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  • 04.04. Geology  (14)
  • 04.01. Earth Interior  (7)
  • 01.01. Atmosphere  (6)
  • Elsevier  (21)
  • MDPI  (6)
  • Institute of Physics
  • Nature Publishing Group
  • 2020-2024  (27)
  • 1995-1999
  • 1
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    An Integrated Geophysical and Unmanned Aerial Systems Surveys for Multi-Sensory, Multi-Scale and Multi-Resolution Cave Detection: The Gravaglione Site (Canale di Pirro Polje, Apulia) (2024)
    MDPI
    Details
    Publication Date: 2024-05-09
    Description: Gravaglione represents one of the main swallow holes of the Canale di Pirro, low Murge, Apulia region, Italy. Here, after an intense rainstorm, a huge volume of rainwater accumulates at the surface. The drainage dynamics suggest that the Gravaglione could be part of a large, and potentially unknown, karst system. To verify this hypothesis and to acquire useful information on the possible karst environment features, an integrated aerial and geophysical multiscale and multimethod approach was applied. In particular, aerial photogrammetry, ground penetrating radar measurements and electrical resistivity tomography surveys were hence conducted and integrated to potentially detect the caves, define the subsurface volume possibly affected by karst systems and to verify the existence of links between the surficial morphology and the subsoil structure. The results provided interesting insights regarding the presence of a complex karst system extending up to 200 m b.g.l. and with a marked 3D nature. Overall, the Gravaglione case study demonstrates the geophysical approach validity and poses the basis for the development of an expeditive and low-cost high-resolution strategy for detecting and characterizing karst caves.
    Description: Published
    Description: 3820
    Description: OSA1: Variazioni del campo magnetico terrestre, imaging crostale e sicurezza del territorio
    Description: JCR Journal
    Keywords: karst environment ; cave detection ; ground penetrating radar ; electrical resistivity tomography ; 04.04. Geology ; 04.02. Exploration geophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 2
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    Holocene palaeoenvironmental and human settlement evolution in the southern margin of the Salpi lagoon, Tavoliere coastal plain (Apulia, Southern Italy) (2023)
    Elsevier
    Details
    Publication Date: 2024-05-09
    Description: This study aims to understand the relationship between the palaeoenvironmental evolution of the southern margin of the Salpi lagoon (Tavoliere coastal plain, Apulia, Italy) and the development of settlements on its shores during the last part of the Holocene (Late Northgrippian to Late Meghalayan) to complement recent archaeological investigations at the site of pre-Roman Salpia Vetus, Roman Salapia and Medieval Salpi. Micropalaeontological, palynological, and sedimentological analyses were conducted on a total of ten drilled cores, revealing local and regional events. Facies and micropalaeontological analyses show that the lagoon was partially connected to the sea between 6.2 ka BP and 3.1 ka BP. Between 3.1 ka BP and 2.4 ka BP, the area was characterised by marshes and swamps with restricted brackish lagoon conditions and permanent freshwater input. After 2.4 ka BP, the continuous freshwater influx from the major rivers of the coastal plain determined the progradation of the floodplain and the closure of the lagoon, with the formation of the two coastal lakes of Lago Salso (north) and Lago Salpi (south). Pollen data show the expansion of halophytic herbs under local brackish conditions during the Early Meghalayan and the continuous spread of dryland herbs consistent with the closure of the basin. The alluvial plain progradation during the Late Meghalayan allowed the intensive exploitation of the area and the development of a highly anthropogenic landscape. The development of the settlements of pre-Roman Salpia Vetus, Roman Salapia, and Medieval Salpi was mainly determined by the insalubrious condition of the surrounding marshes, due to the reduction in water depth and oscillations in salinity.
    Description: Published
    Description: 37-54
    Description: 5A. Ricerche polari e paleoclima
    Description: JCR Journal
    Keywords: Holocene ; Palaeoenvironmental reconstruction ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
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    The noble gas signature of the 2021 Tajogaite eruption (La Palma, Canary Islands) (2024)
    Elsevier
    Details
    Publication Date: 2024-05-06
    Description: Here, we characterize the temporal evolution of volatiles during the Tajogaite eruption by analyzing the elemental (He-Ar-CO2-N2) and isotopic (He-Ar-Ne) composition of fluid inclusions (FI) in phenocrysts (olivine+ pyroxene) identified in erupted lavas. Our 2021 lava samples identify substantial temporal variations in volatile composition. We show that, during the 2021 Tajogaite eruption, the He-CO2-N2 concentrations in FI increased since October 15th; this increase was accompanied by increasing 40Ar/36Ar ratios (from ~300 to 〉500), and paralleled a major shift in bulk lava chemistry, with increasing Mg contents (Mg#, from 47 to 52 to 55–59), CaO/Al2O3 (from 0.65 to 0.74 to 0.75–0.90), Ni and Cr, and decreasing TiO2, P2O5 and incompatible elements. The olivine core composition also became more forsteritic (from Mg# = 80–81 to Mg# = 84–86). Mineral thermobarometry and FI barometry results indicate that the eruption was sustained by magmas previously stored in at least two magma accumulation zones, at respectively ~6–12 km and 15–30 km, corroborating previous seismic and FI evidence. We therefore propose that the compositional changes seen throughout the eruption can be explained by an increased contribution - since early/mid-October - of more primitive, less degassed magma from the deeper (mantle) reservoir. Conversely, Rc/Ra values (3He/4He ratios corrected for atmospheric contamination) remained constant throughout the whole eruption at MORB-like values (7.38 ± 0.22 Ra, 1σ), suggesting an isotopically homogeneous magma feeding source. The Tajogaite He isotope signature is within the range of values observed for the 1677 San Antonio lavas (7.37 ± 0.17Ra, 1σ), but is more radiogenic than the 3He/4He values (〉9 Rc/Ra) observed in the Caldera de Taburiente to the north. The 3He/4He ratios (6.75 ± 0.20 Ra, 1σ) measured in mantle xenoliths from the San Antonio volcano indicate a relatively radiogenic nature of the mantle beneath the Cumbre Vieja ridge. Based on these results and mixing modeling calculations, we propose that the homogeneous He isotopic signatures observed in volatiles from the Tajogaite/San Antonio lavas reflect three component mixing between a MORB-like source, a radiogenic component and small additions (6–15%) of a high 3He/4He reservoir-derived (〉9Ra) fluid components. The simultaneous occurrence of high 3He/4He (〉9Ra)- and MORB-like He signatures in northern and southern La Palma is interpreted to reflect small-scale heterogeneities in the local mantle, arising from spatially variable proportions of MORB, radiogenic, and high 3He/4He components.
    Description: Published
    Description: 107928
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Keywords: La Palma ; 2021 Tajogaite eruption ; Fluid inclusions ; Noble gas ; Magma feeding system ; Mantle source heterogeneity ; 04.08. Volcanology ; 04.01. Earth Interior
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
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    Quaternary slip-rates probabilistic estimation for the Northern Apennines frontal thrust in the Po Plain (Northern Italy) by integrating surface and subsurface data (2024)
    Elsevier
    Details
    Publication Date: 2024-02-01
    Description: The Northern Apennines thrust front in the Po basin exhibits active blind thrusts and associated anticlines, with some anticline crests either emerging or shallowly buried beneath late Pleistocene continental deposits. This study focuses on the outcropping San Colombano Structure and its buried neighbouring Casalpusterlengo-Zorlesco Structure, representing thrust-controlled anticlines in the central part of the Po basin. We reconstruct the Pleistocene evolution of these anticlines by integrating previously published surface geological maps and subsurface geological constraints from geophysical data and boreholes. We performed a trishear inversion of the deformation observed after the decompaction of the sediments. We used the solutions of the trishear inversion to compute the probabilistic distribution of slip rates over distinct time intervals. Our findings align with previous estimations of long-term slip rates in the Po Plain during the Quaternary, revealing rates of approximately 0.63 mm/yr and 0.53 mm/yr over the past 2.4 Myr for the San Colombano and Casalpusterlengo-Zorlesco Structures, respectively. The analysis of stratigraphic markers unveils a general decrease in faults activity during the Pleistocene, with slip rates around 0.2–0.3 mm/yr in the last 0.3 Myr, along with a diverse evolution of the thrust faults governing the two anticlines. Specifically, the activity rates of the San Colombano Structure supersede that of the Casalpusterlengo-Zorlesco Structure during the Middle to Late Pleistocene, implying an out-of-sequence propagation of the San Colombano ramp-anticline in the Late Pleistocene along an oblique right-lateral transfer zone. Incorporating a probabilistic approach in slip rates calculation provides a more comprehensive handling of uncertainties. This attribute is pivotal in seismic hazard assessment analyses and understanding complex fault systems' tectonic evolution.
    Description: Published
    Description: 230227
    Description: OST2 Deformazione e Hazard sismico e da maremoto
    Description: JCR Journal
    Keywords: San Colombano thrust ; Quaternary tectonics ; Slip rates ; Trishear inversion ; Sediment compaction ; 04.07. Tectonophysics ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
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    The NE-SW Sibari fault zone: A seismic hazard source in Ionian Northern Calabria (Italy) (2024)
    Elsevier
    Details
    Publication Date: 2024-01-25
    Description: A multidisciplinary approach including archaeological, geophysical, and geological/geomorphological surveys provided pieces of evidence that allowed us to identify the Sibari fault zone (SFZ) in Northern Calabria (Italy). The SFZ runs in a ~ NE-SW direction for a length of ~18 km from the Ionian coastline to Terranova da Sibari and has an oblique normal-dextral kinematics. The envelope of the SFZ is derived from several direct and indirect evidence resulting in subparallel and locally en-echelon fault traces over a maximum 500 m-wide band, running at different elevations across hills and flat lands. The SFZ was active since at least the Middle-Upper Pleistocene, producing faulting of alluvial deposits, marine terraces, drainage incisions, and the archaeological structures of Sybaris. Given the fault length and assuming a seismogenic behavior, the SFZ is a primary earthquake source possibly producing moderate to large earthquakes (M ≥ 6). We calculated the average slip rates along the SFZ based on the ages and on the accumulated displacements of offset streams and marine terraces. The estimates are of 0.05–0.18 mm/yr and 0.41–0.70 mm/yr for vertical and dextral slip, respectively. Based on both the measured (min. 30 cm) and the expected value (av. 40 cm) of lateral slip per event, we infer an average recurrence for surface faulting events on the SFZ of about 700–1000 yrs. The most recent surface faulting earthquake occurred on the fault is dated 1300–1100 yrs. ago, highlighting that the elapsed time approaches the estimated average recurrence. Considering these findings, the newly recognized SFZ should be included among the faults that contain a potential seismic hazard in this poorly known portion of the Ionian sector of northern Calabria.
    Description: Published
    Description: 230214
    Description: OST2 Deformazione e Hazard sismico e da maremoto
    Description: JCR Journal
    Keywords: Active faults of Italy ; Seismic hazard ; Offset streams ; Displaced marine terraces ; Sybaris archaeological site ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
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    Regulation of deep carbon degassing by gas-rock-water interactions in a seismic region of Southern Italy (2024)
    Elsevier
    Details
    Publication Date: 2024-01-08
    Description: This study is focused on fluids characterization and circulations through the crust of the Irpinia region, an active seismic zone in Southern Italy, that has experienced several high-magnitude earthquakes, including a catastrophic one in 1980 (M = 6.9 Ms). Using isotopic geochemistry and the carbon‑helium system in free and dissolved volatiles in water, this study aims to explore the processes at depth that can alter pristine chemistry of these natural fluids. Gas-rock-water interactions and their impact on CO2 emissions and isotopic composition are evaluated using a multidisciplinary model that integrates geochemistry and regional geological data. By analyzing the He isotopic signature in the natural fluids, the release of mantle-derived He on a regional scale in Southern Italy is verified, along with significant emissions of deep-sourced CO2. The proposed model, supported by geological and geophysical constraints, is based on the interactions between gas, rock, and water within the crust and the degassing of deep-sourced CO2. Furthermore, this study reveals that the Total Dissolved Inorganic Carbon (TDIC) in cold waters results from mixing between a shallow and a deeper carbon endmember that is equilibrated with carbonate lithology. In addition, the geochemical signature of TDIC in thermal carbon-rich water is explained by supplementary secondary processes, including equilibrium fractionation between solid, gas, and aqueous phases, as well as sinks such as mineral precipitation and CO2 degassing. These findings have important implications for developing effective monitoring strategies for crustal fluids in different geological contexts and highlight the critical need to understand gas-water-rock interaction processes that control fluid chemistry at depths that can affect the assessment of the CO2 flux in atmosphere. Finally, this study highlights that the emissions of natural CO2 from the seismically active Irpinia area are up to 4.08·10+9 mol·y-1, which amounts is in the range of worldwide volcanic systems.
    Description: Published
    Description: 165367
    Description: OST3 Vicino alla faglia
    Description: OST5 Verso un nuovo Monitoraggio
    Description: JCR Journal
    Keywords: CO(2) output; Carbon isotopes; Degassing; Earthquakes; Noble gases; Precipitation ; 04.04 Solid Earth ; 01.01. Atmosphere ; 03.01. General ; 03.02. Hydrology ; 04.06. Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
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    Decarbonation and clast dissolution timescales for short-term magma‑carbonate interactions in the volcanic feeding system and their influence on eruptive dynamics: Insights from experiments at atmospheric pressure (2023)
    Elsevier
    Details
    Publication Date: 2023-12-27
    Description: While long-term interactions of magma with carbonate wall-rock (a.k.a. carbonate assimilation) are well-studied, only recently some experimental studies focused on short-term interactions (seconds to minutes) at magma chamber conditions (0.5 GPa and 1200 ◦C). They have shown that carbonate assimilation can effectively release CO2 and dissolve the ingested clast in syn-eruptive timescales. Carbonate wall-rock xenoliths in eruptive products can hence be seen as proof of even shallower ingestion (i.e., within the feeding dyke). To study these shallower interactions, we performed 66 experiments at atmospheric pressure (i.e., at the second endmember of the vol- canic feeding system) and at 950–1230 ◦C with varying melt compositions and limestone compositions. Decarbonation was found to be mainly dependent on temperature and limestone composition while clast dissolution is largely dependent on magma composition, temperature, pressure and interaction time. In natural systems during magma ascent and with increasing quantities of assimilated wall-rock, the magma temperature would steadily decrease, limiting its own decarbonation and assimilation ability. But even in the 950 ◦C-ex- periments decarbonation (i.e., CO2 release) remained a syn-eruptive process. We subsequently discussed the limits of carbonate assimilation as well as the potential effect of syn-eruptive addition of CO2 to the magmatic mixture on magma ascent and eruption dynamics.
    Description: Published
    Description: 121724
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Keywords: Carbonate assimilation ; Volcanic eruption ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
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    Noble gas magmatic signature of the Andean Northern Volcanic Zone from fluid inclusions in minerals (2020)
    Elsevier
    Details
    Publication Date: 2023-11-21
    Description: Trace volatile elements like He are key for understanding the mantle source signature of magmas and to better constrain the relative roles of subduction and crustal processes to the variability of along-arc chemical and isotopic signatures of magmatic fluids. Here we report on noble gas abundances and isotopic data of Fluid Inclusions (FIs) in eruptive products and/or fumarolic gases from the Colombia-Ecuador segment of Andean Northern Volcanic Zone (NVZ). FIs in olivine phenocrysts from Ecuador (El Reventador, Cotopaxi and Tungurahua) yield air-normalized corrected 3He/4He ratios of 7.0–7.4 RA, within the MORB range (8 ± 1 RA). With exception of the Cotopaxi lavas (opx 〈 〈oliv.), these are indistinguishable of those obtained for their cogenetic orthopyroxene pairs and of gas emissions previously reported in literature. Olivine phenocrysts from Nevado del Ruiz fissure lavas also yield the highest 3He/4He (8.5 ± 0.3 RA) for this volcanic system, which is in the range of fumarolic gases for Galeras (previously reported as high as 8.8 RA and here measured to a maximum of 8.3 ± 0.1 RA). Our dataset highlights disparities between isotope signatures of eruptive products from Ecuador (avg. ~7.2 RA) and those reported for the Colombian portion of the NVZ (avg. ~8.5 RA). Previous studies on the geochemistry of erupted products put in evidence significant along-arc variations ascribed either to the involvement of different slab components, or to variable depths of evolution of arc magmas within the continental crust. However, the same variation is not discernible in the signature of noble gases, especially helium, from FIs and gas emissions analyzed in this study, with little inter-variation between Cotopaxi, Reventador and Tungurahua (all within 0.2 RA from the Ecuador average of 7.2) and Galeras and Nevado del Ruiz, whose maximum values differ by ~0.3 RA. We therefore suggest a homogenous MORB-like 3He/4He signature for the mantle wedge beneath this arc segment, whereby along-arc variations in crustal thickness (from 〈35 km at the northernmost part of the segment to ≥50 km at the Ecuadorian arc segment) may factor largely into the variability recorded on our data set. The first CO2/3He ratios obtained in FIs from Andean rocks support the hypothesis of increasing crustal contamination from Colombia to Ecuador, concomitant with increasing crustal thicknesses under the respective arc regions.
    Description: Published
    Description: 119966
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Andean Volcanic Belt ; Northern Volcanic Zone ; Fluid inclusions ; Noble gases ; Helium ; Crustal thickness ; 04.08. Volcanology ; 04.01. Earth Interior
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
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    Petrological and noble gas features of Lascar and Lastarria volcanoes (Chile): Inferences on plumbing systems and mantle characteristics (2020)
    Elsevier
    Details
    Publication Date: 2023-11-16
    Description: Lascar (5592 m a.s.l.) and Lastarria (5697 m a.s.l.) are Chilean active stratovolcanoes located in the Central Volcanic Zone (CVZ; 16°S to 28°S) that have developed on top of a 71 km thick continental crust. Independently of the similarities in their Plinian/Vulcanian eruptive styles, their complex magmatic feeding structures and the origins of their magmatic fluids still necessitate constraints in order to improve the reliability of geochemical monitoring. Here we investigate the petrography, bulk-rock chemistry, and mineral chemistry in products from the 1986–1993 explosive eruptive cycle at Lascar and from several Holocene eruptive sequences at Lastarria. These data are integratedwith measurements of the noble gas isotopes in fluid inclusions (FIs) of minerals fromthe same products as well as in fumarole gases. The geochemistry ofminerals and rocks shows that the studied products belong to high-K–calc-alkaline series typical of subduction-related settings, and provide evidence of differentiation,mixing, and crustal assimilation that are higher at Lastarria. The contribution of slab sediments and fluids to magma genesis in thewedge is limited, suggesting a homogeneous mantle beneath CVZ. The deepest crystallization processes occurred at variable levels of the plumbing systems according to the lithostatic equivalent depths estimated with mineral equilibrium geobarometers at Lascar (15–29 km) and Lastarria (~20–40 km). The 40Ar/36Ar and 4He/20Ne ratios in FIs and fumarole gases indicate the presence of some degree of air contamination in the fluids from both volcanoes. The 3He/4He values at Lascar (6.9–7.3 Ra) are relatively homogeneous and comparable to those of fumaroles, suggesting a main zone of magma crystallization and degassing. In contrast, the 3He/4He values at Lastarria (5.31–8.01 Ra) vary over a wide range, suggesting various magma storage levels and providing evidence of crustal contamination, as indicated by the rock chemistry.We argue thatmantle beneath the two volcanoes has a MORB-like signature of 3He/4He, while local crustal contamination explains the lower ratios measured at Lascar.
    Description: Published
    Description: 105615
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: Lascar ; Lastarria ; noble gases ; Fluid inclusions ; Crustal contamination ; Mantle wedge ; 04.08. Volcanology ; 04.01. Earth Interior
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  • 10
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    The composition of fluids stored in the central Mexican lithospheric mantle: Inferences from noble gases and CO2 in mantle xenoliths (2021)
    Elsevier
    Details
    Publication Date: 2023-11-16
    Description: We present the first isotopic (noble gases and CO2) characterization of fluid inclusions coupled to Raman microspectroscopy analyses in mantle xenoliths from Central Mexico, a geodynamically complex area where the Basin and Range extension was superimposed on the Farallon subduction (terminated at 28 Ma). To characterize the isotopic signature of the Central Mexican lithospheric mantle, we focus on fluid inclusions entrapped in mantle xenoliths found in deposits of the Joya Honda maar (JH), a Quaternary monogenetic volcano belonging to the Ventura Espiritu Santo Volcanic Field (VESVF) in the state of San Luis Potosí (central Mexico). Thirteen ultramafic plagioclase-free xenoliths were selected, all exhibiting a paragenesis Ol 〉 Opx 〉 Cpx 〉 〉 Sp, and being classified as spinel-lherzolites and harzburgites. All xenoliths bring textural evidence of interstitial glass veins bearing dendritic trails of secondary melt and fluid inclusions (composed of silicate glass ± CO2 ± Mg-Ca carbonates ± pyrite). These are related to pervasive mantle metasomatism driven by carbonate-rich silicate melt. The Ar and Ne systematics reflect mixing between MORB-like upper mantle and atmospheric fluids, the latter interpreted as reflecting a recycled air component possibly inherited from the Farallon plate subduction. The 3He/4He ratios vary between 7.13 and 7.68 Ra, within the MORB range (7–9 Ra), and the 4He/40Ar* ratios (0.4–3.11) are similarly close to the expected range of the fertile mantle (1–5). Taken together, these pieces of evidence suggest that (i) either the mantle He budget was scarcely modified by the Farallon plate subduction, and/or (ii) that any (large) crustal contribution was masked by a later metasomatism/refertilization episode, possibly during the subsequent Basin and Range extension. A silicate melt-driven metasomatism/refertilization (revealed by the association between glass veins and fluid inclusions) is consistent with calculated helium residence time for the Mexican lithospheric mantle (20 to 60 Ma) that overlaps the timing of the above geodynamic events. We propose that, after the refertilization event (e.g., over the last ~20 Ma), the lithospheric mantle has evolved in a steady-state, becoming slightly more radiogenic. We also estimated 3He fluxes (0.027–0.080 mol/g), 4He production rates (340–1000 mol/yr), and mantle CO2 fluxes (3.93 × 107 mol/yr to 1.18 × 108 mol/yr) using the helium isotopic values measured in JH mantle xenoliths. Finally, the JH xenoliths exhibit CO2/3He ratios comparable to those of the upper mantle (from 3.38 × 108 to 3.82 × 109) but more positive δ13C values (between - 1.0 and - 2.7‰), supporting the involvement of a crustal carbonate component. We propose that the metasomatic silicate melts recycled a crustal carbonate component, inherited by the Farallon plate subduction.
    Description: Published
    Description: 120270
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: Mexican mantle xenoliths ; Fluid inclusions ; Noble gases ; CO2 ; mantle refertilization ; Carbonate recycling ; 04.01. Earth Interior ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 11
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    Recycled crustal carbon in the depleted mantle source of El Hierro volcano, Canary Islands (2021)
    Elsevier
    Details
    Publication Date: 2023-11-16
    Description: The Canary Islands, in the eastern Atlantic, are among the most enigmatic Oceanic Island provinces on Earth, as the mantle source feeding its volcanism exhibits wide spatial heterogeneity and a multiplicity of sources. Multiisotope whole-rock studies have long revealed the presence of a recycled oceanic crust/lithosphere component in the mantle source. However, noble gas systematics have been more challenging to interpret, and the available carbon isotope data is limited and cannot support/dismiss this interpretation. Here, we present the very first isotopic characterisation of CO2 and noble gases (He-Ne-Ar) in fluid inclusions (FI) in minerals hosted in mantle xenoliths from El Hierro, the youngest and westernmost island of the Canary volcanic archipelago. Six fresh xenoliths from El Julan cliff valley were analysed (3 spinel lherzolites and 3 spinel harzburgites). We find carbon isotopic compositions of CO2 in FI (δ13C) ranging from 􀀀 2.38 to 􀀀 1.23‰ in pyroxenes and from 􀀀 0.19 to +0.96‰ in olivines. These unusually positive δ13C values, well above the typical mantle range (􀀀 8‰ 〈 δ13C 〈 􀀀 4‰), prove, for the first time, the presence of a recycled crustal carbon component in the local source mantle. We interpret this 13C-rich component as inherited from a mantle metasomatism event driven by fluids carrying carbon from C. In contrast, our El Hierro xenoliths identify a depleted mantle-like He signature, with an average Rc/Ra ratio (3He/4He normalised to air ratio and corrected for atmospheric contamination) of 7.45 ± 0.26 Ra. The involvement of depleted mantle-like fluids, variably admixed with air-derived components (possibly recycled via paleo-subduction event(s)), is corroborated by Ne-Ar isotopic compositions. The depleted mantle-like He signature suggests instead the involvement of a primordial He source in the local lithospheric mantle and indicates a marginal role played by past subduction events in modifying the local mantle He budget. When put in the context of previous 3He/4He measurements in FI and surface gases along the Canary archipelago, our results confirm an overall west-to-east decrease of Rc/Ra ratios, which may be interpreted as due to increasing contributions from the African sub-continental mantle, the addition of radiogenic 4He during magma migration in the oceanic crust (whose thickness increases eastward) and/or magma ageing.
    Description: Published
    Description: 106414
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: Canary Islands ; El Hierro ; Mantle xenoliths ; Fluid inclusions ; Recycled carbon ; noble gases ; 04.08. Volcanology ; 04.01. Earth Interior
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 12
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    The role of trapped fluids during the development and deformation of a carbonate/shale intra-wedge tectonic mélange (Mt. Massico, Southern Apennines, Italy) (2020)
    Elsevier
    Details
    Publication Date: 2023-10-26
    Description: Numerous studies exist on exhumed tectonic mélanges along subduction channels whereas, in accretionary wedge interiors, deformation mechanisms and related fluid circulation in tectonic mélanges are still underexplored. We combine structural and microstructural observations with geochemical (stable and clumped isotopes and isotope composition of noble gases in fluid inclusions of calcite veins) and U-Pb geochronological data to define deformation mechanisms and syn-tectonic fluid circulation within the Mt. Massico intra-wedge tectonic mélange, located in the inner part of the central-southern Apennines accretionary wedge, Italy. This mélange developed by shear deformation at the base of a clastic succession. Deformation was characterized by disruption of the primary bedding, mixing, and deformation of relicts of competent olistoliths and strata within a weak matrix of deformed clayey and marly interbeds. Recurrent cycles of mutually overprinting fracturing/veining and pressure-solution processes generated a block-in-matrix texture. The geochemical signatures of syntectonic calcite veins suggest calcite precipitation in a closed system from warm (108°-147 °C) paleofluids, with δ18O vlaues between þ9‰ and 14‰, such as trapped pore waters after extensive 18O exchange with the local limestone host rock and/or derived by clay dehydration processes at T 〉 120 °C. The 3He/4He ratios in fluid inclusions are lower than 0.1 Ra, indicating that He was exclusively sourced from the crust. We conclude that: (1) intraformational rheological contrasts, inherited trapped fluids, and low-permeability barriers such as marlyshaly matrix, can promote the generation of intra-wedge tectonic mélanges and the development of transient fluid overpressure; (2) clay-rich tectonic mélanges, developed along intra-wedge décollement layers, may generate low-permeability barriers hindering the fluid redistribution within accretionary wedges.
    Description: Published
    Description: 104086
    Description: 1T. Struttura della Terra
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Tectonic mélange ; Fluid-rock interaction ; Stable and clumped isotopes ; Noble gases ; Fold and thrust belt ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 13
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    Subduction-related melt refertilisation and alkaline metasomatism in the Eastern Transylvanian Basin lithospheric mantle: Evidence from mineral chemistry and noble gases in fluid inclusions (2020)
    Elsevier
    Details
    Publication Date: 2023-10-25
    Description: Calc-alkaline and alkaline magmatic activity is generally separated in space and/or in time. The Eastern Transylvanian Basin in Romania is one of the few places where, during Pleistocene, alkaline eruptions occurred contemporaneously with the calc-alkaline activity. Mantle xenoliths entrained in Perşani Mts. alkaline volcanic products have been studied in order to investigate the interaction of metasomatic agents of different magmatic affinities with the mantle wedge. Based on mineral major and trace element and noble gases in fluid inclusions, two main events have been recognized. The first was a pervasive, complete re-fertilization of a previously depleted mantle by a calc-alkaline subduction-related melt, causing the formation of very fertile, amphibole-bearing lithotypes. This is shown by the a) increased amounts of modal clinopyroxene up to 21.9 % with Al2O3 contents up to 8.16 wt%, higher than what is expected for clinopyroxene in Primordial Mantle; b) 4He/40Ar* ratios up to 1.2, within the reported range for mantle production; c) 3He/4He in olivine, opx and cpx of 5.8 ± 0.2 Ra, among the most radiogenic values of European mantle, below the typical MORB mantle value (8 ± 1 Ra), reflecting recycling of crustal material in the local lithosphere. The second event is related to later interaction with an alkaline metasomatic agent similar to the host basalts that caused slight LREE enrichment in pyroxenes and disseminated amphiboles and precipitation of vein amphiboles with a composition similar to amphiboles megacrysts also found in the Perşani Mts. volcanic deposits. This is highlighted by the 4He/40Ar* and 3He/4He values found in some opx and cpx, up to 2.5 and 6.6 Ra, respectively, more typical of magmatic fluids.
    Description: Published
    Description: 105516
    Description: 1T. Struttura della Terra
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Keywords: Mantle refertilisation ; Eastern Transylvanian Basin ; Noble gases ; Post-collisional ; Subduction-related metasomatism ; Solid Earth ; 04.01. Earth Interior
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 14
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    Theoretical principles and application to measure the flux of carbon dioxide in the air of urban zones (2023)
    Elsevier
    Details
    Publication Date: 2023-10-24
    Description: •Anthropogenic CO2 flux can be estimated by stable isotopic surveying. •Gas emissions from human activities force the atmospheric CO2. •The monitoring of stable isotopes allows identifying the CO2 sources in the air. •Several tons per day of CO2 flow through the geosphere in urban zones. •Transient in the air CO2 occurs owing to changes in weather variables.
    Description: Atmospheric carbon dioxide (CO2) concentrations increase due to volcanic emissions, diffuse degassing from fault zones, and various human-caused gas emissions, especially in densely populated urban zones, which play a pivotal role in the ongoing climate change. This study aims to examine changes in the concentration and stable isotopic composition of atmospheric CO2. A laser-based analyzer provided the δ13C and δ18O values based on concentration measurements for various CO2 isotopologues. Multiple linear regression (MLR) showed that almost 30% of the atmospheric CO2 changes are caused by weather variations, while ~70% of the changes involve CO2 from various gas sources related to human activities. The Keeling plot approach was used to identify the isotopic signature of the extra CO2, which points to the gas produced by hydrocarbon combustion. An isotopic mass balance model was designed to show the relation between excess atmospheric CO2 and the flux of human-related gas emissions. Calculating the CO2 flux in the atmosphere based on this isotopic mass balance model showed that several tons of CO2 move daily between geospheres. This study shows that surveying atmospheric CO2 in urban zones allows quantifying the CO2 emissions from various sources.
    Description: Published
    Description: 119302
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: 1TR. Georisorse
    Description: 1IT. Reti di monitoraggio e sorveglianza
    Description: 2IT. Laboratori analitici e sperimentali
    Description: 6IT. Osservatori non satellitari
    Description: JCR Journal
    Keywords: CO2 flux ; Carbon stable isotopes ; Oxygen isotope composition ; Atmospheric CO2 ; Geochemical modeling ; Gas Hazard ; Stable isotopes ; Isotopes ; 01.01. Atmosphere ; 04.08. Volcanology ; environmental geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 15
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    Deep and shallow crustal structure control on the late-stage volcanism in Syria Planum (Mars) (2023)
    Elsevier
    Details
    Publication Date: 2023-10-20
    Description: volcanic provinces with the largest shield volcanoes of the Solar System. However, volcanism on Mars is characterized also by the occurrence of broad volcanic fields, either in the form of small lava shields or monogenic volcanic cones. The region of Syria Planum (SP) is located east of the Tharsis province and between Noctis Labyrinthus to the North and Claritas Fossae to the southwest. It is an example of diffuse volcanism, presenting hundreds of small edifices (namely Syria Colles) which occur on top of a large bulge roughly 300 km × 200 km in size. SP exhibits a complex magmatic and volcano-tectonic evolution spanning from the early-Noachian to the more recent Amazonian. In this work, we investigate the geometry of the plumbing system of the SP volcanic field as well as the geometries of the volcanic constructs (i.e., vent elongation and vent alignment) that may be linked to the structures that fed the magma presenting a possible tectonic and volcanic evolution of the distributed volcanism phase in this area. The spatial distribution of vents and the overall map view shape of the volcanic field were studied in terms of vent clustering and spatial distribution. We show that the widespread and diffuse volcanism in SP presents clear vent clusters that are related to a deep source magma reservoir located at ~100 km depth. We also show that Syria Colles vent elongations and azimuth distributions suggest that the magma exploited the inherited regional structural framework, coherent with the Syria Colles late-stage Amazonian magmatic event, and highlighting the role of a shallow crustal tectonic framework in shaping the Martian volcanism.
    Description: Published
    Description: 107830
    Description: OST1 Alla ricerca dei Motori Geodinamici
    Description: JCR Journal
    Keywords: Volcanic vents clustering ; Vent spatial distribution ; Vent spatial distribution Plumbing system ; Structural inheritance ; Mars ; 04.04. Geology ; 04.08. Volcanology ; 05.07. Space and Planetary sciences
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 16
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    Magma storage and degassing beneath the youngest volcanoes of the Massif Central (France): Lessons for the monitoring of a dormant volcanic province (2023)
    Elsevier
    Details
    Publication Date: 2023-10-03
    Description: Developing appropriate monitoring strategies in long-quiescent volcanic provinces is challenging due to the rarity of recordable geochemical and geophysical signals and the lack of experienced eruptive phenomenology in living memory. This is the case in the Massif Central (France) where the last eruptive sequence formed the Pavin’s Group of Volcanoes, about 7 ka ago. There, current evidence of a mantle activity reminiscence is suggested by the presence of mineral springwaters, mofettes, and soil degassing. It appears fundamental as a prerequisite to decipher the evolution of the gas phase in the magmatic system at the time of the eruptive activity to understand the meaning of current local gas emissions. In this study, we develop an innovative approach coupling CO2 densimetry and geochemistry of fluid inclusions from products erupted by the Pavin’s Group of Volcanoes. 3D imagery by Raman spectroscopy revealed that carbonate forming in fluid inclusions may lead to underestimation of CO2 density in fluid inclusions by up to 50 % and thus to unreliable barometric estimates. Fortunately, we found that this effect may be limited by focusing on fluid inclusions with a small diameter (〈4 m) and where no solid phase is detected on Raman spectra. The time evolution of the eruptions of the Pavin’s Group of Volcanoes shows a progressive decrease of the pressure of magma storage (from more than 9 kbar down to 1.5-2 kbar) in parallel to magma differentiation (from basanites at Montcineyre to benmoreites at Pavin). The analysis of the noble gases entrapped in fluid inclusions yielded two main conclusions: (1) the helium isotope signature (Rc/Ra = 6.5-6.8) is in the range of values obtained in fluid inclusions from mantle xenoliths in the Massif Central (Rc/Ra = 5.6±1.1, on average) suggesting partial melting of the subcontinental lithospheric mantle, and (2) magma degassing (4He/40Ar* from 4.0 to 16.2) mirrors magma differentiation and the progressive rise of the magma ponding zones of the Pavin’s Group of Volcanoes. According to our modelling, about 80 % of the initial gas phase would be already exsolved from these magmas, even if stored at mantle depth. Based on the results obtained from fluid inclusions, we propose a model of the evolution of the signature of noble gases and carbon isotopes from mantle depth to crustal levels. In this frame, gas emissions currently emitted in the area (Rc/Ra = 6.1-6.7 and 4He/40Ar* = 1.7) point to an origin in the lithospheric mantle. This study strongly encourages the establishment of a regular sampling of local gas emissions to detect potential geochemical variations that may reflect a change from current steady-state conditions
    Description: Published
    Description: 121603
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Fluid inclusions ; Barometry ; Noble gases ; Magma degassing ; Monitoring ; 04.08. Volcanology ; 04.01. Earth Interior
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  • 17
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    Atmospheric Deposition around the Industrial Areas of Milazzo and Priolo Gargallo (Sicily-Italy)-Part A: Major Ions (2023)
    MDPI
    Details
    Publication Date: 2023-08-29
    Description: The chemical composition of rainwater was studied in two highly-industrialised areas in Sicily (southern Italy), between June 2018 and July 2019. The study areas were characterised by large oil refining plants and other industrial hubs whose processes contribute to the release of large amounts of gaseous species that can affect the chemical composition of atmospheric deposition As in most of the Mediterranean area, rainwater acidity (ranging in the study area between 3.9 and 8.3) was buffered by the dissolution of abundant geogenic carbonate aerosol. In particular, calcium and magnesium cations showed the highest pH-neutralizing factor, with ~92% of the acidity brought by SO42- and NO3- neutralized by alkaline dust. The lowest pH values were observed in samples collected after abundant rain periods, characterised by a less significant dry deposition of alkaline materials. Electrical Conductivity (ranging between 7 µS cm-1 and 396 µS cm-1) was inversely correlated with the amount of rainfall measured in the two areas. Concentrations of major ionic species followed the sequence Cl- 〉 Na+ 〉 SO42- ≃ HCO3- 〉 ≃ Ca2+ 〉 NO3- 〉 Mg2+ 〉 K+ 〉 F-. High loads of Na+ and Cl- (with a calculated R2 = 0.99) reflected proximity to the sea. Calcium, potassium, and non-sea-salt magnesium had a prevalent crustal origin. Non-sea salt sulphate, nitrate, and fluoride can be attributed mainly to anthropogenic sources. Mt. Etna, during eruptive periods, may be also considered, on a regional scale, a significant source for fluoride, non-sea salt sulphate, and even chloride.
    Description: Published
    Description: 3898
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: acidity neutralization ; anthropogenic source ; atmospheric deposition ; major ions ; marine source ; 01.01. Atmosphere
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 18
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    Atmospheric Deposition around the Industrial Areas of Milazzo and Priolo Gargallo (Sicily–Italy)—Part B: Trace Elements (2023)
    MDPI
    Details
    Publication Date: 2023-08-29
    Description: The concentrations of trace elements in atmospheric bulk depositions (wet plus dry) were investigated from two highly industrialised areas of Sicily (southern Italy) from June 2018 to July 2019, in order to recognise the main natural and anthropogenic sources. A side objective of this study was to improve the common sampling procedures and analytical methods used for monitoring trace elements in atmospheric deposition. The trace element VWM (Volume-Weighted Mean) concentrations ranged from less than 0.01 µg L-1 for trace elements such as Cs, Tl, and U, up to 24 µg L-1 for minor elements (Al, Zn, Sr), in the filtered aliquot, while they reached concentrations up to 144 µg L-1 for the same elements, in the unfiltered aliquot. Therefore, significant differences in concentrations between these two aliquots were found, particularly for Al, Fe, Ti, Zn, Cr, Pb, Se, Cs, and U. This implies that filtering operations may produce a consistent underestimation of concentrations of certain ‘constituents’ of the atmospheric deposition. Natural (marine spray, local and regional geogenic input, volcanic emanations) and anthropogenic sources (industrial emissions, auto vehicular traffic, and diffuse background pollution) which influence rainwater chemistry were identified. Enrichment factors (EFs), with respect to the upper crust composition, provided clear evidence of the different sources above mentioned: Ti, Fe, Al, Cs, Cr, Rb, and Co have low EFs (〈1), and are referable to the (local and/or regional) geogenic input, while Se, Sb, Zn, B, Cd, Cu, Mo, Sr, As, with high EFs (〉10), highlight the influence of marine and/or industrial sources. The study produced a novel dataset on the atmospheric deposition rate of several trace elements, which had never been studied in the investigated areas. Finally, a comparison of trace element deposition rates in the studied areas with the atmospheric deposition reported for 53 different sites, belonging to 20 different European nations, was made. The comparison showed that some elements, such as Al, V, Zn, and Mo had higher median deposition fluxes in the Sicilian sites than in European monitoring sites.
    Description: Published
    Description: 737
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: atmospheric deposition ; rainwater ; industrial pollution ; trace elements ; anthropogenic contribution ; 01.01. Atmosphere
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  • 19
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    The Meran-Mauls Fault: Tectonic switching from compression to transpression along a restraining bend of the Periadriatic Fault (2023)
    Elsevier
    Details
    Publication Date: 2023-06-21
    Description: The WSW-ENE Meran-Mauls Fault (MMF) represents a break in the broadly E-W trending Periadriatic Fault (PAF), separating the Southern Alps from the N-verging wedge of the European Alps. Understanding the MMF evolution is mandatory to reconstruct the role of the entire PAF during the evolution of the belt since the late Cenozoic. Structural and microstructural analyses and paleostress calculations based on fault-slip data suggest the occurrence of four evolutionary stages for the MMF: 1) top-to-the-SE mylonites; 2) top-to-the-SE brittle faulting; 3) dextral faulting with re-activation of previous structures; 4) N–S compression associated with conjugate sets of mainly strike-slip fault systems. Paleostress reconstructions point to a σ2-σ3 permutation from stage 2 to stage 3, resulting in the switch from pure thrusting to strike-slip, followed by an anticlockwise rotation of the principal stress axes during stage 4, in a strike-slip regime related to N–S compression. Geochronological and thermochronological data point to 39-22 Ma age for stage 1, 22-17 Ma for stage 2, less than 17 Ma for stage 3. Our reconstruction strongly supports the interpretation of the MMF as a restraining bend of the PAF, which was weakly reactivated along its eastern portion as a dextral fault and later displaced by NNE-SSW left-lateral faults.
    Description: Published
    Description: 104878
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Periadriatic Fault ; Pseudotachylytes ; Meran–Mauls Fault ; Paleostress ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 20
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    Tidal drag and westward drift of the lithosphere (2023)
    Elsevier
    Details
    Publication Date: 2023-06-05
    Description: Tidal forces are generally neglected in the discussion about the mechanisms driving plate tectonics despite a worldwide geodynamic asymmetry also observed at subduction and rift zones. The tidal drag could theoretically explain the westerly shift of the lithosphere relative to the underlying mantle. Notwithstanding, viscosity in the asthenosphere is apparently too high to allow mechanical decoupling produced by tidal forces. Here, we propose a model for global scale geodynamics accompanied by numer- ical simulations of the tidal interaction of the Earth with the Moon and the Sun. We provide for the first time a theoretical proof that the tidal drag can produce a westerly motion of the lithosphere, also com- patible with the slowing of the Earth’s rotational spin. Our results suggest a westerly rotation of the litho- sphere with a lower bound of x % ð0:1 0:2Þ /Myr in the presence of a basal effective shear viscosity g % 1016 Pa s, but it may rise to x 〉 1 /Myr with a viscosity of g K 3 1014 Pa s within the Low- Velocity Zone (LVZ) atop the asthenosphere. This faster velocity would be more compatible with the mainstream of plate motion and the global asymmetry at plate boundaries. Based on these computations, we suggest that the super-adiabatic asthenosphere, being vigorously convecting, may further reduce the viscous coupling within the LVZ. Therefore, the combination of solid Earth tides, ultra-low viscosity LVZ and asthenospheric polarized small-scale convection may mechanically satisfy the large-scale decoupling of the lithosphere relative to the underlying mantle. Relative plate motions are explained because of lat- eral viscosity heterogeneities at the base of the lithosphere, which determine variable lithosphere- asthenosphere decoupling and plate interactions, hence plate tectonics.
    Description: Published
    Description: 101623
    Description: 1T. Struttura della Terra
    Description: JCR Journal
    Keywords: Tidal drag ; Lithosphere-asthenosphere interaction ; Plate motions ; Polarized plate tectonics ; Geodynamics ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 21
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    Spatiotemporal Evolution of Ground Subsidence and Extensional Basin Bedrock Organization: An Application of Multitemporal Multi-Satellite SAR Interferometry (2023)
    MDPI
    Details
    Publication Date: 2023-04-06
    Description: Since the early 1990s, the European (ESA) and Italian (ASI) space agencies have managed and distributed a huge amount of satellite-recorded SAR data to the research community and private industries. Moreover, the availability of advanced cloud computing services implementing different multi-temporal SAR interferometry techniques allows the generation of deformation time series from massive SAR images. We exploit the information provided by a large PS dataset to determine the temporal trend of ground deformation and the relative deformation rate with millimetric accuracy to analyze the spatial and temporal distribution of land subsidence induced by water pumping from a deep confined aquifer in the Northern Valle Umbra Basin (Central Italy), exploiting 24 years of Permanent Scatterers—interferometric SAR data archives. The SAR images were acquired between 1992 and 2016 by satellites ERS1/2 and ENVISAT, the Sentinel 1 ESA missions and the COSMO-SkyMed ASI mission. We observed ground velocities and deformation geometries between 1992 and 2016, with displacements of more than 70 cm and velocities of up to 55 mm/yr. The results suggest that the shape and position of the surface ground displacement are controlled by the fault activity hidden under the valley deposits.
    Description: Published
    Description: 105
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Ground deformation ; Remote Sensing ; PS-InSAR ; Subsidence ; Hidden Faults ; 04.04. Geology
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  • 22
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    On the Radiative Impact of Biomass-Burning Aerosols in the Arctic: The August 2017 Case Study (2022)
    MDPI
    Details
    Publication Date: 2023-03-30
    Description: Boreal fires have increased during the last years and are projected to become more intense and frequent as a consequence of climate change. Wildfires produce a wide range of effects on the Arctic climate and ecosystem, and understanding these effects is crucial for predicting the future evolution of the Arctic region. This study focuses on the impact of the long-range transport of biomass-burning aerosol into the atmosphere and the corresponding radiative perturbation in the shortwave frequency range. As a case study, we investigate an intense biomass-burning (BB) event which took place in summer 2017 in Canada and subsequent northeastward transport of gases and particles in the plume leading to exceptionally high values (0.86) of Aerosol Optical Depth (AOD) at 500 nm measured in northwestern Greenland on 21 August 2017. This work characterizes the BB plume measured at the Thule High Arctic Atmospheric Observatory (THAAO; 76.53∘N, 68.74∘W) in August 2017 by assessing the associated shortwave aerosol direct radiative impact over the THAAO and extending this evaluation over the broader region (60∘N–80∘N, 110∘W–0∘E). The radiative transfer simulations with MODTRAN6.0 estimated an aerosol heating rate of up to 0.5 K/day in the upper aerosol layer (8–12 km). The direct aerosol radiative effect (ARE) vertical profile shows a maximum negative value of −45.4 Wm−2 for a 78∘ solar zenith angle above THAAO at 3 km altitude. A cumulative surface ARE of −127.5 TW is estimated to have occurred on 21 August 2017 over a portion (∼3.1×106 km2) of the considered domain (60∘N–80∘N, 110∘W–0∘E). ARE regional mean daily values over the same portion of the domain vary between −65 and −25 Wm−2. Although this is a limited temporal event, this effect can have significant influence on the Arctic radiative budget, especially in the anticipated scenario of increasing wildfires.
    Description: This research was partially funded by the Italian Ministry of University and Research (MIUR) within the framework of OASIS-YOPP—Observations of the Arctic Stratosphere In Support of YOPP (PNRA 2016–2018); CLARA2—CLouds And Radiation in the Arctic and Antarctica (PNRA 2019–2021), and ECAPAC—Effects of changing albedo and precipitation on the Arctic climate (PRA 2021–2023). The work of F. Calì Quaglia and G. Muscari was also partially funded under the INGV environmental project MACMAP—A Multidisciplinary Analysis of Climate change indicators in the Mediterranean And Polar regions (2020–2023). The NCAR FTIR observation program at Thule, Greenland is supported under contract by the National Aeronautics and Space Administration (NASA). The National Center for Atmospheric Research (NCAR) is sponsored by the U.S. National Science Foundation (NSF). The Thule work is also supported by the NSF Office of Polar Programs (OPP).
    Description: Published
    Description: 313
    Description: 5A. Ricerche polari e paleoclima
    Description: JCR Journal
    Keywords: biomass-burning (BB) ; wildfires ; Arctic ; aerosol radiative effect ; 01.01. Atmosphere
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  • 23
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    Arsenic contamination at the Bagnoli Bay seabed (South Italy) via particle tracking numerical modeling: Pollution patterns from stationary climatic forcings (2023)
    Elsevier
    Details
    Publication Date: 2023-03-16
    Description: Almost 140 years of industrial exploitation have severely degraded the environment of Bagnoli Coroglio (BC), the westernmost neighborhood of the city of Naples (Italy). In this peculiar area, however, geogenic processes overlap with the impact of human activities, making it difficult to distinguish between anthropogenic and geogenic pollution sources. This is particularly true for Arsenic, the concentration of which in the marine sediments largely exceeds the tolerable level for human health and the background value for local pyroclastics. After several studies have used traditional tools based on multivariate statistics, this article attempts at tackling the problem via numerical modeling, which provides a deeper insight into the physics that governs the pollution process. Therefore, we use a particle tracking model to assess whether arsenic levels in the seabed can be affected by the influx of thermal water from an artificial channel outfalling at the westernmost part of the coast The climatic forcings that drive the marine circulation are simplified to basic "scenarios", in which wind and waves are stationary in strength and direction. Since the simulation time is much less than the contamination timescale, the comparison between numerical results and measurements is essentially qualitative and concerns the shape of contamination contours. It was found the primary forcing that enables seabed pollution is the tidal circulation, which, moreover, acts continuously in time. Quantitative arguments based on regression analysis suggest the discharge of thermal water explains almost a quarter of the observed pollution, which is consistent with previous research based on multivariate statistics.
    Description: This research results from a collaboration between the University of Naples Federico II and the National Institute of Geophysics and Vulcanology (INGV). The partnership is born in the frame of the multidisciplinary project ABBaCo, funded by the Italian Ministry of Education and Research, which aimed to provide innovative and environmentally friendly solutions for restoring the Bagnoli area.
    Description: Published
    Description: 134955
    Description: 9T. Geochimica dei fluidi applicata allo studio e al monitoraggio di aree sismiche
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: 1TR. Georisorse
    Description: 7SR AMBIENTE – Servizi e ricerca per la società
    Description: 2IT. Laboratori analitici e sperimentali
    Description: JCR Journal
    Keywords: Adsorption ; Arsenic contamination in marine sediments ; Diffusion in coastal waters ; Numerical modeling ; Particle tracking ; Sediments settling ; 03. Hydrosphere ; 03.02. Hydrology ; 03.04. Chemical and biological ; 04.04. Geology ; 04.08. Volcanology ; 05.08. Risk ; 05.06. Methods
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  • 24
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    Impact on air quality of carbon and sulfur volatile compounds emitted from hydrothermal discharges: The case study of Pisciarelli (Campi Flegrei, South Italy) (2023)
    Elsevier
    Details
    Publication Date: 2023-03-15
    Description: Volcanoes are currently to be regarded as natural sources of air pollutants. Climatic and environmental forcing of large volcanic eruptions are well known, although gases emitted through passive degassing during periods of quiescence or hydrothermal activity can also be highly dangerous for the environment and public health. Based on compositional and isotopic data, a survey on the spatial distribution in air of the main volatile compounds of carbon (CO2 and CH4) and sulfur (H2S and SO2) emitted from the fumarolic field of Pisciarelli (Campi Flegrei, Pozzuoli, Naples), a hydrothermal area where degassing activity has visibly increased since 2009, was carried out. The main goals of this study were (i) to evaluate the impact on air quality of these natural manifestations and (ii) inquire into the behavior of the selected chemical species once released in air, and their possible use as tracers to distinguish natural and anthropogenic sources. Keeling plot analysis of CO2 and CH4 isotopes revealed that the hydrothermal area acts as a net source of CO2 in air, whilst CH4 originated mainly from anthropogenic sources. Approaching the urban area, anthropogenic sources of CO2 increased and, at distances greater than 800 m from the Pisciarelli field, they prevailed over the hydrothermal signal. While hydrothermal CO2 simply mixed with that in the atmospheric background, H2S was possibly affected by oxidation processes. Therefore, SO2 measured in the air near the hydrothermal emissions had a secondary origin, i.e. generated by oxidation of hydrothermal H2S. Anthropogenic SO2 was recognized only in the furthest measurement site from Pisciarelli. Finally, in the proximity of a geothermal well, whose drilling was in progress during our field campaign, the H2S concentrations have reached values up to 3 orders of magnitude higher than the urban background, claiming the attention of the local authorities.
    Description: Published
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Air quality; Carbon and sulfur volatile compounds; Carbon isotopes; Hydrothermal systems; Natural sources of pollutants. ; 04.08. Volcanology ; 01.01. Atmosphere
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 25
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    Towards a National-Scale Dataset of Geotechnical and Hydrological Soil Parameters for Shallow Landslide Modeling (2023)
    MDPI
    Details
    Publication Date: 2023-02-27
    Description: One of the main constraints in assessing shallow landslide hazards through physically based models is the need to characterize the geotechnical parameters of the involved materials. Indeed, the quantity and quality of input data are closely related to the reliability of the results of every model used, therefore data acquisition is a critical and time-consuming step in every research activity. In this perspective, we reviewed all official certificates of tests performed through 30 years at the Geotechnics Laboratory of the Earth Science Department (University of Firenze, Firenze, Italy), compiling a dataset in which 380 points are accurately geolocated and provide information about one or more geotechnical parameters used in slope stability modeling. All tests performed in the past (in the framework of previous research programs, agreements of cooperation, or to support didactic activities) were gathered, homogenized, digitalized, and geotagged. The dataset is based on both on-site tests and laboratory tests, it accounts for 40 attributes, among which 13 are descriptive (e.g., lithology or location) and 27 may be of direct interest in slope stability modeling as input parameters. The dataset is made openly available and can be useful for scientists or practitioners committed to landslide modeling.
    Description: Published
    Description: 37
    Description: 4IT. Banche dati
    Description: JCR Journal
    Keywords: Geotechnics ; Hydrology ; Slope stability ; Landslide ; Modeling ; Geotechnical database ; Input data ; Cohesion ; Internal friction angle ; Permeability ; 04.04. Geology ; 03.02. Hydrology ; 05.02. Data dissemination
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 26
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    Comment on ‘Unveiling ductile deformation during fast exhumation of a granitic pluton in a transfer zone’ by Richard Spiess, Antonio Langone, Alfredo Caggianelli, Finlay M. Stuart, Martina Zucchi, Caterina Bianco, Andrea Brogi, & Domenico Liotta (2023)
    Elsevier
    In:  Spiess, R., Langone, A., Caggianelli, A., Stuart, F.M., Zucchi, M., Bianco, C., et al., 2021. Unveiling ductile deformation during fast exhumation of a granitic pluton in a transfer zone. J. Struct. Geol. 147, 104326.
    Details
    Publication Date: 2023-02-27
    Description: In their paper, Spiess et al. (2021) published structural, geochronological, and EBSD data on one of the monzogranite apophyses (Capo Bianco) of the buried Porto Azzurro Pluton (island of Elba, Northern Apennines, Italy), a pluton emplaced in the upper crust (P 〈 0.2 GPa; e.g. Papeschi et al., 2019). The authors published a new U/Pb age of 6.4 ± 0.4 Ma, associated with the thermal peak, and a U-Th/He apatite age of 5.0 ± 0.6 Ma, indicating cooling below 60 ◦C. Spiess et al. (2021) use these ages to model the exhumation of the pluton controlled, in their model, by the Zuccale Fault, a subhorizontal fault with 6 km of eastward displacement (ZF; Keller & Coward, 1996). Their structural dataset from the macro to the microscale and EBSD analyses relies on a small section (about 100 m wide) in the NE part of the Calamita Peninsula. Based on their documentation of (1) vertical dykes in the monzogranite, (2) vertical to low-angle top-to-the-E extensional faults, and (3) later NWstriking oblique faults, they interpret the Porto Azzurro Pluton as emplaced in an extensional to transcurrent tectonic setting, extrapolating their findings to the entire Eastern Elba.
    Description: Published
    Description: 104499
    Description: 1T. Struttura della Terra
    Description: JCR Journal
    Keywords: Upper crustal deformation ; Magmatic intrusion ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 27
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    A Minoan and a Neolithic tsunami recorded in coastal sediments of Ios Island, Aegean Sea, Greece (2023)
    Elsevier
    Details
    Publication Date: 2023-02-01
    Description: In this work, we document two distinct tsunami deposits on the coasts of Ios Island, Aegean Sea, Greece. The younger tsunami deposit, dated 1831–1368 cal. BCE, includes both marine sediments and pumices from the ∼1600 BCE Minoan eruption of Santorini volcano. This is the first evidence of the Minoan tsunami in the Cycladic Islands North of Santorini. Tsunami waves inundated the Manganari coastal plain, southern coast of Ios, over a distance 〉200 m (〉2 m a.s.l.). The second tsunami deposit reworks pumice from the 22 ka Cape Riva eruption mixed with marine sediment. We assume a Neolithic age for this major tsunami, with a wave runup 〉13 m a.s.l. on the southern and eastern coasts of Ios. The source of this tsunami - volcanic eruption, landslide, or earthquake - remains unknown. Additionally, we provide the first on-land evidence of Cape Riva deposits outside Santorini, thus questioning previous estimates on the magnitude of this eruption.
    Description: Published
    Description: 106908
    Description: 6T. Studi di pericolosità sismica e da maremoto
    Description: JCR Journal
    Keywords: tsunami deposits ; Aegean Sea ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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