ALBERT

Description: The aerosol size distribution and cloud condensation nuclei (CCN) number concentration were measured using a wide-range particle spectrometer (WPS) and a cloud condensation nuclei counter (CCNC) on Mt. Tian from 31 July to 9 September, 2019. Combined with meteorological data, distribution characteristics of aerosol size and CCN and their influencing factors were analyzed. The results indicated that the mean aerosol number concentration was 5475.6 ± 5636.5 cm−3. The mean CCN concentrations were 183.7 ± 114.5 cm−3, 729.8 ± 376.1 cm−3, 1630.5 ± 980.5 cm−3, 2162.5 ± 1345.3 cm−3, and 2575.7 ± 1632.9 cm−3 at supersaturation levels of 0.1%, 0.2%, 0.4%, 0.6%, and 0.8%, respectively. The aerosol number size distribution is unimodal, and the dominant particle size is 30–60 nm. Affected by the height of the boundary layer and the valley wind, the diurnal variation in aerosol number concentration shows a unimodal distribution with a peak at 17:00, and the CCN number concentration showed a bimodal distribution with peaks at 18:00 and 21:00. The particle size distribution and supersaturation have a major impact on the activation of the aerosol into CCN. At 0.1% supersaturation (S), the 300–500 nm particles are most likely to activate to CCN. Particles of 100–300 nm are most easily activated at 0.2% (S), while particles of 60–80 nm are most likely activated at high supersaturation (≥0.4%). The concentrations of aerosol and CCN are higher in the northerly wind. Ambient relative humidity (RH) has little relationship with the aerosol activation under high supersaturation. According to N = CSk fitting the CCN spectrum, C = 3297 and k = 0.90 on Mt. Tian, characteristic of the clean continental type.

Description: The atmospheric boundary layer height is important for constraining air pollution and meteorological models. This study attempted to validate the MODIS-estimated atmospheric boundary layer height (ABLH), and variation in the ABLH in Uganda was evaluated. The ABLH was estimated from MODIS data using the mixing ratio profile gradient method and compared to the ABLH estimated from radiosonde data using three different methods. Unlike in studies in other regions of the world, correlations between ABLH estimated using MODIS and radiosonde data were weak, implying limited usefulness of MODIS data for determining ABLH. However, the diurnal variation in MODIS-derived ABLH and particulate matter (PM10) was consistent with the expected inverse relationship between PM10 mass concentration and ABLH, and the mean MODIS-derived ABLH values were significantly lower during wet seasons than dry seasons, as expected.

Description: In our previous studies, we investigated the performance of a novel pneumatic planar magnetic separator (PMS) for the dry beneficiation of a selected magnetite ore. In the present study, we have extended the studies on the PMS with the focus on investigating how various PMS processing flowsheet configurations influence its performance. The outcomes were subsequently compared with those of a Davis tube recovery (DTR) tester. The study demonstrated that the use of PMS in the dry beneficiation of magnetite ores is feasible, and operating the PMS in different flowsheet configurations positively influences the magnetite concentrate grade and purity. Finally, the study showed that the PMS performance compares well with that of DTR and can potentially replace DTR in operations that are carried out in arid regions.

Description: Festivals are experiential products heavily depending on the recommendations of previous visitors. With the power of social media growing, understanding the antecedents of positive electronic word-of-mouth (eWOM) intentions of festival attendees is immensely beneficial for festival organizers to better promote their festivals and control negative publicity. However, there is still limited research regarding eWOM intentions in the festival context. Thus, this study aims to fill such a gap by investigating the relationships among festival attendees’ enjoyment seeking motivation, perceived value, visitor satisfaction, and eWOM intention in a local festival setting. Additionally, the moderating role of gender was tested as it is one of the most important demographic variables to show individual differences in behavioral intentions. The results of structural equation modeling showed a positive effect of enjoyment seeking motivation on perceived value, visitor satisfaction, and eWOM intention. Moreover, gender differences in eWOM intention and a full mediating effect of visitor satisfaction between perceived value and eWOM intention for female respondents were revealed. The findings of this study extend the existing festival literature and provide insights for strategically organizing and promoting festivals to generate more positive eWOM which can be utilized as an effective marketing tool and a feedback channel.

Description: Ice accretion is a phenomenon whereby super-cooled water droplets impinge and accrete on wall surfaces. It is well known that the icing may cause severe accidents via the deformation of airfoil shape and the shedding of the growing adhered ice. To prevent ice accretion, electro-thermal heaters have recently been implemented as a de- and anti-icing device for aircraft wings. In this study, an icing simulation method for a two-dimensional airfoil with a heating surface was developed by modifying the extended Messinger model. The main modification is the computation of heat transfer from the airfoil wall and the run-back water temperature achieved by the heater. A numerical simulation is conducted based on an Euler–Lagrange method: a flow field around the airfoil is computed by an Eulerian method and droplet trajectories are computed by a Lagrangian method. The wall temperature distribution was validated by experiment. The results of the numerical and practical experiments were in reasonable agreement. The ice shape and aerodynamic performance of a NACA 0012 airfoil with a heater on the leading-edge surface were computed. The heating area changed from 1% to 10% of the chord length with a four-degree angle of attack. The simulation results reveal that the lift coefficient varies significantly with the heating area: when the heating area was 1.0% of the chord length, the lift coefficient was improved by up to 15%, owing to the flow separation instigated by the ice edge; increasing the heating area, the lift coefficient deteriorated, because the suction peak on the suction surface was attenuated by the ice formed. When the heating area exceeded 4.0% of the chord length, the lift coefficient recovered by up to 4%, because the large ice near the heater vanished. In contrast, the drag coefficient gradually decreased as the heating area increased. The present simulation method using the modified extended Messinger model is more suitable for de-icing simulations of both rime and glaze ice conditions, because it reproduces the thin ice layer formed behind the heater due to the runback phenomenon.

Description: Geospatial data is urgently needed in decision-making processes to achieve Sustainable Development Goals (SDGs) at global, national, regional and local scales. While the advancement of geo-technologies to obtain or produce geospatial data has become faster and more affordable, many countries in the global south still experience a geospatial data scarcity at the rural level due to complex geographical terrains, weak coordination among institutions and a lack of knowledge and technologies to produce visualised geospatial data like maps. We proposed a collaborative spatial learning framework that integrates the spatial knowledge of stakeholders to obtain geospatial data. By conducting participatory mapping workshops in three villages in the Deli Serdang district in Indonesia, we tested the framework in terms of facilitating communication and collaboration of the village stakeholders while also supporting knowledge co-production and social learning among them. Satellite images were used in digital and non-digital mapping workshops to support village stakeholders to produce proper village maps while fulfilling the SDGs’ emphasis to make geospatial data available through a participatory approach.

Description: In this study, the flotation behavior of malachite was investigated using hydrophobic talc nanoparticles (TNs) as collectors. To improve the floatability of TN-deposited malachite, various experimental parameters were systematically investigated. We found that the floatability sharply increased as the size of the TNs decreased. The floatability of malachite was enhanced in the presence of smaller TNs, since higher amounts of smaller TNs were deposited on the surface of the malachite, thus rendering the surface more hydrophobic. Moreover, the floatability of the TN-deposited malachite increased as the pH decreased, likely due to the more favorable interaction between TNs and malachite by means of electrostatic attraction. Furthermore, the floatability became more enhanced as the TN concentration increased, likely associated with increases in the amount of TNs deposited on the surface of the malachite, thus enhancing the floatability by altering the hydrophobicity of the surface. Our findings suggest that the application of natural hydrophobic TNs as collectors in malachite flotation should be introduced as a new concept.

Description: Failures of marine propulsion components or systems can lead to serious consequences for a vessel, cargo and the people onboard a ship. These consequences can be financial losses, delay in delivery time or a threat to safety of the people onboard. This is why it is necessary to learn about marine propulsion failures in order to prevent worst-case scenarios. This paper aims to provide a review of experimental, analytical and numerical methods used in the failure analysis of ship propulsion systems. In order to achieve that, the main causes and failure mechanisms are described and summarized. Commonly used experimental, numerical and analytical tools for failure analysis are given. Most indicative case studies of ship failures describe where the origin of failure lies in the ship propulsion failures (i.e., shaft lines, crankshaft, bearings, foundations). In order to learn from such failures, a holistic engineering approach is inevitable. This paper tries to give suggestions to improve existing design procedures with a goal of producing more reliable propulsion systems and taking care of operational conditions.

Description: In this study, the environmental impacts of various alternative ship fuels for a coastal ferry were assessed by the life cycle assessment (LCA) analysis. The comparative study was performed with marine gas oil (MGO), natural gas, and hydrogen with various energy sources for a 12,000 gross tonne (GT) coastal ferry operating in the Republic of Korea (ROK). Considering the energy imports of ROK, i.e., MGO from Saudi Arabia and natural gas from Qatar, these countries were chosen to provide the MGO and the natural gas for the LCA. The hydrogen is considered to be produced by steam methane reforming (SMR) from natural gas with hard coal, nuclear energy, renewable energy, and electricity in the ROK model. The lifecycles of the fuels were analyzed in classifications of Well-to- Tank, Tank-to-Wake, and Well-to-Wake phases. The environmental impacts were provided in terms of global warming potential (GWP), acidification potential (AP), photochemical potential (POCP), eutrophication potential (EP), and particulate matter (PM). The results showed that MGO and natural gas cannot be used for ships to meet the International Maritime Organization’s (IMO) 2050 GHG regulation. Moreover, it was pointed out that the energy sources in SMR are important contributing factors to emission levels. The paper concludes with suggestions for a hydrogen application plan for ships from small, nearshore ships in order to truly achieve a ship with zero emissions based on the results of this study.

Description: We compared the catalytic effects of two polymers (soluble starch and apple pectin) on the flocculation of kaolinite suspension. Moreover, the relationship between the zeta potential value and the time when kaolin particle sedimentation occurred was verified, and the mechanism of flocculation was analyzed. Additionally, a constitutive model was proposed to simulate the non-ideal sedimentation of clay particles in an aqueous system under constant gravity. This model not only considers the inhomogeneity of the solute but also simulates the change in clay concentration with time during the deposition process. This model proposes a decay constant (α) and sedimentation coefficient (s). The model can also be used to calculate the instantaneous sedimentation rate of the clay suspensions at any time and any depth for the settling cylinder. These sedimentary characteristics were simulated by adopting the established deposition model. The results show that the model is capable of predicting the time required for the complete sedimentation of particles in the aqueous system, suggesting the feasibility of engineering wastewater treatment, site dredging, etc.

Description: Dense β-SiC coating with 3C-structure was utilized as a dry cold forging punch and core-die. Pure titanium T328H wires of industrial grade II were employed as a work material. No adhesion or galling of metallic titanium was detected on the contact interface between this β-SiC die and titanium work, even after this continuous forging process, up to a reduction in thickness by 70%. SEM (Scanning Electron Microscopy) and EDX (Electron Dispersive X-ray spectroscopy) were utilized to analyze this contact interface. A very thin titanium oxide layer was in situ formed in the radial direction from the center of the contact interface. Isolated carbon from β-SiC agglomerated and distributed in dots at the center of the initial contact interface. Raman spectroscopy was utilized, yielding the discovery that this carbon is unbound as a free carbon or not bound in SiC or TiC and that intermediate titanium oxides are formed with TiO2 as a tribofilm.

Description: The manufacturing of parts from nickel-based superalloy Alloy 247LC by laser powder bed fusion (L-PBF) is challenging, primarily owing to the alloy’s susceptibility to cracks. Apart from the cracks, voids created during the L-PBF process should also be minimized to produce dense parts. In this study, samples of Alloy 247LC were manufactured by L-PBF, several of which could be produced with voids and crack density close to zero. A statistical design of experiments was used to evaluate the influence of the process parameters, namely laser power, scanning speed, and hatch distance (inherent to the volumetric energy density) on void formation, crack density, and microhardness of the samples. The window of process parameters, in which minimum voids and/or cracks were present, was predicted. It was shown that the void content increased steeply at a volumetric energy density threshold below 81 J/mm3. The crack density, on the other hand, increased steeply at a volumetric energy density threshold above 163 J/mm3. The microhardness displayed a relatively low value in three samples which displayed the lowest volumetric energy density and highest void content. It was also observed that two samples, which displayed the highest volumetric energy density and crack density, demonstrated a relatively high microhardness; which could be a vital evidence in future investigations to determine the fundamental mechanism of cracking. The laser power was concluded to be the strongest and statistically most significant process parameter that influenced void formation and microhardness. The interaction of laser power and hatch distance was the strongest and most significant factor that influenced the crack density.

Description: Laser-based technologies are extensively used for polymer surface patterning and/or texturing. Different micro- and nanostructures can be obtained thanks to a wide range of laser types and beam parameters. Cell behavior on various types of materials is an extensively investigated phenomenon in biomedical applications. Polymer topography such as height, diameter, and spacing of the patterning will cause different cell responses, which can also vary depending on the utilized cell types. Structurization can highly improve the biological performance of the material without any need for chemical modification. The aim of the study was to evaluate the effect of CO2 laser irradiation of poly(L-lactide) (PLLA) thin films on the surface microhardness, roughness, wettability, and cytocompatibility. The conducted testing showed that CO2 laser texturing of PLLA provides the ability to adjust the structural and physical properties of the PLLA surface to the requirements of the cells despite significant changes in the mechanical properties of the laser-treated surface polymer.

Description: Protected areas are the backbone of biodiversity conservation but are fixed in space and vulnerable to anthropogenic climate change. Myanmar is exceptionally rich in biodiversity but has a small protected area system. This study aimed to assess the potential vulnerability of this system to climate change. In the absence of good biodiversity data, we used a spatial modeling approach based on a statistically derived bioclimatic stratification (the Global Environmental Stratification, GEnS) to understand the spatial implications of projected climate change for Myanmar’s protected area system by 2050 and 2070. Nine bioclimatic zones and 41 strata were recognized in Myanmar, but their representation in the protected area system varied greatly, with the driest zones especially underrepresented. Under climate change, most zones will shift upslope, with some protected areas projected to change entirely to a new bioclimate. Potential impacts on biodiversity include mountaintop extinctions of species endemic to isolated peaks, loss of climate specialists from small protected areas and those with little elevational range, and woody encroachment into savannas and open forests as a result of both climate change and rising atmospheric CO2. Myanmar needs larger, better connected, and more representative protected areas, but political, social, and economic problems make this difficult.

Description: Information and communication technologies transform modern education into a more available learning matrix. One of the unexplored aspects of open education is the constant communicative interaction within the student group by using social media. The aim of the study was to determine principal functions of student-led communication in the educational process, the method for assessing its strong points and the disadvantages disrupting traditional learning. For the primary study of the phenomenon, we used methods that made it possible to propose approaches to further analysis. Netnography is the main research method defining the essence and characteristics of the student-led peer-communication. In our research, we applied data visualization, analytical and quantitative methods and developed a set of quantitative indicators that can be used to assess various aspects of student communication in chats. The elaborated visual model can serve as a simple tool for diagnosing group communication processes. We revealed that online group chats perform a support function in learning. They provide constant informational resource on educational and organizational issues and create emotional comfort. Identified features serve to define shortcomings (e.g., lack of students’ readiness to freely exchange answers to assignments) and significant factors (e.g., underutilized opportunities for self-organization) that exist in the modern system of higher education.

Description: Minerals from mantle xenoliths in the Zapolyarnaya pipe in the Upper Muna field, Russia and from mineral separates from other large diamondiferous kimberlite pipes in this field (Deimos, Novinka and Komsomolskaya-Magnitnaya) were studied with EPMA and LA-ICP-MS. All pipes contain very high proportions of sub-calcic garnets. Zapolyarnaya contains mainly dunitic xenoliths with veinlets of garnets, phlogopites and Fe-rich pyroxenes similar in composition to those from sheared peridotites. PT estimates for the clinopyroxenes trace the convective inflection of the geotherm (40–45 mW·m−2) to 8 GPa, inflected at 6 GPa and overlapping with PT estimates for ilmenites derived from protokimberlites. The Upper Muna mantle lithosphere includes dunite channels from 8 to 2 GPa, which were favorable for melt movement. The primary layering deduced from the fluctuations of CaO in garnets was smoothed by the refertilization events, which formed additional pyroxenes. Clinopyroxenes from the Novinka and Komsomolskaya-Magnitnaya pipes show a more linear geotherm and three branches in the P-Fe# plot from the lithosphere base to the Moho, suggesting several episodes of pervasive melt percolation. Clinopyroxenes from Zapolyarnaya are divided into four groups according to thermobarometry and trace element patterns, which show a stepwise increase of REE and incompatible elements. Lower pressure groups including dunitic garnets have elevated REE with peaks in Rb, Th, Nb, Sr, Zr, and U, suggesting mixing of the parental protokimberlitic melts with partially melted metasomatic veins of ancient subduction origin. At least two stages of melt percolation formed the inclined PT paths: (1) an ancient garnet semi-advective geotherm (35–45 mW·m−2) formed by volatile-rich melts during the major late Archean event of lithosphere growth; and (2) a hotter megacrystic PT path (Cpx-Ilm) formed by feeding systems for kimberlite eruptions (40–45 mW·m−2). Ilmenite PT estimates trace three separate PT trajectories, suggesting a multistage process associated with metasomatism and formation of the Cpx-Phl veinlets in dunites. Heating associated with intrusions of protokimberlite caused reactivation of the mantle metasomatites rich in H2O and alkali metals and possibly favored the growth of large megacrystalline diamonds.

Description: People spend most of their time in indoors and, as a result, indoor air quality has become an issue of increasing concern. Due to the use of coal and heavy transportation in Beijing, China, concentrations of polycyclic aromatic hydrocarbons (PAHs) bound to PM2.5 have risen and caused concerns about health risk, both outdoors and indoors. This study carried out quantitative investigation of PM2.5-bound PAHs in middle school classrooms and estimated the health risk to adolescents. According to the results, indoor PM2.5 concentrations ranged from 20.9 μg/m3 to 257.6 μg/m3, indoor PAH concentrations ranged from 8.0 ng/m3 to 83.0 ng/m3, and both were statistically correlated with outdoor concentrations. Results of diagnostic ratios (DR) and the PMF (positive matrix factorization) model indicated that coal combustion was the main source of PAHs in the classroom environment. The average value of incremental lifetime cancer risk (ILCR) was estimated to be 1.49 × 10−6, which indicated a potential health risk to students according to USEPA standards. Predictions showed that by 2021–2022, the risk will be reduced to an acceptable level. Results of this study could provide useful information for air pollution control in Beijing and proposing targeted solution against indoor air pollution.

Description: Highly controlled biomineralization of calcium carbonate is via non-classical mesocrystallization of amorphous precursors. In the present study, a simple in vitro assay was developed to mimic the biological process, which involved stabilized amorphous calcium carbonate and a single crystal substrate of calcite. The microcoating layer formed on the calcite substrate displayed mesocrystalline characteristics, and the layers near the substrate were strongly influenced by the epitaxy to the substrate. This behavior was preserved even when the morphology of the coating layer was modified with poly(acrylic acid), a model anionic macromolecule. Interestingly, the extent of the epitaxy increased substantially with poly(ethylene imine), which barely affected the crystal morphology. The in vitro assay in the present study will be useful in the investigations of the biomineralization and bioinspired crystallization of calcium carbonate in general.

Description: Ti6Al4V alloy is still attracting great interest because of its application as an implant material for hard tissue repair. This research aims to produce and investigate in-situ chitosan/hydroxyapatite (CS/HA) nanocomposite coatings based on different amounts of HA (10, 50 and 60 wt.%) on alkali-treated Ti6Al4V substrate through the sol-gel process to enhance in vitro bioactivity. The influence of different contents of HA on the morphology, contact angle, roughness, adhesion strength, and in vitro bioactivity of the CS/HA coatings was studied. Results confirmed that, with increasing the HA content, the surface morphology of crack-free CS/HA coatings changed for nucleation modification and HA nanocrystals growth, and consequently, the surface roughness of the coatings increased. Furthermore, the bioactivity of the CS/HA nanocomposite coatings enhanced bone-like apatite layer formation on the material surface with increasing HA content. Moreover, CS/HA nanocomposite coatings were biocompatible and, in particular, CS/10 wt.% HA composition significantly promoted human mesenchymal stem cells (hMSCs) proliferation. In particular, these results demonstrate that the treatment strategy used during the bioprocess was able to improve in vitro properties enough to meet the clinical performance. Indeed, it is predicted that the dense and crack-free CS/HA nanocomposite coatings suggest good potential application as dental implants.

Description: This paper presents the studies of the development of a high-performance epoxy coating for steel substrates. To this end, it investigated the synergistic effect of incorporating zinc oxide (ZnO) nanoparticles into nanosilica containing epoxy formulations. The mechanical properties of the epoxy coating formulations were improved by modifying the surfaces of the silica nanoparticles (5 wt.%) with 3-glycidoxypropyl trimethoxysilane, which ensured their dispersal through the material. Next, the ZnO nanoparticles (1, 2, or 3 wt.%) were incorporated to improve the corrosion performance of the formulations. The anticorrosive properties of the coatings were examined by electrochemical impedance spectroscopy (EIS) of coated mild steel specimens immersed in 3.5% NaCl solution over different time intervals (1 h to 30 days). Incorporation of the ZnO nanoparticles and the nanosilica into the coating formulation improved the corrosion resistance of the epoxy coating even after long-term exposure to saline test solutions. Finally, to evaluate how the nanoparticles affected the chemical and morphological properties of the prepared coatings, the coatings were characterized by scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, and X-ray diffraction (XRD).

Description: In the present paper, the identification of the material parameters of a masonry lighthouse is discussed. A fully non-invasive method was selected, in which the material properties were determined via numerical model validation applied to the first pair of natural frequencies and their related mode shapes, determined experimentally. The exact structural model was built by means of the finite element method. To obtain experimental data for the inverse analysis, operational modal analysis was applied to the structure. Three methods were considered: peak picking (PP), eigensystem realization algorithm (ERA) and natural excitation technique with ERA (NExT-ERA). The acceleration’s responses to environmental excitations, enhanced in some periods of time by sheet piling hammering or by sudden interruptions like wind stroke, were assumed within the analysis input. Different combinations of the input were considered in the PP and NExT-ERA analysis to find the most reasonable modal forms. A number of time periods of a free-decay character were considered in the ERA technique to finally calculate the averaged modal forms. Finally, the elastic modulus, Poisson’s ratio and material density of brick, sandstone and granite masonry were determined. The obtained values supplement the state of the art database concerning historic building materials. In addition, the numerical model obtained in the analysis may be used in further cases of structural analysis.

Description: Land-based sources are the key sources of plastic debris, and mismanaged plastic debris can eventually enter the ocean via marine beaches. In this study, the spatial distribution and amount of plastic debris in the land-based source input zone of First Long Beach (FLB), China, which is a major tourist attraction, were first investigated. By using field investigation, sand samples were collected from two sections on FLB adjacent to land-based sources in December 2019, and the plastic debris in the sand samples was quantified and characterized in the laboratory. The amount of plastic debris ranged from 2 to 82 particles/m2 on this marine sand beach. There was a significant difference in plastic debris amount between the transects along the land-based source input zone (p 〈 0.05) due to the impacts of wind, ocean currents, and waves. The most abundant size of plastics was 0.5–2.5 cm (44.4%). Moreover, the most common color was white (60.9%). The most abundant shape of plastic debris fell into the fragment category (76.2%). The plastic debris amounts were significantly correlated with multiple sizes. Our results show that land-based wastewater discharge is a large plastic debris source on FLB under coastal water tide variation. Reduction strategies should be carried out by tracing the various land-based sources of plastic debris.

Description: Some special conditions are important for chemical syntheses, such as high temperature and the medium used; unfortunately, uncontrollable influences are introduced during the process, resulting in unexpectedly low repeatability. Herein, we report a facile, environmentally friendly, stable, and repeatable methodology for synthesizing silver nanoplates (SNPs) at 0 °C that overcomes these issues and dramatically increases the yield. This method mainly employs sodium dodecyl sulfate (SDS) and sodium alginate (SA) as the surface stabilizer and assistant, respectively. Consequently, we produced hexagonal nanoplates and tailed nanoplates, and the characterization showed that SA dominates the clear and regular profiles of nanoplates at 0 °C. The tailed nanoplates, over time, showed the growth of heads and the dissolving of tails, and inclined to the nanoplates without tails. The synthesis method for SNPs used in this study—0 °C without media—showed high repeatability. We confirmed that these special conditions are not required for the synthesis of silver nanostructures (SNSs). Furthermore, we constructed a new method for preparing noble metal nanostructures and proved the possibility of preparing metal nanostructures at 0 °C.

Description: An experimental product study of the reactions of furfural with the main tropospheric oxidants (Cl, OH and NO3) has been carried out using a Fourier Transform Infrared spectrophotometer (FTIR) and a gas chromatograph–mass spectrometer with a time of flight detector (GC–TOFMS). The main gas-phase products detected were 5-chloro-2(5H)-furanone, maleic anhydride, 2-nitrofuran and CO. Molar yields were quantified for the detected products in these reactions, thus suggesting the existence of nongaseous products that could not be observed with the analytical techniques employed. The formation of Secondary Organic Aerosol (SOA) from the oxidation of furfural with Cl atoms, OH, NO3 and ozone was investigated in a smog chamber in the absence of inorganic seed aerosols. The experimental results show the formation of ultrafine particles (less than 1 µm in diameter) for all of the studied reactions except for the nitrate radical. Given their small size, these ultrafine particles (

Description: Precise exposure assessment of air pollutants is crucial in epidemiologic studies to ensure valid estimates of health effects. We conducted a longitudinal study to evaluate the role of air quality monitoring (AQM) measurements and high-resolution modeling outcomes focusing on nitrogen dioxide (NO2) exposure and atopic dermatitis (AD). A total of 128 young children with AD in Seoul Metropolitan Area, Korea, were recruited as a panel. We estimated the participants’ exposure to NO2 for four months, from 1 April through 31 July 2014 based on (1) monitored levels from 60 AQM stations located at varying distances from residential areas (AQM station-based NO2, AQM-NO2) and (2) estimates from a community multi-scale air quality (CMAQ) modeling system with a high-resolution (1 × 1 km) (CMAQ-NO2). We then compared the effect of AQM-NO2 on AD symptoms with that of CMAQ-NO2. The average distance between the participants’ residences and the nearest AQM station was 2.03 ± 1.06 km, ranging from 0.28 km to 5.73 km. Based on AQM-NO2, the AD symptoms increased by 10.28% (95% confidence interval (CI): 3.24, 17.79) with an increase of 10 ppb of NO2. The effect estimates of CMAQ-NO2 were similar to those of AQM-NO2 when assessed in patients living within 3 km from the nearest AQM station. Even within 1 km, the CI estimate obtained from the CMAQ was much narrower than from AQM (44.18–49.54 vs. 7.02–64.75). However, the association of AQM-NO2 with AD symptoms of patients living beyond 3 km was not positive, whereas that of CMAQ-NO2 maintained positive. In conclusion, exposure to ambient NO2 is significantly associated with aggravation of AD symptoms in young children. In addition, our study suggests that exposure assessment of NO2 using measurement data obtained from monitoring stations far from residential locations can lead to misclassification bias.

Description: Reducing plastic pollution in rivers, lakes, and oceans is beneficial to aquatic animals and human livelihood. To achieve this, reliable observations of the abundance, spatiotemporal variation, and composition of plastics in aquatic ecosystems are crucial. Current efforts mainly focus on collecting data on the open ocean, on beaches and coastlines, and in river systems. Urban areas are the main source of plastic leakage into the natural environment, yet data on plastic pollution in urban water systems are scarce. In this paper, we present a simple method for plastic hotspot mapping in urban water systems. Through visual observations, macroplastic abundance and polymer categories are determined. Due to its simplicity, this method is suitable for citizen science data collection. A first application in the Dutch cities of Leiden and Wageningen showed similar mean plastic densities (111–133 items/km canal) and composition (75–80% soft plastics), but different spatial distributions. These observations emphasize the importance of long-term data collection to further understand and quantify spatiotemporal variations of plastics in urban water systems. In turn, this will support improved estimates of the contribution of urban areas to the plastic pollution of rivers and oceans.

Description: This research group has recently used the new technology Distributed Acoustic Sensing (DAS) for the monitoring and the measurement of airplane flutter. To the authors’ knowledge, this is the first such use for this new technology. Traditionally, the measurement of airplane flutter requires the mounting of a very large number of sensors on the wing being monitored, and extensive wiring must be connected to all these sensors. The new system and technology introduced in this paper dramatically reduces the hardware requirements in such an application: all the traditional sensors and wiring are replaced with one fiber optic cable with a diameter of 2 mm. An electro-optical system with the size of a desktop PC monitors simultaneously one or more of such fiber optic cables and detects/characterizes any mechanical disturbances on the cables. Theoretical and experimental results are given.

Description: The objective of our research is to improve the properties of calcium-sulphate hemihydrate parts printed by binder jetting. In this paper, we show the thermal treatment results when using temperature time ramps on binder-jetted ceramic parts without infiltrating. The results show that the mechanical properties of printed parts are improved substantially. Two different thermal cycles were investigated for their effect on the dehydration process of CaSO4·½H2O using infrared analysis. The thermal-treated samples were compared with respect to porosity, surface roughness, compression strength and dimensional and weight variation. The proposed thermal treatment significantly improves the compression strength in a short time, guaranteeing dimensional stability while providing a good surface. This improvement in mechanical properties offers a great chance for using binder-jetted parts as functional components, for example, in the casting field or the medical sector (scaffolds).

Description: Black carbon (BC), organic carbon (OC), and total carbon (TC) in snow are important for their climatic and cryospheric effects. They are also part of the global carbon cycle. Atmospheric black and organic carbon (including brown carbon) may deposit and darken snow surfaces. Currently, there are no standardized methods for sampling, filtering, and analysis protocols to detect carbon in snow. Here, we describe our current methods and protocols to detect carbon in seasonal snow using the OCEC thermal optical method, a European standard for atmospheric elemental carbon (EC). We analyzed snow collected within and around the urban background SMEARIII (Station for Measuring Ecosystem-Atmosphere Relations) at Kumpula (60° N) and the Arctic GAW (Global Atmospheric Watch) station at Sodankylä (67° N). The median BC, OC, and TC in snow samples (ntot = 30) in Kumpula were 1118, 5279, and 6396 ppb, and in Sodankylä, they were 19, 1751, and 629 ppb. Laboratory experiments showed that error due to carbon attached to a sampling bag (n = 11) was

Description: As the use of continuous fiber polymer matrix composites expands into new fields, there is a growing need for more sustainable manufacturing processes. An integrated computational material design framework has been developed, which enables the design of tailored manufacturing systems for polymer matrix composite materials as a sustainable alternative to achieving high-quality components in high-rate production. Trapped rubber processing achieves high pressures during polymer matrix composite processing, utilizing the thermally induced volume change of a nearly incompressible material inside a closed cavity mold. In this interdisciplinary study, the structural analysis, material science and manufacturing engineering perspectives are all combined to determine the mold mechanics, and the manufacturing process in a cohesive and iterative design loop. This study performs the coupled thermo-mechanical analysis required to simulate the transients involved in composite manufacturing and the results are compared with a previously developed test method. The internal surface pressure and temperatures are computed, compared with the experimental results, and the resulting design process is simulated. Overall, this approach maintains high-quality consolidation during curing while allowing for the possibility for custom distributions of pressures and temperatures. This can lead to more sustainable manufacturing by reducing energy consumption and improving throughput.

Description: The aim of this study was to investigate the impact of distributed propulsion systems used on inland and coastal navigation in shallow water. Five layouts were assessed by computational fluid dynamics (CFD) simulation. The hull/propulsion layout cases have been analyzed for discrete flow speed values in the range 0–6 m/s. All cases have been examined under restricted draft conditions in shallow water with a minimum of 0.3 m under keel clearance (UKC) and under unrestricted draft conditions in deep water. The results show that distributed propulsion consisting of 6 or 8 (in some cases, even more) units produces noticeable higher thrust effects in shallow water than the traditional layout. Under restricted conditions, the thrust increase between two distributed layouts with different numbers of propulsors is higher, in contrast to deep water, where differences in performance are not so significant.

Description: Xenogenic collagen-based matrices represent an alternative to subepithelial palatal connective tissue autografts in periodontal and peri-implant soft tissue reconstructions. In the present study, we aimed to investigate the migratory, adhesive, proliferative, and wound-healing potential of primary human oral fibroblasts (hOF) and periodontal ligament cells (hPDL) in response to four commercially available collagen matrices. Non-crosslinked collagen matrix (NCM), crosslinked collagen matrix (CCM), dried acellular dermal matrix (DADM), and hydrated acellular dermal matrix (HADM) were all able to significantly enhance the ability of hPDL and hOF cells to directionally migrate toward the matrices as well as to efficiently repopulate an artificially generated wound gap covered by the matrices. Compared to NCM and DADM, CCM and HADM triggered stronger migratory response. Cells grown on CCM and HADM demonstrated significantly higher proliferative rates compared to cells grown on cell culture plastic, NCM, or DADM. The pro-proliferative effect of the matrices was supported by expression analysis of proliferative markers regulating cell cycle progression. Upregulated expression of genes encoding the adhesive molecules fibronectin, vinculin, CD44 antigen, and the intracellular adhesive molecule-1 was detected in hPDL and hOF cells cultured on each of the four matrices. This may be considered as a prerequisite for good adhesive properties of the four scaffolds ensuring proper cell–matrix and cell–cell interactions. Upregulated expression of genes encoding TGF-β1 and EGF growth factors as well as MMPs in cells grown on each of the four matrices provided support for their pro-proliferative and pro-migratory abilities. The expression of genes encoding the angiogenic factors FGF-2 and VEGF-A was dramatically increased in cells grown on DADM and HADM only, suggesting a good basis for accelerated vascularization of the latter. Altogether, our results support favorable influence of the investigated collagen matrices on the recruitment, attachment, and growth of cell types implicated in oral soft tissue regeneration. Among the four matrices, HADM has consistently exhibited stronger positive effects on the oral cellular behavior. Our data provide solid basis for future investigations on the clinical application of the collagen-based matrices in surgical periodontal therapy.

Description: Recent advances in particle sensor technologies have led to an increased development and utilization of low-cost, compact, particulate matter (PM) monitors. These devices can be deployed in dense monitoring networks, enabling an improved characterization of the spatiotemporal variability in ambient levels and exposure. However, the reliability of their measurements is an important prerequisite, necessitating rigorous performance evaluation and calibration in comparison to reference-grade instrumentation. In this study, field evaluation of Purple Air PA-II devices (low-cost PM sensors) is performed in two urban environments and across three seasons in Greece, in comparison to different types of reference instruments. Measurements were conducted in Athens (the largest city in Greece with nearly four-million inhabitants) for five months spanning over the summer of 2019 and winter/spring of 2020 and in Ioannina, a medium-sized city in northwestern Greece (100,000 inhabitants) during winter/spring 2019–2020. The PM2.5 sensor output correlates strongly with reference measurements (R2 = 0.87 against a beta attenuation monitor and R2 = 0.98 against an optical reference-grade monitor). Deviations in the sensor-reference agreement are identified as mainly related to elevated coarse particle concentrations and high ambient relative humidity. Simple and multiple regression models are tested to compensate for these biases, drastically improving the sensor’s response. Large decreases in sensor error are observed after implementation of models, leading to mean absolute percentage errors of 0.18 and 0.12 for the Athens and Ioannina datasets, respectively. Overall, a quality-controlled and robustly evaluated low-cost network can be an integral component for air quality monitoring in a smart city. Case studies are presented along this line, where a network of PA-II devices is used to monitor the air quality deterioration during a peri-urban forest fire event affecting the area of Athens and during extreme wintertime smog events in Ioannina, related to wood burning for residential heating.

Description: Due to the growing success of neural machine translation (NMT), many have started to question its applicability within the field of literary translation. In order to grasp the possibilities of NMT, we studied the output of the neural machine system of Google Translate (GNMT) and DeepL when applied to four classic novels translated from English into Dutch. The quality of the NMT systems is discussed by focusing on manual annotations, and we also employed various metrics in order to get an insight into lexical richness, local cohesion, syntactic, and stylistic difference. Firstly, we discovered that a large proportion of the translated sentences contained errors. We also observed a lower level of lexical richness and local cohesion in the NMTs compared to the human translations. In addition, NMTs are more likely to follow the syntactic structure of a source sentence, whereas human translations can differ. Lastly, the human translations deviate from the machine translations in style.

Description: The article is devoted to a reconstruction of the sedimentation processes in Kamyshovoye Lake (the Kaliningrad Region, Russia) during the Late Glacial and Holocene. The results of the geochemical analysis of Kamyshovoye Lake’s bottom sediments, accompanied by statistical processing and detailed radiocarbon dating, are presented. It was established that a high proportion of mineral matter dominated in the intervals between 15,000 and 11,400 and between 1400 and 600 cal y BP; enrichment with carbonates was noted between 11,400 and 5200 cal y BP and during the past 600 years; and a high percentage of organic matter was recorded between 7800 and 600 cal y BP. We conclude that the increase in mineral matter was influenced by such factors as reduced vegetation cover due to natural and anthropogenic processes, aeolian transfer, and dead-ice melting during the Late Glacial. The increase in carbonate matter was mainly associated with humidity and the reduction conditions of the lake ecosystem. Organogenic matter content was affected by the autochthonic (biological) productivity of the lake, which directly depends on more favorable climatic conditions.

Description: Fertilized agricultural soils serve as a primary source of anthropogenic N2O emissions. In South Africa, there is a paucity of data on N2O emissions from fertilized, irrigated dairy-pasture systems and emission factors (EF) associated with the amount of N applied. A first study aiming to quantify direct N2O emissions and associated EFs of intensive pasture-based dairy systems in sub-Sahara Africa was conducted in South Africa. Field trials were conducted to evaluate fertilizer rates (0, 220, 440, 660, and 880 kg N ha−1 year−1) on N2O emissions from irrigated kikuyu–perennial ryegrass (Pennisetum clandestinum–Lolium perenne) pastures. The static chamber method was used to collect weekly N2O samples for one year. The highest daily N2O fluxes occurred in spring (0.99 kg ha−1 day−1) and summer (1.52 kg ha−1 day−1). Accumulated N2O emissions ranged between 2.45 and 15.5 kg N2O-N ha−1 year−1 and EFs for mineral fertilizers applied had an average of 0.9%. Nitrogen in yielded herbage varied between 582 and 900 kg N ha−1. There was no positive effect on growth of pasture herbage from adding N at high rates. The relationship between N balance and annual N2O emissions was exponential, which indicated that excessive fertilization of N will add directly to N2O emissions from the pastures. Results from this study could update South Africa’s greenhouse gas inventory more accurately to facilitate Tier 3 estimates.

Description: Achieving sustainable zero-waste and carbon neutral solutions that contribute to a circular economy is critically important for the long-term prosperity and continuity of traditional carbon-based energy industries. The Estonian oil shale (OS) sector is an example where such solutions are more than welcome. The combustion of OS generates a continuous flow of ashes destined to landfills. In this study, the technical feasibility of producing monolith building materials incorporating different OS ashes from Estonia was evaluated. Three binder systems were studied: self-cementation of the ashes, ceramic sintering in clay brick production and accelerated carbonation of OS ash (OSA) compacts. Results showed that most of the OSAs studied have low self-cementitious properties and these properties were affected by ash fineness and mineralogical composition. In case of clay bricks, OSA addition resulted in a higher porosity and improved insulation properties. The carbonated OSA compacts showed promising compressive strength. Accelerated carbonation of compacted samples was found to be the most promising way for the future utilization of OSAs as sustainable zero-waste and carbon neutral solution.

Description: Concrete wastewater infrastructures are important to modern society but are susceptible to sulfuric acid attack when exposed to an aggressive environment. Fibre-reinforced mortar has been adopted as a promising coating and lining material for degraded reinforced concrete structures due to its unique crack control and excellent anti-corrosion ability. This paper aims to evaluate the performance of polyethylene (PE) fibre-reinforced calcium aluminate cement (CAC)–ground granulated blast furnace slag (GGBFS) blended strain-hardening mortar after sulfuric acid immersion, which represented the aggressive sewer environment. Specimens were exposed to 3% sulfuric acid solution for up to 112 days. Visual, physical and mechanical performance such as water absorption ability, sorptivity, compressive and direct tensile strength were evaluated before and after sulfuric acid attack. In addition, micro-structure changes to the samples after sulfuric acid attack were also assessed by X-Ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) to further understand the deterioration mechanism. The results show that overall fibre-reinforced calcium aluminate cement (CAC)-based samples performed significantly better than fibre-reinforced ordinary Portland cement (OPC)-based samples as well as mortar samples in sulfuric acid solution in regard to visual observations, penetration depth, direct tensile strength and compressive reduction. Gypsum generation in the cementitious matrix of both CAC and OPC-based systems was the main reason behind the deterioration mechanism after acid attack exposure. Moreover, laboratory sulfuric acid testing has been proven for successfully screening the cementitious material against an acidic environment. This method can be considered to design the service life of concrete wastewater pipes.

Description: The emergence and outbreak of the novel coronavirus (COVID-19) had a devasting effect on global health, the economy, and individuals’ daily lives. Timely diagnosis of COVID-19 is a crucial task, as it reduces the risk of pandemic spread, and early treatment will save patients’ life. Due to the time-consuming, complex nature, and high false-negative rate of the gold-standard RT-PCR test used for the diagnosis of COVID-19, the need for an additional diagnosis method has increased. Studies have proved the significance of X-ray images for the diagnosis of COVID-19. The dissemination of deep-learning techniques on X-ray images can automate the diagnosis process and serve as an assistive tool for radiologists. In this study, we used four deep-learning models—DenseNet121, ResNet50, VGG16, and VGG19—using the transfer-learning concept for the diagnosis of X-ray images as COVID-19 or normal. In the proposed study, VGG16 and VGG19 outperformed the other two deep-learning models. The study achieved an overall classification accuracy of 99.3%.

Description: This paper presents a review and analysis of large-scale air convection tests and the establishment of intrinsic permeability in coarse open-graded materials. Natural air convection can make a significant contribution to heat transfer during cooling periods. In seasonally freezing environments this can result in excessive frost penetration and subsequent frost-related problems. Intrinsic permeability largely defines the onset of convective heat transfer in granular materials. Conventional methods for measuring intrinsic permeability cannot be applied to very coarse materials. Large-scale laboratory experiments on natural air convection can serve as an alternative method for determining this crucial parameter. This paper gives an overview of four different experimental test setups for measuring natural air convection, all differing in physical shape, boundary conditions and heat flux/temperature measurement devices. Comparison between these is difficult because the air convection pattern can differ and in some cases the shape and number of convection cells cannot be validated. Most of the studies available in the literature use theoretical equations to approximate intrinsic permeability. A method based on the analytical Nu-Ra number relationship is employed to establish the values of intrinsic permeability. Tests that provide enough data to enable the use of the Nu-Ra relationship are very limited. The overall results show a reasonable correlation between experiment-based intrinsic permeability and theoretical approximation. However, several issues must be addressed: first, differences may exist between the intrinsic permeability of natural and of crushed materials due to the shape effect. Second, the method used is in theory valid only for two-dimensional air convection within a square enclosure heated from below. Yet the results show that this method could be extended to other conditions with a certain degree of confidence. Third, a good estimate of intrinsic permeability is possible only with accurate experimental measurement.

Description: A remarkable exposure of tubular authigenic carbonates was found on the seafloor in the Dongsha area of the South China Sea (SCS). The tubular carbonates, around 2–3 cm in diameter and usually less than 10 cm in length, represent broken fragments of once-larger pipes that now protrude from muddy sediments. The morphology, carbon and oxygen stable isotope compositions, and trace and rare earth element contents of the carbonates were analyzed to decipher the mode of carbonate formation. The tubular carbonates exhibit a dark brown coating of iron and manganese hydrous oxides, indicating prolonged exposure to oxic bottom waters. The carbonate content of the micritic pipes falls between 12.5 and 67.3 wt.% with an average of 42.0 wt.%, suggesting formation within the sediment. This inference is supported by trace and rare earth element patterns including a moderate enrichment of middle rare earth elements. Low δ13C values (as low as −50.3‰, Vienna Pee Dee Belemnite (VPDB)) suggest that carbonate precipitation was induced by the anaerobic oxidation of methane. The unusually positive δ18O values of the carbonates (as high as +5.3‰, VPDB) are believed to reflect the destabilization of locally abundant gas hydrate. Taken together, it is suggested that pipe formation was initiated by sediment-dwelling organisms, such as crustaceans or bivalves. The burrows subsequently acted as conduits for upward fluid migration. The lithification of the sediment directly surrounding the conduits and the partial filling of the conduits with carbonate cement resulted in the formation of tubular carbonates. Turbidity currents, sediment slumps, or the vigorous emission of fluids probably induced the fragmentation of tubular carbonates within the sediment. The carbonate fragments had been further subjected to winnowing by bottom currents. This study provides insight into the interaction of megafauna burrowing with fluid migration and carbonate formation at hydrocarbon seeps, highlighting the role of bottom currents and mass wasting on the formation of fragmented tubular carbonates.

Description: In November 2019, the Supreme Court of India issued a notification to all the states in the National Capital Region of Delhi to install smog towers for clean air and allocated INR 36 crores (~USD 5.2 million) for a pilot. Can we vacuum our air pollution problem using smog towers? The short answer is “no”. Atmospheric science defines the air pollution problem as (a) a dynamic situation where the air is moving at various speeds with no boundaries and (b) a complex mixture of chemical compounds constantly forming and transforming into other compounds. With no boundaries, it is unscientific to assume that one can trap air, clean it, and release into the same atmosphere simultaneously. In this paper, we outline the basics of atmospheric science to describe why the idea of vacuuming outdoor air pollution is unrealistic, and the long view on air quality management in Indian cities.

Description: Incorporating various industrial waste materials into concrete has recently gained attention for sustainable construction. This paper, for the first time, studies the effects of silica stone waste (SSW) powder on concrete. The cement of concrete was replaced with 5, 10, 15, and 20% of the SSW powder. The mechanical properties of concrete, such as compressive and tensile strength, were studied. Furthermore, the microstructure of concrete was studied by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy analysis (EDX), Fourier transformed infrared spectroscopy (FTIR), and X-Ray diffraction (XRD) tests. Compressive and tensile strength of samples with 5% SSW powder was improved up to 18.8% and 10.46%, respectively. As can be observed in the SEM images, a reduced number of pores and higher density in the matrix can explain the better compressive strength of samples with 5% SSW powder.

Description: This paper presents a study of the Ti-6Al-4V alloy milling under different lubrication conditions, using the minimum quantity lubrication approach. The chosen material is widely used in the industry due to its properties, although they present difficulties in terms of their machinability. A minimum quantity lubrication (MQL) prototype valve was built for this purpose, and machining followed a previously defined experimental design with three lubrication strategies. Speed, feed rate, and the depth of cut were considered as independent variables. As design-dependent variables, cutting forces, torque, and roughness were considered. The desirability optimization function was used in order to obtain the best input data indications, in order to minimize cutting and roughness efforts. Supervised artificial neural networks of the multilayer perceptron type were created and tested, and their responses were compared statistically to the results of the factorial design. It was noted that the variables that most influenced the machining-dependent variables were the feed rate and the depth of cut. A lower roughness value was achieved with MQL only with the use of cutting fluid with graphite. Statistical analysis demonstrated that artificial neural network and the experimental design predict similar results.

Description: In this work, we demonstrate how the blockchain and the off-chain storage interact via Oracle-based mechanisms, which build an effective connection between a distributed database and real assets. For demonstration purposes, smart contracts were drawn up to deal with two different applications. Due to the characteristics of the blockchain, we may still encounter severe privacy issues, since the data stored on the blockchain are exposed to the public. The proposed scheme provides a general solution for resolving the above-mentioned privacy issue; that is, we try to protect the on-chain privacy of the sensitive data by using homomorphic encryption techniques. Specifically, we constructed a secure comparison protocol that can check the correctness of a logic function directly in the encrypted domain. By using the proposed access control contract and the secure comparison protocol, one can carry out sensitive data-dependent smart contract operations without revealing the data themselves.

Description: Healthcare facilities are constantly deteriorating due to tight budgets allocated to the upkeep of building assets. This entails the need for improved deterioration modeling of such buildings in order to enforce a predictive maintenance approach that decreases the unexpected occurrence of failures and the corresponding downtime elapsed to repair or replace the faulty asset components. Currently, hospitals utilize subjective deterioration prediction methodologies that mostly rely on age as the sole indicator of degradation to forecast the useful lives of the building components. Thus, this paper aims at formulating a more efficient stochastic deterioration prediction model that integrates the latest observed condition into the forecasting procedure to overcome the subjectivity and uncertainties associated with the currently employed methods. This is achieved by means of developing a hybrid genetic algorithm-based fuzzy Markovian model that simulates the deterioration process given the scarcity of available data demonstrating the condition assessment and evaluation for such critical facilities. A nonhomogeneous transition probability matrix (TPM) based on fuzzy membership functions representing the condition, age and relative deterioration rate of the hospital systems is utilized to address the inherited uncertainties. The TPM is further calibrated by means of a genetic algorithm to circumvent the drawbacks of the expert-based models. A sensitivity analysis was carried out to analyze the possible changes in the output resulting from predefined modifications to the input parameters in order to ensure the robustness of the model. The performance of the deterioration prediction model developed is then validated through a comparison with a state-of-art stochastic model in contrast to real hospital datasets, and the results obtained from the developed model significantly outperformed the long-established Weibull distribution-based deterioration prediction methodology with mean absolute errors of 1.405 and 9.852, respectively. Therefore, the developed model is expected to assist decision-makers in creating more efficient maintenance programs as well as more data-driven capital renewal plans.

Description: BiFeO3 nanocrystals were applied as the sensing material to isopropanol. The isopropanol sensor based on BiFeO3 nanocrystals shows excellent gas-sensing properties at the optimum working temperature of 240 °C. The sensitivity of as-prepared sensor to 100 ppm isopropanol is 31 and its response and recovery time is as fast as 6 and 17 s. The logarithmic curves of the sensitivity and concentration of BiFeO3 sensors are a very good linear in the low detection range of 2–100 ppm. In addition, the gas sensing mechanism is also discussed. The results suggest that the BiFeO3 nanomaterial can be potentially applied in isopropanol gas detection.

Description: For the first time, an original compound belonging to the heptazine family has been deposited in the form of thin layers, both by thermal evaporation under vacuum and spin-coating techniques. In both cases, smooth and homogeneous layers have been obtained, and their properties evaluated for eventual applications in the field of organic electronics. The layers have been fully characterized by several concordant techniques, namely UV-visible spectroscopy, steady-state and transient fluorescence in the solid-state, as well as topographic and conductive atomic force microscopy (AFM) used in Kelvin probe force mode (KPFM). Consequently, the afferent energy levels, including Fermi level, have been determined, and show that these new heptazines are promising materials for tailoring the electronic properties of interfaces associated with printed electronic devices. A test experiment showing an improved electron transfer rate from a tris-(8-hydroxyquinoline) aluminum (Alq3) photo-active layer in presence of a heptazine interlayer is finally presented.

Description: A possible approach for providing new properties for textiles is the insertion of natural ingredients into the textile product during the process of its manufacture. Myrrh has long been used in medicine as an antibacterial and antifungal material. Polylactide (PLA) is a thermoplastic synthetic biopolymer obtained from renewable resources—and due its biodegradability, is also widely used in medicine. In this study, films and multifilament yarns from modified biodegradable PLA granules with ethanolic and aqueous myrrh extracts were developed and characterized. Optical microscopy was used to determine the surface morphology of PLA/myrrh multifilament yarns. Tensile tests, ultraviolet-visible (UV-vis), differential scanning calorimetry (DSC) were applied to determine, consequently, mechanical, optical properties and degree of crystallinity of PLA/myrrh films and multifilament yarns. The chemical composition of PLA/myrrh multifilament yarns was estimated by Fourier-transform infrared (FTIR) spectroscopy method. The results showed that it is possible to form PLA melt-spun multifilament yarns with myrrh extract. The type of myrrh extract (ethanolic or aqueous) has a significant influence on the mechanical and optical properties of the PLA films and melt-spun yarns. The mechanical properties of PLA films and melt-spun multifilament yarns formed from PLA granules with aqueous myrrh extract decreased 19% and 21% more than PLA with ethanolic extract, respectively. Analysis of UV-vis spectra showed that, due to the yellow hue, the reflectance of PLA films and melt-spun PLA multifilament yarns modified with myrrh extracts decreased exponentially. The DSC test showed that multifilament yarns from PLA modified with aqueous extract had the highest degree of crystallization.

Description: The problem of wave identification is formulated as applied to the results of measurements of the temperature and the density of the neutral atmosphere in the range height 90–120 km by the artificial periodic irregularities (APIs) technique. The technique is based on the resonant scattering of radio waves by artificial periodic irregularities of the ionospheric plasma emerging in the field of a standing wave arising from the interference of the incident and reflected waves from the ionosphere. APIs were created using SURA heating facility (named as SURA experiment). The acoustic wave theory is reformulated on the base of data which can be observed in the given experimental setup. The basic system of equations is reduced so that it accounts only upward and downward directed waves, ignoring entropy mode. The algorithm of wave identification based on usage of dynamic projection operators for such a reduced case is proposed and explicit form of projection operators is derived. Its application to finite number dataset via Discrete Fourier Transform (DFT) is described and results of its application to the DFT-transformed set of experimental observation of the temperature and density perturbations are presented. The result yields hybrid amplitudes, that allow us to calculate energy of the directed waves that enter the observed superposition. The problem of entropy mode detection is discussed, the corresponding projecting operators for the full evolution system are built and a way to apply the method to quantification of it is proposed.

Description: This paper primarily assesses the scale of adverse changes to the compressive strength of different types of silicates due to the influence of moisture. The study covers three groups of silicate units of different strength classes—15, 20 and 25—obtained from three different manufacturers. It was demonstrated that in all studied groups, moisture significantly decreased the compressive strength by about 30–40%. In addition, microstructural studies were conducted to analyze the relationship between the specific porosity structure of each group of silicate bricks and their compressive strength. On the basis of SEM (Scanning Electron Microscopy) and EDS (Electron Dispersive Spectroscopy) analysis, the elemental composition of individual silicates was determined and the contact zone between the aggregate and the binder was determined, which largely influenced the obtained compressive strength of each silicates. Next, the study referred to the utility of the normative procedure used to determine the strength class of samples with different geometries and at different moisture concentrations. The results of the calculations showed the high accuracy of the normative-based assessment of strength class, regardless of the manufacturer and the moisture values during examination.

Description: Additive manufacturing (AM) is the term for a number of processes for joining materials to build physical components from a digital 3D model. AM has multiple advantages over other construction techniques, such as freeform, customization, and waste reduction. However, AM components have been evaluated by destructive and non-destructive testing and have shown mechanical issues, such as reduced resistance, anisotropy and voids. The build direction affects the mechanical properties of the built part, including voids of different characteristics. The aim of this work is an extended analysis of void shape by means of X-ray computed tomography (CT) applied to fused deposition modeling (FDM) samples. Furthermore, a relation between the tensile mechanical properties and digital void measurements is established. The results of this work demonstrate that void characteristics such as quantity, size, sphericity and compactness show no obvious variations between the samples. However, the angle between the main void axis and the mechanical load axis α shows a relation for FDM components: when its mean value μ(α) is around 80 (degrees) the yield strength and Young’s modulus are reduced. These results lead to the formulation of a novel criterion that predicts the mechanical behavior of AM components.

Description: The objective of this work is to study the geometric properties of surface topographies of hot-work tool steel created by electric discharge machining (EDM) using motif and multiscale analysis. The richness of these analyses is tested through calculating the strengths of the correlations between discharge energies and resulting surface characterization parameters, focusing on the most representative surface features—craters, and how they change with scale. Surfaces were created by EDM using estimated energies from 150 to 9468 µJ and measured by focus variation microscope. The measured topographies consist of overlapping microcraters, of which the geometry was characterized using three different analysis: conventional with ISO parameters, and motif and multiscale curvature tensor analysis. Motif analysis uses watershed segmentation which allows extraction and geometrically characterization of each crater. Curvature tensor analysis focuses on the characterization of principal curvatures and their function and their evolution with scale. Strong correlations (R2 〉 0.9) were observed between craters height, diameter, area and curvature using linear and logarithmic regressions. Conventional areal parameter related to heights dispersion were found to correlate stronger using logarithmic regression. Geometric characterization of process-specific topographic formations is considered to be a natural and intuitive way of analyzing the complexity of studied surfaces. The presented approach allows extraction of information directly relating to the shape and size of topographic features of interest. In the tested conditions, the surface finish is mostly affected and potentially controlled by discharge energy at larger scales which is associated with sizes of fabricated craters.

Description: Laser irradiation is a popular method to produce microtextures on metal surfaces. However, the common laser-produced microtextures were hierarchical (multiscale), which may limit their applicability. In this paper, a method of two-step laser irradiation, combining first-step strong ablation and sequentially second-step gentle ablation, was presented to produce micron-rough surface with single-scale microtextures. The effect of laser fluence on the Ti–6Al–4V surface morphology and wettability were investigated in detail. The morphology results revealed that the microtextures produced using this method gradually evolved from multiscale to single-scale meanwhile from microprotrusions to microholes with increasing the second-step laser fluence from 0.0 to 2.4 J/cm2. The wettability and EDS/XPS results indicated that attributing to the rich TiO2 content and micron roughness produced by laser irradiation, all the two-step laser-irradiated surfaces exhibited superhydrophilicity. In addition, after silanization, all these superhydrophilic surfaces immediately turned to be superhydrophobic with close water contact angles of 155–162°. However, due to the absence of nanotextures, the water-rolling angle on the superhydrophobic surfaces with single-scale microtextures distinctly larger than those with multiscale ones. Finally, using the two-step laser-irradiation method and assisted with silanization, multifunctional superhydrophobic Ti–6Al–4V surfaces were achieved, including self-cleaning, guiding of the water-rolling direction and anisotropic water-rolling angles (like the rice-leaf), etc.

Description: The ultrasonic modulation technique, developed by inspecting the nonlinearity from the interactions of crack surfaces, has been considered very effective in detecting fatigue cracks in the early stage of the crack development due to its high sensitivity. The wave modulation is the frequency shift of a wave passing through a crack and does not occur in intact specimens. Various parameters affect the modulation of the wave, but quantitative analysis for each variable has not been comprehensively conducted due to the complicated interaction of irregular crack surfaces. In this study, specimens with a constant crack width are manufactured, and the effects of various excitation parameters on modulated wave generation are analyzed. Based on the analysis, an effective crack detection algorithm is proposed and verified by applying the algorithm to fatigue cracks. For the quantitative analysis, tests are repeatedly conducted by varying parameters. As a result, the excitation intensity shows a strong linear relationship with the amount of modulated waves, and the increase of modulated wave is expected as crack length increases. However, the change in the dynamic characteristics of the specimen with the crack length is more dominant in the results. The excitation frequency is the most dominant variable to generate the modulated waves, but a direct correlation is not observed as it is difficult to measure the interaction of crack surfaces. A numerical analysis technique is developed to accurately simulate the movement and interaction of the crack surface. The crack detection algorithm, improved by using the observations from the quantitative analyses, can distinguish the occurrence of modulated waves from the ambient noises, and the state of the specimens is determined by using two nonlinear indexes.

Description: This study aimed to develop series analytical solutions based on the Mindlin plate theory for the free vibrations of functionally graded material (FGM) rectangular plates. The material properties of FGM rectangular plates are assumed to vary along their thickness, and the volume fractions of the plate constituents are defined by a simple power-law function. The series solutions consist of the Fourier cosine series and auxiliary functions of polynomials. The series solutions were established by satisfying governing equations and boundary conditions in the expanded space of the Fourier cosine series. The proposed solutions were validated through comprehensive convergence studies on the first six vibration frequencies of square plates under four combinations of boundary conditions and through comparison of the obtained convergent results with those in the literature. The convergence studies indicated that the solutions obtained for different modes could converge from the upper or lower bounds to the exact values or in an oscillatory manner. The present solutions were further employed to determine the first six vibration frequencies of FGM rectangular plates with various aspect ratios, thickness-to-width ratios, distributions of material properties and combinations of boundary conditions.

Description: Conventional technologies for ureteral stent fabrication suffer from major inconveniences such as the development of encrustations and bacteria biofilm formation. These drawbacks typically lead to the failure of the device, significant patient discomfort and an additional surgery to remove and replace the stent in the worst cases. This work focuses on the preparation of a new nanocomposite material able to show drug elution properties, biodegradation and eventually potential antibacterial activity. Poly(2-hydroxyethyl methacrylate) or the crosslinked poly(2-hydroxyethyl methacrylate)-co-poly(acrylic acid) hydrogels were prepared by the radical polymerization method and combined with a biodegradable and antibacterial filling agent, i.e., flower-like Zinc Oxide (ZnO) micropowders obtained via the hydrothermal route. The physico-chemical analyses revealed the correct incorporation of ZnO within the hydrogel matrix and its highly mesoporous structure and surface area, ideal for drug incorporation. Two different anti-inflammatory drugs (Ibuprofen and Diclofenac) were loaded within each composite and the release profile was monitored up to two weeks in artificial urine (AU) and even at different pH values in AU to simulate pathological conditions. The addition of mesoporous ZnO micropowders to the hydrogel did not negatively affect the drug loading properties of the hydrogel and it was successfully allowed to mitigate undesirable burst-release effects. Furthermore, the sustained release of the drugs over time was observed at neutral pH, with kinetic constants (k) as low as 0.05 h−1. By exploiting the pH-tunable swelling properties of the hydrogel, an even more sustained release was achieved in acidic and alkaline conditions especially at short release times, with a further reduction of burst effects (k ≈ 0.01–0.02 h−1). The nanocomposite system herein proposed represents a new material formulation for preparing innovative drug eluting stents with intrinsic antibacterial properties.

Description: The capture of a target spacecraft by a chaser is an on-orbit docking operation that requires an accurate, reliable, and robust object recognition algorithm. Vision-based guided spacecraft relative motion during close-proximity maneuvers has been consecutively applied using dynamic modeling as a spacecraft on-orbit service system. This research constructs a vision-based pose estimation model that performs image processing via a deep convolutional neural network. The pose estimation model was constructed by repurposing a modified pretrained GoogLeNet model with the available Unreal Engine 4 rendered dataset of the Soyuz spacecraft. In the implementation, the convolutional neural network learns from the data samples to create correlations between the images and the spacecraft’s six degrees-of-freedom parameters. The experiment has compared an exponential-based loss function and a weighted Euclidean-based loss function. Using the weighted Euclidean-based loss function, the implemented pose estimation model achieved moderately high performance with a position accuracy of 92.53 percent and an error of 1.2 m. The in-attitude prediction accuracy can reach 87.93 percent, and the errors in the three Euler angles do not exceed 7.6 degrees. This research can contribute to spacecraft detection and tracking problems. Although the finished vision-based model is specific to the environment of synthetic dataset, the model could be trained further to address actual docking operations in the future.

Description: This study is focused on a barian titanian phlogopite found in an alkaline ultramafic dyke transecting Mesozoic limestones of the Gargano Promontory (Apulia, Italy). The rock containing the barian titanian phlogopite, an olivine-clinopyroxene-rich lamprophyre with nepheline and free of feldspars, has been classified as monchiquite. The present study combines chemical analyses, single crystal X-ray diffraction and Raman spectroscopy. Chemical variations suggest that the entry of Ba into the phlogopite structure can be explained by the exchange Ba + Al = K + Si. The crystal structure refinement indicates that the Ti uptake is consistent with the Ti–oxy exchange mechanism. The structural parameters associated with the oxy substitution mechanism are extremely enhanced and rarely reported in natural phlogopite: (a) displacement of M2 cation toward the O4 site (~0.7); (b) M2 octahedron bond-length distortion (~2.5); (c) very short c cell parameter (~10.14 Å). Raman analysis showed most prominent features in the 800–200 cm−1 region with the strongest peaks occurring at 773 and 735 cm−1. Only a weak, broad band was observed to occur in the OH-stretching region. As concerns the origin of the barian titanian phlogopite, the rock textural features clearly indicate that it crystallized from pockets of the interstitial melt. Here, Ba and Ti enrichment took place after major crystallization of olivine under fast-cooling conditions, close to the dyke margin.

Description: The harmonic closeness centrality measure associates, to each node of a graph, the average of the inverse of its distances from all the other nodes (by assuming that unreachable nodes are at infinite distance). This notion has been adapted to temporal graphs (that is, graphs in which edges can appear and disappear during time) and in this paper we address the question of finding the top-k nodes for this metric. Computing the temporal closeness for one node can be done in O(m) time, where m is the number of temporal edges. Therefore computing exactly the closeness for all nodes, in order to find the ones with top closeness, would require O(nm) time, where n is the number of nodes. This time complexity is intractable for large temporal graphs. Instead, we show how this measure can be efficiently approximated by using a “backward” temporal breadth-first search algorithm and a classical sampling technique. Our experimental results show that the approximation is excellent for nodes with high closeness, allowing us to detect them in practice in a fraction of the time needed for computing the exact closeness of all nodes. We validate our approach with an extensive set of experiments.

Description: The lithobiont community encrusting an early Pleistocene palaeocliff cropping out north of Augusta (SE Sicily, Italy) was investigated based on field observations and laboratory inspection of two rocky samples. Bryozoans, serpulids, brachiopods and bivalves encrusted part of the exposed surfaces that were bored mostly by clionaid sponges. Bryozoans, with at least 25 species detected on the rocky samples, are the most diversified skeletonized lithobionts also accounting for the highest number of colonies/specimens and highest coverage. Brachiopods, with the only species Novocrania anomala and a few but large cemented valves, cover wide surfaces. Serpulids, with two species identified on the sampled rocks and further two on the outcrop, were intermediate. A multiphase colonization is present, including a final epilithobiont community locally formed on eroded surfaces exposing a network of pervasive borings. The co-occurrence of very sciaphilic species having circalittoral to bathyal distributions suggests that the studied community thrived on a rocky substratum located near or at the shelf break, probably belonging to the shelf break (or RL) biocoenosis, also in agreement with observations on the fossil content of neighboring marly sediments. The observed relationships among colonizers largely represent mere superimpositions, and real interactions are not enough to state species competitiveness.

Description: In view of the strong constraint zones of the concrete structure on the pile foundation, there are some differences between the calculation results of the isotropic equivalent pile foundation by the volume replacement ratio method and the actual engineering. In this paper, referring to the relevant algorithm of rock mass with anchor, the anchor and rock mass are, respectively, compared to pile and surrounding soil foundation. Eshelby equivalent inclusion theory is introduced into the equivalent mechanical model of soil foundation with pile, and a new equivalent pile foundation algorithm considering anisotropic elastic constant is compiled by Fortran. Three kinds of calculation methods are used to calculate the stress field of the concrete structure of the large pump station on the pile foundation during the construction period, and the stress in the strong constraint zones of the concrete structure are mainly analyzed. It is found that the calculation accuracy of Algorithm 3 is the highest, and the calculation results of Algorithm 2 can be modified by the coefficients to achieve the calculation accuracy of Algorithm 3 and the calculation efficiency is actually improved. Finally, the accuracy of the proposed method is verified by the engineering measured data.

Description: Computer programmers require various instructive information during coding and development. Such information is dispersed in different sources like language documentation, wikis, and forums. As an information exchange platform, programmers broadly utilize Stack Overflow, a Web-based Question Answering site. In this paper, we propose a recommender system which uses a supervised machine learning approach to investigate Stack Overflow posts to present instructive information for the programmers. This might be helpful for the programmers to solve programming problems that they confront with in their daily life. We analyzed posts related to two most popular programming languages—Python and PHP. We performed a few trials and found that the supervised approach could effectively manifold valuable information from our corpus. We validated the performance of our system from human perception which showed an accuracy of 71%. We also presented an interactive interface for the users that satisfied the users’ query with the matching sentences with most instructive information.

Description: Aircrafts require a large amount of fuel in order to generate enough power to perform a flight. That consumption causes the emission of polluting particles such as carbon dioxide, which is implicated in global warming. This paper proposes an algorithm which can provide the 3D reference trajectory that minimizes the flight costs and the fuel consumption. The proposed algorithm was conceived using the Floyd–Warshall methodology as a reference. Weather was taken into account by using forecasts provided by Weather Canada. The search space was modeled as a directional weighted graph. Fuel burn was computed using the Base of Aircraft DAta (BADA) model developed by Eurocontrol. The trajectories delivered by the developed algorithm were compared to long-haul flight plans computed by a European airliner and to as-flown trajectories obtained from Flightradar24®. The results reveal that up to 2000 kg of fuel can be reduced per flight, and flight time can be also reduced by up to 11 min.

Description: The bimodal-grain-size 7075 aluminium alloys containing varied ratios of large and small 7075 aluminium powders were prepared by spark plasma sintering (SPS). The large powder was 100 ± 15 μm in diameter and the small one was 10 ± 5 μm in diameter. The 7075 aluminium alloys was completely densified under the 500 °C sintering temperature and 60 MPa pressure. The large powders constituted coarse grain zone, and the small powders constituted fine grain zone in sintered 7075 aluminium alloys. The microstructural and microchemical difference between the large and small powders was remained in coarse and fine grain zones in bulk alloys after SPS sintering, which allowed for us to investigate the effects of microstructure and microchemistry on passive properties of oxide film formed on sintered alloys. The average diameter of intermetallic phases was 201.3 nm in coarse grain zone, while its vale was 79.8 nm in fine grain zone. The alloying element content in intermetallic phases in coarse grain zone was 33% to 48% higher than that on fine grain zone. The alloying element depletion zone surrounding intermetallic phases in coarse grain zone showed a bigger width and a more severe element depletion. The coarse grain zone in alloys showed a bigger electrochemical heterogeneity as compared to fine grain zone. The passive film formed on coarse grain zone had a thicker thickness and a point defect density of 2.4 × 1024 m−3, and the film on fine grain zone had a thinner thickness and a point defect density of 4.0 × 1023 m−3. The film resistance was 3.25 × 105 Ωcm2 on coarse grain zone, while it was 6.46 × 105 Ωcm2 on fine grain zone. The passive potential range of sintered alloys increased from 457 mV to 678 mV, while the corrosion current density decreased from 8.59 × 10−7 A/cm2 to 6.78 × 10−7 A/cm2 as fine grain zone increasing from 0% to 100%, which implied that the corrosion resistance of alloys increased with the increasing content of fine grains. The passive film on coarse grain zone exhibited bigger corrosion cavities after pitting initiation compared to that on fine grain zone. The passive film formed on fine grain zone showed a better corrosion resistance. The protectiveness of passive film was mainly determined by defect density rather than the thickness in this work.

Description: Joint sealant is affected by various environmental factors in service, such as different temperatures, water soaking, ultraviolet and so on. In this paper, the VAE emulsion–cement compositejoint sealant was pretreated under multiple simulation environments. Thereafter, the degradation rules of fixed elongation and tensile properties of joint sealants at different mix proportions were systemically investigated under the action of external environments (temperature, water soaking and ultraviolet), and the influence mechanisms of diverse environmental factors were analyzed. The research results suggested that, under the action of external environments, the VAE emulsion–cement composite joint sealants exhibited degradation effects to varying degrees. After the addition of plasticizer, the joint sealants had reduced cohesion strength in low temperature environment and enhanced flexible deformability. The addition of water repellent improved the water resistance of joint sealants. Meanwhile, adding ultraviolet shield agent partially improved the ultraviolet radiation aging resistance. A greater powder–liquid ratio led to the lower flexibility of joint sealants, but superior water resistance and ultraviolet radiation aging resistance.

Description: Violent tornadoes are rare in Europe but they can have devastating effects. Damage associated with individual tornadoes can reach several billion euros and they have caused hundreds of fatalities. The tornado risk varies considerably over Europe, but so far only a few national maps of tornado risk and one Europe-wide map exist. We show several different ways to create quantitative maps of tornado occurrence rates as follows: Kernel smoothing of observations, climatologies of convective parameters from reanalysis, output of a logistic regression model to link convective parameters with observed tornadoes, orography-dependent climatologies and finally the population-bias corrected tornado occurrence rates from the Risk Management Solutions (RMS) Europe Severe Convective Storm Model. We discuss advantages and disadvantages of each approach and compare the results. While the climatologies created from the individual methods show a lot of qualitative similarities, we advocate to combine the methods to achieve the most reliable quantitative climatology.

Description: Plasticity and functional diversity of macrophages play an important role in resisting pathogens invasion, tumor progression and tissue repair. At present, nanodrug formulations are becoming increasingly important to induce and control the functional diversity of macrophages. In this framework, the internalization process of nanodrugs is co-regulated by a complex interplay of biochemistry, cell physiology and cell mechanics. From a biophysical perspective, little is known about cellular mechanics’ modulation induced by the nanodrug carrier’s internalization. In this study, we used the polylactic-co-glycolic acid (PLGA)–polyethylene glycol (PEG) nanofibers as a model drug carrier, and we investigated their influence on macrophage mechanics. Interestingly, the nanofibers internalized in macrophages induced a local increase of stiffness detected by atomic force microscopy (AFM) nanomechanical investigation. Confocal laser scanning microscopy revealed a thickening of actin filaments around nanofibers during the internalization process. Following geometry and mechanical properties by AFM, indentation experiments are virtualized in a finite element model simulation. It turned out that it is necessary to include an additional actin wrapping layer around nanofiber in order to achieve similar reaction force of AFM experiments, consistent with confocal observation. The quantitative investigation of actin reconfiguration around internalized nanofibers can be exploited to develop novel strategies for drug delivery.

Description: Exsolved perovskites can be obtained from lanthanum ferrites, such as La0.6Sr0.4Fe0.8Co0.2O3, as result of Ni doping and thermal treatments. Ni can be simply added to the perovskite by an incipient wetness method. Thermal treatments that favor the exsolution process include calcination in air (e.g., 500 °C) and subsequent reduction in diluted H2 at 800 °C. These processes allow producing a two-phase material consisting of a Ruddlesden–Popper-type structure and a solid oxide solution e.g., α-Fe100-y-zCoyNizOx oxide. The formed electrocatalyst shows sufficient electronic conductivity under reducing environment at the Solid Oxide Fuel Cell (SOFC) anode. Outstanding catalytic properties are observed for the direct oxidation of dry fuels in SOFCs, including H2, methane, syngas, methanol, glycerol, and propane. This anode electrocatalyst can be combined with a full density electrolyte based on Gadolinia-doped ceria or with La0.8Sr0.2Ga0.8Mg0.2O3 (LSGM) or BaCe0.9Y0.1O3-δ (BYCO) to form a complete perovskite structure-based cell. Moreover, the exsolved perovskite can be used as a coating layer or catalytic pre-layer of a conventional Ni-YSZ anode. Beside the excellent catalytic activity, this material also shows proper durability and tolerance to sulfur poisoning. Research challenges and future directions are discussed. A new approach combining an exsolved perovskite and an NiCu alloy to further enhance the fuel flexibility of the composite catalyst is also considered. In this review, the preparation methods, physicochemical characteristics, and surface properties of exsoluted fine nanoparticles encapsulated on the metal-depleted perovskite, electrochemical properties for the direct oxidation of dry fuels, and related electrooxidation mechanisms are examined and discussed.

Description: The drilling of holes in CFRP/Ti (Carbon Fiber-Reinforced Plastic/Titanium alloy) alloy stacks is one of the frequently used mechanical operations during the manufacturing of fastening assemblies in temporary civil aircraft. A combination of inhomogeneous behavior and poor machinability of CFRP/Ti alloy stacks in one short drilling brought challenges to the manufacturing community. The impact of the drilling temperature and time delay factor under various cutting conditions on hole accuracy when machining CFRP/Ti alloy stacks is poorly studied. In this paper, the drilling temperature, the phenomenon of thermal expansion of the drill tool, and hole accuracy are investigated. An experimental study was carried out using thermocouples, the coordinate measuring machine method, and finite element analysis. The results showed that the time delay factor varied from 5 (s) to 120 (s), influences the thermal-dependent properties of CFRP, and leads to an increase in hole roundness. Additionally, the thermal expansion of the drill significantly contributes to the deviation of the hole diameter in Ti alloy.

Description: More people appreciate the importance of global sustainability [...]

Description: Retrievals of ice cloud properties require accurate estimates of ice particle mass. Empirical mass–dimensional (m–D) relationships in the form m = a D b are widely used and usually universally applied across the complete range of particle sizes. For the first time, the dependence of a and b coefficients in m–D relationships on median mass diameter (Dmm) is studied. Using combined cloud microphysical data collected during the Olympic Mountains Experiment and coincident observations from Airborne Precipitation Radar Third Generation, Dmm-dependent (a, b) coefficients are derived and represented as surfaces of equally plausible solutions determined by some tolerance in the chi-squared difference χ 2 that minimizes the difference between observed and retrieved radar reflectivity. Robust dependences of a and b on Dmm are shown with both parameters significantly decreasing with Dmm, leading to smaller effective densities for larger Dmm ranges. A universally applied constant m–D relationship overestimates the mass of large aggregates when Dmm is between 3–6 mm and temperatures are between −15–0 °C. Multiple m–D relations should be applied for different Dmm ranges in retrievals and simulations to account for the variability of particle sizes that are responsible for the mass and thus for the variability of particle shapes and densities.

Description: Headland rips, sometimes referred to as boundary rips, are rip currents flowing against natural or artificial obstructions extending seaward from the beach, such as headland or groynes. They can be driven either by the deflection of the longshore current against the obstacle or by alongshore variation in breaking wave height due to wave shadowing in the lee of the obstacle. The driving mechanism therefore essentially depends on the angle of wave incidence with respect to the natural or artificial obstruction. We analyze 42 days of velocity profile measurements against a natural headland at the high-energy meso-macrotidal beach of Anglet, southwest France. Measurements were collected in 6.5–10.5-m depth as tide elevation varied, during the autumn–winter period with offshore significant wave height and period ranging 0.9–6 m and 8–16 s, respectively, and the angle of wave incidence ranging from −20 ∘ to 20 ∘ . Here we analyze deflection rip configurations, corresponding to approximately 24 days of measurements, for which the current meter was alternatively located in the rip neck, rip head or away from the rip as wave and tide conditions changed. Deflection rips were associated with large offshore-directed velocities (up to 0.6 m/s depth-averaged velocities) and tide modulation for low- to moderate-energy waves. The vertical profile of deflection rips was found to vary from depth-uniform in the rip neck to strongly depth-varying further offshore in the rip head with maximum velocities near the surface. Very low frequency motions of the rip were dramatic, ranging 10–60 min with a dominant peak period of approximately 40 min, i.e., with longer periods than commonly reported. The strong offshore-directed velocities measured well beyond the surf zone edge provide new insight into deflection rips as a dominant mechanism for water and sediment exchanges between embayed (or structurally-controlled) beaches and the inner-shelf and/or the adjacent embayments.

Description: In this work, piezoelectric (PZT) actuators were surface bonded on or embedded in a composite laminate and subjected to an electric voltage across the thickness, resulting in a bending effect on the composite laminate. An analytical expression of the deflection of a simply supported cross-ply composite laminate induced by distributed piezoelectric actuators was derived on the basis of classical plate theory and composite mechanics. The theoretical solution can be used to predict the deformation of the composite laminate. Series of parametric studies were performed to investigate the effects of location, size, and embedded depth of PZT actuators on the composite laminate deformation. The analytical predictions were verified with finite element results. A close agreement was achieved. It demonstrated that the present approach provided a simple solution to predict and control the deformed shape of a composite laminate induced by distributed PZT actuators.

Description: Roadside vegetation can affect the performance of installed road lighting. We demonstrate a workflow in which a car-mounted measurement system is used to assess the light-obstructing effect of roadside vegetation. The mobile mapping system (MMS) includes a panoramic camera system, laser scanner, inertial measurement unit, and satellite positioning system. The workflow and the measurement system were applied to a road section of Munkkiniemenranta, Helsinki, Finland, in 2015 and 2019. The relative luminance distribution on a road surface and the obstructing vegetation were measured before and after roadside vegetation pruning applying a luminance-calibrated mobile mapping system. The difference between the two measurements is presented, and the opportunities provided by the mobile 3D luminance measurement system are discussed.

Description: Density-dependent population growth regulates long-term urban expansion and shapes distinctive socioeconomic trends. Despite a marked heterogeneity in the spatial distribution of the resident population, Mediterranean European countries are considered more homogeneous than countries in other European regions as far as settlement structure and processes of metropolitan growth are concerned. However, rising socioeconomic inequalities among Southern European regions reflect latent demographic and territorial transformations that require further investigation. An integrated assessment of the spatio-temporal distribution of resident populations in more than 1000 municipalities (1961–2011) was carried out in this study to characterize density-dependent processes of metropolitan growth in Greece. Using geographically weighted regressions, the results of our study identified distinctive local relationships between population density and growth rates over time. Our results demonstrate that demographic growth rates were non-linearly correlated with other variables, such as population density, with positive and negative impacts during the first (1961–1971) and the last (2001–2011) observation decade, respectively. These findings outline a progressive shift over time from density-dependent processes of population growth, reflecting a rapid development of large metropolitan regions (Athens, Thessaloniki) in the 1960s, to density-dependent processes more evident in medium-sized cities and accessible rural regions in the 2000s. Density-independent processes of population growth have been detected in the intermediate study period (1971–2001). This work finally discusses how a long-term analysis of demographic growth, testing for density-dependent mechanisms, may clarify the intrinsic role of population concentration and dispersion in different phases of the metropolitan cycle in Mediterranean Europe.

Description: Background: Health benefits from physical activity (PA) can be achieved by following the WHO recommendation for PA. To increase PA in inactive individuals, digital interventions can provide cost-effective and low-threshold access. Moreover, gamification elements can raise the motivation for PA. This study analyzed which factors (personality traits, app features, gamification) are relevant to increasing PA within this target group. Methods: N = 808 inactive participants (f = 480; m = 321; age = 48 ± 6) were integrated into the analysis of the desire for PA, the appearance of personality traits and resulting interest in app features and gamification. The statistical analysis included chi-squared tests, one-way ANOVA and regression analysis. Results: The main interests in PA were fitness (97%) and outdoor activities (75%). No significant interaction between personality traits, interest in PA goals, app features and gamification were found. The interest in gamification was determined by the PA goal. Participants’ requirements for features included feedback and suggestions for activities. Monetary incentives were reported as relevant gamification aspects. Conclusion: Inactive people can be reached by outdoor activities, interventions to increase an active lifestyle, fitness and health sports. The study highlighted the interest in specific app features and gamification to increase PA in inactive people through an app.

Description: To optimize the mechanical performance of fused deposition modelling (FDM) fabricated parts, it is necessary to evaluate the influence of process parameters on the resulting mechanical performance. The main focus of the study was to characterize the influence of the initial process parameters on the mechanical performance of thermoplastic polyurethane under a quasi-static and high strain rate (~2500 s−1). The effects of infill percentage, layer height, and raster orientation on the mechanical properties of an FDM-fabricated part were evaluated. At a quasi-static rate of loading, layer height was found to be the most significant factor (36.5% enhancement in tensile strength). As the layer height of the sample increased from 0.1 to 0.4 mm, the resulting tensile strength sample was decreased by 36.5%. At a high-strain rate of loading, infill percentage was found to be the most critical factor influencing the mechanical strength of the sample (12.4% enhancement of compressive strength at 100% as compared to 80% infill). Furthermore, statistical analysis revealed the presence of significant interactions between the input parameters. Finally, using an artificial neural networking approach, we evaluated a regression model that related the process parameters (input factors) to the resulting strength of the samples.

Description: The complexity and high sensitivity of proteins to environmental factors give rise to a multitude of variables, which affect the stabilization mechanisms in protein foams. Interfacial and foaming properties of proteins have been widely studied, but the reported unique effect of pH, which can be of great interest to applications, has been investigated to a lesser extent. In this paper, we focus on the impact of pH on the stability of black foam films and corresponding foams obtained from solutions of a model globular protein—the whey β-lactoglobulin (BLG). Foam stability was analyzed utilizing three characteristic parameters (deviation time, transition time and half-lifetime) for monitoring the foam decay, while foam film stability was measured in terms of the critical disjoining pressure of film rupture. We attempt to explain correlations between the macroscopic properties of a foam system and those of its major building blocks (foam films and interfaces), and thus, to identify structure-property relationships in foam. Good correlations were found between the stabilities of black foam films and foams, while relations to the properties of adsorption layers appeared to be intricate. That is because pH-dependent interfacial properties of proteins usually exhibit an extremum around the isoelectric point (pI), but the stability of BLG foam films increases with increasing pH (3–7), which is well reflected in the foam stability. We discuss the possible reasons behind these intriguingly different behaviors on the basis of pH-induced changes in the molecular properties of BLG, which seem to be determining the mechanism of film rupture at the critical disjoining pressure.

Description: The oxidation state and local atomic environment of admixtures of In, Cu, and Ag in synthetic sphalerite crystals were determined by X-ray absorption spectroscopy (XAS). The sphalerite crystals doped with In, Cu, Ag, In–Cu, and In–Ag were synthesized utilizing gas transport, salt flux, and dry synthesis techniques. Oxidation states of dopants were determined using X-ray absorption near edge structure (XANES) technique. The local atomic structure was studied by X-ray absorption fine structure spectroscopy (EXAFS). The spectra were recorded at Zn, In, Ag, and Cu K-edges. In all studied samples, In was in the 3+ oxidation state and replaced Zn in the structure of sphalerite, which occurs with the expansion of the nearest coordination shells due to the large In ionic radius. In the presence of In, the oxidation state of Cu and Ag is 1+, and both metals can form an isomorphous solid solution where they substitute for Zn according to the coupled substitution scheme 2Zn2+ ↔ Me+ + In3+. Moreover, Ag K-edges EXAFS spectra fitting, combined with the results obtained for In- and Au-bearing sphalerite shows that the Me-S distances in the first coordination shell in the solid solution state are correlated with the ionic radii and increase in the order of Cu 〈 Ag 〈 Au. The distortion of the atomic structure increases in the same order. The distant (second and third) coordination shells of Cu and Ag in sphalerite are split into two subshells, and the splitting is more pronounced for Ag. Analysis of the EXAFS spectra, coupled with the results of DFT (Density Function Theory) simulations, showed that the In–In and Me+–In3+ clustering is absent when the metals are present in the sphalerite solid solution. Therefore, all studied admixtures (In, Cu, Ag), as well as Au, are randomly distributed in the matrix of sphalerite, where the concentration of the elements in the “invisible” form can reach a few tens wt.%.

Description: In urban planning and transportation management, the centrality characteristics of urban streets are vital measures to consider. Centrality can help in understanding the structural properties of dense traffic networks that affect both human life and activity in cities. Many cities classify urban streets to provide stakeholders with a group of street guidelines for possible new rehabilitation such as sidewalks, curbs, and setbacks. Transportation research always considers street networks as a connection between different urban areas. The street functionality classification defines the role of each element of the urban street network (USN). Some potential factors such as land use mix, accessible service, design goal, and administrators’ policies can affect the movement pattern of urban travelers. In this study, nine centrality measures are used to classify the urban roads in four cities evaluating the structural importance of street segments. In our work, a Stacked Denoising Autoencoder (SDAE) predicts a street’s functionality, then logistic regression is used as a classifier. Our proposed classifier can differentiate between four different classes adopted from the U.S. Department of Transportation (USDT): principal arterial road, minor arterial road, collector road, and local road. The SDAE-based model showed that regular grid configurations with repeated patterns are more influential in forming the functionality of road networks compared to those with less regularity in their spatial structure.

Description: The complex failure mechanisms of glass laminates under in-plane loading conditions is modelled within the framework of phase-field strategy. Laminated glass is widely used for structural purposes due to its safe post-glass-breakage response. In fact, the combination of several glass plies bonded together with polymeric interlayers allows overcoming the brittleness of the glass and to reach a pseudo-ductile response. Moreover, the post-breakage behaviour of the laminate is strictly correlated by the mechanical properties of the constituents. Ruptures may appear as cracks within the layers or delamination of the bonding interface. The global response of a glass laminate, validated against experimental results taken from the literature, is carried out by investigating a simplified layup of two glass plies connected by cohesive interfaces through an interlayer. Delamination of the adhesive interface is described, and crack patterns within the materials are fully described. Finally, the proposed approach put the basis for future comparisons with results of experimental campaign and real-life applications.

Description: The size of the fracture process zone (FPZ) has significance for studying the fracture mechanism and fracture characteristics of concrete. This paper presents the method of assessing the FPZ of Mixed-Mode I-II for quasi-static four-point shearing concrete beams with pre-notched by Lagrangian strain profiles from digital image correlation (DIC). Additionally, it explores the influences of volume rates of the coarse aggregate of 0%, 28%, 48%, and 68%, and the specific surface areas of 0.12 m2/kg, 0.15 m2/kg, and 0.26 m2/kg on the size of the FPZ. It shows that the size of FPZ in four-point shearing concrete beam can be characterized by the displacement field and strain field using DIC. The size of FPZ conforms to linear positive correlation with the volume rate of coarse aggregate, and linear negative correlation with the specific surface area of coarse aggregate. It presents that the crack initiation of the four-point shearing beam with the pre notch is dominated by mode I load, and the propagation and fracture of Mixed-Mode I-II cracks are caused by the combined effect of Mode I and Mode II loading.

Description: The structural, mechanical, and electronic properties, as well as stability, elastic anisotropy and effective mass of AlN/GaN/InN in the Pmn21 phase were determined using density functional theory (DFT). The phonon dispersion spectra and elastic constants certify the dynamic and mechanical stability at ambient pressure, and the relative enthalpies were lower than those of most proposed III-nitride polymorphs. The mechanical properties reveal that Pmn21-AlN and Pmn21-GaN possess a high Vickers hardness of 16.3 GPa and 12.8 GPa. Pmn21-AlN, Pmn21-GaN and Pmn21-InN are all direct semiconductor materials within the HSE06 hybrid functional, and their calculated energy band gaps are 5.17 eV, 2.77 eV and 0.47 eV, respectively. The calculated direct energy band gaps and mechanical properties of AlN/GaN/InN in the Pmn21 phase reveal that these three polymorphs may possess great potential for industrial applications in the future.

Description: Mesenchymal stem cells (MSCs) have been isolated from a variety of tissues using different methods. Active research have confirmed that the most accessible site to collect them is the adipose tissue; which has a significantly higher concentration of MSCs. Moreover; harvesting from adipose tissue is less invasive; there are no ethical limitations and a lower risk of severe complications. These adipose-derived stem cells (ASCs) are also able to increase at higher rates and showing telomerase activity, which acts by maintaining the DNA stability during cell divisions. Adipose-derived stem cells secret molecules that show important function in other cells vitality and mechanisms associated with the immune system, central nervous system, the heart and several muscles. They release cytokines involved in pro/anti-inflammatory, angiogenic and hematopoietic processes. Adipose-derived stem cells also have immunosuppressive properties and have been reported to be “immune privileged” since they show negative or low expression of human leukocyte antigens. Translational medicine and basic research projects can take advantage of bioprinting. This technology allows precise control for both scaffolds and cells. The properties of cell adhesion, migration, maturation, proliferation, mimicry of cell microenvironment, and differentiation should be promoted by the printed biomaterial used in tissue engineering. Self-renewal and potency are presented by MSCs, which implies in an open-source for 3D bioprinting and regenerative medicine. Considering these features and necessities, ASCs can be applied in the designing of tissue engineering products. Understanding the heterogeneity of ASCs and optimizing their properties can contribute to making the best therapeutic use of these cells and opening new paths to make tissue engineering even more useful.

Description: In this paper, interactions of double parallel cracks were studied by performing experiments and numerical simulations. Fatigue crack propagation tests were carried out to measure crack growth rates in the specimens with double parallel cracks or a single crack. Finite element method was adopted to calculate stress intensity factors at the crack tips. Results show that the double parallel cracks at different positions present a shielding effect or enhancement effect on crack growth rates and stress intensity factors. When the double parallel cracks are offset, crack interactions mostly behave as enhancement effects. Empirical formulas were obtained to calculate the stress intensity factor at the “dangerous” crack tip of the double parallel cracks. By modifying the material parameters in Paris equation of the single crack, the double parallel cracks are simplified into a single crack with the same crack growth rates.

Description: The following article introduces technologies that build three dimensional (3D) objects by adding layer-upon-layer of material, also called additive manufacturing technologies. Furthermore, most important features supporting the conscious choice of 3D printing methods for applications in micro and nanomanufacturing are covered. The micromanufacturing method covers photopolymerization-based methods such as stereolithography (SLA), digital light processing (DLP), the liquid crystal display–DLP coupled method, two-photon polymerization (TPP), and inkjet-based methods. Functional photocurable materials, with magnetic, conductive, or specific optical applications in the 3D printing processes are also reviewed.

Description: This paper presents a series of dynamic simulations for a ship towed by kite. To ensure time efficient computations, seakeeping analysis with forward speed correction factors is carried out in the frequency domain and then transformed in the time domain by convolution. The seakeeping modeling is coupled with a zero-mass kite modeling assuming linear dependence of aerodynamic characteristics with respect to turning rate. Decoupled (segregated) and coupled (monolithic) approaches are assessed and compared in different environmental conditions. Results show that in regular beam waves, strong interactions between the kite and the ship motions are captured by the monolithic approach. Around the wave frequency, especially for the lower one tested (0.4 rad/s), a kite lock-in phenomenon is revealed. It is concluded that the mean kite towing force can be increased whereas the ship roll amplitude can even be decreased compared to a non-kite assisted ship propulsion configuration.

Description: One of the major issues faced when constructing various materials incorporating inorganic nanoparticles (NPs) is aggregation leading to loss of their final activity. In our work, cellulose acetate (CA) has been used to serve as matrix for the synthesis of UV-shielding and transparent films containing various amounts (1–5 wt.%) of cerium oxide (CeO2) NPs. In order to attain an improved dispersion and a better connectivity between NPs and the cellulose matrix, the surface of CeO2 NPs have been previously functionalized by the reaction with 3-aminopropyl(diethoxy)methylsilane (APDMS). The uniform dispersion of the NPs in the homogeneous thin films has been evidenced by using Transmission Electron Microscopy (TEM) and Fourier Transformation Infrared Spectroscopy (FTIR) characterization. The investigation of the optical properties for the hybrid films through UV-Vis spectroscopy revealed that the presence of CeO2 NPs in the CA matrix determined the appearance of strong UV absorption bands in the region 312–317 nm, which supports their use as efficient UV absorbers. This study has shown that UV shielding ability of the nanocomposites can be easily tuned by adjusting the numberof inorganic NPs in the CA template.

Description: In 1997, in front of the Pescara Harbour (Italy), a detached breakwater was constructed. In the successive years, the sediment transport due to the combined action of waves and coastal currents, in the area between the detached breakwater and the entrance of the Pescara Harbour, produced an accumulation of about 40,000   m 3 of sediment per year. In this paper, the causes of the accretion of the bottom elevation in front of the Pescara Harbour entrance and the effects produced by the existing detached breakwater are investigated. The effects on the sediment transport of the introduction of a new submerged breakwater designed to protect the entrance of the harbour from sediment siltation are investigated. In particular, the ability of the designed submerged breakwater, located orthogonally to the longshore current, to intercept the aforementioned solid material and to significantly reduce the accretion of the bottom in the area in front of the harbour entrance, was numerically verified. Numerical simulations were carried out by means of a model of the bottom-change composed of two sub-models: a two-dimensional phase resolving model that is used to calculate the fluid dynamic variables changing inside the wave period and a second sediment transport sub-model to simulate the bottom changes, in which the suspended sediment concentration is calculated by the wave-averaged advection–diffusion equation. The equations of motion, in which the vector and tensor quantities are expressed in Cartesian components, are written in a generalised curvilinear coordinate system. The fully nonlinear Boussinesq equations are written in an integral form and used to simulate the velocity fields.

Description: The aspects regarding the stiffness of the connections between the beams that support the storage pallets and the uprights is very important in the analysis of the displacements and stresses in the storage racking systems. The main purpose of this paper is to study the effects of both upright thickness and tab connector type on the rotational stiffness and on the capable bending moment of the connection. For this purpose, a number of 18 different groups of beam-connector-upright assemblies are prepared by combining three types of beams (different sizes of the box cross section), three kinds of uprights profiles (with a different thickness of the section walls), and two types of connectors (four-tab connectors and five-tab connectors). Flexural tests were carried out on 101 assemblies. For the assemblies containing the uprights having the thickness of 1.5 mm, the five-tab connector leads to a higher value of the capable moment and higher rotational stiffness than similar assemblies with four-tab connectors. A contrary phenomenon happens in case of the assemblies containing the upright profiles having a thickness of 2.0 mm regarding the capable design moment. It is shown how the safety coefficient of connection depends on both the rotational stiffness and capable bending moment.

Description: This study investigated the heat-induced acceleration of cement hydration and pozzolanic reaction focusing on mechanical performance and structural modification at the meso- and micro-scale. The pozzolanic reaction was implemented by substituting 20 wt.% of cement with silica fume, considered the typical dosage of silica fume in ultra-high performance concrete. By actively consuming a limited amount of water and outer-formed portlandite on the unreacted cement grains, it was confirmed that high-temperature curing greatly enhances the pozzolanic reaction when compared with cement hydration under the same environment. The rate of strength development from the dual reactions of cement hydration and pozzolanic reaction was increased. After the high-temperature curing, further strength development was negligible because of the limited space availability and preconsumption of water under a low water-to-cement environment. Since the pozzolanic reaction does not directly require the anhydrous cement, the reaction can be more easily accelerated under restrained conditions because it does not heavily rely on the diffusion of the limited amount of water. Therefore, it significantly increases the mean chain length of the C–S–H, the size of C–S–H globules with a higher surface fractal dimension. This finding will be helpful in understanding the complicated hydration mechanism of high-strength concrete or ultra-high performance concrete, which has a very low water-to-cement ratio.

Description: Micro-arc oxidation (MAO) treatment is a simple and effective technique to improve the corrosion resistance for magnesium alloys. However, the presence of micro-pores and cracks on the coatings provides paths for corrosive ions to penetrate into and react with the substrate, limiting the long-term corrosion resistance. In this paper, we designed a composite coating with which GelMA hydrogel coatings with varying thicknesses were prepared on the surface of MAO-coated magnesium alloys via a dip-coating method, aiming to improve the biocorrosion resistance and biocompatibility. The surface morphology, the chemical composition of GelMA hydrogels, and the crystallographic structure of magnesium alloys were characterized by scanning electron microscope (SEM), Fourier-transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD), respectively. The corrosion resistance and biocompatibility of all samples were evaluated through electrochemical and biological experiments. The results demonstrated that the addition of GelMA hydrogel could effectively seal the pores and improve the corrosion resistance and biocompatibility of MAO-coated magnesium alloys, especially for the sample with one layer of GelMA hydrogel, showing high cell proliferation rate, and its current density (Icorr) was two orders of magnitude lower than that of the MAO coating. Besides, the balance mechanism between corrosion and protection was proposed. As a result, the GelMA hydrogel coatings are beneficial to the application of MAO-coated magnesium alloys in bone tissue engineering and other fields.

Description: To study the influence of complex terrain with different scales on the structure of near-surface turbulence, the turbulence observational data from Semi-Arid Climate and Environment Observatory of Lanzhou University (SACOL) were analyzed. SACOL is located in typical Loess Plateau topography. The terrain around the site varies greatly with the direction. Representative data from the Northeast, Southeast, Southwest, and Northwest were selected to study the structure characteristics of the near surface turbulence. The complex topography within the flux footprint enhances the vertical scale of turbulence σw and thereby increases the vertical–longitudinal ratio of turbulence Ar. While the turbulent horizontal scale σu is also significantly affected by the distant terrain beyond the flux footprint. The upwind terrain undulation increases σu and reduces Ar. Affected by the complex terrain, the ratio of the spectrum of the vertical velocity to that of the longitudinal velocity, Sw(n)/Su(n), is far less than 4/3 in the southwest direction, and the turbulence is significantly anisotropic.

Description: Providing recommendations in cold start situations is one of the most challenging problems for collaborative filtering based recommender systems (RSs). Although user social context information has largely contributed to the cold start problem, most of the RSs still suffer from the lack of initial social links for newcomers. For this study, we are going to address this issue using a proposed user similarity detection engine (USDE). Utilizing users’ personal smart devices enables the proposed USDE to automatically extract real-world social interactions between users. Moreover, the proposed USDE uses user clustering algorithm that includes contextual information for identifying similar users based on their profiles. The dynamically updated contextual information for the user profiles helps with user similarity clustering and provides more personalized recommendations. The proposed RS is evaluated using movie recommendations as a case study. The results show that the proposed RS can improve the accuracy and personalization level of recommendations as compared to two other widely applied collaborative filtering RSs. In addition, the performance of the USDE is evaluated in different scenarios. The conducted experimental results on USDE show that the proposed USDE outperforms widely applied similarity measures in cold start and data sparsity situations.

Description: This study investigated the recovery stress and bond resistance of cold drawn crimped SMA fiber using two different initial diameters of 1.0 and 0.7 mm. These characteristics are important to the active prestressing effect and crack-closing of the fiber. NiTi SMA fiber was used for the cold drawing, and then crimped shapes were manufactured with various wave heights. After that, tensile, recovery, and pullout tests were conducted. The cold drawn crimped fiber showed softening tensile behavior more clearly than the cold drawn straight fiber when not subjected to heating, whereas they had the same tensile behavior under heating. The recovery stress and the residual stress of the crimped fibers were less than those of the straight fiber with the same diameter. Moreover, crimped fibers with a large diameter and higher wave height would induce more recovery stress and residual stress. The maximum pullout resistance of the crimped fiber was a function of the wave depth, embedded length, yield strength, and flexural rigidity of the fiber.

Description: This paper presents the modification of the antibiotic rifampicin by an anionic polyelectrolyte using a simplified electrochemically mediated atom transfer radical polymerization (seATRP) technique to receive stimuli-responsive polymer materials. Initially, a supramolecular ATRP initiator was prepared by an esterification reaction of rifampicin hydroxyl groups with α-bromoisobutyryl bromide (BriBBr). The structure of the initiator was successfully proved by nuclear magnetic resonance (1H and 13C NMR), Fourier-transform infrared (FT-IR) and ultraviolet–visible (UV-vis) spectroscopy. The prepared rifampicin-based macroinitiator was electrochemically investigated among various ATRP catalytic complexes, by a series of cyclic voltammetry (CV) measurements, determining the rate constants of electrochemical catalytic (EC’) process. Macromolecules with rifampicin core and hydrophobic poly (n-butyl acrylate) (PnBA) and poly(tert-butyl acrylate) (PtBA) side chains were synthesized in a controlled manner, receiving polymers with narrow molecular weight distribution (Mw/Mn = 1.29 and 1.58, respectively). “Smart” polymer materials sensitive to pH changes were provided by transformation of tBA into acrylic acid (AA) moieties in a facile route by acidic hydrolysis. The pH-dependent behavior of prepared macromolecules was investigated by dynamic light scattering (DLS) determining a hydrodynamic radius of polymers upon pH changes, followed by a control release of quercetin as a model active substance upon pH changes.