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  • American Chemical Society  (175.217)
  • BioMed Central  (14.038)
  • Nature Publishing Group  (13.578)
  • Blackwell Publishing Ltd
  • 2025-2025
  • 2005-2009  (205.069)
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  • 1
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    Blackening of Pompeian Cinnabar paintings: X-ray micro-spectroscopy analysis (2007)
    American Chemical Society
    Details
    Publikationsdatum: 2017-04-04
    Beschreibung: Red Pompeian paintings, very famous for their deep intensity, are currently suffering from darkening. The origins of this darkening degradation are not clearly identified yet and remain a major issue for curators. In the specific case of cinnabar (HgS)-based red pigment, a photoinduced conversion into black metacinnabar is usually suspected. This work is focused on the blackening of red cinnabar paintings coated on a sparry calcite mortar. Different samples exhibiting different levels of degradation were selected upon visual observations and analyzed by synchrotron-based microanalytical techniques. Atomic and molecular compositions of the different debased regions revealed two possible degradation mechanisms. On one hand, micro X-ray fluorescence elemental maps show peculiar distributions of chlorine and sulfur. On the other hand, X-ray absorption spectroscopy performed at both Cl and S K-edges confirms the presence of characteristic degradation products: (i) Hg- Cl compounds (e.g., corderoite, calomel, and terlinguaite), which may result from the reaction with exogenous NaCl, in gray areas; (ii) gypsum, produced by the calcite sulfation, in black coatings. Metacinnabar is never detected. Finally, a cross section was analyzed to map the in-depth alteration gradient. Reduced and oxidized sulfur distributions reveal that the sulfated black coating consists of a 5-ím-thick layer covering intact cinnabar.
    Beschreibung: Published
    Beschreibung: 7484-7492
    Beschreibung: reserved
    Schlagwort(e): Microspectroscopy Analysis ; 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 2
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    Evidence of seismic deformation of the paved floor of the decumanus at Tindari (NE, Sicily) (2008)
    Blackwell Publishing Ltd
    Details
    Publikationsdatum: 2017-04-04
    Beschreibung: Most of the ancient town of Tindari (NE, Sicily) was settled on a plateau the most surficial layer of which was made of unconsolidated material. Ongoing excavations at the archaeological site at Tindari uncovered a large portion of the decumanus which suffered deformations preliminarily assigned to coseismic effects. An analysis of the local dynamic response through the simulation of strong seismic shaking to the bedrock and modelling of spectral ratios of the bedrock-soft soil was carried out to verify the susceptibility of superficial terrains of the promontory to coseismic deformations. To perform this simulation the finite element method (FEM) was used. Four accelerometric recordings of three earthquakes of medium-high magnitude, recorded on rocky sites, were chosen to simulate the seismic shaking, using a constitutive law for the materials composing the promontory layers both of linear-elastic type and of elastoplastic type. The analysis of the linear-elastic field allowed the definition of the frequencies for which the spectral ratios of the accelerations recorded the highest amplifications; in particular the frequency range 31.5–37.2 Hz can be combined with deformation of the paved floor of the decumanus. The analysis in the elastoplastic field highlighted the zones of promontory more susceptible to suffer plasticization process. The results show that the topmost layer of the decumanus is the most susceptible to suffer plasticization. Therefore, the performed analysis lends greater support to the hypothesis that the deformations were produced by seismic shaking.
    Beschreibung: Published
    Beschreibung: 213-222
    Beschreibung: 3.10. Sismologia storica e archeosismologia
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Fourier analysis ; Elasticity and anelasticity ; Earthquake ground motions ; Site effects ; Computational seismology ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
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    Tectonic features of the Lipari–Vulcano complex (Aeolian archipelago, Italy) from 10 years (1996–2006) of GPS data (2008)
    Blackwell Publishing Ltd
    Details
    Publikationsdatum: 2017-04-04
    Beschreibung: The tectonic deformation of the Lipari-Vulcano complex, one of the most important active volcanic areas of Mediterranean region, is studied here through the analysis of ten years (1996-2006) of GPS data from both 3 permanent and 13 non-permanent stations. This area can be considered crucial for the understanding of the Eurasia-Africa plates interaction in the Mediterranean area, and, in general, this work emphasize a methodological approach, already applied in other areas worldwide (e.g. Shen et al., 1996, El-Fiki and Kato, 1999) where geodetic data and strain parameters maps of critical areas can help to improve our understanding of their geodynamical aspects. In this framework, this study is aimed at providing a kinematic deformation model on the basis of the dense geodetically estimated velocities of the Lipari-Vulcano complex. In particular, the observed deformation pattern can be described by a mix between 1) the main N-S regional compression and 2) a NNE-SSW compression with a small right-lateral strike slip component acting along a tectonic structure N°40W trending located between the two islands. This pattern was inspected through a simplified synthetic model.
    Beschreibung: This research has benefited from funding provided by the Italian Presidenza del Consiglio dei Ministri – Dipartimento della Protezione Civile (DPC).
    Beschreibung: Published
    Beschreibung: 370–377
    Beschreibung: 1.9. TTC - Rete GPS nazionale
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): GPS ; Aeolian Islands ; strain ; modelling ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
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    P-wave propagation heterogeneity and earthquake location in the Mediterranean region (2008)
    Blackwell Publishing Ltd
    Details
    Publikationsdatum: 2012-02-03
    Beschreibung: We analyse P-wave traveltimes for the Mediterranean area, using both teleseismic and regional arrivals for shallow earthquakes reported in the Bulletins of the International Seismological Centre. We model delays between pairs of 0.5° × 0.5° cells, obtaining a detailed representation of the P traveltime heterogeneities. Examination of these anomalies shows the clear presence of geographically coherent patterns—consistent with known geological features—due to significant structure in the upper mantle. We present a scheme, based on an empirical heterogeneity correction (EHC) to P-wave traveltimes, to improve earthquake location. This method provides similar benefits to those of a location procedure based on ray tracing in a 3-D model, but it is simpler and computationally more efficient. The definition of the traveltime heterogeneity model, being based on a statistical procedure, bypasses most of the critical points and possible instabilities involved in model inversion. EHC relocation, applied to Mediterranean earthquakes, allows one to predict about 70 per cent of the estimated signal due to heterogeneity and produces epicentral and origin time-shifts of, respectively, 4.22 km and 0.35 s (rms). From a synthetic experiment, in which we use the proposed algorithm to retrieve known source locations, we estimate that the rms improvement achieved by the EHC relocation over a simpler, standard, 1-D location is more than 20 per cent for both epicentral mislocation and origin time-shifts.
    Beschreibung: Published
    Beschreibung: 232-254
    Beschreibung: 3.3. Geodinamica e struttura dell'interno della Terra
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): earthquake location ; Mediterranean ; P waves ; traveltime ; upper mantle ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
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    New results of 40Ar/39Ar dating constrain the timing of transition from fissure-type to central volcanism at Mount Etna (Italy) (2008)
    Blackwell Publishing Ltd
    Details
    Publikationsdatum: 2017-04-04
    Beschreibung: Recent geological studies performed at Etna allow reassessing the stratigraphic frame of the volcano where distinct evolutionary phases are defined. This stratigraphic reconstruction was chronologically constrained on the basis of a limited number of U–Th and K–Ar age determinations whose uncertainty margins are sometimes too wide. For this reason, we successfully adopted at Etna the 40Ar/39Ar technique that allowed obtaining more precise age determinations. The incremental heating technique also gives information on sample homogeneity, and potential problems of trapped argon. Five samples were collected from stratigraphically well-controlled volcanic units in order to chronologically define the transition between the fissure-type volcanism of the Timpe phase to the central volcanism of the Valle del Bove Centers. Isotopic ages with an uncertainty margin of 2–4% have been obtained emphasizing that this transition occurred (130– 126 ka) without significant temporal hiatus.
    Beschreibung: University of Catania grants (COFIN- 2002, resp. F. Lentini); CNR-IDPA and INGV-Sezione di Catania grants.
    Beschreibung: Published
    Beschreibung: 292-298
    Beschreibung: 3.5. Geologia e storia dei sistemi vulcanici
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): 40Ar/39Ar dating ; Etna ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
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    Methane seepage in an urban development area (Bacau, Romania): origin, extent, and hazard (2008)
    Blackwell Publishing Ltd
    Details
    Publikationsdatum: 2017-04-04
    Beschreibung: The paper describes a case of a natural emission of methane from soil in an urban development area, generating a significant risk for the local population and buildings, due to gas explosiveness and asphyxiation potential. The site is located on the south-western margin of the East-European Platform in eastern Romania, in a hydrocarbon-prone area crossed by the Pericarpathian lineament and regional faults. Molecular composition of gas and stable isotopic analyses of methane (CH4〉90%, δ to the power of 13 C1: -49.4‰, δD1: -173.4‰) indicate a dominant thermogenic origin, with significant amounts of C2-C5 alkanes (~5%), likely migrating through faults from a deep reservoir. Possible candidates are the Saucesti and Secuieni gas fields, located in the same petroleum system. Two surface geochemical surveys, based on closed-chamber flux measurements, were performed to assess the degassing intensity and the extent of the affected area. Methane fluxes from soil reach orders of 10 to the power of 4 mg m to the power of -2 day to the power of -1. Gas seepage mainly occurs in one zone 30 000 m2 wide, and it is likely controlled by channeling along a fault and gas accumulation in permeable sediments and shallow subsoil. The estimated total CH4 emission is about 40 t year to the power of -1 CH4, of which 8–9 t year to the power of -1 are naturally released from soil and 30–35 t year to the power of -1 are emitted from shallow boreholes. These wells have likely channeled the gas accumulated in shallow alluvial sediment but gas flux from soil is still high and mitigation measures are needed to reduce the risk for humans and buildings.
    Beschreibung: Published
    Beschreibung: 311-320
    Beschreibung: 3.8. Geofisica per l'ambiente
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): gas hazard ; methane seepage ; soil degassing ; thermogenic gas ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
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    New evidence for a mixed inorganic and organic origin of the Olympic Chimaera fire (Turkey): a large onshore seepage of abiogenic gas (2008)
    Blackwell Publishing Ltd
    Details
    Publikationsdatum: 2017-04-04
    Beschreibung: The Chimaera gas seep, near Antalya (SW Turkey), has been continuously active for thousands of years and it is known to be the source of the first Olympic fire in the Hellenistic period. New and thorough molecular and isotopic analyses including methane (approximately 87% v/v; δ to the power of 13 C1 from -7.9‰ to -12.3‰; δ to the power of 13 D1 from -119‰ to -124‰), light alkanes (C2 + C3 + C4 + C5 = 0.5%; C6+: 0.07%; δ to the power of 13 C2 from -24.2‰ to -26.5‰; δ to the power of 13 C3 from -25.5‰ to -27‰), hydrogen (7.5–11%), carbon dioxide (0.01–0.07%; δ to the power of 13 CCO2: -15‰), helium (approximately 80 ppmv; R/Ra: 0.41) and nitrogen (2–4.9%; δ to the power of 15 N from -2‰ to -2.8‰) converge to indicate that the seep releases a mixture of organic thermogenic gas, related to mature type III kerogen occurring in Palaeozoic and Mesozoic organic-rich sedimentary rocks, and abiogenic gas produced by low-temperature serpentinization in the Tekirova ophiolitic unit. Methane is not related to mantle or magma degassing. The abiogenic fraction accounts for about half of the total gas released, which is estimated to be well beyond 50 ton year to the power of -1. Ophiolites and limestones are in contact along a tectonic dislocation leading to gas mixing and migration to the Earth’s surface. Chimaera represents the biggest emission of abiogenic methane on land discovered so far. Deep and pressurized gas accumulations are necessary to sustain the Chimaera gas flow for thousands of years and are likely to have been charged by an active inorganic source.
    Beschreibung: Published
    Beschreibung: 263-273
    Beschreibung: 3.8. Geofisica per l'ambiente
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): abiogenic methane ; isotopic composition ; ophiolites ; seep ; serpentinization ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
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    Multiple hydro-fracturing by boron-rich fluids in the Late Miocene contact aureole of eastern Elba Island (Tuscany, Italy) (2008)
    Blackwell Publishing Ltd
    Details
    Publikationsdatum: 2017-04-04
    Beschreibung: In eastern Elba Island (Tuscany, Italy), a shallow crustal level felsic, tourmaline-bearing, dyke-sill swarm of Late Miocene age is associated with abundant tourmaline-quartz hydrothermal veins and metasomatic masses. Development of these veins and masses in the host rocks demonstrates multiple hydro-fracturing by magmatic, boron-rich saline fluid. Tourmalines in felsic dykes are schorl, whereas in veins and metasomatic masses, tourmaline composition ranges from schorl-dravite through dravite to uvite. This compositional shift is evidence for an increasing contribution to the magmatic boron-rich fluids by a Mg-Ca-Ti-rich external component represented by biotite-rich and amphibolite host rocks. This system can be envisaged as an exposed proxy of the high temperature hydrothermal system presently active in the deepest part of the Larderello-Travale geothermal field (Tuscany).
    Beschreibung: Published
    Beschreibung: 318-326
    Beschreibung: 3.3. Geodinamica e struttura dell'interno della Terra
    Beschreibung: 3.5. Geologia e storia dei sistemi vulcanici
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Hydro-fractures ; geothermal systems ; Magmatism ; southern Tuscany ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
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    The environmental toxicant 2,3,7,8-tetrachlorodibenzo-p-dioxin disrupts morphogenesis of the rat pre-implantation embryo (2008)
    BioMed Central
    Details
    Publikationsdatum: 2022-05-25
    Beschreibung: © 2008 Hutt et al. This is an Open Access article distributed under the terms of the Creative Commons Attribution License 2.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The definitive version was published in BMC Developmental Biology 8 (2008): 1, doi:10.1186/1471-213X-8-1.
    Beschreibung: Environmental toxicants, whose actions are often mediated through the aryl hydrocarbon receptor (AhR) pathway, pose risks to the health and well-being of exposed species, including humans. Of particular concern are exposures during the earliest stages of development that while failing to abrogate embryogenesis, may have long term effects on newborns or adults. The purpose of this study was to evaluate the effect of maternal exposure to the AhR-specific ligand 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) on the development of rat pre-implantation embryos with respect to nuclear and cytoskeletal architecture and cell lineage allocation. We performed a systematic 3 dimensional (3D) confocal microscopy analysis of rat pre-implantation embryos following maternal exposure to environmentally relevant doses of TCDD. Both chronic (50 ng/kg/wk for 3 months) and acute (50 ng/kg and 1 μg/kg at proestrus) maternal TCDD exposure disrupted morphogenesis at the compaction stage (8–16 cell), with defects including monopolar spindle formation, f-actin capping and fragmentation due to aberrant cytokinesis. Additionally, the size, shape and position of nuclei were modified in compaction stage pre-implantation embryos collected from treated animals. Notably, maternal TCDD exposure did not compromise survival to blastocyst, which with the exception of nuclear shape, were morphologically similar to control blastocysts. We have identified the compaction stage of pre-implantation embryogenesis as critically sensitive to the effects of TCDD, while survival to the blastocyst stage is not compromised. To the best of our knowledge this is the first in vivo study to demonstrate a critical window of pre-implantation mammalian development that is vulnerable to disruption by an AhR ligand at environmentally relevant doses.
    Beschreibung: This research was supported by NIH/NIEHS-012916 (BKP), ESHE Fund (DFA), Hall Family Foundation (DFA and KJH) and Biomedical Research Training Grant KUMC (KJH).
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
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  • 10
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    New criteria for selecting the origin of DNA replication in Wolbachia and closely related bacteria (2007)
    BioMed Central
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    Publikationsdatum: 2022-05-25
    Beschreibung: © 2007 Ioannidis et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The definitive version was published in BMC Genomics 8 (2007): 182, doi:10.1186/1471-2164-8-182.
    Beschreibung: Background: The annotated genomes of two closely related strains of the intracellular bacterium Wolbachia pipientis have been reported without the identifications of the putative origin of replication (ori). Identifying the ori of these bacteria and related alpha-Proteobacteria as well as their patterns of sequence evolution will aid studies of cell replication and cell density, as well as the potential genetic manipulation of these widespread intracellular bacteria. Results: Using features that have been previously experimentally verified in the alpha-Proteobacterium Caulobacter crescentus, the origin of DNA replication (ori) regions were identified in silico for Wolbachia strains and eleven other related bacteria belonging to Ehrlichia, Anaplasma, and Rickettsia genera. These features include DnaA-, CtrA- and IHF-binding sites as well as the flanking genes in C. crescentus. The Wolbachia ori boundary genes were found to be hemE and COG1253 protein (CBS domain protein). Comparisons of the putative ori region among related Wolbachia strains showed higher conservation of bases within binding sites. Conclusion: The sequences of the ori regions described here are only similar among closely related bacteria while fundamental characteristics like presence of DnaA and IHF binding sites as well as the boundary genes are more widely conserved. The relative paucity of CtrA binding sites in the ori regions, as well as the absence of key enzymes associated with DNA replication in the respective genomes, suggest that several of these obligate intracellular bacteria may have altered replication mechanisms. Based on these analyses, criteria are set forth for identifying the ori region in genome sequencing projects.
    Beschreibung: PI, PS, SS, GT and KB acknowledge support of their work from intramural funding from the University of Ioannina. SB, JDH, LB and JW acknowledge support of their work from the U.S. National Science Foundation grant EF-0328363. SB also acknowledges the support from the NASA Astrobiology Institute (NNA04CC04A)
    Repository-Name: Woods Hole Open Access Server
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