ALBERT

Description: The roughness of a glacier bed has high importance for the estimation of the sliding velocity and can also provide valuable insights into the dynamics and history of ice sheets, depending on scale. Measurement of basal properties in present-day ice sheets is restricted to ground-penetrating radar and seismics, with surveys retrieving relatively coarse data sets. Deglaciated areas, like the Barents Sea, can be surveyed by shipborne 2-D and 3-D seismics and multibeam sonar and provide the possibility of studying the basal roughness of former ice sheets and ice streams with high resolution. Here, for the first time, we quantify the subglacial roughness of the former Barents Sea ice sheet by estimating the spectral roughness of the basal topography. We also make deductions about the past flow directions by investigating how the roughness varies along a 2-D line as the orientation of the line changes. Lastly, we investigate how the estimated basal roughness is affected by the resolution of the basal topography data set by comparing the spectral roughness along a cross section using various sampling intervals. We find that the roughness typically varies on a similar scale as for other previously marine-inundated areas in West Antarctica, with subglacial troughs having very low roughness, consistent with fast ice flow and high rates of basal erosion. The resolution of the data set seems to be of minor importance when comparing roughness indices calculated with a fixed profile length. A strong dependence on track orientation is shown for all wavelengths, with profiles having higher roughness across former flow directions than along them.

Description: Enhancement of ocean alkalinity using calcium compounds, e.g., lime has been proposed to mitigate further increase of atmospheric CO2 and ocean acidification due to anthropogenic CO2 emissions. Using a global model, we show that such alkalinization has the potential to preserve pH and the saturation state of carbonate minerals at close to today’s values. Effects of alkalinization persist after termination: Atmospheric CO2 and pH do not return to unmitigated levels. Only scenarios in which large amounts of alkalinity (i.e., in a ratio of 2:1 with respect to emitted CO2) are added over large ocean areas can boost oceanic CO2 uptake sufficiently to avoid further ocean acidification on the global scale, thereby elevating some key biogeochemical parameters, e.g., pH significantly above preindustrial levels. Smaller-scale alkalinization could counteract ocean acidification on a subregional or even local scale, e.g., in upwelling systems. The decrease of atmospheric CO2 would then be a small side effect.

Description: Optical televiewer luminosity logs are compared with densities measured gravimetrically on 520 snow, firn and ice samples from two locations of similar annual temperature (~-14 °C) and contrasting accumulation rates (0.23 and 0.43 m w.e. per year) on the Roi Baudouin Ice Shelf, Antarctica. At the scale of ≥10-1 m, an inverse exponential relationship (R2 = 0.96) is recorded between density and luminosity, indicating (i) that OPTV luminosity provides an effective proxy for density at such ice shelves, and (ii) that densities may be reconstructed from boreholes drilled elsewhere by hot water without the need for core material. Our analysis also suggests that this relationship may hold for newly-formed ice as well as for snow and firn. At the scale of ≤10-1 m, both luminosity and density show similar patterns, but precise correlation is confounded by detailed differences between the two records.

Description: Over the last decade, several hundred seals have been equipped with conductivity-temperature-depth sensors in the Southern Ocean for both biological and physical oceanographic studies. A calibrated collection of seal-derived hydrographic data is now available, consisting of more than 165,000 profiles. The value of these hydrographic data within the existing Southern Ocean observing system is demonstrated herein by conducting two state estimation experiments, differing only in the use or not of seal data to constrain the system. Including seal-derived data substantially modifies the estimated surface mixedlayer properties and circulation patterns within and south of the Antarctic Circumpolar Current. Agreement with independent satellite observations of sea ice concentration is improved, especially along the East Antarctic shelf. Instrumented animals efficiently reduce a critical observational gap, and their contribution to monitoring polar climate variability will continue to grow as data accuracy and spatial coverage increase.

Description: [1] The Antarctic Intermediate Water (AAIW) is a key player in global-scale oceanic overturning processes and an important conduit for heat, fresh water, and carbon transport. The AAIW past variability is poorly understood mainly due to the lack of sedimentary archives at intermediate water depths. We present records of benthic stable isotopes from sediments retrieved with the seafloor drill rig MARUM-MeBo at 956 m water depth off northern Chile (GeoB15016, 27°29.48′S, 71°07.58′W) that extend back to 970 ka. The sediments at this site are presently deposited at the boundary between AAIW and Pacific Deep Water (PDW). For previous peak interglacials, our results reveal similar benthic δ13C values at site GeoB15016 and of a newly generated stack of benthic δ13C from various deep Pacific cores representing the “average PDW.” This suggests, unlike today, the absence of AAIW at the site and the presence of nearly pure PDW. In contrast, more positive δ13C values at site GeoB15016 compared to the stack imply a considerable AAIW contribution during cold phases of interglacials and especially during glacials. Besides, we used three short sediment cores to reconstruct benthic δ13C values from the AAIW core during the last glacial and found a δ13C signature similar to today's. Assuming that this was the case also for the past 970 kyr, we demonstrate that sea level changes and latitudinal migrations of the AAIW formation site can only account for about 50% of the full range of past δ13C increases at site GeoB15016 during cold periods. Other processes that could explain the remaining of the positive δ13C anomalies are increases in glacial AAIW production and/or deeper convection of the AAIW with respect to preceding interglacials.

Description: wo commonly used proxies based on the distribution of glycerol dialkyl glycerol tetraethers (GDGTs) are the TEX86 (TetraEther indeX of 86 carbon atoms) paleothermometer for sea surface temperature reconstructions and the BIT (Branched Isoprenoid Tetraether) index for reconstructing soil organic matter input to the ocean. An initial round-robin study of two sediment extracts, in which 15 laboratories participated, showed relatively consistent TEX86 values (reproducibility ±3–4°C when translated to temperature) but a large spread in BIT measurements (reproducibility ±0.41 on a scale of 0–1). Here we report results of a second round-robin study with 35 laboratories in which three sediments, one sediment extract, and two mixtures of pure, isolated GDGTs were analyzed. The results for TEX86 and BIT index showed improvement compared to the previous round-robin study. The reproducibility, indicating interlaboratory variation, of TEX86 values ranged from 1.3 to 3.0°C when translated to temperature. These results are similar to those of other temperature proxies used in paleoceanography. Comparison of the results obtained from one of the three sediments showed that TEX86 and BIT indices are not significantly affected by interlaboratory differences in sediment extraction techniques. BIT values of the sediments and extracts were at the extremes of the index with values close to 0 or 1, and showed good reproducibility (ranging from 0.013 to 0.042). However, the measured BIT values for the two GDGT mixtures, with known molar ratios of crenarchaeol and branched GDGTs, had intermediate BIT values and showed poor reproducibility and a large overestimation of the “true” (i.e., molar-based) BIT index. The latter is likely due to, among other factors, the higher mass spectrometric response of branched GDGTs compared to crenarchaeol, which also varies among mass spectrometers. Correction for this different mass spectrometric response showed a considerable improvement in the reproducibility of BIT index measurements among laboratories, as well as a substantially improved estimation of molar-based BIT values. This suggests that standard mixtures should be used in order to obtain consistent, and molar-based, BIT values.

Description: Estimates of the relative motion between the Hawaiian and Louisville hot spots have consequences for understanding the role and character of deep Pacific-mantle return flow. The relative motion between these primary hot spots can be inferred by comparing the age records for their seamount trails. We report 40Ar/39Ar ages for 18 lavas from 10 seamounts along the Hawaiian-Emperor Seamount Chain (HESC), showing that volcanism started in the sharp portion of the Hawaiian-Emperor Bend (HEB) at ≥47.5 Ma and continued for ≥5 Myr. The slope of the along-track distance from the currently active Hawaiian hot spot plotted versus age is constant (57 ± 2 km/Myr) between ∼57 and 25 Ma in the central ∼1900 km of the seamount chain, including the HEB. This model predicts an age for the oldest Emperor Seamounts that matches published ages, implying that a linear age-distance relationship might extend back to at least 82 Ma. In contrast, Hawaiian age progression was much faster since at least ∼15 Ma and possibly as early as ∼27 Ma. Linear age-distance relations for the Hawaii-Emperor and Louisville seamount chains predict ∼300 km overall hot spot relative motion between 80 and 47.5 Ma, in broad agreement with numerical models of plumes in a convecting mantle, and paleomagnetic data. We show that a change in hot spot relative motion may also have occurred between ∼55 Ma and ∼50 Ma. We interpret this change in hot spot motion as evidence that the HEB reflects a combination of hot spot and plate motion changes driven by the same plate/mantle reorganization.

Description: The western Ross Sea is one of the key sites for cross-shelf water exchange around Antarctica. The mech- anism through which tides affect the cross-shelf exchange in the northwestern Ross Sea is investigated using numeri- cal simulations. Tides are found to increase the high-salinity shelf water (HSSW) outflow through the impact on the warm water intrusion of open ocean origin. The residual tidal currents are onshore along the Modified Circumpolar Deep Water pathway and therefore enhance its intrusion. Lighter ambient water adjacent to the HSSW increases the cross-flow density gradient, thus strengthening the HSSW export. At the same time, the onshore residual current and increased dilution of the HSSW have the potential to reduce the export rate. Owing to the existence of opposite tidal effects, the strongest HSSW export happens at the inter- mediate tidal forcing strength. The amplification of tides on cross-shelf exchange indicates that the relevant dynam- ical processes should be simulated or parameterized in climate models in order to adequately predict the ocean.