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  • Chemistry  (20,532)
  • Cooperatives  (41)
  • Wiley-Blackwell  (20,531)
  • Oxford University Press  (41)
  • American Institute of Physics
  • Elsevier
  • 2020-2022  (1)
  • 2010-2014  (41)
  • 1960-1964  (20,531)
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  • 1
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    Elsevier | Amsterdam
    In:  http://aquaticcommons.org/id/eprint/2000 | 130 | 2010-12-14 16:47:43 | 2000
    Publication Date: 2021-07-11
    Description: During October, 1972 the Patuxent River Estuary was monitored intensively and synoptically over two tidal cycles to determine the spatial and temporal patterns of various hydrodynamic, chemical and biological features. Forty-one depths at eleven stations along nine transects were sampled simultaneously at hourly intervals forsalinity, temperature, dissolved oxygen, chlorohyll a, particulate nitrogen, nitrate, nitrite, total kjeldahl nitrogen, ammonia, particulate carbohydrate, dissolved organic carbon, total hydrolizable phosphorous, dissolved inorganic phosphorous, suspended sediment, particle size distribution, and zooplankton. Tidal velocity wascontinuously monitored at each depth by recording current meters. Riverine input and meteorological conditions were relatively stable for two weeks preceeding the deployment.This communication describes the calculation of the intrinsic rates of change of the observed variables from their measured distributions in the Estuary. The steady-state, one-dimensional equation of species continuity is employed to separate the advection and tidal dispersion of a hydrodynamically passive substance frbm its intrinsic rate of change at point. A new spatial transform isintroduced for the purpose of interpolation and extrapolation of data.The intrinsic rate of change profiles reveal a region of heavy bloom activity in the upper estuary and a secondary bloom near the point in the River that most of the suspended material settles out. Thechanges in ammonia and nitrates are highly correlated to the productivity patterns. Phosphorous rates are less closely correlated to productivity. The perturbations that the Chalk Point steam electric power plant have on the heat and oxygen balances are easily discernible.
    Description: UMCES (University of Maryland Center for Environmental Science); Contribution No. 766
    Keywords: Ecology ; Biology ; Chemistry
    Repository Name: AquaDocs
    Type: book_section , TRUE
    Format: application/pdf
    Format: application/pdf
    Format: 1-26
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  • 2
    Publication Date: 2014-01-22
    Description: Water theft carried out by manipulating water meters constrains volumetric pricing in semi-arid regions. Cooperative management can reduce theft and improve incentives for efficient water use by inducing peer monitoring. Using a theoretical model, we show that theft is more likely when prices are high, punishments are weak, and cooperatives are large. We also show how cooperative membership and punishment levels are determined endogenously by constraints on monitoring. We test the model on data from Tunisia for the years 2001–2003, relying on instruments that proxy for unobservable monitoring costs. The results confirm that well-designed incentives can reduce theft, and that constraints on monitoring costs affect institutional design.
    Keywords: D82 - Asymmetric and Private Information, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness, Q15 - Land Ownership and Tenure ; Land Reform ; Land Use ; Irrigation, Q25 - Water
    Print ISSN: 0002-9092
    Electronic ISSN: 1467-8276
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 3
    Publication Date: 2014-03-21
    Description: This is the first paper to analyze liquidity costs in agricultural futures markets based on the observed bid-ask spread (BAS) faced by market participants. The results reveal a highly liquid corn market that mostly offers order execution at minimum cost. The BAS responds negatively to volume and positively to price volatility, but also affects volume traded and price volatility. While statistically significant, these responses on a cents/bushel or a percentage basis are generally small. Liquidity costs are also virtually impervious to short-term changes in demand for spreading and trend-following trader activity, as well as differences from day-of-the-week changes in market activity. Much larger cents/bushel and percentage changes in BAS occur during commodity index trader roll periods and on USDA report release days. The roll period findings indicate a sunshine trading effect, while announcement effects identify the importance of unexpected information and adverse selection on order execution costs. Overall, our research demonstrates that the transition to electronic trading in the corn futures market has led to low and stable liquidity costs, despite the market turbulence in 2008–2009.
    Keywords: C36- Instrumental Variables (IV) Estimation, G12 - Asset Pricing ; Trading volume ; Bond Interest Rates, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
    Print ISSN: 0002-9092
    Electronic ISSN: 1467-8276
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 4
    Publication Date: 2014-03-21
    Description: The Minnesota Food Network is a limited liability company comprised of 52 farmers producing a variety of high-quality, sustainably produced agricultural products in southern Minnesota. The network's goal is to develop a regional food system to provide locally grown food at a price that "is fair" to both consumers and producers. This case outlines the challenges that the network faces in their efforts to expand to take advantage of a market opportunity. One of their biggest challenges is that they face high operating costs because of their disaggregated distribution system and need to purchase a distribution and storage facility and two vehicles. They will fund the purchase of a building through an angel investor. An angel investor is necessary because the network cannot sustain traditional loan payments in its current form. Students are asked to consider a number of questions pertaining to the decisions in this case outlined in the final section of the case study.
    Keywords: A22 - Undergraduate, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness, Q18 - Agricultural Policy ; Food Policy
    Print ISSN: 0002-9092
    Electronic ISSN: 1467-8276
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 5
    Publication Date: 2014-03-21
    Description: To successfully market new products in a social network it is essential to identify influential individuals whose product recommendations influence the consumption choices of their peers. In this study, we use spatial econometric methods to determine how individuals revise their preferences for product attributes when exposed to product recommendations from peers, and how different individuals who vary in their degree of network connectedness exert influence on the product choices of others. We find evidence that consumers look to others for guidance from peers in their preference for subjective, taste-specific parameters, but tend not to respond to peer price choices. Our spatial methods allow us to empirically determine the influence exerted by individual members on the consumption choices of other members of the social network. We find that connected members of the social network are not always the most influential in revising the consumption choices of others. Our estimates reveal that network proximity explains only 8.8% of influence.
    Keywords: D12 - Consumer Economics: Empirical Analysis, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
    Print ISSN: 0002-9092
    Electronic ISSN: 1467-8276
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 6
    Publication Date: 2014-04-05
    Description: Randomized controlled trials (RCTs) in the social sciences are typically not double-blind, so participants know they are "treated" and will adjust their behavior accordingly. Such effort responses complicate the assessment of impact. To gauge the potential magnitude of effort responses we implement a conventional RCT and double-blind trial in rural Tanzania, and randomly allocate modern and traditional cowpea seed varieties to a sample of farmers. Effort responses can be quantitatively important—for our case they explain the entire "treatment effect on the treated" as measured in a conventional economic RCT. Specifically, harvests are the same for people who know they received the modern seeds and for people who did not know what type of seeds they got; however, people who knew they had received the traditional seeds did much worse. Importantly, we also find that most of the behavioral response is unobserved by the analyst, or at least not readily captured using coarse, standard controls.
    Keywords: Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
    Print ISSN: 0002-9092
    Electronic ISSN: 1467-8276
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 7
    Publication Date: 2014-09-06
    Description: This article investigates the announcement effects of major USDA reports using intraday Chicago Board of Trade corn futures prices and trading volume from the electronic trading platform for July 2009 to May 2012. Focusing on intraday market reactions, we analyze the extent to which new information impacts and is rapidly reflected in prices. Results show that USDA reports contain substantial information for market participants. Strongest price reactions to the releases are found immediately after the market opens, and market reactions persist for approximately ten minutes. The electronic corn futures market quickly incorporates this new public information, and little evidence exists to support systematic under- or overreactions in prices. Other more subtle reactions occur in the last trading session before USDA announcements as traders adjust their market exposure in anticipation of the release.
    Keywords: D80 - General, G14 - Information and Market Efficiency ; Event Studies, Q11 - Aggregate Supply and Demand Analysis ; Prices, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
    Print ISSN: 2040-5790
    Electronic ISSN: 2040-5804
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 8
    Publication Date: 2014-09-06
    Description: Increases in crop yields and changing cropping patterns have placed stress on agribusiness handling and storage facilities. The objective of this research is to gain insight into the relationship between safety culture and safety performance, and to identify the determinants of safety culture in agribusinesses. The research suggests that investments in labor inputs such as increased training, consistent discipline, and recognition of safety achievements all increase safety culture. Furthermore, improvements in employee perceptions of safety culture have a positive impact on reducing employee injuries. Congress has recently funded nine centers to work on occupational health and safety research in agriculture, fisheries, and forestry.
    Keywords: J43 - Agricultural Labor Markets, L66 - Food ; Beverages ; Cosmetics ; Tobacco ; Wine and Spirits, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
    Print ISSN: 2040-5790
    Electronic ISSN: 2040-5804
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 9
    Publication Date: 2014-12-13
    Description: In a well-functioning futures market, the futures price at expiration equals the price of the underlying asset. This condition failed to hold in grain markets for most of 2005-2010, calling into question the ability of these markets to perform their price discovery and risk management functions. During this period, futures contracts expired up to 35% above the cash grain price. We develop a dynamic rational expectations model of commodity storage that explains how these recent convergence failures were generated by the institutional structure of the delivery system. When delivery occurs on a grain futures contract, the firm on the short side of the market provides a delivery instrument (a warehouse receipt or shipping certificate) to the firm on the long side of the market. The firm taking delivery may hold the delivery instrument indefinitely, providing it pays a daily storage rate. The futures exchange sets the maximum allowable storage rate at a fixed value. We show that non-convergence arises in equilibrium when the market price of physical grain storage exceeds the maximum storage rate on delivery instruments. We call the difference between the price of carrying physical grain and the maximum storage rate the wedge , and demonstrate theoretically and empirically that the magnitude of the non-convergence equals the expected present discounted value of a function of future wedges.
    Keywords: G13 - Contingent Pricing ; Futures Pricing, G14 - Information and Market Efficiency ; Event Studies, Q11 - Aggregate Supply and Demand Analysis ; Prices, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
    Print ISSN: 0002-9092
    Electronic ISSN: 1467-8276
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 10
    Publication Date: 2014-12-13
    Description: A recently developed testing procedure is used to detect and date-stamp explosive episodes ("bubbles") in corn, soybean, and wheat futures markets during 2004–2013. We find that the markets experienced price explosiveness only approximately two percent of the time and, when bubbles do occur, they are generally short-lived and small in magnitude. The correspondence between observed price spikes and bubbles is rather low, with a large portion of the price explosiveness occurring during downward price movements. Commodity index trader positions do not significantly affect the probability of a positive bubble occurring in grain futures markets, which directly contradicts the argument (the "Masters Hypothesis") that waves of index investment distorted underlying supply-and-demand relationships and led to a series of massive bubbles in agricultural futures markets. In addition, commodity index trader positions tend to reduce negative bubble occurrence, while general speculative activity as measured by Working's T reduces the probability of a positive bubble. There is some evidence that the positions of noncommercial traders have a direct effect on positive bubble occurrence, but the effect declines when accounting for the composition of other traders in the market. Overall, speculation has little effect or negative effects on price explosiveness. Finally, positive bubbles are more likely to occur in the presence of low inventories, strong exports, a weak U.S. dollar, and booming economic growth, whereas negative bubbles are more likely to occur with large inventories, weak exports, and stagnant economic growth.
    Keywords: D84 - Expectations ; Speculations, G12 - Asset Pricing ; Trading volume ; Bond Interest Rates, G13 - Contingent Pricing ; Futures Pricing, G14 - Information and Market Efficiency ; Event Studies, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness, Q41 - Demand and Supply
    Print ISSN: 0002-9092
    Electronic ISSN: 1467-8276
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 11
    Publication Date: 2014-09-02
    Description: This article discusses the current state of contract theory and its usefulness for conceptualizing issues related to agricultural contracting. The paper will explore the limitations of existing theory for applied work, and what methodological improvements are needed to enhance the usefulness of the theory to agricultural economists. One pervasive problem is that the economic literature on contracts is rather fragmented and the various methodological strands are narrow in their focus. As such, agricultural economists should engage in methodological research to develop applied contracting models that can capture higher-order features of real-world agricultural contracts while delivering generalizable comparative statics predictions because contracting continues to expand along the entire modern food marketing channel. In the latter part of this article, a simple model is developed to illustrate how classic methodological approaches can be combined with recent developments in contract and game theory to construct applied theory models that are useful for capturing some important features of agricultural contracts.
    Keywords: D43 - Oligopoly and Other Forms of Market Imperfection, D82 - Asymmetric and Private Information, D86 - Economics of Contract: Theory, Q12 - Micro Analysis of Farm Firms, Farm Households, and Farm Input Markets, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
    Print ISSN: 0002-9092
    Electronic ISSN: 1467-8276
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 12
    Publication Date: 2014-09-02
    Description: Information and communications technologies have spread rapidly in developing countries. We investigate the impact of mobile phones on traders' search behavior in Niger by constructing a theoretical model of search in which traders engage in sequential search for the optimal sales price. Using a trader panel dataset spanning 2005–2007, we find empirical support for the model in that the duration of mobile phone coverage is associated with increased search activity. This effect evolves dynamically over time and is stronger for larger traders, who engage in arbitrage over longer distances. Results provide empirical evidence for the observed linkages between mobile telephony and price dispersion.
    Keywords: O10 - General, O30 - General, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
    Print ISSN: 0002-9092
    Electronic ISSN: 1467-8276
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 13
    Publication Date: 2014-08-02
    Description: In the past two decades, there has been an explosion of studies eliciting consumer willingness-to-pay for food attributes; however, this work has largely refrained from drawing a distinction between preferences for health, safety and quality on the one hand and consumers' subjective beliefs that the products studied possess these attributes, on the other. Using data from three experimental studies, along with structural economic models, we show that controlling for subjective beliefs can substantively alter the interpretation of results and the ultimate implications derived from a study. The results suggest the need to measure subjective beliefs in studies of consumer choice and to utilise the measures when making policy and marketing recommendations.
    Keywords: C91 - Laboratory, Individual Behavior, D83 - Search ; Learning ; Information and Knowledge ; Communication ; Belief, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness, Q18 - Agricultural Policy ; Food Policy
    Print ISSN: 0165-1587
    Electronic ISSN: 1464-3618
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 14
    Publication Date: 2014-07-23
    Description: Livestock Gross Margin Insurance for Dairy Cattle (LGM-Dairy) is a risk management tool for protecting milk income over feed cost margins. In this article, we examine the assumptions underpinning the method used to determine LGM-Dairy premiums. Analysis of the milk–feed dependence structure is conducted using copula methods, a rich set of tools that allow modelers to capture nonlinearities in dependence among variables of interest. We find a significant relationship between milk and feed prices that increases with time-to-maturity and severity of negative price shocks. Extremal, or tail, dependence is the propensity of dependence to concentrate in the tails of a distribution. A common theme in financial and actuarial applications and in agricultural crop revenue insurance is that tail dependence increases the risk to the underwriter and results in higher insurance premiums. We present, to our knowledge, the first case in which tail dependence may actually reduce actuarially fair premiums for an agricultural risk insurance product. We examine hedging effectiveness with LGM-Dairy and show that, even in the absence of basis or production risk, hedging horizon plays an important role in the ability of this tool to smooth farm income over feed cost margins over time. Rating methodology that accounts for tail dependence between milk and feed prices extends the optimal hedging horizon and increases hedging effectiveness of the LGM-Dairy program.
    Keywords: G13 - Contingent Pricing ; Futures Pricing, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness, Q18 - Agricultural Policy ; Food Policy
    Print ISSN: 0002-9092
    Electronic ISSN: 1467-8276
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 15
    Publication Date: 2014-07-23
    Description: We study the effect of alleviating the information asymmetry regarding product quality that is widespread in contracts between agricultural producers and buyers in developing countries. Opportunistic buyers may underreport quality levels to farmers to reduce the price that they have to pay. In response, farmers may curb investment, thereby negatively affecting farm productivity. In an experiment, we entitle randomly selected smallholder dairy farmers in Vietnam, who are contracted by a large company, to independently verify milk testing results. Results indicate that treatment farmers use 12% more inputs, and they also increase their output significantly. Some wider research and policy implications are discussed.
    Keywords: C93 - Field Experiments, D82 - Asymmetric and Private Information, O13 - Agriculture ; Natural Resources ; Energy ; Environment ; Other Primary Products, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
    Print ISSN: 0002-9092
    Electronic ISSN: 1467-8276
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 16
    Publication Date: 2014-07-23
    Description: We address the question of how the strength of protection for geographical indications (GIs) affects the GI industry's promotion incentives, equilibrium market outcomes, and the distribution of welfare. Geographical indication producers engage in informative advertising by associating their true quality premium (relative to a substitute product) with a specific label emphasizing the GI's geographic origin. The extent to which the names/words of the GI label can be used and/or imitated by competing products—which depends on the strength of GI protection—determines how informative the GI promotion messages can be. Consumers’ heterogeneous preferences (vis-à-vis the GI quality premium) are modeled in a vertically differentiated framework. Both the GI industry and the substitute product industry are assumed to be competitive (with free entry). The model is calibrated and solved for alternative parameter values. Results show that producers of the GI and of the lower-quality substitute good have divergent interests: GI producers are better off with full protection, whereas the substitute good's producers prefer intermediate levels of protection (but they never prefer zero protection because they benefit indirectly if the GI producers’ incentives to promote are preserved). For consumers and aggregate welfare, the preferred level of protection depends on the model's parameters, with an intermediate level of protection being optimal in many circumstances.
    Keywords: D23 - Organizational Behavior ; Transaction Costs ; Property Rights, L15 - Information and Product Quality ; Standardization and Compatibility, M37 - Advertising, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
    Print ISSN: 0002-9092
    Electronic ISSN: 1467-8276
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 17
    Publication Date: 2014-07-23
    Description: Retail-price pass-through is one of the most important issues facing manufacturers of consumer packaged goods. Although retailers tend to pass higher wholesale prices through to consumers quickly and completely, they often do not pass on trade promotions. Currently, asymmetric pass-through is commonly thought to result from retailers’ exercise of market power. Alternatively, it may be because of consumer search behavior and retailers’ competitive response. We test this theory using a panel threshold asymmetric error-correction model applied to wholesale and retail scanner data for ready-to-eat cereal for a number of retailers in the Los Angeles metropolitan market. We find that consumer search behavior contributes significantly to imperfect pass-through. By allowing pass-through to depend on market power and consumer search costs, we find results that are contrary to the conventional wisdom. Namely, market power causes retail prices to fall quickly and rise slowly, whereas consumer search behavior causes retail prices to rise quickly and fall slowly—precisely the "rockets and feathers" phenomenon.
    Keywords: C35 - Discrete Regression and Qualitative Choice Models, L13 - Oligopoly and Other Imperfect Markets, L66 - Food ; Beverages ; Cosmetics ; Tobacco ; Wine and Spirits, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
    Print ISSN: 0002-9092
    Electronic ISSN: 1467-8276
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 18
    Publication Date: 2014-07-23
    Description: The degradation of product quality is one form of rent dissipation resulting from incomplete property rights in fisheries. Industry structure and information asymmetries can also lead to underinvestment in product quality, even when property rights are well defined. In this article we empirically examine whether the voluntary formation of a marketing cooperative was able to mitigate market failures that led to the production of inferior-quality fish. Specifically, we use a difference-in-differences estimation strategy to measure the impact that the Copper River Fishermen's Cooperative, an Alaskan salmon marketing cooperative, had on ex-vessel salmon prices and salmon quality measures. We find that the cooperative was able to improve product quality, as well as attract and sustain a higher price for its salmon. Our findings provide empirical support for many of the key tenets of cooperative theory. Specifically, we find evidence that marketing cooperatives can address existing market failures, that marketing cooperatives can have advantages in high-quality product markets, and that over time, as a result of their success, marketing cooperatives may lead to lasting producer benefits even though they become obsolete due to nonmember free-riding.
    Keywords: Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness, Q22 - Fishery ; Aquaculture
    Print ISSN: 0002-9092
    Electronic ISSN: 1467-8276
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 19
    Publication Date: 2014-07-23
    Description: The emergence of community supported agriculture (CSA) farms has been recognized as a new way for small farms to remain competitive while engaging in their local community through direct marketing. In this study, we report on first revealed preference valuation of CSA attributes using data on share prices and CSA characteristics for the summer 2012 growing season. Using data covering 453 CSA farms in Michigan, New York, Ohio, and Pennsylvania, we develop a hedonic model based on firm-level prices to reveal consumer valuations of CSA attributes, including various types of organic certification. We also test for competition in the CSA market using a model of firm entry to evaluate whether firms appear perfectly competitive, which is a requirement when using firm-level prices in our hedonic analysis. Our results reveal a price premium of approximately 7% for USDA organic certification, although this value is heterogeneous across states. We find no premium associated with competing certified naturally grown programs. Finally, we find that CSA farms exhibit little market power and appear to act competitively even with few market entrants.
    Keywords: Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness, Q51 - Valuation of Environmental Effects
    Print ISSN: 0002-9092
    Electronic ISSN: 1467-8276
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 20
    Publication Date: 2014-03-07
    Description: This paper estimates capitalisation effects of farm attributes with a particular focus on the decoupled Single Farm Payment (SFP) on prices. The spatial analysis employs a sample of mainly small- and medium-sized Swedish farm transactions sold all across Sweden; the results from a spatial multiple-membership model suggest that decoupled SFP has no influence on farm prices. Prices are profoundly influenced by residential characteristics and accessibility to urban amenities. Spatial heterogeneity is found for both regional and local levels, and a large spatial spillover effect is found between neighbouring farms. Results are confirmed by sensitivity analyses.
    Keywords: Q12 - Micro Analysis of Farm Firms, Farm Households, and Farm Input Markets, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness, R38 - Government Policies ; Regulatory Policies
    Print ISSN: 0165-1587
    Electronic ISSN: 1464-3618
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 21
    Publication Date: 2013-02-26
    Description: The survival of agricultural marketing co-operatives depends on their capability of satisfying and maintaining their base of farmer members. Hypotheses regarding these two success factors are developed in neoclassical economics and transaction cost economics. They are tested with a survey of 321 members of marketing co-operatives specialising in fresh fruits and vegetables. Our results show support for both perspectives. Price paid to farmers is important for their satisfaction with the co-operative. Farmers' perceptions of transaction costs are even more important.
    Keywords: D22 - Firm Behavior: Empirical Analysis, D23 - Organizational Behavior ; Transaction Costs ; Property Rights, P13 - Cooperative Enterprises, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
    Print ISSN: 0165-1587
    Electronic ISSN: 1464-3618
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 22
    Publication Date: 2013-02-26
    Description: This paper explores the demand and willingness to pay (WTP) for value-added services to chicken. Since the demand for such services are likely to be highly segmented and often applies only to a market niche, models based on assumptions of homogeneity among consumers are likely to be inappropriate. For this reason, this paper combines discrete and continuous mixing distributions to concurrently identify the size of the niche market and the heterogeneity among consumers within the market niche. Failing to account for the niche market nature of value-added services is shown to have implications for predictions of WTP, demand and total revenue.
    Keywords: C25 - Discrete Regression and Qualitative Choice Models, D12 - Consumer Economics: Empirical Analysis, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
    Print ISSN: 0165-1587
    Electronic ISSN: 1464-3618
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 23
    Publication Date: 2013-11-22
    Description: India and China have the largest farm-household populations in the world—populations that are also among the poorest. Among the many factors that affect farm livelihoods, access to credit has been identified as a significant barrier preventing the escape from poverty. While there has been significant research on credit constraints in developing countries, there is surprisingly little information pertaining to the actual impacts of credit constraints on household well-being. The objective of this paper is to investigate the impacts of credit constraints on various factors affecting farm households, such as physical and human capital formation, agricultural inputs applications, consumption smoothing, and wage-seeking behavior using direct elicitation. This paper contributes to the literature and policy debates by comparing the effects of credit constraints in China and India as surveyed in 2008–2009. The analytical results and data demonstrate that binding credit constraints adversely affect a broad range of production and livelihood choices. We empirically show that credit constraints negatively affect food consumption, farm input applications, and health and educational attainments.
    Keywords: O13 - Agriculture ; Natural Resources ; Energy ; Environment ; Other Primary Products, O17 - Formal and Informal Sectors ; Shadow Economy ; Institutional Arrangements, Q12 - Micro Analysis of Farm Firms, Farm Households, and Farm Input Markets, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
    Print ISSN: 2040-5790
    Electronic ISSN: 2040-5804
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 24
    Publication Date: 2013-11-22
    Description: Using a lab experiment with 351 adult non-student subjects, we investigate the impact of labels and secondary information on willingness to pay (WTP) for foods that use various ingredients and processes that have been the subject of food policy discussions. We find a distinct asymmetry of WTP sensitivity between "Contains X" and "Free of X" labels with negatively-framed secondary information. The "Free of X" label has an impact only when secondary information is provided, and the negative impact of "Contains X" is mitigated by secondary information. We also consider how the results of our study can inform the ongoing debate about mandatory food labeling regulations in the United States: if mandatory labeling is adopted, providing additional information about what the product contains would significantly lessen the negative impact on demand.
    Keywords: M31 - Marketing, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness, Q18 - Agricultural Policy ; Food Policy
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    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 25
    Publication Date: 2013-11-22
    Description: This study examines the risk management opportunities for fluid milk market participants in the United States through the use of milk futures contracts. We estimate the nature of basis risk from 2002–2011 using modern time-series and econometric techniques. The results of this investigation reveal that at sufficient hedging intervals, using class III manufacturing milk futures contracts to cross-hedge fluid milk has the ability to reduce risk and provide revenue stability to market participants. When used in conjunction with milk futures, prediction algorithms for the closing basis facilitate more direct management of fluid milk price risk.
    Keywords: Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness, Q14 - Agricultural Finance, Q18 - Agricultural Policy ; Food Policy
    Print ISSN: 2040-5790
    Electronic ISSN: 2040-5804
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 26
    Publication Date: 2013-05-31
    Description: European Union regulation on quality food products (protected designations of origin (PDO) labelling) is expected to sustain competitiveness within the agricultural sector. This paper examines the impact of this policy on the survival of cheese firms over the period 1990–2006 in France. We show that such a policy (Appellation d'Origine Controlée) reduces exiting risk for smaller firms. However, smaller firms still have a lower survival rate compared with larger ones that cannot be compensated by the quality label effect.
    Keywords: L10 - General, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness, Q18 - Agricultural Policy ; Food Policy
    Print ISSN: 0165-1587
    Electronic ISSN: 1464-3618
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 27
    Publication Date: 2013-12-24
    Description: The investigation of hypothetical bias in choice experiments (CEs) has typically been conducted in the laboratory with only minimal field experiments. Moreover, it is common practice to provide an initial endowment (money or coupons) to respondents. In this research, we employed a between-subject CE in a supermarket with three different treatments (i.e. hypothetical, hypothetical with cheap talk script and real). With the ‘real’ treatment, we required respondents to use their own money when making a payment. The proposed incentive-compatible mechanism mimics as close as possible the everyday purchasing situation. Results confirm the presence of hypothetical bias and the mixed effectiveness of a cheap talk script.
    Keywords: D12 - Consumer Economics: Empirical Analysis, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
    Print ISSN: 0165-1587
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    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 28
    Publication Date: 2013-12-24
    Description: Policymakers have suggested the use of taxes to raise the relative cost of buying fast food. Yet, little is known of the structure of demand for food-away-from-home (FAFH) in general. This study provides estimates of the price-elasticity of demand for four different types of FAFH using a new data set from NPD, Inc. and an econometric approach that accounts for the multiple-discrete–continuous nature of FAFH demand. We find that cross-price elasticities of demand are small, so consumers are unwilling to substitute between food-at-home and any type of FAFH or among types of FAFH. Therefore, taxing fast food may be effective in reducing the number of fast food visits and shifting consumption to at-home meals.
    Keywords: C35 - Discrete Regression and Qualitative Choice Models, D12 - Consumer Economics: Empirical Analysis, I18 - Government Policy ; Regulation ; Public Health, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness, Q18 - Agricultural Policy ; Food Policy
    Print ISSN: 0165-1587
    Electronic ISSN: 1464-3618
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 29
    Publication Date: 2013-12-24
    Description: Using experimental auctions carried out on apples in different European countries, this paper contributes to the assessment of consumer willingness to pay for the reduction of pesticides. We study several systems of good agricultural practices, possibly signalled to consumers, ranging from Integrated Pest Management certifications to organic production methods. The results show a relatively homogeneous behaviour of European consumers and reveal that improving the information on pesticide reduction may have unintended consequences. Results also suggest that taste characteristics and reference to a Protected Denomination of Origin should not be overlooked.
    Keywords: C91 - Laboratory, Individual Behavior, D12 - Consumer Economics: Empirical Analysis, Q01 - Sustainable Development, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
    Print ISSN: 0165-1587
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    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 30
    Publication Date: 2012-12-28
    Description: We investigate the impact of decentralised decision-making on product quality. Comparing a cooperative and an investor-owned firm suggests that members of the cooperative have an incentive to produce too much and to free-ride on quality. Whether or not cooperatives deliver higher quality products depends on the way in which the quality of the final product is determined from the quality levels of the inputs delivered (quality aggregation) as well as the number of members of the cooperative. Empirical evidence on the Austrian wine market suggests that wines produced by cooperatives tend to be of significantly lower quality, ceteris paribus .
    Keywords: D22 - Firm Behavior: Empirical Analysis, D23 - Organizational Behavior ; Transaction Costs ; Property Rights, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
    Print ISSN: 0165-1587
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  • 31
    Publication Date: 2012-03-08
    Description: We determine the circumstances when the absence of public listing, often believed to be a disadvantage, makes a cooperative the unique efficient governance structure. This is established in a multi-task principal–agent model, capturing that cooperatives are not publicly listed and their CEOs have to bring the downstream enterprise to value as well as to serve upstream member interests. Not having a public listing prevents the CEO from choosing the level of the downstream activities too high. Cooperatives are uniquely efficient when the upstream marginal product multiplied with a function increasing in the strength of the chain complementarities is higher than the downstream marginal product.
    Keywords: D21 - Firm Behavior, L23 - Organization of Production, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
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  • 32
    Publication Date: 2012-03-08
    Description: Branded food manufacturers vindicate the use of excess production capacities to justify their production of retailers’ brands. We study the distributor's and food manufacturer's private label (PL) strategy for production within a framework featuring endogenous store brand quality, bargaining power, possible differences in production technology and potential capacity constraints for the branded manufacturer. Depending on the structure of capacity constraint (applying to both products or to the PL only), we find that the retailer may prefer to choose an independent firm for the production of the store brand whereas the branded manufacturer is chosen in the case of excess capacity.
    Keywords: L11 - Production, Pricing, and Market Structure ; Size Distribution of Firms, L13 - Oligopoly and Other Imperfect Markets, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
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  • 33
    Publication Date: 2012-05-29
    Description: Using stated preference data from Kentucky and Ohio, USA, we estimate consumer willingness-to-pay for varieties of a processed food product (blackberry jam) that are differentiated with respect to their local production labelling and a series of other value-added claims. Results show that consumers were willing to pay more for the product indicating locally produced, produced in their state or in a well-identified multi-state region. Consumers were willing to purchase organic products, although there might be some confusion as to the meaning of the organic logo. Our results also supported the notion that consumers are willing to support small family farms.
    Keywords: Q11 - Aggregate Supply and Demand Analysis ; Prices, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
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  • 34
    Publication Date: 2012-05-29
    Description: This paper studies the determinants and consequences of heterogeneous market participation among Polish dairy farmers using a unique data set on supply chain characteristics and individuals with different market relationships. It investigates factors that cause households not to participate in the market and then estimates farm orientation effects on revenues, using semi-parametric methods. The key finding is that farms maintaining commercial dairy business were better off than those who ceased milk sales. However, detailed analysis shows that this difference could be attributed to supply chain modernisation and becomes insignificant once subsistence farmers are compared to commercial farms supplying the traditional marketing channel.
    Keywords: D22 - Firm Behavior: Empirical Analysis, Q12 - Micro Analysis of Farm Firms, Farm Households, and Farm Input Markets, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
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  • 35
    Publication Date: 2012-08-03
    Description: This study investigates the choice of quality by producer organisations (POs) in charge of defining product specifications for geographical indications. The model assumes that the PO chooses the quality level that maximises joint producer profits in anticipation of the competitive equilibrium that arises once quality is set. Using a fairly general variant of the vertical differentiation model and a flexible specification of production costs, we show that the PO has an incentive to supply quality in excess of the socially optimal level.
    Keywords: L15 - Information and Product Quality ; Standardization and Compatibility, L44 - Antitrust Policy and Public Enterprises, Nonprofit Institutions, and Professional Organization, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
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    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 36
    Publication Date: 2012-12-28
    Description: This paper investigates household expenditures on food away from home by type of facility. A system of expenditures at full-service restaurants, fast-food restaurants and other facilities are estimated with a multivariate sample selection procedure, for three types of households by household composition. Statistical significance of error correlations suggests endogeneity of sample selectivity and justifies estimation of the equations in a system to improve statistical efficiency. Differentiated effects of economic and demographic factors are found on expenditures at different facilities and across household types. Findings on the roles of economic and socio-demographic factors can inform marketing strategies and policy deliberations.
    Keywords: C31 - Cross-Sectional Models ; Spatial Models ; Treatment Effect Models, D12 - Consumer Economics: Empirical Analysis, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
    Print ISSN: 0165-1587
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    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 37
    Publication Date: 2011-11-24
    Description: We use a stochastic dynamic programming model to simulate the market implications of alternative foot and mouth disease scenarios in the Finnish pig sector. The model considers the dynamics of animal stock adjustment and price movements when the duration of export disruptions is unknown. Explicit treatment of these issues is crucial in the economic analysis of livestock epidemics, especially if there is a risk of a prolonged export ban. Results suggest that the risk of a prolonged ban increases disease losses considerably. It also increases economic benefits from production adjustments.
    Keywords: C61 - Optimization Techniques ; Programming Models ; Dynamic Analysis, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness, Q18 - Agricultural Policy ; Food Policy
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    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 38
    Publication Date: 2011-11-24
    Description: Consumers' preferences for food safety characteristics are investigated with a particular focus on the existence of an embedding effect. Embedding exists if consumer valuation of food safety is insensitive to scope. We conduct between-attribute external tests for embedding in two choice experiments concerning the value of food safety attributes in minced pork and chicken breasts. We find no evidence of embedding neither when using food safety attributes that are not close substitutes and which exhibit both private and public good characteristics, nor when using food safety attributes that are closer substitutes and which have primarily private good characteristics.
    Keywords: Q10 - General, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness, Q18 - Agricultural Policy ; Food Policy
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    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 39
    Publication Date: 2011-11-24
    Description: This paper presents an empirical investigation of the link between intangible expenses of French wine companies and their financial performance. A flexible moment-based approach is used to analyse the impact of tangible and intangible expenses on the mean, variance and skewness of profit. Econometric evidence shows that a high level of intangible expenses has a positive impact on performance by increasing the expected profit and reducing variance risk. A lower level of intangible expenses reduces risk and mean of profit of corporations. This study provides insights on the use of intangible expenses as a risk management tool.
    Keywords: G32 - Financing Policy ; Financial Risk and Risk Management ; Capital and Ownership Structure, Q12 - Micro Analysis of Farm Firms, Farm Households, and Farm Input Markets, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
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    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 40
    Publication Date: 2011-11-24
    Description: Economists frequently use choice experiments (CEs) to evaluate demand for new attributes in food products. Using a split-sample experimental design focused on demand for pork chop attributes, we find consumer inferences regarding food safety and quality to impact estimates of marginal willingness to pay, market participation, policy appropriateness and consumer welfare effects. Our results suggest that interpretation of findings should be noted as conditional on attributes included in original analyses. A split-sample experimental approach involving multiple CE designs is described and suggested to practitioners to better consider consumer inference effects in future studies.
    Keywords: B40 - General, D12 - Consumer Economics: Empirical Analysis, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness, Q18 - Agricultural Policy ; Food Policy
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  • 41
    Publication Date: 2011-11-24
    Description: Geographical origin labels are important information and marketing tools and have recently become a central component of EU agricultural promotion. We consider demand in a non-EU export market for two distinct label types: country of origin (COO) and geographical indications (GIs). Additionally, two types of GIs, ‘protected designations of origin’ (PDOs) and ‘protected GIs’ (PGIs) are considered. Empirical findings indicate consumers’ willingness to pay varies with the oil's COO and is greater for GIs than for non-GIs from a given country. Weaker evidence that consumers value PDOs more than PGIs is also found.
    Keywords: C25 - Discrete Regression and Qualitative Choice Models, D12 - Consumer Economics: Empirical Analysis, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness
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  • 42
    Publication Date: 2011-12-27
    Description: European cattle markets have recently undergone significant change. We explore the simultaneous impacts of agricultural policy reform and the occurrence of an animal health crisis on spatial interdependencies of calf prices of four major European Union markets. The markets are found to be integrated. Price shocks are rapidly absorbed. We find that the member state specific implementations of the 2003 Common Agricultural Policy reforms significantly affected prices of both the national market and of other member states. The blue tongue disease further induced structural change. Using counterfactual scenarios, we show that the decoupling of payments from production led to reduced calf prices.
    Keywords: C32 - Time-Series Models, Q13 - Agricultural Markets and Marketing ; Cooperatives ; Agribusiness, Q18 - Agricultural Policy ; Food Policy
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  • 43
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    Biopolymers 2 (1964), S. 1-8 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The results of electrophoresis experiments on aqueous solutions of native and thermally denatured DNA are reported. A significant decrease of the electrophoretic mobility has been observed following thermal denaturation, which under suitable conditions gives rise to a resolution into two peaks of 1 : 1 mixtures in the electrophoretic pattern. This result is entirely consistent with the previously reported increase of the activity coefficient of sodium counterions following thermal denaturation. The hypothesis that thermal denaturation of calf thymus DNA induces a large decrease of charge density on the macroion which has been ascribed to the population of more extended conformations of the chains in the disordered region of the molecule is therefore further confirmed.
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  • 44
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The kinetics of the depolymerization of native dextran in dilute hydrochloric acid at different temperatures has been followed by measurements of M̄w, M̄n, [η], 〈ρ2〉1/2, and S. The data allow the correlation of the various parameters of the total hydrolyzate at various degrees of depolymerization. At a first approximation the results conform to a random splitting of a statistical, branched polymer.
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  • 45
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The γ-ethyl-L-glutamate NCA polymerization initiated by di-n-butyl and di-isopropyl amine was studied. The experimental kinetic curves show an autocatalytic portion with 25-30% conversion, followed by a pseudo first-order region which extends up to at least 85-90%. In this linear region, the reaction order appears to be 0.5 in initiator with both amines. High degrees of polymerization and high reaction rates were observed. These results are similar to those obtained in the γ-benzyl-L-glutamate NCA polymerization initiated by sodium methoxide.
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  • 46
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The dielectric constant and the electric birefringence of poly-γ-benzyl-L-glutamate in ethylene dichloride-dichloroacetic acid mixtures have been measured as functions of the solvent composition. These properties undergo a marked decrease with the addition of a small amount of dichloroacetic acid, as well as an abrupt change accompanying the helix-coil transition in the vicinity of 75 vol.-% dichloroacetic acid. The former is attributed to the apparent diminution of the dipole moment of helical poly-γ-benzyl-L-glutamate molecule, which may be due to the protonation of terminal amide groups.
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  • 47
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    Biopolymers 2 (1964) 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 48
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The polymerization of γ-benzyl-L-glutamate NCA initiated by n-hexylamine in DMF proceeds with two successive propagation rates whose ratio is about 1.5. The onset of the increase in rate of propagation occurred at a DPn of 7-14, which was independent of initiator to anhydride ratio and anhydride concentration and not a result of anhydride impurities. The increase in rate is likely a result of a conformational change in the polymer at a DPn of 7-14.
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  • 49
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    Biopolymers 2 (1964), S. 147-161 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The NCAs of the N-benzyl derivatives of β-alanine, β-DL-aminobutyric acid, and β-DL-aminoisobutyric acid (nonplanar six-membered rings) were prepared by reacting the corresponding N-chloroformyl derivatives, obtained on reaction of the N-benzyl amino acids with phosgene, with triethylamine. Contrary to the others, the NCA of N-benzyl-β-alanine polymerized readily on heating in vacuo or in solution, using n-hexylamine or methanolic sodium methoxide as initiators. With n-hexylamine the molecular weights of the polymers obtained in benzene, dioxan, and dimethylsulfoxide, were in accordance with DP = [NCA]/[Initiator], as was found with conventional five-membered ring NCAs of α-amino acids. With sodium methoxide initiation, DPs of the polymers obtained were smaller than the (NCA)/[Initiator] ratio, contrary to what was found previously with α-amino acid NCAs. The possibility that stereochemical factors are responsible for the differences in polymerization activity of various. N-alkyl β as well as α amino acid NCAs is discussed.
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    Biopolymers 2 (1964), S. 231-236 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The electrophoretic mobility of DNA in the presence of tetramethylammonium and alkali metal ion chlorides has been studied as a function of ionic strength. Each cation exhibits a characteristic behavior in accord with the idea that the order of inter-action with DNA is Li+ 〉 Na+ 〉 K+ 〉 TMA+. The application of theories of the electrophoresis of polyelectrolytes is discussed, leading to an attempt to calculate the fractional charge per DNA phosphorus from the mobility data. Over the range 0.05-0.4M a constant and unique value of the DNA charge is obtained in the presence of each cation. Values of the zeta potential and of the friction factor per monomer unit are also calculated.
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  • 52
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    Biopolymers 2 (1964), S. 135-146 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A simple quantitative theory of inactivation of transforming DNA has been formulated. It is based on the idea that genetic recombination of the molecule of transforming DNA with the bacterial genome is possible only, from the point mutation of the gene up to the nearest hit or point of damage on the corresponding DNA molecule. Our data and the data of other authors on the kinetics of inactivation by HNO2 or U.V. light or both are consistent with these theoretical predictions. Theoretical predictions were made concerning the extent of reactivation by fusion mid annealing of damaged DNA with a diluting genetically inactive DNA. These estimates have been reasonably confirmed by our experimental results.
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  • 53
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    Biopolymers 2 (1964), S. 15-25 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In order to study the effect of glucose substitution on the sedimentation velocities of the T-even phage DNA's, T2 and T2*, and T6 and T6* bacteriophages were grown with H3and P32 labeling. Zone sedimentation of the DNA's isolated from these phagea showed that the glucosylated DNA's from both T2 and T6 sediment faster than the nonglucosylated molecules. Nonglucosylated DNA from TG and T2 phages sedimented with the same velocity, suggesting that the molecules of these phages are of the same length.
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    Biopolymers 2 (1964), S. 43-49 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: We report a simple method for measuring partial specific volumes, of polymers in dilute solutions with an accuracy of 3 parts per thousand. This method has been applied to 7 polypeptides in 4 organic solvents. The residue volumes deduced from these data are compared to those calculated by a differential method. The discrepancy is generally of the order of 1.5%.
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    Biopolymers 2 (1964), S. 283-286 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 56
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    Biopolymers 2 (1964) 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 57
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: It is shown that the formation of the three-strand poly (A + 2U) complex is accompanied by a decrease in optical absorbance at 280 mμ, while the format ion of poly (A + U) is not. This difference makes it possible to demonstrate that in dilute solutions (∼10-4 monomolar), a 1 : 1 mixture of poly A and poly U always forms poly (A + U) at room temperature. At higher temperatures in solutions containing more than about 0.2M sodium ion, poly (A + U) is converted to poly (A + 2U) and free poly A. These results are consistent with the observations reported by Miles and Frazier, using infrared absorption spectra, at much higher polymer concentrations. It is concluded that most of the physicochemical studies of 1 : 1 mixtures of poly A and poly U in dilute aqueous solution refer to the two-stranded species.A simple thermodynamic analysis is developed to explain the two- to three-strand conversion, and with the use of a “phase diagram” showing conditions of stability of the various poly A-poly U structures as a function of salt and temperature, it is possible to estimate the value of the enthalpy of formation of poly (A + 2U).
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    Biopolymers 2 (1964), S. 337-347 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Using a chromatographic technique, the adsorption of the polyribonucleotides s-RNA and poly-A provided with tri-n-butylammonium ions from an aqueous solution on to the surface of polymeric hydrocarbon granules has been demonstrated. The aqueous solution from which adsorption takes place is the aqueous phase which results on agitating together n-butanol (100), water (130), tri-n-butylamine (10), n-butyl ether (10), and glacial acetic acid (2.5) (parts by volume). Microporous polyethylene granules, microporous fluorinated polyethylene granules, and solid grains of polyethylene powder have been employed as adsorbents. The adsorbed polyribonucleotides could be eluted by aqueous solutions of sodium chloride, urea, or triethylammonium acetate. s-RXA with tri-n-butylammonium counterions could also be adsorbed on polymethacrylic acid in tri-n-butylammonium form and eluted therefrom with aqueous urea solutions. It is considered that the adsorption from aqueous solution of polyribonucleotides with tri-n-butylammonium counterions on polymeric hydrocarbon surfaces is mediated by hydrophobic bond formation. Van der Waals forces may also contribute to the bonding. It is suggested that studies on the adsorption of polynucleotides provided with counterions: possessing nonpolar groups at an aqueous solution-polymeric hydrocarbon interlace may permit the elaboration of experimental systems to serve as models for the evaluation of the role of hydrophobic and van der Waals bonding forces in the interaction of polynucleotides with cell membrane surfaces.
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    Biopolymers 2 (1964), S. 395-398 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Biopolymers 2 (1964), S. 361-380 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Deoxyribonucleic acids (DNA's) extracted from several biological sources have been studied by means of the flow dichroism method, using the transparent coaxial cylinder apparatus. This study has two purposes: (1) to make clear the hydrodynamic behavior of the DNA chain, and the regularity in the orientation of purine and phrimidine bases about the molecular axis; and (2) to develop this particular flow dichroism method as an established device for the study of chain regularity of DNA and other chain polymers. The velocity gradient dependence of dichroism agrees well, to a first approximation, with the behavior of a model of a hydrodynamically equivalent ellipsoid in revolution. Differences between theoretical and empirical curves have been tentatively ascribed to the flexibility of the chain under consideration. Two kinds of data, 1 lie rotary diffusion coefficient and internal dichroism, have been evaluated by a graphical device in which the double logarithmic plots of reduced dichroism and velocity gradient of flow are compared with the theoretical curve. The data obtained have shown good reproducibility for DNA samples prepared by the same method from the same biological source. However, a remarkable difference in internal dichroism and rotary diffusion constant has been observed between DNA groups of different biological origin. The difference may be caused by fragmentation of DNA during the deproteinization procedure, bill the possibility that some of these differences originate in the biological source of the DNA cannot be denied. Orientation of purine and phrimidine bases in aqueous solution is found to be quite regular in direction, as predicted by the Watson-Crick model. Dichroic spectra have shown that the direction of the oscillator dipole corresponding to the 260 mμ absorption band has a different angular relationship to the helical axis than the oscillator dipole for the 220 mμ band.
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    Biopolymers 2 (1964), S. 381-393 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A study of the super helical structure of synthetic polypeptides, such as poly-γ-benzyl-D (or L)-glutamate (PBDG or PBLG) was carried out. The PEG was dissolved in dimethylformamide (DMF). The solution was either allowed to remain at room temperature for a long time or poured into some fatty acid, such as formic acid, acetic acid, propionic acid, or caprylic acid. Whether the polymer precipitated slowly or rapidly depended upon the aging of the solution or the nature of the acid used. The precipitated gels revealed the coiled coil fibrils, but the feature and degree of coiling varied, depending upon the length of aging or the nature of the acid used for precipitation. After a short aging of the solution, there was no helical structure in the gels. After long aging, very fine-coiled coil macrofibrils or small spindle-like fibrils were obtained. The macrofibrils consisted of the spindle-like fibrils which in turn consisted of microfibrils (diam. 60-70A.). When using the fatty acid precipitation very fine to medium fine super helices were obtained. Extremely fine super helices were obtained in propionic acid. In these gels the PBG chains have an α-helical conformation. When PMLG-DCA solution was stored for a long time, another type of precipitation was obtained, one giving evidence of so-called cross-β crystallization and no coiled coil fibrils. The precipitation of cross-β fibrils was obtained when the concentration of the solution was above 8%.
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  • 62
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    Biopolymers 2 (1964) 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 63
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    Biopolymers 2 (1964), S. 399-413 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Titration studies of the 1 : 1 helical polynucleotide complex of polyinosinic acid and polycytidylic acid reveal that these two polymers form a complex when the polycytidylic acid is protonated near pH 3. Sedimentation studies show that the protonated complex also has a 1 : 1 stoichiometry. However, the protonated complex is more stable than the unprotonated neutral complex as judged by its thermal stability. The molecular structure of the protonated complex is not the same as the neutral form. Study of the kinetics of the reaction of the protonated complex with formaldehyde suggests that the amino group of cytosine is involved in hydrogen bonds which hold the polynucleotide strands together.
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  • 64
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    Biopolymers 2 (1964), S. 415-444 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The protein sequences now known have been reconstructed as a kind of intriguing logical-mathematical puzzle using information about fragments of the molecules. We wish to show that the reconstruction can be done systematically by repeating a series of elementary operations on these same data governed by a set of well-defined rules. The completely automatic reconstruction of polymer sequences by a high speed digital computer using these operations and rules is demonstrated.
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  • 65
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    Keywords: Chemistry ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology
    Notes: The mechanism of the renaturation of DNA molecules is examined on the basis of the bimolecular interaction of Gaussian chain polymers. In the nucleus formation by hydrogen bonding in segment-segment interaction, two types of interchain interaction, that is, one between complementary chains and one between noncomplementary chains, and one noncomplementary intrachain interaction are considered to be, in competition. Several previously observed characteristics of the renaturation process are displayed by this simple model. In particular it accounts for the dependence of the extent of renaturation on the heterogeneity, molecular weight, and radius of gyration of DNA, and of the ratios of the reaction rates between complementary and noncomplementary segments. Among these variables the ratio of reaction rates has shown to have a quite specific value, as high as the order of 104, which favors the complementary-strand interaction. This very great bias in favor of complementary strand interaction emphasizes that the renaturation phenomena displays the same character of biological specificity that is associated with enzyme-substrate interaction or antigen-antibody interaction. Moreover, since DNA is a good example of a one-dimensional system, it seems to provide a suitable clue for pursuing the analysis of pattern recognition at the macromolecular level.
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  • 66
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    Biopolymers 2 (1964), S. 463-481 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The polymerization of DL-β-Phenylalanine N-carboxy anhydride adsorbed on polysarcosine dimethylamide has been studied further. This unusual reaction, which is analogous kinetically to reactions catalyzed by enzymes, was called the “chain-effect.” For polymerization of N-carboxy anhydrides by this mechanism it is necessary that the initiating polymer should possess an adsorption site and a terminal base group. The effect is shown to occur with simple compounds such as amino acid dimethylamides but not with poly-L-proline due to the inability of this polymer to adsorb the anhydride. From a study of the reaction of block copolymers of L-proline and sarcosine with DL-β-phenylalanine it is concluded that the relative positions of the adsorption site and terminal base group do not greatly influence the reaction rate, but the accessibility of the adsorption sites is an important factor determining the reactivity of polysarcosine dimethylamides of various degrees of polymerization (n). At high values of n the polymer exists in a coiled form and only those sites close to the terminal base group participate in the reaction. Initial rate studies give a detailed description of the early stage of the chain-effect polymerization. With these data and by use of analog computer techniques the complete reaction has been studied. It is concluded that the poly-DL-β-phenylalanine block produced is not permanently attached to the polysarcosine chain by hydrogen bonds during its formation but that an equilibrium exists between the polysarcosine and the poly-DL-phenylalanine blocks.
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  • 67
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    Keywords: Chemistry ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology
    Notes: Del Re's method for the study of saturated compounds has been adapted so as to deal with the σ-framework of conjugated molecules. This modified procedure is used in evaluating the σ-contribution to the dipole moments of the nucleic bases and of the A-T and G-C base pairs and also to the free energy change in the tautomeric, equilibria of the bases. Associated with an appropriate Hückel method for evaluating the π-contribution, the results obtained predict a small resultant moment for A-T versus a large moment for G-C. The energy calculations predict the keto and amino forms of the bases to be the most stable forms and cytosine to be the most easily involved in tautomeric shift to the rare form.
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    Biopolymers 2 (1964) 
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    Keywords: Chemistry ; Polymer and Materials Science
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  • 69
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    Keywords: Chemistry ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology
    Notes: Temperature jump measurements employing optical rotation to follow transients show an upper limit of 10μsec. on the half time of the helix-random coil relaxation in poly-α, L-glutamic acid. No relaxations are observed under conditions where the polymer exists in completely helical or completely random coil form. Assuming that the helix-coil transition can be described kinetically as a pure growth process, expressions for the relaxation time are derived for three special cases. A comparison is made between the rate of the helix-coil transition and the rate of imide proton exchange.
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    Biopolymers 2 (1964), S. 501-501 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
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    Biopolymers 2 (1964), S. 561-574 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Numerical calculations have been done on the exciton spectrum of a schematic model of a linear polymer. The model consists of a random sequence of two kinds of subunit whose energy levels and transition moments are almost, but not quite, the same. The orders of magnitude of parameters are taken from DNA, but the full helical geometry has not been considered. Results are given for the density of energy levels, the dipole transition strength per unit energy, and the distribution of excitation energy along the polymer in individual states. A number of localized exciton states were found.
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    Biopolymers 2 (1964) 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Biopolymers 2 (1964), S. 9-14 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A calculation based upon Gorin's equation for the electrophoresis of a rigid cylinder is used to compare the available results of electrophoresis and membrane equilibrium experiments on DNA. The distribution of chloride ions across a membrane impermeable to DXA is considered. For a reasonable choice of parameters, agreement within about 2% is obtained between the values calculated from electrophoresis and the results of membrane equilibrium studies over a twenty-fold range of NaCl concentration.
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  • 74
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    Keywords: Chemistry ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology
    Notes: Light-scattering, sedimentation, viscosity, and reducing power measurements have been carried out on a sample of native dextran from Leuconostoc mesenteriodes B-512. The results are discussed in relation to the structure, polydispersity, and branching of the polysaccharide. The effect of different solvents on the behavior of native dextran has been studied. The molecular weight of the dextran remains unchanged in all the solvents used, while the radius of gyration shows a significant increase in some of them (concentrated salts, urea, and glucose solutions); in water-methanol solutions the radius of gyration slightly decreases.
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    Biopolymers 2 (1964), S. 65-68 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology
    Notes: The statistical mechanical theory of the helix-coil transition of DNA has been recently discussed by one of the authors, who considered an assembly of DNA molecules with a Markoff distribution of nucleotide sequences. The present communication improves upon the above mentioned theory by introducing approximate normalization factors for the unnormalized statistical weights of finding a given molecule of the assembly in a given microscopic state.
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    Biopolymers 2 (1964), S. 103-103 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Biopolymers 2 (1964), S. 79-89 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The effect of small quantities of metal ions on the electrophoretic mobility of calf thymus DNA in solutions maintained at 0.2 ionic strength with weakly interacting (CH3)4N+ ions yields information about interactions occurring in a region very close to the polymer chain. By means of this technique, it is demonstrated that the binding order to DNA is Li+ 〉 Na+ 〉 K+ for the alkali metal ions and Mn++ 〉 Mg ++ 〉 Ca++ for the divalent ions studied. The quantitative details are compared to earlier work on the long-chain polyphosphates. Close agreement between the two systems is obtained indicating that an intrinsic property of individual phosphate groups is being observed and that minor discrepancies probably arise from secondary factors. Three types of stability constants representing the binding of alkali metal ions to DNA are calculated and although differing in absolute magnitude, they all satisfactorily represent the result that the order of interaction is Li+ 〉 Na+ 〉 K+ with respective relative strengths of 1.5 : 1 : 0.8.
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    Biopolymers 2 (1964), S. 113-121 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Topics: Chemistry and Pharmacology
    Notes: Birefringence relaxation times on removing the electric field characterize the rigidity of a flexible linear macromolecule structure. Electrical birefringence investigation of DNA solutions supports this view. This principal regularities displayed by relaxation times of electric birefringence decay curves in solutions of chain macromolecules are considered.
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    Berichte der deutschen chemischen Gesellschaft 97 (1964), S. 186-189 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: m-Dinitro-benzol und einige seiner Derivate (I, II, VII) lassen sich durch aufein-anderfolgende Einwirkung von Alkylmagnesiumhalogeniden, Methylamin/Formaldehyd und Essigsäure zu Mannich-Verbindungen von Dinitrodialkylcyclohexenen (Vb-e, VIII) umsetzen.
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    Berichte der deutschen chemischen Gesellschaft 97 (1964), S. 132-139 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 3-Brom-cyclo-penten,-hexen und-hepten reagieren mit Lithiumaluminiumhydrid unter Bildung der jeweiligen cyclischen Monoolefine. Ann substituierten 3-Brom-cyclohexenen wurde gezeigt, daß die Reaktion sowohl als einfache nucleophile Substitution des Broms durch Wasserstoff als auch unter Allylumlagerung mit Angriff des Hydridions am C-Atom 1 verläuft. Die in beiden Allylstellungen bromierten cyclischen Olefine reagieren mit Lithiumaluminiumhydrid unter Bildung mehrerer Produkte, die durch Angriff des Hydrids an einem halogentragenden C-Atom (a), an einem olefinischen C-Atom (b) und an einem Brom-atom (c) entstanden sind. Reaktion (a) liefert Monoolefin, (b) ergibt 4-Bromolefin und nach (c) entsteht 1.3-Diolefin. Die Eliminierung nach (c) wurde allerdings nur am unsubstituierten Cyclohexen- und Cycloheptendibromid beobachtet. Für die Eliminierung wird ein weitgehend koplanarer Übergangszustand angenommen, der bei den anderen untersuchten Dibromiden nicht möglich ist.
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    Berichte der deutschen chemischen Gesellschaft 97 (1964), S. 165-168 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Desaminierung des 9-Amino-Δ4(10)-octalins in essigsaurer Lösung gibt zu etwa 80% die substituierten Allylalkohole Δ9(10)-Octalol-(1) und Δ4(10)-Octalol-(9) nebst Acetat, sowie die aus diesen durch normale Wasserabspaltung hervorgehenden Hexaline.
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    Berichte der deutschen chemischen Gesellschaft 97 (1964), S. 179-185 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Umsetzung von β-Phenäthylmercaptan mit Aldehyden und Chlorwasserstoff entstehen [α-Chlor-alkyl]- β-phenäthyl-sulfide, die mit Aluminium-chlorid unter Ringschluß zu Isothiochromanen reagieren. - 1-Chlor-isothio-chroman, durch Einwirkung von Chlor auf Isothiochroman gewonnen, liefert mit Alkyl- oder Arylmagnesiumhalogeniden 1-Alkyl- bzw. 1-Aryl-isothiochromane, mit Mercaptanen 1-Alkylmercapto-, mit sekundären Aminen 1-Di-alkylamino- und mit Alkoholen 1-Alkoxy-isothiochromane. - Durch Umsetzung der letzteren mit Natriumhydrogensulfit entsteht Isothiochroman-sulfonsäure-(1), die in Isothiochroman-S-dioxid-sulfonsäure-(1) bzw. deren Ester übergeführt werden kann.
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    Berichte der deutschen chemischen Gesellschaft 97 (1964), S. 218-224 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1.2-Benzpyren gibt der Bromierung das 5.8-Dibromderivat II und bei der Chlorierung das 3.5.8.10-Tetrachlorderivat V. Aus II wird das 5.8-Dinitril III und daraus die entsprechende Dicarbonsäure IV dargestellt. Die Hydrierung des 1.2-Benzpyrens führt zunächst zu einer Hexahydroverbindung, die ein Anthracenderivat ist, und dann zu dem Decahydro-1.2-benzpyren VI, das einen Naphthalinkern enthält. Die Oxydation verläft sehr komplex und liefert neben dunklen Kondensationsprodukten nur geringe Mengen zweier Säuren, die bei der Decarboxylierung Phenanthren und Triphenylen geben. - 3.4-Benzpyren liefert unter milden Bedingungen das 5-Brom-Derivat VII. Weitere Chlorierung von Trichlor-3.4-benzpyren VIII führt zum Trichlor-3.4-benzpyren-tetrachlorid IX.
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    Berichte der deutschen chemischen Gesellschaft 97 (1964), S. 249-254 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Produkte des Zerfalls der 1.2-Benzo-cyclenyl-(4)-diazonium-lonen (II) in Essigsäure werden mit denen der Acetolyse der 1.2-Benzo-cyclenyl-(4)-tosylate (VI) verglichen. Die erste Reaktion vollzieht sich am Beispiel des Vertreters mit 7-gliedrigem Ring mit 53-proz., die zweite mit 89-proz. Konfigurationserhaltung.
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    Berichte der deutschen chemischen Gesellschaft 97 (1964), S. 282-284 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Thioschwefelsäure läß sich mit Thionylchlorid in guten Ausbeuten unter Chlorwasserstoffabspaltung zu einem äquimolaren Gemisch aus Disulfan-disulfonsäure und Trisulfan-disulfonsäure oxydieren. Mit Sulfurylchlorid bildet H2S2O3 neben HCI und Schwefeldioxid reine H2S4O6.
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    Berichte der deutschen chemischen Gesellschaft 97 (1964), S. 285-294 
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    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 4.5.8-Trihydroxy-6-mercapto-chinolin-carbonsäure-(2) (II) wird durch Spaltung des Xanthogenats XV mit Aluminiumbromid dargestellt. Die Spaltung von XV mit Bromwasserstoffsäure führt zur reduktiven Abspaltung der Schwefelfunktion. Bei der Methylierung von II mit Diazomethan entsteht neben dem vollmethylierten Chinolinderivat XXI ein Chinolon XXII, bei dem die zur Chinolon-Carbonylgruppe peri-ständige 5-Hydroxygruppe unmethyliert bleibt. II ist wider Erwarten nicht identisch mit einem aus dem Ommochrom „Ommin A“ dargestellten Abbauprodukt.
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    Berichte der deutschen chemischen Gesellschaft 97 (1964), S. 300-301 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
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    Topics: Chemistry and Pharmacology
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    Berichte der deutschen chemischen Gesellschaft 97 (1964), S. 307-311 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Oxydation von Pyrogallol in alkoholischer Lösung wird Purpurogallincarbonsäure-(9)-ester gebildet, dessen Konstitution sich aus dem Abbau zu Purpurogallin und Methylterephthalsäure ergibt.
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    Berichte der deutschen chemischen Gesellschaft 97 (1964), S. 312-324 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1′.2′-Dihydroxy-benzotropolon-Derivate können nach zwei Methoden dargestellt werden: 1.aus 3 Moll. eines o-Benzochinons mit unsubstituierter Doppelbindung und 1 Mol. eines geeigneten Pyrogallolderivates, 2. durch Oxydation eines Gemisches geeigneter Brenzcatechin- und Pyrogallolderivate mit KJO3 bzw. K3[Fe(CN)6]. Bei der Umsetzung von o-Benzochinonen mit 4-Methylpyrogallol wird nur dasjenige Isomere (I a) gebildet, bei welchem die Reaktionspartner im Orientierungskomplex die räumlich günstigste Anordnung (Methylgruppe auf der von der Verknüpfungsstelle abgewandten Seite) haben. Zwei Synthesen für Trimethylpyrogallol und die Darstellung von 2′-Hydroxy-benzotropolon-chinon-(1′.4′) (VIII) werden beschrieben.
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    Berichte der deutschen chemischen Gesellschaft 97 (1964), S. 349-362 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: symm. Tetra-pyrenyl-(3)-äthan (III), symm. Di-pyrenyl-(3)-diphenyl-äthan (VII), 2.3-Di-[pyrenyl-(3)]-butan (IX), 2.2.5.5-Tetramethyl-3.4-diphenyl-3.4-di-[pyrenyl-(3)]-hexan (X) und Hexa-pyrenyl-(3)-äthan (XI) wurden dargestellt und ihre Fähigkeit zur Dissoziation in Radikale bei Raumtemperatur mit Hilfe der Elektronenspinreasonanz -Method (ESR) untersucht. Mit Ausnahme von 2.3-Di-[pyrenyl-(3)]-butan sind sämtliche der untersuchten Verbindungen bei Raumtemperatur partiell, das Hexa-[pyrenyl-(3)]-äthan erwartungsgemäß quantitativ dissoziiert. Beim symm. Tetra-α-naphthyl-äthan (VIII) ist dagegen keine Radikaldissoziation nachweisbar. - Das von Pyren ausgehend in guter Ausbeute in zweistufiger Synthese darstellbare symm. Tetra-pyrenyl-(3)-äthan ist im organischen Solvens bei Raumtemperatur unlöslich. Es ist im festen Zustand zu 0.0025% in Radikale dissoziiert. - Die Abhängigkeit der Carbonylfrequenz im IR-Spektrum von Mono- und Diarylderivaten des Formaldehyds vom Kondensationsgrad des Arylrestes wurde untersucht.
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  • 91
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    Berichte der deutschen chemischen Gesellschaft 97 (1964), S. 390-395 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 3-Halogen-pyridazine reagieren mit Anthranilsäure oder Anthranilsäure-äthyl-ester zu Pyridazino[3.2-b ]chinazolonen-(10), deren Eigenschaften beschrieben werden.
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  • 92
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    Berichte der deutschen chemischen Gesellschaft 97 (1964), S. 382-389 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei Eliminierung des Chlors aus cis-3.4-Dichlor-cyclobuten mittels Natriumamalgam in äther. Lösung entsteht das syn-Tricyclo[4.2.0.02.5]octadien-(3.7) (I), identisch mit dem früher aus 1.2.3.4-Tetrabrom-cyclobutan erhaltenen Produkt. Bei ähnlicher Behandlung mit Lithiumamalgam bildet sich überwiegend das isomere anti- Tricycloocatadien (II). Die Ozonspaltung und einige Derivate dieser Kohlenwasserstoffe werden beschrieben.
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  • 93
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 97 (1964), S. 415-418 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Umsetzung von L-Tryptophan mit D-Fructose liefert kristallisierte 2-Nα-L-Tryptophan-2-desoxy-D-glucose(I), mit D-Glucose 1-Nα-L-Tryptophan-1-desoxy-D-fructose (II), Aus L-Histidin und D-Fructose entsteht 2-Nα-L-Histidin-2-desoxy-D-Glucose (II).
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  • 94
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 97 (1964), S. 426-432 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Umsetzung der Hexacarbonyle der Chromgruppe mit Bipyridyl-(2.2′) bzw. 1.10-Phenanthrolin geht die Substitution über die Tetracarbonylstufen M(CO)4bipy bzw. M(CO)4phen hinaus, wenn man in hochsiedenden Kohlenwasserstoffen, wie Decalin, Tetralin oder 1-Methyl-naphthalin arbeitet. Während mit Mo(CO6 und W(CO)6 die Dicarbonylverbindungen M(CO)2bipy2 bzw. M(CO)2phen2 gebildet werden, entstehen mit Cr(CO)6 die totalsubstituierten Typen Cr(bipy)3 und Cr(phen)3.
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  • 95
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Hexacarbonyle M(CO)6 (M=Cr, Mo, W) setzen sich bei 120° mit flüssigem NH3 zu den Tricarbonyltriamminverbindungen M(CO)3(NH3)3 um; nur beim Cr(CO) 6 ist bei 80° auch Cr(CO)5NH3 zugänglich. Bei den Reaktionen von M(CO)4bipy und M(CO)4phen (bipy = Bipyridyl-(2.2′), phen = 1.10-Phenanthrolin) mit flüssigem NH3 erfolgt bei 120° Substitution einer CO-Molekel unter Bildung der Verbindungstypen M(CO)3 bipyNH3 bzw. M(CO)3phenNH3. Bei den Umsetzungen von M(CO)4bipy mit Kaliumcyanid in flüssigem NH3 wird bei 60° bipy vollständig durch CN⊖ ersetzt. Hierbei werden mit Cr(CO)4bipy K2[Cr0(CO) 4(CN)2], mit Mo(CO)4bipy und W(CO)4bipy unter gleichzeitiger CO-Substitution K3[M0(CO) 3(CN)3] gebildet.
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  • 96
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 97 (1964), S. 472-479 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aryl- und Alkylisocyanate reagieren mit Benzolderivaten unter Friedel-Crafts-Bedingungen zu N-substituierten Benzoesäureamiden. Auch die wenig reaktionsfähigen Halogenbenzole sind der Umsetzung zugänglich.
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  • 97
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    Berichte der deutschen chemischen Gesellschaft 97 (1964), S. 563-565 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Das kürzlich als 2-Hydroxy-4.5-epoxy-6-O-methyl-tetrahydro-apogalanthamin beschriebene Abbauprodukt aus Galanthamin wurde als (-)-Epigalanthamin identifiziert.
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  • 98
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 97 (1964), S. 579-587 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Wegen der zentralen Stellung der Chinonmethide in der Chemie des Lignins wurden 3 niedermolekulare p-Chinonmethide auf ihre chemischen Reaktionen und ihre Polymerisation untersucht. Die Polymerisate sind zur monomeren Stufe abzubauen und bestehen aus fortlaufend verätherten p-Hydroxy- benzyl-alkoholen (Polybenzylaryläthern) vom Typus XX.
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  • 99
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    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 97 (1964), S. 602-609 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die cis-Formen geometrischer Isomerenpaare scheinen ganz allgemein energie ärmer zu sein, wenn nicht H-H-Wechselwirkung oder extreme Raumbeanspruchung wie beim 1.2-Dijod-äthylen vorliegen. Die Isolierung der geometrischen Isomeren der im Titel genannten Verbindungen erlaubt deren Strukturzuordnung und die Untersuchung der thermischen Gleichgewichte. Die cis-cis-Isomeren sind in Benzollösung energetisch gegenüber den trans-trans-Isomeren stark bevorzugt, welche bei den Meßtemperaturen von 100° und 150° nur zu 10 bis 15% im Gleichgewicht vertreten sind.
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  • 100
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Messungen der Optischen Rotationsdispersion und des Zirkulardichroismus von N-Phthalyl-aminen beweisen die Existenz von mindestens einer optischaktiven Absorptionsbande im Bereich oberhalb von 300 mμ, die im UV-Spektrum nicht erkennbar ist. Aus dem Vorzeichen der zugehörigen Cotton-Effekt-Kurve kann die absolute Konfiguration bestimmt werden: N-Phthalyl-Derivate optisch-aktiver Amine der (R)-Reihe zeigen einen negativen Cotton-Effekt, solche der (S)-Reihe einen positiven. Entsprechende Messungen an N-Phthalyl-Derivaten von α-Aminosäuren führten zum Nachweis von mindestens zwei optischaktiven Absorptionsbanden, die wiederum im UV-Spektrum nicht erkennbar sind. Die vorliegende Untersuchung stellt ein weiteres Beispiel dar für die Anwendung der Optischen Rotationsdispersion und besonders des Zirkulardichroismus zur Ermittlung verdeckter Absorptionsbanden.
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