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  • Artikel  (145)
  • sol-gel  (85)
  • evolution  (60)
  • Springer  (145)
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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Entomologia experimentalis et applicata 82 (1997), S. 37-44 
    ISSN: 1570-7458
    Schlagwort(e): Barbarea vulgaris ; Cruciferae ; Phyllotreta nemorum ; Chrysomelidae ; Alticinae ; flea beetle ; plant defence ; genetics ; sex-linkage ; X- and Y-chromosome ; evolution
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract A polymorphism in host plant exploitation has been discovered in the flea beetle, Phyllotreta nemorum L. (Coleoptera: Chrysomelidae: Alticinae) where one resistant population is able to use Barbarea vulgaris R.Br. ssp. arcuata (Opiz.) Simkovics (Brassicaceae) as a host plant while a susceptible population is not. Crosses (F1, F2, and backcrosses) between the two flea beetle populations were made, and survival of the progeny on B. v. ssp. arcuata was measured. The ability of P. nemorum larvae to survive in this plant species depended on the presence of major, dominant genes (R-genes). The two most abundant R-genes in the resistant flea beetle population were X- and Y-linked, respectively. The use of B. v. ssp. arcuata as a natural host plant by the resistant population of P. nemorum seems to be an extension of the host plant range of the species. The role of sex-linked genes in the evolution of host range is discussed.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Entomologia experimentalis et applicata 82 (1997), S. 25-35 
    ISSN: 1570-7458
    Schlagwort(e): Barbarea vulgaris ; Cruciferae ; Phyllotreta nemorum ; Chrysomelidae ; Alticinae ; flea beetle ; plant defence ; resistance ; host plant ; variation ; evolution
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract Several sorts of variation in the interaction between the insect, Phyllotreta nemorum L. (Coleoptera:Chrysomelidae:Alticinae), and the plant, Barbarea vulgaris R.Br. (Brassicaceae), have been discovered: 1) genetic differences in the levels of defences in the plant, 2) genetic differences in the ability of insects to cope with the plant defences, 3) seasonal variation in levels of defences in the plant, and 4) differences between leaf types in levels of defences. Two plant accessions were suitable for larval development throughout the season while the remaining nine accessions were more or less unsuitable for larvae from the ‘susceptible’ T-population at least at certain times of the year. All accessions were suitable for the ‘resistant’ E-population throughout the year. There was a seasonal variation in levels of defences in some accessions which were unsuitable for the T-population during the summer period when beetles were present, but not during autumn and spring when the beetle were hibernating. Upper (younger) cauline leaves of these accessions had higher levels of defences than lower (older) cauline leaves. The resistant E-population used B. vulgaris as a natural host plant while the susceptible T-population did not. The use of B. vulgaris as a natural host plant by the E-population of P. nemorum seems to be an extension of the host plant range of the species. Variation in plant defences may have facilitated the switch in host plant use by the resistant flea beetle population.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    ISSN: 1573-0417
    Schlagwort(e): colonization ; evolution ; lakes ; Norway ; deglaciation ; land uplift ; invertebrates ; Chironomidae ; Porifera ; Bryozoa ; diatoms ; Charophyta ; tsunami
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Geologie und Paläontologie
    Notizen: Abstract Invertebrate colonization of lakes following the uplift of land from the sea was studied in four lakes, currently situated between 39 and 24 m a.s.l., on the central Norwegian coast. The lakes were isolated from the sea between 9500 and 7700 years B.P. Animal and algal remains picked from core samples showed that the first colonizers preserved as fossils were usually members of the Chironomidae, Daphnidae/Chydoridae, Acarina, Porifera (Ephydatia mülleri and Spongilla lacustris), Bryozoa (Cristatella mucedo and Plumatella spp.) and Charophyta (Chara sp.). Of the chironomids, the genus Chironomus was present in the oldest lacustrine layers of all four lakes, but other genera recorded at the marine/lacustrine boundary were Dicrotendipes, Procladius (?), Einfeldia, Microtendipes, and Glyptotendipes. Remains of the caddis fly family Limnephilidae were also present in the earliest lacustrine sediments in Kvennavatnet and Kvernavatnet. The oldest invertebrate fauna is typical for mesotrophic lakes. However, chironomids and mites have been present in this area from at least about 10 500 years B.P. A diverse chironomid community was established between 300 and 800 years after isolation from the sea at Kvernavatnet on the island of Hitra, while only between 80 and 120 years passed before a comparably diverse community developed at Kvennavatnet on the mainland coast. A similar development of the invertebrate fauna occurred in Kvennavatnet, Kvernavatnet and Storkuvatnet. However, Litjvatnet deviates greatly from the ‘normal’ pattern because a tsunami disturbed the bottom sediments and fauna. The tsunami, a gigantic sea wave, was caused by a submarine slide from the Norwegian continental slope. It reached Litjvatnet, today located 24 m a.s.l., but was not traced in Storkuvatnet at 30 m a.s.l. This event happened about 7200 years B.P.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Springer
    Antonie van Leeuwenhoek 71 (1997), S. 159-178 
    ISSN: 1572-9699
    Schlagwort(e): aromatic pathways ; chlorobenzenes ; evolution ; genes ; plasmids ; pseudomonas
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract Chlorobenzenes are substrates not easily metabolized by existing bacteria in the environment. Specific strains, however, have been isolated from polluted environments or in laboratory selection procedures that use chlorobenzenes as their sole carbon and energy source. Genetic analysis indicated that these bacteria have acquired a novel combination of previously existing genes. One of these gene clusters contains the genes for an aromatic ring dioxy-genase and a dihydrodiol dehydrogenase. The other contains the genes for a chlorocatechol oxidative pathway. Comparison of such gene clusters with those from other aromatics degrading bacteria reveals that this process of recombining or assembly of existing genetic material must have occurred in many of them. Similarities of gene functions between pathways suggest that incorporation of existing genetic material has been the most important mechanism of expanding a metabolic pathway. Only in a few cases a horizontal expansion, that is acqui sition of gene functions to accomodate a wider range of substrates which are then all transformed in one central pathway, is observed on the genetic level. Evidence is presented indicating that the assembly process may trigger a faster divergence of nearby gene sequences. Further ‘fine-tuning’, for example by developing a proper regulation, is then the next step in the adaptation.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Springer
    Antonie van Leeuwenhoek 71 (1997), S. 265-270 
    ISSN: 1572-9699
    Schlagwort(e): bacteria ; DNA ; evolution ; genome ; RNA
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract This review examines evolution of bacterial genomes with an emphasis on RNA based life, the transition to functional DNA and small evolving genomes (possibly plasmids) that led to larger, functional bacterial genomes.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Springer
    Antonie van Leeuwenhoek 71 (1997), S. 257-263 
    ISSN: 1572-9699
    Schlagwort(e): bacteria ; energy ; evolution ; genome ; metabolism
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract This article examines the relationship between (or dependence of) bacterial evolution in prokaryotes and metabolism, and the changing physical-chemical conditions present during early evolution.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Springer
    Antonie van Leeuwenhoek 71 (1997), S. 363-368 
    ISSN: 1572-9699
    Schlagwort(e): assembly ; anode ; bacteria ; cathode ; DNA ; evolution ; genetics ; molecular ; surfaces
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract Molecular evolution is examined in bacteria with an emphasis on mineral surfaces, membranes, cathodes and anodes. In early molecular evolution, cathode-anode system may have been naturally occurring on a nm to µm scale. Secondly, the cathode-anode system could have been separated by a primitive, permeable lipid or microsphere on a mineral surface, that was a precursor of a more advanced membrane with a charge differential on either side of the membrane. These aspects will be considered from a theoretical evolutionary perspective.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    Springer
    Antonie van Leeuwenhoek 72 (1997), S. 251-259 
    ISSN: 1572-9699
    Schlagwort(e): bacteria ; catalysis ; DNA ; enzyme ; evolution ; microorganisms ; optimization ; RNA ; time
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract Microbial populations (and life) not only evolve, they optimize. The transition from a random, unorganized, lifeless Earth to the present situation, where the Earth is virtually covered with nucleic acids and diverse and complex species, required numerous molecular changes and the integration of metabolic pathways over billions of years. Primitive prokaryotic life was dependent on and constrained by the physical-chemical conditions on the Earth, while slowly reshaping conditions present. In this review, molecular evolution and molecular optimization are examined with an emphasis on the order in which evolutionary events occurred.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 48 (1997), S. 989-996 
    ISSN: 1572-8943
    Schlagwort(e): sol-gel ; TG ; thermal decomposition ; Y-Ba-Cu superconductors
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A precursor of Y-Ba-Cu oxides was prepared by a modified alkoxide sol-gel method and its thermal decomposition in air was studied by on-line coupled TG-FTIR and High Resolution Thermogravimetric measurements. A continuous more or less stepwise weight loss was observed between room temperature and 600°C at which all organic compounds had evolved and were progressively oxidized as the temperature increased leaving only Y and Cu oxides and bariumcarbonate. Between 700 and 800°C a final weight loss was observed due to the decomposition of bariumcarbonate into oxide.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 48 (1997), S. 1051-1067 
    ISSN: 1572-8943
    Schlagwort(e): reaction mechanisms ; sol-gel ; superconductors ; thermoanalytical techniques
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The high temperature superconducting compound YBa2Cu3O72212;δ (Y-123) is synthesised by sol-gel process using various precursors viz., acetate, acetate-citrate, nitrate-citrate and acrylamide. The phase purity of the final product depends on the homogeneity of the gels which intern depends on the bonding of the metal ions in the gels. The samples prepared by acrylamide and nitrate-citrate gel routes yielded phase pure Y-123 compound with better superconducting properties. The mechanism of formation of Y-123 in all these four gel routes is established by characterising the gels and intermediate phases using TG, DTA and XRD techniques. Kinetic analysis is carried out on the mass loss data using the method proposed by Phadni's and Deshpande. Avrami-Erofeev nuclei growth in case of acrylamide, diffusion controlled process in nitrate-citrate and phase boundary reaction mechanisms in case of acetate-citrate gels are found to be responsible for the formation of Y-123 phase.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 11
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 50 (1997), S. 105-115 
    ISSN: 1572-8943
    Schlagwort(e): BiSCCO synthesis ; fluorine substitution ; sol-gel
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Sol-gel citrate technology was used to prepare BiSCCO 2223 and 2212 superconducting phases. Fluorine in the initial mixture was shown to enhance considerably formation of the 2223 phase. Fluorine substitution of up to three F atoms per Bi(Pb)SCCO 2223 formula was achieved by treatment of the sample in 80 Torr ClF3 atmosphere. A number of experimental methods have been used to characterize the samples and to trace the phase transformations in the sol-gel process: DTA/TG, XRD, atomic absorption, potentiometry with fluoride selective electrode, magnetic susceptibility measurements.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 12
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 10 (1997), S. 309-316 
    ISSN: 1573-4846
    Schlagwort(e): lactate dehydrogenase ; sol-gel ; biosensor ; lactic acid
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Physical adsorption and physical entrapment techniques have been utilized for the immobilization of lactate dehydrogenase (LDH) on tetraethylorthosilicate (TEOS) derived sol-gel films. The enzyme (LDH) activity has been assayed as a function of time, temperature, pH and pyruvate concentration. The results of photometric measurements used for monitoring the reaction yield a response time of about 1 min, linearity over a concentration range of 0–1.5 × 10-3 M and detection limit of 5 × 10-5 M. The TEOS sol-gel films containing LDH have been found to be stable for about 30 days at temperatures 4 to 10°C.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 13
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 77-81 
    ISSN: 1573-4846
    Schlagwort(e): iron oxide ; structural control ; complexing agent ; thin film ; sol-gel
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The structure of iron oxide was controlled by regulating the hydrolytic polymerization of aquo iron complexes with organic polydentate ligands such as diols. Iron oxides were prepared by calcining the precursor polymers obtained from iron nitrate nonahydrate and diols. When the diols were 1,2-pentanediol, 1,2-hexanediol and 1,2-octanediol, α -Fe2O3 with corundum structure appeared exclusively or as the main crystalline phase, in spite of the amount of diol used and the calcination temperature. In the case of 1,2-decanediol and 1,2-dodecanediol, when five moles of the diols were used to one mole of iron nitrate and the calcination temperatures were below 400° C, γ -Fe2O3 with spinel structure appeared as the main phase and, when less than five moles of the diols were used, α -Fe2O3 appeared exclusively or as the main phase, irrespective of the calcination temperature. This tendency was also observed in thin films. Thus, a transparent magnetic film composed of γ -Fe2O3 could be prepared by applying a benzene solution of the iron polymer, obtained with 5 equivalents of 1,2-decanediol, on quartz and calcining the gel film at 350° C.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 14
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 83-88 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; gelation modelling ; TiO2 gels ; simulation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract We present here an experimental and numerical study of the chemical and aggregative mechanisms for titanium alkoxide in a reverse micellar medium. NMR experiments were done to study the first step of the sol-gel process: hydrolysis of titanium isopropoxide. Light and X-ray scattering experiments were then conducted to characterize the clustering of aggregates and aggregation kinetics. Fractal dimension, measured by U.S.A.X.S., varies with the hydrolysis ratio and the hydration of the surfactant. This evolution was explained by polydispersity of the hydrolysis which depends on the surfactant concentration. This hypothesis was tested through a numerical simulation of irreversible aggregation using a chemically limited aggregation model. The hydrolyzed sites are distributed among the monomers by a random procedure governed by a polydispersity parameter p , varying from 0 to 1. The total number of hydrolyzed sites is governed by a parameter q belonging to the interval [0, 1]. The p -q evolution of the fractal dimension coincides rather well with the experimental data in all the region of the two dimensional phase space.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 15
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 107-110 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; zinc aluminate ; spinel structure ; catalyst support
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract ZnAl2O4 was prepared by hydrolyzing a mixture of aluminum alkoxide with zinc nitrate dissolved in hexylene glycol and calcining at 800°C. The results are compared with those obtained by wet mixing and coprecipitation. The sol-gel method produces solids whose surface areas and pore volumes are 100% larger and with a more homogeneous pore size distribution.
    Materialart: Digitale Medien
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  • 16
    ISSN: 1573-4846
    Schlagwort(e): mullite ; organic ligand ; hydrolytic polymerization ; sol-gel
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The preparation of mullite by the sol-gel method using organic polydentate ligands and the effect of the raw materials and organic polydentate ligands on the formation of mullite were investigated. Two series of samples were prepared using tetraethoxyorthosilicate (TEOS) and aluminum nitrate nonahydrate, or dibutoxyethylacetoacetatoaluminum (Al(OBu)2(AcAcEt)) as the silica and alumina sources, respectively, and using ethylene glycol (EG), 1,3-propanediol (PD), 1,3-butanediol (BD), 2-methyl-2, 4-pentanediol (MPD), diethlene glycol monoethyl ether (DEME) and ethoxyethanol as the ligands. When the alumina source was aluminum nitrate nonahydrate, mullite was apt to appear in the order of EG 〉 PD 〉 MPD. When Al(OBu)2(AcAcEt) was the alumina source, the tendency toward the appearance of mullite crystalline phase was EG 〉 BD 〉 DEME 〉 MPD. Between the two alumina sources, aluminum nitrate nonahydrate gave mullite much easier than Al(OBu)2(AcAcEt). These relationships were discussed from the viewpoints of the coordination ability of the ligands and the miscibility between the silica and alumina.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 17
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 9 (1997), S. 279-283 
    ISSN: 1573-4846
    Schlagwort(e): AgTCNQ ; photochromism ; sol-gel
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Preparation and photochromic behavior of ormosil containing encapsulated AgTCNQ molecules were studied in this paper. The ormosil resulted from hydrolysis and polycondensation of glycidoxypropyltrimethoxysilane, dimethyldimethoxysilane and methyltrimethoxysilane. The time to add AgNO3 water solution into the resultant sol was a key factor to synthesize AgTCNQ molecules inside ormosil matrix. AgTCNQ molecules encapsulated in the ormosil showed different photochromic behavior compared with pure AgTCNQ film: normal photochromic reaction can be realized, while reverse photochromic reaction can not. The “cage” model was used to explain this phenomenon.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 18
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 9 (1997), S. 239-249 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; alumina-gel ; multicomponent ; mullite ; phase transformation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The capacity of the sol-gel process of producing highly pure, homogeneous alumina-silica based materials had been demonstrated in the last few years. However, a full understanding on the mechanisms associated to sol formation and sol to gel transition has not yet been achieved and is required for the development of a new generation of nano-structurally tailored materials that will significantly enhance the technological importance of the sol-gel process. In this work, tetraethyl orthosilicate (TEOS) and aluminum isopropoxide were used to prepare materials within the entire silica-alumina system. Process parameters, such as gelation time, were correlated to variables of the initial stage of the process, such as pH, temperature of hydrolysis and water/alkoxide ratio. The obtained gels were dried at 105°C and subsequently heat treated at 500 and 1100°C for 3 hours. X-ray diffraction and infrared spectroscopy were used to characterize the materials and phase transformations. Structural information obtained from phase characterization and phase transformations was correlated to the effects of the process variables on sol formation and gelation, providing insights related to the mechanisms involved. The influence of temperature of aluminum isopropoxide hydrolysis on peptization and gelation of the mixtures was noted. The different behavior of mixtures hydrolyzed at low and high temperatures was suggested to be caused by different mechanisms of surface charge formation on the structurally different aluminum hydroxides. Monophasic and diphasic mullite xerogels were produced by changing temperature of aluminum isopropoxide hydrolysis, and led to formation of mullite and Al−Si spinel phases respectively, when treated at 1100°C.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 19
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 365-369 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; SiO2 ; TiO2 ; ultraviolet ; densification
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Structural changes in SiO2 and TiO2 gel films were investigated using ultraviolet (UV) and vacuum ultraviolet (VUV) irradiations. A significant compaction with dehydration of SiO2 gel films was induced by irradiation of photons in the range of 9–18 eV. The refractive index and the shrinkage of the irradiated SiO2 gel films were comparable to those obtained by sintering at 1000°C. Densification of TiO2 gel films was also observed with irradiation of 5–14 eV photons. However, effects of the irradiation on TiO2 gel were smaller that those on SiO2 gel. The structural changes in the gel films are attributed to electronic excitations which are induced by irradiation with photons having higher energies than the bandgap of the oxides. The photo-induced effects are presumed to depend on the optical properties and structure of the gels.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 20
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 9 (1997), S. 239-249 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; alumina-gel ; multicomponent ; mullite ; phase transformation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The capacity of the sol-gel process of producing highly pure, homogeneous alumina-silica based materials had been demonstrated in the last few years. However, a full understanding on the mechanisms associated to sol formation and sol to gel transition has not yet been achieved and is required for the development of a new generation of nano-structurally tailored materials that will significantly enhance the technological importance of the sol-gel process. In this work, tetraethyl orthosilicate (TEOS) and aluminum isopropoxide were used to prepare materials within the entire silica-alumina system. Process parameters, such as gelation time, were correlated to variables of the initial stage of the process, such as pH, temperature of hydrolysis and water/alkoxide ratio. The obtained gels were dried at 105°C and subsequently heat treated at 500 and 1100°C for 3 hours. X-ray diffraction and infrared spectroscopy were used to characterize the materials and phase transformations. Structural information obtained from phase characterization and phase transformations was correlated to the effects of the process variables on sol formation and gelation, providing insights related to the mechanisms involved. The influence of temperature of aluminum isopropoxide hydrolysis on peptization and gelation of the mixtures was noted. The different behavior of mixtures hydrolyzed at low and high temperatures was suggested to be caused by different mechanisms of surface charge formation on the structurally different aluminum hydroxides. Monophasic and diphasic mullite xerogels were produced by changing temperature of aluminum isopropoxide hydrolysis, and led to formation of mullite and Al-Si spinel phases respectively, when treated at 1100°C.
    Materialart: Digitale Medien
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  • 21
    ISSN: 1573-4927
    Schlagwort(e): glycophorins ; gorilla ; evolution ; gene family ; gene expression
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract Homologues of MN blood group antigens, encoded by members of the glycophorin A (GPA) gene family, are expressed in man, anthropoid apes, and some species of Old World monkeys. Previous studies had shown that a three-gene framework, most closely related to that in man, is present in the chimpanzee. Here we report the genomic structure, transcript map, and protein expression of the GYPA locus in gorillas. Compared to the corresponding human and chimpanzee homologues, gorilla GPA, GPB, and GPB/E genes each showed a high degree of sequence identity, with the same exon-intron organization. However, the expression of exons III, IV, or V encoding the extracellular or membrane domains of homologous glycophorins varied among the three species. Gorilla GPA and GPB/E genes were unique in that the former occurred in two allelic forms with or without the expression of exon III, whereas the latter contained one (ψ exon III) instead of two silenced exons (ψ exons III and IV). Differences from human but not chimpanzee GPA also included the presence of a hybrid M/N epitope and the absence of the sequon for N-glycosylation. Owing to the retention of a functional exon III, gorilla GPB was more similar to chimpanzee GPB than human GPB. A transspecies allele was identified in the gorilla that gave rise to the Henshaw (He)-like antigen similar to that found in man. These results provide further insight into the model for evolution of the GPA gene family, indicating that the mechanisms underlying inter- and intraspecific polymorphism of glycophorins could predate the divergence of gorillas as the consequence of gene duplication and diversification.
    Materialart: Digitale Medien
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  • 22
    Digitale Medien
    Digitale Medien
    Springer
    Journal of chemical ecology 23 (1997), S. 1527-1547 
    ISSN: 1573-1561
    Schlagwort(e): Secondary metabolites ; chemical defense ; evolution ; ascidians ; sponges
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract We used three chemical fractions (spanning a wide range of polarities) from the extracts of four marine invertebrates, the spongesCrambe crambe andHemimycale columella and the ascidiansCystodytes dellechiajei andPolysyncraton lacazei, to test inhibition of cell division, photosynthesis, and settlement. We used assay organisms from the same habitat, seeking to determine whether a species may display diverse, ecologically relevant bioac-tivities and, if so, whether the same types of compound may be responsible for such activities. Cell division was strongly inhibited by the spongeC. crambe. A dichloromethane fraction fromC. crambe prevented development of sea urchinParacentrotus lividus eggs at a concentration of 10 μg/ml, as did the butanolic fraction, but at higher concentrations (50 and 100 μg/ml). At 50 μg/ml, the aqueous fraction ofC. crambe allowed cell division but prevented eggs from developing beyond the gastrula stage. Similar results were recorded with the dichloromethane fraction ofP. lacazei and from the aqueous fraction ofH. columella. Photosynthesis was unaffected by any of the species at 50 μg/ml. Larval settlement was inhibited by one or another fraction from the four species surveyed at a concentration of 50 μg/ml, althoughC. crambe exhibited the greatest amount of activity. We therefore found that various fractions displayed the same type of bioactivity, while compounds from the same fraction were responsible for multiple activities, suggesting that secondary metabolites are multiple-purpose tools in nature, which is relevant to our understanding of species ecology and evolution. Moreover, results showed that the assessment of the role of chemical compounds is significantly influenced by the assay organism, fractionation procedure, concentration, and duration of experiments. All these factors should be carefully considered when testing ecological hypotheses of the roles of chemically-mediated bioactivities.
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  • 23
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 381-384 
    ISSN: 1573-4846
    Schlagwort(e): barium osumilite ; sol-gel ; alkoxide ; crystallisation ; microstructure
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The crystallisation sequence of stoichiometric barium osumilite prepared by partial-alkoxide (PAR) and all-alkoxide routes (AAR) and the microstructure of the fully crystallised glass ceramic were examined. Comparing the crystallisation behaviours of the gel-glasses obtained revealed that the first phase to crystallise was mullite in PAR but hexacelsian in AAR. Barium osumilite crystals grew randomly and more homogeneously in PAR while in AAR larger barium osumilite crystals grew in clusters. Cordierite formed as a secondary phase in both routes and it crystallised on and between the osumilite lamellae. Mullite and hexacelsian also persisted up to the stage when full crystallisation had taken place.
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  • 24
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 409-413 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; thin films ; crystallization ; anatase ; rutile
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The aim of this work was to investigate the crystallization behavior of thin films of SiO2-TiO2 made by the sol-gel process as function of the TiO2 content and the temperature and time of heat treatment. Precursor solutions were prepared by hydrolysis of TEOS (tetraethoxysilane) and TPOT (titanium tetraisopropoxide). Multilayer films were spun on single crystal silicon wafers. The compositions studied were (on a molar percentage basis) 20TiO2-80SiO2, 30TiO2-70SiO2, 40TiO2-60SiO2 and pure TiO2. The films were heat treated at different temperatures between 300°C and 1200°C, for different periods of time (30 s–90 h). The crystallization kinetics were followed by micro-Raman spectrometry. Grazing incidence X-ray diffraction showed that the films crystallized into one or both of two crystalline phases of TiO2: anatase and rutile (for pure TiO2 only). The volume fractions of the crystalline phase varied from very low values (〈1%), up to 100%, for a TiO2 sample heat treated at 800°C for 8 hours. The results show that the volume fraction of crystalline phase is strongly influenced by the heat treatment temperature and also, to a smaller extent, by the heat treatment time. The most important parameter, however, is the composition of the films: the higher their TiO2 concentration, the lower is the crystallization temperature and the larger is the crystallized fraction.
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  • 25
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 425-430 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; thin films ; lead titanate ; microstructure
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A sol-gel route is developed for the synthesis of samarium modified lead titanate precursor solutions. The solutions are used for the deposition of thin films. After thermal treatment of the films, two crystalline phases are observed by X-ray diffraction analysis: an undesirable pyrochlore phase and a ferroelectric perovskite. These two phases are clearly distinguished in the film microstructure, showing a fined grained fraction of pyrochlore and a-axis oriented rosette grains of perovskite. The development of these phases as well as the evolution of the perovskite/pyrochlore ratio in the films is related to the chemistry of the synthesized solutions and the thermal treatment used for crystallization.
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  • 26
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 603-607 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; silsesquioxanes ; hybrid organic-inorganic materials ; silicas ; pore structure ; Si–C bond cleavage ; alkynyl silanes
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Hybrid organic-inorganic materials containing labile organic fragments with various structural features have been prepared. The mild cleavage of Si–C bonds allowed removal of the organic moities. It led to silica which pore structure varied according to the nature of the organic component eliminated.
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  • 27
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 615-618 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; magnetic nanocomposite ; iron oxide ; Mössbauer spectroscopy ; Kerr effect
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Magnetic nanocomposites γ-Fe2O3/silica were prepared by a one-step sol-gel method. The sol was prepared by TEOS (tetraethyl orthosilicate) acid hydrolysis in the presence of an iron salt soluble in methanol. After gelation and drying, the transparent samples were characterized after treatment at different temperatures. The particle size, observed by HR TEM, was in the range of 2–10 nm and depended on Fe-concentration and heating temperature. Magnetic measurements showed either a ferromagnetic or a superparamagnetic behaviour and could be explained by the particle size. The dependence of the magnetic behaviour on the particle size was also studied by Mössbauer spectroscopy. The samples in which the Fe2O3 particle size was approximately 10 nm showed magnetic splitting (sextet) at room temperature, while smaller particles (2–3 nm) showed this splitting only at the temperature of liquid helium. The optomagnetic properties of the samples were also measured (Kerr effect).
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  • 28
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 663-666 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; immunoassays ; antigen ; antibody
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Porous silica gels, synthesized via the acid hydrolysis and basic condensation of TMOS, have been used for the encapsulation of antigens. The pores of the matrix are large enough to allow the diffusion of antibodies through the gel. Antigen-antibody specific fixation occurs within the sol-gel matrix. It can be detected via the so-called enzyme linked immunosorbent assays (ELISA). Antigen-antibody associations occurring in the gel are optically detected via the reaction of a peroxidase conjugate with ortho-phenylenediamine leading to the formation of a yellow coloration. Immunoassays have been performed using the hydatid cyst fluid as the source of antigens and sera from human patients as the source of antibodies. Specific fixation appears to be as good in the sol-gel matrix as in antigen solutions.
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  • 29
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 681-684 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; acetates ; Bi-based superconductors
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Metal acetates represent suitable precursors in the sol-gel method. Generally, acetates are used in multicomponent systems with alkoxides or other carboxylic salts. However, Bi-Sr-Ca-Cu-O superconductors have been obtained by the sol-gel method starting only from acetate mixture. This work was intended to study the gelling process of acetates involved in the formation of bismuth-based superconducting phases, both individually and in the bi- and multicomponent systems. Probably, copper acetate is mainly responsible for the gel formation in these systems. The gelling process was monitored by measuring the pH, density and viscosity changes. The gels obtained were characterized by UV-VIS and IR spectra, DTA/TGA and powder X-ray diffraction.
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  • 30
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 721-723 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; lead titanate ; ferroelectric ; electroactive material ; composites
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Powders of (Pb0.8Ca0.2)(Ti0.99Mn0.01)O3 have been prepared by sol-gel processing. A tetragonal phase is formed after heat treatment at as low as 800°C. The tetragonality was found to be 1.053 ± 0.005 and Curie temperature 315°C. Composite films with 0–3 connectivity were prepared from 800°C heat treated powders and P(VDF-TrFE) by the solvent casting technique. Composites poled at 20 MV/m, exhibited a pyroelectric coefficient of 17.4 μC/m2K and a pyroelectric figure of merit (FOMp = p/ɛ) of 0.51 μ C/m2K.
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  • 31
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 729-734 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; thin films ; titanate perovskites
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A description is made of a wet chemical method for obtaining ferroelectric thin films. The processing is based on a twofold synthetic scheme: the synthesis of a titanate gel from a sol-gel process and the rehydration of this gel during the incorporation into the system of other ions as water-soluble salts. The versatility of this route has made possible preparation of modified lead titanate precursor solutions. Alkaline earth ions or lanthanides such as Ca2+ or Sm3+, have been used as modifier elements. Physico-chemical properties of the solutions are studied as well as the reaction mechanisms that make possible the rehydration of the titanate gel. The solutions obtained are used for the deposition and crystallization of titanate based thin films. Crystallinity, microstructure and polarization-electrid field characteristics of the films are shown.
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  • 32
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 735-742 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; Nb2O5 ; film ; photoconductivity ; photoelectrochemistry ; semiconductor ; solar cell
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Structural, optical, electro and photoelectrochemical properties of amorphous and crystalline sol-gel Nb2O5 coatings have been determined. The coatings are n-type semiconductor with indirect allowed transition and present an overall low quantum efficiency (φ 〈 4%) for UV light to electric conversion. The photoconducting behavior of the coatings is discussed within the framework of the Gärtner and Södergren models. Improvement can be foreseen if Nb2O5 coatings can be made of 10–20 nm size nanoparticles.
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  • 33
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 759-763 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; bismuth titanate ; spin-coating ; thin films ; ferroelectric
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Bi4Ti3O12 thin films were obtained by the sol-gel method. The precursor solution was prepared by allowing the two metallic alkoxides, Bi(OC2H4OCH3)3 and Ti(OC2H4OCH3)4, to react in 2-methoxy-ethanol to form the mixed alkoxide. This stable sol was deposited by spin-coating onto platinized silicon substrates. X-Ray diffraction patterns indicate that the perovskite initial crystallization temperature is 460°C for powder samples and it ranges between 400 and 500°C, for thin films, as a function of the number of coating layers. Dense, smooth and crack free thin films with grain sizes ranging from 20 nm to 500 nm are obtained, depending on the number of coating layers and on the post-deposition temperature annealing.
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  • 34
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 819-824 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; diffusion limited cluster-cluster aggregation ; theory of gelation ; fluctuating bond aggregation ; numerical simulations ; aggregation ; chemical gels formation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The diffusion limited cluster-cluster aggregation (DLCA) model is modified by including cluster deformations during aggregation, with a tuning flexibility parameter F. A three-dimensional computer simulation is presented, which starts from a collection of f-functional monomers randomly distributed in a cubic box with a volumic fraction c (concentration) and which uses the highly efficient bond fluctuation algorithm to describe the cluster deformations. It is shown that, for F ≠ 0, there exists a well defined threshold value of the volumic fraction below which the realization of all intra-aggregate bonding possibilities prevents the formation of a gelling network. For c 〉 c g , a true sol-gel transition occurs at a characteristic time t g , after which an infinite cluster (which is self connected via the boundary conditions) appears. In contrast to DLCA, t g does not increase as the box size increases. The transition at c g is characterized by a divergence of the final clusters size for c〈c g and a divergence of the gel time for c〉c g . Several other numerical results are reported.
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  • 35
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 895-899 
    ISSN: 1573-4846
    Schlagwort(e): luminescence ; pyranine ; sol-gel ; hybrid coatings ; emission anisotropy
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The sensitivity of the pyranine fluorescence to protonation/deprotonation is used to follow modifications in cured sol-gel thin films. The acid concentration in the sol-gel solution is varied for TEOS-based coatings and a series of organically modified silanes Si(OR)3R′ are added to the TEOS solution. The concentration of the organically modified silane is varied as well as the chain length of the alkylgroup (R′). The stationary fluorescence measurements show that the equilibrium between the protonated and the deprotonated form of pyranine changes depending on the type of silica matrix. The deprotonated form is dominant in the cured SiO2 films and the protonation/deprotonation ratio of pyranine is constant for the different acid concentrations used. The protonated form becomes dominant as the concentration of Si(OR)3R′ is increased and as the alkyl chain length (R′) of the organically modified silanes is augmented. Emission anisotropy measurements of pyranine in the same coatings show that the rotational freedom of the molecule changes due to modifications in the cages for the TEOS-based coatings. These modifications are produced by the acid concentration used to prepare the coatings. An increase in the rotational freedom of pyranine is observed in the TEOS-Si(OR)3R′ systems.
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  • 36
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 927-929 
    ISSN: 1573-4846
    Schlagwort(e): organic-inorganic hybrids ; sol-gel ; photochromic performance ; spirooxazine
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Organic-inorganic hybrid materials synthesized via sol-gel processing are excellent solid matrices for photochromic dyes like spirooxazine, and the photochromic performance can be further enhanced by introducing suitable additives. This work describes the effects of additives on the photochromic intensity (Δ A 0), decolouration rate (k) and photostability of spirooxazine in sol-gel derived organic-inorganic hybrid matrices. They include fluoro-alkylsilane (FAS), bisphenol A (BPA) and methyl-imidazole (MI). FAS enhances both Δ A 0 and photostability, but has little effect on k. The higher the content of BPA, the higher the Δ A 0 and the higher the photostability, but the lower the k. The effect of MI on Δ A 0 and k is not so considerable as that of BPA and is a little complicated, while significant improvement in photostability is achieved by the addition of MI at an optimum concentration with the presence of BPA at a higher content.
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  • 37
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 931-935 
    ISSN: 1573-4846
    Schlagwort(e): photochromic ; fiber optic ; sol-gel
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Photochromic-doped sol-gel materials have been prepared by adding a spiropyran photochromic dye to a solution of ethoxy silane monomers containing non-reacting ethyl radicals. After polymerization, normal photochromism (i.e., colored material upon UV irradiation) is obtained in the resulting matrix. The sol-gel matrix hinders the organic molecule rotations, thus giving two stable states, which can be reversibly switched by UV and green-blue irradiation respectively. If these materials are attached to optical fibers, the properties of the light throughput may be modified. Simple fiber-optic/photochromic devices made of two optical fibers placed in a V-groove removable connector have been prepared. Once cured, these devices behave as optically addressed variable delay generators. The same devices can be used for preparing simple optical switches and routing systems.
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  • 38
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 979-983 
    ISSN: 1573-4846
    Schlagwort(e): fluorescence ; pH ; ruthenium polypyridyl ; sol-gel
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Tetraethoxysilane (TEOS) sol-gel monoliths impregnated with three different luminescent [Ru(L)3]2+ complexes (where L = 2,2′-bipyridine (bpy), 1,10-phenanthroline (phen), or 4,7-diphenyl,1,10-phenanthroline (dpp)) have been prepared. The photoluminescence properties of these complexes were followed as a function of time, as the sol-gel reactions proceeded. Clear differences were observed in the emission energies and the emission lifetimes of the complexes upon gel formation. These differences can be explained by the different extent of electrostatic interaction between the surface of the siloxane polymer and the immobilised complex.
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  • 39
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 991-997 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; optical waveguides ; semiconductor-doped glass ; nonlinear optics ; laser writing
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Sol-gel processes show many promises for the development of low-loss, high-performance glass integrated optical circuits. Special attention is being paid to the preparation of composite glass films, where the properties of organic or inorganic dopant compounds included in the glass matrix are fully exploited. Nonlinear optical glass film waveguides have the potential to become key devices in the future, leading to further technical advances of fiber optic communication systems. This paper briefly reviews current activities in sol-gel glasses for integrated optics, with particular focus on silica-titania and semiconductor-doped films.
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  • 40
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 999-1005 
    ISSN: 1573-4846
    Schlagwort(e): ZrO2 ; sol-gel ; planar waveguide ; Raman scattering
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract ZrO2 waveguides are prepared by the sol-gel process from a solution containing zirconium n-propoxide and acetylacetone in propanol-2. Structural characterizations are investigated for different annealing temperatures using suitable techniques including Waveguide Raman Spectroscopy, Electron Microscopy and Atomic Force Microscopy. Films are amorphous at 300°C and the pure ZrO2 tetragonal crystalline phase appears beyond 400°C. Crystallized films present a dense, uniform and polycrystalline structure made up by randomly oriented nanocrystallites, the diameter of which increases from 38 Å at 400°C to 53 Å at 600°C. Waveguides are at least monomode TE0 at 632.8 nm. At this wavelength, optical losses are about 0.8 ± 0.2 dB/cm for amorphous layers and increase up to 2.5 ± 0.4 dB/cm for 600°C heat-treated waveguides.
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  • 41
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 1013-1016 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; neodymium and erbium doped planar waveguide ; fluorescence lifetime measurement ; phosphorous and aluminium codoping
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A multilayer sol-gel process has been developed in order to make highly doped rare-earth planar waveguides on silica or silicon substrates. Starting with a small range of constituents, such as SiO2, TiO2, P2O5 and Al2O3, we show that a large variety of gel compositions, with different spectroscopic behaviour, can be made when doped with rare-earths. We have doped the sol-gel films with neodymium and we have optimized their compositions by measuring the neodymium fluorescence lifetime. For a composition with 10 atom% of phosphorous, the lifetime evolution with neodymium concentration was studied and a quenching concentration was found at 1% of neodymium. We have also shown the strong influence of phosphorous or aluminium in the sol composition on the fluorescence lifetime, for a given neodymium concentration. First results on similar planar waveguides, doped with erbium, are also presented. The stability of the fluorescence lifetime over a long period of time is an other important point to be checked for these new materials: the lifetime evolution over a 9 months measurement period is presented.
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  • 42
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 1053-1061 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; optical chemical sensor ; waveguide sensor ; fibre optic sensor
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The use of the sol-gel process to produce materials for optical chemical sensors and biosensors is attracting considerable interest. This interest derives mainly from the design flexibility of the sol-gel process and the ease of fabrication. In most applications the sol-gel material is used to provide a microporous support matrix in which analyte-sensitive species are entrapped and into which smaller analyte molecules may diffuse. Sensors based on entrapped organic and inorganic dyes, enzymes and other biomolecules have been reported. A range of sensor configurations has been employed, including monoliths, thin films, as well as more elaborate structures. In this paper a selection is presented of recent significant developments in optical chemical sensors which employ sol-gel-derived materials. These developments include the tailoring of sol-gel materials to optimise sensor response, advanced waveguide structures and novel probe-tip sensors. Those issues which remain critical to the eventual deployment of sol-gel sensors are examined. In particular, the problems of leaching, microstructural stability, diffusion-limited response time, and susceptibility to interferents are discussed and some solutions proposed.
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  • 43
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 1063-1066 
    ISSN: 1573-4846
    Schlagwort(e): GDLC ; color display ; liquid crystal ; sol-gel
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Liquid crystal microdroplets trapped into silica gel-glasses by sol-gel processes may be used for display applications. Gel-glass dispersed liquid crystals (GDLC) are switched between opaque and transparent states by applying external AC-voltage signals; no polarizers are required. The feasibility of applying these materials to colored displays has been explored. A comparative study of different dyes for GDLC color displays, which were either embedded in the sol-gel matrix or dissolved in the liquid crystal microdroplets is presented.
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  • 44
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 1067-1070 
    ISSN: 1573-4846
    Schlagwort(e): cholinesterase ; sol-gel ; pesticide ; THA ; enzyme activity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Biological activity of cholinesterases can be determined by optically monitoring the enzymatic reaction with indophenyl acetate, (N-4′-acetoxyphenyl)-4-quinone imine. At pH 8.0 cholinesterases hydrolyze this yellow dye to yield a blue reaction product. Cholinesterase inhibitors reduce the rate of this hydrolysis. Thus, by monitoring absorbance of the hydrolysis product at its maximum (630 nm) as a function of time, reaction rates of both cholinesterase activity and cholinesterase inhibition may be quantified spectroscopically. Using this technique, we measured the enzymatic activity of butyrylcholinesterase (BuChE) molecules encapsulated in tetramethyl orthosilicate (TMOS) silicate gel-glass prepared by hydrolysis and condensation. This activity is reduced, in a concentration-dependent manner, by the reversible cholinesterase inhibitors 1,5-bis(4-allyldimethyl-ammoniumphenyl) pentan- 3-one dibromide (BADAPP) and 9-amino-1,2,3,4-tetrahydroacridine (THA; tacrine, Cognex). The gel-glasses are rigid and compact, transparent, and porous enough to allow reagents to diffuse in and out.
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  • 45
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 1121-1125 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; thin films ; oxygen sensor
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Sol-gel-derived silica films were fabricated by dip-coating onto planar and optical fibre substrates. The films were pre-doped with the oxygen-sensitive ruthenium complex [Ru(II)-tris(4,7-diphenyl-1,10-phenanthroline)], whose fluorescence is quenched in the presence of oxygen. The structure and behaviour of sol-gel films is related to the fabrication parameters. In order to optimise the films for oxygen sensing in gaseous and in aqueous media, the quenching behaviour was monitored as a function of dip-speed and water : precursor ratio. By adjusting the above parameters, film properties can be tailored to optimise oxygen quenching in particular concentration ranges and environments.
    Materialart: Digitale Medien
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  • 46
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 29-33 
    ISSN: 1573-4846
    Schlagwort(e): ceramic fibers ; spinnability ; sol-gel
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Structural ceramic oxide fibers like α-Al2O3, MgAl2O4 (spinel), Y3Al5O12 (YAG) and eutectic Al2O3−Y3Al5O12 as well as the functional Pb(Zr1−xTix)O3 (PZT) fibers were successfully prepared by sol-gel processing. All precursors are based on metal oxohydroxopropionates. A comparative study of sol-gel routes leading to spinnable sols demonstrates the key role of propionic acid as an excellent agent for controlling hydrolysis and condensation reactions.
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  • 47
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 77-81 
    ISSN: 1573-4846
    Schlagwort(e): iron oxide ; structural control ; complexing agent ; thin film ; sol-gel
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The structure of iron oxide was controlled by regulating the hydrolytic polymerization of aquo iron complexes with organic polydentate ligands such as diols. Iron oxides were prepared by calcining the precursor polymers obtained from iron nitrate nonahydrate and diols. When the diols were 1,2-pentanediol, 1,2-hexanediol and 1,2-octanediol, α-Fe2O3 with corundum structure appeared exclusively or as the main crystalline phase, in spite of the amount of diol used and the calcination temperature. In the case of 1,2-decanediol and 1,2-dodecanediol, when five moles of the diols were used to one mole of iron nitrate and the calcination temperatures were below 400°C, ψ-Fe2O3 with spinel structure appeared as the main phase and, when less than five moles of the diols were used, α-Fe2O3 appeared exclusively or as the main phase, irrespective of the calcination temperature. This tendency was also observed in thin films. Thus, a transparent magnetic film composed of γ-Fe2O3 could be prepared by applying a benzene solution of the iron polymer, obtained with 5 equivalents of 1,2-decanediol, on quartz and calcining the gel film at 350°C.
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  • 48
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 83-88 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; gelation modelling ; TiO2 gels ; simulation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract We present here an experimental and numerical study of the chemical and aggregative mechanisms for titanium alkoxide in a reverse micellar medium. NMR experiments were done to study the first step of the sol-gel process: hydrolysis of titanium isopropoxide. Light and X-ray scattering experiments were then conducted to characterize the clustering of aggregates and aggregation kinetics. Fractal dimension, measured by U.S.A.X.S., varies with the hydrolysis ratio and the hydration of the surfactant. This evolution was explained by polydispersity of the hydrolysis which depends on the surfactant concentration. This hypothesis was tested through a numerical simulation of irreversible aggregation using a chemically limited aggregation model. The hydrolyzed sites are distributed among the monomers by a random procedure governed by a polydispersity parameterp, varying from 0 to 1. The total number of hydrolyzed sites is governed by a parameterq belonging to the interval [0, 1]. Thep-q evolution of the fractal dimension coincides rather well with the experimental data in all the region of the two dimensional phase space.
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  • 49
    ISSN: 1573-4846
    Schlagwort(e): mullite ; organic ligand ; hydrolytic polymerization ; sol-gel
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The preparation of mullite by the sol-gel method using organic polydentate ligands and the effect of the raw materials and organic polydentate ligands on the formation of mullite were investigated. Two series of samples were prepared using tetraethoxyorthosilicate (TEOS) and aluminum nitrate nonahydrate, or dibutoxyethylacetoacetatoaluminum (Al(OBu)2(AcAcEt)) as the silica and alumina sources, respectively, and using ethylene glycol (EG), 1,3-propanediol (PD), 1,3-butanediol (BD), 2-methyl-2, 4-pentanediol (MPD), diethlene glycol monoethyl ether (DEME) and ethoxyethanol as the ligands. When the alumina source was aluminum nitrate nonahydrate, mullite was apt to appear in the order of EG〉PD〉MPD. When Al(OBu)2(AcAcEt) was the alumina source, the tendency toward the appearance of mullite crystalline phase was EG〉BD〉DEME〉MPD. Between the two alumina sources, aluminum nitrate nonahydrate gave mullite much easier than Al(OBu)2(AcAcEt). These relationships were discussed from the viewpoints of the coordination ability of the ligands and the miscibility between the silica and alumina.
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  • 50
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 365-369 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; SiO2 ; TiO2 ; ultraviolet ; densification
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Structural changes in SiO2 and TiO2 gel films were investigated using ultraviolet (UV) and vacuum ultraviolet (VUV) irradiations. A significant compaction with dehydration of SiO2 gel films was induced by irradiation of photons in the range of 9–18 eV. The refractive index and the shrinkage of the irradiated SiO2 gel films were comparable to those obtained by sintering at 1000°C. Densification of TiO2 gel films was also observed with irradiation of 5–14 eV photons. However, effects of the irradiation on TiO2 gel were smaller than those on SiO2 gel. The structural changes in the gel films are attributed to electronic excitations which are induced by irradiation with photons having higher energies than the bandgap of the oxides. The photo-induced effects are presumed to depend on the optical properties and structure of the gels.
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  • 51
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 381-384 
    ISSN: 1573-4846
    Schlagwort(e): barium osumilite ; sol-gel ; alkoxide ; crystallisation ; microstructure
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The crystallisation sequence of stoichiometric barium osumilite prepared by partial-alkoxide (PAR) and all-alkoxide routes (AAR) and the microstructure of the fully crystallised glass ceramic were examined. Comparing the crystallisation behaviours of the gel-glasses obtained revealed that the first phase to crystallise was mullite in PAR but hexacelsian in AAR. Barium osumilite crystals grew randomly and more homogeneously in PAR while in AAR larger barium osumilite crystals grew in clusters. Cordierite formed as a secondary phase in both routes and it crystallised on and between the osumilite lamellae. Mullite and hexacelsian also persisted up to the stage when full crystallisation and taken place.
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  • 52
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 409-413 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; thin films ; crystallization ; anatase ; rutile
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The aim of this work was to investigate the crystallization behavior of thin films of SiO2−TiO2 made by the sol-gel process as function of the TiO2 content and the temperature and time of heat treatment. Precursor solutions were prepared by hydrolysis of TEOS (tetraethoxysilane) and TPOT (titaniums tetraisopropoxide). Multilayer films were spun on single crystal silicon wafers. The compositions studied were (on a molar percentage basis) 20TiO2−80SiO2, 30TiO2−70SiO2, 40TiO2−60SiO2 and pure TiO2. The films were heat treated at different temperatures between 300°C and 1200°C, for different periods of time (30 s-90 h). The crystallization kinetics were followed by micro-Raman spectrometry. Grazing incidence X-ray diffraction showed that the films crystallized into one or both of two crystalline phase of TiO2: anatase and rutile (for pure TiO2 only). The volume fractions of the crystalline phase varied from very low values (〈1%), up to 100%, for a TiO2 sample heat treated at 800°C for 8 hours. The results show that the volume fraction of crystalline phase is strongly influenced by the heat treatment temperature and also, to a smaller extent, by the heat treatment time. The most important parameter, however, is the composition of the films: the higher their TiO2 concentration, the lower is the crystallization temperature and the larger is the crystallized fraction.
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  • 53
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 23-28 
    ISSN: 1573-4846
    Schlagwort(e): hydrolysis pathway ; Ni-Sb-ethoxides ; sol-gel
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The hydrolysis-condensation pathways of Ni-Sb-ethoxides in different toluene-ethanol solvents have been studied. The hydrolysis was performed by slow addition of controlled amounts of water, diluted in toluene-ethanol solvents. Characterization of the hydrolysis products was performed with single crystal X-ray determinations, IR-spectroscopy, UV-Vis spectroscopy and TGA. In this way, a number of different Ni-Sb-(oxo)-ethoxides have been isolated and characterized. It was thereby shown that the Ni:Sb ratio of the hetero bimetallic oxo-alkoxides varied much depending on the degree of hydrolysis and that the species formed vary with the solvent used and the speed at which the water is added.
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  • 54
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 29-33 
    ISSN: 1573-4846
    Schlagwort(e): ceramic fibers ; spinnability ; sol-gel
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Structural ceramic oxide fibers like α-Al2O3, MgAl2O4 (spinel), Y3Al5O12 (YAG) and eutectic Al2O3-Y3Al5O12 as well as the functional Pb(Zr1−xTix)O3 (PZT) fibers were successfully prepared by sol-gel processing. All precursors are based on metal oxohydroxopropionates. A comparative study of sol-gel routes leading to spinnable sols demonstrates the key role of propionic acid as an excellent agent for controlling hydrolysis and condensation reactions.
    Materialart: Digitale Medien
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  • 55
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 603-607 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; silsesquioxanes ; hybrid organic-inorganic materials ; silicas ; pore structure ; Si−C bond cleavage ; alkynyl silanes
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Hybrid organic-inorganic materials containing labile organic fragments with various structural features have been prepared. The mild cleavage of Si−C bonds allowed removal of the organic moities. It led to silica which pore structure varied according to the nature of the organic component eliminated.
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  • 56
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 615-618 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; magnetic nanocomposite ; iron oxide ; Mössbauer spectroscopy ; Kerr effect
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Magnetic nanocomposites γ-Fe2O3/silica were prepared by a one-step sol-gel method. The sol was prepared by TEOS (tetraethyl orthosilicate) acid hydrolysis in the presence of an iron salt soluble in methanol. After gelation and drying, the transparent samples were characterized after treatment at different temperatures. The particle size, observed by HR TEM, was in the range of 2–10 nm and depended on Fe-concentration and heating temperature. Magnetic measurements showed either a ferromagnetic or a superparamagnetic behaviour and could be explained by the particle size. The dependence of the magnetic behaviour on the particle size was also studied by Mössbauer spectroscopy. The samples in which the Fe2O3 particle size was approximately 10 nm showed magnetic splitting (sextet) at room temperature, while smaller particles (2–3 nm) showed this splitting only at the temperature of liquid helium. The optomagnetic properties of the samples were also measured (Kerr effect).
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  • 57
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 663-666 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; immunoassays ; antigen ; antibody
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Porous silica gels, synthesized via the acid hydrolysis and basic condensation of TMOS, have been used for the encapsulation of antigens. The pores of the matrix are large enough to allow the diffusion of antibodies through the gel. Antigen-antibody specific fixation occurs within the sol-gel matrix. It can be detected via the so-called enzyme linked immunosorbent assays (ELISA). Antigen-antibody associations occurring in the gel are optically detected via the reaction of a peroxidase conjugate with ortho-phenylenediamine leading to the formation of a yellow coloration. Immunoassays have been performed using the hydatid cyst fluid as the source of antigens and sera from human patients as the source of antibodies. Specific fixation appears to be as good in the sol-gel matrix as in antigen solutions.
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  • 58
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 681-684 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; acetates ; Bi-based superconductors
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Metal acetates represent suitable precursors in the sol-gel method. Generally, acetates are used in multicomponent systems with alkoxides or other carboxylic salts. However, Bi−Sr−Ca−Cu−O superconductors have been obtained by the sol-gel method starting only from acetate mixture. This work was intended to study the gelling process of acetates involved in the formation of bismuth-based superconducting phases, both individually and in the bi-and multicomponent systems. Probably, copper acetate is mainly responsible for the gel formation in these systems. The gelling process was monitored by measuring the pH, density and viscosity changes. The gels obtained were characterized by UV-VIS and IR spectra, DTA/TGA and powder X-ray diffraction.
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  • 59
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 721-723 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; lead titanate ; ferroelectric ; electroactive material ; composites
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Powders of (Pb0.8Ca0.2)(Ti0.99Mn0.01)O3 have been prepared by sol-gel processing. A tetragonal phase is formed after heat treatment at as low as 800°C. The tetragonality was found to be 1.053±0.005 and Curie temperature 315°C. Composite films with 0–3 connectivity were prepared from 800°C heat treated powders and P(VDF-TrFE) by the solvent casting technique. Composites poled at 20 MV/m, exhibited a pyroelectric coefficient of 17.4 μC/m2K and a pyroelectric figure of merit (FOMp=p/ε) of 0.51 μC/m2K.
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  • 60
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 729-734 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; thin films ; titanate perovskites
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A description is made of a wet chemical method for obtaining ferroelectric thin films. The processing is based on a twofold synthetic scheme: the synthesis of a titanate gel from a sol-gel process and the rehydration of this gel during the incorporation into the system of other ions as water-soluble salts. The versability of this route has made possible preparation of modified elements. Physico-chemical properties of the solutions are studied as well as the reaction mechanisms that make possible the rehydration of the titanate gel. The solutions obtained are used for the deposition and crystallization of titanate based thin films. Crystallinity, microstructure and polarization-electrid field characteristics of the films are shown.
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  • 61
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 735-742 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; Nb2O5 ; film ; photoconductivity ; photoelectrochemistry ; semiconductor ; solar cell
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Structural, optical, electro and photoelectrochemical properties of amorphous and crystalline sol-gel Nb2O5 coatings have been determined. The coatings aren-type semiconductor with indirect allowed transition and present an overall low quantum efficiency (ϕ〈4%) for UV light to electric conversion. The photoconducting behavior of the coatings is discussed within the framework of the Gärtner and Södergren models. Improvement can be foreseen if Nb2O5 coatings can be made of 10–20 nm size nanoparticles.
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  • 62
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 759-763 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; bismuth titanate ; spin-coating ; thin films ; ferroelectric
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Bi4Ti3O12 thin films were obtained by the sol-gel method. The precursor solution was prepared by allowing the two metallic alkoxides, Bi(OC2H4OCH3)3 and Ti(OC2H4OCH3)4, to react in 2-methoxy-ethanol to form the mixed alkoxide. This stable sol was deposited by spin-coating onto platinized silicon substrates. X-Ray diffraction patterns indicate that the perovskite initial crystallization temperature is 460°C for powder samples and it ranges between 400 and 500°C, for thin films, as a function of the number of coating layers. Dense, smooth and crack free thin films with grain sizes ranging from 20 nm to 500 nm are obtained, depending on the number of coating layers and on the post-deposition temperature annealing.
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  • 63
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 819-824 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; diffusion limited cluster-cluster aggregation ; theory of gelation ; fluctuating bond aggregation ; numerical simulations ; aggregation ; chemical gels formation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The diffusion limited cluster-cluster aggregation (DLCA) model is modified by including cluster deformations during aggregation, with a tuningflexibility parameterF. A three-dimensional computer simulation is presented, which starts from a collection off-functional monomers randomly distributed in a cubic box with a volumic fractionc (concentration) and which uses the highly efficientbond fluctuation algorithm to describe the cluster deformations. It is shown that, forF≠0, there exists a well defined threshold value of the volumic fraction below which the realization of all intra-aggregate bonding possibilities prevents the formation of a gelling network. Forc〉c g , atrue sol-gel transition occurs at a characteristic timet g , after which an infinite cluster (which is self connected via the boundary conditions) appears. In contrast to DLCA,t g does not increase as the box size increases. The transition atc g is characterized by a divergence of the final clusters size forc〈c g and a divergence of the gel time forc〉c g . Several other numerical results are reported.
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  • 64
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 895-899 
    ISSN: 1573-4846
    Schlagwort(e): luminescence ; pyranine ; sol-gel ; hybrid coatings ; emission anisotropy
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The sensitivity of the pyranine fluorescence to protonation/deprotonation is used to follow modifications in cured sol-gel thin films. The acid concentration in the sol-gel solution is varied for TEOS-based coatings and a series of organically modified silanes Si(OR)3R’ are added to the TEOS solution. The concentration of the organically modified silane is varied as well as the chain length of the alkylgroup (R’). The stationary fluorescence measurements show that the equilibrium between the protonated and the deprotonated form of pyranine changes depending on the type of silica matrix. The deprotonated form is dominant in the cured SiO2 films and the protonation/deprotonation ratio of pyranine is constant for the different acid concentrations used. The protonated form becomes dominant as the concentration of Si(OR)3R’ is increased and as the alkyl chain length (R’) of the organically modified silanes is augmented. Emission anisotropy measurements of pyranine in the same coatings show that the rotational freedom of the molecule changes due to modifications in the cages for the TEOS-based coatings. These modifications are produced by the acid concentration used to prepare the coatings. An increase in the rotational freedom of pyranine is observed in the TEOS-Si(OR)3R’ systems.
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  • 65
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 931-935 
    ISSN: 1573-4846
    Schlagwort(e): photochromic ; fiber optic ; sol-gel
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Photochromic-doped sol-gel materials have been prepared by adding a spiropyran photochromic dye to a solution of ethoxy silane monomers containing non-reacting ethyl radicals. After polymerization, normal photochromism (i.e., colored material upon UV irradiation) is obtained in the resulting matrix. The sol-gel matrix hinders the organic molecule rotations, thus giving two stable states, which can be reversibly switched by UV and green-blue irradiation respectively. If these materials are attached to optical fibers, the properties of the light throughput may be modified. Simple fiber-optic/photochromic devices made of two optical fibers placed in a V-groove removable connector have been prepared. Once cured, these devices behave as optically addressed variable delay generators. The same devices can be used for preparing simple optical switches and routing systems.
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  • 66
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 947-951 
    ISSN: 1573-4846
    Schlagwort(e): hexagonal ferrites ; thin films ; sol-gel ; magneto-optics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Pure and Co, Ti-substituted hexagonal barium ferrite (BaFe12O19, BaM) films were prepared by the dip-coating method from alkoxides. After repeated dipping, drying and calcining at 500°C for about 15 minutes in an oxygen atmosphere, polycrystalline films with a thickness of 1–1.8 μm on SiO2 substrates were obtained. Spectral dependencies of the Faraday rotation and the optical transmission of BaCo x Ti x Fe12−2x O19(0≤x≤0.8) films were measured in the range from 500 to 2500 nm at room temperature. The absorption coefficient did not display much structure, but specific Faraday rotation spectra of Co, Ti-ferrite films showed local maxima at 720, 1475 and 1750 nm. At those wavelengths, the magneto-optical figure of merit attains its maximum values. For comparison of the crystallization and magnetic properties, Ba(CoTi) x Fe12−2x O19 (x=0.9) powder has also been prepared by the sol-gel method.
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  • 67
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 979-983 
    ISSN: 1573-4846
    Schlagwort(e): fluorescence ; pH ; ruthenium polypyridyl ; sol-gel
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Tetraethoxysilane (TEOS) sol-gel monoliths impregnated with three different luminescent [Ru(L)3]2+ complexes (whereL=2,2′-bipyridine (bpy), 1,10-phenanthroline (phen), or 4,7-diphenyl,1,10-phenanthroline (dpp)) have been prepared. The photoluminescence properties of these complexes were followed as a function of time, as the sol-gel reactions proceeded. Clear differences were observed in the emission energies and the emission lifetimes of the complexes upon gel formation. These differences can be explained by the different extent of electrostatic interaction between the surface of the siloxane polymer and the immobilised complex.
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  • 68
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 991-997 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; optical waveguides ; semiconductor-doped glass ; nonlinear optics ; laser writing
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Sol-gel processes show many promises for the development of low-loss, high-performance glass integrated optical circuits. Special attention is being paid to the preparation of composite glass film, where the properties of organic or inorganic dopant compounds included in the glass matrix are fully exploited. Nonlinear optical glass film waveguides have the potential to become key devices in the future, leading to further technical advances of fiber optic communication systems. This paper briefly reviews current activities in sol-gel glasses for integrated optics, with particular focus on silica-titania and semiconductor-doped films.
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  • 69
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 999-1005 
    ISSN: 1573-4846
    Schlagwort(e): ZrO2 ; sol-gel ; planar waveguide ; Raman scattering
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract ZrO2 waveguides are prepared by the sol-gel process from a solution containing zirconiumn-propoxide and acetylacetone in propanol-2. Structural characterizations are investigated for different annealing temperatures using suitable techniques including Waveguide Raman Spectroscopy, Electron Microscopy and Atomic Force Microscopy. Films are amorphous at 300°C and the pure ZrO2 tetragonal crystalline phase appears beyond 400°C. Crystallized films present a dense, uniform and polycrystalline structure made up by randomly oriented nanocrystallites, the diameter of which increases from 38 Å at 400°C to 53 Å at 600°C. Waveguides are at least monomode TE0 at 632.8 nm. At this wavelength, optical losses are about, 0.8±0.2dB/cm for amorphous layers and increase up to 2.5±0.4 dB/cm for 600°C heat-treated waveguides.
    Materialart: Digitale Medien
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  • 70
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 1013-1016 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; neodymium and erbium doped planar waveguide ; fluorescence lifetime measurement ; phosphorous and aluminium codoping
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A multilayer sol-gel process has been developed in order to make highly doped rare-earth planar waveguides on silica or silicon substrates. Starting with a small range of constituents, such as SiO2, TiO2, P2O5 and Al2O3, we show that a large variety of gel compositions, with different spectroscopic behaviour, can be made when doped with rare-earths. We have doped the sol-gel films with neodymium and we have optimized their compositions by measuring the neodymium fluorescence lifetime. For a composition with 10 atom% of phosphorous, the lifetime evolution with neodymium concentration was studied and a quenching concentration was found at 1% of neodymium. We have also shown the strong influence of phosphorous or aluminium in the sol composition on the fluorescence lifetime, for a given neodymium concentration. First results on similar planar waveguides, doped with erbium, are also presented. The stability of the fluorescence lifetime over a long period of time is an other important point to be checked for these new materials: the lifetime evolution over a 9 months measurement period is presented.
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  • 71
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 947-951 
    ISSN: 1573-4846
    Schlagwort(e): hexagonal ferrites ; thin films ; sol-gel ; magneto-optics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Pure and Co, Ti-substituted hexagonal barium ferrite (BaFe12O19, BaM) films were prepared by the dip-coating method from alkoxides. After repeated dipping, drying and calcining at 500°C for about 15 minutes in an oxygen atmosphere, polycrystalline films with a thickness of 1–1.8 μm on SiO2 substrates were obtained. Spectral dependencies of the Faraday rotation and the optical transmission of BaCoxTixFe12-2xO19 (0 ≤ x ≤ 0.8) films were measured in the range from 500 to 2500 nm at room temperature. The absorption coefficient did not display much structure, but specific Faraday rotation spectra of Co, Ti-ferrite films showed local maxima at 720, 1475 and 1750 nm. At those wavelengths, the magneto-optical figure of merit attains its maximum values. For comparison of the crystallization and magnetic properties, Ba(CoTi)xFe12-2xO19 (x = 0.9) powder has also been prepared by the sol-gel method.
    Materialart: Digitale Medien
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  • 72
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 107-110 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; zinc aluminate ; spinel structure ; catalyst support
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract ZnAl2O4 was prepared by hydrolyzing a mixture of aluminum alkoxide with zinc nitrate dissolved in hexylene glycol and calcining at 800°C. The results are compared with those obtained by wet mixing and coprecipitation. The sol-gel method produces solids whose surface areas and pore volumes are 100% larger and with a more homogeneous pore size distribution.
    Materialart: Digitale Medien
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  • 73
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 425-430 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; thin films ; lead titanate ; microstructure
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A sol-gel route is developed for the synthesis of samarium modified lead titanate precursor solutions. The solutions are used for the deposition of thin films. After thermal treatment of the films, two crystalline phases are observed by X-ray diffraction analysis: an undesirable pyrochlore phase and a ferroelectric perovskite. These two phases are clearly distinguished in the film microstructure, showing a fined grained fraction of pyrochlore anda-axis oriented rosette grains of perovskite. The development of these phases as well as the evolution of the perovskite/pyrochlore ratio in the films is related to the chemistry of the synthesized solutions and the thermal treatment used for crystallization.
    Materialart: Digitale Medien
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  • 74
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 927-929 
    ISSN: 1573-4846
    Schlagwort(e): organic-inorganic hybrids ; sol-gel ; photochromic performance ; spirooxazine
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Organic-inorganic hybrid materials synthesized via sol-gel processing are excellent solid matrices for photochromic dyes like spirooxazine, and the photochromic performance can be further enhanced by introducing suitable additives. This work describes the effects of additives on the photochromic intensity (ΔA 0), decolouration rate (k) and photostability of spirooxazine in sol-gel derived organic-inorganic hybrid matrices. They include fluoroalkylsilane (FAS), bisphenolA (BPA) and methyl-imidazole (MI). FAS enhances both ΔA 0 and photostability, but has little effect onk. The higher the content of BPA, the higher the ΔA 0 and the higher the photostability, but the lower thek. The effect of MI on ΔA 0 andk is not so considerable as that of BPA and is a little complicated, while significant improvement in photostability is achieved by the addition of MI at an optimum concentration with the presence of BPA at a higher content.
    Materialart: Digitale Medien
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  • 75
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 1063-1066 
    ISSN: 1573-4846
    Schlagwort(e): GDLC ; color display ; liquid crystal ; sol-gel
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Liquid crystal microdroplets trapped into silica gel-glasses by sol-gel processes may be used for display applications. Gel-glass dispersed liquid crystals (GDLC) are switched between opaque and transparent states by applying external AC-voltage signals; no polarizers are required. The feasibility of applying these materials to colored displays has been explored. A comparative study of different dyes for GDLC color displays, which were either embedded in the sol-gel matrix or dissolved in the liquid crystal microdroplets is presented.
    Materialart: Digitale Medien
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  • 76
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 1053-1061 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; optical chemical sensor ; waveguide sensor ; fibre optic sensor
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The use of the sol-gel process to produce materials for optical chemical sensors and biosensors is attracting considerable interest. This interest derives mainly from the design flexibility of the sol-gel process and the ease of fabrication. In most applications the sol-gel material is used to provide a microporous support matrix in which analyte-sensitive species are entrapped and into which smaller analyte molecules may diffuse. Sensors based on entrapped organic and inorganic dyes, enzymes and other biomolecules have been reported. A range of sensor configurations has been employed, including monoliths, thin films, as well as more elaborate structures. In this paper a selection is presented of recent significant developments in optical chemical sensors which employ solgel-derived materials. These developments include the tailoring of sol-gel materials to optimise sensor response, advanced waveguide structures and novel probe-tip sensors. Those issues which remain critical to the eventual deployment of sol-gel sensors are examined. In particular, the problems of leaching, microstructural stability, diffusion-limited response time, and susceptibility to interferents are discussed and some solutions proposed.
    Materialart: Digitale Medien
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  • 77
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 1067-1070 
    ISSN: 1573-4846
    Schlagwort(e): cholinesterase ; sol-gel ; pesticide ; THA ; enzyme activity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Biological activity of cholinesterases can be determined by optically monitoring the enzymatic reaction with indophenyl acetate, (N-4′-acetoxyphenyl)-4-quinone imine. At pH 8.0 cholinesterases hydrolyze this yellow dye to yield a blue reaction product. Cholinesterase inhibitors reduce the rate of this hydrolysis. Thus, by monitoring absorbance of the hydrolysis product at its maximum (630 nm) as a function of time, reaction rates of both cholinesterase activity and cholinesterase inhibition may be quantified spectroscopically. Using this technique, we measured the enzymatic activity of butyrylcholinesterase (BuChE) molecules encapsulated in tetramethyl orthosilicate (TMOS) silicate gel-glass prepared by hydrolysis and condensation. This activity is reduced, in a concentration-dependent manner, by the reversible cholinesterase inhibitors 1,5-bis(4-allyldimethyl-ammoniumphenyl) pentan 3-one dibromide (BADAPP) and 9-amino-1,2,3,4-tetrahydroacridine (THA; tacrine, Cognex). The gel-glasses are rigid, and compact, transparent and porous enough to allow reagents to diffuse in and out.
    Materialart: Digitale Medien
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  • 78
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 8 (1997), S. 1121-1125 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; thin films ; oxygen sensor
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Sol-gel-derived silica films were fabricated by dip-coating onto planar and optical fibre substrates. The films were pre-doped with the oxygen-sensitive ruthenium complex [Ru(II)-tris(4,7-diphenyl-1,10-phenanthroline)], whose fluorescence is quenched in the presence of oxygen. The structure and behaviour of sol-gel films is related to the fabrication parameters. In order to optimise the films for oxygen sensing in gaseous and in aqueous media, the quenching behaviour was monitored as a function of dip-speed and water: precursor ratio. By adjusting the above parameters, film properties can be tailored to optimise oxygen quenching in particular concentration ranges and environments.
    Materialart: Digitale Medien
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  • 79
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 9 (1997), S. 5-15 
    ISSN: 1573-4846
    Schlagwort(e): rheology ; sol-gel ; barium titanate
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract BaTiO3 gels were prepared by hydrolysis and polycondensation reactions between titanium isopropoxide and barium hydroxide in presence of methoxyethanol, methanol and water. The rheology of the sol-gel transition was studied with a rheometer allowing low amplitude sinusoidal oscillations. Experimental data show a continuous increase in the complex viscosity along with time, showing the progressive character of the transition. The influence of synthesis operating variables was studied. The gelation time, which definition is based on viscoelastic measurements, increases exponentially when the water content is increased, when the dilution due to the methoxyethanol is reduced or when the temperature is lowered. Different growth models were used for the characterization of the particles in the solution. These models suggest that the polymerisation first produces spherical particles (mass fractals) and that these spherical particles then agglomerate to form a linear network.
    Materialart: Digitale Medien
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  • 80
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 9 (1997), S. 17-24 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; hydroxyapatite ; FT-EPR
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Calcium hydroxyapatite powder was prepared by sol-gel method using calcium acetate and PO(OC2H5)3 as initial compounds, and alcohol (methyl, ethyl, and propyl-alcohol) as solvent. Homogeneous solution and gels were prepared using a molar ratio of Ca/P = 1.67. The evolution of the structure was detected by X-ray diffraction, IR, and FT-n(=1,2,3)D-EPR spectroscopy. The dried gels exhibit a signal characterized by a central line and two satellites. The 2D spectrum (ESEEM vs. field sweep) showed the same modulation for the central line. The FT-EPR spectrum vs. field sweep 2D-spectrum indicated that the satellites are due to an hfs splitting with water. The central region of this 2D spectrum is influenced by P and H in a concentration ratio of [H]/[P]=2.5. The ESEEM spectrum was simulated assuming the equation $$V_{\bmod } = V_{\bmod } (P)^m V_{\bmod } (H)^n $$ for two spin systems S = 1/2 and I = 1/2. This simulation gave for m and n the values of 2 and 5, respectively. This finding suggests the structure: $$\begin{gathered} {\text{ O = P}}---{\text{O}}---{\text{CH}}_{\text{2}} ---{\text{CH}}_{\text{3}} \hfill \\ {\text{ |}} \hfill \\ {\text{ O}} \hfill \\ {\text{O}}---*{\text{P}}---{\text{O}}---{\text{CH}}_{\text{2}} ---{\text{CH}}_{\text{3}} \hfill \\ {\text{ |}} \hfill \\ {\text{ O}} \hfill \\ {\text{ O = P}}---{\text{O}}---{\text{CH}}_{\text{2}} ---{\text{CH}}_{\text{3}} \hfill \\ \end{gathered} $$ for the unpaired state. It appears that one ethyl group does not hydrolyse in the gelation process. The ESEEM spectra of hydroxyapatite exhibit a modulation generated by P, H and Ca atoms.
    Materialart: Digitale Medien
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  • 81
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 9 (1997), S. 65-69 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; cerium ; silica gel ; rehydration
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Cerium is exploited as a probe cation for elucidating the structure of an alkoxide-derived silica gel and its progressive evolution to a glass network as a function of heat-treatment up to 1000°C. At intermediate temperatures, the host structure exhibits inhomogeneity due to insufficient formation of siloxane bonds, which is reflected by at least two different sites and co-ordination spheres (termed “high” and “low” water ligation) for cerium. This is proved by the response of the gels heated up to 700°C to rehydration. Further formation of Si-O-Si network (900°C) leads to the destruction of the “high water” sites of cerium and progression towards a glassy structure. It is, however, only after heat-treatment at 1000°C that a dense silica glass network, not responding to rehydration, is finally obtained with cerium ions embedded in it.
    Materialart: Digitale Medien
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  • 82
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 9 (1997), S. 95-101 
    ISSN: 1573-4846
    Schlagwort(e): SrBi2Ta2O9 ; sol-gel ; thin films ; ferroelectric non-volatile memories
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Phase pure powder and thin films of the novel ferroelectric materials SrBi2Ta2O9 (SBT) have been prepared using the organic precursors. The xero-gel formed was dried and characterized using TGA and DTA to determine the organic burn out and crystallization temperature of SBT. Powder X-ray diffraction was used systematically to check the crystallinity of SBT. Phase pure SBT powder was formed as low as 650°C and thin films at 600°C in comparison to other earlier reported work. SEM micrographs show a grain size of ∼0.1 μm and show crack free films with a film thickness of 2 μm.
    Materialart: Digitale Medien
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  • 83
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 9 (1997), S. 5-15 
    ISSN: 1573-4846
    Schlagwort(e): rheology ; sol-gel ; barium titanate
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract BaTiO3 gels were prepared by hydrolysis and polycondensation reactions between titanium isopropoxide and barium hydroxide in presence of methoxyethanol, methanol and water. The rheology of the sol-gel transition was studied with a rheometer allowing low amplitude sinusoidal oscillations. Experimental data show a continuous increase in the complex viscosity along with time, showing the progressive character of the transition. The influence of synthesis operating variables was studied. The gelation time, which definition is based on viscoelastic measurements, increases exponentially when the water content is increased, when the dilution due to the methoxyethanol is reduced or when the temperature is lowered. Different growth models were used for the characterization of the particles in the solution. These models suggest that the polymerisation first produces spherical particles (mass fractals) and that these spherical particles then agglomerate to form a linear network.
    Materialart: Digitale Medien
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  • 84
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 9 (1997), S. 17-24 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; hydroxyapatite ; FT-EPR
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Calcium hydroxyapatite powder was prepared by sol-gel method using calcium acetate and PO(OC2H5)3 as initial compounds, and alcohol (methyl, ethyl, and propyl-alcohol) as solvent. Homogeneous solution and gels were prepared using a molar ratio of Ca/P=1.67. The evolution of the structure was detected by X-ray diffraction, IR, and FT-n(=1,2,3)D-EPR spectroscopy. The dried gels exhibit a signal characterized by a central line and two satellites. The 2D spectrum (ESEEM vs. field sweep) showed the same modulation for the central line. The FT-EPR spectrum vs. field sweep 2D-spectrum indicated that the satellites are due to an hfs splitting with water. The central region of this 2D spectrum is influenced by P and H in a concentration ratio of [H]/[P]=2.5. The ESEEM spectrum was simulated assuming the equation Vmod=Vmod(P)mVmod(H)n for two spin systems S=1/2 and I=1/2. This simulation gave form andn the values of 2 and 5, respectively. This finding suggests the structure: for the unpaired state. It appears that one ethyl group does not hydrolyse in the gelation process. The ESEEM spectra of hydroxyapatite exhibit a modulation generated by P, H and Ca atoms.
    Materialart: Digitale Medien
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  • 85
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 9 (1997), S. 65-69 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; cerium ; silica gel ; rehydration
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Cerium is exploited as a probe cation for elucidating the structure of an alkoxide-derived silica gel and its progressive evolution to a glass network as a function of heat-treatment up to 1000°C. At intermediate temperatures, the host structure exhibits inhomogeneity due to insufficient formation of siloxane bonds, which is reflected by at least two different sites and co-ordination spheres (termed “high” and “low” water ligation) for cerium. This is proved by the response of the gels heated up to 700°C to rehydration. Further formation of Si−O−Si network (900°C) leads to the destruction of the “high water” sites of cerium and progression towards a glassy structure. It is, however, only after heat-treatment at 1000°C that a dense silica glass network, not responding to rehydration, is finally obtained with cerium ions embedded in it.
    Materialart: Digitale Medien
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  • 86
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 9 (1997), S. 95-101 
    ISSN: 1573-4846
    Schlagwort(e): SrBi2Ta2O9 ; sol-gel ; thin films and ferroelectric non-volatile memories
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Phase pure powder and thin films of the novel ferroelectric materials SrBi2Ta2O9 (SBT) have been prepared using the organic precursors. The xero-gel formed was dried and characterized using TGA and DTA to determine the organic burn out and crystallization temperature of SBT. Powder X-ray diffraction was used systematically to check the crystallinity of SBT. Phase pure SBT powder was formed as low as 650°C and thin films at 600°C in comparison to other earlier reported work. SEM micrographs show a grain size of ≈0.1 μm and show crack free films with a film thickness of 2 μm.
    Materialart: Digitale Medien
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  • 87
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 9 (1997), S. 139-143 
    ISSN: 1573-4846
    Schlagwort(e): Ge nano-crystal ; photoluminescence ; doped glass ; sol-gel
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Ge nanocrystal-embedded SiO2 glasses were prepared by a sol-gel process. The glasses synthesized through the hydrolysis of Si(OC2H5)4 and GeCl4 were heated in H2 gas atmosphere at 500 to 800°C, in which Ge4+ ions were reduced to precipitate nanosized Ge crystals with the size smaller than 10 nm diameter. Glasses doped with Ge nanocrystals of diameter of ∼5nm showed the optical absorption edge at ∼2.8 eV and a broad photoluminescence exhibiting the peak at around 2.2 eV. Large Ge crystals precipitated by heating above 800°C showed no photoluminescence.
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  • 88
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 9 (1997), S. 183-199 
    ISSN: 1573-4846
    Schlagwort(e): KTP ; sol-gel ; non-linear optics ; solution chemistry ; mixed metal oxide
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The solution chemistry and aggregation mechanisms involved in sol-gel synthesis of potassium titanyl phosphate (KTP) are studied in detail. The chemistry of the metal precursors are shown to be critical for the formation of the desired KTP phase. The precursor solution as well as some preparation intermediates were studied by several spectroscopic methods to determine the structure of the organometallic species present in these solutions. The structural evolution taking place in the solution after hydrolysis was studied using photon correlation spectroscopy and small angle X-ray scattering techniques. The influence on the gelation of several preparation parameters such as, the precursors chemistry, the mixing order of the metal alkoxides, the solvent/KTP ratio and the water/KTP molar ratio was also examined.
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  • 89
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 9 (1997), S. 139-143 
    ISSN: 1573-4846
    Schlagwort(e): Ge nano-crystal ; photoluminescence ; doped glass ; sol-gel
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Ge nanocrystal-embedded SiO2 glasses were prepared by a sol-gel process. The glasses synthesized through the hydrolysis of Si(OC2H5)4 and GeCl4 were heated in H2 gas atmosphere at 500 to 800°C, in which Ge4+ ions were reduced to precipitate nanosized Ge crystals with the size smaller than 10 nm diameter. Glasses doped with Ge nanocrystals of diameter of ≈5 nm showed the optical absorption edge at ≈2.8 eV and a broad photoluminescence exhibiting the peak at around 2.2 eV. Large Ge crystals precipitated by heating above 800°C showed no photoluminescence.
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  • 90
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 9 (1997), S. 183-199 
    ISSN: 1573-4846
    Schlagwort(e): KTP ; sol-gel ; nonlinear optics ; solution chemistry ; mixed metal oxide
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The solution chemistry and aggregation mechanisms involved in sol-gel synthesis of potassium titanyl phosphate (KTP) are studied in detail. The chemistry of the metal precursors are shown to be critical for the formation of the desired KTP phase. The precursor solution as well as some preparation intermediates were studied by several spectroscopic methods to determine the structure of the organometallic species present in these solutions. The structural evolution taking place in the solution after hydrolysis was studied using photon correlation spectroscopy and small angle X-ray scattering techniques. The influence on the gelation of several preparation parameters such as, the precursors chemistry, the mixing order of the metal alkoxides, the solvent/KTP ratio and the water/KTP molar ratio was also examined.
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  • 91
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 9 (1997), S. 279-283 
    ISSN: 1573-4846
    Schlagwort(e): AgTCNQ ; photochromism ; sol-gel
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Preparation and photochromic behavior of ormosil containing encapsulated AgTCNQ molecules were studied in this paper. The ormosil resulted from hydrolysis and polycondensation of glycidoxypropyltrimethoxysilane, dimethyldimethoxysilane and methyltrimethoxysilane. The time to add AgNO3 water solution into the resultant sol was a key factor to synthesize AgTCNQ molecules inside ormosil matrix. AgTCNQ molecules encapsulated in the ormosil showed different photochromic behavior compared with pure AgTCNQ film: normal photochromic reaction can be realized, while reverse photochromic reaction can not. The “cage” model was used to explain this phenomenon.
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  • 92
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 10 (1997), S. 91-100 
    ISSN: 1573-4846
    Schlagwort(e): sol-gel ; composite ; substrate ; permittivity ; silica
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Low permittivity ceramic substrates with a sandwich structure consisting of a porous, fiber-reinforced SiO2 core and two thin polymer plates were fabricated by sol-gel processing, and polymer infiltration. The rheological behavior of an aqueous colloidal SiO2 sol, containing short SiO2 fibers was studied as a function of particle loading, fiber loading and gelation time. Short SiO2 fibers were introduced to limit drying shrinkage and thus minimize substrate cracking during drying. After the psuedoplastic sol was tape cast and sintered at 1150°C for 2 h, a polyimide solution was infiltrated into the porous SiO2 core. Permittivities ranging from 1.81 to 3.08 could be obtained by using 32–42% SiO2, 5–50% polyimide and 63 to 8% porosity. The substrate strength was increased from 1.93 MPa to 3.83 MPa after polyimide infiltration.
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  • 93
    Digitale Medien
    Digitale Medien
    Springer
    Plant systematics and evolution 206 (1997), S. 33-45 
    ISSN: 1615-6110
    Schlagwort(e): Compositae ; Barnadesioideae ; Doniophyton ; Chuquiraga ; Argentina ; Chile ; evolution ; systematics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract This revision describes, illustrates and documents morphological variation inDoniophyton (Compositae, Barnadesioideae), restricted to Argentina and Chile. Two species are recognized,D. anomalum andD. weddellii (sp. nova), possessing distinct morphological and chromosomal features, elevational tolerances, and nearly allopatric distributions.Doniophyton weddellii occurs primarily in central to northern Andean Chile and Argentina from 1900–4000 m a. s. l.;D. anomalum is found principally in centralwestern Argentina and south into Patagonia at 0–1800 m a. s. l. Close relationship exists withChuquiraga of subfam.Barnadesioideae. It is hypothesized thatDoniophyton evolved out ofChuquiraga in the high central Andes between Chile and Argentina. It is suggested thatD. weddellii differentiated first, correlating with an aneuploid chromosomal decrease from n = 27 (inChuquiraga) to n = 25. Further evolution and chromosomal decrease to n = 24 resulted inD. anomalum, with accompanying migration into southern Andes and Patagonia. Nomenclatural changes result from examination of protologues and type specimens:Doniophyton anomalum replaces the commonly used nameD. patagonicum, and a new species,D. weddellii, is described for the taxon masquerading under the routinely used superfluous nameD. andicola.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 94
    Digitale Medien
    Digitale Medien
    Springer
    Biology and philosophy 12 (1997), S. 207-224 
    ISSN: 1572-8404
    Schlagwort(e): evolution ; epistemology ; evolutionary epistemology ; naturalized epistemology ; thought experiments ; modality ; utility ; fitness ; adaptation ; reliability ; possible worlds
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Philosophie
    Notizen: Abstract Roy Sorensen advances an evolutionary explanation of our capacity for thought experiments which doubles as a naturalized epistemological justification. I argue Sorensen”s explanation fails to satisfy key elements of environmental-selectionist explanations and so fails to carry epistemic force. I then argue that even if Sorensen succeeds in showing the adaptive utility of our capacity, he still fails to establish its reliability and hence epistemic utility. I conclude Sorensen”s account comes to little more than a “just-so story”.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 95
    Digitale Medien
    Digitale Medien
    Springer
    Biology and philosophy 12 (1997), S. 385-397 
    ISSN: 1572-8404
    Schlagwort(e): morality ; evolution ; error theory
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Philosophie
    Notizen: Abstract Michael Ruse‘s Darwinian metaethics has come under just criticism from Peter Woolcock (1993). But with modification it remains defensible. Ruse (1986) holds that people ordinarily have a false belief that there are objective moral obligations. He argues that the evolutionary story should be taken as an error theory, i.e., as a theory which explains the belief that there are obligations as arising from non-rational causes, rather than from inference or evidential reasons. Woolcock quite rightly objects that this position entails moral nihilism. However, I argue here that people generally have justified true beliefs about which acts promote their most coherent set of moral values, and hence, by definition, about which acts are right. What the evolutionary story explains is the existence of these values, but it is not an error theory for moral beliefs. Ordinary beliefs correspond to real moral properties, though these are not objective or absolute properties independent of anyone‘s subjective states. On its best footing, therefore, a Darwinian metaethics of the type Ruse offers is not an error theory and does not entail moral nihilism.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 96
    Digitale Medien
    Digitale Medien
    Springer
    Journal of porous materials 4 (1997), S. 67-112 
    ISSN: 1573-4854
    Schlagwort(e): pore structure control ; silica gels ; phase separation ; spinodal decomposition ; chromatography ; sol-gel
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau
    Notizen: Abstract In the alkoxy-derived sol-gel system, various macroporous morphologies can be obtained by inducing the phase separation parallel to the sol-gel transition. This principle of macroporous morphology control can be best applied to pure silica and silica-based multicomponent oxide systems. The earlier the phase separation takes place than the sol-gel transition, the larger the characteristic sizes of pores and gel skeletons become. The time resolved light scattering measurements revealed that the morphology formation process exhibits the features of spinodal decomposition and that the final gel morphology is determined by the competitive kinetics between the domain coarsening and the structure freezing by sol-gel transition. The mesopore structure of such macroporous gel skeletons could be easily tailored by the solvent exchange procedures. Silica gels with controlled macropores and mesopores were successfully applied as a material for the continuous rod type column for high performance liquid chromatography.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 97
    Digitale Medien
    Digitale Medien
    Springer
    Evolutionary ecology 11 (1997), S. 301-335 
    ISSN: 1573-8477
    Schlagwort(e): ecological associations ; evolution ; integrative biology ; Opisthobranchia ; resource tracking ; Sacoglossa ; Ulvophyceae
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract Evolution in the opisthobranch order Sacoglossa has been closely linked to their specialized suctorial herbivorous habits. All shelled Sacoglossa (about 20% of the species) feed on one algal genus, Caulerpa. The non-shelled Sacoglossa have 'radiated' to other diets, mainly siphonalean or septate green algae (Class Ulvophyceae). Comparing the phylogeny of sacoglossan genera with the phylogeny of the Ulvophyceae indicates that co-speciation may have taken place at the basal node of the Sacoglossa, and that host switching has taken place several times in the two non-shelled clades. It is suggested that the most important evolutionary process has been speciation by 'resource-tracking'; the resource tracked is most probably cell wall composition of the algal prey. The fossil record of extant sacoglossan genera dates back to the Eocene and, based on the fossil record of siphonalean green algae, the Sacoglossa most likely appeared in the Cretaceous. It is hypothesized that the ancestral sacoglossan was epifaunal, suctorial and herbivorous, and the 'ancestral' food plant was not Caulerpa, but filamentous, calcified, now extinct, Udoteaceae.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 98
    ISSN: 1573-8477
    Schlagwort(e): dispersal ; evolution ; evolutionarily stable strategy ; migrant ; resident ; survival
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract We investigate how age-structure and differences in certain demographic traits between residents and immigrants of a single species act to determine the evolutionarily stable dispersal strategy in a two-patch environment that is heterogeneous in space but constant in time. These two factors have been neglected in previous models of the evolution of dispersal, which generally consider organisms with very simple life-cycles and assume that, whatever their origin, individuals in a given habitat have the same bio-demographic characteristics. However, there is increasing empirical evidence that dispersing individuals have different demographic properties from phylopatric ones. We develop a matrix model in which recruitment depends on local population densities. We assume that dispersal entails a proportional cost to immigrant fecundity, which can be compensated by differences in survival rates between immigrants and residents. The evolutionarily stable strategies (ESS) for dispersal are identified using a combination of analytical expressions and numerical simulations. Our results show that philopatry is selected (1) when dispersal rates do not vary in space, (2) when the metapopulation is a source-sink system and (3) when dispersal rates vary in space (asymmetric dispersal) and immigrants do not compensate for their reduced fecundity. We observe that non-zero asymmetric dispersal rates may be evolutionarily stable when (1) immigrants and residents are demographically alike and (2) immigrants compensate totally for their reduced fecundity through an increase in adult survival. Under these conditions, we find that the ESS occurs when the fitnesses at equilibrium in the two habitats, measured in our model by the realized reproductive rates, are each equal to unity. A comparison with previous studies suggests a unifying rule for the evolution of dispersal: the dispersal rates which permit the spatial homogenization of fitnesses are ESSs. This condition provides new insight into the evolutionary stability of source-sink systems. It also supports the hypothesis that immigrants have adapted demographic strategies, rather than the hypothesis that dispersal is costly and immigrants are at a disavantage compared with residents.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 99
    Digitale Medien
    Digitale Medien
    Springer
    Hydrobiologia 365 (1997), S. 33-46 
    ISSN: 1573-5117
    Schlagwort(e): Phylogeny ; cladistics ; taxonomy ; systematics ; classification ; evolution ; history ; chronicle ; Nemertea ; Hoplonemertea
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract I review how some influential nemertean systematistshave perceived and illustrated phylogenetic trees andargue that the nineteenth century nemerteantaxonomists still influence many contemporarynemertean taxonomists to a high degree. By showing hownineteenth century systematics differs from moremodern views on trees, I hope to convey the advantagesof a cladistic approach to tree-thinking and nemerteansystematics. Furthermore I propose a systematizationof the Eureptantia that illustrates the cladisticapproach to tree-thinking but, more importantly, isalso a better representation of eureptantic phylogenythan previous classifications.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 100
    ISSN: 1573-3297
    Schlagwort(e): Aggression ; nest-building behavior ; wild house mice ; behavioral strategies ; bidirectional selection ; Y chromosome ; evolution
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Psychologie
    Notizen: Abstract This study takes the first step toward testing a Y chromosomal effect on both aggression and thermoregulatory nest-building behavior in mouse lines either bidirecrionally selected for short (SAL) and long (LAL) attack latency or high (HIGH) and low (LOW) nest-building behavior. Using reciprocal crosses between SAL and LAL, and between HIGH and LOW, we found no indications for Y chromosomal effects on thermoregulatory nest-building behavior. As for aggression, we confirmed earlier studies on SAL and LAL, i.e., the origin of the Y chromosome influences attack latency, i.e., aggression. However, we did not find indications for a Y chromosomal effect on aggression in the HIGH and LOW lines. Since aggression and nest-building behavior have been shown to be characteristic parameters of two fundamentally different behavioral strategies, the present data underline the improbability of Y chromosomal genes underlying the genetic architecture of alternative behavioral strategies.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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