainless steels.
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    Applied crystallography online 2 (1969), S. 192-192 
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    Applied crystallography online 2 (1969), S. 200-209 
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    Notes: A method is presented which combines the analysis of X-ray absorption profiles and selected area X-ray topographs. The method is based on X-ray divergent beam patterns obtained in transmission. The absorption profiles are obtained by unfolding the spectral distribution from the profiles of the deficiency conics, whereas the selected area topographs derive from the corresponding diffraction conics. The synergy of the two techniques makes the method particularly useful for the elucidation of anisotropic effects and inhomogeneities of defect structures. An example is given for the room temperature deformation of beryllium.
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    Applied crystallography online 2 (1969), S. 223-230 
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    Notes: An X-ray reflexion topography camera has been designed to study structural defects near the surface of monocrystalline semiconductors. Large surfaces can be covered by means of successive fixed exposures. A surface of 30 mm x 10 mm for example can be studied in less than ten minutes on nuclear emulsions. The conditions for the observations of dislocations in gallium arsenide have been examined: the choice of reflecting planes is limited by the depth of penetration of X-rays, so that the effective crystal thickness must be of the order of the width of a dislocation image (2-5 microns). Studies to which these observations can be applied are numerous: structural defects induced by diffusion, lattice strains, orientation of dislocations near the surface, structural evolution of silicon during integrated circuits elaboration, structure of cleavage surfaces, lapping and polishing defects, structural defects of epitaxic layers.
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    Applied crystallography online 2 (1969), S. 234-234 
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    Applied crystallography online 2 (1969), S. 236-236 
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    Applied crystallography online 2 (1969), S. 249-252 
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    Notes: The practical importance of tungsten monocarbide prompted an investigation into its wear mechanism. Initial studies on ball-milled tungsten carbide powders revealed considerable plastic deformation, coupled with a reduction in crystallite size. Deformation stacking faults, involving slip on the basal plane, were observed. The work was extended to sintered blocks, tool tips and single crystals. Studies on the worn surfaces of these revealed plastic deformation that extended to a depth of a few microns below the surface. The plastic deformation is an important factor in the wear of tungsten carbide.
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    Applied crystallography online 2 (1969), S. 295-297 
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    Notes: A method is suggested which allows several independent determinations of the rhombohedral angle using data from a single diffraction pattern. This is applied to the intermetallic compound SbSn.
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    Applied crystallography online 2 (1969), S. 297-300 
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    Notes: The Hankel transform method proposed by Fedorov & Aleshin (1966; Vysokomol. Soed. 8, 1506; English translation, 1967: Polymer Science USSR 8, 1657) for calculating the electron density of long cylindrical particles with circular cross section is tested with theoretical intensity functions for which the density can be found both by an exact calculation and by numerical integration. (In this method, the density is assumed to depend only on the distance from the cylinder axis.) The tests show how the degree of resolution obtained in the density curve is related to the largest scattering angle at which data are available. For the step function density corresponding to a cylinder with uniform electron density, the requirements are more severe than for continuously decreasing density functions. The possibility of obtaining useful results with the available scattering data from two biological macromolecules is discussed.
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    Applied crystallography online 2 (1969), S. 247-248 
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    Notes: A previously given analysis of the beam and specimen tilt errors in the Bond single-crystal method of lattice parameter determinations is extended to give a simple generalized treatment. This shows that the error passes through a maximum in accordance with an empirical observation by other workers. Crystal alignment procedures are examined in the light of the results.
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    Applied crystallography online 2 (1969), S. 259-261 
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    Notes: A storage oscilloscope has been attached to the IBM 1800 computer that is used for pole-figure data acquisition. It allows fast plotting of pole figures by modulation of the cathode ray beam according to the pole density as it scans the stereographic projection along a spiral path. The time needed to plot the pole figure is reduced by a factor of eight as compared with a mechanical plotter.
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    Applied crystallography online 2 (1969), S. 281-288 
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    Notes: The axial thermal expansion of monoclinic and tetragonal ZrO2 and of monoclinic HfO2 was studied over the temperature range from room temperature to 1400 °C. The linear thermal expansion coefficients were calculated. Thermal expansion along (x 106 per °C) a = 10.31 monoclinic ZrO2, 11.60 tetragonal ZrO2, 9.34 monoclinic HfO2; b = 1.35 monoclinic ZrO2, – tetragonal ZrO2, 2.98 monoclinic HfO2; c = 14.68 monoclinic ZrO2, 16.08 tetragonal ZrO2, 13.10 monoclinic HfO2. Some aspects of the present study, such as anisotropy of thermal expansion and a pretransformation vibrational anomaly, are discussed briefly.
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    Applied crystallography online 8 (1975), S. 29-36 
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    Notes: A stereographic projection method of analysis has been developed for analyzing the misorientation contrast of crystal subgrain boundaries which are observed in Berg–Barrett X-ray micrographs. The boundary appearance is described in terms of the geometry of the boundary with respect to the crystal surface, the angular misorientation of the adjacent subgrains, and the X-ray diffraction conditions. The rotation axis for the misorientation of adjacent subgrains, including the sense of the rotation, and the amount of misorientation is determined from the width and relative contrast of the boundary in various images. Experimental results are described for subgrain boundaries in zinc crystals solidified along different crystallographic growth directions. The Burgers vectors of the dislocations composing the subgrain boundary are indirectly determined by this method.
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    Applied crystallography online 8 (1975), S. 42-44 
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    Notes: A means of measuring strain and lattice parameter directly in epitaxic layers by `double-crystal' X-ray diffraction is presented. The method described has three major advantages; that it is achieved by a simple addition to a commercial goniometer; that the area of sample illuminated is defined solely by the collimator; and that single or double-crystal diffraction can be selected, simultaneously if needed, on exactly the same specimen area.
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  • 56
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    Applied crystallography online 8 (1975), S. 45-48 
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    Notes: A silicon powder Standard Reference Material, SRM-640, has been prepared for use as a standard in powder diffractometry. Powder diffraction measurements were performed with a tungsten internal standard and a high-angle goniometer. The measured a/λ is 3.525176. With λ(Cu Kα1 peak) taken as 1.5405981 Å, a = 5.430880 (35) Å, uncorrected for refraction. Comparison of a with values obtained with a single-crystal from one of the boules reveals a difference of 3 parts in 105. This difference suggests a subtle systematic error in powder diffractometry or a change in lattice spacing near crystal boundaries. Use of the SRM should permit individual measurements of lattice parameters to be made reproducible to near 1 part in 105 and an absolute accuracy of at least 3 parts in 105.
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  • 57
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    Applied crystallography online 8 (1975), S. 111-114 
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    Topics: Geosciences , Physics
    Notes: The assumptions in the Borie & Sparks [Acta Cryst. (1971). A27, 198–201] procedure for the separation of order- and displacement-dependent components of diffuse X-ray scattering from a binary system AB are examined with the use of the concentration deviation (spin-like) notation. The more limiting assumption, that the structure-factor ratio η = (mAfA + mBfB)/(fA−fB) is constant in reciprocal space, is shown to produce an incomplete separation for normal variations in η. A matrix-inversion method for completing the separation is suggested for those cases in which the approximate equality of the Debye–Waller factors (DWF) of the individual atomic species indicates that some terms of the scattering equation may be neglected. The extension suggested by Ramesh & Ramaseshan [Acta Cryst. (1971). A27, 569–572] that anomalous dispersion induced changes in η could be used to separate the atomic static displacement properties of the various atomic pairs is shown to require a change in η greater than the variation of η across the reciprocal-space volume. Some difficulties of obtaining such a change are pointed out.
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  • 58
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    Applied crystallography online 8 (1975), S. 121-126 
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    Notes: The role of positional information in determining the thermodynamics of crystalline solid solutions is considered. It is noted that, with certain exceptions (e.g.b.c.c. Fe–B), such solutions can be classified as being exclusively either substitutional or interstitial with respect to each solute. Calculation of thermodynamic properties of intersitital solutions requires knowledge of the types of sites preferentially occupied by the solute. The problem of determining that occupancy is considered for several binary systems. A cumulant expansion technique, which meets with good success in describing dilute, high-temperature, interstitial solutions, is applied to the case of high-temperature binary substitutional systems of similar metals. The technique is shown to be of limited utility in this application.
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    Applied crystallography online 8 (1975), S. 127-127 
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    Topics: Geosciences , Physics
    Notes: It may be essential in certain cases (e.g. non-dilute alloys and dislocations) to take into account the (pair and higher-order) correlations in the defect distribution. To this end the kinematic expression for the total scattered intensity is rewritten.
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    Applied crystallography online 8 (1975), S. 132-132 
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    Notes: If the occurrence of one or two-dimensional local order in alloys or in neutron-irradiated materials has been known for many years, the observation by X-ray and neutron scattering of quasi-one-dimensional order due to displacements or correlated motions of atoms along independent chains is more recent. Examples to be discussed are given.
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    Applied crystallography online 8 (1975), S. 75-75 
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    Applied crystallography online 8 (1975), S. 76-76 
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    Applied crystallography online 8 (1975), S. 128-128 
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    Topics: Geosciences , Physics
    Notes: Structural studies showed that oxygen atoms in Ih ice are well ordered whereas hydrogen atoms are `statistically' distributed on two possible sites on each O–H–O bond.
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    Applied crystallography online 8 (1975), S. 185-185 
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    Notes: The integral Huang diffuse X-ray scattering from crystals containing small dislocation loops can be analyzed to obtain two types of information: (1) the size distribution of the loops and (2) the total number of point defects contained in the loops. This technique has been applied to copper crystals irradiated under a number of conditions of neutron irradiation flux, dose and temperature, for which loops are produced, and to selected annealing studies of these loops, with all X-ray measurements made at room temperature.
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    Applied crystallography online 8 (1975), S. 191-192 
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    Topics: Geosciences , Physics
    Notes: Explanations for the broadening of X-ray line profiles of plastically deformed crystals in terms of the density and the distribution of the dislocations introduced during deformation are given.
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    Applied crystallography online 8 (1975), S. 140-140 
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    Notes: The ω phase transformation in Zr–Nb alloys has been studied by measuring the X-ray diffuse scattering in the (110) plane and the Mössbauer diffuse scattering along the 〈111〉 direction of separate single crystals with compositions ranging from 8 to 30% Nb.
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    Applied crystallography online 8 (1975), S. 141-141 
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    Topics: Geosciences , Physics
    Notes: A simple crystallographic approach in obtaining the final martensitic structure [3R, 1R, 2H) from the initial displacive modes is presented.
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    Applied crystallography online 8 (1975), S. 142-142 
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    Notes: The theory of the diffuse scattering from crystals with small concentrations of point defects and small clusters is reviewed.
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    Applied crystallography online 8 (1975), S. 143-143 
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    Notes: Analytic expressions for the dilation and the stress tensor in reciprocal space are discussed.
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    Applied crystallography online 8 (1975), S. 203-203 
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    Notes: The boundary between the −X and Z growth regions in synthetic quartz has been studied using X-ray topography and other techniques and it has been found that the crystal lattice remains coherent at the boundary.
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    Applied crystallography online 8 (1975), S. 204-204 
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    Notes: The diffraction of electrons is, in principle, a very sensitive probe of the relative atomic positions in ordered or disordered crystals. The full potential of electron diffraction and electron microscopy methods for the study of local atomic arrangements has not been realised because of the difficulties of conducting experiments under sufficiently well defined conditions and because of the complications introduced by the dynamical diffraction processes involved.
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    Applied crystallography online 8 (1975), S. 183-183 
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    Notes: The diffuse elastic neutron scattering due to distortion of the Pb host lattice around Bi substitutional atoms has been measured at the HFR in Grenoble and the results discussed.
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    Applied crystallography online 8 (1975), S. 175-183 
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    Notes: For interstitials the scattering cross section between the Bragg reflections is very sensitive to the position of the defect atom and the displacements of the neighbouring lattice atoms. In contrast to this the scattering near the Bragg reflections (Huang scattering) is mainly governed by the displacement field at large distances from the defect and gives information about defect symmetry and strength [Trinkaus, H. (1972). Phys. Stat. Sol. (b) 51, 307–319]. For determining structures of point defects a measurement of scattering far from reciprocal-lattice points is therefore the best suited and most direct method. X-ray measurements of point-defect scattering in this region far from reciprocal-lattice points are difficult. With conventional X-ray set-ups it is not possible to separate the defect scattering from the thermal diffuse and Compton background scattering which is up to two orders of magnitude larger in the case of typical defect concentrations of some 10−4. Such measurements, however, become possible if large X-ray sources of high luminous density are used in connexion with multidetector arrangements. As an example an experimental arrangement [Haubold, H.-G. & Schilling, W. (1975). To be published; Haubold, H.-G. (1974). Rep. Kernforschungsanlage Jülich, JUL-1090-FF] is reviewed, in which the scattering cross-section of self-interstitials in aluminium was measured in samples containing an atomic density of interstitials up to 5 × 10−4.
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    Applied crystallography online 8 (1975), S. 184-184 
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    Notes: Second-order pseudopotential calculations are known to reproduce fairly well the structure and phonon spectra of many simple metals. The validity of the underlying assumption of linear screening for impurities with valences and core radii close to those of the host can be checked a posteriori and by comparing calculated properties with measurements on dilute alloys, and, especially, coherent elastic neutron scattering.
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    Applied crystallography online 8 (1975), S. 185-185 
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    Notes: Analytical methods to describe the scattering from crystals containing defect clusters with strong displacement fields are reviewed.
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    Applied crystallography online 8 (1975), S. 193-194 
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    Notes: Work which has been started at Pelindaba on small-angle scattering in neutron irradiated copper is described.
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    Applied crystallography online 8 (1975), S. 193-193 
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    Notes: Voids formed in neutron irradiated metals are faceted on various crystallographic planes. This faceting has been shown to cause significant anisotropy in the small-angle scattering pattern. It is shown that it is possible to obtain the specific void surface energies from small-angle diffuse scattering data.
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    Applied crystallography online 8 (1975), S. 224-224 
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    Notes: The weak-beam method of electron microscopy provides a means for studying lattice defects with greatly increased resolution compared with normal diffraction contrast techniques.
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    Applied crystallography online 8 (1975), S. 386-387 
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    Notes: The thermal expansion of cyclopentadienylthallium, TlC5H5, was determined in the range 78 to 295 K, using X-ray powder diffractometry. Expansion is very anisotropic: α1 = 125 ± 12, α2 = 97 ± 5, α3 = 0 ± 4 (all 10−6 K−1). Directions and ratio of the two greatest expansion coefficients: α1 and α2, are explained by considering the shortest distances Tl+–Tl|+ in this ionic structure.
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    Applied crystallography online 8 (1975), S. 392-395 
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    Notes: Several guanidinium salts have been studied since, because they contain six hydrogen atoms per unit charge, they are likely to contain multiple hydrogen bonding systems [see e.g. Adams & Small (1974). Acta Cryst. B30, 2191–2193], which are of interest in themselves and are also likely to cause stabilization of the structure. The crystal data of a range of salts were collected and are given. Space group and approximate cell dimensions were obtained from oscillation and Weissenberg photographs. Powder diffraction data [0° to 60° (2&thgr; using Cu Kα)] were indexed and the cell parameters refined using the programs PIRUM of Werner [Program No. 1, World List of Crystallographic Computer Programs (3rd. ed.): J. Appl. Cryst. (1973). 6, 309–346] and CELFIT of Bracher [UKAEA Research Report, AERE-R5412 (1967)].
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    Applied crystallography online 8 (1975), S. 397-397 
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    Notes: Unlike the position with negatively charged substituents, little has been done on benzaldehydes ortho-substituted with positively charged groups. This is more especially true in the field of crystallography where only the X-ray and neutron diffraction study of o-nitrobenzaldehyde has been reported [Coppens & Schmidt, Acta Cryst. (1964). 17, 222–228; Coppens, Acta Cryst. (1964). 17, 573–578]. Preliminary results of a structural investigation on Se- and Te-containing benzaldehydes are presented. The main purpose is to corroborate and to complete the conclusion of recent n.m.r. work on the conformation of these molecules [Baiwir, Llabres, Denoel & Piette, Mol. Phys. (1973). 25, 1–7]. The following compounds have been studied: C6H4.COH.TeCl, C6H4.COH.TeBr, C6H4.COH.TeI, C6H4 COH.SeCl, C6H4.COH.SeBr. The crystal structure of the second (TeBr) has been recently reported [Baiwir Llabres, Dideberg, Dupont & Piette, Acta Cryst. (1974). B30, 139–143] and the structure of the last (SeBr) is presently in the final stage of refinement.
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    Applied crystallography online 8 (1975), S. 402-402 
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    Applied crystallography online 8 (1975), S. 403-403 
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    Applied crystallography online 8 (1975), S. 405-414 
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    Notes: Quantitative liquid-structure analysis using energy-scanning diffraction rather than the traditional angle-scanning diffraction is introduced. In the experimental method, white radiation and a solid-state detector are employed. This new method is inherently faster and less beset with problems of experimental instability than are angular-scanning methods. However, many differences in analysis are introduced. In particular, measurement of the primary beam spectrum, the nature of the absorption and dispersion corrections, details of the polarization correction, the ranges of the atomic scattering factor and of the incoherent scattering term, and the mating of different scattering regimes all require special consideration. Application of the new instrumental method and the reconstructed analytical procedure to liquid mercury at room temperature has produced a result in agreement with other recent studies.
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    Applied crystallography online 8 (1975), S. 421-429 
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    Notes: A new small-angle X-ray scattering facility which utilizes a 6 kW rotating anode, pin-hole collimation, and a position-sensitive proportional counter has been developed. As presently constructed, the minimum scattering vector κ (= 4π sin &thgr;/2) which can be reached with Cu Kα radiation is 5 × 10−3 Å−1. Under these conditions the flux incident on the specimen has been found to be 6 × 105 photons s−1. The system has several advantages compared with traditional long-slit geometries; namely, (i) it can quantitatively measure anisotropic scattering distributions, (ii) it avoids large mathematical corrections of the data for slit-smearing effects, and (iii) it minimizes double Bragg scattering in crystalline materials and multiple diffuse scattering in amorphous or liquid materials. To illustrate the performance of this instrument, the scattering curves obtained from four widely different samples are shown. These are: polyethylene, a neutron-irradiated aluminium single-crystal containing voids, a dilute suspension of Ludox spheres, and duck tendon collagen. Quantitative comparisons of the performance with a Kratky camera and with the neutron small-angle scattering facility in Jülich are given.
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    Applied crystallography online 8 (1975), S. 457-458 
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    Notes: The lattice constants of a diamond platelet and of large single, undoped, crystals of silicon and germanium have been determined from measurements of multiple diffraction patterns by the method described in Part I [Post (1975). J. Appl. Cryst. 8, 452–456]. The mean values, based on measurements of eight to twelve reflections, and their standard deviations are: diamond a = 3.566986 Å, Aa/a = 2.6 × 10−6; silicon a = 5.430941 Å, Aa/a = 2 × 10−6; germanium a = 5.657820 Å, Δa/a = 1.6 × 10−6.
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    Applied crystallography online 8 (1975), S. 469-472 
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    Notes: The Mn3+ site distribution in a manganese-containing tsilaisite tourmaline sample has been determined as 46±3 wt. % in the larger Y octahedral sites and 54± 3 wt. % in the smaller Z octahedral sites. For this, a novel application of anomalous X-ray scattering techniques, in conjunction with the energy dispersive X-ray diffraction procedure, has been used. This method appears to be versatile and applicable to many different elements.
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    Applied crystallography online 8 (1975), S. 491-492 
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    Notes: An inexpensive calculation is outlined for determining those reflexions suffering large absorption errors, and for correcting those with smaller errors.
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    Applied crystallography online 8 (1975), S. 496-496 
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    Applied crystallography online 8 (1975), S. 496-497 
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    Applied crystallography online 8 (1975), S. 375-379 
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    Notes: The lattice parameters and the linear coefficient of the lattice thermal expansion of f.c.c. β-Cu2−xSe (1.86 ≥ 2−x ≥ 1.72) were determined by means of the Debye–Scherrer X-ray diffraction technique in the temperature range 25–336°C. The concentration and temperature dependence of the coefficient of thermal expansion are discussed. In addition the equilibrium phase diagram of the Cu–Se system in the region of a non-stoichiometric Cu2−xSe compound (2.00 ≥2−x ≥1.72) was redetermined, with special consideration of the homogeneity range of the f.c.c. β-Cu2−xSe, and compared with previously published results.
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    Applied crystallography online 8 (1975), S. 391-391 
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    Notes: Crystals of Tl2GeS3 were grown by solidification from melts. The compound is triclinic with lattice parameters a = 8.06, b = 12.70, c = 6.76 Å, α = 96°39′, β = 93°10′, γ = 99°31′. Powder data are given.
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    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 8 (1975), S. 589-597 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: A computer program has been written in Fortran for the numerical calculation, using generalized spherical harmonics, of the texture of a sample, even when it has no symmetry. Automatically plotted pole figures, corrected and normalized, make it possible to begin to control the results. Reconstituted pole figures are plotted as a function of Cmνl. The calculations, based on the theoretical developments of Bunge [Mathematische Methoden der Texturanalyse. (1969). Berlin: Akademie Verlag] were carried out with different numerical analyses so as to reduce the size of the calculation and the time taken.
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  • 94
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    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 8 (1975), S. 578-581 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: The white X-ray diffraction method with the use of a powder sample [Laine, Läihteenmäki & Kantola (1972). X-ray Spectrosc. 1, 93–98] was improved by paying special attention to the following four points: (i) the determination of the energy spectrum of incident white X-rays, (ii) the measurement of the energy dependence of the relative absorption coefficient, (iii) the correction for the contribution from thermal diffuse scattering, and (iv) the correction for the anomalous dispersion. The determination of the structure factors of GaP is shown as an example of its applications. The structure factors determined were compared with those obtained by the usual angle dispersive method with monochromated X-rays on the same sample. It is shown that these two sets of structure factors mostly agree within the limit of reproducibility.
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  • 95
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    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 8 (1975), S. 612-614 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: The errors in the Fourier coefficients of the α1 component obtained by α2 elimination are investigated analytically. The effects of counting statistics, of an incorrect intensity ratio of the α1 and α2 components and of an incorrect doublet separation are calculated. The mean-square error in the Fourier coefficient caused by counting statistics is a periodic function of the harmonic number, while errors in the intensity ratio and in the doublet separation primarily affect the first Fourier coefficients. The results are confirmed by computer simulations and by computations with experimental line profiles. The α2 elimination methods assume a perfect shape identity of the α1 and α2 components, but this assumption is not completely justified. Deviations might be interpreted as local errors in the doublet separation and the intensity ratio.
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  • 96
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    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 8 (1975), S. 628-635 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: The textures of undirectionally and reversed rolled aluminium sheets were measured using thermal neutrons and Cu and Mo Kα radiation. The samples for the X-ray measurements were prepared in three different ways so that the degree of correspondence between textures as measured with neutrons and X-rays could be investigated. It is shown that agreement can be achieved if the X-rays used penetrate sufficiently into the sample and if a composite type sample is used.
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  • 97
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    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 9 (1976), S. 14-17 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: A detailed description of an automatic low-temperature apparatus to be used in single-crystal diffractometry is given. The crystal is cooled by a stream of nitrogen gas. Prevention of ice formation on the crystal is achieved by heating the outer parts of the gas stream by a conical metal device. The unit-cell dimensions of α-quartz have been determined in the temperature range 86–298 K with this apparatus on a four-circle diffractometer of type CAD-4.
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  • 98
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    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 9 (1976), S. 34-38 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: X-ray reflection topographs were taken of a zinc surface oriented about 1° from a basal plane. Basal dislocations are revealed in the topographs, and their apparent depth was determined using stereo pairs of topographs. The apparent depths observed in a complimentary pair of topographs using 10\bar 13 and \bar 1013 reflections were significantly greater than those observed in an asymmetric pair of topographs in which the same 10\bar 13 reflection was used. This difference is attributed to shifts of the image with respect to the dislocation position. Quantitative estimates of the image shifts and the actual depths of the observed dislocations are obtained from the measurement of apparent depths. Dislocations are visible over the range of depths from 1.7 to 4.5 μm.
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  • 99
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    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 9 (1976), S. 253-254 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: A set of Fortran programs for radial distribution function analyses of X-ray and electron diffraction data of liquid and amorphous samples is available. The programs relate, first, to the formation of a reduced intensity function, F(K) ≡ (I − 〈f2〉)/〈f〉2, where I is the coherent scattered intensity in electron units, K is 4π sin &thgr;/λ, and 〈f〉 is the average of the scattering factors. The experimental radial distribution function G(r) = 4πr[ρ(r)−ρ0], is derived as the Fourier sine integral of F(K).
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  • 100
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    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 9 (1976), S. 257-258 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
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