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  • Chemistry  (50,852)
  • ddc:330
  • 2020-2023  (46)
  • 1990-1994  (50,872)
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  • 1
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    Karlsruhe : Müller | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2018-11-19
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 2
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    The Hague : Europ. Environmental Bureau | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 3
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    Bonn : Economica-Verl. | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2014-08-15
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 4
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    Hamburg : Dt. Übersee-Inst. | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 5
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 6
    Publication Date: 2014-08-15
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 7
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2014-08-15
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 8
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2018-04-30
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 9
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    Berlin : Duncker & Humblot | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 10
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2014-08-15
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 11
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2014-08-15
    Keywords: ddc:330
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    Language: English
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  • 12
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    Marburg : Metropolis-Verl. | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 13
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 14
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 15
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 16
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    Ulm : Univ.-Verl. Ulm | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 17
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2014-08-15
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 18
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    Heidelberg : Physica-Verl. | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 19
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    Wien : Ibera-Verl. | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 20
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 21
    Publication Date: 2018-04-30
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 22
    Publication Date: 2018-04-30
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 23
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    Essen : Rheinisch-Westfälisches Inst. für Wirtschaftsforschung | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: report , doc-type:report
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  • 24
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    Bremen : Bremer Tabak-Collegium | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2014-08-15
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 25
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2014-08-15
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 26
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2014-08-15
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 27
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 28
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    Wuppertal : Inst. für Ökologische Wirtschaftsforschung | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2018-11-19
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 29
    Publication Date: 2022-03-07
    Description: Industrial demand response can play an important part in balancing the intermittent production from a growing share of renewable energies in electricity markets. This paper analyses the role of aggregators - intermediaries between participants and power markets - in facilitating industrial demand response. Based on the results from semi-structured interviews with German demand response aggregators, as well as a wider stakeholder online survey, we examine the role of aggregators in overcoming barriers to industrial demand response. We find that a central role for aggregators is to raise awareness for the potentials of demand response, as well as to support implementation by engaging key actors in industrial companies. Moreover, we develop a taxonomy that helps analyse how the different functional roles of aggregators create economic value. We find that there is considerable heterogeneity in the kind of services that aggregators offer, many of which do create significant economic value. However, some of the functional roles that aggregators currently fill may become obsolete once market barriers to demand response are reduced or knowledge on demand response becomes more diffused.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 30
    Publication Date: 2022-04-25
    Description: In den vergangenen zwei Jahren hat sich die Welt verändert und vermehrt beherrschen Krisen das Bild. Jahrzehntelange Gewissheiten gelten nicht mehr, Risiken und Unsicherheiten nehmen zu, die Herausforderungen werden immer komplexer und erfordern gleichzeitig immer schnelleres und konsequenteres Handeln.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 31
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    Berlin : Birkhäuser | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2018-11-19
    Description: Wir haben zwanzig Jahre Umweltpolitik betrieben, haben nach Nanogrammen von Giften gejagt und Schadstoffemissionen reduziert. Vielleicht ist die Umwelt dadurch etwas sauberer geworden, aber dennoch drohen unserer Ökosphäre immer größere Katastrophen. Was machen wir falsch? Jeder Verbrauch, sei es von Rohstoffen, sei es von Energie, zieht unweigerlich ein Stück veränderte Umwelt nach sich. Und wir verbrauchen Megatonnen. Friedrich Schmidt-Bleek hat ein ökologisches Maß entwickelt, das erstmals den Verbrauch umfassend bestimmen kann. Dieses Maß - MIPS für Material Intensität Pro Serviceeinheit - ermöglicht es, die Umweltbelastung von Prozessen, Produkten und Leistungen zu ermitteln und miteinander zu vergleichen. Wollen wir dauerhaft unsere Ökosphäre retten, müssen wir in recht kurzer Zeit dass Ziel "Faktor 10" erreichen: also Reduzierung allen Verbrauchs auf den zehnten Teil - bei gleichbleibendem Wohlstand. Der Autor zeigt praxisnahe Wege, an dieses Ziel zu gelangen. Wir müssen nicht einfach den Gürtel enger schnallen, sondern wir müssen lernen, mit den zur Verfügung stehenden Ressourcen rationaler und effektiver umzugehen. Es ist durchaus üblich, Wohlstand zu schaffen - für alle Menschen.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 32
    Publication Date: 2018-11-19
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: doctoralthesis , doc-type:doctoralThesis
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  • 33
    Publication Date: 2022-02-18
    Description: The study sheds light on the background of the prevention of plastic waste from packaging and disposable products by explaining the need for action, the environmental impacts and risks to human health. Experiences of the members of the PREVENT Waste Alliance and their partners in the prevention of plastic waste by multi-actor partnerships are presented by means of 17 best practice examples. Finally, the study gives recommendations for the reduction of plastic waste and the further work of the PREVENT Waste Alliance. These include success factors for waste prevention, necessary next steps and conclusions regarding the necessary political framework conditions.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 34
    Publication Date: 2022-02-18
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 35
    Publication Date: 2022-02-18
    Description: Die GLS Bank finanziert gezielt nachhaltige Projekte und Unternehmen in den Bereichen erneuerbare Energien, nachhaltige Wirtschaft, Ernährung, Wohnen, Bildung & Kultur, Soziales & Gesundheit. Eine zentrale Herausforderung ist es, die Nachhaltigkeitswirkung der Finanz- und Anlagestrategie robust zu quantifizieren und transparent darzustellen. Die GLS Bank hat sich zum Ziel gesetzt, die hierfür notwendigen Methoden und Daten zur Bewertung der Nachhaltigkeitswirkungen ihres Finanz- und Anlagenportfolios schrittweise weiterzuentwickeln, um eine richtungssichere Portfoliosteuerung und Kundenbetreuung zu unterstützen. Ziel des Projektes ist zunächst, das Emissionsgeschehen der finanzierten Wertschöpfungskette abzubilden (Scope 3), aber auch die eingesparten Emissionen als einen Beitrag zum Klimaschutz zu bewerten (Scope 4). Es werden die Scope 3 Emissionen der GLS Bank in den folgenden Finanz- und Anlagebereichen für das Berichtsjahr 2019 bilanziert: 1. Aktien- und Klimafonds; 2. Kredite; 3. Unternehmensbeteiligung. Scope 4 Emissionen werden in Form vermiedener Emissionen (Carbon Handprint) dabei ausschließlich für Bereiche bilanziert, in denen THG-Reduktionspotentiale richtungssicher abgeschätzt werden können. Im vorliegenden Bericht wird der Untersuchungsrahmen, die vom Wuppertal Institut entwickelte Methodik sowie Lösungsstrategien für die Überbrückung geringer Datenqualität/-verfügbarkeit beschrieben. Die Robustheit der Ergebnisse wird durch Prüfungsmethoden reflektiert und dem Leser somit eine Interpretationsunterstützung gegeben. In einem Ausblick werden Weiterentwicklungsbedarfe und -möglichkeiten skizziert, um schrittweise eine zunehmend robuste und wissenschaftliche fundierte Methodik und Datengrundlage zur Bewertung der Klimawirkung sowie weiterer Nachhaltigkeitswirkungen des Finanz- und Anlageportfolios der GLS Bank in Zusammenarbeit mit relevanten Stakeholdern zu etablieren.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 36
    Publication Date: 2022-02-18
    Description: Damit sich die weltweit zunehmend ambitionierten Klimaschutzziele erreichen lassen, müssen auch im Industriesektor weitgehende Emissionsreduktionen innerhalb weniger Jahrzehnte realisiert werden. Expertinnen und Experten sind sich einig, dass dies nicht ohne den Umstieg von fossilen auf erneuerbare Energieträger und Rohmaterialien - sogenannte Feedstocks - umsetzbar ist. Im Zuge der verstärkten Nutzung dieser grünen Energieträger ist denkbar, dass sich deren Verfügbarkeit und Kosten zu immer wichtigeren Standortfaktoren für die Produktion industrieller Güter entwickeln werden. Dies könnte dazu führen, dass zukünftig Standorte mit kostengünstiger Verfügbarkeit von erneuerbaren Energien attraktiver gegenüber anderen Standorten werden und es dann zu Standortverlagerungen kommt - insbesondere im Bereich der energieintensiven Industrie. In dem vorliegenden Artikel greifen die Autoren diese möglichen Verlagerungen industrieller Produktion auf. In diesem Zusammenhang führen sie auch den Begriff "Renewables Pull" ein. Die in bestimmten Regionen der Welt kostengünstig und in großen Mengen verfügbaren erneuerbaren Energien könnten nach Ansicht der Autoren künftig eine Sogwirkung auslösen und bestimmte Teile der industriellen Produktion anziehen - auch Pull-Effekt genannt.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 37
    Publication Date: 2022-02-18
    Description: The transition from today's "take, make, waste" economic paradigm to a circular economy requires a joint effort from actors on all levels: governments, business, and civil society. While companies are among the drivers of the circular transformation, they find it hard to achieve a circular economy on their own. Hence, cross-industry collaboration is one of the imperatives for scaling a circular economy. Against this background, econsense, together with Accenture and the Wuppertal Institute, launched its study "Germany's Transition to a Circular Economy - How to Unlock the Potential of Cross-Industry Collaboration". Based on a survey and expert interviews within the econsense community, the study finds that companies are yet to unlock the full potential of cross-industry collaboration. While two thirds of analysed industry collaborations have a high potential for scaling the circular economy, only 43 per cent of those already show a high degree of interaction. The study provides concrete guidance for companies to get started with circularity and identify the right partners for cross-industry collaboration. Specifically, the report recommends companies: 1) Understand what circularity is about and map it on their own operations and processes. 2) Understand the different circular business models and identify the ones relevant to each business. 3) Discover areas where collaboration can help to create the needed foundation and to execute circular actions.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 38
    Publication Date: 2022-02-18
    Description: Digitalisation is taking place at a fast pace in all European countries and it is transforming the economies, societies, communication, jobs and the necessary skills for the workplace and everyday life. The Covid-19 pandemic is also accelerating digitalisation at many levels. To address the great challenges resulting from this, the European Commission has launched the Green Deal, a long-term transformation strategy towards an innovative and sustainable society. Three important initiatives under the Green Deal are the New Circular Economy Action Plan, the Biodiversity Strategy for 2030 and the Zero Pollution Action Plan. The various strategies and action plans draw up a large portfolio of measures, instruments and milestones that are always linked to digital technologies. Ideally, these are eco-innovative and sustainable and contribute to improving living conditions in Europe. The EIO Biennial Report 2020, which looks at a different topic every two years, considers digitalisation a major opportunity to accelerate the transition to a circular Europe. In the current report, the authors provide an overview of eco-innovation trends, illustrated by digital technology and policy practices that can further drive the circular economy.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 39
    Publication Date: 2022-02-18
    Description: Auf dem Weg zu einer ressourceneffizienten Gesellschaft bedarf es richtiger Rahmenbedingungen, Informationen und Handlungsalternativen. Eine Möglichkeit, diese Voraussetzungen zu schaffen, ist ein kommunales Zero-Waste-Konzept. Zero Waste lässt sich übersetzen mit "Null Abfall, null Verschwendung" und verfolgt das Ziel, möglichst wenig Abfall zu produzieren sowie effizient und sparsam mit Ressourcen umzugehen. Ein solches Konzept wie in Kiel ist die Basis für eine Zertifizierung als Zero Waste City, eine Auszeichnung, die der europäische Verein Zero Waste Europe vergibt. 2007 wurde die italienische Gemeinde Capannori zur ersten Zero Waste City in Europa erklärt, seitdem sind knapp 400 europäische Gemeinden dieser Bewegung gefolgt.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 40
    Publication Date: 2022-02-18
    Description: Die beiden mächtigsten Energiekonzerne in Deutschland fusionieren wechselseitig ihre Geschäftsfelder. Das Ergebnis wird eine bisher nie dagewesene Marktbeherrschung im Energiesektor darstellen. Die beiden Autoren beleuchten den Deal und kritisieren die Untätigkeit sämtlicher Aufsichtsbehörden.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 41
    Publication Date: 2022-02-18
    Description: Prepaid-Stromzähler sind in Deutschland noch selten, bieten jedoch zukünftig einen interessanten Markt. Vor allem kleinere Anbieter, aber auch erste Regionalversorger kombinieren die Megatrends Digitalisierung und Energiewende und kreieren daraus neue Dienstleistungen. Zusammen mit IT-Firmen entwickeln sie daraus neue Geschäftsideen, die auch hinsichtlich sozialer Aspekte hohen Anforderungen genügen. Der Rollout von Smart Metering-Lösungen eröffnet zukünftig noch größere Chancen, durch Echtzeit-Datenerfassung den Energieverbrauch und damit auch Einsparpotenziale transparent zu machen. Hochaufgelöste Daten ermöglichen innovative Dienstleistungen und bringen die Kundenbeziehung auf eine neue Ebene.
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  • 42
    Publication Date: 2022-02-18
    Description: Öffentliche Mittel für die Unterstützung von Unternehmen sollten bestenfalls so eingesetzt werden, dass sie eine möglichst große, nachhaltige Wirkung haben und mit einem gesellschaftlichen Nutzen verbunden sind. Das kann unmittelbar erfolgen, in dem die konkrete Förderung an bestimmte Vorgaben gebunden wird, wie etwa den Ausbau von zukunftsfähigen Infrastrukturen. Es besteht jedoch auch die Möglichkeit, die Risikoabsicherung von Unternehmen - beispielsweise über Bürgschaften oder andere geeignete Finanzierungskonditionen - an der Nachhaltigkeitsperformance der Unternehmen auszurichten. Der vorliegende vierstufige Leitfaden, den der WWF Deutschland und das Wuppertal Institut entwickelt haben, dient als Grundlage für die zielorientiertere Vergabe von Mitteln und deren praktische Umsetzung. Er baut auf der von der Europäischen Union entwickelten "Taxonomie" für nachhaltige Investitionen auf. Darin enthalten sind Grenzwerte, welche die Nachhaltigkeitsperformance wirtschaftlicher Aktivitäten definieren. Auf diese Weise lässt sich filtern, ob ein wirtschaftliches Vorhaben zukunftsfähig ist. Hierbei unterstützt der "Entscheidungsbaum" des Leitfadens die Anwendung der EU-Taxonomie als Regelwerk.
    Keywords: ddc:330
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  • 43
    Publication Date: 2022-02-18
    Description: Mehr als sechs Millionen Tonnen Kunststoffabfälle fallen in Deutschland jährlich an, nur etwas weniger als die Hälfte kann werk- und rohstofflich genutzt werden, der Rest wird verbrannt. Gerade gemischte Kunststoffarten erschweren das Recycling. Hier bietet sich das chemische Recycling (Pyrolyse) an. Bei diesem Verfahren werden die Stoffe durch hohe Temperaturen zersetzt und in kleinere Moleküle aufgespalten. Diese lassen sich im Sinne der Kreislaufwirtschaft in neue Kunststoffe oder chemische Grundstoffe überführen. Die Schätzungen gehen von bis zu zwei Millionen Tonnen Kunststoffabfall jährlich aus, der auf diese Weise wiederverwendet werden könnte. Das vorliegende Diskussionspapier zeigt, dass Pyrolyse von gemischten Kunststoffabfällen die chemische Industrie sowie die Abfallwirtschaft klimafreundlicher gestalten kann. Im Papier geht das Autorenteam auf die Potenziale und Entwicklungsperspektiven für Nordrhein-Westfalen ein mit dem Ziel, wissenschaftliche Grundlagen für Investitionsentscheidungen und Projektentwicklung im Sinne der Kreislaufwirtschaft zu schaffen.
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  • 44
    Publication Date: 2022-02-04
    Keywords: ddc:330
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  • 45
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    Publication Date: 2022-02-04
    Keywords: ddc:330
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  • 46
    Publication Date: 2022-02-18
    Description: Diese Kurzstudie ist Teil des Verbundvorhabens "Circular Economy als Innovationsmotor für eine klimaneutrale und ressourceneffiziente Wirtschaft (CEWI)" der Stiftung 2°, dem WWF Deutschland und dem Wuppertal Institut und hat zum Ziel, die Potenziale des Gebäudesektors und der dazugehörigen Wertschöpfung im Hinblick auf die Umsetzung von zirkulären Ansätzen zu analysieren und den Beitrag zur Ressourceneinsparung und dem Klimaschutz zu bewerten. Das Ergebnis dieser Kurzstudie leitet sich aus einem intensiven Bewertungsprozess verschiedener Maßnahmen-Cluster ab und besteht aus sechs Handlungsfeldern, die ein Potenzial für den Ausbau von Klimaneutralität und Ressourceneffizienz im Gebäudesektor aufweisen. Diese Handlungsfelder bilden die Grundlage für den weiteren Projektverlauf von CEWI, in dem Industrieakteure in Workshops gemeinsam Pilotprojekte modellieren werden.
    Keywords: ddc:330
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  • 47
    Publication Date: 2022-02-18
    Description: Diese Kurzstudie ist Teil des Verbundvorhabens "Circular Economy als Innovationsmotor für eine klimaneutrale und ressourceneffiziente Wirtschaft (CEWI)" der Stiftung 2°, dem WWF Deutschland und dem Wuppertal Institut und hat zum Ziel, die Potenziale des Automobilsektors und der dazugehörigen Wertschöpfung im Hinblick auf die Umsetzung von zirkulären Ansätzen zu analysieren und den Beitrag zur Ressourceneinsparung und dem Klimaschutz zu bewerten. Das Ergebnis dieser Kurzstudie leitet sich aus einem intensiven Bewertungsprozess verschiedener Maßnahmen-Cluster ab und besteht aus sechs Handlungsfeldern, die ein Potenzial für den Ausbau von Klimaneutralität und Ressourceneffizienz im Automobilsektor aufweisen. Diese Handlungsfelder bilden die Grundlage für den weiteren Projektverlauf von CEWI, in dem Akteure aus der Praxis in Workshops gemeinsam Pilotprojekte modellieren werden.
    Keywords: ddc:330
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  • 48
    Publication Date: 2022-02-18
    Description: Die Wirtschaftsförderung Region Stuttgart GmbH (WRS) unterstützt die Transformation der Region Stuttgart in Richtung Nachhaltigkeit und sieht die Bioökonomie als eine wichtige Strategie zu diesem Zweck. Die WRS hat das Wuppertal Institut mit dieser Kurzstudie mit dem Fokus auf die industrielle Bioökonomie beauftragt, um eine Informationsgrundlage für die Spezifikation weiterer Aktivitäten der WRS im Kontext der Bioökonomie zu schaffen. Die Studie gibt einen Überblick über definitorische Ansätze und Diskurslinien der Bioökonomie. Sie fasst Einschätzungen des deutschen Bioökonomierates zu Marktpotenzialen der Bioökonomie in verschiedenen Branchen zusammen, die u.a. für Automobil, Biotechnologie und IKT als gut eingeschätzt werden. Anschließend umreißt die Studie die Innovationsansätze Biomimikry und Biointelligenz. Für den Ansatz Biointelligenz zur biologischen Transformation der industriellen Wertschöpfung werden die in Studien von Dritten identifizierten Marktpotenziale der Biointelligenz zusammengefasst, u.a. in den Bereichen Unterstützungssysteme, Produktionssysteme/-technologien und Baumaterialien. Darüber hinaus stellt die Studie Schnittstellen relevanter Landesstrategien in Baden-Württemberg zu Bioökonomiethemen dar, die synergetisch genutzt werden könnten. Ergänzend gibt die Studie einen Überblick über die Akteurslandschaft in Baden-Württemberg. Der Überblick basiert insbesondere auf dem Bioökonomie Kompetenzatlas wissenschaftlicher Akteure, der von der Landeskoordinierungsstelle an der Universität Hohenheim herausgegeben wird, sowie einer Akteursanalyse aus dem Projekt "Bioökonomie in Baden-Württemberg", das am KIT durch das ITAS durchgeführt wurde und durch die BIOPRO Baden-Württemberg GmbH unterstützt wurde. Auf Basis dieser Informationssammlung entwirft die Studie weiterführende Fragen in Bezug auf mögliche weitere Aktivitäten der WRS im Kontext der Bioökonomie, u.a. die mögliche Nutzung von Innovationsansätzen aus dem Bereich der Living Lab und Reallaborforschung.
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  • 49
    Publication Date: 2022-02-23
    Keywords: ddc:330
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  • 50
    Publication Date: 2022-02-23
    Keywords: ddc:330
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    Language: German
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  • 51
    Publication Date: 2022-02-23
    Description: Two thirds of today's world trade is based on global value chains and supply networks. Purely regional supply chains have become less important in recent decades. The effects of these globalised structures are manifold. On the one hand, they promote employment and generate prosperity. On the other hand, they are beset by extreme social, ecological and economic imbalances. The COVID-19 pandemic has demonstrated the fragility of existing supply chain systems. The lockdown continues to disrupt complex supply chains and many problems of existing production and consumption continue to worsen. COVID-19 is one example of the crises that can shake globally networked supply chains in the short term. Other crises, such as climate change, develop more insidiously and are less immediately recognisable. Different as they are, such crises have one thing in common: they highlight the vulnerability of global social and economic structures and illustrate the impact of global trade on the regions and people of the world. This is precisely where global sustainability strategy comes in - it aims to fundamentally reduce differences and inequalities in opportunities and quality of life. The COVID-19 pandemic has forced the entire world into upheaval, creating an opportunity to make sustainability a central political resilience strategy. In the wake of the Corona pandemic, the discussion about resilient communities has flared up. In order to guarantee supply in the face of such crises, these should be more strongly regional and circular in their economic approach and global and sustainable in their perspective. The aim should be sustainable, transparent, non-exploitative supply chains that guarantee the security of supply to cover basic needs and public services despite sudden changes and crises. This discussion paper draws a future scenario of globally cooperative, circular regional economies that fundamentally reduce global inequalities in opportunities and quality of life, while at the same time permanently preserving the natural foundations of life.
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  • 52
    Publication Date: 2022-02-23
    Description: Seitdem Einweg-Plastikartikel wie Kunststofftüten und Strohhalme verboten wurden, sind Straßen und Strände sauberer geworden. Zudem wurde auch die öffentliche Diskussion über nachhaltigen Konsum intensiviert. Die Gesamtmenge an Kunststoff-Abfällen ließ sich mit "Plastikverboten" hingegen nicht signifikant reduzieren. Zu diesem Ergebnis kommt der vorliegende Polyproblem-Report der gemeinnützigen Röchling Stiftung und des Beratungshauses Wider Sense in Zusammenarbeit mit dem Wuppertal Institut. Die Autor*innen haben die Wirkung staatlicher Verbote von Einweg-Plastikprodukten unter die Lupe genommen und die Erfahrungen aus Deutschland, Kenia und Kalifornien analysiert.
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  • 53
    Publication Date: 2022-01-26
    Description: Within the Shaping Digitalisation project, we aim to highlight and discuss the opportunities that digitalisation can bring to Germany. In particular, we are discussing three stand-out areas where action is most needed to achieve ecological transformation: mobility, the circular economy, and agriculture and food. This report addresses the second area in need of action. Up until now, discussions on the circular economy have been limited to recycling and the re-use of materials. We must expand the scope of these discussions to include new, resource-efficient business models and the comprehensive transformation of value chains and industrial structures. Our analysis has found that digitalisation is indispensable for this transformation if used properly. We hope this report will provide the impetus needed to kick-start a climate- and resource-friendly industrial transformation in Germany. Here, we have incorporated the findings of our interdisciplinary workshop on "Shaping the Digital-Ecological Industrial Transformation - Business Models and Political Framework Conditions for Climate and Resource Protection" that was attended by experts from international research institutes, civil organizations, public authorities, and private companies.
    Keywords: ddc:330
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  • 54
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2022-11-09
    Description: Die Europäische Union (EU) hat erkannt, dass das Ziel der Klimaneutralität bis 2050 ein zentraler Innovations- und Wachstumsmotor für Industrie und Wirtschaft in der EU sein kann. Neben großen Chancen stellt dies die europäische Wirtschaft und überwiegend die besonders emissionsintensiven sowie im international starkem Wettbewerb stehenden Grundstoffindustrien auch vor erhebliche Herausforderungen. Eine integrierte Klima- und Industriestrategie ist für den Klimaschutz von zentraler Bedeutung, da auf die Produktion von Stahl, Zement, Grundstoffchemikalien, Glas, Papier und anderen Materialien in der EU und weltweit rund 20 Prozent der gesamten Treibhausgasemissionen entfallen. Auch in einer treibhausgasneutralen Zukunft kann auf diese Materialien nicht verzichten werden. Zugleich ist die emissionsfreie Herstellung der Materialien technologisch sowie mit Blick auf die dafür erforderlichen Infrastrukturen besonders herausfordernd. Dies gilt vor allem für die Frage woher die hohen benötigten Mengen an grüner Energie - insbesondere Strom und Wasserstoff - zu wettbewerbsfähigen Preisen kommen sollen. Analysen zeigen, dass trotz erheblicher Kosten bei der Prozessumstellung die Kosten der Transformation der Grundstoffindustrie für die Gesellschaft insgesamt tragbar sind. Denn bezogen auf die Endprodukte betragen die Mehrkosten meist nur wenige Prozentpunkte; die Preise von Rohstahl oder Zement dagegen würden sich zwischen einem Drittel und 100 Prozent verteuern. Da fast alle Grundstoffhersteller in starker Weltmarktkonkurrenz stehen, können sie die Investitionen in eine klimaneutrale Produktion und die benötigten Energieinfrastrukturen aber nicht ohne Unterstützung tragen. Das vorliegende Papier skizziert ein integriertes Klima-Industriepolitikpaket, das der EU ermöglichen kann, die bestehende technologische Führung in vielen dieser Industrien zielgerichtet zum Aufbau einer treibhausgasneutralen Grundstoffindustrie zu nutzen.
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  • 55
    Publication Date: 2022-10-10
    Description: The introduction of a Digital Product Passport (DPP) is an opportunity to create a system that can store and share all relevant information throughout a product's life cycle. This would provide industry stakeholders, businesses, public authorities and consumers with a better understanding of the materials used in the product as well as their embodied environmental impact. With the COVID-19 pandemic, the Russian invasion of Ukraine and the cost-of-living crisis, now is a critical moment to transform our economic and business models, while also addressing the huge scale of material emissions. DPPs can be a pivotal policy instrument in this goal. Furthermore, DPPs can accelerate the twin green and digital transitions as part of EU efforts to deliver positive climate action and sustainable economies. In 2020, the European Commission (EC) adopted a new Circular Economy Action Plan (CEAP), which emphasised the need for circular economy initiatives to consider the entire life cycle of products, from the production of basic materials to end-of-life disposal. The Circular Economy Package published in March 2022 includes a proposal for an Ecodesign for Sustainable Products Regulation (ESPR), which builds upon the Ecodesign Directive that covers energy-related products. A DPP will form a key regulatory element of the ESPR by enhancing the traceability of products and their components. This will provide consumers and manufacturers with the information needed to make better informed choices by taking their environmental impact into consideration. As discussed in the report, there is widespread agreement amongst business leaders that a well-designed DPP could have both short- and longer-term benefits, improving access to reliable and comparable product sustainability information for businesses, consumers and policymakers. A well-designed DPP can unify information, making it more readily accessible to all actors in the supply chain. This will support businesses to ensure an effective transformation towards a decarbonised industry. It could also create incentives for companies to make their products more sustainable, as improving access to reliable and consistent information across supply chains will make it easier for customers to make comparisons.
    Keywords: ddc:330
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  • 56
    Publication Date: 2022-10-07
    Keywords: ddc:330
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  • 57
    Publication Date: 2022-10-24
    Description: Die Dekarbonisierung der Mietwohnungsbestände ist zwingende Voraussetzung für die Einhaltung deutscher Klimaschutzziele. Hierzu ist eine schnelle und deutliche Verbesserung der Energieeffizienz unabdinglich. Aber: funktioniert der Markt für Energieeffizienz bei Mietwohnungen? Eine empirische Untersuchung auf dem Wuppertaler Mietwohnungsmarkt gibt Antworten darauf. Um die Sanierungsrate signifikant zu steigern, etwa durch eine höhere Zahlungsbereitschaft für Energieeffizienz, braucht es sowohl für Vermieter als auch für Mieter verbesserte Rahmenbedingungen.
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  • 58
    Publication Date: 2022-10-24
    Description: A main goal of this study - which also functions as deliverable 210078-D07 of the Circular Economy Beacons (CEB) project - is to evaluate currently available frameworks that measure and operationalise Circular Economy (CE), with a particular focus on the urban context. The regional focus lies on the Western Balkan region, which is at the centre of the project. Such "Urban Circularity Hotspot Frameworks" (UCHF) aim at providing decision support for policy makers, companies, citizens etc. regarding the transition to CE within cities. Based on the analysis of different frameworks, suggestions are derived regarding UCHF suitable for the specific characteristics of Western Balkan municipalities, i.e. a Circular Economy Beacons Urban Circularity Hotspot Framework (CEB-UCHF) ready for short-term implementation.
    Keywords: ddc:330
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  • 59
    Publication Date: 2022-10-24
    Description: Circular economy seems a vital enabler for sustainable use of natural resources which is also important for achieving the 2030 agenda for sustainable development goals. Therefore, a special session addressing issues of "sustainable solutions and remarkable practices in circular economy focusing materials downstream" was held at the 16th International Conference on Waste Management and Technology, where researchers and attendees worldwide were convened to share their experiences and visions. Presentations focusing on many key points such as new strategies, innovative technologies, management methods, and practical cases were discussed during the session. Accordingly, this article compiled all these distinctive presentations and gave insights into the pathway of circular economy towards the sustainable development goals. We summarized that the transition to circular economy can keep the value of resources and products at a high level and minimize waste production; the focus of governmental policies and plans with the involvement of public-private-partnership on 3Rs (reduce, reuse, and recycle) helps to improve the use of natural resources and take a step ahead to approach or achieve the sustainability.
    Keywords: ddc:330
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  • 60
    Publication Date: 2022-10-24
    Description: In Germany, the number of renewable energy prosumers has increased rapidly since 2000. However, the development of prosumers has faced and will continue to face various economic, social, and technological challenges, which have triggered the emergence of a number of innovative business models (BM). This paper enriches the empirical basis for prosumer-oriented BMs by investigating two BM innovations in Germany (P2P electricity trading and aggregation of small-size prosumers) drawing on business model and socio-technical transition theories. A mix of qualitative data collection methods, including document analysis and semi-structured expert interviews, was applied. We found that while both BMs can potentially address the challenges associated with renewable energy prosumer development in Germany, small-scale prosumers’ participation in both BMs has been limited so far. We identified various internal and external drivers and barriers for scaling up these BMs for prosumer development in Germany. Despite these barriers, both aggregation and centralized P2P targeting prosumers may potentially be also taken up by incumbent market actors such as utilities. Decentralized P2P on the other hand still faces significant internal and external barriers for upscaling. Based on the analysis, the paper provides policy recommendations with respect to the identified drivers and barriers. From a theoretical perspective, our findings provide further evidence to challenge the dichotomous understanding of niche actors and incumbents, the latter of which are often theorized to be resistant to radical innovations.
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  • 61
    Publication Date: 2022-11-10
    Description: Die Emscher-Lippe Region ist seit vielen Jahren von einer intensiven wirtschaftlichen Transformation geprägt. Die fortschreitende De-Industrialisierung bzw. die Neuorientierung der Industrie nach dem Wegfall der Kohle- und Stahlindustrie stellt regionale Entscheidungsträger vor große Herausforderungen, wenn es darum geht, der hohen Arbeitslosenquote zu begegnen, Beschäftigungsquoten zu sichern, mit der prekären Finanzsituation in den kommunalen Haushalten umzugehen und den Wirtschaftsstandort zu stabilisieren und neu aufzustellen. Der Strukturwandel der Region ist mit Schließung der letzten Steinkohle-Zeche Ende 2018 nicht abgeschlossen, sondern geht mit dem Kohleausstieg im Energiesektor in eine zweite Phase. Dies sollte auch als Chance verstanden werden, den Wirtschaftsstandort Emscher-Lippe mit seinen energiereichen Industrien innovativ neu zu gestalten und die Region sowohl energetisch, als auch stofflich von der Nutzung fossiler Träger abzukoppeln. Eine wichtige Säule der regionalen Wirtschaftsförderung besteht darin, strategische Netzwerke und regionale Wertschöpfungsketten zu stärken, um die in der Region ansässigen (mittelständischen) Unternehmen zu unterstützen und den Strukturwandel innerhalb der dominierenden Industrien aus den Bereichen Energieerzeugung und chemischer Industrie zu begleiten. Die vorliegende Studie bereitet auf, welche Bedeutung die Wasserstoffwirtschaft in der Emscher-Lippe Region in diesem Zusammenhang derzeit spielt und zukünftig spielen könnte.
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  • 62
    Publication Date: 2022-11-10
    Description: Immer mehr Unternehmen verkünden, klimaneutral sein zu wollen und zahlreiche Firmen bieten bereits klimaneutrale Produkte oder Dienstleistungen an: Von der klimaneutralen Paketzustellung bis zur Flugreise. Doch was bedeuten die Neutralitätsziele der Unternehmen genau? Ist das gesetzte Ziel ambitioniert? Und welche Rolle spielt Offsetting, also der Ankauf von Klimaschutzzertifikaten und deren Anrechnung auf das eigene Klimaschutzziel? Die hinter den verkündeten Zielen stehenden Ansätze sind häufig nur schwer nachvollziehbar. Vor diesem Hintergrund gibt der vorliegende Zukunftsimpuls zehn Empfehlungen für die Festlegung und Umsetzung von Neutralitätszielen. Die Autorinnen und Autoren sprechen sich dabei unter anderem für die Nutzung einer robusten Datenbasis als Grundlage für Neutralitätsziele aus, betonen die Bedeutung einer transparenten Kommunikation und zeigen auf, welche Rolle Offsetting spielen sollte. So sollten angekaufte Klimaschutz-Zertifikate einen möglichst begrenzten Beitrag zur Zielerfüllung leisen und ausschließlich zum Ausgleich von Emissionen genutzt werden, die nicht reduziert oder vermieden werden können. Insgesamt sollten Neutralitätsziele nicht zum alleinigen Kriterium für ambitionierten Klimaschutz von Unternehmen gemacht werden, sie stellen vielmehr ein Baustein einer weitaus umfassenderen unternehmerischen Klimaschutzstrategie dar.
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  • 63
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26299 | 23782 | 2019-03-27 06:00:01 | 26299 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Chemistry ; Fisheries ; Malaysia ; Pesticides ; Biological sampling ; Fish ; Fishery products ; Biochemical analysis ; Lethal limits
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26300 | 23782 | 2019-03-27 05:58:36 | 26300 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Aquaculture ; Chemistry ; Fisheries ; Myanmar ; Pesticides ; Biological sampling ; Fish ; Fishery products ; Lethal limits
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
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    Format: 75-83
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26303 | 23782 | 2019-03-27 05:51:15 | 26303 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Chemistry ; Fisheries ; Thailand ; Pesticides ; Biological sampling ; Fish ; Fishery products ; Dried products ; Lethal limits
    Repository Name: AquaDocs
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26826 | 23782 | 2019-11-21 00:56:12 | 26826 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Presented in the paper is the standard procedure in the determination of K value which is an index to measure the enzymatic freshness of fish and squid. Specifically, reagents, apparatus and the analytical procedures needed and the calculations are presented.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Fishery products ; Fish inspection ; Fishery industry ; Food technology ; Standards ; Specifications
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26825 | 23782 | 2019-11-21 00:52:35 | 26825 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Presented in the paper is the standard procedure in measuring K value in fish meat by means of the freshness testing paper technique.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Fishery products ; Fish inspection ; Fishery industry ; Food technology ; Standards ; Specifications
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26802 | 23782 | 2019-11-12 05:28:20 | 26802 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Presented in the paper is the standard procedure in the measurement of pH in the fresh fish meat. Specifically, the procedures in sampling and sample preparation, apparatus and reagents required, and the analytical procedures are presented.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Microbiological analysis ; Fishery products ; Processed fishery products ; Fish inspection ; Fishery industry ; Food additives ; Food technology ; Standards ; Specifications ; pH
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26842 | 23782 | 2019-11-15 07:54:48 | 26842 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Starch is commonly used in the production of fish jelly products as an extender and as binding agent. The paper provides the methodology in the determination of starch in fish jelly products. Instructions for sample preparation and the reagents needed are presented. Detailed procedures in the determination of the starch in a sample are provided.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Fishery products ; Fishery industry ; Food technology ; Standards ; Specifications ; Starch ; Additives ; Food additives
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26852 | 23782 | 2019-11-15 07:36:44 | 26852 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Cholera is an acute specific infection caused by the organism, Vibrio cholera. Diagnosis may be confirmed by the presence of large numbers of the comma-shaped bacilli on direct microscopic examination of a fecal or vomitus smear, and by the isolation of the organism on culture. Fish and shellfish have been identified as vehicles of cholera. Large numbers of V. cholera must usually be ingested to cause cholera. Thus problems often occur when poor handling and inadequate refrigeration have allowed the organism to multiply. Presented in the paper is the methodology of determining the presence of Vibrio cholera in fish and fishery products.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Fishery products ; Fishery industry ; Food technology ; Standards ; Specifications ; Aerobic bacteria ; Microbiological analysis ; Microorganisms ; Pathogenic bacteria ; Pathogens ; Health and safety ; Public health ; Microbial contamination ; Vibrio cholerae
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26843 | 23782 | 2019-11-15 07:52:55 | 26843 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Sodium chloride is an important additive for the production of fish jelly products. It extracts the salt soluble protein to give the gel strength of the final product. The paper provides the methodology in the determination of the amount of sodium chloride in fish jelly products. Instructions for sample preparation and the reagents needed are presented. Detailed procedures in the determination of the salt in a sample are provided.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Fishery products ; Fishery industry ; Food technology ; Standards ; Specifications ; Additives ; Food additives ; Salts ; Sodium chloride
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26851 | 23782 | 2019-11-14 01:29:31 | 26851 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Food poisoning due to Vibrio parahaemolyticus is a food-borne infection resulting from the ingestion of a large number of this organism (about 106-109 viable cells). The major symptoms are diarrhea and abdominal pain with headache, fever, and vomiting also occurring. The organisms are excreted during the acute stage of the illness after which they decrease rapidly. The differentiation of V. parahaemolyticus from other pathogenic species of Vibrio is based mainly on salt tolerance, Voges-Proskauer reaction, fermentation of sucrose, and growth at 43°C. Presented in the paper is the methodology of determining the presence of Vibrio cholera in fish and fishery products.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Fishery products ; Fishery industry ; Food technology ; Standards ; Specifications ; Aerobic bacteria ; Microbiological analysis ; Microorganisms ; Pathogenic bacteria ; Pathogens ; Health and safety ; Public health ; Microbial contamination ; Vibrio parahaemolyticus ; Vibrio cholerae
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    Format: E-8.1-E-8.6
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  • 73
    Publication Date: 2022-08-09
    Description: With increasing world population and an unsettling resource scarcity in the back, sustainble consumption has moved to the foreground of political, economical and social discussions. One major school-of-thought is Circular Economy (CE), an approach summarizing various sustainable consumption activites under one roof. However, quantitative studies on the consumer are rare, yet crucial for a transfer from linear to circular consumption. This dissertation adds to literature by providing pioneer insights into consumer behavior in CE as an overarching concept, instead limiting research on singular subconcepts. Namely, four consumer activities are studied: recycling, upcycling, renting and sharing. In order to identify relevant insights for both academics and practitioners in CE, the research question ("what drives participation in CE?") is broken down into sub-hypotheses, which are addressed by three empirical studies. Using the SOR-Model (adaption Belk 1975) as overarching logic, the three studies deal with (1) the consumer (and their motivation) and situational stimuli (both (2) offline and (3) online). Respectively, three data sets are consulted to assess the sub-hypotheses and to identify overarching insights on how to accelerate consumer participation in CE, The research methodology employed ranges from a structured equation model (SEM), a random allocation field experiment during Fashion Week in Berlin to a discrete-choice model with best-worst scaling. The dissertation succeeds in revealing that (1) different activities in CE can be summarized in one latent variable, proving CE as a wholesome concept in consumer-related activities; that (2) Trust has a leveraging effect on participation in CE activities. Further, Trust can be enhanced offline via face-to-face interaction and online via third-party online attributes.; and that (3) experience in CE activities affects perception of online attributes, implying the need for adapted measures when dealing with CE-unexperienced consumers as compared to consumers with prior experience in CE activities.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: doctoralthesis , doc-type:doctoralThesis
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  • 74
    Publication Date: 2022-12-19
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: contributiontoperiodical , doc-type:contributionToPeriodical
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    Publication Date: 2022-12-12
    Description: How do recent changes in consumption in the wake of the COVID-19 pandemic affect the avoidance of packaging waste? How can an increase in packaging waste be countered and the previous trend towards unpackaged and reusable solutions be revived and promoted? To tackle these questions, we use a systemic approach that regards packaging as a network of interrelated interests of industry (manufacturing and logistics), trade (retail and catering), consumers and the waste management sector. To analyse this network, we applied three methods. First, we analysed secondary sources such as surveys. Second, we conducted semi-structured interviews with seven actors from industry, consumer education and waste management in May and June 2020. Third, we used the questions from the interview guideline to do an online survey among representatives of the public waste management industry.
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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    Publication Date: 2022-05-27
    Keywords: ddc:330
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: contributiontoperiodical , doc-type:contributionToPeriodical
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  • 77
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    Astrophysics and space science 216 (1994), S. 153-154 
    ISSN: 1572-946X
    Keywords: Chemistry ; Molecular Hydrogen ; Cloud Models
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Observations of the CO J=1-0 line are commonly used as a tracer for molecular material in clouds. The ratio of the H2 column density to the integrated intensity of this line,X, is often taken to be constant, despite theoretical and observational uncertainty. We have tried to identify how this ratio depends on cloud parameters, testing a simple theoretical argument suggesting its invariance with respect to density. The apparent constancy can be understood if clouds are clumpy on scales of Av ≈ 1-2 mag.
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  • 78
    ISSN: 1573-739X
    Keywords: Antimalarials ; Artemisia annua L ; Artemisinin ; Biosynthesis ; Chemistry ; Clinical trials ; Pharmacology ; Phytochemistry ; Sesquiterpenes ; Toxicology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Artemisinin, a sesquiterpene lactone endoperoxide isolated fromArtemisia annua L., and a number of its semisynthetic derivatives have shown to possess antimalarial properties. They are all eflective againstPlasmodium parasites that are resistant to the newest and commonly used antimalarial drugs. This article gives a survey of the literature dealing with artemisinin-relaled antimalarial issues that have appeared from the end of 1989 up to the beginning of 1994. A broad range of medical and pharmaceutical disciplines is covered, including phytochemical aspects like the selection of high-producing plants, analytical procedures, and plant biotechnology. Furthermore, the organic synthesis of artemisinin derivatives is discussed, as well as their mechanism of action and antimalarial activity, metabolism and pharmacokinetics, clinical studies, sideeffects and toxicology, and biological activities other than antimalarial activity.
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    Pharmacy world & science 13 (1991), S. 109-118 
    ISSN: 1573-739X
    Keywords: Chemistry ; Consumer product safety ; Drug packaging ; Environmental pollution ; Plasticizers ; Polyvinyls
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract In this report the state of the art with respect to PVC as pharmaceutical packaging material is described. A general introduction into the applications of PVC is followed by a description of its production process. The metabolic effects of the monomer of PVC, vinyl chloride and of the most commonly used plasticizer diethylhexylphthalate are mentioned. Special attention is given to the pharmaceutical properties of plasticized PVC bags in comparison to other plastics and the environmental aspects of waste PVC disposal. Although there are emotional and political queries regarding the future use of PVC as a (pharmaceutical) packaging material, we conclude that there is no scientific justification for a total or partial ban of PVC. PVC will remain a fact of life as a cheap, versatile, high-performance and well-investigated plastic material for medical and pharmaceutical applications, to be replaced by newer plastics only for certain well-defined indications where the requirements of the plastic to be used are so specific that it will economically and technically be justified to use another polymer. Community and hospital pharmacists have to be prepared for a role in intake of waste plastic disposables, probably against deposit money, in order to fulfil the logistics needed for recycling.
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  • 80
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    Plant systematics and evolution 171 (1990), S. 1-14 
    ISSN: 1615-6110
    Keywords: Angiosperms ; Compositae ; Chemistry ; systematics ; evolution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The broad knowledge of the chemistry of theCompositae allows the discussion of its relevance for the systematics and evolution within the family. Furthermore a separation into subfamilies can be supported by the observed differences in the distribution of the main constituents in the tribes.
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  • 81
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    Angewandte Makromolekulare Chemie 175 (1990), S. 107-116 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Zur Beschreibung der Polymerisationsgeschwindigkeit der radikalischen Fallungspolymerisation von Acrylsäure in Toluol wurde ein Modell entewickelt. Die experimentelle Überprüfung des Modells erfolgte durch Messungen in einem isotherm betriebenen Reaktionskalorimeter. Das Modell beschreibt die Polymerisationsgeschwindigkeit bis zum vollständigen Umsatz in einem Temperaturbereich von 40 bis 60°C.
    Notes: A kinetic model for the free-radical precipitation polymerization of acrylic acid in toluene was developed and verified experimentally by using an isothermal reaction calorimeter. The model predicts the rate of polymerization accurately up to complete conversion in the temperature range of 40 to 60°C.
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  • 82
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    Angewandte Makromolekulare Chemie 175 (1990), S. 157-168 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Es wird über Untersuchungen an Legierungen aus isotaktischem Polypropylen und EPDM-Elastomer berichtet, die mit hochenergetischen Elektronen bestrahlt worden waren. Die Mischungsverhältnisse in den Proben überstrichen sowohl den für elastomermodifizierte Thermoplaste typischen Bereich als auch den der thermoplasticschen Elastomeren. Eine Vernetzung der Komponenten über die Grenzfläche hinweg wurde nachgewiesen. Diese grenzflächenübergreifende Vernetzung bewirkte eine merkliche Verbesserung der mechanischen Eigenschaften insbesondere des thermoplastischen Elastomeren.
    Notes: Blends of isotactic polypropylene and EPDM rubber have been treated by electron irradiation in the composition range of rubber modification and in the thermoplastic rubber composition range as well. Mutual crosslinking of the components through the interface could be detected. This intercrosslinking caused a remarkable improvement of the mechanical properties particularly of the thermoplastic rubber.
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  • 83
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    Angewandte Makromolekulare Chemie 175 (1990), S. 205-205 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
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  • 84
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The mechanisms of photooxidation usually envisaged, are perfected by taking into account photoreactions of peroxy radicals. They involve interaction of a peroxy radical with the polymer to yield a hydroperoxy radical and a pair of macroradicals. After peroxidation, this pair will usually undergo bimolecular termination. The influence of such a reaction on photooxidation kinetics is particularly important for polyethylene. Then, chain termination occurs mainly by interaction of two hydroperoxy radicals or of a hydroperoxy radical with a macroperoxy radical. The reaction does not only affect kinetics of photooxidation but also the nature of the photooxidation products. The latter is more important for polypropylene than for polyethylene.
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  • 85
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Isothermal Differential Thermal Analysis was used to test the thermooxidative stability of pipes of polybutene during internal pressure tests at 110°C. At low hoop stresses and long testing times pipe failure was exclusively caused by thermooxidative degradation of the polymer.The stabilizer distribution in the initial state and its alteration during the pressure tests could easily be measured by isothermal DTA. Leaching of antioxidants from pipe walls could be detected. The decrease of residual thermooxidative stability was degressive.Degradation of pipe material started from the exterior pipe wall. Molecular weight of polybutene decreased rapidly after stabilizer exhaustion which could be observed by isothermal DTA.
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  • 86
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A base of experimental data on the ageing of commerial grade plastics is created. In includes assorted physical and chemical properties of plastics and their changes at natural ageing. An automated system for storing and processing of the experimental data is designed. Processing involves mathematical modeling of the changes in properties that aids in empirical prediction. The possibilities of the system are verified with experimental results from a 5-year ageing period of PE-LD and PE-HD. The results show a good agreement between the predicted and real data for selected models.
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  • 87
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    Angewandte Makromolekulare Chemie 179 (1990), S. 35-56 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Morphologie von Polypropylen-Spritzgußteilen mit Bindenaht wurde mit Röntgenweit-und Kleinwinkelstreuung, Lichtstreuung und Polarisationsmikroskopie untersucht. Die erhaltenen morphologischen Daten wurden mit mechanischen Werten aus Zugversuchen korreliert. Es wird gefunden, daß die mechanischen Eigenschaften der untersuchten Proben im wesentlichen von der sphärolithstruktur beeinflußt werden. Anhäufungen von Sphärolithen mit Kristallen der hexagonalen β-Modifikation und eine starke Inhomogenität der Sphärolithstruktur senkrecht zur Bindenaht sind der wesentliche Grund für die verschlechterten mechanischen Eigenschaften. Diese Sphärolithstruktur wird durch die Temperatur des Spritzgußwerkzeugs stark beeinflußt. Die Lamellen-Überstruktur hat dagegen einen vernachlässigbar kleinen Einfluß auf das mechanische Verhalten.
    Notes: The morphology of polypropylene plaques containing a weld line, has been investigated by x-ray wide and small angle scattering, light scattering and polarization microscopy. The results are correlated to mechanical values obtained from tensile tests. While the lamellar morphology is of neglectable influence, it is found, that the mechanical properties of the samples are strongly influenced by the spherulitic structure. Clustering of β-type spherulites and strong morphological inhomogeneities in the vicinity of the weld line are the primary reason for the mechanical weakening of the plaques. The temperature of the mould has a strong effect on the spherulitic structure and thus on the tensile properties of the samples.
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  • 88
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    Angewandte Makromolekulare Chemie 179 (1990), S. 77-85 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Füllstoffe für PVC- und PP-Formmassen wurden mit Mikrowellenplasma behandelt. Photoakustische FT-IR-Spektren zeigen, daß die Plasma-Polymerhülle auf der Füllstoffoberfläche —C=C—, —CH2—, CH3— und andere Gruppen enthält. Aus Röntgenelektronenspektren geht hervor, daß zwischen Siliciumdioxid und der organischen Beschichtung chemische Bindungen existieren. Durch Compoundieren von plasmabehandelten Füllstoffen mit PVC und PP werden Materialien mit guten mechanischen Eigenschaften bei niedrigen Kosten erhalten.
    Notes: Fillers for PVC and PP compounds have been treated by microwave plasma. FT-IR photoacoustic spectroscopy studies show that the plasma polymer sheath on filler's surface contains —C=C—, —CH2—, —CH3 groups, etc. X-ray photoelectron spectroscopy studies reveal that interfacial chemical bondings exist between silica and the organic coating. Application of plasma-treated fillers in PVC and PP compounds gives rise to materials of good mechanical properties and low cost.
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  • 89
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    Angewandte Makromolekulare Chemie 179 (1990), S. 135-148 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Poly-(alkylenadipat)-diole mit Molmassen von 1500, 2000 und 3000 wurden bei Temperaturen von 25 und 60°C in Gegenwart verschiedener Alkohole und unterschiedlicher PUR-Katalysatoren (1,4-Diazabicyclo[2.2.2]octan (DABCO), Dibutylzinndilaurat (DBTL),Dibutylzinndiethoxid (DBTEO) und Dibutylzinnoxid (DBTO)) in Ethylacetat bzw. Toluol gelagert und die Alkoholyse verfolgt. Die erhaltenen Ergebnisse werden mit dem Alkoholyseverhalten verschiedener Dialkyladipate sowie des Lösungsmittels Ethylacetat unter den selben Bedingungen verglichen. Die Alkoholyse verlauft in Gegenwart der zinnorganischen Verbindungen etwa mit gleicher Geschwindigkeit, ohne daß diese selbst signifikant zersetzt werden, wahrend DABCO praktisch inaktiv ist. Die Aktivitat der Alkohole ist starker von ihrer sterischen Struktur als von ihrer Basizitat abhangig. Die Stabilität der Polyalkylenadipate gegenüber einer Umesterung nimmt mit der Lange der Diolalkyleneinheiten des Polyols zu. Die Umesterung von Adipinsäuredialkylestern findet auch partiell in Anwesenheit eines großen Uberschusses an Ethylacetat statt.
    Notes: Poly(alkylene adipate)diols having molar masses of 1500, 2000 and 3000 were stored at temperatures of 25 and 60°C in the presence of low amounts of different alcohols and some polyurethane (PUR) catalysts, such as dibutyltindilaurate (DBTL), dibutyltindiethoxide (DBTEO), dibutyltinoxide (DBTO), and 1,4-diazabicyclo[2.2.2]octane (DABCO). Alcoholysis was studied using either ethyl acetate (EA) or toluene as solvent. The results were compared with those obtained by examining the behaviour of several dialkyl adipates and ethyl acetate under identical conditions. The alcoholysis in the presence of the tin catalysts proceeds at the same reaction rate without significant decomposition of the catalyst, whereas DABCO is practically inactive. The nucleophilic activity of the alcohols depends on their bulk size rather than their basicity. The resistance of polyalkylene adipates to transesterification increases with the increasing alkyl chain length of diol units in polyester. A partial transesterification of dialkyl adipates takes place too, in spite of ethyl acetate being present in excess.
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  • 90
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    Angewandte Makromolekulare Chemie 179 (1990), S. 157-171 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Es wurde das Permeations- und Trennverhalten von Alkohol/Wasser-Systemen durch poröse PVA-Membranen untersucht. PVA-Membranen mit unterschiedlicher Anzahl und Große von Poren wurden über Mischungen in Lösung mit verschiedenen synthetisierten Polymeren und Copolymeren, wie Polyacrylsäure, Polyacrylnitril, Polyacrylamid, Poly(Methylmethacrylat-co-Maleinsäureanhydrid) etc., anschließendes Gießen von Filmen und Extraktion der Polymeren oder Copolymeren durch Lösungsmittel hergestellt. Die Abhängigkeit der Durchlässigkeit und Trennwirkung von der Größe und Form der permeierenden Moleköle wurde qualitativ diskutiert. Des weiteren wurde die Selektivität der Trennwirkung in Abhangigkeit von der Zusammensetzung von Alkohol/Wasser-Gemischen und von der Größe und Anzahl der Poren untersucht. Es wurde gefunden, daß die Selektivität von der Menge und dem Molekulargewicht der in die Membranen eingebrachten Polymeren abhängt. Wenn der Gewichtsanteil des verwendeten Polymeren größer als 0,1 war, permeierte bevorzugt der Alkoholanteil bei methanolischen Msungen, wobei der Trennfaktor mit steigender Methanolkonzentration anstieg. In Gemischen mit anderen Alkoholen zeigten die Membranen andererseits eine selektive Durchlässigkeit für Wasser. Der Einfluß der Versuchsbedingungen wurde ebenfalls untersucht.
    Notes: The permeation and separation characteristics of alcohol/water systems through porous PVA membranes were investigated. Porous PVA membranes with different pore size and number were prepared by solution blending of PVA with several synthesized polymers or copolymers, such as polyacrylic acid, polyacrylamide, polyacrylonitrile, and methylmethacrylate-co-maleic anhydride, etc. Then casting, and finally extracting the blended polymers or copolymers by solvent from the membranes. The dependency of both permeation and separation on the molecular size and shape of the permeating species was dicussed qualitatively. Moreover, the permselectivity was investigated with attention to the feed composition of alcohol/water mixture and the effect of pore size and number. The selectivity was found to depend on the weight ratio and the molecular weight of polymer introduced to the membrane. When the weight ratio of polymer introduced into the membrane was larger than 0.1, methanol was permeated through membrane preferentially in methanol/water system, and the separation factor increased with increasing the methanol feed concentration. On the other hand, membrane had a selective permeability for water in the other alcohol/water systems. The influence of operating conditions was also studied.
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  • 91
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    Angewandte Makromolekulare Chemie 175 (1990), S. 29-38 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Temperatur des T1-Minimums für die Segmentbewegung in Polypropylen, das einen hohen ataktischen Anteil besitzt, ist niedriger als die in isotaktischem Polypropylen. Ein kurzes T1, T1s, tritt bei beiden Materialien auf. Bei Temperaturerhöhung nimmt T2a (T2 der beweglichen amorphen Bezirke) stark und T2m (T2 der dazwischen liegenden Bezirke) leicht zu, während sich T2c (T2 der steifen kristallinen Bezirke) kaum ändert. T2a in Polypropylen mit hohem ataktischem Anteil ist länger als in isotaktischem Polypropylen.Der Massenbruch der kristallinen Bezirke, Fc, nimmt bei Temperaturerhöhung ab und der der amorphen Bezirke, Fa, zu. Die Relaxationsgeschwindigkeit, 1/ (T1min), steigt linear mit Zunahme des amorphen Anteils an, außer bei der mit siedendem n-Heptan extrahierten Probe. Mit Zunahme der Peaktemperatur von tan δ fällt T2a nahezu linear ab, während die Temperatur des T1-Minimums zunimmt.
    Notes: The temperature of the T1 minimum for the segmental motion in polypropylene containing a lot of atactic fraction is lower than that in isotactic polypropylene. A short T1, T1s, appears for both materials. As the temperature is raised, there is a large increase in T2a (T2 of the mobile amorphous regions), and a mild increase in T2m (T2 of the intermediate regions), while there is no substantial change in T2c (T2 of the rigid crystalline regions). T2a in polypropylene containing a lot of atactic fraction is longer than that in isotactic polypropylene.The mass fraction of crystalline regions, Fc, decreases and that of the amorphous regions, Fa, increases as the temperature is raised. There is a linear increase in the relaxation rate, 1/(T1min), as the amorphous fraction is increased, except for the sample extracted with boiling n-heptane. With increase of the peak temperature of tanδ, T2a decreases nearly linearly, while the temperature of the T1 minimum increases.
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  • 92
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    Angewandte Makromolekulare Chemie 180 (1990), S. 191-198 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Bestrahlung von PTFE mit Elektronen niedriger Energie führt zur Abspaltung von Fluor und zum Einbau von Sauerstoff in die Polymeroberfläche. Es wird gezeigt, daß das Ausmaß der Oberflächenveränderungen hauptsächlich von der Zahl und kaum von der Energie der Elektronen abhängt, die die Oberfläche erreichen. Änderungen in der Oberflächenenergie resultieren in unterschiedlichem Benetzungsverhalten. Kontaktwinkelmessungen und Kurvenanalysen der C-1s-Peaks aus Röntgenphotonenspektroskopiemessungen zeigen, daß der am wenigsten benetzbare Teil der bestrahlten Oberflächen in den meisten Fällen aus —CF2 —CF-Einheiten besteht. Werden bei der Bestrahlung nahezu alle Fluoratome abgespalten, bleiben nur isolierte —CF2-oder —CF-Gruppen zurück. Die „receding“-Winkel werden mit zunehmender Sauerstoffkonzentration in der Oberfläche kleiner, was auf die Bildung stark oxidierter Bereiche hinweist. Die Unabhängigkeit der Kontaktwinkel von der Alterungsdauer deutet auf eine sehr geringe Beweglichkeit der Makromoleküle hin, was mit einer starken Vernet-zung an der Oberfläche zusammenhängen könnte.
    Notes: Low energy electron irradiation of PTFE induced fluorine depletion and introduction of oxygen on the surface. The effect on surface chemistry was shown to be dependent mostly on the amount of electrons reaching the sample, rather than on their energy.Changes in surface energy resulted in different wetting behaviors. The measurement of advancing water contact angles and the analysis of XPS C-1s peak shapes showed that the least wettable portion of irradiated surfaces is made in most cases of —CF2—CF — units. When the treatment caused a nearly complete fluorine depletion, only isolated —CF2— or —CF— groups are present. Receding angle values decreased linearly depending on the amount of oxygen introduced on the sample during the treatment, suggesting the formation of strongly oxidized polymer islets. The invariance of contact angles with aging time indicated very low macromolecular mobility, probably related to extensive surface crosslinking.
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  • 93
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    Angewandte Makromolekulare Chemie 181 (1990), S. 41-52 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: In aqueous dispersions of anionic polyurethanes containing the triethylammonium salt of 2,2-dimethylol propionic acid as chain extender, triethylamine can be largely replaced by ammonia. For electrostatic reasons, NH4+ is namely more tightly bound in the ion pairs located in the Stern layer than NH(C2H5)3+. Thermal treatment of films leads to a loss of base, whereby ammonia is more rapidly released than triethylamine. Therefore, crosslinking with partially methylated hexamethylolmelamine proceeds the faster the more triethylamine is replaced by ammonia.
    Notes: In Dispersionen aus anionischen Polyurethanen, die das Triethylammoniumsalz der 2,2-Dimethylolpropionsäure als Kettenverlängerungsmittel enthalten, läßt sich durch Zugabe von Ammoniak eine weitgehende Verdrängung des Triethylamins erreichen. Aus elektrostatischen Gründen ist nämlich in den in der Sternschen Schicht lokalisierten Ionenpaaren NH4+ fester gebunden als NH(C2H5)3+. Bei der thermischen Behandlung der Filme tritt Basenabspaltung ein, dabei erfolgt die Abgabe von Ammoniak deutlich schneller als die von Triethylamin. Die Spannungswerte der mit teilmethyliertem Hexamethylolmelamin vernetzten Proben sind daher um so höher, je mehr Triethylamin durch Ammoniak ersetzt wurde.
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  • 94
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    Angewandte Makromolekulare Chemie 181 (1990), S. 53-66 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Viskoelastizitäts-Parameter von geschmolzenem Polystyrol (PS) wurden mit einem Instron-Kapillarrheometer gemessen.Die Drucknachgiebigkeit B(t) zeigt ein Plateau sowohl im Schmelze (B1)- als auch im Glaszustand (Bg); beide nehmen mit abnehmender Spannung ab. Durch Verschiebung der B(t)-Kurven werden Master-Kurven erhalten, mit denen das Gesamtdruckverhalten (überlagerte elastische und viskose Deformationen) analysiert werden kann. Die stationäre Nachgiebigkeit (Bs) erlaubt eine Beschreibung des elastischen Energieanteils und scheint mit der Extrusions-Strangaufweitung (Bcs/Bds) korreliert zu sein. Die Volumenviskosität (ηk) nimmt mit zunehmender Spannung (P), zunehmender Belastungsgeschwindigkeit (k) und abnehmender Temperatur ab.
    Notes: Viscoelastic parameters of polystyrene (PS) melt in compression creep have been measured in an lnstron capillary-rheometer.Bulk compression creep compliance B(t) shows plateau regions in the molten state (B1) and the glassy state (Bg), both decreasing with increasing stress. Shifting of B(t) curves provides master curves suitable to analysing the total (superposed elastic and viscous deformations) bulk compression behaviour. The steady-state creep compliance (Bs) allows to describe the recoverable elastic energy (Be) and seems to be related to the extrusion die swell (Bcs/Bds). Volume viscosity (ηk) decreases with decreasing stress (P), increasing compression rates (k) and decreasing temperature (T).
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  • 95
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    Angewandte Makromolekulare Chemie 181 (1990), S. 67-74 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Es wurden Untersuchungen über Molekulargewichtsänderungen an physikalisch bei Raumtemperatur gealterten isotaktischen Polypropylenfilamenten (iPP) mit Hilfe der Hochtemperaturgelpermeationschromatographie (HTGPC) durchgeführt. Das Ergebnis der Untersuchungen weist auf eine sehr unbedeutende Änderung des Molekulargewichts des Materials während der Alterung hin.Das Materialgranulat wurde als Bezugsstandard gewählt. Basierend auf der Uneinheitlichkeit D = Mw/Mn des Granulats wurden Filamente der Handelsprodukte GYE 47 und PXC 31399 charakterisiert, deren Alterungsdauer zwischen 2 Wochen und 8 Monaten lag. Bei den Filamenten der Qpe GYE 47 verringerte sich die Breite der Molekulargewichtsverteilung D um durchschnittlich 12%. Andererseits zeigen die Filamente des PXC 31399-vps einen weniger eindeutigen Trend zur Änderung, jedoch im Mittel hat sich die Breite der Verteilung um etwa 20% erniedrigt. Bei letzterem ist die Verteilung iiber die Alterungsdauer stark gestreut. Der GYE 47-Typ zeigt eine nahezu asymptotische Abnahme. Es wird angenommen, daß die Ungleichartigkeit in der Ändenz der Anderung von D zwischen beiden Proben in ihrer unterschiedlichen thermodynamischen Stabilitat liegen ktinnte; PXC 31399 ist weniger stabil.
    Notes: Experiments on the molecular weight variations of physically, room temperature aged isotactic polypropylene (iPP) filaments were done using the High Temperature Gel Permeation Chromatography (HTGPC). Evidence emanating from the studies indicates a very marginal change in molecular weight of the materials during aging.The granules of the materials were chosen as the reference standard. Based on the polydispersity D = Mw/Mn of the granules, filaments of commercial grades GYE 47 and PXC 31399 were characterized between an aging period ranging from 2 weeks to 8 months. The filaments of the GYE 47 grade have their distributions D lowered on the average by about 12%. On the other hand, those of the PXC 31399 grade have a less definite trend in change, but on the average, D is lowered by about 20%. The distributions of this latter grade are highly scattered over the period of aging. The GYE 47 grade shows a reduction in the distribution of a near asymptotic nature. It is believed that the disparity in the trend of change of D between the two samples could be attributed to their relative thermodynamic stability with the PXC 31399 grade being less stable.
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  • 96
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The properties (squared dimensions, anisotropy, numbers of intra- and intermolecular contacts) of a single five-way cubic lattice chain embedded into an environment (matrix) of chains of the same length n = 50 were evaluated as a function of matrix volume fraction (matrix density) v and intermolecular interaction between the matrix polymer and the minority chain segments, characterized by a parameter φ. No convincing evidence was found for the occurrence of a coil-globule transition in the range of matrix densities (v ≤ 0.7) and repulsive interactions between matrix and minority chain (φ ≤ 0.2) investigated. For moderate attractive interaction (φ ≈ -0.17) a compensation of the chaincompressing action of the matrix and the chain-expanding interaction with the matrix was observed resulting in a zero-dependence of the size and shape of the minority chain on matrix density. It further turned out that there are fixed relations among the various size and shape data irrespective of the specific combination of matrix density and thermodynamic interaction by which a particular polymer dimension is produced. These interrelations are fairly the same as those evaluated for isolated chains the size of which is varied by an intramolecular energy parameter φi.
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  • 97
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: New three phases composite materials made of glassbeads as filler, water as liquid dispersed phase and polystyrene as matrix were obtained by polymerization of a water in oil emulsion formed by water dispersed in styrene in which glass beads are added. For this purpose glass beads have to be modified by silanization by a coupling agent 3-(Trimethoxysilyl)propylmethacrylate (TPM) or a silane Octadecyltrichlorosilane (ODMS), in order to prevent the wetting of the glass by water. Only low coverage of the glass surface by the coupling agent (0,05% of TPM) are convenient for the preparation cellular materials having good mechanical properties. At higher coverage ratio, strong hydrophobic glass beads are obtained which destabilize the water / styrene emulsion and lead to macroporous products. Study of the rheology of the filled emulsion appears to be the more simple and more sensitive method to determine the level of wettability of the glass bead by the emulsion which is the most significant parameter for the preparation of such three phases composite materials. Composite materials made of glass beads, air and polystyrene are simply obtained by evaporation of water under vacuum.
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  • 98
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: To test the molecular parameters concerning gas sorption in polymers, the concentration of CO2, N2O, CO, N2, CH4 and the noble gases Ne, He in glassy poly(butylene terephthalate) films (PBTP) has been studied gravimetrically with a recording microbalance at 25°C. The sorption isotherms exhibit downward curvature to the pressure axis. As neither solubility nor adsorption can explain the experimental results, analysis was carried out based on the dual-sorption model: gas dissolution and microvoid filling are considered as independent sorption mechanisms. The parameters of the dual-sorption model for the mentioned penetrants are determined. The results indicate that for parameter correlation the Lennard-Jones potential parameters give a rough idea, but size exclusion of gases in small diameter microvoids is proposed and special chemical interactions must be considered.
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  • 99
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    Angewandte Makromolekulare Chemie 185 (1991), S. 283-292 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: The ring opening metathesis polymerisation (ROMP) of 5-cyano-2-norbornene with tungsten hexachloride, tungesten oxytetrachloride, bis(dichloralkoxo)tungsten tetrachloride and bis(dichloralkoxo)tungsten oxydichloride as transition metal component was studied. Methylaluminoxan, diethylaluminium ethoxide, tetraisobutyldialuminoxan and tetrabutyltin served as cocatalyst. Toluene, Chlorobenzene and dichloromethane were used as solvents. The concentration of the tungsten components was in the range from 5 × 10-4 to 5 × 10-3 mol/l. Among the catalyst studied, tungsten hexachloride with diethylaluminium ethoxide proved to be the best. The polymerisation was highly selective with this system even at high monomer/tungsten ratios (e.q. 10200:1) and let to high conversions (≥82%).
    Notes: Die ringöffnende metathetische Polymerisation (ROMP) von 5-Cyano-2-norbornen wurde unter Einsatz von Wolframhexachlorid, Wolframoxidterachlorid, Bis(dichloralkoxo)wolframtetrachlorid und Bis(dichloralkoxo)wolframoxiddichlorid als Übergangsmetallkomponente untersucht. Als Cokatalysatoren dienten Methylaluminoxan, Diethylaluminiumethoxid, Tetraisobutyldialuminoxan und Tetrabutylzinn. Als Lösungsmittel wurden Toluol, Chlorbenzol und Dichlormethan verwendet. Die Konzentration der Wolframkomponente lag im Bereich 5 × 10-4 - 5 × 10-3 mol/l. Unter den geprüften Katalysatoren erwies sich Wolframhexachlorid in Verbindung mit Diethylalumiumethoxid als der geeignetste. Mit diesem System verlief die Polymerisation auch bei großen Monomer/Wolfram-Verhältnissen (10200 :1) hochselektiv und führte zu großen Umsätzen (≥82%).
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  • 100
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The dependence of dilution on the chain propagation and termination rate constants was investigated in the polymerization of ethyl acrylate in benzene solution at 50°C, with the rotating sector method. The errors of the above rate constants were determined and, by our method applied to decrease these errors, the errors of the propagation rate constant was reduced to its half value. By the application of our earlier results in polymerization kinetics, we found that in this system the chain propagation step is exclusively responsible for the solvent effects observed. Our experimental results can be quantitatively described in terms of the hot redical theory.
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