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  • Cell & Developmental Biology  (11.846)
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  • 1
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    Exploring Resilience (2021)
    Springer Nature
    Details
    Publikationsdatum: 2021-02-10
    Beschreibung: Resilience has become an important topic on the safety research agenda and in organizational practice. Most empirical work on resilience has been descriptive, identifying characteristics of work and organizing activity which allow organizations to cope with unexpected situations. Fewer studies have developed testable models and theories that can be used to support interventions aiming to increase resilience and improve safety. In addition, the absent integration of different system levels from individuals, teams, organizations, regulatory bodies, and policy level in theory and practice imply that mechanisms through which resilience is linked across complex systems are not yet well understood. Scientific efforts have been made to develop constructs and models that present relationships; however, these cannot be characterized as sufficient for theory building. There is a need for taking a broader look at resilience practices as a foundation for developing a theoretical framework that can help improve safety in complex systems. This book does not advocate for one definition or one field of research when talking about resilience; it does not assume that the use of resilience concepts is necessarily positive for safety. We encourage a broad approach, seeking inspiration across different scientific and practical domains for the purpose of further developing resilience at a theoretical and an operational level of relevance for different high-risk industries. The aim of the book is twofold: 1. To explore different approaches for operationalization of resilience across scientific disciplines and system levels. 2. To create a theoretical foundation for a resilience framework across scientific disciplines and system levels. By presenting chapters from leading international authors representing different research disciplines and practical fields we develop suggestions and inspiration for the research community and practitioners in high-risk industries. This book is Open Access under a CC-BY licence. ; Explores different approaches for operationalization of resilience across scientific disciplines and system levels Creates a theoretical foundation for a resilience framework across scientific disciplines and system levels Develops suggestions and inspiration for the research community and practitioners in high-risk industries Presents chapters from leading international authors representing different research disciplines and practical fields
    Schlagwort(e): Engineering ; Quality control ; Reliability ; Industrial safety ; Health economics ; Environmental management ; Health informatics ; Organization ; Planning ; Health care management ; Health services administration ; bic Book Industry Communication::K Economics, finance, business & management::KC Economics::KCQ Health economics ; bic Book Industry Communication::K Economics, finance, business & management::KJ Business & management::KJU Organizational theory & behaviour ; bic Book Industry Communication::M Medicine::MB Medicine: general issues::MBG Medical equipment & techniques ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RN The environment::RNF Environmental management ; bic Book Industry Communication::T Technology, engineering, agriculture::TG Mechanical engineering & materials::TGP Production engineering::TGPR Reliability engineering
    Sprache: Englisch
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  • 2
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    The Hackable City (2021)
    Springer Nature
    Details
    Publikationsdatum: 2024-03-25
    Beschreibung: This open access book presents a selection of the best contributions to the Digital Cities 9 Workshop held in Limerick in 2015, combining a number of the latest academic insights into new collaborative modes of city making that are firmly rooted in empirical findings about the actual practices of citizens, designers and policy makers. It explores the affordances of new media technologies for empowering citizens in the process of city making, relating examples of bottom-up or participatory practices to reflections about the changing roles of professional practitioners in the processes, as well as issues of governance and institutional policymaking. ;
    Schlagwort(e): Engineering ; Electrical engineering ; Regional planning ; Urban planning ; User interfaces (Computer systems) ; thema EDItEUR::R Earth Sciences, Geography, Environment, Planning::RP Regional and area planning ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJK Communications engineering / telecommunications ; thema EDItEUR::U Computing and Information Technology::UY Computer science::UYZ Human–computer interaction::UYZG User interface design and usability
    Sprache: Englisch
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  • 3
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    City of the Future Graduation Lab (2023)
    TU Delft OPEN Publishing
    Details
    Publikationsdatum: 2024-03-23
    Beschreibung: The Cross Domain City of the Future Graduation Lab, situated in the Faculty of Architecture and the Built Environment at TU Delft, has been a pioneer in experimenting with a multidisciplinary approach to education on the built environment. Drawing upon this expertise over the past years, this book reflects on multidisciplinarity in the built environment and its implementation in education on the built environment. How should one approach multidisciplinarity in education and practice? What encompasses its core elements, benefits, and challenges? By addressing these questions, the book aims to inform students and practitioners within the realm of the built environment by sharing insights from experiences in multidisciplinary education. It presents eight conclusions regarding the future of multidisciplinary education and, thereby, seeks to contribute to a more humane and sustainable future for cities: 1.Process is central to multidisciplinary collaboration. Negotiating positions, ensuring an environment of respect, balance and open-mindedness, and setting a common vocabulary. 2.Multidisciplinarity can be a way to foster innovation. It triggers complementarity and confrontation. As with any innovation, there is potential for greater outcomes, but, at the same time, extra risks emerge. These need to be managed. 3.Multidisciplinarity could be better integrated into organisational structures. 4.Disciplinarity and multidisciplinarity are in mutual coexistence. They are inseparable. They can complement and contradict each other. 5.Problem precedes solution, not the opposite. Framing the problem, or ‘problematizing’, is a considerable share of the actual solution. This is particularly applicable to multidisciplinarity. 6.Multidisciplinarity is by nature composed of fluid boundaries. Navigating through an enormous diversity of perspectives requires agility, flexibility, independence, spirit of adventure and embracing uncertainty. 7.Professionals should be trained as ‘T-shape’: grounded in their field while able to dialogue with other fields. 8.Both generalists and specialists are needed. Education should provide opportunities for both.
    Schlagwort(e): City ; Future ; Multidisciplinarity ; Design ; Education ; Engineering ; Graduation Lab ; Built Environment ; Architecture ; Urban Design ; Management ; Geomatics ; Transport ; Infrastructure ; Logistics ; Collaboration ; thema EDItEUR::A The Arts::AM Architecture
    Sprache: Englisch
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  • 4
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    Handbook of Contact Mechanics (2021)
    Springer Nature
    Details
    Publikationsdatum: 2024-04-07
    Beschreibung: This open access book contains a structured collection of the complete solutions of all essential axisymmetric contact problems. Based on a systematic distinction regarding the type of contact, the regime of friction and the contact geometry, a multitude of technically relevant contact problems from mechanical engineering, the automotive industry and medical engineering are discussed. In addition to contact problems between isotropic elastic and viscoelastic media, contact problems between transversal-isotropic elastic materials and functionally graded materials are addressed, too. The optimization of the latter is a focus of current research especially in the fields of actuator technology and biomechanics. The book takes into account adhesive effects which allow access to contact-mechanical questions about micro- and nano-electromechanical systems. Solutions of the contact problems include both the relationships between the macroscopic force, displacement and contact length, as well as the stress and displacement fields at the surface and, if appropriate, within the half-space medium. Solutions are always obtained with the simplest available method - usually with the method of dimensionality reduction (MDR) or approaches which use the solution of the non-adhesive normal contact problem to solve the respective contact problem.
    Schlagwort(e): Engineering ; Mechanics ; Mechanics, Applied ; Mechanics ; Applied mathematics ; Engineering mathematics ; thema EDItEUR::P Mathematics and Science::PH Physics::PHD Classical mechanics ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues::TBJ Maths for engineers ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGM Materials science::TGMD Engineering: Mechanics of solids
    Sprache: Englisch
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  • 5
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    Algorithms for Scheduling Problems (2021)
    MDPI - Multidisciplinary Digital Publishing Institute
    Details
    Publikationsdatum: 2022-01-31
    Beschreibung: This edited book presents new results in the area of algorithm development for different types of scheduling problems. In eleven chapters, algorithms for single machine problems, flow-shop and job-shop scheduling problems (including their hybrid (flexible) variants), the resource-constrained project scheduling problem, scheduling problems in complex manufacturing systems and supply chains, and workflow scheduling problems are given. The chapters address such subjects as insertion heuristics for energy-efficient scheduling, the re-scheduling of train traffic in real time, control algorithms for short-term scheduling in manufacturing systems, bi-objective optimization of tortilla production, scheduling problems with uncertain (interval) processing times, workflow scheduling for digital signal processor (DSP) clusters, and many more.
    Schlagwort(e): QA75.5-76.95 ; QA1-939 ; Scheduling under Resource Constraints ; Enumerative Algorithms ; Scheduling under Uncertainty ; Assembly Scheduling ; Timetabling ; Approximation Algorithms ; Scheduling Problems in Logistics ; Complex Scheduling Problems ; Engineering ; Complexity Issues ; Scheduling Heuristics and Metaheuristics ; Agent Based Scheduling ; Just-in-Time Scheduling ; Real-Time Scheduling ; Scheduling Problems in Segments of a Supply Chain ; Healthcare ; Evolutionary Algorithms ; Energy Management etc. ; Transport ; Vehicle Routing ; Sports
    Sprache: Englisch
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  • 6
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    Autonome Shuttlebusse im ÖPNV (2021)
    Springer Nature
    Details
    Publikationsdatum: 2024-04-11
    Beschreibung: Automatisiertes Fahren wird aktuell auf allen Ebenen diskutiert. Dieses Open Access Buch greift das Thema aus Sicht des ÖPNV auf und stellt Chancen und Risiken des Einsatzes automatisierter Shuttlebusse im Nahverkehr dar. Am Beispiel Bad Birnbach/Niederbayern wird gezeigt, welche Herausforderungen bei der Einführung eines solchen Services zu erwarten sind und wie diese gelöst werden können. Dabei fokussiert sich das Buch auf die Vermittlung von im Feld erhobenen Daten, z.B. zu technischen Schwierigkeiten, Erfahrungsberichten von Anwohnern und Gästen, Akzeptanz in der Bevölkerung, infrastrukturellen Anforderungen, etc. Konkrete Handlungsempfehlungen für Städteplaner, ÖPNV-Betreiber/-Strategen oder Kommunen, die eine Einführung automatisierter Busse in Erwägung ziehen, runden das Werk ab.
    Schlagwort(e): Engineering ; Automotive engineering ; Transportation engineering ; Traffic engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TN Civil engineering, surveying and building::TNH Highway and traffic engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TR Transport technology and trades::TRC Automotive technology and trades
    Sprache: Deutsch
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  • 7
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    Technè/Technology (2023)
    Amsterdam University Press
    Details
    Publikationsdatum: 2024-03-23
    Beschreibung: Techne;/Technology offers a penetrating, close look at the origins of the term techne;, which unleashed a revolution in cinema and media studies when it was first introduced and which continues to influence the study of film as the digital revolution rolls along. The contributors investigate the effects of technologies on major film debates and, moreover, how technologies have affected film theory and its key concepts.
    Schlagwort(e): Film Studies ; Communication Studies ; Engineering ; thema EDItEUR::A The Arts::AT Performing arts::ATF Films, cinema ; thema EDItEUR::A The Arts::AT Performing arts::ATJ Television ; thema EDItEUR::J Society and Social Sciences::JB Society and culture: general::JBC Cultural and media studies::JBCT Media studies ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues
    Sprache: Englisch
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  • 8
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    How nature shaped echolocation in animals (2021)
    Frontiers Media SA
    Details
    Publikationsdatum: 2024-03-31
    Beschreibung: Echolocation has evolved in different groups of animals, from bats and cetaceans to birds and humans, and enables localization and tracking of objects in a dynamic environment, where light levels may be very low or absent. Nature has shaped echolocation, an active sense that engages audiomotor feedback systems, which operates in diverse environments and situations. Echolocation production and perception vary across species, and signals are often adapted to the environment and task. In the last several decades, researchers have been studying the echolocation behavior of animals, both in the air and underwater, using different methodologies and perspectives. The result of these studies has led to rich knowledge on sound production mechanisms, directionality of the sound beam, signal design, echo reception and perception. Active control over echolocation signal production and the mechanisms for echo processing ultimately provide animals with an echoic scene or image of their surroundings. Sonar signal features directly influence the information available for the echolocating animal to perceive images of its environment. In many echolocating animals, the information processed through echoes elicits a reaction in motor systems, including adjustments in subsequent echolocation signals. We are interested in understanding how echolocating animals deal with different environments (e.g. clutter, light levels), tasks, distance to targets or objects, different prey types or other food sources, presence of conspecifics or certain predators, ambient and anthropogenic noise. In recent years, some researchers have presented new data on the origins of echolocation, which can provide a hint of its evolution. Theoreticians have addressed several issues that bear on echolocation systems, such as frequency or time resolution, target localization and beam-forming mechanisms. In this Research Topic we compiled recent work that elucidates how echolocation – from sound production, through echolocation signals to perception- has been shaped by nature functioning in different environments and situations. We strongly encouraged comparative approaches that would deepen our understanding of the processes comprising this active sense.
    Schlagwort(e): QP1-981 ; Q1-390 ; bats ; Biosonar ; Humans ; marine mammals ; sensory biology ; Birds ; Behavior ; Communication ; thema EDItEUR::M Medicine and Nursing::MF Pre-clinical medicine: basic sciences::MFG Physiology
    Sprache: Englisch
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  • 9
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    BioMEMS (2021)
    Taylor & Francis | CRC Press
    Details
    Publikationsdatum: 2022-04-28
    Beschreibung: As technological advancements widen the scope of applications for biomicroelectromechanical systems (BioMEMS or biomicrosystems), the field continues to have an impact on many aspects of life science operations and functionalities. Because BioMEMS research and development require the input of experts who use different technical languages and come from varying disciplines and backgrounds, scientists and students can avoid potential difficulties in communication and understanding only if they possess a skill set and understanding that enables them to work at the interface of engineering and biosciences. Keeping this duality in mind throughout, BioMEMS: Science and Engineering Perspectives supports and expedites the multidisciplinary learning involved in the development of biomicrosystems. Divided into nine chapters, it starts with a balanced introduction of biological, engineering, application, and commercialization aspects of the field. With a focus on molecules of biological interest, the book explores the building blocks of cells and viruses, as well as molecules that form the self-assembled monolayers (SAMs), linkers, and hydrogels used for making different surfaces biocompatible through functionalization. The book also discusses: Different materials and platforms used to develop biomicrosystems Various biological entities and pathogens (in ascending order of complexity) The multidisciplinary aspects of engineering bioactive surfaces Engineering perspectives, including methods of manufacturing bioactive surfaces and devices Microfluidics modeling and experimentation Device level implementation of BioMEMS concepts for different applications. Because BioMEMS is an application-driven field, the book also highlights the concepts of lab-on-a-chip (LOC) and micro total analysis system (μTAS), along with their pertinence to the emerging point-of-care (POC) and point-of-need (PON) applications.
    Schlagwort(e): BioMEMS ; Engineering ; Perspectives ; Science ; bic Book Industry Communication::M Medicine::MF Pre-clinical medicine: basic sciences ; bic Book Industry Communication::T Technology, engineering, agriculture::TC Biochemical engineering::TCB Biotechnology ; bic Book Industry Communication::M Medicine::MQ Nursing & ancillary services::MQW Biomedical engineering ; bic Book Industry Communication::T Technology, engineering, agriculture::TJ Electronics & communications engineering::TJF Electronics engineering ; bic Book Industry Communication::T Technology, engineering, agriculture::TG Mechanical engineering & materials::TGM Materials science
    Sprache: Englisch
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  • 10
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    Frontiers in Chemistry: Rising Stars (2021)
    Frontiers Media SA
    Details
    Publikationsdatum: 2024-04-04
    Beschreibung: The Frontiers in Chemistry Editorial Office team are delighted to present the inaugural “Frontiers in Chemistry: Rising Stars” article collection, showcasing the high-quality work of internationally recognized researchers in the early stages of their independent careers. All Rising Star researchers featured within this collection were individually nominated by the Journal’s Chief Editors in recognition of their potential to influence the future directions in their respective fields. The work presented here highlights the diversity of research performed across the entire breadth of the chemical sciences, and presents advances in theory, experiment and methodology with applications to compelling problems. This Editorial features the corresponding author(s) of each paper published within this important collection, ordered by section alphabetically, highlighting them as the great researchers of the future. The Frontiers in Chemistry Editorial Office team would like to thank each researcher who contributed their work to this collection. We would also like to personally thank our Chief Editors for their exemplary leadership of this article collection; their strong support and passion for this important, community-driven collection has ensured its success and global impact.
    Schlagwort(e): Green and Sustainable Chemistry ; Analytical Chemistry ; Theoretical and Computational Chemistry ; Polymer Chemistry ; Medicinal and Pharmaceutical Chemistry ; Organic Chemistry ; Nanoscience ; Catalysis and Photocatalysis ; Supramolecular Chemistry ; Electrochemistry ; Inorganic Chemistry ; Chemical Biology ; thema EDItEUR::P Mathematics and Science::PD Science: general issues
    Sprache: Englisch
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  • 11
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    Flexitranstore (2021)
    Springer Nature
    Details
    Publikationsdatum: 2024-04-11
    Beschreibung: This open access book comprises 10 high-level papers on research and innovation within the Flexitranstore Project that were presented at the FLEXITRANSTORE special session organized as part of the 21st International Symposium on High Voltage Engineering. FLEXITRANSTORE (An Integrated Platform for Increased FLEXIbility in smart TRANSmission grids with STORage Entities and large penetration of Renewable Energy Sources) aims to contribute to the development of a pan-European transmission network with high flexibility and high interconnection levels. This will facilitate the transformation of the current energy production mix by hosting an increasing share of renewable energy sources. Novel smart grid technologies, control and storage methods, and new market approaches will be developed, installed, demonstrated, and tested introducing flexibility to the European power system. FLEXITRANSTORE is developing a next-generation Flexible Energy Grid (FEG) that will be integrated into the European Internal Energy Market (IEM) through the valorization of flexibility services. This FEG addresses the capabilities of a power system to maintain continuous service in the face of rapid and large swings in supply or demand. As such, a wholesale market infrastructure and new business models within this integrated FEG must be upgraded for network players, and offer incentives for new ones to join, while at the same time demonstrating new business perspectives for cross-border resource management and energy trading.
    Schlagwort(e): Engineering ; Power electronics ; Electronics ; Microelectronics ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TH Energy technology and engineering::THR Electrical engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJF Electronics engineering
    Sprache: Englisch
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  • 12
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    Specification for Tunnelling (2024)
    Emerald Publishing | ICE Publishing
    Details
    Publikationsdatum: 2024-04-11
    Beschreibung: The ebook edition of this title is Open Access and freely available to read online. Specification for Tunnelling, Fourth edition is a standard industry document for tunnelling contracts and forms the basis of tunnelling specifications for projects throughout the world. It reflects current industry best practice and considers technological advancements over the last ten years. It also investigates a range of new topics. Since the publication of the third edition in 2010, the British tunnelling industry has completed several major projects both domestic and abroad. This updated fourth edition captures the many advances made in the field of tunnelling and the lessons learned on these projects through a comprehensive review of all content by subject matter experts. The importance of sustainability and the increased market share of low CO2e materials have been reflected by removal of prescriptive requirements and a strong emphasis on performance-based specification. All references to codes, standards and other design documents have been comprehensively updated. Drafted by an expert editorial committee and supported by multiple rounds of industry-wide peer reviews, the Specification for Tunnelling in its fourth edition will continue to be the de facto standard reference work for tunnelling in the UK and worldwide.
    Schlagwort(e): Engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TN Civil engineering, surveying and building ; thema EDItEUR::L Law::LN Laws of specific jurisdictions and specific areas of law::LNC Company, commercial and competition law: general::LNCQ Construction and engineering law ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TN Civil engineering, surveying and building::TNK Building construction and materials ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TN Civil engineering, surveying and building ; thema EDItEUR::L Law::LN Laws of specific jurisdictions and specific areas of law::LNC Company, commercial and competition law: general::LNCQ Construction and engineering law ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TN Civil engineering, surveying and building::TNK Building construction and materials
    Sprache: Englisch
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  • 13
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    Impedance Spectroscopy. Advanced Applications: Battery Research, Bioimpedance, System Design (2021)
    De Gruyter
    Details
    Publikationsdatum: 2024-04-11
    Beschreibung: This book covers new advances in the field of impedance spectroscopy including fundamentals, methods and applications. It releases selected extended and peer reviewed scientific contributions from the International Workshop on Impedance Spectroscopy (IWIS 2017) focussing on detailed information about recent scientific research results in electrochemistry and battery research, bioimpedance measurement, sensors, system design, signal processing.
    Schlagwort(e): TA1-2040 ; International Workshop on Impedance Spectroscopy ; Engineering ; Electrochemistry and Battery Research ; Bioimpedance Measurement ; Sensors ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues::TBX History of engineering and technology
    Sprache: Englisch
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  • 14
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    Chocolate and Health: Friend or Foe? (2021)
    Frontiers Media SA
    Details
    Publikationsdatum: 2024-03-30
    Beschreibung: In the ancient past, cocoa has been appreciated as a high-calorie food to boost energy in soldiers and for its undefined medicinal and mystical properties. During other times, chocolate has been considered as the forbidden “food of God”: a treasure of pleasure for the mind and the soul. The overall perception of the consumer for chocolate was of a “charming” and appealing food with lots of negative aspects related to high sugar content leading to consider chocolate as “junk food” for its “obesigen” calories. Recently, in association with the renewed interest of nutrition science in alternative source of health-promoting foods and ingredients, a large body of research has been conducted to unravel the pro and cons of cocoa in relation to human health. Epidemiological evidences indicate that cocoa consumption helps preventing cardiovascular disease for its high content in bioactive flavonoids. Clinical trials show that chocolate consumption might improve vascular function, decreasing platelet aggregation and display an antioxidant and anti-inflammatory effect. The putative protective action of cocoa seems to be multi-factorial and involving different aspects of vascular, antioxidant and endothelial function. However, the mechanism(s) that account for the benefits of cocoa it is still unclear. The aim of this Research Topic is therefore to provide the reader with an objective picture of the state of art on the association between cocoa and health, mainly through the evidences of human trials; overwhelmingly considered the golden standard for nutritional science. The Research Topic will cover the analysis of the manufacturing processes of the chocolate and the antioxidant effects in humans as well as the majority of the putative health effects of chocolate and cocoa, such as anti-inflammatory properties, effect on immunity, platelet aggregation, blood pressure, endothelial function and cognitive behavior. Unraveling the functional properties of cocoa will help to understand if the 'food of God' is a primordial gift for the health of mankind.
    Schlagwort(e): R5-920 ; RC581-607 ; TX341-641 ; Antioxidants ; Obesity ; Flavonoids ; Humans ; Chocolate ; Blood pressure ; Inflammation ; Cognitive function ; Cocoa ; Immunity
    Sprache: Englisch
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  • 15
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    Gender Equity in STEM in Higher Education (2021)
    Taylor & Francis | Routledge
    Details
    Publikationsdatum: 2024-03-29
    Beschreibung: This timely volume brings together a range of international scholars to analyse cultural, political, and individual factors which contribute to the continued global issue of female underrepresentation in STEM study and careers. Offering a comparative approach to examining gender equity in STEM fields across countries including the UK, Germany, the United States, Hong Kong, Taiwan, South Africa, and China, the volume provides a thematic breakdown of institutional trends and national policies that have successfully improved gender equity in STEM at institutions of higher education. Offering case studies that demonstrate how policies interact with changing social and cultural norms, and impact women’s choices and experiences in relation to the uptake and continuation of STEM study at the undergraduate level, the volume highlights new directions for research and policy to promote gender equity in STEM at school, university, and career levels. Contributing to the United Nations’ (UN) 2030 Agenda for Sustainable Development, this text will benefit researchers, academics, and educators with an interest in science education, higher education, and gender equity in STEM fields. The text will also support further discussion and reflection around multicultural education, educational policy and politics, and the sociology of education more broadly.
    Schlagwort(e): Access ; Chilly culture in STEM ; Diversity ; discrimination ; Engineering ; female agency ; Gender equality ; Gender equity ; gendered norms ; gender disparities ; Higher education ; Inclusion ; inequalities ; leaky pipeline in STEM ; Math ; Mathematics ; Minorities ; National Science Foundation (NSF) ; ProActive Network (WEPAN) ; participation ; Science ; STEM ; STEM careers ; STEM education ; STEM labor market ; STEM tertiary education ; STEM workforce ; Sustainable Development Goals ; Technology ; UN SDG ; bic Book Industry Communication::J Society & social sciences::JN Education::JNM Higher & further education, tertiary education ; bic Book Industry Communication::J Society & social sciences::JN Education ; bic Book Industry Communication::J Society & social sciences::JN Education::JNF Educational strategies & policy ; thema EDItEUR::J Society and Social Sciences::JN Education::JNM Higher education, tertiary education ; thema EDItEUR::J Society and Social Sciences::JN Education ; thema EDItEUR::J Society and Social Sciences::JN Education::JNF Educational strategies and policy
    Sprache: Englisch
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  • 16
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    Electricity in Africa (2023)
    Boydell & Brewer | James Currey an imprint of Boydell & Brewer
    Details
    Publikationsdatum: 2024-03-29
    Beschreibung: No country has managed to develop beyond a subsistence economy without ensuring at least minimum access to electricity for the majority of its population. Yet many sub-Saharan African countries struggle to meet demand. Why is this, and what can be done to reduce energy poverty and further Africa's development? Examining the politics and processes surrounding electricity infrastructure, provision and reform, the author provides an overview of historical andcontemporary debates about access in the sub-continent, and explores the shifting role and influence of national governments and of multilateral agencies in energy reform decisions. He describes a challenging political environment for electricity supply, with African governments becoming increasingly frustrated with the rules and the processes of multilateral donors. Civil society also began to question reform choices, and governments in turn looked to new development partners, such as China, to chart a fresh path of energy transformation. Drawing on over fifteen years of research on Uganda, which has one of the lowest levels of access to electricity in Africa and has struggled to construct several, large hydroelectric dams on the Nile, Gore argues that there is a critical need to recognize how the changing political and social context in African countries, and globally, has affected the capacity to fulfil national energy goals, minimize energy poverty and transform economies.
    Schlagwort(e): Political Science ; African Studies ; Engineering ; bic Book Industry Communication::J Society & social sciences::JP Politics & government ; bic Book Industry Communication::T Technology, engineering, agriculture::TH Energy technology & engineering::THR Electrical engineering::THRB Power generation & distribution ; thema EDItEUR::J Society and Social Sciences::JP Politics and government ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TH Energy technology and engineering::THY Energy, power generation, distribution and storage
    Sprache: Englisch
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  • 17
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    Variant Construction from Theoretical Foundation to Applications (2021)
    Springer Nature
    Details
    Publikationsdatum: 2024-04-06
    Beschreibung: This open access book presents theoretical framework and sample applications of variant construction. The first part includes the components variant logic, variant measurements, and variant maps, while the second part covers sample applications such as variation with functions, variant stream ciphers, quantum interference, classical/quantum random sequences, whole DNA sequences, and multiple-valued pulse sequences. Addressing topics ranging from logic and measuring foundation to typical applications and including various illustrated maps, it is a valuable guide for theoretical researchers in discrete mathematics; computing-, quantum- and communication scientists; big data engineers; as well as graduate and upper undergraduate students.
    Schlagwort(e): Engineering ; Electronic circuits ; Logic design ; Electronic circuits ; Information theory ; thema EDItEUR::P Mathematics and Science::PB Mathematics::PBW Applied mathematics ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJF Electronics engineering::TJFC Electronics: circuits and components ; thema EDItEUR::U Computing and Information Technology::UY Computer science::UYF Computer architecture and logic design
    Sprache: Englisch
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  • 18
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    Buildings for Education (2021)
    Springer Nature
    Details
    Publikationsdatum: 2024-03-29
    Beschreibung: This open access book presents theoretical and practical research relating to the vast, publicly financed program for the construction of new schools and the reorganization of existing educational buildings in Italy. This transformative process aims to give old buildings a fresh identity, to ensure that facilities are compliant with the new educational and teaching models, and to improve both energy efficiency and structural safety with respect to seismic activity. The book is divided into three sections, the first of which focuses on the social role of the school as a civic building that can serve the needs of the community. Innovations in both design and construction processes are then analyzed, paying special attention to the Building Information Modeling (BIM) strategy as a tool for the integration of different disciplines. The final section is devoted to the built heritage and tools, technologies, and approaches for the upgrading of existing buildings so that they meet the new regulations on building performance. The book will be of interest to all who wish to learn about the latest insights into the challenges posed by, and the opportunities afforded by, a comprehensive school building and renovation program.
    Schlagwort(e): Engineering ; Buildings—Design and construction ; Building ; Construction ; Engineering, Architectural ; Energy efficiency ; Building materials ; Materials science ; Schools ; bic Book Industry Communication::J Society & social sciences::JN Education::JNL Schools ; bic Book Industry Communication::T Technology, engineering, agriculture::TG Mechanical engineering & materials::TGM Materials science::TGMT Testing of materials ; bic Book Industry Communication::T Technology, engineering, agriculture::TH Energy technology & engineering ; bic Book Industry Communication::T Technology, engineering, agriculture::TN Civil engineering, surveying & building::TNK Building construction & materials ; thema EDItEUR::J Society and Social Sciences::JN Education::JNL Schools and pre-schools ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGM Materials science::TGMT Testing of materials ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TH Energy technology and engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TN Civil engineering, surveying and building::TNK Building construction and materials
    Sprache: Englisch
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  • 19
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    The Functional Organization of the Auditory System (2021)
    Frontiers Media SA
    Details
    Publikationsdatum: 2024-04-05
    Beschreibung: This eBook comprises s series of original research and review articles dealing with the anatomical, genetic, and physiological organization of the auditory system from humans to monkeys and mice.
    Schlagwort(e): RC321-571 ; Q1-390 ; audition ; monkeys ; gens ; translational ; Humans ; Rodents ; Memory ; Perception ; Physiology ; functional imaging ; Anatomy ; thema EDItEUR::P Mathematics and Science::PS Biology, life sciences::PSA Life sciences: general issues::PSAN Neurosciences
    Sprache: Englisch
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  • 20
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    The Way Ahead (2021)
    University of Ottawa Press / Les Presses de l’Université d’Ottawa
    Details
    Publikationsdatum: 2022-04-28
    Beschreibung: Canada is a prosperous country, but this prosperity is being stressed by demographics, pressures on the public purse, and low productivity growth. To maintain the nation's high quality of life, prosperity must increase while remaining sustainable. Combining Tom Brzustowski's extensive knowledge of government, industry, and academia, 〈i〉The Way Ahead〈/i〉, articulates a strategy for moving the Canadian economy towards higher-value products based on research and development, describing the practical steps government, industry and academia must take to improve things in the short term and prepare strategically for the long term. He recommends increasing productivity growth by embracing an economy based on innovation, prioritizing research and development, marketing Canadian products internationally, and encouraging entrepreneurial activities in all sectors. Ultimately, increasing prosperity will require a new level of understanding, strategic coherence, and mutual support between the private and public sectors in Canada, a challenge that the author feels Canada is prepared to and absolutely must face.
    Schlagwort(e): economy ; canada ; Basic research ; Commodity ; Engineering ; Entrepreneurship ; Gross domestic product ; Research and development ; bic Book Industry Communication::K Economics, finance, business & management::KC Economics
    Sprache: Englisch
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  • 21
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    Brain and Human Body Modeling (2021)
    Springer Nature
    Details
    Publikationsdatum: 2024-04-01
    Beschreibung: This open access book describes modern applications of computational human modeling with specific emphasis in the areas of neurology and neuroelectromagnetics, depression and cancer treatments, radio-frequency studies and wireless communications. Special consideration is also given to the use of human modeling to the computational assessment of relevant regulatory and safety requirements. Readers working on applications that may expose human subjects to electromagnetic radiation will benefit from this book’s coverage of the latest developments in computational modelling and human phantom development to assess a given technology’s safety and efficacy in a timely manner. Describes construction and application of computational human models including anatomically detailed and subject specific models; Explains new practices in computational human modeling for neuroelectromagnetics, electromagnetic safety, and exposure evaluations; Includes a survey of modern applications for which computational human models are critical; Describes cellular-level interactions between the human body and electromagnetic fields.
    Schlagwort(e): Engineering ; Biomedical engineering ; Electronic circuits ; Microwaves ; Optical engineering ; thema EDItEUR::M Medicine and Nursing::MQ Nursing and ancillary services::MQW Biomedical engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJF Electronics engineering::TJFC Electronics: circuits and components ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJF Electronics engineering::TJFN Microwave technology
    Sprache: Englisch
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  • 22
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    Acceso, democracia y comunidades virtuales (2023)
    CLACSO
    Details
    Publikationsdatum: 2024-04-14
    Beschreibung: Description not available.
    Schlagwort(e): Technology ; Engineering ; Political Science ; thema EDItEUR::U Computing and Information Technology::UB Information technology: general topics::UBW Internet: general works ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJF Electronics engineering ; thema EDItEUR::J Society and Social Sciences::JP Politics and government::JPH Political structure and processes::JPHV Political structures: democracy
    Sprache: Spanisch
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  • 23
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    Safety Cultures, Safety Models (2021)
    Springer Nature
    Details
    Publikationsdatum: 2024-04-16
    Beschreibung: The objective of this book is to help at-risk organizations to decipher the “safety cloud”, and to position themselves in terms of operational decisions and improvement strategies in safety, considering the path already travelled, their context, objectives and constraints. What link can be established between safety culture and safety models in order to increase safety within companies carrying out dangerous activities? First, while the term “safety culture” is widely shared among the academic and industrial world, it leads to various interpretations and therefore different positioning when it comes to assess, improve or change it. Many safety theories, concepts, and models coexist today, being more or less appealing and/or directly useful to the industry. How, and based on which criteria, to choose from the available options? These are some of the questions addressed in this book, which benefits from the expertise of its worldwide famous authors in several industrial sectors.
    Schlagwort(e): Engineering ; Quality control ; Reliability ; Industrial safety ; Economic sociology ; Industrial psychology ; Industrial organization ; thema EDItEUR::J Society and Social Sciences::JH Sociology and anthropology::JHB Sociology::JHBL Sociology: work and labour ; thema EDItEUR::J Society and Social Sciences::JM Psychology::JMJ Occupational and industrial psychology ; thema EDItEUR::K Economics, Finance, Business and Management::KC Economics::KCD Economics of industrial organization ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGP Production and industrial engineering::TGPR Reliability engineering
    Sprache: Englisch
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  • 24
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    Integrating Information into the Engineering Design Process (2021)
    Purdue University Press
    Details
    Publikationsdatum: 2022-05-02
    Beschreibung: Engineering design is a fundamental problem-solving model used by the discipline. Effective problem-solving requires the ability to find and incorporate quality information sources. To teach courses in this area effectively, educators need to understand the information needs of engineers and engineering students and their information gathering habits. This book provides essential guidance for engineering faculty and librarians wishing to better integrate information competencies into their curricular offerings. The treatment of the subject matter is pragmatic, accessible, and engaging. Rather than focusing on specific resources or interfaces, the book adopts a process-driven approach that outlasts changing information technologies. After several chapters introducing the conceptual underpinnings of the book, a sequence of contributions go into detail about specific steps in the design process and the information needs for those steps.
    Schlagwort(e): Engineering ; Teaching ; design ; engineering ; education ; technology ; learning ; bic Book Industry Communication::J Society & social sciences::JN Education::JNT Teaching skills & techniques
    Sprache: Englisch
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  • 25
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    Tecnologías digitales (2023)
    CLACSO
    Details
    Publikationsdatum: 2024-04-11
    Beschreibung: Este libro indaga desde múltiples preguntas y perspectivas las transformaciones provocadas por el incremento descomunal del flujo de información generada por el uso masivo e intensivo de las tecnologías digitales. El estudio de las apropiaciones por parte de la sociedad configura un mosaico desigual y combinado de usos y empleos de las tecnologías digitales. ¿Cómo han impactado en los grupos sociales, económicos y generacionales los usos de las tecnologías? ¿Que desafíos entrañan y que problemas nuevos generan las herramientas cotidianas a través de las cuales conocemos y nos comunicamos con nuestro entorno y el mundo?
    Schlagwort(e): Engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJF Electronics engineering
    Sprache: Spanisch
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    Standort Signatur Erwartet Verfügbarkeit
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  • 26
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    Regeneration of the Built Environment from a Circular Economy Perspective (2021)
    Springer Nature
    Details
    Publikationsdatum: 2021-02-10
    Beschreibung: This open access book explores the strategic importance and advantages of adopting multidisciplinary and multiscalar approaches of inquiry and intervention with respect to the built environment, based on principles of sustainability and circular economy strategies. A series of key challenges are considered in depth from a multidisciplinary perspective, spanning engineering, architecture, and regional and urban economics. These challenges include strategies to relaunch socioeconomic development through regenerative processes, the regeneration of urban spaces from the perspective of resilience, the development and deployment of innovative products and processes in the construction sector in order to comply more fully with the principles of sustainability and circularity, and the development of multiscale approaches to enhance the performance of both the existing building stock and new buildings. The book offers a rich selection of conceptual, empirical, methodological, technical, and case study/project-based research. It will be of value for all who have an interest in regeneration of the built environment from a circular economy perspective.
    Schlagwort(e): Engineering ; Buildings—Design and construction ; Building ; Construction ; Engineering, Architectural ; Sociology, Urban ; Economic development—Environmental aspects ; Sustainable development ; Environmental economics ; bic Book Industry Communication::J Society & social sciences::JH Sociology & anthropology::JHB Sociology ; bic Book Industry Communication::K Economics, finance, business & management::KC Economics::KCN Environmental economics ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RN The environment::RNU Sustainability ; bic Book Industry Communication::T Technology, engineering, agriculture::TN Civil engineering, surveying & building::TNK Building construction & materials
    Sprache: Englisch
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  • 27
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    How to Do Things with Sensors (2023)
    University of Minnesota Press
    Details
    Publikationsdatum: 2024-04-04
    Beschreibung: An investigation of how-to guides for sensor technologies Sensors are increasingly common within citizen-sensing and DIY projects, but these devices often require the use of a how-to guide. From online instructional videos for troubleshooting sensor installations to handbooks for using and abusing the Internet of Things, the how-to genres and formats of digital instruction continue to expand and develop. As the how-to proliferates, and instructions unfold through multiple aspects of technoscientific practices, Jennifer Gabrys asks why the how-to has become one of the prevailing genres of the digital. How to Do Things with Sensors explores the ways in which things are made do-able with and through sensors and further considers how worlds are made sense-able and actionable through the instructional mode of citizen-sensing projects. Forerunners: Ideas First Short books of thought-in-process scholarship, where intense analysis, questioning, and speculation take the lead
    Schlagwort(e): Science & Technology Studies ; General Science ; Engineering ; thema EDItEUR::P Mathematics and Science::PD Science: general issues::PDR Impact of science and technology on society ; thema EDItEUR::P Mathematics and Science::PD Science: general issues::PDA Philosophy of science ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering
    Sprache: Englisch
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  • 28
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    IMPROVE - Innovative Modelling Approaches for Production Systems to Raise Validatable Efficiency (2021)
    Springer Nature
    Details
    Publikationsdatum: 2024-04-11
    Beschreibung: This open access work presents selected results from the European research and innovation project IMPROVE which yielded novel data-based solutions to enhance machine reliability and efficiency in the fields of simulation and optimization, condition monitoring, alarm management, and quality prediction.
    Schlagwort(e): Engineering ; Quality control ; Reliability ; Industrial safety ; Robotics ; Automation ; Input-output equipment (Computers) ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGP Production and industrial engineering::TGPR Reliability engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJF Electronics engineering::TJFM Automatic control engineering::TJFM1 Robotics ; thema EDItEUR::U Computing and Information Technology::UT Computer networking and communications
    Sprache: Englisch
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  • 29
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    Spatial memory - a unique window into healthy and pathological ageing (2021)
    Frontiers Media SA
    Details
    Publikationsdatum: 2024-04-05
    Beschreibung: The global population aged over 60 is set to rise dramatically in the coming decades. In many countries, the older population now faces the prospect of spending a quarter of their lives aged over 65, and a significant proportion will have to cope with cognitive decline associated with normal ageing or with dementia disorders. Given that these fundamental demographic changes will pose a significant challenge to health care systems, a detailed understanding of age-related cognitive and neurobiological changes is essential in helping elderly populations maintain cognitive performance. In addition, developing sensitive biomarkers to identify those at risk of developing dementia is crucial for early and effective interventions. To make inferences about the ageing process from the animal model back to the human, rigorous behavioral paradigms must be used to ensure that the same function is being examined across species. Given that similar navigational paradigms can easily be applied to humans and animals, recent years have seen an expansion of studies attempting to bridge the gap between age-related changes in animal and human spatial cognition. These studies begin to suggest that disruptions in spatial computations are among the earliest indicators of impending cognitive decline. In addition, although many animal studies have identified pathological mechanisms with paradigms involving spatial navigation, these mechanisms support many nonspatial cognitive functions as well. As a consequence, a successful characterization of how spatial processing changes in the ageing brain could reveal fundamental effects of cognitive ageing that could inform about general mechanisms underlying decline in perception, mnemonic processing and multisensory integration.
    Schlagwort(e): RC321-571 ; Q1-390 ; Neuroscience ; spatial navigation ; Humans ; Aging ; Animal Models ; Dementia ; thema EDItEUR::P Mathematics and Science::PS Biology, life sciences::PSA Life sciences: general issues::PSAN Neurosciences
    Sprache: Englisch
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  • 30
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    Introduction to Permanent Plug and Abandonment of Wells (2021)
    Springer Nature
    Details
    Publikationsdatum: 2021-02-10
    Beschreibung: This open access book offers a timely guide to challenges and current practices to permanently plug and abandon hydrocarbon wells. With a focus on offshore North Sea, it analyzes the process of plug and abandonment of hydrocarbon wells through the establishment of permanent well barriers. It provides the reader with extensive knowledge on the type of barriers, their functioning and verification. It then discusses plug and abandonment methodologies, analyzing different types of permanent plugging materials. Last, it describes some tests for verifying the integrity and functionality of installed permanent barriers. The book offers a comprehensive reference guide to well plugging and abandonment (P&A) and well integrity testing. The book also presents new technologies that have been proposed to be used in plugging and abandoning of wells, which might be game-changing technologies, but they are still in laboratory or testing level. Given its scope, it addresses students and researchers in both academia and industry. It also provides information for engineers who work in petroleum industry and should be familiarized with P&A of hydrocarbon wells to reduce the time of P&A by considering it during well planning and construction.
    Schlagwort(e): Engineering ; Ocean engineering ; Geotechnical engineering ; Energy policy ; Energy and state ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RB Earth sciences ; bic Book Industry Communication::T Technology, engineering, agriculture::TH Energy technology & engineering ; bic Book Industry Communication::T Technology, engineering, agriculture::TT Other technologies & applied sciences::TTS Marine engineering::TTSH Offshore engineering
    Sprache: Englisch
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  • 31
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    Error-Correction Coding and Decoding (2021)
    Springer Nature
    Details
    Publikationsdatum: 2024-04-09
    Beschreibung: Coding; Communications; Engineering; Networks; Information Theory; Algorithms
    Schlagwort(e): Coding ; Communications ; Engineering ; Networks ; Information Theory ; Algorithms ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues
    Sprache: Englisch
    Format: image/jpeg
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  • 32
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    Compact Models for Integrated Circuit Design (2021)
    Taylor & Francis
    Details
    Publikationsdatum: 2024-04-11
    Beschreibung: This modern treatise on compact models for circuit computer-aided design (CAD) presents industry standard models for bipolar-junction transistors (BJTs), metal-oxide-semiconductor (MOS) field-effect-transistors (FETs), FinFETs, and tunnel field-effect transistors (TFETs), along with statistical MOS models. Featuring exercise problems at the end of each chapter and extensive references at the end of the book, the text supplies fundamental and practical knowledge necessary for efficient integrated circuit (IC) design using nanoscale devices. It ensures even those unfamiliar with semiconductor physics gain a solid grasp of compact modeling concepts.
    Schlagwort(e): Engineering ; Electrical Engineering ; computer-aided design ; CAD ; compact modeling ; MOSFET ; Circuit Simulation ; compact models ; SPICE model ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJF Electronics engineering::TJFC Electronics: circuits and components
    Sprache: Englisch
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  • 33
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    Artificial Intelligence in Medical Imaging: The Beginning of a New Era (2023)
    MDPI - Multidisciplinary Digital Publishing Institute
    Details
    Publikationsdatum: 2024-04-11
    Beschreibung: Artificial intelligence is a term that refers to the ability to provide machines with human intelligence. In medicine it is becoming widely used. It finds application especially in the diagnostic and tumor fields. It is not yet able to replace the human brain, but several studies show how its support can be useful in making diagnoses and providing prognoses. This reprint addresses various satellite topics of this discipline, giving practical examples in various clinical fields. In addition, it highlights the strengths of this tool and proposes methods to improve its weaknesses by addressing issues such as increasing data sets and selecting the right features. It also addresses other innovative aspects that together with artificial intelligence can lead to improvements in surgery.
    Schlagwort(e): Artificial Intelligence ; Automatic ; Diagnostics ; Engineering ; Imaging ; Machine Learning ; Deep Learning ; Features ; Biomedics ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues::TBX History of engineering and technology
    Sprache: Englisch
    Format: application/octet-stream
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  • 34
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    Oil Fictions (2023)
    Pennsylvania State University Press
    Details
    Publikationsdatum: 2024-03-27
    Beschreibung: Oil, like other fossil fuels, permeates every aspect of human existence. Yet it has been largely ignored by cultural critics, especially in the context of the Global South. Seeking to make visible not only the pervasiveness of oil in society and culture but also its power, Oil Fictions stages a critical intervention that aligns with the broader goals of the energy humanities.Exploring literature and film about petroleum as a genre of world literature, Oil Fictions focuses on the ubiquity of oil as well as the cultural response to petroleum in postcolonial states. The chapters engage with African, South American, South Asian, Iranian, and transnational petrofictions and cover topics such as the relationship of colonialism to the fossil fuel economy, issues of gender in the Thermocene epoch, and discussions of migration, precarious labor, and the petro-diaspora. This unique exploration includes testimonies of the oil encounter—through memoirs, journals, and interviews—from a diverse geopolitical grid, ranging from the Permian Basin to the Persian Gulf.By engaging with non-Western literary responses to petroleum in a concentrated, sustained way, this pathbreaking book illuminates the transnational dimensions of the discourse on oil. It will appeal to scholars and students working in literature and science studies, energy humanities, ecocriticism, petrocriticism, environmental humanities, and Anthropocene studies.In addition to the editors, the contributors to this volume include Henry Obi Ajumeze, Rebecca Babcock, Ashley Dawson, Sharae Deckard, Scott DeVries, Kristen Figgins, Amitav Ghosh, Corbin Hiday, Helen Kapstein, Micheal Angelo Rumore, Simon Ryle, Sheena Stief, Imre Szeman, Maya Vinai, and Wendy W. Walters.
    Schlagwort(e): Language & Literature ; Sustainability ; Engineering ; Environmental Science ; thema EDItEUR::D Biography, Literature and Literary studies::DS Literature: history and criticism::DSB Literary studies: general::DSBH Literary studies: c 1900 to c 2000 ; thema EDItEUR::D Biography, Literature and Literary studies::DS Literature: history and criticism::DSB Literary studies: general ; thema EDItEUR::D Biography, Literature and Literary studies::D Biography, Literature and Literary studies::DS Literature: history and criticism ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TH Energy technology and engineering::THF Fossil fuel technologies::THFP Petroleum technology ; thema EDItEUR::R Earth Sciences, Geography, Environment, Planning::RN The environment::RNF Environmental management
    Sprache: Englisch
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  • 35
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    Biostratigraphic and Geological Significance of Planktonic Foraminifera (2023)
    UCL Press
    Details
    Publikationsdatum: 2024-04-09
    Beschreibung: The role of fossil planktonic foraminifera as markers for biostratigraphical zonation and correlation underpins most drilling of marine sedimentary sequences and is key to hydrocarbon exploration. The first - and only - book to synthesize the whole biostratigraphic and geological usefulness of planktonic foraminifera, Biostratigraphic and Geological Significance of Planktonic Foraminifera unifies existing biostratigraphic schemes and provides an improved correlation reflecting regional biogeographies. Renowned micropaleontologist Marcelle K. Boudagher-Fadel presents a comprehensive analysis of existing data on fossil planktonic foraminifera genera and their phylogenetic evolution in time and space. This important text, now in its Second Edition, is in considerable demand and is now being republished by UCL Press.
    Schlagwort(e): Geology ; Paleontology ; Geography ; Agriculture ; Engineering ; thema EDItEUR::R Earth Sciences, Geography, Environment, Planning::RB Earth sciences::RBG Geology, geomorphology and the lithosphere ; thema EDItEUR::W Lifestyle, Hobbies and Leisure::WN Nature and the natural world: general interest::WNR Rocks, minerals and fossils: general interest ; thema EDItEUR::R Earth Sciences, Geography, Environment, Planning::RG Geography ; thema EDItEUR::R Earth Sciences, Geography, Environment, Planning::RB Earth sciences::RBX Palaeontology ; thema EDItEUR::R Earth Sciences, Geography, Environment, Planning::RB Earth sciences::RBG Geology, geomorphology and the lithosphere::RBGH Stratigraphy ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TV Agriculture and farming ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TH Energy technology and engineering::THF Fossil fuel technologies::THFP Petroleum technology
    Sprache: Englisch
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  • 36
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    Special Topics in Information Technology (2021)
    Springer Nature
    Details
    Publikationsdatum: 2024-04-11
    Beschreibung: This open access book presents nine outstanding doctoral dissertations in Information Technology from the Department of Electronics, Information and Bioengineering, Politecnico di Milano, Italy. Information Technology has always been highly interdisciplinary, as many aspects have to be considered in IT systems. The doctoral studies program in IT at Politecnico di Milano emphasizes this interdisciplinary nature, which is becoming more and more important in recent technological advances, in collaborative projects, and in the education of young researchers. Accordingly, the focus of advanced research is on pursuing a rigorous approach to specific research topics starting from a broad background in various areas of Information Technology, especially Computer Science and Engineering, Electronics, Systems and Controls, and Telecommunications. Each year, more than 50 PhDs graduate from the program. This book gathers the outcomes of the nine best theses defended in 2018-19 and selected for the IT PhD Award. Each of the nine authors provides a chapter summarizing his/her findings, including an introduction, description of methods, main achievements and future work on the topic. Hence, the book provides a cutting-edge overview of the latest research trends in Information Technology at Politecnico di Milano, presented in an easy-to-read format that will also appeal to non-specialists.
    Schlagwort(e): Engineering ; Electrical engineering ; Control engineering ; Data structures (Computer science) ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJF Electronics engineering::TJFM Automatic control engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJK Communications engineering / telecommunications ; thema EDItEUR::U Computing and Information Technology::UM Computer programming / software engineering::UMB Algorithms and data structures ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJF Electronics engineering::TJFM Automatic control engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJK Communications engineering / telecommunications ; thema EDItEUR::U Computing and Information Technology::UM Computer programming / software engineering::UMB Algorithms and data structures
    Sprache: Englisch
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    Dynamic Spectrum Management (2021)
    Springer Nature
    Details
    Publikationsdatum: 2024-04-11
    Beschreibung: This open access book, authored by a world-leading researcher in this field, describes fundamentals of dynamic spectrum management, provides a systematic overview on the enabling technologies covering cognitive radio, blockchain, and artificial intelligence, and offers valuable guidance for designing advanced wireless communications systems. This book is intended for a broad range of readers, including students and professionals in this field, as well as radio spectrum policy makers.
    Schlagwort(e): Engineering ; Electrical engineering ; Wireless communication systems ; Mobile communication systems ; Computer organization ; Computers ; Artificial intelligence ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJK Communications engineering / telecommunications ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJK Communications engineering / telecommunications::TJKW WAP (wireless) technology ; thema EDItEUR::U Computing and Information Technology::UT Computer networking and communications ; thema EDItEUR::U Computing and Information Technology::UY Computer science::UYQ Artificial intelligence ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJK Communications engineering / telecommunications ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJK Communications engineering / telecommunications::TJKW WAP (wireless) technology ; thema EDItEUR::U Computing and Information Technology::UT Computer networking and communications ; thema EDItEUR::U Computing and Information Technology::UY Computer science::UYQ Artificial intelligence
    Sprache: Englisch
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  • 38
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    Machine Learning for Cyber Physical Systems (2021)
    Springer Nature
    Details
    Publikationsdatum: 2024-04-11
    Beschreibung: This Open Access proceedings presents new approaches to Machine Learning for Cyber Physical Systems, experiences and visions. It contains some selected papers from the international Conference ML4CPS – Machine Learning for Cyber Physical Systems, which was held in Karlsruhe, October 23-24, 2018. Cyber Physical Systems are characterized by their ability to adapt and to learn: They analyze their environment and, based on observations, they learn patterns, correlations and predictive models. Typical applications are condition monitoring, predictive maintenance, image processing and diagnosis. Machine Learning is the key technology for these developments.
    Schlagwort(e): Engineering ; Computational intelligence ; Computer organization ; Electrical engineering ; Data mining ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJK Communications engineering / telecommunications ; thema EDItEUR::U Computing and Information Technology::UN Databases::UNF Data mining ; thema EDItEUR::U Computing and Information Technology::UT Computer networking and communications ; thema EDItEUR::U Computing and Information Technology::UY Computer science::UYQ Artificial intelligence ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJK Communications engineering / telecommunications ; thema EDItEUR::U Computing and Information Technology::UN Databases::UNF Data mining ; thema EDItEUR::U Computing and Information Technology::UT Computer networking and communications ; thema EDItEUR::U Computing and Information Technology::UY Computer science::UYQ Artificial intelligence
    Sprache: Englisch
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    Models, Methods and Tools for Product Service Design (2021)
    Springer Nature
    Details
    Publikationsdatum: 2021-02-10
    Beschreibung: This open access book summarizes research being pursued within the Manutelligence project, the goal of which is to help enterprises develop smart, social and flexible products with high value added services. Manutelligence has improved Product and Service Design by developing suitable models and methods, and connecting them through a modular, collaborative and secure ICT Platform. The use of real data collected in real time by Internet of Things (IoT) technologies underpins the design of product-service systems and makes it possible to monitor them throughout their life cycle. Available data allows costs and sustainability issues to be more accurately measured and simulated in the form of Life Cycle Cost (LCC) and Life Cycle Assessment (LCA). Analysing data from IoT systems and sharing LCC and LCA information via the ICT Platform can help to accelerate the design of product-service systems, reduce costs and better understand customer needs. Industrial partners involved in Manutelligence provide a clear overview of the project’s outcomes, and demonstrate how its technological solutions can be used to improve the design of product-service systems and the management of product-service life cycles.
    Schlagwort(e): Engineering ; Manufactures ; Computational intelligence ; Artificial intelligence ; Service industries ; bic Book Industry Communication::K Economics, finance, business & management::KN Industry & industrial studies::KNS Service industries ; bic Book Industry Communication::T Technology, engineering, agriculture::TG Mechanical engineering & materials::TGP Production engineering ; bic Book Industry Communication::U Computing & information technology::UY Computer science::UYQ Artificial intelligence
    Sprache: Englisch
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    Gender in Science and Technology (2021)
    transcript Verlag
    Details
    Publikationsdatum: 2022-05-02
    Beschreibung: What role does gender play in scientific research and the development of technologies? This book provides methodological expertise, research experiences and empirical findings in the dynamic field of Science and Technology Studies. The authors, coming from computer science, social sciences, or cultural studies of science, discuss how to ask questions about gender and give examples for the application in interdisciplinary research, development and teaching. Topics range from the design of information and communication technologies, epistemologies of biology and chemistry to teaching mathematics and professional processes in engineering. Contributions by Anne Balsamo, Wendy Faulkner, Rebecca Jordan-Young, Barbara Orland, Els Rommes, and others.
    Schlagwort(e): Sociology ; Gender ; Innovation Research ; Science ; Technology ; Engineering ; Gender Studies ; Sociology of Science ; Sociology of Technology ; Cultural Studies ; Sociology ; Gender ; Innovation Research ; Science ; Technology ; Engineering ; Gender Studies ; Sociology of Science ; Sociology of Technology ; Cultural Studies ; Epistemology ; Feminism ; London ; bic Book Industry Communication::J Society & social sciences::JF Society & culture: general::JFS Social groups::JFSJ Gender studies, gender groups
    Sprache: Englisch
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    Program Earth (2023)
    University of Minnesota Press
    Details
    Publikationsdatum: 2024-04-04
    Beschreibung: Sensors are everywhere. Small, flexible, economical, and computationally powerful, they operate ubiquitously in environments. They compile massive amounts of data, including information about air, water, and climate. Never before has such a volume of environmental data been so broadly collected or so widely available. Grappling with the consequences of wiring our world, Program Earth examines how sensor technologies are programming our environments. As Jennifer Gabrys points out, sensors do not merely record information about an environment. Rather, they generate new environments and environmental relations. At the same time, they give a voice to the entities they monitor: to animals, plants, people, and inanimate objects. This book looks at the ways in which sensors converge with environments to map ecological processes, to track the migration of animals, to check pollutants, to facilitate citizen participation, and to program infrastructure. Through discussing particular instances where sensors are deployed for environmental study and citizen engagement across three areas of environmental sensing, from wild sensing to pollution sensing and urban sensing, Program Earth asks how sensor technologies specifically contribute to new environmental conditions. What are the implications for wiring up environments? How do sensor applications not only program environments, but also program the sorts of citizens and collectives we might become? Program Earth suggests that the sensor-based monitoring of Earth offers the prospect of making new environments not simply as an extension of the human but rather as new "technogeographies" that connect technology, nature, and people.
    Schlagwort(e): General Science ; Science & Technology Studies ; Engineering ; thema EDItEUR::P Mathematics and Science::PD Science: general issues::PDA Philosophy of science ; thema EDItEUR::P Mathematics and Science::PD Science: general issues::PDR Impact of science and technology on society ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering
    Sprache: Englisch
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    Strain-Engineered MOSFETs (2021)
    CRC Press
    Details
    Publikationsdatum: 2024-04-11
    Beschreibung: This book brings together new developments in the area of strain-engineered MOSFETs using high-mibility substrates such as SIGe, strained-Si, germanium-on-insulator and III-V semiconductors into a single text which will cover the materials aspects, principles, and design of advanced devices, their fabrication and applications. The book presents a full TCAD methodology for strain-engineering in Si CMOS technology involving data flow from process simulation to systematic process variability simulation and generation of SPICE process compact models for manufacturing for yield optimization.
    Schlagwort(e): Engineering ; Electrical Engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJF Electronics engineering
    Sprache: Englisch
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  • 43
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    Stoßprobleme in Physik, Technik und Medizin (2021)
    Springer Nature
    Details
    Publikationsdatum: 2024-04-04
    Beschreibung: Dieses Open Access Buch widmet sich dem Problem der Mechanik des Zusammenstoßes zweier makroskopischer Körper. Falls die Dynamik der Körper als Ganzes dies erlaubt, ohne in unüberschaubare Komplexität zu verfallen (in der Regel ist das nur für das reine Normalstoßproblem der Fall), werden allgemeine axialsymmetrische Stoßpartner betrachtet. Für das allgemeine räumliche Stoßproblem wird sich auf den Kontakt von Kugeln beschränkt. Zunächst werden im Buch sehr ausführlich die kontaktmechanischen Grundlagen (Elastizität, Plastizität, Viskoelastizität, Adhäsion, Gradientenmedien) dargestellt und anschließend auf das Stoßproblem übertragen. Mit der Methode der Dimensionsreduktion, der ein eigenes Kapitel gewidmet ist, steht außerdem seit wenigen Jahren ein Werkzeug zu Verfügung, das die sehr effiziente analytische und numerische Behandlung von dynamischen Kontaktproblemen (wie z.B. Stößen) ermöglicht. Den Abschluss des Buch bilden Anwendungsfälle aus verschiedenen Gebieten.
    Schlagwort(e): Engineering ; Mechanics ; Mechanics, Applied ; Mechanics ; Applied mathematics ; Engineering mathematics ; bic Book Industry Communication::P Mathematics & science::PH Physics::PHD Classical mechanics ; bic Book Industry Communication::T Technology, engineering, agriculture::TB Technology: general issues::TBJ Maths for engineers ; bic Book Industry Communication::T Technology, engineering, agriculture::TG Mechanical engineering & materials::TGM Materials science::TGMD Mechanics of solids ; thema EDItEUR::P Mathematics and Science::PH Physics::PHD Classical mechanics ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues::TBJ Maths for engineers ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGM Materials science::TGMD Engineering: Mechanics of solids
    Sprache: Deutsch
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  • 44
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    The 3rd International Conference on Advances in Mechanical Engineering (2024)
    MDPI - Multidisciplinary Digital Publishing Institute
    Details
    Publikationsdatum: 2024-04-11
    Beschreibung: The 3rd International Conference on Advances in Mechanical Engineering 2023 (ICAME-23) was organized on 24th August 2023 by the Department of Mechanical Engineering, Capital University of Science and Technology (CUST). All the articles are single-blindfold reviewed. The acceptance rate of the conference was 65%. ICAME is held annually and welcame high-quality theoretical and empirical original research papers, case studies, and review papers from researchers, academicians, professionals, practitioners, and students worldwide. ICAME-23 accepted research papers in the discipline of: Experimental and Computational Fluid Dynamics; Thermodynamics and heat transfer analysis; Machine and Mechanisms; Design and Solid Mechanics; Manufacturing, Production and Industrial Engineering; Engineering and Technology Management; Renewable Energy and Environmental Engineering; Bioengineering; Materials and Failure Analysis; Other Related Fields. The ICAME-23 conference provided a platform for the national and international speakers/participants to present their state-of-the-art research work to diverse audiences from academia and industry. The conference proceedings are published in the Engineering Proceeding of MDPI, Switzerland. All the articles are individually indexed and are citable via Digital Object Identification (DOI).
    Schlagwort(e): Engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues::TBX History of engineering and technology ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials
    Sprache: Englisch
    Format: application/octet-stream
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    Factories of the Future (2021)
    Springer Nature
    Details
    Publikationsdatum: 2024-04-11
    Beschreibung: Engineering; Industrial engineering; Production engineering
    Schlagwort(e): Engineering ; Industrial engineering ; Production engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGP Production and industrial engineering
    Sprache: Englisch
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  • 46
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    Cold Micro Metal Forming (2021)
    Springer Nature
    Details
    Publikationsdatum: 2024-04-11
    Beschreibung: This open access book contains the research report of the Collaborative Research Center “Micro Cold Forming” (SFB 747) of the University of Bremen, Germany. The topical research focus lies on new methods and processes for a mastered mass production of micro parts which are smaller than 1mm (by forming in batch size higher than one million). The target audience primarily comprises research experts and practitioners in production engineering, but the book may also be of interest to graduate students alike.
    Schlagwort(e): Engineering ; Manufactures ; Quality control ; Reliability ; Industrial safety ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGP Production and industrial engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGP Production and industrial engineering::TGPR Reliability engineering
    Sprache: Englisch
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    El capital de la esperanza (2023)
    CLACSO
    Details
    Publikationsdatum: 2024-03-30
    Beschreibung: Gustavo Lins Riberio conjuga y tensiona la teoría con el trabajo de campo para desentrañar los significados que atribuyen los trabajadores a la construcción de Brasilia. Ello le permitirá reconstruir una memoria donde caben las penurias, los enojos, las broncas, las injusticias laborales, las solidaridades, las amistades, la familia, las lealtades, los sabores de las comidas, la música, la organización, el sindicato y los conflictos, en un todo desordenado pero legible a luz de la teoría. En definitiva, la experiencia de clase se puede leer en El capital de la esperanza de modo transversal, así como también las contradicciones del capitalismo, las políticas urbanistas, las condiciones de trabajo y demás campos problemáticos que han abordado las ciencias sociales. Las y los invitamos a leer —por primera vez o una vez más— esta obra magistral que nos permite comprender y complejizar la dinámica de la expansión capitalista.
    Schlagwort(e): Labor & Employment Relations ; Engineering ; History ; Latin American Studies ; thema EDItEUR::K Economics, Finance, Business and Management::KC Economics::KCF Labour / income economics ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TN Civil engineering, surveying and building::TNK Building construction and materials ; thema EDItEUR::N History and Archaeology::NH History::NHK History of the Americas
    Sprache: Spanisch
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  • 48
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    Model Tests and Numerical Simulations of Liquefaction and Lateral Spreading (2021)
    Springer Nature
    Details
    Publikationsdatum: 2021-02-10
    Beschreibung: This open access book presents work collected through the Liquefaction Experiments and Analysis Projects (LEAP) in 2017. It addresses the repeatability, variability, and sensitivity of lateral spreading observed in twenty-four centrifuge model tests on mildly sloping liquefiable sand. The centrifuge tests were conducted at nine different centrifuge facilities around the world. For the first time, a sufficient number of experiments were conducted to enable assessment of variability of centrifuge test results. The experimental data provided a unique basis for assessing the capabilities of twelve different simulation platforms for numerical simulation of soil liquefaction. The results of the experiments and the numerical simulations are presented and discussed in papers submitted by the project participants. The work presented in this book was followed by LEAP-Asia that included assessment of a generalized scaling law and culminated in a workshop in Osaka, Japan in March 2019. LEAP-2020, ongoing at the time of printing, is addressing the validation of soil-structure interaction analyses of retaining walls involving a liquefiable soil. A workshop is planned at RPI, USA in 2020.
    Schlagwort(e): Engineering ; Engineering geology ; Engineering—Geology ; Foundations ; Hydraulics ; Quality control ; Reliability ; Industrial safety ; Geotechnical engineering ; Soil science ; Soil conservation ; Natural disasters ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RB Earth sciences ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RB Earth sciences::RBG Geology & the lithosphere::RBGB Soil science, sedimentology ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RB Earth sciences::RBP Meteorology & climatology ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RN The environment::RNR Natural disasters ; bic Book Industry Communication::T Technology, engineering, agriculture::TG Mechanical engineering & materials::TGP Production engineering::TGPR Reliability engineering
    Sprache: Englisch
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    Hidden Depths (2022)
    White Rose University Press | White Rose University Press
    Details
    Publikationsdatum: 2022-12-06
    Beschreibung: In Hidden Depths, Professor Penny Spikins explores how our emotional connections have shaped human ancestry. Focusing on three key transitions in human origins, Professor Spikins explains how the emotional capacities of our early ancestors evolved in response to ecological changes, much like similar changes in other social mammals. For each transition, dedicated chapters examine evolutionary pressures, responses in changes in human emotional capacities and the archaeological evidence for human social behaviours. Starting from our earliest origins, in Part One, Professor Spikins explores how after two million years ago, movement of human ancestors into a new ecological niche drove new types of collaboration, including care for vulnerable members of the group. Emotional adaptations lead to cognitive changes, as new connections based on compassion, generosity, trust and inclusion also changed our relationship to material things. Part Two explores a later key transition in human emotional capacities occurring after 300,000 years ago. At this time changes in social tolerance allowed ancestors of our own species to further reach out beyond their local group and care about distant allies, making human communities resilient to environmental changes. An increasingly close relationship to animals, and even to cherished possessions, appeared at this time, and can be explained through new human vulnerabilities and ways of seeking comfort and belonging. Lastly, Part Three focuses on the contrasts in emotional dispositions arising between ourselves and our close cousins, the Neanderthals. Neanderthals are revealed as equally caring yet emotionally different humans, who might, if things had been different, have been in our place today. This new narrative breaks away from traditional views of human evolution as exceptional or as a linear progression towards a more perfect form. Instead, our evolutionary history is situated within similar processes occurring in other mammals, and explained as one in which emotions, rather than ‘intellect’, were key to our evolutionary journey. Moreover, changes in emotional capacities and dispositions are seen as part of differing pathways each bringing strengths, weaknesses and compromises. These hidden depths provide an explanation for many of the emotional sensitivities and vulnerabilities which continue to influence our world today.
    Schlagwort(e): Human demography ; Group size ; Lithic transfers ; Raw material movements ; Bonobos ; Dog burial ; Comfort ; Symbolic objects ; Symbolism ; Mobiliary art ; Attachment fluidity ; Hypersociability ; Human-animal relationships ; Dog domestication ; Attachment object ; Approachability ; Approach behaviour ; Avoidance behaviour ; Androgens ; Physiological responses ; Cognitive Archaeology ; Autism Spectrum Condition ; Handaxe ; Biface ; Neurodiversity ; Palaeolithic stone tools ; Evolution of neurodiversity ; Rock art ; Ice age art ; Material Culture ; Cultural transmission ; Emotional commitment ; Biopsychosocial approach ; Social tolerance ; Attachment ; Genus Homo ; Acheulian ; Cultural evolution ; Skeletal abnormality ; Injury ; Illness ; Interdependence ; Emotional sensitivity ; Moral emotions ; Evolution of Altruism ; Hominins ; Upper Palaeolithic ; Lower Palaeolithic ; Ecological niche ; Selective pressure ; Behavioural ecology ; Wolves ; Affective empathy ; Cognitive empathy ; Theory of mind ; Human Cognition ; Vulnerability ; Evolutionary Psychology ; Developmental psychology ; Helping behaviours ; Social cognition ; Social mammals ; Human Emotion ; Human social collaboration ; Generosity ; Emotional brain ; Social emotions ; Comparative behaviour ; Evolution ; Social carnivores ; Primate behavioural ecology ; Primate social systems ; Human Evolution ; Human ancestors ; Collaboration ; Evolutionary Biology ; Emotional vulnerability ; Social connection ; Decolonisation ; Social networks ; Middle Palaeolithic ; Community resilience ; Convergent evolution ; Chimpanzee ; Origin of modern humans ; Social safeness ; Wolf domestication ; Cherished possessions ; Compensatory attachment ; Loneliness ; Palaeolithic art ; Stress reactivity ; Bonding hormones ; Humans ; Hunter-gatherers ; Intergroup collaboration ; Tolerance ; Emotional connection ; Autism ; Trust ; Early Prehistory ; Palaeopathology ; Origins of healthcare ; Human self-domestication ; Palaeolithic Archaeology ; Social brain ; Care-giving ; Empathy ; Neanderthals ; Compassion ; Social Connection ; Evolution of Emotions ; Human Origins ; Adaptation ; Prehistory ; bic Book Industry Communication::J Society & social sciences::JH Sociology & anthropology::JHM Anthropology ; bic Book Industry Communication::H Humanities::HD Archaeology ; bic Book Industry Communication::P Mathematics & science::PS Biology, life sciences ; bic Book Industry Communication::P Mathematics & science::PS Biology, life sciences::PSA Life sciences: general issues::PSAF Ecological science, the Biosphere ; bic Book Industry Communication::P Mathematics & science::PS Biology, life sciences::PSA Life sciences: general issues::PSAJ Evolution ; bic Book Industry Communication::J Society & social sciences::JP Politics & government::JPW Political activism::JPWQ Revolutionary groups & movements ; bic Book Industry Communication::J Society & social sciences::JM Psychology
    Sprache: Englisch
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    Neuropharmacological, Neurobiological and Behavioral Mechanisms of Learning and Memory (2021)
    Frontiers Media SA
    Details
    Publikationsdatum: 2024-04-04
    Beschreibung: This eBook is a collection of articles from a Frontiers Research Topic. Frontiers Research Topics are very popular trademarks of the Frontiers Journals Series: they are collections of at least ten articles, all centered on a particular subject. With their unique mix of varied contributions from Original Research to Review Articles, Frontiers Research Topics unify the most influential researchers, the latest key findings and historical advances in a hot research area! Find out more on how to host your own Frontiers Research Topic or contribute to one as an author by contacting the Frontiers Editorial Office: frontiersin.org/about/contact
    Schlagwort(e): drugs ; Behavior ; Memory tasks ; pre-clinical ; clinical ; Humans ; Animals ; thema EDItEUR::P Mathematics and Science::PD Science: general issues ; thema EDItEUR::M Medicine and Nursing::MK Medical specialties, branches of medicine::MKG Pharmacology
    Sprache: Englisch
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    Open Design Systems (2023)
    TU Delft OPEN Publishing
    Details
    Publikationsdatum: 2024-03-29
    Beschreibung: Current systems design and decision management methodologies can be single-sided, ignoring or failing to capture the dynamic interplay between multi-stakeholder preferences (‘what they want’) and system performances (‘what they can’). In addition, these methodologies often contain fundamental modelling errors and do not provide single best-fit solutions. This leaves designers or decision-makers without unique answers to their problems. Above all, mainstream higher education primarily applies instructivist and research-based learning methods, and therefore does not adequately prepare students for designing solutions to future complex problems. This book introduces both a state-of-the-art participatory design methodology (Odesys), and a design-based learning concept (ODL), which together overcome the aforementioned issues. Odesys is a pure act of open design integration to confront conflicting socio-technical interests and is the key to unlocking these complexities to deliver socially responsible systems. Odesys’ design engine, the Preferendus, enables stakeholders to cooperatively identify their best-fit design synthesis. It employs a novel optimisation method that maximises the aggregated preferences, integrating sound mathematical and extended U-modelling via open technical-, social-, and purpose cycles. The art of ODL is a constructivist design-based and well-proven learning concept fostering students’ design capabilities to become open and persistent problem solvers. It is a reflective, creative, and engaged learning approach that opens human development and unlocks new knowledge and solutions. The author also introduces new management features such as the corporate social identifier (CSI), the ‘socio-eco’ threefold organization model and U-model based open loop management. Finally, the author places Odesys & ODL within the integrative context of empiricism, rationalism, spiritualism, and constructivism to unite the open design impulse. This book will be of interest to both academics and practitioners working in the field of complex systems design and managerial decision-making, and functions as a textbook on systems design and management for master students from diverse backgrounds.
    Schlagwort(e): Management ; Technology ; Engineering ; bic Book Industry Communication::J Society & social sciences::JN Education::JNV Educational equipment & technology, computer-aided learning (CAL) ; thema EDItEUR::J Society and Social Sciences::JN Education::JNV Educational equipment and technology, computer-aided learning (CAL)
    Sprache: Englisch
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    Women's Under-Representation in the Engineering and Computing Professions: Fresh Perspectives on a Complex Problem (2021)
    Frontiers Media SA
    Details
    Publikationsdatum: 2024-03-29
    Beschreibung: Understanding the many complexities that define gender inequality has been described by researchers as a grand challenge. Novel insights, innovation, a broader community to conduct research and to ascertain effective interventions are essential in the challenge to create organizations that are gender equal. As such, this Research Topic in Frontiers in Psychology addresses the under-representation of women in engineering and computing as a complex, but solvable problem. This Research Topic seeks to inform the global community about advances in understanding the under-representation of women in engineering and computing with a focus on what enables change. Further, this Topic will promote fresh perspectives, innovative methodologies, and mixed method approaches important to accelerating the pace of change.
    Schlagwort(e): BF1-990 ; Q1-390 ; Women ; Engineering ; Tech ; Gender Equity ; Under-Represention of Women ; Computing ; STEM ; bic Book Industry Communication::J Society & social sciences::JM Psychology ; thema EDItEUR::J Society and Social Sciences::JM Psychology
    Sprache: Englisch
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    Transforming Institutions (2021)
    Purdue University Press
    Details
    Publikationsdatum: 2024-03-29
    Beschreibung: Higher education is coming under increasing scrutiny, both publically and within academia, with respect to its ability to appropriately prepare students for the careers that will make them competitive in the 21st-century workplace. At the same time, there is a growing awareness that many global issues will require creative and critical thinking deeply rooted in the technical STEM (science, technology, engineering, and mathematics) disciplines. Transforming Institutions brings together chapters from the scholars and leaders who were part of the 2011 and 2014 conferences. It provides an overview of the context and challenges in STEM higher education, contributed chapters describing programs and research in this area, and a reflection and summary of the lessons from the many authors’ viewpoints, leading to suggested next steps in the path toward transformation.
    Schlagwort(e): Engineering ; Undergraduate ; Education ; Science ; Technology ; bic Book Industry Communication::J Society & social sciences::JN Education::JNF Educational strategies & policy ; thema EDItEUR::J Society and Social Sciences::JN Education::JNF Educational strategies and policy
    Sprache: Englisch
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    Gender and STEM: Understanding Segregation in Science, Technology, Engineering and Mathematics (2021)
    MDPI - Multidisciplinary Digital Publishing Institute
    Details
    Publikationsdatum: 2023-12-20
    Beschreibung: This volume features thirteen original chapters on the causes and consequences of gender segregation in scientific, technical, engineering, and mathematics (“STEM”) occupations and fields of study. Although women have made great strides in equalizing access to labor markets and higher education, many STEM fields—particularly in the physical sciences and engineering—remain strongholds of gender segregation in the United States and other reputably gender-progressive societies. Policymakers, business leaders and activists have launched countless initiatives to diversify access to lucrative, high status occupations and ameliorate labor shortages that diminish innovation and competitiveness. Contributors to this volume apply diverse theoretical lenses and methodological approaches to understand the individual, interactional, organizational, and cultural dynamics that drive this segregation in the United States. Results show that the gender composition of scientific and technical fields varies a great deal over time and across organizational contexts and socio-demographic groups defined by race, ethnicity, class, and sexuality. But despite this variability, STEM work and STEM workers are widely presumed to be naturally and inevitably masculine. Research presented here reveals how these stereotypes combine with cultural beliefs about natural and fundamental differences between men and women to produce gendered aspirations and reinforce inequalities in the US scientific and technical workforce.
    Schlagwort(e): HM401-1281 ; NX1-820 ; H1-99 ; Women ; Engineering ; Segregation ; Race/ethnicity ; Men ; Sexuality ; Science ; Mathematics ; Gender ; STEM ; Inequality ; bic Book Industry Communication::J Society & social sciences::JF Society & culture: general::JFF Social issues & processes::JFFP Social interaction
    Sprache: Englisch
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  • 55
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    Animating Unpredictable Effects (2021)
    Springer Nature | Palgrave Macmillan
    Details
    Publikationsdatum: 2024-03-24
    Beschreibung: Uncanny computer-generated animations of splashing waves, billowing smoke clouds, and characters’ flowing hair have become a ubiquitous presence on screens of all types since the 1980s. This Open Access book charts the history of these digital moving images and the software tools that make them. Unpredictable Visual Effects uncovers an institutional and industrial history that saw media industries conducting more private R&D as Cold War federal funding began to wane in the late 1980s. In this context studios and media software companies took concepts used for studying and managing unpredictable systems like markets, weather, and fluids and turned them into tools for animation. Unpredictable Visual Effects theorizes how these animations are part of a paradigm of control evident across society, while at the same time exploring what they can teach us about the relationship between making and knowing.
    Schlagwort(e): Animation ; Film/TV Industry ; Film Theory ; Film and Television Industry ; Visual Effects ; Live-Action Cinema ; Economics ; Mechanical Control ; Socio-Political ; Engineering ; Open Access ; Animated films ; Performing arts ; Film history, theory & criticism ; thema EDItEUR::A The Arts::AT Performing arts::ATF Films, cinema::ATFV Animated films and animation ; thema EDItEUR::A The Arts::AT Performing arts::ATF Films, cinema ; thema EDItEUR::A The Arts::AT Performing arts::ATJ Television ; thema EDItEUR::A The Arts::AT Performing arts::ATF Films, cinema::ATFA Film history, theory or criticism
    Sprache: Englisch
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    Research Journeys to Net Zero (2024)
    Taylor & Francis | Routledge
    Details
    Publikationsdatum: 2024-04-07
    Beschreibung: This book provides useful insight into how academics from diverse disciplinary backgrounds, such as science, engineering, technology, social science, policy, design, architecture, built environment, business, and management, have been conducting research into how to realise net zero emissions to address climate change. This book explores the ways in which countries around the world have pledged to achieve net zero emissions through decarbonisation processes. It presents the highest calibre research and impact activities carried out in the UK, Europe, North America, Australia, Asia, and Africa. Such activities include conceptualisation, opportunity identification, specific case studies, demonstration of proof of concepts, provision of evidence, education of the general public, and knowledge transfer to companies. Further to this, the chapters also bring to light personal career journeys to net zero by current and future international research leaders. From this book, readers will gain a full understanding of net zero research via multiple disciplinary pathways, be inspired by personal accounts, and will learn key methodologies, including quantitative and qualitative approaches. The diversity of authors and topics make the book widely applicable to a range of fields, and it will be of great interest to researchers, students, practitioners, and decision makers working towards the goals of net zero and decarbonisation.
    Schlagwort(e): Net Zero ; Net Zero emissions ; Decarbonisation ; Climate change ; Interdisciplinary education ; Carbon neutral ; 2050 ; Sustainability ; Sustainable consumption ; Sustainability transitions ; Sustainable fashion ; Engineering ; thema EDItEUR::A The Arts::AB The arts: general topics ; thema EDItEUR::A The Arts::AK Design, Industrial and commercial arts, illustration::AKP Product design ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TH Energy technology and engineering::THV Alternative and renewable energy sources and technology ; thema EDItEUR::R Earth Sciences, Geography, Environment, Planning::RN The environment::RNP Pollution and threats to the environment::RNPG Climate change ; thema EDItEUR::R Earth Sciences, Geography, Environment, Planning::RP Regional and area planning::RPC Urban and municipal planning and policy ; thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GT Interdisciplinary studies::GTP Development studies ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TQ Environmental science, engineering and technology ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues::TBC Engineering: general ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues::TBD Technical design::TBDG Ergonomics ; thema EDItEUR::P Mathematics and Science::PH Physics::PHD Classical mechanics::PHDY Energy ; thema EDItEUR::J Society and Social Sciences::JB Society and culture: general::JBS Social groups, communities and identities::JBSD Urban communities ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TD Industrial chemistry and manufacturing technologies::TDP Other manufacturing technologies
    Sprache: Englisch
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    Enhancing Future Skills and Entrepreneurship (2021)
    Springer Nature | Springer
    Details
    Publikationsdatum: 2024-04-11
    Beschreibung: This open access book presents the proceedings of the 3rd Indo-German Conference on Sustainability in Engineering held at Birla Institute of Technology and Science, Pilani, India, on September 16–17, 2019. Intended to foster the synergies between research and education, the conference is one of the joint activities of the BITS Pilani and TU Braunschweig conducted under the auspices of Indo-German Center for Sustainable Manufacturing, established in 2009. The book is divided into three sections: engineering, education and entrepreneurship, covering a range of topics, such as renewable energy forecasting, design & simulation, Industry 4.0, and soft & intelligent sensors for energy efficiency. It also includes case studies on lean and green manufacturing, and life cycle analysis of ceramic products, as well as papers on teaching/learning methods based on the use of learning factories to improve students’problem-solving and personal skills. Moreover, the book discusses high-tech ideas to help the large number of unemployed engineering graduates looking for jobs become tech entrepreneurs. Given its broad scope, it will appeal to academics and industry professionals alike.
    Schlagwort(e): Industrial and Production Engineering ; Renewable and Green Energy ; Engineering/Technology Education ; Study and Learning Skills ; Energy Efficiency ; Energy Policy, Economics and Management ; Engineering and Technology Education ; Engineering ; Entrepreneurship ; Education ; Sustainability ; Learning factories ; International collaboration ; Open Access ; Production engineering ; Alternative & renewable energy sources & technology ; Higher & further education, tertiary education ; Technology: general issues ; Study & learning skills: general ; Energy technology & engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGP Production and industrial engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TH Energy technology and engineering::THV Alternative and renewable energy sources and technology ; thema EDItEUR::J Society and Social Sciences::JN Education::JNM Higher education, tertiary education ; thema EDItEUR::J Society and Social Sciences::JN Education::JNZ Study and learning skills: general ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TH Energy technology and engineering
    Sprache: Englisch
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    Twin-Control (2021)
    Springer Nature
    Details
    Publikationsdatum: 2024-04-11
    Beschreibung: This open access book summarizes the results of the European research project “Twin-model based virtual manufacturing for machine tool-process simulation and control” (Twin-Control). The first part reviews the applications of ICTs in machine tools and manufacturing, from a scientific and industrial point of view, and introduces the Twin-Control approach, while Part 2 discusses the development of a digital twin of machine tools. The third part addresses the monitoring and data management infrastructure of machines and manufacturing processes and numerous applications of energy monitoring. Part 4 then highlights various features developed in the project by combining the developments covered in Parts 3 and 4 to control the manufacturing processes applying the so-called CPSs. Lastly, Part 5 presents a complete validation of Twin-Control features in two key industrial sectors: aerospace and automotive. The book offers a representative overview of the latest trends in the manufacturing industry, with a focus on machine tools.
    Schlagwort(e): Engineering ; Manufactures ; Vibration ; Dynamical systems ; Dynamics ; Control engineering ; Machinery ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGB Mechanical engineering::TGBN Engines and power transmission ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGM Materials science ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGP Production and industrial engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJF Electronics engineering::TJFM Automatic control engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGB Mechanical engineering::TGBN Engines and power transmission ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGM Materials science ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGP Production and industrial engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJF Electronics engineering::TJFM Automatic control engineering
    Sprache: Englisch
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    Digital Transformation of the Design, Construction and Management Processes of the Built Environment (2021)
    Springer Nature
    Details
    Publikationsdatum: 2021-02-10
    Beschreibung: This open access book focuses on the development of methods, interoperable and integrated ICT tools, and survey techniques for optimal management of the building process. The construction sector is facing an increasing demand for major innovations in terms of digital dematerialization and technologies such as the Internet of Things, big data, advanced manufacturing, robotics, 3D printing, blockchain technologies and artificial intelligence. The demand for simplification and transparency in information management and for the rationalization and optimization of very fragmented and splintered processes is a key driver for digitization. The book describes the contribution of the ABC Department of the Polytechnic University of Milan (Politecnico di Milano) to R&D activities regarding methods and ICT tools for the interoperable management of the different phases of the building process, including design, construction, and management. Informative case studies complement the theoretical discussion. The book will be of interest to all stakeholders in the building process – owners, designers, constructors, and faculty managers – as well as the research sector.
    Schlagwort(e): Engineering ; Buildings—Design and construction ; Building ; Construction ; Engineering, Architectural ; Computer-aided engineering ; Building—Superintendence ; Construction industry—Management ; Construction superintendence ; Remote sensing ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RG Geography::RGW Geographical information systems (GIS) & remote sensing ; bic Book Industry Communication::T Technology, engineering, agriculture::TN Civil engineering, surveying & building::TNK Building construction & materials ; bic Book Industry Communication::T Technology, engineering, agriculture::TN Civil engineering, surveying & building::TNT Building skills & trades ; bic Book Industry Communication::U Computing & information technology::UG Graphical & digital media applications::UGC Computer-aided design (CAD)
    Sprache: Englisch
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    Kommunikation und Bildverarbeitung in der Automation (2021)
    Springer Nature
    Details
    Publikationsdatum: 2024-04-11
    Beschreibung: In diesem Open-Access-Tagungsband sind die besten Beiträge des 9. Jahreskolloquiums "Kommunikation in der Automation" (KommA 2018) und des 6. Jahreskolloquiums "Bildverarbeitung in der Automation" (BVAu 2018) enthalten. Die Kolloquien fanden am 20. und 21. November 2018 in der SmartFactoryOWL, einer gemeinsamen Einrichtung des Fraunhofer IOSB-INA und der Technischen Hochschule Ostwestfalen-Lippe statt. Die vorgestellten neuesten Forschungsergebnisse auf den Gebieten der industriellen Kommunikationstechnik und Bildverarbeitung erweitern den aktuellen Stand der Forschung und Technik. Die in den Beiträgen enthaltenen anschaulichen Beispiele aus dem Bereich der Automation setzen die Ergebnisse in den direkten Anwendungsbezug.
    Schlagwort(e): Engineering ; Electrical engineering ; Signal processing ; Image processing ; Speech processing systems ; Robotics ; Automation ; Quality control ; Reliability ; Industrial safety ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGP Production and industrial engineering::TGPR Reliability engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJF Electronics engineering::TJFM Automatic control engineering::TJFM1 Robotics ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJK Communications engineering / telecommunications ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TT Other technologies and applied sciences::TTB Applied optics::TTBM Imaging systems and technology
    Sprache: Englisch , Deutsch
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    Human and Organisational Factors (2021)
    Springer Nature
    Details
    Publikationsdatum: 2021-02-10
    Beschreibung: This open access book addresses several questions regarding the implementation of human and organisational factors (HOF) so that recent improvements in industrial safety can be built upon. It addresses sources of frustration in senior management with high expectations of operational recommendations and disquiet on the part of HOF specialists struggling to have an impact on high-level decision making. The brief explores these issues with an emphasis on examples and lessons learned based on the experience of its authors, who come from different academic disciplines and various industrial sectors such as oil and gas, energy and transportation. It then offers some ways forward for a better consideration of HOF in hazardous companies with a view of promoting safety and facing challenges in a rapidly changing world.
    Schlagwort(e): Engineering ; Engineering economics ; Engineering economy ; Industrial psychology ; Economic sociology ; Welfare economics ; bic Book Industry Communication::J Society & social sciences::JH Sociology & anthropology::JHB Sociology::JHBL Sociology: work & labour ; bic Book Industry Communication::J Society & social sciences::JM Psychology::JMJ Occupational & industrial psychology ; bic Book Industry Communication::K Economics, finance, business & management::KC Economics::KCA Economic theory & philosophy ; bic Book Industry Communication::T Technology, engineering, agriculture::TB Technology: general issues::TBC Engineering: general
    Sprache: Englisch
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    En un ambiente tóxico (2023)
    CLACSO
    Details
    Publikationsdatum: 2023-10-05
    Beschreibung: En junio del 2014 la comunidad Kukama de Cuninico, fue afectada por el derrame de 2500 barriles de petróleo. Como muchas otras comunidades nativas en la Amazonia, Cuninico está enfrascada en un contexto postdesastre agudizado por la ineficiencia estatal. Las dinámicas intrafamiliares y comunitarias, así como las expectativas a futuro de los que allí viven, han cambiado profundamente. En este contexto son las mujeres las que deben asumir más responsabilidades para enfrentar la crisis.
    Schlagwort(e): Environmental Science ; Sustainability ; Engineering ; bic Book Industry Communication::R Earth sciences, geography, environment, planning::RN The environment::RNK Conservation of the environment ; bic Book Industry Communication::T Technology, engineering, agriculture::TH Energy technology & engineering::THF Fossil fuel technologies::THFP Petroleum technology
    Sprache: Spanisch
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    Pacific Climate Cultures (2022)
    De Gruyter | De Gruyter Open Poland
    Details
    Publikationsdatum: 2022-11-22
    Beschreibung: This edited volume examines the opportunities to think, do, and/or create jointly afforded by digital storytelling. The contributors discuss digital storytelling in the context of educational programs, teaching anthropology, and ethnographic research involving a variety of populations and subjects that will appeal to researchers and practitioners engaged with qualitative methods and pedagogies that rely on media technology.
    Schlagwort(e): Discourse ; Climate Change ; Humans ; Nature ; Oceania ; Resilience ; Environmental Ethics ; Environmental Change ; Worldview ; bic Book Industry Communication::J Society & social sciences::JF Society & culture: general::JFF Social issues & processes::JFFC Social impact of disasters ; bic Book Industry Communication::J Society & social sciences::JF Society & culture: general::JFH Popular beliefs & controversial knowledge::JFHF Folklore, myths & legends ; bic Book Industry Communication::J Society & social sciences::JF Society & culture: general::JFS Social groups::JFSL Ethnic studies::JFSL9 Indigenous peoples ; bic Book Industry Communication::J Society & social sciences::JH Sociology & anthropology::JHB Sociology::JHBD Population & demography ; bic Book Industry Communication::J Society & social sciences::JH Sociology & anthropology::JHM Anthropology ; bic Book Industry Communication::P Mathematics & science::PS Biology, life sciences::PSX Human biology::PSXM Medical anthropology
    Sprache: Englisch
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    Künstliche Intelligenz (2021)
    Springer Nature
    Details
    Publikationsdatum: 2024-03-26
    Beschreibung: Dieses Buch ist eine Open-Access-Publikation unter einer CC BY 4.0 Lizenz. Künstliche Intelligenz (KI) klingt in aktuellen Debatten oft abstrakt und alltagsfremd. Doch die meisten Internetnutzerinnern und -nutzer sind bereits täglich mit ihr konfrontiert – wenn auch unbewusst: sei es bei der Sprachsteuerung des Smartphones, bei Kaufempfehlungen im Online-Shop oder bei der Abfrage von auf Webseiten häufig gestellten Fragen (Frequently Asked Questions, FAQ). KI ist ein Teilaspekt der Digitalisierung, der als Schlagwort immer häufiger in den Medien auftaucht. Das aktuell große Interesse liegt darin begründet, dass es in den vergangenen Jahren verschiedene technologische Fortschritte gab, welche die Nutzung der KI nun auf andere Ebenen heben. Mit diesem Themenband des Instituts für Innovation und Technik (iit) „Künstliche Intelligenz“ erhalten Leserinnen und Leser einen schlaglichtartigen Einblick in die KI hinsichtlich ihrer Technologien, aktuellen und potenziellen Anwendungen sowie Auswirkungen auf die Gesellschaft.
    Schlagwort(e): Engineering ; Electrical engineering ; Humanities—Digital libraries ; Educational technology ; thema EDItEUR::D Biography, Literature and Literary studies::D Biography, Literature and Literary studies::DS Literature: history and criticism ; thema EDItEUR::J Society and Social Sciences::JN Education::JNV Educational equipment and technology, computer-aided learning (CAL) ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TJ Electronics and communications engineering::TJK Communications engineering / telecommunications
    Sprache: Deutsch
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    Sonic Skills (2021)
    Springer Nature
    Details
    Publikationsdatum: 2024-04-11
    Beschreibung: It is common for us today to associate the practice of science primarily with the act of seeing—with staring at computer screens, analyzing graphs, and presenting images. We may notice that physicians use stethoscopes to listen for disease, that biologists tune into sound recordings to understand birds, or that engineers have created Geiger tellers warning us for radiation through sound. But in the sciences overall, we think, seeing is believing. This open access book explains why, indeed, listening for knowledge plays an ambiguous, if fascinating, role in the sciences. For what purposes have scientists, engineers and physicians listened to the objects of their interest? How did they listen exactly? And why has listening often been contested as a legitimate form of access to scientific knowledge? This concise monograph combines historical and ethnographic evidence about the practices of listening on shop floors, in laboratories, field stations, hospitals, and conference halls, between the 1920s and today. It shows how scientists have used sonic skills—skills required for making, recording, storing, retrieving, and listening to sound—in ensembles: sets of instruments and techniques for particular situations of knowledge making. Yet rather than pleading for the emancipation of hearing at the expense of seeing, this essay investigates when, how, and under which conditions the ear has contributed to science dynamics, either in tandem with or without the eye.
    Schlagwort(e): Engineering ; Acoustical engineering ; Technology—History ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues::TBX History of engineering and technology ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TT Other technologies and applied sciences::TTA Acoustic and sound engineering
    Sprache: Englisch
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    Impedance Spectroscopy (2021)
    De Gruyter
    Details
    Publikationsdatum: 2024-04-11
    Beschreibung: This book covers new advances in the field of impedance spectroscopy including fundamentals, methods and applications. It releases selected extended and peer reviewed scientific contributions from the International Workshop on Impedance Spectroscopy (IWIS 2017) focussing on detailed information about recent scientific research results in electrochemistry and battery research, bioimpedance measurement, sensors, system design, signal processing.
    Schlagwort(e): Engineering ; International Workshop on Impedance Spectroscopy ; Electrochemistry and Battery Research ; Bioimpedance Measurement ; Sensors ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TB Technology: general issues::TBM Instruments and instrumentation::TBMM Engineering measurement and calibration
    Sprache: Englisch
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    Risk Communication for the Future (2021)
    Springer Nature
    Details
    Publikationsdatum: 2024-03-25
    Beschreibung: The conventional approach to risk communication, based on a centralized and controlled model, has led to blatant failures in the management of recent safety related events. In parallel, several cases have proved that actors not thought of as risk governance or safety management contributors may play a positive role regarding safety. Building on these two observations and bridging the gap between risk communication and safety practices leads to a new, more societal perspective on risk communication, that allows for smart risk governance and safety management. This book is Open Access under a CC-BY licence.
    Schlagwort(e): Engineering ; Quality control ; Reliability ; Industrial safety ; Operations research ; Management science ; Communication ; thema EDItEUR::G Reference, Information and Interdisciplinary subjects::GT Interdisciplinary studies::GTC Communication studies ; thema EDItEUR::K Economics, Finance, Business and Management::KJ Business and Management::KJT Operational research ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TG Mechanical engineering and materials::TGP Production and industrial engineering::TGPR Reliability engineering
    Sprache: Englisch
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    Engaging Students (2023)
    UJ Press | UJ Press
    Details
    Publikationsdatum: 2024-03-29
    Beschreibung: The book provides a rich, informative picture of the current state of student engagement evaluation, while also highlighting challenges and opportunities for future advances. A particular strength of this publication is its emphasis on the importance of taking evidence-based decisions, and showing how the South African Survey of Student Engagement (SASSE) can provide the evidence for well-informed changes in policy and practice in order to enhance student success." - Prof Magda Fourie-Malherbe, Stellenbosch University
    Schlagwort(e): Academics ; Academic achievement ; Academic advising ; Academic advisors ; Academic challenge ; Academic development ; Academic literacy ; Academic performance ; Academic support ; Access ; Academic staff (also see academics/Lecturers) ; Actionable ; Active learning ; Agency ; Aggregated ; Analyse ; Apply ; Ask questions ; Assessment ; Attitude ; Australasian Survey of Student Engagement (AUSSE) ; Beginning University Survey of Student Engagement (BUSSE) ; Benchmarking ; Bloom’s taxonomy ; Business ; economics and management ; Campus environment ; Capacity ; Career advisors ; Challenges ; Classroom activities ; Classroom Survey of Student Engagement (CLASSE) ; Co-curricular (also see extra-curricular) ; Cognitive ; Cognitive development ; Cognitive educational activities ; Cognitive functions ; Cognitive skills ; Collaborative learning ; Colleges ; Community college ; Comprehensive universities ; Conditional formatting ; Contextual ; Contextual challenges ; Contextualised ; Council on Higher Education (CHE) ; Course (module/subject) ; Critical thinking ; Culture ; Curriculum ; Data ; Data-informed ; Decision-making ; Decolonisation ; Deep learning ; Department chairs (heads of departments) ; Department of Higher Education and Training (DHET) ; Development ; Developmental outcomes ; Diagnostic ; Disaggregating ; Discussions ; Discussion with diverse others ; Dropout ; Education outcomes ; Effective educational behaviours ; Effective educational practices ; Effective leadership ; Effective teaching practices ; Empirical ; Engagement – also see Student Engagement ; Engineering ; Equity ; Equitable outcomes ; Evaluate ; Evidence ; Evidence-based ; Expectations ; Expected academic difficulty ; Expected academic perseverance ; Experiential learning ; Experience with staff ; Extended degree ; Extended curricula ; Extra-curricular (also see co-curricular) ; Financial Stress Scale ; First-generation ; First-year ; Food ; Food insecurity ; Frequency ; Freshman myth ; Gender ; Graduate attributes (Learning outcomes) ; Group work ; Heads of departments ; High-Impact practices ; Higher education outcomes ; Higher-Order Learning ; Holistic ; Humanities ; Incentive ; Indicators ; Innovation ; Innovative ; Instructional paradigm ; Interactions ; Interventions ; Institutional culture ; Institutional performance ; Institutional research ; Institutional researchers ; Institution-wide approaches ; Interpersonal relationships ; Interpersonal skills ; Intersectional ; Intersectionality ; Irish Survey of Student Engagement (ISSE) ; Knowledge ; Knowledge society ; Language ; Law ; Leaders ; Leadership (management/university leadership) ; Learning ; Learning environments ; Learning facilitator ; Learning outcomes ; Learning paradigm ; Learning strategies ; Learning with peers ; Lecturer Survey of Student Engagement (LSSE) ; Lecturers (also see academics/academic staff) ; Librarians ; Management (University leaders and Leadership) ; Mathematics ; Memorisation ; Mentor ; Mentoring ; Mentorship ; Mission ; Module (course/subject) ; Motivation ; National Benchmark Tests (NBT) ; National Benchmark Test Project (NBTP) ; National Development Plan ; National Survey of Student Engagement (NSSE) ; Natural and Agricultural Sciences ; Next Generation of Academics Programme (nGAP) ; Numeracy development ; Off-campus ; On-campus ; Online resources ; Pathways ; Peer learning (also see Tutor) ; Pedagogical approaches ; Pedagogical contexts ; Pedagogical environments ; Pedagogical experiences ; Pedagogical innovation ; Pedagogical practices ; Pedagogical relationship ; Pedagogical responsiveness ; Pedagogies ; Perceived academic preparation ; Perceived preparedness ; Persistence ; Policies ; Policy ; Policy makers ; Practical significance ; Practical work ; Preparing for class ; Professional development ; Professionals ; Professional staff ; Quadrant ; Quality ; Quality assurance ; Quality of interactions ; Quantitative reasoning ; Reflection ; Reflective and integrative learning ; 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    Sprache: Englisch
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  • 69
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    Ambisonics (2021)
    Springer Nature
    Details
    Publikationsdatum: 2024-04-07
    Beschreibung: This open access book provides a concise explanation of the fundamentals and background of the surround sound recording and playback technology Ambisonics. It equips readers with the psychoacoustical, signal processing, acoustical, and mathematical knowledge needed to understand the inner workings of modern processing utilities, special equipment for recording, manipulation, and reproduction in the higher-order Ambisonic format. The book comes with various practical examples based on free software tools and open scientific data for reproducible research. The book’s introductory section offers a perspective on Ambisonics spanning from the origins of coincident recordings in the 1930s to the Ambisonic concepts of the 1970s, as well as classical ways of applying Ambisonics in first-order coincident sound scene recording and reproduction that have been practiced since the 1980s. As, from time to time, the underlying mathematics become quite involved, but should be comprehensive without sacrificing readability, the book includes an extensive mathematical appendix. The book offers readers a deeper understanding of Ambisonic technologies, and will especially benefit scientists, audio-system and audio-recording engineers. In the advanced sections of the book, fundamentals and modern techniques as higher-order Ambisonic decoding, 3D audio effects, and higher-order recording are explained. Those techniques are shown to be suitable to supply audience areas ranging from studio-sized to hundreds of listeners, or headphone-based playback, regardless whether it is live, interactive, or studio-produced 3D audio material.
    Schlagwort(e): Engineering ; Signal processing ; Image processing ; Speech processing systems ; Acoustical engineering ; Acoustics ; Music ; thema EDItEUR::A The Arts::AV Music ; thema EDItEUR::P Mathematics and Science::PH Physics::PHD Classical mechanics::PHDS Wave mechanics (vibration and acoustics) ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TT Other technologies and applied sciences::TTA Acoustic and sound engineering ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TT Other technologies and applied sciences::TTB Applied optics::TTBM Imaging systems and technology
    Sprache: Englisch
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  • 70
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    Poor Man's Fortune (2023)
    University of North Carolina Press
    Details
    Publikationsdatum: 2024-04-02
    Beschreibung: White working-class conservatives have played a decisive role in American history, particularly in their opposition to social justice movements, radical critiques of capitalism, and government help for the poor and sick. While this pattern is largely seen as a post-1960s development, Poor Man's Fortune tells a different story, excavating the long history of white working-class conservatism in the century from the Civil War to World War II. With a close study of metal miners in the Tri-State district of Kansas, Missouri, and Oklahoma, Jarod Roll reveals why successive generations of white, native-born men willingly and repeatedly opposed labor unions and government-led health and safety reforms, even during the New Deal. With painstaking research, Roll shows how the miners' choices reflected a deep-seated, durable belief that hard-working American white men could prosper under capitalism, and exposes the grim costs of this view for these men and their communities, for organized labor, and for political movements seeking a more just and secure society. Roll's story shows how American inequalities are in part the result of a white working-class conservative tradition driven by grassroots assertions of racial, gendered, and national privilege.
    Schlagwort(e): History ; American Studies ; Labor & Employment Relations ; Engineering ; thema EDItEUR::N History and Archaeology::NH History::NHK History of the Americas ; thema EDItEUR::K Economics, Finance, Business and Management::KN Industry and industrial studies::KNX Industrial relations, occupational health and safety::KNXN Industrial arbitration and negotiation ; thema EDItEUR::T Technology, Engineering, Agriculture, Industrial processes::TT Other technologies and applied sciences::TTU Mining technology and engineering
    Sprache: Englisch
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  • 71
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    Digitale Medien
    The compositional distribution of coding sequences and DNA molecules in humans and murids (1988)
    Springer
    Journal of molecular evolution 27 (1988), S. 311-320 
    Details
    ISSN: 1432-1432
    Schlagwort(e): Genome composition ; Coding sequences ; Isochores ; Humans ; Murids
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Summary The compositional distributions of coding sequences and DNA molecules (in the 50-100-kb range) are remarkably narrower in murids (rat and mouse) compared to humans (as well as to all other mammals explored so far). In murids, both distributions begin at higher and end at lower GC values. A comparison of homologous coding sequences from murids and humans revealed that their different compositional distributions are due to differences in GC levels in all three codon positions, particularly of genes located at both ends of the distribution. In turn, these differences are responsible for differences in both codon usage and amino acids. When GC levels at first+second codon positions and third codon positions, respectively, of murid genes are plotted against corresponding GC levels of homologous human genes, linear relationships (with very high correlation coefficients and slopes of about 0.78 and 0.60, respectively) are found. This indicates a conservation of the order of GC levels in homologous genes from humans and murids. (The same comparison for mouse and rat genes indicates a conservation of GC levels of homologous genes.) A similar linear relationship was observed when plotting GC levels of corresponding DNA fractions (as obtained by density gradient centrifugation in the presence of a sequence-specific ligand) from mouse and human. These findings indicate that orderly compositional changes affecting not only coding sequences but also noncoding sequences took place since the divergence of murids. Such directional fixations of mutations point to the existence of selective pressures affecting the genome as a whole.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF02101193
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  • 72
    Digitale Medien
    Digitale Medien
    Phylogenetic evidence for multiple Alu source genes (1992)
    Springer
    Journal of molecular evolution 35 (1992), S. 7-16 
    Details
    ISSN: 1432-1432
    Schlagwort(e): Alu source genes ; Humans ; Gorillas ; Retrotransposition
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Summary A member of the young PV Alu sub-family is detected in chimpanzee DNA showing that the PV subfamily is not specific to human DNA. This particular Alu is absent from the orthologous loci in both human and gorilla DNAs, indicating that PV subfamily members transposed within the chimpanzee lineage following the divergence of chimpanzee from both gorilla and human. These findings and previous reports describing the transpositional activity of other Alu sequences within the human, gorilla, and chimpanzee lineages provide phylogenetic evidence for the existence of multiple Alu source genes. Sequences surrounding this particular Alu resemble known transcriptional control elements associated with RNA polymerase III, suggesting a mechanism by which cis-acting elements might be acquired upon retrotransposition.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF00160256
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  • 73
    Digitale Medien
    Digitale Medien
    An analysis of codon usage in mammals: Selection or mutation bias? (1991)
    Springer
    Journal of molecular evolution 33 (1991), S. 442-449 
    Details
    ISSN: 1432-1432
    Schlagwort(e): Humans ; Mouse ; Rat ; Codon usage ; Mutation bias ; Selection
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Summary A new statistical test has been developed to detect selection on silent sites. This test compares the codon usage within a gene and thus does not require knowledge of which genes are under the greatest selection, that there exist common trends in codon usage across genes, or that genes have the same mutation pattern. It also controls for mutational biases that might be introduced by the adjacent bases. The test was applied to 62 mammalian sequences, the significant codon usage biases were detected in all three species examined (humans, rats, and mice). However, these biases appear not to be the consequence of selection, but of the first base pair in the codon influencing the mutation pattern at the third position.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF02103136
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  • 74
    Digitale Medien
    Digitale Medien
    The evolution of two west African populations (1992)
    Springer
    Journal of molecular evolution 34 (1992), S. 336-344 
    Details
    ISSN: 1432-1432
    Schlagwort(e): Humans ; Mitochondrial DNA ; Nuclear polymorphisms ; Heteroplasmy ; Genetic differentiation ; Sickle cell ; Rain forest refuges
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Summary The identification of genetically coherent populations is essential for understanding human evolution. Among the culturally uniform ethnic groups of west Africa, there are two geographically distinct populations with high frequencies of sickle-cell hemoglobin (HbS). Although the HbS mutation in each group is found on distinguishable chromosomes 11, these populations have been assumed to be parts of a single population. Analysis of mitochondrial DNA (mtDNA) in these populations demonstrated that the two populations identified by alternative chromosomes 11 bearing HbS have distinct distributions of mitochondrial genotypes, i.e., they are maternally separate. These studies also showed that, contrary to expectation, the mtDNA of some individuals is heteroplasmic. For nuclear loci, a comparison of the frequency of alternative alleles established that these populations are genetically distinct. Both the mitochondrial and nuclear data indicate that these populations have been separate for approximately 50,000 years. Although HbS in the two populations is usually attributed to recent, independent mutations, the duration of the separation and the observed geographic distribution of the population allow for the possibility of an ancient origin of HbS. Assuming an ancient mutation and considering the known biogeography, we suggest that HbS protected selected populations from malaria in rain forest refuges during the most recent ice age.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF00160241
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  • 75
    Digitale Medien
    Digitale Medien
    Agaricus Bisporus: An assessment of its carcinogenic potency (1993)
    Springer
    Mycopathologia 124 (1993), S. 73-77 
    Details
    ISSN: 1573-0832
    Schlagwort(e): Assessment ; Cancer ; Humans ; Hydrazines ; Mushroom
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Medizin
    Notizen: Abstract This assessment focuses on the concentrations of some chemicals present in theAgaricus bisporus mushroom, the cancer-inducing doses of these chemicals or mushroom used in the animal experiments, the total amounts of these chemicals or mushroom needed to induce cancer in these mice, and the estimated total amounts of these chemicals or mushroom needed to induce cancer in humans. By adding the estimated amounts of chemicals needed to induce cancer and by comparing it with the amount of raw mushroom needed to induce the same effect, it becomes obvious that we have accounted for less than 2% of the carcinogenic components of theAgaricus bisporus mushroom. Since some unavailable data handicapped this assessment, it should be regarded as tentative and subject to further adjustment.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF01103105
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  • 76
    Digitale Medien
    Digitale Medien
    The solar wind and human birth rate: A possible relationship due to magnetic disturbances (1990)
    Springer
    International journal of biometeorology 34 (1990), S. 42-48 
    Details
    ISSN: 1432-1254
    Schlagwort(e): Briths ; Humans ; Solar wind ; Geomagnetism ; Melatonin
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geographie , Physik
    Notizen: Abstract Data obtained from the literature on the annual pattern of human conceptions and plasma melatonin at high latitudes indicated that simple annual rhythms do not exist. Instead, prominent semiannual rhythms are found, with equinoctial troughs and solsticial peaks. A prominent semiannual environmental event is the magnetic disturbance induced by the solar wind. The semiannual magnetic disturbances are worldwide, but most pronounced in the auroral zones where the corpuscular radiation enters the atmosphere. Magnetic indices that predominantly reflect these events were obtained from the literature and correlated with the melatonin and conception data. Significant and inverse correlations were found for Inuit conceptions and the melatonin data. The correlations obtained for 48 contiguous states of the United States indicated that only the extreme northern states exhibited this relationship. These data were compared with a previous correlational study in the United States which established that sunshine was correlated with conceptions in the middle latitude and southern states. An hypothesis of dual control by electromagnetic and magnetic energies is proposed: melatonin is a progonadal hormone in humans controlled by both factors, depending on their relative strength. Other studies are reviewed regarding the possible factors involved in determining the annual pattern of human conceptions. Demographic studies of geographic variation in temporal patterns of conceptions, with particular regard to variations of the magnetic fields on the earth's surface, may provide some insight into the efficacy of these different factors.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF01045819
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  • 77
    Digitale Medien
    Digitale Medien
    Implementation of periodic acid-thiosemicarbazide-silver proteinate staining for ultrastructural assessment of muscle glycogen utilization during exercise (1985)
    Springer
    Cell & tissue research 242 (1985), S. 229-232 
    Details
    ISSN: 1432-0878
    Schlagwort(e): Skeletal muscles ; Ultrastructure ; Exercise ; Glycogen ; Humans
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Medizin
    Notizen: Summary Distribution of glycogen particles in semithin and ultrathin sections of biopsy samples from human muscles subjected to either short- or long-term running were investigated using PAS and Periodic Acid-ThioSemiCarbazide-Silver Proteinate (PA-TSC-SP) staining methods. Glycogen particles were predominantly found immediately under the sarcolemma or aligned along the myofibrillar Iband. After long-term exhaustive exercise type-1 fibers with a few or no glycogen particles in the core of the fibers were frequently observed. The subsarcolemmal glycogen stores of these “depleted” type-1 fibers were about three times as large as after exhaustive short-time exercise. Another indication of utilization of subsarcolemmal glycogen stores during anaerobic exercise was that many particles displayed a pale, rudimentary shape. This observation suggests fragmental metabolization of glycogen. Thus, depending on type of exercise and type of fiber differential and sequential glycogen utilization patterns can be observed.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF00225582
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  • 78
    Digitale Medien
    Digitale Medien
    Introducing engineering into American secondary education (1993)
    Springer
    Journal of science education and technology 2 (1993), S. 397-406 
    Details
    ISSN: 1573-1839
    Schlagwort(e): Engineering ; technological literacy ; hands-on experiments ; active learning ; content instruction ; videotaping
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Allgemeine Naturwissenschaft , Technik allgemein
    Notizen: Abstract Media reports indicate the decline of the technological literacy of American youth, especially that students in other countries are better prepared in science and mathematics. Our active-learning program, which consists of numerous hands-on experiments, introduces engineering applications into science and math programs, that will demonstrate to students the usefulness of the theory that they currently do not see as useful. The program, when fully developed, will make optimum use of technology, especially computers and videotapes. The hands-on experiments allow students to discover fundamental principles through data analysis and then use the principles to synthesize a solution to a technological problem. This discovery-based education will help school systems better meet performance standards such as those in the Maryland School Performance Plan. The experimental approach to science education is especially important in a technology-oriented economy where children use the new technologies without understanding the principles on which they are based.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF00694528
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  • 79
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    Digitale Medien
    Einfluß der Substituenten auf Aktivierungsenthalpie-,-entropie und -volumen beim Zerfall organischer Perester (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 240-245 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: Influence of Substituents on the Enthalpy, Entropy and Volume of Activation in the Decomposition of Organic PerestersThe influence of the ester group on the decomposition of organic peroxides was studied on peresters of the pivalic and neodecanoic acid with tert-butyl, tert-amyl, 1-methyl-1-propylpentyl and 1,1,4-trimethylpentyl groups at temperatures of 393 to 473 K and pressures up to 3000 bar using a flow method. As expected the half-live times decrease with increasing temperature and increase with rising pressure. With increasing bulkiness of the substituents the rates of decomposition as well as the enthalpies of activation increase. This surprising fact can be explained by the simultaneous increase of the entropies and the volumes of activation.
    Notizen: Der Einfluß der Estergruppe auf den Zerfall organischer Peroxide wurde an Perestern der Pivalin- und der Neodecansäure mit tert-Butyl-, tert-Amyl-, 1-Methyl-propylpentyl- sowie 1,1,4-Trimethylpentylresten bei Temperaturen von 393 bis 473 K und Drücken bis 3000 bar in einer Strömungsapparatur untersucht. Die Zerfallshalbwertszeiten nehmen erwartungsgemäß mit steigender Temperatur stark ab und mit steigendem Druck zu. Mit zunehmender Größe der Substituenten steigen sowohl die Zerfallsgeschwindigkeiten als auch die Aktivierungsenthalpien. Dieser überraschende Effekt kann durch die Vergrößerung der Aktivierungsentropie und des Aktivierungsvolumens erklärt werden.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19851180123
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  • 80
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    Digitale Medien
    Zur Lewis-Acidität von Nickel(0), III. Alkalimetall-hydridotrialkylaluminat-Komplexe von Ni(CDT) (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 313-322 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: On the Lewis Acidity of Nickel(0), III. Alkali Metal Hydridotrialkylaluminate Complexes of Ni(CDT)Ni(CDT) reacts with hydridotrialkylaluminates of the alkali metals in ether/THF or ether/amine mixtures at temperatures below -50°C to form the temperature-sensitive compounds [MA(n-Donor)n]+[R3Al—H—Ni(CDT)]- (1-7) (MA = Li, Na; R = Me, Et, iBu). An Al—H—Ni three-centre bond is present in these complexes. On the basis of NMR data, the strength of the hydridoaluminate-nickel bond and the charge on nickel, caused by the hydridoaluminate residue, are compared with the corresponding characteristics of other ligand-Ni(CDT) complexes in which donor-acceptor σ-bonds are present.
    Notizen: Ni(CDT)Abkürzungen: CDT = trans, trans, trans-1,5,9-Cyclododecatrien, COD = 1,5-Cyclooctadien, MA+ (solvatisiertes) Alkalimetall-Ion, PMDTA = N,N,N′,N″N″-Pentamethyldiethylentriamin, TMEDA = N,N,N′,N′-Tetramethylethylendiamin. reagiert mit Alkalimetall-hydridotrialkylaluminaten in Ether/THF-oder Ether/Amin-Mischungen als Lösungsmittel unterhalb von -50°C zu den thermisch labilen Verbindungen [MA(n-Donor)n]+[R3Al—H—Ni(CDT)]- (1-7) (MA = Li, Na; R = Me, Et, iBu). In diesen Komplexen liegt eine Al—H—Ni-Mehrzentrenbindung vor. Anhand NMR-spektroskopischer Daten lassen sich die Stärke der Hydridoaluminat-Nickel-Bindung und die Beladung des Nickels durch den Hydridoaluminat-Rest mit den Bindungsverhältnissen in anderen Ligand-Ni(CDT)-Komplexen mit Donor-Akzeptor-σ-Bindungen vergleichen.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19851180128
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  • 81
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    Digitale Medien
    Zur Lewis-Acidität von Nickel(0), I. Methyllithium-Komplexe von Nickel(0) (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 275-297 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: On the Lewis Acidity of Nickel(0), I. Methyllithium Complexes of Nickel(0)The synthesis and properties of the methyllithium complexes of nickel(0) of the type (n-Donor)m-(LiCH3)Ni0(π-Ligand)n (1a-c, 16a-c, 20a-c) [n-Donor = chelating amine or THF; π-Ligand = CDT, ethene, or CO] are described. The structure of (PMDTA)(LiCH3)Ni(C2H4)2 (1b) has been determined by X-ray crystallography.  -  In these ate complexes, a carbanionic methyl group is σ-bonded to a nickel atom, the acceptor strength of which depend on the π-ligands. The chemical and spectroscopic properties indicate that the Ni—CH3 bond in the carbonyl complex is largely covalent whereas in the CDT and ethene compounds it is more polar. The CDT complex is thermolabile in solution. The findings are in agreement with the following series of increasing acceptor strength: Ni(CDT) 〈 Ni(C2H4)2 〈 Ni(CO)3.
    Notizen: Es wird über die Synthese und Eigenschaften der Methyllithium-Komplexe von Nickel(0) (n-Donor)m(LiCH3)Ni0(π-Ligand)n Wir bezeichnen mitπ-Liganden solche Liganden, die als π-Akzeptoren mit einem Übergangsmetallatom dπ—pπ—oder dπ—dπ-Rückbindungen auszubilden vermögen (Alkene, CO, auch Phosphane);n-Donoren solche Liganden, die als „harte Basen“ (Ether, Amine) über ihre freien Elektronenpaare vornehmlich Hauptgruppenmetall-Ionen, d.h. „harte Säuren“ komplexieren;σ-Donoren solche Liganden, die  -  ohne über Akzeptororbitale zu verfügen  -  entweder polare Bindungen enthalten und Mehrzentrenbindungen eingehen können (Metallalkyle und -hydride) oder ein freies Elektronenpaar bereitstellen (Carbanionen, Phosphorane, Hydrid-Ion), wobei σ-Bindungen zu einem niederwertigen Übergangsmetallatom ausgebildet werden. (1a-c, 16a-c, 20a-c) mit Chelataminen oder THF als n-Donoren und CDTAbkürzungen: CDT = trans,trans,trans-l,5,9-Cyclooctadien; COT = Cyclooctatetraen; PMDTA = Pentamethyldiethylentriamin; TMEDA = Tetramethylethylendiamin; MA+A = Alkalimetall- bzw. quartäres Ammonium-Kation., Ethen oder CO als π-Liganden berichtet. Die Struktur von (PMDTA)(LiCH3)Ni(C2H4)2 (1b) wurde röntgenographisch bestimmt.  -  In diesen at-Komplexen ist eine carbanionische Methylgruppe über eine σ-Bindung an ein Nickelatom gebunden, dessen Akzeptorstärke von den π-Liganden abhängt. Chemische und spektroskopische Eigenschaften der Komplexe lassen für CDT oder Ethen als π-Liganden auf vergleichsweise polare, für den CDT-Komplex in Lösung dazu thermolabile Ni—CH3-Bindungen schließen, während für den Carbonyl-Komplex aufgrund von 13C-NMR-Daten eine überwiegend kovalente Ni—CH3-Bindung anzunehmen ist. Die Befunde stehen mit folgender Reihe zunehmender Akzeptorstärke im Einklang: Ni(CDT) 〈 Ni(C2H4)2 〈 Ni(CO)3.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19851180126
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  • 82
    Digitale Medien
    Digitale Medien
    Über das korrespondierende Verhalten von heteroatom-stabilisierten Carbokationen und dem Cycloheptatrien-Norcaradien-Gleichgewicht (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 620-633 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: On the Correspondence of Heteroatom-stabilized Carbocations and the Cycloheptatriene-Norcaradiene EquilibriumThe effects of alkoxyiminium substituents on the cycloheptatriene-norcaradiene equilibria 1 ⇄ 2 have been investigated. Due to the energetics two classes of compounds were found (ΔH° 〈 0, and ΔH° 〉 0). The transfer of the substituent effect from carbocation to carbocyclus is inhibited by a p-phenylene group. From 1H and 13C NMR spectra at variable temperatures thermodynamic parameters are deduced and correlated with σR-constants obtained from 19F NMR spectroscopy. By extrapolation, the enthalpy difference for the unsubstituted cycloheptatriene and norcaradiene is calculated as 9.3 kcal/mol.
    Notizen: Der Einfluß von Alkoxyiminium-Substituenten an C-7 auf die Lage des Cycloheptatrien-Norcaradien-Gleichgewichts 1 ⇄ 2 wird untersucht. Auf Grund der Energetik gibt es Verbindungen, bei denen Temperaturabsenkung eine Verschiebung des Gleichgewichts zum Norcaradien (ΔH° 〈 0) ergibt, bei anderen Beispielen ist ΔH° 〈 0. Eine p-Phenylenbrücke zwischen Kation und Carbocyclus blockiert den Substituenteneffekt. Aus den 1H- und 13C-NMR-Spektren bei verschiedenen Temperaturen wurden thermodynamische Daten ermittelt und mit den durch 19F-NMR bestimmten σR-Konstanten korreliert. Durch Extrapolation konnte die Enthalpiedifferenz des unsubstituierten Cycloheptatriens und Norcaradiens zu 9.3 kcal/mol abgeschätzt werden.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19851180221
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  • 83
    Digitale Medien
    Digitale Medien
    Hydrated oxocarbons, IV. Silylation of 1,1-dihydroxy compounds (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 661-669 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: Hydratisierte Oxokohlenwasserstoffe, IV. Silylierung von 1,1-Dihydroxy-VerbindungenDie Anwendung von verschiedenen Silylierungsreagenzien auf mono- und polyvicinale 1,1-Di-hydroxy-Verbindungen wurde untersucht. Mit einigen dieser Reagenzien konnten aus Ninhydrin (2) und Rhodizonsäure (17) die entsprechenden geminalen Bis(trimethylsilyloxy)-Derivate 1 und 20 gewonnen werden. Während 1 leicht zu Hexamethyldisiloxan und Indantrion (4) fragmentiert, ist 20 thermisch relativ stabil, es gibt pyrolytisch bei 500°C nur Spuren des Tetraketons 21 ab. Andere Silylierungsreagenzien bewirken unerwartete C-Alkylierung oder C-Amidierung am Dihydroxykohlenstoff. Silylierungen von Perhydroxycyclobutan und -cyclohexan führen zu Ringaufspaltungs- bzw. Verengungsprodukten.
    Notizen: The action of various silylating agents on mono- and polyvicinal 1,1-dihydroxy compounds has been investigated. Some of these reagents converted ninhydrin (2) and rhodizonic acid (17) into the corresponding geminal bis(trimethylsilyloxy) derivatives 1 and 20, respectively. Compound 1 readily fragments to form hexamethyldisiloxane and indantrione (4). The rhodizonic acid derivative 20 is, however, rather stable and even on pyrolysis at 500°C gives only traces of the tetraketone 21. With other silylating agents unexpected C-alkylation or C-amidation at the dihydroxy carbon is observed. Silylation of perhydroxycyclobutane and -cyclohexane leads to ring opened and contracted products.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19851180225
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  • 84
    Digitale Medien
    Digitale Medien
    Cycloadditionen des Triphenylallenyl-Kations mit Cyclopentadien  -  Studium des Reaktionsmechanismus unter stabilen Ionen-Bedingungen (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 694-703 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: Cycloadditions of the Triphenylallenyl Cation with Cyclopentadiene  -  Investigation of the Reaction Mechanism under Stable Ion ConditionsThe triphenylallenyl cation (5) reacts with cyclopentadiene in a concerted [4 + 2] and a stepwise [2 + 2] cycloaddition. The reaction mechanisms are elucidated by NMR spectroscopic observation of the intermediate carbenium ions.
    Notizen: Das Triphenylallenyl-Kation (5) geht mit Cyclopentadien eine konzertierte [4 + 2]- sowie eine stufenweise [2 + 2]-Cycloaddition ein. Die Reaktionsmechanismen werden durch NMR-spektro-skopische Beobachtung der intermediären Carbenium-Ionen aufgeklärt.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19851180229
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  • 85
    Digitale Medien
    Digitale Medien
    Synthese und Struktur Platin-haltiger Tripeldecker- und Tetradecker-Komplexe (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 729-740 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: Synthesis and Structure of Platinum-Containing Triple-Decker and Tetra-Decker ComplexesStacking of the acceptor sandwich bis(η5-2,3-dihydro-1H-1,3-diborolyl)platinum 1 (≙ (C2B2C)2Pt) with (C5H5)M fragments leads to the unsymmetrical triple-decker complexes (η5-C5H5)M-μ-(η5-C2B2C)Pt(η5-C2B2C) 2 (M = Co) and 3 (M = Ni) as well as to the symmetrical tetra-decker complexes [(η5-C5H5)M-μ-(η5-C2B2C)]2Pt 4 (M = Fe) and 5 (M = Ni). In these reactions 1 and (C5H5)Fe(C8H12) yield the tetra-decker 4, whereas with (C5H5)Co(C2H4)2 only the triple-decker 2 is formed. With [(C5H5)Ni(CO)]2 both the triple-decker 3 and the tetra-decker 5 are obtained. NMR studies on the diamagnetic complexes 2 (30 valence electrons), 4 (42 VE), and 5 (46 VE) indicate high-symmetrical conformations, or free rotation of the ligands. 2 and 3 crystallize isotypic; the X-ray structure analyses exhibit the triple-decker arrangement with antiperiplanar conformation of the heterocycles. 3 in comparison with 2 is elongated along the molecular axis. The tetra-deckers 4 and 5 also crystallize isotypic; for the first time a synclinale conformation of the bridging ligands is found.
    Notizen: Aufstockung des Akzeptor-Sandwichs Bis(η5-2,3-dihydro-1H-1,3-diborolyl)platin 1 (≙ (C2B2C)2Pt) mit (C5H5)M-Fragmenten führt zu den unsymmetrischen Tripeldecker-Komplexen (η5-C5H5)M-μ(η5-C2B2C)Pt(η5-C2B2C) 2 (M = Co) und 3 (M = Ni) sowie zu den symmetrischen Tetradecker-Komplexen [(η5-C5H5)M-μ-(η5-C2B2C)]2Pt 4 (M = Fe) und 5 (M = Ni). Dabei ergibt die Reaktion von 1 mit (C5H5Fe(C8H12) den Tetradecker 4, während mit (C5H5)Co(C2H4)2 nur der Tripeldecker 2 entsteht. Mit [(C5H5)Ni(CO)]2 werden der Tripeldecker 3 und der Tetradecker 5 gebildet. NMR-Untersuchungen an den diamagnetischen Komplexen 2 (30 Valenzelektronen), 4 (42 VE) und 5 (46 VE) sprechen für hochsymmetrische Konformationen oder freie Rotation der Liganden. 2 und 3 kristallisieren isotyp; die Röntgenstrukturanalysen zeigen die Tripeldeckeranordnung mit antiperiplanarer Konformation der Heterocyclen. 3 ist im Vergleich zu 2 entlang der Molekülachse aufgeweitet. Die Tetradecker 4 und 5 kristallisieren ebenfalls isotyp, es wird erstmals eine synclinale Konformation der Brückenliganden gefunden.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19851180232
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  • 86
    Digitale Medien
    Digitale Medien
    Ein neuer Zugang zu Alkylthio(trifluoracetyl)furanen durch thermische [3 + 2]-Cycloadditionen neuer mesoionischer 1,3-Oxathiol-4-one an Alkine (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 785-795 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: A New Entry to Alkylthio(trifluoroacetyl)furans by Way of Thermal [3 + 2]Cycloaddition Reactions of New Mesoionic 1,3-Oxathiol-4-ones to AlkynesAs cyclic carbonyl ylides, the novel 2-alkylthio-5-trifluoroacetyl-1,3-oxathiolylium-4-olates of type 1a-d combine with dimethyl acetylenedicarboxylate across the 2,5-position with formation of non-isolable primary adducts, which release COS to give the furandicarboxylic diesters 3a-d. Methyl propiolate reacts with 1a-c to produce mixtures of the regioisomeric furancarboxylic esters 4a-c and 5a-c, whose main components 4a-c are isolable. On the other hand, the reactions of phenylacetylene, 1-diethylaminopropyne, or (Z)-1-methoxy-1-buten-3-yne with 1a proceed with regiospecific formation of the furan derivatives 6, 7, or 8, respectively. The observed regioselectivities are qualitatively discussed on the basis of MO-perturbation theory.
    Notizen: Als cyclische Carbonyl-ylide nehmen die neuen 2-Alkylthio-5-trifluoracetyl-1,3-oxathiolylium-4-olate vom Typ 1a-d in 2,5-Stellung Acetylendicarbonsäure-dimethylester unter Bildung nicht-isolierbarer Primäraddukte auf, die unter COS-Abspaltung Furandicarbonester 3a-d liefern. Mit Propiolsäure-methylester reagiert 1a-c zu Gemischen aus den regioisomeren Furancarbonestern 4a-c und 5a-c, deren Hauptkomponenten 4a-c isolierbar sind. Dagegen vereinigen sich Phenylacetylen, 1-Diethylaminopropin bzw. (Z)-1-Methoxy-1-buten-3-in mit 1a regiospezifisch zu den Furan-Derivaten 6, 7 bzw. 8. Die beobachteten Regioselektivitäten werden qualitativ auf der Basis der MO-Störungstheorie diskutiert.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19851180237
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  • 87
    Digitale Medien
    Digitale Medien
    Notizen. Thermolysis and photolysis of hexachloro-tris-σ-homotropone and related compounds (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 840-844 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Thermolyse und Photolyse von Hexachlor-tris-σ-homotropon und verwandten VerbindungenTroponethylenacetal (2) reagiert mit überschüssigem CCl2 zu den Mono-, Bis- und Tris-Addukten 3, 4a, b und 5. Thermolyse von 5 führt nicht zum Hexachlor-tris-σ-homobenzol (1), ebensowenig wie die Photolyse des Ketons 6a, bei der unter Öffnung einer Cyclopropan-Brückenbindung das sterisch mehr gehinderte Isomere 6b erhalten wird. Die Photolyse von 8 verläuft ebenfalls nicht unter Decarbonylierung (→ 7) sondern unter Cyclopropanring-Öffnung zu 9 bzw. 10, wobei hier die von der Carbonylgruppe am weitesten entfernten Bindungen geöffnet werden.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19851180241
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  • 88
    Digitale Medien
    Digitale Medien
    Schwefelextrusion aus 5(2H)-Isothiazolonen und 5(2H)-Isothiazolthionen zu intermediären Imidoylketenen und -thioketenen (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 851-862 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: Sulfur Extrusion from 5(2H)-Isothiazolones and 5(2H)-Isothiazolethiones to give Intermediate Imidoyl Ketenes and Imidoyl ThioketenesFrom 5(2H-isothiazolethiones (2) and propylene oxide a series of new 5(2H-isothiazolones (7) was prepared. With tributylphosphane (or cyanide ions) 2 and 7 eliminated one sulfur atom. The resulting assumed imidoyl ketenes (8) and imidoyl thioketenes (3) could not be detected spectro-scopically. But by isolation of dimeric imidoyl thioketenes (1,3-dithietanes, 1) and trapping with alcohols, amines, or benzylideneisopropylamine to give derivatives of acrylic acid (4-6) or dihydropyrimidones (9) it is shown that 3 and 8 are probably intermediates.
    Notizen: Aus 5(2H)-Isothiazolthionen (2) wurde mittels Propylenoxid eine Reihe neuer 5(2H)-Isothiazolone (7) hergestellt. Beide Substanzklassen reagieren mit Tributylphosphan (oder Cyanid-Ionen) unter Abspaltung eines Schwefelatoms zu vermuteten, spektroskopisch aber nicht nachgewiesenen Imidoyl-thioketenen (3) bzw. Imidoylketenen (8). Ihr intermediäres Auftreten wurde durch die Isolierung von dimeren Imidoyl-thioketenen (1,3-Dithietanen, 1) und durch Abfangreaktionen mit Alkoholen, Aminen oder Benzylidenisopropylamin zu den Derivaten der Acrylsäure 4-6 bzw. den Dihydropyrimidonen 9 wahrscheinlich gemacht.
    Zusätzliches Material: 4 Tab.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19851180302
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  • 89
    Digitale Medien
    Digitale Medien
    Heterocyclische β-Enaminoester, 36. Das Cycloadditions-Ringerweiterungsprinzip beim 4,5-Dihydropyrrol: 6,7-Dihydro-1H-azepine, Pyrimido[4,5-b]azepine und 1,2,4-Triazolo[5′,1′: 2,3]pyrimido[4,5-b]azepin (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 863-872 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: Heterocyclic β-Enamino Esters, 36. The Cycloaddition-Ring Enlargement Principle on 4,5-Dihydropyrroles: 6,7-Dihydro-1H-azepines, Pyrimido[4,5-b]azepines, and 1,2,4-Triazolo[5′,1′: 2,3]pyrimido[4,5-b]azepineThe 2-amino-1-tosyl-Δ2-pyrroline enamino esters 2a, b react with dichlorotriphenylphosphorane to give the iminophosphoranes 3a, b. With acetylenic esters (4a-c) the 6,7-dihydro-1H-azepines 6a-d are formed according to the cycloaddition-ring enlargement principle. Acids hydrolyze to afford the free azepine enamino esters 7a, c, d. With phenyl isocyanate 6a gives the carbodiimide 9, which upon treatment with 5% aq. NaOH cyclizes to give the pyrimido[4,5-b]azepine 10. Analogously, isopropylamine and hydrazine lead to the 2-N-substituted bicycles 11a, b; with triethyl orthoformiate 11a yields the novel 5:6:7-tricycle 13.
    Notizen: Die 2-Amino-1-tosyl-Δ2-pyrrolin-enaminoester 2a, b reagieren mit Dichlortriphenylphosphoran zu den Iminophosphoranen 3a, b. Mit Acetylenestern (4a-c) entstehen nach dem Prinzip Cycloaddition-Ringerweiterung die 6,7-Dihydro-1H-azepine 6a-d. Säuren hydrolysieren zu den freien Azepin-enaminoestern 7a, c, d. Mit Phenylisocyanat ergibt 6a das Carbodiimid 9, das sich mit 5proz. Natronlauge zum Pyrimido[4,5-b]azepin 10 ringschließen läßt; Isopropylamin und Hydrazin führt analog zu den 2-N-substituierten Bicyclen 11a, b, 11a ergibt mit Orthoameisensäure-triethylester den neuen 5:6:7-Tricyclus 13.
    Zusätzliches Material: 5 Tab.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19851180303
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  • 90
    Digitale Medien
    Digitale Medien
    Carbonylvanadate(-I) mit ungesättigten Liganden: 51V-NMR-und IR-spektroskopische Charakterisierung der Tieftemperaturspezies [V(CO)5L]-; L = N2, Alkin, Alken, CS2 und SO2 (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 895-904 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: Carbonylvanadates(-I) Containing Unsaturated Ligands:51V NMR and IR Characterization of Low-temperature [V(CO)5L]- Complexes; L = N2, Alkyne, Alkene, CS2, and SO2UV irradiation of [Et4N]V(CO)6 + L in THF (L = alkyne, alkene) or 2-Me-THF (L = N2) at 200 K yields the pentacarbonylvanadates [V(CO)5L]- with end-on (N2) and side-on (alkynes, alkenes) coordinated ligands, respectively. [V(CO)5SO2]- (η1S) and [V(CO)5CS2]- (η2-C,S) were obtained from the reaction between [V(CO)5THF]- and L at 200 K. The N2 complex is also formed from [V(CO)5OCMe2]- and N2. The complexes are characterized by their IR and 51V NMR spectra. Shielding of the 51V nucleus decreases in the order alkene 〉 alkyne ≍ N2 〉 SO2 〉 CS2 〉 {O}. Compared to η1-coordination, η2-coordination gives rise to a deshielding contribution of 110 to 280 ppm. The compounds decompose at temperatures above 225 K (L = N2, 2-pentyne, 3-hexyne, cyclopentene, cyclohexene), 240 - 250 K (SO2, CS2, 1-pentene), or 285 K (1-hexyne); with PPh3, [V(CO)5PPh3]- is formed.
    Notizen: Die UV-Bestrahlung von [Et4N][V(CO)6] + L in THF (L = Alkin, Alken) oder 2-Me THF (L = N2) bei 200 K führt zu Pentacarbonylvanadaten [V(CO)5L]- mit end-on (N2) bzw. side-on (Alkine, Alkene) gebundenen Liganden. [V(CO)5SO2]- (η1-S und [V(CO)5CS2]- (η2C,S) wurden durch Umsetzung von [V(CO)5THF]- mit L bei 200 K erhalten. Der N2-Komplex entsteht auch aus [V(CO)5OCMe2]- und N2. Die Komplexe werden durch ihre IR- und 51V-NMR-Spektren charakterisiert. Die Abschirmung am Kern 51V nimmt in der Reihe Alken 〉 Alkin ≍ N2 〉 SO2 〉 CS2 〉 {O} ab. Die η2-Koordination liefert gegenüber der η1-Koordination einen Entschirmugsbeitrag von 110 - 280 ppm. Die Verbindungen zersetzen sich bei Temperaturen oberhalb 225 K (L = N2, 2-Pentin, 3-Hexin, Cyclopenten, Cyclohexen), 240 - 250 K (SO2, CS2, 1-Penten) bzw. 285 K (1-Hexin); mit PPh3 erfolgt Umsetzung zu [V(CO)5PPh3]-.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19851180307
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  • 91
    Digitale Medien
    Digitale Medien
    (Trifluormethyl)selen(VI)-Verbindungen, Synthese und Eigenschaften von Tetrafluor(trifluormethyl)selen-halogeniden sowie Trifluormethanselenonaten (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 943-951 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: (Trifluoromethyl)selenium(VI) Compounds, Synthesis and Properties of Tetrafluoro(trifluoromethyl)selenium Halides and TrifluoromethaneselenonatesFluorination of CF3SeF3 with liquid F2 or AgF2 leads to CF3SeF5, which decomposes to CF4 and SeF4. With water CF4 and SeOF2 are formed. Addition of ClF to CF3SeF3 gives CF3SeF4Cl, which splits mainly into CF3Cl and SeF4. Hydrolysis provides analogously CF3Cl and SeOF2. A neutral concentrated solution of KMnO4 oxydizes CF3SeO2H in water in good yields to CF3SeO3K, the free acid of which is obtained with 74% HClO4. The aqueous solution can be concentrated up to 90%, but above this concentration spontaneous decomposition to CF4, COF2, and SeO2 occurs. Trifluoromethaneselenonates are stable at room temperature but decompose when heated.
    Notizen: Die Fluorierung von CF3SeF3 mit flüssigem Fluor bzw. AgF2 führt zu CF3SeF5 das thermisch in CF4 sowie SeF4 zerfällt und mit H2O zu CF4 und SeOF2 hydrolysiert. Durch Addition von ClF an CF3SeF3 entsteht CF3SeF4Cl, das sich hauptsächlich zu CF3Cl und SeF4 zersetzt. Die Hydrolyse liefert analog CF3Cl und SeOF2. Mit wäßr., gesättigter KMnO4 liefert CF3SeO2H in guter Ausbeute CF3SeO3K, aus dem die freie Säure mit 74proz. HClO4 erhalten wird. Sie läßt sich in wäßriger Lösung bis zu 90% anreichern und zerfällt bei weiterem Konzentrieren spontan zu CF4, COF2 und SeO2. Ihre Salze sind bei Raumtemperatur stabil und explodieren beim Erhitzen.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19851180312
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  • 92
    Digitale Medien
    Digitale Medien
    Metallkomplexe mit biologisch wichtigen Liganden, XXXIV. Allyl-Palladium(II)- und Triphenylphosphan-Gold(I)-Komplexe mit Nucleobasen und Nucleosiden (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 931-942 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: Metal Complexes with Biologically Important Ligands, XXXIV. Allyl-Palladium(II) and Triphenylphosphane Gold(I) Complexes with Nucleobases and NucleosidesThe reactions of (η3-allyl)Pd(μ-Cl)2Pd(η3-allyl) (A) and (COD)Rh(μ-Cl)2Rh(COD) with nucleobases and nucleosides give the complexes (η3-C3H5)Pd(L)Cl (1) (L = inosine, adenosine, guanosine, cytosine, cytidine, 2-thiouracil, 2-thiocytosine) and (COD)Rh(cytosine)Cl (2), respectively. With adenosine and purine also ligand bridged complexes (η3-C3H5)(Cl)Pd—L—Pd(Cl)(η3-C3H5) (3) have been obtained. Ph3PAuCl reacts with the anions L′ of purine, adenine, uridine, and inosine to give the complexes Ph3PAuL′ (5). Ph3PAu+ is added to both N atoms of the dianion of uracil with formation of 6. The coordination of the nucleobases is discussed on the basis of the 1H and 13C NMR spectra. The X-ray structure of Ph3PAu(adeninate) (5b) has been determined.
    Notizen: Die Umsetzung von (η3-Allyl)Pd(μ-Cl)2Pd(η3-Allyl) (A) sowie von (COD)Rh(μ-Cl)2Rh(COD) mit Nucleobasen und Nucleosiden liefert unter Spaltung der Chlorobrücken die Komplexe (η3C3H5)-Pd(L)Cl (1) (L = Inosin, Adenosin, Guanosin, Cytosin, Cytidin, 2-Thiouracil, 2-Thiocytosin) bzw. (COD)Rh(Cytosin)Cl (2). Mit Adenosin und Purin wurden auch Ligand-verbrückte Komplexe (η3-C3H5)(Cl)Pd—L—Pd(Cl)(η3-C3H5) (3) erhalten. Ph3PAuCl setzt sich mit den Anionen L′ von Purin, Adenin, Uridin und Inosin zu Ph3PAuL′ (5) um; Ph3PAu+ addiert sich an die beiden N-Atome des Dianions von Uracil unter Bildung von 6. Die Koordination der Nucleobasen wird anhand der 1H- und 13C-NMR-Spektren diskutiert. Die Struktur von Ph3PAu (Adeninat) (5b) wurde röntgenographisch bestimmt.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19851180311
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  • 93
    Digitale Medien
    Digitale Medien
    Bicyclofulvene, XI. Zur Frage der Spirokonjugation bei Spiro[cycloheptatrien-7,7′-norbornadien] (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1000-1007 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: Bicyclofulvenes, XI. On the Question of Spiroconjugation in Spiro[cycloheptatriene-7,7′-norbornadiene]The title compound 4 as well as the derivatives 5 und 6 have been prepared. The first band in the UV spectrum of 4 in n-heptane is blue-shifted by ca. 20 nm with respect to those of 5 and 6. Model calculations with the CNDO/S-CI method indicate that this hypsochromic shift as well as the bathochromic shift of the corresponding band of 2 relative to that of 3, cannot be explained by spiroconjugation. The thermolysis of 4 yields benzene, heptafulvalene (15), and fulveneallene (16). The latter products are probably derived from cycloheptatrienylidene (14) as an intermediate.
    Notizen: Die Titelverbindung 4 sowie die Derivate 5 und 6 wurden dargestellt. Die erste Bande im UV-Spektrum von 4 in n-Heptan zeigt eine hypsochrome Verschiebung um ca. 20 nm verglichen mit den Banden in 5 und 6. Modellrechungen mit der CNDO/S-CI-Methode zeigen, daß, sowohl diese hypsochrome Verschiebung als auch die bathochrome Verschiebung der entsprechenden Bande von 2 im Vergleich zu 3 nicht auf Spirokonjugation beruht. Die Thermolyse von 4 ergibt neben Benzol Heptafulvalen (15) und Fulvenallen (16). Diese Produkte machen eine Spaltung von 4 in Benzol und Cycloheptatrienyliden (14) wahrscheinlich.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19851180316
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  • 94
    Digitale Medien
    Digitale Medien
    Neue Reagenzien, XXXII. Alkyldiphenylbismutane: Synthese, Eigenschaften und Halogenolyse (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1031-1038 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: New Reagents, XXXII. Alkyldiphenylbismutanes: Synthesis, Properties, and HalogenolysisAlkyldiphenylbismutanes 1 have been synthesized for the first time (61-92%). These compounds are air sensitive, not spontaneously inflammable liquids which decompose not below ≍ 170°C. The diphenylbismutino group is a very good equivalent for Cl- or Br-substituents at aliphatic residues since halogenolysis of the Bi-Alk bond with SO2Cl2 or Br2 already occurs at -40 to 0°C (corresponding fissions of As-Alk and Sb-Alk bonds afford heating to ≍ 130 or ≍ 220°C).
    Notizen: Erstmals konnten Alkyldiphenylbismutane 1 synthetisiert werden (61-92%). Es sind luftempfindliche, nicht selbstentzündliche Flüssigkeiten, die sich erst bei ≍ 170°C zersetzen. Die Diphenylbismutino-Gruppe ist ein sehr gutes Äquivalent für aliphatisch gebundenes Chlor oder Brom, da die Halogenolyse der Bi-Alk-Bindung mit SO2Cl2 oder Br2 bereits bei - 40 bis 0°C abläuft (entsprechende Spaltungen von As-Alk- und Sb-Alk-Bindungen erfolgen bei ≍ 130 bzw. ≍ 220°C).
    Zusätzliches Material: 5 Tab.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19851180319
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  • 95
    Digitale Medien
    Digitale Medien
    Dimere Phospha- und Thiastannylene: Ylidartige Diphospha- und Dithiadistannetane (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1045-1049 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: Dimeric Phospha- and Thiastannylenes: Ylide-type Diphospha- and DithiadistannetanesBis(di-tert-butylphosphino)tin(II) (1) is obtained from the reaction of potassium di-tert-butyl-phosphide with stannous chloride or with the stannous chloride-triethylphosphane complex. Bis(tert-butylthio)tin(II) (2) is prepared by reaction of (η5-C5H5)2Sn with 2-methyl-2-propanethiol or from stannous chloride and (tert-butylthio)trimethylsilane. In solution, 1 and 2 are PR2-and SR-bridged dimers, respectively. NMR spectra indicate that rapid scrambling of terminal and bridging substituents occurs in 2 but not in the cyclic \documentclass{article}\pagestyle{empty}\begin{document}$ \mathop {\rm P}\limits^ + - \mathop {\rm S}\limits^{\rm - } {\rm n} $\end{document} ylide 1.
    Notizen: Bis(di-tert-butylphosphino)zinn(II) (1) entsteht durch Reaktion von Kalium-di-tert-butylphos-phid mit Zinndichlorid oder dem Zinndichlorid-Triethylphosphan-Komplex. Bis(tert-butylthio)-zinn(II) (2) wird hergestellt durch Umsetzung von (η5-C5H5)2Sn mit 2-Methyl-2-propanthiol und entsteht auch bei der Reaktion von Zinndichlorid mit (tert-Butylthio)trimethylsilan. 1 und 2 liegen in Lösung als PR2- bzw. SR-verbrückte Dimere vor. Kernresonanzspektren zeigen, daß bei dem cyclischen \documentclass{article}\pagestyle{empty}\begin{document}$ \mathop {\rm P}\limits^ + - \mathop {\rm S}\limits^{\rm - } {\rm n} $\end{document}-Ylid 1 im Gegensatz zu 2 auch in Ethern keine raschen Platzwechselvorgänge (Brücke/terminal) ablaufen.
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19851180321
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  • 96
    Digitale Medien
    Digitale Medien
    Regioselektive Addition von Grignard-Reagenzien an 3-Methoxy- und 3-Nitrophthalsäureanhydrid (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1058-1070 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: Regioselective Addition of Grignard Reagents to 3-Methoxy- and 3-Nitrophthalic AnhydrideThe regioselectivity in the addition of the grignard reagents 5a and 6a to the anhydrides 1 and 2 is determined by the solvent system: in a highly selective manner (3: 97), the meta carbonyl group is attacked in tetrahydrofuran/tetramethylethylenediamine, while predominant, but relatively unselective (maximum 78:22) addition to the ortho carbonyl group is observed in diethyl ether. The influence of the solvent system on the regioselectivity is discussed. The LUMO-coefficients of the carbonyl carbon atoms in 1 and 2 were calculated.
    Notizen: Die Addition der Grignard-Reagenzien 5a und 6a an die Anhydride 1 und 2 wird entscheidend vom Reaktionsmedium beeinflußt: in Tetrathydrofuran/Tetramethylethylendiamin wird hochselektiv (3: 97) die meta-ständige, in Diethylether dagegen überwiegend, aber mit nur geringer Selektivität (maximal 78: 22), die ortho-Carbonylgruppe angegriffen. Die Strukturen der dabei erhaltenen Addukte werden durch Umwandlung in die Ester 7-10, in die Lactone 11 sowie in die Ketone 12 und 13 bewiesen. Im Zusammenhang mit dem Versuch, die lösungsmittelabhängige Regioselektivität zu interpretieren, wurden die LUMO-Koeffizienten der Carbonylkohlenstoff-atome in 1 und 2 berechnet.
    Zusätzliches Material: 3 Tab.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19851180323
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  • 97
    Digitale Medien
    Digitale Medien
    Cyanphosphorverbindungen, 8. Das ungewöhnliche Anion P2C10N102- (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1078-1085 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: Cyanophosphorus Compounds, 8. The Unusual Anion P2C10N102-The reaction P(CN)3 + CN- (as [18]crown-6-sodium salt) leads via the spectroscopically identified P(CN)4 - to a disproportionation PIII → PI + PV. P(CN)2 - and P2C10N102- (1) have been isolated as products (with Ph3PCHPPh3 + as counter ion). In the latter an anionic aminomalononitrile bridge connects a dicyanophosphino and a pentacyanophosphate group, -P(CN)2 and - P(CN)5-, respectively.
    Notizen: Die Reaktion P(CN)3 + CN- (als [18]Krone-6-Natriumsalz) führt über das nur spektroskopisch erkennbare P(CN)4- zur Disproportionierung PIII → PI + PV. Als Produkte können (mit Ph3PCHPPh3 + als Kation) P(CN)2- und P2C10N102- (1) gefaßt werden. In letzterem sind ein Dicyanphosphino-und ein Pentacyanophosphatrest, -P(CN)2 bzw. - P(CN)5-, über eine anionische Aminomalononitrilbrücke miteinander verbunden.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19851180325
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  • 98
    Digitale Medien
    Digitale Medien
    Addition von Aldehyden an aktivierte Doppelbindungen, XXXV. α-Ketosäuren als Äquivalent für Aldehyde in der Thiazoliumsalz-katalysierten Addition (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1115-1125 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: Addition of Aldehydes to Activated Double Bonds, XXXV. α-Keto Acids as an Equivalent for Aldehydes in the Thiazolium Salt-Catalyzed Additionα-Keto acids can be used instead of aldehydes in the thiazolium salt-catalyzed addition to vinyl ketones. The yields of γ-diketones 1-7 resulting from the aliphatic α-keto acids are equivalent with those obtained from the aldehydes. The diketo acids 9-19 are prepared from the easily accessible 2-oxodiacids. Phenylpyruvic acids are easier to prepare than the phenylacetalehydes and give better yields compared with the corresponding aldehydes in the addition to vinyl ketones leading to the γ-diketones 20-29. These diketones are converted to cyclopentenones. The dihydrofurylglyoxylic ester 40 leads to the diketone 43, which is converted to the diketone 44. There is no aldehyde known equivalent to that keto acid.
    Notizen: α-Ketosäuren können anstelle von Aldehyden in die Thiazoliumsalz-katalysierte Addition an Vinylketone eingesetzt werden. So entstehen die γ-Diketone 1-7 aus den α-Ketosäuren der aliphatischen Reihe in Ausbeuten, die der Aldehydaddition entsprechen. Aus den gut zugänglichen 2-Oxodisäuren werden die Diketosäuren 9-19 erhalten. Phenylbrenztraubensäuren sind besser als Phenylacetaldehyde zu synthetisieren und liefern in der Addition an Vinylketone zu den γ-Diketonen 20-29 bessere Ausbeuten. Diese Diketone wurden in Cyclopentenone übergeführt. Aus dem Dihydrofurylglyoxylsäure-ethylester 40 kann das Diketon 43 und daraus das Diketon 44, erhalten werden, ein entsprechender Aldehyd ist nicht bekannt.
    Zusätzliches Material: 3 Tab.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19851180328
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  • 99
    Digitale Medien
    Digitale Medien
    Masthead (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985) 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19851180501
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  • 100
    Digitale Medien
    Digitale Medien
    Heterocyclische 8π-Systeme, 16. Eliminierung an 2-Alkoxy-3-hydroxyindolinen (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1726-1731 
    Details
    ISSN: 0009-2940
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Heterocyclic 8π-Systems, 16. Elimination Reactions of 2-Alkoxy-3-hydroxyindolinesThermolysis of 2-ethoxy-3-hydroxyindolines 1a-f affords oxindoles 3a-f as main products and the corresponding 3-indolinones 2a-f as by-products. The reaction course via indole 2,3-oxide intermediates is discussed. For this reason rearrangement reactions of 3-hydroxyindoleninium salts 4a, f are investigated.
    Zusätzliches Material: 3 Tab.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cber.19851180439
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